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HomeMy WebLinkAboutWI0501074_Application_20211110North Carolina Department of Environmental Quality — Division of Water Resources APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Groundwater Remediation (15A NCAC 02C .0225) Do not use this form for UIC wells Permitted by Rule (ref. 15A NCAC 02C .0217) Permit Number (to be completed by DWR for new projects): WI0501074 I. APPLICATION INFORMATION 1. Project is: [ ] New [X ] Modification [ ] Renewal without modification [ ] Renewal with modification 2. If this application is being submitted for Renewal and/or Modification to an existing permit, provide: Existing permit number WI0501074 Issued Date: 7-2-2021 & Expiration Date: 5-31-2026 For all Renewals, attach an updated site map and status report including monitoring results of all injection activities to date. For Renewal without modification only, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (f the applicant is not the owner). II. WELL OWNER(S)/PERMIT APPLICANT (generally the responsible party) 1. Name(s): Schlage Lock Company LLC 2. Signing Official's Name*: Russell E. Eiler Title: Director, Global EHS Compliance, Schlage Lock Company LLC * Signing Official must be in accordance with instructions in Part XII. 3. Mailing address of Permittee/Applicant: 11819 N. Pennsylvania St. City: Carmel State: IN Zip: 46032 4. Telephone number: 1-317-810-3874 Email: russ.eiler@allegion.com 5. Status (choose one): Individual X Business/Org. Federal State County Municipality III. PROPERTY OWNER(S) (if different than well owners) 1. Name(s): Agrede, LLC (Greg Hodges) 2. Mailing address: 400 English Rd City: Rocky Mount State: NC Zip: 27804 3. Telephone number: 252-985-1070 Email: N/A IV. PROJECT CONTACT — (generally the environmental/engineering consultant). 1. Name: Mike Burcham Title: Project Engineer 2. Company: Geosyntec Consultants of NC, P.C. 3. Address: 2501 Blue Ridge Rd, Ste 430 4. City: Raleigh State: NC Zip: 27607 5. Telephone number: +1 919-424-1850 Email: mburcham(ageosyntec.com Groundwater Remediation Application Rev. 2-17-2020 Page 1 of 9 V. FACILITY INFORMATION 1. Facility name: Former Schlage Lock Plant Phone No. (if available): 2. Physical address: 213 Red Iron Road City: Rocky Mount County: Nash Zip: 27804 3. Geographic Coordinates: Latitude: 36° 01' 25" Longitude: 77°46' 00" Reference Datum: World Geodetic System, 1984 (WGS84) Accuracy: N/A Method of Collection (i.e., Google Earth, GPS, etc.): Google Maps 4. Brief description of business: VI. INCIDENT DESCRIPTION 1. Source and date of contamination: PCE impacts first identified on site in 1986. RCRA Facility Assessment Report identified multiple solid waste management units and areas of concern. They were generally associated with historical industrial activities (degreaser), chlorinate solvent storage (PCE transfer vault), and drum storage. 2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): Chlorinated volatile organic compounds 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? [X] YesIf yes, list maximum measured separate phase thickness: not measured feet [ ] No If no, list maximum concentration of total VOCs observed at site: ppb 4. Agency managing the contamination incident: [ ] UST Section [ ] Superfund Section (including REC Program and DSCA sites) [ ] DWR Aquifer Protection Section [ ] Solid Waste Section [X] Hazardous Waste Section [ ] Other: 5. Incident manager's name: Rob McDaniel Phone No.: 919-707-8215 6. Incident number or other incident mgmt. agency tracking number: NCD 065 300 519 Groundwater Remediation Application Rev. 2-17-2020 Page 2 of 9 VII. PERMITS List all applicable permits or construction approvals issued for the facility or incident: 1. Previous or other UIC permits issued by DWR (e.g., NOIs) WI0500984 for potable drip water for thermal remediation electrodes 2. Other Non -Discharge or NPDES permit issued by DWR: NPDES NC0079227 3. County or DEH subsurface wastewater disposal permits: 4. Hazardous waste management or other environmental permits required by state or federal law: Groundwater Remediation Application Rev. 2-17-2020 Page 3 of 9 VIII. INJECTION SUMMARY 1. List all proposed injectants/additives. NOTE: Only injectants approved by the epidemiology section of the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at http: //deq.nc.gov/about/divisions/water-re sources/water-resources-permits/wastewater-branch/ground-water- protection/ground-water-approved-injectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info if you wish to get approval for a different additive. However, please note it may take 3 months or longer. If no injectants are to be used use N/A. Injectant: ABC Total Amt. to be injected (gal)/event: 11,000 Injectant: ABC+ Total Amt. to be injected (gal)/event: 2,700 (from 3,000) Injectant: KB-1/KB-1 Plus Total Amt. to be injected (L)/event: 465 total (180 KB-1 /285 KB-1 Plus) (from 325 total) Injectant: Buffering - Magnesium Hydroxide Total Amt. to be injected (lb)/event: 4,500 (from 5,400) Injectant: Buffering — Sodium Bicarbonate Total Amt. to be injected (lb)/event: 51,000 (from 130,000) Injectant: Sodium Sulfite Total Amt. to be injected (lb)/event: 150 (from 287) Injectant: KB-1 Primer Total Amt. to be injected (lb)/event: 900 (from 1,200) Injectant: Dechlorinator Total Amt. to be injected (gal)/event: 0 gal (from 1.5) Total Amt. to be injected (gal/event): (reduced from 550,000 gal total) 325,000 2a1 of diluted ABC/ABC+ and anaerobic chase water No. of separate injection events: 1 Total Amt. to be injected (gal): 325,000 Source of Water (if applicable): On -site fire hydrant(s) 2. Estimated Injection rate per well: 4-8 GPM 3. Estimated Injection pressure: 5-100 pounds/square inch (PSI) 4. Temperature at point of injection: ambient °F 5. Injection will be via: Existing well(s)- Total No.: N/A ; Well Type (DPT, Permanent, etc.): N/A Proposed well(s)- Total No.: 102 (from 89) ; Well Type (DPT, Permanent, etc.): Temporary DPT 6. NC Certified Well Drilling Contractor's Name (if known): TBD NC Well Contractor Certification No.: TBD 7. Date to be constructed if proposed: As soon as possible (may be less than 2 months post -approval) (attach well construction records [GW-1s] for existing injection wells) 8. Screened interval/Injection interval of injection wells: Depth from 12 to 50 feet below land surface (BLS) (if multiple intervals, indicate shallowest to deepest depth) 9. Well casing (leave blank if Geoprobes®): Type (PVC, stainless steel, other): Casing depth: to ft. BLS Type (PVC, stainless steel, other): Groundwater Remediation Application Rev. 2-17-2020 Page 4 of 9 Casing depth: to ft. BLS 10. Grout (leave blank if Geoprobes): Type (cement, bentonite, other): Grout depth: to ft. BLS Type (cement, bentonite, other): Grout depth: to ft. BLS IX. ATTACHMENTS — provide the following information in separate attachments. The attachments should be clearly identified and presented in the order below to expedite review of the permit application package. 1. INJECTION ZONE — Per 15A NCAC 02C .0225(f)(3), specify the horizontal and vertical portion of the subsurface within which the proposed injection activity will take place and beyond which no violations of groundwater quality standards shall result from the injection as determined by an approved monitoring plan. The determination shall be based on the hydraulic properties of the specified zone. Provide any supporting documentation in a separate attachment. 2. HYDROGEOLOGIC EVALUATION — Per 15A NCAC 02C .0225(f)(4), provide a hydrogeologic evaluation of the injection zone that includes all of the following: (A) Regional and local geology and hydrology; (B) Changes in lithology underlying the facility; (C) Depth to bedrock; (D) Depth to the mean seasonal high water table; (E) Hydraulic conductivity, transmissivity, and storativity, of the injection zone based on tests of site -specific material, including a description of the test(s) used to determine these parameters; (F) Rate and direction of groundwater flow as determined by predictive calculations or computer modeling; (G) Lithostratigraphic and hydrostratigraphic logs of any existing test and injection wells; and (H) For systems re -injecting treated on -site contaminated groundwater only- evaluation of infiltration galleries or injection wells. 3. INJECTANT INFORMATION — Per 15A NCAC 02C .0225(0(6). provide information on each injectant as indicated below: (A) MSDS, concentration at the point of injection, and percentage if present in a mixture with other injectants; (B) The source of fluids used to dilute, carry, or otherwise distribute the injectant throughout the injection zone. If any well within the area of review of the injection facility is to be used as the fluid source, then the following information shall be submitted: location/ID number, depth of source, formation, rock/sediment type, and a chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site; (C) A description of the rationale for selecting the injectants and concentrations proposed for injection, including an explanation or calculations of how the proposed injectant volumes and concentrations were determined; (D) A description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; (E) A summary of results if modeling or testing was performed to investigate the injectant's potential or susceptibility for biological, chemical, or physical change in the subsurface; and (F) An evaluation concerning the development of byproducts of the injection process, including increases in the concentrations of naturally occurring substances. Such an evaluation shall include the identification of the specific byproducts of the injection process, projected concentrations of byproducts, and areas of migration as determined through modeling or other predictive calculations. Groundwater Remediation Application Rev. 2-17-2020 Page 5 of 9 4. INJECTION PROCEDURE — Per 15A NCAC 02C .0225(0(7). submit a table with a detailed description of the proposed injection procedure that includes the following: (A) The proposed average and maximum daily rate and quantity of injectant; (B) The average maximum injection pressure expressed in units of pounds per square inch (psi); and (C) The total or estimated total volume to be injected. 5. FRACTURING PLAN (if applicable) — Per 15A NCAC 02C .0225(f)(9), submit a detailed description of the fracturing plan that includes the following: (A) Material Safety Data Sheets of fracturing media including information on any proppants used; (B) a map of fracturing well locations relative to the known extent of groundwater contamination plus all buildings, wells, septic systems, underground storage tanks, and underground utilities located within the Area of Review; (C) a demonstration that buildings, wells, septic systems, underground storage tanks, and underground utilities will not be adversely affected by the fracturing process; (D) injection rate and volume; (E) orientation of bedding planes, joints, and fracture sets of the fracture zone; (F) performance monitoring plan for determining the fracture well radius of influence; and (G) if conducted, the results of geophysical testing or pilot test of fracture behavior conducted in an uncontaminated area of the site. 6. WELL CONSTRUCTION DETAILS — Per 15A NCAC 02C .0225(f)(10), submit the following information in tabular or schematic form as appropriate for each item: (A) number and depth of injection wells; (B) number and depth of borings if using multi -level or "nested" well systems; (C) indication whether the injection wells are existing or proposed; (D) depth and type of casing; (E) depth and type of screen material; (F) depth and type of grout; (G) indication whether the injection wells are permanent or temporary "direct push" points; and (H) plans and specifications of the surface and subsurface construction details. 7. MONITORING PLAN — Per 15A NCAC 02C .0225(f)(11). submit a monitoring plan that includes the following: (A) target contaminants plus secondary or intermediate contaminants that may result from the injection; (B) other parameters that may serve to indicate the progress of the intended reactions; (C) a list of existing and proposed monitoring wells to be used; and (D) a sampling schedule to monitor the proposed injection. Monitoring wells shall be of sufficient quantity and location to detect any movement of injection fluids, injection process byproducts, or formation fluids outside the injection zone. The monitoring schedule shall be consistent with the proposed injection schedule, pace of the anticipated reactions, and rate of transport of the injectants and contaminants. 8. WELL DATA TABULATION — Per 15A NCAC 02C .0225(0(12). provide a tabulation of data on all existing or abandoned wells within the area of review of the injection well(s) that penetrate the proposed injection zone, including monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's type, depth, and record of construction or abandonment. 9. MAPS AND CROSS -SECTIONS — Per 15A NCAC 02C .0225(f)(13), provide scaled, site -specific site plans or maps depicting the location, orientation, and relationship of facility components including the following: (A) area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site; (B) topographic contour intervals showing all facility related structures, property boundaries, streams, springs, lakes, ponds, and other surface drainage features; (C) all existing or abandoned wells within the area of review of the wells listed in the well data tabulation that penetrate the proposed injection zone; (D) potentiometric surface map(s) that show the direction of groundwater movement, existing and proposed wells; (E) contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, and existing and proposed wells; Groundwater Remediation Application Rev. 2-17-2020 Page 6 of 9 (F) cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, major changes in lithology, and existing and proposed wells; and (G) any existing sources of potential or known groundwater contamination, including waste storage, treatment, or disposal systems within the area of review of the injection well or well system. X. UIC SYSTEMS RE -INJECTING TREATED ON -SITE CONTAMINATED GROUNDWATER ONLY 1. FEES — Per 15A NCAC 02C .0225(m), submit/attach fees for new permits or modifications (refer to fee schedule at https://deq.nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/non-discharge-groundwater-remediation 2. SOILS EVALUATION - Per 15A NCAC 02C .0225(0(2), for systems with proposed discharge within seven feet of land surface and above the seasonal high water table, a soil evaluation of the disposal site shall be provided to the Division by the applicant. If required by G.S. 89F, a soil scientist shall submit this evaluation. This evaluation shall be presented in a report that includes the following information: (A) Field description of soil profile. Based on examinations of excavation pits or auger borings, the following parameters shall be described by individual horizons to a depth of seven feet below land surface or to bedrock: thickness of the horizon; texture; color and other diagnostic features; structure; internal drainage; depth, thickness, and type of restrictive horizons; pH; cation exchange capacity; and presence or absence of evidence of any seasonal high water table. Applicants shall dig pits when necessary for evaluation of the soils at the site. (B) Recommendations concerning annual and instantaneous loading rates of liquids, solids, other wastewater constituents and amendments. Annual hydraulic loading rates shall be based on in -situ measurement of saturated hydraulic conductivity in the most restrictive horizon. 3. ENGINEERING PLANNING DOCUMENTS — Per 15A NCAC 02C .0225(0(8), the following documents shall be provided to the Division by the applicant (Note: if required by G.S. 89C, a professional engineer shall prepare these documents): (A) engineering plans for the entire system, including treatment, storage, application, and disposal facilities and equipment, except those previously permitted unless they are directly tied into the new units or are critical to the understanding of the complete process; (B) specifications describing materials to be used, methods of construction, and means for ensuring quality and integrity of the entire groundwater remediation system; (C) plans that include construction details of recovery, injection, and monitoring wells and infiltration galleries; (D) operating plans that include: (i) the operating schedule including any periodic shut -down times; (ii) required maintenance activities for all structural and mechanical elements; (iii) a list of all consumable and waste materials with their intended source and disposal locations; (iv) restrictions on access to the site and equipment; (v) provisions to ensure the quality of the treated effluent and hydraulic control of the system at all times when any portion of the system ceases to function, such as standby power capability, complete system -off status, or duplicity of system components; and (E) Completed, signed, and sealed Professional Engineer's Certification for new permit applications (form attached). Groundwater Remediation Application Rev. 2-17-2020 Page 7 of 9 XII. CERTIFICATION (to be signed as required below or by that person's authorized agent*) NCAC 15A 02C .021 1(e) requires that all permit applications shall be signed as follows: 1. for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor, respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. *If an authorized agent is signing on behalf' of the applicant, then supply a letter signed by the applicant that names and authorizes their agent. "l hereby certify under penalty of law that l have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my ins/llir.y of those indii'iduals immediately responsible for obtaining said information, / believe that the information is true, accurate. and complete. 1 can aware that there are penalties, including the possibility of fines and imprisonment, for submitting false information. / agree to construct, operate, maintain, repair, and if applicable, abandon the Injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit." Typed or Printed/Nan) and Tij e: J) RAell E. Eller, Director, Global EHS Compliance Signature: Date: November 04, 2021 XIII. CONSENT OF PROPERTY OWNER (if the property is not owned by the permit applicant) "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contra►y agreement in writing. "As owner of the property on which the injection well(s) are to be constructed and operated, / hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (I SA NCAC 02C .0200)." Typed or Printed Name and Title: (De n ��r? �. C�E" Signature: Date: / /// 1/a")_2 Submit TWO hard copies of the completed application package with an electronic version in CD or USB Flash Drive to: DIVISION OF WATER RESOURCES — UIC PROGRAM 1636 MAIL SERVICE CENTER RALEIGH, NORTH CAROLINA 27699-1636 TELEPHONE NUMBER: (919) 707-9000 Groundwater Re►nediation Application Rev. 2-17-2020 Page $ of 9 Professional Engineer's Certification (for new permit application for UIC systems re -injecting treated on -site contaminated groundwater on : Permit No.: NOT APPLICABLE Typed or Printed Name of Professional Engineer: License Number: Name of Engineering Firm (if applicable): Mailing Address: City: State: Zip: Office Number: ( ) Mobile Number: ( ) Email Address: attest that this application for has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. North Carolina Professional Engineer's Seal, Signature, and Date: Groundwater Remediation Application Rev. 2-17-2020 Page 9 of 9 1. INJECTION ZONE — Per 15A NCAC 02C .0225(f)(3), specify the horizontal and vertical portion of the subsurface within which the proposed injection activity will take place and beyond which no violations of groundwater quality standards shall result from the injection as determined by an approved monitoring plan. The determination shall be based on the hydraulic properties of the specified zone. Provide any supporting documentation in a separate attachment. Modification description: All locations where Middle and Lower Aquifers will be treated were modified such that they will be completed using separate boreholes (i.e., one borehole for Middle Aquifer and a second borehole for Lower Aquifer). This increased the number of separate injection locations from 89 to 102. This modification did not result in appreciable changes to injection locations and the overall injection footprint. The general injection areas are provided on Figure 5, attached (Geosyntec, 2021b) and the specific injection locations are provided on Figures 6 through 7, attached (Geosyntec, 2021b). These figures do not provide vertical extents of the injection locations. Tables 3 and 4, attached (Geosyntec, 2021b) provide proposed injection intervals for each injection location. Table 3. Injection Location Coordinates and Treatment Intervals Allegion Rocky Mount Rocky Mount, North Carolina Geosyntec ° consultants Geosyntec Consultants of NC, P.C. Injection Area DPT Injection Location ID Target Aquifer(s) ZVI? Treatment Interval (ft BLS) Monitoring Well(s) Used for Design Primary PCE Concentration(s) (µg/L) Notes High Concentration Injection Locations High Concentration Area 1 (HC1) HC1-01 Middle / Lower 18 to 32 / 40 to 50 MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-02 Middle / Lower 18 to 32 / 38 to 50 MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-03 Middle / Lower MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-04 Middle / Lower MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-05 Middle / Lower 14 to 36 / 40 to 50 MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-06 Middle / Lower MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer High Concentration Area2 (HC2) HC2-01 Middle ✓ 16 to 32 MW-75S 103,000 HC2-02 Middle ✓ MW-75S 103,000 HC2-03 Middle ✓ MW-75S 103,000 HC2-04 Middle ✓ MW-75S 103,000 HC2-05 Middle ✓ MW-75S 103,000 HC2-06 Middle ✓ MW-75S 103,000 HC2-07 Middle ✓ MW-75S 103,000 HC2-08 Middle ✓ MW-75S 103,000 HC2-09 Middle ✓ MW-75S 103,000 HC2-10 Middle ✓ MW-75S 103,000 HC2-11 Middle ✓ MW-75S 103,000 HC2-12 Middle 19 to 31 MW-75S 103,000 HC2-13 Middle MW-75S 103,000 HC2-14 Middle MW-75S 103,000 HC2-15 Middle MW-75S 103,000 HC2-16 Middle 22 to 36 MW-22 6,550 HC2-17 Middle MW-22 6,550 HC2-18 Middle MW-22 6,550 HC2-19 Middle MW-75S 103,000 HC2-20 Middle 21 to 33 MW-75S 103,000 HC2-21 Middle MW-75S 103,000 HC2-22 Middle MW-75S 103,000 HC2-23 Middle MW-76S 5,630 HC2-24 Middle MW-76S 5,630 HC2-25 Middle 19 to 31 MW-76S 5,630 HC2-26 Middle MW-75S 103,000 HC2-27 Middle MW-75S 103,000 HC2-28 Middle MW-75S 103,000 HC2-29 Middle MW-75S 103,000 HC2-30 Middle MW-75S 103,000 High Concentration Area 3 (HC3) HC3-01 Middle ✓ 16 to 30 MW-78S 22,800 HC3-01 Lower 34 to 50 MW-78D 8,900 Lower injection interval at HC3-01 will not receive ZVI HC3-02 Middle .716 to 30 MW-78S 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer Lower 34 to 50 MW-78D HC3-03 Middle / Lower ✓ 16 to 30 / 34 to 50 MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-04 Middle / Lower ✓ MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-05 Middle 18 to 30 MW-78S 22,800 HC3-06 Middle MW 78S 22,800 HC3-07 Middle 18 to 30 MW-78S 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer Lower ✓ 34 to 50 MW-78D HC3-08 Middle / Lower 18 to 30 / 34 to 50 MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-09 Middle / Lower MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-10 Middle / Lower MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-11 Middle 17 to 29 MW-78S 22,800 HC3-12 Middle MW-78S 22,800 HC3-13 Middle MW-78S 22,800 HC3-14 Middle MW-58S 5,400 HC3-15 Middle MW-58S 5,400 High Concentration Area 4 (HC4) HC4-01 Lower 26 to 46 MW-30 3,260 HC4-02 Lower MW-30 3,260 HC4-03 Lower MW-30 3,260 Downgradient Injection Locations Downgradient Area 1 (DGl) DG1-01 Middle 12 to 22 MW-37S 474 DG1-02 Middle MW-37S 474 DG1-03 Middle 12 to 22 MW-37S 474 DG1-04 Middle MW-37S 474 DG1-05 Middle 12 to 24 MW-37S 474 DG1-06 Middle / Lower 12 to 22 / 25 to 41 MW-37S / MW-47D 474 / 99.7 Separate injection locations for Middle and Lower Aquifer DG1-07 Middle / Lower MW-37S / MW-47D 474 / 99.7 Separate injection locations for Middle and Lower Aquifer DG1-08 Middle / Lower MW-37S / MW-47D 474 / 99.7 Separate injection locations for Middle and Lower Aquifer DG1-09 Middle / Lower MW-37S / MW-47D 474 / 99.7 Separate injection locations for Middle and Lower Aquifer DG1-10 Middle 12 to 22 MW-37S 474 DG1-11 Middle MW-37S 474 DG1-12 Middle MW-37S 474 DG1-13 Middle MW-37S 474 DG1-14 Middle MW-37S 474 Downgradient Area 2 ) DG2-01 Lower 35 to 45 MW-74D 86.6 DG2-02 Lower MW-74D 86.6 DG2-03 Lower MW-74D 86.6 DG2-04 Lower MW-74D 86.6 Downgradient Area 3 (DG3) DG3-01 Lower 38 to 50 MW-41DDR 377 DG3-02 Lower MW-41DDR 377 DG3-03 Lower MW-41DDR 377 DG3-04 Lower MW-41DDR 377 DG3-05 Lower MW-41DDR 377 DG3-06 Lower MW-41DDR 377 DG3-07 Lower MW-41DDR 377 DG3-08 Lower MW-41DDR 377 DG3-09 Lower MW-70D 172 DG3-10 Lower 40 to 50 MW-70D 172 DG3-11 Lower MW-70D 172 DG3-12 Lower MW-70D 172 Notes: 1. ft BLS indicates feet below land surface. 2. DPT indicates direct push technology. 3. PCE indicates tetrachloroethene. 4. µg/L indicates micrograms per liter. 5. ✓ indicates zero-valent iron (ZVI) is included at the location. No fill indicates ZVI will not be included. 6. Primary PCE Concentration(s) provides the most recent PCE sampling result (as of February 2021) for the monitoring well(s) used for design. 7. All locations will be confirmed in the field, based on nearby monitoring wells. 2021 Bioremediation Interim Measures Workplan Page 1 of 1 Table 4. Injection Location Volumes Allegion Rocky Mount Rocky Mount, North Carolina Geasyntec° consultants IP : ("un%Pl[nnb nl NC. PC ABC+* Amendment Injection Locations (includes ZVI) Per 2-ft Injection Interval Per Injection Location Target Aquifer Injection Area Injection Locations Treatment Interval (ft BLS) Injection Interval (ft BLS) Target ROI (ft) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) High Concentration Area - 0.3 lb of Carbon Amendment per ft3 of Treatment Volume Middle Aquifer HC2 HC2-01, HC2-02, HC2-03, HC2-04, HC2-05, HC2-06, HC2-07, HC2-08, HC2-09, HC2-10, HC2-11 16 to 32 16 to 18 14 283 109 0.65 2.264 872 5.20 18 to 20 14 283 109 0.65 20 to 22 14 283 109 0.65 22 to 24 14 283 109 0.65 24 to 26 14 283 109 0.65 26 to 28 14 283 109 0.65 28 to 30 14 283 109 0.65 30 to 32 14 283 109 0.65 HC3 HC3-01, HC3-02, HC3-03, HC3-04 16 to 30 16 to 18 14 284 108 0.65 1.988 756 4.55 18 to 20 14 284 108 0.65 20 to 22 14 284 108 0.65 22 to 24 14 284 108 0.65 24 to 26 14 284 108 0.65 26 to 28 14 284 108 0.65 28 to 30 14 284 108 0.65 Lower Aquifer HC3 HC3-03, HC3-04, HC3-07 34 to 50 34 to 36 14 288 105 0.65 2.304 840 5.20 36 to 38 14 288 105 0.65 38 to 40 14 288 105 0.65 40 to 42 14 288 105 0.65 42 to 44 14 288 105 0.65 44 to 46 14 288 105 0.65 46 to 48 14 288 105 0.65 48 to 50 14 288 105 0.65 ABC® Amendment Injection Location (no ZVI) OM Per 2-ft Injection Interval Per Injection Location Target Aquifer Injection Area Injection Locations Treatment Interval (ft BLS) Injection Interval (ft BLS) Target ROI (ft) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) High Concentration 0.3 lb of Carbon Amendment per fe of Treatment Volume Middle Aquifer HCl HC1-01,HC1-02, HC1-03,HC1-04 188032 18 to 20 14 379 83 0.65 2,653 581 4.55 20 to 22 14 379 83 0.65 22 to 24 14 379 83 0.65 24 to 26 14 379 83 0.65 26 to 28 14 379 83 0.65 28 to 30 14 379 83 0.65 30 to 32 14 379 83 0.65 HC1 HC1-05,HC1-06 14to36 14 to 16 14 382 79 0.65 4.202 869 7.15 16 to 18 14 382 79 0.65 18 to 20 14 382 79 0.65 20 to 22 14 382 79 0.65 22 to 24 14 382 79 0.65 24 to 26 14 382 79 0.65 26 to 28 14 382 79 0.65 28 to 30 14 382 79 0.65 30 to 32 14 382 79 0.65 32 to 34 14 382 79 0.65 34 to 36 14 382 79 0.65 HC2 HC2-12, HC2-13, HC2-14, HC2-15, HC2-25, HC2-26, HC2-27, HC2-28, HC2-29, HC2-30 19 to 31 19 to 21 14 377 84 0.65 2.262 504 3.90 21 to 23 14 377 84 0.65 23 to 25 14 377 84 0.65 25 to 27 14 377 84 0.65 27 to 29 14 377 84 0.65 29 to 31 14 377 84 0.65 HC2 HC2-16, HC2-17, HC2-18, HC2-19 22 to 36 22 to 24 14 379 83 0.65 2,653 581 4.55 24 to 26 14 379 83 0.65 26 to 28 14 379 83 0.65 28 to 30 14 379 83 0.65 30 to 32 14 379 83 0.65 32 to 34 14 379 83 0.65 34 to 36 14 379 83 0.65 HC2 HC2-20, HC2-21, HC2-22, HC2-23, HC-24 21 to 33 21 to 23 14 380 81 0.65 2,280 486 3.90 23 to 25 14 380 81 0.65 25 to 27 14 380 81 0.65 27 to 29 14 380 81 0.65 29 to 31 14 380 81 0.65 31 to 33 14 380 81 0.65 HC3 HC3-05, HC3-06, HC3-07, HC3-08 HC3-09, HC3-10 18 to 30 18 to 20 14 378 83 0.65 2,268 498 3.90 20 to 22 14 378 83 0.65 22 to 24 14 378 83 0.65 24 to 26 14 378 83 0.65 26 to 28 14 378 83 0.65 28 to 30 14 378 83 0.65 HC3 HC3-11, HC3-12, HC3-13, HC3-14, HC3-15 17 to 29 17 to 19 14 380 81 0.65 2,280 486 3.90 19 to 21 14 380 81 0.65 21 to 23 14 380 81 0.65 23 to 25 14 380 81 0.65 25 to 27 14 380 81 0.65 27 to 29 14 380 81 0.65 2021 Bioremediation Interim Measures Workplan Page 1 of 2 Table 4. Injection Location Volumes Allegion Rocky Mount Rocky Mount, North Carolina Geasyntec° consultants 1, Ic+� ConsRltnnb nl NC. PC ABC® Amendment Injection Location (no ZVI) Per 2-ft Injection Interval Per Injection Location Target Aquifer Injection Area Injection Locations Treatment Interval (ft BLS) Injection Interval (ft BLS) Target ROI (ft) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) High Concentration 0.3 Ib of Carbon Amendment per ftS of Treatment Volume Lower Aquifer HC1 HC1-01,HC1-O5, HC1-06 40 to 50 40 to 42 14 387 74 0.65 1,935 370 3.25 42 to 44 14 387 74 0.65 44 to 46 14 387 74 0.65 46 to 48 14 387 74 0.65 48 to 50 14 387 74 0.65 HCl HC1-02,HC1-03, HC1-04 38to50 38 to 40 14 378 83 0.65 2,268 498 3.90 40 to 42 14 378 83 0.65 42 to 44 14 378 83 0.65 44 to 46 14 378 83 0.65 46 to 48 14 378 83 0.65 48 to 50 14 378 83 0.65 HC3 HC3-01, HC3-02,40 HC3-08 HC3-09, HC3-10 34 to 50 34 to 36 14 380 81 0.65 3.040 648 5.20 36 to 38 14 380 81 0.65 38 to 40 14 380 81 0.65 to 42 14 380 81 0.65 42 to 44 14 380 81 0.65 44 to 46 14 380 81 0.65 46 to 48 14 380 81 0.65 48 to 50 14 380 81 0.65 HC4 HC4-01, HC4-02, HC4-03 26 to 46 26 to 28 14 380 81 0.65 3,800 810 6.50 28 to 30 14 380 81 0.65 30 to 32 14 380 81 0.65 32 to 34 14 380 81 0.65 34 to 36 14 380 81 0.65 36 to 38 14 380 81 0.65 38 to 40 14 380 81 0.65 40 to 42 14 380 81 0.65 42 to 44 14 380 81 0.65 44 to 46 14 380 81 0.65 Downgradient Area - 0.30 Ib of Carbon Amendment per ft3 of Treatment Volume Middle Aquifer DG1 DG1-05 12 to 24 12 to 14 14 467 110 0.80 2.802 660 4.80 14 to 16 14 467 110 0.80 16 to 18 14 467 110 0.80 18 to 20 14 467 110 0.80 20 to 22 14 467 110 0.80 22 to 24 14 467 110 0.80 DG1 DG1-01, DG1-02, DG1-03, DG1-04, DG1-06, DG1-07, DG1-08, DG1-09, DG1-10, DG1-11, DG1-12, DG1-13, DG1-14 12 to 22 12 to 14 14 465 112 0.80 2.325 560 4.00 14 to 16 14 465 112 0.80 16 to 18 14 465 112 0.80 18 to 20 14 465 112 0.80 20 to 22 14 465 112 0.80 Lower Aquifer DG1 DG1-06, DG1-07, DG1-08, DG1-09 25 to 41 25 to 27 14 475 101 0.80 3.800 808 6.40 27 to 29 14 475 101 0.80 29 to 31 14 475 101 0.80 31 to 33 14 475 101 0.80 33 to 35 14 475 101 0.80 35 to 37 14 475 101 0.80 37 to 39 14 475 101 0.80 39 to 41 14 475 101 0.80 DG235 DG2-01, DG2-02, DG2-03, DG2-04 to 45 35 to 37 14 470 106 0.80 2,350 530 4.00 37 to 39 14 470 106 0.80 39 to 41 14 470 106 0.80 41 to 43 14 470 106 0.80 43 to 45 14 470 106 0.80 DG3 DG3-01, DG3-02, DG3-03, DG3-04, DG3-05, DG3-06, DG3-07, DG3-08, DG3-09 38 to 50 38 to 40 14 474 102 0.80 '.844 612 4.80 40 to 42 14 474 102 0.80 42 to 44 14 474 102 0.80 44 to 46 14 474 102 0.80 46 to 48 14 474 102 0.80 48 to 50 14 474 102 0.80 DG3 DG3-10, DG3-11, DG3-12 40 to 50 40 to 42 14 467 110 0.80 2,335 550 4.00 42 to 44 14 467 110 0.80 44 to 46 14 467 110 0.80 46 to 48 14 467 110 0.80 48 to 50 14 467 110 0.80 Notes: 1. ft BLS indicates feet below land surface. 2. gal indicates gallons. 3. ZVI indicates zero-valent iron. 4. Ib indicates pound. 5. ft' indicates cubic foot. 6. KB-1 Volume refs to the volume ofbioaugmentation culture required. See Work Plan for details on the selection of KB-1 versus KB-1 Plus by location. 2021 Bioremediation Interim Measures Workplan Page 2 of 2 3. INJECTANT INFORMATION— Per 15A NCAC 02C .0225(0(6). provide information on each injectant as indicated below: (A) MSDS, concentration at the point of injection, and percentage if present in a mixture with other injectants; (B) The source of fluids used to dilute, carry, or otherwise distribute the injectant throughout the injection zone. If any well within the area of review of the injection facility is to be used as the fluid source, then the following information shall be submitted: location/ID number, depth of source, formation, rock/sediment type, and a chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site; (C) A description of the rationale for selecting the injectants and concentrations proposed for injection, including an explanation or calculations of how the proposed injectant volumes and concentrations were determined; (D) A description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; (E) A summary of results if modeling or testing was performed to investigate the injectant's potential or susceptibility for biological, chemical, or physical change in the subsurface; and (F) An evaluation concerning the development of byproducts of the injection process, including increases in the concentrations of naturally occurring substances. Such an evaluation shall include the identification of the specific byproducts of the injection process, projected concentrations of byproducts, and areas of migration as determined through modeling or other predictive calculations. Modification description: Modifications to the injectants are summarized below. • The concentration of ABC+/ABC at the point of injection has been modified as shown below: Treatment Area Aquifer Carbon Amendment Diluted Carbon Amendment Concentration (lb/gal) ZVI ZVI Concentration (lb/gal) High Concentration Middle ABC+ 0.55 ZVI 0.55 Lower 0.55 ZVI 0.55 Middle ABC 0.41 -- -- Lower 0.41 -- -- Downgradient Middle ABC 0.41 -- -- Lower 0.41 -- -- • KB-1 and KB-1 Plus will be applied at a concentration of approximately 0.0014 to 0.0017 L of KB-1/KB-1 Plus per gal of injection solution. o Note that KB-1 Plus was included in the initial UIC permit application but was not included in the executed permit because it was not an improved injectate. KB-1 Plus has since become an approved injectate. Its SDS has been reattached. • KB-1 Primer will be applied at a concentration of 0.00175 lb/gal or 0.0071b/gal for diluted electron donor or anaerobic chase water, respectively. o Note that KB-1 Primer was included in the initial UIC permit application but was not included in the executed permit because it was not an improved injectate. KB-1 Primer has since become an approved injectate. Its SDS has been reattached. • Sodium sulfite will be applied at a concentration of 0.00053 lb/gal. • Sodium bicarbonate will be applied at a concentration of approximately 0.073 to 0.5721b/gal depending on the injection interval and location. • Magnesium hydroxide will be applied at a concentration of 0.021 to 0.131 lb/gal depending on the injection interval. • A revision of Appendix F (Electron Donor Dosing and Injection Volume Calculations and KB-1 Bioaugmentation Dosing) is provided (A) The following is a summary of concentrations of the primary injectant materials at the point of injection: Treatment Area Aquifer Carbon Amendment Diluted Carbon Amendment Concentration (lb/gal) ZVI ZVI Concentration (lb/gal) High Concentration Middle ABC+ 0.55 ZVI 0.55 Lower 0.55 ZVI 0.55 Middle ABC 0.21 -- -- Lower 0.21 -- -- Downgradient Middle ABC 0.21 -- -- Lower 0.21 -- -- ABC refers to the product Anaerobic Biochem (ABC®) by Redox Tech, LLC. ABC+ is a mixture of ABC and zero-valent iron (ZVI). ZVI and ABC will be mixed at a 1:1 basis by weight. Safety Data Sheets (SDSs) for primary injectant materials (ABC and ZVI) are attached. Information sheets for these materials are also attached. KB-1 Primer will be applied at a 0.2-0.8 kg to 250-gal ratio for diluted electron donor or anaerobic chase water. Information sheets for these materials are also attached. (B) Source water will be obtained from the onsite fire hydrant, provided approval or the appropriate applications or permits from the City of Rocky Mount. (C) See attached Appendix F (Electron Donor Dosing and Injection Volume Calculations and KB-1 Bioaugmentation Dosing) for details on the ABC/ABC+ and KB-1/KB-1 Plus dosing calculations (Geosyntec, 2021b). ABC was selected as the primary injectant because it has previously been used on site for the same purpose and was successful in remediating tetrachloroethene (PCE) impacts. ABC+ (ABC and ZVI mixture) was selected to treat select areas with elevated PCE concentrations, as ZVI promotes anaerobic biodegradation and reductive dechlorination of halogenated solvents in groundwater. The ZVI enables immediate reduction by providing short and long-term nutrients to anaerobic growth. ABC/ABC+ dosing was were adjusted based on the PCE concentrations (higher concentration areas received higher dosing). (D) The primary contaminant of concern is PCE. Using ABC/ABC+, degradation of chlorinated volatile organic compounds (CVOCs) begins via dechlorination. Degradation rates using ZVI are orders of magnitude greater than natural conditions, thus the degradation of CVOCs does not result in the formation ethane, ethane, and methane. Ethyl lactate converts to ethanol and lactic acid through hydrolysis. The following describes the elimination pathway prompted by ABC+ (ABC with ZVI) and ABC, respectively: 13 -elimination = TCE 4 chloroacetylene 4 acetylene 4 ethane Hydrogenolysis Pathway = TCE 4 cis-DCE 4 vinyl chloride 4 ethene 4 ethane (E) N/A (F) There is potential for these technologies to generate secondary impacts, such as increased concentrations of methyl ethyl ketone (MEK) in impacted injection areas. During the previous bioremediation implementation at the Site (2007 to 2008, which utilized ABC), elevated MEK concentrations were observed in a single monitoring well. Concentrations of MEK typically attenuate rapidly to background concentrations (Fowler, et. al, 2011). MEK concentrations will be monitored, as shown in the attached proposed Performance Monitoring Plan (Geosyntec, 2021b). SiREM Leading Science • Lasting Solutions KB-1® Plus Material Safety Data Sheet Section 1: Material Identification Trade Name: KB-16Plus Chemical Family: bacterial mixture Chemical name: No IUC name for mixture is known to exist Manufacturer/Supplier: SiREM 130 Research Lane, Suite 2, Guelph, Ontario, Canada N 1 G 5G3 For Information call: 519-822-2265 / 1-866-251-1747 x236 Emergency Number: 519-822-2265 Description: Microbial inoculum (non-pathogenic, non -hazardous) Trade Name: KB-1° Plus Product Use: Bioremediation of contaminated groundwater. Date Prepared: 23 October 2008 130 Research Lane, Ste 2 Guelph ON N1G 5G3 (519) 822-2265 Section 2: Composition, Information on Ingredients KB1® Plus is a microbial culture grown in a dilute aqueous mineral salt solution media containing no hazardous ingredients. The microbial composition of KB-1°Plus is listed in Table 1. Table 1. Major Microbial Groups Identified in KB-1® Plus Microbial Inoculum Dehalococcoides sp. Geobacter sp. Methanomethylovorans sp. Dehalobacter sp. Dehalogenimonas sp. Section 3: Hazards Identification: A review of the available data does not indicate any known health effects related to normal use of this product. Section 4: First Aid Measures: Avoid direct contact with skin and eyes. In any case of any exposure which elicits a response, a physician should be consulted immediately. Eye Contact: Flush eyes with water for at least 15 minutes, occasionally lift upper and lower eyelids, if undue irritation or redness occurs seek medical attention. Skin Contact: Remove contaminated clothing and wash skin thoroughly with water and antibacterial soap. Seek medical attention if irritation develops or open wounds are present. 1�(�T B.1' siremlab.com 1/3 SiREM Ingestion: Do not induce vomiting, drink several cups of water, seek medical attention. Inhalation: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen. Call a physician. Section 5 - Fire Fighting Measures: Non-flammable Flash Point: not applicable Upper flammable limit: not applicable Lower flammable limit: not applicable Section 6 — Accidental Release Procedures Spilled KB-1® Plus should be soaked up with sorbant and saturated with a 10% bleach solution (prepared by making a one in ten dilution of diluted standard bleach [normally sold at a strength of 5.25% sodium hypochlorite] to disinfect affected surfaces. Sorbant should be double bagged and disposed of as indicated in section 12. After removal of sorbant, area should be washed with 10% bleach solution to disinfect. If liquid from the culture vessel is present on the fittings, non -designated tubing or exterior of the stainless steel pressure vessel liquid should be wiped off and the area washed with 10% bleach solution. Section 7 - Handling and Storage KB-1® Plus is shipped in stainless steel pressure vessels in a protective over pack. KB-1® Plus should be handled with care to avoid any spillage. Vessels are shipped with 1 pound per square inch (psi) pressure; valves should not be opened until connections to appropriate lines for subsurface injection are in place. Storage Requirements: Avoid exposing stainless steel pressure vessels to undue temperature extremes (i.e., temperatures less than 0°C or greater than 30°C may result in harm to the microbial cultures and damage to the vessels). All valves should be in the closed position when the vessel is not pressurized or not in use to prevent the escape of gases and to maintain anaerobic conditions in the vessel. Avoid exposure of the culture to air as the presence of oxygen will kill dechlorinating microorganisms. Section 8 - Exposure Controls/Personal Protection Personal protective equipment: Skin: Protective gloves (latex, vinyl or nitrile) should be worn. Eye Protection: Wear appropriate protective eyeglasses or goggles when opening pressure vessels, valves, or when pressurizing vessels to inject contents into the subsurface. Respiratory: No respiratory protection is required. Engineering Controls: Good general room ventilation is expected to be adequate. Section 9: Physical and Chemical Properties: Physical State: liquid Odour: skunky odour Appearance: dark grey, slightly turbid liquid under anaerobic conditions, pink if exposed to air (oxygen). Specific gravity: 1 Vapor pressure: not applicable Vapor density: not applicable Evaporation rate: not determined Boiling point: —100° C Freezing point/melting point: — 0°C KM' I si• remlab.com 2/3 SiREM pH: 6.5-7.5 Solubility: fully soluble in water Section 10 — Stability and Reactivity Data Stable and non -reactive. Maintain under anaerobic conditions to preserve product integrity. Materials to avoid: none known Section 11 - Toxicological Information Potential for Pathogenicity: KB1® Plus has tested negative (i.e., the organisms are not present) for a variety of pathogenic organisms listed in Table 2. While there is no evidence that virulent pathogenic organisms are present in KB-1° Plus, there is potential that certain organisms in KB-1® Plus may have the potential to act as opportunistic (mild) pathogens, particularly in individuals with open wounds and/or compromised immune systems. For this reason standard hygienic procedures such as hand washing after use should be observed. Table 2, Results of Human Pathogen Screening of KB-1°Plus Organism Disease(s) Caused Test result Salmonella sp. Typhoid fever, gastroenteritis Not Detected Listeria monocytogenes Listerioses Not Detected Vibrio sp., Cholera, gastroenteritis Not Detected Campylobacter sp., Bacterial diarrhea Not Detected Clostridia sp., Food poisoning, Botulism, tetanus, gas gangrene Not Detected Bacillus anthracis Anthrax Not Detected Pseudomonas aeruginosa Wound infection Not Detected Yersinia sp., Bubonic Plague, intestinal infection Not Detected Yeast and Mold Candidiasis, Yeast infection etc. Not Detected Fecal coliforms Indicator organisms for many human pathogens diarrhea, urinary tract infections Not Detected Enterococci Various opportunistic infections Not Detected Section 12. Disposal Considerations Material must be disinfected or sterilized prior to disposal. Consult local regulations prior to disposal. Section 13 — Transport Information Non -hazardous, non-pathogenic microbial inoculum Chemicals, Not Otherwise Indexed (NOI), Non -hazardous Not subject to TDG or DOT guidelines. Disclaimer: The information provided on this MSDS sheet is based on current data and represents our opinion based on the current standard of practice as to the proper use and handling of this product under normal, reasonably foreseeable conditions. Last revised: 12 June 2012 FJi"I m I si• remlab.com 3/3 "SiREM SAFETY DATA SHEET KB-1® Primer Prepared according to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Union REACH Regulations SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION 1.1 PRODUCT NAME: PRODUCT CODE: CHEMICAL FAMILY NAME: U.N. NUMBER: U.N. DANGEROUS GOODS CLASS: 1.2 PRODUCT USE: 1.3 SUPPLIER/MANUFACTURER'S NAME: ADDRESS: 1.4 EMERGENCY PHONE: BUSINESS PHONE: WEB SITE: 1.5 DATE OF PREPARATION: DATE OF LAST REVISION: KB-1® Primer N/A Mixture None Not Regulated For preparation of anaerobic water for use in groundwater remediation. KB1® products are intended for laboratory research and field applications for groundwater remediation, and are not intended to be used as human or animal therapeutics, cosmetics, agricultural or pesticidal products, food additives, or as household chemicals. SiREM 130 Stone Road, West, Guelph, Ontario Canada N1G 3Z2 519-515-0840 519-515-0840 (Product Information) www.siremlab.com December 05, 2018 New SECTION 2 - HAZARDS IDENTIFICATION 2.1 Classification of the mixture: This product does meet the definition of a hazardous substance or preparation as defined by 29 CFR 1910. 1200 AND the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC, 2015/830/EU and subsequent Directives. Component(s) Contributing to Classification(s) L-Cysteine 2.2 GHS Label elements, including precautionary statements: Pictogram(s): None applicable. Signal Word: Warning! GHS Hazard Classification(s): Acute Toxicity Category 5 (Oral) Hazard Statement(s): H303: May be harmful if swallowed Prevention Statement(s): None Applicable Response Statement(s): P312: Call a POISON CENTER/doctor if you feel unwell. Storage Statement(s): None Applicable Disposal Statement(s): None Applicable. 2.3 Other Hazards: This mixture does not meet the criteria for PBT or vPvB in accordance with Annex VII. December 2018 Page 1 of 8 KB-1 PRIMER siremlab.com •• SiREM SAFETY DATA SHEET KB-1® Primer SECTION 3 - COMPOSITION and INFORMATION ON INGREDIENTS 3.1 Substances: Not applicable 3.2 Mixtures: HAZARDOUS INGREDIENTS: CAS # EINECS # Index # WT % GHS CLASSIFICATION L-Cysteine 52-90-4 200-158-2 Not Listed 1-10% ACUTE TOX. CAT 4 (ORAL) Balance of other ingredients are non -hazardous or hazardous below the applicable cut-off level. Additional Information: See SECTION 16 for full classification phrases. SECTION 4 - FIRST -AID MEASURES 4.1 Description of first aid measures: Contaminated individuals of chemical exposure must be taken for medical attention if any adverse effect occurs. Rescuers should be taken for medical attention, if necessary. Take copy of label and SDS to health professional with contaminated individual. EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for at least 15 minutes. Seek medical attention if irritation persists. SKIN CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists. Remove contaminated clothing. Launder before re -use. INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention. INGESTION: If product is swallowed, call physician or poison control center for most current information. If professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or SDS with the victim to the health professional. 4.2 Most important symptoms and effects, both acute and delayed: May be harmful if swallowed. See section 11 for additional information. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing skin problems may be aggravated by prolonged or repeated contact. 4.3 Indication of immediate medical attention and special treatment needed: Treat symptoms and reduce over -exposure. SECTION 5 - FIRE -FIGHTING MEASURES 5.1 Extinguishing media: Use media suitable for surrounding area. Carbon dioxide, foam, dry chemical, halon, water spray. 5.2 Specific hazards arising from the chemical: No data available for this product. Explosion Sensitivity to Mechanical Impact: Not Sensitive. Explosion Sensitivity to Static Discharge: Not Sensitive Minimum Ignition Energy (M.I.E.) No Data at this time 5.3 Special firefighting Procedure: Incipient fire responders should wear eye protection. Structural firefighters must wear Self -Contained Breathing Apparatus and full protective equipment. Isolate materials not yet involved in the fire and protect personnel. Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. December 2018 Page 2 of 8 KB-1 PRIMER siremlab.com •• SiREM SAFETY DATA SHEET KB-1® Primer SECTION 6 - ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without suitable training. Do not touch or walk through spilled material. Avoid breathing dust. Provide adequate ventilation. Use appropriate respirator when ventilation is inadequate and use personal protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on health hazards. 6.2 Environmental precautions: No specific data available for this product. 6.3 Methods and material for containment and cleaning up: Wear suitable protective clothing. Avoid dust formation. Avoid breathing dust. Carefully sweep up and remove. Place material in a dry container and cover. Remove from the area. Flush spill area with water. Do not let products enter drains. Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13, Disposal Considerations). SECTION 7 - HANDLING and STORAGE 7.1 Precautions for safe handling: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Use in a well -ventilated location. Remove contaminated clothing immediately 7.2 Conditions for safe storage, including any incompatibilities: Store in a tightly sealed container in a cool, dry and well -ventilated place. Store away from direct light. Avoid generation of dust. Do not breathe dust. Wash thoroughly after handling. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Segregate from strong oxidizing agents, acids, bases. 7.3 Specific end uses: See section 1.2. SECTION 8 - EXPOSURE CONTROLS - PERSONAL PROTECTION 8.1. Control parameters: EXPOSURE LIMITS/GUIDELINES: None established for this product. 8.2 Exposure Controls: Currently, International exposure limits are not established for the components of this product. Please check with competent authority in each country for the most recent limits in place. VENTILATION AND ENGINEERING CONTROLS: Generally not required under normal conditions of use. If method of use will result in significant dust generation, use in lab hood or under conditions of adequate ventilation. The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, or standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection), and those of Japan. Please reference applicable regulations and standards for relevant details. RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, the European Standard EN149, or EU member states. EYE PROTECTION: Safety glasses or chemical goggles as appropriate to prevent eye contact. If necessary, refer to U.S. OSHA 29 CFR 1910.133 or appropriate Canadian Standards. HAND PROTECTION: Use chemical resistant gloves to prevent skin contact. If necessary, refer to U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada. BODY PROTECTION: Use body protection appropriate to prevent contact (e.g. lab coat, overalls). If necessary, refer to appropriate Standards of Canada, or appropriate Standards of the EU, Australian Standards, or relevant Japanese Standards. December 2018 Page 3 of 8 KB-1 PRIMER siremlab.com •• SiREM SAFETY DATA SHEET KB-1® Primer SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties: PHYSICAL STATE: Solid (Granules) APPEARANCE: White to off-white powder or granules ODOR: Odorless ODOR THRESHOLD (PPM): Not Available pH: 6-8 (aqueous solution) MELTING / FREEZING POINT (C°): Not Available BOILING POINT (C°): Not Available FLASH POINT: Not Available EVAPORATION RATE (nBuAc = 1): Not Available FLAMMABILITY (solid, gas): Not Available FLAMMABLE LIMITS (in air by volume, %): Not Available VAPOR PRESSURE (mmHg): Not Available VAPOR DENSITY (AIR=1): Not Available RELATIVE DENSITY 2.4 to 2.6 g/cm3, depending on formulation SOLUBILITY IN WATER (%) Soluble PARTITION COEFFICIENT: N-OCTANOL/WATER: Not Available AUTOIGNITION TEMPERATURE: Not Available DECOMPOSITION TEMPERATURE: Not Available VISCOSITY: Not Available EXPLOSIVE PROPERTIES: Not Available OXIDISING PROPERTIES: Not Available 9.2 Other Information: PACKING DENSITY: VOC: Not Available Not Available SECTION 10 - STABILITY and REACTIVITY 10.1 Reactivity: See section 10.5. 10.2 Chemical Stability: Product is stable. 10.3 Possibility of Hazardous Reactions: Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to avoid: Contact with incompatibles, exposure to light, and moist air. 10.5 Incompatible materials: Strong oxidizing agents, bases. 10.6 Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides, potassium oxides. SECTION 11 - TOXICOLOGICAL INFORMATION 11.1 Information on Toxicological Effects: TOXICITY DATA: L-Cysteine CAS# 52-90-4 Oral LD50 1890 mg/kg Rat Oral LD50 660 mg/kg Mouse December 2018 Page 4 of 8 KB-1 PRIMER siremlab.com •• SiREM SAFETY DATA SHEET KB-1® Primer 11.1.2 Mixtures: Acute toxicity Acute Toxicity Category 5 (Oral) Skin corrosion / irritation Based on available data, the classification criteria are not met Serious eye damage / irritation Based on available data, the classification criteria are not met Respiratory or skin sensitization Based on available data, the classification criteria are not met Germ cell mutagenicity Based on available data, the classification criteria are not met Carcinogenicity Based on available data, the classification criteria are not met Reproductive toxicity Based on available data, the classification criteria are not met STOT-single exposure Based on available data, the classification criteria are not met STOT-repeated exposure Based on available data, the classification criteria are not met Aspiration hazard Based on available data, the classification criteria are not met Other Information POTENTIAL HEALTH HAZARDS OR RISKS FROM EXPOSURE: ACUTE: EYE CONTACT: Eye exposure may produce irritation. SKIN CONTACT: Prolonged or repeated skin exposure may cause irritation. INHALATION HAZARDS: Inhalation of dusts may cause irritation. INGESTION HAZARDS: May be harmful if swallowed. May cause gastrointestinal tract irritation. CHRONIC: None Known TARGET ORGANS: ACUTE: Organs CHRONIC: None Known CARCINOGENICITY: None of the ingredients are found on the following lists: FEDERAL OSHA Z LIST, NTP, CAL/OSHA, IARC and therefore are not considered to be, nor suspected to be a cancer -causing agent by these agencies. IRRITANCY OF PRODUCT: Contact with this product can be irritating to skin and eyes. SENSITIZATION OF PRODUCT: This product is not considered a skin sensitizer. REPRODUCTIVE TOXICITY INFORMATION: No information concerning the effects of this product and its components on the human reproductive system. MUTAGENICITY INFORMATION: This product does not contain a component that is suspected to be a mutagenicity hazard. SPECIFIC TARGET ORGAN TOXICITY — SINGLE EXPOSURE: Data not sufficient for classification. SPECIFIC TARGET ORGAN TOXICITY — REPEATED EXPOSURE: Data not sufficient for classification. ASPIRATION HAZARD: Not applicable SECTION 12 - ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. 12.1 Toxicity: No specific data available on this product. 12.2 Persistence and Degradability: No specific data available on this product. 12.3 Bioaccumulative Potential: No specific data available on this product. 12.4 Mobility in Soil: No specific data available on this product. 12.5 Results of PBT and vPvB Assessment: No specific data available on this product. 12.6 Other Adverse Effects: No specific data available on this product. 12.7 Water Endangerment Class: Not believed to be water endangering in accordance with EU Guideline 91/155-EWG. At present there are no ecotoxicological assessments for this product. December 2018 Page 5 of 8 K81 PRIMER siremlab.com •• SiREM SAFETY DATA SHEET KB-1® Primer SECTION 13 - DISPOSAL CONSIDERATIONS 13.1 Waste Treatment Methods: Waste disposal must be in accordance with appropriate Federal, State, and local regulations, those of Canada, Australia, EU Member States and Japan. SECTION 14 - TRANSPORTATION INFORMATION 14.1 Transport Information: US DOT; IATA; IMO; ADR: THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: None HAZARD CLASS NUMBER and DESCRIPTION: Not Regulated UN IDENTIFICATION NUMBER: None PACKING GROUP: None DOT LABEL(S) REQUIRED: None NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2016): None MARINE POLLUTANT: This product does not contain ingredients that are classified by the DOT as a Marine Pollutant (as defined by 49 CFR 172.101, Appendix B) TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not classified as Dangerous Goods, per regulations of Transport Canada INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA): This product is not classified as Dangerous Goods, by rules of IATA: INTERNATIONAL MARITIME ORGANIZATION SHIPPING and MARITIME DANGEROUS GOODS CODE SHIPPING INFORMATION (IMO / IMDG): This product is not classified as Dangerous Goods. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR): This product is not classified by the United Nations Economic Commission for Europe to be dangerous goods. SECTION 15 - REGULATORY INFORMATION 15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture: UNITED STATES REGULATIONS SARA REPORTING REQUIREMENTS: This product is not subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows: None TSCA: All components in this product are listed on the US Toxic Substances Control Act (TSCA) inventory of chemicals. SARA 311/312: Acute Health: No Chronic Health: No Fire: No Reactivity: No U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this product. The default Federal SDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR 370.20. U.S. CERCLA REPORTABLE QUANTITY (RQ): None CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): None of the ingredients are on the California Proposition 65 lists. CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS:AII of the components of this product are on the DSL Inventory CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No component of this product is on the CEPA First Priorities Substance Lists. CANADIAN WHMIS CLASSIFICATION and SYMBOLS: This product is categorized as per WHMIS 2015 Hazardous Product Regulations. December 2018 Page 6 of 8 KB-1 PRIMER siremlab.com •• SiREM SAFETY DATA SHEET KB-1® Primer EUROPEAN ECONOMIC COMMUNITY INFORMATION: EU LABELING AND CLASSIFICATION: Classification of the mixture according to Regulation (EC) No1272/2008. See section 2 for details. AUSTRALIAN INFORMATION FOR PRODUCT: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: Components of this product are listed on the AICS. STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Not applicable. JAPANESE INFORMATION FOR PRODUCT: JAPAN INDUSTRIAL SAFETY AND HEALTH LAW: This product has been classified per the Japan Industrial Safety and Health Law. See Section 2 for the GHS Classification. KOREA ACT ON REGISTRATION AND EVALUATION OF CHEMICAL SUBSTANCES (K-REACH): This product has been classified per K-REACH. See Section 2 for the GHS Classification. INTERNATIONAL CHEMICAL INVENTORIES: Listing of the components on individual country Chemical Inventories is as follows: Asia-Pac: Listed Australian Inventory of Chemical Substances (AICS): Listed Korean Existing Chemicals List (ECL): Listed Japanese Existing National Inventory of Chemical Substances (ENCS): Listed Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed Swiss Giftliste List of Toxic Substances: Listed U.S. TSCA: Listed 15.2 Chemical Safety Assessment: A chemical safety assessment has not been performed on this product. SECTION 16 - OTHER INFORMATION HMIS Rating (Scale 0-4) Health hazard: 1 Flammability: 0 Physical Hazard: 0 NFPA Rating (Scale 0-4) Health hazard: 1 Flammability: 0 Physical Hazard: 0 Caution: HMIS and NFPA ratings are based on a 0-4 rating scale 0= Minimal Hazard 1= Slight 2= Moderate 3= High 4= Extreme Abbreviations and ACGIH CFR DOT GHS HMIS HCS IARC IATA ICAO IMDG IMO LD50/LC50 NFPA NIOSH acronyms American Conference of Governmental Industrial Hygienists Code of Federal Regulations Federal Department of Transportation The Globally Harmonized System of Classification and Labelling of Chemicals Hazardous Material Identification System Hazard Communication Standard International Agency for Research on Cancer The International Air Transport Association The International Civil Aviation Organization International Maritime Dangerous Goods International Maritime Organization Lethal Concentration/Dose, 50 percent National Fire Protection Association National Institute for Occupational Safety and Health December 2018 Page 7 of 8 KB-1 PRIMER siremlab.com •• SiREM SAFETY DATA SHEET KB-1® Primer NTP National Toxicology Program OSHA Occupational Safety and Health PEL OSHA Permissible Exposure Limit SARA Superfund Amendments and Reauthorization Act TLV ACGIH Threshold Limit Value TWA Time -Weighted Average Acute Tox Acute Toxicity Skin Corr Skin Corrosion PREPARED BY: Chris Eigbrett MSDS to GHS Compliance History Log: December 05, 2018 - Document creation End of SDS Sheet December 2018 Page 8 of 8 KB-1 PRIMER siremlab.com Appendix F. Electron Donor Dosing and Injection Volume Calculations Former Schlage Lock Plant Rocky Mount, North Carolina Geosyntec° consultants Geosyntec Consultants of NC, P.C. Treatment Area Treatment Geology Treatment Interval (ft BLS) Number of Location of Injection Injection Points Points Porosity (Equal to Effective Porosity) Target ROI (ft) Injection Location Area z n'(ROI) (ft) Total Injection Interval (feet) Number of 2-ft Injection Intervals Total Injection Area Injection Location Area * Number of Injection Points (ft3) Total Treatment Volume for the Target ROI Total Injection Area ' Injection Interval (ft) Treatm ent Pore Volume Total Trealm ent Volume` Porosity 3 ' 7.481 gal/ft (gal) Electron Donor Required Based on Treatment Pore Volume Dosing Treatm ent Pore Volume ` Dosing 3 (0.3 Ib/ft) (Ib) Amendment Volume Electron Donor Required / 60% Electron Donor / Specific Weight of Amendment (Rounded Up to Nearest 10) (gal) ZVI Mass Amendment Volume` Specific Weight of Amendment (1:1 by weight electron donocZVl) (Ib) Pore Volume Displacement Total Injection Volume (Based on 14-ft ROI) Treatment Pore Volume * Pore Volume Displacement (Round Up to Nearest 1 gal) (gal) Amendment Dilution (1:15 or 1:20) Total Diluted Amendment Volume Amendment Volume ` Amendment Dilution (gal) Diluted Amendment Concentration Amendment Volume' Specific Weight of Am endment/ Total Diluted Amendment Volume (Ib/gal) Total Chase Water Volume oInjection Volume -Total Diluted Amendment Volume (gal) Per Location Per Location Diluted Chase Water Amendment Volume Total Diluted Total Chase Amendment Water Volume/ Volume / No. No. of Inj. of Inj. Points Points (Round Up to (Round Up to Nearest 1 gal) Nearest 1 gal) (gal) (gal) Per Injection Per Injection Interval Interval Diluted Chase Water Amendment Volume Total Chase Total Diluted Water Amendment Volume/No. Volume / No. of Inj. of Inj. Intervals Intervals (Round Up to (Round Up to Nearest 1 gal) Nearest 1 gal) (gal) (gal) High Concentration Area (HC 1, HC2, HC3, HC4) High Concentration Area - Middle Aquifer - ABC+ (with ZVI) Middle Aquifer 16 to 32 11 HC2 - MW75S 0.25 14 616 16 8 6,773 108,372 202,683 8,129 1,660 13,612 0.17 34,457 15 24,900 0.55 9,557 2,264 869 283 109 16 to 30 4 HC3 - MW78S 0.25 14 616 14 7 2,463 34,482 64,490 2,587 530 4,346 0.17 10,964 15 7,950 0.55 3,014 1,988 754 284 108 MiddleAguifer Totals (with ZVI) 15 --- 116 9,236 142,855 267,174 10,716 2,190 17,958 --- 45,421 --- 32,850 0.55 12,571 -- -- -- -- High Concentration Area - Lower Aquifer - ABC+ (with ZVI) Lower Aquifer 34 to 50 3 HC3 - MW78D 0.25 14 616 16 8 1,847 29,556 55,277 2,217 460 3,772 0.17 9,398 15 6,900 0.55 2,498 2.300 833 288 105 LowerAqu"er Totals (with ZVI) 3 --- 24 1,847 29,556 55,277 2,217 460 3,772 --- 9,398 --- 6,900 0.55 2,498 -- -- -- High Concentration Area - Middle Aquifer - ABC ONLY Middle Aquifer 18 to 32 4 HC1 - MW76S 0.25 14 616 14 7 2,463 34,482 64,490 2,587 530 0 0.20 12,899 20 10,600 0.41 2,299 2,650 575 379 83 14 to 36 2 HC1 - MW76S 0.25 14 616 22 11 1,232 27,093 50,671 2,032 420 0 0.20 10,135 20 8,400 0.41 1,735 4,200 868 382 79 19 to 31 10 HC2 - MW75S 0.25 14 616 12 6 6,158 73,890 138,193 5,543 1,130 0 0.20 27,639 20 22,600 0.41 5,039 2,260 504 377 84 22 to 36 4 HC2 - MW75S 0.25 14 616 14 7 2,463 34,482 64,490 2,587 530 0 0.20 12,899 20 10,600 0.41 2,299 2,650 575 379 83 21 to 33 5 HC2 - MW75S 0.25 14 616 12 6 3,079 36,945 69,097 2,771 570 0 0.20 13,820 20 11,400 0.41 2,420 2,280 484 380 81 18 to 30 6 HC3 - MW78S 0.25 14 616 12 6 3,695 44,334 82,916 3,326 680 0 0.20 16,584 20 13,600 0.41 2,984 2,267 498 378 83 17 to 29 5 HC3 - MW78S 0.25 14 616 12 6 3,079 36,945 69,097 2,771 570 0 0.20 13,820 20 11,400 0.41 2,420 2,280 484 380 81 Middle Aquifer Totas o ZVI) 36 --- 234 22,167 288,172 538,954 21, 616 4,430 0 --- 107, 796 --- 88, 600 0.41 19,196 -- -- -- High Concentration Area - Lower Aquifer - ABC ONLY Lower Aquifer 40 to 50 3 HC1 - MW76D 0.25 14 616 10 5 1,847 18,473 34,548 1,386 290 0 0.20 6,910 20 5,800 0.41 1,110 1,934 370 387 74 38 to 50 3 HC1 - MW76D 0.25 14 616 12 6 1,847 22,167 41,458 1,663 340 0 0.20 8,292 20 6,800 0.41 1,492 2,267 498 378 83 34 to 50 5 HC3 - MW78D 0.25 14 616 16 8 3,079 49,260 92,129 3,695 760 0 0.20 18,426 20 15,200 0.41 3,226 3,040 646 380 81 26 to 46 3 HC4 - MW30 0.25 14 616 20 10 1,847 36,945 69,097 2,771 570 0 0.20 13,820 20 11,400 0.41 2,420 3,800 807 380 81 Y Lower Aquer ata s (Na ZVI) 14 --- 103 8, 621 126,845 237,232 9,515 1,960 0 --- 47,448 --- 39,200 0.41 8,248 -- -- -- -- HighConcentration Area Totals 68 - - - - - 477 41,871 587,428 I,098,636 44,063 9,040 21,730 --- 210,063 --- 167,550 -- 42,513 -- - - -- Treatment Area Treatment Geology Treatment Interval (ft BLS) Number of Location of Injection Injection Points Points Porosity (Equal to Effective Porosity) Target Width (14-ft ROI x2) (ft) Target Length (ft) Total Injection Interval (feet) Number of 2-ft Injection Intervals Total Target Area Target Width' Target Length (ft) Total Treatment Volume for theTarget Area TotalTarget Area * Injection Interval (ft) Treatm ent Pore Volume TotalTreatm ent Volume' Porosity a * 7.481 gal/ft (gal) Electron Donor Required Based on Treatment Pore Volume Dosing Treatm ent Pore Volume * Dosing (0.3 Ib/ft3) (lb) Amendment Volume Electron Donor Required / 60% Electron Donor / Specific Weight of Ameudmeut (Rounded Up to Nearest 10) (gal) ZVI Mass Amendment Volume * Specific Weight of Amendment (lb) Pore Volume Displacement Total Injection Volume (Based on 14-ftROI)Volume n'(ROIf * Total Injection Interval` Number of Injection Points' Porosity` 3 7.481 gal/ft `Pore Volume Displacement (Round Up to Nearest 1 gal) (gal) Ameudmeut Dilution (120) . Total Diluted Amendment Amendment Volume * Amendment Dilution (gal) Diluted Amendment Concentration Ameudm ent Volume' Specific Weight p of Amendment / Total Diluted Amendment Volume (Ib/gal) Total Chase Water Volume Total Injection Volume -Total Diluted Amendment Volume (gal) Per Location Per Location Diluted Chase Water Amendment Volume Total Diluted Total Chase Amendment Water Volume/ Volume / No. No. of Inj. of Inj. Points Points (Round Up to (Round Up to Nearest 1 gal) Nearest 1 gal) (gal) (gal) Per Injection Per Injection Interval Interval Diluted Chase Water Amendment Volume Total Chase Total Diluted Water Amendment Volume/No. Volume / No. of Inj. of Inj. Intervals Intervals (Round Up to (Round Up to Nearest 1 gal) Nearest 1 gal) (gal) (gal) Downgradrent Area (DG1, DG2, DG3) Dowugradieut Area - Middle Aquifer - ABC ONLY Middle Aquifer 12 to 22 13 DG1 - MW37 0.25 28 353 10 5 9,884 98,840 184,856 7,414 1,510 0 0.25 37,428 20 30,200 0.41 7,228 2,324 556 465 112 12 to 24 1 DG1 - MW37 0.25 28 27 12 6 756 9,072 16,967 680 140 0 0.25 3,455 20 2,800 0.41 655 2,800 655 467 110 Middle Agu" er Totals 14 --- --- -- --- --- 71 10,640 107,912 201,822 8,094 1,650 0 --- 40,883 --- 33,000 0.41 7,883 -- -- -- Dowugradieut Area - Lower Aquifer - ABC ONLY Lower Aquifer 25 to 41 4 DG1 - MW47D 0.25 28 110 16 8 3,080 49,280 92,166 3,696 760 0 0.25 18,426 20 15,200 0.41 3,226 3,800 807 475 101 35 to 45 4 DG2 - MW74D 0.25 28 110 10 5 3,080 30,800 57,604 2,310 470 0 0.25 11,517 20 9,400 0.41 2,117 2,350 530 470 106 38 to 50 DG3 - North of 9 MW70D 0.25 28 249 12 6 6,972 83,664 156,473 6,276 1,280 0 0.25 31,094 20 25,600 0.41 5,494 2,844 611 474 102 40 to 50 DG3 - around 3 MW70D 0.25 28 81 10 5 2,268 22,680 42,417 1,701 350 0 0.25 8,638 20 7,000 0.41 1,638 2,333 546 467 110 LawerAgu"er Totals 20 --- --- -- --- --- 121 15,400 186,424 348,659 13,984 2,860 0 --- 69,675 --- 57,200 0.41 12,475 -- -- -- DowngradientArea Totals 34 - - - -- - 192 26,040 294,336 550,482 22,078 4,510 0 - 110,558 - 90,200 - 20,358 - - -- - Total Injection Amounts 102 --- - 669 67,911 881,764 1,649,118 66,141 13,550 21,730 --- 320,621 --- 257,750 -- 62,871 -- -- -- -- Notes: 1. ft BLS indicates feet below land surface. 2. x indicates 3.14159265359. 3. ROI indicates radius of influence. 4. ftz indicates square feet. 5 ft3 indicates cubic feet. 6. gal indicates gallons. 7. Ib indicates pound. 8. ROI indicates radius of influence. 9. ZVI indicates zero valent iron. 10. Injection calculations are divided into two areas, based on how the Total Treatment Volume was calculated (High Concentration Area and Downgradieut Area). Page 1 of 1 Geosyntec Consultants of NC, PC Appendix F. KB-1® Bioaugmentation Dosing Former Schlage Lock Plant Rocky Mount, North Carolina Geosyntec° consultants Geosyntec Consultants of NC, P.C. Variable Value Unit/Notes Treatment Pore Volume 1,649,118 Gallon (gal) 6,242,572 Liter (L; 3.8754 L per gal) KB-1® Dosing 7.14E-05 Liter of KB-1® per Liter treatment pore volume (2.5 L of KB-1 per 35,000 L of groundwater) KB-1® Volume for Pore Volume 446 L Middle Aquifer: High Concentration Area 806,127 Treatment Pore Volume (gal) 3,051,514 Treatment Pore Volume (L) 218 KB-1 Requirement (rounded up to nearest whole number) 350 Total Injection Intervals 0.623 Liter of KB-1 per injection interval (rounded to nearest 0.001) 0.650 KB-1 (L) per injection interval (rounded up to nearest 0.05) 227.50 Total KB-1 (L) to Inject Middle Aquifer: Downgradient Area 201,822 Treatment Pore Volume (gal) 763,979 Treatment Pore Volume (L) 55 KB-1 Requirement (rounded up to nearest whole number) 71 Total Injection Intervals 0.775 Liter of KB-1 per injection interval (rounded to nearest 0.001) 0.800 KB-1 (L) per injection interval (rounded up to nearest 0.05) 56.8 Total KB-1 (L) to Inject Lower Aquifer: High Concentration Area 292,509 Treatment Pore Volume (gal) 1,107,264 Treatment Pore Volume (L) 80 KB-1 Requirement (rounded up to nearest whole number) 127 Total Injection Intervals 0.630 Liter of KB-1 per injection interval (rounded to nearest 0.001) 0.650 KB-1 (L) per injection interval (rounded up to nearest 0.05) 82.55 Total KB-1 (L) to Inject Lower Aquifer: Downgradient Area 348,659 Treatment Pore Volume (gal) 1,319,816 Treatment Pore Volume (L) 95 KB-1 Requirement (rounded up to nearest whole number) 121 Total Injection Intervals 0.785 Liter of KB-1 per injection interval (rounded to nearest 0.001) 0.800 KB-1 (L) per injection interval (rounded up to nearest 0.05) 96.8 Total KB-1 (L) to Inject Total KB-1 Volume 463.65 Sum of individual KB-1 volumes (L) for each aquifer and aquifer area. Page 1 of 1 Geosyntec Consultants of NC, PC 4. INJECTION PROCEDURE — Per 15A NCAC 02C .0225(0(71. submit a table with a detailed description of the proposed injection procedure that includes the following: (A) The proposed average and maximum daily rate and quantity of injectant; (B) The average maximum injection pressure expressed in units of pounds per square inch (psi); and (C) The total or estimated total volume to be injected. Modification Description: Modifications include the reduction in total injection volume. It's estimated that up to approximately 325,000 gal total will be injection (Refer to the attached Appendix F. Electron Donor Dosing and Injection Volume Calculations for revisions). A Injection Timelines — Proposed Inj. Rate Injection Locations Operating at Once Injection Gal per Day Average DPT - ABC+ 7.8 1 2,800 DPT - ABC 4 6 8,640 Injection Timelines — Proposed Inj. Rate Injection Locations Operating at Once Injection Gal per Day Maximum DPT - ABC+ 15 1 5,400 DPT - ABC 10 10 36,000 Refer to the attached Appendix F. Electron Donor Dosing and Injection Volume Calculations (Geosyntec, 2021b) for injection volume details. Proposed maximum rates are not anticipated to be implemented at all active injection locations; however, historical injection information indicated injection rates above 10 gallons per minute are possible. A process flow diagram (PFD) for the ABC and ABC+ injection process is provided on the attached Figures 8 and 9 (Geosyntec, 2021b). All injections will occur from the bottom up. (B) Injection pressure: 5-100 psi (based on historical injection information) (C) Up to 550,000 gal (Refer to the attached Appendix F. Electron Donor Dosing and Injection Volume Calculations (Geosyntec, 2021b) for design injection volume) Appendix F. Electron Donor Dosing and Injection Volume Calculations Former Schlage Lock Plant Rocky Mount, North Carolina Geosyntec° consultants Geosyntec Consultants of NC, P.C. Treatment Area Treatment Geology Treatment Interval (ft BLS) Number of Location of Injection Injection Points Points Porosity (Equal to Effective Porosity) Target ROI (ft) Injection Location Area z n'(ROI) (ft) Total Injection Interval (feet) Number of 2-ft Injection Intervals Total Injection Area Injection Location Area * Number of Injection Points (ft3) Total Treatment Volume for the Target ROI Total Injection Area ' Injection Interval (ft) Treatm ent Pore Volume Total Trealm ent Volume` Porosity 3 ' 7.481 gal/ft (gal) Electron Donor Required Based on Treatment Pore Volume Dosing Treatm ent Pore Volume ` Dosing 3 (0.3 Ib/ft) (Ib) Amendment Volume Electron Donor Required / 60% Electron Donor / Specific Weight of Amendment (Rounded Up to Nearest 10) (gal) ZVI Mass Amendment Volume` Specific Weight of Amendment (1:1 by weight electron donocZVl) (Ib) Pore Volume Displacement Total Injection Volume (Based on 14-ft ROI) Treatment Pore Volume * Pore Volume Displacement (Round Up to Nearest 1 gal) (gal) Amendment Dilution (1:15 or 1:20) Total Diluted Amendment Volume Amendment Volume ` Amendment Dilution (gal) Diluted Amendment Concentration Amendment Volume' Specific Weight of Am endment/ Total Diluted Amendment Volume (Ib/gal) Total Chase Water Volume oInjection Volume -Total Diluted Amendment Volume (gal) Per Location Per Location Diluted Chase Water Amendment Volume Total Diluted Total Chase Amendment Water Volume/ Volume / No. No. of Inj. of Inj. Points Points (Round Up to (Round Up to Nearest 1 gal) Nearest 1 gal) (gal) (gal) Per Injection Per Injection Interval Interval Diluted Chase Water Amendment Volume Total Chase Total Diluted Water Amendment Volume/No. Volume / No. of Inj. of Inj. Intervals Intervals (Round Up to (Round Up to Nearest 1 gal) Nearest 1 gal) (gal) (gal) High Concentration Area (HC 1, HC2, HC3, HC4) High Concentration Area - Middle Aquifer - ABC+ (with ZVI) Middle Aquifer 16 to 32 11 HC2 - MW75S 0.25 14 616 16 8 6,773 108,372 202,683 8,129 1,660 13,612 0.17 34,457 15 24,900 0.55 9,557 2,264 869 283 109 16 to 30 4 HC3 - MW78S 0.25 14 616 14 7 2,463 34,482 64,490 2,587 530 4,346 0.17 10,964 15 7,950 0.55 3,014 1,988 754 284 108 MiddleAguifer Totals (with ZVI) 15 --- 116 9,236 142,855 267,174 10,716 2,190 17,958 --- 45,421 --- 32,850 0.55 12,571 -- -- -- -- High Concentration Area - Lower Aquifer - ABC+ (with ZVI) Lower Aquifer 34 to 50 3 HC3 - MW78D 0.25 14 616 16 8 1,847 29,556 55,277 2,217 460 3,772 0.17 9,398 15 6,900 0.55 2,498 2.300 833 288 105 LowerAqu"er Totals (with ZVI) 3 --- 24 1,847 29,556 55,277 2,217 460 3,772 --- 9,398 --- 6,900 0.55 2,498 -- -- -- High Concentration Area - Middle Aquifer - ABC ONLY Middle Aquifer 18 to 32 4 HC1 - MW76S 0.25 14 616 14 7 2,463 34,482 64,490 2,587 530 0 0.20 12,899 20 10,600 0.41 2,299 2,650 575 379 83 14 to 36 2 HC1 - MW76S 0.25 14 616 22 11 1,232 27,093 50,671 2,032 420 0 0.20 10,135 20 8,400 0.41 1,735 4,200 868 382 79 19 to 31 10 HC2 - MW75S 0.25 14 616 12 6 6,158 73,890 138,193 5,543 1,130 0 0.20 27,639 20 22,600 0.41 5,039 2,260 504 377 84 22 to 36 4 HC2 - MW75S 0.25 14 616 14 7 2,463 34,482 64,490 2,587 530 0 0.20 12,899 20 10,600 0.41 2,299 2,650 575 379 83 21 to 33 5 HC2 - MW75S 0.25 14 616 12 6 3,079 36,945 69,097 2,771 570 0 0.20 13,820 20 11,400 0.41 2,420 2,280 484 380 81 18 to 30 6 HC3 - MW78S 0.25 14 616 12 6 3,695 44,334 82,916 3,326 680 0 0.20 16,584 20 13,600 0.41 2,984 2,267 498 378 83 17 to 29 5 HC3 - MW78S 0.25 14 616 12 6 3,079 36,945 69,097 2,771 570 0 0.20 13,820 20 11,400 0.41 2,420 2,280 484 380 81 Middle Aquifer Totas o ZVI) 36 --- 234 22,167 288,172 538,954 21, 616 4,430 0 --- 107, 796 --- 88, 600 0.41 19,196 -- -- -- High Concentration Area - Lower Aquifer - ABC ONLY Lower Aquifer 40 to 50 3 HC1 - MW76D 0.25 14 616 10 5 1,847 18,473 34,548 1,386 290 0 0.20 6,910 20 5,800 0.41 1,110 1,934 370 387 74 38 to 50 3 HC1 - MW76D 0.25 14 616 12 6 1,847 22,167 41,458 1,663 340 0 0.20 8,292 20 6,800 0.41 1,492 2,267 498 378 83 34 to 50 5 HC3 - MW78D 0.25 14 616 16 8 3,079 49,260 92,129 3,695 760 0 0.20 18,426 20 15,200 0.41 3,226 3,040 646 380 81 26 to 46 3 HC4 - MW30 0.25 14 616 20 10 1,847 36,945 69,097 2,771 570 0 0.20 13,820 20 11,400 0.41 2,420 3,800 807 380 81 Y Lower Aquer ata s (Na ZVI) 14 --- 103 8, 621 126,845 237,232 9,515 1,960 0 --- 47,448 --- 39,200 0.41 8,248 -- -- -- -- HighConcentration Area Totals 68 - - - - - 477 41,871 587,428 I,098,636 44,063 9,040 21,730 --- 210,063 --- 167,550 -- 42,513 -- - - -- Treatment Area Treatment Geology Treatment Interval (ft BLS) Number of Location of Injection Injection Points Points Porosity (Equal to Effective Porosity) Target Width (14-ft ROI x2) (ft) Target Length (ft) Total Injection Interval (feet) Number of 2-ft Injection Intervals Total Target Area Target Width' Target Length (ft) Total Treatment Volume for theTarget Area TotalTarget Area * Injection Interval (ft) Treatm ent Pore Volume TotalTreatm ent Volume' Porosity a * 7.481 gal/ft (gal) Electron Donor Required Based on Treatment Pore Volume Dosing Treatm ent Pore Volume * Dosing (0.3 Ib/ft3) (lb) Amendment Volume Electron Donor Required / 60% Electron Donor / Specific Weight of Ameudmeut (Rounded Up to Nearest 10) (gal) ZVI Mass Amendment Volume * Specific Weight of Amendment (lb) Pore Volume Displacement Total Injection Volume (Based on 14-ftROI)Volume n'(ROIf * Total Injection Interval` Number of Injection Points' Porosity` 3 7.481 gal/ft `Pore Volume Displacement (Round Up to Nearest 1 gal) (gal) Ameudmeut Dilution (120) . Total Diluted Amendment Amendment Volume * Amendment Dilution (gal) Diluted Amendment Concentration Ameudm ent Volume' Specific Weight p of Amendment / Total Diluted Amendment Volume (Ib/gal) Total Chase Water Volume Total Injection Volume -Total Diluted Amendment Volume (gal) Per Location Per Location Diluted Chase Water Amendment Volume Total Diluted Total Chase Amendment Water Volume/ Volume / No. No. of Inj. of Inj. Points Points (Round Up to (Round Up to Nearest 1 gal) Nearest 1 gal) (gal) (gal) Per Injection Per Injection Interval Interval Diluted Chase Water Amendment Volume Total Chase Total Diluted Water Amendment Volume/No. Volume / No. of Inj. of Inj. Intervals Intervals (Round Up to (Round Up to Nearest 1 gal) Nearest 1 gal) (gal) (gal) Downgradrent Area (DG1, DG2, DG3) Dowugradieut Area - Middle Aquifer - ABC ONLY Middle Aquifer 12 to 22 13 DG1 - MW37 0.25 28 353 10 5 9,884 98,840 184,856 7,414 1,510 0 0.25 37,428 20 30,200 0.41 7,228 2,324 556 465 112 12 to 24 1 DG1 - MW37 0.25 28 27 12 6 756 9,072 16,967 680 140 0 0.25 3,455 20 2,800 0.41 655 2,800 655 467 110 Middle Agu" er Totals 14 --- --- -- --- --- 71 10,640 107,912 201,822 8,094 1,650 0 --- 40,883 --- 33,000 0.41 7,883 -- -- -- Dowugradieut Area - Lower Aquifer - ABC ONLY Lower Aquifer 25 to 41 4 DG1 - MW47D 0.25 28 110 16 8 3,080 49,280 92,166 3,696 760 0 0.25 18,426 20 15,200 0.41 3,226 3,800 807 475 101 35 to 45 4 DG2 - MW74D 0.25 28 110 10 5 3,080 30,800 57,604 2,310 470 0 0.25 11,517 20 9,400 0.41 2,117 2,350 530 470 106 38 to 50 DG3 - North of 9 MW70D 0.25 28 249 12 6 6,972 83,664 156,473 6,276 1,280 0 0.25 31,094 20 25,600 0.41 5,494 2,844 611 474 102 40 to 50 DG3 - around 3 MW70D 0.25 28 81 10 5 2,268 22,680 42,417 1,701 350 0 0.25 8,638 20 7,000 0.41 1,638 2,333 546 467 110 LawerAgu"er Totals 20 --- --- -- --- --- 121 15,400 186,424 348,659 13,984 2,860 0 --- 69,675 --- 57,200 0.41 12,475 -- -- -- DowngradientArea Totals 34 - - - -- - 192 26,040 294,336 550,482 22,078 4,510 0 - 110,558 - 90,200 - 20,358 - - -- - Total Injection Amounts 102 --- - 669 67,911 881,764 1,649,118 66,141 13,550 21,730 --- 320,621 --- 257,750 -- 62,871 -- -- -- -- Notes: 1. ft BLS indicates feet below land surface. 2. x indicates 3.14159265359. 3. ROI indicates radius of influence. 4. ftz indicates square feet. 5 ft3 indicates cubic feet. 6. gal indicates gallons. 7. Ib indicates pound. 8. ROI indicates radius of influence. 9. ZVI indicates zero valent iron. 10. Injection calculations are divided into two areas, based on how the Total Treatment Volume was calculated (High Concentration Area and Downgradieut Area). Page 1 of 1 Geosyntec Consultants of NC, PC Appendix F. KB-1® Bioaugmentation Dosing Former Schlage Lock Plant Rocky Mount, North Carolina Geosyntec° consultants Geosyntec Consultants of NC, P.C. Variable Value Unit/Notes Treatment Pore Volume 1,649,118 Gallon (gal) 6,242,572 Liter (L; 3.8754 L per gal) KB-1® Dosing 7.14E-05 Liter of KB-1® per Liter treatment pore volume (2.5 L of KB-1 per 35,000 L of groundwater) KB-1® Volume for Pore Volume 446 L Middle Aquifer: High Concentration Area 806,127 Treatment Pore Volume (gal) 3,051,514 Treatment Pore Volume (L) 218 KB-1 Requirement (rounded up to nearest whole number) 350 Total Injection Intervals 0.623 Liter of KB-1 per injection interval (rounded to nearest 0.001) 0.650 KB-1 (L) per injection interval (rounded up to nearest 0.05) 227.50 Total KB-1 (L) to Inject Middle Aquifer: Downgradient Area 201,822 Treatment Pore Volume (gal) 763,979 Treatment Pore Volume (L) 55 KB-1 Requirement (rounded up to nearest whole number) 71 Total Injection Intervals 0.775 Liter of KB-1 per injection interval (rounded to nearest 0.001) 0.800 KB-1 (L) per injection interval (rounded up to nearest 0.05) 56.8 Total KB-1 (L) to Inject Lower Aquifer: High Concentration Area 292,509 Treatment Pore Volume (gal) 1,107,264 Treatment Pore Volume (L) 80 KB-1 Requirement (rounded up to nearest whole number) 127 Total Injection Intervals 0.630 Liter of KB-1 per injection interval (rounded to nearest 0.001) 0.650 KB-1 (L) per injection interval (rounded up to nearest 0.05) 82.55 Total KB-1 (L) to Inject Lower Aquifer: Downgradient Area 348,659 Treatment Pore Volume (gal) 1,319,816 Treatment Pore Volume (L) 95 KB-1 Requirement (rounded up to nearest whole number) 121 Total Injection Intervals 0.785 Liter of KB-1 per injection interval (rounded to nearest 0.001) 0.800 KB-1 (L) per injection interval (rounded up to nearest 0.05) 96.8 Total KB-1 (L) to Inject Total KB-1 Volume 463.65 Sum of individual KB-1 volumes (L) for each aquifer and aquifer area. Page 1 of 1 Geosyntec Consultants of NC, PC 6. WELL CONSTRUCTION DETAILS — Per 15A NCAC 02C .0225(1)(10). submit the following information in tabular or schematic form as appropriate for each item: (A) number and depth of injection wells; (B) number and depth of borings if using multi -level or "nested" well systems; (C) indication whether the injection wells are existing or proposed; (D) depth and type of casing; (E) depth and type of screen material; (F) depth and type of grout; (G) indication whether the injection wells are permanent or temporary "direct push" points; and (H) plans and specifications of the surface and subsurface construction details. Modification description: The number of temporary injection locations has been increased from 89 to 102. This occurred because at each location where the Middle and Lower Aquifers are to be treated, separate boreholes will be used to target each aquifer. Revised injection interval tables (Tables 3 and 4) are attached. (A) See the injection interval tables (Tables 3 and 4) attached (Geosyntec, 2021b). (B) N/A (C) N/A (D) N/A (E) N/A (F) N/A (G) Temporary "direct push" points (H) N/A Table 3. Injection Location Coordinates and Treatment Intervals Allegion Rocky Mount Rocky Mount, North Carolina Geosyntec ° consultants Geosyntec Consultants of NC, P.C. Injection Area DPT Injection Location ID Target Aquifer(s) ZVI? Treatment Interval (ft BLS) Monitoring Well(s) Used for Design Primary PCE Concentration(s) (µg/L) Notes High Concentration Injection Locations High Concentration Area 1 (HC1) HC1-01 Middle / Lower 18 to 32 / 40 to 50 MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-02 Middle / Lower 18 to 32 / 38 to 50 MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-03 Middle / Lower MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-04 Middle / Lower MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-05 Middle / Lower 14 to 36 / 40 to 50 MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer HC1-06 Middle / Lower MW-76S 5,630 Separate injection locations for Middle and Lower Aquifer High Concentration Area2 (HC2) HC2-01 Middle ✓ 16 to 32 MW-75S 103,000 HC2-02 Middle ✓ MW-75S 103,000 HC2-03 Middle ✓ MW-75S 103,000 HC2-04 Middle ✓ MW-75S 103,000 HC2-05 Middle ✓ MW-75S 103,000 HC2-06 Middle ✓ MW-75S 103,000 HC2-07 Middle ✓ MW-75S 103,000 HC2-08 Middle ✓ MW-75S 103,000 HC2-09 Middle ✓ MW-75S 103,000 HC2-10 Middle ✓ MW-75S 103,000 HC2-11 Middle ✓ MW-75S 103,000 HC2-12 Middle 19 to 31 MW-75S 103,000 HC2-13 Middle MW-75S 103,000 HC2-14 Middle MW-75S 103,000 HC2-15 Middle MW-75S 103,000 HC2-16 Middle 22 to 36 MW-22 6,550 HC2-17 Middle MW-22 6,550 HC2-18 Middle MW-22 6,550 HC2-19 Middle MW-75S 103,000 HC2-20 Middle 21 to 33 MW-75S 103,000 HC2-21 Middle MW-75S 103,000 HC2-22 Middle MW-75S 103,000 HC2-23 Middle MW-76S 5,630 HC2-24 Middle MW-76S 5,630 HC2-25 Middle 19 to 31 MW-76S 5,630 HC2-26 Middle MW-75S 103,000 HC2-27 Middle MW-75S 103,000 HC2-28 Middle MW-75S 103,000 HC2-29 Middle MW-75S 103,000 HC2-30 Middle MW-75S 103,000 High Concentration Area 3 (HC3) HC3-01 Middle ✓ 16 to 30 MW-78S 22,800 HC3-01 Lower 34 to 50 MW-78D 8,900 Lower injection interval at HC3-01 will not receive ZVI HC3-02 Middle .716 to 30 MW-78S 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer Lower 34 to 50 MW-78D HC3-03 Middle / Lower ✓ 16 to 30 / 34 to 50 MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-04 Middle / Lower ✓ MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-05 Middle 18 to 30 MW-78S 22,800 HC3-06 Middle MW 78S 22,800 HC3-07 Middle 18 to 30 MW-78S 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer Lower ✓ 34 to 50 MW-78D HC3-08 Middle / Lower 18 to 30 / 34 to 50 MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-09 Middle / Lower MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-10 Middle / Lower MW-78S / MW-78D 22,800 / 8,900 Separate injection locations for Middle and Lower Aquifer HC3-11 Middle 17 to 29 MW-78S 22,800 HC3-12 Middle MW-78S 22,800 HC3-13 Middle MW-78S 22,800 HC3-14 Middle MW-58S 5,400 HC3-15 Middle MW-58S 5,400 High Concentration Area 4 (HC4) HC4-01 Lower 26 to 46 MW-30 3,260 HC4-02 Lower MW-30 3,260 HC4-03 Lower MW-30 3,260 Downgradient Injection Locations Downgradient Area 1 (DGl) DG1-01 Middle 12 to 22 MW-37S 474 DG1-02 Middle MW-37S 474 DG1-03 Middle 12 to 22 MW-37S 474 DG1-04 Middle MW-37S 474 DG1-05 Middle 12 to 24 MW-37S 474 DG1-06 Middle / Lower 12 to 22 / 25 to 41 MW-37S / MW-47D 474 / 99.7 Separate injection locations for Middle and Lower Aquifer DG1-07 Middle / Lower MW-37S / MW-47D 474 / 99.7 Separate injection locations for Middle and Lower Aquifer DG1-08 Middle / Lower MW-37S / MW-47D 474 / 99.7 Separate injection locations for Middle and Lower Aquifer DG1-09 Middle / Lower MW-37S / MW-47D 474 / 99.7 Separate injection locations for Middle and Lower Aquifer DG1-10 Middle 12 to 22 MW-37S 474 DG1-11 Middle MW-37S 474 DG1-12 Middle MW-37S 474 DG1-13 Middle MW-37S 474 DG1-14 Middle MW-37S 474 Downgradient Area 2 ) DG2-01 Lower 35 to 45 MW-74D 86.6 DG2-02 Lower MW-74D 86.6 DG2-03 Lower MW-74D 86.6 DG2-04 Lower MW-74D 86.6 Downgradient Area 3 (DG3) DG3-01 Lower 38 to 50 MW-41DDR 377 DG3-02 Lower MW-41DDR 377 DG3-03 Lower MW-41DDR 377 DG3-04 Lower MW-41DDR 377 DG3-05 Lower MW-41DDR 377 DG3-06 Lower MW-41DDR 377 DG3-07 Lower MW-41DDR 377 DG3-08 Lower MW-41DDR 377 DG3-09 Lower MW-70D 172 DG3-10 Lower 40 to 50 MW-70D 172 DG3-11 Lower MW-70D 172 DG3-12 Lower MW-70D 172 Notes: 1. ft BLS indicates feet below land surface. 2. DPT indicates direct push technology. 3. PCE indicates tetrachloroethene. 4. µg/L indicates micrograms per liter. 5. ✓ indicates zero-valent iron (ZVI) is included at the location. No fill indicates ZVI will not be included. 6. Primary PCE Concentration(s) provides the most recent PCE sampling result (as of February 2021) for the monitoring well(s) used for design. 7. All locations will be confirmed in the field, based on nearby monitoring wells. 2021 Bioremediation Interim Measures Workplan Page 1 of 1 Table 4. Injection Location Volumes Allegion Rocky Mount Rocky Mount, North Carolina Geasyntec° consultants IP : ("un%Pl[nnb nl NC. PC ABC+* Amendment Injection Locations (includes ZVI) Per 2-ft Injection Interval Per Injection Location Target Aquifer Injection Area Injection Locations Treatment Interval (ft BLS) Injection Interval (ft BLS) Target ROI (ft) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) High Concentration Area - 0.3 lb of Carbon Amendment per ft3 of Treatment Volume Middle Aquifer HC2 HC2-01, HC2-02, HC2-03, HC2-04, HC2-05, HC2-06, HC2-07, HC2-08, HC2-09, HC2-10, HC2-11 16 to 32 16 to 18 14 283 109 0.65 2.264 872 5.20 18 to 20 14 283 109 0.65 20 to 22 14 283 109 0.65 22 to 24 14 283 109 0.65 24 to 26 14 283 109 0.65 26 to 28 14 283 109 0.65 28 to 30 14 283 109 0.65 30 to 32 14 283 109 0.65 HC3 HC3-01, HC3-02, HC3-03, HC3-04 16 to 30 16 to 18 14 284 108 0.65 1.988 756 4.55 18 to 20 14 284 108 0.65 20 to 22 14 284 108 0.65 22 to 24 14 284 108 0.65 24 to 26 14 284 108 0.65 26 to 28 14 284 108 0.65 28 to 30 14 284 108 0.65 Lower Aquifer HC3 HC3-03, HC3-04, HC3-07 34 to 50 34 to 36 14 288 105 0.65 2.304 840 5.20 36 to 38 14 288 105 0.65 38 to 40 14 288 105 0.65 40 to 42 14 288 105 0.65 42 to 44 14 288 105 0.65 44 to 46 14 288 105 0.65 46 to 48 14 288 105 0.65 48 to 50 14 288 105 0.65 ABC® Amendment Injection Location (no ZVI) OM Per 2-ft Injection Interval Per Injection Location Target Aquifer Injection Area Injection Locations Treatment Interval (ft BLS) Injection Interval (ft BLS) Target ROI (ft) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) High Concentration 0.3 lb of Carbon Amendment per fe of Treatment Volume Middle Aquifer HCl HC1-01,HC1-02, HC1-03,HC1-04 188032 18 to 20 14 379 83 0.65 2,653 581 4.55 20 to 22 14 379 83 0.65 22 to 24 14 379 83 0.65 24 to 26 14 379 83 0.65 26 to 28 14 379 83 0.65 28 to 30 14 379 83 0.65 30 to 32 14 379 83 0.65 HC1 HC1-05,HC1-06 14to36 14 to 16 14 382 79 0.65 4.202 869 7.15 16 to 18 14 382 79 0.65 18 to 20 14 382 79 0.65 20 to 22 14 382 79 0.65 22 to 24 14 382 79 0.65 24 to 26 14 382 79 0.65 26 to 28 14 382 79 0.65 28 to 30 14 382 79 0.65 30 to 32 14 382 79 0.65 32 to 34 14 382 79 0.65 34 to 36 14 382 79 0.65 HC2 HC2-12, HC2-13, HC2-14, HC2-15, HC2-25, HC2-26, HC2-27, HC2-28, HC2-29, HC2-30 19 to 31 19 to 21 14 377 84 0.65 2.262 504 3.90 21 to 23 14 377 84 0.65 23 to 25 14 377 84 0.65 25 to 27 14 377 84 0.65 27 to 29 14 377 84 0.65 29 to 31 14 377 84 0.65 HC2 HC2-16, HC2-17, HC2-18, HC2-19 22 to 36 22 to 24 14 379 83 0.65 2,653 581 4.55 24 to 26 14 379 83 0.65 26 to 28 14 379 83 0.65 28 to 30 14 379 83 0.65 30 to 32 14 379 83 0.65 32 to 34 14 379 83 0.65 34 to 36 14 379 83 0.65 HC2 HC2-20, HC2-21, HC2-22, HC2-23, HC-24 21 to 33 21 to 23 14 380 81 0.65 2,280 486 3.90 23 to 25 14 380 81 0.65 25 to 27 14 380 81 0.65 27 to 29 14 380 81 0.65 29 to 31 14 380 81 0.65 31 to 33 14 380 81 0.65 HC3 HC3-05, HC3-06, HC3-07, HC3-08 HC3-09, HC3-10 18 to 30 18 to 20 14 378 83 0.65 2,268 498 3.90 20 to 22 14 378 83 0.65 22 to 24 14 378 83 0.65 24 to 26 14 378 83 0.65 26 to 28 14 378 83 0.65 28 to 30 14 378 83 0.65 HC3 HC3-11, HC3-12, HC3-13, HC3-14, HC3-15 17 to 29 17 to 19 14 380 81 0.65 2,280 486 3.90 19 to 21 14 380 81 0.65 21 to 23 14 380 81 0.65 23 to 25 14 380 81 0.65 25 to 27 14 380 81 0.65 27 to 29 14 380 81 0.65 2021 Bioremediation Interim Measures Workplan Page 1 of 2 Table 4. Injection Location Volumes Allegion Rocky Mount Rocky Mount, North Carolina Geasyntec° consultants 1, Ic+� ConsRltnnb nl NC. PC ABC® Amendment Injection Location (no ZVI) Per 2-ft Injection Interval Per Injection Location Target Aquifer Injection Area Injection Locations Treatment Interval (ft BLS) Injection Interval (ft BLS) Target ROI (ft) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) Diluted Carbon Amendment Volume (gal) Anaerobic Chase Water Volume (gal) KB-1 Volume (liter) High Concentration 0.3 Ib of Carbon Amendment per ftS of Treatment Volume Lower Aquifer HC1 HC1-01,HC1-O5, HC1-06 40 to 50 40 to 42 14 387 74 0.65 1,935 370 3.25 42 to 44 14 387 74 0.65 44 to 46 14 387 74 0.65 46 to 48 14 387 74 0.65 48 to 50 14 387 74 0.65 HCl HC1-02,HC1-03, HC1-04 38to50 38 to 40 14 378 83 0.65 2,268 498 3.90 40 to 42 14 378 83 0.65 42 to 44 14 378 83 0.65 44 to 46 14 378 83 0.65 46 to 48 14 378 83 0.65 48 to 50 14 378 83 0.65 HC3 HC3-01, HC3-02,40 HC3-08 HC3-09, HC3-10 34 to 50 34 to 36 14 380 81 0.65 3.040 648 5.20 36 to 38 14 380 81 0.65 38 to 40 14 380 81 0.65 to 42 14 380 81 0.65 42 to 44 14 380 81 0.65 44 to 46 14 380 81 0.65 46 to 48 14 380 81 0.65 48 to 50 14 380 81 0.65 HC4 HC4-01, HC4-02, HC4-03 26 to 46 26 to 28 14 380 81 0.65 3,800 810 6.50 28 to 30 14 380 81 0.65 30 to 32 14 380 81 0.65 32 to 34 14 380 81 0.65 34 to 36 14 380 81 0.65 36 to 38 14 380 81 0.65 38 to 40 14 380 81 0.65 40 to 42 14 380 81 0.65 42 to 44 14 380 81 0.65 44 to 46 14 380 81 0.65 Downgradient Area - 0.30 Ib of Carbon Amendment per ft3 of Treatment Volume Middle Aquifer DG1 DG1-05 12 to 24 12 to 14 14 467 110 0.80 2.802 660 4.80 14 to 16 14 467 110 0.80 16 to 18 14 467 110 0.80 18 to 20 14 467 110 0.80 20 to 22 14 467 110 0.80 22 to 24 14 467 110 0.80 DG1 DG1-01, DG1-02, DG1-03, DG1-04, DG1-06, DG1-07, DG1-08, DG1-09, DG1-10, DG1-11, DG1-12, DG1-13, DG1-14 12 to 22 12 to 14 14 465 112 0.80 2.325 560 4.00 14 to 16 14 465 112 0.80 16 to 18 14 465 112 0.80 18 to 20 14 465 112 0.80 20 to 22 14 465 112 0.80 Lower Aquifer DG1 DG1-06, DG1-07, DG1-08, DG1-09 25 to 41 25 to 27 14 475 101 0.80 3.800 808 6.40 27 to 29 14 475 101 0.80 29 to 31 14 475 101 0.80 31 to 33 14 475 101 0.80 33 to 35 14 475 101 0.80 35 to 37 14 475 101 0.80 37 to 39 14 475 101 0.80 39 to 41 14 475 101 0.80 DG235 DG2-01, DG2-02, DG2-03, DG2-04 to 45 35 to 37 14 470 106 0.80 2,350 530 4.00 37 to 39 14 470 106 0.80 39 to 41 14 470 106 0.80 41 to 43 14 470 106 0.80 43 to 45 14 470 106 0.80 DG3 DG3-01, DG3-02, DG3-03, DG3-04, DG3-05, DG3-06, DG3-07, DG3-08, DG3-09 38 to 50 38 to 40 14 474 102 0.80 '.844 612 4.80 40 to 42 14 474 102 0.80 42 to 44 14 474 102 0.80 44 to 46 14 474 102 0.80 46 to 48 14 474 102 0.80 48 to 50 14 474 102 0.80 DG3 DG3-10, DG3-11, DG3-12 40 to 50 40 to 42 14 467 110 0.80 2,335 550 4.00 42 to 44 14 467 110 0.80 44 to 46 14 467 110 0.80 46 to 48 14 467 110 0.80 48 to 50 14 467 110 0.80 Notes: 1. ft BLS indicates feet below land surface. 2. gal indicates gallons. 3. ZVI indicates zero-valent iron. 4. Ib indicates pound. 5. ft' indicates cubic foot. 6. KB-1 Volume refs to the volume ofbioaugmentation culture required. See Work Plan for details on the selection of KB-1 versus KB-1 Plus by location. 2021 Bioremediation Interim Measures Workplan Page 2 of 2