NCS000189_MONITORING INFO_20180207

- - ---STORMWATER"DIVISION-CODING-SHEET---
PERMIT NO.
NCB 00U l ?G)
DOC TYPE
❑ FINAL PERMIT
)l MONITORING INFO
❑ APPLICATION
❑ COMPLIANCE
❑ OTHER
DOC DATE
❑ 201 02 D--�
YYYYM M DD

Domtar
P. Box 747
Plymouth, NC 27962
T 252-793 8111
Domtar F281
wwwdodomta r. CCom
February 7"i, 201 S
Division of Water Resources
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
Certified Mail
Return Receipts Requested
REC'ziVED
FEB 5 7018
LCN 1 F� f FILEc
CWR 'EOT1Oj
Subject: NPDES Permit # NCS000189, Monitoring Period August 1, 2017 to January 31, 2018
Required Stormwater Analyses for Domtar Paper Company, LLC, Plymouth, North Carolina
Dear Sirts):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge
Monitoring Report" for Monitoring Period August 1, 2017 to January 31, 2018.
On August Sth, 2017, we collected a sample from CL-1 I. The sample we collected resulted in a
TSS of 60 mg/L. This was the third consecutive sample that resulted in a "rsS below 100 mg/L;
therefore, we are no longer in Tier II for TSS at the CL-I I outfall. There was no Ilow from two of
the outfalls, which were RY01 and SS.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email,[e-mail].
Sincerely,
John Lilley
Environmental Engineer
xc: Departincnt files

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189
or
Samples Collected During Calendar,Year 2017 and 2018
Certificate of Coverage Number: NCG
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
FACILITY NAME Dormer Paper
Company, LLC
COUNTY Martin and Washington
PERSON COLLECTING SAMPLE(S)
Tim Davis, Lori Hurdle, Paul Allen, J.T. Liffey
PHONE NO. 2 7 -8611
CERTIFIED LABORATORY(S)
ALS
Lab# 527
/ �/
Dormer Paper Company Co, LLC
Lab# 171
(SIGNATURE DESIGNEE)
Wastewater Lab -Plymouth
By this signature, I certify that this report is accurate and
Environment 1
Lab# 109 S
complete to the best of my knowledge.
Part A: Specific Monitoring Requirements
Outfall
No.
".:
Date
Sample
Collected
Event
Duration
Hr Min
Total
Rainfall
Inches-
BOO -
m 8
COD
m /I
TSS
mg/1 '.
PH -
mg/1
Dioxin
Notes
mrfVddlyr
__
30
120
100
&9
NO
WLS
1/13/2018
24
0.74
4.3
34
95
7.7
ND
OBA
11/13/2017
24
0.25
2.3
<20
5
6.4
NA
CL11
8/8/2017
24
0.88
3
30
60
7.4
NA '
CL11
10/24/2017
24
0.55
3
28
13
7.1
NA
LF01
10/24/2017
24
0.55
6
43
16
7.8
NA
WYN
12/20/2018
24
0.2
19
75
30
6.4
NA
LF03
12/20/2017
24
0.2
4
31
17
6.9
NA
RS01
1/26/2018
24
1.65
4
31
69
6.7
NA
RY01
1/29/20113
24
1.65
NA
NO FLOW
WRA
1 1/29/2018
24
1.65
NA
NO FLOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? Yes No
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
60050 -
556
530
400
Total Flow -
Oil and
Grease
Total
Suspended
Solids
PH
New Motor
Oil Usage
molddlyr ,
MG
mgil a
mgll
unit
gal/mo -
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
(if more than one storm event was sampled)
Date 8/812017
Total Event Precipitation (Inches)
0.88
Event Duration (Hours)
24
Date 10/2412017
Total Event Precipitation (Inches)
0.55
Event Duration (Hours)
24
Date 11/13/2017
Total Event Precipitation (Inches)
0.25
Event Duration (Hours)
24
Date 12120/2017
Total Event Precipitation (Inches)
0.2
Event Duration (Hours)
24
Mail Original and one copy to:
Division of Water Quality
Date 1/13/2018
Total Event Precipitation (Inches) 0.74
Event Duration (Hours) 24
Dale 1/29/2018
Total Event Precipitation (Inches) 1.65
Event Duration (Hours) 24
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
of Permittee)
�2' 9 '� 0
(Date)
Form SWU-246-051100
Page 2 of 2

Domtar
Domtar
P. Box 747
Plymouth, NC 27962
T 252-793-8111
F 252-793 8164
www.domtar.com
August 20"', 2018
Division of Water Resources
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
Certified Mai[
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Monitoring Period February I, 2018 to July
31, 2018. Required Stornrwater Analyses for Dondar Paper Company, LLC Plymouth,
North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge
Monitoring Report" for Monitoring Period February I, 2018 to July 31, 2018.
There was no (low from two of the outfalls, which were WRA and SS.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, [e-mail].
Sincerely,
llr4�
John Lilley
Environmental Engineer
xe: Department Files
RPCENED
AUG 2 4 2018
CEN i HAL FILES
DWR SECTION

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC 5000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Dormer Paper Company, LLC
PERSON COLLECTING SAMPLES) Tim Davis, Lori Hurdle, J.T. Lilley
CERTIFIED LABORATORY(S) ALS Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Environment 1 Lab# 109 S
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2018
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO- [phone]
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Outten
No.
Date .
Sample
Collected
Event ..
Duration
He Min
Total -
Rainfall
Inches
BOO
m/l
COD
m 0
TSS
m l
PH
mgA
Dioxin
Notes
mnVddtyl
30
120
100
6-9
NO
WLS
5/29/2018
24
3.1
3
44
11
8
NO
OBA
5/29/2018
24
3.1
5
52
6
7.5
NA
CL11
5/29/2018
24
3.1
3
23
8
8.3
NA
LF01
5/29/2018
24
3.1
4
45
29
T7
NA
LF03
5/29/2018
24
3.1
7
62
11
7.4
NA
WYN
7/24/2018
24
2.94
11
56
40
6.4
NA
R501
5/29/2018
24
3.1
3.5
42
14
7.7
NA
RY01
5/29/2018
24
3.1
4
41
4
7.3
NA
WRA
7/24/20181
24
2.94
NA
NO FLOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
558 •'.
530
400
Total Flow
00 and <y....
Grease.-
Total'
Suspended
Solids
pH
New Motor"
Oil Usage.
moldd/yr
MG
mg/1
mg0
unit
gal/mo
Yes
No X
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SW U-246-051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
(if more than one storm event was sampled)
Date 5/2912018
Total Event Precipitation (Inches)
3.1
Event Duration (Hours)
24
Date 7/24/2018
Total Event Precipitation (Inches)
2.94
Event Duration (Hours)
24
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Date 1/29/2018
Total Event Precipitation (Inches)
Event Duration (Hours)
Mail Original and one copy to:
Division of Water Quality
1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Date)
Form SWU-246-051100
Page 2 of 2

Hardison, Diane
From: Bohn, Allan
Sent: Tuesday, August 21, 2018 1:27 PM
To: Makris, Steve; Management Staff (Plymouth); Spence, Everick; Nowicki, Stefan; Bryant, Larry;
Floyd, Charlie; Cooper, Tracie Y.; Delegation of Authority; Bickerstaff, Bracky
Subject: Re: Delegation
All, I neglected to mention that Diane Hardison will have my environmental certification authority.
Regards,
Allan
> On Aug 21, 2018, at 5:25 AM, Bohn, Allan <Allan.Bohn @domtar.com> wrote:
> All, while I am away from the mill, traveling on business(8/21-9/1), David Council has my delegation of authority.
> Take care,
> Allan
> Sent from my iPhone

A6 Domtar
P. Box 747
Plymouth, NC 27962
`. T 252793-8111
Domtar wwwdoritar4
www,dom[arcom
October 6i6, 2017
Division of Water Resources
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECENED
OCT 18 2017
CENTRAL FILES
DWR SECTION
Certified Mall
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Monitoring Period February 1, 2017 to July
31, 2017. Required Stormwater Analyses far Domtar Paper Company, LLC, Plymouth,
North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge
Monitoring Report" for Monitoring Period February 1, 2017 to July 31, 2017.
CL I 1 exceeded the benchmark for solids. The upper limit being 100 mg/L, and the exceedance
was 203 mg/L in the month of May and 296 mg/L in the month of June. As a result, we fell under
Tier 11. We have been sampling CL-I 1 once per month. Our last sample we collected in the
month of July was below the benchmark. We will continue to collect a sample every month, until
we have collected three consecutive samples in which the results are below the benchmark. There
was no flow from two of the outfalls, which were WRA and SS.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, [e-mail].
Sincerely,
John /illle`y�
1j
Environmental Engineer
xe: Department tiles

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLES) Velma Faucette, Lorenza Palin, Tim Davis, Lon Hurdle
CERTIFIED LABORATORY(S) ALS Lab# 527
Domtar Paper Company Co. LLC Lab# 171
Wastewater Lab -Plymouth
Environment 1 Lab# 109 S
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2017
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONENO. � ,?. )793-8611
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Oudall
No.
Date
Sample
Collected
Event
Duration
Hr: Min
Total
Rainfall
Inches
BOD
m /I
COD
m /I
TSS
m A
PH
m A
Dioxin
Notes
mm/dd/ r
30
120
100
6-9
NO
WLS
5/5/2017
24
1.02
6
41
3
7.4
NO
OBA
5/5/2017
24
1.02
4
52
30
7A
NA
CL11
5/5/2017
24
1.02
3
22
203
8
NA
CL11
6/20/2017
24
0.85
5
296
8.4
NA
CL11
7/14/2017
24
0.61
9
34
93
8.1
NA
LF01
5/5/2017
24
1.02
1 4
44
50
1 7.4
NA
WYN
5%2017
24
1.02
4.5
35
6
7.3
NA
LF03
5/5/2017
24
1.02
20
84
30
7.3
NA
RY01
5/5120171
24
1 1.02
6
56
4
7.2
NA
WRA
5/5120171
24
1 1.02
1
NA
IND FLOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
If yes, complete Part B)
Part 8: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mofdd/yr
MG
mgn
mg/I
unit
gal/mo
Yes
No X
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
(if more than one storm event was sampled)
Date 5/5/2017
Total Event Precipitation (Inches) 1.02
Event Duration (Hours) 24
Date 6/20/2017
Total Event Precipitation (Inches) 0.85
Event Duration (Hours) 24
Date 7114/2017
Total Event Precipitation (Inches) 0.61
Event Duration (Hours)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Mail Original and one copy to:
Division of Water Quality
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my Inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
/�q—Q—/-2
(Date)
Forth S W U-246-051100
Page 2 of 2

DDmtar
P. Box 747
J Plymouth, NC 27962
�. T 253793 122
Domtar wwwdomtar4
www.domtar.com
July 21, 2017
Division of Water Resources
RECEIVED
JUl 21 2017
pW-rP,AL FILES
R SECTION
Attn: Central Files Certified Mail
1617 Mail Service Center Return Receipts Requested
Raleigh, NC 27699-1617
Subject: NPDES Permit # NCS000189, Required Tier Two Monthly Storm water
Analyses for outfall CL-11 for Domtar Paper Company, LLC, Plymouth, North
Carolina — July 2017
Dear Sir(s):
CL-I I outfall is a tier two for TSS. We collected a sample this month from the outfall and the
TSS was below the benchmark .Wc will continue to perform monthly monitoring at the Cl. 1 I
outfall.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, iohnthomas.lilleyndomtar.com.
Sincerely,
Jo inl T. Lil ey
Environmental Engineer
xe: Department files

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC 3000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Lori Hurdle
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2017
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. [phone]
(SIGNATURE OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
------------
------------
------------
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
moiddlyr
MG
mgll
mgll
unit
gallmo
Yes
No X
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no curtails located in this area.
Fonn SWU-246-051100
STORIvt&ygyd CHARACTERISTICS: S:\Emironmentar\water_smm\ti rer 11 ReponsF2017 ps July Tier 2 ReOriginal and one copy to: Page 1 of 2

Date 7/14/2017
Total Event Precipitation (Inches) 0.61
Event Duration (Hours) 16
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
of Permittee)
(Date)
Forth S W U-246-051100
SWDOMR &TuvimnmentaftWater_stonu ier 11 Reports@017 July Tier 2 Reportals Page 2 of

' , 1
Domtar
Domtar
P Box 747
Plymouth, NC 27962
T 252-793 8111
F 252-793 8164
www.domtar.com
August 15, 2017
Division of Water Resources
Attn: Central Files Certified Mail
1617 Mail Service Center Return Receipts Requested
Raleigh, NC 27699-1617
Subject: NPDES Permit # NCS000189, Required Tier Two Monthly Storm water
Analyses far outfall CL-11 for Domtar Paper Company, LLC, Plymouth, North
Carolina — July 2017
Dear Sir(s):
CL-I 1 outfall is a tier two for TSS. We collected a sample this month from the outfall and the
TSS was below the benchmark .This is the second consecutive month the TSS has been below the
benchmark. We will continue to perform monthly monitoring at the CL-11 outfall.
If you have any questions or require any additional inionnation pertaining to this report, please
contact me by phone, [phone] or by email, iohnthomas.lilley(a)domtar.com.
Sincerely,
John T. Lilley
Environmental Engineer
xc: Department tiles
RECEFI VED
406 2 31017
DwR SEC. 10 S

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Lori Hurdle
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2017
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. �_ [phone]
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
------------
------------
------------
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(If yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/ddfyr
MG
mg/I
mg0
unit
gallmo
Yes
No X
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
N1 Form SWU-246-051100
STORIv�����d CHARACTERISTICS: 31Environmentaftwater_smenliier 11 Reports@Oi7 august Tier 2 RepoSY.�Rriginal and one copy to: Page I of 2

Date 8/8/2017
Total Event Precipitation (Inches) 0.88
Event Duration (Hours) 16
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
,4 Ii/a / %
(Date)
Form SWU-246-051100
SW DOMR S1EnvironmenlahW ater_stonn\Tier 11 Reponst2017 August Tier 2 Report.xls Page 2 of 2

Domtar
P. Box 747
/ 1 Plymouth, NC 27962
`. T 252-793-8111
-8164
Domtar www.d mtar
www.domta[Com
October 6, 2017 RECEIVED
OCT 12 2017
CENTRAL FILES
Division of Water Quality DWR SECTION
Attn: Central Files Certified Mai/
1617 Mail Service Center Return Receipts Requested
Raleigh, NC 27699-1617
Subject: NPDES Permit # NCS000189, Required Tier Two Monthly Storm water
Analyses for outfall CL-ll for Domtar Paper Company, LLC, Plymouth, North
Carolina — September 2017
Dear Sir(s):
CL-11 outfall is a tier two for TSS. There was no flow from the outfall in September .We will
continue to perform monthly monitoring at the CL-11 outfall.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, iohnthomas.lillev a domtar.com.
Sincerely, '
John T. Lilley
Environmental Engineer
xe: Department tiles

Domtar
Dom tar Paper Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
www.domtar.com
November 6. 2017
Division of Water Quality
F�ItCEIVED
DEC 01 2017
CENTRAL FILES
D1NR SECTION
Attn: Central Files Certified Mail
1617 Mail Service Center Return Receipts Requested
Raleigh, NC 27699-1617
Subject: NPDES Permit # NCS000189, Required Tier Two Monthly Stormwater
Analyses for outfall CL-11 for Domtar Paper Company, LLC, Plymouth, North
Carolina — September 2017
Dear Sir(s):
CL-1 I outfall is no longer in tier two for TSS. The sample that was taken on 10/24/2017 had a
TSS of 13 mg/L. This is the third consecutive sample taken at CL 11, in which the TSS was
below the benchmark. As a result, we are no longer in tier two at CL I 1 for TSS.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, johnthomas.lilley@,domtar.com.
John T. L;Iley
Environmental Engineer
xc: Department tiles

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Lon Hurdle
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2017
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. 252)793-8611 /
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
01
- =
r
•r
MM®---
------------
------------
------------
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
molddlyr
MG
mgll
mgll
unit
gallmo
Yes
No
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
STORM &VpYT CHARACTERISTICS: "] original and one copy to: Form SWU-246-051100
"SOODOMR S \Environmenla�Wa�er_storm\Tier II RepoM1s12017 October Tier 2 Repon x3 Page 1 of 2

Date 10/2412017
Total Event Precipitation (Inches) 0.55
Event Duration (Hours) 16
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Division of Water Quality
Arm Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the Information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
11-6-17
(Date)
Form SWU-246-051100
SWDOMR S \Environmental\Water_stoen\Tier 11 Reporis\2017 October Tier 2 Report As Page 2 of 2

' , 1
Domtar
Domtar
P. Box 747
Plymouth, NC 27962
T 252-793 8221
F 252-793 8164
www.domtar.com
May 31" , 2016
Division of Water Resources
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
EGEIVED
JUN. 03 2016
CENTRAL FILES
DWR SECTION
edified Mail
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Monitoring Period February 1, 2016 to July
31, 2016. Required Stormwater Analyses for Domtar Paper Company, LLC, Plymouth,
North Carolina
Dear Sir(s): FILECEnclosed you will find the original and one copy of a apt,
omwater Discharge
Monitoring Report" for Monitoring Period February 1, 2016 to July 31, 2016.
All analytical results were below the benchmarks; there was no flow from four of the outfalls.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, [e-mail].
Sincerely,
/r&I G�
John Lilley
Environmental Engineer
xc: Deparnment tiles

Permit Number: NC S000189
Certificate of Coverage Number: NCG
or
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLES) Velma Faucette, Lorenza Palin, Tim Davis, Lod Hurdle
CERTIFIED LABORATORY(S) ALS Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Environment 1 Lab# 109 S
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2016
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. /7-1252)793-8611 -
(SIGNATURE OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Oudall
No.
Date
Sample
Collected
Event
Duration
Hr: Min
Total
Rainfall
Inches
BOD
nn/I
COD
m /I
TSS
m /I
PH
m /I
Dioxin
Notes
mnVddtyr
30
120
100
6-9
NO
WLS
2/4/2016
24
2.35
3
35
- 7
7
NO
OBA
2/4/2016
24
2.35
3
42
14
6.7
NA
CL11
2/4/2016
24
2.35
2
23
7
7
NA
LF01
2/4/2016
24
2.35
3
42
5
7.1
NA
WYN
5/30/2016
24
1.19
NA
NO FLOW
LF03
2/4/2016
24
2.35
3
39
17
7
NA
RY01
2/4/2016
24
2.35
4
36
4
6.9
NA
WRA
1 5/30/20161
24
1 1.19
1
1
1
1
1 NA
I NO FLOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
molddtyr
MG
mg/l
mgn
unit
gal/mo
Yes
No X
Note: There is a garage onsite, however it Is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
RECEIVED
JUN 0 3 2U1b
CENTRAL FILES
DWR SECTION
Form S W U-246051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
(if more than one storm event was sampled)
Date 2/4/2016
Total Event Precipitation (Inches)
2.35
Event Duration (Hours)
24
Date 5/30/2016
Total Event Precipitation (Inches)
1.19
Event Duration (Hours)
24
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Mail Original and one copy to:
Division of Water Quality
"9 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
l -Z-16
(Date)
Form SWU-246-051100
Page 2 of 2

Domtar
It all begins with paper.'
Domtar Paper Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
T 2S2793-8112
www.domtar.com
February 7°' , 2017
Division of Water Resources
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECNEC
FEB , i zoV
r,E.NTRAI FILES
pWR SECTION
Certified Mai!
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Monitoring Period August 1, 2016 to January
31, 2017. Required Stormrvater Analyses for Dmntar Paper Company, LLC, Plymouth,
North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge
Monitoring Report" for Monitoring Period August 1, 2016 to January 31, 2017.
Cl- I I exceeded the benchmark for solids. The upper limit being 100 mg/L, and the exceedance
was 384 ni As a result, we completed the Tier 1 response. The sample was analyzed on
9/30/2016, discussion took place 10/12/2016, and implementation of the mitigation measures
were completed 11/3/2016. There was no flow from two of the outfalls, which were WRA and
WYN.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, [e-mail].
Sincerely,
John Lilley
Environmental Engineer
xc: Department files

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number NC S000189_ or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Velma Faucette, Lorenza Palin, Tim Davis, Lori Hurdle
CERTIFIED LABORATORY(S) ALS Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Environment 1 Lab# logs
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2016
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO.—[phone]
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Outfall
No.
Date
Sample
Collected `-:
Event
Duration
Hr, Mal ."
Total
Rainfall
Inches
BOD
m Pr
COD
m 4
TSS
m A
PH
m /I
Dioxin
Notes
mm/ddlyr
30
120
100
6-9
ND
WLS
9/29/2016
24
1.78
11
59
7
7.5
ND
OBA
9/29/2016
24
1.78
5
64
28
7.3
NA
CL11
9/29/2016
24
1.78
- 2
25
384
TS
NA
LF01
9/29/2016
24
1.78
6
58
35
8.3
NA
WYN
9/29/2016
24
1.78
NA
NO FLOW
LF03
9129/20161
24
1.78
5
41
27
7.1
NA
RY01
9/29/2016
24
1.78
4
53
15
6.7
NA
WRA
9/29/20i6j
24
1 1.78
1
1
NA
INGFILOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
"
Date
Sample
Collected
50050
556-
530>
400
Total Flow
Oil and
Grease
..
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/dd/yr
MG
mg/I
mg/1
unit-.
gal/mo
Yes
No X
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no ouHalls located in this area.
RECEIVED
F€6 17 2017
CENTRAL FILES
DWR SECTION
Form SWU-246-051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
(if more than one storm event was sampled)
Date 9/29/2016
Total Event Precipitation (Inches)
1.78
Event Duration (Hours)
24
Date 112/2017
Total Event Precipitation (Inches)
0.65
Event Duration (Hours)
24
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Mail Original and one copy to:
Division of Water Quality
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Date)
Form SWU-246-051100
Page 2 of 2

Domtar
P. B" 747
1 Plymouth, NC 27962
�. T 252-793-S112
Domtar www.domtar.com
RECEIVED
April 1. 2015
APR 0 8 2015
CENTRAL FILES
Division of Water Quality DWR SECTION
Attn: Central Files Certified My
1617 Mail Service Center Return Receipts Requested
Raleigh, NC 27699-1617
Subject: NPDES Permit # NCS000189, Required Tier Two MonthIv Stornnvater
Analvses for outfall CL-11-jor Dongar Paper Congnnrv, LLC, Plvnmuth, North
Carolina — March 2015
Dear Sir(s):
CI-1 I outfall has entered Tier II staves. The samples in Sep 2014 and February 2015 were above
the benchmark fix TSS. We implemented monthly testing in March 2015. The '1 SS result in
March was again above the benchmark value. 862 ntg/L. We have implemented several BMPs
over the past few years at CIS 11 including: sediment (raps. Iiltration basin, coconut sox, check
dams, grassed ditches, rip rap, etc. I`ve called Bill Moore with NCDFNR and he is planning a site
visit to assist its with nest steps.
We will continue to perform monthly monitoring at the CL-I I outfall.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone. [phone] or by email. kari.cahoon(iidonttar.com.
Sincerely,
Ca-ot-Tzv J
Kari Cahoon
Environmental Engineer
.cc: Department tiles

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLES) Velma Faucette
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC, Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2015
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. [phone]
(SIGNATURE OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
------------
------------
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date -
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/dd/yr
MG
mg/1
mg/I
unit
gal/mo
Yes
No
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
SWDOMR U9My Documents\EnvironmentaaSlormwalenTier 21201512015 March Tier 2 Repon.xls Page 1 of 2

STORM EVENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Quality
Date 3/5/2015 Ann: Central Files
Total Event Precipitation (Inches) 0.15 1617 Mail Service Center
Event Duration (Hours) 24 Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations." .
y/3/]s
(Date)
Form SWU-246-051100
SVJDOMR U:\My Documents\EnvironmentaaStormwatenTier 2VO15QO15 March Tier 2 Report As Page 2 of 2

Domtar
Domtar
P. Box 747
Plymouth, NC 27962
T 252-793-8111
F 252-793-8164
www.domtar.com
May 1.2015
Division ol' Watcr Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECEIVED
MAY 0 7 2L)
CENTRAL FILES
DWR SECTION
Certified Ma
Return Receipts Requested
Stthjectr NPDES Permit # NCS000189, Required Tier Two Monthly Stornnvttter
Analyses for ontfall CL-11 firr Donrtar Paper Ganpany, LLC, Plymonth, North
Carolina — April 2015
Dear Sir(s):
CIS 11 oLit faII is a tier Iwo for TSS. There was no tlow from the outfall this month.
We will continue to perform monthly monitoring at the CI-1 1 outfall.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, kari.calloon(rL)domtae.cont.
Sincerely.
0" Ca.kun^j
Kari Cahoon
Environmental Engineer
xc: Department Ides

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Velma Faucette
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2015
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO, ,(252)793$611 i4
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil. and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/ddlyr
MG
mg/l
mg/I
unit
gal/mo
Yes
No
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
SWDOMR U.Wy DocumentslEnvironmental%StormwateATier 2120152015 Apnl Tier 2 Repon.xls Page 1 of 2

STORM EVENT CHARACTERISTICS:
Mail Original and one copy to:
Division of Water Quality
Date
Attn: Central Files
Total Event Precipitation (Inches)
1617 Mail Service Center
Event Duration (Hours)
Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Date)
Form SWU-246-051100
SWDOMR U:Wy DocumentslEnvimnmentanStormwatenTier 2Q015Q015 Apnl Tier 2 Report As Page 2 of 2

Domtar
P. Bol 747
Plymouth• NC 27962
w T252-793-Sill
F252
Domtar
www.domtar.omtcom
.tune 1. 2015
Division of Water Quality
Atm: Central Piles
1617 Mail Service Center
Raleigh, NC 27699-1617
Certified Mai!
Return Receipts Requester/
Subject: NPDES Permit # NCSO##189, Required Tier Two Monthly Stormwater
Analyses%or outfirll CL-1 l %or Domtar Paper Cnmpnny, LLC, Plynronth, North
Carolina — May 2015
Dear Sir(s):
CL-I I outfall is a tier two for "fSS. There was no flow from the outfitll this month.
We Will continue to perform monthly monitoring at the CI..-1 I outfall.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, ,I,:nri_cahuon c�,dumtar.ci�m.
Sincerely,
Kari Cahoon
Environmental Engineer
,yc: Department tiles

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Dormer Paper Company, LLC
PERSON COLLECTING SAMPLE(S)
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2015
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. _.J252)793-8611 _ i
(SIGNATURE-OFPERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
------------
------------
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Pan B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
-
Date
Sample
Collected
50050
556
530 -
400
_
Total Flow
Oil. and
Grease
T(5tal
Suspended
Solids
pH
:
New Motor
Oil Usage.
Froldd/yr
MG
mg/l `
mgn
unit .-
gallmo
Yes
No
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
CMMJ
0
1
Form SWU-246-0511 W
SWDOMR S:\Environmental\Water_slorm\Tier 11 Reports\2015 May Tier 2 Repon. xls Page 1 of 2

STORM EVENT CHARACTERISTICS:
Mail Original and one copy to:
Division of Water Quality
Date
Atm Central Files
Total Event Precipitation (Inches)
1617 Mail Service Center
Event Duration (Hours)
Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
(Date)
Form SWU-246-051100
SWDOMR S9EnvironmentaOWater_slorm\Tier 11 Repons12015 May Tier 2 Repon.xls Page 2 of 2

11
Domtar
July 1, 2015
Domtar
P. Box 747
Plymouth, NC 27962
T 252-793-8111
F 252-793-8164
www.domtar.com
Attention: Central Files
NC DENR Division of Water Quality
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: NPDES Permit #NCS000189
RECEIVED
yu_ 31 2015
CENTRAL FILES
DWR SECTION
Certified Mail
Return Receipt Requested
Required Tier Two Monthly Stormwater Analyses for Outfoll CL-11,
Domtar Paper Company, LLC, Plymouth, North Carolina —June 2015
Dear Sir(s):
RECEIVED
11L 31 2015
CENTRAL FI
OWR SECTIONS
CL-11 outfall is a tier two for TSS. We collected a sample this month from the outfall and the
TSS was below the benchmark. We will continue to perform monthly monitoring at the CL-11
outfall.
If you have any questions, or require any additional information pertaining to this report,
please contact me at [phone] or by email at [e-mail].
Sincerely,
0 ak'%'
Kari Cahoon
eat Cn1,J
Environmental Engineer
xc: Department Files

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Dormer Paper Company, LLC
PERSON COLLECTING SAMPLES) Lorenza Palin
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Damtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2015
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. — _ [phone]
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/dd/yr
MG
mg/I
mg/I
unit
gal/mo
Yes
No
r*�
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
SWDOMR 59EnviromnentaftWater_storm\Tier If Reportst2015 June Tier 2 Report.xls Page 1 of 2

STORM EVENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Quality
Date 6/2/2015 Attn: Central Files
Total Event Precipitation (Inches) 0.65 1617 Mail Service Center
Event Duration (Hours) 24 Raleigh. North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations"
(Date)
Form SWU-246-051100
SW DOMR S:1EnvimnmenlaRWater_storm\Tier 11 Repons12015 June Tier 2 Repori Page 2 of 2

Domtar
Domtar
P. Box 747
Plymouth, NC 27962
T 252-793-8111
F 252-793-8164
www.domtarcom
August 6, 2015
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
Certified Mail
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Year 6 - Period 2 Monitoring Period February
1, 2015 to July 31, 2015. Required Stormwater Analyses for Domtar Paper Company,
LLC, Plymouth, North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge
Monitoring Report" for the Year 6 — Period 2 Monitoring Period designated from February 1,
2015 to July 31, 2015.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, kari.cahoon(cildomtaccom.
Sincerellyny,' ,/ /n�A )
b`V`-"" Ca�v 5) v
Kari Cahoon
Environmental Engineer
xc: Department tiles
RECEIVED
AUG 1 0 2015
CENTRAL FILES
DWR SECTION

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Dormer Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Paul Allen, Velma Faucette, Lorenza Palin, Tim Davis
CERTIFIED LABORATORY(S) ALS Lab# 527
Dormer Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Environment 1 Lab# 109 S
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2015
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. (252�793-8611 _
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Outfall -
No .:
Date _
Sample: _
Collected .
Event 5.,
Duman 5
Hr. Min
Total`.'.
Rainfall,`
Inches
POD :. _ , _.....
y, .�
m I w-
COD
... -
TSS r.-
'
PH - _
fl
Dioyun =". "
Notes`
-
--
min/
- a:=. .
-v
-` 30 , r.:
"' .. 120
-; 100 -.:.
;` 6-9 ,'-
:. _:,. NO
WLS
2/23/2015
24
0.26
5
33
91
7.5
ND
OBA
3/27/2015
24
1.4
5
47
42
5.9
NA
CL11
6/2/2015
24
0.65
8
44
53
8
NA
LF01
3/27/2015
24
1.4
7
54
40
7.3
NA
WYN
6/3/2015
24
0.53
3
41
17
6.8
NA
LF03
NO FLOW
RY01
NO FLOW
W RA
I
I
I
I
I
I
I
NO FLOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall'T
Date.' :
Sample =
Collected
50050.
556 =--='
530 ."'
400
Total. Flow '''
Oil'and
Grease'
..
Total , f `:'`;
Suspended
Solids �;
pH a `:'
New
Oil Usage-
-
mofdd/yc
MG .,
mg/I `hs
mgll '
unit -.
gal/mo %a
Yes
No
gi
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no ouHalls located in this area.
Form SWU-245051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
(if more than one storm event was sampled)
Date
2/23/2015
Total Event Precipitation (Inches)
0.26
Event Duration (Hours)
24
Date
3/2712015
Total Event Precipitation (Inches)
1.4
Event Duration (Hours)
24
Date
6/2/2015
Total Event Precipitation (Inches)
0.65
Event Duration (Hours)
24
Date
6/3/2015
Total Event Precipitation (Inches)
0.53
Event Duration (Hours)
24
Mail Original and one copy to:
Division of Water Quality
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision In accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my Inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the Information submitted is, to the best
of my knowledge and belief, two, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possi "lity of fines and imprisonment for knowing violations."
(Signature of Permittee)
(Date) � — 7
Form SWU-246-051100
Page 2 of 2

Domtar
P Box 747
Plymouth, NC 27962
�. T252-793 8111
Domtar F252
www.domtar.omtCom
August 6, 2015
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECEIVED
AUG 01
CENTRAL FILES
DWR SECTION
Certified Mail
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Required Tier Two Monthly Stormwater
Analyses for outfall CL-11 for Domtar Paper Company, LLC, Plymouth, North
Carolina — July 2015
Dear Sir(s):
CL-11 outfall is a tier two for TSS. There was no flow from the outfall in July .We will continue
to perform monthly monitoring at the CL-I1 outfall.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, kari.cahoon i domtar.com.
Sincerely,
(a-u- '�a_ karj
Kari Cahoon
Environmental Engineer
xc: Department files
I

Domtar
P Box 747
Plymouth, NC 27962
T252-793 8111
4
Domtar www.ww.domtamtar.com
September I, 2015
Attn: Central Files
Division of Water Quality
1617 Mail Service Center
Raleigh, NC 27699-1617
�1
�OD
RECEIVED
SEP 08 am
CENTRAL FILES
DWR SECTION
Certified Mai!
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Required Tier Two Monthly Stormwater
Analyses for outfall CL-11 for Domtar Paper Company, LLC, Plymouth, North
Carolina — AuRust 2015
Dear Sir(s):
CL-I I outfall is a tier two for TSS. We collected a sample this month from the outfall and the
TSS was below the benchmark .This is the second month that the'I'SS was below the benchmark.
We will continue to perform monthly monitoring at the CL-I I outfall.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, kari.cahoonamdomtar.com.
Sincerely,
Kari Cahoon
Environmental Engineer
xe: Department files

Domtar
It all begins with paper"
Do mtar Paper Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
T 252793-8111
www.domtar.com
October I, 2015
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECEIVED
DEC 0 S 2015
pWTRAL FILES
R SECTION
Certifier/ Mail
Return Receipts Requester/
Subject: NPDES Permit #NCS000189, Required Tier Two Monthly Stornnvater
Analyses for outfall CL-11 for Domtar Paper Company, LLC, Plymouth, North
Carolina — September 2015
Dear Sir(s):
CL-I 1 outfall is a tier two for TSS. We collected a sample this month from the outfall and the
TSS was below the benchmark with a value of 22 mg/I. This is the third consecutive sample that
the TSS has been below the benchmark and therefore this outfall is no longer subject to Tier 11.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, kari.cahoon(cDdomtar.com.
Sincerely, 8.6� C/.�na�
Kari Cahoon
Environmental Engineer
xe: Department files

Domtar
It all begins with paper.'
Do mtar Paper Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
T 2S2-793-8111
www.domtar.com
February 22, 2016
Division of Water Resources
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECEIVED
MAR o�2
CENTRAL FILES
DWR SECTION
Certified Mail
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Required Tier Two Monthly Storrnwater
Analyses for outfall CL-11 for Dondar Paper Company, LLC, Plymouth, North
Carolina — September 2015
Dear Sir(s):
Enclosed is the SDMR for the CL-I 1 outfall. The CL-1 I was a tier 11 for'I'SS but for three
months in a row the results were below the benchmark. A cover letter was submitted 10/l/I5 with
the TSS data but the SDMR was not submitted.
If you have any questions or require any additional information pertaining to this report, please
P
contact me by phone, [phone] or by email, kari.cahoon�domtar.com.
Sincerely,
Kari Cahoon
Environmental Engineer
xe: Department files

Permit Number: NC S000189
Certificate of Coverage Number: NCG
or
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Lorenza Palin
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2015
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. [phone] _
(SIGNATURE OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
------------
------------
------------
------------
------------
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/ddtyr
MG
mg/I
mg/1
unit
gaUmo
Yes
No x
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
U
Form SWU-246-051100
SWDOMR S,\Envlrnrmental\Water_s10rm\Tier 11 ReporfrQ015 September Tier 2 Report. xls Page 1 of 2

STORM EVENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Quality
Date 912512015 Attn. Central Files
Total Event Precipitation (Inches) 0.52 1617 Mail Service Center
Event Duration (Hours) 16 Raleigh, North Carolina 27699-1617
(it more than one storm event was sampled)
Date
Total Event Precipitation (inches)
Event Duration (Hours)
"I cenity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations"
,E ,Z /,y
(Date)
Form SWU-245-051100
SWDOMR S:\Environmental\Water storm\Tier 11 ReponsV015 September Tier 2 Repon As Page 2 of 2

t
Domtar
Domtar
P. Box 747
Plymouth, NC 27962
T 2S2-793-8111
F 252-793-8164
wwwcomtarcom
February 21, 2016
FEB � y
OR SFc-"ON
B 1"
Division of Water Resources
Attn: Central Files Certified Mai/
1617 Mail Service Center Return Receipts Requested
Raleigh, NC 27699-1617
Subject: NPDES Permit # NCS000189, Monitoring Period August 1, 2015 to January
31, 2016. Required Stornnwatcr Analyses for Dondar Paper Company, LLC, Plymouth,
North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge\
Monitoring Report" for Monitoring Period August 1, 2015 to January 31, 2016. 11ZZ
All analytical results were below the benchmarks; there was no flow from four of the o6ffalls
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, kari.cahoonOdomtaceom.
Sincerely,
U> O— c-' Coc &uw"J
Kari Cahoon
Environmental Engineer
xc: Department files

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLES) Velma Faucette, Lorenza Palin, Tim Davis, Lori Hurdle
CERTIFIED LABORATORY(S) ALS Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Environment 1 Lab# 109 S
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2016
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. � _(252)793:8611 ,.
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Outfall
No.
Date
Sample
Collected
Event
Duration
Hr: Min
Total
Rainfall
Inches
BOD
m 0
COD
mgd
TSS
MgA
PH
m A
Dioxin
Notes
mm/ddlyr
30
120
100
6-9
ND
WLS
11/19/2015
24
0,53
8
48
9
7.9
NO
OBA
9/25/2015
24
0.52
3
26
31
7
NA
CL11
9/25/2015
24
0.52
6
44
22
T5
NA
LF01
12/7/2015
24
0.23
4
32
22
T2
NA
WYN
NA
NO FLOW
LF03
NA
NO FLOW
RY01
NA
NO FLOW
WRAI
I NA
INO FLOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556 -
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/ddtyr
MG
mg/I
mg/1
unit
gal/mo
Yes
No X
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
(if more than one storm event was sampled)
Date 9/25/2016
Total Event Precipitation (Inches)
0.52
Event Duration (Hours)
24
Date 11/19/2015
Total Event Precipitation (Inches)
0.53
Event Duration (Hours)
24
Date 12/7/2015
Total Event Precipitation (Inches)
0.23
Event Duration (Hours)
24
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
24
Mail Original and one copy to:
Division of Water Quality
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
02" 2 yrl�
(Date)
Form SWU-246-051100
Page 2 of 2

Domtar
` P. Box 747
Plymouth, NC 27962
T252-793-8222
Domtar F252
www.domtar.omtcom
August I, 2014
Division of Water Quality
Attu: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECEIVED
AUG 11 2014
CENTRAL FILES
DWQ/BOG
Certified Mail
Return Receipts Requested
Subject: NPDES Permit #,NCS0001 89, Year 5 — Period 2 Monitoring Period February
1, 2014 to ./u(h 31, 2014. Required Stornnvuter Analyses for Domtar Paper Company,
LLC, Plymouth, North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Slot mwater Discharge
Monitoring Report" for the Year 5 — Period 2 Monitoring Period designated fiom February
2014 to July 31. 2014.
The dioxin analysis for Stormwater outfall W LS01 was 2.88 pg/L.. The result had two data
qualifier tags. First, the result is an estimated value because the analyte concentration was below
the method reporting limit and above the estimated dctcetion limit. Second, the result is an
estimated maximum possible concentration because the on ahundancc ratios between the primary
and secondary ions were outside oftheoretical acceptance limits.
If you have any questions or rcquirc any additional information pertaining to this report, please
contact me by phone, [phone] or by email, kari.cahoon(iidomtar.com.
Sincerely,
Kari Cahoon
Environmental Engineer
sc: Department files

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Paul Allen, Velma Faucette
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Environment 1 Lab# 109 S
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2014
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO. [phone]
(SIGNATURE OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Outlet
No.
_
Dale
Sample
Collected
Event
Duration
Hr Min
Total -
Rainfall
Inches
BOD
rrg/l
COD
mg/I
TSS
m9/f
PH
mg/I
Dioxin
Notes
mm/dd! r
30
120
100
6-9
NO
WLS
3/29/2014
24
0.76
4
34
6
7.9
2,88
see letter
OBA
3/7/2014
24
1,65
4
31
18
5.8
na
CL11
3/7/2014
24
1.65
2
<20
89
7.9
na
LF01
2/5/2014
24
0.3
3
34
3
8.4
na
LF03
3/7/2014
24
1.65
4
31
86
7,8
na
RY01
5/16/2014
24
0.89
7
103
7
6.8
na
WYN
5/16/2014
24
0.89
8
57
82
7.8
na
WRA
I
I
I NO FLOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? Yes No
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall. - •
No.
Date
Sample
Collected
50050
556
530
400
T661:FIOw
Oil and '
Grease
Total
Suspended
Solids
pH
.Oil
New Motor -
Usage
mo/oBtyr j
MG' �',
ing11 1
and/1'
unit
gal/mo
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246 051100
Page 1 of,2

STORM EVENT CHARACTERISTICS:
Of more than one storm event was sampled)
Date 2/5/2014
Total Event Precipitation (Inches) 0.3
Event Duration (Hours) 24
Date
3/7/2014
Total Event Precipitation (Inches)
1.65
Event Duration (Hours)
24
Date
3/29/2014
Total Event Precipitation (Inches)
0.76
Event Duration (Hours)
24
Date
511612014
Total Event Precipitation (Inches)
0.89
Event Duration (Hours)
24
Mail Original and one copy to:
Division of Water Quality
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the pos ibility of fines and imprisonment for knowing violations."
(Signature of Permittee) (Date)
From SVVU-246-051100
Page 2 of 2

Domtar
P. Box 747
1 Plymouth, NC 27962
T252 793-8111
Do
mt www do 8164
111 1 www.m[ar.com
February 3, 2015
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECEIVED
FEB 0 6 2015
CEN'fRA' h Certified Ma
DWR SEReh� tyReceipfs Requested
Subject: NPDES Permit # NCS000189,-Monitoring Period August 1, 2014 to Jununy
31, 2015. Required Stormwater Anattwes for Domtar Paper Company, LLC, Plymouth,
North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge
Monitoring Report" for Monitoring Period August I, 2014 to January 31, 2015.
The TSS result for CL-I I was 927. The storntwatcr picked up solids from the gravel parking area.
Sediment jackets, straw wattle, and a catch basin were installed to help capture solids. See
attached Tier I report.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, kari.cahoonti�domtar.com.
Sincerely,
Kari Cahoon
Environmental Engineer
se: Department files

Stormwater Tier One Response Record
Domtar Paper Company, LLC — Plymouth. NC
NPDES Stormwater Permit NCS000189
• Outfall — CL-1 1
• Rain Event total — .38 inches
• Date of sample collection — 9/4/ 14
• Date sample results communicated — 9/9/14
• Parameter exceeding benchmark value — TSS
o Analyses results — 927 mg/l
o Permitted Benchmark target — 100 mg/I
1. Inspection Date by Kari Cahoon: 9/10/14
2. Cause of benchmark exceedance —1-lard rain picked up solids from the gravel parking
lot area and carried them through the drain pipe. Most of the area drains to this ditch.
3. Mitigation Measures: There is vegetation, silt fence, and rock dams already in place
to capture/reduce solids. Ordered three sedimentation jackets to try to capture solids
in the stormwater piping in the ditches. Ordered a pallet of straw wattle to put in the
ditches to capture solids. Dug a catch basin to try to slow down the flow and allow
solids to settle out.
4. Implementation of measure must be complete by 10/31/14.
5. Actual Date measure was implemented 10/31/14.
6. Notes: A lot of work has been done at this outfall to reduce TSS in stormwater.
UAMy Documents\Envirommerttal\Stonmvater\'I'ier 1\09 04 14 Stornmatcr'I'ier One Response Record CLI I.doc Page I of I
Record to be stored with Stormwater Pollution Prevention Plan and Compliance Manual

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Dormer Paper Company, LLC
PERSON COLLECTING SAMPLES) Paul Allen, Velma Faucette
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Dormer Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Environment 1 Lab# 109 S
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2014
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Outfall
Ni.
y
tc:sd,i7
Sample `
Sam
Collected
EventC-".m'
D�uraatio
Hr.Mm
Total
Ramt.11
Inches .I
SODT ;:`:
-. ..
CODS"" A
TSS r
m�0i.-a,.r_�'
PH -
mg/1-
Di&0m ' ^""` 'r
Notes
r ' 7
Y 7
-Date,-
- -- —1
mMdd 'T -.,
F_.6
30.
..:720�=.„
�.-.7>IW:
.6-9
NO
-
-
WLS
11/26/2014
24
0.61
4
29
5
6.7
NO
OBA
9/24/2014
24
0.2
2
25
8
6.5
na
CL11
9/4/2014
24
0.38
7
24
927
7
na
LF01
9/24/2014
24
0.2
8
57
12
7
na
LF03
11/26/2014
24
0.61
3
24
42
66
na
RY01
11/26/2014
24
0.61
4
58
53
6.5
na
RS01
1120141
24
0.61
1 3
37
3
7
na
WYN
1 24
-
na
NO FLOW
WRA
I
I
NO FLOW
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall 1
No: +
Date -
Sample ^-
Collected
50050 -.
556
530F ..
400.
'
Total Flow
Oil and,
Grease
Total 1
SuspenAed
Susp
Sods .�
'pH
New Motor
Od Usage
and/dd/yr„`I
MG
mg/I 31111,
m'g/111;,:4 ':7I
Wilt %gal/mo
Yes
No
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no cattails located in this area.
Form SWU-246-051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
(if more than one storm event was sampled)
Date 9/4/2014
Total Event Precipitation (Inches) 0.38
Event Duration (Hours) 24
Date
9/24/2014
Total Event Precipitation (Inches)
0.2
Event Duration (Hours)
24
Date
11/26/2014
Total Event Precipitation (Inches)
0.61
Event Duration (Hours)
24
Date
Total Event Precipitation (Inches)
Event Duration (Hours) 24
Mail Original and one copy to:
Division of Water Quality
"9 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
2, y-ems
(Date)
Form SWU-246-051100
Page 2 of 2

Ill
llk�
Domtar
December 19. 2011
Division of Water Quality
Attu: Brian Lowther
1617 Mail Service Center
Raleigh, NC 27699-1617
Domtar Paper Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
TeL [phone]
DEC 2 3 2011
WETUNDSMDSTOR QE 1 1R8PARCh
Certifier/ Ma
Return Receipts Requested
Subject: NPDES Permit # NCS000189, Required Tier Two Monthly Stornrwater
Analyses fi)r oatfalls CL-11, WYN and WRA for Domtar Paper Contpairy, LLC,
P11'mouth, North Caroliarr
Dear Sir(s):
You will find enclosed, one copy of a monthly stornnvatcr report for Cl, 1 I, WYN and W RA,
which are permitted outfalls at Domtail facility in Plymouth, NC. As a reminder, WYN outfall
is it tier two for TSS and COD. Thcrc was no flow Rom WYN outfall in November. This is the
fourth month in it row which demonstrates the effectiveness of our mitigation measures. WRA
outfall is a tier two for COD and a tier one fix TSS. There was no flow at WRA outfall for the
month of November.
Previously, Cl,-I I outfall was above the benchmark value four times Foil However, for the
three consecutive months of.luly, August, and September, the TSS and BOD were below the
benchmark values. We did not perform it COD on the July sample although all previous COD
results (for the Feb —.July 2011 sampling period) were below the benchmark. The ph results for
July and August were below the benchmark. The ph in September was above the benchmark, at
9.1. We believe this is because of the kind of rock that is used on the gravel road and in the
stonnwater ditch: the stonnwater picked up the limestone and caused an elevated ph. We did not
collect it sample in October because we thought all the parameters were below the benchmarks
but later noticed that there was no COD lest performed in July and the ph for the September
sample was above 9. Per my conversation with Brian Lowther on 1 1/16/1 I, we collected a tier
two sample from CIS I 1 in November. The sample was not collected within the first thirty
minutes ofthe rain event.Thc'fSS results were above the benchmark, 720. The ph was also
elevated though not in exceedence. A tier two record is attached with mitigation measures that are
underway.
"rhe BOD and COD results for CIS I I were not provided in the original Tier II reports for July
and August 201 1. 1 have attached revised reports so there is no incomplete data. As noted above,
there was no COD performed on the Cl_-1 I sample.luly 2011.
www.domtar.com

We Will continue to perform monthly monitoring of CL-1 I, WYN, and WRA Offlialls, Ifyou have
any questions or require any additional information pertaining to this report, please contact me by
phone, [phone] or by email, kari.cahoonitidrnntar.con.
Sincerely,
CIS' C kMl
Kari Cahoon
Environmental Engineer
ac: Department tiles
se: Brian Lowther

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000169 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLES) Paul Allen & Alan Barnes
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Dormer Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2011
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
(SIGNAFrURE OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
------------
------------
------------
------------
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/dd/yr
MG
mg/I
mg/I
unit
gal/mo
Yes
No
NOTE: This BOD result is not valid because the sample was improperly diluted during analysis.
Another sample will be taken at this outfall and BOD will be analyzed again during a subsequent rain
event, if flow is observed at this outfall.
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
SWDOMR U Wy Documents\Environmentah5tormwatenTier 212011 Nov Tier 2 Report As Page 1 of 2

STORM EVENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Quality
Date 11/29/2011 Aim Central Files
Total Event Precipitation (Inches) 0.33 1617 Mail Service Center
Event Duration (Hours) 24 Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowled a an belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including th ossibiliry of es and i risonment for knowing violations."
J�zic 6enn1 Ak,,j r2/ZI /ll
(Signature of Per ittee) (Dale)
Form SWU-246-051100
SWDOMR U Wy Dowmenls%EnvimnmentaftStormwater Tier 2%2011 Nov Tier 2 Repon.xls Page 2 of 2

Permit Number: NC S000189
Certificate of Coverage Number: NCG
or
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Paul Allen & Alan Barnes
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2011
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washinqton
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/dd/yr
MG
mg/I
mg/I
unit
gal/mo
Yes
No
NOTE: This BOD result is not valid because the sample was improperly diluted during analysis.
Another sample will be taken at this outfall and BOD will be analyzed again during a subsequent rain
event, if flow is observed at this outfall.
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
SWDOMR U:Wy Dowments%EnvironmentaftStormwatenTier 212011 July Tier 2 Report.xls Page 1 of 2

STORM EVENT CHARACTERISTICS:
Mail Original and one copy to:
Division of Water Quality
Date 7/6/2011
Aim Central Files
Total Event Precipitation (Inches)
1.43
1617 Mail Service Center
Event Duration (Hours)
24
Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date 7/9/2011
Total Event Precipitation (Inches)
1.34
Event Duration (Hours)
24
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including ssitolipy of fines and imprisonment for knowing violations."
(Signature of ISermittee) (Date)
Form SVJU-246y051100
SWDOMR U:Wy De ments\EnvironmentaOStormwatei\Tier 2@011 July Tier 2 Report.xls Page 2of2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLES) Paul Allen & Alan Barnes
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2011
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
------------
------------
------------
------------
------------
------------
------------
------------
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
556
530
400
Total Flow
Oil and
Grease
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/dd/yr
MG
mg/l
mg/I
unit
galfmo
Yes
No
NOTE: This BOD result is not valid because the sample was improperly diluted during analysis.
Another sample will be taken at this outfall and BOD will be analyzed again during a subsequent rain
event, if flow is observed at this outfall.
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
SWDOMR U1My Documents%EnvironmenlaaStormwatenTier 212011 August Tier 2 ReporlAs Page 1 of 2

STORM EVENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Quality
Date 812012011 Attn'. Central Files
Total Event Precipitation (Inches) 1.1 1617 Mail Service Center
Event Duration (Hours) 24 Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the po sibility ZAnelmnsonment for knowing violations"
�etnni� AkcA t2�? l�ll
(Signature of Perm e) - (Date)
Form SWU-246-051100
SWDOMR U:Wty DocumentslEnvironmentall.SStormwatenTier 212011 August Tier 2 Report.vls Page 2 of 2

Stormwater Tier Two Response Record
Domtar Paper Company, LLC — Plymouth, NC
NODES Stormwater Permit NCS000189
1. Outfall — Contractor Laydown Area 1 1 (Representative Outfall for Cl_-11, 13, and
14)
2. Date of sample collection —November 29, 2011
3. Date Results Received — November 30, 2011
4. Rain Event total — .33 inches
5. Parameter exceeding benchmark value — TSS
6. Analyses results — 720 mg/I
7. Permitted Benchmark target — 100 mg/l
8. Cause of benchmark exceedance — Parking lot silt, gravel was picked up by
rainwater and transported down the ditch. There are two ditches that carry
stormwater to the outfall from this area, one on the south side of the road and one
on the north side of the road. The ditch on the north side has several BMPs in
place. The south side has none. This underground pipe discharging into the ditch
to the outfall wasn't noticed until this inspection.
9. Mitigation Measures considered:
o Add straw and rock inside the south side ditch. Add a silt fence just prior to
the drainage pipe going under the road
o Add rock and straw to the discharge side of the drainage pipe after it comes
out from under the road.
o Will investigate to see if something else is short-circuiting the BMPs currently
in place.
10. Implementation of mitigation measure must be complete by — 12/29/1 1.
11. A field inspection was conducted by Kari Cahoon 12/14/1 I. Alan Barnes, Diane
Hardison, Don Wynne were part of the discussion of next steps 12/8/1 1.
U:\My Documents\Environmental\Slornl"ater\Tier 2\7icr'1'wo Response Records\Stormuater'I'ier'Lew Response Record CIA 111
29 1I.doc Page I of I
Record to be stored with StonmValer Pollution Prevention Plan and Compliance Manual

Domtar
It all begins with paper'
Domtar Paper Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
T 2S2-793-6111
www.domtar.com
February 16, 2010
Mr. Al Hodge
Division of Water Quality
NC Department of Environment and Natural Resources
943 Washington Square Mall
Washington, NC 27889
Mr. Brian Lowther
Wetland and Stormwater Branch
Division of Water Quality
NC Department of Environment and Natural Resources
1617 Mail Service Center
Raleigh, NC27699-1617
Certified Mail
Return Receipt Requested
Subject: Request to Remove Dioxin Sampling/Analyses Requirement from Permit
Request for Representative Outfall Status
Domtar Paper Company, LLC - Plymouth, North Carolina
NPDES Stormwater Permit # NCS000189
Domtar received revised stornwater permit NPDES# NCS000189 for its Plymouth, NC facility
in 2009, effective as of August 1, 2009. Since that time, the facility has completed the first six-
month monitoring period. Based on Domtar's observations of the permitted outfalls and test
results from the analytical sampling, we requests modification of our permit as follows:
Removal of the requirement to sample and analyses outfalls for dioxin,
Designation of two outfalls as representative for five; therefore, removing sampling
requirements for three outfalls,
Designation of sheet flow status for one outfall; therefore, removing sampling
requirements for one outfall.
This request submittal includes the following attached references:
• Summary Table of Permitted Outfalls
• Stormwater Discharge Outfall Monitoring Report for August 2009
• Stormwater Discharge Outfall Monitoring Report for November 2009
• Stormwater Sampling Worksheet
• Copies of the Analytical reports from the Dioxin Sampling
• Map of the Stormwater Drainage Area for the West Contractor Laydown Area
• Map of the Stormwater Drainage Area for Landfills No. 2 and 3
• Map of the Stormwater Drainage Area for the Wood Recycle Area
D:\Documents and Settings\MccraDa\l.ocal Settings\l'emporary Intemet Piles\OLK45\Req Redltequirementsl'eb2010.doc
Page I of 3
Domtar Paper Company, LLC—Plymouth, NC

25 z p gr rf8( w,j
3 • ISM.,
Zs z 9� g 39s3
¢1zyo w:iL -raj-

Dioxin Sampling and Analyses
The rain events of this past August and November allowed successful sampling of 1 1 permitted
outfalls at the facility. Outfalls not sampled were either not required to be sampled or did not
produce channeled flow that could be sampled. Dioxin analyses results for the sampled outfalls
were all below detection levels. Therefore, we request that the DWQ remove the dioxin
sampling and analyses requirement from our permit for all outfalls. Copies of the analytical
reports for the dioxin analyses are included with this submittal for your reference.
Designation of Representative Outfall Status
The Plymouth facility has potentially two opportunities for grouping outfalls and designating one
in each group for representative status:
1. Outfalls CLl1, CL13 and CL14 are closely located to each other and all discharge runoff
from the contractor laydown area, at the west end of the facility This area is pervious to
rainfall, covered in gravel and primarily serves as a parking lot and laydown area for
equipment. The table below summarizes the analytical results from the August 1, 2009 —
January 31, 2010 monitoring period. Based on these data and the co -locations of these
outfalls, we recommend that our permit designate outfall CL14 as representative of
the runoff from this laydown area; and therefore, not require analytical monitoring
(sampling) from CLl1 or CL13.
Outfall
BOD m /l
COD m /I
TSS ma/1
pH
Dioxin
CL1 l
2.47
8
53
7.6
Not Detected
CL13
2.54
11
4
7.6
Not Detected
CL14
1
32
44
8.2
Not Detected
2. Outfalls LF01 and LF02 discharge stormwater from two sedimentation ponds which
collect runoff from the closed, capped and vegetated No. 2 landfill. LF01 (on the east
side of Landfill No. 2) regularly discharges flow during moderate to heavy rain events.
However, LF02 (on the west side of Landfill No. 2) rarely discharges flow. The
excessive rain event of last November, which produced nearly seven inches of rain in a
48-hr period, caused discharge from LF02. The table below summarizes the analytical
results from the August 1, 2009 — January 31, 2010 monitoring period. Based on these
data and the historical precedence of little to no flow from LF02, we recommend that
our permit designate outfall LF01 as representative of the runoff from the No. 2
landfill area; and therefore, not require analytical monitoring (sampling) from
LF02.
Outfall
BOD m /l
COD m /I
TSS m /I
pH
Dioxin
LF01
6.21
49
12
7.5
Not Detected
LF02
4
46
20
6.8
Not Detected
D:ADocuments and Scuings\MccraDaALUCaI SettingsCrmnponny Intcinet FiIcsVOLK45\Rcgltcdl2cquiremcntshcb20l0.doc
Page 2 of 3
Dumtar Paper Company, LLC — Plymouth, NC

Removal of Requirement to Sample Outfall WRA Due to Sheet Flow
The stormwater drainage area identified as the Wood Recycle Area, does not produce any
channeled flow that can be sampled. This was true under the conditions of the former
stormwater permit for the facility. Even the excessive rain event of last November did not
produce any channeled flow from this area. Therefore, we request that DWQ remove the
requirement to sample outfall WRA from the permit.
Note Concerning Outfall LF03:
You will notice in the previously submitted Stormwater Monitoring Reports and the attached
information that LF03 neither produced any flow during the August 1, 2009 — January 31, 2010
monitoring period. This outfall serves the currently active No. 3 landfill. After cell one of this
landfill is closed and capped, this outfall will discharge stormwater from a sedimentation pond
which will collect the runoff from cell one. However, until cell one of this landfill is closed and
capped, neither runoff will collect into the pond, nor will any flow discharge through outfall
LF03. Closure of cell one will begin in late 2010. LF03 may begin generating discharge in
2011.
Should you have any questions concerning the requests of this submittal or require additional
information in order to process these requests, please contact Tamika Boone at
tamika.boonendomtar.com (252-793-7490) or me at diane.hardison cr,domtar.com (252-793-
8611). We further welcome visits from DWQ representatives to the Plymouth facility in order to
help facilitate these requests.
Sincerely,
Diane R. Hardison
Environmental Manager
xc: Tamika Boone — Domtar
Alan Barnes — Domtar
Bill Morris - Domtar
DADocuments and Scam gs\MccraDa\LocaI Settings\Temporary Internet Fi Ics\OLK45\I2eq kcdRequirementsl'e62010.doc
Page 3 of 3
Domtar Paper Company, LLC — Plymouth, NC

Yea
Oointar Paper Company,LLC
Plymouth Mill
._-.
PO Cox 747
11)O ^���a .r,l+
Highway 149 North
��IIlHA
Plymouth, NC 27962
T 252-793-8211
It :ill bayius wall paper'
www.domo, com
December
10, 2009
Division of slater Quality
Att1Y. Count! files
1617 Mail Service Center
Raleigh, NC 27699-1617
Ceriijied IVlni1
Reiurn ReceipiS Regussied
Subjeci: WDI's Permii # NCSOOONN, Wear 1 — Period J lYloniiurin,, Period
August 1, 2009 io January 31, 2010. Reg1Lh ed Siormtvrrie1 Anrdy.r%s jor Oomiar
Paper Company, U C, Plymouth, North Carolina
Dcar Sii(s):
Enclosed you will find the original and one copy of a completed "Siormevzlter Discharge
Monitoring Report' Col the Year I — Period I Monitoring Period designated from August
I, 2009 to January 3 I, 2010 An attempt was made to collect a sample from each of the
designated outfalIS that was not samplcCI during a previous storm avcnt. This report
includes 7 of Ti; 9 remaining requireC sampling locutions required by DOInta1 �5 stronn
water permit No. NCS0001 89. We have also included a spreadsheet that contains
intonnation regarding the progress of Rumpling during the representative 'storm events.
The COD sample result for the W\} Nf location was 316 mg/L, which exceeded the
benchmark value in our permit. As a result of this excecclance,, a nocting and field
inspection was conducted per the action steps required by the permit. The report tronn
HIM meeting is included and further Cliscusses what oilier actions need to be taken.
If you have any questions or require any additional information pertaining to this report,
please coniact me by phone; [phone] or by email, tamil:a.boonaii�dorntar.com.

STORMVVATER DISC...RGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189
or
Samples Collected During Calendar Year 2009
Certificate or Coverage Number: NCG
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
FACILITY NAME Dormer Paper
Company, LLC
COUNTY Martin and Washington
PERSON COLLECTING SAMPLE(S)
Diane Hardison, Tamika Boone & Alan Barnes
PHONE.NO. [phone]
CERTIFIED LABORATORY(S)
Columbia Analytical Lab4 527-
i
Domtar Paper Company Co, LLC Lab# 171
(SIGNATURE OF PERMITTEE OR DESIGNEE)
Wastewater Lab -Plymouth
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Fart A: Specific Monitoring Requirements
Obtfall
Date'
Even,
Total �'
60D v
Dtoxln{'
F!o...
Sanple ,
DDratlon ,r.
Ralnfzl
aw ,�„'.;
JCODI
s',.
','1�c
��'.
- r
a•5
mg/l4y�-
x•.
❑igll
mgll�:
_
,s,
;
n.,tm../dd/yra ,
:
'
-y
R
'
tu
1 N
11/12/2009
6.at
17
316
34
7.4
Not detected
NBA
11/12/2009
6,81
3
37
17
6.3
Not detected
OBA
11/11/2009
6,81
10
93
49
7.5
Not detected
LF04
11/12/2009
6.at
2
46
69
6.9
Not detected
CL14
11/11/2009
6,81
1
32
44
8.2
Not detected
ILF02
I 11/12/2009
6.61
4
46
20
6.8
Not detected
RY01
11/11/2009
6.81
3
23
22
8
Not detected
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? Yes No
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfa"II
No
v
Dite
S Ic
Collected'v'..a.,
50050
hotel Flow
556
Od andr"-
Greasy.,
'
530
Total
Suspendods' r
Solids. __-
400
pH- >i
,
°.
New Motor
OI sago
_
m_ olddlyr . -
MG
mgll" -
mgll
tin -it
gallmo `
i
r
SV•/DOMR
Note: There is a grage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
U:\Water%Sto,mwater\S WAnalyticalReporFormNov2009.xis
Form SWU-246-051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
Date 11110-12109
Total Event Precipitation (Inches) 6.81
Event Duration (Hours) 53
Mail Original and one copy to:
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date.
-total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of Permiltee) (Date)
Form SWU-245-051100
S W DOMR U:\Water\Stormwater\SWAnalyticalRepoOForm Nov2009 xis Page 2 of 2

Dormer Paper Company, LLC
Permit No. NCS000189
Siormwaier Sampling worksheet
Date
Outfall No.
Time
Analytical Sampling
Point (Y/N)
If yes, was a sample
taken?
Flow
(Y/N)
pFl
Total
Rainfall
(Inches)
Comments
OBA
12.33PM
Y
N
N
1.62
WYN
11;45AM
Y
N
Y
1.62
Only sheet flow. No channeled flow
CL 11
12,02PM
Y
YES
Y
7.6
1,62
CL14
12:21 PM
Y
N
N
1.62
WLS01
11:25AM
Y
YES
Y
8.3
1.62
CL13
12.13PM
Y
YES
Y
7.6
1.62
^?
LF01
1025AM
Y
YES
Y
7.5
1.62
I LF02
11:00AM
Y
NO
N
1.62
WRA
11:14AM
Y
NO
Y
1.62
Sheet Flow
`-'
NBA
10:55AM
Y
NO
N
1_62
LF04
10:47AM
Y
NO
N
1.62
L-1
LF03
10:40AM
-
Y-
-
NO
N
.1.62
No flow to pond because there is no runoff
from the landfill. It has not yet been capped
and closed.
I
RY01
11:41AM
Y
NO
N
1.62
CL14
2:37PM
Y
YES
Y
8.2
6-81
CP01
1:53PM
N
6,81
—_
PR PA
1:39PM
N
6,81
RY01
1:49PM
Y
YES
Y
8
6.81
c
ORA
11:51am
Y
YES
Y
BS, 7.5
6.81
�.
FY01
10 40am
N
6.81
AR01
10:45am
N
6.81
II took more than five inches of rain to
generate flow at this site. There was no flow
LF02
9.46AM
Y
YES
Y
6.8
6.81
on the previous day
It took more than five inches of rain to
-
generate flow at this site. There was no flow
WYN
10:26AM
Y
YES
Y
74
6,81
on the previous day
N
CD
It took more than five inches of rain to
generate flow at this site. There was no flow
LF04
9:12AM
Y
YES
Y
6.89
6.81
on the previous day
It took more than five inches of rain to
generate flow at this site. There was no flow
NBA
9:32AM
Y
YES
Y
6.3
6.81
on the previous day
Highlighted information includes outfalls where a sample has been obtained.
Required sampling point where samples have yet to be obtained.

Storimivater Tier One 12esptuise Abecortl
Domtar Paper Company, LLC — I'I)'mouth, NC
NPDES Stormwatei Permit NCS000189
1. Outfall — Woodyard North
2. Date of sample collection - November 12, 2009
3. Rain Event total — 6.82 inches
4. Wonn or exceeding bend mHak value —COD
o Analyses result — 316 mg/I
o Permitted Benchmark target — 120 mg/l
• Date analyses received — November 24, 2009
5. Date of discussion meeting and stormvwater management inspection — November 30,
2009.
Partici 3a�:
o Marvin Haire— Woodyard manager
o Diane Hardison — Environmental Manager
o Tamika Boone — Environmental Engineer
o Roger Harrell — Woodyard Operations
o John Ge%— Piberline/Woodyard Maintenance Manager
o Allan Barnes — Envlronarnow ll Engineer
6. Cause of benchmark exceedance— abnormally heavy rains produced flow that could be
sampled from the hog fuel (bark) pile. The area has not been observed to produce
charmeled flow which could be sampled, before. However, nearly 7 inches of rain fell
over a 48 hour period November 10'h — 120 of 2009. The rains washed over a bark pile
which likely released volaiiles into the runoff from the degrading wood.
7. Mitigation Measures considered:
a.. Dig a trench along the south side of Ille road which boarders the balk pile to collect
any runoff before it crosses road and flows into adjacent forest.
o Trench will cause safety issues with chip and balk trucks that travel the
road.
o Trench would encroach on ground water which vwould have to be pumped.
There is no cost effective, technically feasible way to pump the ground
water to any logical receiving location.
b. Build a small berm along the north side of the road which boarders the bark pile
to prevent any runoff crossing the road from flowing into the adjacent Forest.
c, Wspect berm on a regular basis to ensure integrity
c. Install some type of filtration clevice
R. Selected Option — b above
9. Implementation of mitigation measure must be complete by—,Ianttary 30, 2010
D1Dual Ile nls anJSeums\bonnet:uul\I_ucaI Set ings\Temporiry Inleincl File>\0LK36\Sturmwmci Tier one Idesponsc
Record Nov2009.doc loge I of I
As pielimed by Dime Hafdison — Hnvimomenlnl Dept
Recnnl lu he stmed wish Slorntwaler Pollution hevenlion flat anal conlpli;tttcc Nrl"wil

oorntat Papep Company, w_
Plymouth Will
PO Box 747
T �� Highway 149 No,th La Plymcluth,K 27962
T BATI8111
It all begins with p:ipcI: www doiniaLCOm
September 21, 2009
Division of Water Quality
Ann: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
Cerlij ierl IYlni[
ReOwn ,Receipts Rep7reyed
Subject: IVPDES Peima 4 NCS000189, Yem 1 — Period 1 IWo7iiloring Period
Augusl 1, 2009 to January31, 2010. R%iluirerl Sbrumuder A7u21yses for Domkc
Paper C'omptiny, 1_LC, 111ymowh, North C'arohim
Dear Sir(s)
Enclosed you will And the original and one copy of a completed `StormwLttcr Dischargc
Monitoring Repoli' for the Year I — Period t Monitoring Period cicsi iaied itum August
1, 2009 to January 3 L 2010. An attempt was made to collect a sample from each
designated outfalt however, there was no How present at nine of the outtalls. As a tcsult,
this report only includes 4 of the 13 required sampling locations required by Domtai's
storm water permit No. NCS000189. We will make every attempt to sarnple the
remaining locations during subsequent representative storm events before the end of the
period.
If you have any questions of require any additional information pertaining to this report,
please contact me b Shona, 2e2) 793-7490 or b y email, mcnika bl.�unef�r,!dointar.conl. I
I Y I (� ���. ) ,
Sincerely,
[amika Boone
Environmental Eugilwel
�:c: De pain iu nl tiler

Permit Number. NC S000189
Certificate of Coverage Number: NCG
,FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Alan Barnes R Lorenza Palin
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
or
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC I_ab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2009
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washincton
PHONE NO. [phone]
(SIGNATURE OF PF-RMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Outfall;
Date, ._
Event -
Foal`
BOD `, -COD
TSS = -
Pro-.. -
D�ox�n
No
Sample—,`Dulatfon:�
*
RalrifalL
`
p
-'-.
s
_
-
"
Coltebtedy .
Hr 1vlln '
Inclies" t
mgll „s'^'; :
mcrl `
mg/I -
mg/6
_
Winter Log
Storage
8/31/2009
24 Hr
1,68
2.93
10
13
8.3
Not detected
CL11
8/31/2009
24 Hr
1 68
2.47
8
53
7.6
Not detected
CL13
3/31/2009
24 Hr
1.68
2.54
11
4
7.6
Not detected
LFO i
3/31/2009
24 Hr
1.68
6.21
49
12
7.5
Not detected
�J
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
50050 _`
556 _--- ;-
530 Mt ay, `'
400 �-
Sample "
Total Flofrv� t
011�a nd-,.,
Totahx 4+,r
pH
Nev+M`ot'ori_„
Collected,
`+
Greaser >
Sus pendedz,'`
-
Oil Usage,
_-
Solids'
NG,�
mg/11y,- s
Inglf - ;....-,
unit ., -_T?`
galhno= :> .
)
)
SWDOMR
Yes
NO
Note: There is a garage onslte, however it is fully contained and drains directly to
Our v✓astewater treatment system. Also, there are no outfalls located in this area.
U.\W a terNStormwate r\5`NA na lytica I R e po GFo rmAug 2009. zls
Form SINIJ-246-05i100
Paoe I of

STORPl1 EVENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Oualitv
Date 3/30-31109 AUn: Central Files
Total Event Precipitation (Inches) 1.62 1617 Mail Service Center
Event Duration (Hours) 24 Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
9/21/2009
(Dale)
Form SWU-246-051100
SINDOMR U:\Water\Stormwater\SWAnalyticalPeportFormAug200g.xls Page 3 of 3

STORMWATER DISCHARGE OUTFALL (SDO)
1140NITORING REPORT
Permit Number: NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Alan Barnes 3 Lorenza Patin
CERTIFIED LABORATORY(S) Columbia Analytical I_ab# 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2009
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results frorn the laboratory.)
COUNTY Martin and Washington
PHONE.NO. [phone]
(SIGNATURE OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate and
complete to the best of my knowlenlye.
Ou fall..
No
'
Da e
Sample,
Collected
went � 1�
Tc al
BOD
COD a
164
ASS
tin/I
PI -I
mg/6.
Dioxini.
_
v
Winter Log
Storage
8/31/2009
24 Hr
1.68
2.93
10
13
3.3
Not detected
CL11
8/31/2009
24 Hr
1.68
2.47
8
53
7.6
Not detected
CL73
8/31/2009
24 Hr
1,68
2,54
11
4
Z6
Not detected
LF01
3/31/2009
24 Hr
1.68
6.21
49
12
7.5
Not detected
J
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall. "'
,+�-'��
556 - °530"
400
No
Tota llFlow
011jan d�'
TotaP-
pH v.RNew Motor
Grease
Suspended
'� 011 Usage
xSolidsMGF
ADate­�50050
i
1
I d q
Yes
No
Note: There is a garage onsite, however it is fully contained and drains directly to
our wastewater treatment system. Plso, there are no outfalls located in this area.
Form SWIJ-246 051100
SWDOMR U:\Water\Siormwater\SWAnalyticalReponFofmAag2009.As Page i Of

STORM EVENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Duality
Date 3/30-31/09 Attu. Central Files
Total Event Precipitation (Inches) 1.62 1617 Mail Service Center
Event Duration (Hours) 24 Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
' I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
2/21/2009
(Date)
Form SWU.246-051100
SWDOMR U.\Water\Stormwater\SWAnalvticalRepoc FormAug2eeg.xis Page 2 of 3

Domtar Paper Company, LLC
Permit No. NCS00O189
Stormwater Sampling worksheet
Date
Outfall No.
Time
Analytical Sampling
Point(YIN)
If yes, was a sample
taken?
Flow
Y/N
H
Total
Rainfall
Inches
Comments
OBA
12:33PM
Y
N
N
1.62
WYN
11;45AM
Y
N
Y
1.62
Only sheet flow. No channeled flow
CL11
12;02PM
Y
YES
Y
7.6
1.62
CL14
12:21 PM
Y
N
N
1.62
WLS01
11:25AM
Y
YES
Y
8.3
1.62
ao
CL13
12:13PM
Y
YES
Y
7.6
1.62
LF01
10:25AM
Y
YES
Y
7.5
1.62
N
LF02
11:OOAM
Y
NO
N
1.62
o
0
WRA
11;14AM
Y
NO
Y_
1.62
Sheet Flow
�
NBA
10:55AM
Y
NO
N
1.62
LF04
10:47AM
Y
NO
N
1.62
LF03 _
10:40AM
Y
NO
N
1.62
No flow to pond because there is no runoff
from the landfill. It has not yet been capped
and closed.
RY01
11:41AM
Y
NO
N
1.62
CL14
2:37PM
Y
YES
Y
8.2
6.81
CP01
1:53PM
N
6.81
N
6.81
PRPA
1:39PM
YES
Y
8
6.81
RY01
1:49PM
Y
o
OBA
11:51am
Y
YES
Y
8.5.7.5
6.81
to
FY01
10:40am
N
6.81
AR01
10:45am
N
6.81
It took more than five inches of rain to
generate flow at this site. There was no flow
LF02
9:46AM
Y
YES
Y
6.8
6.81
on the previous day
It took more than five inches of rain to
generate flow at this site. There was no flow
WYN
10:26AM
Y
YES
Y
1 7.4
6.81
on the previous day
N
It look more than five inches of rain to
c
o
1
generate flow at this site. There was no flow
0
LF04
9:12AM
Y
YES
Y
6.89
6.81
on the previous day
It took more than five inches of rain to
generate flow at this site. There was no flow
NBA
9:32AM
Y
YES
Y
6.3
6.81
on the previous day
(Highlighted information includes outfalls where a sample has been obtained.
Required sampling.point where samples have yet to be obtained.

4�fAS Columbia W/
Analytical Services" 14zw.1cs111,_vAe200 r 11-11111"!4,:.:zzss ! :n.,7") 21iiemm
i
September 21, 2009 Service Request No: J0904340
Diane Hardison
Domtar Paper Company, LLC
P.O. Box 747
Plymouth, NC 27962
Laboratory Results for: St01'mWater Testing
Dcar Diane:
Enclosed are the results of the sample(s) submitted to our laboratory on September 2, 2009. For
your reference, these analyses have been assigned our service request number J0904340.
All analyses were performed according to our laboratory's quality assurance program. The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc.
(CAS) is not responsible for use of less than the complete report. IZesults apply only to the items
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report
Please contact me if you have any questions. %Nly extension is 4403. You may also contact me
via email at TKissinger cr caslab.com.
Respectfully submitted,
Columbia Analytical Services, Inc.
Tom Kissinger
Project Manager
Page 1 of 3
Fora specific list refer to the cei tifications section ar
�1ll.w.cucluh.com

Clien(: Domtar Paper Company, LLC Service Request: J0904340
Project: Stormwater Testing
SAMPLE CROSS-REFERFACE
SAMPLE
ClIENTSAMPLE ID
DATE
91ML'
J0904340-001
Winter Log Storage
8/31/09
l 1:25
J0904340-002
Cl; 11
8/31/09
1202
J0904340-003
Cl- 13
8/31/09
12:13
J0904340-004
LF-01
8/31/09
1025
PrinleJ 9e 1i09 12:28
Sample Sununan,
Page I of I

Columbia Analytical Services,'tire.
Cooler Rcccipt and Preservation Form
i(-..!c 1. is Cam. Scl'v;cc RcouesL -
cF
(Cooler received on C)CZ and op;tted onC:A
cFt.y
COURIER: CAS FEDEX DHL CLIENT Tracking UPS
I Wei e custody seats on outside of cooler?
Yes No N/A
Were seals intact, signed and dated?
Yes No /n
3 Were custody papers properly filled out?_
No N/A
Temperature of coo [Cr(S) upon receipt - (Shodd be a 2 g�
de 'ee5 C)
Correct Temperature?
b Wero Ice or Ice Packs present
No Nov
- Did all bottles arrive in good condaiori (unbroken, etc....)?
A c.e all bottle libels complete (sa.uplc Ill. t.resr<v anon, etc...)'.
Q ?:a
9 Did at boaie Iabets and tags agree scith custody papers?
G Were tha eoltectbottles used tct the tests indicated?
.lo
I I `•ve'e ah of the preserved botties recervvcd with tile Ipproul to pmscrvativ;;?
v ,s N.
HNO3 pFh2 H2SO4 pH<2 Zn."c2/.Na0H pH>9 Na011 pt1>12
Iici
I'll�el'V III!) I! )"s I10In b00w
e!'e all samples received within analysis holding times?s;
f y'h
o N;A
I i We, V0.4 vials checked for absence of eir bubbles) If present, note 'below
Yes NO i�i/;A '
14 Where did the bottles originate?
I
C, Clicat
tMa nlf. Lot # or CAS
Simple ID
Reagent
ChemID
ml added
nititials
1
I
Additional conur.ents anti/or explanation of all discrepancies noted above:
i1
i
khen[ approval to 1'llil samples if dI5C1'dp:1nC1Bs acted:
Date: �
-1 -12

, :,,,, i .1 1 , tlschrs, unJ —,, 11, e,, 11 .1,,n I,Lo1 .11 I'll.. — ;..� —1., "',l .n 1110 11.1.
e'o.'
®a
��
�50��5
_���
o_
_fie
p.��_��=-::_
�
a
:�
'
BCC
�

ACmaylia
nalyilcal
Services �-
as�o �e
CHAIN OF CUSTODY / LABORATORY ANALYSIS REQUEST FORM
9143 Philips Higlway, Suite 200 lacksom-illq Florida 32256/Phonc(904)739-22771800-695-7222/Fae 904-739-2011
ScfloY�v�
Contact
P:aieel came
Stormwater Testing
ProJert Numbor
Report CC
Alan Barnes
_4
z
��.
w0
W
ANALYSIS
0
REQUESTED
_
(Include
Method
Number
en
Report To
Diane Hardison
x
.0
1. HCL
2. HNO3
3. H2SO4
4. N.OH
5. Zn. Acclatc
6. NkOH
7.NaHSO4
ItENIARKS
Company/Addrea
Domtar Paper Company
P.O. Box 747
Plymouth, NC 27962
Phone N
252-793-8611
FAX k _
262-793-8871
Sumple/a Sjpyamr_
t i (:i,/✓
>1
Samplor's Dprt,d Namc /r� r-
a/'/` v�iC �/'JL'J
CLIENT SAMPLE ID
LAB ID
SAMPLING
DATE TIME
Matrix
Winter Log Storage
Dioxin
8/31/09
11:25
Water
2
X
CL-il
Dioxin
8/31/09
12.02
Water
2
X
Cl,-13
Dioxin
8/31/0912:13
Water
2
X
LF-01
Dioxin
8/31/09
10:25
Water
2
X
Winter Log Storage - AM
CL-11 -PM
CL73 -PM
LF-01 - AM
Stornlwater Samples for Dioxin Testing.
�
(f/�) �f L�//%:... ✓` �� '^'U��•� iU �'C,��ryS��U
/
"
TURNMROUND REQUIREMENTS
RUSHlSUR6I.VtO2S MPl1')
STA.\DARD
QUESTED 1. UATE
U6STm REPORT DATE
REPORT REQUIRNMENTS
L RerW40NY
II.R ilui QC Summ f
RCS. DUT. MSMSD requssed)
X M- ..wines bowo.a�
I'✓. UOe VWi7. Report w Rm D. '
Edah Y'e No
INVOICR INSORNW TON
P.O.q a!'4'+%IV`W�• �•
muw
L/I KoIn uu c y
Siglature /t �J
RTN,Wy
Slgunue
Keftai.,Ind by
Signature
erve v
Signs
Rehrqu,,hod By
Sigumro
R.t,.d By
Sig auo,
Pnnted N Y'
:ram , r ^J 1
1'nnted Name
r. z
Prime Name
p
PcRlted Namo
Printed Nwne
Fvm 1p�d+v
Fr
F'
F
Firm
F=
Date
Date/Cimc
Datdrime
D !I'vne „r-..
CS(
D Irlfvne
Date IUnt,

,�,'' Columbia
EN Analytical Services -
Appendix A
Columbia Analytical Services
9143 Philips Highway, Suite 200
Jacksonville, FL32256
Tel [phone]
Fax [phone]
Subcontracted Analytical Results

Columbia
Analytical Services-
19408 Park Row, Suite 320. Houston, TX 77084 1 713.266.1599 www.caslab.com
.. ... .......... ..........
.. .. ..... .. ..... .... _............ ... ._. .......... .. ...
September 17, 2009
Tom Kissinger
Columbia Analytical Services
9143 Philips Hwy, Suite 200
Jacksonville, FL 32256
Laboratory Results for: Stormwater Testing
Dear Tom:
Set -vice Request No: J0904340
Enclosed are the results of the sample(s) submitted to our laboratory oil September 03, 2009. For
your reference, these analyses have been assigned our service request number J0904340.
Analyses were performed according to our laboratory's NELAP approved quality assurance
program. The test results meet requirements of the cwTent NELAP standards, where applicable,
and except as noted in the laboratory case narrative provided. All results are intended to be
considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for
use of Icss than the complete report. Results apply only to the items submitted to the laboratory
for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the
NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any
quantitative analysis will be supplied upon request.
Please contact me if you have any questions. My direct line is 281-994-2954. You may also
contact me via email at D13iles n caslab.com.
Respectfully submitted,
Columbia Analytical Services, Inc.
Danen Hiles
Project Manager
For a specific list ofVELAP-accredited analptes, refer to the. certifications section. at ... .... .... _
1oww. caslab. coin.
1`,n Enullo5ee O'.vnad company NELPAgcredied tc t. Saal of &ceiumce AVnrC I Please consido'the einvironrnrnt before printing
1 of 26
7

Columbia
Analytical Services -
Certificate ofAnarysis
'19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]'130
www.caslab.com
Ao Employee Ovmed Company
2 of 26
8

COLUMBIA ANALYTICAL SERVICES, INC
Client: Delmtar Industries
11roj ect Stormwater Testing
S:unple Matt iz: Water
CASE NARRATIVE
Service Request No.: J0904340
Date Received: 9/3/09
All analyses were perfomred in adherence to the quality assurance program of Columbia Analytical Services, Inc.
(CAS). This report contains analytical results for samples designated for Tier 11. When appropriate to the method,
method blank results have been reported with each analytical test.
Sample Receipt
Four water samples were received for analysis at Columbia Analytical Services on 9/3/9.
The samples were received at 0°C in good condition and ire consistent with the accompanying chain of custody
form. The samples were stored in a refiigeralor at 4°C upon receipt at the laboratory.
Please note the reporting forms are currently referencing the date CAS- Jacksonville received the samples (9/2/09)
and not the date CAS -Houston received the samples (913/09.)
Data Validation Notesand Discussion
AiS/DAIS
HQ0900362: Laboratory Control Spike/Duplicate Laboratory Control Spike (LCS/DLCS) samples were analyzed
and reported in lieu of an ;NIS/DIAS for this extraction batch. The batch quality control criteria were met.
Delccliou Limits
Detection limits arc calculated for each congener in each sample by nreasming the height of the noise level for each
quantitation ion for the associated labeled standard. The concentration equivalent to 2.5 times the height of the
noise is then calculated using the appropriate response factor snid the weight of the sample. The calculated
concentration equals the detection limit.
Approved bv: CL� �����✓'� ��
Xiang lip Liana, Laboratory Dirccto-
Dalc: 09/18/09
3 of 26
9

Client: Spectrum Analvlical, Inc.
Proycc Jmnaica GW
SAMPLE 4
K0904340-001
K0904340-002
I',imc,l n95/oq 11 1)
CLIENT SAMPLED
SA94763-01
S'.A94768-01
SADiPLE CROSS -It EPERENCE
Scmce Request: K0904340
DATE. TIME
5/13/09 1005
5/13109 1005
4 of 26
s,.,ie sun 'a., 10 Page I or

Laboratory Certifications
2009-2010
STATE/11ROGRAM
AGENCY
CI,,I2TIEICATION ID
FAP DATE
ARIZONA
AZ-DliS
AZ0725
05/26/10
ARKANSAS
ADE
09-048-0
06/16/10
CALIFORNIA
CA-ELAP
2452
02/28/11
BLORIu,VNELAP
FI. DOHS
ES7611
06/30/10
ll'mml
III-DOFI
N/A
06130/10
ILLINOWNELAP
IL -EPA
002122
10/06/09
LOUIS IAN,VNE -AP
LELAP
03048
06/30/10
MAINE
M1 DOFIS
2008031
06/05/10
MICHIGAN
NIIDEQ
9971
06/30/10
MINNESOTA
MDH
048-999-427
03/25/10
NEVAUA
NDEP
TX014112009A
07/31/10
NEwJerzsev
NJDEP
TXOOS
06/30/10
NEwa7Exlco
NMED-DWR
N/A
06/30/10
NESv YORK/NELAP
NY -DOH
11707
03/31/10
IN'FESC/NAVY
NFESC
N/A
O1/09/10
Om„wonm
OKDEQ
2009-23
08/31/10
ORF.GON/NFLAP
ORELAP
TX200002-006
03/24/10
TENNE.SSEE
TNDEC
04016
06/30/10
-PExAs/NELAP
TCEQ
Tt04704216-09-TX
06/30/10
UTAIJ/NF,LAP
UTELCP
COLU2
06/30/10
SOIL Imu,ORT Prizml I
USDA
P330-09-00067
03/27/12
WAS IUNG'10NhN' ELA P
WA -Ecology
CIS55
11/14/09
WESTVIRGINIA
WVDEP
347
O6/30/10
5 o126
11

Abbreviations, Acronyms & Definitions
Cal
Calibration
Conc
CONCentration
Dioxin(s)
Polychlorinated dibenzo-p-dioxin(s)
EDL
Estimated Detection Limit
EMPC
Estimated Maximum Possible Concentration
Flags
Data qualifiers
Furan(s)
Polychlorinated dibenzofuran(s)
g
Grams
ICAL
Initial CALibration
ID
IDentifier
Ions
Masses monitored for the analyte during data acquisition
L
Liter (s)
LCS
Laboratory Control Sample
DLCS
Duplicate Laboratory Control Sample
MB
Method Blank
MCL
Method Calibration Limit
MOIL
Method Detection Limit
MRL
Method Reporting Limit
mL
Milliliters
MS
Matrix Spiked sample
DIMS
Duplicate Matrix Spiked sample
NO
Number of peaks meeting all identification criteria
PCDD(s)
Polychlorinated dibenzo-p-dioxin(s)
PCDF(s)
Polychlorinated dibenzofuran(s)
ppb
Parts per billion
ppnt
Parts per million
ppq
Parts per quadrillion
ppt
Parts per trillion
QA
Quality Assurance
QC
Quality Control
Ratio
Ratio of areas from monitored ions for an analyte
%Rec.
Percent Recovery
RPD
Relative Percent Difference
RRF
Relative Response Factor
RT
Retention Time
RRT
Relative Retention Time
SDG
Sample Delivery Group
S/N
Signal -to -Noise ratio
TEF
Toxicity Equivalence Factor
TEQ
Toxicity Equivalence Quotient
6 of 26
12

Data Qualifier Flags — Dioxin/Furans
o B Indicates the associated analyte is found in the method blank, as well as in the sample.
o C Confirmation of the TCDF compound: When 2378-TCDF is detected on the DB-5 column,
confirmation analyses are performed on a second column (DB-225). The results from both the
DB-5 column and the DB-225 column are included in this data package. The results from the
DB-225 analyses should be used to evaluate the 2378-TCDF in the samples. The confirmed
result should be used in determining the TEQ value for TCDF.
o E Indicates an estimated value - used when the analyte concentration exceeds the upper end of
the linear calibration range.
o J Indicates an estimated value - used when the analyte concentration is below the method
reporting Hrnit(MRL) and above the estimated detection limit(EDL).
o K EMPC - When the ion abundance ratios associated with a particular compound are outside the
QC limits, samples are flagged with a'K' flag. A'K' flag indicates an estimated maximum
possible concentration for the associated compound.
o U Indicates the compound was analyzed and not detected.
o Y Samples that had recoveries of labeled standards outside the acceptance limits are flagged
with'Y'. In all cases, the signal-to-noise ratios are greater than 10:1, making these data
acceptable.
o ND Indicates concentration is reported as 'Not Detected.'
o 5 Peak is saturated; data not reportable.
o P Indicates chlorodiphenyl ether interference present at the retention time of the target
compound.
o Q Lock -mass interference by chlorodiphenyl ether compounds.
7 of 26
13

CAS/H[OU Form Production, Pecr Review &, Project Review Signatures
Date 9/17/09 Reviewerg
i
8 ar 26

Columbia
AN Analytical Services -
Analytical Results
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Faz(713)266-0130
www.caslab.com
An Employee Owned Company
9 of 26
15

COLUJI It IA A:NALV'II CA I. SI?R VIC
FS, INC.
Anaiytical Report
Client
Donaar l odustries
Scivice Request:
J0904340
I'rnject:
Stormwatci Iesting
Date Collected:
8/3 1109 1125
S:unple Matrix:
Water
(late Received:
9/2/09
Sample Name:
Winter Log Storage
Units:
pg/L
Lab Code
.10904340-001
Basis:
NA
Polychlm'inaled Dibenzodinsins and Polychlorinated Dibenzofurmts
by
IIIZGC/IIRNIS
Analytical Method:
1613B
Date Analyzed:
9/10/09 1443
I'rep Mcihod:
Method
Date hxlracted:
9/4/09
Sample Amount:
920ml-
Instrument Name:
6FFRMS-04
CC Column:
D6-5
DnIa File Name:
P204129
Blank Nile Namc:
P204108
ICA[, Date:
O8120/03
Cal Ver. Pile Name:
P204122
ton
Dilutinn
.-tn:drte Nmoe
Result Q LDI- NIRl,
Italia
121t1' Natlur
2.3,7,8=fCDD
ND U 0.355 IM
1
Spike Cure,
G:utral
lun
Lubclul Comp.i0 n4'
Cmm(Pg) 1'0and (pg) 'aatcc Q
LIn" is
Ratio RR'I'
13C-2,3,7,8--TCDD
2000 1300.000 65
25-164
0.78 1.007
370-23,7,8-TCDIJ
ROIL 692,895 87
35-197
NA I O(A
Pamu1 411]/a9 11,012
'ilnlLueZlS:ailLunLlmrNopzNnnl>'uoulHepotl rp�
Form IA
s„r��su rt,r«<�ce 09.000alz��ble7�
16

COLIIJIBIA ANALY-1ICAL SERVICES, INC
Analytical Rep]n
Client:
Donuar Industries
Set, ice Retlnest:
J0904340
P.ojccl:
Slom]waler Testing
Date Collected:
8/3 1/09 1202
San ld, 1Mab'ix:
Water
Date Received:
9/2/09
S:unple No ... c:
CI, -I I
Units:
pg/L
Lab Code_
J0904340-002
Basis:
NA
Polyeblorinuled Dihen[odinxins
and Polvehlorinaled Dibcn>,ofurans
by 1IRGC/HUMS
Analytical Method:
1613B
Date Analyzed:
9110/09 1530
Prep Method:
Method
Date Extracted:
9/4/09
Sample Amount:
940ml-
Instrument Name:
E-HRMS-04
CCColmnn:
DB-5
Data rue Name:
P204130
Blank File Namc:
P204108
I C.U. Dale:
08/20/08
Cal Ver. File Namc:
P204122
lot]
Dilution
An:dylc N:une
Result Q
BDL NIRI,
Ratio
R HTFactor
2,3,7,8-I-CDD
ND U
0.354 10.6
1
Spike
Can'.
Control
lot)
Labeled Compmin(l'
Cmte.(pg)
Round (pg) '%lire Q
Limits
Ratio RR'r
13C-2,37,8-1'C'DD
2000
1377.510 69
25-164
0.78 1.007
37CI-2,3,7,8=1CDD
800
722.898 90
35-197
NA 1.008
prin¢J 9i l itn9 11'.Ilt lbnn LA
.,InnonQ.StWinn4.Inn0.ry�.��Auilyuc-0N ywn rpi SUPtFSCt Rtftrtnc¢ 0900001]il]�n
17

COI.UNIBlA ANALY'I'I CAI. SEIMCES, INC.
Analytical Repon
Client:
Donuar ludusuies
Pr njccC
Svmnmater'I'esom,
sample A'latric:
Water
Sample Name:
CL-13
Lab Code:
J0904340-003
Service Request
.J0904340
Date Collected:
8131/09 1213
Date Reccivcd:
9/ 2109
Units:
pg/L
Basis:
NA
Polycbloi inatcd Dibenzodio�ias anti POdYcbinrinatcd 1)i1)cnznfor; uu by ]IRGC/IIRI\IS
Analytical Mcthod:
1613B
Date Analvzcd:
9/10/09 1618
Prep Method:
Method
Date Eshoctcd:
9/4/09
s:mtple Amount:
940mL
In.sti umem Name:
E-1IRMS-04
GC Column:
DB-5
Data File Name:
P204131
Black Rile Name:
P204108
ICAL Dale:
08/20/08
Cal Ver. File Nana:
P204122
Ion Dilution
Amdv¢•:N;wo,
12c,mh 0 I.DL Mu. Ratin ImI' Factor
2, 7,8-ICDD
' La ha4:d Cmnpawnls
ND U 0.238 10.6
Spike Cone.
Conc.(pg) Found (pg) %Ilcc Q
C..,I,.l tun
Lon il, Ratio RI2T
13C-2.3,7,9-fCDD 2000 1,112.958 71 25-164 0.77 1.007
37CI-2.3,7,.8=fCDD 800 723.263 90 35-197 NA 1008
I'i lnl<a 9:1 i/no I I'.02 total I A
:dnilo.. 6m�IImi LimsN.»Unals ��olRaPo��m� So Sa ReV—, 09�
v« oo0012`�3bR2go
18

COLU:MBIA ANALYTICAL SERVICES, INC.
Analytical Repnn
Client:
Dommi lndu.sirics
I'rnjcct
Slormwalcr Testing
Sample INlab'ic:
Water
Sample Nnmc:
LF-01
Lob Code:
J0904340-004
Service Regoesl:
J0904340
Date Collected:
8131/09 1025
Date Rcceiced:
9/ 2/09
Units:
po,
Basis:
NA
Polychlorinated Dibum'dinxins and I'nlychlorinaled Dibenzol'urans by 1IRGUHRMS
Amnlylical Method:
1613B
Date Analyzed:
9/10/09 1706
I'rgr INlelhod:
Method
Date Enacted:
9/4/09
Sample Anui oot:
930ml.
Instrument Name
B-IIRMS-04
GC Column:
DB-5
Dale File Name:
P204132
Blank File Name
P204108
I CA I, Date:
08/20/09
Cal Ver. File Name:
P204122
Ion Dilution
A nah'tc Name
Result Q IZDL MR1, Ratio HILT Factor
2,3,7„8-TCDD
ND U
0.3,18 10.8
I
Spike
Cone.
Cnnirol
Inn
I-abelrll (;n11111.......
CmIC.(pri)
tound(pk) Q
Limits
Ratio RRI
13C-2,3.7,3-TCDD
2000
1232.920 62
25-164
0.78 1,008
170-2,3,7,8=1 CDD
800
735.856 92
35-197
NA 1,008
rn....n-I,.
Ihinmd'I11U0911 02 Ponn IA
J 1,110-2V.91rll.-I.innaarye, naltiial0.epun iyi 5npertiel Relnaice: 09LO1o19IT; 2p 19

COLUNIBIA AN.V,1'9'IC9L SERVICES, INC.
Analytical Repon
Clicnl:
Domiar Industries
Service Request:
/0904340
1'rojen:
Stornnenter'resliug
Date Collected:
NA
' Sample \tau ix:
Water
Date Received:
NA
.s mn,J lc Name:
Method Blank
Units:
pg/L
Lab Code:
EQ0900362-01
Basis:
NA
Polychlorinated DiItcitzodioxins anti Pit lychloriitaIc(1 Di
benzofit rans by
IIRGC/I IRNIS
:\nalyticai Method:
1613B
Date Analyzed:
9/9/09 1906
Prep Mcthnd:
Method
Date Estracled:
9/4/09
&aniple:Aniount:
1000mi,
Instrument Name.
E-1'IRMS-04
GC Colmmw
DD-S
Dala Nile S:uu e:
['204103
Blank file Name:
P204103
I C:Ah Dntm
08/20/08
Cal Vm'. file Namc:
P204106
ton
Dilution
:Anni'le Name
Resull Q
EDL NIRL
Ratio
R12'I' Factor
23,7.1-1 C D D
ND U
0.333 10.0
I
Spike
Can,
Cmt(rol
Imt
Lo hrlcd Com puu nda
Cmn:.(pg)
found (pg) 4blicc Q
Limits
Raliu RIO
13C-2,3,7,3=rCDD
2000
943.243 47
25-164
0.77 1.003
37062,3,7,4-fCDD
S00
614.495 77
35-197
NA 1.009
Cno�inni u.
hm,d 2'IM1, 11 01 Fosm 1A
Y.Inllo.. �CinilnnSl_inishcpfUmlyuhlaul'o �n^ S""s, lt91'ocnre'. 09-0OWI.t'11Wbrff
20

Columbia
Analytical Services -
Accuracy and Precision
I
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.caslab.com
An Employee Owned Company
15 of 26
21

n
COLUMBIA ANALVI'l CA L SI'at\'ICES, IN(
QA/QC Report
Clicnl:
Domlar Industries
Service Request:
J0904340
Project
Stonmvater Testing
Date Analyzed:
9/9/09
San. ple .S l It Iris:
Water
Lab Control Sample SU111111atY
P elychI orinated
Dibetwodioxi its and PolYch l ormated D i I) enzofu Iit 11S by 11I2(7C/DIt1'IS
Anal}'lical Method:
1613B
Units:
PgA,
I'rcp McDlod:
Method
Basis:
NA
E%Oactlon Lot:
95259
Lab Cllnt,ol Salllllle' Dupll Cate Lab Control Sample
EQ0900362-02 EQ0900362-03 % Rec
RPD
AIIn IYt I' Mimi,
Resull Expected Ref Result Ex peCted % Ree Litt Its
RPD Limit
2,3,7,8=I'C'DD
231 200 116 227 200 114 67- 159
2 50
I'J.11, `ll17/09 I I'.:I3 1 xb C"WIOI Saalple Sumpwry
IIImIu:✓A10rliinaWm�Rwa+L=bConvolSamVl��p. Snpc:Sa Reference. po.pOpul:DN!)I �� Ib?� b

COLUMBIA ANALN TICAL SERVICES, IN'C.
Analytical Report
Client:
Delmar Industries
P n:jca:
slorlmvutei'I'esting
Sample Mail is:
Water
Smupic Nam c:
Lan Control Sample
Lab Cwk:
EQ0900362-02
Sctvice Request: J0904340
Date Collected: NA
Date Reech ed: NA
Units: Pg-[L
Bask: NA
Polychlorinated Dibenzndiuzins and Polychlorinated Dibenzaht.ans by 11RGC/llRMS
Aunk iird Method:
161313
Date Analyzed:
9/9/09 1518
flop \lethal:
Method
Date Euracted:
9/4/09
Sample AnmunL
1000mL
Inst ru nl call Name:
E-FIRMS-04
CC Colunm:
D6-3
Data Pile Name:
P204104
Blank bile Name:
P204108
IC:AI. Dale:
08/20/09
Cal Vet. File Name:
['204099
Inn Dilution
,)nalytc Name
licsnit Q 11,11)1, NMI, Ratio RR'l Factor
2,3,7,8-TCDD
231
0.245
10.0
0.76 1.001 1
Spike
Cone.
Cnntrul Inn
l abelcd C'nmpou ads
Conc.(pg)
For md (pq)
'Y.Rcc Q
Limils Ratio lilt'1'
UC-2,3,7,8-TCDD 2000 1355.027 68 25-164 0.7s 1,008
37(.'1-2,3,7,8-TC'DD 800 732327 92 3S.197 NA 1.009
Cn„.:n,.....
nad )It 10911:02 wan 1A
u,,,;..:•:.:,a,:%IiL nit,, +k„h dculNgvn:n+ s,r�s�, x.r�,ma: ra.00aoizj,�tbFT6"
23

COLI4\i81.A :A N,A 1.1' ricm, sl-RV'ICE1, INC.
Analpol Report
CIi,"1:
Domtar Industries
So -vice Reyuol:
10904340
1'. oyrt:
Slonnevater Testing
Date Collected:
NA
Sample r\1atrix:
Water
Date Received:
NA
S:Imple Nano:
Lab Control Sample Dup
Units:
pg/L
Lab Code:
EQ0900362-03
Basis:
NA
Polychlurimated Dibcnzodioxins and Polychlorinated Dibcnznl'ui ans by IIRGC MINIS
An:dyticd 1AIethnl:
1613E
Date Analyzed:
9/9/09 1606
PIcp Aletlod:
Method
Date Extracted:
9/4/09
Sample Amount:
1000m1,
Instrument Name:
E-FIRMS-04
CC Column:
DBS
Data File Name:
P204105
Blank File Name:
P204108
ICA1, Dale:
09/20/08
Cal Ver. File Name:
P204099
Ion Dilution
Anmlytc INan"
Result 0
EDL MR1, Ratio RR'r Factor
2,3,7.8=fCDD
227
0.259 10.0 0,77 1.000 1
Spike Cone. Control 10.
Lnbelnl Cn nrpnun Js Cmm.(pg) Found (pg) '71tcc 0 Lonit" Ratio RRI
13C-2,3,7,9-FCDD 2000 1244.291 62 25-164 0,78 1.008
370L2,3,7,8-TCDD 800 698.849 87 35-197 NA 1.008
curnr,r.mo�
R zaed 9i 1 i109 11.0 Form 1 A
pinrluw'_'SUJim\I irnaaepaUnalp OcalRcpen:yr SuytrStr Rd... a 09000012PKn6'I
24

Columbia
Analytical Services
(hair of custody
19408 Park Row, Suite 320, Houston, 7X 77084
Phone[phone] Fax[phone]
www.casiab.com
An Employee Owned Company
19 of 26
25

Intra-Nev,vork 'Caiat❑ of Custody
9143 Philips Hishrcvy • lackmnzi Ile, FI..'._''-56 - 90-1-7;Q-2277 - FAX [phone] I
Project Same: .S tornmatcr l 'stun_.
Pntjacl \'umber:
P rojeel ,Sls " ger: I )ianc I Fart ison
Cemp:urr: Done:u F':gx'r lnm pony, L LC
Lnb Cede Cliem Sample ID 9ofCom. ,Matrix
1 " n
i '7 —
i
Sample Dole 1 C
Mute Time Re"i red Send To
J t7904340-001 Win¢r lag Sumac
'
� �`.Vamr
5/31/09
1125 1 92/09 HOUSTON j II
J0904740.002 CL-I I
Wa[cr,
S/31/09
I202
i 92/09 HOUSTON
J0904340-003 CL-13
Water
65 1/09
1213 i 9(+/09 HOUSTON ❑ '
-
10904340-004 LF-01
Water
8/31/09
1025 9122/09 HOUSTON 11�
Test Cumumn (.
Dioxins Furans-1613D 10%47.10-001,2,34
Special 1 natruetions/Cma mcnti
PLEASE SEND
RESULTS TD
`4AN0Y SUL L I VAN
d
237E TCDD only,mport in mkt
Turnaround Requirements
_BUSH (Surcharees Appl))
PLEASE CIRCLE R`ORK DAYS
1 2 3 4 3
STA,N DA RD
Requested FAX D:rtc
Requested Report Date: 09/23/09
T� —
CAS CcnticC Tom Kissinger
J1
Report Requirements
I. Results Only
11. Results+QC Summaries
III. Resells +QC and Calibmtion Sunnnaries
_ IV_ Data Vnlidatiou Repot with Raw Data
I'QL/tdDlJJ Y
EDD N
rVmCe In(onnvlipn
J0904340
RelinquisheJ By: /�{ _ Lw / ,l�L U/�/� Recei. ed 8)',� r_�, `� v `lirbill Numhcr: (� X � Ly � J2w-9?f ' � U/ l 7
/v-+�• F-,[. I.Sa / 313C Po6e

Columbia Analytical Services, Inc.
Cooler Receipt Form
Client/Project Domtar Paper Company / Stormwater Testing Service Request J0904340
Received:_ _ 09/03/09 Opened (Date/Time): 09/03/09 0955 By: NAB
I. Samples were received via? [I US Mail ❑Feder QUPS ❑DIiL ❑Courier 711and Delivered
2. Samples were received in: (circle) Cooler ❑Boc ❑ Other ❑Nd
3. Were custody scats present on coolers? QY ❑N If yes, how many and where?
If present, were custody seals intact? QY ❑N Upresent, were they signed and dated? QY ❑N
4. Is shipper's air -bill filed? []NA ❑Y ❑✓ N If not, record air bill number: 1ZX5W0980140778136
5. Temperature of cooler(s) upon receipt (°C): 0
6. If applicable, list Chain of Custody numbers:
7. Were custody papers properly filled our (ink, signed, etc.)? ❑NA QY ❑N
S. Packing material used: ❑hrserts Q&rbble fflmp ❑Bhte fce R]Wet Ice QSleeve,s ❑Other
9. Were the correct types of bottles used for the tcsts indicated? QY ❑N
Did all bottles arrive in good condition (unbroken)? Indicate in the table below. QY ❑N
Sample tD
Bottle Count
Bottle Type
Out ofTemp
Broken
initials
❑
❑
❑
❑
_
❑
❑
❑
❑
❑
❑
❑
❑
❑
10. Werc all bottle labels complete (i.e. analysis, ID, etc.)'? QY ❑N
Did all bottle labels and tags agree with custody papers? Indicate in the table below. QY ❑N
Sample ID on Bottle Sample'If) on COC . Simplc_ [D.on Bo(tle Sample ID on COC
I I. Additional notes, discrepancies, and resolutions.
21 of 26
Page Prf. Q I ❑ 2

Sample acceptance Policy
Custody Seals (desirable, mandatory if specified in SAP):
✓ On outside of cooler
✓ Seals intact, signed and dated
Chain -of -Custody documentation (mandatory):
✓ Properly filled out in ink & signed by the client
✓ Sign and date the coc for CAS/HOU upon cooler receipt
✓ Coc must list method number
✓ If no coc was submitted with the samples, complete a CAS/HOU coc for the client
Sample Integrity (mandatory):
✓ Sample containers must arrive in good condition (not broken or leaking)
✓ Sample IDs on the bottles must match the sample IDs on the coc
✓ The correct type of sample bottle must be used for the method requested
✓ The correct number of sample containers received must agree with the
documentation on the coc
✓ The correct sample matrix must appear on the coc
✓ An appropriate sample volume or weight must be received
Temperature Preservatives (varies by sample matrix):
✓ Aqueous and Non -aqueous samples must be shipped and stored cold, at 0 to 60C
✓ Tissue samples must be shipped and stored frozen, at-20 to-10°C
✓ Air samples can be shipped and stored at ambient temperature, —230C
✓ The sample temperature must be recorded on the coc
✓ Notify a Project Chemist ifany samples are outside the acceptance temperature or
have compromised sample integrity - the client must decide re: replacement sample
submittal or continue with the analysis
Cooler Receipt Form, CRF (mandatory):
✓ Cooler receipt forms must be completed for each coc & SR#
✓ Sample integrity issues must be documented on the CRF
✓ A scan of the carrier and the airbill number must be recorded in CAS LIMS
Sample Integrity Issues/Resolutions (mandatory):
✓ Sample Integrity issues are documented on the CRF and given to the Project Chemist
for resolution with the client
✓ Client resolution is documented in writing (typically email or on the CRF) and filed in
the project folder(s)
22 of 26
28

Fold" k
,)(1904340
Client Name:
Dumtar Indrulnes
Project Nam,
Slornnv;tcr TCbng
Project Number:
It cporl "ro:
Diane H;udmm
Domtat Papei Company. LLC
PAl BUx 717
Plymouth, NC: 27962
Phone Number
252-793-9611
Cell NUmbcr
Fax Number
252-793-SS71
E-mail:
dune.hordison n donuar.com
Service Reaucst Summary
Project Chemise
Durrett Bile,
Oricinminc Lab:
JAX
Logged By:
SLIGH1'SFY
Date Received:
9/ 2/09
Interval DUe Date
9/23i09
QAP:
LAB OAP
Qualifier Sec
CAS Standard
Formse[
CAS Standard
Merged?:
N
Report to MDL?:
Y
P.O" Number:
4550161974
EDD:
No BDD Speeitied
sent I
. I
I �
j_
S
,
Cas Some Nu
CUems.—P No.
Aatri<
CulleovA
I"
I�
J0904340-001
Winter Log S,.ag. -
-----WnR,
8/l1/09
11251 Ii
II1904J40-00'_
. ..
CI; II
........ _.
W:na
B13 rJ UI/0'1
O)
....I._..._
I20211It
... .. ....
)0901340-003
Q-p
Name
.. .....
8/?1fog
..- ..._... .
Ill? I1 I
0901 _ ........
ID904340_U 04
...
LR01
_.. ..
VVnI_�
..."
_8/31/09
.I ....
1025 :_IT
Test Comments:
Croup Tcsf/Mcdlad Sanrpleb Comments
Semivoa GCMS Dioxins Furors/16136
N
1-4 237S TCDD only,repoil in mgA.
s . IUUO I. ur.. n,an,: \cal d1151761'dlun I.6u,
Location: F-WICUI
NPDLS
23 of 26
Primed 9/150009 1:16:N MI ScowKe,.evt fur J0904340 Page I of I

Preparation M.Prmation 6eiielisheet
Trap Ruud: 9i259 1'. kp \\'m'kFluw: OrgF�D\q(365) Status: Prepped
Tram: Scmit'ua GCMS/.AICODUR Plop MulBod: MC010d Prep Dat Jl'imr: 9/4/09 11:01) AM
w
Lab Code
Client ID
B#
Method (Test
pH
Matrix
Amt. Ext.
Sample Description
I
C09UO715-001
A1329731
.01
1o13BIDiovinr Fumnz
S
Wmm
IIOOmL
clear cnlurlcss liquid
C0900723-UOI
67441_3
01
1613B/Diucins Fnnns
9
Wulewmcr
950mL
v 11ow liquid
3
EOVU0724-001
Cnmp U,luu OF001 Curn ,
01
1613➢1Dioxins Fnurnv
]
\Vnvmvmor
IOOOmL
dery .1 1., Ilquld
4
E090U725-D0I
L+2150
0I
16138/Dioxins Fnnns
]
Wn,,r
I005nuL
ct,., .lurlms liquid
5
C0900728-WI
RP4BOS2709
'01
1613501."1" Fnurns
]
t.",
990m1.
clan <.1arl., liquid
6
C0900729-002
RNA082909
OI
lb 138!Dia,ns Fnurns
S
Wamr
960mL
blown liquid
]
U0900739-DOI
34M17001
.UI
16 BWDloxirs Furn,
9
Dunkin, W,ecr
I000in1,
ycllow limed liquid
8
170900739-002
341506001
UI
161MDioxins Funne
S
Drinking ll'au
910m1.
ydlu.v timed liquid
9
E0900739-OU3
342615001
Ol
16131IDioxinc Fnrans
S
Drinking Water
I000mL
yellow timed liquid
IO
E0900741-00l
OW98015-1
01
16BB/Du—in,Funus
S
Winn
9'0.L
yellow l inlcd liquid
11
C0900742-001
119,81
01
I613B/Dioxin, Furnns
]
Drinkiug Water
900mL
dc:u colnrlcss liquid
12
E0900743-001
1
.01
1613B/Dioxins F'urnu,
]
Wa¢r
900nd.
yellow liquid
13
U900745-001
Chip elcach 2009-09-01_-1
.01
1613B!Dioxins Funs
3
Wau
"ad,[,
brigtu arangc ycllow liquid
14
E0900745-002
Sawdus* Bluodi 2009-09 EDK
'01
16135IDioxine Fmmu
3
Wamr
960mL
ycllmv onngc liquid
15
EQ0900362 01
MIB
16I3 B/Dioxins Fur,
Liquid
IOOOmI.
16
EQU900362-02
LCS
10 ❑51Dioxins F... u.s
Liquid
I000mL
17
EQ0900362-03
DLCS
1613B!Dioslnv Frumrs
Liquid
1000mL
I9
LQ09003ti2-04
MB
1613 B!Dioxins Fu.urs
Drinking Water
10001111.
19
EQC900362-05
LCS
1613BNiozins Furnns
Drinking Nauru
I000111,
20
EQ0900362-06
DLCS
1613B!Diaxins Furnns
Drinking Wmcr
GOOmL
21
10904340-001
Maur, Lug $tnmge
01
1613B/DiOmins Fnrans
]
Wn¢r,
WorrL
limed dlow liquid
22
J0904340-002
CIA
01
1613B/Dioxins Funus
6
Wn¢r
940mL
doudy yellow liquid
23
J0904340-003
CL-13
01
161313M.,ins Fin u,
]
Water
940nd.
Unmd liquid
24
J09043e0-004
LF-01
01
1613 B/Dioxins Furrus
]
W..,
930inL
ycllaw liquid
25
K0907366-005
Mkio, ,,
05
1613B/Dioxns Fnnns
S
tt'aar
930mL
cloudv liquid
26
F:090]e6S-005
MIMI021_21
'05
1613B/Dioxin, Fnnns
6
Wma
980mL
Purple dear liquid
W
CD
I'rinmd 9/9109 13:22
Preparuliun lnrormminn BcnchsLccl
24 0} 26
Pugc I

Preparation Information Benchsheet
P. If unr,: 95259 I'rcp Wnr'L Pluv: Orgf'clAII(365) Status Prepped
'['earn: Semivnal GCNIS/AKODUR Pi'l, Tlcth id: Mclhud 1'rcp DatJI'i nm: 9/4/09 11:00 AM
SpiLing Solution.,
Wlme: 1613B Mam< Working Standard Inventors ID 11191 Logbook Ref. D10-55-30 Expires On 07/24POI4
EQ0900161_-02
IoffmfIL r
EQ0900362.01
too thopl.
EQ0900362-03
100.00f11,
EQ0900162-06
100DUpL
Min,: 16 13 B
Labeled Work, ng
Standard
Inwmow ID 12038
Logbook Ref:
D1U-70-313 Expires On 09/02/2014
J0904340-00.-•
1000.00)IL
J0904340-M-1
Udto.00pl-
KOW7966-005
100000I11.
KO%7868-005
1,000.oi
Name: 8290/1613B Cleanup Working Standard Inventory ID 12093 Logbook Ref. D10-70-5NB Expires On. 09/OS2014
ED900713-001 100 00 11 L
E0900723-001
Ioff (in p I,
E0900724-001
100.0011L
E0900725-001
100.00pL
E0900728-0111 too oopl-
F,0900728-002
too oop1_
E090039-001 too DopL
C0900739-002
too o0pL
E0900739-00,
1uo.OopL
E0900741-001
IOo.00pL
E0900747-001 100.00)d-
E0900743-001
IoUOopl-
E0900745-001 100 Cop
E0900745402
too. UOpl-
E00900362-01
too oopL
F.Q0900362-02
IOO.00fIL
F00900362-01 I0000fth
EQO%036'_-04
100 OOfl I_
EOu900362-05 too oopf-
EQ0900362.06
too.00IlL
Jox14340-001
too 00p1.
J0904340-002
Iuu DoµL
J0904340-003 1000upL
JD904340-004
too oopl-
K0907866-005 tooDOpl-
R0907968-005
100 oopL
Nnmc: 1613B Labeled Working
Smndnrd
Inventory ID 12086
Loglamk Rel'.
DIO-70-413
[spires On: 09/042014
F000715-001 I000.00pL
E0900723-001
1,000 oopL
Fo900724-001
l00000pl_
F0900725-003
I000.ot
E0900728.001 1000 DopL
EOW0728-002
1,000.off pL
e0900739-DOI Imo .00IIL
F:0900739-0n2
10uooupL
C0900739-003
I0n0.00pL
F:0900741-001
[oho oopL
E0900742-001 1,uu000pl-
E0900743-001
1,000.00pl-
E0900745-00I 1ooD.00pL
EN00745-002
1000oopL
EQ0'40362-oI
1o00 oopL
EQ0900362.02
1000 oopL
EQ0900362-03 LOoo.00pl-
EQO`H10362-04
10oo.00pL
EO0900362-05 1000 oupL
EQ0900362-06
00000pl-
10904340-001
1off off
10904340-002
I00000 It
1'rc past inn i\Interi:ds
.Aeanne 99,5% Minimum
Cl- I6-007(71M))
Carbon, Iligh Porlp,
C2-19-005(7161)
Ethvl AeelMa 929% Ftinin,nnr
C2-23-006(9462)
EIQAe
Gloss Wool
C2-13-005 (7198)
Sulfuric Acid Reagent
Grade
C2-24-003 (946 D
IJIdJoron¢dunc (Mcthylcum
C2-25-001 (9449)
H2504
Chloride) 99.9% McCB
Sodium Chloride Reagent Grade
CI-104-2(3306)
Sodium l lydrocide Reagent
C'_-24-002(9463
Sodium SulG¢Anhyd,00a
C-19-0O6(7201)
NaCl
Grade Nn011
Reagent Grade MOSO4
Tlideeanc (o-I idecnne)
C2-24-001 (9460)
13wmle (u-Plexnne) 98.5".o
C2-25-004 (9441)
Nonanc (mNonmc) 99%
C2-21-004 (9457)
Minimum
pB Paper 0-14
(1008)
Silica Get Rcogcnl Grad.
C2-27-007 (9456)
T9lucne 9%9%Min .... i
C2-25-OU3 (9446)
T reparation Steps
Step: Fanmdoo
Sl"
Acid Cleve
Step:
Siliea Gel
Clean
Sl" Final Volume
Smncd'. 9N/0911:00
Ssraod:
9/8/090900
Staned:
91810913.00
Si ncd: 9/9/0907,00
`�iniand 9/4/09 17 30
Finished'.
918/090900
Finished'.
9W0917.30
Finished: n9/D913'Do
By: NBRORN
By:
NBROWN
Br:
NBROWN
Br. NBROWN
25 of 26
Plumed 9/9109 13:11 Preparmion Inlbrmmion B-Iuif ea P„ge 2

Prcpl4inN: 951_59
l'cmn: semrvau GCNIS/AKODI/R
Commcros:
R—iewcd By: Nicole Brown
Preparation Information Benchsheet
Prcp \Vorlc FI on: OrgF:a Aq(36+)
Prcp ale mod: Method
°^'" 09/09/09
ain .1 cn:mdy
RdinynisLcJ By: _ _— _ Ovtt:
(�nvms Exn ned
Received By. Dv¢'. Yvs m Nu
slain.,: Prepped
Pre{i Uvic/Pienrt 9/4/09 11.00 AM
Primed 9l9109 13: P_ Prcpnrmion Inlbnnmion Benehshcet Pvge 3

4%-®lumbia
r
Af1aijRICBis@YO/IGE'S" s,nt�ecn ,vi.szxsa 1 xuniwas>v � s04.7.19w+I.i
December 08, 2009
Diane Hardison
Domtar Paper Company, LLC
P.O. Box 747
Plymouth, NC 27962
Laboratory Results for: Plymouth Stornmater Testing
Dear Diane:
Service Request No: J0905693
Enclosed are the results of the sample(s) submitted to our laboratory on November 17, 2009. For
your reference, these analyses have been assigned our service request number.10905693.
All analyses were performed according to our laboratory's quality assurance program. The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc.
(CAS) is not responsible for use of less than the complete report. Results apply only to the items
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report.
Please contact me if you have any questions. My extension is 4408. You may also contact me
via email at'[Xissinger cr caslab.com.
Respectfully submitted,
Columbia Analytical Services, Inc.
"torn Kissinger (�J
Project N anaoer
Page I of 3�
CGIS.Jocksmwille is NELfIC-accredited by the State o%Florida, #E82502. Other slate accreditalions
inclwk. Georgia, 058; Kentucky, 403, Loui.siona. #02086: North CcuMlina, 11527; South Carolina,
#96021001: Tcsas, 1fT104704197-09-TY

lient: Domtar Paocr Conmanv- LLC
IL I
rojeci: Plymouth Stonnwater Testing
Set -vice Request: J0905693
SAMPLE CROSS-REITRENCE
SAMPLE #
CLIENT SAMPLE ID
DATE
TIME
J0905693-001
RYOI - Norfolk Southern
11/11/09
13:49
J0905693-002
OBA - Old Borrow Area
1 t/t 1/09
1454
J0905693-003
Cl. 14 West Con Laydown
11/11/09
14:37
J0905693-004
LP-04
11/12/09
09115
J0905693-005
NBA
11/12/09
09:32
J0905693-000
LP02
11/)2/09
09:46
J0905693-007
Woodyard
11/12/09
1026
d 12I8/09 11:55 Sample Sunm1a6' — Pag, I of I

Columbia Amth, icatl Services, Inc.
Cooler Receipt and Preservation form
Service Request
pro cct
� ` i
Cooley received on �� '' lJ 1 and opel"I>`t2'oil \ \• �
COUR117,R. CAS PS PEDEX DHL CLIENT Tracking rl" � \V �� Plly L"n �� 1
1 Were custody seals on outside of cooler? Yes C�i N/A
2 Were seals intact, signed and dated? Yes No N/A y
Were custody papers properly filled out? es No N/A
4 Temperature of cooler(s) upon receipt (Snood be a+i- 2 degrees C)
Con'ect Temperature? es No NrA
6 `Were ice or Ice Packs present es No nvA
7 Did all bottles arrive in ,00d condition (e.ubioken, etc ...)'? cs l Nc A/A
vk ere all bottle labels complete (sample ID, presciv,,tion, etc....)' es No NGt
J Did all bottle labels and trigs agree with caslody papers? cs No N A
10 Vdere the correct bottles used for the tests inr.icatcil, 1 No NIA
I I lVcre all of the preserved bonles received with the aptnopriale n1ese1Vit11Ve7 Yes \o l:
HNO3 pH<:2 H2SO4 ptl<2 %nAc2/NaOH pH%9 NaOH pli%12 !-! i pl{Q
Rcservnuve addoons "Ou"! bdaw
12 SVere all samples received within analysis holding times?
13 Were VOA vials checked Ibr absance of air bubbles? Hprnsum, note below
14 Where did the bottles originate'1
Manuf. Lot n or CAS
ID Reahent Chem ID rill added
Additional comments and/or explanation of all discrepancics noted above:
Yes iJo �Ni;'s••�
Cliem
inititutls
nt approval to ran samples if discrepancies noted: Date:

.ta
SRI: JOc'1O56'3
l�1 UG1
0,1, Inal nH is cnecMeA nnn meek Ine fetJuvetl pll cnleuOn Irslec m fna rcJ:nun nedtllnG unleu Unermist nolaf on cpnlcr receipt loan.
6oWe Code
1 nr.11
1
30nL
(
2
101nL
G
3
40 l
G
4
40int,
G
5
125m1125mt
P
6
P
]
125mL
Pr
B
1 5 1
5
150mL
11
lu
250 L
1
I II
?50p,0
I' -�
1 12
2 L
1 13
250m
I
1 1.
h2 L2
C—
IS
0 L
1 1
00 L
P
17
500nL
1 16
SOOnL
P
191
1
P
20
1L
P
121
IL
G
22
IL
G
23
11
C
24
20
G
25
ao]
G
26
:3
C
tn
uo
C
6
..
LNO
2
100 L
P
If
M
1 re.
IICI
H2SO4c:
IICI
M25Or
H JOJ
:
IL Oi
HNGJ1
lIuU11
Y OH
�
HNO3
'
HISJ
HNO3'
HNO
IICI
H $0
l.-
L'/A?
NIA`
ina 1
TN�INt-li
2
'MN/AR
c2
mWA
:2
Nf
2
PH
J/A'
Nlr"
%9
12
.MIA.
Q
Nln.'
'2
NI?
c2
NIA
PIA
NIA
UA
17
Jf
JlIe
mJ
or.:
oos
_
--
I
--
--
--�—_--I-
I--_
3
—
.n 10
—"
141,—_r_
-
-
-
-014
.el..—
.016
021
022
I _
----
..
,127
on
_

olumbia
Analytical
Se.rviGQS°`
aL A�o
q-.nAlly Vr k—UJ1vvY / L.AIJ"KA1' '.Y AlNALYJI.N REQUEJ1 bVKINI
CAS Conmet l
9143 Philips Iughway, Suite 200 Jacksonvl lie FlorSdn 3225(111)hone(904)739-2277JS0(1-695.7222/Fax [phone] PaI�c I Of I
Pl,jeei Naole
Project Nmnhcr
ANALYSIS
REQUESTED
(Include
Mallod
Number
an
Plmouth Swonwaser Tessin,
Preser.al
we
p
Report I.
Report CC
Dinnc Ilardison
Alin Barnes
m
Z
1. n
2. I [NO,
Cnnlpany/Address
Q
DOnnlalPaper Company )any
Z
00
x
3. H2SO4
4.M,011
P.O. Rox 747
0
Plvmouth, NC 27962
0
5, 7.o. Aurle
6. McOPI
Phalle II
FAX C
252-793-S611
252-793-8871
;D
7. NAISO4
$smplc/r'S Signatur//e++
Sampler's Printed Name
REMARKS
SAMPLING
CLIENT SAMPLE ID
LAB ID
DATE TIME
di+irk
RYOI - Norfolk Southern
Dioxin
11/11/09
1:49 PM
Water
2
X
OBA - Old Borrow Area
Dioxin
11/11/09
2:54 PM
Watcr
2
X
CL-14 - West Cron. Lnvdown
Dioxin
11/11/09
2:37 PM
Water
2
X
LR04
Dioxin
1 I/12/09
9:15 AM
Prater
2
X
N13A
Dioxin
11/12/09
9:32 AM
Water
2
X
LP02
Dioxin
11/12/09
9:46AM
Water
2
X
Woodvard
Dioxin
1IM/09
R199171 1;
Water
2
X
Woodyard- 10:26 AM
$Im'IOwnfcr svmPlCS(ac dia'in Iftllg
1'IIRFAROnFn REQIIrREMEN7S
REPORT RFQ111RF,ptFh7S
INVOICE. r.VM02\1A1IVL'
R10sn ('0Rc11A0..ES APPI \ I
I. RCSnLs On1Y
II. K-111I QC Sumnurin
rr�
P.O. x d�DY.it w G`PO-
S SI1\NIlA0.p
lI C'S aIID,.VtiAtSU:rs rryuirtJl
X nl.P.exum.
Bill,.:
RBnuLTCa rnx M.F.
Iv. neu \'�liaaiun e;ryn viin R,e nzu
RFQutireo RrPORr MI'E
FAata Ycs No
Rel inqu,,hed By
Itcccrvcd Hy
Itclin wished Nr
ycd`f
Relingnished By
Received By
Si�lm�
y �
Silnamre
Slcmnure
Sign;ure
Signawrc
sigrut,
Printed Miele �
�
Printed Name
^
n G
!'ri t Nal e-�
Pr- t vdAd a
PrinleJ Name
Primed Nano
r °
rr
FGn V
�
Firm
Finn _
f
J
D.,tefFlme _
Dalolilmc
Datu Ime �-'
BaalF r _1 —�
Daze/Time
Dalefilm,

Services -
Appendix A
Columbia Analytical Services
9143 Philips Highway, Suite 200
Jacksonville, FL 32256
Tel [phone]
Fax [phone]
Subcontracted Analytical Results

ASColumbia
Analytical Services -
December 3, 2009
Tom Kissinger
Columbia Analytical Services
9143 Philips Hwy, Suite 200
Jacksonville, FL 32256
19,108 Park Rev.-, Suite 320, Houston, TX. 770a1 I 713.266.1599 , vnv%.v.caslab.com
Laboratory Results for: Plymouth Stornnvater Testing
Dear Tom:
Service Request No: J0905693
Enclosed are the results of the samplc(s) submitted to our laboratory on November 13, 2009. For
your reference, these analyses have been assigned our service request number J0905693.
Analyses were performed according to our laboratory's NELAP-approved quality assurance
program. The test results meet requirements of the current NELA P standards, where applicable,
and except as noted in the laboratory case narrative provided. All results are intended to be
considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for
use of Ics6 than the complete report. Results apply only to the items submitted to the laboratory
for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the
NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any
quantitative analysis will be supplied upon request.
Please contact me if you have any questions. 1NIy direct line is 28 1-994-2954. You may also
contact me via email at [e-mail].
Respectfully submitted,
Columbia Analytical Se'rvNiiices,, Inc.
Darren 13iles
Project Nlanager
For a specific list ofNELRP-occi edited analvtes, refer to the certifications section at
IVWW.ca.slcab. com.
v,c LnWmee O:,rk;•^ Compar; NELA- hrsredltee AGIL SeA of &cclle•nen iv au: . Please consider Ore environment beore printing �-
1 of 29
7

Columbia
Analytical Services -
Certificate of Analysis
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.caslab.com
An Employee Owned Company
2 of 29

COLUMBIA ANALYTICAL SERVICES, INC
Client: Domlar Industries Service Request No.:
I'roject: Plymouth Stonnwater Testing Date Received:
Sample Matrix: Water
CASE NARRATIVE
J0905693
1 1 / 13/09
All analyses were performed in adherence to the quality assurance program of Columbia Analytical Services, Inc.
(CAS). This report contains analytical results for samples designated for Tier H. When appropriate to the method,
method blank results have been reported with cach analytical test.
Sample Receint
Seven water samples were received for analysis at Columbia Analytical Services on 11/18/09.
The following discrepancies were noted upon initial sample inspection: no custody seals on cooler(s). The
exceptions are also noted on the cooler receipt and prescivation form included in this data package.
The samples were received at 0°C in good condition and are consistent with the accompanying chain of custody
form. The samplcs were stored in a refrigerator at 4'C upon receipt at the laboratory.
I'Icis e note the reporting forms arc Current Iy referencing the date CAS- Jac lcsonvi l le received the samples (I 1/17/09)
and not the date CAS-HOUston received the samp lcs (1 1/18/09.)
Data Validation Notes and Discussion
D1S/UtAIS
EQ0900491: Laboratory Control Spike/Duplicate Laboratory Control Spike (I,CSiDLCS) samples were analyzed
and reponcd in her of an MS/DtNIS for this extraction batch. The batch quality control criteria were met.
Deteclion Limits
Detection limits arc calculated for each congener in each sample 6y measuring the height of the noise level for each
quantitation ion for the associated labeled standard. The concentration equivalent to 2.5 times the height of the
noise is then ca Iculated using the appropriate response factor and the weight of sample. The calculated
concentration equals the detection limit.
:approved by:
Ni:mggill Liam Laboratory Director
3 0l 29
Date: 12 / 07 / 0 9

4
Clicnl:, Domlar PaDei Compatrv. LLC Service Requot: J0905693
1'."jcU: Plymouth Slornnvater Testing
SAlNIPLF CROSS-REITI21:NCE
SAMPLE 9
CLIENT SAMPLE ID
DATE
"TfMG
J0905693-001
RY01-Norfolk Southcm
11/11/09
13:49
J0905693-002
013A- Old Borrow Arco
11/11/09
14:54
J0905693-003
CL-14 West Con Laydown
11/11/09
14:37
10905693-004
LF-04
11/12/09
09:15
10905693-005
NBA
11/12/09
09:32
.10905693-006
1102
11/12/09
09:46
J0905693-007
Woodyard
11/12/09
10:26
4 of 29
Ili 11k i IL3f0) 113z Suniylc Sunnnnry :l,' Pug<l oft

Laboratory Certifications
2009-2010
STATE/PROGRAIM
AG NCY
CERTIFICATION 11)
EXP DAT
,ViIzoNA
AZ-DI{S
AZ0725
05/26/10
MtKANSAS
ADEQ
09-048-0
06/16/10
CALIFORNIA
CA -FLAP
2452
02/28/11
Ft.oaiuA/NELAI'
FL -DOHS
P87611
06/30/10
1-1AWAII
HI -DOH
N/A
06/30/10
lu.wois/ NELAI'
Ili EPA
002380
10/06/10
1.ouisiANA/NE1,AI'
LELAP
03048
06/30/10
MAINS
NIE-DOHS
200SO31
06/05/10
AIICmC,iN
MIDEQ
9971
06/30/10
MINNESOTA
MDII
048-999-427
03/25/10
NI?vAHA
NDEP
TX014112009A
07/31/)0
NP:w Jliltsliy
NJDEI'
TX008
06/30/10
No-:wD7EXico
LAMED-DWB
N/A
06/30/10
NEwYowI/NELAP
NY -DOH
11707
03/31/10
NFESC/N:wv
NFESC
N/A
01/09/10
OKLAHOMA
OKDEQ
2009-25
OS/31/10
OREGON/N'ELAP
ORELAP
TX200002-006
03/24/10
'I'ENNESSEE
TNDEC
04016
06/30/10
TExAS/NELAI'
TCEQ
T104704216-09-TX
06/30/10
U'I'AII/NI?LAV'
UTELCP
COLU2
06/30/10
Soil. hwoln I't?uaH'r
USDA
P330-09-00067
03/27/12
N':�SHING'roN'/NFLAP
WA -Ecology
C1855
11/14/09
NVSTVIRCINI:v
I WVDEP
347
06/30/10
5 of 29

6
Abbreviations, Acronyms & Definitions
Cal
Calibration
Conc
CONCentration
Dioxin(s)
Polychlorinated dibenzo-p-dioxin(s)
EDL
Estimated Detection Limit
EMPC
Estimated Maximum Possible Concentration
Flags
Data qualifiers
Furan(s)
Polychlorinated dibenzofuran(s)
g
Grams
ICAL
Initial CALibration
ID
IDentifier
Ions
Masses monitored for the analyte during data acquisition
L
Liter (s)
LCS
Laboratory Control Sample
DLCS
Duplicate Laboratory Control Sample
MB
Method Blank
MCL
Method Calibration Limit
MDL
Method Detection Limit
MRL
Method Reporting Limit
mL
Milliliters
MS
Matrix Spiked sample
DMS
Duplicate Matrix Spiked sample
NO
Number of peaks meeting all identification criteria
PCDD(s)
Polychlorinated dibenzo-p-dioxin(s)
PCDF(s)
Polychlorinated dibenzofuran(s)
ppb
Parts per billion
ppm
Parts per million
ppq
Parts per quadrillion
ppt
Parts per trillion
QA
Quality Assurance
QC
Quality Control
Ratio
Ratio of areas from monitored ions for an analyze
% Rec.
Percent Recovery
RPD
Relative Percent Difference
RRF
Relative Response Factor
RT
Retention Time
RRT
Relative Retention Time
SDG
Sample Delivery Group
S/N
Signal -to -Noise ratio
TEE
Toxicity Equivalence Factor
TEQ
Toxicity Equivalence Quotient
6 of zs
1�

7
Data Qualifier Flags — Dioxin/Furans
o B Indicates the associated analyte is found in the method blank, as well as in the sample.
o C Confirmation of the TCDF compound: When 2378-TCDF is detected on the DB-5 column,
confirmation analyses are performed on a second column (DB-225). The results from both the
DB-5 column and the DB-225 column are included in this data package. The results from the
DB-225 analyses should be used to evaluate the 2378-TCDF in the samples. The confirmed
result should be used in determining the TEQ value for TCDF.
o E Indicates an estimated value -used when the analyte concentration exceeds the upper end of
the linear calibration range.
o J Indicates an estimated value - used when the analyte concentration is below the method
reporting limit (MRL) and above the estimated detection limit (EDL).
o K EMPC - When the ion abundance ratios associated with a particular compound are outside the
QC limits, samples are flagged with a W flag. A W flag indicates an estimated maximum
possible concentration for the associated compound.
o U Indicates the compound was analyzed and not detected.
o Y Samples that had recoveries of labeled standards outside the acceptance limits are flagged
with'Y'. In all cases, the signal-to-noise ratios are greater than 10:1, making these data
acceptable.
o ND Indicates concentration is reported as 'Not Detected.'
o 5 Peak is saturated; data not reportable.
o P Indicates chlorodiphenyl ether interference present at the retention time of the target
compound.
o Q Lock -mass interference by chlorodiphenyl ether compounds.
7 of 2s
i�

8
CA H 0' - Forni Pioduc[iori, P.-ci- 1, en;;cR, 1- e t Rew-
SO= Unique D1
lim
I JI�
Dd�t (2-
Cate
Mm
Gate
Daie
j �
Date 12/07/09
Persond
Person 2
Primary Daia Reviewer
econda7/ Data Re /revee:
Reviewer
—

9
Columbia
Analytical Services~
Analytical Results
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone]S99 Fax[phone]
www.caslab.com
An Employee Owned Company
9 of 29
1�

COLUMBIA ANALYTICAL SFRVICES, INC.
AnalytiLIP Report
Client
Donttar Industries
Service Retlucs :
109D5693
1'rojccL
Plymouth Stornnanter'I-csting
Date Collected:
11/111091349
Sample Mall ix:
enter
Date Received:
11/17/09
Sample Name:
RYOI - Norfolk Southern
Units:
pg/L
Lab Code:
J0905693-001
Basis:
NA
Polychlorinated DIbCTUOIliONius and Polychlorinaled Dibenrolm ans by IIRGClli RNIS
Analytical Method:
I6136
Date Analyzed:
11/23/092244
Prep Mcd od:
Method
Date Extracted:
11/19/09
Sample Amount:
990mL.
Instrnment,Name:
13-HRMS-04
GC Column:
1)13-5
Data File !Name:
1`205095
Blank File Name:
P205051
H, U, Date:
08/20/08
Cal Vc.. File Name.
P205079
lou Dilution
Aoalylc N':onc
Result Q EDI. MRI. Ratio RICl, Factor
2,3,7,8-7CDO
Labeled Cnmpuu ol,
13C-2,3,7,s-PCDD
37CI 2.},7,8=fCDD
ND U 0.0705 10.1
Spike Conc.
Cone.(pg) Found (pg) '%Rcc Q
Cnnt rnl Inn
Limits Ratio RR'L
2000
1IS6.717
59
25-164
0,79
1008
S00
534.670
67
35-197
NA
1.009
P,,1,0 125I09 11 3a Fonn IA
tlfnlLm3l9.ulinalLinnRcryb�mlmiaaBaryn:pl 10 of 29 Slipvrsel Relbencc O'I.UDU01 ffi]nl mo W

COLUNunA ANALV I'ICAL SEAMCFS, INC.
AnalytiJall Report
Client:
Donvar Industries
- Service Request:
J0905693
PTojecb
Plymouth Stonnwaler l'esting
Date Collected:
11/11/09 1454
Sample Mall it
Water
Date Received:
11/17/09
Sample Name:
O13A - Old Borrow Alea
units:
Pg/L
Lab Cade
J0905693-002
Basis:
NA
hoINcblorinaled DlbCrl%IIdiOXIns and PoINchlorinated DIbenzo1n1'n n, II)' IIRGC./IIRBIS
An: l)'tic:d Method:
161313
Date Analyzed:
11/23/09 2331
Veep :Method:
AMethod
Dale l'xo acted.
11/19/09
sample Aalalllll:
975mL
Instrument iName:
G-FIRMS-04
GC Column:
DBS
Data file Name:
P205086
Blank File Name:
P205091
ICAL Dale:
08/20/08
Cal Vet. file Name
P205079
Inn Dilution
An:dvle A'ume
Result Q ML MR1, Ratio RRT Factor
2.3.7.8-TCDD ND U 0.232 10.3 1
Spike CGmc. Conval Ion
Labrlyj L"nm pnu ads Cune.(pg) Found (pg) We Q Limits Rath) RRT
13C ?,3,7,S-TCDD 2000 1039.043 52 25-164 0.79 1.009
37CI .,3,7,3-TCDD 800 465,367 58 35-197 NA I DW
Con,..,,.....:
1'nineJ 129N91164 Toni IA
v�ao,.ns�.,d�nsu.nn,s.n:nna�pro�x.pnu,pi 11 of 29 son«se�ic�rcmna on-wroearoi .woo
l

COLUIMBI A ANAINTICAL SERVICE'S. INC.
Analyti �:� Repon
Client
Dollar Industries
Service Request:
J0905693
I'rujcct
Plymouth Stonnwatcr Testing
Date Collected:
11/11/091437
Sample'Nhtrix:
Water
Date Received:
11/17/09
Sample Name:
CL-14 West Con I,aydossat
Units:
pg/L
Loh Colic:
J0905693-003
Basis:
NA
Polychlorinated Dihcnzodiu>fnn and Polychlorinated Dibenzofur:us by [IRCCAIRMS
Ao:dytical \lethud:
1613B
Date Analyzed:
11/241090019
I'sep Alethud:
Method
Dade Extracted:
11/19/09
Sample Amomv:
950ml-
Instrument Name:
E-HRaNIS-04
CC Column:
DB-5
Data Filc Name:
P205087
Blank File Name:
P205081
ICAL Dale:
Os/20/08
Cal Vet. File Name:
1'205079
No Dilution
Aoalyle Name
Result Q EDL NIR1- Ratio RRT Factor
2— 7.8-1 C'DD ND U 0-197 105
Spike Cone Control lon
Lahrled Cornpou" ik Conc(pg) Fo wul (pg) '7 Rn: Q Limits Ratio RIO,
13C-2,3.7,8-TCDD 2000 1216.257 61 25-164 0.77 1.009
370-2,3,7,8-1 CDD 800 546.674 68 35-197 NA 1,009
(b nunemr:
. dnmd C17:119111-1 Form L\
12of29 Sorcrsu Ratan.,... m.,mansnfi—W
18

COLUMRIA A NAINI'ICALSFUVICES, INC.
AnalyliL9 Report
CIicn1:
Donuar, h-irlusirics
Service Request:
J0905693
I'rnject:
Plymouth Sturmwaler Testing
Date Collected:
11/12/09 09 15
Ssmplc Malri,v:
wa cr
Date Received:
I1/17/09
Sample Name:
LP-04
Units:
pg/L
Lab Cock:
J0905093-004
Ila,i,s:
NA
Polyc h I"I inaIcd Dibcuzod ioxi ns and PoIycItIm inatcd Di benzo(urans by II RG(Al10IS
Annlpticul Jiclhod:
1613B
Dale Anal}'zed:
11/24/09 0107
Prep Method:
Method
Dale Extracted:
11/19/09
Sample Awounl:
950mL
Instillment Nunle:
E-FIRMS-04
CC Colonuu
1)R-5
Data file Name:
P20gS8
Blank Pile Name:
P205081
ICAL Dale:
08/20/08
Cal Ver. Rile Name:
P205079
Inn Dilution
Analvie Name
Resull Q Ill DL NIRI Ratio RR'P Factor
2,7,7,Y 'fCDD ND If 0.106 10.5
Spike
Cone
Control
Inn
I.nbnlcd Cnmpanaols
Cnuc.(pg)
Round (pg) ''/fRlc Q
Li,nicr
Ratio MCI
13C-2,3,7, 8 J C DD
2000
1167.670 58
25-164
0.78 L009
370-2,3,7,E-l*CDD
Soo
521.018 65
35-197
NA 1,009
Cronin en ln:
Pdmad 12G09 I I:7J Form IA
'alnnm.nsindin�su.insncPs,�m�y data°Pon 9„ 13ot29 SnPcsc: acr,��c�: ov-0000r_svm «,.N
i J

COLUNIBIA ANALYTICAL SFRVICFS, INC.
Analyliiat Rcpnn
Clieni:
Dolotar l ndusli ies
Service Bequest:
J0905603
Project:
Plymoudt Slonmvater Testing
Date Collected:
I1/]2/090932
Sample Mati i>:
Water
Date Received:
11/17/09
S:Imple :Name:
NBA
Units:
pg/L.
I-vh C,ofc:
J0905693-005
Basis:
NA
Polychlorinated Dibenzodlaxins and Polychlorinated DibenzoCurans by II RCC/III2BIS
Aoal}'tinvl Mciltntl:
16138
Date Anah'zed:
11/24/090ln
Prep Nlethod:
Method
Date ISxtracled:
11/19/09
Samplc;Alnu n t:
940ml-
Instrument Name
L-HRMS-04
CC Column:
DB-3
Dala File N:mrc:
P205089
131:mk Pile :Name:
P2050I
ICAI, Dore:
O8/20/08
Cal Ver. Rile Name.
1'205079
Ion Dilution
A n:dyte lNamc
Resuit 0 171)], AIRL Ratio RRT Factor
2,3,7,8=fCDD
ND tl
0.209
10.6 -- 1
Spike
Colic.
Control lon
Labeled Compounds
Conc(pg)
Fount) (pg)
% Rcc Q Limit" Ratio WIT
13C-2,3,7_S=rmi) 2000 1242 M2 62 2i-164 0.80 1.009
37C1-2,3,7,8-1 CDD S00 585.202 73 35-197 NA 1.009
Cnnunnns.
nfinmd I�r9/09 IIaJ Form IA
.:Lulu�._'Sndi�nPL�msRans\\mlp nlliapon. qn ,,S,l Rd,r.e: O9-
14 of 29 5 lip 0000leMl ,ruo
20

COLU.\I Ii L\AN A LVI ICA LSERVI CES. INC.
Analyticla� Rgort
Client:
Donitar Industries
Service Request:
J0905693
Project
PIyn10u111 Slomnvuler'I esline
-
Date Collected:
11/12/090946
Sample N aoi\:
wait.
Dale Received:
I I/17/09
Sample Namc:
LP02
I»ts:
pg/L
Lah Code:
J0905693-006
Basis:
NA
Polychlorinuled Dibenzodi'mos and Pnl3chloria0ted Dibenzofm'ans by IIIZCC/HRNIS
Analytical Method:
161313
Date Analyzed:
I1/24/090242
Prep :Method:
Method
Date Extracted:
11/19/09
Sample A1lnlalll:
940m1,
Instrument Name:
E-11RMS-04
CC Colonel:
D13-5
Data Pile Na"":
11205090
Blank File Name:
P205081
ICAL Date.
08/20/08
Cal Vey. File Name:
P205079
Inn Dilution
Anulyte N:uuc
Result Q EDl- TNIRL 101ie 12RT Fachn'
2,3,7,8- PCDD
I :Ibelyd CouqunnuH
ND U 0.232 10.6
Spike Couc.
Cone.Qy) Found (Pg) °hRee 1)
Control Inn
limits Ratio RR"P
I3C=2,3,7.5-TCDD 2000 1119.426 56 25-164 0.77 1.009
37CI-2.3,7,E-TCDD 800 517,661 65 35-197 NA 1.009
Coinn,rna:
Pi inlcd 1?13/09 1 1:71 rn,ni L\
Plnllo.c^..Sculims'LinnRgrs4,n.Jyuc;dP.rym. ryi 150129 SupaS"Rc&rcnce: 09.wau 118711¢c00
l

'
COLUINII31A ANALVI'lCM, SERVICES, INC.
.
An:dytil:0 Report
Clime
Domlar Industries
Service Request:
J0905693
Project:
Plymouth Storm�valci 1'eslino
Date Collected:
11/12/09 1026
Sample Mattis:
Water
Dale Received:
11/17/09
sample Name:
Woodyard
knits:
pg/L
Lab Cudc:
J090i693-007
Basis:
NA
Polychlorinated Dibenzudiucins and Pnlycbinrivated Dihenzolurans by F112CGIIRMS
Analytical Method:
161313
Date Analyzed:
11/24/09 0330
Prep McOlod:
Method
Date Extracted:
I1/19!09
Sample Amount:
960ml-
Instrument Namc:
F-FIRMS-04
CC Column:
DB-5
Data Fllc Name.
1`205091
Blank File Name:
P205081
ICA1, Date:
08/20/08
Cal Ver. File Name:
P205079
Ion
Diluting
Al,ah'le N:uue
Result Q
hDl. NIRL
Ratio
11 RT Facto'
2.1 7,8= PCDD
ND U
0,169 10.4
1
Spike
Cunc
Control
Ion
Lnbcted Con poaOu'
Cmle.(pg)
Found (Pg) '% lire 0
Limits
Ratio MIT
13C-2,3.7,S-TCDD
2000
1241.959 62
25-164
0.76 1.003
7C1?,3,7,8-TCDD
800
630694 79
35-197
NA 1.009
0
Prlumd 1213100 I1:31 Form IA
:tm,1.-, L rsRons•..1mlydnlNgw,vpi 16 of 29 SuperSet ReCereace, W 0000129701 ¢.00
77

•
COI, U.NI BIA ANAL1`fI CA I, SKItVICES, INC.
An:dyeC,71 Report
Chem:
Dorntar Industries
Sen'ice Bequest:
J0905693
Project
Plymouth Stormvater Testing
Date Collected:
NA
Sample IAiatri>:
Water
Date Received:
NA
sample Name:
Method Blank
Units:
pg/L
Lab Code:
EQ0900491-01
Basis:
NA
Polychlorinated Dibenzodiosins and Pnlychlolinacd Dil enzofmans by IMCC/lIRMS
An:dylical d'Icthod:
1613B
Date Analyzed:
11/23/09 1933
Prep Mrthud:
Method
Date F\oacted:
11/19/09
S:uup lc Amount
100011L
Instrmnent Name:
E-I1RMS-04
CC O lmno:
D13S
Data File Name:
P205091
Blank Pile Name:
P2030E1
ICU,. Date:
08/20/0S
Cal Vet. Rile Name
P205079
Inn
Dilution
Analyte Name
It"I]It Q
I:UL A-Ilil,
12olio
I212'I' Far tnr
2,3,7,E=PCUD
ND U
0.23) 10.0
1
Spike
Conc.
Control
ton
Labeled Cem puua'Is
Conc.(pg)
Round (pg) /'Rec Q
Limits
12atio RRT
13C-2,3,7.8-"lCUD
2000
1242.100 62
25-164
0.78 1.009
370-2.3,7,8-FCDD
S00
492. 198 62
35-197
NA 1.009
(:nI N II en I,:
Pnleul 12/310911:34 Fnan IA
',1 lnllmo]6b111 -el ..... slAnn ylic:aReponlVl 17 of 29 Supers. Reference 09-0 00128701 rev 00

In
S Columbia
u� Analytical Services-
Accuracy and Precision
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.casiab.com
An Employee Omwd Company
18 of 20
iG

Client
Project
Sample Matrix:
Analytical Method:
Prep Method:
COLDNIRI.\: NAINTICAL SERVICES, INC.
19
QA/QC Repon
Domtai Industries Senice Request: J0905693
Plymouth Storinmoter 1'esting Date Analyzed: 11/24/09
Water
Lab Control Sample Sunimaty
Volychlm'inated Dibenzodioxins and Polychlorinated Dibenz0(m'an,s by IMCC/lIRNIS
1613E Units: pg/L
Method Basis: NA
Lab Cnntrnl Sample
EQ0900491-02
Anake iN'amc 12csidl 17,pccicd °' Re
2.3.7 3-TCDD 219 200 109
C..... mews
Exuaction Lot: 101047
Duplicate Lab Control Sample
EQ0900491-03 n/ Rec MID
Rcvdt I>xlmdal A Rec Limits RI'D Lin.it
209 200 104 67 - 159 5 50
rrunen LO/09II:34 Lab Coalrol Smnplc Snnnvnnv
'�Imlo�a\Surlina'.Lin�ckep, LobCnnvol$anplcrpl 19 of 29 Supu$e�Nelerenee'. 09.W001i$]01...00
'1

COLUMBIA ANALV HCAL SERVICES, INC.
AnalytiKq Report
Client
Domlar Industries
Project:
PlyntOulh Stormneater Testing
Sample Matric:
0,'ster
Sample N:uue:
Lab Control Sample
Lab Code
F.00900491-02
Service Request:
J0905693
Date Collected:
NA
Date Received:
NA
Units:
pg/l,
Basis:
NA
I'ulpehloriuuted Dibenzodio.<ins and PolTchlnrinated Dibcmtu(ura ns by 1i 12C: C/H12V'IS
AnAvImil ,Method:
1613B
Date Analyzed:
11/24/09 0418
1'. ep Method;
Method
Date Fxtracted:
11/19/09
3aluple Amount:
100011IL
Instrument Name:
E-FIRMS-04
CC Column:
DIM
Duto File Namc:
P2O5092
Blank Rile Nanle:
P205081
WC 1. Date
08/20/08
Cal Vei. File Namc
P205079
Ion Dilution
Annh'te lN:uuc
Result Q RDL MR], Ratio RIO Factor
2,3,7,5-TCDD 219 2176 10.0 0.77 1.001 1
Spike
Colic.
Cnlnl'ol
Iml
Labeled Conpnnlall°
Conc(pg)
Found (pg) 'Zdle, Q
Linuta
Ratio RR'l
IR-2,3,7.S=TCDD
2000
1572.725 79
25-164
0.75 1,009
37C1-2,3,7,S-TCDD
SOO
619.830 77
3 1-19 1
NA 1,009
r.�,ulalCa6:
111ia¢d 1`if09I I'}I farm IA
'dlnllaw•,Simlm;:Lim;Repal:AnohunilRep.m TI 20 of 29 s",'sn Ro..... N 0000I2970I rev 00
2 6

COLU:MBI.A ANALVTICAL SERVICES, INC.
AnalytZ) Report
Client:
Dointar Industries -
Sereice Request:
J0905693
Project:
Plynnnnh Sim m,liter Testing
Date Collected:
NA
Sample \7at rix:
Water
Date Received:
NA
Sample Name:
Lab Control Sample Dup
Units:
pg/L
Lab Code:
1-Q0900491-03
BusiS:
NA
Polychlorinated DiI)euaodioxins and Polychlorinated Dibcnzofur:ns by II12CC/111211S
:Anaklical Method:
161313
Date Analyzed:
11/24/09 0505
Prep Method:
Method
Date Esh'ncled:
11/19/09
$:unplc Anunum
10001111,
Instillment Name:
E-FIRMS-04
CC Column:
DB-5
Data File N:une:
P205093
Blank (tile Name:
P205081
ICAI.Date:
08/20108
Cal Vei. bile Name:
P205079
loll Dilution
An:dvie Name
Resell Q FD1, NIRI, Ratio RIZT Factor
23,7,8=17CDD 209 0.0930 10.0 0.75 1.001
Spike
Cane
Canovl
Ion
Labeled Compound,
Cntc.(pg)
Fotuul (pg) '% Itec Q
Limits
Ratio RIIP
13C',3,7,8-TCDD
2000
153 1.5 11 77
25-104
0,79 1.009
37CI-2,3,7,8=1-CDD
800
555.658 69
31-191
NA 1.009
I'rinmd 12Oi0911.3d Porm IA
o.I�a�,e£:Sndlnsti �,.,a=rot-t . i.,I.nikeran mi 21 of 29 su,'se acremn«: on_000mexvol m. eo
,7

. r i
i
19408 Park Row, Suite 320, Houston, TX 77084
Phone(7'13)266-1599 Fax[phone]
www.casiab.com
Employee Owned Gomp,
22 of 29
28

1'ruject Nanm: Pl ynr9 uth Stamtwa ter I sting
Pr oj cc :N unt bcr:
Project?hmager: Diane Hardison
Cnmpane: DOMUF Paper Cnmpam'. LLC
Lrb Code Client Sample N P ufCoot
J0905693-001 RYOI - Norfolk Southern
i
:
I I090569 -002 073A Old Fiorrmr Area ,
_ __
J090569+-003 CL 14 West Coo l,3dncan �
J0905693-004 j LP-04
J090569 -005 NBA
j J0905693-006 1I'02
�50905693-007� Woodyard
Special Instructions/Comments
w z Lc jA1 E? A
PLEASE SEND
<- t% ;, RESULTS TO
v-)A-� I't1? `` �' �'� M A N D Y SULLIVAN
Il1u-a-NetWo
it
is CLIStody
,
- Of
9N3 Philips Ifighw�r
• Jncksunvillc, FI 232,56 • 904-7.39-2277 -FAX gr64-739-101
1
1
t
lample
Date
i —
= i
C
Matrix
Date 'Pint,
Reccivcd Send To
Winer
111/11/09 1349
1 11/)7/09 HOUSTON
II -
Water
t 11/11/09 14 s4
1I/f 7/09 HOUSTON
7I
W aloe
-. II/I 1/09 1 1437
11/17/09 HOl1S'fON
H
II/R/09 091f,
11/17/09 1IOUSTON
iWater II
R'mcr
! I I/12/09 0931
11/17/09 HOUSTON
[[ :
Water
11/12/09 1 0946
I
1 11/17/00 HOUSTON
IL
Water
I 11/12/09 1026
t 11/17/09 i HOUSTON
tl
Rclinyuished Ry / 1 r / !l // %/'✓'`! Received
Turnaround Requirements
_Kl1SF1 (Surch¢rgca Apply)
PLEASE CIRCLE WORK DAYS
1 2 3 4 5
STANDARD
Rcqucstcd FAX Date:
Requested Repot Date: 12/08/09
�S Cmtrrct Tom Kissit.
111111 't`J 1
Report Requirements
1. Results Only
✓II. Results +QC Summaries
Ill. Resul Ls+QC and Calibration Summaries
IV, Data Validation Repoo with Raw Data
PQIIMDL/J Y
1,017) N
hrvoiee Information
PO:;
10905693
to
Airbill Numbe, I 06 D�t fi
V Pagc I

Reset'Fomi' ;
Columbia Analytical Services, Inc.
Cooler RJLipt Form
':IienNprojcct Domtar Paper / Plymouth Stormwater Testing Service Request:
Received: 11/18/090953 Opened(Date/Time): 11/18/091001 By:
1.
2.
3.
4.
5
6
7
S
9
J0905693
Samples were received via? ❑US Mail ❑Feclee ✓❑UPS ❑DIIL ❑Cotoier
Samples were received in: (circle) Elcooler ❑Box ❑ Other
Were custody seals present on coolers? ❑Y ✓❑N If yes, how many and where?
If present, were custody seals intact? ❑Y ❑N If present, were they signed and dated?
Is shipper's air -bill filed? ❑NA ❑Y ❑✓ N If not, record an bill number: 1ZX
❑Hanel Deliverer!
❑NA
❑Y El IN
5WO980142068140
Temperature of cooler(s) upon receipt (°C): 0
Ifapplicable, list Chain of Custody numbers:
Were custody papers properly filled out (inl:, signed, etc.)? ❑NA 0Y ❑N
Packing material used: ❑ht.rerrs ❑✓ Bubble Wrap ❑Blue Ice ❑✓ 6Pet Ice ❑Sleeves ❑Other
\%c the correct types of bottles used for the tests indicated? ❑J Y ❑N
Did all bottles arrive in good condition (i.e. unbroken, out of temp.)? Inclicote in the table below. ❑✓ Y ❑N
Sample ITS
Bottle Count
Bottle Type
Out of Temp:
Broken
Initials,
❑
❑
❑
❑
El
❑
❑
❑
❑
❑
❑
10. Were all bottle labels complete (i.e. analysis, ID, etc.)'?
Did all bottle labels and tags agree with custody papers? Inclicate in the table below.
❑✓Y ❑N
❑✓Y ❑N
Sample ID on Bottle Sample ID on COC Sample ID on Bottle Sample Ip onCOC
Additional notes, discrepancies, and resolutions:
24 of 29
CRF2092109.pdf Paae . 0 I ❑ 2

2s
Sample Acceptance Policy
Custody Seals (desirable, mandatory if specified in SAP):
✓ On outside of cooler
✓ Seals intact, signed and dated
Chain -of -Custody documentation (mandatory):
✓ Properly filled out in ink & signed by the client
✓ Sign and date the coc for CASMOU upon cooler receipt
✓ Coc must list method number
✓ If no coc was submitted with the samples, complete a CASMOU coc for the client
Sample Integrity (mandatory):
✓ Sample containers must arrive in good condition (not broken or leaking)
✓ Sample IDs on the bottles must match the sample IDs on the coc
✓ The correct type of sample bottle must be used for the method requested
✓ The correct number of sample containers received must agree with the
documentation on the coc
✓ The correct sample matrix must appear on the coc
✓ An appropriate sample volume or weight must be received
Temperature Preservatives (varies by sample matrix):
✓ Aqueous and Non -aqueous samples must be shipped and stored cold, at 0 to 60C
✓ Tissue samples must be shipped and stored frozen, at -20 to -10°C
✓ Air samples can be shipped and stored at ambient temperature, -23°C
✓ The sample temperattue must be recorded on the coc
✓ Notify a Project Chemist if any samples are outside the acceptance temperature or
have compromised sample integrity - the client must decide re: replacement sample
submittal or continue with the analysis
Cooler Receipt Form, CRF (mandatory):
✓ Cooler receipt forms must be completed for each coc & SRk
✓ Sample integrity issues must be documented on the CRF
✓ A scan of the carrier and the airbill number must be recorded in CAS LIMS
Sample Integrity Issues/Resolutions (mandatory):
✓ Sample integrity issues are documented on the CRF and given to the Project Chemist
for resolution with the client
✓ Client resolution is documented in writing (typically email or on the CRF) and filed in
the project folder(s)
25 of 29

Service Reao..,t Stinunary
Fuld,,, 4:
J0905693
choln Name'.
Dania, Industries
Project Name;
Plymouth Stintowaler Testing
Project Nlumbcr:
R,porl'Fo:
Dune Hardison
Donuar Paper Company, LLC
P.O. Rox 747
PI\•nlouth, NC 27962
Phone Number
252-793-8611
CA Numbcr
Pax Number:
252-793-8871
E-mail:
ditme.hardisonC,domtar.com
GV
Prnjeel Chemist:
Darren 13i1a
0 iiginating Lab:
JAX
Logged R3':
SLIGHTSPY
Date Rcceived:
11/17/09
Intcnud Dow Dive :
12/8/09
QAP:
LAB QAP
Qualifier Set.
CAS Standnni
ForniseC
CAS Standard
Merecd^:
NI
Repon to MDL'I
Y
P.O-Numbcr
<1550171884
EDD:
No FDD Specified
I
I I
1 -
CAS S,-,No Client Sao, No. \lapis COI -I'd
JO%5693-001
RYOI-Nonoll, Soollorn
Walm
I lit 1/09
1319.
II
...
JU9U5693-n03
_ ... ..
OBA - Old Borro� Arca
_ _. _
Wo r
........
1 FI 1/09
..
1154
.. .
J09D5693-003
Cl-IJ %Vlo Con L:p'dawn
.....
Wnlcr
11/11/09
1437
11
J090>693-004
LP -Oa
Wmc1
II/13/09
0915
IL
... ......
JDYUS693-005
......
NBA
.. ...
Winn
.. .. ...
Illl'J09
..i ..
0933
..... 1
ll �
10905693-II06
Lt'0_
Wun-r
II!IJ09
0946!
II
. .....
J0905693-007
.... ..... ... ... ........
l4orrclynN
nr
N':uN
.__
II/12 9
.1
IO2tij �
1026
... .
❑ t
Test Colnlnents:
Group T,,st/Nlethod
Semivoa GCMS
Dioxins Furans/16138
Samples
Comments
1-7 2378 TCDD only
III _ IDUU n.I--(Iss Houle AA'NI ANIRER TOI Liou1 Ilop¢rcracJ
Location: E-Disposed, F.-WIC01
NPDES
26 of 29
Printed 12/3/200911:312IAM Semi, Rnlneet tm J119U5693 Pngc 10l'1

Preparation Infa7..rntion Benchsheet
z
1'rnpRunF: 101047 PrepWin I N...: 0rgGxlAy(365)
Teo: ,: Scmicna GCv1S/AKODUR Prep Di cthml: Method
Status: Propped
Prep Dalefl'imc: 11/19/09 03:301'b1
Lab Code
Client ID
99
Method /Test
pH
Matrix
Amt. Ext.
Sample Description
10901034-001
Kruger P'la'1 Fcnis
01
I6GB/IJioxiv Fwsux
]
Wasmmnw,
1000nd,
limed clan liquid
2
E0901036-001
01 11 PINEDALE I6-0691 09B
01
1613B/Dimins Furans
S
Drinking Water
920mL
clue colorless liquid
E0901038-001
67940S
01
161313/1)ioshu F.,
]
W:umw:ecr
935m1-
:inud clear liquid
4
F0901043-002
9K 1.9005-'
01
1613BH)iozinz Furans
S
Wmn
850n,L
sandy cloudy liquid
5
EQ09e0J91-01
p3B
1611 B/Dioxins Fnrwu
Liquid
1000 .
6
EQ09004 9 1 -02
LCS
1613B/Diosim Furans
Liquid
I000nd.
]
E00900491-03
DLCS
1613B/1)ioxins Fun.,
Lignid
100end.
S
EQ0900491-04
ply
161380iacins Fmm�,s
Liquid
IUBOnd.
9
I.QU900491-05
LC.S
1613Br'Di.<ins Furans
Liquid
10ON'L
10
EQ0900491-06
DLCS
1613B/DI.zIn, Furans
Liquid
1000n:L
I I
J0905693-001
Ry01 - N.,W'k S.nt6arn
'01
1613B/D... i., Fwzia
5
Nvaw,
990nd.
hared cicur liquid
12
109DS693-002
013A - Old Rono,. Area
01
1613BNio.cire Furans
5
Wmcr
975.,L
yellow brawn cloudy liquid
13
J091)5693-003
CL-14 Wen Con L:nvlmcn
'01
1613610m,ms Roans
5
W:der
950nd.
tinted Oew liquid
14
J0905693.00I
LF-04
.01
1613B/Dioxins Furans
6
t a,,
950nd.
yell.,. cloudy liquid
15
J0905693-005
NBA
01
1613B/Dlumins Angus
5
Wain
9J0... L
lighr yell.. clnndy liquid
16
10905693.006
I.FW
.01
16138/Dioxins Fnmus
6
Wo,e,
9.10m1.
light yell.,. 6dy liquid
I]
J09USG')3-0W
W..dymd
01
1613B/Diosins Furans
6
W'wm
9GOmL
brm.n clnndy liquid
I%
1:0910960-W3
Bloch Mani Canpsfn.
'01
1668/Diosins Furans
5
W wl .,
1005.E
red brown clear liquid
I'J
K0911U?]-00?
DW-7-09IIII
.03
1613B/Dimins F.—,,
]
%Vw,
IOJUmL
dnlod cic:u liquid
?0
K0911U?]-OOJ
DW-9-09111'
03
1613B/Dios6rs Furans
0
Wmcr
1025mL
tinted clear liquid
?I
K09110J9-OU?
56229(AR)
03
16 UB/Uinsins Fnrm,s
6
Wmcr
1000111L,
beige c londy liquid
tiJ
27 of 29
Frinmd I I/'_3I09 11_:45 Prepnnnion In ldrmminn Bvncbshcm Pnge 1

Preparation lnfr.,,attlion Benchsheet
28
Prep Run...:: 101047 Prep R'oi kliloa': 0rflCatAy(361) Stole': Prepped -
'1'r:un: Semi,ou GCNIS/AKODUR Prep 1\Ir11unl: Nlelhod Prcp Datcll'ime: 11/19/09 03:30 I'M
Spiking Solutions
Name161311 hllaric Working Standard Invcntogq II) 11191 Logbook Rcf: 1)10�55-313 lispires On: 07/24/2014
EQ0900491-01 loo,00pl- e0o900491-03 too on)IL r, oOQOO 191-03 100.0opL EQ0900491-n6 100.00111.
LNine 8290/I613E Clcanup
Wmkimg Standard
n ID 13355
Logbook Ref
DIO-90-IA/R
Expires On
6/2010
E09O 1 U31-UUI
100.(to I11.
E0901036-001
IOO. UUpL
E09011138-IIUI
I00.00111-
1-09010,13-002
100.00111.
EQ090U491.OI too oojtL
EQU900-191-02
100.0opI.
F.Q090D491-D3
too.00pL
EQOl)OO191-04
100.00pL
EQ0900491-05
10000111-
LQr19Uo491-06
I01),00pL
J090s693-001 loo.OUpL
J0903693-002
100DopL
J0905693-003
100.00 pL
1090,695-004
100. no p l_
J0905691-005
100.00 it 1_
J0905693-006
IOU,IItIpL
J0905693-007 IOO.00liL
KU910960-UO3
too not,L
IC0911017-002
too.OopL
K0911027-00.1
100.00pl,
K0911049-002
too Uo11L
Name: 1613B Labeled Working Slandaud
Invenmry ID 13509
Logbook RcE
DIU-91-2(3
Expires On:
11/19/2010
C0901036-001 1,00o 0011L
E0901038-001
1000.001,1
EU9U 1043-002 10o0oott1L
J0905693-001
LUOO.00 pL J0905690-002 I,OOn00111..
3U'JU5693-003
1o0o.onpL
J0905693-004 1,000. 00111,
10905693-005
1 00000pL
J0905693-006 1 0n00U111.
JO905693-007
1,006.00 pL K091 U960-001 1,000. Good.
K0911027-002
10oo,o0p1,
K01)11017-(104 10011oojiL
K0911049-002
Lott oopl-
Name_ 1613R Labcicd W'ofkiog
Standard
Imenmry 11) 13310
Lngboak Ref:
DIO-902B
Expires On.
11/16/3010
L09010314-001 1000.00111.
LQO900491-01
10000UpL
EQ0900491-02 10000np 1,
UQ0900191-0.i
IOW oopl_ EQ0901F191-P1 1000UopL
000900491-05
1000. GOpl.
LQ0900491-06 1.000 no 1t L
Preparation Materials
A9c,9nc 99,1/ Mlnlnn.m
C2-I6-007 (7199)
Carbon, high Puny
C2-23-004 (9452)
Ethyl ncanrc 99.9'9 Mn,imom
C2-23-006 (9462)
EIOAc
Flukil Gd)
C2-8-003(36U3)
Glass M9o1
C2-13-005 (7 193)
SW lurk Acid R<agnv Grade
C2-24-003(9161)
112SOJ
Dichloramclhane(Metlrylene
C2-2S-001(9449)
Salium'll,insulfrte Anhydrous
C2-312(13072)
Sodom, Chloride Rengnn Grade
Cl- 104-2(3306)
Chladde) 99.9%\IcC12
Reagem Gmde NaS203
Xzcl
Sodlun, Hydroxide Ro gcnt
C'224-002 (940)
Sodium SNfnrc Anhydrous
C2-19-006 (BDI)
hidccanc (n-T,ideeane)
C1-24-001 (9460)
.
(',ade N9014
Reoganl Grade Na2SO4
Ile,,ane l„-Hezane)993'G
C2-25-004 (914 1)
Nonnne (n-Non,nsJ 99%
CM)-004 Ot57)
Al Papc,O-I4
(1008)
mmimnn,
.Silica Gd Rcagenr Ondu
C2-27-007 (9456)
'1'Macnc 99.956 h oun .um.
C2-25-O03 (9416)
Preparation Steps
Step: Earnclion
Stcp:
Acid Cl,..,
st, Silica Gd Clean
Stop: Final Obluns
li 5taned: 1111910915:30
sn"'.l:
11/20/09 US: on
Sinned: 11/20/09 I4:00
S"ni,oL II/23/U907:00
. cMudshul: 11/10,09 17:15
Fiuikhud
1117W09 OR: on
Finished' 11/20I09 MOO
Finished: 11; 23N9 to:9n
6y: AnODUR
0,
AKODUR
19p: ARODIIR
Ep: AKODUR
28 of 29
Rimed 11/23/09 11:45 R9parmim, Ldanuxtlon I3enchshce, R,ge 2

Prep I(oaN: IIIIU 17
Tram: Scmivoa GCMS/AKODUR
Commmnrs
Preparation,Lzformation Benchsheet
29
I'rcp AA4: rld�loo': OrgF.�tAy(3G�)
Prep :Method: Mclhod
Slat oa: prepped
1'rcp Datdl'inu: 11/19/09 0330I'M
Kcvlc:. rn By: JD oal�. 11/23/2009
fie?a.. arc::aod�.
8n:uc15 lis; ieA
K.ccivcJ ❑r: D;rtc. Ycs 1.b
0
P:mn,d 11/13/09 L, Is I'rcparml9n Intimmunna BracASLw Pa, 3

Domtar Company - Plymouth
Rainfall Amount
11/10/2009 to 11113/2009
Climate Final
Discharge
Pumps Rain
Gauge in
Date/Time
1/101200900:00 0.66
1/11/200900:00 5
1/12/2009 00:00 1.15
Minimum:
0.66
Maximum:
5.00
Average:
2.27
Total:
6.81
Monday, December 07, 2009
Page i

Boone, Tamika
From: Hardison, Diane
it: Thursday, November 12, 2009 12:12 PM
i J: Boone, Tamika
Cc: Barnes, Alan
Subject: Notes from 11/12 stormwater sampling effort
Alan and I went out again today and checked outfalls and collected samples from 4 additional outfalls that were producing
flow. The rain gauge showed 5 inches of rain this morning — 9:30 am, when Lorenza checked it. Here is the data on the
outfalls from which we collected samples:
LF04 ph =6.89
NBA ph=6.3
LF02 ph= 6.8
WYN ph = 7.4
1 have completed Qualitative Monitoring Reports for these as well. I will rewrite them so they are neat and leave them with
YOU to add to the record for this entire event.
Diane R. Hardison
Dom for Paper Company, LLC
Environmental Department
P.O. Box 747
Plymouth, NC 27962
Office phone [phone]
Cell phone [phone]
`max [phone]

Woodyard NBA OBA
COD 316 37
BOD 17 3
Solids 34 17
LF04 CL14 LF02 RY01 005
93 46 32 46 23 23
10 2 1 4 3 2
49 69 44 20 22 5

NOTE:
AREAS WHICH ARE NOT HIGHLIGHTED F
z NOT REGULATED AREAS BECAUSE:
a
1. AREA IS ENGINEERED TO DRAIN TO THE
WASTEWATER TREATMENT SYSTEM OR
2. AREA IS NOT USED FOR INDUSTRIAL
ACTIVITIES.
J
i
A jr
q86
l � t
1NEW
SALV^ a�
1p'.
/ ���bYyyyElY 3 JL
CC 19 I✓` 1. J �,�
a
_ --SALVAGE
AREA
" (RELOCATED)
A Imo 7 ii
CONS$ 1G
14
/
PARKING AR4!A
(R LO ATED)
URS
LEGEND " �� I X Jr eG Yoilh Cu�Gn 11760J
i'?e Ideplron J79xa,09Si1 E'xt 919)7900217
9.
�5
DOMTAR I'APhR COMPANY, LLC
PLYMOUTI I NOR LII CAROL INA
i opClE4 l07D x * \ �`"`�nF ' I'I 1 � � AL \S S7101VN 1DRN 9 h�13G{3A�( (1/,), ,,,I FIL�?l0. -
DR,lINAGE 4RLA v 1���" SV �7ID0=
`x ftOXIMATE SCALE � � �
,• .,. A xi., C_ _a s::a.n�s'� -- � � 1VIS!(() Ill( It��.I.AYI,)L�l,.,e1,A
j 00 3U0 Fteij 10I
t

SEDIMENT PONDS
RUNOFF COLLECTION AREA
01SCHARGE VOLUME
POND No.
BEGIN OPERATION
(ACRES)
(ACRE-FEET)
1
1990
33.9
10.5
2
1990
6.5
2.0
3
2001
I6.7
5.2
4
2010
16.4
5.1
5
2014
30.8
9.6
5
2072
40.5
12.6
LF04
2005
TEMPORARY
NOTES
1. PHASE CONSTRUCTION IS BASED ON AN ESTIMATED WASTE GENERATION RATE
OF 100,000 CUBIC YARDS PER YEAR.
2. DISCHARGE VOLUME IS BASED ON A 25 YEAR/24 HOUR STORM EVENT.
3. LANDFILL #3 IS UNDER CONSTRUCTION. CELLS 1 & 2 ARE IN SERVICE.
URS
/ LIRS CoryOrziiou Maryland
Jt09 Poplaru and Cuml, Suite 301
Rah h 'lrmxh C+rohn e 7604
1'dapham /¢19J P`0-9.i l l l n (919,7'V 0217
UONITAR PAPER COMPANY, LLC
PL'YMOUTH, NORTH C'AROLINA
_CAL: ORN BY: c P �ATF bOf) M. DIO
15 .SHOl4\ R'VISED: dhl3 55100.-
A 20KA1ATE SCALP .q�
0 b0� i0}0

j
LEGEND
DRAINAGE AREA
/ I � SPOT ELEVATION
/ 30 /
SURFACE FLOW DRAINAGE DIRECTION
� SWAMP
U x„
3 / — APPROXIMATE SCALE — \
0 20'— FEET
WOO
/ CLE
AREA /
n
/ X
169 /
I
NOTE: F
AREAS WHICH ARE NOT HIGHLIGHTED ARE
NOT REGULATED AREAS BECAUSE:
1§.9
,a., 1. AREA IS ENGINEERED TO DRAIN TO THE
\ EARTHB WASTEWATER TREATMENT SYSTEM OR
\ BERM
3 / 2. AREA IS NOT USED FOR INDUSTRIAL lJ T Tii�l S
63 acrlvlTlEs.
J R�l'rl ).c Sui�
AI as" mid
l"m.
\ Lrahn 7604
1)11))790-0217
DOMTAR PAPHR COMPANY
i'LYMOC IH \0H2TH (' 1ROI I\ NA A
\ / CAIE: rRN 9
1 li 11 f DATL. " (") HlE N0.
_ 13A AssilowN REVISED I"Hi DATE -__ I( 09 _ S�l�n'.
94 — ( I
i

North Carolina
Beverly Eaves Perdue
Governor
Ms. Diane Hardison
Domtar Paper Company, LLC
PO Box 747
Plymouth, NC 27962
Dear Ms. Hardison:
FRI r
NCDENR
Department of Environment and
Division of Water Quality
Coleen H. Sullins
Director
October 1, 2010
Natural Resources
Dee Freeman
Secretary
Subject: Modified NPDES Stormwater Permit
Perm it NCS000189
Domtar Paper Company, LLC
Martin County
In response to your request to remove Dioxin Sampling/Analyses from the NPDES stormwater permit
NCS000189, the Division of Water Quality (Division) is forwarding herewith the modified NPDES permit. This
permit is issued pursuant to the requirements of North Carolina General Statute 143-215 .1 and the
Memorandum of Agreement between North Carolina and the U.S. Environmental Protection agency dated
October 15, 2007 (or as subsequently amended).
This modified permit includes one change from the final permit sent to you on July 24, 2009. The monitoring
for Dioxin was changed to only the outfall in the Winter Log Storage area (WLSOI). This was based on the
recommendation from the Washington Regional Office (WaRO) because of the positive detection of dioxin in a
soil sample from this area.
Based on recommendation by the WaRO representative outfall status will be approved for Outfall CL71 and
LFOI. Outfall CLI I will represent all the outfalls from the Contractor Laydown Area (CL71, CL13 and CL74).
Outfall LFOI will represent all of the stormwater discharges from the two sedimentation ponds which collect
runoff from the closed, capped and vegetated No. 2 Landfill (LFOI and LF02). Please remember, qualitative
sampling must be done at every outfall.
If you have any questions or comments concerning this permit, contact Brian Lowther at [phone] or
brig n.lowtherQncden r. gov.
Sincerely,
for Coleen H. Sullins, Director
cc Washington Regional Office, Water Quality Section
Mike Mitchell, EPA Region IV
Stormwater Permitting Unit
Central Files
Attachments: Modified NPDES Stormwater Permit NCS000189
Wetlands and Stormwater Branch OI1C t
1617 Mail Service Center, Raleigh, North Carolina 27699-1617 NOittICaFOtllla
Location: 912 N. Salisbury St. Rale19-807, North Carolina r SeNi ��ry��/N`����
Phone::[phone]
ter FAX: [phone] Customer Service: 1-877-623-6746 Naturally
Internet: vnwv.ncwateryualiry.org
An Enual Onnorinniry \ Alfirmaliva Action Emnlnver

NCS000189
STATE OF NORTH CAROLINA
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WATER QUALITY
PERMIT
TO DISCHARGE STORMWATER UNDER THE
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
In compliance with the provisions of North Carolina General Statute 143-215.1, other lawful
standards and regulations promulgated and adopted by the North Carolina Environmental
Management Commission, and the Federal Water Pollution Control Act, as amended,
Domtar Paper Company, LLC
is hereby authorized to discharge stormwater from a facility located at
Domtar Paper Company, LLC - Plymouth
Highway 149 North
Plymouth, NC
Martin County
to receiving waters designated as Welch Creek, a -class C;Sw stream and the Roanoke River, a
class C;Sw in the Roanoke River Basin, in accordance with the discharge limitations, monitoring
requirements, and other conditions set forth in Parts I, II, III, IV, V and VI hereof.
This permit shall become effective November 1, 2010.
This permit and the authorization to discharge shall expire at midnight on July 31, 2014.
Signed this day October 1, 2010.
for Coleen H. Sullins, Director
Division of Water Quality
By the Authority of the Environmental Management Commission

Permit No. NCS000189
TABLE OF CONTENTS
PART I INTRODUCTION
Section A: Individual Permit Coverage,
Section B: Permitted Activities
Section C: Location Map
PART 11 MONITORING, CONTROLS, AND LIMITATIONS FOR PERMITTED
DISCHARGES
Section A: Stormwater Pollution Prevention Plan
Section B: Analytical Monitoring Requirements
Section C: Qualitative Monitoring Requirements
Section D: On -Site Vehicle Maintenance Monitoring Requirements
PART If] STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL
PERMITS
Section A: Compliance
and Liability
I .
Compliance Schedule
2.
Duty to Comply
3.
Duty to Mitigate
4.
Civil and Criminal Liability
5.
Oil and Hazardous Substance Liability
6.
Property Rights
7.
Severability
8.
Duty to Provide Information
9.
Penalties for Tampering
10.
Penalties for Falsification of Reports
Section B: General
Conditions
l .
Individual Permit Expiration
2.
Transfers
i

Pemit No. NCS000189
3. Signatory Requirements
4. Individual Permit Modification, Revocation and Reissuance, or
Tennination
5. Pennit Actions
Section C: Operation and Maintenance of Pollution Controls
l . Proper Operation and Maintenance
2. Need to Halt or Reduce Not a Defense
3. Bypassing of Stormwater Control Facilities
Section D: Monitoring and Records
I.
Representative Sampling
2.
Recording Results
3.
Flow Measurements
4.
Test Procedures
5.
Representative Outfall
6.
Records Retention
7.
Inspection and Entry
Section E: Reporting
Requirements
1.
Discharge Monitoring Reports
2.
Submitting Reports
3.
Availability of Reports
4.
Non-Stormwater Discharges
5.
Planned Changes
6.
Anticipated Noncompliance
7.
Bypass
8.
Twenty-four Hour Reporting
9.
Other Noncompliance
10.
Other Information
PART IV LIMITATIONS REOPENER
PART V ADMINISTERING AND COMPLIANCE MONITORING FEE
REQUIREMENTS
PART VI DEFINITIONS
ii

Permit No. NCS000189
PART I INTRODUCTION
SECTION A: INDIVIDUAL PERMIT COVERAGE
During the period beginning on the effective date of the permit and lasting until expiration, the
permittee is authorized to discharge stormwater associated with industrial activity. Such
discharges shall be controlled, limited and monitored as specified in this permit.
If industrial materials and activities are not exposed to precipitation or runoff as described in 40
CFR § I22.26(g), the facility may qualify for a No Exposure Exclusion from NPDES stormwater
discharge permit requirements. Any owner or operator wishing to obtain a No Exposure
Certification must submit a No Exposure Certification NOI form to the Division; must receive
approval by the Division; rnusl maintain no exposure conditions unless authorized to discharge
under a valid NPDES stormwater permit; and must reapply for the No Exposure Exclusion once
every five (5) years.
SECTION B: PERMITTED ACTIVITIES
Until this pen -nit expires or is modified or revoked, the pennittee is authorized to discharge
stormwater to the surface waters of North Carolina or separate storm sewer system that has been
adequately treated and managed in accordance with the terms and conditions of this individual
pen -nit. All stormwater discharges shall be in accordance with the conditions of this permit.
Any other point source discharge to surface waters of the state is prohibited unless it is an
allowable non-stormwater discharge or is covered by another permit, authorization, or approval.
The stormwater discharges allowed by this individual pen -nit shall not cause or contribute to
violations of Water Quality Standards.
This permit does not relieve the pennittee from responsibility for compliance with any other
applicable federal, state, or local law, rule, standard, ordinance, order, judgment, or decree.
Part I Page 1 of 2

SECTION C: LOCATION NIAP
Permit No. NCSOOO 199
V......
T117 _S
ND
CONTRACTOR
MOOD YARD NORT
LAYDOWN AREA
PR PA
OUTFALL CL1 1
OUTFALL CP01
Ix
e4
OUTFALL CL14 OUTFALLFYO1 Ilk
OD AND ASH RECY ��AREA - CUTFALL AR01 CL
`--dOUTFALL LF01 -LF04
F",
i0o P R AREAOVV-�
'ja
LANDFILL No.2
LANDFILL BORROW AREA
7-
LANDFILL No 3
T-
NCS000189
II
A W Scale 1. 30, XO
Domta r Paper Company, LLC
Lad tude: 350 5 1' 29" N
Longitude: 760 47' 19" W
County: rvbrbn
Receiving Stream: Wdch Creek; Roanoke Riwr
Stream Class: C; Sw
Sub -basin: 03-02-09 (Roanoke River Basin)
Facility Location
Part I Page 2 of 2

Permit No. NCS000189
PART H MONITORING, CONTROLS, AND LIMITATIONS FOR
PERMITTED DISCHARGES
SECTION A: STORM\VATER POLLUTION PREVENTION PLAN
The Permittee shall develop a Stormwater Pollution Prevention Plan, herein after referred to as
the Plan. This Plan shall be considered public information in accordance with Part III, Standard
Conditions, Section E, Paragraph 3 of this individual permit. The Plan shall include, at a
minimum, the following items:
Site Plan. The site plan shall provide a description of the physical facility and the
potential pollutant sources which may be expected to contribute to contamination of
stormwater discharges. The site plan shall contain the following:
(a) A general location map (USGS quadrangle map or appropriately drafted
equivalent map), showing the facility's location in relation to transportation
routes and surface waters, the name of the receiving water(s) to which the
stormwater outfall(s) discharges, or if the discharge is to a municipal separate
storm sewer system, the name of the municipality and the ultimate receiving
waters, and accurate latitude and longitude of the point(s) of discharge. The
general location map (or alternatively the site map) shall identify whether each
receiving water is impaired (on the state's 303(d) list of impaired waters) or is
located in a watershed for which a TMDL has been established, and what the
parameter(s) of concern are.
North Carolina's 303(d) List can be found here:
http://h2o.enr.state.nc.us/tmdl/General_303d.htm#Downloads
North Carolina TMDL documents can be found here:
Irttp://h2o.enr.state.ne.us/tmdl/TMDL list.htm#Final TNIDLs.
(b) A narrative description of storage practices, loading and unloading activities,
outdoor process areas, dust or particulate generating or control processes, and
waste disposal practices. A narrative description of the potential pollutants which
could be expected to be present in the stormwater discharge from each outfall.
(c) A site map drawn to scale (including a distance legend) showing: the site property
boundary, the stormwater discharge outfalls, all on -site and adjacent surface
waters and wetlands, industrial activity areas (including storage of materials,
disposal areas, process areas, loading and unloading areas, and haul roads), site
topography, all drainage features and structures, drainage areas for each outfall,
direction of flow in each drainage area, industrial activities occurring in each
drainage area, buildings, existing BMPs, and impervious surfaces. The site map
must indicate the percentage of,each drainage area that is impervious.
(d) A list of significant spills or leaks of pollutants that have occurred at the facility
during the three (3) previous years and any corrective actions taken to mitigate
spill impacts.
Part 11 Page 1 of 10

Pemit No. NCS000189
(e) Certification that the stormwater outfalls have been evaluated for the presence of
non-stormwater discharges. The certification statement will be sigmed in
accordance with the requirements found in Part 111, Standard Conditions, Section
B, Paragraph 5. The permittee shall re -certify annually that the stormwater
outfalls have been evaluated for the presence of non-stormwater discharges.
2. Stormwater Management Plan. The stormwater management plan shall contain a
narrative description of the materials management practices employed which control or
minimize the exposure of significant materials to stormwater, including structural and
nonstructural measures. The stormwater management plan, at a minimum, shall
incorporate the following:
(a) Feasibility Study. A review of the technical and economic feasibility of changing
the methods of operations and/or storage practices to eliminate or reduce exposure
of materials and processes to stormwater. Wherever practical, the permittee shall
prevent exposure of all storage areas, material handling operations, and
manufacturing or fueling operations. In areas where elimination of exposure is
not practical, the stormwater management plan shall document the feasibility of
diverting the stormwater runoff away from areas of potential contamination.
(b) Secondary Containment Requirements and Records. Secondary containment is
required for: bulk storage of liquid materials; storage in any amount of Section
313 of Title III of the Superfund Amendments and Reauthorization Act (SARA)
water priority chemicals; and storage in any amount of hazardous substances, in
order to prevent leaks and spills from contaminating stormwater runoff. A table
or summary of all such tanks and stored materials and their associated secondary
containment areas shall be maintained. If the secondary containment devices are
connected directly to stormwater conveyance systems, the connection shall be
controlled by manually activated valves or other similar devices (which shall be
secured closed with a locking mechanism), and any stormwater that accumulates
in the containment area shall be at a minimum visually observed for color, foam,
outfall staining, visible sheens and dry weather flow, prior to release of the
accumulated stormwater. Accumulated stormwater shall be released if found to
be uncontaminated by the material stored within the containment area. Records
documenting the individual making the observation, the description of the
accumulated stormwater, and the date and time of the release shall be kept for a
period of five years.
(c) BMP Summary. A listing of site structural and non-structural Best Management
Practices (BMP) shall be provided. The installation and implementation of BMPs
shall be based on the assessment of the potential for sources to contribute
significant quantities of pollutants to stormwater discharges and data collected
through monitoring of stormwater discharges. The BMP Summary shall include a
written record of the specific rationale for installation and implementation of the
selected site BMPs. The BMP Summary shall be reviewed and updated annually.
Part 11 Page 2 of 10

Perniit No. NCS000189
3. Spill Prevention and Response Plan. The Spill Prevention and Response Plan (SPRP)
shall incorporate an assessment of potential pollutant sources based on a materials
inventory of the facility. Facility personnel (or the team) responsible for implementing the
SPRP shall be identified in a written list incorporated into the SPRP and signed and dated
by each individual acknowledging their responsibilities for the plan. A responsible
person shall be on -site at all times during facility operations that have the potential to
contaminate stormwater runoff through spills or exposure of materials associated with the
facility operations. The SPRP must be site stormwater specific. Therefore, an oil Spill
Prevention Control and Countermeasure plan (SPCC) may be a component of the SPRP,
but may not be sufficient to completely address the stormwater aspects of the SPRP. The
common elements of the SPCC with the SPRP may be incorporated by reference into the
SPRP.
4. Preventative Maintenance and Good Housekeeping Program. A preventative
maintenance and good housekeeping program shall be developed. The program shall list
all stormwater control systems, stormwater discharge outfalls, all on -site and adjacent
surface waters and wetlands, industrial activity areas (including material storage areas,
material handling areas, disposal areas, process areas, loading and unloading areas, and
haul roads), all drainage features and structures, and existing structural BMPs. The
program shall establish schedules of inspections, maintenance, and housekeeping
activities of stormwater control systems, as well as facility equipment, facility areas, and
facility systems that present a potential for stormwater exposure or stormwater pollution.
Inspection of material handling areas and regular cleaning schedules of these areas shall
be incorporated into the program. Timely compliance with the established schedules for
inspections, maintenance, and housekeeping shall be recorded in writing and maintained
in the SPPP.
5. Employee Training. Training programs shall be developed and training provided at a
minimum on an annual basis for facility personnel with responsibilities for: spill response
and cleanup, preventative maintenance activities, and for any of the facility's operations
that have the potential to contaminate stormwater runoff. Facility personnel (or team)
responsible for implementing the training shall be identified, and their annual training
shall be documented by the signature of each employee trained.
6. Responsible Party. The Stormwater Pollution Prevention Plan shall identify a specific
position(s) responsible for the overall coordination, development, implementation, and
revision to the Plan. Responsibilities for all components of the Plan shall be documented
and position assignments provided.
Plan Amendment. The permittee shall amend the Plan whenever there is a change in
design, construction, operation, or maintenance which has a significant effect on the
potential for the discharge of pollutants to surface waters. All aspects of the Stormwater
Pollution Prevention Plan shall be reviewed and updated on an annual basis. The annual
update shall include an updated list of sigmificant spills or leaks of pollutants for the
previous three years, or the notation that no spills have occurred. The annual update shall
include re -certification that the stormwater outfalls have been evaluated for the presence
of non-stormwater discharges. Each annual update shall include a re-evaluation of the
Part 11 Page 3 of 10

Permit No. NCS000199
effectiveness of the BMPs listed in the BMP Summary of the Stormwater Management
Plan.
The Director may notify the pennittee when the Plan does not meet one or more of the
minimum requirements of the permit. Within 30 days of such notice, the permittee shall
submit a time schedule to the Director for modifying the Plan to meet minimum
requirements. The pennittee shall provide certification in writing (in accordance with
Part 111, Standard Conditions, Section B, Paragraph 5) to the Director that the changes
have been made.
Facility Inspections. Inspections of the facility and all stormwater systems shall occur as
part of the Preventative Maintenance and Good Housekeeping Program at a minimum on
a semi-annual schedule, once during the first half of the year (January to June), and once
during the second half (July to December), with at least 60 days separating inspection
dates (unless performed more frequently than semi-annually). These facility inspections
are different from, and in addition to, the stormwater discharge characteristic monitoring
required in Part II B and C of this permit.
9. Implementation. The permittee shall implement the Plan. Implementation of the Plan
shall include documentation of all monitoring, measurements, inspections, maintenance
activities, and training provided to employees, including the log of the sampling data and
of actions taken to implement BMPs associated with the industrial activities, including
vehicle maintenance activities. Such documentation shall be kept on -site for a period of
five years and made available to the Director or the Director's authorized representative
immediately upon request.
Part 11 Page 4 of 10

Permit No. NCS000189
SECTION B: ANALYTICAL MONITORING REQUIREMENTS
Analytical monitoring of stormwater discharges shall be performed as specified in Table 1. All
analytical monitoring shall be performed during a representative storm event. The required
monitoring will result in a minimum of ten analytical samplings being conducted over the term of
the permit at each stormwater discharge outfall (SDO).
A representative storm event is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours in which no storm event measuring greater than 0.1
inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation. For example, if it rains for 2 hours without producing any collectable discharge,
and then stops, a sample may be collected if a rain producing a discharge begins again within the
next 10 hours.
Table 1. Analytical Monitoring Requirements
Discharge
Characteristics
Units
Measurement
Fre uenc l
Sample
Type2
Sample
Location3
Biological Oxy e.n Demand (BODO
m > L
semi-annual
Grab
SDO
Chemical Oxygen Demand (COD)
m L
semi-annual
Grab
SDO
Total Suspended Solids
m L
semi-annual
Grab
SDO
Dioxins
in • L
semi-annual
Grab
WLSOI
H
standard
semi-annual
Grab
SDO
Total Rainfall°
inches
semi-annual
Rain Gauge
Footnotes:
I Measurement Frequency: Twice per year during a representative storm event, for each year until either another
permit is issued for this facility or until this permit is revoked or rescinded. If at the end of this permitting cycle
the pemtittee has submitted the appropriate paperwork for a renewal permit before the submittal deadline, the
perminee will be considered for a renewal application. The applicant must continue semi-annual monitoring until
the renewed permit is issued. See Table 2 for schedule of monitoring periods through the end of this permitting
cycle.
2 If the stormwater runoff is controlled by a stormwater detention pond, a grab sample of the discharge from the
pond shall be collected within the first 30 minutes of discharge.
3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) unless representative
outfall status has been granted.
4 For each sampled representative storm event the totalprecipitation must be recorded. An on -site rain gauge or
local rain gauge reading must be recorded.
Part 11 Page 5 of 10

Permit No. NCS000189
The permittee shall complete the minimum ten analytical samplings in accordance with the
schedule specified below in Table 2. A minimum of 60 days must separate Period 1 and
Period 2 sample dates unless monthly monitoring has been instituted under a Tier Two
response.
Table 2_ Mnnitorinv Schedule
Monitoring periodt'Z
Sample Number
Start
End
Year 1 — Period 1
1
August 1, 2009
January 31, 2010
Year 1 — Period 2
2
February 1, 2010
July 31, 2010
Year 2 — Period 1
3
August I, 2010
January 31, 2011
Year 2 — Period 2
4
February 1, 2011
July 31, 2011
Year 3 — Period 1
5
August 1, 2011
January 31, 2012
Year 3 — Period 2
6
February I, 2012
July 31, 2012
Year 4 — Period 1
7
August 1, 2012
January 31, 2013
Year 4 — Period
8
February 1, 2013
July 31, 2013
Year 5 — Period 1
9
August 1, 2013
January 31, 2014
Year 5 — Period 2
10
February I, 2014
July 31, 2014
Footnotes:
I Maintain semi-annual monitoring during permit renewal process. The applicant must continue semi-annual
monitoring until the renewed permit is issued.
2 If no discharge occurs during the sampling period, the permittee must submit a monitoring report indicating "No
Flow" within 30 days of the end of the six-month sampling period.
The permittee shall report the analytical results from the first sample with valid results within the
monitoring period. The permittee shall compare monitoring results to the benchmark values in
Table 3. The benchmark values in Table 3 are not permit limits but should be used as guidelines for
the permittee's Stormwater Pollution Prevention Plan (SPPP). Exceedences of benchmark values
require the permittee to increase monitoring, increase management actions, increase record keeping,
and/or install stormwater Best Management Practices (BMPs) in a tiered program. See below the
descriptions of Tier One and Tier Two.
Table 3. Benchmark Values for Analvtical Monitoring
Discharge Characteristics
Units
Benchmark
Biological Oxygen Demand
mg/L
30
Chemical Oxygen Demand
mg/L
120
Total Suspended Solids
mg/L
100
Dioxins
mg/L
Any Detection
PH
standard
6-9
Part 11 Page 6 of 10

Pennit No. NCS000189
Tier One
If: The first valid sampling results are above a benchmark value, or outside of the benchmark
range, for any parameter at any outfall;
Then: The permittee shall:
1. Conduct a stormwater management inspection of the facility within two weeks of receiving
sampling results.
2. Identify and evaluate possible causes of the, benchmark value exceedence.
3. Identify potential, and select the specific: source controls, operational controls, or physical
improvements to reduce concentrations of the parameters of concern, or to bring
concentrations to within the benchmark range.
4. Implement the selected actions within two months of the inspection.
5. Record each instance of a Tier One response in the Stonnwater Pollution Prevention Plan.
Include the date and value of the benchmark exceedence, the inspection date, the personnel
conducting the inspection, the selected actions, and the date the selected actions were
implemented.
Tier Two
If: During the term of this permit, the first valid sampling results are above the benchmark values,
or outside of the benchmark range, for any specific parameter at a specific discharge outfall two
times in a row (consecutive);
Then: The permittee shall:
1. Repeat all the required actions outlined above in Tier One.
2. Immediately institute monthly monitoring for all parameters at every outfall where a
sampling result exceeded the benchmark value for two consecutive samples. Monthly
(analytical and qualitative) monitoring shall continue until three consecutive sample results
are below the benchmark values, or within the benchmark range, for all parameters at that
outfall.
3. If no discharge occurs during the sampling period, the permittee is required to submit a
monthly monitoring report indicating "No Flow."
4. Maintain a record of the Tier Two response in the Stormwater Pollution Prevention Plan.
Part It Page 7 of 10

Pennit No. NCS000199
During the term of this permit, if the valid sampling results required for the permit monitoring
periods exceed the benchmark value, or are outside the benchmark range, for any specific
parameter at any specific outfall on more than four occasions, the permittee shall notify the DWQ
Regional Office Supervisor in writing within 30 days of receipt of the fourth analytical results.
DWQ may, but is not limited to:
• require that the permittee increase or decrease the monitoring frequency for the remainder
of the permit;
• require the permittee to install structural stormwater controls;
• require the permittee to implement other stormwater control measures; or
• require that the permittee implement site modifications to qualify for the No Exposure
Exclusion.
This site discharges to impaired waters which are currently subject to a Fish Advisory for
Dioxin and Mercury. If a Total Maximum Daily Load (TMDL) is approved for this segment of
Roanoke River or Welch Creek, the permittee may be required to monitor for the pollutant(s) of
concern in the future and submit results to the Division of Water Quality. The Division will
consider the monitoring results in determining whether additional BMPs are needed to control
the pollutant(s) of concern to the maximum extent practicable.
If additional BMPs are needed to achieve the required level of control, the permittee will be
required to (1) develop a strategy for implementing appropriate BMPs, and (2) submit a timetable
for incorporation of those BMPs into the permitted Stormvater Pollution Prevention Plan.
Part 11 Page 8 of 10

Permit No. NCS000189
SECTION C: QUALITATIVE MONITORING REQUIREMENTS
Qualitative monitoring requires a visual inspection of each stormwater outfall regardless of
representative outfall status and shall be performed as specified in Table 4, during the analytical
monitoring event. [If analytical monitoring is not required, the permittee still must conduct semi-
annual qualitative monitoring.] Qualitative monitoring is for the purpose of evaluating the
effectiveness of the Stonnwater Pollution Prevention Plan (SPPP) and assessing new sources of
stormwater pollution.
In the event an atypical condition is noted at a stormwater discharge outfall, the permittee shall
document the suspected cause of the condition and any actions taken in response to the
discovery. This documentation will be maintained with the SPPP.
Table 4. Qualitative Monitoring Requirements
Discharge Characteristics
Frequencyt
Monitoring
Location2
Color
semi-annual
SDO
Odor
semi-annual
SDO
Clarity
semi-annual
SDO
Floating Solids
semi-annual
SDO
Suspended Solids
semi-annual
SDO
Foam
semi-annual
SDO
Oil Sheen
semi-annual
SDO
Erosion or deposition at the
outfall
semi-annual
SDO
Other obvious indicators
of stormwater pollution
semi-annual
SDO
Footnotes:
1 Measurement Frequency: Twice per year during a representative storm event, for each year until either another
permit is issued for this facility or until this permit is revoked or rescinded. If at the end of this permitting cycle
the permittee has submitted the appropriate paperwork for a renewal permit before the submittal deadline, the
permittee will be considered for a renewal application. The applicant must continue semi-annual monitoring until
the renewed permit is issued. See Table 2 for schedule of monitoring periods through the end of this permitting
cycle.
2 Monitoring Location: Qualitative monitoring shall be performed at each stormwater discharge outfall (SDO)
regardless of representative outfall status.
SECTION D: ON -SITE VEHICLE MAINTENANCE MONITORING REQUIREMENTS
Facilities which have any vehicle maintenance activity occurring on -site which uses more than 55
gallons of new motor oil per month when averaged over the calendar year shall perform
analytical monitoring as specified below in Table 5. This monitoring shall be performed at all
stormwater discharge outfalls which discharge stormwater runoff from vehicle maintenance
Part 11 Page 9 of 10

Permit No. NCS0001 89
areas, and in accordance with the schedule presented in Table 2 (Section B). All analytical
monitoring shall be performed during a representative storm event.
Table 5. AnahTical Monitoring Requirements for On -Site Vehicle Maintenance
Discharge Characteristics
Units
Measurement
Fre uencvt
Sample
T e2
Sample
Location3
H
standard
semi-annual
Grab
SDO
Oil and Grease
mg/1
semi-annual
Grab
SDO
Total Suspended Solids
mg/1
semi-annual
Grab
SDO
Total Rainfall4
inches
semi-annual
Rain gauge
New Motor Oil Usage
gallons/month
semi-annual
Estimate
Footnotes:
I Measurement Frequency: Twice per year during a representative storm event, for each year until either another
permit is issued for this facility or until this permit is revoked or rescinded. If at the end of this permitting cycle
the permittee has submitted the appropriate paperwork for a renewal permit before the submittal deadline, the
permittee will be considered for a renewal application. The applicant must continue semi-annual monitoring until
the renewed permit is issued. See Table 2 for schedule of monitoring periods through the end of this permitting
cycle.
2 If the stormwater runoff is controlled by a stormwater detention pond a grab sample of the discharge from the
pond shall be collected within the first 30 minutes of discharge from the pond.
3 Sample Location:. Samples shall be collected at each stormwater discharge outfall (SDO) that discharges
stormwater runoff from area(s) where vehicle maintenance activities occur.
4 For each sampled representative storm event the total precipitation must be recorded. An on -site or local rain
gauge reading must be recorded.
Monitoring results shall be compared to the benchmark values in Table 6. The benchmark
values in Table 6 are not permit limits but should be used as guidelines for the permittee's
Stormwater Pollution Prevention Plan (SPPP). Exceedences of benchmark values require the
permittee to increase monitoring, increase management actions, increase record keeping, and/or
install stormwater Best Management Practices (BMPs), as provided in Part 11 Section B.
Table 6. Benchmark Values for Vehicle Maintenance Analytical Monitoring
Discharge Characteristics
Units
Benchmark
pH
standard
6-9
Oil and Grease
mg/L
30
Total Suspended Solids
mg/L
100
Part 11 Page 10 of 10

Permit No. NCS000189
PART III STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS
SECTION A: COMPLIANCE AND LIABILITY
Compliance Schedule
The permittee shall comply with Limitations and Controls specified for stormwater discharges in
accordance with the following schedule:
Existing Facilities already operating but applying for permit coverage for the first time: The Stormwater
Pollution Prevention Plan shall be developed and implemented within 12 months of the effective date of the
initial permit and updated thereafter on an annual basis. Secondary containment, as specified in Part 11,
Section A, Paragraph 2(b) of this permit, shall be accomplished within 12 months of the effective date of
the initial permit issuance.
New Facilities applying for coverage for the first time and existing facilities previously permitted and
applying for renewal under this permit: The Stormwater Pollution Prevention Plan shall be developed and
implemented prior to the beginning of discharges from the operation of the industrial activity and be
updated thereafter on an annual basis. Secondary containment, as specified in Part II, Section A, Paragraph
2(b) of this permit shall be accomplished prior to the beginning of discharges from the operation of the
industrial activity.
Dutv to Complv
The permittee must comply with all conditions of this individual permit. Any permit noncompliance
constitutes a violation of the Clean Water Act and is grounds for enforcement action; for permit
termination, revocation and reissuance, or modification; or denial of a permit upon renewal application.
a. The permittee shall comply with standards or prohibitions established under section 307(a) of the
Clean Water Act for toxic pollutants within the time provided in the regulations that establish these
standards or prohibitions, even if the permit has not yet been modified to incorporate the
requirement.
b. The Clean Water Act provides that any person who violates a permit condition is subject to a civil
penalty not to exceed $25,000 per day for each violation. Any person who negligently violates any
permit condition is subject to criminal penalties of $2.500 to 25,000 per day of violation, or
imprisonment for not more than 1 year, or both. Any person who knowingly violates permit
conditions is subject to criminal penalties of $5,000 to $50,000 per day of violation, or
imprisonment for not more than 3 years, or both. Also, any person who violates a permit condition
may be assessed an administrative penalty not to exceed $10,000 per violation with the maximum
amount not to exceed $125,000. [Ref: Section 309 of the Federal Act 33 USC 1319 and 40 CFR
122.41(a).]
C. Under state law, a daily civil penalty of not more than ten thousand dollars ($10,000) per violation
may be assessed against any person who violates or fails to act in accordance with the terms,
conditions, or requirements of a permit. [Ref: NC General Statutes 143-215.6A].
d. Any person may be assessed an administrative penalty by the Director for violating section 301,
302, 306, 307, 308, 318 or 405 of the Act, or any permit condition or limitation implementing any
of such sections in a permit issued under section 402 of the Act. Administrative penalties for Class
1 violations are not to exceed $10,000 per violation, with the maximum amount of any Class
penalty assessed not to exceed $25,000. Penalties for Class 11 violations are not to exceed
Part III Page I of 8

Permit No. NCS000189
$10,000 per day for each day during which the violation continues, with the maximum amount of
any Class 11 penalty not to exceed $125,000.
3. Duty to Mitigate
The permittee shall take all reasonable steps to minimize or prevent any discharge in violation of this
individual permit which has a reasonable likelihood of adversely affecting human health or the environment.
4. Civil and Criminal Liabilitv
Except as provided in Part Ill, Section C of this permit regarding bypassing of storrnwater control facilities,
nothing in this individual permit shall be construed to relieve the permittee from any responsibilities,
liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3, 143-215.6A, 143-215.6Q, 143-
215.6C or Section 309 of the Federal Act. 33 USC 1319. Furthermore, the permittee is re,ponsible for
consequential damages, such as fish kills, even though the responsibility for effective compliance may be
temporarily suspended.
5. Oil and Hazardous Substance Liabilitv
Nothing in this individual permit shall be construed to preclude the institution of any legal action or relieve
the permittee from any responsibilities, liabilities, or penalties to which the permittee is or may be subject to
under NCGS 143-215.75 et seq. or Section 311 of the Federal Act, 33 USC 1321. .
6. Property Rights
The issuance of this individual permit does not convey any property rights in either real or personal
property, or any exclusive privileges, nor does it authorize any injury to private property or any invasion of
personal rights, nor any infringement of Federal, State or local laws or regulations.
Severabilitv
The provisions of this individual permit are severable, and if any provision of this individual permit, or the
application of any provision of this individual permit to any circumstances, is held invalid, the application
of such provision to other circumstances, and the remainder of this individual permit, shall not be affected
thereby.
8. Duty to Provide Information
The permittee shall furnish to the Director, within a reasonable time, any information which the Director
may request to determine whether cause exists for modifying, revoking and reissuing, or terminating the
permit issued pursuant to this individual permit or to determine compliance with this individual permit. The
permittee shall also furnish to the Director upon request, copies of records required to be kept by this
individual permit.
9. Penalties for Tampering
The Clean Water Act provides that any person who falsifies, tampers with, or knowingly renders inaccurate,
any monitoring device or method required to be maintained under this individual permit shall, upon
conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more
than two years per violation, or by both. If a conviction of a person is for a violation committed after a first
conviction of such person under this paragraph, punishment is a fine of not more that $20,000 per day of
violation, or by imprisonment of not more than 4 years, or both.
Part III Page 2 of 8

Permit No. NCS000189
10. Penalties for Falsification of Reports
The Clean Water Act provides that any person who knowingly makes any false statement, representation, or
certification in any record or other document submitted or required to be maintained under this individual
permit, including monitoring reports or reports of compliance or noncompliance shall, upon conviction, be
punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years
per violation, or by both.
SECTION B: GENERAL CONDITIONS
Individual Permit Expiration
The permittee is not authorized to discharge after the expiration date. In order to receive automatic
authorization to discharge beyond the expiration date, the perrnittee shall submit forms and fees as are
required by the ageecy authorized to issue permits no later than 180 days prior to the expiration date. Any
permiuee that has not requested renewal at least 180 days prior to expiration, or any permiuee that does not
have a permit after the expiration and has not requested renewal at least 180 days prior to expiration, will be
subjected to enforcement procedures as provided in NCGS e 143-2153.6 and 33 USC 1251 et. seq. .
2. Transfers
This permit is not transferable to any person except after notice to and approval by the Director. The
Director may require modification or revocation and reissuance of the permit to change the name and
incorporate such other requirements as may be necessary under the Clean Water Act. The Permittee is
required to notify the Division in writing in the event the permitted facility is sold or closed.
3. Signatory Requirements
All applications,reports, or information submitted to the Director shall be signed and certified.
a. All applications to be covered under this individual permit shall be signed as follows:
(1) In the case of a corporation: by a principal executive officer of at least the level of vice-
president, or his duly authorized representative, if such representative is responsible for
the overall operation of the facility front which the discharge described in the permit
application form originates;
(2) In the case of a partnership or limited partnership: by a general partner;
(3) In the case of a sole proprietorship: by the proprietor;
(4) In the case of a municipal, state, or other public entity: by a principal executive officer,
ranking elected official, or other duly authorized employee.
b. All reports required by the individual permit and other information requested by the Director shall
be signed by a person described above or by a duly authorized representative of that person. A
person is a duly authorized representative only if
(1) The authorization is made in writing by a person described above;
(2) The authorization specified either an individual or a position having responsibility for the
overall operation of the regulated facility or activity, such as the position of plant
manager, operator of a well or well field, superintendent, a position of equivalent
Part III Page 3 of 8

Permit No. NCS000189
responsibility, or an individual or position having overall responsibility for environmental
matters for the company. (A duly authorized representative may thus be either a named
individual or any individual occupying a named position.); and
(3) The written authorization is submitted to the Director.
C. Any person signing a document under paragraphs a. or b. of this section shall make the following
certification:
"I certify, under penalty of law, that this document and all attachments were prepared under my
direction or supervision in accordance with a system designed to assure that qualified personnel
properly gather and evaluate the information submitted. Based on my inquiry of the person or
persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate,
and complete. 1 am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
4. Individual Permit Modification Revocation and Reissuance, or Termination
The issuance of this individual permit does not prohibit the Director from reopening and modifying the
individual permit, revoking and reissuing the individual permit, or terminating the individual permit as
allowed by the laws, rules, and regulations contained in Title 40, Code of Federal Regulations, Parts 122
and 123, Title 15A of the North Carolina Administrative Code, Subchapter 2H .0100; and North Carolina
General Statute 143-215.1 et al.
5. Permit Actions
The permit may be modified, revoked and reissued, or terminated for cause. The notification of planned
changes or anticipated noncompliance does not stay any individual permit condition.
SECTION C: OPERATION AND MAINTENANCE OF POLLUTION CONTROLS
Proper Operation and Maintenance
The permittee shall at all times properly operate and maintain all facilities and systems of treatment and
control (and related appurtenances) which are installed or used by the permittee to achieve compliance with
the conditions of this individual permit. Proper operation and maintenance also includes adequate
laboratory controls and appropriate quality assurance procedures. This provision requires the operation of
back-up or auxiliary facilities or similar systems which are installed by a permittee only when the operation
is necessary to achieve compliance with the conditions of this individual permit.
2. Need to Halt or Reduce Not a Defense
It shall not be a defense for a permittee in an enforcement action that it would have been necessary to halt or
reduce the permitted activity in order to maintain compliance with the condition of this individual permit.
3. Bypassing of Stormwater Control Facilities
Bypass is prohibited and the Director may take enforcement action against a permittee for bypass unless:
a. Bypass was unavoidable to prevent loss of life, personal injury or severe property damage; and
PartIII Page 4 of 8

Permit No. NCS000189
b. There were no feasible alternatives to the bypass, such as the use of auxiliary control facilities,
retention of stonnwater or maintenance during normal periods of equipment downtime or dry
weather. This condition is not satisfied if adequate backup controls should have been installed in
the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal
periods of equipment downtime or preventive maintenance; and
C. The permittee submitted notices as required under, Part III, Section E of this permit.
If the Director determines that it will meet the three conditions listed above, the Director may approve an
anticipated bypass after considering its adverse effects.
SECTION D: MONITORING AND RECORDS
Representative Samolinc
Samples collected and measurements taken, as required herein, shall be characteristic of the volume and
nature of the permitted discharge. Analytical sampling shall be performed during a representative storm
event. Samples shall be taken on a day and time that is characteristic of the discharge. All samples shall be
taken before the discharge joins or is diluted by any other waste stream,. body of water, or substance.
Monitoring points as specified in this permit shall not be changed without notification to and approval of
the Director.
2. Recording -Results
For each measurement, sample, inspection or maintenance activity performed or collected pursuant to the
requirements of this individual permit, the permittee shall record the following information:
a. The date, exact place, and time of sampling, measurements, inspection or maintenance activity;
b. The individual(s) who performed the sampling, measurements, inspection or maintenance activity;
C. The date(s) analyses were performed;
d. The individual(s) who performed the analyses;
e. The analytical techniques or methods used; and
f. The results of such analyses.
3. Flow Measurements
Where required, appropriate flow measurement devices and methods consistent with accepted scientific
practices shall be selected and used to ensure the accuracy and reliability of measurements of the volume of
monitored discharges.
4. Test Procedures
Test procedures for the analysis of pollutants shall conform to the EMC regulations published pursuant to
NCGS 143-215.63 et. seq, the Water and Air Quality Reporting Acts, and to regulations published pursuant
to Section 304(g), 33 USC 1314, of the Federal Water Pollution Control Act, as Amended, and Regulation
40 CFR 136.
Part III Page 5 of 8

Permit No. NCS000189
To meet the intent of the monitoring required by this individual permit, all test procedures must produce
minimum detection and reporting levels and all data generated must be reported down to the minimum
detection or lower reporting level of the procedure.
5. Representative Outfall
If a facility has multiple discharge locations with substantially identical story neater discharges that are
required to be sampled, the permittee may petition the Director for representative outfall status. If it is
established that the stormwater discharges are substantially identical and the permittee is granted
representative outfall status, then sampling requirements may be performed at a reduced number of cattails.
6. Records Retention
Visual monitoring shall be documented and records maintained at the facility along with the Stomrwater
Pollution Prevention Plan. Copies of analytical monitoring results shall also be maintained on -site. The
permittee shall retain records of all monitoring information, including all calibration and maintenance
records and all original strip chart recordings for continuous monitoring instrumentation, and copies of all
reports required by this individual permit for a period of at least 5 years from the date of the sample,
measurement, report or application. This period may be extended by request of the Director at any time.
Insnection and Ent
The permittee shall allow the Director, or an authorized representative (including an authorized contractor
acting as a representative of the Director), or in the case of a facility which discharges through a municipal
separate storm sewer system, an authorized representative of a municipal operator or the separate storm
sewer system receiving the discharge, upon the presentation of credentials and other documents as may be
required by law, to;
a. Enter upon the permittee's premises where a regulated facility or activity is located or conducted,
or where records must be kept under the conditions of this individual permit;
b. Have access to and copy, at reasonable times, any records that must be kept under the conditions of
this individual permit;
C. Inspect at reasonable times any facilities, equipment (including monitoring and control equipment),
practices, or operations regulated or required under this individual permit; and
d. Sample or monitor at reasonable times, for the purposes of assuring individual permit compliance
or as otherwise authorized by the Clean Water Act, any substances or parameters at any location.
SECTION E: REPORTING REQUIREMENTS
I. Discharge Monitoring Reports
Samples analyzed in accordance with the terms of this permit shall be submitted to the Division on
Discharge Monitoring Report (DMR) forms provided by the Director. Submittals shall be delivered to the
Division no later than 30 days from the date the facility receives the sampling results from the laboratory.
When no discharge has occurred from the facility during the report period, the permittee is required to
submit a discharge monitoring report within 30 days of the end of the six-month sampling period, giving all
required information and indicating "NO FLOW" as per NCAC T15A 0213.0506.
Part III Page 6 of 8

Pennit No. NCS000189
The permittee shall record the required qualitative monitoring observations on the SDO Qualitative
Monitoring Report (QMR) form provided by the Division, and shall retain the completed forms on site.
Qualitative monitoring results should not be submitted to the Division, except upon DWQ's specific
requirement to do so.
2. Submitting Reports
Duplicate signed copies of all reports required herein, shall be submitted to the following address:
Division of Water Quality
Surface Water Protection Section
ATTENTION: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Availability of Reports
Except for data determined to be confidential under NCGS 143-215.3(a)(2) or Section 308 of the Federal
Act, 33 USC 1318, all reports prepared in accordance with the terms shall be available for public inspection
at the offices of the Division of Water Quality. As required by the Act, analytical data shall not be
considered confidential. Knowingly making any false statement on any such report may result in the
imposition of criminal penalties as provided for in NCGS 143-215.6E or in Section 309 of the Federal Act.
4. Non-Stormwater Discharges
If the storm event monitored in accordance with this individual permit coincides with a non-stonnwater
discharge, the permittee shall separately monitor all parameters as required under the non-stonnwater
discharge permit and provide this information with the stor ma-ater discharge monitoring report.
5. Planned Changes
The permittee shall give notice to the Director as soon as possible of any planned changes at the permitted
facility which could significantly alter the nature or quantity of pollutants discharged. This notification
requirement includes pollutants which are not specifically listed in the individual permit or subject to
notification requirements under 40 CFR Part 122.42 (a).
6. Anticipated Noncompliance
The permittee shall give notice to the Director as soon as possible of any planned changes at the permitted
facility which may result in noncompliance with the individual permit requirements.
7. Bypass
a. Anticipated bypass. If the permittee knows in advance of the need for a bypass, it shall submit
prior notice, if possible at least ten days before the date of the bypass; including an evaluation of
the anticipated quality and affect of the bypass.
b. Unanticipated bypass. The permittee shall submit notice within 24 hours of becoming aware of an
unanticipated bypass.
Twenty-four Hour Reporting
The permittee shall report to the central office or the appropriate regional office any noncompliance which
may endanger health or the environment. Any information shall be provided orally within 24 hours from
Part III Page 7 of 8

Permit No. NCS000189
the time the permittee became aware of the circumstances. A written submission shall also be provided
within 5 days of the time the permittee becomes aware of the circumstances.
The written submission shall contain a description of the noncompliance, and its causes; the period of
noncompliance, including exact dates and times, and if the noncompliance has not been corrected, the
anticipated time compliance is expected to continue; and steps taken or planned to reduce, eliminate, and
prevent reoccurrence of the noncompliance.
The Director may waive the written report on a case -by -case basis if the oral report has been received
within 24 hours.
9. Other Noncompliance
The permittee shall report all instances of noncompliance not reported under 24 hour reporting at the time
monitoring reports are submitted.
10. Other Information
Where the permittee becomes aware that it failed to submit any relevant facts in an application for an
individual permit or in any report to the Director, it shall promptly submit such facts or information.
Part III Page 8 of 8

NCS000189
PART IV LIMITATIONS REOPENER
This individual permit shall be modified or alternatively, revoked and reissued, to comply with any applicable
effluent guideline or water quality standard issued or approved under Sections 302(b) (2) (c), and (d), 304(b) (2) and
307(a) of the Clean Water Act, if the effluent guideline or water quality standard so issued or approved:
a. Contains different conditions or is otherwise more stringent than any effluent limitation in the individual
permit; or
b. Controls any pollutant not limited in the individual permit.
The individual permit as modified or reissued under this paragraph shall also contain any other requirements in the
Act then applicable.
PART V ADMINISTERING AND COMPLIANCE MONITORING FEE
REQUIREMENTS
The permittee must pay the administering and compliance monitoring fee within30 (thirty) days after being billed by
the Division. Failure to pay the fee in timely manner in accordance with 15A NCAC 2H .0105(b)(4) may cause this
Division to initiate action to revoke the Individual Permit.
PART VI DEFINITIONS
Act
See Clean Water Act.
2. Arithmetic Mean
The arithmetic mean of any set of values is the summation of the individual values divided by the number of
individual values.
Allowable Non-Stormwater Discharges
This permit regulates stormwater discharges. Non-stormwater discharges which shall be allowed in the
stormwater conveyance system are:
(a) All other discharges that are authorized by a non-stormwater NPDES permit.
(b) Uncontaminated groundwater, foundation drains, air -conditioner condensate without added
chemicals, springs, discharges of uncontaminated potable water, waterline and fire hydrant
flushings, water from footing drains, (lows from riparian habitats and wetlands.
(c) Discharges resulting from fire -fighting or fire -fighting training.
4. Best Management Practices (BMPs)
Measures or. practices used to reduce the amount of pollution entering surface waters. BMPs may take the
form of a process, activity, or physical structure.
Parts IV, V and VI Page I of 5

Permit No. NCS000189
5. Bypass
A bypass is the known diversion of stormwater from any portion of a stotmtwater control facility including
the collection system, which is not a designed or established operating mode for the facility.
6. Bulk Storage of Liquid Products
Liquid raw materials, manufactured products, waste materials or by-products with a single above ground
storage container having a capacity of greater than 660 gallons or with multiple above ground storage
containers located in close proximity to each other having a total combined storage capacity of greater than
1,320 gallons.
7. - Clean Water Act
The Federal Water Pollution Control Act, also known as the Clean Water Act (CWA), as amended, 33
USC 1251, et. seq.
8. Division or DWO
The Division of Water Quality, Department of Environment and Natural Resources.
9. Director
The Director of the Division of Water Quality, the permit issuing authority
10. EMC
The North Carolina Environmental Management Commission.
11. Grab Sample
An individual sample collected instantaneously. Grab samples that will be directly analyzed or qualitatively
monitored must be taken within the first 30 minutes of discharge.
12. Hazardous Substance
Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Water Act.
13. Landfill
A disposal facility or part of a disposal facility where waste is placed in or on land and which is not a land
treatment facility, a surface impoundment, an injection well, a hazardous waste long-term storage facility or
a surface storage facility..
14. Municipal Separate Storm Sewer System
A stormwater collection system within an incorporated area of local self-government such as a city or town.
15. No Exposure
A condition of no exposure means that all industrial materials and activities are protected by a storm
resistant shelter or acceptable storage containers to prevent exposure to rain, snow, snoµmrelt, or runoff.
Industrial materials or activities include, but are not limited to, material handling equipment or activities,
Part VI Page 2 of 5 Pages

Permit No. NCS000189
industrial machinery, raw materials, intermediate products, by-products, final products, or waste products.
DWQ may grant a No Exposure Exclusion from NPDES Stormwaler Permitting requirements only if a
facility complies with the terms and conditions described in 40 CFR § 122.26(g).
16. Overburden
Any material of any nature, consolidated or unconsolidated, that overlies a mineral deposit, excluding
topsoil or similar naturally -occurring surface materials that are not disturbed by mining operations.
17. Permittee
The owner or operator issued a permit pursuant to this individual permit.
18. Point Source Discharge of Stormwater
Any discernible, confined and discrete conveyance including, but not specifically limited to, any pipe, ditch,
channel, tunnel, conduit, well, or discrete fissure from which stormwater is or may be discharged to waters
of the state.
19. Representative Storm Event
A storm event that measures greater than 0..1 inches of rainfall and that is preceded by at least 72 hours in which no
storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive
hours of no precipitation. For example, if it rains for 2 hours without producing any collectable discharge, and then
stops, a sample may be collected if a rain producing a discharge begins again within the next 10 hours.
20. Representative Outfall Status
When it is established that the discharge of stormwater runoff from a single outlall is representative of the
discharges at multiple outfalls, the DWQ may grant representative outfall status. Representative outlall
status allows the permittee to perform analytical monitoring at a reduced number of outfalls.
21. Rinse Water Discharge
The discharge of rinse water from equipment cleaning areas associated with industrial activity. Rinse
waters from vehicle and equipment cleaning areas are process wastewaters and do not include washwaters
utilizing any type of detergent or cleaning agent.
22. Secondary Containment
Spill containment for the contents of the single largest tank within the containment structure plus sufficient
freeboard to allow for the 25-year, 24-hour storm event.
23. Section 313 Water Priority Chemical
A chemical or chemical category which
a. Is listed in 40 CFR 372.65 pursuant to Section 313 of Title III of the Superfund Amendments and
Reauthorization Act (SARA) of 1986, also titled the Emergency Planning and Community Right -
to -Know Act of 1986;
b. Is present at or above threshold levels at a facility subject to SARA Title III, Section 313 reporting
requirements; and
c. That meets at least one of the following criteria:
Part VI Page 3 of 5 Pages

Permit No. NCS000189
(1) Is listed in Appendix D of 40 CPR part 122 on Table II (organic priority pollutants),
Table III (certain metals, cyanides, and phenols), or Table IV (certain toxic pollutants and
hazardous substances);
(2) Is listed as a hazardous substance pursuant to section 31 I(b)(2)(A) of the CWA at 40
CFR 116.4; or
(3) Is a pollutant for which EPA has published acute or chronic water quality criteria.
24. Severe Property Damane
Means substantial physical damage to property, damage to the control facilities which causes them to
become inoperable, or substantial and permanent loss of natural resources which can reasonably be . .
expected to occur in the absence of a bypass. Severe property damage does not mean economic loss caused
by delays in production.
25. Significant Materials
Includes, but is not limited to: raw materials; fuels; materials such as solvents, detergents, and plastic .
pellets; finished materials such as metallic products; raw materials used in food processing or production;
hazardous substances designated under section 101(14) of CERCLA; any chemical the facility is required to
report pursuant to section 313 of Title III of SARA; fertilizers; pesticides; and waste products such as ashes,
slag and sludge that have the potential to be released with stormwater discharges.
26. Sinnificant Spills
Includes, but is not limited to: releases of oil or hazardous substances in excess of reportable quantities
under section 311 of the Clean Water Act (Ref: 40 CFR 1 10.10 and CFR 117.21) or section 102 of,
CERCLA (Ref: 40 CFR 302.4).
27. StormwaterRunoff
The flow of water which results from precipitation and which occurs immediately following rainfall or as a
result of snowmelt.
28. Stormwater Associated with Industrial Activity
The discharge from any point source which is used for collecting and conveying stormwater and which is
directly related to manufacturing, processing or raw material storage areas at an industrial site. Facilities
considered to be engaged in "industrial activities" include those activities defined in 40 CFR 122.26(b)(14).
The term does not include discharges from facilities or activities excluded from the NPDES program.
29. Stormwater Pollution Prevention Plan
A comprehensive site -specific plan which details measures and practices to reduce stormwater pollution and
is based on an evaluation of the pollution potential of the site.
30. Ten Year Design Storm
The maximum 24 hour precipitation event expected to be equaled or exceeded on the average once in ten
years. Design storm information can be found in the State of North Carolina Erosion and Sediment Control
Planning and Design Manual.
Part VI Page 4 of 5 Pages

Permit No. NCS0001 89
31. Total Flow
The flow corresponding to the time period over which the entire storm event occurs. Total flow shall be
either; (a) measured continuously, (b) calculated based on the amount of area draining to the outfall, the
amount of built -upon (impervious) area, and the total amount of rainfall, or (c) estimated by the
measurement of flow at 20 minute intervals during the rainfall event.
32. Total Maximum Daily Load !TMDL)
A TMDL is a calculation of the maximum amount of a pollutant that a waterbody can receive and still meet
water quality standards, and an allocation of that amount to the pollutant's sources. A TMDL is a detailed
water quality assessment that provides the scientific foundation for an implementation plan. The
implementation plan outlines the steps necessary to reduce pollutant loads in a certain body of water to
restore and maintain water quality standards in all seasons. The Clean Water Act, Section 303, establishes
the water quality standards and TMDL programs.
33. Toxic Pollutant
Any pollutant listed as toxic under Section 307(a)(1) of the Clean Water Act.
34. Unset
Means an exceptional incident in which there is unintentional and temporary noncompliance with
technology based permit effluent limitations because of factors beyond the reasonable control of the
permittee. An upset does not include noncompliance to the extent caused by operational error, improperly
designed treatment or control facilities, inadequate treatment or control facilities, lack of preventive
maintenance, or careless or improper operation.
35. Vehicle Maintenance Activity
Vehicle rehabilitation, mechanical repairs, painting, fueling, lubrication, vehicle cleaning operations, or
airport deicing operations. -
36. Visible Sedimentation
Solid particulate matter, both mineral and organic, that has been or is being transported by water, air,
gravity, or ice from its site of origin which can be seen with the unaided eye.
37. 25-year, 24 hour storm event
The maximum 24-hour precipitation event expected to be equaled or exceeded, on the average, once in 25
years.
Part VI Page 5 of 5 Pages

r / ,
' \ 1
Domtar
It all begins with paper.'
Domtar Paper Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
T 252793-6111
www.domtar.com
August 3, 2010
Mr. Al Hodge
Division of Water Quality
NC Department of Environment and Natural Resources
943 Washington Square Mall
Washington, NC 27889
Mr. Brian Lowther
Certified Mail
Return Receipt Reptrested
Wetland and Stormwater Branch r "• ��
Division of Water Quality
NC Department of Environment and Natural Resources
1617 Mail Service Center
Raleigh, NC27699-1617
Subject: Request to Remove Dioxin Sarupling/Aa ilyses RegWrentent front Permit
Douttar Paper Company, LLC - Plymouth, North Carolina
NPDES Stormwater Permit # NCS000189
Enclosed you will find the laboratory results for the soil samples collected for dioxin
(2, 3, 7, 8 TCDD) analysis. Per our previous conversation, we picked four locations
closest to Welch Creek which included Winter Log Storage (WLS), Old Borrow Area
(PB01), External Coal Yard (CP01), and Norfolk Southern Rail Yard (RY01). These
locations were chosen since soils around these outfills could be influenced by flood
waters from Welch Creek, a remetliation site for dioxins that were historically discharged
(prior to 1988) via NPDES permits in the creek sediments. Of the four locations sampled,
dioxin was detected at only one outfall, WLS at a concentration of 0.704 J, K(I) ng/kg,
which is a highly qualified, estimated value, below the method reporting limit and
quantifiable level of the testing procedure. This estimated concentration is considered
extremely small when compared to the preliminary remediation goal for dioxins in
residential soil established by the EPA, which is 1000 ng/kg.
As we discussed with Al dodge of DWQ earlier this summer, with the potential
exception of soils along a limited portion of the shores along Welch Creek, soils in and
around the Domtar-Plymouth site are not susceptible to dioxin contamination since any
(1) K typically is assigned when the detection limit may be elevated due to the presence of an unrequested analyte.
During data validation process, a "u" would be assigned when laboratory reported detection deemed not valid during
data validation process. This result should be considered not valid and would have a u flag after data validation. The
"7" flag designates that the reported concentration is estimated.

dioxin generated from historical chlorine bleaching operations was discharged through
closed process sewers, into the wastewater treatment system and then into Welch Creek.
Further, as detailed in our most recent stormwater permit renewal application request,
dated April 24, 2006, all process sewers and stormwater runoff from the industrial
footprint of the facility drains to the onsite wastewater treatment system and not offsite to
adjacent wetlands, surface waters or forests.
We have completed the second round of stormwater outfall monitoring for dioxin from
which all results were non -detect, just as with the first round of sampling. That set of
stormwater dioxin analyses has been included with this transmittal.
In consideration of this additional data, Domtar requests that the Division of Water
Quality remove the requirement to sample and analyze for dioxin from each of the
permitted outfalls listed in our stormwater permit.
If you have any questions or require any additional information pertaining to the
information provided, please contact me by phone, [phone] or by email,
tamika.booneCiDdomtar.com.
Sincerely,
Tamika Boone
Environmental Engineer
(1) K typically is assigned when the detection limit maybe elevated due to the presence of an unrequested analyte.
During data validation process, a "u" would be assigned when laboratory reported detection deemed not valid during
data validation process. This result should be considered not valid and would have a u flag after data validation. The
"J" flag designates that the reported concentration is estimated.

K:\NPDES\NPDES\NCG - NPDES Inspections - Tracking - General\NCG - NPDES Rescission Requests\NCG - Recission Requests - Original Re q uest from Raleigh
Click on the hyperlink above to see the original notification from Raleigh. The form below has been created due to the original being in pdf format.
Comments
RO
Appl.
Comments
due back
Inspection
Comments
Issued
Expired
Comment
Permit No.
Owner Name / Facility
County
SPU Staff
Rec'v. SPU
Req. to RO
to SPU
Date
Submitted
Draft Date
Date
Date
Inspector
Submitted
Comments
gave me a tour of the facility. I did not see any area of concern. Prior to leaving, I emphasized the
Universal Forest Products Inc
Thom
NCS000336
- Eastern Division - E. City
Pasquotank
Lowther
11/24/2008
1/1/2009
2/1/2009
2/11/2009
Edgerton
Y
importance of SW management, due to their location along Knobbs Creek. (Just a Note) - I mentioned
Loxco - Airgas National
Thom
i uto not 5ee any areas of major concern. i oia not see a second ourfall and RoBble una5e, Plant
Manager, [phone] said that he was unaware of more than just the one outfall at the NE corner of
the property (roadside ditch along Hinnant Rd.) The Lime ponds are still in use, but were said to be in
NCS000043
Welders, Inc.
Wayne
Jones
12/10/2008
3/5/2009
1
1
Edgerton
Y
the process of being taken out of service and changing to a recycle system. There was no obvious
practices is that the storm water ditches are used as fore bays for the storm water ponds. NuCor has
NCS000379
Nucor Steel
Hertford
5/20/2009
Travis Smith
Y_
permit with the Army Corps of Engineers for a created wetlands that receives water from the C1 pond.
Thom
NCS000372
BMCA Goldsboro Inc.
Wayne
Lowther
2/19/2009
Edgerton
Response letter from Domtar received on
8/3/2010 regarding removing dioxin
sampling/analyses requirements from permit -
lab results for soil samples submitted with
NCS000314
Marine Corps Air Station
Craven
Randall
letter
NGS000189
Domtar Paper Company LLC
Plymouth
Martin
Lowther
11/5/2008
4/9/2009
5/26/2009
Travis Smith
Y
ennrt specrticadons. I he taallty puts signs up idanntymg
map. The signs also tell who to contact in case of a spill and which
waterway d will drain into. Another good practice the facility uses, is when a landfill is closed they each
Seymour Johnson Air Force
NCS000335
Base
Wayne
I visited the site along with Brian Lowther and Cory Larsen. Dave Gardner drove us on a site tour, that
Thom
was very informative, of the facilities operation, highlighting all environmental operations. The purpose
NCS000211
Weyerhaeuser Company
Craven
Lowther
12/5/2008
8/5/2009
8/31 /2009
2/5/2009
8/26/2009
Edgerton
Y
of the visit was to better understand the processes while creating a draft for the new permit is being
NGS000377
Green Thumb of NC LLC
Hyde
Hendrix and Dail, Inc. / Ricky
Thom
I am to create questions for Mr. Al and myself to ask Steve Tedder [phone] and Myd Nisely (919)
791-4255. 1 called Cory Larsen [phone] and he email me the new date that our comments are
NCS000509
Keck
Pitt
Pickle
5/22/2009
3/25/2009
9/22/2009
Edgerton
Y_
due back (May 22, 2009). 1 mentioned that this would likely be a good site for the centeral office staff to
EJE Solid Waste Transfer
Station and Recycling Facility
NCG130059
/ Judson Whitehurst
Pitt
Larsen
9/28/2009
10/28/2009
10/8/2009
Bill Whom

Help Desk -Marketplace User Agreement I eCampus.com I Textbooks -Easy. Fast. Cheap! Page 5 of 5
A1Mine Pmgom ecampgs Blog emer"rams snap eysmea l`MtANeSKUNE'
E,Oma Catalog e0ampus Emounge Prlvary Polity Site Seounty
Bal vxl4p k Carotene Help Deal, Rent Textbooks Site Me, TLSTLg ONLY Il -QG
Buy Textolooks Link to Us Realm Polley Terms B C.Itbns
College Apparel Mvkstgaee let Sall TextEoOb NrWal BookCues
�san� ConGq Us MNia 9iippng Rates
Need Help?s.SSCke�ss3mPYi3tl11 CaPYdhM1909-2010
t
t
Help Desk -Marketplace User Agreement eCampus.com Textbooks -Easy. Fast. Cheap! Page 4 of 5
' r
-7)-.? -pry-PW i
http://www.ecampus.com/help/marketplace-user-agreement.asp 8/11 /2010

�� Columbia
Analytical Services- 9143 Philips Highway, Suite 200 1 Jacksonville, FL 32256I 904-739-2277 904-739@011 fax ww
w.casab.com
June 09, 2010
Diane Hardison
Domtar Paper Company, LLC
11.0. Box 747
Plymouth, NC 27962
Laboratory Results for: Special Dioxin Testing
Dear Diane:
Service Request No: J1002252
Enclosed are the results of the sample(s) submitted to our laboratory on May 13, 2010. For your
reference, these analyses have been assigned our service request number J1002252.
All analyses were performed according to our laboratory's quality assurance program. The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc.
(CAS) is not responsible for use of less than the complete report. Results apply only to the items
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report.
Please contact me if you have any questions. My extension is 4408. You may also contact me
via email at TKissinger cr caslab.com:
Respectfully submitted,
Columbia Analytical Services, Inc.
Tom Kissinger
Project Manager
Page 1 of
CAS Jacksonville is NELAC-accredited by the State of Florida, #E82502. Other state accreditation
include: Georgia, 4958; Kentucky, #63; Louisiana, 902086, North Carolina, 9527; South Carolina,
996021001, Texas, #T104704197-09-TX

Client Domtar Paper Companv, LLC
Project Special Dioxin Testing
SAMPLE CROSS-REFERENCE
Service Request: J1002252
SAMPLE #
CLIENT SAMPLE ID
DATE
TIME
J1002252-001
Winter Log Storage
5/12/10
07:42
J1002252-002
PBOI (Old Borrow)
5/12/10
08:03
J 1002252-003
Coal -Yard
5/12/10
07:52
J1002252-004
Railyard
5/12/10
07:47
2
Tinted 6/9/10 9:26 Sample Summary Page I of I

Oki CnI Ow,
Columbia Analytical Services, Inc.
t—ooter t<ecetpt roan
Client 1(YiTo (Z, Service Request
Project: GCtC C)XIll) -Fe (t
Cooler received on and opened of O by _
COURIER: CAS UP) FEDEX Client Other Airbill # F7 gir3(? 3MOA
1
Were custody seals on outside of cooler?
Yes
If yes, how many and where?
q; l
2
Were seals intact and signature and date correct?
es
3
Were custody papers properly filled out?
4
Temperature of cooler(s) upon receipt (Should be 4 +/- 2 degrees C) Ot /
5
Thermometer ID r b
6
Temperature Blank Present?
Yes
7
Were Ice or Ice Packs present
ce
8
Did all bottles arrive in good condition (unbroken, etc...)?
Ycs
9
Type of packing material present
10
Were all bottle labels complete (sample ID, preservation, etc....)?
Yes
1 1
Did all bottle labels and tags agree with custody papers?
Yc
12
Were the correct bottles used for the tests indicated?
13
Were all of the preserved bottles received with the appropriate preservative?
Yes
HNO3 pH<2 H2SO4 pH<2 ZnAC2/NaOH pH>9 NaOH pH> 12
HCl pH<2
Preservative additions noted below
14
Were all samples received within analysis holding times?
15
Were VOA vials checked for absence of air bubbles? If present, note below
Yes
16
Where did the bottles originate?
/CC
No
on li other
No N/A
No N/A
No
Ice Packs No
No N/A
No
No
No
No
No
No
Client
Sample ID Reagent Lot # nil added Initials Date/Time
comments and/or explanation of all discrepancies noted above:
N/A
N/A
N/A
NiA
Client approval to run samples if discrepancies noted:
Date:
3

Columbia
Jacksonville Laboratory
LS"iitlyi"" l Condition Upon Receipt - Sample pH
^Y sR a : l ocas Dater 1 3) �V Initials'.
Note that pH is check and meets the required pH criterion listed in the column heading unless otherwise noted on the cooler receipt form.
Eo
-001
.002
.003
-004
-005
-006
.007
-008
-009
-010
-011
-012
-013
-014
-015
-016
-017
-018
-019
-020
-021
.022
-023
-024
-025
-026
027
-028
-029
-030
.031
-032
-033
-034
035
�036
-037
-038
-039
-040
�0000000000000000000000000000_0®
®MNS
OM
®®®`
me
iaa�vaevaae�veeeeeeveea�e���ee�e
_-
----------__-_____--M_-
-001
{ 02
003
004
005
006
007
008
009
010
011
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
030
031
032
033
034
035
036
037
038
039
040
NOTE: VOA pH checks are performed by the analytical area, not sample control

*0
an Columbia CHAIN OF CUSTODY / LABORATORY ANALYSIS REQUEST FORM
Analytical
Services M 9143 phd Highway, Sti a 200 Jacksonville, Florida 32256'Phmrc(904)739 2277/800 695-7227 Fax [phone] [ Page
,...o vl
www.esdeD.mm
SR#
S/r�Sz
CAS Contact
Project Narne
Special Dioxin Testing
Protect Number
ANALYSIS
REQUESTED
(Include
Method
Number
a
Fre+e^'
0
Report To
Diane Hardison
Report CC
Alan Barnes
W
W
'0
'p
0. None
1. HCL
2. HNO3
3. H2SO4
4. NaOH
5. Zn. Acetate
6. McOH
7.NaH504
REMARKS
Company/Address
mtar Paver Coin
P.O. Box 747
Plymouth, NC 27962
phone #
252-793-8611
FAX #
252-793-8871
Sampler's Siguatme
Sampler's Printed Name
CLIENT SAMPLE ID
LAB ID
SAMPLING
DATE TYKE
Matrix
Winter Log Storage
Dioxin
5/12/10
7:42 AM
Soil
1
X
PBOI Old Borrow
Dioxin
5/12/10
9:03 AM
Soil
I
X
Coal -Yard
Dioxin
5/12/10
7:52 AM
Soil
I
X
Rail and
Dioxin
5/12110
7:47 AM
Soil
I
X
Special Testing of Soil for Dioxin.
u""OUND"QUIUMEwrs
VRU� (aURCRAROFJ APPL»
ATRIV.
RRPORT DAT6
"PORT RxQUlitxmx a
1.R +QOet
n. Rem. � Qc sonu,mm
MCs. DVP. MMIDIII. Rn r QC and CWaf0lm Munnate
a a VYNmaa Report wan R Daa
daa Ya NO
INVOICx INFORMATION
P.o. s fo�3/Fly
to
Rcterclumoca ut
Sign J
Recarml by
Signal—
Relvaciteshod By
Signature
lane
Rerm=q By
Signature
Recervod By
Signature
F� e / �GtNiL��^ J^+�
Printed
Name )
Pnnk sane
Printed Name
mn
rm
Fum ,nS
Fnm
Firm
et 7
0 ,6
Da arts
arts
D �T//O 0,7
arts
Da we

4SColumbia
Analytical
Services -
Appendix A
Columbia Analytical Services
9143 Philips Highway, Suite 200
Jacksonville, FL 32256
Tel [phone]
Fax [phone]
Subcontracted Analytical Results
0

Columbia 1
4fAS
Analytical Services- 19408 Park Row, Suite 320, Houston, TX 77084 1 713.266.1599 f www.caslab.com
June 8, 2010
Tom Kissinger
Columbia Analytical Services
9143 Philips Hwy, Suite 200
Jacksonville, FL 32256
Service Request No: J 1002252
Laboratory Results for: Domtar Paper Company, LLC/Special Dioxin Testing
Dear Tom:
Enclosed are the results of the sample(s) submitted to our laboratory on May 14, 2010. For your
reference, these analyses have been assigned our service request number J1002252.
Analyses were performed according to our laboratory's NELAP-approved quality assurance
program. The test results meet requirements of the current NELAP standards, where applicable,
and except as noted in the laboratory case narrative provided. All results are intended to be
considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for
use of less than the complete report. Results apply only to the items submitted to the laboratory
for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the
NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any
quantitative analysis will be supplied upon request.
Please contact me if you have any questions. My direct line is 281-994-2954. You may also
contact me via email at [e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
vl�
Darren Biles
Project Manager
For a specific list of NELAP-accredited analytes, refer to the certifications section at wivw.caslab.conf.
An Employee Owned Company L NELAPAccredited il ACIL Seal of Excellence Award J Please consider the environment before printing 17
J1002252 1 of 27
7

t-.
Service's -
Certificate of Analysis
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.casiab.com
J1002252 2 of 27
g

COLUMBIA ANALYTICAL SERVICES, INC
Client: Domtar Industries
Project: Special Dioxin Testing
Sample Matrix: Soil
CASE NARRATIVE
Service Request No.: J1002252
Date Received: 5/14/10
All analyses were performed in adherence to the quality assurance program of Columbia Analytical Services, Inc.
(CAS). This report contains analytical results for samples designated for Tier II. When appropriate to the method,
method blank results have been reported with each analytical test.
Sample Receipt
Four soil samples were received for analysis at Columbia Analytical Services on 5114110.
The samples were received at I°C in good condition and are consistent with the accompanying chain of custody
form. The samples were stored in a refrigerator at 40C upon receipt at the laboratory.
Please note the reporting forms are currently referencing the date CAS- Jacksonville received the samples (5/13/10)
and not the date CAS -Houston received the samples (5/14/10.)
Data Validation Notes and Discussion
MS/DMS
EQ1000252: Laboratory Control Spike/Duplicate Laboratory Control Spike (LCS/DLCS) samples were analyzed
and reported in lieu of an MS/DMS for this extraction batch. The batch quality control criteria were met.
K B:tes
CAS/Houston reports EMPC results that comply with Section 1 1.2.6 of the DLM02.2 SOW. An EMPC result is
Flagged with a'K' Flag.
Detection Limits
Detection limits are calculated for each congener in each sample by measuring the height of the noise level for each
quantitation ion for the associated labeled standard. The concentration equivalent to 2.5 times the height of the
noise is then calculated using the appropriate response factor and the weight of the sample. The calculated
concentration equals the detection limit.
Approved by:
r
Xiangqiu Liang, Laboratory Director
Date: 06 / 0 8 / 10
J1002252 3ot 27
9

4
' Client: Donatar Paper Company, LLC Service Request: J1002252
Project: Special Dioxin Testing
SAMPLE CROSS-REFERENCE
SAMPLE ;
CLIENT SAMPLE ID
DATE
TIME
J1002252-001
Winter Log Storage
5/12/10
07:42
J1002252-002
PB01 (Old Borrow)
5/12/10
O8:03
J1002252-003
Coal -Yard
5/12/10
07:52
11002252-004
Railyard
5112/10
07:47
J1002252 4 of 27
Pnnl.d filril l0 9) 27 Salnple Summary 10 Page I of I

Laboratory Certifications
2010-2011
STATE/PROGRAM
AGENCY
CERTIFICATION ID
EXP DATE
ARIZONA
AZ-DHS
AZ0725
05/27/11
ARKANSAS
ADE
09-048-0
06/16/10
CALIFORNIA
CA-ELAP
2452
02/28/11
DOD ELAP
A2LA
2897.01
11/30/11
FLORIUA/NELAP
FL -DOHS
E87611
06/30/10
HAWAII
HI -DOH
N/A
06/30/10
ILLINOWNELAP
IL -EPA
002380
10/06/10
IS017025
A2LA
2897.01
11/30/11
LouISIANA/NELAP
LELAP
03048
06/30/10
LoUISIANA/NELAP
LDHH
LA100032
12/31/10
MAINE
ME -DOHS
2008031
06/05/10
MICHIGAN
MIDEQ
9971
06/30/10
N71N'NFSOTA
MDH
048-999-427
12/31/10
NEVADA
NDEP
TX014112010A
07/31/10
NEW JERSEY
NJDEP
TX008
06/30/10
NEW NIEXICO
NMED-DWB
N/A
06/30/10
NEWYORK/NELAP
NY -DOH
11707
04/01/11
OKLAHOMA
OKDEQ
2009-25
08/31/10
OREGON/NELAP
ORELAP
TX200002-006
03/24/10
PENNSVLVANIA/NELAP
PLAP
002
06/30/11
TENNESSEE
TNDEC
04016
06/30/10
Texas/NELAP
TCEQ
T104704216-09-TX
06/30/16
UTAH/NELAP
UTELCP
COLU2
06/30/10
SOIL IMPORT PERMIT
USDA
P330-09-00067
03/27/12
WASHINGTOWNELAP
WA-Ecolo
C1855
11/14/10
WESTVIRGINIA
WVDEP
347
06/30/11
J1002252 5o(27

6
Abbreviations, Acronyms & Definitions
Cal
Calibration
Conc
CONCentration
Dioxin(s)
Polychlorinated dibenzo-p-dioxin(s)
EDL
Estimated Detection Limit
EMPC
Estimated Maximum Possible Concentration
Flags
Data qualifiers
Furan(s)
Polychlorinated dibenzofuran(s)
g
Grams
ICAL
Initial CALibration
ID
IDentifier
Ions
Masses monitored for the analyte during data acquisition
L
Liter (s)
LCS
Laboratory Control Sample
DLCS
Duplicate Laboratory Control Sample
MB
Method Blank
MCL
Method Calibration Limit
MDL
Method Detection Limit
MRL
Method Reporting Limit
mL
Milliliters
MS
Matrix Spiked sample
DMS
Duplicate Matrix Spiked sample
NO
Number of peaks meeting all identification criteria
PCDD(s)
Polychlorinated dibenzo-p-dioxin(s)
PCDF(s)
Polychlorinated dibenzofuran(s)
ppb
Parts per billion
ppm
Parts per million
ppq
Parts per quadrillion
ppt
Parts per trillion
CIA
Quality Assurance
QC
Quality Control
Ratio
Ratio of areas from monitored ions for an analyte
%Rec.
Percent Recovery
RPD
Relative Percent Difference
RRF
Relative Response Factor
RT
Retention Time
RRT
Relative Retention Time
SDG
Sample Delivery Group
S/N
Signal -to -Noise ratio
TEF
Toxicity Equivalence Factor
TEQ
Toxicity Equivalence Quotient
J1002252 6 of 27
12

7
Data Qualifier Flags — Dioxin/Furans
o B Indicates the associated analyte is found in the method blank, as well as in the sample.
o C Confirmation of the TCDF compound: When 2378-TCDF is detected on the DB-5 column,
confirmation analyses are performed on a second column (DB-225). The results from both the
DB-5 column and the DB-225 column are included in this data package. The results from the
DB-225 analyses should be used to evaluate the 2378-TCDF in the samples. The confirmed
result should be used in determining the TEQ value for TCDF.
o E Indicates an estimated value —used when the analyte concentration exceeds the upper end of
the linear calibration range.
o J Indicates an estimated value —used when the analyte concentration is below the method
reporting limit (MRL) and above the estimated detection limit (EDL).
o K EMPC -When the ion abundance ratios associated with a particular compound are outside the
QC limits, samples are flagged with a'K' flag. A'K' flag indicates an estimated maximum
possible concentration for the associated compound.
o U Indicates the compound was analyzed and not detected.
o Y Samples that had recoveries of labeled standards outside the acceptance limits are flagged
with'Y'. In all cases, the signal-to-noise ratios are greater than 10:1, making these data
acceptable.
o ND Indicates concentration is reported as 'Not Detected.'
o s Peak is saturated; data not reportable.
o P Indicates chlorodiphenyl ether interference present at the retention time of the target
compound.
o Q Lock -mass interference by chlorodiphenyl ether compounds.
J1002252 7 of 27
13

COLUMBIA ANALYTICAL SERVICES, INC. — Houston
Data Processing/Form Production and Peer Review Signatures
Unique. ►D B-Octyl
yy First iiye1,-Data,Prgcessjn b yperson:geneiatmgtheforms r<rFti ,:1
g :'`=.to be filled
J1002252 8 of 27

J1002252 9 of 27
15

COLUMBIA ANALYTICAL SERVICES, INC
10
Analytical Report
Client:
Domtar Industries
Service Request:
/1002252
Project:
Special Dioxin Testing
Date Collected:
5/12/10 0742
Sample Matrix:
Soil
Date Receired:
5/13/10
Sample Name:
Winter Log Storage
Units:
ng/Kg
Lab Code:
J1002252-001
Basis:
Dry
Percent Solids:
83.7
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans
by IIRGC/DRIYIS
Analytical Method:
1613B
Date Analyzed:
5/28/10 1224
Prep Method:
Method
Date Extracted:
5/22/10
Sample Amount:
12.933g
Instrument Name:
E-HRMS-04
GC Column:
DB-5
Data File Name:
P207823
Blank File Name:
P207807
]CAL Date:
01/15/10
Cal Ver. File Name:
P207821
[on
Dilution
Anal7te Name
Result Q
EDI, MRL
Ratio
RRT Factor
2,3,7,8=I'CDD
0.704 JK
0.0510 0.924
0.64
1,000 1
Spike
Cone.
Control
Ion
Labeled Compounds
Cone.(pg)
Found (pg) %Bee Q
Limits
Ratio RRT
13C-2,3,7,8-TCDD
2000
1155.997 58
25-164
0.79 1.009
37CI-2,3,7,8-TCDD
1600
1054. 126 66
35-197
NA 1.009
Cummenls:
Prinled6/9110 9,11
Form IA
\\Inllow2\Sindin�s\Limsl4p.c\Analyiocantc
wn. ryi
Super5el 0.<fercnce: In-OOOOId5156
rtv 0e
J1002252
10 of 27
16

COLUMBIA ANALYTICAL SERVICES, INC.
11
Analytical Report
Client:
Domtar Industries
Service Request:
J1002252
Project:
Special Dioxin 'I esting
Date Collected:
5/12/100803
Sample Matrix:
Soil
Date Receivcd:
5/13/10
Sample Name:
PB01 (Old Borrow)
Units:
ng/Kg
Lab Code:
J1002252-002
Basis:
Dry
Percent Solids:
58.5
Polychlorinated Dibenzndioxins and Polychlorinated Dibenzofurans by HRGC/HRDIS
Analytical Method:
1613B
Date Analvzed:
5/28/10 1313
Prep ltlethod:
Method
Date Extracted:
5/22110
Sample Amount:
18.661g
Instrument Name:
E-HRMS-04
GC Column:
DB-5
Data File Name:
P207824
Blank File Name:
P207807
ICAL Date:
01/15/10
Cal Ver. File Name:
P207821
Ion Dilution
An:dyte Name
Result Q
EDL MRL Ratio RRT Factor
2,3,7,8-TCDD ND U 0.0614 0.916
Spike Conc. Control Ion
Imbeled Compounds Conc.(pg) Found (pg) %Rea Q Limits Ratio RRT
13C-2,3,7,8-TCDD 2000 1143.825 57 25-164 0.79 1.008
37C'I-2,3,7,8=I'CDD 1600 1011.281 63 35-197 NA 1.010
Cpa.ment,
Pdined OW10 9.11 Fomr IA
\\InaowlVmLlnssLLimsRepsUnalyilca)Repon.Su,,ses Reference I D 0000145156 rev 00
J1002252 11 of 27
17

COLUMBIA ANALYTI CAI, SERVICES, INC.
1z
Analytical Report
Client:
PI ojec l:
Sample Matrix:
Sample Name.
Lab Code.
Domtar Industries
Special Dioxin Testing
Soil
Coal -Yard
J 1002252-003
Service Request: J1002252
Date Collected: 5/12/10 0752
Date Received: 5/13/10
Units: ng/Kg
Basis: Dry
Percent Solids: 38.6
Polychlorinated Dihenzodioxins and Polychlorinated Dibenzofurans by HRGC/IIRMS
Analytical Method:
1613B
Date Analyzed:
5/28110 1401
Prep Method:
Method
Date Extracted:
5/22/10
Sample Amount:
144197g
Instrument Name:
E-HRMS-04
GC Column:
DB-5
Data File Name:
P207825
Blank File Name:
P207807
ICU- Date:
01/15/10
Cal Vcr. File Name:
P207821
ton Dilution
Analyte Name
Result Q EDL MRL Ratio RRT Factor
2,3,7,9-TCDD ND U 0.0601 1.82
Spike
Colic.
Control
lull
LabOrd Campnunds
Cunc.(pg)
Found (pg) /.Bee Q
Limits
Ratio RRT
13C-2,3,7,8-TCDD
2000
1330.991 67
25-164
0.78 1.008
37CI-2,3,7,8-TCDD
1600
1132.493 71
35-197
NA 1.009
cnmmenl,:
Printed &VIO 9.11 Form IA
\kIrmow2ntmlimsLLims s"nalytiu Rewn rpr Sr,,r'si Refttence: 10.0000145156 rw DO
J1002252 12 of 27
18

COLUMBIA ANALYTICAL SERVICES, INC.
13
Analytical Report
Client:
Donuar Industries
Service Request:
J1002252
Project:
Special Dioxin Testing
Date Collected:
5/12/10 0747
Sample Matrix:
Soil
Date Received:
5/13/10
Sample Name:
Railyard
Units:
ng/Kg
Lab Code:
J1002252-004
Basis:
Dry
Percent Solids:
58 4
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by HRCC/1112bIS
Analytical Method:
1613B
Date Analyzed:
5/28/10 1450
Prep Method:
Method
Date Extracted:
5/22/10
Sample Amount:
16.130g
Instrument Name:
E-HRMS-04
CC Column:
DB-5
Data File Name:
P207826
Blank File Name:
P207807
ICAL Date:
01/15/10
Cal Ver. File Name:
P207821
Ion Dilution
Analyle Name
Result Q
EDL MRL Ratio RRT Factor
2,3,7,8=TCDD ND U 0.0201 1.06 1
Spike Cone. Control Ion
Labeled Compounds Cone.(pg) Found (pg) %Bee Q Limits Ratio RRT
13C-2,3,7,8-TCDD 2000 1085.560 54 25-164 0.77 1.008
37CI-2,3,7,8-TCDD 1600 1141.248 71 35-197 NA 1.010
C... -n'nw
Primed 6/8/10 9:11 F.1A
\\InnewRSiulimsVimsRepa nLpicalRepan. Mi SuperSel Rdamce', IOLO00143156 rev 0a
J10UM 13 of 27
19

COLUMBIA ANALYTICAL SERVICES, INC
14
Analytical Report
Client:
Domtar Industries
Service Request:
J1002252
Project:
Special Dioxin Testing
Date Collected:
NA
Sample Matrix:
Soil
Date Received:
NA
Sample Name:
Method Blank
Units:
ng/Kg
Lab Code:
EQ1000252-01
Basis:
Dry
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by FIROC/DRMS
Analytical Method:
1613B
Date Analyzed:
5/27/10 1916
Prcp Method:
Method
Date Extracted:
5/22/10
Sample Amount:
10.000g
Instrument Name:
E-II12MS-04
CC Column:
DB-5
Data File Name:
P207807
Blank File Name:
P207807
ICAL Date:
01/15/10
Cal Ver. File Name:
P207805
Ion Dilution
Analyze Name
Result Q
EDL MRL Ratio RRT Factor
2,3,7,8-TCDD ND U 0.0358 1.00
Spike
Cone.
Control
Jon
Labeled Compounds
Cone-(pg)
Found (pg) %Rec Q
Limits
Ratio RRT
13C-2,3,7,8-TCDD
2000
1299,090 65
25-164
0.80 1,009
37CI-2,3,7,8-TCDD
1600
1001.060 63
35-197
NA 1.009
Cnnuncnn:
Printed 6/R/lo 9:11 Fomt IA
\llnnoxQlSurlimsLLimzRrysbinalyiicalRqurtrpt SuperSa Reference'. 10-0000145156 rev 00
J1002252 14 of 27
20

15
Columbia
640W'.i.
Accuracy and Precision
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.casiab.com
An Emalovee Owned Comaanv
J1002252 15 of 27
21

Client:
PI of cct:
Sample Matrix:
Analytical Method:
Prep Method:
COLUMBIA ANALY'QCAL SERVICES, INC.
QA/QC Report
Dormar industries
Special Dioxin Testing
Soil
Service Bequest:/1002252
Date Analyzed: 5/28/10
Lab Control Sample Summary
Polvchlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRGC/URMS
1613R Units: ng/Kg
Method B D
Lab Control Sample
EQ1000252-02
Analyle Name Result Expected % Rec
2,3,7,9--'fCDD 21.9 20.0 109
Con,ntemv
s as. ry
Extraction Lot: 111716
Duplicate Lab Control Sample
EQ1000252-03 % Rcc RPD
Result Expected % Rcc Limits RPD Limit
20.4 20.0 102 67 - 158 7 50
Pti nwd 619/10 9:16 Leb Control Swnple Summwy
Nnnow2lStarlimlLiniskM . ControlSampleMt So,,Sa Ndertncc 1P00001E5156«v 00
J1002252 16 of 27
22

COLUMBIA ANALYTICAL SERVICES, INC.
17
Analytical Report
Client:
Domlar Industries Service Request:
J1002252
Project:
Special Dioxin Testing Dute Collected:
NA
Sample INlatrlx:
Soil r Date Received:
NA
Sample Name:
Lab Control Sample Units:
ng/Kg
Lab Code:
EQI000252-02 Basis:
Dry
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by HRGC/FIRMS
Analytical Method:
1613E
Date Analyzed:
5/28/10 0410
Prep Method:
Method
Date Extracted:
5/22/10
Sample Amount:
10.000g
Instrument Name:
E-IRMS-04
GC Column:
DH-5
Data File Name:
P207818
Blank File Name:
P207807
IC\L Date:
01/15/10
Cal Ver. File Name:
P207805
Ion Dilution
Analyte Name
Result Q EDL MRL Ratio RRT Factor
2,3,7,8-TCDD 21.9 0,0382 1.00 0.78 L001 1
Spike
Conc.
Control
Ion
labeled Compounds
Conc.(pg)
Found (pg)
%Rcc Q
Limits
Ratio
RRT
13C-2,3,7,8-TCDD
2000
1288.752
64
20-175
0.78
1.009
37CI-2,3,7,8-TCDD
1600
977.725
61
31-191
NA
1.010
Cmvn<ms:
Rimed 6/8/10 9:11
1. IA
OlnOowE�SudimsLLimsReeps\Awly�icalRepnn mr
SuperSct Resttmn .
10.0000145156 rev 00
J1002252
17 of 27
23

COLUMBIA ANALYTICAL SERVICES, INC.
18
Analytical Report
Client:
Domlar Industries
Service Request:
J1002252
Project:
Special Dioxin Testing
Date Collected:
NA
Sample Matrix:
Soil
Date Received:
NA
Sample Name.
Duplicate Lab Control Sample
Units:
ng/Kg
Lab Code:
EQ1000252-03
Basis:
Dry
Pulychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRGC/IIRMS
Analytical Method:
1613B
Date Analyzed:
5/28/10 0458
Prep Method:
Method
Date Extracted:
5/22/10
Sample Amount:
IoMog
Instrument Name:
E-HRMS-04
GC Column:
DD-5
Data File Name:
P207819
Blank File Name:
P207807
ICAL Date.
01/15/10
Cal Ver. File Name:
P207805
Ion Dilution
Analyze Name
Result Q FDL MRI, Ratio RRT Factor
2,3,7,8-1 CDD
20.4
0,0549
1.00
0.75 1.001 1
Spike
Conc.
Control Ion
Labeled Compounds
Cone(pg)
Found (pg)
%Bee Q
Limits Ratio RRT
13C-2,3,7,8-TCDD 2000 1384.868 69 20-175 0.78 1M9
37CI-2,3,7,8-TCDD 1600 1029,755 64 31-191 NA 1.010
Conunutn:
Printed rvw in 9:11 Fonn 1 A
\VnfloW2 tadims imsRrysUnalyticalRepn., S.p,Sa Reference: 10 WOO 145156mW
J1002252 18 of 27
24

J1002252 19 of 27
25

Project Name: Special Dioxin Testing
Project Number:
Project Managcr: Jim Hutchens
Company: RMT Inc.
Lab Code Client Sample ID
J1002252-00I
J Winter Log Storage
J 1002252 002
1 PB01 (Old Borrow)
! 11002252-003
j Coal -Yard
I
0 _.-__
1_10022_52_-004-
_ .
I Railya_rd
Special I nstruetions/Com menu
PLEASE SEND
RESULTS TO
MANDY SULLIVAN
Intra-Network Chain Of Custody CAS Contact. Tom Kissinger
9143 Philips Highonv • Jacksonville, PL3'156 • 904-739-2277 • FAX [phone]
j
I
I
�
C G
5
i
Sample
Dale
C
,Matrix
Date
'rime
Received
Send To
I'
I
Soil
5/12/10
0742
5/13/10
FIO—FON
❑
I H
Sod
5/12/10
0803
5113/10
1IOUSTON
Soil
5/12/10
0752
/13/10
! HOUSTON I
❑ i
II
Soil
5/12/10
0747
I 5/13/10
I HOUSTON j
Turnaround Requirements
_RUSH (Surcharges Apply)
PLEASE CIRCLE WORK DAYS
1 2 3 4 5
STANDARD
Requested FAX Date:
Requested Report Date:. 06/03/10
Report Requirements
I. Results Only
�L ❑. Results + QC Summaries
III. Results + QC and Calibration Summaries
IV. Data Validation Report with Raw Data
PQLAIDUJ N
EDD
Relinquished ByjlooZX fReceived By: 1/0 /oap Airbill Number
Invoice Information
J1002252
to
Page I

.,� ;Reset Form
Columbia Analytical Services, Inc.
Cooler RJieipt Form
Client/project RMT Inc/ Special Dioxin Testing Service Request:
Received: 05/14/10 1000 Opened (Date/Time): 05/14/10 10D5 By:
J1002252
CD for EC
I. Samples were received via? ❑USmail ❑Fedex ❑JUPS ❑DHL ❑Courier
❑Hand Delivered
2. Samples were received in: (circle) ❑✓ Cooler ❑Box ❑ Other
DNA
3. Were custody seats present on coolers'? 21Y ON If yes, how many and where?
1 front
If present, were custody seals intact? ❑✓ Y ❑N If present, were they signed and dated?
❑✓ Y
ON
4. Is shipper's air -bill filed? DNA ❑Y 21N If not, record air bill number: 1ZTSWO980140502370
5. Temperature of cooler(s) upon receipt (°C): 1
6. If applicable, list Chain of Custody numbers:
7. Were custody papers properly filled out (ink, signed, etc.)?
DNA ❑✓ Y
❑N
8. Packing material used: ❑Inserts ❑✓ Bubble Wrap ❑Blue lce ❑✓ Wet 1ce ❑✓ Sleeves ❑Other
9. Were the correct types of bottles used for the tests indicated?
❑✓ Y
❑N
Did all bottles arrive in good condition (i.e. unbroken, out of temp.)? Indicate in the table below.
❑J Y
ON
Sample ID
Bottle Count`
BottictType
_ Out of -Temp
Broken '
"Intttals '
❑1:1
❑
El
❑
❑
❑
❑
❑
1 ❑
❑
1 ❑
10. Were all bottle labels complete (i.e. analysis, ID, etc.)? ❑✓ Y ❑N
Did all bottle labels and tags agree with custody papers? Indicate in the table below. ❑✓ Y ❑N
Sample ID on Bottle .
"Sample B? on COC
Sample ID on Bottle
", Sample ID on COC'
11. Additional notes, discrepancies, and resolutions:
J1002252 21 of 27
CRF_r092109.pdf
Page 7f.O 1 ❑ 2

22
Sample Acceptance Policy
Custody Seals (desirable, mandatory if specified in SAP):
✓ On outside of cooler
✓ Seals intact, signed and dated
Chain -of -Custody documentation (mandatory):
✓ Properly filled out in ink & signed by the client
✓ Sign and date the coc for CASMOU upon cooler receipt
✓ Coc must list method number
✓ If no coc was submitted with the samples, complete a CASMOU coc for the client
Sample Integrity (mandatory):
✓ Sample containers must arrive in good condition (not broken or leaking)
✓ Sample IDs on the bottles must match the sample IDs on the coc
✓ The correct type of sample bottle must be used for the method requested
✓ The correct number of sample containers received must agree with the
documentation on the coc
✓ The correct sample matrix must appear on the coc
✓ An appropriate sample volume or weight must be received
Temperature Preservatives (varies by sample matrix):
✓ Aqueous and Non -aqueous samples must be shipped and stored cold, at 0 to 60C
✓ Tissue samples must be shipped and stored frozen, at -20 to -10°C
✓ Air samples can be shipped and stored at ambient temperature, -230C
✓ The sample temperature must be recorded on the coc
✓ Notify a Project Chemist if any samples are outside the acceptance temperature or
have compromised sample integrity - the client must decide re: replacement sample
submittal or continue with the analysis
Cooler Receipt Form, CRF (mandatory):
✓ Cooler receipt forms must be completed for each coc & SR#
✓ Sample integrity issues must be documented on the CRF
✓ A scan of the carrier and the airbill number must be recorded in CAS LIMS
Sample Integrity Issues/Resolutions (mandatory):
✓ Sample integrity issues are documented on the CRF and given to the Project Chemist
for resolution with the client
✓ Client resolution is documented in writing (typically email or on the CRF) and filed in
the project folder(s)
J1002252 22 of 27
28

Service Request Summary
Folder 9:
,110022j2
Project Chemist:
Darren Biles
Client Name:
Domtar Industries
Originating Lab:
JAX
Project Name:
Special Dioxin Testing
Logged By:
SLIGHTSEY
Project Number.
Date Received:
5/13/10
Report To:
Diane Hardison
Internal Due Date:
6/3/10QAP:
Domtar Paper Company, LLC
LAB QAP
P.O. Box 747
Qualifier Set:
CAS Standard
Plymouth- NC 27962
Formset
CAS Standard
Phone Number:
252-793-8611
Merged?:
N
Cell Number:
Report to MDL?:
Y
Fax Number:
252-793-8871
P.O. Number:
4550171884
E-mail:
dianc.hardisunt7gdomtar.com
EDD:
No EDD Specified
SV11
a
0
o e o
N CAS Sam, Nu Client Sxinp No. pimria Cullerted 2 Q
V
J1002252-001
Wiraer L , Sto ugc
Soil
5/12/10
0742
11
11
J 1002 52-00
P1301 (Old A w)
Soil
5/1 110
0803
11
11
11002252003
Co01)and
so➢
5/12/10
075
If
II
J 1002252-0Da
Rory d
8 it
3/12/10
0747I
11
11
Test Comments:
Group
Semivoa GCMS
Test/Method
Dioxins Furans/161313
Samples Comments
1-4 2378 TCDD only
4 -8 or. -Glue Jar WM CLEAR TO].. Liner llnynseneJ
Location: Freezer N5, E-WIC01
NPDES
J1002252 23 of 27
Pnnrcd 6/8/2010 9:37.20AAI Service Request for J1002252 pa, I of I

Preparation Information Benchsheet
24
Prep Run#: 111716 Prep WorkFloe': OrgExIS(365)
Team: Sclnivoa GCMS/AK0DUR Prep Method: Method
Status: Prepped
Prep Date/Time: 5/22/10 10'30 AM
#
Lab Code
Client ID
B#
Method /Test
pH
Matrix
Amt. Ext.
Sample Description
I
I EI000S16-M5
SINE 006-GRI
01
16131IMmircans Furans
Sediment
14.986g
dark brown wet mud
2
EIN0516-016
SINE 007-GR1
.01
1613BJDioxins Furans
Sediment
13.708g
dark brown wet mud
3
E1000S 16-017
SINE 002-GRI
01
161313/Dkwins Furans
Sediment
14,800g
light tan sand
4
E1000516A 18
SINE 003 -OR I
01
1613B/Diodmi Finami
Sediment
111211,
dark brown very wet mud
5
E1000525-002
SINE 049-GRI
01
161313/Dioxins Furait,
Sedimetl
11.154g
dark brown wet mud
6
E1000532-002
SJNE-045-GR 1
.01
1613B/Dwmai Fumns
Sediment
14058g
dark brown wet ..it
7
E1000532.003
SJNE-044-GRI
.01
16I3B/Dioairw Furans
Sediment
11.766g
dark brown wet mud
8
E10005324)04
SJNE-043-GRI
.06
1613BMiosins Furans
Sediment
12.2118
dark brown very wet sand
9
E1000532-005
ME-042-GRI-1
.01
1613B/Dioxins Faunas
Sediment
12.872g
dark brown wet mud
10
E1000532-006
SJNE-042-GRI-2
'01
1613B/Dioxins Forms
Sediment
12763g
dark brown wet mud
11
E1000532-007
SJNF-04I-GRI
04
1613BMioxins Furans
Sediment
12255g
brown wet mud
12
E1000532-008
SJNE-040-GRI
01
1613B/Dioxlns Furans
Sediment
I0t33g
dmk brown wet mud
13
E1000532-009
SINE-039-GRI
01
1613BIDioxins Furans
Sediment
12,078g
dark brown wet mud
14
E1000532-010
SJNE-032-GRI
04
1613BJDioxins Forms
Sediment
14748g
dark brown wcnnud
15
E1000532-011
SJNE-033-GRI
.01
1613B/Dimans Furans
Sediment
IS 242g
dark brown wet mud
16
E1000532-012
SJNF.-034-011I
.01
16138/Dloxins Furans
Sediment
15.066g
brown wet sand
17
EQ 1000252-0I
MB
1613B/Dloxin5 Furans
Solid
10.000g
I8
EQ1000252-02
LCS
1613B/Dioxout Furary
Solid
10.000g
19
EQ1000252-03
DLCS
1613&Dioxins Futons
Solid
100008
20
11002252-001
Winter Log Stooge
01
16t3B/Dioxin,r Furors
Soil
12.933g
brown wet sand
21
J1002252-002
PRO (Old Borrow)
'01
1613B/Diaxins Furans
Soil
18.66)g
light tart wet mud
22
11002252-003
Coal -Yard
01
1613B/Dioxins Furans
Soil
14.197g
black wet mud
23
J1002252-004
Rail,m
.01
1613B/Dioxins Furans
Soil
16.130g
brown wet mud
W
O
J 1002252 24 of 27
Printed 6/4/ 10 14'.58 Preparation Information Benchsheet Page I

Prep Runty: 111716
Team: Sentivoa GCMS/AKODUR
Spiking Solutions
Preparation Information Benchsheet
25
Prep WorkFlon': Org[xtS(365)
Prep Method: Method
Status Prepped
Prep Date/Time; 5/22/10 10:30 AM
Name: 1613B Matrix Working Standard Inventory ID 16265 Logbook Ref DI 1-16.1 B Expires On: 03/162011
E1000516-015 t0000faL
E1000516-018 too oopL
E1000532-003 too oop1_
E1000532-006 t0000µL
E 100053 2-009 1 oo. oo µL
E1000532-012 RD) 100.00pL
11002252-003 too ooµL
E1000516-0I5.R01 IN oopL
E1000516-018.R01 too ooµL
E1000532-003 RD) 100.0opL
E1000532-0O6.R01 too Wpl-
E1000532-010 100 oopL
EQ 100025 2-01 t o o. oo p L
110022 52-004 I D o. oo p L
E1000516-016 IOO.00pL
ElOW525-002 t0000pL
E1000532-004 t00.00pL
E1000532-007 too 0011L
ElOW532-010.Ro1 IN oopL
EQ1000252-02 IOO.00pL
E1000516-016.R01 t0000pl-
E1000525-0o2. RD] 100.0opL
E1000532-004.R01 too, oopL
E I OW532-007.R01 too .00pL
E 1000532-011 100 OopL
EQ1000252-03 too. oopL
E1000516-017 10000pl-
E1000532-002 10000µL
E 1000532-005 100,00µl-
E 1000532.008 100.00 p L
E 1000532411 RDI 100.0OpL
11002252-001 100 OOP L
E1000516-017.R01 too. DopL
E1000532-002.R01 100OopL
E 100053 2-005. RD I too ooµL
E1000532-008. RD) 100 oopL
E1000532-012 too ooftL
11002252-002 Ioo.00pL
Name: M13B Labeled Working Standard Inventory 3D 18184 Logbook Ref: DI1-28-3B Expires On: 05/222011
E I N0516-015
I, 000. o o p L
EI N05164I8
I,000. oopL
E 1000532-003
1,000.00 pL
E10005324106
IOOoNlDL
EDOW532-009
1,000.00pl,
E1000532-012.RO1
1000 OOpl,
31002232-003
1 000.00µL
E1000516-0I5.R01
1,000.00µ L
E 1000 516-018. R 0 I
1, 000.00 p L
E I00o532-003.ROI
1,000ooµL
E IOOOS32-006.ROI
I,000.00µL
EI000532-010
I'm oopL
rQ1000252-01
Iooa oopL
J 002252-004
1,000.00pL
E1000516-016 l o00 ooµL
E l000525-002 1000.00 µ L
E 1000532-004 l 000.00pL
E 1000532-007 I,who oopL
E 1000532-010. R01 1, 000.00 It L
EQ1000252-02 L000.00pl-
E 1000516-016.R01 1.000.DoµL
E 1000525-002.Ro l I,000.00 µL
F-1000532-004. R01 1 000.00 p L
E 1000532-007. R01 1000.00 p L
E. I ON 5 32-011 1 000. DOµ L
EQ1000252-03 1 000.Ooµl-
E 1000516-017
1,0o0.00 )tL
E1000532-002
t,o00.00VL
E 1000532-005
1 O0000pL
E 1000532-008
1,000.00 pL
E1000532-01[.RD 1
1 000.00pL
11002252-001
i000 oopL
E 1000516-017.R01 1,000 OOP L
E1000532-002. RD] 1,000. Doll L
E1000532-005.R01 1 000.0op L
EI W0532-008.R01 1000.00p L
E 100053 2-012 I OOO.00 ft L
11002252402 1000.00It L
Name: 829011613E Cleanup Working Standard Inventory ID 18185 Logbook Ref. D11-31-3A/B Expires On: 05252011
E1000516-015 200.00p1-
E1000516-018 2oo.00µL
E1000532.003 200.00pl,
E1000532-006 20000pL
E1000532-009 200.00pl-
E 1000532-012.RD I 200.00µl-
JIo02252-003 20000pl-
Preparation Materials
Acetone 99.5 : Minimum
Emaction Thimbles 43 x123
mm
Dichlaromethane (Methylene
I-�htmide) 99.9% McC12
odium Sulfate Anhydrous
Reagent Grade Na2SO4
Nosam, (n-Nomme) 99%
E1000516-015.R01 200 oopL
E 1000516-018. R 01 200.00 p I_
E1000532-003.R0I 200.o0µL
E 1000532-006.R01 200 NpL
E1000532-010 200,00pL
EQ 1000252-01 200 00)tl,
JtG02252-004 200nopL
C2-34-1(15539)
(1577)
C2-34-1(15540)
C2-36.004 (16226)
C2-33-001(13944)
E1000516-016 20o.o0pL
E 1000525-002 200.00µL
E10005324N 200.00pL
EIOD0532-007 2oo.00µL
E1000532-01O.Ro l 200.00pL
EQ1000252-02 200o0IiL
Carbon, High Purity
Glue Wool
Sodium Chloride Reagent Grade
N.CI
Tridecane(n-Ttidecane)
Silica Gel Reagent Grade
E 1000516-016. R01 200oopL
E I000525-o02R01 200,0opL
E 1000532-004. R01 200.00 µ L
E 1000532-0O7.R01 200.0oµL
ElOW53241l 2oo.00pL
EQ1000252-03 200.00)1L
C2-32-005 (13986)
C2-13-005 (7198)
CI-104-2(3306)
C2-34-3 (15537)
C2-31-005 (13988)
E 1000516417 200.60µL
E1000532-002 2oo.00µL
E1000532-005 200.OopL
E 1000532-008 200.00pl-
E 100053 2-011. R01 200.00 µ L
H002252-001 2oo.00µL
Ethyl Acetate W.9%. Minimum
EIOAe
Sul fork Acid Reagent Grade
142SO4
Sodium Hydroxide Reagent
Grade NeOH
Hcxanc (n-Hexanc) 98.5%
Minimum
Tolucnc 99.9% Minimum
E 1000516-01 T R D I 200.00 p L
E1000532-002.R01 200.00p L
E 1000532-005.R01 200.00 pL
E 1000532-008.R01 200 oopL
E1000532-012 200.00fl-
n002252-002 20o.00pL
C2-33-2(14437)
C2-344(15542)
C2.24-002(9463)
C2-36-002(16224)
C2-36-003 (16225)
J1002252 25 of 27
Primed 6/4110 14:58 Preparation Information Benchsheet Page 2

Prep Rung: 111716
Team:
Semivoa GCMS/AKODUR.
Preparation
Steps
-
Step:
Extrnelion
Step:
Slaved:
5/22/10 10:30
Started:
Finished:
5/23/1007:50
Finished'.
By
CDONOVAN
By:
Comments'
Preparation Information Benchsheet
26
Prep Workflow: OrgBstS(365)
Prep Method: Method
.Acid Clean
Step:
Silica Gel Clean
Sap'.
Final Vohime
5/26/10 08:00
Staved-.
5/26110 12:30
Started'.
5/27/10 06: 15
5/26/1009: 10
Finished:
5/26/1015,45
Finished.
5/27/1010.36
CDONOVAN
By.
CDONOVAN
By:
CDONOVAN
Reviewed By: CD Date: -- 6 / 4 / 2 010
w
Wain of Cnaody
Relu ctaished By: Date:
Extracts Examined —
Received By Date'. Yes No
Status: Prepped
Prep DaterFime: 5/22/10 10.30 AM
Printed 6/4/10 14:58 Preparation Information Benchsheet Paee 3

COLUM131A ANALYTACAL SERVICES, INC.
Total Solids Report
Sample ID
Tare O
Tare +Wet Wt.O
Tarc+Dry Wt.(g)
%Total Solids
E1000516-015
13.249
18.522
15.282
38.6
E 1000516-016
12.886
21.012
18.413
68.0
E1000516-017
13.347
24.220
22.035
79.9
E 1000516-018
13.354
19.536
17.551
67.9
E1000525-002
13.316
19.684
15.544
35.0
E1000532-002
13.347
24.512
20.950
68.1
E1000532-003
13.393
18.704
15.074
31.7
E1000532-004
12.968
24.478
21.444
73.6
E1000532-005
13.396
19.313
15.626
37.7
E1000532-006
12.893
19.207
15.265
37.6
E1000532-007
13.290
20.574
15.892
35.7
F1000532-008
12.973
19.232
15.170
35.1
E1000532-009
13.202
20.589
15.388
29.6
E1000532-010
13.037
18.294
15.988
56.1
E1000532-011
12.940
20.930
16.631
46.2
E1000532-012
13.311
24.777
20.583
63.4
Batch No.:
Comments: Date of Tare+ Dry :5/28/10 at 1700
Anal st: EB Date/Time: 6/7/10 4:51 PM 11
J1002252 27 of 27
33

Domta
It all begins with gaped
Domtar Paper Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
T 2827938111
www.domcar.com
April 27, 2010
Division of Water Quality
Attn: Central Piles
1617 Mail Service Center
Raleigh, NC 27699-1617
Certified Mail
Return Receipts Reouesterl
Subject: NPDES Permit # NCS000189, Year I — Period 2 Monitoring Period February
1, 2010 to July 31, 2010. Required Stornnvater Analyses for Domtar Paper Company,
LLC, Plymouth, North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge
Monitoring Report" for the Year i — Period 2 Monitoring Period designated from February 1,
2010 to July 31, 2010. With the submission of this report, Dormar has now sampled at all of the
remaining SW outfalls required by storm water permit No. NCS000189, for this period.
The COD sample result for sampling location WRA was 357 mg/L, which exceeded the
benchmark value in our permit. As a result of this parameter exceedance, a meeting and field
inspection was conducted per the action steps required by the permit. The report from that
meeting is included and further discusses what other actions need to be taken.
In the previous set of samples that were submitted, we noted that the BOD analysis would be
redone for outfall WYN, due to the improper dilution of the sample. As a result, this report
includes this outfall with a valid BOD result, along with the rest of the parameters analyzed as
well.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, tamika.boone(cDdomtar.com.
Sincerely,
i
Tamika Boone
Environmental Engineer
xc: Department files

I
Permit Number: NC S000189
Certificate of Coverage Number: NCG
or
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
FACILITY NAME Delmar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Lorenza Patin & Alan Barnes
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
jomt@r Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2010
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO�..-
[phone]
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
OLItiall_,�
Dater
Sam 6-
51
Eventz
Duration."
'H r, !Zr.-
Total i
,
Rianfail
In.
BOD
CW;4 ... tY
wl
A
mQML
PHQ6,:­_��
in J�
g
Dioxih­��,_,!��'�'-'
ffi.
mmidd
VVYN
3/29/2010
14
2.93
13
95
142
7.2
Not detected
LF04
3/29/2010
14
2.93
3
48
28
6.4
Not detected
LF02
3/29/2010
14
2,93
3
71
33
7.1
Not detected
RY01
3129/2010
14
2.93
2
48
10
7.5
Not detected
WRA
3/29/2010
14
2.93
16
357
27
7.4
Not detectetl
LF03
3/29/2010
14
2.93
1
43
81
7.4
Not detected
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
(:tutfall
50050�3�
5 56 z'
5 3 0 _F �F� _1�; '�,g
400t�
"�a ­4�&
TottiliFlow,,4
Oillanol�','_
Total
pl-1-
e to-.-
-%-�i
Sample,z' l
Collected�ti
Grease-Sus)ende&'
Oil iagel-eg,,
S61j
molddlyr,' .
MGg
rrigfli
unit _t,�
g llrf rio ::
zi
Yes
am
Note: There is a garage onsite, however it is fully contained and drains directly to our wastewate
treatment system. Also, there are no outfalls located in this area.
Form SWLJ.246-051 100
SWDOMR UdWatehStarmwateASWAnalyticalRepor,FormMar29 2010 As Page 1 of 2

STORM EVENT CHARACTERISTICS:
Mail Original and one copy to:
Division of Water Quality
Date 3/28/10-3/29112/10
Attn: Central Files
Total Event Precipitation (Inches) 2.93
1617 Mail Service Center
Event Duration (Hours) 14
Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Date)
Form SWU-246-051100
S W DOMR U:\Water\StormwatehS WAnalyticalRepor FormMar29 2010AS Page 2 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000189 or Samples Collected During Calendar Year 2010
Certificate of Coverage Number: NCG (This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
FACILITY NAME Domtar Paper Company, LLC COUNTY Martin and Washington
PERSON COLLECTING SAMPLE(S) Lorenza Palin & Alan Barnes PHONE NO' [phone]
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527C'6--�/��!
Domtar Paper Company Co, LLC Lab# 171 (SIGNATURE OF PERMITTEE OR DESIGNEE)
Wastewater Lab -Plymouth By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Part A: Specific Monitoring Requirements
Oiitfalli+ 7
Not a•
r I
? ...».
Dzter- �'
Sam le
P >
Collected".§.,,
Eveht 4'xc
` n ra
Duratlonr�
H Jsin?.. .�-
Total +aid
Rain aH„
�,. d,,
Ihchest'
eOD nya ^ _ "a
r .
.a �.s.. .;mg/Its-%iis_4.c
mg/I+ >', �s:*
CODS='
E'm9/I
TSS a`i_7
r �"
v
PH,°,gs,
kDlozlnT",� r.
�,r:
i 4
- lvd'
i
mm/dd/yr??;
WYN
3/29/2010
14
2.93
13
95
142
7.2
Not detected
LF04
3/29/2010
14
2.93
3
48
28
5A
Not detected
LF02
3/29/2010
14
2.93
3
71
33
7.1
Not detected
RY01
3/29/2010
14
2.93
2
48
10
7.5
Not detected
WRA
3/29/2010
14
2,93
161
357
27
7,41
Not detected
LF03
3/29/2010
14
2.93
1
43
81
7A
Not detected
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfalir
N ,r
x 32r3
Date
Sample
Collected
ITotma laFlow"Fy+
-�'
OilfandMi
GreaseF
530 sy,�,,
Tota
spend tl' $
400 A3y,q-'<p,�+
pH z
}yam'
N—Motd'
OiHU:
g5"
rrio/dd/yr,g :s
MG.f:s1...s "
m9/I`�r.'Yr�
m9/yy.'.?.`
unit`' '
9allino*.:,;',,,,"^r.:;t
Yes
No
Note: There is a garage onsite, however it is fully contained and drains directly to our wastewa
treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
SWDOMR U1WatedStorr atenSWAnalyticalReportFormMar292010xis Page 1 of

STORM EVENT CHARACTERISTICS:
Mail Original and one copy to:
Division of Water Quality
Date 3128110-3129112110
Attn: Central Files
Total Event Precipitation (Inches) 2.93
1617 Mail Service Center
Event Duration (Hours) 14
Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Date)
Form SWU-246-051100
SWDOMR U:\WatehStormwater\SWAnalyticalRepogFormMar29 2010.xis Page 20l2

LSColumbia
Analytical Services- 9143 Philips Highway, Suite 200 1 Jacksonville, FL 32258 1 g04-739-2277 1 904-738$011 fax I wvnv.Wsla6.tom
April 20, 2010
Diane Hardison
Domtar Paper Company, LLC
P.O. Box 747
Plymouth, NC 27962
Laboratory Results for: Plymouth Stormwater Testing
Dear Diane:
Service Request No: J1001458
Enclosed are the results of the sample(s) submitted to our laboratory on April 1, 2010. For your
reference, these analyses have been assigned our service request number J1001458.
All analyses were performed according to our laboratory's quality assurance program. The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc.
(CAS) is not responsible for use of less than the complete report. Results apply only to the items
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report.
Please contact me if you have any questions. My extension is 4408. You may also contact me
via email at [e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
Tom Kissinger
Project Manager
Page 1 of
CAS Jacksonville is NELAC-accredited by the State of Florida, 9E82502. Other state accreditation
include: Georgia, #958; Kentucky, #63, Louisiana, 902086; North Carolina, 9527; South Carolina,
996021001; Texas, 9T104704197-09-TX.

:lient: Domtar Paper Company, LLC Service Request:/1001458
'roject: Plymouth Stormwater Testing
SAMPLE CROSS-REFERENCE
SAMPLE #
CLIENT SAMPLE ID
DATE
TIME
J1001458-001
WDY
3/29/10
08:30
11001458-002
LF04
3/29/10
10:55
J1001458-003
LF02
3/29/10
11:20
J1001458-004
RY01
3/29/10
09:50
J1001458-005
WRA
3/29/10
10:05
11001458-006
LF03
3/29/10
10:40
4
rinted 4/20/10 14:24 Semple Summary Page I of I

�( Columbia Analytical Services, Inc.
\U"'K%aI
�T 4No-.s Cooler Receipt Form
Client:
�(\ Q� �— Service Request 7:
Cooler
received on and opened on'—t
by
COURIER:
CAS UPS FEDEX Client Other
Airbill #tby'�[ Z><y,tyaga9s
1
Were custody seals on outside of cooler?
e
No
If yes, how many and where?
k on
id
other
2
Were seals intact and signature and date correct?
Yes
No
N/A
3
Were custody papers properly filled out?
GiD
No
N/A
4
Temperature of cooler(s) upon receipt (Should be 4+/- 2 degrees C) A-
5
Thermometer ID T
6
Tempci'atLire Blank Present'?
cs
No
7
Were Ice of Ice Packs present
Ice
Ice Packs
No
b
Did all bottles arrive in good condition (unbroken, etc....)?
es
No
N/.A
9
Type of packing material present
10
Were all bottle labels complete (sample ID, preservation, etc....)?
0cs
No
N/A
I I
Did all bottle labels and tags agree with custody papers?
Ycs
No
N/A
12
Were the correct bottles used for the tests indicated?
Yes
No
N/A
I3
Were all of the preserved bottles received with the appropriate presen'ative?
Yes
No
N/A
FL103 pH<2 H2SO4 pH<2 ZnAc2/NaOH pH>9 NaOH pH>12
HCI pH<2
Preservative additions noted below
14
Were all samples received within analysis holding times?
es
No
N,A
15
Were VOA vials checked for absence of air bubbles? If present, note below
Yes
No
N/A
16
Where did the bottles originate?
CAS
Client
Sample ID Reagent Lot # ml added Initials Date/Time
Additional comments and/or explanation of all discrepancies noted above:
Client approval to run samples if discrepancies noted:
Date:
3

Jacksonville Laboratory
(L),�4nuhliml
Condition Upon Receipt -Sample pH
5R a : J Date: ` \ 0 Initials:
Note that pH is check and meets the required pH criterion listed in the column heading unless otherwise noted on the cooler receipt form.
Container
Pres.
Roo, pH
sample 71
-001
-002
003
-004
-005
-006
007
-008
-009
-010
-011
012
-013
-014
-015
-016
-017
-018
-019
-020
-021
-022
-023
-024
-025
-026
027
-028
-029
-030
-031
-032
-033
-034
-035
036
-037
-038
-039
-040
Cr •r-
r
����MMHM0®������r.
000000000�0000000000000
®Iffw
va�aaeeaee�eeevaeeveee�a���ee�e
-__--__--_
MMM
MMMMIM__--_-------
---_----_--
001
002
003
004
005
006
007
008
009
010
011
012
013
014
D15
016
017
018
019
020
021
022
023
024
025
026
027
028
029
030
031
032
033
034
035
036
037
038
039
040
NOTE: VOA pH checks are performed by the analytical area, not sample control

4;
a®
(.(1�U1llblil
$erIces"'
CHAIN OF CUSTODY / LABORATORY ANALYSIS REQUEST FORM
9143 Philips highway, Suite 200 Jacksmni0e, Florida 32256•Phone[phone]/Fae 904-739-2011 Page
SR f
S1001Y58
CAS Contact
1 of I
www.caJab+cam
Project Name
Project Number
ANALYSIS REQUESTED (Include Method Number
0
Pl ntoulli Stornlwater Testingt'13°`a`
Report To
Report CC
Diane Hardison
Alnn Barnes
�
1. Het.
2, IIN03
Company/Address
Donitar Paper Company
G
C�
O
.o
3. H2SO4
4. NaOH
Y.O. Box 747
Phnouth. NC 2796E
a
p
5. zn. Acetate
6. Mooll
Phone p
F.4% 9
7. NaHSO4
252-797-R611
22-793-88711
Samplel'9 Signature
Sarnplces Printed Name
i
SAMPLING
CLIENT SAMPLE ID
LAB ID
DATE TIME
WDY
Dioxin
3/29/10
8:30
2
X
FWater
LF04
Dioxin
3/29/10
10:55
2
X
LF02
Dioxin
3/29/10
1120
2
X
RY01
Dioxin
329/10
9:50
2
X
WRA
Dioxin
3/29/10
10:05
Water
2
X
LF03
Dioxin
329/10
10:40
Water
2
X
Special Stornmater tosting at Donlrr Pl}mouth.
TURNAROUND REQUIREMENTS
REPORT REQUIREMENTS
INVOICE INFORMATION
1. R.a, OW,
S�a FFl+wcfe.-P a•
RUSH(nRCHARGES APPLY)
IL Ruo:u+ QC Summvin
P.O.M
X STANDARD
(Les. DLP. NSMSD c fmu )
X III.RuWa+QCmd Celibm0a Summmiu
EEno:
REQUESTED FAX DATE
V. Dau VNi&60F1 Repon wW, Ruv Da.
---
REQUESTID REPORT DATE
Edala _Yes _N'o
Relinquished V
Roccaved By
Relinquished By
cm By
RthrunIoluId rly
Recened by
Signature f/ Signature
Slglamre
Signal
SlgnAUre
SignamR
/./'
Pant �grpc Primed
Namc
Printed Name
P to
Printed'Name
Printed Name
Firm i��
hrn
Firm
Fir. -
Finn
Fimi
Datelima
DatdTone
DaIcYTime
Dateltime
�clne
D/atl'v
DatclCime
_'

4�AfSColumbia
Analytical Services -
Appendix A
Columbia Analytical Services
9143 Philips Highway, Suite 200
Jacksonville, FL 32256
Tel [phone]
Fax [phone]
Subcontracted Analytical Results
M

�fASColumbia
Analytical Services -
April 19, 2010
Tom Kisssinger
Columbia Analytical Services
9143 Philips Hwy, Suite 200
Jacksonville, FL 32256
19408 Park Row, Suite 320. Houston. TX 77084 1 713.266.1599 www.casiab.coni
Service Request No: I1 001458
Laboratory Results for: Domtar Paper Company, LLC/Plymouth Stormwater "resting
Dear Torn:
Enclosed are the results of the sample(s) submitted to our laboratory on April 2, 2010. For your
reference, these analyses have been assigned our service request number 31001458.
Analyses were performed according to our laboratory's NELAP-approved quality assurance
program. The test results meet requirements of the current NELAP standards, where applicable,
and except as noted in the laboratory case narrative provided. All results are intended to be
considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for
use of less than the complete report. Results apply only to the items submitted to the laboratory
for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the
NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any
quantitative analysis will be supplied upon request.
Please contact me if you have any questions. My direct line is 281-994-2954. You may also
contact me via email at [e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
Darren Biles
Project Manager
---.. _ _ ....-- — -----'--------- — --- -- ------- — — ------------------------- " -------------- — ....
For a specific list ofNELAP-accredited analytes. refer to the certifications section at itw .caslab.com.
An Emoloyee Owned Company i NELAP Accredited ! ACIL Seal of Excellence Award ! Please consider the environment before printing
J1001458 1 of 28

Certificate of Analysis
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.casiab.com
An Employee Owned Compe
J1001458 2 of 28 g

COLUMBIA . NALYTICAL SERVICES, INC
Client: Delmar Industries Service Request No.:
Project: Plymouth Stormwater Testing Date Received:
Sample Matrix: Water
CASE NARRATIVE
J10001458
4/2/10
All analyses were performed in adherence to the quality assurance program of Columbia. Analytical Services, Inc.
(CAS). This report contains analytical results for samples designated for Tier II. When appropriate to the method,
method blank results have been reported with each analytical test.
Sample Receipt
Six water samples were received for analysis at Columbia Analytical Services on 4/2/10.
The samples were received at IOC in good condition and are consistent with the accompanying chain of custody
form. The samples were stored in a refrigerator at 4°C upon receipt at the laboratory.
Please note the reporting forms are currently referencing the dale CAS- Jacksonville received the samples (411/10)
and not the date CAS -Houston received the samples (4/2/10.)
Data Validation Notes and Discussion
MS/DMS
EQ1000162: Laboratory Control Spike/Duplicate Laboratory Control Spike (LCS/DLCS) samples were analyzed
and reported in lieu of an MS/DMS for this extraction batch. The batch quality control criteria were met.
Detection Limits
Detection limits are calculated for each congener in each sample by measuring the height of the noise level for each
quantitation ion for the associated labeled standard. The concentration equivalent to 2.5 times the height of the
noise is then calculated using the appropriate response factor and the weight of the sample. The calculated
concentration equals the detection limit.
/ ✓ t
Approved by:
4
%ianggiu Liang, Laboratory Director
Date: 04/20/10
J1001458 3 of 28 9

4
Client: Domtar Parer Cumnam'- LLC Sen ice Requecc .11001458
Project: Plc mouth Stormwater Testing
SAMPLE CROSS-REFERENCE
SAMPLE.4
CLIENT SAMPLE ID
DATE
TIME
J1001458-001
WDY
3129/10
08:30
11001458-002
LF04
3/29/10
10:55
J1001458-003
LF02
3/29/10
11:20
J1001458-004
RYOI _
3/29/10
09:50
11001458-005
WRA
3/29/10
10:05
J 1001458-006
LF03
3/29/10
10:40
A 001458 4 of 28 10
Printed V19/in 7:06 SvnPle Summary
Page I of I

Laboratory Certifications
2010-2011
STATE/PROGRAM
AGENCY
CERTIFICATION ID
EXP DATE
ARIZONA
AZ-DHS
AZ0725
05/26/10
ARKANSAS
ADE
09-048-0
06/16/10
CALIFORNIA
CA -FLAP
2452
02/28/11
DoD ELAP
A2LA
2897.01
11/30/11
FI.oRIDA/NELAP
FL -DOHS
E87611
06/30/10
HAWAII
HI -DOH
N/A
06/30/10
❑.IANOWNELAP
IL -EPA
002380
10/06/10
IS017025
A2LA
2897.01
11/30/11
LoUISIAN%/NELAP
LELAP
03048
06/30/10
MAINE
ME -DOHS
2009031
06/05/10
MICHIGAN
MIDEQ
9971
06/30/10
MINNESOTA
MDH
048-999-427
12/31/10
NEVADA
NDEP
TX014112009A
07/31/10
NmJERsm'
NJDEP
TX008
06/30/10
NEW MEXICO
NMED-DWB
N/A
06/30/10
NEwYORK/NELAP
NY -DOH
11707
04/01/11
OKLAHOMA
OKDEQ
2009-25
08/31/10
OREGON/NELAP
ORELAP
TX200002-006
03/24/10
TENNESSEE
7NDEC
04016
06/30/10
TEXAs/NELAP
TCEQ
T104704216-09-TX
06/30/10
UTA[UNELAP
UTELCP
COLU2
06/30/10
SOIL INIPORT PERnuT
USDA
P330-09-00067
03/27/12
WASIIINGTON/NELAP
WA-Eco10
C1855
11/14/10
WESTVIRGINIA
WVDEP
347
06/30/11
J1001458 - 5 of 28

N
Abbreviations, Acronyms & Definitions
Cal
Calibration
Conc
CONCentration
Dioxin(s)
Polychlorinated dibenzo-p-dioxin(s)
EDL
Estimated Detection Limit
EMPC
Estimated Maximum Possible Concentration
Flags
Data qualifiers
Furan(s)
Polychlorinated dibenzofuran(s)
g
Grams
ICAL
Initial CALibration
ID
IDentifier
Ions
Masses monitored for the analyte during data acquisition
L
Liter (s)
LCS
Laboratory Control Sample
DLCS
Duplicate Laboratory Control Sample
MB
Method Blank
MCL
Method Calibration Limit
MOIL
Method Detection Limit
MRL
Method Reporting Limit
mL
Milliliters
MS
Matrix Spiked sample
DMS
Duplicate Matrix Spiked sample
NO
Number of peaks meeting all identification criteria
PCDD(s)
Polychlorinated dibenzo-p-dioxi.n(s)
PCDF(s)
Polychlorinated dibenzofuran(s)
ppb
Parts per billion
ppm
Parts per million
ppq
Parts per quadrillion
ppt
Parts per trillion
QA
Quality Assurance
QC
Quality Control
Ratio
Ratio of areas from monitored ions for an analyte
% Rec.
Percent Recovery
RPD
Relative Percent Difference
RRF
Relative Response Factor
RT
Retention Time
RRT
Relative Retention Time
SDG
Sample Delivery Group
S/N
Signal -to -Noise ratio
TEF
Toxicity Equivalence Factor
TEQ
Toxicity Equivalence Quotient
J1001458 6 of 28 12

7
Data Qualifier Flags — Dioxin/Furans
o B Indicates the associated analyte is found in the method blank, as well as in the sample.
o C Confirmation of the TCDF compound: When 2378-TCDF is detected on the DB-5 column,
confirmation analyses are performed on a second column (DB-225). The results from both the
DB-5 column and the DB-225 column are included in this data package. The results from the
DB-225 analyses should be used to evaluate the 2378-TCDF in the samples. The confirmed
result should be used in determining the TEQ value for TCDF.
o E Indicates an estimated value —used when the analyte concentration exceeds the upper end of
the linear calibration range.
o J Indicates an estimated value — used when the analyte concentration is below the method
reporting limit (MRL) and above the estimated detection limit (EDL).
o K EMPC -When the ion abundance ratios associated with a particular compound are outside the
QC limits, samples are flagged with a W Flag. A'K' flag indicates an estimated maximum
possible concentration for the associated compound.
o U Indicates the compound was analyzed and not detected.
o Y Samples that had recoveries of labeled standards outside the acceptance limits are flagged
with'Y'. In all cases, the signal-to-noise ratios are greater than 10:1, making these data
acceptable.
o ND Indicates concentration is reported as 'Not Detected'
o 5 Peak is saturated; data not reportable.
o P Indicates chlorodiphenyl ether interference present at the retention time of the target
compound.
o Q Lock -mass interference by chlorodiphenyl ether compounds.
J1001458 7 of 28 13

8
CAS/HOU - Form Production- Peer Review & Project Review Signatures i
I
I
i
SR# Unique ID
Date (� f3
Person 1
Date
Person 2
Date err O
Primary Data Reviewer
Date
Secondary Data Reviewer
MOM" HIM
Date 4/20/10
Reviewer
PS
I
I
J1001458
8 of 28
i
I
14
TA-EVVI ianM 10)

CA.S/FIOU - Form Production, Peer Review & Project Review Signatures
SR# Unique ID
MOTO
Date Person 1
Date Person 2
l 1TRAREM..- .. .- .. ..
Date Primary Data Reviewer
5O
Date Secondary Data Reviewer
Date 4 / 2 0 / 10 Reviewer S
J1001458 9 of 28
_ c _ > >ol

Analytical Results
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.casiab.com
J1001458 10 of 28 16

Client:
Project:
Sample ;Matrix:
Sample Name:
Lab Code:
COLUMBIA ANALYTICAL SERVICES, INC.
Analptila7 Repon
Dotntar Industries Sen ice Request: 31001458
Plymouth Stonno•ater Iesling Date Collected: 3/29/100930
Water Date Received: 4/ 1/10
WDY Units: Pg/L
J1001458-001 Basis: NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzorurans by HRCC/HRMS
Analytical Method:
1613B
Date Analyzed:
4/7/101337
Prep Method:
Method
Date Extracted:
4/2/10
Sample Amount:
960mL
Y Instrument Name:
E-HRMS-03
CC Column:
DB-5
Data File Name:
P108133
Blank File Name:
P108229
ICAL Date:
07/29/09
Cal Ver. File Name:
P108125
Inn Dilution
Analrle Name
Result Q F,DI. MRL Ratio RR"r Factor
23.7.8-TCDD ND U 0.719 10.4 1
Spike Cone. Control Ion
Labeled Compounds Cone.(Pg) Found (pg) % lice Q Limits Ratio RR'r
13C-2.3,7-9-rCDD 2000 1142.692 57 25-164 0.78 1.008
37CI-2,3,7.8=rCDD 800 653,437 82 35-197 NA 1.009
Comments:
Pnntcd 4119110 7:02 - Form IA
ttmao..z�cuu:m,u,19'f�FYd' iyr�viRrRorr ret 11 of 28 Sapersn Reference: iM"140151 r" M

COLUMBIA ANALYTICAL SERVICES, INC.
AnalynLl) Report
Client:
Donitar lndaStrleS
Sen ice Request:
.11001458
Project:
Plymouth Stormsvater Testing
Date Collected:
3/29/10 11155
Sample Matrix:
Water
Dale Recched:
4/ 1/10
Sample Name.
LF04
Units:
pg/I.
Lab Code:
11001458-002
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofunns
by HRGC/HRMS
Analytical Method:
1613B
..
Date Analyzed:
4/7/101425
Prep Method:
Method
Date Extracted:
4/2/10
Sample Amount:
960mL
Instrument Name:
E-HRMS-03
GC Column:
D13-5
Data File Name:
11108134
Blank File Name:
P109229
ICAL Date:
07/29/09
Cal Ver. File Name:
P108125
lon
Dilution
Anals'te Name
Result Q
EDL Aalit.
Ratio
RRT Factor
23.7-8-YCDD
ND li
0.561 IQ4
I
Spike
Cone.
Control
Ion
Labeled Compound,
Cmic(pg)
Found (Pg) %Ree Q
Limits
Ratio RRT
13C-2,3.7,8=PCDD
2000
1303.055 65
25-164
0.79 1.008
37CI-2,3,7.8=PCDD
800
671.228 84
35-197
NA 1.009
Comments:
Printed 4/19/10 7:02 Fan IA
lwno�-zs5uri�m,a,19'fJffR4.S'�1„�eaiRmna,Pr 12 of 28 S.MSr Reference: 10-0 140151 rcv 00
18

COLT MBIA ANA LNTICA L SERVICES. INC.
Analytii4l Relxrtt
Client:
Domtar Industries
Sen ice Request:
J1001.158
Project:
Pl; mouth Slonmmter Testing
Dale Collected:
3/29/10 1120
Sample Matrix:
Water
Date Received:
4/ 1/10
Sample Name:
LF02
Units:
Pg/l,
Lab Code:
1100 145 8-003
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRGC/IIRMS
Analytical Method:
1613B
Date Analyzed:
4/7/10 1512
Prep Method:
Method
Date Extracted:
4/2/10
Sample Amount
960mL
Instrument Name:
E-HRMS-03
GC Column:
D13-5
Data File Name:
11108135
Blank File Name:
P108229
ICAL Date:
07/29/09
Cal Ver. Pile Name:
P108125
Ion Dilution
Analyte Name
Result Q EDI, NIRL Ratio RRT Factor
2.3.7.8-fCDD ND 1) 0.522 1OA I
Spike Cone. Control Ion
Labeled Compounds Conc.(pg) Found (In-) . ]Zee Q Limits Ratio RR'F
13C-2.3.7.8-1 CDD
37CI-23.7.8-TCDD
Comments:
2000 1432.169 72 25-164 0.79 1.008
800 732.770 92 35-197 NA 1.009
Printed 4/19/10 7:02 Forth IA
WnnuwRSuaim 9Tb1Q�gsl.4aa1 timlRepno rpt 13 of 28 J UU 4�O) SnRcr$e Reference: 10.0000140151 re. 00
19

COLUMBIA ANALYTICAL SEIRVICES, INC.
Analyfl leg Report
Client:
Dolnmr Industries
Service Request:
/1001458
Project:
Plymouth Stonmvatcr'1'esting
Date Collected:
329/100950
Sample Matrix:
Water
Date Received:
4/ 1/10
Sample Name:
RY01
Units:
pg/L
Lab Code:
11001458-004
Basis:
NA
Polychlorinated Dibenzodioxins
and Polychlorinated Dibenzofurans
by HRCC/HRMS
Analytical Method:
1613B
Date Analyzed:
4/7/10 1600
Prep Method:
Method
Date Extracted:
4/2/10
Sample Amount:
IOOOmL
Instrument Name:
E-HRMS-03
CC Column:
DB-5
Data File Name:
P108136
Blank File Name:
1`108229
ICAL Date:
07/29/09
Cal Ver. Pile Name:
1`108125
Ion
Dilution
Anah'tc Name
Result Q
EDI, MR1,
Ratio
ItRT Factor
2.3.7.8-'I CDD
ND U
OA20 10.0
Spike
Conc.
Control
Ion
Labeled Compounds
Conc.(pg)
Found(pg) %Rec Q.
Limits
Ratio RRT
13C-2,3.7,8=PCDD
2000
1466.782 73
25-164
0.79 LOOS
37CI-2.3.7.8-FCDD
800
763.545 95
35-197
NA 1,009
Comments:
Rimed 4119/10 7:02 y,. Fonn IA
\Vnnow2`SudimsV�m1 s4an'1�oraiRmon ma 14 of 28 SuMSr Refermc , 10.00001401511 —00

COLUMBIA ANALYTICAL SERVICES, INC.
AnalylA Report
Client:
Domtar Industries
Sers ice Request:
J1001-158
Project:
Plymouth Slortnwater Testing
hale Collected:
3/29/10 1005
Sample Matrix:
Water
Date Received:
4/ 1/10
Sample Name:
WRA
Units:
pg/L
Lab Code:
J1001458-005
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by HRGC/ERMS
Analytical Method:
1613B
Date Analyzed:
4/7/10 2017
Prep Method:
Method
Date Extracted:
4/2/10
Sample Amount:
960mL
Instrument Name:
E-HRMS-03
GC Column:
D13-5
Data File Name:
P108140
Blank File Name:
P108229
ICAI- Date:
07/29/09
Cal Ver. File Name.
P108137
lon
Dilution
Analyte Name
Result Q EDL MRL Ratio
RRT Factor
2.3.7.8=1 CUD
ND U 0.630 10.4
1
Spike Cone. Control lon
Labeled Compounds Conc.(I)g) Found (pl;) %Bee Q Limits Ratio RRT
13C-2,3.7.8=fCUD 2000 1280.991 64 25-164 0.80 1.008
37C1-2.3,7.8=1CDD 800 748.560 94 35-197 NA 1.009
Comments:
Ponied 4/19!10 7:02 Fomt I A
w�no.z,su,nm,�rJ�ga,i v
, ucalaevont 15 of 28
Y Super$n Ref rnce' 10-00rA140111 m00
21

C01,11MBIA ANALYTICAL SERVICES, INC
.Anal, ticl RMort
Client:
Donitar Industries
Service Request:
J1001458
Project:
Plymouth Stonnwmer testing
Date Collected:
3/29/10 1040
Sample Matrix:
Water
Date Receixcd:
4/ 1110
Sample Name:
LF03
units:
pg/L
Lab Code:
11001458-006
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by HRGCAIRMS
Analytical Method:
1613B
Date Analyzed:
4/7/10 2105
Prep Method:
Method
Date Extracted:
4/2/10
Sample Amount:
IOOOmL
Instrument Name:
E-IIRMS-03
GC Column:
D13-5
Data File Name:
P108141
Blank File Name:
P108229
ICAL Date:
07/29/09
Cal Ver. File Name:
P108137
Ion
Dilution
Analyte Name
Result Q
EDL MRL
Ratio
RRT Factor
2.3,7.8-'1 CDD
ND U
0.628 10.0
I
Spike
Cone.
Control
Ion
Labeled Compounds
Conc.(pg)
Found (pg) %lice Q
Limits
Ratio RRT
13C-2.3,7.8=FCDD 2000 1266.189 63 25-164 0.77 1.008
37CI-2.3.7.8-TCDD 800 707.237 88 35-197 NA 1.009
Comments:
Printed 4/19/10 7:02 Form IA
\Unnox2\tiurlimsLLJ9rcflzozQMaly13mlRepon. rpt 16 Ot 28 SumSel Referenee. 10-OOWI40151 re, W
UUl J6 22

COLUMBIA ANALYHCAL SERVICES. INC.
_
Analytiitll Report
Client:
Domtar Industries
Scrvice Request
J1001458
Project
Plymouth Storm�carcr'I estine
Date Collected:
NA
Sample Matrix:
Water
Date Received:
NA
Sample Name:
Method Blank
Units:
pg/L
Lab Code:
EQ1000162-01
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofuraus by HRCC/HRMS
Analytical Method:
1613B
Date Analyzed:
4/14/101344
Prep Method:
Method
Date Extracted:
4/2/10
Sample Amount
1000ml-
Instrument Name:
E-IIRMS-03
CC Column:
DB-5
Data File Name:
P108229
Blank File Name:
P108229
[CAL Date.
07/29/09
Cal Ver. File Name:
P108221
Ion
Dilution
Analrte Name
Result Q 1:1)1. MRL Ratio
RRT Factor
2.3.7.8-FC1)D
ND U 034,1 10.0
1
Spike Cone. Control Ion
Labeled Compounds Cone.(pg) Found (pg) %Rec Q Limits Ratio RRT
13C-2.3,7,8-ICDD
37C1-2.3.7.8= PCDD
Comments:
2000 1580.890 79 25-164 0.79 1.007
800 745.963 93 35-197 NA 1,008
Printed 4/19110 7:02 Fnnn IA
t`now2""-"jTftl�Fg1y1i�1Repon.rpt 17 of 28 Sup rSn Werenm. 10-0000140151 m, 00
23

Services -
Accuracy and Precision
19408 Park Row, Suite 320, Houston, 7X 77084
Phone [phone] Fax [phone]
www.caslab.com
An EmDlovee Owned Comm
J1001458 18 of 28 24

COLUMBIA ANALYTICAL- SERVICES, IN(
19
QAiQC Report
Client:
Dominr Industries Senice Rcyuest:
J1001458
Project:
Plymouth Slormaater Testing DateAnal)%ed:
4/6/10-
Sample Matrix:
Water
4/ 7/10
Lab Control Sample Summary
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IlRCC/IIRMS
Analytical Method:
1613E Units:
pg/L
Prep Method:
Method Basis:
NA
Extraction Lot:
108678
Lab Control Sample Duplicate Lab Control Sample
EQ 1000162-02 EQ 1000162-03 % Rec
RPD
Analyte Name
Result Expected % Rec Result Expected % Bee Limits
RPD Limit
2.3.7.8-'I'CDD
211 200 105 217 200 108 67 - 158
3 50
Commenl5:
PnwM 4/19110 7.03 Lab Cora.) Sample Swnmary
wnfl r2� smrums%LjT& rXefontrolSample.rpt 19 of 28 Superset Reference: 10-0000140151 rev 00
25

COLUMBIA ANALYTICAL SERVICES, INC.
AnalytiRg Repon
Client:
Domtar 111dll5tr1e5
Service Request:
.11001458
Project:
Plymouth Stormwater Testing
ILttc Collected:
NA
Sample Matrix:
Water
Date Received:
NA
Sample Name:
Lab Comrol Sample
Units:
pg/L
Lab Code:
EQ1000162-02
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzol'urans by HRCC/HRMS
Analytical Method:
1613B
Date Analyzed:
416/10 1618
Prep Method:
Method
Date Extracted:
4/2/10
Sample Amount:
10o0mL
Instrument Name:
B-FIRMS-03
GC Column:
DB-5
Data Pile Name:
P108108
Blank File Name:
PI08229
IC.AL Date:
07/29/09
Cal Ver. File Name:
P108100
Ion
Dilution
An:dpte Name
Result Q EDI, MRI- Ratio
RRr Factor
2.3.7.8- I'CDD
211 0.698 10.0 0.78
Loll) I
Spike Cone. Control Ion
Labeled Compounds Conc.(pg) Found (pg) %Rec Q Limits Ratio RRT
13C-2,3.7.8=1CDD 2000 1451.362 73 25-164 0.79 1.007
370-2.3.7.8-1'CDD 800 748,083 94 31-191 NA L0U8
Comments:
Pnntd 4/19110 7:02 Fan. IA
twna.?�udhms�yTdff9dWYti°1Rep'° rpt 20 of 28 Sup.Sei Ref ease. 10 M)0140151 sv 00

COLOIBIA ANALYTICAL SERVICES, INC.
Analvu,2ul Report
Client:
Donitar Industries
Sen-ice Request:
/1001458
Project:
PIN mouth Stonnscater Testing
Date Collected:
NA
Sample Matrix:
Water
Date Received:
NA
Sample Name:
Duplicate Lab Control Sample
Units:
pe/1.
Lab Code:
EQ1000162-03
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRCC/IIRMS
Analytical Method:
1613B
Date Analyzed:
4/7/ 10 0312
Prep Method:
Method
—
Date Extracted:
412/10 —
Sample Amount
1000mL
Instrument Name:
E-HRMS-03
CC Column:
DB-5
Data File Name:
P108121
Blank File Name.
11108229
ICAL Date:
07/29/09
Cal Ver. File Name:
P108110
Ion
Dilation
Analyte Name
Result Q
KDL NIIIL
Ratio
RRT Factor
2.3.7.8-1 CDD
217
0.707 10.0
0.76
1.001 1
Spike
Cone.
Control
Ion
Labeled Corn pounds
Couc.(pg)
Found (pg) % Rec Q
Limits
Ratio RRT
13C-2,3.7.8-TCDD 2000 1297.142 65 25-164 0.79 1.008
37CI-2.3,7.8-TCDD goo 670,166 84 31-191 NA 1.009
Comae.o:
Primed 4/19I10 7:02 Form IA
\Unnaw2""\`JTbb1qt'g 1p.lk<,,, pr 21 of 28 SuperSer acfcreru. lo.00aow27 rr. oo

Y" i .,.;
4��� �; r
Chain of Custody
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.casiab.com
J1001458 22 of 28 28

Intra-Network Chain of Custody
9143 Philips IIighway • Jacksonville, F1.3A56 • 904-739-2277 • FAX [phone]
Project Name: Plymouth Stonuwater Testing --1
Project Number:
Project Manager: Diane Hardison
Company: Domtnr Paper Company, LLC
• - n
Sample Date C I \
Lab Code Client Sample 111 # of Cont. Matrix Unlc 'Time Received Send To
J1001458-001 IVDY —Water 3/29/10 OR30� 4/1110 HOUSTON II
11001458-002 LF04 Water 1 3/29/10 1 1055 4/I/l0 HOUSTON II
11001458-003 LF02 Water i 329/10 1120 1 4/I/I0 I4OUSl'ON 11
11001458-004 RY01 Water 3/29/10 � 0950 4/I/10 1IOUS'FON 11
J1001458-005 WRA Water 3(29/10 1005 4/1110 1IOUSTON II
1-- -- - 910 -- ---- - -- -- - - -'r
J1001458-006 LI:03 Walcr 3/29/10 1040 4/I/10 HOUSTON
Special Instructions/Comments
PLEASE SEND
RESULTS TD
MANDY SULLIVAN
I"urin round Requirements
_RUSII (Surcharges Apply)
PLEASE CIRCLE WORT: DAYS
1 2 3 4 5
I'ANDARD
Requested FAX Date:
Requested Report Date: 04/19/10
CAS Contact: Tom Kissinger
Report Requirements
_ I. Results Only
Results +QC Summaries
If. Results + QC and Calibration Summaries
—IV. Data Validation Report wilt Rau Data
PQUMDUJ Y
LED N
Invoice Inturn)anon
J 1001458
to
Relinquished By ,110 A�� l i Received By. t _✓1` of 28 1 byl u r /�5
bN 7y, y���V 2 y 21 Z S" Airbill Number c� ZeC,
%yF 1 ; �- n sw o� e I 1r>�y � L
Q pt'..c r� 1-ic,a,2ti Se L�}(..��7 _.�_.-6�6r�.. w/r, t� P.—I

Columbia Analytical Services, Inc.
Cooler Receipt Form
� rrmt,rorm r
Client/Project: Domtar Paper Com, LLC / Plymouth Stormwater 14 Service Request:
Received: 04/02/10 0945 Opened (Date/Time): 04/02/10 1000 By:
J1001458
EC
I. Samples were received via? ❑US Mail
❑Fedex
QUPS ❑DHL ❑Courier
❑Hand Delivered
2. Samples were received in: (circle) ❑✓ Cooler ❑Box ❑ Other
❑NA
3. Were custody seals present on coolers?
ZY
❑N If yes, how many and where?
1-front
If present, were custody seals intact? ✓❑Y
❑N
If present, were they signed and dated?
ZY ❑N
4. Is shipper's air -bill filed? DNA ❑Y
❑✓ N
If not, record air bill number: 1Z X5W 098 01 4079 2852
5.
6.
T
8.
9.
Temperature of cooler(s) upon receipt ff): 1
If applicable, list Chain of Custody numbers:.
Were custody papers properly filled out (ink, signed, etc.)?
Packing material used: ❑Inserts ❑✓ Bubble Wrap ❑Blue Ice
Were the correct types of bottles used for the tests indicated?
DNA ✓❑Y ❑N
Z Wet Ice ZSleeves ❑Other
Did all bottles arrive in good condition (i.e. unbroken, out of temp.)? Indicate in the table below.
DY ❑N
ZY ❑N
Sample ID
Bottle Count
Bottle Type
Out of Temp
Broken
Initials
❑
❑
❑
❑
El
❑
❑
❑
❑
❑
❑
❑
❑
10. Were all bottle labels complete (i.e. analysis, ID, etc.)? ✓❑Y ❑N
Did all bottle labels and tags agree with custody papers? Indicate in the table below. 0Y ❑N
Sample ID on Bottle Sample ID 6r COC . Sample, ID on Bottle Sample IDon COC•
11. Additional notes, discrepancies, and resolutions:
A 001458 24 of 28
CRF_r092109.pdf Pa e31OL ❑✓ 1 ❑ 2

25
Sample Acceptance Policy
Custody Seals (desirable, mandatory if specified in SAP):
✓ On outside of cooler
✓ Seals intact, signed and dated
Chain -of -Custody documentation (mandatory):
✓ Properly filled out in ink & signed by the client
✓ Sign and date the coc for CASMOU upon cooler receipt
✓ Coc must list method number
✓ If no coc was submitted with the samples, complete a CASMOU coc for the client
Sample Integrity (mandatory):
✓ Sample containers must arrive in good condition (not broken or leaking)
✓ Sample IDs on the bottles must match the sample IDs on the coc
✓ The correct type of sample bottle must be used for the method requested
✓ The correct number of sample containers received must agree with the
documentation on the coc
✓ The correct sample matrix must appear on the coc
✓ An appropriate sample volume or weight must be received
Temperature Preservatives (varies by sample matrix):
✓ Aqueous and Non -aqueous samples must be shipped and stored cold, at 0 to 60C
✓ Tissue samples must be shipped and stored frozen, at-20 to -100C
✓ Air samples can be shipped and stored at ambient temperature, -230C
✓ The sample temperature must be recorded on the coc
✓ Notify a Project Chemist if any samples are outside the acceptance temperature or
have compromised sample integrity - the client must decide re: replacement sample
submittal or continue with the analysis
Cooler Receipt Form, CRF (mandatory):
✓ Cooler receipt forms must be completed for each coc & SR#
✓ Sample integrity issues must be documented on the CRF
✓ A scan of the carrier and the airbill number must be recorded in CAS LIMS
Sample Integrity Issues/Resolutions (mandatory):
✓ Sample integrity issues are documented on the CRF and given to the Project Chemist
for resolution with the client
✓ Client resolution is documented in writing (typically email or on the CRF) and filed in
the project folder(s)
J1001458 25 of 28 31

Service Request Summary
Fulder #:
.11001458
Project Chemist:
Darren Bites
Client Name:
Domtar Industries
Originating Lab:
JA\
['inject Name:
Plymouth Stormwater Tcsting
Logged By:
SLIGHTSGY
Project Number:
Date Received:
4/ 1/10
Internal Due Date:
4/19/10
12epurt To:
Diane Hardison
QAP:
LAB QAP
Domlar Paper Company, I,LC
Qualifier Set
(:.45 Standard.
P.O. Box 747
P.O. Box 47
Formset:
CAS Standard
27962
131vPhone
Merged".:
N
Number:
252-793-8611
liep NJDLumber:
Y
Cell Number:
P.O.N
. Number.
18R4
Fax Number:
252-793-8871
BDD:
No ED
No BUU Specified
E-mail:
diane.hmdiscnnl,dommr.com
sent
� e
c u
CAS Snmp No C'liel Sony Na. Matrix CMIerled 12
JI001458-WI
WUY
R'aier
3/29/10
0830
11
......... .. ..... ....
J1001458-002
..... .... __
LF04
_.. ..
Wwor
.. ...-._....
3129/10
.... .....
1055
II
J1001458-003
LF02
Rater
Y29/10
1120
11
JI001458-004
RY01
R'aler
3/29/10
0950
II
JI001458-005
WRA
Walcr
3129110
1005
II
J1001458-006
LF03
wwK,
3/29110
1040
11
Test Comments:
Croup
Semivoa GCMS
W
N
Test/Niethud
Dioxins Flnans/161313
Samples / Comments
1-6 2378 TCDD only
12 - 1000 in LGless Bole WM AMBER l'c thin Liner 1!npieserurd
Location: In Lab, F,-WIC01
NPDES
/
J1001458 26 of 28
Printed 4119/2010 7:05.42AM Send¢ Request far J 100 1458 Inge 1 01 1

Prep Bunk: 108678
Tcam: Semivoa GCMS/CDONOVAN
Preparation Information Benchsheet
27
Prep WorkPloe': 0rgExtAq(365)
Prep Method: Method
Status: Prepped
Prep DatelTime: 4/2/10 04:00 I'M
N
Lah Code
Client ID
BR
Method Rest
pH
Matrix
Amt. Ext.
Sample Description
I
E1000312-001
MW-10(7-121
.02
I613B/Dioxins Furmrs
7
Water
96nal
orange cloudy liquid
2
1:1000329-001
EPSD-006
01
1613B/Dioxins Furans
6
Water
104010,
clam colorless liquid
3
EI000330-001
B.F. Wall PI.
.01
i613B/Dioxins Furans
7
Ground W.I.
IU80mL
orange cloudy liquid
4
E1000331.001
AC08345
01
16138/Dioxins Furans
7
Water
1020nsl-
gray c loud, liquid
5
EI000333-001
Tem Well 02
01
1613E/Dioxins Purans
7
Water
980m1.
tinted clear liquid
6
EI000333-002
Test Well NI
01
1613B/Diuxius Fuans
7
Water
1020aIL
tinted clear liquid
7
E1000334-001
AC05795
01
16138/Dioxins Furans
7
Water
940m1.
clear colorless liquid
8
EI000335-601
AC05222
.01
1613B/Dioxins Fuans
7
Water
880.1
d-cur colorless liquid
9
EQ1000162-01
MB
1613B/Dioxias Forms
Liquid
I000mL
10
EQIOOU162-02
LCS
I613B/Dio,ma Furors
Liquid
1000.1
II
EQ 1000162-03
DLCS
1613RIDioxim Furans
Liquid
1000nIL
12
J1001458-001
WD}-
.01
1613B/Dioxins Fames
6
Water
96Dnd.
blown cloudy liquid
13
J1001458-002
LF04
01
1613B/Dioxins Furors
5
Water
960mL
yellow cloudy liquid
14
J1001458-003
LF02
01
1613B/Dioxins Furans
5
Water
960ud,
3cio,, cloudy liquid
15
J1001458-004
g}'UI
.01
1613B/Dioxins Furors
5
Water
I000mL
Yellow clear l iquid
16
J100145&005
µ•R.4
01
1613B/Dioxins Furmrs
6
µ"ater
960ad,
ormige cloudy liquid
17
J1001458-006
LF03
III
1613BlDiaxins Fuans
6
Water
I000w1.
beige cloudy liquid
Spiking Solutions
Name: 1613B Matrix Working Standard Inventory ID 16265 Logbook Ref: DII-16-IB Expires On: 03/16/2011
EQ1000162-02 too oopL EQ I000162-03 loonoµl.
Name 8290/1613B Cleanup Working Standard Inventory lD 16581 Logbook Ret. DII-18-4 A/B Expires On 03/31/2011
E1000312-001
ion ouIIL
E1000329-001
Jon. oopL
F:1000330-001
wo OoIIL
E1000331-001
100.0011L
E1000333-001
IOO.00pL
E1000333-002 IOU 00l1L
E1000334.001
IOO.00pL
EW00335-UUI
ion oopL
F-QI000162-01
B10.0011L
EQW00162-02
IOU.00pI.
EQI000162-03
w000pl..
J1001458-UUI twomOlIL
J1001458-002
too oopL
11001458-003
l0o.00frL
J1001458-00.1
100.oaµL
J1001458-005
Ioo.00µl-
J1001458-006
IOO.00fiL
Name: 1613B Labeled Working Standard Inventory Ill 16755 Logbook Rcf-. 1)11-19-211 Expires On: 04/02/2011
I'L00031A001 1000.00µL
E1000329-001 I000 wfuL
E1000330-001 1000.WpL LIW0331-UUI
1.000vOlII
EI000333-001 LOOO.OUIIl, E1000333-002 I000.11U111,
W
131000334-001 I000.quit L
EI0010335-001 IOOU. oopL
EQI000162-01 100o.0oli L, EQ 1000162.02
1,00000pL
EQ1000162-03 I,000oolll, J1001458.001 I.Quo0011L
JI00N58-002 1,000.0Opl.
11001458-003 1000. imp
11001458404 1000,00pL 11001458-U05
I u00. roll1.
11001158-006 10oo.wit
J1001458
27 of 28
Printed 4/6/10 15'11
Nepumlion bdonnaliou Bendshnel
I'uge I

Prep Run#: 108678
Team: Semivoo GCNIS/CDONOVAN
Preparation tihderinis
Acetone 99.50,10hlininmm
C2-34-1(15539)
Glass Wool
C2.13-OO5 t719R)
Sodium l'h WIfi to Anhydrous
U-32-006(13979)
Reagent Gmde NnS203
Didecane(n=rr ifecane)
C2-34.3 (15537)
pH Paper O-14
(1008)
Preparation Steps
Step: ExOactian
Step.
Stared. 4/2110 16.00
Stared:
Finished: 4/3/10 14:30
Finished:
By: ECANALES
By:
Comments:
Preparation Information Benchsheet
28
Prep N orkFlow: OrgExtA(1(365) Status: Prepped
Prep Method; Method Prep Date/]'true: 4/2/10 04:00 I'M
Carbon, High Panty C2-32-005 (13986)
12hy14kcaatc 99.9",' hlininunn
C2-33-2 (14437)
FIOAc
Sulfuric Acid Reagent Grade C2.34-6(15542)
Dichluronrcthane(Methylene
C2-34-1(15540)
H2SO4
Chloidc199.9% NlcCl2
Sodium Hydroxide Reagent C2-24-002(9463)
Stxlimn Stikine Anhydrotu
C2-36-004 (16226)
Grade NaOH
Reagent Grade Na2SO4
Hexane (n-Hexane)98.598 C2-36-002(16224)
Nananc(n-Nnnane)99%
C2-33-001(13944)
Minimum
Silica Gel Reagent Grade C2-31-005 (13998)
'1'alume, 99.95: Minintunt
C2-36-003 (16225)
Acid Clean
Step: Silica Gel Clean
Step:
Final Volans
4/511006:00
Staned: 4/5/IU 12:30
Stared:
4l611U 07.U0
4/51100600
Finished. 4/5/1015: 10
Finished:
4t61011.49
ECANALES
By: ECANALES
E5':
ECANALES
Ru�wcd BY EC Date 4 / 6 / 10
A
Chain ol'CustuJy
Re ,trashed By: Date _
E.Vrnas lixaminnl
Received By: Dale: 1'cs Nu
inrilAelt ?A M ?A
Ptinted 4/6/IU 15:11 Preparation Information HeOeItallcel Page 2

It nil begins wilt paper:
Dointar Papet Company, LLC
Plymouth Mill
PO Box 747
Highway 149 North
Plymouth, NC 27962
T 2S2-793-3111
www.domta, com
April 15, 2010
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
Certiiuerl Mail
Return Receilmy Requested
Subject: NPDES Permit # NCS0001 B9, Year I — Period 2 Mouiioria, Period February
1, 2010 io July 31, 2010. Required Stornnoater Analyses for Domtar Paper Company,
LLC, Ply7uouth, North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed " Stormwater Discharge
Monitoring Report' for the Year 1 — Period 2 Monitoring Period designated fiam February 1,
2010 to July 31, 2010. An attempt was made to collect a sample from each of the remaining
designated outfalls; however, there was no flow present at five of the outfalls. As a result, this
report only includes 2 of the remaining 7 required sampling locations required by Domtai's storm
water permit No. NCS0001 89. We will make every attempt to sample the remaining 5 locations
during subsequent representative storm events before the end of the period.
The TSS and COD sample results for sampling location WYN were 169 ni and 3091rg/L,
respectively, which exceeded the benchmark value in our permit This is the second exceedancc
for COD at this outfell so the tier two requirements will be implemented. As a result of these
parameter exceedarices, a meeting and field inspection was conducted per the action steps
required by the permit The report fion1 that meeting is included and further discusses what other
actions need to be taken.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, tamika.booneQdomtar.com.
Sincerely,
Oi Vc� �lyl
Tamika Boone
Environmental Engineer
Xc: Department files

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC SOOD189 or
Samples Collected During Calendar Year 2010
Certificate of Coverage Number: NCG
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
FACILITY NAME Donner Paper Company, LLC
COUNTY Martin and Washington
PERSON COLLECTING SAMPLE(S) Lorenza Palin & Alan Barnes
PHONE NO, [phone]
CERTIFIED LABORATORY(S) Columbia Analytical Lab# 527
Domtar Paper Company Co, LLC Lab# 171
(SIGNATURE OF PERMITTEE OR DESIGNEE)
Wastewater Lab -Plymouth
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
Part A: Specific Monitoring Requirements
Outfall'.
No.
Date `.
Sample .Duration
Collected #
Event
t
Hi::Min
Total
Rainfall-,"','-
Inches , .7
BOD
; ' `'�` w
m illa
COD f T
rz ;~ -- 4r
m !1
TSSTs_ rt
3-•ti,,a^r
PH�`.f fir`
.,-1., s
Dioxin T i'
,u,7Ny�c, ,"'E
s ""
#"-z !
f +
•� :,
_x
'
mm/dd/ r
OBA
3/11/2010
IA6
2
25
9
7.9
Not detected
WYN
3/12/2010
1.16
9
309
169
7.2
Not detected
I
L
I
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? Yes No
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitorinq Requirements
Outfall )
No.
Date._ ' v;S'
Sample .
Collecte
50050 "... -
556 � "`�
530
Total Flow
Oil and t,
_-
Total i J, c
ended ,
pH r r„
-. -
New Motor
OiUs�a-
ges
+
mo/dd/yr .,..
MG '.i
irig/I -?
rr5g/I ,
i mt,;
gal/rno
Note: This result for BOB is not valid because the sample was imoropudy diluted during analysis.
Another sample will be taken at this outfal! and BOD will be analyzed again during n subsequent
rain event, during this sampling period.
Note: There is a grage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form S W U-246-051100
SWDOMF• U:\Water\StormwaaASW results\SWAnalylicalPteponFormMarl22010.xis Page 1 of2

STORM EVEN( CHARACTERISTICS:
Mail Original and one copy to:
Division of Water Quality
Date 3/10/10-3/3/12/10
Attn: Central Files
Total Event Precipitation (Inches) 1.16
1617 Mail Service Center
Event Duration (Hours) 32
Raleigh, North Carolina 27699-1617
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
(Date)
Form S W U-246-051100
SWDOMR U:\Water\Stormwater\SW results\SWAnalyticalReporlForm Marl22010.xls Page 2 of 2

fermi: Nurnbe:: NC 50001&5
Certificate ei Coverage Number: NCG
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
e:
FACILI-fY NAM. Domtar Paper Company, LLC
, -ERSON COLLECTING SAMPLE(S) Lorenza Patin & Alan Barnes
C--RTIFIED LABOFi P,TORY(S) Columbia Analytical LabV 527
Domtar Paper Company Co, LLC Labri 171
Wastewater Lab -Plymouth
far: F.: Soecibc Monitoring Reduiremeocs
Samples Collected During Calendar Year 2010
(This monitoring report shall be received by the Division no later than 30 days Iran,
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONE NO: [phone]
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
�OUtfall
9 No.
Date Event Total
Sample , Duration " Rainfall
Collected Hc`Mtn 'Inches
BOD
mq/I_. -
COD z
TSS. vt
..
PH
m /h?, „. at,,
Dioxin '
i
•r '
. OB'.
IWYN
3/11/20101.16
dl212010�I 1.16
2
;:
251
309I
9
169
7.9
7.2
Not detected
Not detected
I
1
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(ii yes, complete 'Par, B)
Par: B: Vehicle Maintenance Activibr Monitoring Remtiremenls
Outlall Date ;150050
556
530 -
400' ,
Flow Oil and '
Totil
pH `.;',
New Motor'
No. < Sample :Total
Collected
! Grease
Sus ,Fended
Oil Usage H
:z,
Solids
_
_
mo/dd/yr +
rVIG :_: mg/I
m6/1
unit
gallmo
t f
t
Yes
'VGi.. ISLII�
To,_ +S l.�i ,. S_ ',:.t.: �F,. y., e v..c JLdi^.. W,tr t.;:•
n ,dii , o .:N. :.L,.r; L.. . -.�.. ✓:. u.J ..:- o tu:, ag i .wring
6G:'�i
Note: There is a grage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
Form SWU-246-051100
SW DOME U9WateAS1ormwasASW results\SWAnaNlicalReportFormMarl2 2010.z1s Page 1 of 2

STORM 'EV'ENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Duality
Data; 3/10/10-3/3/12/16 Attn: Central Files
To.al Event Precipitation (Inches) 1.1£ 1617 Mail Service Center
Event Duration (Hours) S2 Raleigh, North Carolina 27699-1617
(ir were Than one storm event was sampled)
Date
Toe! Event Precipitation (Inches)
event Dvrmion (Flours)
"I certify, under penalty of taw, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure U-mi qualified personnel properly gather and evaluate the information submitted Based on my inquiry of the person:
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belie.-, true, accurate, and complete. I am aware that there are significant Penalties for submitting false information,
including the possibility o'r lines and imprisonment for knowing violations."
(Date)
Form SWU-246-051100
SW DOME: U:\WaleAStormwaler\6W re5ulls\SWAnalyticalRepodFormMar122010AS Page 2 of

LSColumbia
Analytical Services- 9743 Philips Highway, Suite 200 1 Jacksonville, FL 32256 904-739-2277 904-739.2011 fax I www.caslab.com
April 12, 2010
Diane Hardison
Domtar Paper Company, LLC
P.O. Box 747
Plymouth, NC 27962
Laboratory Results for: Plymouth Cluster Rule
Dear Diane:
Service Request No: J 1001227
Enclosed are the results of the sample(s) submitted to our laboratory on March 17, 2010. For
your reference, these analyses have been assigned our service request number J1001227.
All analyses were performed according to our laboratory's quality assurance program. The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc.
(CAS) is not responsible for use of less than the complete report. Results apply only to the items
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report.
Please contact me if you have any questions. My extension is 4408. You may also contact me
via email at [e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
Tom Kissinger
Project Manager Z q
Page 1 of
CAS Jacksonville is NELAC-accredited by the State of Florida, 4E82502. Other state accreditations
include: Georgia, 9958; Kentucky, 963; Louisiana, #02086, North Carolina, 4527; South Carolina,
#96021001; Texas, 9T104704197-09-TX

Aient: Domtar Paper Companv. LLC
'roject: Plymouth Cluster Rule
Service Request: J1001227
SAMPLE CROSS-REFERENCE
SAMPLE #
CLIENT SAMPLE ID
DATE
TIME
J1001227-001
Old Borrow
3/11/10
14:48
31001227-002
North Woodyard
3/12/10
14:50
2
rinted 4/12/10 7:19 Sample Summary Page I of I

,06Xanumem
Columbia Analytical Services, Inc.
tooter Keceipt corm
Client:
Q(X✓1lar
Service Request #:
�c,`on `-a
Project.
p
Cooler received
on 37l)
and opened on 3l/o/,o
by S�
COURIER:
CAS UP FEDEX Client
Other
Airbill # JZ Y2� `SXnr?/�
I
Were custody seals on outside of cooler?
tie No
If yes, how many and where?
--
# C on Id other
2
Were seals intact and signature and date correct?
es� No N/A
3
Were custody papers properly filled out?
es No N/A
4
Temperature of cooler(s) upon receipt (Should be 4+1< 2 degrees Q
d
Thermometer ID
6
Temperature Blank Present?
'es
No
7
Were Ice or Ice Packs present
(ce
ice Packs
8
Did all bottles arrive in good condition (unbroken, etc....)?
No
N/A
9
Type of packing material present
riba)o �Aa_
10
Were all bottle labels complete (sample ID, preservation, etc....)?
No
N/A
11
Did all bottle labels and tags agree with custody papers?
yj2
No
N/A
12
Were the correct bottles used for the tests indicated?
No
N/A
13
Were all of the preserved bottles received with the appropriate preservative?
Yes
No
CpI
HNO3 pH<2 H2SO4 pH<2 ZnAc2/NaOH pH>9 NaOH pH>12
HCl pH<2
Preservative additions noted below
14
Were all samples received within analysis holding times?
(Yes
No
NiA
15
Were VOA vials checked for absence of air bubbles? If present, note below
Yes
No
t9TS
16
Where did the bottles originate?
OAZ
Client
Sample ID Reagent Lot # ml added 11nitials Date/Time
comments and/or explanation of all discrepancies noted above:
No
Client approval to run samples if discrepancies noted: Date:

Aaw,nma Jacksonville Laboratory
�i1jt1c Condition Upon Receipt - Sample pH
Senicr�•, ^^
. SR a'J `DOk-)� _ Date: 1 /ia Initials:_
Note that pH is check and meets the required kill criterion listed in the column heading unless otherwise noted on the water receipt faint.
[,Req
001
-002
-003
-004
-005
-006
-007
-008
009
-010
-011
-012
-013
-014
-015
-016
-017
-018
-019
020
g2,
-022
-023
-024
-025
-026
-027
-028
-029
03g
-031
-032
-033
-034
-035
-P'036
-037
-036
039
-040
EIMM
�ee�e_�eee��eaeaeeeeeaa�e��_ea�a
EMIll
E
GGaEEEa
�EEGGEGE�C�G
EEG=
EG
GBGGE
EEEGGE_
E_=EB
�
CC
EEE
C
as
E-�
Ea
E__
a
EEIMM
E
_
_G
_____
-
-a-Ea
EE
a-
E
EEEGGGE
G
___
E
GEEGGIM
MMIMEaaEGE
E-EE
EEEEEE-E-EE_EEE
E
E
a
E
a
G_
_
E
___
aGG�
__
EEGG_
�GBBEEEEGEGBGEE
__
E
-
---
E_
---
-
--
EE_EE
_
_
__
_E
___
_
E
E
_
a
EE
G
EE
_
_
EEE
a
E_p_==
aGEIM
EGG
E
E__
EB
_G__
EE_
_
E_G_
_
E
a
___
___G_
E
E
G-mGEEGE�E
�GEGG
-E-aE-EEGG
-E_E_
_E_��----EMEE_
001
002
003
004
005
006
007
008
009
010
O,,
012
013
014
015
016
017
018
019
020
021
022
323
)24
)25
)26
)2'1
)28
)29
)30
)31
32
33
)34
)35
)36
)37
)36
)39
)40
NO E: VOA pH checks are Performed by the analytical area, not sample wn6ol

an
®Y
Columbia
An,Wital
Services"
CHAIN OF CUSTODY / LABORATORY ANALYSIS REQUEST FOR]
9143 Philips It ighway, Suite 200 Jacksonville, Florida 32256/Phone[phone]/Fax [phone]
Project Name
Plymouth Cluster Rule
Project Number
ANALYSIS REQUESTED (Include Method Number and
Preservative
I
101
Preservative Key
Report To
Diane Hardison
Report CC
Alan Barnes
rn
c4
Q
Z
O
Q
uJ
z
x
p
0. None
L HCL
2. HNO3
3. H2SO4
4. Na0H -
5. 2, Acetate
6. McOH
7. NvHSO4
REMARKS
Company/Address
Domtar Paper Company
P.O. Box 747
Plymouth, NC 27962
Phone 9
252-793-8611
FAX N
252-793-8871
Sampler's Signature
Sampler's Printed Name
CLIENT SAMPLE ID
LAB ID
SAMPLING
DATE TIME
Matrix
Old Borrow
Dioxin
3/11/10
2:48 PM
Water.
2
X
North Woodyard
Dioxin
3/12/t0
2:50 PM
Water
2
X
Special Analysis for stOrmWater testing.
TURNAROUND REQUIREMENTS
RUSH (SURCHARGES APPLY)
X STANDARD
REQUESTED FAX DATE
REQUESrE.DREPORI DAN
REPORTREQUIREMENTS
I. Roans Only
II. Rcxult,.QCSummoi,i
(LCS. DUP. MS/MSDvs rryui.)
X 111.0.auhs`QC aM Gliarvlion 5ummenn
W. Dau Velidmian R,o vilh Raw Dal.
Edala Yes No
INVOICE INFORMATION
Poo
Hill lo:
Relinquished By
Signature
R eived By
e
SignaturZia
Relinquished By
$ignaNre
I
Received By
Signature
RelinquishedBy
Signature
Received By
Signature
Printed Naltle I
PJ
Pr ame
'Printed Name
Printed Name
Printed Name
Printed Name
Firm
Firm
Firm
Firm
Firm -
Firm
DatefFime
Date/h'
2/ S
Dale rime
DatelFime
Date/Fime
DatcTme

��Columbia
Analytical Services -
Appendix A
Columbia Analytical Services
9143 Philips Highway, Suite 200
Jacksonville, FL 32256
Tel [phone]
Fax [phone]
Subcontracted Analytical Results
M

Columbia 1
41fAS
Analytical Services- 19408 Park Row, Suite 320. Houston, TX 77084 1 713.266.1599 f www.caslab.com
April 9, 2010
Tom Kissinger
Columbia Analytical Services
9143 Philips Hwy, Suite 200
Jacksonville, FL 32256
Laboratory Results for: Domtar Paper Company, LLC
Dear Tom:
Service Request No: J1001227
Enclosed are the results of the sample(s) submitted to our laboratory on March 19, 2010. For
your reference, these analyses have been assigned our service request number J1001227.
Analyses were performed according to our laboratory's NELAP-approved quality assurance
program. The test results meet requirements of the current NELAP standards, where applicable,
and except as noted in the laboratory case narrative provided. All results are intended to be
considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for
use of less than the complete report. Results apply only to the items submitted to the laboratory
for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the
NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any
quantitative analysis will be supplied upon request.
Please contact me if you have any questions. My direct line is 281-994-2954. You may also
contact me via email at [e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
Darren Biles
Project Manager
For a specific list of NELAP-accredited analytes, refer to the certifications section at www.caslab.conl.
An F. rnployee O.vneo Company NELAP Aecredlted i ACIL Seal of Excellence Award I Please consider the environment before printing
J1001227 1 of 23
7

rl ,M1 i Columbia.
Certificate of Analysis
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.casiab.com
J1001227 2 of 23

COLUMBIA ANALYTICAL SERVICES, INC
Client: Domtar Industries
Project: Plymouth Cluster Rule
Sample Matrix: Water
CASE, NARRATIVE
Service Request No.: J1001227
Date Received: 3/19/10
All analyses were performed in adherence to the quality assurance program of Columbia Analytical Services, Inc.
(CAS). This report contains analytical results for samples designated for Tier 11. When appropriate to the method,
method blank results have been reported with each analytical test.
Sammle Receipt .
Two water samples were received for analysis at Columbia Analytical Services on 3/19/10.
The samples were received at I °C in good condition and are consistent with the accompanying chain of custody
form. The samples were stored in a refrigerator at 4°C upon receipt at the laboratory.
Please note the reporting forms are currently referencing the date CAS- Jacksonville received the samples (3/17/10)
and not the date CAS -Houston received the samples (3/19/10.)
Data Validation Notes and Discussion
MS/DrvIS
EQ1000140: Laboratory Control Spikc/Duplicate Laboratory Control Spike (LCS/DLCS) samples were analyzed
and reported in lieu of an MS/DMS for this extraction batch. The batch quality control criteria were met.
Detection Limits
Detection limits are calculated for each congener in each sample by measuring the height of the noise level for each
quantitation ion for the associated labeled standard. The concentration equivalent to 2.5 times the height of the
noise is then calculated using the appropriate response factor and the weight of the sample. The calculated
concentration equals the detection limit.
.Zv f- 7
Approved by: 1 ,
Xiangqiu Liang, Laboratory Director
J1001227 3 of 23
Date:04/09/10

4
Client: Domtar Paper Company- LLC Service Request: 31001227
Project: Plymouth Cluster Rule
SAMPLE 4
11001227-001
11001227-002
CLIENT SAMPLE Ill
Old Borrow
North Woodyard
SAMPLE CROSS-REFERENCE
DATE TIME
3/11/10 14:48
3/12/10 14:50
J1001227 4 of 23
Prime) 40110 7:58 Sample Summary 10 PaSc I of 1

Laboratory Certifications
2009-2010
)!'LA" -'IA
OKDE
2009-25
08/31/10
OREGONO/NELAP
ORELAP
TX200002-006
03/24/10
TENNESSEE
TNDEC
04016
06/30/10
TEXAs/NELAP
TCE
T104704216-09-TX
06/30/10
UTAH/NELAP
UTELCP
COLU2
06/30/10
SOIL IMPORT PERMIT
USDA
P330-09-00067
03/27/12
WASHING'I'ON/NELAP
WA-Ecolo
C1855
11/14/10
WEs'r VIRGINIA
WVDEP
347
06/30/10
Jl DO1227 5 of 23

6
Abbreviations, Acronyms & Definitions
Cal
Calibration
Conc
CONCentration
Dioxin(s)
Polychlorinated dibenzo-p-dioxin(s)
EDL
Estimated Detection Limit
EMPC
Estimated Maximum Possible Concentration
Flags
Data qualifiers
Furan(s)
Polychlorinated dibenzofuran(s)
g
Grams
ICAL
Initial CALibration
ID
IDentifier
Ions
Masses monitored for the analyte during data acquisition
L
Liter (s)
LCS
Laboratory Control Sample
DLCS
Duplicate Laboratory Control Sample
M13
Method Blank
MCL
Method Calibration Limit
MDL
Method Detection Limit
MRL
Method Reporting Limit
mL
Milliliters
MS
Matrix Spiked sample
DMS
Duplicate Matrix Spiked sample
NO
Number of peaks meeting all identification criteria
PCDD(s)
Polychlorinated dibenzo-p-dioxin(s)
PCDF(s)
Polychlorinated dibenzofuran(s)
ppb
Parts per billion
Ppm
Parts per million
ppq
Parts per quadrillion
ppt
Parts per trillion
QA
Quality Assurance
QC
Quality Control
Ratio
Ratio of areas from monitored ions for an analyte
% Rec.
Percent Recovery
RPD
Relative Percent Difference
RRF
Relative Response Factor
RT
Retention Time
RRT
Relative Retention Time
SDG
Sample Delivery Group
S/N
Signal -to -Noise ratio
TEF
Toxicity Equivalence Factor
TEQ
Toxicity Equivalence Quotient
J1001227 6 of 23
12

7
Data Qualifier Flags - Florida DEP
o V Indicates the associated analyte is found in the method blank, as well as in the sample
o U Indicates the compound was analyzed and not detected
o N Indicates 2378-TCDF was confirmed on a DB-225 column. Everytime 2378-TCDF is detected on
the DB-5 column, confirmation analyses are performed on a second column (DB-225.) The
results from both the DB-5 column and the DB-225 column are included in this data package.
The results from the DB-225 analyses should be used to evaluate the concentration of 2378-
TCDF in the samples. The confirmed result should be used in determining theTEQ value for
TCDF.
o L Indicates an estimated value and is used when the analyte concentration exceeds the upper
end of the linear calibration range. The actual value is known to be greater than the reported
value.
o I Indicates an estimated value and is used when the reported value is between the estimated
detection limit (EDL) and the method reporting limit (MRL)
o J Indicates an estimated concentration and is used when the ion abundance ratios associated
with a particular compound are outside their acceptance criteria. A'J' Flag indicates an
estimated maximum possible concentration (EMPC) for the associated compound.
J1 001227 7 or 23
13

e
CAS/HOU - Form Production, Peer. Review & Project Review Signatures
SR# Unique ID 7 16 p / 7-1-3
•
Date Person 1
Date Person 2
Date O, / f O Primary Data Reviewer C �, Z)
�f 6
Date Secondary Data Reviewer
Date 4/9/10 Reviewer �D
J
I
I
i
i
i
i
i
i
1
I
i
I
i
J1001227 8 of 23
J
DAIViEV SIGI(3I202010)

J1001227 9 of 23
15

COLUMBIA ANALYTICAL SERVICES, INC.
AnulytiAl Report
Client:
Domtar Industries
Project:
Plymouth Cluster Rule
Sample Dlatrix:
Water
Sample Name:
Old Borrow
Lab Code:
J1001227-001
Service licyucet: J1001227
Date Collected: 3/11/10 1448
Date Received: 3/17/10
Units: pg/L
Basis: NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzoturans by DRGC/FIRMS
Analytical Method: 1613B
Prep plcthod: Method
Ion Dilution Date Time Date
Analyte Name Result Q F,DL MRI, Ratio RRT Factor Analyzed Analyzed Extracted
2,3,7,8-TCDD
NO U
0.189
10.3
1
3/25/10 2257 3/23/10
Spike
Conc.
Control
lon
Labeled Cnmyaunds
Conc.(pg)
Found (pg)
%Rec Q
Limits
Ratio
RRT
13C-2,3,7,8=TCDD
2000
1315,123
66
25-164
0.81
1.010
37CI-2,3,7,8-TCDD
800
732.284
92
35-197
NA
1,011
C'ouunc.w
11, hat d 4/9/I0 7:56 Fur. IA
Wrnow2%Starims1 ��cl R fty ic.IRe,a 10 of 23 Su,,Sn Reference: la DC139279 ne W
UU1LL 16

COLUMBIA ANALYTICALSERVICES, INC.
Analyti2al Relnrt
Client:
Dointar Industries
Project:
Plymouth Cluster Rule
Sample \lalrix:
Water
Sample came:
North Woodyard
Lab Code:
J1001227-002
Service Request:
J1001227
Date Collected:
3/12/10 1450
Date Received:
3/17/10
Units:
pg/L
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRGC/IIRNIS
Anah'lical Mclbod: 1613R
Prep Method: Method
Ion Dilution Date Time Date
Anah'le Name Result Q EDL AIRL Ratio RRT Factor Analyzed Analyzed Extracted
2,3,7,8-TCDD
ND U
0.229
10A
1
Y25/10 2345 3/23/10
Spike
Cone.
Control
Ion
Labeled Cmnpoun&
Cooc.(pg)
Found (pg)
%Rec Q
Limits
Ratio
RRT
13C-2,3,78=TCDD
2000
1071.416
54
25-164
0.80
1,010
37C'I2,3,7,8=TCDD
800
704.268
88
35-197
NA
1.011
( �nts:
Printed J19110 256 Form IA
-lln l—VNF,, i,nsllJ4�s� IpicilR<pnn TI 11 of 23 Sup rSct Reference: 10.0000139179 ov W
17

COLUMBIA ANALYTICAL SERVICFS, INC.
Analytia Report
Client: Donnar Industries Service Request: J1001227
Project: Plymouth Cluster Rule Date Collected: NA
Sample Matrix: Water Date Received: NA
Sample Name: Method Blank Units: pg/L
Lab Code: EQ1000140-01 Basis: NA
Polychlorinated Dibenzudioxins and Polychlorinated Dibenzofurans by IIROC/HRMS
Analvtical Method: 1613B
Prep Method: Method
ton Dilution Date Time Date
Analyse Name Result Q EDL MR1. Ratio Rwr Factor Analyzed Analyzed Extracted
2,3,7,8-TCDD ND U 0,199 10.0 1 3/25/10 1942 3/23/10
Spike Cone. Control ]on
labeled Cnugml'lals Conc.(pg) Found (pg) %Rcc Q Limits Ratio RRT
13C-2,3,7,8=TCDD 2000 1559203 78 25-164 0.78 1.010
37CI-2,3,7.8-TCDD 800 827.988 103 35-197 NA 1.011
en,n,nevrs:
11ri nlcd 419110 7.56 N. LA
\\InOowTS�adlms�Lj~tsReq��n�.lylicalRepnrt.ry� 12 of 23 SuperSa Reference: IO-OONU9279 re. 00
1 UU LL 8

J1001227 13 of 23
19

Client:
Project:
Sample Matrix
Analytical Method
Pi cp Method:
\An:dyte Name
2,3,7,8= FCDD
18®
COLUiMBIA ANALYTICAL SERVICES, INC.
14
QA/QC Report
Dormar Industries
Plymouth Cluster Rule
Water
Service Request:/1001227
Date Analyzed: 3/26/10
Lab Control Sample Summary
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRCC/IIRMS
1613B Units: pg/L
Method B ' NA
Lab Control Sample
EQ 1000140-02
Result Expected % Rec
218 200 109
as1s.
Extraction [,of: 107877
Duplicate Lab Control Sample
EQ 1000140-03 % Rcc RPD
Result Expected %Rec Limits Rill) Limit
218 200 109 67 - 158 0 50
11iimed 419110 7:57 Lab COIIIl01 Sample Summary
tunnnwa9unnn,lL��, 1z �eon„ols.mol..m� 14 of 23 S.,,Set Rdulnc, 10 NW139279 m 00
20

COLUMBIA ANALYTICAL SERVICES, INC.
Analytidl� Report
Client:
Domtar Industries
1'rojece
Plymouth Cluster Rule
Sample Matrix:
Water
Sample Name:
Lab Control Sample
Lab Code
EQ1000140-02
Service Request:
/1001227
Date Collected:
NA
Date Received:
NA
Units:
pg/L
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzol'urans by HRGC/IHLMS
Analytical Method: 1613B
Prep Method: Method
Ion Dilution Date Time Date
Analyte Name Result Q EDL MRL Ratio RRT Factor Analyzed Analyze) Extracted
2,3,7,8-TCDD
218
0.182
10.0
0.77 1.001
1
3/26/10 0437 3/23/10
Spike
Cone,
Control
Ion
Labeled Conl pounds
Conc.([tg)
Found (pg)
%Rec Q
Limits
Ratio
RRT
13C-2,3,7,8=TCDD
2000
1556.164
78
25-164
0.80
1.010
37CI-2,3,7,8=TCDD
800
850.460
106
31-191
NA
1,011
8
Cnmmen ":
Primed 4I9/10 7.56 Fnrm IA
\\Inlluu3t6�mOmflLJ�aaegsLloalY�ical0.epun rpr 5 of 23 S,,"sef aefe'm0 e: 10-OOOO 393]9 rev 00
UU LLB 1
21

COLUMBIA ANALYTICAL SERVICES, INC.
AnalyflA Report
Client:
Domtar Industries
Service Request:
J1001227
Project:
Plymouth Cluster Rule
Date Collected:
NA
Sample Matrix:
Water
Date Received:
NA
Sample Name:
Duplicate Lab Control Sample
Units:
pg/L
Lah Code.
EQ1000140-03
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRCC/IIRAIS
Anah'lical Mcthod: 1613U
Prep Method: Method
Ion Dilution Date Time Date
Anahte Name Result Q EDL MRL Ratio RRT Factor Analyzed Analyzed Extracted
2,3,7,8-TCDD
218
0,148
10.0
0.76 1.001
1
3/26/10 0526 3/23/10
Spike
Colic.
Control
Ion
Labeled Compounds
Cone.(pg)
Found (pg)
%Rec Q
Limits
Ratio
RRT
13C-2,3,7,8-TCDD
2000
1544.452
77
25-164
0.77
1.010
37CI-2,3:7,8-'TCDD
800
818547
102
31-191
NA
1.011
co...
Primed 419110 7:56 y Ponn IA
°n0u""'1a" "J9 9 1Y1iC'laePO"� 16of23 S.,,SaRefo.: 10 139179irW
22

17
Services -
Chain of Custody
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.caslab.com
An Emolovee Owned Comoonv
J1001227 17 of 23
23

Project Name: Plymouth Cluster Rule
Project Number:
Prujcel %tanager: Diane Ilurdison
Company: Domtar Paper Compamy, LLC
Intra-Network Clain of Custody CAS Contact Torn Kissinger
9113 Philips Highway - Jacksonville, H. 324g6 • 904-739-2277 • FAX [phone]
F_]
Sample
Date
Lab Code
Client Sample ID #of ConL
Matrix
Date 'Time
Received
Send-1
11001227-001
Old Borrow
i Wamr
3/11/10 1448
J/17/10
HOUSTON
J1001227-002
North Woodyard
Water
3/12/10 I 1450
1 3/17/10
HOUSTON
Test Comments
Dioxins Pur:ms - 1613R 11001227-001.2 Report 2378'I'CDD only
Special Instructions/Comments
_ A SE S E N D
Turnaround Requirements
_RUSH (Surcharges Apply)
YLEASF. CIRCLE WORE DAYS
Report Requirements
1. Results Only
_ ❑. Results +QC Summaries
Invoice Information
pp#
E S U L T S T D
1 2 3 4 5
_ III. Results +QC and Calibration Summaries
J 1001227
D I SULLIVAN
_ STANDARD
_ IV. Data Validation Report with Rmv Data
Bill to
'
Requested FAX Date:
PQUMDUI Y
N
EDD N
Requested Report Date: 04/07/10
(/P—>
Relinquished 11 Received By: C�./.LI _ �9"1 Airbill Number: i �. XSw 090, OI 4?L9 63g1
.�aea,xr o� 3ffer /�
/-c'A"J5 Sa l f"I 611171'u t.✓rc.y Page l
Wea ff-L

iReset Form ,'-..
Columbia Analytical Services, Inc.
Cooler Retceipt Form
Client/Project Domtar Paper Company LLC/ Plymouth Cluster Fjy Service Request:
Received: 03/19/10 0945 Opened (Date/Time): 03/19/10 0945 By:
A 001227
EC
I. Samples were received via? ❑US wail ❑Fedex OUPS ❑DIIL []Courier
❑Ilnnd Delivered
2. Samples were received in: (circle) ECooler ❑Box ❑ Other
❑tVA
3. Were custody seals present on coolers? DY ❑N If yes, how many and where?
1-front
If present, were custody seals intact? 2)Y ❑N If present, were they signed and dated?
DY
❑N
4. Is shipper's air -bill filed? DNA ❑Y ON If not, record air bill number: I X5W 098 01 4269 6391
5. Temperature of cooler(s) upon receipt (°C): 1
6. If applicable, list Chain of Custody numbers:
7. Were custody papers properly filled out (ink, signed, etc.)?
DNA DY
❑N
8. Packing material used: ❑Inserts OBubble Wrap ❑Blue Ice QWet Ice QSleeves ❑Other
9. Were the correct types of bottles used for the tests indicated?
QY
❑N
Did all bottles arrive in good condition (i.e. unbroken, out of temp.)? Indicate in the table below.
ZY
❑N
Sample ID
Bottle Count
Bottle Type'
Out of Temp
Broken
Initials
El
❑
❑
❑
❑
❑
❑
10. Were all bottle labels complete (i.e. analysis, ID, etc.)? DY ❑N
Did all bottle labels and tags agree with custody papers? Indicate in the table below. Ply ❑N
Sample ID on Bottle
Sample,ID:on COC, `.
SampleID.on Bottle
Sample ID,on COC;
1 I. Additional notes, discrepancies, and resolutions:
A 001227 19 of 23
CRF_r092109.pd1
Page 0 1 ❑ 2

20
Sample Acceptance Policy
Custody Seals (desirable, mandatory if specified in SAP):
✓ On outside of cooler
✓ Seals intact, signed and dated
Chain -of -Custody documentation (mandatory):
✓ Properly filled out in ink & signed by the client
✓ Sign and date the coc for CASMOU upon cooler receipt
✓ Coc must list method number
✓ If no coc was submitted with the samples, complete a CASMOU coc for the client
Sample Integrity (mandatory):
✓ Sample containers must arrive in good condition (not broken or leaking)
✓ Sample IDs on the bottles must match the sample IDs on the coc
✓ The correct type of sample bottle must be used for the method requested
✓ The correct number of sample containers received must agree with the
documentation on the coc
✓ The correct sample matrix must appear on the coc
✓ An appropriate sample volume or weight must be received
Temperature Preservatives (varies by sample matrix):
✓ Aqueous and Non -aqueous samples must be shipped and stored cold, at 0 to 60C
✓ Tissue samples must be shipped and stored frozen, at -20 to -10°C
✓ Air samples can be shipped and stored at ambient temperature, -230C
✓ The sample temperature must be recorded on the coc
✓ Notify a Project Chemist if any samples are outside the acceptance temperature or
have compromised sample integrity - the client must decide re: replacement sample
submittal or continue with the analysis
Cooler Receipt Form, CRF (mandatory):
✓ Cooler receipt forms must be completed for each coc & SR#
✓ Sample integrity issues must be documented on the CRF
✓ A scan of the carrier and the airbill number must be recorded in CAS LIMS
Sample Integrity Issues/Resolutions (mandatory):
✓ Sample integrity issues are documented on the CRF and given to the Project Chemist
for resolution with the client
✓ Client resolution is documented in writing (typically email or on the CRF) and filed in
the project folder(s)
J 1001227 20 of 23
26

Service Request Sti nmary
Folder At:
.111101227
Project Chemist:
Darren Biles
Client Name:
Donnar Industries
Originating Lab:
JAX
Project Name:
Plymouth Cluster Rule
Logged By:
GBAUER
Project Number:
Date Received:
3/17110
Report To:
Dime Hardison
Internal Due Date:
4/7/10
Dolmar Paper Company, LLC
QAP:
LAB QAP
P O Box 747
Qualifier Set:
CAS Standard
Plymouth, NC 27962
Formset
CAS Standard
Phone Number:
252-793-8611
Merged':
Y
Cull Number:
Report to MDL?:
Y
Fax Number:
252-793-8871
P.O. Number:
4550171884
E-mail:
diane.hardisonndomtaLcom
EDD:
No EDD Specified
Svm
I.o 5
cos same N. cBem camp ran. nmrri= eoneena 2 a
1-
J1001227-001 Old Borrow _.._ Water 3/II/10 1448I 11
.... .... ................... ..._ _ .................. ...._..
11001227.002 Nndlt WoodYnr d Wahr 3/12/10 1450 II
Test Comments:
Group
Semivoa GCMS
Semivoa GCMS
N
v
J1001227
Primed 4/W2010 7:57A2An/
Tut/Method Sumpies
Dioxins Furans/161313 2
Dioxins Furans/1613B 1
Comments
Report 2378 TCDD only
TCDD
21 of 23
Service Request for J1001227
4 . IOW id. -Glass Battle Next AMBER "Teflon Liner Unprascrrved
Location: E-Disposed, E-WIC01
NPDES
Pays I of 1

Prep Runty: 107877
Team: Scinivoa GCMS/AKODUR
Preparation Information Kenchsheet
22
Prep WorkFIeN': OigBIA4(305)
Prep Method: Method
Status: Prepped
Prep Datelfinu': 3/23/10 12130 PM
u
Lab Code
Client ID
B#
Method /Test
pH
I Matrix
Amt. Ext.
Sample Description
1
E1000285-001
10032667-I
01
161390oxins Fears
B
W'ate,
1070mf-
ycllmv cloudy liquid
2
E1000286-001
EPDS :i/GP 100059
.01
1613130omia5 Trans
7
Drinking Water
IIIOmL
clear colorless liquid
3
E10002874tOI
EPDSEI
01
1613B/Dioxim Furors
7
Drinking Wan,
Inherit
c le,o colorless liquid
4
E1000288-001
NN0269 Lake Valle, 2 15'1'-565A IOB60
01
1613B/Dioxins Furans
7
Drinking W'arer
IO IOnd,
yclluw clear liquid
5
E1000289-001
NNO269 Lake Vnlley 1 15'1'-565 101359
01
1613BNirxins Forms
7
Drinking Wnter
1050mL
yellmv clear liquid
6
E1000293-001
WWDR 117
01
1613WDmim Turns
8
D,inking Water
97UmL
yellow clear liquid
7
EQ1000140-01
NAB
1613B/Dioxins Forms
Liquid
IOOOmL
8
EQIOo0140-02
LCS
16138/Dioxins Furans
Liquid
l000r I.
9
EQI000140-03
DLCS
16138/Dioxe, Furans
Liquid
I000.1
10
J1001227-001
Old flcu.w.
01
16138/Dioxins Furors
6
Water
970mL
yclluw clear liquid
11
J1001227.002
North Wood)ard
.01
1613B/Dioxins Finaru
6
Water
990n,L
bmran cloudy liquid
12
K1002504-052
EB-01
01
1613R/Dioxins Forms
5
Wan,
106UmL
tinted clear liquid
Spiking Solutions
Name_ 1613B Matrix Working Standard Inventory ID 16265
EQ1000140-02 too oopL EQ 1000140-03 too ooµL
Logbook Ref: DII-16-1B
Expires On: 03116POI I
Name: 8290/1613B Cleanup Working Standard Inventory ID 16422 Logbook Ref. DI I-17-IA/B Expires On: 03/23/2011
EIOOO285-001 1oo.wpL E1000286-001 too, oopL E1000297-001 itiewµl- EI OW29SAO1 IOo00µL E1000289-001 Ioo.00µl, EI000293-001 too wpL
EQI000140-01 I0000ltL EQ I NO 140-02 1oo Oil EQIW014043 t00. ooµL JI001227-001 100.00µL J1001227-002 too oopL KID02504-052 too oopL
Name. 1613E labeled Working Standard Inventory ID 16427 Logbook Ref: DI1-16-5B Expires On. 03/23/2011
EI000285-0OI 1 oo0.00pL
EQIOOOI40-01 low wµL
Preparation Materials
Acetone 99.5%Minimum
Gloss Wool
�adinm Thiosulfnle Anhydrous
Rwgent Gmde NaS203
Tridecane (n-Tridccmc)
pH Paper 0-14
J1001227
Printed 3/26/10 8:12
E1000286-001 I 0000tpL E1000287-001 Ioo0.0oµL EI000288-001 Io0o00µL EI000_'89-001 I o00.00; L E1000293-001 LowooµL
EQI00014002 LowoofiL EQ1000140-03 Lo00.00µl- Jt00I227-0o1 Low oo llL J1001227-002 Ioriewµl- KI002504-052 Low Onto L
C2-34.1 (15539)
Carbon, High Purity
C2.32-005 (13986)
C2-13-005 (7199)
Sulfuric Acid Reagent Grade
C2-34L (15542)
H2SO4
C2-32-006 (13979)
Sodium Hydroxide Reagent
C2 24-002 (9463)
Dade NaOH
C2-34-3(15537)
Hexmc(n-Hexme)98.5%
C2.36-002(16224)
Mininmm
(1008)
Silica Get Reagent Grade
C2-3 1-005 (13988)
22 of 23
Prcparmion
Information Benchsheel
Ethyl Acetate 99.9%Minimum
C2-33-2(14437)
F:10Ac
Didduromethane (Methylene
C2-34-1 (15540)
Chloride) 999% M[C12
Sodium Sulfate Anhydrous
C2-36-004(162261
Reagent Grade Na2SO4
Nanane (n-Nonmc) 9"16
C2-33-001 (13944)
Toluene W9 /, Mininmm C2-36-003 (16225)
Paµ I

C
Preparation Information Benc'hsheel
23
Prep RtIO:
107877
Prep WorkHow: OfgEalAy(365)
Te:Bn:
SemiYoa GCNIS/AKODUR
Prep Method: Method
Preparation Sleps
Step:
Emractinn
Step:
Acid Clean
Step: Silica Gel Clean
Step:
Final Valumc
Started'.
3/23/101230
Starred:
3/24110 M.00
Started: 3/1411012A0
Started:
3125110 0700
Finished:
3/23/1015: 15
Finished.
3/24110 M 00
Finished: 3/24/1014:W
Finished:
32511013:20
By:
ECANALES
By:
ECANALFS
By: ECANALES
Hy:
ECANALES
Comments:
Reviewed By: ak pate: 3 / 2 6 / 10
IJ
Rain of Custody
Relinquished By: Bate:
Extracts Ennmined
Received By: Bate: Yes No
Staw,: Prepped
Prep Datelfime: 3/23/10 12:30 PNI
Printed 3126/10 8:12 Preparation Information Beuchsheet Pagc'_

1 Domtar Paper Company, LLC
Plymouth Mill
PO Box 747
Domta(�'0..„�
.wy`Highway 49
jj' Plymouth, NCN27962
T 282 793 8111
is all begins with paper: I WWW.domtar.COM
I
April 6, 2010
Division of Water Quality
Attn: Central riles
1617 Mail Service Center
Raleigh, NC 27699-1617
Certified Alai,
Retartt Receipts Repuested
Subject: NPDLS Pet init #NCS0001 89, Year 1— Period 2 Nloiiitoi ing Period Iibruaty
1, 2010 to .1uly 31, 2010. Required Storurlputer ,I ualyses for Doutt(ir Ptq)er Coutpany,
LLC, Plyruouth, North Carolina
Dear Sir(s):
Enclosed you will find the original and one copy of a completed "Stormwater Discharge
Monitoring Report" for the Year 1 —Period 2 Monitoring Period designated from February 1,
2010 to July 31, 2010. An attempt was made to collect a sample from each designated outfall;
however, there was no flow present at seven of the outfalls. As a result, this report only includes 6
of the 13 required sampling locations required by Domtai's storm water permit No. NCS000189.
We will make evety attempt to sample the remaining locations during subsequent representative
storm events before the end of the period.
The TSS sample results for sampling location CL14 and CL1 I were 309 mg/L and 1871ng/L,
respectively, which exceeded the benchmark value in our permit. The pI-I reading for sampling
location NBA was 5.4, which also exceeded the benchmark value. As a result of these
exceedances, a meeting and field inspection was conducted per the action steps required by the
permit The report from that meeting is included and further discusses what other actions need to
be taken.
If you have any questions or require any additional information pertaining to this report, please
contact me by phone, [phone] or by email, tamika.boone(rudonitar.com.
Sincerely,
Tamika Boone
Environmental Engineer
sc: Dcpmtment files

Permit Number: NC SOOO189
Certificate of Coverage Number: NCO
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
or
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Lorenza Palin & Alan Barnes
CERTIFIED LABORATORY(S) C011-linbia Analytical Lab# 527
Dorrear Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Pan A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2010
(This monitoring report shall be received by the Division no later than 30 days from,
the date the facility receives the sampling results from the laboratory,)
COUNTY Martin and Washington
PHONE,NO. [phone]
By this signature, I certify that this report is accurate and
complete to the best of my knowledge
Date .,Z-z
No aSample;
Collected
E-7en't, -
Duration7!
Hc'fvii
air
iric s
0.
�mjoijjyr
YJ
NBA 313/2010
24
1,55
3
48
34
5A
Not detected
3/3/2010
24�
1.SSi
2
16
90
7.6
Not detected
CL14 j itillu i u1
JWLSO-, 3/3/2010
iLF01 j 3/3/2010
24
24
24
1,55
1.55
3
1
32
19
309
3
5,2
6.6
Not detected
Not detected
Not detected
CL11 3/3/2010
24�
1.55
31
16
1871
8,5
Not detected
Does this facility perform Vehicle Maintenance ACTOVItIeS using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
Part B Vehicle Maintenance Activitv Monihorinq Requirements
0,6ff
D 9A 5 60 5 0 5��,
400
T66l:Fl6%v`, �al T61�lii�
So_ -V, I Oil-
*d
llep,cl
JC
mo/dCf/_ z I r
SWCOMr
Yes
No x
Note: There is a garage onsite, however it is fully contained and drains directly to our
wastewater treatment system. Also, there are no outfals located in this area.
U:\WateoStoonwateoSW lesults\SWAnalytica]RepC((FormMar3 2010.xis
Form SVVU-246-051100
Page 1 of 2

STORM EVENT CHARACTERISTICS:
Date 3/2/10-3/3/10
Total Event Precipitation (Inches)
Event Duration (Hours)
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Mail Original and one copy to:
Division of Water Quality
Attu: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27599-1617
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted Based on my inquiry of the person
or persons who manage the system, or those'persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Date)
Form SWU-246-051100
S W DOMR U.\W alerlStormwater)SVJAnalylicalReportFormMar3 2010. xls Page 2 of 2

Siormwater Tier One 1Respouse (Record
Domtar Paper Company, LLC — Plymouth, NC
NPDES StonnwaterPermitNCS000139
1. Outfall — Contractor Layclown Area 11 &14
2. Date of sample collection — March 3, 2010
3. Rain Event total — 1.55 inches
4. Parameter exceeding benchmark value — TSS
o Analyses result— 137 mg/l for CLI I and 309 mg/1 for CL14
o Permitted Benchmark target — 120 mg/l
o Date analyses received — March 13, 2010
5. Date of discussion meeting and stormwater management inspection— March t? 20tO.
Participants:
o Diane Hardison — Environmental Manager
o TamikaBootie— EnvironmentalEngiucer
o Bill Morris —Environmental Engineer
6. Cause of benchmark exceedance—1,Road grading had just occurred prior to rain event.
Loose gravel and sediment was easily washed out.
7. Mitigation Measures considered:
o Silt fence will be added to ditch where water flows offsite. (Silt fences
were Put in place the week of March 15t1i)
o Samples will be taken after runoff has had a chance to flow through silt
fence.
S. Implementation of mitigation measure must be complete by — May 42, 2010
U:\\Va1er\Stomnv.im`tSto, mu Lei Escecdances\Soo Lima ter Tier one Response Record'darch 12 2010.doc Page 1 or 1
Record to be stored kith Stommaler Pollution Prevention flan and Compliance Manual

4ASColumbia
Analytical Services- 9143 Philips Highway, Suite 200 I Jacksonville, FL 32256 1 904-739-2277 1 904-739-2011 fax I www.caslab.com
April 02, 2010
Diane Hardison
Domtar Paper Company, LLC
P.O. Box 747
Plymouth, NC 27962
Laboratory Results for: Plymouth Stormwater Testing
Dear Diane:
Service Request No: J 1001092
Enclosed are the results of the sample(s) submitted to our laboratory on March 9, 2010. For
your reference, these analyses have been assigned our service request number J1001092.
All analyses were performed according to our laboratory's quality assurance program. The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc.
(CAS) is not responsible for use of less than the complete report. Results apply only to the item;
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report.
Please contact me if you have any questions. My extension is 4408. You may also contact me
via email at [e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
// o..,.,,_ C
Tom Kissinger /
Project Manager ��
Page 1 of
CAS Jacksonville is NELAC-accredited 6y the State of Florida, #E82502. Other state accreditation
include: Georgia, #958; Kentucky, #63; Louisiana, #02086, North Carolina, 9527; South Carolina,
496021001, Texas, #T104704197-09-TX

Service Request: J1001092
"lient: Domtar Paper Companv. LLC
'roject: Plymouth Stormwater Testing
SAMPLE CROSS-REFERENCE
SAMPLE ti
CLIENT SAMPLE ID
DATE
TIME
J1001092-001
CL-13
3/3/10
10:10
J1001092-002
CL-11
3/3/10
09:55
J1001092-003
WLSO1
3/3/10
11:03
11001092-004
LF-01
3/3/10
11:15
J1001092-005
CL-14
3/3/10
10:30
J1001092-006
NBA
3/3/10
11:45
2
'rinsed 4/2/10 8:15 Sample Summary Page I of I

Columbia Analytical Services, Inc.
Cooler Receipt Form
Client:
Project:
��x�� CLrL Service Request
51+.3�"nC)
Cooler received on — \O and opened on 3 9 -\3y
COURIER:
CAS tS! FEDEX Client Other
Airbill
# 'y< q a-1
I
Were custody seals on outside of cooler?
Yes
No
If yes, how many and where? on lid other_
2
Were seals intact and signature and date correct?
es
No N/A
3
Were custody papers properly filled out?
Yes
No N/A
4
es
Temperature of cooler(s) upon receipt (Should be 4+/- 2 degrees C) �, \
✓]
d
6
Themiometer ID\
Temperature Blank Present? tics
No
7
Were Ice or Ice Packs present
Ice D
Ice Packs No
8
Did all bottles arrive in good condition (unbroken, etc....)?
No N/A
9
Type of packing material present��
10
Were all bottle labels complete (sample ID, preservation, etc....)?
15s
No N/A
11
Did all bottle labels and tags agree with custody papers?
cs
No N/.a
12
Were the correct bottles used for the tests indicated?
Yc
No N/A
13
Were all of the preserved bottles received with the appropriate preservative?
Yes
No i .4
HNO3 pH<2 H2SO4 pH<2 ZnAc2/NaOH pH>9 NaOH pH>12 HCI
pH<2
Preservative additions noted below
14
Were all samples received within analysis holding times?
Ycs
No NiA
15
Were VOA vials checked for absence of air bubbles? If present, note below
Yes
No N/A
16
Where did the bottles originate?
CAS
Client
Sample ID Reagent Lot # ml added Initials Date/Time

LSra�;min;�i Jacksonville Laboratory
A v nucm
&•nlms^ 1 Condition Upon Receipt -Sample pH
(^ r
` SR d : J ' `� ' � Date: � �—� � � `� Initials:
I
Note that pH is check arM meets the required pH criterion listed in the column heading unless otherwise noted on the cooler receipt farm.
E�q
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
-011
-012
-013
-014
-015
-016
-017
-018
.019
-020
-021
-022
-023
-024
-025
-026
-027
-028
-029
-030
-031
-032
-033
-034
435
36
037
-038
-039
-040
�000�oor000�0000000000000000000®
EMMM
iee�a®aa�aa�vaaeevaveee�e���aa�e
001
002
003
004
005
006
007
008
009
010
011
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
030
031
032
033
034
035
036
037
038
039
040
NOTE: VOA all checks are performed by the analytical area. not sample control

�4. 4
lllllhj8
A11
a1
)4irgl
Services"`
wsv.caslab.com
SRC
CHAIN OF CUSTODY / LABORATORY ANALYSIS REQUEST FORM 5, oo 10�
CAS Contact
9143 Philips I lighway, Suite 200 Jacksonville, Florida 32256/Phone[phone]/SOO-695-72221F'ax 904-739-2011 Page I Of I
Project Name
Project Number
ANALYSIS
REQUESTED
(Include
Method
Numb
Preservative
0
Plymouth Stormwater Testing
Report To
Repon CC
v
Diane Hardison
Alan Barnes
z
L
z
I. HCL
2. HN-03
Company/Address
Q
DOnitar Paper Company
[—
z
O
O
3. H2SO4
4. NaOH
P.O. Box 747
Plymouth, NC 27962
U
p
x
5. Zu. Aceusle
6. ko0H
Phone k
FAX 0
L7
252-793-8611
252-793-8871
c7
J
7. NaHSO4
Sampler's Signature
Sampler's Printed Name
7_
REMARKS
SAMPLING
Minn.
CLIENT SAMPLE ID
LAII ID
DATE TIME
CL-13
Dioxin
3/3/10
D%)D
Water
2
X
CL-II
Dioxin
3/3/10
S+li
Water
2
X
WLS01
Dioxin
3/3/10
//:05
Water
2
X
LF-01
Dioxin
3/3/10
// •l�
Water2
X
CL-14
Dioxin
3G/i0/D:9°
Water
2
X
/.3A
Dioxin
3/3/10
/:f'
Water
2
X
Slormwater sampling for dioxin toiling.
TURNMItOUSD nEQUIRENETTS
REI'QRT REQUIREMENTS
IS'OICE L.SFORMATIOT
��-
4 )
�- �-✓✓
RUSH(SURCHARGESAPPIv)
S >TANmSNU
IL Roulu O Summ n
ILU, x14w4Da,)
POr w To
X III, Rca.iu-$:vW Cet.nrz.- 5ummmo
Bill to:
REQUESTED FAX DATE
Iv. ❑nu vAJuiion R.,rl with Raw Mi.
REQUESTED REPORT DATR
Edaw Yes No
Relinquished By
Received By
Relinquished By
Received By
Relinquished By
Received By
Signature
Signature
Signature
Siena ve
Signature
Signature
Primed Name
Printed Name
Printed Name
Pri , a
Printed Name
Printed Name
Finis
Finn
Finis
Firtn (�
H....Finis
i
Datc/I'line
DIT fl- ne
Date/Fime
D.IcMuse
D ten into
Date/limc
C('� ;1

4�AfSColumbia
Analytical Services -
Appendix A
Columbia Analytical Services
9143 Philips Highway, Suite 200
Jacksonville, FL 32256
Tel [phone]
Fax [phone]
Subcontracted Analytical Results
0

4�AfSColumbia
Analytical Services -
March 31, 2010
Tom Kissinger
Columbia Analytical Services
9143 Philips Hwy, Suite 200
.Jacksonville, FL 32256
19408 Park Row, Suite M. Houston, TX 77064 1 713.266.1599 wmw.caslao.com
Service Request No: J1001092
Laboratory Results for: Domtar Paper Company, LLC
Dear Tom:
Enclosed are the results of the sample(s) submitted to our laboratory on March 12, 2010. For
your reference, these analyses have been assigned our service request number J 1001092.
Analyses were performed according to our laboratory's NELAP-approved quality assurance
program. The test results meet requirements of the current NELAP standards, where applicable,
and except as noted in the laboratory case narrative provided. All results are intended to be
considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for
use of less than the complete report. Results apply only to the items submitted to the laboratory
for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the
NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any
quantitative analysis will be supplied upon request.
Please contact me if you have any questions. My direct line is 281-994-2954. You may also
contact me via email at [e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
Darren Biles
Project Manager
..... _ .. For. a.specific list ofNELAP.-accredited analvtes, refer to.the.certifications. scetion.at .... . . ...... . . ... . ... . ... . .. .
www.caslab.com.
An Employee Owned Company NELAPAccredited j ACIL Seal of Excellence Award Please consider the environment before printing
J1001092 1 of 29 7

4 w..
Services -
Certificate ofAnaiysis
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.casiab.com
J1001092 2 of 29

COLUMBIA ANALYTICAL SERVICES, INC
Client: Domtar Industries Service Request No.:
Project: Plymouth Stormwater Testing Date Received:
Sample Matrix: Water
CASE NARRATIVE
J1001092
3/12/10
All analyses were performed in adherence to the quality assurance program of Columbia Analytical Services, Inc.
(CAS). This report contains analytical results for samples designated for Tier II. When appropriate to the method,
method blank results have been wported with each analytical test.
Sample Receipt
Six water samples were received for analysis at Columbia Analytical Services on 3./12/10.
The samples were received at 6°C in good condition and are consistent with the accompanying chain of custody
form. The samples were stored in a refrigerator at 4°C upon receipt at the laboratory.
Please note the reporting forms are currently referencing the date CAS- Jacksonville received the samples (3/9/10)
and not the date CAS-Ilouston received the samples (3/12/10.)
Data Validation Notes and Discussion
MS/DMS
EQ1000120: Laboratory Control Spike/Duplicate Laboratory Control Spike (LCS/DLCS) samples were analyzed
and reported in lieu of an MS/DMS for this extraction batch. The batch quality control criteria were met.
Detection Limits
Detection limits are calculated for each congener in each sample by measuring the height of the noise level for each
quantitation ion for the associated labeled standard. The concentration equivalent to 2.5 times the height of the
noise is then calculated using the appropriate response factor and the weight of the sample. The calculated
concentration equals the detection limit.
Approved by:
Xiangqiu Liang, Laboratory Director
Date: 0 4 / 01 / 10
J1001092 3 of 29 9

4
Client: Domiar Paner Comnam. LLC Senice Request: J 1001092
Project: Plymouth Suinn oalcr besting
SAMPLE CROSS-REFER NCF
SAMPLE #
CLIENT SAMPLE ID
DATE
TIME
11001092-001
CL-13
3/3/10
10:10
J1001092-002
CL-11
3/3/10
09:55
1100 1092-003
WLSOI
3/3/10
11:03
J 1001092-004
LF-01
3/3/10
1 L15
J 1001092-005
Cl, 14
3/3/10
10:30
J 1001092-006
NBA
3/3/10
11:45
JIOOIO92 4 of 29 10
Pdmad 3/31/10 16:30 Sample Summary
rage I of I

Laboratory Certifications
2009-2010
STATE/PROGRAM
AGENCY
CERTIFICATION ID
EXP DATE
ARIZONA
AZ-DHS
AZ0725
05/26/10
ARKANSAS
ADE
09-048-0
06/16/10
CALIFORNIA
CA-ELAP
2452
02/28/11
DOD ELAP
A2LA
289701
11/30/11
FI.ORIDA/NELAP
FL - DOHS
E87611
06/30/10
HAAYAII
HI -DOH
N/A
06/30/10
IIA.INOIS/NELAP
IL -EPA
002380
10/06/10
IS017025
A2LA
2897.01
11/30/11
LoulSIANA/NELAP
LELAP
03048
06/30/10
MAINc
ME -DOHS
2008031
06/05/10
MICnlcnN
NIIDEQ
9971
06/30/10
MINNESO'I'A
MDH
048-999-427
03/25/10
NEVADA
NDEP
'rX014ll2009A
07/31/10
NcNvJi-'2si;v
NJDEP
I'X008
0680/10
NEw MEXICO
NMED-DWB
N/A
06/30/10
NER'YOIIK/NELAP
NY-D011
11707
03/31/10
OKLAHOMA
OKDEQ
2009-25
08/31/10
ORRGON/NELAP
ORELAP
TX200002-006
03/24/10
TENNESSEE
TNDEC
04016
06/30/10
TEXAS/NELAP
TCE
T104704216-09-TX
06/30/10
UTAIUNELAP
UTELCP
COLU2
06/30/10
SOH, IMPORT PERMIT
USDA
I P330-09-00067
03/27/12
WASHINcrON/NELAP
WA -Ecology
C1855
ll/14/10
WESTVIRGINIA
WVDEP
347
06/30/10
JI001092 5 of 29

5
Abbreviations, Acronyms & Definitions
Cal
Calibration
Conc
CONCentration
Dioxin(s)
Polychlorinated dibenzo-p-dioxin(s)
EDL
Estimated Detection Limit
EMPC
Estimated Maximum Possible Concentration
Flags
Data qualifiers
Furan(s)
Polychlorinated dibenzofuran(s)
g
Grams
ICAL
Initial CALibration
ID
IDentifier
Ions
Masses monitored for the analyte during data acquisition
L
Liter (s)
LCS
Laboratory Control Sample
DLCS
Duplicate Laboratory Control Sample
MB
Method Blank
MCL
Method Calibration Limit
MDL
Method Detection Limit
MRL
Method Reporting Limit
mL
Milliliters
MS
Matrix Spiked sample
DMS
Duplicate Matrix Spiked sample
NO
Number of peaks meeting all identification criteria
PCDD(s)
Polychlorinated dibenzo-p-dioxin(s)
PCDF(s)
Polychlorinated dibenzofuran(s)
ppb
Parts per billion
ppm
Parts per million
ppq
Parts per quadrillion
ppt
Parts per trillion
QA
Quality Assurance
QC
Quality Control
Ratio
Ratio of areas from monitored ions for an analyte
% Rec.
Percent Recovery
RPD
Relative Percent Difference
RRF
Relative Response Factor
RT
Retention Time
RRT
Relative Retention Time
SDG
Sample Delivery Group
S/N
Signal -to -Noise ratio
TEF
Toxicity Equivalence Factor
TEQ
Toxicity Equivalence Quotient
J1001092 6 of 29 12

7
Data Qualifier Flags - Dioxin/Furans
o B Indicates the associated analyte is found in the method blank, as well as in the sample.
o C Confirmation of the TCDF compound: When 2378-TCDF is detected on the DB-5 column,
confirmation analyses are performed on a second column (DB-225). The results from both the
DB-5 column and the DB-225 column are included in this data package. The results from the
DB-225 analyses should be used to evaluate the 2378-TCDF in the samples. The confirmed
result should be used in determining the TEQ value for TCDF.
o E Indicates an estimated value -used when the analyte concentration exceeds the upper end of
the linear calibration range.
o 1 Indicates an estimated value - used when the analyte concentration is below the method
reporting limit (MRL) and above the estimated detection limit (EDL).
o K EMPC - When the ion abundance ratios associated with a particular compound are outside the
QC limits, samples are flagged with a W flag. A'K' flag indicates an estimated maximum
possible concentration for the associated compound.
o U Indicates the compound was analyzed and not detected.
o Y Samples that had recoveries of labeled standards outside the acceptance limits are flagged
with'Y'. In all cases, the signal-to-noise ratios are greater than 10:1, making these data
acceptable.
o ND Indicates concentration is reported as 'Not Detected.'
o 5 Peak is saturated; data not reportable.
o P Indicates chlorodiphenyl ether interference present at the retention time of the target
compound.
o Q Lock -mass interference by chlorodiphenyl ether compounds.
J1001092 7 of 29 13

8
CAS/HOU - i omn Prod cdon. p--?i Review. Project RZ'%,, - Sta 23L111''S
SR= Unique !DI j Oy ( U'1-l-
Date 3 / 31 / 10 Rev;ewer
J1001092 8 of 29

CAS/1-H0U, - Form Production. Peer Review &- 117'roject Reviem, Si
1211arui-es
I.
SR# Unique ID
1160 1 Qqa
I Date 3/31/10 Reviewer ICJ i
J1001092 9 of 29 15

Analytical Results
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.casiab.com
J1001092 10 or 29 16

COLUMBIA ANA[ATICA I. SER\ICES, INC.
.AnalytiiN Reporl
Client
Domlar Industries
Sen ice Request:
/1001092
Project:
Plymouth Slorzn,alcr Testing
Date Collected:
3/ 3/10 1010
Sample Matrix:
Water
Date Received:
3/ 9110
Sample Name:
Cl: 13
Units:
pe/I.
Lab Code:
11001092-001
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibcnzofurans by IIRGCAIRMS
Analytical Method: 1613B
Prep Method: Method .
Ion Dilution Date Time Date
AnahYe Name Result Q ED], MRI, Ratio RRT Factor Analyzed Analyzed Estracted
2.3.7.8-TCDD
ND U
0.401 9.90
1
3/18/10 2352 3/12/10
Spike
Cone.
Control
Ion
Labeled Compounds
Cone(py)
Found (pg) % Ree Q
Limits
Ratio
RRT
13C-2.3.7.8=ICDD
2000
1567,606 78
25-164
0.79
1.007
37CI-2.3.7.8-rCDD
800
804.791 101
35-197
NA
I MOS
i
Comments:
Primed 3/31/10 1625 Fann I
,1mno.,zlsurl ms`JT&I�iydvaiReeun.,o, 11 of 29 s�perSn Rdoeoce: ,o-oaom �e.Ia rev oo
17

COLUNIBIA ANALYTICAL SERNACES, INC.
Anafmt:l 1 Report
Client:
Domtar Industries
Sen'ice Request:
/1001092
Project:
Plymouth Slormtyater testing
Date Collected:
3/ 3110 095i
Sample Matrix:
Water
Date Reecked:
3/ 9/10
Sample -Name:
C7. 11
Units:
pg/L
Lab Code:
I1001092-002
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dihenzofurans by 1IRGC/t1RMS
Analytical Method: 1613B
Prep Method: Method
[on
Dilution
Date Time Date
Analyle Name
Result Q
EDL
DIRL
Ratio RRT
Factor
Analyzed Analyzed Extracted
2.3.7.8-TCDD
ND U
0.412
10.4
1
3/19/10 0040 3/12110
Spike
Cone
Cunlrnl
It'll
Labeled Compounds
Cnne.(pg)
Found (pg)
1,611ec Q
Unlits
Ratio
RR F
13C-2.3.7.8=TCDD
2000
1528.601
76
25-164
0.79
1.007
37CI-2.3.7.8-TCDD
800
81 LO55
101
35-197
NA
1.008
Comments:
Printed 3/.31/10 16:25 Fonn IA
meaewSSun1`"`1 J bpd1 `. 21,aa e1Reyun rp` 12 of 29 S.MSa Referrnve. 10-NM139514 rev 00

COLVNIBIA AN:U.N ICAL SERVICES, INC.
Analytlll� Report
Client:
Dontlar btdustrics
SeTwice Request:
11001092
Project:
Plymouth Slonnwater Testing
Date Collected:
313110 1103
Sample iNlatric:
kater
Dale Items cc]:
3/9/10
Sample Name:
WLS01
Units:
pg./L
LabCode:
J1001092-003
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRGC/HRMS
Analytical Method: 1613B
Prep Method: Method
Inn Dilution Date "rime Date
Analyte Name Result Q F,DI- bl ltl, Ratio RRT Factor Analyzed Analyzed Extracted
2.3.7.8-TCDD
ND U
0.241
10.2
1
3/19/10 0128 3/12/10
Spike
Cone.
Control
Ion
Labeled Compound,
Cone.(Pg)
Pound
v Ree Q
Looks
Ratio
RRT
13C-2-3.7.8-rC1)1)
2000
1571.272
79
25-164
0.79
L007
37C1-2.3.7.8-TCDD
800
771.417
96
35-197
NA
1,008
Comments:
Pnoled 3/.31/10 16:25 Fonn IA
wnnowzl5udlm:LLJTdq§tyticolReeon.rpt 13 of 29 S.Mx teet,, u: in.000013911,yt<. to

COLUMBIA ANA1-1"I'ICA1, SFRVICES, WC.
AuakiiJol Report
Client-.
Domlar Industries
Sen ice Bequest:
11001092
Project:
Phntouth Stonmvater Testing
Date Collected:
3/ 3/10 111 i
Sample Matrix:
Water
Date Received:
319,110
Sample Nante:
1,17-01
Units:
Pg/1-
Lab Code:
J1001092-004
Basis:
NA
Polychlorinated Dibenzodiozins and Polychlorinated Dibenzofurans by RRGC/IIRMS
Analvtical Method: 1613B
Prep Method: Method
Ion Dilution Date Time Date
Analyle Name Result Q EDI, MR1, Ratio RRT Factor Anayzed Analyzed Extracted
2.3.7.8-1'0D1)
ND U
0.391 10.2
1
3/19/10 0804 3/12/10
Spike
Cone.
Goutol
Ion
Labeled Compound,
Cnnc-(pg)
Found(pg) %Rec Q
Limits
Ratio
RRT
13C-23.7.8=TCDD
2000
1534.408 77
25-164
0.78
1.007
370-2.3.7.8=1 CDD
800
805543 101
35-197
NA
1.008
Comments:
Pnn¢d 3131/10 16.25 Form IA
\klnflow2\Surlims�LjTtfelbl TiytimlRep rpr )4 of 29 Super$el Reference: 1P0000138514meW
U U L 20

COLUMBIA ANALYTICAL SERVICES, INC.
Anal, 6LIJ1 Rcpon
Client
Duntlnr Industries
Sen ice Request:
.11001092
Project
Plymouth StonnoVnter'Festin°
Date Collected:
3/ 3/10 1030
Sample Matrix:
Water
Date Received:
3/ 9/10
Sample Name:
CI: 14
Units:
pg/L
Lab Code:
J1001092-005
Basis:
NA
Polvchlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by 1IRCC/F112MS
Analytical Method: 1613B
Prep :Method: Method
Ion Dilution Date Time Date
An:dyte Name Result Q EDL h1RL Ratio RRT Factor Anahzed Analyzed Extracted
2.3.7.8-1"CDD
ND U
0.402
10.4
1
3/19/10 0852 3/12/10
Spike
Cone.
Conhnl
Inn
Labeled Cmnpounds
Cone.(pg)
Pound (pg)
% Rec Q
Limits
Ratio
RRT
13C-2.3.7.8-TC'.DD
2000
1387.274
69
25-164
0.79
1.008
37C'I-2.17.8=TCDD
800
769.720
96
35-197
NA
1.(108
Comments:
tlowmd 3/31/10 16:25 Fonn IA
ulnnow_ts:a�am:tl��i 9 1yt1e1fteport `n� 15 of 29 S„ee,sn Rdtene< 10-00W39514,e'00
21

COLUMBIA ANALN IIIC'AL SERVICES, INC.
AntdyliN Report
Client
Domtnr Industries
Sen"ice Request:
.11001092
Project:
Plymouth Stormwaler lesting
Date Collected:
3/3/101145
Sample :Matric:
Water
Date Received:
3/9/10
Sample Name:
NBA
Units:
Pg/1,
Lab Code:
J1001092-006
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRGC/I[RMS
Analytical Method: 1613B
Prep Method: Method
Ion Dilution Date Time Date
Analyte Name Result Q EDI, MIZE Ratio RRT Factor Anah'zed Anahzed Extracted
2.3,7.8-TCDD
ND U
0.344
10.2
1
3/19/10 0940 3/12110
Spike
Cone
Control
lon
Labeled Compound,
Cone.(pg)
Found (pg)
Rec Q
Limiln
Ratio
RRT
I.C-2.3-7.8-]CD1)
2000
1498,629
75
25-164
0.80
1.008
37CI-2-3.7.8=TC1)D
800
776.027
97
35-197
NA
LU08
Comments:
Printed 3%31/10 16:25 Fe. IA
nnnowzlS„dim:uJ9, q 1.d�laenea�o, 16 of 29 00
S�peBn aderence io-000aua 22
e�

COLUMBIA ANALFIICAL SERVICES, INC.
Ana1,6,):7 Report
Client:
Donvar Industries
Sereice Rcyuests
/1001092
Project:
Phmouth Stonumaler Te51in2
Date Collected:
NA
SampleMatrix:
Water
Date Recened:
NA
Sample Name:
Method Blank
Units:
pg/L
Lab Code.
EQ 1000120-01
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by IIRCC/HRMS
Analytical Method: 1613B
Prep Method: Method
Ion Dilution Date Time Date
Analyle Name Result Q EDL i\IRL Ratio RRT Factor Analyzed Analyzed Extracted
2,3.7.8-TCDD
ND U
0.367
10.0
1
3118/10 1026 3/12/10
Spike
Cone
Control
Inn
Labeled Compound,
Conc.(pg)
Found(pg)
%lice Q
Limits
Ratio
RRI
1312-2.3.7.8-TCDD
2000
1610.809
81
25-164
0.77
1.007
370-2.3.7.8-TCDD
800
773582
97
35-197
NA
1.007
Comments:
Rin led 3131/10 1625 Form IA
Vlnnnw.su,limslLl�cReq.� a ,Iv�inlRepon rp� t 7 of 29 Su,,Se, Referenu. 1 a-000013851+ rev 00
UU UAL 23

Ill
, � 1
Services -
Accuracy and Precision
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.casiab.com
A 001092 18 of 29 24

COLUMBIA ANAL1'I'I CAI. SERVICES, Inc
is
QAiQC Repon
Client:
Domtar Industries Sen'ice Request:
J1001092
Project:
Plymouth Storm cater Testing Date Analyzed:
3/I R!10
Sample Matrix:
Water
Lab Control Sample Summary
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by HRGC/HRMS
A nalytical Method:
1613B Units:
pg/L
Prep Method:
Method Basis:
NA
Extraction Lot:
107517
Lab Control Sample Duplicate Lab Control Sample
EQ1000120-02 EQ 1000120-03 %Bee
RPD
Analy(c Name
Result Expected %Rec Result Expected %12ec Limits
Itl'U -Limit
2.3.7.8-TC'DD
247 200 123 237 200 118 67- 158
4 50
Comments:
Prinlcd 3/31/10 16:25 Lab Control Sample Summary
tvansw2xS=r1 lmsujMbV�ComrolSamplerpt i9of29 Sump Refcrmu: 10.0000U851a ra o0
25

COLUMRI:A A.—NALN HCAL SERVICES, INC.
Anal,162a Report
Client:
Domtar Industries
Sem ice Request:
/1001092
Project:
Plymouth Storntssater 1'eming
Dale Collected:
NA
Sample ,Matri,C
Water
Date Received:
NA
Sample Name:
Lab Control Sample
Units:
pg/L
Lab Code:
EQ1000120-02
Basis:
NA
Polychlorinated Dibenzedioxins and Polychlorinated Dibenzoliurans by IIRGC/HRNIS
Analytical Method: 1613B
Prep Method: Method
lon
Dilution
Date Time Date
Analyte Name
Result Q
FDL
MRI-
Ratio RRT
Factor
Analyzed Analyzed Fztracted
2.3.7.8-FC9D
247
0.492
10.0
0.78 1.001
1
3/19/10 1247 3/12/10
Spike
Cone.
Control
Ion
Labeled Compounds
Cnne.(pg)
Found (J)")
%R,c Q
Limits
Ratio
RR I'
13C-2.3.7.8-TCDD
2000
1415.564
71
25-164
0.78
1.007
370-23.7.8=1 CDD
800
736.374
92
3 1- 191
NA
L007
Omorn mts:
Primed 3/31/10 16:25 Fonn IA
w�now2�s�dimauJ�Weq=n .lyumlacpoarpi 20 of 29 s�persn xer mnoe. io.woaunsla«goo
UU UAL 26

COLU:MBIA ANA L)']'ICAL SFRVICES, INC.
Ana]v62j)I Report
Client:
Dointar Industries
Sen'ice Bequest:
J 1001092
Project:
Plyuunuh Stonmcaier Testing
Date Collected:
NA
Sample Matrix:
Water
Date Received:
NA
Sample Name:
Duplicate Lab Control Sample
Units:
pg/l.
Lab Code:
EQ 1000120-03
Basis:
NA
Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans by HRCCA RATS
knalytieal Method: 1613B
Prep Method: Method
Lon
Dilution
Date Time Date
Analvle Name
Result Q
PAL
MRL,
Ratio RR"F
Factor
Analyzed Analyzed Extracted
2.3.7.8-'I"CDD
237
0.647
10.0
0.78 1.001
1
3/18/10 1335 3/12/10
Spike
Conc.
Control
Ion
Labeled Compounds
Conc.(pg)
Pound (pg)
'X. 12ee Q
Limits
Ratio
RWI
13C-2,3.7-8-TCDD
2000
1493.678
75
25-164
0.81
1.007
37CI-2.3.7.8=FCDD
800
716,832
91
31-191
NA
1.007
Comments:
Printed 3131/10 10:25 ro. IA
Iwnow'_6unlm9Lr�Waa�.AnalyrlcalReporupt 21 of 29
Sr,,Set Reference: 10.0000138514 rep lq

} :rlumbia
Chain of Custody
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.casiab.com
An Employee Owned Companv
J1001092 22 of 29 28

Intra Network Chain of Custodv
- - �9143 Philips Highway • Jacksonville, FI:}h56 • 904-739.2277 • FAX [phone]
Project Name:
I lymouth Stormmatcr I esung
_
Project Punt ber'
-.
. .
Project Manager:
Diane Hardison
Company:
Domtar Paper Company, LLC
-
LL M
J _
.
-
Sample
Date
-Lab Code
Client Sample lD
Nor Cont.
Matrix
Dale .Time
Received Send To
j
11001092-001
13
a _
Water
3/3/10
1010
3/9/10
IIOUSTON
--
Water
313110
0955
3/9/10
IIOUSTON
i
11
J 1001092-002
—CI
CI -II
11001092-003
WLS01
Water
3/3/10
1103
3/9/10
f{Ol15TON
Ir II
J1001092-004
LP-01
Water ..
313/10
1115
. 3/9110
IIOUSTON
II
J 1001092-005
CI. 14
a.
Water:_
3/3/10.
1030
3/9110
IIOUS"hON
: H
J1001092.006
_ _
NRA _
Water
313/10
1195
3/9110
FIOr1STON
II
Test Co m m c n is
.Dioxins Furans-1613D. 11061092-001,2,3,4,5,6
Lill station or effluent
CAS I lous(on
Special Instructions/Comments
Turnaround Requirements
Report Requirements -
Invoice Information
-
RUSH (Surcharges Apply)
—I. Results Only
'-
PLEASE SEND
r1,FAsc CIRCLE WORK DA V s
-
II. Results Summaries
—
roN
1 2 - 3 4 5
_ III. Results and Calibration Summaries
�- 1I001092
R E S U L i S. TO
_ srANDARD
IV. Data Validation Report with Raw Data
M A N D Y, SULLIVAN
Requested FAX Date:
PQUmI)UJ N
Bill to
Requested Report Datc: 03/20/10
GDD N
Relinquished 13yJ100110 o n I 1 d'll\AA e y ( _ Received fSyc 129 Airbill Number /
�111—tea b;cL ••fS 310 I000 I� x�w o98 01yo2� �G (7
0) _� SIiR t,e11 F3hb7.t. t✓12.j-t {VP.-1 i0— Pagel

t<eSeT corm`:,, )
Columbia Analytical Services, Inc.
Cooler Rf�&ipt Form
rant corm,,::;
Client/Project: Domtar Paper Corn, LLC/ Plymouth Stormwater tff Service Request:
Received: 03/12/10 1000 Opened (Date/Time): 03/12/10 1020 By:
J1001092
EC
I. Samples were received via? ❑US Mail ❑Fedex ❑✓ UPS ❑DHL ❑Courier
❑Hand Delivered
2. Samples were received in: (circle) ❑✓ Cooler ❑Box ❑ Other
❑NA
3. Were custody seals present on coolers? ZY ON If ycs, how many and where?
1-front
If present, were custody seals intact? ❑✓ Y ❑N If present, were they signed and dated?
❑✓ Y
❑N
4. Is shipper's air -bill filed? DNA ❑Y ❑✓ N If not, record air bill number: I X5W 098 01 4020 5647
5. Temperature of cooler(s) upon receipt (°C): 6
6. If applicable, list Chain of Custody numbers:
7. Were custody papers properly filled out (ink, signed, etc.)?
❑NA J❑Y
❑N
S. Packing material used: ❑lnserts ZBlibble Wrap ❑Blue Ice Z 6Vet Ice ❑� Sleeves ❑Other
9. Were the correct types of bottles used for the tests indicated?
❑J Y
❑N
Did all bottles arrive in good condition (i.e. unbroken, out of temp.)? Indicate in the table below.
❑✓ Y
❑N
Sample ID
Bottle Count
Bottle Type
Out of Temp
Broken
Initials
❑
❑
❑
❑
❑
❑
❑
❑
❑
I ❑
10. Were all bottle labels complete (i.e. analysis, ID, etc.)?
Did all bottle labels and tags agree with custody papers? Indicate in the table below.
❑Y ❑N
❑Y ❑N
Sample ID on Bottle Sample ID oti COCSample ID on Bottle Sample ID on COC
it. Additional notes, discrepancies, and resolutions:
J1001092 24 of 29
CRF_r092109.pdf Pa A : F/� l ❑ 2

2s
Sample Acceptance Policy
Custody Seals (desirable, mandatory if specified in SAP):
✓ On outside of cooler
✓ Seals intact, signed and dated
Chain -of -Custody documentation (mandatory):
✓ Properly filled out in ink & signed by the client
✓ Sign and date the coc for CASMOU upon cooler receipt
✓. Coc must list method number
✓ If no coc was submitted with the samples, complete a CASMOU coc for the client
Sample Integrity (mandatory):
✓ Sample containers must arrive in good condition (not broken or leaking)
✓ Sample IDs on the bottles must match the sample IDs on the coc
✓ The correct type of sample bottle must be used for the method requested
✓ The correct number of sample containers received must agree with the
documentation on the coc
✓ The correct sample matrix must appear on the coc
✓ An appropriate sample volume or weight must be received
Temperature Preservatives (varies by sample matrix):
✓ Aqueous and Non -aqueous samples must be shipped and stored cold, at 0 to 60C
✓ Tissue samples must be shipped and stored frozen, at -20 to -10°C
✓ Air samples can be shipped and stored at ambient temperature, —23°C
✓ The sample temperature must be recorded on the coc
✓ Notify a Project Chemist if any samples are outside the acceptance temperature or
have compromised sample integrity — the client must decide re: replacement sample
submittal or continue with the analysis
Cooler Receipt Form, CRF (mandatory):
✓ Cooler receipt forms must be completed for each coc & SRk
✓ Sample integrity issues must be documented on the CRF
✓ A scan of the carrier and the airbill number must be recorded in CAS LIMS
Sample Integrity Issues/Resolutions (mandatory):
✓ Sample integrity issues are documented on the CRF and given to the Project Chemist
for resolution with the client
✓ Client resolution is documented in writing (typically email or on the CRF) and filed in
the project folder(s)
J1001092 25 of 29 31

Service Request Summary
Folder N:
11001092
Project Chemist:
Darren 13ilcs
Client Name:
Donitar Industries
Originating Lab:
JAX
Project Name:
PIvinoulh Slonucvaler besting
Logged By:
SOSTROM
Project Number:
Dale Received:
3/9/10
Internal Due Date:
3/26/10
Report To:
Dunne Hardison
QSe �, .
LAB QAP
Domtar Paper Company. LLC
Qualifier Set
CAS Standard
P.O. Box 747
Fornlsel:
CAS Standard
Plymouth, NC 27962
Merged?:
Y
Phone Number:
252-793-8611
Report to MDL?:
Y
Cell Number:
P.O. Number:
4350171 RR4
Fax Number:
252-79.3-8871
GDD:
No ELIU Specified
E-mail:
diane.hardison rldannai.com
S\ \I
Z
m
LL
CAS Snmp No
Client Samp No.
]tolrix
Collected
JW01092-OUI
CL-13
Winer
3/3/10
1010
H
J IOU 1092-002
CL-II
R'aler
313/10
0955
ll
J 1001092-003
WLS01
Water
3/3/10
1103
11
J 1001092-004
I.F-01
NWmr
313110
1115
II
J1001092-005
CL-14
N'aler
3/3/10
I030
11
J 1001092-006
NBA
1Vntcr
313110
1145
-rest Contnlents:
Group "rest/Niethod
Samples
Colonlents
Semivoa GCMS Dioxins- Furans/1613B 1-6 -rCDD only. Final due 4/2
W
N
12 - 1000 mL-Gloss Bollle Wh9 APIBBR Ten nn Liner I�nprcso vcd
Location: G-Disposed. L-WICOI
NPDES
J1001092 26 of 29
Printed 113112U 10 4:27:24PM Service RN,,c,l for d U01092 I'aea el I

Preparation Information Benchsheet
27
Prep Run#: 107517 Prep R"urkl'1ow: OrgEMAy(765)
Team: Semivoo GCNIS/AKODUR Prep Method: Method
Status: Prepped
Prep DalefFimc: 3/12/I0 02:45 PM
u
Lab Code
Client ID
8#
Method Rest
pH
Matrix
Amt. Ext.
Sample Description
1
EI000258-001
IV031017-OUI
.01
1613B/Dioeins Fauns
Wusewater
107Um1-
slightly beige clear liquid
2
E1000259-001
365304-1
01
16013/1)ioxins guns
6
Water
990m1.
pa le y ell ow elea, liquid
3
EW00260-001
NN3027 COVF 12'1-666 IOR53
01
1613E/Diuxins Furans
6
Driakaue Water
96(ad.
timed clear liquid '
4
E1000261-00I
NNV282 Lupton I (18T-60I) IOB68
01
1613B/Dioxins Furans
7
Note,
940nd.
tinted clear liquid
5
E1000262-001
NM03O2 Ruckslunags 2(16 T-5951101369
.01
16131311Di uo; Furans
A
Dunking Water
910nd.
tilled clear liquid
6
E1000263-001
OUTFALL 004
'01
1613B/Dioeins Funas
3
W.,Icwamr
106O L
Laige cloudy liquid
7
E1000263-002
OUTFALL 005
.01
1613B/Dioxins Furans
6
Wastewater
WIN,[-
orange doudv liquid
8
E1000264-001
95SO Out GdI SC-002
'01
1613B/Dioxins Furans
6
W. er
1050mL
rlexr miorless liquid
9
E1000264-002
9557 Outfall SC-003
01
16136/Dioxins FrOins
7
Wade,
1050m1,
c lenr polo less liquid
10
13I000266-UUI
9566 Oulall CW-0001149)
.01
1613B/Dioxins Furore
6
Wuter
IWou'l.
clear colodess liquid
11
E1000266-002
9578 Outfidl DUP02
01
1613B1Dwirs Furore
6
Water
1050ad.
clear colorless liquid
12
EQ 1000120-0I
NIB
1613B1DIonlns Furans
Liquid
10003al.
13
EQ I000120-02
LCS
161313/Diuxins Furans
Liquid
IOOO nL
14
EQIOM)120-03
DI.CS
161313/13ioxins Furans
Liquid
IOOUnd.
15
J10O1092AO1
C1, 13
01
161361136.,ns Furmis
5
Water
1010al.
beige cloudy liquid
16
JID01092-002
CL.II
.01
IGI-B/Dioxins Furans
S
Water
Was].
beige eioudv liquid
17
J1001092-003
WLSOI
Ol
1613B/Dioxins Forms
5
Wmer
WUnd.
pale yellow clear liquid
18
J1001092-OIM
LI;-OI
'01
1613B/Dioxins Furans
6
Water
980mL
cellaw slightly cloudy liquid
19
J100B/92-005
CL.1q
01
1613WI)toxias Furans
5
Water
960m1.
ran cloudy liquid
20
J1001092-006
NBA
.01
1613B/Dioxins Fuans
J
Water
98Und.
vcllua slightly cloudy liquid
W
W
J1001092 27 of 29
Primed 3/23/10 17'50 Preparation boloaaalion Rrnchshed P,e I

Prep Run#: 107517
Tcam: Scmivua GCMS/AKODUR
Spiking Solutions
Preparation Information Benchsheet
28
Prep Wurkl7lovs: OrgExlAq(365)
Prep Blethod: Method
Status: Prepped
Prep Dateffinle: 3/12/10 02:45 1'M
Nnlne: 161313 Matrix Working Standard Inventory ID 13977 Logbook Rell D10-94-213 Expires On: 12/09/2010
EQ1000120-02 100.00PL EQ[000120-03 IoompL
Name: 82901161313 Cleanup Working Standard inventoryID ]6116 Logbook Ref, DII-I5-2AB Expires On 03/)2/2011
E1000258-WI
10(rWlhL
E1000263-002
looOold,
FQ I OOR120-01
1 oo cop L
11001092-004
100. Doll 1,
E 1000259.001 wo.oOpL
E1000263-002.R01 too oopL
LQ 1000120-02 Ioo.00ld,
11001092-005 Ino. no111,
E 1 W0260-001
1orlooltL
EI W0264-00I
100. W p L
EQ1000120-03
loo.oullL
11001092-006
IW,00pL.
[71000261-001 1000uflL E1000262-001 Ion. ooµL E1000263-001 100,00pl,
F:10002W-002 looOopl, E1009266-001 10o.00llL E1000266-002 Iao arld-
11001092-n01 I00.0upL 11001092-002 Io0.001hL I1001092-003 I000Ulll.
Name: 161313 Labeled Working Standard Inventory ID 16133 Logbook Ref. DI I-15-313 Expires On: 03/12ro l I
E1000258-001 1,00000[lL
E1000263-002 I,oriourn1L
EQ 1000120-01 1,000mo ti L
11001092-004 100o00p 1,
Preparation Materials
Accmne 99 5% Minimum
Glass wtell
Sodaua Thiosullale Anhydrous
Reogoa Glade NaS203
I tidccane(a-Tndecane)
pH Paper 0-14
Preparation Steps
Step: EXaarimn
Sla wd: 3/12/I0 14A5
Finished: 3/12/10 17: 10
By: AKODUR
E 1000259-001 I'o0o 00ll I.
E )o00263-W 2. Rat 1 000.00µ L
EQ 1(100I 20-02 1,000.00111.
JIu01092-005 1,Ooo.urifd,
E 1000260-001
I'tion0opI.
E 1000264-001
I owoop L
EQ1000120-03
l000.00pl,
11001092-006
loo.00p L.
E1000261-out IO0o0oµL, E1000262-001 Iwo. oopL F-I000263.001 10oo ouµ 1,
E19002W-002 I W0.0upL E1000'_66-001 LOW.WPL E1000266-002 tp0u.011tIL
I Ion 1092-0o1 imutro0µ1_ I 1010 1 (192-002 riarompL J1001092-003 I.OI)0.r10 p 1.
C2-34-1(15539)
Carbon. High Purity- C2-2i-005(13983)
Ethyl Aeewte 99.9°: Alinimunt
C2.23-006(9462)
EIOAc
C2-13-005(7198)
Snlfinic Acid Rengenl Grade C2-30-()0=(13953)
Uichl... .. ham(Aloh.'kne
C2-28-005 (13939)
H2SO4
( hlodde) 99.9% NlcC12
C2-32-006 (13979)
Sodium lkdrmidc Rwgea C2-24-002 (9463)
Sodium Sultzae A lhyd.mu
C2-35-004 (15668)
Gmde NaOFI
Reaget0 Grade Na2SO4
C2.26-006(13946)
14csane ln-Hexane)99595 C2-26-007(13915,
No ... ne OsNonenel 9T/.
C2-29-002(13943)
M in inmm
(1008)
Silica Gel Reagent Glade C2-24-007(9450)
1'olunle 999% Minimum
C2-28-003(139331
Step:
Acid Clean
SRp: Silica GO Clewt
Step:
Final V' hime -
Stailcd:
3115111)08.00
Shined: 3n5/1010:00
Slum)
3,16111007,00
Finished:
3/15110 08,00
FinishedM15/10 12:00
Finished:
1,16,'10 1(1,10
Hy:
ARDDUR
By: AKODUR
By:
AKODUR
J1001092 28 of 29
Printed .3/23/10 17:50 Ihepurntion Info n alion Hcndishcel 2

Prep Runes: 107517
Team: Semivua GCMS/AKODUR
Ravimved Br
w Cl of Cnslody
ak
Preparation Information Benchsheet
2s
Prep WorkFlo": OigLxtAq(365)
Prep Method: Mcihod
Date . 3/16/10
Relinquished By Dam:
Iaancls IixanmicJ
Recaired By Dale: 1bs No
Status: Prep)xd
Prep Date/Time: 3/12/10 02:45 Pbl
Prime) 3/23/10 1 ].50 PI epnmlian Infounal ion lianchsheel Page

V
�
y
Z2
Qyy
j
Op
+a
0

�M l'fZ SUM flQ
Representing NCDE�m32
Has completed
Visitor Safety Orientation Training
�����i��A 3-31-Io
Amhon'red byDate
EXPIRES IN ONE YEAR
Form n506 (R a07)

� ,ate
I�
M
�
�
IT -
l i I�,
N
tA
_•
-(po-
Po
t
I
V
s
1/77
-
1
IV
vlj
i I
I
KP
�I

I
!il
I
Y
I-
1-
�
1
I
1
� �� �
I �
I
1
j
�
I
• I
�
1
I
I.
`
1-
���.
1� I
I 1 I
y•
I
}
II
i
1'

Dumpor, Samir
From:
Dumpor, Samir
Sent:
Tuesday, May 04, 2010 3:51 PM
To:
'[e-mail]'
Cc:
Hodge, Al; Bennett, Bradley; Lowther, Brian
Subject:
Domtar - NCS000189 - moval od dioxin testing from Tier Two response program
Attachments:
image001.jpg
Diane,
Your request to remove the dioxin testing from Tier Two response program (per permit Number NCS000189) was
discussed between Al Hodge and me here in Washington Regional Office and Bradley Bennett and Brian Lowther from
the Central Office. Due to the fact that sampling results did not show any traces of dioxin in two separate sampling
periods, we believe that COD exceedance of benchmark values for Outfall WYN will not have any effect on dioxin
resultants. By this e-mail we want to inform you that your request to remove the dioxin testing from the Tier Two
response program for Outfall WYN is approved until such time that three consecutive COD sample results are below the
benchmark values.
Samir Dumpor
Environmental Engineer II
NC Department of Environment and Natural Resources
Surface Water Protection Section
Washington Regional Office
943 Washington Square Mall
Washington, NC 27889
Office: 252.948.3959
Fax: [phone]
NOTE: Please update your address book with my new email address
S(amir. Dumpor(dncdenr. eov
`�' Please consider the environment before printing this e-mail.
E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be
disclosed to third parties.

Memorandum_
From: AI Hodge — DWQ Washington Regional Office Supervisor
Date: 4/8/10
Re: Request to Remove Dioxin Sampling/Analysis Requirements from permit and Request for
Representative Outfall Status for Domtar Paper Company, LLC — Plymouth, North Carolina,
NPDES Stormwater Permit #NCS000189
• July 24, 2009
DWQ issued a NPDES Stormwater Renewal permit # NCS000189 to
Domtar Paper Company, LLC located in Plymouth, Martin County,
North Carolina.
• March 9, 2010 Request for removal of Dioxin Sampling/Analyses requirement from
the NPDES permit, as well as Request for Representative Outfall
Status for two areas of the facility and removal of the requirement to
sample outfall due to sheet flow conditions.
• March 31, 2010 On March 31,.2010, Samir Dumper of the Washington Regional
Office conducted a facility inspection, together with Diane Hardison,
Tamika Boone and Alan Barnes of Domtar Paper Company, to
determine if request for removal of Dioxin Sampling/Analysis and
representative Outfall Status can be granted.
Facility Inspection findings
• Request to Remove Dioxin Sampling/Analysis Requirements from Permit.
Request -for Representative Outfall Status for Outfall CL14.
Outfalls CLI 1, CLI 3 and CL14 are closely located to each other and service the Contractor Laydown
Area. This area of the facility does not have any raw materials or processes placed on it, hence the
biggest concern as far is analytical monitoring is TSS and pH. The drainage areas for outfalls CLI 3 and
CL14 is approximately same with the drainage area for outfall CLI 1 being slightly larger. On my
recommendation, Ms Diane R. Hardison, the Environmental Manager of the Domtar Paper Company
agreed to have outfall CLI I as Representative Outfall instead of CL14 as requested. At this time I
believe that granting the Rresentative Outfall Status for On fall-CLsl-l-would-not-cause-any damages to
surface he State ar-f. �
Request for Representative Outfall Status for Outfall LFOl,
Outfalls LF01 and LF02dis6harge stormwater from two sedimentation ponds which collect runoff from
the closed, capped and vegetated No. 2 Landfill. Site visit confirmed that LF01 on the east side of
Landfill No. 2 regularly discharges flow during moderate to heavy rain events, while the outfall LF02
located on west side of Landfill No. 2 rarely discharges flow. Only excessive rain events of this winter
and spring caused discharge from LF02. My conclusion is that granting the Representative Outfall Status
to outfall LFO1 would be beneficial to both parties, DWQ and Domtar Paper Company.

• Request to remove the requirement to sample outfall WRA from the permit due to sheet flow
Conditions was retracted by the Domtar Staff due to facility inspection. They were able to collect
The sample during last rain event.
Notes:

Domtar
It all begins with paper..'
Domtar Paper Company, LLC
Plymouth Mill
PC Box 747
Highway 149 North
Plymouth, INC 27962
T 2S2-793-8111
www.domtar.com
February 16, 2010
io :s n
MAR 9 2010
Ra , 'a i% :f a.8'?1] 1�rJ'
Mr. Al Hodge
Division of Water Quality
NC Department of Environment and Natural Resources
943 Washington Square Mall
Washington, NC 27889
Mr. Brian Lowther
Wetland and Stonnwater Branch
Division of Water Quality
NC Department of Environment and Natural Resources
1617 Mail Service Center
Raleigh, NC27699-1617
Certified Mail
Return Receipt Requester)
Subject: Request to Remove Dioxin Sampling/Analyses Requirement from Permit
Request for Representative Outfall Status
Domtar Paper Company, LLC- Plymouth, North Carolina
NPDES Stornrvater Permit # NCS000189
Domtar received revised stormwater permit NPDES# NCS000189 for its Plymouth, NC facility
in 2009, effective as of August 1, 2009. Since that time, the facility has completed the first six-
month monitoring period. Based on Domtar's observations of the permitted outfalls and test
results from the analytical sampling, we requests modification of our permit as follows:
1. Removal of the requirement to sample and analyses outfalls for dioxin,
2. Designation of two outfalls as representative for five; therefore, removing sampling
requirements for three outfalls,
3. Designation of sheet flow status for one Outfall; therefore, removing sampling
requirements for one outfall.
This request submittal includes the following attached references:
• Summary Table of Permitted Outfalls
• Stormwater Discharge Outfall Monitoring Report for August 2009
• Stormwater Discharge Outfall Monitoring Report for November 2009
• Stormwater Sampling Worksheet
• Copies of the Analytical reports from the Dioxin Sampling
• Map of the Stormwater Drainage Area for the West Contractor Laydown Area
• Map of the Stormwater Drainage Area for Landfills No. 2 and 3
• Map of the Stonnwater Drainage Area for the Wood Recycle Area
D:ADocumwts and Settings\MCCraDaALocal Settings\Temporary Internet PilesVOLK45\Negl2ed RequiremenlsPeb2010.doc
Page I of 3
Domtar Paper Company, LLC — Plymouth. NC

n
Dioxin Sampling and Analyses
The rain events of this past August and November allowed successful sampling of 11 permitted
outfalls at the facility. Outfalls not sampled were either not required to be sampled or did not
produce channeled Flow that could be sampled. Dioxin analyses results for the sampled outfalls
were all below detection levels. Therefore, we request that the DWQ remove the dioxin
sampling and analyses requirement from our permit for all outfalls. Copies of the analytical
reports for the dioxin analyses are included with this submittal for your reference.
Designation of Representative Outfall Status
The Plymouth facility has potentially two opportunities for grouping outfalls and designating one
in each group for representative status:
I. Outfalls CLl 1, CL13 and CL14 are closely located to each other and all discharge runoff
from the contractor laydown area, at the west end of the facility This area is pervious to
rainfall, covered in gravel and primarily serves as a parking lot and laydown area for
equipment. The table below summarizes the analytical results from the August 1, 2009 —
January 31, 2010 monitoring period. Based on these data and the co -locations of these
outfalls, we recommend that our permit designate outfall CL14 as representative of
the runoff from this laydown area; and therefore, not require analytical monitoring
(sampling) from CLl1 or CL13. �ns�eaci
�L14
Outfall
BOD m /l
COD m /l
TSS m /I
pH
Dioxin
U., -, i Lm
CLl 1
2.47
8
53
7.6
Not Detected
wzA ye,
CL13
2.54
11
4
7.6
Not Detected
qr
CL14
1
321
44
8.2
Not Detected
� CJ.-.((
2. Outfalls LFOI and LF02 discharge stornnvater from two sedimentation ponds which ley T�
collect runoff from the closed, capped and vegetated No. 2 landfill. LFO1 (on the east �
side of Landfill No. 2) regularly discharges Flow during moderate to heavy rain events. 1
However, LF02 (on the west side of Landfill No. 2) rarely discharges flow. The 1
excessive rain event of last November, which produced nearly seven inches of rain in a
48-hr period, caused discharge from LF02. The table below summarizes the analytical
results from the August 1, 2009 — January 31, 2010 monitoring period. Based on these
data and the historical precedence of little to no flow from LF02, we recommend that
our permit designate outfall LF01 as representative of the runoff from the No. 2 0'L
landfill area; and therefore, not require analytical monitoring (sampling) from S
LF02.
Outfall
BOD m /l
COD m /I
TSS m /I
pH
Dioxin
LF01
6.21
49
12
7.5
Not Detected
LF02
4
46
20
6.8
Not Detected
D:\Documents and SatingsValecraDa\Local Settings\'I'emporary Internet Filcs\OLK45\Req Rcd Requiremcntsl'eb2010.doc
Page 2 of 3
Domlar Paper Company, U-C — Plymouth, NC

Removal of Requirement to Sample Outfall WRA Due to Sheet Flow
The stonnwater drainage area identified as the Wood Recycle Area, does not produce any
channeled flow that can be sampled. This was true under the conditions of the former
stormwater permit for the facility. Even the excessive rain event of last November did not
produce any channeled flow from this area. Therefore, we request that DWQ remove th
requirement to sample outfall WRA from the
.ail\ r , W 'k
Note Concerning Outfall LF03:
kLe C,,-44 "}
'pile �v>•t�h 0.r�`/
You will notice in the previously submitted Stonnwater Monitoring Reports and the attached
information that LF03 neither produced any flow during the August 1, 2009 — January 31, 2010 46
monitoring period. This outfall serves the currently active No. 3 landfill. After cell one of this J"
landfill is closed and capped, this outfall will discharge stormwater from a sedimentation pond
which will collect the runoff from cell one. However, until cell one of this landfill is closed and Gbo rr4t-s
capped, neither runoff will collect into the pond, nor will any flow discharge through outfall &ne.
LF03. Closure of cell one will begin in late 2010. LF03 may begin generating discharge in
2011.
Should you have any questions concerning the requests of this submittal or require additional
information in order to process these requests, please contact Tamika Boone at
tamika.boonendomtar.com (252-793-7490) or me at diane.hardison a,domtar.conm (252-793-
8611). We further welcome visits from DWQ representatives to the Plymouth facility in order to
help facilitate these requests.A or s�
Sincerely, — tJ3I- 0Ogr U n-ewe
d -R �
Diane R. Hardison
Environmental Manager
xc: Tamika Boone — Domtar
Alan Barnes — Donmtar
Bill Morris - Domtar
t� 6 r7lJi 1 ✓� \
�0-- �,V a.& WL. r-s
WDocuments and Seuings\Mecra Da\Local Settings\Temporary Internet Files\OLK45\RegRedRequirementsFeb2Ol O.doc
Page 3 of 3
Domtar Paper Company, LLC — Plymouth, NC

yDorntar
Paper Company, LLC
Plymouth Mill
Po Sox747
Highway 165 Will
Plymouth,A 27962
T 252:%N 1n
it all x-miswith papen.
www.donntal;Com
December
10, 2009
Division of Wafer (duality
Afin: Central Piles
1617 Mail Service Center
Raleigh, NC 27699-1617
Ceriil ed Mall
Return Receipts Req«ssiet
Subject: iV.PDES nuii #WS0001S), Year 1—Period 1 &foniiorin,; Period
Arr,gast 1, 2009 to Tanaaty 31, 2010. Regtured % n water: I nalyses jar Domtar
Paper Company, Lf C, Plyinoulh, Not!h Carolina
Dear Sit(s):
Eneloscil you will had the original and one copy of it completed "Stormwater Discharge
Nlouitoting Re'poiT' for the Year I — Period I Monitoring Period designated from August
1, 2009 to lanuaty 31, 2010. An attempt was made to collect a sample from each of the
designated outfalls that was not sampled during a previous storm event. This report
includes 7 of the 9 remaining required sampling locations reiluircd by Domiar�s storm
wetter permit No. NCS0001 89. Ile have also included it spreadsheet that contains
information regarding the progress of sampling during the reprcsenlative storm events.
The COD sample result for WWMI location was 316 ing/f2which exceeded the
benchmak value in our permit!ZAs it result of this cxcccdancc, s erecting and held
inspection was conducted per the action sups requircil by the permit. The report from
that meeting is included and 'further discusses what other actions need to be taken.
If you have any iluesnons or requite any additional hibrulation pertaining to this report,
please contact one by phone, P32) 793-7490 or by email, (amil:a boon 0dorntttr.o n ,

Permit Number: NC SOOD189
Cedhicate oF Coverage Number: NCG
STORMWATERDISL. RGEOUTFALL(SDO)
MONITORING REPORT
or
FACiLi -1-Y NAME Domer Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Diane Hardison, Tairl Boone & Alan Barnes
CERTIFIED LABORATORY(S) Columbia Analytical Lab*,' 527
Domtar Paper Company Co, LLC Labtl 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2009
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
TUBE OF PERMITTE
By this signature, I certify that this report is accurate and
complete to the best of my knowledge.
4AiiI
t,0
;D
Sanple4uhattow
A
s,
u-ir
'a'n
5
ni-
n
WYN
11/12/2009
6.61
17
316)34
7.4
Not detected
NBA
11/12/2009
6SI
3
37
17
6.3
Not detected
F-
iOBA
11/11/2009
6.81
10
93
49
T5
Not detected
LFOa
11112/200
6.81
2
46
69
6,9
Not detected
CL14
11/11/2009
6.81[
1
12
a4
8.2
Not detected
!LF02
1 1/12/2009
6.81
n
461
20
6.8
Not detected
i rn:'
11/11/2009
6.81
3
23
22
8
Not detected
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month"
!ir yes, complete Part E;)
Part E; Vehicle Maintenance Activity Monitoring Requirements
Cut
50050 a A 5 5 6i�- 530_F'<'
'
-f-y
r40
H�, , '-,s
Nie, I&
Aa Grease tF)e�Za to
n
OH,Usago 'Z
unit,,
SWDOMR
Yes
No
Note: There is a grage onsite, however it is Fully contained and drains directly to our
wastewater treatment system. Also, there are no outfalls located in this area.
U kWaterkSto,mwaier\SWAnalyticalReponFormNov2OO9 As
Form SWU 246-051100
Page 1 of 2

STORM EVEN CHARACTERISTIC:::
Date '11M 0-'12/09
Total Event Precipitation (Inches)
Event Duration (Hours)
(if more than one storm event was sampled)
Dare
'total Event Precipitation (Inches)
Event Duration (Hours)
Mail Original and one copy to:
Division of Water Quality
Alm Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
'I certify, under penalty of law, that this documem and all attachments were prepared antler my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee) (Date)
Form SWU-246-051100
SWDOMR U:\Water\Stormwater\SWAnalyticalReponFormNOv2009.%Is Page 2 of, 2

32
_7�n

Domiar gaper Company, " i C
Yermii No. NCS00O189
Siormwa'rer Sampling workshee?
Date
Outfall No.
�—
Time
Analytical Sampling
Point (Y/N)
It yes, was a sample
taken?
Flow
(Y/N)
pH
Total
Rainfall
(Inches)
Comments
OBA
12:33PM
Y
N
N
1_62
WYN
11;45AM
Y
N
Y
1.62
Only sheet flow. No channeled flow
CL11
12;02PM
Y
YES
Y
T6
1.62
CL14
1221 PM
Y
N
N
1_62
WLS01
11:25AM
Y
YES
Y
8.3
1.62
CL13
12:13PM
Y
YES
Y
7.6
1_62
LF01
10,25AM
Y
YES
Y
7.5
1.62
LF02
11:OOAM
Y
NO
N
1.62
_
VVRA
11:14AIA
Y
NO
Y
1:62
Sheet Flow
NBA
10 55AM
Y
NO
N
1.62
LF04
10:47AM
Y
NO
N
1.62
LF03
10:40AM
Y
NO
N
4.62.
No' Imv to pond because there is no runoff
from, the landfill. 16 has not yet been capped
and. closed.
RY01
11:41APA
Y
NO
N
1.62
CL14
2:37PM
Y
YES
V
8.2
6.81
—_
CP01
1:53PM
N
6.81
PRPA.
1:39PM
N
6.61
RV01
1:49PM
Y
YES
8
6.81
c
_
OBA
151am
t
Y
YES
Y
8.5. 7.5
6.81
FY01
10:40am
N
6.61
AR01
10:45am
N
6.81
It took more than five inches of rain to
generate flow at this site. There was no flow
LF02
9.46AM
Y
YES
Y
6.8
6.81
on the previous day
It took more than five inches of rain to
generate flow at this site. There was no flow
WYN
10:26AiM
Y
YES
Y
T4
6.81
on the previous day
It took more than five inches of rain to
generate flow at this site. There was no flow
LF04
9:12AM
Y
YES
Y
6.89
6.81
on the previous day
If took more than five inches of rain to
1
generate flow at this site. There was no flow
NBA
9:32AM
V
VES
Y
6.3
6.81
on the previous day
Highlighted information includes outfalls where a sample has been obtained.
Required sampling point where samples have yet to be obtained.

Sfoririwater Tier One Response Record
Domtar Paper Company, LLC — Plymouth, NC.
NPDES Ste) mwatei Permit NCS000189
I. Outfall — Woodyard North
2. Date of sample collection - November 12, 2009
3. Rain Event total — 6.82 inches
4-. Parameter exceeding benchmark value — COD
• A My= rmult — 316 mg/I
o Permitted Benchmark target— 120 inWl
o Date analyses received — November 20, 2009
5. Date of discussion meeting and stornnvater management inspection — November 30,
2009.
Participants:
o Marvin Flare —Woodyard manager
o Diane Hardison — Environmental (Manager
o Tamika Boone — Environmental Engineer
o Roger 1-larrell — Woodyard Operations
o John Gedu — hibedinc/Woodyaid Maintenance Mai Ligcr
o Allan Barnes — Environmental Engineer
6. Cause of benchmark excecdance — abnormally heavy rains produced flow that could be
sampled from the hog fuel (bark) pile, The area has not been observed to produce
channeled flow which could be sampled, before. However, nearly 7 inches of rain fell
over a 48 hour period November 10" — 11h of 2009. The rains washed over a bark pile
which likelyinleased volatiles into the runoff from the degrading wood.
7.140g tion Measures considered:
a. Dig a trench ;dong the south We of the ro, d which boarders the bark pile to collect
any runoff before it crosses road and flows into adjacent forest.
o Trench will cause safety issues with chip and bark trucks that travel the
road.
o Trench would encroach on ground water which would have to be pumped.
"Pere is no cost effective, technically feasible wily to pump the °round
water to any logical receiving location.
b. Build a small berm along the north side of the road which boarders the bark pile
to prevent any runoff crossing the road fi'om flowing into the adjacent forest.
o Inspect berm on a regular basis to ensure integrity
c. h'Istall some type of filtration device
8. Selected Option — b above
9. Implementation of mitigation measure must be complete by ._ Jai;t,ai,y -30, LQY.O
D Wmummmu and SoinesA6aunemuJLLoeul SmingAATcauy" ry Imancl Pi 1aeN 1LI(M a,rore:m TO One Hespnnsc
Bcc)rd Nov2009 doc Pu e I or I
As p¢prcd by Diane Hanlisim — Gnvi, unnKmal Depi
hcuvd to h': Iwod wish smrnim;ticr 1""Baia" Precendon Plant and Con Ip I iune<P I IIILI1 I

Donntaf Pape, Company. LLB_
�l Plymuulh Mill
PO Sw 57
al Highway 149 NO,
D Plyrncoth,nli VMI
T 3179'IAl
Itallbeginsixaltpope1'. wwwdonitar.[om
September 21, 2009
Division of Watci Quality
Aiin: Central tiles
1617 Vlail Service Center
Raleigh,NC 27699-1617
C'eriiped Mail
Retain Receiyts Repuested
Subject: IVPES Pei ma 9 NC'M00159, Yeat 1 — Period 1 itfoniioring Period
=1 ttg usi 1, 2009 io .lanuroy 31, 2010. ?egllired Siormuu7ler A1rrrlyses for Doanlai
Paper Company, LL,C, Plymouth, lVortll C(aolDra
Dear Sir(s).
Enclosed you will find the original and one copy of a cornpleied ' Stoomwater Discharge
Monitoring P.cport" for the Ycar I — Putiod 1 96naming Niod designated ninn August
1, 2009 to January 31, 2010. ;An attempt was made to tolled a sample hom each
designated outAH; however, there was no flow present at nine o, the outtalls. As a result;
this report only include, 4 oC the 13 required sampling locations required by Dormal's
storm water permit No. NCS0001 N. We will make every attempt to sample the
remaining locations during subsequent representative storm events b^foie the end of the
period
Ifyou have any ip shoos ur require any additional information pertaining to this report,
please contact me by phone, 1252) 793-7490 or by email, tamilhu„one;ii �Iumtar.eonI.
Sincewo,
I amiha Boone
❑VlC011nlellial E'.I1gII1::Cf
:,C: I)CIMI LI IIC 1it I11,.,

STORMVVATER DISCHARGE CUTFALL (SDO)
MONITORING REPORT
Permit Number INC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Bomar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Alan Barnes & Loren¢a Patin
CERTIFIED LABORATORY(S) Columbia Analytical 1_ab# 527
Domlar Paper Company Co, LLC I_abN 171
Wastewater Lab-Plvmouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2009
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Martin and Washington
PHONEYO. (252)793-1--,611
(SIGNATURE OF PERMITTEE OR DESIGNEE
3y this signature, I certify that this report is accurate and
complete to the best of !nv !ato'lacge.
Outall r^1.
�y
«kG
2
;.v..
Y
D
< s o�
"°D
it
lls—O
n y.
n`
.,Da
IVOA' .>^
{
SaPlpe '>•
©Ura ten
Raln a"
"`
Y{T'' c a'7`
p•�
-` -.+rr Y,
`y 'a" .-
s.
4
i.',
° 2
-
r.. x
v �.1
Eollected
.•c
FI5
w r .a
'^' �'
ingll
`
t, -.
�..;?;..
.,_.
Ivga. _„
Inches ,
❑7a11 Wig.;
<
Winter Log
Storage
3/31/2009
24 Hr
1.63
2.93
10
13
3.3
Not detected
Z�L11
8/31/2009
24 Hr
1.68
2.47
8
53
7.5
Not detected
:;L13
8/31/2009
24 Hr
1.68
2.54
11
4
7.6
Not detected
_F01
8/31/2009
24 Hr
L68
6.21
49
12
7.5
Not detected
I
I
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of nev+motor oil per month?
.if yes, complete Part D)
'art B: Vehicle Maintenance Activity Monitoring Requirements
J ufallxv-
v Pis
...
r �� �
Date '�i
Sample '4`-
C. ^F
Collected;
50050 V2':as�j
556$Y' -"'
530'400 `x'-- 4
I
TotafF16 7, K'n
A.— - i
f� � "t'Tu
G�4G
011 and "111To
r� a- "`T
Grmaa+s�eC�
�SSNat
aI
4'�" ) V .t xt > "£F
Suspentrled�3N"�.,,
Sp1 sr c1 tofvr
y h •.
molcld%YrraS y
MG '�
mg/I v_:,r -
mg/It"-:_,-zn ..- unit >,- 1
9al✓moc �4':`+.
(e5
No
Note There is a garage onsile, however it is folly contained anti drains directly to
our wastewater treatment system. Also, there are no outfalls located in this area.
Form SWV-24r-05t100
SWDOMR V:\Water\Slormwater\S%NAnalylicalrepora=orolAug2009 rls Pape 1 or $

STORM EVENT CHARACTERISTICS:
Date 3/3031/09
Total Event Precipitation (Inches) 1.G2
Event Duration (Hours) 24
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
Mail Original and one copy to:
Division of Water Ouality
Attn: Central Files
1G17 Mail Service Center
Raleigh, North Carolina 27699-1617 -
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
of Permittee)
2/21/2009
(Date)
c.v, EN1-240-051 too
SWDOMP IJ\Waler\Stormwaler\SWAnalvlicalPeportFomnA.U92000 sls 'ago?, of

STORMWATER DISCHARGE OUTFALL (SOO)
MONITORING REPORT
Permit Number NC S000189 or
Certificate of Coverage Number: NCG
FACILITY NAME Domtar Paper Company, LLC
PERSON COLLECTING SAMPLE(S) Alan Barnes & Lorenzo Palin
CERTIFIED LABORATORY(S) Columbia Analytical LabY 527
Domtar Paper Company Co, LLC Lab# 171
Wastewater Lab -Plymouth
Part A: Specific Monitoring Requirements
Samples Collected During Calendar Year 2009
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratorv.)
COUNTY Martin and Washington
PRONE f,10. [phone]
(SIGNATURE OF PERMITTEE OR DESIGNEE{
3v this signature, I certify that this report is accurate and
complete to the best of my knowledge.
(OutfalU'u'Gc
�{>
.r u
DaceEventx
a
.g�-^ss
Pi
C`pl eCleo, '�
1� '
� Ilo�� �
rt a'i�
I�clae�ss�{fit,
a
t x
k- ":*,z"
m9/I� ,r �.».k�
},
+zT°dY
rn�*�' a
av X"x 3 r e&
n���'� �
g .� :-t
r �`
'`k`
tE»gll � �
F
c. � a., . 7
� ..•w.nc,��i _
��'�
, Tc"^FM•as.,
Winter Lo
Storage I
8/31/2009
2a Hr
1 68
2.93
10
1„
3 o
Not delectetl
CI 11
_ 3/312009
24 Hr
i.63
247
3
53
7 C
Not detected
ICL13
LFUI
3131/200924
3/31/2009
Hr
24 Hr
1.63
1.68
2.54
6.21
11
49
a
12
7.6
7.5
Not detected
Not detected
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor of per month?
(if yes, complete Part B)
?art B: Vehicle Maintenance Activity Monitoring Requirements
Ou fa]IL�
50050 °- r
556 a
530 -
00
'% y
r
Sant pl
T�otalt
Orlon
Toga l`
p ty.
gel+rlo ors'?
s t .sa, ^"',
Collected
,#a •
Groase a
Stledl�:. §s
uspen
tom".
OII Usage y
z...
Solidsp,�t-�`","'r.�"
Y
I
y
N
Yes
No
Note: There is a garage onshe, however it is fully Contained and drains directly to
our wastewater treatment System. Also. there are no outfalis lor;aled in this Brea.
�WU.22r-051100
SWDOMR V9WaterlStonnwater\SWAnalvlicalReponFonnP.og2009. xis Page 1 of

STORM EVENT CHARACTERISTICS:
Mail Original and one copy to:
Division of Water Quality
Date 3130-31109
Alin. Central Files
Total Event Precipitation (Inches) 1,62
1617 Mail Service Center
Event Duration (Hours) 24
Raleigh, Ntmh Carolina 27C99-1r17
(if more than one storm event was sampled)
Date
Total Event Precipitation (Inches)
Event Duration (Hours)
'9 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
312112009
(Date)
prm NIV 2 16 0 1100
SWDOMR IJPage of 1-1

Domtar Paper Company, LLC
Permit No. NCSO00189
Stormwater Sampling worksheet
Date
Outfall No.
Time
Analytical Sampling
Point (Y/N)
If yes, was a sample
taken?
Flow
Y/N
H
Total
Rainfall
Inches)
Comments
OBA
12:33PM
Y
N
N
1.62
WYN
11;45AM
Y
N
Y
1.62
Only sheet flow. No channeled flow
CL11
12;02PM
Y
YES
Y
7.6
1.62
CL14
12:21 PM
Y
N
N
1.62
WLS01
11:25AM
Y
YES
Y
8.3
1.62
m
CL13
12:13PM
Y
YES
Y
7.6
1.62
LF01
10:25AM
Y
YES
Y
7.5
1.62
N
LF02
11:OOAM
Y
NO
N
1.62
o
0
W RA
11:14AM
Y
NO
Y.
,
1.62
Sheet Flow
(o
NBA
10:55AM
Y
NO
N
1.62
LF04
I
10:47AM
Y
NO
N
1.62
LF03
- 10:40AM
Y
NO
N
-
1.62
No low to pon because there is no runoff
from the landfill. It has not yet been capped
and closed.
RY01
11:41AM
Y
NO
N
1.62
CL14
2:37PM
Y
YES
Y
8.2
6.81
CP01
1:53PM
N
6.81
N
6.81
PRPA
1:39PM
YES
Y 1
8
6.81
RY01
1:49PM
Y
o
OBA
11:51am
Y
YES
Y
8.5.7.5
6.81
to
FY01
10:40am
N
6.81
AR01
10:45am
N
6.81
It took more than five inches of rain to
generate flow at this site. There was no flow
LF02
9:46AM
Y
YES
Y
6.8
6.81
on the previous day
It took more than five inches of rain to
generate flow at this site. There was no flow
WYN
10:26AM
Y
YES
Y
1 7.4
6.81
on the previous day
N
It took more than five inches of rain to
o
o
generate flow at this site. There was no flow
LF04
9:12AM
Y
YES
Y
6.89
6.81
on the previous day
It took more than five inches of rain to
generate flow at this site. There was no flow
NBA
9:32AM
Y
YES
Y
6.3
6.81
on the previous day
(Highlighted information includes curtails where a sample has been obtained.
Required sampling point where samples have at to be obtained. 7

AfColumbia m
Analytical Services- P. e: . o�..,,,.:V •.tno ..;:,....an<.e ��..-_;: n. .. .
September 21, 2009 Service Request No: J0904340
Diane Hardison
Domtar Paper Company, LLC
P.O. Box 747
Plymouth, NC 27962
Laboratory Results for: Stormwater Testing
Dear Diane:
Enclosed are the results of the sample(s) submitted to our laboratory on Scptcinber 2, 2009. For
your reference, these analyses have been assigned our service request nuntber.l0904340.
All analyses were performed according to our laboratory's quality assurance program The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results arc intended to be considered in their entirety, and Columbia Analytical Services, Inc.
(CAS) is not responsible for use of less than the complete report. Results apply only to the items
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report.
Please contact me if you have any questions. fly extension is 44W You may also contact me
via email atIl<issinger a easlab.com.
Respectfully submitted.
Colupthia Analytical Services, Inc.
U.L
Tom Kissinger
Project Manager
Page I of 3 Z
For a speci%ie li,u of ATL.I P-ucL) ccItIetl unalptes, refer co the c'et'Irfic(it ions section a
"n rug. c(is lob. con).
I

Client: Domtar Paver Company, LLC Service Request: J0904340
I'rojecC Stornmater Testing
SAINIPLF. CROSS-REFERENCE
SAMPLE N
CLIENT SAMPLE ID
DATE
'rimE
J0904340-001
Winter Log Storage
8/31/09
11-25
J0904340-002
CL-11
8/31/09
12:02
J0904340-003
CL-13
8/31/09
12:13
J0904340-004
LF-01
8/31/09
10:25
I
11 mI.J 912 lip91'23 Sxmple Sunm;nN Page I of

Cohtmbiu Analytical Se; vices, nc.
Cooler Receipt and R eseIvmion Norm
cnc
`eivice Request
:;ool;:r
q \
receh ed on ` � �, — ��� and op; Died On�A
COURIER:
CAS UPS FEDEX DHL CLIENT Tracking
-2-� ^ g
1
Were custody seals on outside of Cooler?
Yes Na 1vU.A
2
Were seals intact, signed and dated?
Yes No 4a
3
Were custody papers property filled out?
vex No NiA
Tempel of coolers a on receipt d: re_,, C) 1 1
P �) P 1 iSho�ld Cc» -a: g �.
5
Correct Temperature''.
tr.•` No N,�,
6
Wcic Icc of Ice Packs present
,1
Yes xo ^i4�
-
Did Lill bodes arrive in good midltion (unbroken, eic..... )?
N; ,
bPere all bottle labels complete (SLill 1p!c ID, prescrvs1 01It e.tc._.)'?
9
Did all bottle labels and tags i;«ree %. uh custody papers?
1 r
vftere the correct bottles used for .he taws indicated?
1 1
WV ru Al of the p-escrvcd 1 ottlas lh the approoru le or .rv.Itl%c%
, '+o 1 E
INO3 01,-2 H2SO4 PHo ZnAc2lNaOF1 nH%9 NLOH PFI%12
HCl n r•--
IL.,'�I V'.11',VC '.Iltd I�IL1115 I1GCd hCUVI
r
bV'ere all samples received widtin analysis holding times?�Q
�-
'Wcic VOA vials checked for absence main bubbles? if Present, nnte oeosr
1
I LI
Where did the bottles originate?
�, '•-S �� Client
Manuf. Lot 4 m CAS
I
Sample ID
Reagent
Chem ID
ml added
I inumals
i
1
II
I
Addlr:ortal eoiramnts and/or explanation of all discrepancies noted above
i
i
I
t
Clicrt
approval to run samples if discrepancies noted:
i
Date:,
1 -1

�E:e
�o��E�
_
--
�
6
_
E
�_
�Ee�e�—e=_
�CCC_
:CE
�
CE
�
_.
���CCe
C�
eoEv
:_
E_
�.
E
__
__C
',���
E�e�'
�
.
E=E
EE
__--
'EEB6
�E65E
.__.gym
—
s_
E
E
�E
"pie
��
��:C:C
�C
SCE
=
MEN
WEEEE6B5�B6�
6E
E�
E�°
E'
. .... . . . . . .. . . . . . . . . .a . .. . . . . . . .

:C
.: (,oluntbia
- AnnIyGC'.al
hme �o
CHAIN OF CUSTODY / LABORATORY ANALYSIS REQUEST FORM
9143 NO, Fhghway, Seat, 200 Jacksonville, F-londa 32256Q'none(904)739-2277/500-695-7222/Fm 904-739-2011
SlflaY390
contact
projocl Nvnc
Stomlwater Testint;
Project Nurnbcr
ANALYSIS REQUESTED (Include 19lethod Number an
0
_
Report To
Dime Hardison
Rcpon CC
Allan Barnes
'l
a
V
0
C
W
�
:J
z
'x
p
1. HCL
2. R!J03
3. H2SO4
4, NaOH
Accra ,
6, MCOH
7.Na SO4
R'MARKS
Cian, my/Addre3s
Domtar Pater Company
P.O. ]iOS 747
PIY'Inouth, NC 27962
Phanc 4
252-793-9611
FAX d -
A
252-793-SS71
Sampler's Sigyawrc
Sampler's and Namc it—
fir ;/'c ✓�'
CLIENT SAiAMLE ID
I.AB ID
SAMPLING
DATE TIDIE
»tri
Winter Log Storage
DIOxin
8/31/09
1125
Water
2
X
CL-I1
Dioxin
8/31/09
12:02
Water
2
X
CL-13
Dioxin
8/31/09
12:13
Water
2
X
LF-01
Dioxin
8/31109
10:25
Water
2
X
Winter Log Storage - AM
CL-11 - PM
CL-13 - PM
LF-01 - AM
Stormtiarcr Stsinples for l)Iailll -t'o,ting. �.
G (
��N, /']Cf ��.�•�✓"rJ/ �f/�✓`y" iN '--c. C't C!s>A
/
'
TURNAROUND REQUIn8MN\'TS
RUtia(SUR61•VQO&S MPL19
taltQn D
RE I.RSTEDF \DATE
i orott mRETORTDAM
REPORT RE( UIItRMENTS
T. RerWU OWy
IT Rauht t QOSw�una
(LC3..NSMSDurWooll
X III.RUW1a Y �QC wE CWLttllon 3wvmior
IV. Opn Vu4Cwlon Report w Rry Du
FIE }•LS No
1110rcB I.YFORNpT10N
p/ f�
Po.H Y.Y YPW 4V D.
BiY to:
V t e uuh w r
si,ro,re '✓ 7.
4
Galva y
Signnt➢m
c qmx c y
Sipamrc
Hery
3"'t, -
e q y
Sigtlttom
cerne y
Sigrunue
Pnmed N
Prootod Name
Prurt,d Namc
Pemted Name
Prinmd Name
F
F
Firm
F.
Damp' m /
/// n c s t„p�'1
Dalc/rimc
Umdlvnc
U /I'imc
_ C` �J t�
D [elflme
ate/flme

Columbia
Analytical Services -
Appendix A
Columbia Analytical Seivices
9143 Philips Highway, Suite 200
Jacksonville, FL 32256
Tel [phone]
Fax [phone]
Subcontracted Analytical Results

4RY Columbia
1 Analytical Services- 19408 Park feov:. Suite 820. Houston, TX 77084 1 711266.1599 c:v :v.caslab com
September 17, 2009
Tom Kissinger
Columbia Analytical Services
9143 Philips Hwy, Suite 200
Jacksonville, I'L 32256
LtlboiMoiyResults for: SlurmwaterTesiing
Dear Ton:
Service Request No: J0904340
Fnclosed are the results of the sample(s) submitted to our laboratory on September 03, 2009. For
your reference, these analyses have been assigned our service request number.10904340.
Analyses were perfonned according to our laboratory's NELAP-approved quality assurance
program. 1'he test results meet iequitements of the current NELAP standards, where applicable,
and o.xcept as noted in the laboratory case nan'ative provided. All results are intended to be
considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible lot
use of less than the complete report. Results apply only to the items submitted to the laboratory
fur analysis and individual items (samples) analyzed, as listed in the repots. fit accordance to the
NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any
quantitative analysis will be supplied upon request.
Please contact tine if you have any questions. My direct line is 281-994-2954. You may also
contact me via email at Dl31lus@crfshl).com.
crfshl).com.
Respectfully submitted,
Columbia Analytical Services, Inc.
Ny
Danen Biles
Project Manager
For a specific list ofNELAP-accredited nualvtes, refer to the certlfications.sectiazat ...
wunn�. cnsf ub. rnnl.
Emnlir^._ Onmec cmnoanv NEUNP ArcreCited AOL Sao[ of DC HPMCfl Flv;ard Please consic`." the a:nvironmon[ ceior� printlng
1 of 26
7

Columbia
Analytical Services-
.
Certificate ofAnalysis
�I
i
19408 Park Row, Suite 320, 40usTon, 7X 17084
Phone [phone] Fax [phone]
vw v caslab com
A Em01oy eO. d(.""a,Y
2 al 26
S

COLD BIA ANA[,V ICA L, SVRV ICES, INC
Client: Doubter Industries
I'rojece Smarewater Testing
Sample :Matrix: water
CASE? NARRATIVE;
Semce Request No.: J0904340
Date Received: 9/3/09
All analyses were performed in adherence to the quality assurance program of Columbia Analytical Services, Inc.
(CAS). This report contains analytical results for samples designated for Tier II. When appropriate to the method,
method blank results have been reported with each analytical test.
Samnle Rece,ini
Four Water samples were received for analysis at Columbia Analytical Services ou 9/3/9.
The samples were received at 0°C in good condition and arc consistent with the accompanying chain of custody
form. The samples were stored in a refrigerator at 4°C upon receipt at the laboratory.
Please note the reporting forms are currently referencing the date CAS- Jacksonville received the samples (9/2/09)
and not the data CAS-Flouston received the samples (9/3/09.)
Data 1'alidation Notes and Discussion
rMS/Ur\iS
EQ0900362: Laboratory Curial Spike/Duplicate L,iboratory Connnl Spike (LCS/DLCS) sonmplcs were analy-ccd
and reported in lieu of an NIS/DIMS for this extraction batch. The bareh quality control criteria were met.
Detection Limits
Detection limits arc calculated for each congenerin each simple by nicaswing the height of the noise Icvcl for each
quantization ion for the associated labeled standard. The concentration equivalent to 25 times the height of the
noise is then calculated using the appropriate response factor and the weight of the sample The calculated
concentration equals the detection limit.
Approver) bv:.f(c
Niang(Im Liang, Labm'atory Director
Data: 09/18/09
3 of 26
9

Cliem: Suectrwn Anale'tical. hac.
19 ujccc Jamaica GW
SAMPLE CROSS-REFERENCE
SAMPLE / CLIENT SAMPLL' ID
K0904340-001 SA9476MI
K0904340-002 SA9476S-01
Poim.J 9'i;'09 1 i'.17 Snmple Smunu»y
Scwice Rqucst: K0904340
DATE TIME
5/13/09 10.05
5/13/09 10.05
a126
10 Payc

Laboratory Certifications
2009-2010
STATE/PROGRANI
AGE' INC Y
CERTIFICATION ID
EXP DATE
ARIZONA
AZ-DHS
AZ0723
05/26/10
ARKANSAS
ADE
09-048-0
06/16/10
CAI-IPORN A
CA-ELAP
2452
02/28/11
Ri-of mA/NELAP
PL-DOHS
E87611
_
06/30/10
HAWAII
HI -DOH
N/A
06/30/10
IWANOIS/NGLAP
II --EPA
002122
10/06/09
LOUISIANAANELAP
LELAP
03048
06/30/10
MAINE
ME-DOFIS
2008031
06/05/10
MICHIGAN
NIfDEQ
9971
06/30/10
M INNESOTA
iNIDH
048-999-427
03/25/10
NiwADA
NDEP
'FX014112009A
07/31/10
NcwJusity
N1DEP
TX008
06/30/10
NEW iIN9EXICo
Niv1ED-DWD
N/A
06/30/10
NEW YORWNELAP
NY -DOH
11707
03/31/10
Ne ESC/NAVY
NEESC
N/A
01/09/10
Oia-niaoNlA
OKDEQ
2009-25
08/31/10
OREGONhN'E,l,AP
ORELAP
TX200002-006
03/24/10
TENNrSSEE
TNDEC
04016
06/30/10
'I'EXASII ELAP
TCEQ
T104704216-09-TX
06/30/10
LTA H/NEI,AP
U'PELCP
COLU2
06/30/10
SOn-IMPORT PE,RMI'I
USDA
7330-09-00067
03/27/12
WASHING ION/NIA-AP
WA-Ecoluuv
C1855
I1/14/09
cVEsI Vie(
WVUEP
3,17
06/30/10
5 M26
11

Abbreviations, Acronyms & Definitions
Cal
Calibration
Conc
CONCentration
Dioxin(s)
Polychlorinated dibenzo-p-dioxin(s)
EDL
Estimated Detection Limit
EMPC
Estimated Maximum Possible Concentration
Flags
Data qualifiers
Furan(s)
Polychlorinated dibenzofuran(s)
g
Grams
ICAL
Initial CALilontion
ID
IDentifier
Ions
Masses monitored for the analyte during data acquisition
L
Liter (s)
LCS
Laboratory Control Sample
DLCS
Duplicate Laboratory Control Sample
MB
Method Blank
MCL
Method Calibration Limit
MDL
Method Detection Limit
MRL
Method Reporting Limit
mL
Milliliters
MS
Matrix Spiked sample
DMS
Duplicate Matrix Spiked sample
NO
Number of peaks meeting all identification criteria
PCDD(s)
Polychlorinated dibenzo-p-dioxin(s)
PCDF(s)
Polychlorinated dibenzofuran(s)
ppb
Parts per billion
PPm
Parts per million
ppq
Parts per quadrillion
PPt
Parts per trillion
CA
Quality Assurance
QC
Quality Control
Ratio
Ratio of areas from monitored ions for an analyte
%Rec.
Percent Recovery
RPD
Relative Percent Difference
RRF
Relative Response Factor
RT
Retention Time
RRT
Relative Retention Time
SDG
Sample Delivery Group
S/N
Signal -to -Noise ratio
TEF
Toxicity Equivalence Factor
TEQ
Toxicity Equivalence Quotient
6 of 26
12

Data Qualifier Flags — Dioxin/Furans
o B Indicates the associated analyte is found in the method blank, as well as in the sample.
o C Confirmation of the TCDF compound: When 2378-TCDF is detected on the DB-5 column,
confirmation analyses are performed on a second column (DB-225). The results from both the
DB-5 column and the DB-225 column are included in this data package. The results from the
DB-225 analyses should be used to evaluate the 2378-TCDF in the samples. The confirmed
result should be used in determining theTEQ value for TCDF.
o E Indicates an estimated value- used when the analyte concentration exceeds the upper end of
the linear calibration range.
o J Indicates an estimated value - used when the analyte concentration is below the method
reporting limit (MRL) and above the estimated detection limit (EDL).
o K EMPC- When the ion abundance ratios associated with a particular compound are outside the
QC limits, samples are Flagged with a'K' flag. A'K' flag indicates an estimated maximum
possible concentration for the associated compound.
c U Indicates the compound was analyzed and not detected.
o Y Samples that had recoveries of labeled standards outside the acceptance limits are flagged
with'Y'. In all cases, the signal-to-noise ratios are greater than 10:1, making these data
acceptable.
o ND Indicates concentration is reported as'Not Detected'
c S Peak is saturated; data not reportable.
o P Indicates chlorodiphenyl ether interference present at the retention time of the target
compound.
o Q Lock -mass interference by chlorodiphenyl ether compounds.
7 of 26
13

CAS/HOU - Form Production, Peer Review R Project Review Signatures
9 / 17 / 09 Reviewer
8 of 26

Columbia
Analytical Services -
Analytical Result.
3
I
19408 Park Row, Suite 320, Houston, 7X 77084
Phone[phone] Fax[phone]
:.vww.caslab.com
—____ Fln En;ploy ee O:vned Company
9 of 26
15

CoLOINJIBIA ANA L VII C\ I. SFR VI CES, IN(
Analytical Report
Client:
Domtar Industries
Sni4ce Rec nest:
J0904340
Project:
Stornmatcr Tcstine
Date Collected:
8/311091125
sample Mat, iz:
Water
Date Received:
9/2/09
Sample N:une:
Winner Log Storage
Units:
pg/L
Lab Code,
J0904340-001
Basis:
NA
Polychlol mated Dibenzodoosins
and Polychlol noted Dilmaofm':ws
by
1IRGC71LRA'IS
:Analytical Method:
1613B
Dote Analyzed:
9/10/09 1443
Prep Jicthod:
Method
Date Cxtrocted:
9/4/09
snmpleAnioont:
Mill
Insb'umcnt Name:
E-1 RIMS-04
GC Column:
DB-5
Daln File Name:
P204129
Blank File Name:
P204103
ICV, Dot':
03/20/03
Col Ver. File Name:
P204122
ion
Dilation
:An:dyle Non„
Ihsalt Q
EI)1. Mitt.
Rntin
IMI Pauor
2.3,7,3-1 CDD
ND U
0.355 10.9
1
Spike
Cone,
Control
Ion
LalideA Campnu1OI4
Cooc(pg)
Found (pg) %.Ree Q
Limits
Rolio 1212T
13C 2.3,7,3-ICDD
2000
1300.000 65
25-164
0.78 1.007
37CI-2.3.7.3-TCDD
300
692,895 37
35-197
NA 1,009
I'uumd 91 ]l09 I In,
ynlw+^.luiliu.. �imsR.VID\mlyi¢ilR<Wc ryi
Form IA
R'r,..m.. ay.0000l IfArff
16

COLIi\IBIA :wAIXI I CAI. SKRVICES, INC
Analytical Reputt
Clicno
Dotmar lndusnics
Sm ice Ro,loosl:
J090434U
I'rnjecl:
Smrnmiter Testing
Date Collected:
3/311091207
Snugtic Alalcis:
Water
Dalo lleccire d:
9/2/09
1:.... plo Nn I,, C:
CI: I I
IJ u i I%;
pg/I.
I,ab Cndc:
J0904340-002
Basis:
NA
Polychlurivated Dihcnzodiosins
and IIt c It l nl'i n a l c tl Di
bcn zu IItIva by
1112GC/I IIL\IS
Anal)ti'A IMothod:
1613B
Datc Analy'zetl:
9110/09 1530
I'rcp AlclIIA:
Method
I)nlc Estrncted:
9/4/09
Sample Amuuw:
940mL
Instimnent Nnmr.
E-HRMS-04
GCColumn:
DB-5
Darn Filc Na nm:
1`204130
lilanla file IN:
P204108
IC:AL Dalo:
03/20/08
Cul Vcr. file ','ante:
P204122
Ia:
Dihtlinu
A"A'tc Namc
Result Q
EDL Mid-
Ratio
RRf Icael nr
2.3 7,S-1'CDD
ND U
0.354 10.6
1
Spiltc
Cnnc.
Connol
Ion
I.abelud Compounds
Conc.(pg)
Pound (pg) %Bec Q
Limits
Ratio RRT
)3C-',3,7,S-FCDD
2000
1377.510 69
25-164
0.78 1.007
-,7(:1-'_,3.7,3=1 C'DD
100
722.399 90
35.197
NA LOOS
I'r0un! of 17V11) I1 nE I'onn la
'Jurin.. S,.uLno�Ilrns0.eM1°bnlyualRrynr, mr Sn Sat Rd,,— o9 W001
o" T1'bt`ff
17

COLUiNIRI A:%,NALYI'I C:AL SERV I CES, INC,
Analylical Repurt
Client:.
Donitar Industries
Project:
Stomltvater Test in
Simple d'latrim
Water
Sample Nome.:
CL-13
Lob Code:
10904340-003
Service Requesl:
J0904340
Mile Collected:
8/31109 1213
Date Received:
9/ 2/09
Units:
pg/L.
Basis:
NA
Pulychlnrinnted Diherundiouns and Polycblon ivated Dibcnzo(urans by IIRGC MINIS
Analytical Method:
1613B
Date Analyzed:
9/10/09 1618
I'rep,McOm&
Method
Date Extracted:
9/4/09
Sanlple,Anlnl,W
940mL
Instrument Nanle:
E-FIRMS-04
' GC Coln nm:
DB-5
Detu File Nome:
P204131
Blank File Name
P204108
ICAI, Date:
08/20/011
Cal Vcf. File Name:
P204122
loll Dilutioll
:A,A'F'iA'nmc
I2cull Q F1)1. A1121. Ratio RR7 Factor
2,1,7.8-1 C D D NO U 0.238 10.6 1
Spike Cone. Control Iml
labelcil Cunlpuunl)s Conc.(pp) Found (pg) %Itec Q Limits Ratio RRT
3C2.3,7,8-TCDD 2000 1412.95S 71 25-164 0.77 1,007
37C1-2.3.7,SJCDD S00 723.263 90 35-197 NA 1,008
on.nn...c,.
I'JumJ 9:I7109 I1'.01 F.— I A
.Inxm.:lsi.�IImS I.uiuK.pSUmly u<oIll,rl qn suptda aeic...... 09 000011 1
P� brz€°
is

CO I, UN I B IA ANAL'i"I ICA 1,SFIMCFS, INC.
Analytical Report
C;ienC
Dona, Industries
Crojccc
Stormtvater Testing
San, ple dln[cir
Wnter
sample Name
LF-01
lab Code:
J09043-10-004
Service RalucsC/0904340
Date Collected: 8/31/09 1025
Dole Received: 9/ 2/09
Units: pg/L
Basis: NA
I'ol3chlorinated Dibenzodinsins and P olychloi inated Dibewofuruns by IIRCCAIRNIS
Anal -y ical iMelhod:
1613B
Date Analyzed:
9110/09 1706
1'rcp dlclhod:
Method
Dale PaImefed:
9/4/09
s:unplc ,Amound:
930r11
Inste unient Name:
E-1IRMS-04
.
GC Column:
DB-5
Data File Name
P204M
Blank File Nme:
P204108
ICAI. Date
08/20/08
Cal Ver. File Name:
P204122
Ion Dilnlinn
Anolp(c Name
Result Q EDL tNIRI, Ratio RRT Faelor
2,3 7,3-fCDD
I..�bcicd Cu nipoun Js
A'D U 0.348 10.8
sp he Conc.
Cone(p-) Found(pg) %14Q
Cunlcnl Inn
Limits Ratio RRT
IX-2,3.7,8-fCDD 2000 1232.920 62 25-164 0,78 1.008
37CI-'_,3,7, 8-fCDD S00 735.856 92 35-197 NA LOOS
h lined 91I7mo I I OZ funn I
nniln.,SlSmllmsa.I�ns0..erbtmlyiimiaepo¢ryi Sup�rSat Refumce. Meo001qYa
002p
19

COLIL\IBIA AN•AIX11CAI, SFRVICES, 1NC.
Analytical Report
Client:
Domim Industries
P, Jj ,I:
Stomwater Tesliug
Sample rNimri.c:
Water
Sample Name:
Method Blank
Lab Code:
17Q0900362-01
Semcc 12cqucsu J0904340
Date Collected: NA
Date Rcceiecd: NA
Units: pg/L
Basis: NA
Polychlm'inated Dibenzodioxins:md Polychlorinated Dibenzofm ans by IIRGUIRMS
Anal} licol lMd1bod:
1613B
Date Analvzcd:
9/9/09 1906
Prep M,chod:
Method
Date Exoacicd:
9,14/09
Sangdc Anmuu l:
1000mt.
Inso m,,m Name:
E-I'IRNIS-04
CCColumn:
DB-5
D.,Fn I II, S.rmc:
11204105
Blank Rile Name:
P204103
ICAl. Dale:
09/20/03
Cal Ver'. Rile N•anre
P204106
Inn Dilution
Anolyle Name
liesoll Q EDL MRI, Ratio RRI' Racmr
2.3.7,8-1 CDD ND U 0.333 10.0
Spike Con,. Contml Inn
L:JrdrJ C'ompu"^'la Coac.(pg) Round (pg) V.R,, Q Llmib Ratio RItT
1',C-2,3,7,8='C'DD 2000 948,243 47 25-16`1 0.77 1.003
37C1�2,3,7,3-TCDD H00 614.495 77 35-197 NA 1.009
(:uom... "
ILvn„1 v:! UOY I p; Form I A
Ia0r.+.,Yna,r•d LrrniNugUmlyrialRe{wn rVr S,P ,Sn Wn<na'. 09-000012`ih OF`Lp
20

SSColumbia
Analytical Services -
Accuracy and Precision
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www,caslab.corn
15 of 26
21

COLUdI Ii IA ANAL1 I IC'AL 6L It \'1 Cl'S, INC.
QA/QC Report
C'.licnf. Domiar lodustrics
Sclvicc l2equcsC J0904340
Pnijec I: Slorrnwaier Testing Date Anzlyzcd: 9/9/09
Sangde Dlztrix: Prater
Lab Comrol Sample Sumnmrp
Polychlorin:led Dibenzodioxins and polvchlal'innted Dibenzofivaos by IIIICC/11101S
Anal, Beal lAlethod: 1613D Units: pg/L
Prep I\Icthod: Method Basis: NA
Lab Couirol Sample
EQ0900362-02
Annlrte Nan'c Result Expected % lice
2,3.7,8- l C DD 231 200 116
Gsbaclinn Lot: 95259
D uplicale I,ab C ntrol Sample
EQ0900362-03 % Rec RPD
R"idt E.tpccicd %Rec Limits RPD limit
227 200 114 67-158 2 i0
I'iinlul FYI L1�0 11 03 LA CII S.nnpla 5nmmory
J In 11,,,T9In, lmI �l.InIdtaps'.L>bConlol SeinpR In SuparSS<iRderen[e 09-0a001'OJ]nRf',pp
I O7 7

COI-IAIRIA ,ANA LYTICAL SFRVICGS, hVC.
Analpeal Repor[
Client:
Dom(ar Industries
I'rujec l:
S torawate r Test in
Sat, p I, dla I,
Water
Sample Nam":
Lab Control Sample
Lob Cud":
F.Q0900362-02
Service Request: J0904340
Date Collected: NA
Date Received: NA
Units: pg/L
Basis: NA
P olychim inned Dibenlodioxins and Pal)chlor inated Dihcnrol i,rans by 1112GC/ARMS
Anah tied Mcthod:
1613B
Date Analyzed:
9/9109 1518
I'r"p ;Method:
Method
Date FXtroc ed:
9/4/09
Sample Anuuurt:
1000mL
Instrument Name:
B-FIRMS-04
CC Column:
DB-5
fit" Name:
P204104
Blank file Name:
P204108
K, %I, Date
08/20/08
Cal Ver. file N':une:
['204099
lot, Dilution
:xnnlyle Name
Result Q CsDI, NIRL Ratio RRT Fact",.
2,3,7.9-1-CDD
231
0.245 10.0
0.76 1.001 1
Spike
Con.
Control Ion
:.ibdnl Comlioinitls
Con.(pg)
Inund(pg) '%R"c Q
Limits R:din Rli'I'
13C-2,3.7,R-TCDD
2000
1355.027
68
25-164
0,78
1.008
37CI-2,3,7,8-TCDD
Soo
732,327
92
35-197
NA
1.009
i:112 1' inn, I A
- -I,izI su,r.,.... rv-aooizj'PbYz6'
23

('()[,I IN I AINA1.1 I RCA 1. .S 6:RV IC4:S. INC':.
.Anal; ucal Repou
Client:
Doom, Industries
Prnj"I:
Stomm:ner Testing
S:unple Matrix:
Water
Sannpl, Fa nnc:
Lab Control Sample Dup
I.ah Cade:
EQ0900362-03
Scn'icc Bequest: J0904340
Dnlc Collected: NA
Date Received: NA
Units: pg/L
Basis: NA
Polychloriented Dibenmdiosins and Polrchlmmated Dibenzolurans by II12CC/FIRMS
Analyticnl Method:
1613B
Date Analyzed:
9/9/09 1606
Prep n\Iethod:
Method
Date Exlracted:
9/4109
Soniple A'nounC
1000nnL
Insh'unenl Nuns
E-HRMS-04
CC Column:
DB-5
Data File Name:
P204105
Blank File Nave:
P204103
]CAL Dane:
03/20/08
Cal Ver. File N:une:
P204099
lou Dilution
,An:dyle lN.'nm
Result Q PDL INIRII Roan WIT Factor
_i?.5=I CDD
227
0.259
10.0
0.77 1,000 I
Spiltn
Con'.
Canlml Inn
I-:Ibelcd (on,puands
Cnne(pg)
Fomnd (pg)
'Y.nlac Q
Li ... it, Ratio RRT
13C-2,3,7.VTC'DD 2000 12,14.291 62 25-164 0.73 LOOS
-7C'I-2.37,3-TCDD 800 698.849 37 35-197 NA 1.003
rdm<a 11 I7A19 1 1 61 Fmin IA
Huna..+SudlmnUmiaepidn+l.enl0.epun I, SnperSn ReR¢nu OWN 1
'WbrAll
24

Columbia
Anal)tflcal Services -
Chain of Custody
19408 Park Row, Suite 320, Houston, X 77084
Phonet713)266-1599 Fax[phone]
www.Caslab.COn1
Ao E,npinyee Owned Campany
19 of 26
25

I'rojea N'nmv: 9unnu:ner Tcv im;.
I'nijrtt \'uni hr. r.
1'n,jccl ?L nxgvr Ui:us IlivJi>on
Cmnpa ny: Dunv:u Paper C'nn,pmn', LLC
fjlti2l-l\1et\i7ulR Ctlal❑ OfCusto (y
9143 Ph i llpe High.cn� t lc, F1. 3", 91H-739-2" 77 -FAX [phone]--'011
S I.
. en,p,
Date
I
Lab Code
CI Ien. Sa m p le lD
nnf Corn. AIa Mc
Dole l'in,e
Itecelced
Scnd F.
J0904340-001
! Winmr l og Storage
—r
Wmar
9g1/09 1125
92f09
110USTON
ll
J0904340- 00_o
I CI.-11
W:eaI10
I'_02
9209
-! HOUS"fON
II
J0904340003
J0901340004
(L 1_
LP 01
T Wall'
Wiwi-R/a
8/31/09
l/1N)
1 I'll
102i
9/_/09
9/2/09
HOUSTON
HOUSTONif
"I'cst Ca.nnwuts
Diocins Rims - 161 iD J091H340-001,2,1 4
Special lu.vruuionsfrom men..
PLEASE SEND
RESULTS TO
1441JUY SOL L I VAN
237E "fCDD onlr,rcpun in myi
-1'urnn, oun❑ Rcgni remcn is
_RUSH (Sumhargcs Apply)
PLCASE CIRCLE VWORK DAYS
1 _ n 4 5
ST'A,NDARD
Rcqucncd FAX D,tw
Requcncd Report Drdc:, 09/23/09
CAS Contact Tom Kissinger
t
Report Requirements
I. Rcsults Only
_ 11. Rcsults + QC Summaries
_ III. Results -OC and Cnlibmma Smnmarics
IV. Data ValAntion Report pith Raw Data
PQU\IDVJ Y
EDD N
D.colcc Intonnatm
J090M1;M10
to
Rclinquishul 13Y: (LU/� RttcivcdB /// �Jv /�{� Airhilt N,:mbcr:
26 `/9f0 /
7
(�I � �
i
Pngc

' Reset Form_
Columbia Analytical Services, Inc.
Cooler Receipt Form
Clicnt/Project Domtar Paper Company / Storinwater Testing Service Request
Received:---- 09/03/09 Opencd (Date/Time): 09/03/09 0955 By:
J0904340
NAB
I. Samples were received via? ❑US Niail ❑heder ✓❑UPS ❑DHL ❑Courier
❑Harr! Delivered
2. Samples were received in: (circle) ❑Cooler ❑Box ❑ Other
❑NA
3. Were custody seats present on coolers? ❑✓ Y ❑N If yes, how many and where?
If present, were custody seals intact? ❑✓ Y ❑N If present, were they signed and dated?
Ely
❑N
4. Is shipper's air -bill tiled? ❑NA ❑Y ❑J N II not, record an bill number: 1ZX5WO980140778136
5. Temperature of cooler(s) upon receipt (°C): 0
6. If applicable, list Chain of Custody numbers:
7. Were custody papers properly filled our (ink, signed, etc.)?
❑NA ❑Y
❑N
S. Packing material used: ❑Inserts ❑J Bubble Wicip ❑Slue /ce ❑✓ 4'et Ice QSleeves ❑Other
9. Were the correct types of bottles used for the tests indicated'?
❑✓ Y
❑N
Did all bottles aiTive in eood condition (unbroken)? Indicate in the table below.
QY
❑N
Sample iD
Bottle Count
Bottle Type
Out of Temp
Broken
Initials
❑
❑
❑
I❑
❑
❑
❑
❑
❑
1 ❑
❑
1 ❑
10. Were all bottle labels complote (i.e. analysis, ID, etc.)? ❑J Y ❑N
Did all bottle labels and tags agree with custody papers? Indicate in the table below. ❑Y ❑N
Sample ID on Bottle Sample ID on COC Sainple ID on Bottle Sample Ill on COC
11. Additional notes, discrepancies, and resolutions:
21 of 26
Page'': ❑I ❑2

Sample Acceptance Policy
Custody Seals (desirable, mandatory if specified in SAP):
✓ On outside of cooler
✓ Seals intact, signed and dated
Chain -of -Custody documentation (mandatory):
✓ Properly filled out in ink R signed by the client
✓ Sign and date the coc for CASMOU upon cooler receipt
✓ Coc must list method number
✓ If no coc was submitted with the samples, complete a CASMOU coc for the client
Sample Integrity (mandatory):
✓ Sample containers must arrive In good condition (not broken or leaking)
✓ Sample IDs on the bottles must match the sample IDs on the coc
✓ The correct type of sample bottle must be used for the method requested
✓ The correct number of sample containers received must agree with the
documentation on the coc
✓ The correct sample matrix must appear on the coc
✓ An appropriate sample volume or weight most be received
Temperature Preservatives (varies by sample matrix):
✓ Aqueous and Non -aqueous samples must be shipped and stored cold, at 0 to 60C
✓ Tissue samples must be shipped and stored frozen, at-20 to -10°C
✓ Air sarnples can be shipped and stored at ambient temperature, -23°C
✓ The sample temperature must be recorded on the coc
✓ Notify a Project Chemist if any samples are outside the acceptance temperature or
have compromised sample integrity - the client must decide re: replacement sample
submittal or continue with the analysis
Cooler Receipt Form, CRF (mandatory):
✓ Cooler receipt forms must be completed for each coc 8, SRtt
✓ Sample integrity issues must be documented on the CRF
✓ A scan of the cagier and the airbill number must be recorded in CAS LIMS
Sample Integrity Issues/Resolutions (mandatory):
✓ Sample integrity issues are documented on the CRF and given to the Project Chemist
for resolution with the client
✓ Client resolution is documented in writing (typically email or on the CRF) and filed in
the project folder(s)
22 of 2G
28

Pblder h:
J090-13411
Client Nnntc
Domon Ind usn ms
111'0jecr Name:
Sturnnvnrcr l"Inne
Project Number:
Rc pnrf 'I'n:
Diane FI'.0 disun
Domtar Toper Company, LLC
P.O. Bos 717
PI) mouth, NC 27962
Phone Number:
252-793-861 I
Cell Number
Fu, Number:
252-793-SS71
L-mzil:
dimtc.haMisunliidonnar.com
Service Request Summat
Project Cln,rn,s L.
D:un'n Riles
Or iginating Lub:
JAN
Logged Rp:
SI.IGHI Sf Y
Date Received:
9/ 2/09
Internal Duc Dora:
9/23i09
QAP:
LAIC OAP
Qualifier Set
CAS Standard
Formset
CA.S Standard
Mergcd7:
N
Report to MDL'.>:
Y
Y.O. Number'.
45'ID161974
HDD:
No FDD Spectfed
0
CASs:-,, n„
cn".l s,.,n1�r+.�.
J0904)cU-001
\\'in¢r Lug Slant:.
\Va¢
6r)Itt19
11351 It
II1901340-001
01.11
\Veer
8131/09
COy1 ti
... ..
J09Ui NU-003
L'L I)
L
..
\Vnl.r
..._...I
861/U9
....
C1)i I( I
J0901340-004
_..,
LF-UI
Naler
S:i 1/09
1025 (1
Test Continents:
Croup Tesd.%IV lhnd
Semivoa GCMS
Prne<d 9/152009 1'162811M
Samples
Comntcnts
Dioxins Furans/161313 1-4 2375 TCDD only,repori in mg/J.
scrvlcc ltcqu¢I for J0904340
n . our, n, l: Glass nolne e'11 tl:.lnlir n-0un Liner unluaacn:.,l
Location: 8-WIC01
NrDES
23 of 26
Pups I nr I

Piepnralitin Lrfior/na/ion Benchsheel
I'rg1 Rung: 99359 I`re1, %%:.1 lu+a: OrpFzlA,1(365) St:nu.: Prepped
'Ib:mr Semivua GL'\4S/.NC ODUR 1'rap NktIwd: Mt,lhod Prep Dut Jl'in , 961/09 1 C0D AM
a
Lah Code
Client ID
BM
Method /Test
pH
Matrix
Amt. Ext.
Sample Description
I
L0900215-UUI
1329231
'01
10331Dioxins F1umu
3
Wmc+
IIUUmL
clear colorless liquid
E0900723-001
67411ii
tll
1613 B/Diuxi ns Fnrnnn
9
Wmmwarur
930mL
ycl l o.v llgaid
3
E0900724-001
Camp Upfh+u OF-001 Cu.",
01
1613B/Diocins Hums
9
Wnamwnncr
1000mL
dnv colorless liquid
c
E090025-00I
11125D
.01
1613 B/Dioxins Fnrnns
V
Wa1cr
100 L
drnr cnlcnf-s liquid
5
C0900729-001
U413D82709
01
I613B/Dio.eins Fnrnns
1
Wn1nr
990mL
clear enlorless ""quid
6
C0906729-002
RP4AO82709
.01
1613B/Dioxins Finns
S
WnIc+
960inL
Lrown liquid
2
E0900739-DOI
3:2567001
.01
1613B/Dioxins Fnrnns
9
Drinking tt':dxr
1000n 1-
Ydlnw lulu liquid
8
1:0900939A01
142F66001
01
16138/Dioxins Fans
6
Ddnklug Walur
91Dn+L
y<Iluw tined liquid
9
E0901,239-003
312615001
01
16131310iosins Ftn—,
S
Drinking W.lnai
IOUOmL
ye"low tinned liquid
10
E090074 I.001
09098015.1
01
161i3113in6ns Fnrv+s
8
Wnm1
920n,1.
ydlowlined lignid
I I
E9900792.001
11938I
01
16131IMio.eine Fnrnns
]
Dunkin, W.uu
9DOud.
clor enlndess liquid
12
E09007�3-001
1
01
161➢B/Diocins Fnrnns
9
R'atar
900ni 1,
ydluw liquid
13
E0900745-001
Chip Blanch 2009-09-01_ I
01
1613B/Dioxins Fumu
3
Wner
990n 1,
bright orung ycllmv liquid
19
F.0900795-602
9mathn" Blanch 1009-09-Ur-K
01
1613B/Dinxius Fu,nS
3
Wal"
960"LL.
yd10w mango l ignid
15
FO09W362-01
.11B
1613 B1Dioci,+s Hanna
Liquid
1000nd.
16
EQ0900362-01
LCS
1615 B/I3inx ins ❑urann
Liquid
InOU.nL
17
EQD90062L3
DLCS
Id 138/Dia.dns F,n,u
Liquid
1000n 1.
IS
6Q09UU3G2-09
NEE
1613B/Dioxins Furnns
Drinking Win-,
1000m1.
19
F,Q0900362-b
LCS
1613130insins Fnrnns
Drinking Waror
Montt
20
EQD900362-06
ULCS
16I3B.+Dioxins Furnns
Drinking Walur
10001nl-
21
J0909340-001
Wimv Log Smngc
'01
161313/1)ioxins Fnrm+s
2
Wnmr
920nd
l ined vdlmr liquid
22
J0909140-002
CL-II
DI
1613B/Dioxins Forams
6
Water
9-WtnL
Bondy yellow liquid
23
J0909340-003
CL-13
.01
16I3B/Dio.ains Furnns
]
Wa¢s
941mL
limed liquid
29
J090434MOJ
LF-pl
01
1613B/Dioxins Furnns
_7
V—.
930od.
ycllmv 6gold
25
K0907866005
M0102122
.05
1613B/Dioxins Fnrnns
3
Warc1
930IL
cloudy liquid
26
K090]866-OOi
l.I.NID2P1
Di
1613E/Diocins Puns
It
Wma
980m1.
purFlc dear liquid
W
O
1-6."d 9Rl/09 13;22
rrcpan+ion Inlnrmmion Bcnchshca
24 of 26

Prep(1ralion I11jbrrnarior7 Benclrshee7
1'rrp Enna: 9)159
I'Ixp %ND, Sln,,:
0rg13xL4q(365)
slam,: prepped
-I emn, Scnllvnn OCNIS/AKODUN.
I'ycp Niclln,d:
69clhod
P, p Dalell Info: 914/09 I1.00 AM
S),Ilzing ... ,C
N:imr: I013B MalrN Working Standard
I,,cDto, ID 11101
I.OghoUk Ref: D10-5.1-313
E,pi,"On: 07/242014
EQ0900362-03 100Aopl. rQo9n0362-03
too UUIIL E00WO362-05 1n0. 0011L
EQ0900362-D6 Iuo UopL
N:unc. 1613E Labeled Working Standard
Inven lory ID 1203E
Lnt book Ref.
DID-70-3!3
Espnes On:
09/02/2014
109�04340-00 loouoo)tL
J090434D 004
IpuD. Opp
K09071166005
Io00oo111-
KU907868-005
I000,00µl-
Nsn4r 829011613E CIcnnnp\forking
Slaind.rd
Invcnron ID 12GS3
Logbook Rel'
D10-70-5A/B
Expires On:
09/03,1014
ED900715-001 Io000pL
E0900723-001
Iononp 1.
E09DO724-001
Ion.00j,L
F09D0725-001
10000pL
E0900728-001 too ouµl-
E0900729-002
100.00ftL
E0900739-001 100 uopL
E0900739-002
MOOOpL
E09DO739-003,
ion aoµ1.
E0900741-001
IonDofIL
E0900742-001 IDD aopl-
E0900743-UUI
IOaDop1.
E0900741 nor 1000Up1.
EOWO745-002
1Do a0pL
E(09org62-01
100on pL
EQO900362-02
too oo11L
rQ0900362-D3 Iou uopL
FQ0900362-0.1
100Dop I_
E00900362-05 too,00pL
FQ0900362A6
100 oo ftL
1D`HIe340-DUI
100. DoflL
J09043,10-002
IUo.OUpf-
10904340-003 IOOOO,'lL
10904340-D04
Ia0.on f,L
A0907S66.0115 too OOPL
KOW7965-005
too. oupL
Nnon, 1613B Labeled Working
Slanducl
Inventory ID 12036
Logbook Ref
DIO-70-48
Expires On.
09104,1014
269007IS not Io00.00p 1.
FD900723-001
),Dun no IL
LOWO72.1-U01
1,0ouoopi-
E0900725-DoI
Io0molil-
E0900726.001 I000.001,1,
E0900725-002
160o. ou)IL
ED911n739-Or11 Lonn.00,,L
20900739-002
1.0.0. oupL
C09DO710-003
1,000. oo ItL
F,09D0741-001
taOO.0011L
E0900742.u01 I 000 ao)tL
E090074-, 001
I0000UPL
E090074,-001 1a006DµL
Iao90o745.002
1,000. DopL
EQ %0362-01
1 UoO. BpL
EQ0900362-02
1 0000o d-
1
EQ0900362.01 1 ono.o9p1.
E OW0362 04
Q
I000.00pL
Ef)11911D362-o5 I00000f1L
EQO900]62-06
1,000.00ILL
J090434IJ-001
IuO0 OOpL
m90,1340-002
IOno oupL
1"'Itmaliun Materials
Acclnnc 99.5% Minimum
C2-16-007(7199)
Carbon, Hig0l'urip'
0-19-005(716!)
EILyl Aalnlc 999%M1lininnun
C2-23-00G (9462)
EIOA,
Glum Wool
C2-13-003{7196)
SWPori< And R9.gem
Grade
C2-24-003(946 t)
Dieh!oromahane(Mohy4um
(72-25-001(9449)
HIS04
Chloride) 99.9% lleCC
sudinm Chlnnde Reagan Grade
CI-104 ±(3306)
Sodium Hydrmide Rceguu
C2-24-DO2(940)
S9d,—, SulGm Aul, cl.a.
C.19-006(7201)
Mac]
G, .& NaDl I
Rcvgcnl Gmdc Nn'SO4
Tndee;,— (n-I nde,—)
C2-24-001 (9460)
Hexm,u (n-Hcwne) 99
5%
C2--25-004 (9441)
Ntot,, (n-Nonnne) 99'.
C2-21-004 (9437)
Min nm
pH R,per a-1J
(100.)
Gd Rcvl;cnl Gmdc
027-007(9456)
'19hicnc 99. 9% Mininuun
C2-25-003(9446)
Irlepnration Steps
Step: Ectm9d9rr
si,
Avid Clair
Smp:
Silica Gel
Clean
Slap: Flnvl Vuluum
,
Srancd'. 9/4/091100
Shoed:
9/5/090FOo
SI:nICO:
918/0913:00
Sl:mcd. M010907,00
O' Inishcd: 914U9 11 AI
Flnishcd
919109 us:00
Flniehcd'.
91810917:30
Finished: 9/9,0913:00
By: NBROWN
By:
NBIW¢N
a'.
NBROXS
4
By: NBKQWN
25 of 26
I'nnmd 9/v109 13:22 Prepnrnnan Inlbrmmion Ncne6ihce raae 2

1'rcp It mrtr 95159
'1''n.a Senvv uo GCMS/AMODIIR
Comnxm,
R,;—d By: Nicole Broom
Preparation Infiirrnation Benchsheet
Prep A�`m'kBhi�.': Or �Ex1:Ay(i6�1
Prep Vclh od: MCIhod
Dal, 09/09/09
R�h,-e bul Br Dom:
E,I... Fsamin�d
Rea Hed Bp: Dat, Va h'o
SIu11a: Prepped
I'rcp Ualdl'imr: 9/4/09 I1.00 AM
I'rimed 919%U9 I:?� Pmpvnnon MI.I natinn B..ehlh-, Pays 3

Columbia
AnalyticalSP.MCE?5- ;—s i„c, 4.1111 a.ss 1 enn.�sz-' z+.,ii:or: i
December 08, 2009
Diane Hardison
Domtar Paper Company, LLC
P.O. Box 747
Plymouth, NC 27962
1_,ahoratory Results for: Plymouth Store»eater Testing
Dear Diane:
Service Request No: J0905693
Enclosed are the results of the sample(s) submitted to our laboratory on November 17, 2009..For
your reference, these analyses have been assigned our service request nLill) ber.10905693.
All analyses were performed according to our laboratory's quality assurance program. The test
results meet rcquircments of the NFLAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc.
(CAS) is not responsible for use of less than the complete report. Results apply only to the items
submitted to the laboratory For analysis and individual items (samples) analyzed, as listed in the
report.
Plcase contact me if you have any questions. My extension is 4408. You may also contact me
via ernail at "[e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
Tom Kissinger
Project Manager
Page I of
CASJack.wm:ille is NELAC-accredited by the Stare of l'lorida, #E82502. Other state oceredireuions
include: Georgia, #958, Kentucky, #63: Louisiona. #02086: North Curolina. #527: South Ca olum,
#96021001. Texas. #T104704197-09-TX..

lient: Domtar Paocr Connoanv, LLC
i
eject: Plymouth Stormwatel Testing
Service Request: J0905693
SAMPLE CROSS-REFERENCE
SAMPLE #
CLIENT SAMPLE ID
DATE
-TIME
J0905693-001
RYOI - Norfolk Southern
I I/11/09
13 49
J0905693-002
OBA - Old Borrow Arca
11111109
14:54
J0905693-003
CL-14 West Con Laydown
11/11/09
14:37
J0905693-004
LF-04
11/12/09
09:15
J0905693-005
,IBA
11/12/09
09:32
J0905693-006
LF02
11/12/09
09:46
J0905693-007
Woodyard
II/12/09
1026
Ll IJS109 I I: i$ 1Miplt Suumui0' — Puer ul'

L.IJ l l ill, lit:l :, ilall I IIt'll OL1 'i eCCsI lt.c.
Cooler Receipt and Presell'Htlo❑ For[.1
G"f W:
l _.
LOoler !-eoct
A'8d oil '�,_i �l and opCl
COURIER: CAS PS FEDE\ DHL CLIENT Tracking �7 \1&.;�\
1
Were custody seals on outside of cooler?
Yes
<fo:�) N/A
2
Were seals intact, signed and dated?
Yes
No
Were custody papers properly filled out?
Yes
No NIA
4
Tempernalre of eoolei(s)upon receipt (Shocle!be.+r-: degrecs C)
Con 'ectTcnipciature'?
��
No N4�
6
;Vert Ice or Ice Packs present
Did ntl bottles arrive in good condition. (unbroken, cic...)'>
Y
N/A
were -lit bottle Iai,eL com.pleie i•sanlpbc ID, presCrvaiion, etc....)?
e, ,
do Ni:\
9
Dial sli bou.le labels and taus agree v; ith custody Papers'?
ilo ;•;%;v
Ili
Were t'.te ccrrcci bottle; used fathe Tests indicatcii'?
tCC�
;\Io Ny;\
1
W:I'C 111 of the preser•'cd bodes received vlllh III,-- 41)pTOpllal9 prLSo: va!ive.!
`f,c
o
KNO3 PH=2 H2SO4 pHkQ i:nAc2risli1011 pH>) Ns611 pi1>12
1 Cl pi-iQ
l
r:eS•`I'Vdt:4'•_ ::L'�I:101'.5 IIGi,:: 41c1n44'
12 Weic all samples received vvid.in analysis holding times'? V"
1 ; bXcic VOA ials checked for absent, of air bubbles? If present, note below Yes
14 Where did the bottles originate'? C;4;
No N/A
i
Sample ID
Reagent
Mauuf. Lot ;t of CAS
Chem ID
ml added
Inititiials
S
�I
itional comments and/or ezulanation of all discrepancies noted above.
Client approval to nm sarnpies if discrepancies noted: Date:

0
---
uale mcil 1H is mea0 om molts Ills amarca DI I mte.mn u"" io m,, A:unn neaow" unit35 el➢crw 11 nnluu or: Inrm_
6 t L nA
J S 2J
ID IOn1 12 LI 5m 125mL 1"+5 I SDmL 5D Ll.d Ll 2� L ).A7 A L2A A5n . 1111 SODIn 1L 1L IL tL 12 4o Bo Im 5] tIXl
30
l W n
f G p p P I p { L P F C fI P P P C G ( G G 0 G Cllc p
MH
ME
SO4
2
,. w
krNlAd
11CI
T
M504
2
HIJ03
.11:
'NIP-
Ol
11repD
N 011
9
N OH.
- 1 t
'Clln
<1
'Jlt.-
H2 bI
HNO3
NlP
VINO
2
I
HCI
H250
N7A
r_
Ii1A
N/A
,4IA
NTA
- Nlpd
xNlAi
[
^
-
NIC
L
(A1
010.
-
--
---
_
—
v
-
. ct�.3
til5
p13
_
TT
.In•..
I
------
-i--
-
_
-
-
--r-
-
fill,
0:11
01,
..t
ii)
.imi,

'(71UII11/1F1
Analytical
S(aJvcns
k-11A IIN "V %—U31 UL/V / C.A bUEAI '.Y AINA LIYSi KLQ/U 1LJl F'U KIWI I
CAS Cornocl , J
9143PhiISpvlll¢1jlrny, Siiae 200 Jacksonvi l lc,Florid:132256/Vhuno(404)7392277/SOO695-7?2Vpcx 904-739-2011 PBL,,c 1 Of I
Pmjccl Name
Project Numhcr
ANALYSIS
REf)UBJri
i) (Include
Method
Number
an
Phnouth Stonnwater-1 estin;
Prescnmtivc
0
Rcpon Tu
R"wr CC:
Diane I -la rdl5on
Alan D2rncs
L
Z
1. IiNOi
Company/Addrfss
2
Domulr Pa. cr Com miry
x
0. 112504
4. N,orl
P.O. Box 747
0
Plymouth, NC 27962
p
�.
p
i. LI. ncfrnf
ti_ Me011
Phnnc ;:
FAX II
J
252-793-8611
i
;)
7-N,HSO4
Rampkr's Sign:uu�rc
Samplrr's I'tin¢d Namc
/!
i
/
7.
REMARKS
-
SAMPLING
M:Ilrix
CIA I"INT SAMPLE, ID
LAB ID
DATE TINIF,
RYOI - Norfolk Southern
Dioxin
11/11/09
1:491'M
Water
2
X
OHA —Old Borrow Area
Dioxin
11/11/09
2:54 PM
Water
2
X
CL-14 - West Con. Laydown
Dioxin
I1/11/09
2,371'M
Water
2
X
LP-04
Dioxin
11/12/09
9:15 AM
Water
2
X
N13A
Dioxin
11/12/099,32
AM
Wnmr
2
X
LF02
Dioxin
11/12/09
9:46 AM
Water
2
X
\Voodywd
Dioxin
11/12/09
91,78444
\Nato
2
X
Woodyard- 10:26 AM
I
$IOrnlvv'.Jcr sdmp4 (ur JiO%in tfslinR.
'I 1111NARIUNI1 RY.QUI1FMCITS
REPORT RE.QLRRFMENT.s
INVOICE INFORNIAII ON
FUSI I(SURE, IA ROES APLI.1'1
I. Hcvulu Only
IL NuuILa�(%'Sumnnri.�
p
P.OJ d/.d'"roZ/C,/p'O'
\'IANVARn
(ICI, OUP, MIV ISD u�rynitv'JI
X IILltnnln e Oe...a CWM......n Su......
I
RII I�
RC)UG., rrO FIx IIAI I
IV. IAm 1,1." lnnK,-"il1, Rn.. O:ne
RRQUETeO RCPORI DAI E
r\
fdau Ycs No
RCIIngulshcJ 11)'
Itccerved Ry
Rclingulshed R\'
\ Rc red1 y
Itdingwshed By
Recerved Ry
�
S lmal)Itj`� ��
$Inn Rlre
.S II{II:Illlfc
tii It:lllll l:
I'rin¢d Namc /� _y
Pr'vncd Nanm/"
�>
{'rinlr, Nvyi—
Pf ILA"
Printed Namc
I'rinlcd Nave
Pirn \
-inn JI
1'- J ^�
Flan
Pinn
Dai lll.f ./_ _),-/{✓�
Unmllime
L:uc Tmle '—"'-"
I3v4.ls f n•
YD
Date/iinm
D:�m/iime
/x
_i

Columbia
� Analytical Services -
Appendix A
Columbia Analytical Services
9143 Philips Highway, Suite 200
Jacksonville, FL 32256
Tel [phone]
Fax [phone]
Subcontracted Analytical Results

ia�IU Ylbia
C,. Analytical Se, vices_
December 3, 2009
Torn Kissinger
Columbia Analytical Services
9143 Philips [-levy, Suite 200
Jacksonville, FL 32256
19409 Park Rov,,, Suite 320, Houston, TX 7708,: 1 713. 266.1599 v:ww.ra51ah.con1
Laboratory Results for: Plymouth Stornnvater Testing
Dear Tom:
Set -vice Request No: J0905693
Enclosed arc the results of the sample(s) submitted to our laboratory on November 18, 2009. For
your reference, these analyses have been assigned our service request number J0905693.
Analyses were performed according to our laboratory's NELAP-approved quality assurance
program. The test results meet requirements of the current NELAP standards, where applicable,
and except as noted in the laboratory case narrative provided. All results are intended to be
considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for
Ilse of less than the complete report. Results apply only to the items submitted to the laboratory
for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the
NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any
quantitative analysis will be supplied upon request.
Please contact me if you have any questions. Nly direct line is 281-994-2954. You may also
contact me via email at [e-mail].
Respectfully submitted,
Columbia Analytical Services, Inc.
Danen Bites
Project Manager
For a specific list of NELAP-accredited onalvtes, refer to the ceruficatiols section at . .
r o1rm. cus(ab. can.
�: i r,-._ Lrane:f t:omo r•, '.( �t�°r?.,i,i(t; ,:,. �U�S.:at of ,r.a.; _, .�.r Ple:,:o cJnsicCa .no cr.'iv. mantU'•ore pnror r51
1 of 29

AlColumbia
Analytical
Services-
(ertificate of Analysis
19408 Park Row, Suite 320, Houston, TX 77084
Phone [phone] Fax [phone]
www.caslab.coni
2 of 2s
0

COLUB93UA ANALYTICAL SERVICES, INC
Client: Dorntar industries Service Request No.: J0905693
Project: Plytnouth StonnwaterTesting Date Received: 11/18/09
Sample Nlairix: Water
CAS NARRATIA1F
All analyses were performed in adherence to the quality assurance progam of Columbia Analytical Services, Inc.
(CAS). Chis report contains analytical results for samples designated for Tier 11, When appropriate to the method,
method blank results have been reported with each analytical test.
Sample Receipt
Seven water samples were received for analysis at Columbia Analytical Services on 1 1/18/09,
The following discrepancies were noted upon initial sample inspection: no custody seals on coolcr(s). The
exceptions are also noted on the cooler receipt and preservation form included in this data package.
The samples were received at 0°C in good condition and arc consistent with the accompanying chain of custody
foim. The samples were stored in a refrigerator at 4°C upon receipt at the laboratory.
Please note the reporting fOrnn5 are currently refinencing the date CAS- Jacksonville received the samples (11/17/09)
and not the date CAS -Houston received the samples (11/18109.)
Oato Validation Notes :md Uiscussiou
:AIS/DJMS
EQ0900491: Laboratory Control Spike/Duplicate Laboratory Control Spikc (LCS/DLCS) samples were analyzed
and reported in lieu of an BAS/DMS for this extraction batch. The batch quality control criteria were met.
Dolectina Limits
Detection limits roc calculated for each congener in each sample by measuring the height of the noise level for each
quantitation ion for the associated labeled standard. The concentration equivalent to?S times the height of the
noise is then calculated using the approtinatc response factor and the weight of the sample. The calculated
concentration equals the detection limit.
u =
Approved by:
17
\ionggiu Liaug, Lnborntory Director
3 of 29
Date: 12/07/09

Client:. Domer Paner Comnanv. LLC Service Bequest: 30905693
I'ruject: PIynlOulh Slonmvaicr Testing
SAB9 PLE CROSS-REFEAZENC IS
SAIv11ILF H
CLIFN'I' SAMPLE ID
DATE
TIME
J0905693-001
RYOI-Norfolk Southern
11/11/09
13:49
(0905693-002
013A - Old Borrow Area
11/11/09
14:54
J0903093-003
CL; 1.1 West Con Laydown
11/11/09
I4:37
10905693-004
LF-04
11/12/09
09: 13
10905693-005
NBA
11/12/09
09:32
J0905693-006
LF02
11/12/09
09:46
J0903693-007
Woodyard
11/12/09
10:26
4 of 20
IginmJ I':9ai•� i.i. Sample Summ^6' a Page of I

Laboratory Certifications
2009-.2010
STATE/PROGRAM
AGLNCY
CLRTIF1CATION ID
LX;P DATE
ARIZONA
AZ-DHS
AZ0725
05/26/10
ARI<ANSAs
ADEQ
09-049-0
06/16/10
CAI-uroaNlA
CA -FLAP
2452
02/28/11
FLOM UA/N'E LAP
FL -DOHS
E97611
06/30/10
HAWAII
HJ-DOFI
N,;A
06/30/10
If-IrNols/N IsLAP
IL -EPA
002380
10/06/10
LO0ISIANA/NELAI'
LELAP
03048
06/30/10
MAINE
lolE-DOFIS
2008031
06/OS/10
DhCmcAN
MIDFQ
9971
06/30/10
MIN'NESOrA
MDH
048-999-427
03/25/10
NEV,ADA
NDL'P
TX014112009A
07/31/10
NEw Je:usE�'
NJDEP
TX008
06/30/10
\Iiw D91,SICO
LAMED-DWB
N/A
06/30/10
Niaw Yow</NELAP
NY -DOH
11707
03/31/10
NFESC/Nnvv
NFESC
N/A
01/09/10
OKLAIIO.WA
OKDEQ
2009-25
08/31/10
OaecoNh�tiLAl'
ORELAP
TX200002-006
03/24/10
'ITNNESSFE
TNDEC
04016
06/30/10
TEXAS/NELAP
TC1EQ
T104704216-09-TX
06/30/10
UT.A Ii/NLLAP
U-CELCP
COLU2
06/30/10
SOIL huom PEu�u'r
USDA
P330-09-00067
03/27/12
11'.aSFUNGTOi�/NLLAP
WA-Fcology
CIS55
11/14/09
WESI'VIRCINIA
WVDEI'
347
06/35/10
5 of 29

C
Abbreviations, Acronyms & Definitions
Cal
Calibration
Con:
CONCentration
Dioxin(s)
Polychlorinated dibenzo-p-dioxin(s)
EDL
Estimated Detection Limit
EMPC
Estimated Maximum Possible Concentration
Flags
Data qualifiers
Furan(s)
Polychlorinated dibenzofuran(s)
9
Grams
ICAL
Initial CALibration
ID
Dentifier
Ions
Masses monitored for the analyze during data acquisition
L
Liter (s)
LCS
Laboratory Control Sample
DLCS
Duplicate Laboratory Control Sample
MB
Method Blank
MCL
Method Calibration Limit
MDL
Method Detection Limit
MRL
Method Reporting Limit
mL
Milliliters
MS
Matrix Spiked sample
DMS
Duplicate Matrix Spiked sample
NO
Number of peaks meeting all identification criteria
PCDD(s)
Polychlorinated dibenzo-p-dioxin(s)
PCDF(s)
Polychlorinated dibenzofuan(s)
ppb
Parts per billion
ppm
Parts per million
ppq
Parts per quadrillion
ppt
Parts per trillion
QA
Quality Assurance
QC
QualityConttol
Ratio
Ratio of areas from monitored ions for an analyte
0/0 Rec.
_
Percent Recovery
RPD
Relative Percent Difference
RRF
Relative Response Factor
RT
Retention Time
RRT
Relative Retention Time
SDG
Sample Delivery Group
S/N
Signal -to -Noise ratio
TEF
Toxicity Equivalence Factor
TEQ
Toxicity Equivalence Quotient
6 of 29

7
Data Qualifier Flags - Dioxin/Furans
o B Indicates the associated analyte is found in the method blank, as well as in the sample.
o C Confirmation of the TCDF compound: When 2378-TCDF is detected on the DB-5 column,
confirmation analyses are performed on a second column (DB-225). The results from both the
DB-5 column and the DB-225 column are included in this data package. The results from the
DB-225 analyses should be used to evaluate the 2378-TCDF in the samples. The confirmed
result should be used in determining the TEQ value for TCDF.
o E Indicates an estimated value -used when the analyte concentration exceeds the upper end of
the linear calibration range.
o J Indicates an estimated value -used when the analyte concentration is below the method
reporting limit (MRL) and above the estimated detection limit (EDL).
o 1( EMPC- When the ion abundance ratios associated with a particular compound are outside the
QC limits, samples are flagged with a'K' flag. A'K' flay indicates an estimated maximum
possible concentation for the associated compound.
o IJ Indicates the compound was analyzed and not detected.
o Y Sarnples that had recoveries of labeled standards outside the acceptance limits are Flagged
with'Y'. In all cases, the signal-to-noise ratios are greater than 10:1, making these data
acceptable.
o ND Indicates concentration is reported as 'Not Detected.'
0 5 Peak Is saturated; data not reportable.
o P Indicates chlorodiphenyl ether interference present at the retention time of the target
compound.
o Q Lock-inass interference by chlorodiphenyl ether compounds.
7 or 29

;HOt-1 - Forni Production -el- R-vc,,v ci Dmiect Revic \A; Signarui-es,
SR' Uniaue ID
Laie Person 2
Cale
Ua7a reviewer
Seconnary Da(a Psj:evve�
8 of 2

9
Columbia
Analyticai Services -
Analytical L�sults
a
'19408 Park flow, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.caslab.com
An Employee Onned Cornpeny
9 of 29
1�

COLUMBI:A:AN AL1'CIIC:AL SE 1: 'VICES, INC.
Analylilll Report
Client:
Domlor Industries
Service Request:
J0905693
Ptojecl:
Plymouth Slornnvntcr TeStine
Date Collected:
11/11/091349
Sample Matrix:
Water
Date Received:
11/17/09
Sample iName:
RYOI - Norfolk Southem
limits:
pg/L.
LabCude
J0905693-001
Basis:
NA
Polychlorin INd Dibcnzodinci,m aid Polpchloi inated Dibcmzofmals by llR6C/IiW\iS
Analytical iMellmd:
1613B
Date Aualwed:
11/23/09 2244
Prep Method:
'Method
Date lictracted:
11/19/09
sample Amount:
99011IL
I nstt unl en t,Va m e:
E-14RIVIS-04
CC Column:
DB-5
Detu File Nnn1e
P205035
Blank File Name:
P20508t
KCAL hale:
08/20/08
Cal A'e,. File 1Came:
P205079
Ion
Dilution
V iAl (e N:unc
Result Q
EDI, AiRL
It21im
itkrf Factor
_,3,7,S=fCDD
ND U
0.070S 10.1
I
Spike
Conc.
Control
Ion
Iabdul Compuu ads
Couc.(pg)
Fol"Id (pg) %It cc Q
Limits
12:1tio IMA
1.3C-2,3,7,8-TCDD
2000
1 186.7 17 59
25-161
0.79 1,008
370-2,3,7,8=1CDD
S00
53,1.070 07
35-197
NA 1.009
PiiumJ ILJi0911 3 Form I:\
n,a....asonl.,:au10 of 29 sip�.,Sn rner 41..X)uur.slo,... ao
C

-
COLUMBIA ANALYf1 CA I. silt,+ICES, INC.
Aaalytiia} Report
CI
Domtar Industries
Sen'ice Request:
J0905693
Project:
Plymouth Stomnvatei Testing
Date Collected:
11/I1109 145.1
Sample Aiah it
Water
Date Received:
II/IW09
S:uup lc Nmae:
O13A-Old Borrow Arca
Units:
p&L
Lnb Code:
J0905693-002
Basis:
NA
Polychlm'in:Ved Dibenzodioxins and Poh'chlorinated Diheno.nfumns by IIRCC/RRNIS
Analytical Method:
1613B
Date Analvzcd:
11123/09 2331
Prep rAIethnd:
Method
Date E6ti awed-
11/19/09
S'ampleAmount:
975mL
Inslrmncnt Name:
F-HRNIS-04
GC C,Aanaw
DD-5
DaI.1 File Name:
P205096
Blank Pile Name:
P205031
ICAL Date:
0V20/08
Cal Vei. file Name:
P205079
Ion Dilution
A ne lvtc Nn me
Res aIt Q IML dIIt11 Ratio ItRT Factor
2,3,23-TCDD NO U 0.2,92 10.3 I
Spike
Colic.
Control
Ion
Lu hcicd Co,ii') 11s
Gme(Itg)
Round II:,g)
Limits
Ratio It12T
13C-2,1,7,8=TCD1)
2000
1039,043 52
25-164
0.79 1.009
17C'I-3,3,7,S=1 CDD
8011
463367 58
35-197
irA 1.010
Cnemmma
hi not 1 1,3: a9 11 34 Penn IA
•arminmv'6unnn:.l �n„a,pc.tn.d.-n:.dx. y,u nn 71 of 29 5oyudeiim@.ace ur onae uerm a. ou

(:0LU.N[It A AN'ALVTI(:AI, ifsRVICES: INC.
Analp,,1� Rcpon
Client
DOnnar Industries
Service Request:
J0905693
Project-
Plymouth Stormwater Testing
Date Collected:
11/111091,137
S'aolplc INlati IN:
Water
Date Received:
11/17/09
Sanlple Name:
CL-14 West Con Laydosm
Units:
pg/L
Lab Code:
J0905693-003
Basis:
NA
Pol}'chloi inated Dibmlzodio>ius and 1'olychlm'ivated Dibenzoliu-ans by HUCC/HILV'IS
Analytical :Method:
1613B
Date An:03zed-
11124/090019
I'tcp Mclhnd:
lblcthod
Date Extracted:
11/19/09
Sample Anvnmt:
950mL
Dlstrument Name:
F-HRINIS-04
- CC Column:
DB-5
Dana File :Nanny:
P205087
Blank File N'mnc:
P2050S1
ICAI. Date
US/20/08
Cal Vet. File Name:
P205079
Iml Dilution
A"aIyIe N11111e
R"a It Q I.DL ItN IR1, Ra IIO RRI Vaet01
3,3 7.5-TCDD ND U 0,197 105
Spike
Cnnc.
Con("d
Ion
L:Ibelyd Compounds
Gmc.(pg)
Gonad (pg) %Itcc Q
Limits
Ratio
lzRT
13C--13,7,8-TCDD
Not)
1216,257 61
25-164
0.77
1.009
37C'1-2,3,7,S=1 CDD
SOD
546.674 68
35-197
NA
1.009
Coi::::::::n.
LeLn:.Nvelano Lnozaepsb\alynclReCrn iP: Su{e:Sal Rdi' n[el 0'l-iAW L5701
12 Of 29 "" f0
iS

COLUiMBI.A:AN,AI,V'PI GVI. 56:12VICI?S, IiINC.
.4nalytil� Repon
Client:
Domtarindustries
Service Request:
J0905693
Project:
Plymouth Siormsvatur Testing
Date Collected:
11/12/090915
Sample Mat]
lh'ater
Date Received:
11/17;09
SampleNanw
LP-04
Units:
pg/L
Lab Cade:
J0905693-004
Basis:
NA
Polycblm'inated DibewodioSinS auA Polychlnrioatcd Dibenaoturaov by IIRGC/IIRNIS
,An:d) licalMethod:
161313
Date ;Analyzed:
I I/24/09 0107
Prep Method:
Method
Date Evf,acted:
I UI9/09
Sample Mnuunt:
9501111,
Inshvmcut Name:
114IRMS-04
CC Column:
DB-5
Data Rlle INmlle:
P205088
Blank file Nome:
P20308I
ICAL Date:
OS/20/08
Cal Vet. File Nome:
P205079
h tl
Dilution
AnakTe iName
Result Q
(?DL MRI.
Ratio
RRT Ractor
2,37,S-FC'DD
ND U
0.106 10.5
1
Spike
Conc.
Control
lot,
L bded Compounds
ConcQlg)
Round (p.") dice Q
I,iniitN
Ratio kR'I
13C-23,7,S.TCDF1
2000
1167.670 58
25-164
0.78 1,009
370-2,_,7,8-TC DD
800
521.01E 65
35-197
NA I.009
P, Furm IA
'Jlnan.;psinonuV.in�sRaea,li,�pn:.aa.r��, �p� S�gmria�nciucncr. o�.noom xe�o�nv oo
13 of 29
9

COLU,MBIA ANA1,Y ICAL SFRYICFS, INC
AnalytiLl i Relxm
CIicni_
DoInmr Industries
9evi,u Request:
J0905693
PlojecL
Plymoudt Sionnmeter Tcsting
Date Collected:
ll/12/090932
Sample Nlah'i%:
Water
Date Received:
11/17/09
Sample Nnmc:
NBA
Units:
pg/L
Lab Cute
J0905693-005
Basis:
NA
t'nlychlorinatcd Dibcnzodioxins
and I'olpehlorinacd Dibenzofurans by IIRGOIRNS
Vnalylicel N4ethod:
1613B
Date Auah'zed:
11/24/090155
I'r,p dlethnd:
N4ethod
Date Exh'acted:
11/19/09
Snngdv Amuunl:
940mL
1n.str ument Name
GHRNIS-04
GC Column:
DB-5
Dala File N'unre:
11205OS9
Blank File Nmnc:
P205081
IC:V, Date
08/20/OS
Col Ver. Pile Nnmu:
P205079
ton Dilution
An.d)te Name
Rl,sult Q
BDL J'IRI, R;ltiu RRT Factor
2.;.7s=fCDD ND 1.1 0.209 10.6
spike
Con,.
Control
Ton
Ln bclud Co mpnu nd'
Conc.(pg)
Found (pg) 'y"12e, Q
Limits
Ratio RWI,
I;C-2,;,7.S=fCDD
2000
1242.502 62
25-164
0.s0 1.009
i7C12._,7.S=fCDD
SOO
535.202 7;
35-197
NA 1,009
in, ul I]n/pq I1:)1 POO➢ IA
...... +rbbmly„"IrtaCo ,. nn S
14 a(29 "es" a,tt: ... avooco, 'svui
�V

COLIHMAIA ANAL)k I'ICALSERVIUS. INC.
Ana1yti2:5 Report
Client:
Doom, industries
Service Request:
J0905693
Prujcet
Plymouth Slonnwater l-estine
Dute Collected:
I V12/09 0946
Sample ivintr i\:
Winer
Date Received:
11/17/09
Sample Name:
I_F02
Units:
p,,/L
Lab Code:
J0905693-006
Basis:
NA
Polychlorinated Dihcuzodioxin,c and Polychlorinated Dibeu20fu runs by II12CC/FIRMS
,Anniytical Biclhod:
16139
Dote Analyeed:
11/2,1/0902,12
Prep :Method:
Melhud
Date Estractcd:
11/19/09
Sample AniuunL
9401111.
Instrument lN:unc:
F-EIRNIS-0d
CC Coltmin:
DB-J
Dolo File N:ium:
1,205090
Blank File Nnmc:
P205081
ICAI, Date:
08/20/08
Cut Vcr- File :Name:
P205079
IOn Dilution
,vn:dytc Nano
Result Q FSDL AiR1, Ratio RRT factor
,3,7,8-TCDD
I.nbuI'll Compounds
ID U 0.232 10.6
5pil:c Cunc.
Cone.(pg) Pound (p(t)%Ncc Q
Con ev:l I m
Limits Ratio 1212T
LC-2.3,7.8-TCDD 2000 1119.426 56 25-16d 0.77 1.009
3",U-M,7,8-FCDD 800 517661 65 35-197 NA 1.009
P.1k,d 1213M,I) 1 I?J roan I
Am11,1 2en0 1aeP„n.:W 15 o129 SxkpuSn Rel rtn.c ns.wooltabn a,w
�1

COL LINT BIA AN A LYFICA L SIP IL V I CES, INC.
Aoalptii:n Report
Cl i en l:
Domtar Industries
Service Requcst:
J0905693
Project
Plymouth Storntwater I estin.-
Date Collecled:
11/12i091026
sample d'lit, iv
Water
Date Received:
11/17/09
Sample 1Name:
`Voodvard
Units:
po/L
I,ab Code:
J0905693-007
Basis:
NA
Polpchlro mated Dibouzodiosins .md Polyddnrinal ell Diben'iofurans bP IIILCC/IIILtIS
Analytical PlOrud:
1613B
Dale Analyzed:
11/24/09 0330
Prep J1etbod:
Method
Datc Fctracted:
11/19.109
Sample Amount
960ml-
Insh'ument Name:
E-HRMS-04
CC Column:
DB,i
Dula File Name:
P205091
Blank File Name:
P205031
[CAI. Dale:
08/20/OS
Cal Vet. File Name.
P205079
loll Dilution
An'eh9c N;mlc
Rcsdl Q FDL Midi, 166o 12RT Factor
2.3,7,5-1'C'DD
Labeled Coln pow ds
ND U 0.169 10A
Spike Colic.
Cone.(pg) Found (pe) '%lice Q
Control loll
Lill its Ratio I212T
I3C'-2.3,7,S-rCDD 2000 124L959 62 25-164 0.76 1.003
370-2,3,7,5=1'C'DD 800 630.694 79 35-197 NA 1.009
P.... j 12, 11191 I:; J Fonn IA
-Iu:1,.,.: G;iLn.� lamvli<ps::;nolp¢ilRepm.rG� 16 of 29 :;u,S,1 Raf<rcnm: OeW0i2al Ul iv W
71�

COLU:\'Ill IA ANALY'f I CAI, SERVICE'S, INC.
A,mlyligll Report
Client-.
Donator fndusvics
Sem" Request:
J0905693
Project
Plymouth Stonmvamr Testing
Date Collected:
NA
S:iniple IAinIkis:
Watcr
Date Received:
NA
Sample Nanac:
Method Blank
Units:
POL
1,A6 Cod,,:
LQ0900491-01
Basis:
NA
PolycJdorinnted Dibenzodioxias and Nolychlm'inatcd Dibenzolm
arcs by 1IRG.C/11RA'IS
\nalytical Aielbnd:
1613B
D;n,, Analyzedr
11/23/09 1933
1'rep Alclhnd:
1Method
Date FStraeted:
11/19/09
Samplc:AmnunC
I0001111-
Instrument lName:
E-FIUIS-04
CC Column:
DB-i
Data File N:une:
P203081
Blank File iN:uue:
['205081
ICU. Date:
08/20i0S
Cal Vei. Pile Same:
P205079
lo"
Dilution
:UmINe Noole
Result Q
Il1)1 Iblltl,
Ratio
IMT Factor
2,37,9- CDD
ND U
0.235 100
1
Spike
Colic.
Cnnnol
I611
Labeled Compnands
Colm(pg)
Found (pg) "/'Rec Q
Limits
Ratio RRT
13C-2,3,7,8-TCDD
2000
1242.100 62
25-164
US 1-009
370-2.37,3-TCDD
Soo
492.198 62
35-197
NA 1,001)
Cau,n,�a s.
I'nu�cJ 1'.Ur 0911:34 Pon.. Id
17 of 29 Sua�sa a<i<m�m< ay.uotal;vul ,<.w
7

Columbia
Analytical Services -
Accuracy and Precision
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.caslab.com
An Emolovee ow"M Comnanv
18 of 29
.a

CO LIIJ9 BIA ANA I. VTICA L SGR V ICIS, INC
19
QA/QC Repon
Clicn l:
Dommr Industries Service Request
J0905693
I'rojuct
Plyulouth StIM111"atCr I'cstin� D:dc Analyzed:
11/24/09
Saul plcAia tris:
Wtller
LA CWltl'01 S:II111)IC SIIIi1111J1'y
Polychlorinated Dibenrodiosins and Polychlorinated Dibenzolurons by IIRCC/IIRNIS
Amdytical lMohod:
1613B Units:
pg/L
Pi cp Alclhod:
I%lethod Basis:
NA
6vh'sclion Lot
1010-17
Lnb Conh'ol Sample Duplicate LIJ) Control Sample
F00900491-02 EQ0900491-03 %12ee
RVD
A,,Avlc lNanlc
Ihsuh f \pcctcd % Rec Rcsnit tispcctcd % Rec Linlits
RPD Limit
2,3.7.8-FCDD
219 Zoo 109 209 200 104 67 - 153
3 50
[�nnnln
PI nncd I `;VW 11 34 Lab Comrel SauryL Snnmi:vy
FLn1noL:5l.vl..w'J n... SupmSel Nerv.nu. 09000011Y101m 019 of 29
'l C

•
COLUa I BIA ANA LVI ICA I, SERVICES. INC.
Analvti2� Report
Client:
Domtar Industiics
Serviau Request:
10905693
P'')jccl:
Plymouth Slormwaler Testing
Dade Collected:
NA
sample ,Mat,
water
Dnte Received:
NA
Sample Name:
Lab Control Smnple
Units:
pg/L
Lah Code
FQ0900491-02
basis:
NA
Polgchlorinated Dibeiwodiusius and Pnh"Ch101'lllDtell Dibenzofm'ans by IIRGC/1112,A,1S
A, :Ayiical .Ai ethod:
1613B
Date :Anahaed:
11/24/09 0,118
P,r p :Aicthod:
b1cdlod
Date Extracted:
11/19/09
j1l n, plc Amount:
IDOOmL
Insh'ummnt Nome.
E-1-IRMS-04
GC Column:
D13-i
Daly bile Name:
P20i092
Blank Rile Name.
P205081
IC AL Date:
W20/03
Cal Vc, Ffle Nnmc:
P205079
Ion
Dilutiml
V,ml, tc A'anlc
Result Q
LDL
AIM,
Rn110
RIYI I•:lclor
2,3.7,8-TCDD
219
0.176
10.0
0.77
1.001 1
Spike
Couc.
Cont,oflon
Lubdcd Cmnpo°nds
Conc.(pg)
Found (pg)
%Rcr Q
Limits
Ratio RICI
13C-2,],',,d-TCDD 2000 1572,723 79 25-164 0.73 1.009
37C'I-2.37,3-ICUD 300 619.3b0 77 31-191 NA 1009
Co,.nac„u:
I'nmN I`tlrt,Y I I Nl Porn, IA
aL,fo..2Uwd,n,,. L,m. Rapb,i,.nt n of Rgxm ry1 su 4, 0.c6rnrtc. 03i000,2tl701 r,, 00
20 a129 P"
26)

COLUMBI:%AV: INTICAL SERVICES, INC.
AnalytiD Repoli
Clime
Donnar lndusnics
Service Request:
J09056793
�
I'rojcc0
I'lymoulh Simimvalci Testing
Datc Collcutal:
NA
Sample ,Mall is:
Water
Dole Received:
NA
Sample Name.
Lab Control Sample Dup
Units:
pg/L
Lab Code:
EQ0900491-03
Basis:
NA
Pillychlorinated Dibenzodio.cins and Polychlurinalcd Dlbcn'eofin ails by IIRCCAIRNIS
AaA-v(icd INlethod:
1613B
Date Analyzed:
11/24/09 0505
I'rcp Aielhod:
Method
Date Est acled:
11/19/09
S.unple .Amount
I000ml.
Instrument Name:
E-HRNIS-04
CC Column:
DB-5
Daly File :Nanle:
P)05093
Blank File Name:
P205031
ICAL Dale:
081"0.108
Cal Ver. File Nmne
P205079
Ion Dilutio.l
Aaalyle lien'
Result Q EDI, fit It11 Ratio It12T Factor
2,3,7,8-TCDD
209
0.0930 10.0
0.75 1,001 I
Spike
Couc.
Caan'ol Inn
LaLded lolnponndv
Conc.(pg)
Found (pg) %Nee Q
limits Ratio 121Z'I'
13C2.3,7,3-TCDD 2000 1i31511 77 25-164 0.79 1.009
37CI-2,3,7,8=I-CDD 800 555.658 69 31�191 NA 1,009
L'nnnn urn.
hinnd IJ U911 iJ Form IA
o,Lulm.I`S:,n,nslms2.0 `+6, oIPrNn. rya 21 0129 furerS'lRd"[-'. Oa.WOOL.Ya0l ,m ea

22
Columbia
Analytical Services°�
�I
i
�I
19408 Park Row, Suite 320, Houston, TX 77084
Phone[phone] Fax[phone]
www.casla6.com
ACcmpnny
22 of 29

i 11.113-IV C1 W01,!i.
'.
J-1, O1
'CUS C)CII'
91:1i 1'161lpn
11,hmav Ja i::om'i l lc,
F'1.23356 901 739-2177
FAX904
739-2G1I
PI'Uj"I \':I pl Cl
h \'1110t1th 1tOflll\Calt'I TCYIIII�
- —
ProJfl'1:N'nlnFt'r:
Prrjucl?hmapcm
tinna 11:udison
1
Company:
Domrar Paper C... Tom, Ll_C
-
_ - I
Simple
Dole
11)C.Illle
Client Snogilc ID
11oIFCunL
Mat'iy
Dal,
1i...
IL'u'iv"I
Sod To
_
1 10905693-001
RYOI - Norfolk Smnhem
waicr
11/11/09
1349
1 U17109
! HOUSTON
- It
110)O.693-002
OBA - Old Bormv'Arn
Rua
II/11/Do
I1-d
II/I7/09
HOUSTON
It
10905693001
-CL-I I'A',, I C on La i do,,o
I
Wal"
II/II/On
1437
II117;09
1 HOUSTON
f[
1 J09U>(93-004
! LF-04
- ---__
Wntcr
—
i II/L2N9
0915
I I/l7/U9
—
IIOUSTON
11
J090 (73-00
1 N6A
I W(cr
11/12/0) i
0932
11/17/09
HOUSTON
1
j
)0905693-006
IJ:07
Water
II/1 /09
0946
11/17/09
HOUSTON----I
!I-
�_
r
i
I .109055693-007
Woudyvrd
�
I \Nazar
I II/I?/O)
1036
I II/I ]/09
I HOUSTON
Peps;i �7S CP1) 00,V
CAS Contact: Tom Kissi(.
Special los'tructions/Comments _ C! J it IBC I I
i ..-C;-r1 i.0 \'\ C C:,,'S'. / - .-
�/.i �
�� .JL r-•.•- ��. ( -.. I-1 P L L A S F Ci C N
'Furmvo and llquircmeNs
RUSH(Surchnrgcy Apply)
PLEASE CIRCLE WORN DAPS
Report ltcquircmulls
-- I. Resnlu only.
✓i'. Results+Lx; Summaries
I n'oice larm'ntalian
poll'
7
1 2 11 4 5
_ 111Results +OC nod Cslihration Summaries
10905693
MANDY SULIIVAN'
STANDA121)
_ IV. Data Vnlidaon t Rcpon o'oh Rnw Dam
Bill
Rc red FAX Daw
PQUMDllJ y
[n
I ,' ��,•
Rcqucsrcd Rerynt Dale: 12/08/09
I?DD _N
Rdm mahcd A ��/ ,LC-T7.f%23ra%f rhill Number. `-. Racvetl C)/29
l/sr, I;v f 1 (1 �` j �= l•.�Iy L'! [� (�
i Pa,e

ireset f-O,rril _
Columbia Analytical Services; Inc.
Cooler RJceipt Fonn
`:Iient/Project Domtar Paper/ Plymouth Stonnwatei Testing Service Request J0905693
Received: 11/18/090953 Opened(Date/Time): 11/18/091001 By: NAB
I. Samples were received via? ❑US Alail ❑Fedex Ell UPS ❑DHI, ❑Cowrie ❑Hattl Delivered
2 Samples were received in: (circle) ❑Cooler ❑Boe ❑ Other ❑NA
=. Were custody seals present on coolars? ❑Y ON If ycs, how many and where'?
If present, were custody seals intact? ❑Y El Ni If present, were they signed and dated? El El IN
4. Is shipper's air -bill tiled? [:]NA ❑Y ❑✓ N If not, record an bill number: 1ZX5W0980142068140
i. Temperature of cooler(s) upon receipt (°C): 0
6. [f applicable, list Chain of Custody cumbers:
7. Were custody papers properly filled out (n!<, signed, etc.)? ❑NA ❑✓ Y ❑Nr
S. Packing material used: ❑lnscrts ❑✓ Bubble Mhap ❑Blue Ice ❑✓ 611et Ice ❑S/eeves ❑Odic
9. W'eru the correct types of bottles used for the tests indicated? ❑Y ❑N
Did all bottles arrive in good condition (i.e. unbroken, out of temp.)? Indicate in the table below. ✓❑Y ON
Sample M
Bottle Count
Bottle Type
Out ofTemp
Broken
Initials
❑
❑
_
❑
❑
❑
❑
❑
❑
❑
❑
❑
❑
lo. Werc all bottle labels complete (i.c. analysis, ID, etc.)'? ❑Y ON
Did all bottle labels and tags agree with custody papers? Indicate in the table below.❑Y ON
Sample ID oil Bottle Sample ID on COC Sample ID on Bottle Sample ID on COC
I
11. Additional notes, discrepancies, and resolutions:
24 of 29
CRF r092109.pdf
- Pnoe P 2 1 ❑ 2

25
Sample Acceptance Policy
Custody Seals (desirable, mandatory if specified in SAP):
✓ On outside of cooler
✓ Seals intact, signed and dated
Chain -of -Custody documentation (mandatory):
✓ Properly filled out in ink & signed by the client
✓ Sign and date the coc for CASMOU upon cooler receipt
✓ Coc must list method number
✓ If no coc was submitted with the samples, complete a CASMOU coc for the client
Sample Integrity (mandatory):
✓ Sample containers must arrive in good condition (not broken or leaking)
✓ Sample IDs on the bottles must match the sample IDs on the coc
✓ The correct type of sample bottle must be used for the method requested
✓ The correct number of sample containers received must agree with the
documentation on the coc
✓ The correct sample matrix must appear on the coc
✓ An appropriate sample volume or weight must be received
Temperature Preservatives (varies by sample matrix):
✓ Aqueous and Non -aqueous samples must be shipped and stored cold, at 0 to 6°C
✓ Tissue samples must be shipped and stored frozen, at -20 to -I O'C
✓ An samples can be shipped and stored at ambient temperature, —23°C
✓ The sample temperature must be recorded on the coc
✓ Notify a Project Chemist if any samples are outside the acceptance temperature or
have compromised sample integrity— the client must decide ie: replacement sample
submittal or continue with the analysis
Cooler Receipt Norm, CRF (mandatory):
✓ Cooler receipt for must be completed for each coc & SR#
✓ Sample integrity issues must be documented on the CRF
✓ A scan of the carrier and the airblll number must be recorded in CAS LIMS
Sample Integrity Issues/Resolutions (mandatory):
✓ Sample Integrity issues are documented on the CRF and given to the Project Chemist
for resolution with the client
✓ Client resolution is documented in writing (typically email or on the CRF) and filed in
the project folders)
25 of 29

Service Rccm ,f Sumin:ary
folder 4:
.10905693
I'mjcct CbcIUIS11
Nlf(Ct 6110
C lien. Name
Dumt'ar Indust, ics
L.ab'.
JAN
Project Name
11 lyinmlh S IBrmtz:Ocr Tesli m,
Logecd Li)':
SLID Hl:S!a'
Project N'ulllb rl
Datc Rcecn'ed:
I I/17/09
n1CrIlUI Doc Dale:
12/8/01)
12eport l'o:
Donilm a
Q.AP:
LAB QAP
Pape,
Donuar Paper Company. LLC
Qualifier Sel:
CAS Stemdard
P.O. Ros 747
Ponuscl:
CAS Standard
Plvluouth, NIC 27962
Merged'
N
Phone Number:
252-793-5611
Report to !vl'DI:?:
Y
Cell Number:
P.O. Number:
d550171SSA
Pa.e Num 6cr;
252-79;-SS77
kiDD:
No F,DU Specified
L-mai1:
dianc.hardison(n dmntnr cum
1
I
0
C,,IN! mp ,Cu
Cliun Sanip .Nu. dlnlrix
Gdlectril
10010,13,-0UI _--------
RVOI-Nn 1.1k Snmhmll W:en
I1i11109
"w
IU`)Uib93-00'
ORA Ohl norrmv Arco tl'mer
11:11/09
1154,
10905E93-003
Cl. IJ Well Con I-:ry11n111. W:ecr
I I/I I/09
14i7
J090i693-001
LF-0� Wvu
II/12/09
Ooli; 1l
ID995693_005
.. ...
ND:\ Wnml
_.
11/V' 09
..I .. ....
0932I 1!
11NIOS693-1106
I,F01 0.'nlcr
II/I2/09
0946 I ❑
J090i(9.1-007 .....
.. Wuotly:ud ... ...... W:acr
II/I1/0.)
106l. ..11
.
Test Comments:
Croup
S:unples
Comments
Scntivon GCNIS Dioxins'Furans/1613R 1-7 237E TCDD only
P.)
LI loud na: Gl:rss nwe,.scnv nelnea r,:um: Lhlei unPru==med
—ocation: C-Disposed, F.-WIC01
NPDES
26 of 29
Prinbd I1/3/1009 11 31:'_LAM tier.... kmplwl fn: .)090S693 Pay_ I nl l

preparatioll 1/r/`o. 27rntimi Terlchsheet
IYup Runk: 1O1047
l'uou Sc nucoa GCMS/AKCIDUIt
P,eI, Wur kl� I, Ol, F.e IA q(; lii)
I'rrp ,\'I clhud: Mahnd
Slams: Prepped
Pre-p lhrtrrri0,c 11/19/090330 PA'1
TLah Code
Client ID
B?
tlolhod /Test
pH
tdatriz
Amt. Ext.
Sample Description
1
I'0901014-001
f ugzc, Pilo ,a Fertic
01
1613BIDinz1'rs Fiumis
7
\Wule,enlcl
10000d,
linlcd clear liquid
2
r0901036-001
0211 PINEDAI E I6-0691 090
.01
1013B/Ilioxins Funms
S
Drinking Wumr
920mL
clan colorless liquid
LO90I015-601
679106
'01
lul3S!Di1)suu' Ful'nns
7
R'uslcwatal
Mud.
linlcd clear liylliI
d
EO'1010n3-002
9KI9005 1
.01
161313;Dioxins Fumns
N
Wum:
850nLL.
sandy cloudy liquid
5
[QO9004191U1
"B
1613WDiuclns Furnns
Liquid
IOUOm1.
6
CQ09009'11-02
LCS
1613B/Diamins huane
Liquid
IoMul.
7
B00900991-01
DLCS
1613N/Dlo.eins lhuons
Liquid
100011:t.
S
0O090049L04
MR
16138IDio.cins Furors
l iquid
IOOOnd,
'/
1Q0900491-05
LCS
1613B'Dio,ins Furnns
I. ignld
I0001n1_
10
EQ0900991.06
DLCS
161-,BM i.,,o, Fu au,
Liquid
lOOO,nL
II
JU905693-001
RYOI- No,foid, Soo16c: a
All
1613B/Dw1lm-Fnreos
c
Wmcr
990n1
linmd 0,a liquid
12
J090693-002
OBA - Old B9rtmr Arc:'
.01
16pB,Dlozius r-uruns
5
Wane
975.L
yellow brmcn eIu 1,liquid
Il
J0905691 003
CI. 11 AV¢I ( uu ,,dmvn
01
1611 B'Dius i ns Furuns
5
Wumr
950mL
linlcd clear liquid
19
30905691-00-1
1-17-04
01
1613611)i v—Furnns
6
W:ac:
950mL
vellum elnudy lignld
15
J090569;-005
Neu
'01
16 GBID'mclnc Furmnu
5
Wam
940n:L
Ishc yellow cloudy liquid
16
J0905693-006
1,170'
01
16133/Dinzins Forams
6
wu.+,
940nd.
light yellow cloudy liquid
17
J09U5693-O07
\\...... rd
Ol
161,B/Dioxins ISuvu
6
tlrmcr
960mL
bro,nn cloudy liquid
IS
K09J0960-00
Bleach Pl:ml Composilc
01
16139/Dinzins Fnruns
5
Uhler
1005m1-
ted Frown elezr liquid
19
K0911017-002
OW-7-091I I
OD
16138/D.—in, Finans
7
U'mu
IOgUmL
Ihncd clot liquid
20
K0O 11025 004
DW 9-09111'
'03
1613131176oeia, Fou.u,
7
Wmcr
1025roL
luu,d clear liquid
_1
K0911049-002
56229(AA)
01_
161i8!Dimins Furnns
6
W'alc:
1000nil.
beige cloudy liquid
27 0/ 29
Pn u'd 1I,13109 11-:45 Ihepvmion Inlnnnmirm Bencluhcet Pugc 1

Preporution InfL..rlation Berlchsheet
zs
Piet, I'low I0IU47 Prep A%'(,I Xlo+v: OrgF.,c1Aq(36,) ShHus: Prepped
Tulln: Semiepil UCNIS/AKODUR Prep IAielhbd: Mulhod Prep D1tlorl')mc: 11/19/09 03-.30 PM
$pilcin'„ Solulions
ZNUn 1. 161311 Al nuim \49rk ing Standard Invcmoq ID 11 191 Logbook Rc;. f310-55-313 Ispires On: 07/242014
L00900491-02 Ioo,opop)_ rQ0900191-D3 too.onoL E00900491-05 lool)t1)11_ P.Q0900401-06 100.0010.
Name: S290/I013f3 Clcnnup Worh:ing Standard
f
Invenlu, ID 1335S
Logbook Ref:
1)10-90-IA/9
Expires On:
I/1601010
E0901034-001
100,01)pI-
EUDO103GUOI
too )0111_
1'i0901U33-001
100.0011E
1309D 1043A02
1(to no I I L
LQ01900191-01 1to, ontiL
EQ0900,191-02
100, o0)11.
EQW,00.191-03
1no,00pL.
LQW00491-04
IOuOOpL
LQD900491-05
Ino.DOIiL
LQ01900491-05
100.0011E
10901693-Dal 10000pL.
10905693-002
Io000)1L
10905693-003
too.00pL
)0005693-Oo4
100, 00111.
J0905693-005
too.00p1_
J11905693-006
Iou.Oupj-
10905693-00: 100.0011L
'0910960-003
100-oopl-
K09110^_7-002
too oo µ)_
KU9110'_7004
I00. D01d.
K(191 I049-002
100. U01r1_
Moo,,: 1613E Labeled Working Smndllyd
Inventory ID 13509
Logbao),'Rrf.
MU-91-213
6xplmsOil II/19C010
C09010316-001 i,000.00ItL E0901019-001
1000.oupl_ LO9mn.t3-002 IooOooltL.
AY)W693-001
IouOOopL
109U5693-DO_' IOo0oopl. )0905693-003 1000.oupl.
10905693-004 1.000 OOpL 10905(.93-no,
1000out,L 10905693-006 100000 of
1090569;-007
100000❑1.
K0910960-00; 1000.00111. K0911017.002 1u0000pl.
Kn9I I0I2-004 I.000. ooµL K091 I049 On'
luuo.nupL
Nanm. 1613H Labd,d Working Standard
Invamrty 10 13510
Logbook' Ref
MU-90-213
Explres 0o: 11/16/2010
1i0901014-001 1000 until.
LQ090ul')!-01
IOOU.u9pl,
EQ0900-19 1 -02 IOoo,00pl.
EQD900:91-03
100000p1- LQO900491-01 IOoU.00p1_
EQ09u0491-u5 1000. o0)I)_
1iQUVUU491-Du 100(100n L.
I'rcpa ration ,bLfcrin1,
Aeebne vr.S%'Imm,um
C3-IO-D0)(]I99)
C a rbnn. I ligh Put ip'
C223-001(9-,5.21
EI 1nI A cc Late 999v M in nn e In
C223-006(946li
E10Ac
Floriail(Mayncsi.+Silica Gel)
C2-8-00)(+61)3)
G1:Iss Wool
C9-13-005(7 198)
Snlfuni A: id RengmO Grndc
C2-24-003 (946 1)
I US04
Dic fl.,t, elL.nm (klclhylcnc
C2-25-001 (9149)
Sodium'I I;... n.I o. Anhydrous
C-31.2 (13071)
Sudium Chluridc ftcngcnl Grndc
CI-104-2 (3306)
Chloride)99,9%MuCL
Rc', enl Grad, MaS203
Nacl
S 9din m I it RcagrnL
C2-24-002(9463)
Sndinn+ Sulfmc Anhydrous
C2-19-006(7101)
J... lccnnc(n-Tooke ,e)
C2-24-001(9460) -
(lrade Na011
Ruiycnl Gmde Na2SO4
Hc[;Ino(mHee Ve) 9S.5%
C2-25-004(9441)
Nonanc ln-\ou:ns)M.
C2--21-0114(9i57)
IFl P:4Yr U-14
(IOOS)
Min +
SIIIeaGO Rea,"i Craek
C2-29-n07(9416)
3'nhmnc 99.1yFo \iininuan
C2-25-003(9416)
11repo,ation Slops
Step: Lnr,Iolion
Step.
Acid Clain
Smp: Silica Gel Clnn
Slop: Rind veiunw
I,Slnr:cd: 11119/091530
SIII11edi
11120/0905:(to
.Stinted: IICUi0914:(IV
Snored: IIQ3/0907.UO
-1�Fini0ed 11/19/09 I2:15
Finiffia1:
1IR0:0909 Do
Finished: Iirwop, MOO
I'mkhed: IIn3/U910:00
By: AKODUI<
By:
AKODUR
8p. AKODUR
8, AKODUIt
28 of 29
Prfnlud I IC3/09 13`43 PmPa allmt Infonnlxfon Bcnchshcn Pa'.

Prep I<unH: I(1 10.17
"fan m: Sem,oaGCMS/AKUDUk
Cnm ,cws:
Hari,—d R, JD
aHr ... of ce,.d,
Prepnralion /nfnr„,ration Fsenchsheel
29
I'mp\\'ur1:I�lua': Ur@Fs I:\q(iG?1
I'Cell �,\9CtIlod Method
11/23/2009
Iam�Hwsnad ny: oar.:
Fcai red lit: Dw,, Yw No
or
Slnlm: Prepped
I'rop U:ltC/time: I I/19/09 03 30 I'M
Prlomd I U,3109 1'_ 45 - I'rcprvrnilnn lulin m,Gon PcuMsnccl P", t

Dorntar Cornpany - Ply11101.1th
Rainfall Amount
11110/2009 to 1111312009
Climate Final
Discharge
Pumps Rain
Gauge in
Date/Time
1/10/200900:00 0,66
1/11/200900:00 5
1/12/2009 00:00 1.15
Minimum:
0.66
Maximum:
5.00
Average:
2.27
Total:
6.81
Monday, December 07, 2009
Page 1

Boone, i a nika
Front: Hardison, Diane
it: Thursday, November 12, 2009 12:12 PM
,,,: Boone, Tamika
Cc: Barnes, Alan
Subject: Notes from 11/12 stormwater sampling effort
Alan and I went out again today and checked outfalls and collected samples from 4 additional outfalls that were producing
flow. The rain gauge showed 5 inches of rain this morning -- 9:30 am, when Lorenza checked it. Here is the data on the
outfalls from which we collected samples:
LF04 ph =6.89
NBA ph=6.3
LF02 ph= 6.8
WYN ph = 7.4
1 have completed Qualitative Monitoring Reports for these as well. I will rewrite them so they are neat and leave them with
you to add to the record for this entire event.
Diane R. Hardison
Dom for, Paper Company, LLC
Environmental Department
P.O. Box 747
Plymouth, NC 27962
Office phone [phone]
Cell phone [phone]
''x [phone]

Woodyard NBA OBA
COD 316 37
BOD 17 3
Solids 34 17
LF04 CL14 LF02 RY01 005
93 46 32 46 23 23
10 2 1 4 3 2
49 69 44 20 22 5

Domtar
II all houfns mil h paper
Dom la: Paper Company, LLC
Plymmith Mill
PO Boe 7a7
Highway 149 Noilh
Plymouth, NC 279E1.
T 2S2-7939111
�vww,domtarcom
February 17. 2010
N,k. COICeII SUlllnS. Chief
Water Qualit)• SCC6011, Division of Water Quality
Dcparttucnt of 1:11ViI011111ellI and Nattu'al Resources
1617 Mail Service Center
Ralcieh. North Carolina 27699-1617
Deal' Ms. Sullins:
CERTIFIED MAIL
RETURN RECEIPT REQUESTED
Re: 2010 Plan Dioxin Monitoring of -Fish
NPDES No. NC0000680 (Plymouth Mill)
Enclosed arc uvo copies of the fish saoillfinI, plan for 2010 per the Plymouth Mill's NPDFS permit
requirements. The 2010 plan includes lish collections al the same locutions as sampled in 1989, and
all of these sites have been sampled annually since 2002. Bottomtish/catfish will be collected and
analyzed ❑t all locations in 2010, Gamcf ish will not be collected and analyzed, except at tlic Welch
ecreck-localion, which is conskMitwith9he chaii,c io the 2000 study saglecd upon 1w the NCDWQ,
in your letter dated April 10. 2000. -
We plus to have collections and initial ploccssiag of fish done for the Plymouth mill undo' contract
with CZ..R. Inc. of Wilmiagton. NC. Completion of the final report will also be contracted with
C'7_R. Inc. with report review provided by AECOM in 2010. The mill environmental staff will
provide oversi,ht lift the project io 2010, Sample analyses will be part ofa coau'act with Columbia
Analytical Services. htc. in Jacksonville. Florida with the actual sample analysis conducted by their
lab in Houston,'I MIS.
Should you have any comments or questions, please call me at 252/793-8984, Please provide
Written acceptance for this plan to my attention.
Sincerely.
Don \ lie
I nvironnlclital Engineer
Plvnnxlth
ze: Diane llardison
Sam Cooper- CZR. Inc.
Kristen Durochcr- Ah:COM
Al Flod,c.-NC DWQ Washington Regional Office
JelTDeBeradinis-NC DWQ Environmental Sciences Section, Raleigh

Plymouth Mill NPDES Study Plan: Environmental Dioxins
PLYMOUTH MILL NPDES FISH DIOXIN STUDY
2010 PLAN
BACKGROUND
This study plan supports a dioxin monitoring requirement in the NPDES permit of the
Plymouth Mill (permit No. NC0000680). Supplement /Special Condition A(9) of the
permit contains a condition for analysis of fish tissue for dioxins. The fish tissue
collected for dioxin analysis will consist of only edible (i.e., fillet) tissue. The permit
specifies that a study plan approved by the North Carolina Division of Water Quality
(NCDWQ) contain the following minimum sampling requirements: (1) determine the
levels of TCDD and TCDF in ambient fish tissues at one station upstream and two
stations downstream of the discharge; (2) annual sampling; (3) dioxin data will be
reported within 3 months of collection (i.e., data is complete).
This plan represents the twentieth year of sampling under NPDES permit or
administrative letter requirements. The sampling design for 2010 provides a strategy
for obtaining data at more than the minimum number of stations required by permit to
continue monitoring the reduction of dioxin in channel and white catfish in the areas
corresponding to current dioxin -based fish consumption advisories. Sampling stations
will remain consistent with those in past years as depicted in Figure 1. The mill
discharge station was added in 2002 to further characterize fish dioxin concentrations in
the river closer to the mill discharge than the River Marker 15 station. The Welch Creek
station has been voluntarily sampled by the Plymouth Mill every year since 1989 to
monitor declines in fish concentrations following removal of the effluent discharge from
the creek in the late 1980's.
Consistent with the 2000 study when the requirement to sample gamefish was
discontinued, only catfish samples will be collected in 2010 at all stations except Welch
Creek. Catfish samples and an additional two gamefish samples will be sampled from
Welch Creek. As in studies since 1994, three catfish samples will be obtained at each
station, where possible, to provide better fish size stratification so that year-to-year
size/age and lipid content variations can be minimized. Variations in previous years'
fish sizes and lipid content, and thus dioxin levels, has partly obscured trend
comparisons in the past.
APPROACH
1. Fish will be collected from eight stations spanning from 29 miles above the mill on
the Roanoke River to Bull Bay in Albemarle Sound, about 25 miles below the mill
(Figure 1):
- Near Williamston (Will)- 29 miles upriver from the mill: the reach spanning two
miles upstream of the Hwy 17 bridge at Williamston to Sweetwater Creek, about
two miles downstream of the bridge
Page 1

Plymouth Mill NPDES Study Plan: Environmental Dioxins
- Mill discharge (Mill)- downstream of the mill effluent discharge on the Roanoke
River from 100 yards upstream of the mouth of Welch Creek downstream
approximately one mile
- Welch Creek (Welch)- lower creek area generally within one mile upstream and
downstream of Trowbridge Road bridge
- River Marker 15 (RM15)- on the Roanoke River 4.8 miles downstream of the mill
- Sound Marker 1/Albemarle Beach (ASM1)- in the western end of Albemarle Sound,
about 10 miles downstream from the mill
- Chowan River mouth, Hwy 17 bridge (Hwy 17)- in the northwestern area of
Albemarle Sound
- Highway 32 bridge (Hwy 32)- in Albemarle Sound, about 19 miles downstream.
- Bull Bay (B.Bay)- in Albemarle Sound, about 25 miles downstream.
Plymouth Mill Roanoke River/Albemarle Sound
2010 NPDFS Dioxin Sample Plan
No. of composite No. of composite
Station catfish samples gamefish samples
Williamston
3
Welch Creek
3
Mill Discharge'
3
River Marker 15
3
Sound Marker 1 Albemarle Beach
3
Highway 32
3
Chowan/Hwy 17
3
Bull Bay
3
Total Samples
24
Station added to plan in
2. Fish collections will begin in the spring and may extend into the summer -fall period
depending on the capture success for some catfish species. Composites will consist of the best
available samples after fishing at a level -of -effort that is similar or within the range of previous
Page 2

Plymouth Mill NPDES Study Plan: Environmental Dioxins
years sampling efforts; but which are also dependent on weather/river conditions and fish
availability.
3. The target fish will be bottom dwelling catfish species; channel catfish (Ictalurus punctatus)
or white catfish (Ictalurus catus). Other species may be substituted depending on availability.
In addition to the catfish, largemouth bass (Micropterus salmoides) and bluegill sunfish
(Lepomis macrochirus) will be collected for Welch Creek gamefish samples.
4. Three composite samples of catfish fillet tissue will be collected for each station, where
possible, an additional two gamefish fillet composite samples will be collected in Welch Creek.
Where possible, the three catfish samples will be allocated to two channel catfish samples and
one white catfish sample. Composites of white catfish will be substituted for channel catfish
when channel catfish are not available.
5. A target for each composite sample will be four to ten individual fish, although the
actual number of fish making up a composite may vary because of availability of the
particular species. An attempt will be made to obtain fish of the same species and size
range for the particular station for previous years. The number of composite dioxin
samples totals 26 this year (31station X 7 stations + 5 Welch Creek samples), provided
fish are available. At least two catfish composites will be collected for all stations (plus
the two gamefish composites in Welch Creek). Therefore, the goal or target is three (2
channels and 1 white) samples each consisting of at least 4 fish with at least two
samples provided, where available. For example, if 8 white catfish are collected, then
2 samples of 4 fish will be utilized rather than 1 sample of 8 fish. This is dependent on
fish sizes and availability of fish.The number of fish to be collected and retained totals
between 104 and 260 (26 samples X 4 to 10 fish/composite).
6. Lipid content of the muscle tissue (i.e., fillet) will be analyzed to determine the dioxin
concentrations relative to lipid content.
7. Samples will be analyzed for all seventeen of the 2,3,7,8- chlorine substituted dioxin and
furan congeners. The analyses will be done on a fresh weight basis using high -resolution gas
chromatography/high resolution mass spectrometry by a competent laboratory using EPA or
equivalent techniques.
METHODS
Fish collections and initial processing will be done for Domtar Paper Company, LLC under
contract with CZR Inc. of Wilmington, North Carolina. CZR will collect fish using appropriate
collection permits and licenses. CZR completed collections of fish for Weyerhaeuser and now
Domtar over the past nine sampling seasons (2001-2009) under the supervision of the
Weyerhaeuser SEFS and now the Plymouth Mill environmental staff. The Plymouth mill will
continue active oversight of the study in 2010.
Page 3

liz
Plymouth Mill NPDES Study Plan: Environmental Dioxins
Standard fishery techniques -- gill.nets, hoop nets, electrofisher, trawls, trotlines, rod/reel -- will be
used to collect the fish. Fish collection and handling in the field will minimize potential cross
contamination and assure sample quality control. When fish are collected, water proof field logs
will be used to record pertinent data -- station, date, time, and collection technique. Excess fish or
unwanted species will be returned to the water; fish for analysis will be placed on ice in separate
coolers for each station. Fish will be on ice for a maximum of two days.
Each fish retained will be measured for total length (mm) and weight (g) and receive an individual
identifying number. The boneless and skinless fillet from each fish will be removed using hexane
and methanol rinsed utensils with clean up between fish. Sex of the fish will be determined during
the filleting step. Each fillet will be wrapped in solvent -cleaned foil and placed in labeled plastic
bags and frozen until processed for fillet composites. Composite samples may be prepared
immediately in the preceding step if all the fish required for the sample are available.
Composite samples will be prepared from iced or thawed muscle fillets from 4 to 10 individual fish
when possible. Composite samples (grouped, but unblended fish fillets) will be wrapped in
solvent cleaned aluminum foil and placed in freezer bags, frozen, and shipped to Columbia
Analytical Services, Inc. in Houston, Texas, or other suitable, competent laboratory. An analysis
request and chain -of -custody sheet will accompany the shipped samples. Homogenization of the
fish composites and dioxin analysis procedures will be done using EPA or equivalent methods.
Reporting limits will be < 1 ppt for dioxins. Lipid and moisture content will also be determined.
The remaining, homogenized samples will be archived for three years.
Page 4

G
Plymouth Mill NPDES Study Plan: Environmental Dioxins
N
A5 0 5 Miles Cowan River
CR-17
J ^AS -BB
Hwy 45
Albernade Sound 5-32 -_1._J
RR-75 OAS-M1 } -�
-
_- - �....._.......___.. oa�Oke mill discharg
RR -WI —a onnoke on river RR -MD
River ` PI mou1M1
Wlliamston
.� rymouth/-
Jamesvilie \ Mill r.
r
WC -LC 7roworb a
ekh Rd
Crook
0 1 mile
Ifv 64
Figure 1. Plymouth sampling stations (in bold) for dioxins in fish fillets, 2010.
Page 5

Q�c3Np
NOTE:
AREAS WHICH ARE NOT HIGHLIGHTED A
.r .
NOT REGULATED AREAS BECAUSE:
1. AREA IS ENGINEERED TO DRAIN TO THE
WASTEWATER TREATMENT SYSTEM OR
2. AREA IS NOT USED FOR INDUSTRIAL
ACTIVITIES.
J
I P i,E g80
N {
`J
_ — SALVAGE
AREA
(RELOCATED) a /'
it
Y w FT
,
i
V CONSIUM iir-nj
PARK NG 'r,REA
2 .. ..., (RE10 ATED) URS
il� i
o-. � •� �5 li._„, ,t3 .a I I ��'.' ,�,1. lelrph3o1n0
lrR(1
S-`i1(9luriicIn I 'uvl uvAiine
01
LEGEND N.&,�eh�
nt-t
4
F,c(9N),JU O>l'._
DONIT.IR PAPER COMPANYCL('.
o PI.YMOUIH NORIHCAROLPl4
n gNEI_ {'\,� r,.._J' �I•� I SCALE CRN 9V d111(P:1f OAiE )/00/7/UI FltE M0.
DRAINAGE AROei 5i 100 _
��, i lssuuwv �RENSEo iAt-a oar�:U.,o/n� �_
`r" koxIMATE SCALE I —fr!i
" N,
!{-51 i'O, I')t

1 0
U
C3Li (FAt L LF02
EXISTING
.._ SEDIMENT
^ POND. No. Y
C
POSED
SEDIMENT
SEDIMENTMENT
POND No.
DISCHARGE
(Future)
OUTF 4LL LF'UI
E:t3TING
°No ��
EXISTING
ASBESTOS
LANDFILL
SECONDARY SL
EWATERLNG CIITIY
j
DISCHARGE
(FutureLi
I LANDFILL No. Si
OU-IFALt.
1rI DISCHARGE
lo, 5 (Future)
OUTFALL 1 FO,3 k
V
SEDIMENT PONDS
1rI DISCHARGE
lo, 5 (Future)
OUTFALL 1 FO,3 k
V
SEDIMENT PONDS
RUNOFF COLLECTION AREA
DISCHARGE VOLUME
POND No.
BEGIN OPERATION
(ACRES)
(ACRE-FEET)
1
1990
33.9
10.5
2
1990
6.5
2.0
3
2001
16.7
52
4
2010
16.4
5.1
5
2014
30.8
9.6
6
2072
40.5
126
LF04
2005
TEMPORARY
..-''
NOTES
1. PHASE CONSTRUCTION IS BASED ON AN ESTIMATED WASTE GENERATION RATE
¢
OF 100,000 CUBIC YARDS PER YEAR.
z
2. DISCHARGE VOLUME IS BASED ON A 25 YFAR/24 HOUR STORM EVENT.
3. LANDFILL 13 IS UNDER CONSTRUCTION. CELLS I & 2 ARE IN SERVICE.
O
G
7
iJRS
/
l Rti ('�gwai�on Al ,p lend
316Jlaplu iva0d! ert Suite 30l
RelmEh, North C unhn, 27604
_.
Polepherre (T/9)Ss0-4E11 Fal(9/9)790-0217
1)0\1 PAR PAPER COMPANY, LLC
PLYMOUTI{, NOR "PF1 CAROLNA
SCAI Fi
DRN BY. K 111 �E. I,00
—
FiLF NO
d
A 'ZOXIMATE SC4U
"
itiSItOSYV
REVISED: l}B JFT�G L �s
i100. =
�Fii
a
_s 1
I O-;.
0 CO IL.TI,-El
1Y;U ,S11 '(71^I 17

\
I
I
1
II
\
I
I
APPROXIMATE SCALE
/ 3 0 200 400 FEET
a
a
i
I I
/17
y / (
a
\ 1
10.9
LEGEND
DRAINAGE AREA
a�
SPOT ELEVATION
SURFACE FLOW DRAINAGE DIRECTION
i.6 awr... l5 X 7.7
SWAMP
I
I!
WOO
R CLE
I ( AREA
j64 , ' / 193 /• • 2a.2
1 / 12.8 i89 I
I I,, V lg5
II
15.6
FORMER SILT FENCE
ASH AND SHALLOW 1s,9 >ea
RECYCLE x
I I DITCH 13.3
AREA
J I NOTE:
AREAS WHICH ARE NOT HIGHLIGHTED ARE
_ NOT REGULATED AREAS BECAUSE:
149
14.7 1. AREA IS ENGINEERED TO DRAIN TO THE
EARTHS, WASTEWATER TREATMENT SYSTEM OR
GERM
2 AREA IS NOT USED FOR INDUSTRIAL
T T �C
ACTIVITIES �,J �7
1 I2i Cali 11 C rttvsulle
31097�pitnrv�adl ours Su76901
Rule h Narh C�rnkn7 '7604
filephnn„lR79)C+!}9511 I•et 1919)7!41-0217
7 DOMT:AR PAPER COMPANY. I 1 L
PLYMOU H NORTH CAROL NA —
DRN 8Y Ic V t AT
SCALEt yip FILE N0.
: S)IOO.
13.4 AS SFi0A1A 'REVISED_—
�' `�' WOOD RI CY(1 1. ARC \

/ V W W o/ 8 WAMINGTON OFFICE
FEB 0 3 1995
STORMWATER DISCHARGE OUCFALL (SDO)
MONITORING REPORT D. E M.
GENERAL PERMIT NO. NCG120000 (Landfill)
CERTIFICATE OF COVERAGE NO. NCG12 0022
FACILITY NAME Weverhaeuser
PERSON COLLECTING SAMPLE(S) Ed Thompson: Bob Lee
CERTIFIED LABORATORY(S) Weyerhaeuser - Plymouth LAB # 171
Weyerhaeuser - New Bern LAB # 135
Weyerhaeuser - Tacoma, WA LAB # 374
Part A:
No.1 Pond 1 11/16/94 1 0.00014 1 7
5
%01
SAMPLES COLLECTED DURING CALENDAR YEAR 1994
(all samples collected during a calendar year, shall be reported no
later than January 31 of the following year)
COUNTY MARTIN
PHONE NO. [phone] a
(Signature of Permittee or DesidAee)
By this signature, I certify that this report is accurate and complete to
the best of my knowledge.
<3 1 <3 1 <5 1 <0.010 1 <3 1 <0.2 1 <8 1 114
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes V no
(If yes, complete Part B)
FORM MR12

00
STORM EVENT CHARACTERISTICS:
Total Event Precipitation (inches): 0.46
Event Duration (hours): 3
(if more than one storm event was sampled)
Total Event Precipitation (inches):
Event Duration (hours):
1 Applies only for facilities at which fueling occurs.
Mail Original and one copy to:
Attention: Central Files
Division of Environmental Management
DEHNR
P O Box 29535
Raleigh, NC 27626-0535
2 Detergent monitoring is required only at facilities which conduct vehicle cleaning operations.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.
Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware
that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations."
(Signature of
-/7' /
(Date)
FORM MR12

a'
Stormwater Discharge Outfall
Monitoring Report
Permit No. NCS000189
Facility Name Weyerhaeuser
Person Collecting Sample(s) Ed Thompson, Bob Lee
Samples Collected During Calendar Year 1994
County Martin
Phone No. [phone]
Certified Laboratory(s) Weyerhaeuser Company - Plymouth 171; Weyerhaeuser Company - New Bern 135
Weyerhaeuser Company - Tacoma, WA 374
Outfall
No.
Date
Sample
Collected
nzo/da/ r
Total
Flow
(MG)
Total
Rainfall
(in-ches)
Event
Duration
(hours)
Chemical
Oxygen
Demand
m /L
Total
Suspended
Solids
m /L
BODs
m /L
Total
Phosphorus
m /L
006
11-16-94
0.02112
0.46
3
140
264
6
0.52
007
11-16-94
0.05703
0.46
3
260
490
32
0.55
008
11-16-94
0.04781
0.46
3
310
35
8
0.51
(Signature of P, r
By this signature, I cerfig
complete to the best of my
or Designee)
that this report is accurate and
knowledge.

Weyerhaeuser
January 20, 1995
Attention: Central Files
NC DEM - DEHNR
P O Box 29535
Raleigh, NC 27626-0535
Dear Sir:
P.O. Box 787
Plymouth, North Carolina 27962
Tel [phone]
Certified Mai[
Return Receipt Requested
Enclosed are 1994 Stormwater Monitoring Reports for Weyerhaeuser Company,
Plymouth, NC. These reports are for Permit No. NCS000189 and General Permit No.
NCG120000.
If you have any questions concerning these reports, please call me at [phone].
Sincerely,
William R. Glover
Environmental Specialist
WRG:dmc
Enclosure
xc: File

Stormwater Information Exchange Meeting
Weyerhaeuser Company — Plymouth, NC
Thursday, September 16, 2004
Requested Attendees
NC Division of Water Quality:
Robert Tankard, Washington Regional Office
Weyerhaeuser
Bracky,Bickerstaff
Jerry Coker
Jerry Foster
Will Hardison
Diane Hardison
Bob Lee
Bill Morris
Ed Thompson
Proposed Meeting Agenda
I. Purpose of meeting
II. Introduction of attendees
0
111. Overview of current consolidated facility -wide storm water permit
A. Overview mill aerial
B. Overview each stonmwater drainage area and its outfalls
C. Overview changes in SWPPP (stormwater improvement projects) since issuance of
permit.
• 006 drainage area — . iaf ne.,�,Jlred' off'^ ^�"'tQ Alfclrna�a- ev�. jaw^}
• Contractor Laydown (additional outfall and some renumbering)
• Winter Log Storage area — in SWPPP, not in original application or permit —
Norfolk Southern Railyard — in SWPPP, not in original application or permit
• Two new sedimentation ponds for landfill 93 — mentioned in application, dot Isi'5
in permit, next revision of SWPPP should include them ��
IV. Specific questions concerning I" round of quarterly analytical sampling
A. For the contractor laydown area, may we sample CL09 instead of CLI 1? CL09 is
better configured in the field.
B. We need to confirm method for calculating flow (drainage area) for each
representative outfall to be sampled.
C:\DOCUM E—I \ROnERT-d \LOCA LS-1 \TEM P\S W Info6xchangMeetingD W Q091604.doe
Page 1 of 2
Created on 9/15/2004 10:16 AM Created by Diane Ilardison

f
May we use the AutoCAD Cale method of mapped drainage areas?
Are we to Cale total area and report, or total area divided by number of
outfalls, in areas with many on and only 1 or 2 designated for sampling?
• Confirm use of flow measurements where they can be measured and applied.
C. Defin VOC �SVOCalytical methods for stormwater samples.
D. Is the require TPH)inalysis for the gas or diesel fraction or both?
V. Outfall tour — field review of drainage areas and outfalls
VI. Other Questions
A. How should we handle changes in drainage areas and outfalls?
B. How should we handle incorporation of new landfill sedimentation ponds into
consolidated facility -wide permit?
C. Does original construction -related stormwater permit for landfill sedimentation
ponds remain effective?
D. Discuss plans for developing a wet log storage yard, with spray system — what are
the applicable regulations and permitting requirements?
• Tour site
V II. Wrap up — other questions/comments
VIII. Follow-up action items
Handouts provided in the meeting:
• Weyerhaeuser stormwater permit No. NCS000189
• Listing of all outfalls with descriptions
• Facility -wide outfall maps
• Monitoring report form
• Conceptual design proposed for wet log storage site
C:\D000M E—I \R06ERT-1 \LOCALS-1 \TEM P\S W Info ExchangMectingD WQ091604.doc
Page 2 of 2
Created on 9/15/2004 10:16 AM Created by Diane Hardison

Permit Number: NC or
Certificate of Coverage Number: NCG
FACILITY NAME
PERSON COLLECTING SAMPLES)
CERTIFIED LABORATORY(S)
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR:
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY
PHONE NO.
(SIGNATURE OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate
complete to the best of my knowledge.
Outfall ."
No;..
;Date ,
Saipple
Collected
50050
Total"
Flow;'.s
�'
r
"
tmdldd/ r -
MG- "
'::N
tw ,` M *
`,
7,77,
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? yes no
(if yes, complete Part B) _—
Part B: Vehicle Maintenance Activi Moni[orin Re uirements
Otitfall'
No. -
_
Date
Sample ;Total
'Collected"
50050
;00556 m{, `C,
00530t ,zs`00400
Floiv
Ot)-.and} ;�. -_
Grease
1Tota1 `- s
Suspe ded'
pH -. t
.ty+
nett Motoi•,�
OiIUsage
-
'.mo/dd/yr.
z
MG
m'1�
Form SWU-246-051100
Page 1 of 2

.a
STORM EVENT CHARACTERISTICS:
Date
Total Event Precipitation (inches):
Event Duration (hours):
(if more than one storm event was sampled)
Date
Total Event Precipitation (inches):
Event Duration (hours):
Mail Original and one copy to:
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
(Date)
Form SWU-246-051100
Page 2 of 2

Outfall Number
Outfall Name/Description
SW Control Measures In Place
sheet pile bulkhead along river front with outlets
Power/Recovery office parking lot
for sheet flow runnoff from parking lot,
drainage area, formerly known as 006
containment around nearby truck and rail car
006
ditch
unloading areas
Manual stop gate in outfall, concrete collection.
CP01
External Coal Pile
ditches around coal pile which drain to wwts
RY01
Norfolk Southern Rail Yard
Grassed lined ditches
Contractor laydown area behind NICO
CL01
trailer
rip -rap check dams in shallow ditches
Contractor laydown 2 area east of
CL02
laydown 6
rip -rap check dams in shallow ditches
Contractor laydown area 1 east of
CL03
laydown 6
rip -rap check dams in shallow ditches
Contractor laydown area due north of
CL04
security
rip -rap check dams in shallow ditches
Contractor laydown area west of paint
CL05
building
rip -rap check dams in shallow ditches
Contractor laydown area 1 west of
CL06
laydown 7
rip -rap check dams in shallow ditches
Contractor laydown area modernization
CL07
clock alley
rip -rap check dams in shallow ditches
contractor laydown area west of scrap
CLO8
metal
vegetation in swales
Contractor laydown area east discharge.
CLO9
to swamp
rip -rap check dams in shallow ditches
Contractor laydown area west discharge
CL10
to swamp.
vegetation in swales
Contractor laydown area west of salvage
CL11
area
vegetation in swales
Contractor laydown area west of salvage
CL12
area
vegetation in swales
OBA
Old Borrow Area
rip -rap dams, silt fencing, vegetation
LB01
New Borrow Area
WLS01
Winter Log Storage
mostly sheet flow, no controls
FY01
Flail yard North
vegetative cover
FY02
Flail yard South
vegetative cover
Flail yard scale catch basin discharge to
FY03
pond
clear path to pond with vegetative cover
Wood recycle area
earthen berm around ash pile, rip rap dam and silt
WRA
fence in drainage path by ash pile, paved access
road.
ARA01
Ash recycle area
Landfill pond 1 NE corner of LF#2
vegetated slopes, daily cover over landfill
LF01
material, ponds discharge via overflow pipes, rip-
LF02
Landfill pond 2 SW corner of LF #2
rap at outfall of pipes.
LF03
Lanfill pond cornero
revision 5/11/04 hardidr\stormwater\OutfallLocationsand Control Measures
1 of 1 . V

PROPERTY
BOUNDARY
.EXTERNAL COAL PILE: 35*5
'NbRFoLk'sb&mFkN
,76'45 48 'BORRO 35-56 01 11
THE OTHER DRAWAG
DIRECTLYT-' --- -- --
STRIAMAND INSTEAD ARE SHEET FLOW OR: `
DISCHARGE TO SWAMPY AREAS7.
M.
A
NPDF—'; OUTFALL 001
NORFOL
RAM AR
BORROW AREA.,
;�LLP THIS 2400 ACREPROPERTY Z:
OF REGULATED. INDUSTRIAL-',;
i:STgRM"TERDISPHARGE.,TEE'-,.
MAJORITY OFTHE SITE ISNOT
'
'-t F!EdULAtEDBECAUSE:""
APPROXIMATE SCALE
0 1500 3000 FEET
URS
URS Corporation - Maryland
3109 Pbpla ood Court Suite 301
Rab*Yh North Carolina 27604
Telephone( 1�)&50-9511 Fa [phone]
WEYERHAEUSER COMPANY
PLYMOUTH, NORTH CAROLINA
SCALE: I�DLN BY: KAH PATE: — FILE No
)0
AS SHOWN MSED: FTS INC-SPO JOATE, !O��3 5516
�0.22
FIGLIF
OVERALL SITE PLAN 1 3-2
I

0
O
WELL 14 \ 1��
�ID
PROPOSED BULKHEAD
(COMPLETED)
ROANOKE RIVER
� � OLD WET MACHINE
W
0
IL
LE�EN� N0.1 LIFT STATION
COAL PILE REBUILD —
POWER / RECOVERY AREA (COMPLETE)
AREA 8
LIFT STATION N0.1
WOOD YARD
tee"
r
0
PREVIOUS
OUTFALL 006
IMPROVEMENTS
(COMPLETE)
L
D I GE
I EMENTS
(IN NAL- COMPLETE)
URErp
vRsco,up -TSyua
3109Po .woad CaWr9rlte l0l
Reid l- Cvo0ae27601
Tdephace ( 9)55 Ml Fu [phone]
WEYERHAEUSER COMPANY
PLYMOUTH, NORTH CAROLINA
DRN BY: KAFi TE: SAO FllE N0.
AS SHOWN EVISED: FFS INC-SPO TE: 6 3 55I60.22
DRAINAGFHVIPROVEMENTPROJECTS 3-3

LEGEND
DRAINAGE AREA
o IMPROVEMENT PROJECT
SPOT ELEVATION
NO. 10
TU 131 NE T TURBINE
GENERAIORR
9.0
NOTE:
AREAS WHICH ARE NOT HIGHLIGHTED ARE
NOT REGULATED AREAS BECAUSE:
1. AREA IS ENGINEERED TO DRAIN TO THE
WACTPWATPI? TPPATkTPMT qv,,zmm nu
-1 oxp�b_ 0
AREA 2
MEDIA MAINTENANCE SHOP
STORAGE
LJ
04 in
m
NO. 2 6:) URS
HOG FUEL Zof• URS Corpmdon - MaTybnd
EL
Lcl. iwn z t)f
U) 3109 le wwdcomsotto Sol
t
BOILER R &Cmvlina 27604
FAN M OR ��t7 jo)8p 0
Trjeph� (. 1 �850,9511 F� [phone]
�95
�U= & DRIVE R (Y_—�
WEYERHAEUSER COMPANY
PLYMOUTI-L NORTH CAROLINA
RN Fl �NO
1,,: 8 L�E _51 00
SCN�'-s sloWN _ I �:� 5511060.22
ISED,FrSINC-SM JDATE, 6/003
OUTFALL 006 DRAINAGE AREA
3-4
7.6
------ 411

TURBINE PRECIP.
BUILDING AREA
RILEY
BORER O
BILE
c�
z
Nz
9
Zm I 10i1 Boil
BUILDING d AREA 1 k4
SHOP
7
12.5
O NO
w—
e
NO. 9
TURBINE
GENERATOR
F1
9.0
I
NO. I
HOG FUEL
BOILER
13.3
0 0 0 0 0 0% o 0..�
0
NO. 2
HOG FUEL
BOILER
.3
r
84
10.A
28.0
`",
NOTE:
. AREAS WHICH ARE NOT HIGHLIGHTED ARE
NOT REGULATED AREAS BECAUSE:
1. AREA IS ENGINEERED TO DRAIN TO THE
WASTEWATER TREATMENT SYSTEM OR
2. AREA IS NOT USED FOR INDUSTRIAL
ACTIVITIES.
\I
- �^ -
Y
IV-r RVM1IMRIC JW.L
'
_120 240 FEET
U SS
Cepmarim - Marylmd
L
PPoopptmwood Goer, saaro sol
erh North C1+oliae 27604
I)8549511 Far [phone]
HAEUSER COMPANY
TH, NORTH CAROLINA
cKAH TE 8100 FILE RO.
TS INCSPO TE: 5 7 oolw.22
COAL PILE AND
RAIL CAR STORAGE 3-5

S3
7A 6
9 ..
75 }
NOTE: - - /n
t _91
AREAS WHICH ARE NOT HIGHLIGHTED ARE- - 7 z 95
NOT REGULATED AREAS BECAUSE
1. AREA IS ENGINEERED TO DRAIN TO THE: -... / - . : - _ 1,, _ ; .-tar: • /' %/ \ �. i '"
WASTEWATER TREATMENT SYSTEM OR
2. AREA IS NOT USED FOR INDUSTRIAL, ` �_ ' -� •'ij i' !/ it
ACTIVITIES / O CLAlr r . \ o;3 �q L/ i o •"�' �'
X. SAMPLING REQUIRED BY ERMTC / .\ " "'"•! i .. r .,r.t�l9di f3 ,�c7� Q .,�i "o. o- .�
ourFALL X i ) °
\"vim` a pp
O �Ai:T.
1
/ r
it
OUTFACE � /� ../7,h--� .. ,�• r,:. Fhb �t 'lo-� I e �� t'.. I,'i� J4
35
` ..�-�. .- •.°. r-O\•. ,•.. IJ ri
_44
OUTFALI; 77
- CLA6 `�/ /.� O \I�� O •: 40's 6.9 i' � _ taa" I % ��////�
OUTFACE / / / // .:' O \�. J ': u ( 1 _.. �� a • ' R
VE,�• r O-__ � - •�'� � I� >,/ 14b..� � b
74 i•7 :/i / AREA �!/ `IIiI 4.z s9. //�!/ j71
6) I -'
\ _ - / �PJEND
X' S
\ L II DRAINAGE AREA II
\_ O" BALL • 4 .�.1 O TFA2 L.
72
�.p$w •,\\ r.�� hl � I � t�,'�'' "e'Y$` t I�', I �� -_ 5A i � �i� t'1.
94 ]3 - I
I � �• g I. 179 , � 157
7.1 \ CONSTRICTION
AREA
4.11 U S
f( �+ URS C uoa - lard
�\ s511 1 _ n Man
I ` •�127, I\ `.,I 1i g I(I ti i ,{ I 4 3109 1xA'oadCao+t, Sane "Is l I m 1,._j, Ball Norio CmoUw 27604
It , t i Telephone( 14)8.50.9511 Fe (919)7910217
WEYERHAEUSER COMPANY
;•. I PLYMOUTH, NORTH CAROLINA
t' �` ° o b - ' 3p d I I !: 9 9 k i ( 1 DRN BI: KAH/PAF PATE 9N0 / 7p1 FILE
N0.
I SWE:S SHOWN NEVISEO: FFS INC-SPO 7E: 6,U3 55160.22
`- - APPROXIMATE SCALE :r I'
IGURE
;!
PPNEI 070 ''0 - >�\�' ",i �,,,�,+" 0 400 't 800 FEET :; W,1 III I;, 1 I c A I I = CONTRACTOR LAYDOWNAREA
. n 3-6

x
4p1y0
.1.2
x1.2
// O t•
/
LEGEND '\
OD DRAINAGE AREA ti
\
1.2 SPOT ELEVATION
SURFACE FLOW DRAINAGE DIRECTION ,
APPROXIMATE SCALE
300
600 FEET
URS Corporation -Maryland
3109 Poplarwood Court, Suite 301
WEYERHAEUSER COMPANY
PLYMOUTH, NORTH CAROLINA
SCALE: DRN BY: KAH ATE: a10 FILE NO.
AS SHOWN CHECKED BY. KB DATE: 9/M 55100.22
FLAIL YARD AND
WINTER LOG STORAGE
3-7

�4rT 3..0 /
I�
I kIy
1 I�
I
U
/ — APPROXIMATE SCALE —
0 200 400 FEET
cr
/.
10.9
\I
1.7
r
r � ))
ram;
14 .I . � • �`^ � 11 �
I 0 fr I
��c,
t
r 192
9j
19..5 ti
\
I 15.9 \ � aea
[-IIGiiLIGHTED°
202
/.
10.9
\I
1.7
r
r � ))
ram;
14 .I . � • �`^ � 11 �
I 0 fr I
��c,
t
r 192
9j
19..5 ti
\
I 15.9 \ � aea
[-IIGiiLIGHTED°
202
US
URS Corporation - Maryland
3109Poplarwood Court, Suite 301
Ra/ieyh North Carolina 27604
Telephone (91J)850-9511 F. [phone]
WEYERHAEUSER COMPANY
PLYMOUTH, NORTH CAROLINA
- SCALE:
AS SHOWN
DRN HY: KAH
ATE: 9/00
RLE NO.
551 .22
REVISED: FTS INC-SPO
DATE: 6 03
FIGURE
WOOD AND ASH RECYCLE AREAS
I
3_8

9.9
44.5
ab
CHECK
as
m
1.6
m
APPRO)
0 200 400 FEET
I
URSURS Corpomdon- MuryL .. d
3109 Pbplmwood CuaM Suite 301
27604
Telephone )ro692@—&[phone]
WEYERHAEUSER COMPANY
PLYMOUTH, NORTH CAROLINA
SCALE: ORN W.- KAH FILE NO.
AS SHOWN RUKED W. KB PrATF. q 55100.22
FIGUR
BORROW AREA 3-10

J
�4D�S 0ov ALU pp1
�1 J1 �
O*-V Y
IWO
-0
l t�Y fr 1
'o
�`` EXIST: NO. 2
SUBSTATION r
LEGEND 4
_, ,, �•��::'=-"�� / ,,;=., �� DRAINAGE AREA FOR RAIL YARD
SURFACE FLOW DRAINAGE DIRECTION
V �LJ j'SOLI
/c-
URSAPPROXIMATE SCALE0 00 00 FEETf,URS ryland
3109 Popla ood Court, Suite 301
Ral/e h North Carolina Carolina
Telephone ( 1 )850-9511 F. [phone]
WEYERHAEUSER COMPANY
PLYMOUTH, NORTH CAROLINA
SCALE; DRN I KAH/PAF ATE: 9/l10/7/0l FILE N0.
AS SHOWN CHECKED HY: KH DATE: 9 55100.22
NORFOLK SOUTHERN FIGUR
RAIL YARD 1 3-11