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HomeMy WebLinkAboutWI0600234_Permit (Issuance)_20211207 (2)North Carolina Department of Environmental Quality — Division of Water Resources NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are "permitted by rule" and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C.0200 (NOTE: This form must be received at least 14 DAYS prior to injection) AQUIFER TEST WELLS (15A NCAC 02C .0220) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION (15A NCAC 02C .0225) or TRACER WELLS (15A NCAC 02C .0229): 1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be submitted for replacement of each sock used in ORC systems). 2) Small -Scale Injection Operations — Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells are located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater. Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete. DATE: November 22, 2021 PERMIT NO. A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (to be filled in by DWR) (1) Air Injection Well ....Complete sections B through F, K, N (2) Aquifer Test Well Complete sections B through F, K, N (3) X Passive Injection System Complete sections B through F, H-N (4) Small -Scale Injection Operation Complete sections B through N (5) Pilot Test Complete sections B through N (6) Tracer Injection Well Complete sections B through N B. STATUS OF WELL OWNER: State Government C. WELL OWNER(S) — State name of Business/Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name(s): NCDEQ-DWM, UST Section, Federal & State Lead Program; Attn: Hassan Osman Mailing Address: 1646 Mail Service Center City: Raleigh State: NC Zip Code: 27699-1646 County: Wake Day Tele No.: 919-707-8167 Cell No.: NA EMAIL Address: Hassan.Osman@ncdenr.gov Fax No.: 919-715-1117 Deemed Permitted GW Remediation NOI Rev. 1-06-2021 Page 1 D. PROPERTY OWNER(S) (if different than well owner/applicant) Name and Title: Paige Raquel Oxendine, Property Owner Company Name Mailing Address: PO Box 1410 Rd City: Pembroke State: NC Zip Code: 28372 County: Robeson Day Tele No.: 910-736-1562 Cell No.: EMAIL Address: Fax No.: E. PROJECT CONTACT (Typically Environmental Engineering Firm) Name and Title: G. Matthew James, P.G., Project Manager Company Name WithersRavenel, Inc. Mailing Address: 115 MacKenan Drive City: Cary State: NC Zip Code: 27511 County: Wake Day Tele No.: 919-469-3340 Cell No.: EMAIL Address: mjames@withersravenel.com F. PHYSICAL LOCATION OF WELL SITE Fax No.: 919-467-6008 (1) Facility Name & Address: Former Country Store & Feed (JECO Kwik Stop) — 7828 Deep Branch Rd, Pembroke, NC; NCDEQ Incident #7605 City: Pembroke County: Robeson Zip Code: 28372 (2) Geographic Coordinates: Well MW-4R : Latitude**: 34.663702° Longitude**: -79.197415° Reference Datum: Google Earth Accuracy: +/- 5m Method of Collection: Google Earth **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume square feet Land surface area of inj. well network: square feet (< 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: (must be < 5% of plume for pilot test injections) H. INJECTION ZONE MAPS — Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. Deemed Permitted GW Remediation NOI Rev. 1-06-2021 Page 2 DESCRIPTION OF PROPOSED INJECTION ACTIVITIES — Provide a brief narrative regarding the purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration of injection over time. a. Purpose: The purpose of this passive injection (installation of two RemRx Persulfate Extended - Release Oxidant (XRO) In Situ Chemical Oxidation sleeves) in MW-4R is to further reduce the concentrations of dissolved phase contaminants (BTEX) to further reduce values below the Gross Contaminant Levels to reach site closure. b. Scope: The scope of this passive injection event will be to install two 2.5-ft RemRx XRO sleeves into MW-4R. The sleeves will remain in place until the site is sampled in March of 2022 (approximately 3 months). c. Goals: The goal of using the Rem RX XRO sleeves is to further reduce the dissolved phase contaminant concentrations in groundwater in the vicinity of MW-4R over an approximately 3 month period. J. APPROVED INJECTANTS — Provide a MSDS for each injectant (attach additional sheets if necessary). NOTE: Only injectants approved by the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at http://deq.nc.gov/about/divisions/water- resources/water-resources-permits/wastewater-branch/ground-water-protection/ground-water-approved-inj ectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919- 807-6496). Injectant: RemRx XRO In Situ Chemical Oxidation Sleeves Volume of injectant: Two 2.5-ft sleeves Concentration at point of injection: Percent if in a mixture with other injectants: Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: Inj ectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: K. WELL CONSTRUCTION DATA (1) Number of injection wells: 0 Proposed 1 Existing (provide GW-1s) (2) For Proposed wells or Existing wells not having GW-1 s, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as -built): Deemed Permitted GW Remediation NOI Rev. 1-06-2021 Page 3 L. SCHEDULES — Briefly describe the schedule for well construction and injection activities. The monitoring well (MW-4R) that the RemRx XRO sleeves will be installed in was constructed on 10/4/2021. Two sleeves will be placed in this monitoring well in early January and remain there for approximately 3-months to allow for the dissolved phase contaminants in groundwater in the vicinity of the well to be further reduced in an effort to advance the site towards closure. M. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. WR will advise the NCDEQ incident manager that the sleeves should be removed in March 2022 and the site should be sampled following the removal of the sleeves. N. SIGNATURE OF APPLICANT AND PROPERTY OWNER Well Owner/Applicant: `I hereby certify, under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the 15A NCAC 02C 0200 Rules." G. Matthew James, PG, Project Manager, WithersRavenel, On behalf on NCDEQ-DWM for Incident # 31314 Signature of Applicant Print or Type Full Name and Title Property Owner (if the property is not owned by the Well Owner/Applicant): "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C .0200)." "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. SEE ATTACHED NCDEQ STATE -LEAD ACCESS AGREEMENT FOR PROPERTY Signature* of Property Owner (if different from applicant) Print or Type Full Name and Title *An access agreement between the applicant and property owner may be submitted in lieu of a signature on this form. Please send 1 (one) hard color copy of his NOI along with a copy on an attached CD or Flash Drive at least two (2) weeks prior to injection to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 807-6464 Deemed Permitted GW Remediation NOI Rev. 1-06-2021 Page 4 LEGEND TYPE II MONITORING WELL LOCATION TYPE III MONITORING WELL LOCATION FORMER UST PIT LOCATION (APPROXIMATE) [___] FORMER DISPENSER ISLAND (APPROXIMATE) — • — WATER LINE (APPROXIMATE) I1v BTEX ISOCONCENTRATION (DASHED WHERE APPROXIMATE) NOTES: 1.) AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT. 2.) UST PIT AND PUMP ISLAND APPROXIMATED FROM SEPTEMBER 1997 WELL SURVEY / SAMPLING RESULTS REPORT BY S&ME. 3.) BTEX CONCENTRATIONS ARE FROM THE MOST RECENT SAMPLING EVENTS THAT EACH WELL WAS SAMPLED IN. MW- } WithersRavenel Engineers I Planners I Surveyors 115 MacKenan Drive I Cary, NC 27511 I t: 919.469.3340 I license #: C-0832 I COUNTRY STORE & FEED INC. # 7605 7828 DEEP BRANCH ROAD PEMBROKE, ROBESON COUNTY, NC MW-15.. (5,743.6 ug/L) BTEX ISOCONCENTRATION MAP ( GRAPHIC LE 25 50 1 inch = 5Q DRAWN BY: SCALE: FIGURE NO DV 1"=50' 1 APPROVED BY: DATE: PROJECT NO.: MJ 11/22/2021 02172214.45 Kavi n-znovral+.4a-r1mEa - Country 90n FAMIW NOWADozlnal+.4e Wr10a1.ma2ap- Pawner 22. 2221 - VAL. WM 1. Identification Product identifier Other means of identification SDS number CAS number Recommended use Recommended restrictions SAFETY DATA SHEET CAIROX® potassium permanganate 7722-64-7 Potassium Permanganate is an oxidant recommended for applications that require a strong oxidant. Use in accordance with supplier's recommendations. Manufacturer/Importer/Supplier/Distributor information Company name CARUS CORPORATION Address 315 Fifth Street, Peru, IL 61354, USA Telephone +1 815 223-1500 - All other non -emergency inquiries about the product should be directed to the company E-mail salesmkt@caruscorporation.com Website www.caruscorporation.com Contact person Shelley Corban Emergency Telephone For Hazardous Materials [or Dangerous Goods] Incidents ONLY (spill, leak, fire, exposure or accident), call CHEMTREC at CHEMTREC®, USA: 001 (800) 424-9300 CHEMTREC®, Mexico (Toll -Free - must be dialed from within country): 01-800-681-9531 CHEMTREC®, Other countries: 001 (703) 527-3887 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards Oxidizing solids Category 2 Acute toxicity, oral Category 4 Skin corrosion/irritation Category 1C Serious eye damage/eye irritation Category 1 Specific target organ toxicity, repeated Category 2 (Liver) exposure Hazardous to the aquatic environment, acute Category 1 hazard Hazardous to the aquatic environment, Category 1 long-term hazard OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement May intensify fire; oxidizer. Harmful if swallowed. Causes severe skin burns and eye damage. May cause damage to organs (Liver) through prolonged or repeated exposure by ingestion. Very toxic to aquatic life with long lasting effects. CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 1/10 Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Keep away from heat. Keep/Store away from clothing and other combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Avoid release to the environment. In case of fire: Use water for extinction. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Get medical advice/attention if you feel unwell. Wash contaminated clothing before reuse. Collect spillage. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. None. 3. Composition/information on ingredients Substances Chemical name Common name and synonyms CAS number Potassium permanganate 7722-64-7 > 97.5 Composition comments 4. First -aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire -fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Remove victim to fresh air and keep at rest in a position comfortable for breathing. For breathing difficulties, oxygen may be necessary. Get medical attention immediately. Take off immediately all contaminated clothing. Immediately flush skin with plenty of water. Get medical attention immediately. Wash contaminated clothing before reuse. Contact with skin may leave a brown stain of insoluble manganese dioxide. This can be easily removed by washing with a mixture of equal volume of household vinegar and 3% hydrogen peroxide, followed by washing with soap and water. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids wide apart. Continue rinsing. Get medical attention immediately. Immediately rinse mouth and drink plenty of water. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical attention immediately. Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent eye damage including blindness could result. Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Decomposition products are alkaline. Brown stain is insoluble manganese dioxide. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. For personal protection, see Section 8 of the SDS. Wash contaminated clothing before reuse. Flood with water from a distance, water spray or fog. The following extinguishing media are ineffective: Dry chemical. Foam. Carbon dioxide (CO2). Halogenated materials. May intensify fire; oxidizer. May ignite combustibles (wood, paper, oil, clothing, etc.). Contact with incompatible materials or heat (135 °C / 275 °F) could result in violent exothermic chemical reaction. Oxidizing agent, may cause spontaneous ignition of combustible materials. By heating and fire, corrosive vapors/gases may be formed. During fire, gases hazardous to health may be formed such as: Carbon oxides (COx). Metal oxides. CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 2/10 Special protective equipment and precautions for firefighters Fire fighting equipment/instructions General fire hazards Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Dike fire control water for later disposal. Water runoff can cause environmental damage. The product is not flammable. May intensify fire; oxidizer. May ignite combustibles (wood, paper, oil, clothing, etc.). Contact with incompatible materials or heat (135 °C / 275 °F) could result in violent exothermic chemical reaction. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Keep unnecessary personnel away. Keep upwind. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors and contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Local authorities should be advised if significant spillages cannot be contained. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Should not be released into the environment. This product is miscible in water. Stop leak if possible without any risk. Dike the spilled material, where this is possible. Clean up spills immediately by sweeping or shoveling up the material. Do not return spilled material to the original container; transfer to a clean metal or plastic drum. To clean up potassium permanganate solutions, follow either of the following two options: Option # 1: Dilute to approximately 6% with water, and then reduce with sodium thiosulfate, a bisulfite or ferrous salt solution. The bisulfite or ferrous salt may require some dilute sulfuric acid (10% w/w) to promote reduction. Neutralize with sodium carbonate to neutral pH, if acid was used. Decant or filter and deposit sludge in approved landfill. Where permitted, the sludge may be drained into sewer with large quantities of water. Option # 2: Absorb with inert media like diatomaceous earth or inert floor dry, collect into a drum and dispose of properly. Do not use saw dust or other incompatible media. Disposal of all materials shall be in full and strict compliance with all federal, state, and local regulations pertaining to permanganates. To clean contaminated floors, flush with abundant quantities of water into sewer, if permitted by federal, state, and local regulations. If not, collect water and treat as described above. Never return spills in original containers for re -use. For waste disposal, see Section 13 of the SDS. Do not allow to enter drains, sewers or watercourses. Contact local authorities in case of spillage to drain/aquatic environment. Take any precaution to avoid mixing with combustibles. Do not get this material in your eyes, on your skin, or on your clothing. Do not breathe dust or mist or vapor of the solution. Use personal protection as recommended in Section 8 of the SDS. If clothing becomes contaminated, remove and wash off immediately. When using, do not eat, drink or smoke. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Avoid release to the environment. Store locked up. Keep container tightly closed and in a well -ventilated place. Store in a cool, dry place. Store away from incompatible materials (See Section 10). Store in accordance with local/regional/national/international regulation. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Potassium permanganate Ceiling 5 mg/m3 (CAS 7722-64-7) US. ACGIH Threshold Limit Values Material Type Value Form CAIROX® potassium permanganate TWA 0.1 mg/m3 lnhalable fraction. 0.02 mg/m3 Respirable fraction. CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 3/10 US. ACGIH Threshold Limit Values Components Type Value Form Potassium permanganate TWA 0.1 mg/m3 Inhalable fraction. (CAS 7722-64-7) US. NIOSH: Pocket Guide to Chemical Hazards Material Type 0.02 mg/m3 Respirable fraction. Value Form CAIROX® potassium permanganate Components TWA Type 1 mg/m3 Fume. Value Form Potassium permanganate (CAS 7722-64-7) Biological limit values Exposure guidelines Appropriate engineering controls STEL 3 mg/m3 Fume. TWA 1 mg/m3 Fume. No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. Provide adequate general and local exhaust ventilation. An eye wash and safety shower must be available in the immediate work area. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Skin protection Other Respiratory protection Thermal hazards General hygiene considerations Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes. Wear chemical -resistant, impervious gloves. Use protective gloves made of: Rubber or plastic. Suitable gloves can be recommended by the glove supplier. Wear appropriate chemical resistant clothing. Rubber or plastic apron. In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment with particle filter. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR 1910.134. Measurement Element: Manganese (Mn) 10 mg/m3 Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter -mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any supplied -air respirator. 25 mg/m3 Any supplied -air respirator operated in a continuous -flow mode. Any powered, air -purifying respirator with a high -efficiency particulate filter. 50 mg/m3 Any air -purifying, full -face piece respirator equipped with an N100, R100, or P100 filter. Any supplied -air respirator with a tight -fitting face piece that is operated in a continuous -flow mode. Any powered, air -purifying respirator with a tight -fitting face piece and a high -efficiency particulate filter. Any self-contained breathing apparatus with a full face piece. Any supplied -air respirator with a full face piece. 500 mg/m3 Any supplied -air respirator operated in a pressure -demand or other positive -pressure mode. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full face piece and is operated in a pressure -demand or other positive -pressure mode. Escape Any air -purifying, full -face piece respirator equipped with an N100, R100, or P100 filter. Any appropriate escape -type, self-contained breathing apparatus. Wear appropriate thermal protective clothing, when necessary. When using, do not eat, drink or smoke. Keep from contact with clothing and other combustible materials. Remove and wash contaminated clothing promptly. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 4/10 9. Physical and chemical properties Appearance Physical state Form Color Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Dark purple solid with metallic luster. Solid. Solid. Dark purple. Odorless. Not available. Not applicable. Starts to decompose with evolution of oxygen (02) at temperatures above 150 °C. Once initiated, the decomposition is exothermic and self sustaining. Not applicable. Not applicable. Not applicable. Non flammable. Upper/lower flammability or explosive limits Flammability limit - lower Not applicable. (%) Flammability limit - upper Not applicable. (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto -ignition temperature Decomposition temperature Viscosity Other information Density Explosive properties Molecular formula Molecular weight Oxidizing properties 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Not available. Not available. Not applicable. Not applicable. 2.7 (20 °C) ( Water = 1) 6 % (20 °C) Not available. Not available. 464 °F (240 °C) Not applicable. 2.70 g/cm3 Not explosive. Can explode in contact with sulfuric acid, peroxides and metal powders. H-M n-04. K 158.03 g/mol Strong oxidizing agent. The product is stable and non -reactive under normal conditions of use, storage and transport. Stable at normal conditions. Contact with combustible material may cause fire. Can explode in contact with sulfuric acid, peroxides and metal powders. Starts to decompose with evolution of oxygen (02) at temperatures above 150 °C. Once initiated, the decomposition is exothermic and self sustaining. Contact with incompatible materials or heat (135 °C / 275 °F) could result in violent exothermic chemical reaction. Acids. Peroxides. Reducing agents. Combustible material. Metal powders. Contact with hydrochloric acid liberates chlorine gas. By heating and fire, corrosive vapors/gases may be formed. CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 5/10 11. Toxicological information Information on likely routes of exposure Inhalation Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Harmful if swallowed. Components Species May cause respiratory irritation. Causes severe skin burns. Causes serious eye damage. Harmful if swallowed. Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent eye damage including blindness could result. Test Results Potassium permanganate (CAS 7722-64-7) Acute Dermal LD50 Rat 2000 mg/kg Oral LD50 Rat 2000 mg/kg Skin corrosion/irritation Causes severe skin burns. Serious eye damage/eye irritation Causes serious eye damage. Respiratory or skin sensitization Respiratory sensitization Not classified. Skin sensitization Not classified. Germ cell mutagenicity Not classified. Carcinogenicity Not classified. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. NTP Report on Carcinogens Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not regulated. Reproductive toxicity Not classified. Specific target organ toxicity - Not classified. single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Not classified. Chronic effects May cause damage to organs (Liver) through prolonged or repeated exposure by ingestion. May cause damage to respiratory system. Prolonged exposure, usually over many years, to manganese oxide fume/dust can lead to chronic manganese poisoning, chiefly affecting the central nervous system. 12. Ecological information Ecotoxicity Very toxic to aquatic life with long lasting effects. Components Species Test Results Potassium permanganate (CAS 7722-64-7) Aquatic Fish LC50 Bluegill (Lepomis macrochirus) Carp (Cyprinus carpio) 2.7 mg/I, 96 hours static 2.3 mg/I, 96 hours flow through 2.3 mg/I, 96 hours 1.8 - 5.6 mg/I 3.16 - 3.77 mg/I, 96 hours CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 6/10 Components Species Test Results Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Goldfish (Carassius auratus) Milkfish, salmon -herring (Chanos chanos) Rainbow trout (Oncorhynchus mykiss) 2.97 - 3.11 mg/I, 96 hours 3.3 - 3.93 mg/I, 96 hours static > 1.4 mg/I, 96 hours 1.8 mg/I, 96 hours 1.08 - 1.38 mg/I, 96 0.77 - 1.27 mg/I, 96 hours hours Expected to be readily converted by oxidizable materials to insoluble manganese oxide. Potential to bioaccumulate is low. The product is miscible with water. May spread in water systems. None known. 13. Disposal considerations Disposal instructions Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Dispose of contents/container in accordance with local/regional/national/international regulations. D001: Ignitable waste The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Do not allow this material to drain into sewers/water supplies. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Rinse container at least three times to an absence of pink color before disposing. Empty containers should be taken to an approved waste handling site for recycling or disposal. UN 1490 Potassium permanganate 5.1 5.1 I I Yes Read safety instructions, SDS and emergency procedures before handling. IB8, IP2, IP4, T3, TP33 152 212 240 UN 1490 Potassium permanganate 5.1 I I Yes 5L Read safety instructions, SDS and emergency procedures before handling. UN 1490 POTASSIUM PERMANGANATE 5.1 I I CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 7/10 Environmental hazards Marine pollutant Yes EmS F-H, S-Q Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code General information IMDG Regulated Marine Pollutant. DOT Regulated Marine Pollutant. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. Drug Enforcement Administration (DEA) (21 CFR 1310.02 (b) 8: List II chemical. Department of Homeland Security (DHS) Chemical Facility Anti -Terrorism Standards (6 CFR 27, Appendix A): Listed. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Potassium permanganate (CAS 7722-64-7) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical Classified hazard Oxidizer (liquid, solid, or gas) categories Acute toxicity (any route of exposure) Skin corrosion or irritation Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) SARA 313 (TRI reporting) Chemical name CAS number % by wt. Potassium permanganate 7722-64-7 > 97.5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Potassium permanganate (CAS 7722-64-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Clean Water Act (CWA) Hazardous substance Section 112(r) (40 CFR 68.130) Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Potassium permanganate (CAS 7722-64-7) 6579 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Potassium permanganate (CAS 7722-64-7) 15 %WT DEA Exempt Chemical Mixtures Code Number Potassium permanganate (CAS 7722-64-7) 6579 CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 8/10 US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. California OSH Hazardous Substance List: Listed. US. Massachusetts RTK - Substance List Potassium permanganate (CAS 7722-64-7) US. New Jersey Worker and Community Right -to -Know Act Potassium permanganate (CAS 7722-64-7) US. Pennsylvania Worker and Community Right -to -Know Law Potassium permanganate (CAS 7722-64-7) US. Rhode Island RTK Not regulated. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # HMIS® ratings NFPA ratings List of abbreviations 27-November-2013 24-April-2018 04 Health: 3 Flammability: 0 Physical hazard: 1 GHS: Globally Harmonized System of Classification and Labeling of hazardous properties of Chemicals. TWA: Time weighted average. LD50: Lethal Dose, 50%. LC50: Lethal Concentration, 50%. IMDG: International Maritime Dangerous Goods. IATA: International Air Transport Association. MARPOL: International Convention for the Prevention of Pollution from Ships. CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 9/10 References Disclaimer HSDB® - Hazardous Substances Data Bank Registry of Toxic Effects of Chemical Substances (RTECS) IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices The information contained herein is accurate to the best of our knowledge. However, data, safety standards and government regulations are subject to change and, therefore, holders and users should satisfy themselves that they are aware of all current data and regulations relevant to their particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN. CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions relating to storage, handling, and use of the product are beyond the control of Carus Corporation, and shall be the sole responsibility of the holder or user of the product. (Carus and design) is a registered service mark of Carus Corporation. CAIROX® is a registered trademark of Carus Corporation. CAIROX® potassium permanganate 907273 Version #: 04 Revision date: 24-April-2018 Issue date: 27-November-2013 SDS US 10 / 10 SAFETY DATA SHEET Sodium Persulfate SDS # : 7775-27-1 Revision date: 2018-07-13 Format: NA Version 1.04 FeroxyChem 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name CAS -No Synonyms Sodium Persulfate 7775-27-1 Sodium Peroxydisulfate; Disodium Peroxydisulfate; Peroxydisulfuric acid, disodium salt; Peroxydisulfuric acid, sodium salt. Recommended use of the chemical and restrictions on use Recommended Use: Polymerization initiator; Etchant and cleaner for printed circuit boards; Hair bleaching formulations; Secondary oil recovery; Oxidizing agent for a variety of organic reactions. Restrictions on Use No uses to be advised against were identified. Manufacturer/Supplier Emergency telephone numbers PeroxyChem LLC 2005 Market Street Suite 3200 Philadelphia, PA 19103 Phone: +1 267/ 422-2400 (General Information) E-Mail: sdsinfo@peroxychem.com For leak, fire, spill or accident emergencies, call: 1 800 / 424 9300 (CHEMTREC - U.S.A.) 1 703 / 527 3887 (CHEMTREC - Collect - All Other Countries) 1 303/ 389-1409 (Medical - U.S. - Call Collect) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2B Respiratory sensitization Category 1 Skin sensitization Category 1 Specific target organ toxicity (single exposure) Category 3 Oxidizing Solids Category 3 Page 1 / 9 Sodium Persulfate SDS # : 7775-27-1 Revision date: 2018-07-13 Version 1.04 GHS Label elements, including precautionary statements EMERGENCY OVERVIEW Danger Hazard Statements H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation H319 - Causes serious eye irritation H315 - Causes skin irritation H317 - May cause an allergic skin reaction H302 - Harmful if swallowed H272 - May intensify fire; oxidizer Precautionary Statements - Prevention P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray P285 - In case of inadequate ventilation wear respiratory protection P271 - Use only outdoors or in a well -ventilated area P280 - Wear protective gloves/ protective clothing P264 - Wash face, hands and any exposed skin thoroughly after handling P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P220 - Keep/Store away from clothing/combustible materials P221 - Take any precaution to avoid mixing with combustibles Precautionary Statements - Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/ attention P302 + P352 - IF ON SKIN: Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice/ attention P362 - Take off contaminated clothing and wash before reuse P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell P330 - Rinse mouth P370 + P378 - In case of fire: Use water for extinction Precautionary Statements - Storage P403 + P235 - Store in a well -ventilated place. Keep cool Hazards not otherwise classified (HNOC) No hazards not otherwise classified were identified. Other Information Risk of decomposition by heat or by contact with incompatible materials Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity Page 2 / 9 Sodium Persulfate SDS # : 7775-27-1 Revision date: 2018-07-13 Version 1.04 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Na2O8S2 Chemical name CAS -No Weight % Sodium Persulfate 7775-27-1 > 99 Sodium sulfate 7757-82-6 < 1 4. FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed, if necessary Remove from exposure, lie down. Show this material safety data sheet to the doctor in attendance. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids intermittently. Consult a physician. In case of contact, immediately flush eyes with plenty of water. If symptoms persist, call a physician. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation develops and persists. Remove from exposure, lie down. If breathing is irregular or stopped, administer artificial respiration. Call a physician immediately. Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Drink 1 or 2 glasses of water. Itching; Redness; Coughing and/ or wheezing. Treat symptomatically 5. FIRE -FIGHTING MEASURES Suitable Extinguishing Media Unsuitable extinguishing media Specific Hazards Arising from the Chemical Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Protective equipment and precautions for firefighters Water. Cool containers with flooding quantities of water until well after fire is out. Do not use carbon dioxide or other gas filled fire extinguishers; they will have little effect on decomposing persulfate. Decomposes under fire conditions to release oxygen that intensifies the fire. Not sensitive. Not sensitive. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Other Keep off any unprotected persons. Avoid contact with the skin and the eyes. Avoid breathing dust. Wear personal protective equipment. Never add other substances or combustible waste to product residues. Page 3 / 9 Sodium Persulfate Environmental Precautions Methods for Containment Methods for cleaning up SDS # : 7775-27-1 Revision date: 2018-07-13 Version 1.04 Knock down dust with water spray. Avoid penetration into waterways, sewers, soil or groundwater. Local authorities should be advised if significant spillages cannot be contained. Vacuum, shovel or pump waste into a drum and label contents for disposal. Avoid dust formation. Store in closed container. Clean up spill area and treat as special waste. Dispose of waste as indicated in Section 13. 7. HANDLING AND STORAGE Handling Storage Incompatible products Wear personal protective equipment. Avoid breathing dust. Handle product only in closed system or provide appropriate exhaust ventilation at machinery. Avoid contact with skin and eyes. Remove and wash contaminated clothing before re -use. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep away from heat. Do not store near combustible materials. Avoid contamination of opened product. Keep away from food, drink and animal feedingstuffs. Avoid formation and deposition of dust. Acids. Bases, Halides, Oxidizing agents, Strong reducing agents, Combustible materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH Mexico Sodium Persulfate 7775-27-1 TWA: 0.1 mg/m3 - - - Chemical name British Columbia Quebec Ontario TWAEV Alberta Sodium Persulfate 7775-27-1 TWA: 0.1 mg/m3 - TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 Appropriate engineering controls Engineering measures Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Hand Protection Respiratory Protection Hygiene measures Eye protection recommended. Chemical goggles consistent with EN 166 or equivalent. Wear long-sleeved shirt, long pants, socks, and shoes. Protective gloves: Neoprene gloves, Polyvinylchloride, Natural Rubber. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn: particulate filtering facepiece respirators. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Wash hands before breaks and after shifts. Keep work clothes separate, remove contaminated clothing - launder after open handling of product. General information Protective engineering solutions should be implemented and in use before personal protective equipment is considered. Page 4 / 9 Sodium Persulfate SDS # : 7775-27-1 Revision date: 2018-07-13 Version 1.04 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Physical State Color Odor Odor threshold pH Melting point/freezing point Boiling Point/Range Flash point Evaporation Rate Flammability (solid, gas) Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Density Specific gravity Water solubility Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Molecular weight VOC content (%) Bulk density Crystalline solid Solid White odorless Not applicable 6.0 (1% solution) 180 °C (Decomposes) Decomposes on heating Not flammable Not applicable Not flammable Not applicable No information available No information available 6.07E-30 mm Hg at 25°C No information available 2.59 g/cm3 (crystal density) No information available 42 % @ 25 °C No information available No information available No evidence of combustion up to 600°C > 100 °C (assume) No information available (Solid) No information available Not explosive oxidizer 238.1 Not applicable 1.12 g/cm3 (loose) 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Possibility of Hazardous Reactions Hazardous polymerization Conditions to avoid Incompatible materials Strong oxidizer. Oxidizer. Contact with other material may cause fire. Decomposition can occur on exposure to heat or moisture. Use of persulfates in chemical reactions requires appropriate precautions and design considerations for pressure and thermal relief. Decomposing persulfates will evolve large volumes of gas and/or vapor, can accelerate exponentially with heat generation, and create significant and hazardous pressures if contained and not properly controlled or mitigated. Use with alcohols in the presence of water has been demonstrated to generate conditions that require rigorous adherence to process safety methods and standards to prevent escalation to an uncontrolled reaction. Hazardous polymerization does not occur. Heat. (decomposes at 275 °C); Moisture. Bases, Halides, Oxidizing agents, Strong reducing agents, Combustible materials. Acids. Hazardous Decomposition Products Oxygen which supports combustion; Sulfur oxides. 11. TOXICOLOGICAL INFORMATION Product Information Page 5/9 Sodium Persulfate Unknown acute toxicity LD50 Oral LD50 Dermal LC50 Inhalation Serious eye damage/eye irritation Skin corrosion/irritation Sensitization Component Information 0% of the mixture consists of ingredient(s) of unknown toxicity 895 920 mg/kg (rat) (Sodium Persulfate) > 10,000 mg/kg (rabbit) (Sodium Persulfate) > 5.1 mg/L (rat) (4-hr) (Sodium Persulfate) Irritating to eyes. Minimally irritating. Sensitizing to skin and respiratory system. SDS # : 7775-27-1 Revision date: 2018-07-13 Version 1.04 Chemical name LD50 Oral LD50 Dermal LC50 Inhalation NOAEL Oral Value Sodium Persulfate (7775-27-1) 895 mg/kg ( Rat) > 10000 mg/kg ( Rabbit) > 21.6 mg/L ( Rat ) 4 h Sodium sulfate (7757-82-6) > 10000 mg/kg ( Rat ) Information on toxicological effects Symptoms Symptoms of allergic reaction may include rash, itching, swelling and trouble breathing. Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation corrosivity Carcinogenicity Mutagenicity Reproductive toxicity STOT - single exposure STOT - repeated exposure Subchronic toxicity Target organ effects Aspiration hazard Irritating to eyes, respiratory system and skin. None. Did not show carcinogenic effects in animal experiments. In vivo tests did not show mutagenic effects. This product is not recognized as reprotox by Research Agencies. May cause respiratory irritation. Not classified. Oral (NOAEL) = 131.5 mg/kg bw (Sodium Persulfate) Inhalation (NOAEC) = 10.3 mg/m3 (Ammonium Persulfate) Dermal: No data available Eyes, Skin, Respiratory System. Not applicable. Page 6/9 Sodium Persulfate SDS # : 7775-27-1 Revision date: 2018-07-13 Version 1.04 12. ECOLOGICAL INFORMATION Ecotoxicity Ecotoxicity effects Sodium Persulfate (7775-27-1) Active Ingredient(s) Duration Species Value Units Sodium Persulfate 96 h LC50 Rainbow trout 163 mg/L Sodium Persulfate 48 h LC50 Daphnia magna 133 mg/L Sodium Persulfate 96 h LC50 Grass shrimp 519 mg/L Sodium Persulfate 72 h EC50 Algae Selenastrum capricornutum 116 mg/L Persistence and degradability Biodegradability does not pertain to inorganic substances. Bioaccumulation Does not bioaccumulate. Mobility Dissociates into ions. Other Adverse Effects None known. 13. DISPOSAL CONSIDERATIONS Waste disposal methods US EPA Waste Number Contaminated Packaging This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations. D001. Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT UN/ID no UN 1505 Proper Shipping Name SODIUM PERSULFATE Hazard class 5.1 Packing Group III TDG UN/ID no UN 1505 Proper Shipping Name SODIUM PERSULFATE Hazard class 5.1 Packing Group III MEX UN/ID no UN 1505 Proper Shipping Name SODIUM PERSULFATE Hazard class 5.1 Packing Group III ICAO/IATA UN/ID no 1505 Proper Shipping Name SODIUM PERSULFATE Hazard class 5.1 Packing Group III IMDG/IMO Page 7 / 9 Sodium Persulfate UN/ID no 1505 Proper Shipping Name SODIUM PERSULFATE Hazard class 5.1 Packing Group III ADR/RID UN/ID no UN 1505 Proper Shipping Name SODIUM PERSULFATE Hazard class 5.1 Packing Group III ADN Proper Shipping Name Hazard class Packing Group SODIUM PERSULFATE 5.1 III SDS # : 7775-27-1 Revision date: 2018-07-13 Version 1.04 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories This product has the following hazards that are reportable under The Emergency Planning and Community Right -to -Know rule (EPCRA Tier II): • Oxidizer • Acute toxicity • Skin corrosion/irritation • Serious eye damage/eye irritation • Respiratory/skin sensitization • Specific Target Organ Toxicity (STOT) - Single Exposure Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA/EPCRA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations U.S. State Right -to -Know Regulations This product contains the following substances regulated under state Right -to -Know laws: Chemical name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Sodium Persulfate X Sodium sulfate x x California Proposition 65 This product does not contain any Proposition 65 chemicals CANADA Page 8 / 9 Sodium Persulfate SDS # : 7775-27-1 Revision date: 2018-07-13 Version 1.04 Environmental Emergencies This product contains no substances listed under Canada's Environmental Emergency regulations. Canadian National Pollutant Release Inventory This product contains no substances reportable under Canada's National Pollutant Release Inventory regulations. International Inventories Component TSCA (United States) DSL (Canada) EINECS/EL INCS (Europe) ENCS (Japan) China (IECSC) KECL (Korea) PICCS (Philippines ) AICS (Australia) NZIoC (New Zealand) Sodium Persulfate 7775-27-1 (> 99 ) X X X X X X X X X Sodium sulfate 7757-82-6 (< 1 ) X X X X X X X X X Mexico Mexico - Grade Slight risk, Grade 1 16. OTHER INFORMATION NFPA Health Hazards 1 Flammability 0 Stability 1 Special Hazards OX HMIS Health Hazards 1 Flammability 0 Physical hazard 1 Special precautions J NFPA/HMIS Ratings Legend Revision date: Revision note Issuing Date: Severe = 4; Serious = 3; Moderate = 2; Slight = 1; Minimal = 0 OX = Oxidizer Protection=J (Safety goggles, gloves, apron, combination dust and vapor respirator) 2018-07-13 SDS sections updated: 3. 2018-10-16 Disclaimer PeroxyChem believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of PeroxyChem, PeroxyChem expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By: PeroxyChem © 2019 PeroxyChem. All Rights Reserved. End of Safety Data Sheet Page 9 / 9