NC0089958_Application_20210524 (2)

ROY COOPER
Governor
t
DIONNE DELLI-GATTI
Secretory
S.DANIEL SMITH NORTH CAROLINA
Director Environmental Quality
May 28, 2021
TGACSE Center Square, LLC.
Attn: Barry James, Project Manager
121 W Trade Street, Ste 2550
Charlotte, NC 28202
Subject: Permit Application
Application No. NC0089958
Central Square
Mecklenburg County
Dear Applicant:
The Water Quality Permitting Section acknowledges receipt of your application for a new NPDES WW permit, including
supporting documentation and your check number 000023 in the amount of $860.00 as payment of the application fee.
These items were received in our offices on May 24, 2021. Your application will be assigned to a permit writer within the
Section's NPDES WW permitting branch. The permit writer will contact you if additional information is required to
complete evaluation of your application. Your timely and direct response to any such request will help to expedite the
review process. Please note that acceptance of the application does not guarantee a NPDES permit will be issued for the
proposed activity. A permit will only be issued following a complete review of the application, concluding the proposed
discharge is allowable per applicable statutes and rules.
Information regarding the status of your renewal application can be found online using the Department of Environmental
Quality's Environmental Application Tracker at:
https://deq.nc.gov/permits-regulations/permit:guidance/environmental-application-tracker
If you have any additional questions about the permit, please contact the primary reviewer of the application using the
links available within the Application Tracker.
Sincerely,
Wren Th ford
Administrative Assistant
Water Quality Permitting Section
cc: Joseph Nestor-ESC SOUTHEAST, LLP.
ec: WQPS Laserfiche File w/application
E C North li Dement of m Quality I W
dS' MooresCaroville Regnaionpartal Office lab East Centerental Avenue,Suite
Division
301
of
Mooresvilaterle.NortResourcesh Carolina 28115
704.663.1699
MI°ECS SOUTHEAST LLP Setting the Standard for Service"
Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F-1078
NC Registered Geologists Firm C-553
SC Registered Engineering Firm 3239
May 19, 2021
Derek Denard
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section-NPDES
1617 Mail Service Center
Raleigh, NC 27699-1617
Reference: Application Package for a National Pollutant Discharge Elimination System (NPDES) Permit
for Construction and Permanent Dewatering
Central Square RECEIVED
Located Southwest of Intersection of Central Avenue and Pecan Avenue
Charlotte, North Carolina l 2 4 2021
NCDEQ Brownfields Project No. 24002-20-060
ECS Project No. 10756-C NCDEQ/DWR/NPDES
Dear Mr. Denard:
ECS Southeast, LLP (ECS) prepared the enclosed application package for a National Pollutant Discharge
Elimination System (NPDES) Permit on behalf of TGACSE Central Square, LLC for the discharge of treated
groundwater produced by construction and permanent dewatering. Also enclosed is the payment for the
Minor Individual Permit Fee($860.00)
If you have any questions or comments concerning the contents of the enclosed documents or other related
topics, please feel free to contact us.
Respectfully submitted,
ECS SOUTHEAST,LLP
P. )1itiw7
seph P. Nestor, P.G., P.E.Roger A. Smith, P.G.
Environmental Principal Principal Geologist
[e-mail] [e-mail]
704-280-7422 704-552-5152
Enclosure:NPDES Permit Application—Forms 1, 2C,&2E
Letter frorrr Charlotte Stormwater Services
Topographic Maps
Request for Waiver of Requirement to Monitor Certain Conventional Parameters
Line Drawing
Description of System Components
Tables for Groundwater Monitoring Data from February 2020 and August 2020
Analytical Reports-Groundwater Sample Collected in February 2020 and August 2020
Engineering Alternative Analysis
ECS Capitol Services,PLLC • ECS Florida,LLC • ECS Mid-Atlantic,LLC • ECS Midwest,LLC • ECS Southeast.LLP • ECS Southwest,LLP
www.ecslimited.com
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
Form U.S.Environmental Protection Agency
2 EPA Application for NPDES Permit to Discharge Wastewater
NPDES GENERAL INFORMATION
SECTION 1.ACTIVITIES REQUIRING AN NPDES PERMIT(40 CFR 122.21(f)and(f)(1))
1.1 Applicants Not Required to Submit Form 1
Is the facility a new or existing publicly owned Is the facility a new or existing treatment works1.1.1
treatment works?
1.1.2
treating domestic sewage?
If yes,STOP. Do NOT complete No If yes,STOP. Do NOT No
Form 1.Complete Form 2A. complete Form 1.Complete
Form 2S.
1.2 Applicants Required to Submit Form 1
1.2.1 Is the facility a concentrated animal feeding 1.2.2 Is the facility an existing manufacturing,
operation or a concentrated aquatic animal commercial,mining,or silvicultural facility that is
a production facility? currently discharging process wastewater?
o Yes 4 Complete Form 1 No Yes 4 Complete Form No
z and Form 2B. 1 and Form 2C.
1.2.3 Is the facility a new manufacturing,commercial, 1.2.4 Is the facility a new or existing manufacturing,
mining,or silvicultural facility that has not yet commercial,mining,or silvicultural facility that
commenced to discharge? discharges only nonprocess wastewater?
0 ElYes 4 Complete Form 1 No Yes 4 Complete Form 0 No
re and Form 2D. 1 and Form 2E.
1.2.5 Is the facility a new or existing facility whose
discharge is composed entirely of stormwater
associated with industrial activity or whose
discharge is composed of both stormwater and
non-stormwater?
Yes-4 Complete Form 1 0 No
and Form 2F
unless exempted by
40 CFR
122.26(b)(14)(x)or
b 15 .
SECTION 2.NAME,MAILING ADDRESS,AND LOCATION(40 CFR 122.21(f)(2))
2.1 Facility Name
Central Square
2.2 EPA Identification Number
0 New Facilty
a
2.3 Facility Contact
f/1
Name(first and last) Title Phone number
Barry James Construction Project Manager 704)414-7477
Q
cn Email address
[e-mail]
2.4 Facility Mailing Address
E
coStreet or P.O. box
c/o Crosland Southeast;201 South College Street,Suite 1300
City or town State ZIP code
Charlotte NC 28244
EPA Form 3510-1(revised 3-19) Page 1
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
N caCras Central Square
OMB No.2040-0004
w 13 2.5 Facility Location
a 47.
Street,route number,or other specific identifier
a U 1314 1318,1322,1324,1326,1330,1332,1334,1336,1400,and 1426 Central Av&1111,1113,and 1235 Pecan Av
c Countyname Countycode(if known)o
2 u Mecklenburg
ev c City or town State ZIP code
Charlotte NC 28205
SECTION 3.SIC AND NAICS CODES(40 CFR 122.21(f)(3))
3.1 SIC Code(s) Description(optional)
653100100 Real Estate Agents and Mangers
62829905 Manager Of Mutual Funds,Contract or Fee Basis
oTBD Tentants for retail space have not leased space
co 6513 Operators of Apartment Buildings
3.2 NAICS Code(s) Description(optional)
v
CO 531190 Lessors of Other Real Estate Property
rn
523920 Portfolio Management
TBD Tentants for retail space have not leased space
531311 Residential Property Managers
SECTION 4.OPERATOR INFORMATION(40 CFR 122.21(f)(4))
4.1 Name of Operator
TGACSE Central Square,LLC(Attn.Mr.Barry James)
4.2 Is the name you listed in Item 4.1 also the owner?
Yes No
4.3 Operator Status
wTIS Public—federal El Public—state Other public(specify)
Private Other(specify)
4.4 Phone Number of Operator
704)414-7477
4.5 Operator Address
o Street or P.O. Box
m c/o Crosland Southeast;201 South College Street,Suite 1300
c
c City or town State ZIP code
o v Charlote NC 28244
m
Email address of operator
[e-mail]
SECTION 5.INDIAN LAND(40 CFR 122.21(f)(5))
c 5.1 Is the facility located on Indian Land?
C J Yes No
EPA Form 3510-1(revised 3-19) Page 2
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 6.EXISTING ENVIRONMENTAL PERMITS(40 CFR 122.21(f)(6))
6.1 Existing Environmental Permits(check all that apply and print or type the corresponding permit number for each)
d NPDES(discharges to surface RCRA(hazardous wastes) UIC(underground injection of
a 'awater) fluids)
2 -
w a PSD(air emissions) Nonattainment program(CAA)NESHAPs(CAA)
x Ocean dumping(MPRSA) Dredge or fill(CWA Section 404) Other(specify)
SECTION 7.MAP(40 CFR 122.21(f)(7))
7.1 Have you attached a topographic map containing all required information to this application?(See instructions for
a. specific requirements.)
co
Yes No CAFO—Not Applicable(See requirements in Form 2B.)
SECTION 8.NATURE OF BUSINESS(40 CFR 122.21(f)(8))
8.1 Describe the nature of your business.
The site is being redeveloped as a vertically integrated mixed used project. The site will be used for office,parking
surface and below grade),retail,commercial,multifamily residential,recreational,and entertainment
U)
y
7co
O
N
is
SECTION 9.COOLING WATER INTAKE STRUCTURES(40 CFR 122.21(f)(9))
9.1 Does your facility use cooling water?
L d Yes No-3 SKIP to Item 10.1.
9.2 Identify the source of cooling water.(Note that facilities that use a cooling water intake structure as described at
E 40 CFR 125,Subparts I and J may have additional application requirements at 40 CFR 122.21(r).Consult with your
cY NPDES permitting authority to determine what specific information needs to be submitted and when.)
c c
SECTION 10.VARIANCE REQUESTS(40 CFR 122.21(f)(10))
10.1 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(m)?(Check all that
CAapply.Consult with your NPDES permitting authority to determine what information needs to be submitted and
when.)
d Fundamentally different factors(CWA Water quality related effluent limitations(CWA Section
d Section 301(n)) 302(b)(2))
Non-conventional pollutants(CWA Thermal discharges(CWA Section 316(a))
co Section 301(c)and(g))
Not applicable
EPA Form 3510-1(revised 3-19) Page 3
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
OMB No.2040-0004
SECTION 11.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d))
11.1 In Column 1 below,mark the sections of Form 1 that you have completed and are submitting with your application.
For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note
that not all applicants are required to provide attachments.
Column 1 Column 2
Section 1:Activities Requiring an NPDES Permit wl attachments
r Section 2: Name,Mailing Address,and Location w/attachments
Section 3:SIC Codes wl attachments
r Section 4:Operator Information wl attachments
Section 5: Indian Land w/attachments
r Section 6: Existing Environmental Permits wl attachments
Section 7:Map 0 matopographic
0 w/additional attachments
co
cn
o r Section 8:Nature of Business wl attachments
Section 9:Cooling Water Intake Structures w/attachments
Section 10:Variance Requests w/attachments
r Section 11:Checklist and Certification Statement wl attachments
a 11.2 Certification Statement
U
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted.Based on my inquiry of the person or persons who manage the system,or those persons
directly responsible for gathering the information,the information submitted is,to the best of my knowledge and
belief,true,accurate,and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations.
Name(print or type first and last name) Official title
fit- 16^1.0> AU S INWS
Signature Date signed
Si
EPA Form 3510-1(revised 3-19) Page 4
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ir kit„..-_ , - A, r Ne\ AI ''', ?
illrffl 144 A' P.,,..,,ft ' I I
i
i, '
I/ , . f: ,
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SCALE 1:24 000
I 0.5 C IKt_E:,MLTtxS I
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WO 5CC 0 WALKS 1DUO DOC
L`_S D No
L 7.51
MILLS 140 MILS
1000I C 1000 2000 1000 4000 51:00 8000 7000 &10C 9000 I0000 2 MMkS
FELT
UTE4 GM AND 2719 MAC F11C NORTH
DECLINATION Al CENTER OF SHEET
CONTOUR INTERVAL 10 FECT
NORTH AMERKAN VlRTKAL DATUM OF 19M
SOURCE:
FIGURE 1
USGS TOPOGRAPHIC MAP SITE TOPOGRAPHIC LOCATION MAP
CAHRLOTTE EAST CENTRAL SQUARE
liS
7.5 MINUTE QUADRANGLE Central Avenue at Pecan Avenue
DATED 2019 Charlotte, Mecklenburg,North Carolina
ECS PROJECT NO.49-10756-C
1M
a Wanton Sc
si
DISCHARGE TO r
UNNAMED TRIBUTARY r
TO LITTLE SUGAR
CREEK
OUTFALL ID
ULS020-SW0258000) k
u
o
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a V
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LEGEND
N
APPROXIMATE SITE BOUNDARY STORMWATER PIPE
r e
STORMWATER STRUCTURE EIFLOW DIRECTION s
SOURCE: I 4 FIGURE 2
VIRTUAL CHARLOTTE WEB MAPPING APPLICATION DISCHARGE LOCATION MAP
ACCESSED APRIL 5,2021 CENTRAL SQUARE
APPROXIMATE SCALE: Charlotte, MecklenburgAvenueatPecan, NorthAvenueCarolina
1 INCH=382 FEET
o 382 FEET ECS PROJECT NO.49-10756-C
L I l 1TM
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
Form U.S.Environmental Protection Agency
2C EPA Application for NPDES Permit to Discharge Wastewater
NPDES EXISTING MANUFACTURING,COMMERCIAL,MINING,AND SILVICULTURE OPERATIONS
SECTION 1.OUTFALL LOCATION(40 CFR 122.21(g)(1))
1.1 Provide information on each of the facility's outfalls in the table below.
o
Numbelr Receiving Water Name Latitude Longitude
001 Trib.to Little Sugar Creek 35° 13' 25.0"80° 19' 7.7"
0
SECTION 2.LINE DRAWING(40 CFR 122.21(g)(2))
p, 2.1 Have you attached a line drawing to this application that shows the water flow through your facility with a water
3 balance?(See instructions for drawing requirements.See Exhibit 2C-1 at end of instructions for example.)
J R
Yes No
SECTION 3.AVERAGE FLOWS AND TREATMENT(40 CFR 122.21(g)(3))
3.1 For each outfall identified under Item 1.1,provide average flow and treatment information.Add additional sheets if
necessary.
Outfall Number** 001
Operations Contributing to Flow
Operation Average Flow
Dewatering
Projected to Co Less than 0.050 mgd
c
mgd
rts
mgd
mgd
3
LL Treatment Units
Description
Code from
Final Disposal of Solid or
include size,flow rate through each treatment unit,
Table 2C-1
Liquid Wastes Other Than
cl)
retention time,etc.) by Discharge
18,000 Gallon Frac Tank 1-U Landfill
1,000 Gallon Surge Tank 1-0
Two 1,000 pound GAC vessels 2-A Landfill
EPA Form 3510-2C(Revised 3-19)Page 1
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
3.1 Ouffall Number**
cont. Operations Contributing to Flow
Operation Average Flow
mgd
mgd
mgd
mgd
Treatment Units
Description
Code from
Final Disposal of Solid or
include size,flow rate through each treatment unit,
Table 2C-1
Liquid Wastes Other Than
retention time,etc.) by Discharge
cu
0
c.)
c
m
E
is
m
Ouffall Number**
Operations Contributing to Flow
Operation Average Flow
mgd
co
mgd
mgd
mgd
Description
Code from
Final Disposal of Solid or
include size,flow rate through each treatment unit,
Table 2C-1
Liquid Wastes Other Than
retention time,etc.) by Discharge
3.2 Are you applying for an NPDES permit to operate a privately owned treatment works?
E El Yes No 4 SKIP to Section 4.
cn M 3.3 Have you attached a list that identifies each user of the treatment works?
Yes No
EPA Form 3510-2C(Revised 3-19)Page 2
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 4.INTERMITTENT FLOWS(40 CFR 122.21(g)(4))
4.1 Except for storm runoff,leaks,or spills,are any discharges described in Sections 1 and 3 intermittent or seasonal?
Yes 0 No 4 SKIP to Section 5.
4.2 Provide information on intermittent or seasonal flows for each applicable outfall.Attach additional pages,if necessary.
Outfall Operation Frecuency Flow Rate
Number list)
Average Average Long-Term Maximum Duration
Days/Week Months/Year Average Daily
days/week months/year mgd mgd days
days/week months/year mgd mgd days
days/week months/year mgd mgd days
a,
m
days/week months/year mgd mgd days
c
days/week months/year mgd mgd days
days/week months/year mgd mgd days
days/week months/year mgd mgd days
days/week months/year mgd mgd days
days/week months/year mgd mgd days
SECTION 5.PRODUCTION#40 CFR 122.21(g)(5))
5.1 Do any effluent limitation guidelines(ELGs)promulgated by EPA under Section 304 of the CWA apply to your facility?
Yes 0 No 4 SKIP to Section 6.
5.2 Provide the following information on applicable ELGs.
ELG Category ELG Subcategory Regulatory Citation
Q
5.3 Are any of the applicable ELGs expressed in terms of production(or other measure of operation)?
Yes 0 No 4 SKIP to Section 6.
0
5.4 Provide an actual measure of daily production expressed in terms and units of applicable ELGs.
J OutfallOperation,Product,or Material Quantity per Day
Unit of
Number Measure
n3
O
EPA Form 3510-2C(Revised 3-19)Page 3
EPA Identfication Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 6. IMPROVEMENTS(40 CFR 122.21(g)(6))
6.1 Are you presently required by any federal,state,or local authority to meet an implementation schedule for constructing,
upgrading,or operating wastewater treatment equipment or practices or any other environmental programs that could
affect the discharges described in this application?
Yes 0 No 4 SKIP to Item 6.3.
6.2 Briefly identify each applicable project in the table below.
Affected Final Compliance Dates
Brief Identification and Description of Outfalls Source(s)of
Project list outfall Discharge Required Projected
number)
0)da
a
6.3 Have you attached sheets describing any additional water pollution control programs(or other environmental projects
that may affect your discharges)that you now have underway or planned?(optional item)
ElYeSNC Brownfields Program No Not applicable
SECTION 7.EFFLUENT AND INTAKE CHARACTERISTICS(40 CFR 122.21(g)(7))
See the instructions to determine the pollutants and parameters you are required to monitor and, in turn,the tables you must
complete.Not all applicants need to complete each table.
Table A.Conventional and Non-Conventional Pollutants
7.1 Are you requesting a waiver from your NPDES permitting authority for one or more of the Table A pollutants for any of
your outfalls?
II Yes No 4 SKIP to Item 7.3.
7.2 If yes,indicate the applicable outfalls below.Attach waiver request and other required information to the application.
Outfall Number 001 Outfall Number Outfall Number
7.3 Have you completed monitoring for all Table A pollutants at each of your outfalls for which a waiver has not been
N requested and attached the results to this application package?
No;a waiver has been requested from myNPDES
Yes with the exception of TSS for which q
fC sampling not practicable at this time. permitting authority for all pollutants at all outfalls.
Table B.Toxic Metals,Cyanide,Total Phenols,and Organic Toxic Pollutants
7.4 Do any of the facility's processes that contribute wastewater fall into one or more of the primary industry categories
listed in Exhibit 2C-3?(See end of instructions for exhibit.)
Yes No 4 SKIP to Item 7.8.
7.5 Have you checked`Testing Required"for all toxic metals,cyanide,and total phenols in Section 1 of Table B?
Yes No
7.6 List the applicable primary industry categories and check the boxes indicating the required GC/MS fraction(s)identified
in Exhibit 2C-3.
Primary Industry Category
Required GC/MS'Fraction(s)
Check applicable boxes.)
Volatile 0 Acid 0 Base/Neutral 0 Pesticide
Volatile 0 Acid Base/Neutral Pesticide
0 Volatile 0 Acid 0 Base/Neutral 0 Pesticide
EPA Form 3510-2C(Revised 3-19)Page 4
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
7.7 Have you checked"Testing Required"for all required pollutants in Sections 2 through 5 of Table B for each of the
GC/MS fractions checked in Item 7.6?
Yes No
7.8 Have you checked"Believed Present"or"Believed Absent"for all pollutants listed in Sections 1 through 5 of Table B
where testing is not required?
Yes No
7.9 Have you provided(1)quantitative data for those Section 1,Table B,pollutants for which you have indicated testing is
required or(2)quantitative data or other required information for those Section 1,Table B,pollutants that you have
indicated are"Believed Present"in your discharge?
El Yes No
7.10 Does the applicant qualify for a small business exemption under the criteria specified in the instructions?
Yes 4 Note that you qualify at the top of Table B,
No
then SKIP to Item 7.12.
5 7.11 Have you provided(1)quantitative data for those Sections 2 through 5,Table B,pollutants for which you have
o determined testing is required or(2)quantitative data or an explanation for those Sections 2 through 5,Table B,
pollutants you have indicated are"Believed Present"in your discharge?
0 Yes NoN
W Table C.Certain Conventional and Non-Conventional Pollutants
12 7.12 Have you indicated whether pollutants are"Believed Present"or"Believed Absent"for all pollutants listed on Table C
c for all outfalls?
El Yes No
0 7.13 Have you completed Table C by providing(1)quantitative data for those pollutants that are limited either directly or
indirectly in an ELG and/or(2)quantitative data or an explanation for those pollutants for which you have indicated
Believed Present"?
0 Yes No
Table D.Certain Hazardous Substances and Asbestos
7.14 Have you indicated whether pollutants are"Believed Present"or"Believed Absent"for all pollutants listed in Table D for
all outfalls?
ElYes No
7.15 Have you completed Table D by(1)describing the reasons the applicable pollutants are expected to be discharged
and(2)by providing quantitative data,if available?
r Yes No
Table E.2,3,7,8-Tetrachlorodibenzo-p-Dioxin(2,3,7,8-TCDD)
7.16 Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the instructions,or do you
know or have reason to believe that TCDD is or may be present in the effluent?
Yes 4 Complete Table E. E No 4 SKIP to Section 8.
7.17 Have you completed Table E by reporting qualitative data for TCDD?
Yes No
SECTION 8.USED OR MANUFACTURED TOXICS(40 CFR 122.21(g)(9))
8.1 Is any pollutant listed in Table B a substance or a component of a substance used or manufactured at your facility as
an intermediate or final product or byproduct?
Yes No- SKIP to Section 9.
8.2 List the pollutants below.
Tc
1. 4. 7.
0
2. 5. 8.
3. 6. 9.
PA Form 3510-2C(Revised 3-19)Page 5
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 9. BIOLOGICAL TOXICITY TESTS(40 CFR 122.21(g)(11))
9.1 Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made
within the last three years on(1)any of your discharges or(2)on a receiving water in relation to your discharge?
Yes No 4 SKIP to Section 10.
9.2 Identify the tests and their aurposes below.
Test(s) Purpose of Test(s)
Submitted to NPDES
Date Submitted
Permittin. Authorit ?
0
Yes No
0
0
m Yes No
Yes No
SECTION 10.CONTRACT ANALYSES(40 CFR 122.21(g)(12))
10.1 Were any of the analyses reported in Section 7 performed by a contract laboratory or consulting firm?
Yes No 4 SKIP to Section 11.
10.2 Provide information for each contract laboratory or consulting firm below.
Laboratory Number 1 Laboratory Number 2 Laboratory Number 3
Name of laboratory/firm
Pace Analytical Services,LLC
Laboratory address
9800 Kincey Ave;Suite 100
Huntersville,NC 208078
0
Co
r_
c0 Phone number
704)875-9092
Pollutant(s)analyzed
cots,SV0Cs,metals
SECTION 11.ADDITIONAL INFORMATION(40 CFR 122.21(g)(13))
11.1 Has the NPDES permitting authority requested additional information?
a Yes No 4 SKIP to Section 12.
0
E 11.2 List the information requested and attach it to this application.
1. 4.
Coa0
0 2. 5.
0
3. 6.
EPA Form 3510-2C(Revised 3-19)Page 6
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 12.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d))
12.1 In Column 1 below,mark the sections of Form 2C that you have completed and are submitting with your application.
For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note
that not all applicants are required to complete all sections or provide attachments.
Column 1 Column 2
Section 1:Outfall Location r wl attachments
Section 2:Line Drawing w/line drawing r wl additional attachments
ui Section 3:Average Flows and
wl list of each user of
Treatment
w/attachments ID privately owned treatment
works
ElSection 4: Intermittent Flows w/attachments
ElSection 5: Production w/attachments
w/optional additional
ElSection 6: Improvements w/attachments 0 sheets describing any
additional pollution control
plans
wl request for a waiver and w/explanation for identical
supporting information outfalls
w/small business exemption
wl other attachments
request
Section 7:Effluent and Intake
w/Table A Elw/Table BCharacteristics
C0
El w/Table C 0 w/Table D
w/Table E
w/analytical results as an
c attachment
Section 8:Used or Manufactured
w/attachments
Toxics
Section 9:Biological Toxicity w/attachments
Tests
U
0 Section 10:Contract Analyses w/attachments
Section 11:Additional Information w/attachments
Section 12:Checklist and
El w/attachments
Certification Statement
12.2 Certification Statement
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted.Based on my inquiry of the person or persons who manage the system,or those persons directly
responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,
accurate,and complete.I am aware that there are significant penalties for submitting false information,including the
possibility of fine and imprisonment for knowing violations.
Name(print or type first and last name) Official title
rA Mtkdi S A X Said
Signature Date sig ed
9-6 I
EPA Form 3510-2C(Revised 3-19)Page 7
i
This page intentionally left blank.
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001 OMB No.2040-0004
TABLE A.CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(iii))1
Effluent Intake
Waiver
Optional)
Pollutant Requested
Units Maximum Maximum Long-Term
if applicable
este
specify) Daily Monthly Average Daily Number of Long-Term Number of
Discharge Discharge Discharge Analyses Average Value Analyses
required) if available) if available)
Check here if you have applied to your NPDES permitting authority for a waiver for all of the pollutants listed on this table for the noted outfall.
Biochemical oxygen demand
Concentration
1' (
BODe)
Mass
Chemical oxygen demand
Concentration
2'
COD)
Mass
Concentration
3. Total organic carbon(TOC)
Mass
Concentration It is not practical to sample collect samples for TSS until dewatering apperatus
4. Total suspended solids(TSS) is in place. We anticipate maximum daily and monthly TSS to be less than 45 —Mass
and 30 mg/L, respectively.
Concentration
5. Ammonia(as N)
Mass
6. Flow Rate It is not practical to monitor flow until dewatering apperatus is in place. We
anticipate maximum daily flow to be less than 50.000GPD or 0.05 MGD.
Temperature(winter) C C
7.
Temperature(summer) C C
pH(minimum) Standard units s.u.
8.
pH(maximum) Standard units s.u.
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2C(Revised 3-19)Page 9
This page intentionally left blank.
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))'
Presence or Absence
check one) Effluent
Intake
optional)
Pollutant/Parameter Testing Units
Maximum Maximum Long-Term
and CAS Number,if available) Required Believed Believed specify) Average Number Long- Number
Present Absent Daily Monthly Term
Discharge ' Discharge Daily of
Average
of
required) (if available)
Dischar(
ifavailable)
ge Analyses
Value
Analyses
Check here if you qualify as a small business per the instructions to Form 2C and,therefore,do not need to submit quantitative data for any of the organic toxic pollutants in Sections
1-1 2 through 5 of this table.Note,however,that you must still indicate in the appropriate column of this table if you believe any of the pollutants listed are present in your discharge.
Section 1.Toxic Metals,Cyanide,and Total Phenols
Antimony,total Concentration
1.1 (
7440-36-0) Mass
Arsenic,total Concentration
1.2 (
7440-38-2) Mass
1.3
Beryllium,total Concentration
7440-41-7) Mass
1.4
Cadmium,total 0
Concentration
It is not practical to collect effluent samples until dewatering7440-43-9) Mass
apperatus is in place. The maximum Chromium detected in
1.5
Chromium,total CI U
Concentration
Groundwater is 128 ug/L.7440-47-3) Mass
Copper,total Concentration
1.6 (
7440-50-8) Mass
Lead,total
El 0
Concentration
1.7 (
7439-92-1) Mass
1.8 Mercury,total Concentration
7439-97-6) Mass
1.9
Nickel,total Concentration
El El7440-02-0) Mass
Selenium,total Concentration
1.10 (
7782-49-2) Mass
Silver,total Concentration
1.11 (
7440 22 4) 0
Mass
EPA Form 3510-2C(Revised 3-19)Page 11
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
OMB No.2040-0004CentralSquare001
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long• Number
Present Absent Daily Monthly Daily of
Term
of
Discharge Discharge
Discharge Analyses
Average
Analyses
required) (if available) (
if available)
Value
Thallium,total Concentration
1.12 (
7440-28-0) Mass
Zinc,total Concentration
1.13 (
7440-66-6) Mass
1.14
Cyanide,total El
Concentration
57-12-5) Mass
1.15 Phenols,total I 0
Concentration
I Mass
Section 2.Organic Toxic Pollutants(GCIMS Fraction—Volatile Compounds)
2.1
Acrolein Concentration
107-02-8) Mass
Acrylonitrile El
Concentration
2.2 El El107-13-1) Mass
2.3
Benzene Concentration
71-43-2) Mass
2.4
Bromoform Concentration
El 0
75-25-2) Mass
2.5
Carbon tetrachloride ElConcentration
56-23-5) Mass •
Chlorobenzene z
Concentration
2.6 El 0108-90-7) Mass
Chlorodibromomethane Concentration
2.7 El 0124-48-1) Mass
2.8
Chloroethane Concentration
75-00-3) Mass
EPA Form 3510-2C(Revised 3-19)Page 12
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))l
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
of of
Discharge
d
Discharge)
f available)
DisDcharge Analyses
Averageaily
Value
Analyses
if available)
2.9
2-chloroethylvinyl ether Concentration
110-75-8) Mass
2.10 Chloroform(67-66-3) PI 1
Concentration
KM 1It is not practical to collect effluent samples until dewatering
2.11
Dichlorobromomethane Concentration apperatus is in place. The maximum Chloroform detected in
75 27 4) Mass Groundwater is 9.2 ug/L. The maximum Dichlorobromethane
2.12
1,1-dichloroethane Concentration detected in Groundwater is 1.9 ug/L.
75-34-3) Mass
2.13
12-dichloroethane
tEl
Concentration
107-06-2) Mass
2.14
1,1-dichloroethylene Concentration
75-35-4)
r
Mass
2.15
1,2-dichloropropane Concentration
r
78-87-5) Mass
2.16
13-dichloropropylene Concentration
542-75-6) Mass
2.17
Ethylbenzene Concentration
100-41-4) Mass
2 18
Methyl bromide Concentration
El El r
74-83-9) Mass
2.19
Methyl chloride Concentration
74-87-3) Mass
2.20
Methylene chloride 0
Concentration
75-09-2) Mass
2.21
1,1,2,2-tetrachloroethane Concentration
El I=179-34-5)
r
Mass
EPA Form 3510-2C(Revised 3-19)Page 13
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
OMB No.2040-0004
Central Square 001
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long Number
Present Absent Daily Monthly Term
Discharge Discharge Daily of
Average
of
required) (if available)
Dischar(
ifavailable)
ge Analyses
Value
Analyses
2.22
Tetrachloroethylene Concentration
127-18-4) Mass
2.23
Toluene 0
Concentration
108-88-3) Mass
2.24
1,2-trans-dichloroethylene 0
Concentration
156-60-5) Mass
2.25
1,1,1-trichloroethane Concentration
71-55-6) Mass
2.26
1 1,2-trichloroethane Concentration
79-00-5) Mass
2.27
Trichloroethylene 0
Concentration
79-01-6) Mass
2 28
Vinyl chloride 0 0
Concentration
75-01-4) Mass
Section 3.Organic Toxic Pollutants(GC/MS Fraction—Acid Compounds)
3.1
2-chlorophenol Concentration
95-57-8) Mass
2,4-dichlorophenol Concentration
3.2 (
120-83-2) Mass
2,4-dimethylphenol 0
Concentration
3.3 El 0105-67-9) Mass
4,6-dinitro-o-cresol Concentration
3.4 (
534-52-1) 0 0
Mass
3.5
2 4-dinitrophenol Concentration
51-28-5) Mass
EPA Form 3510-2C(Revised 3-19)Page 14
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J
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))l
Presence or Absence
check one) Effluent Intake
optional)
PollutantlParameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long-and
Present Absent Daily Monthly Term
Discharge Discharge Daily of
Average
of
required) (if available)
Discharge Analyses
Value
Analyses
if available)
3,4-be nzofluoranthene Concentration
4.7 (
205-99-2) CI CI
Mass
Benzo(ghi)perylene Concentration
4.8 (
191-24-2) Mass
Benzo(k)fluoranthene Concentration
4.9 (
207-08-9) ID
Mass
4.10
Bis(2-chloroethoxy)methane 0
Concentration
111-91-1) Mass
4.11
Bis(2-chloroethyl)ether Concentration
111-44-4) Mass
4.12
Bis(2-chloroisopropyl)ether CIConcentration102-80-1) Mass
Bis(2-ethylhexyl)phthalate 0
Concentration
4.13 CI 0117-81-7) Mass
4-bromophenyl phenyl ether
0
Concentration
4.14 I:I El101-55-3) Mass
4.15
Butyl benzyl phthalate CI CIConcentration
85-68-7) Mass
4.16
2-chloronaphthalene CI
Concentration
91-58-7) Mass
4-chlorophenyl phenyl ether 0
Concentration
4.17 CI CI7005-72-3) Mass
4.18
Chrysene Concentration
CI CI CI218-01-9) Mass
4.19
Dibenzo(a,h)anthracene CI CI
Concentration
53-70-3) Mass
EPA Form 3510-2C(Revised 3-19)Page 16
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001 OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
Intake 1
check one) Effluent
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
of of
Discharge Dd) ischarge
DisDcharge Analyses
Averageaily
Value
Analyses
if available)
4.20
12-dichlorobenzene Concentration
95-50-1) Mass
4.21
1,3-dichlorobenzene 0
Concentration
541-73-1) Mass
4 22
1,4-dichlorobenzene Concentration
106-46-7) Mass
4.23
3,3-dichlorobenzidine Concentration
91-94-1) Mass
4.24
Diethyl phthalate 0
Concentration
El El84-66-2) Mass
Dimethyl phthalate Concentration
4.25 (
131-11-3) Mass
4.26
Di-n-butyl phthalate Concentration
84-74-2) Mass
4.27
2,4-dinitrotoluene Concentration
0 El121-14-2) Mass
4.28
2,6-dinitrotoluene 0
Concentration
0 El606-20-2) Mass
4.29
Di-n-octyl phthalate 0
Concentration
117-84-0) Mass
4.30
1,2-Diphenylhydrazine
0
Concentration
as azobenzene)(122-66-7) Mass
4.31
Fluoranthene Concentration
206-44-0) Mass
4.32
Fluorene
0
Concentration
El 086-73-7) Mass
EPA Form 3510-2C(Revised 3-19)Page 17
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
OMB No.2040-0004
Central Square 001
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
of of
Discharge Discharge
Discharge Analyses
Average
Analyses
required) (if available) (
if available)
Value
4.33
Hexachlorobenzene Concentration
118-74-1) Mass
4.34
Hexachlorobutadiene D
Concentration
87-68-3) Mass
4.35
Hexachlorocyclopentadiene Concentration i
El 077-47-4) Mass
4.36
Hexachloroethane 0
Concentration
El 067-72-1) Mass
4.37
Indeno(1,2,3-cd)pyrene Concentration
193-39-5) Mass
4.38
Isophorone 0
Concentration
El 078-59-1) Mass
4.39
Naphthalene 0
Concentration
91-20-3) Mass
4.40
Nitrobenzene 0
Concentration
0 098-95-3) Mass
4.41
N-nitrosodimethylamine Concentration
62-75-9) Mass
4.42
N-nitrosodi-n-propylamine Concentration
I=1 El El
621-64-7) Mass
4.43
N-nitrosodiphenylamine 0 0
Concentration
DI86-30-6) Mass
4.44
Phenanthrene 0
Concentration
CI El
85-01-8) Mass
Pyrene Concentration
4.45 (
129-00-0) El El
Mass
EPA Form 3510-2C(Revised 3-19) Page 18
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))l
Presence or Absence
Intakecheckone) Effluent
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
of of
Discharge Discharge
DisDcharge Analyses
Average
Analyses
required) (if available) Value
if available)
i 4.46
1,2,4-trichlorobenzene Concentration
120-82-1) Mass
Section 5.Organic Toxic Pollutants(GC/MS Fraction—Pesticides)
Aldrin Concentration
5.1 (
309-00-2) El
Mass
a-BHC Concentration
5.2 (
319-84-6) El
Mass
Q-BHC Concentration
5.3 (
319-85-7) Mass
5.4 y-BHC
El
Concentration
58-89-9) Mass
b-BHC Concentration
5.5 (
319-86-8) Mass
5.6
Chlordane Concentration
57-74-9) Mass
5.7
4,4'-DDT Concentration
El El 050-29-3) Mass
5.8
4,4'-DDE Concentration
72-55-9) Mass
5.9
4,4'-DDD Concentration
72-54-8) Mass
5.10
Dieldrin Concentration
0 060-57-1) 0
Mass
5.11
a-endosulfan Concentration
115-29-7) Mass
EPA Form 3510-2C(Revised 3-19)Page 19
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05119
Central Square 001 OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
of of
Discharge Discharge
DisDchar a Analyses
Average
Analyses
required) (if available) (
if available) Value
R-endosulfan Concentration
5.12 (
115-29-7) Mass
Endosulfan sulfate Concentration
5.13 (
1031-07-8) El
Mass
5.14
Endrin Concentration
El I:(72-20-8) Mass
Endrin aldehyde Concentration
5.15 (
7421-93-4) 0
Mass
5.16
Heptachlor Concentration
ID 11(76-44-8) Mass
Heptachlor epoxide Concentration
5.17 (1024-57-3) 0
Mass
PCB-1242 Concentration
5.18 (53469-21-9) 0 0 0
Mass
PCB-1254 Concentration
5.19 (11097-69-1) Mass
PCB-1221 Concentration
5.20 (11104-28-2) 0 0 0
Mass
PCB-1232 Concentration
5.21 (11141-16-5) Mass
PCB-1248 Concentration
5.22 (12672-29-6) Mass
PCB-1260 Concentration
5.23 (11096-82-5) 0 0
Mass
PCB-1016 Concentration
5.24 (12674-11-2)
I
Mass
EPA Form 3510-2C(Revised 3-19) Page 20
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence Intake
check one) Effluent
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long-Number
Present Absent Daily Monthly Daily of
Term
of
D(
req fired a Df available)
ischarge
Discharge Analyses AValuee Analyses
if available)
Toxaphene Concentration
5.25 (8001-35-2) El 0
Mass
I Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2C(Revised 3-19) Page 21
This page intentionally left blank.
i EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square
OMB No.2040-0004
TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))l
Presence or Absence
check one) Effluent Intake
Optional)
Pollutant Units Maximum Long-TermBelievedBelievedspecify) Maximum Daily Long-Term
Present Absent Discharge Monthly Average Daily Number of
Average
Number of
required) Discharge Discharge Analyses
Value
Analyses
if available)if available)
Check here if you believe all pollutants on Table C to be present in your discharge from the noted outfall.You need not complete the"Presence or Absence"column of Table C for
each pollutant.
Check here if you believe all pollutants on Table C to be absent in your discharge from the noted outfall.You need not complete the"Presence or Absence"column of Table C for
each pollutant.
1 Bromide Concentration
24959-67-9) Mass
Chlorine,total Concentration
2'
residual Mass
Concentration
3. Color 0 0
Mass
Concentration
4. Fecal coliform 0 0
Mass
5 Fluoride 0 0
Concentration
16984-48-8)Mass
Concentration
6 Nitrate-nitrite 0 0
Mass
Nitrogen,total Concentration
7.
organic(as N) Mass
Concentration
8. Oil and grease 0 0
Mass
Phosphorus(as Concentration
9.
P),total(7723-14-0)
El
10.
Sulfate(as SO4) Concentration
14808-79-8) Mass
Concentration
11. Sulfide(as S) 0
Mass
EPA Form 3510-2C(Revised 3-19)Page 23
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
OMB No.2040-0004
Central Square
TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1
Presence or Absence
check one) Effluent Intake
Optional)
UnitsPollutant Maximum Long-Term 1BelievedBelievedspecify) Maximum Daily Long-Term
Present Absent Discharge Monthly Average Daily Number of
Average
Number of
Discharge Discharge Analyses Analyses
required)
if available)if available)
Value
12. Sulfite(as SO3) Concentration
14265-45-3)Mass
Concentration
13. Surfactants
Mass
14. Aluminum,total Concentration
7429-90-5) Mass
15. Barium,total Concentration
7440-39-3) Mass
16. Boron,total Concentration
7440-42-8) Mass
17.
Cobalt,total El
Concentration
7440-48-4) Mass
18 Iron,total 0
Concentration
7439-89-6) Mass
19 Magnesium,total Concentration
7439-95-4) Mass
Molybdenum, Concentration
20. total 0
Mass7439-98-7)
21. Manganese,total Concentration
7439-96-5) Mass
22. Tin,total Concentration
7440-31-5) Mass
23 Titanium,total ID
Concentration
7440-32-6) Mass
EPA Form 3510-2C(Revised 3-19) Page 24
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square
OMB No.2040-0004
ABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1
Presence or Absence
Intake
check one) Effluent
Optional)
UnitsPollutant Maximum Long-TermBelievedBelievedspecify) Maximum Dail Lon -Term
Present Absent Discharge
y Monthly Average Daily Number of
Average
Number of
required) Discharge Discharge Analyses
Value
Analyses
if available)if available)
24. Radioactivity
Concentration
Alpha,total
Mass
Concentration
Beta,total
Mass
Concentration
Radium,total
Mass
Concentration
Radium 226,total
Mass
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2C(Revised 3-19) Page 25
This page intentionally left blank.
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 12221(g)(7)(vii))l
Presence or Absence
Pollutant check one)
Reason Pollutant Believed Present in Discharge Available Quantitative Data
Believed Believed specify units)
Present Absent
1. Asbestos CI
2. Acetaldehyde r
3. Allyl alcohol r
4. Allyl chloride 0
1
5. Amyl acetate 0 0
6. Aniline 0 r
7. Benzonitrile 0 r
8. Benzyl chloride 0
9. Butyl acetate r
10. Butylamine 0
11. Captan r
12. Carbaryl r
13. Carbofuran 0 CI
14. Carbon disulfide 0 0
15. Chlorpyrifos r
16. Coumaphos 0
17. Cresol 0 r
18. Crotonaldehyde 0 0
19. Cyclohexane 0 r
EPA Form 3510-2C(Revised 3-19) Page 27
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001 OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))l
Presence or Absence
Pollutant check one)
Reason Pollutant Believed Present in Discharge Available Quantitative Data
Believed Believed specify units)
Present Absent
20. 2,4-D(2,4-dichlorophenoxyacetic acid) 0
21. Diazinon 0 0
22. Dicamba 0
23. Dichlobenil 0 0
24. Dichlone 0 0
25. 2,2-dichloropropionic acid 0 0
26. Dichlorvos 0 0
27. Diethyl amine 0 0
28. Dimethyl amine 0 0
29. Dintrobenzene 0
30. Diquat 0 0
31. Disulfoton 0 0
32. Diuron 0 0
33. Epichlorohydrin 0
34. Ethion 0 0
35. Ethylene diamine 0 0
36. Ethylene dibromide 0 0
37. Formaldehyde 0 0
38. Furfural 0 0
EPA Form 3510-2C(Revised 3-19) Page 28
1
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))1
Presence or Absence
Pollutant check one) Available Quantitative Data
Believed Believed Reason Pollutant Believed Present in Discharge
specify units)
Present Absent
39. Guthion
40. Isoprene 0
41. Isopropanolamine 0
42. Kelthane r
43. Kepone
44. Malathion 0 r
45. Mercaptodimethur r
46. Methoxychlor 0
47. Methyl mercaptan
48. Methyl methacrylate 0
49. Methyl parathion 0
50. Mevinphos
51. Mexacarbate 0
52. Monoethyl amine 0
53. Monomethyl amine 0 r
54. Naled 0 El
55. Naphthenic acid El
56. Nitrotoluene 0 r
57. Parathion El
EPA Form 3510-2C(Revised 3-19)Page 29
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001 OMB No.2040-0004
i
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 12221(g)(7)(vii))l
Presence or Absence
Pollutant check one) Available Quantitative Data
Believed Believed Reason Pollutant Believed Present in Discharge
specify units)
Present Absent
58. Phenolsulfonate 0
59. Phosgene 0
60. Propargite 0
61. Propylene oxide 0
62. Pyrethrins 0
63. Quinoline 0
64. Resorcinol 0
65. Strontium 0
66. Strychnine 0
67. Styrene 0
68.
2,4,5-T(2,4,5-trichlorophenoxyacetic 0acid)
69. TDE(tetrachlorodiphenyl ethane) 0
70. 2,4,5-TP[2-(2,4,5-trichlorophenoxy)
propanoic acid]
71. Trichlorofon 0
72, Triethanolamine 0
73. Triethylamine 0 0
74. Trimethylamine 0
75. Uranium 0
76. Vanadium 0
EPA Form 3510-2C(Revised 3-19)Page 30
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))l
Presence or Absence
Pollutant check one) Available Quantitative Data
Believed Believed
Reason Pollutant Believed Present in Discharge
specify units)
Present Absent
77. Vinyl acetate
78. Xylene 0
79. Xylenol 0
80. Zirconium 0 0
Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2C(Revised 3-19) Page 31
This page intentionally left blank.
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square
OMB No.2040-0004
TABLE E.2,3,7,8 TETRACHLORODIBENZO P DIOXIN(2,3,7,8 TCDD)(40 CFR 122.21(g)(7)(viii))
TCDD Presence or
Congeners
Absence
Pollutant
Used or
check one) Results of Screening Procedure
Manufactured
Believed Believed
Present Absent
2,3,7,8-TCDD
EPA Form 3510-2C(Revised 3-19)Rage 33
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FIGURE 1
USGS TOPOGRAPHIC MAP SITE TOPOGRAPHIC LOCATION MAP
CAHRLOTTE EAST CENTRAL SQUARE
7.5 MINUTE QUADRANGLE Central Avenue at Pecan Avenue
111111111
DATED 2019 Charlotte, Mecklenburg,North Carolina
ECS PROJECT NO.49-10756-C
TM
Jrs, Z
Y
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4• DISCHARGE TO
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OUTFALL ID
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LEGEND
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APPROXIMATE SITE BOUNDARY STORMWATER PIPE
Yi e
STORMWATER STRUCTURE a FLOW DIRECTION s
SOURCE: FIGURE 2
VIRTUAL CHARLOTTE WEB MAPPING APPLICATION DISCHARGE LOCATION MAP
ACCESSED APRIL 5,2021 CENTRAL SQUARE
Central Avenue at Pecan Avenue
APPROXIMATE SCALE: Charlotte, Mecklenburg, North Carolina
1 INCH=382 FEET
0 382 FEETMit;INS ECS PROJECT NO.49-10756-C
I TM
LINE DRAWING
CENTRAL SQUARE
NPDES PERMIT APPLICATION FOR GROUNDWATER PRODUCED BY DEWATERING
ECS PROJECT NO. 10756-C
CO2 GAS FOR PH ADJUSTMENT
CARBON VESSELS
AS NEEDED) NOS.1&2
PARTICULATE FILTERS (
1,000 POUNDS GAC EACH)
NOS.1&2
50,000 GPD
50,000 GPD O TO OUTFACE 001
FROM DEWATERING 18,000-GAL 1,000-GAL
FRAC TANK MIXING/SURGE
TANK 0
RECIRCULATION/MIXING LOOP
14,440 GPD
ITEMS SHOWN IN RED WILL BE REMOVED WHEN
DEWATERING OPERATIONS TRANSITION FROM
CONSTRUCTION DEWATERING TO PERMANENT
BUILDING DEWATERING
1—`..._.___
SYSTEM NOTES
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Comr..rm,.* Updated March 27,2020 by ECD
ECS SOUTHEAST, SettingLLP the Standard for Service"
Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F-1078
NC Registered Geologists Firm C-553
SC Registered Engineering Firm 3239
May 19, 2021
Derek Denard
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section - NPDES
1617 Mail Service Center
Raleigh, NC 27699-1617
Reference: Request for Waiver for Monitoring of Certain Conventional Parameters
Submitted with Application for
National Pollutant Discharge Elimination System (NPDES) Permit for Construction and
Permanent Dewatering
Central Square
Located Southwest of Intersection of Central Avenue and Pecan Avenue
Charlotte, North Carolina
ECS Project No. 10756-C
Dear Mr. Denard:
ECS Southeast, LLP (ECS) requests on behalf of its client TGACSE Central Square, LLC that certain
conventional parameters not be required for the proposed discharge as shown in NPDES Permit
Application Form 2C. Specifically, it is requested that monitoring for Biological Oxygen Demand,
Chemical Oxygen Demand, Total Organic Carbon, Ammonia, Temperature (winter), and Temperature
summer) not be required as part of the permit.
As described in the application package the discharge is for construction and permanent dewatering
and the aforementioned parameters are not applicable for the indicated discharge. Summary data
tables and laboratory results are included in the application package for groundwater monitoring that
has been performed at the site.
If you have any questions or comments concerning this waiver request or other related topics, please feel
free to contact us.
Respectfully submitted,
ECS SOUTHEAST, LLP
P. Atwi
seph P. Nestor, P.G., P.E.R ger A. mith, P.G.
Environmental Principal Principal Geologist
[e-mail] [e-mail]
704-280-7422 704-552-5152
ECS Capitol Services,PLLC • ECS Florida,LLC • ECS Mid-Atlantic,LLC • ECS Midwest,LLC • ECS Southeast,LLP • ECS Southwest,LLP
www.ecslimited.com
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Crown Central
OMB No.2040-0004
U.S.Environmental Protection Agency
FORM Application for NPDES Permit to Discharge Wastewater
2E
NPDES
a EPA MANUFACTURING,COMMERCIAL,MINING,AND SILVICULTURAL FACILITIES WHICH
DISCHARGE ONLY NONPROCESS WASTEWATER
SECTION 1.OUTFALL LOCATION(40 CFR 122.21(h)(1))
1.1 Provide information on each of the facility's outfalls in the table below.
c
Outfall
Receiving Water Name Latitude Longitude
Co
Number
c 001 Trib.to Little Sugar Creek 35° 13' 25.0"80° 19' 7.7"
To
0
SECTION 2.DISCHARGE DATE(40 CFR 122.21(h)(2))
rn 2.1 Are you a new or existing discharger?(Check only one response.)
c R New discharger El Existing discharger 4 SKIP to Section 3.
2.2 Specify your anticipated discharge date:O 11/01/2021
SECTION 3.WASTE TYPES(40 CFR 122.21(h)(3))
3.1 What types of wastes are currently being discharged if you are an existing discharger or will be discharged if you are a
new discharger?(Check all that apply.)
Sanitary wastes Other nonprocess wastewater(describe/explain
ElRestaurant or cafeteria waste directly below)
a Non-contact cooling water
Groundwater from dewatering
I— 3.2 Does the facility use cooling water additives?
Yes No 4 SKIP to Section 4.
3.3 List the cooling water additives used and describe their composition.
Cooling Water Additives Composition of Additives
list) if available to you)
SECTION 4.EFFLUENT CHARACTERISTICS(40 CFR 122.21(h)(4))
4.1 Have you completed monitoring for all parameters in the table below at each of your outfalls and attached the results to
this application package?
Yes a No;a waiver has been requested from my NPDES permitting authority
attach waiver request and additional information)4 SKIP to Section 5.
4.2 Provide data as requested in the table below.1 (See instructions for specifics.)
Number of Maximum Daily Average Daily Source
Parameter or Pollutant Analyses Discharge Discharge (use codes
if actual data specify units) specify units) per
reported) Mass Conc. Mass Conc. instructions)
co Biochemical oxygen demand(BOD5)
41
Total suspended solids(TSS)
41 Oil and grease
Ammonia(as N)
Discharge flow
pH(report as range)
Temperature(winter)
Temperature(summer)
Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant
parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2E(revised 3-19) Page 1
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Crown Central OMB No.2040-0004
4.3 Is fecal coliform believed present,or is sanitary waste discharged(or will it be discharged)?
Yes El No 4 SKIP to Item 4.5.
4.4 Provide data as requested in the table below.1 (See instructions for specifics.)
Number of Maximum Daily Average Daily Source
Parameter or Pollutant Analyses Discharge Discharge (Use codes
if actual data specify units) specify units) per
reported) Mass Conc. Mass Conc. Instructions.)
Fecal coliform
0 E.coila)
c Enterococci
4-2
c0 4.5 Is chlorine used(or will it be used)?
cn ElYes El No 4 SKIP to Item 4.7.
4.6 Provide data as requested in the table below.t(See instructions for specifics.)
Number of Maximum Daily Average Daily Source
cc
Parameter or Pollutant Analyses Discharge Discharge (use codes
if actual data specify units) specify units) per
reported) Mass Conc. MassConc. instructions)
c
Total Residual Chlorine
w 4.7 Is non-contact cooling water discharged(or will it be discharged)?
Yes ElNo 4 SKIP to Section 5.
4.8 Provide data as requested in the table below.1 (See instructions for specifics.)
Number of Maximum Daily Average Daily Source
Parameter or Pollutant Analyses Discharge Discharge (use codes
if actual data specify units) specify units) per
reported) Mass Conc. Mass Conc. instructions)
Chemical oxygen demand(COD)
Total organic carbon(TOC)
SECTION 5.FLOW(40 CFR 122.21(h)(5))
5.1 Except for stormwater water runoff,leaks,or spills,are any of the discharges you described in Sections 1 and 3 of this
application intermittent or seasonal?
Yes 4 Complete this section. No 4 SKIP to Section 6.
0 5.2 Briefly describe the frequency and duration of flow.
The flow is expected to be continuous and less than 50,000 GPD or 0.05 MGD.
SECTION 6.TREATMENT SYSTEM(40 CFR 122.21(h)(6))
6.1 Briefly describe any treatment system(s)used(or to be used).E
Qf The system will include an 18,000-gal frac tank for settling and grit removal followed by a 1,00-gallon surge/mixing tank,
followed by two particulate filters in series,followed by two 1,000-pound carbon vessels in series. A line drawing and
cn P&ID drawing are included with permit application package.
m A carbon dioxide gas dosing system will used up stream of the mixing/surge tank during construction dewatering. The
E carbon dioxide gas dosing system and 18,000-gal frac tank will be removed when project transitions from construction
ddewatering to permanent building dewatering.
It
Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant
parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2E(revised 3-19) Page 2
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05119
Crown Central
OMB No.2040-0004
SECTION 7.OTHER INFORMATION(40 CFR 122.21(h)(7))
7.1 Use the space below to expand upon any of the above items. Use this space to provide any information you believe the
reviewer should consider in establishing permit limitations.Attach additional sheets as needed.
o Groundwater at the site has been monitored as part of the North Carolina Brownfileds Program. The triahalomethance
compounds(THMs)were detected(Bromodichloromethane,Chloroform,&Dibromochloromethane). The THMs
0
potentially could be the result of a municipal water line leak since THMs are associated with disinfection of municpal
c water supplies. The metals Barium and Chromium were detected in groundwater. The concentrations of the detected
m metals may have been biased high due to sediment potentally being present in samples as a result of c\sample
s
O collection methods.
Summary data tables and laboratory results are attached to permit application package.
SECTION 8.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d))
8.1 In Column 1 below,mark the sections of Form 2E that you have completed and are submitting with your application.
For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note that
not all applicants are required to provide attachments.
Column 1 Column 2
Section 1:Outfall Location w/attachments(e.g.,responses for additional outfalls)
r Section 2:Discharge Date w/attachments
El Section 3:Waste Types wl attachments
Section 4: Effluent Characteristics w/attachments
m
m
r Section 5:Flow CI w/attachments
u)
0 0 Section 6:Treatment System GI w/attachments
47- El Section 7:Other Information w/attachments
E
a Section 8:Checklist and Certification Statement 0 wl attachments
c
4 8.2 Certification Statement
certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted.Based on my inquiry of the person or persons who manage the system,or those persons directly
responsible for gathering the information, the information submitted is,to the best of my knowledge and belief,true,
accurate,and complete. I am aware that there are significant penalties for submitting false information,including the
possibility of fine and imprisonment for knowing violations.
Name(print or type first and last name) Official title
t 40112AI5ten iii/, ILWItilViZ100 SEI U•AtCP.4"
Signature 1 Date signed
5 1 t Ri
EPA Form 3510-2E(revised 3-19)Page 3
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ma
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CONTI1A INTERVAL 10 FEET
DECLINATION AT CENTER OF SHEET
NORTH AACR9GW VERTKAL DATUM OF 14ffi
SOURCE:
FIGURE 1
USGS TOPOGRAPHIC MAP SITE TOPOGRAPHIC LOCATION MAP
CAHRLOTTE EAST CENTRAL SQUARE
MIIIIIIS
7.5 MINUTE QUADRANGLE Central Avenue at Pecan Avenue
DATED 2019 Charlotte, Mecklenburg,North Carolina
ECS PROJECT NO.49-10756-C
s•
y
L
DISCHARGE TO
UNNAMED TRIBUTARY 7t
TO LITTLE SUGAR
CREEK
OUTFALLID
ULS020-SW0258000) i•
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LEGEND
N
APPROXIMATE SITE BOUNDARY STORMWATER PIPE 1PYI
STORMWATER STRUCTURE J FLOW DIRECTION s
SOURCE: I, A FIGURE 2
VIRTUAL CHARLOTTE WEB MAPPING APPLICATION DISCHARGE LOCATION MAP
ACCESSED APRIL 5, 2021 CENTRAL SQUARE
Central Avenue at Pecan Avenue
IIIIIIIIIICISAPPROXIMATESCALE: Charlotte, Mecklenburg, North Carolina
1 INCH=382 FEET
0 382 FEET
ECS PROJECT NO.49-10756-C
I I 1.
TABLE 3:SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
PECAN&CENTRAL AVENUE
CHARLOTTE,MECKLENBURG COUNTY,NORTH CAROLINA
ECU PROJECT NO.49-10756-A
Parameter ANALYTICAL RESULTS COMPARISON CRITERIA
Sample ID TW-1 TN-2 TW-3 TW-4 TW-S TW-6 TW-7
NC2LGWQS GCL
NCDEQ RESIDENTIAL NCDEQ NON-RESIDENTIAL
Collection Date 2/11/2020 2/11/2020 2/11/2020 2/10/2020 2/10/2020 2/10/2020 2/10/2020 VISL VISL
Volatile Organic Compounds(VOCs)by EPA Method 8260
Bromodichloromethane BRL 1.9 BRL BRL BRL BRL BRL 0.6 NS 8.8 38
Chloroform BRL 9.2 BRL BRL BRL BRL BRL 70 70,000 8.1 36
Dibromochloromethane BRL 1.3 BRL BRL BRL BRL BRL 0.4 400 NS NS
Semi-Volatile Organic Compounds(SVOCs)by EPA Method 8270
For All I BRL I BRL I BRL I 88l I BRL I BRL I BRL I NS I NS I NS I NS
Resource Conservation and Recovery Act(RCRA)Metals by EPA Methods 6020,7471,and 7199
Mercury BRL BRL BRL BRL BRL BRL BRL 1 NS 0.18 0.75
Barium 104 218 261 39.6 17.7 43.1 23.9 700 700,000 NS NS
Chromium BRL 94.0 128 BRL 9.3 BRL BRL 10 10,000 NS NS
Notes:
Results presented in micrograms per liter(ug/L),analogous to parts per billion(ppb)
NC2LGWQS=North Carolina 2L Groundwater Quality Standards
NCDEQ=North Carolina Department of Environmental Quality
VISL=Vapor Intrusion Screening Levels
DUP-3 is a duplicate sample collected from MW-3
NS=No Standard
1 Flag denotes an estimated concentration between the laboratory reporting limit and the laboratory detection limit
GCL=Gross Contamination Limit
Bold denotes an exceedance of the NC2LGWQS
Italics denotes an exceedance of the NCDEQ Residential VISL
Underline denotes an exceedance of the NCDEQ Non-Residential VISL
TABLE 3: SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
FORMER SHERWIN WILLIAMS-ADDITIONAL BROWNFIELDS ASSESSMENT
CENTRAL AVENUE&PECAN AVENUE
CHARLOTTE,MECKLENBURG COUNTY,NORTH CAROLINA
NCDEQ,BROWNFIELDS PROJECT NO.24002-20-060
ECS PROJECT NO.49-10756-DD
PARAMETER ANALYTICAL RESULTS SCREENING LEVEL
Sample ID TW-1 TW-2 TW-DUP Trip Blank
Collection Date 8/5/20
NC2LGWQS
Semi-Volatile Organic Compounds(SVOCs)By EPA Method 8270
For All ND ND ND ND Various
Volatile Organic Compounds(VOCs)By EPA Method 8260
Acetone 25.0 25.0 25.0 52.3 6,000
All other VOCs ND ND ND ND Various
Notes:
Results presented in micrograms per liter(ug/L),analogous to parts per billion(ppb)
NC2LGWQS=North Carolina 2L Groundwater Quality Standard as of April 1,2013
NS=No Standard
ND=Not detected at or above adjusted reporting limit.
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacelabs.com 704)875-9092
February 17, 2020
Chris Orrell
ECS Southeast, LLP
1900 Center Park Dr
Suite D
Charlotte, NC 28217
RE: Project: Central & Pecan
Pace Project No.: 92464666
Dear Chris Orrell:
Enclosed are the analytical results for sample(s) received by the laboratory on February 11, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Clgt10, Lill, -$aLon
Angela Baioni for
Taylor Ezell
[e-mail]
704)875-9092
Project Manager
Enclosures
cc: ECS Southeast Reporting,ECS Southeast
ti i REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
a
without the written consent of Pace Analytical Services,LLC. Page 1 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
CERTIFICATIONS
Project: Central&Pecan
Pace Project No.: 92464666
Pace Analytical Services Charlotte
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Certification#:99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 VirginiaNELAP Certification#:460221
North Carolina Wastewater Certification#: 12
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 VirginiaNELAP Certification#:460222
North Carolina Drinking Water Certification#:37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 47
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.paeelatn.com 704)875-9092
SAMPLE ANALYTE COUNT
Project: Central&Pecan
Pace Project No.: 92464666
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92464666001 TW-1 EPA6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666002 TW-2 EPA6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666003 TW-3 EPA6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666004 TW-4 EPA6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666005 TW-5 EPA6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666006 TW-6 EPA6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666007 TW-7 EPA 6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 47
Pace Analytical Services,LLC
aceAnaI ical 9800 Kinsey Ave. Suite 100
Huntersville,NC 28078
ww.'aeNatbs.cem 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-1 Lab ID: 92464666001 Collected: 02/11/20 14:20 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:03 7440-38-2
Barium 104 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:03 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:03 7440-43-9
Chromium ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:03 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:03 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:03 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:03 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:07 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:09 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:09 51-28-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 47
Pace Analytical Services,LLC
ace Analytical
9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-1 Lab ID: 92464666001 Collected: 02/11/20 14:20 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 19:09 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:09 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 88-06-2
Surrogates
Nitrobenzene-d5(S) 55 13-130 1 02/12/20 10:23 02/12/20 19:09 4165-60-0
2-Fluorobiphenyl(S) 49 13-130 1 02/12/20 10:23 02/12/20 19:09 321-60-8
Terphenyl-d14(S) 87 Ao 25-130 1 02/12/20 10:23 02/12/20 19:09 1718-51-0
Phenol-d6(S) 37 Ao 10-130 1 02/12/20 10:23 02/12/20 19:09 13127-88-3
2-Fluorophenol(S) 46 10-130 1 02/12/20 10:23 02/12/20 19:09 367-12-4
2,4,6-Tribromophenol(S)58 Ao 10-137 1 02/12/20 10:23 02/12/20 19:09 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 18:37 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 18:37 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 18:37 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 18:37 74-97-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 47
Pace Analytical Services,LLC
9800 ncey Ave. Suite 100
ace Analytical Huntersville,NC 28078
wrw.pacdabs.cao 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-1 Lab ID: 92464666001 Collected: 02/11/20 14:20 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Bromodichloromethane ND ug/L 1.0 1 02/12/20 18:37 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 18:37 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 18:37 74-83-9 IK,M1
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 18:37 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 18:37 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 18:37 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 18:37 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 18:37 75-00-3
Chloroform ND ug/L 5.0 1 02/12/20 18:37 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 18:37 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 18:37 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 18:37 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 18:37 96-12-8
Dibromochloromethane ND ug/L 1.0 1 02/12/20 18:37 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 18:37 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 18:37 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 18:37 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 18:37 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 18:37 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 18:37 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 18:37 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 18:37 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 18:37 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 18:37 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 18:37 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 18:37 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 18:37 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 18:37 10061-02-6
Diisopropyl ether ND ug/L 1.0 1 02/12/20 18:37 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 18:37 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 18:37 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 18:37 591-78-6
p-Isopropyltoluene ND ug/L 1.0 1 02/12/20 18:37 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 18:37 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 18:37 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 18:37 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 18:37 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 18:37 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 18:37 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 18:37 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 18:37 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 18:37 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 120-82-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 47
L-
Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.cate 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-1 Lab ID: 92464666001 Collected: 02/11/20 14:20 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 18:37 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 18:37 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 18:37 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 18:37 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 18:37 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 18:37 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 18:37 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 18:37 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 18:37 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 18:37 95-47-6
Surrogates
4-Bromofluorobenzene(S) 102 70-130 1 02/12/20 18:37 460-00-4
1,2-Dichloroethane-d4(S) 99 70-130 1 02/12/20 18:37 17060-07-0
Toluene-d8(S) 99 70-130 1 02/12/20 18:37 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.paeNabs.ean 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-2 Lab ID: 92464666002 Collected: 02/11/20 12:40 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:15 7440-38-2
Barium 218 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:15 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:15 7440-43-9
Chromium 94.0 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:15 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:15 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:15 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:15 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:09 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:34 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:34 51-28-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 47
Pace Analytical Services,LLC
CG
p n' n'
9800 Kincey Ave. Suite 100
lreH'I ti Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-2 Lab ID: 92464666002 Collected: 02/11/20 12:40 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 19:34 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:34 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 88-06-2
Surrogates
Nitrobenzene-d5(S) 83 13-130 1 02/12/20 10:23 02/12/20 19:34 4165-60-0
2-Fluorobiphenyl(S) 80 13-130 1 02/12/20 10:23 02/12/20 19:34 321-60-8
Terphenyl-d14(S) 105 25-130 1 02/12/20 10:23 02/12/20 19:34 1718-51-0
Phenol-d6(S) 58 10-130 1 02/12/20 10:23 02/12/20 19:34 13127-88-3
2-Fluorophenol(S) 71 10-130 1 02/12/20 10:23 02/12/20 19:34 367-12-4
2,4,6-Tribromophenol(S) 106 10-137 1 02/12/20 10:23 02/12/20 19:34 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 18:56 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 18:56 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 18:56 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 18:56 74-97-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite100
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ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-2 Lab ID: 92464666002 Collected: 02/11/20 12:40 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method: EPA 8260D
Bromodichloromethane 1.9 ug/L 1.0 1 02/12/20 18:56 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 18:56 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 18:56 74-83-9 IK
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 18:56 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 18:56 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 18:56 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 18:56 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 18:56 75-00-3
Chloroform 9.2 ug/L 5.0 1 02/12/20 18:56 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 18:56 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 18:56 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 18:56 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 18:56 96-12-8
Dibromochloromethane 1.3 ug/L 1.0 1 02/12/20 18:56 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 18:56 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 18:56 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 18:56 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 18:56 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 18:56 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 18:56 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 18:56 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 18:56 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 18:56 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 18:56 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 18:56 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 18:56 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 18:56 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 18:56 10061-02-6
Diisopropyl ether ND ug/L 1.0 1 02/12/20 18:56 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 18:56 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 18:56 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 18:56 591-78-6
p-lsopropyltoluene ND ug/L 1.0 1 02/12/20 18:56 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 18:56 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 18:56 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 18:56 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 18:56 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 18:56 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 18:56 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 18:56 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 18:56 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 18:56 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 120-82-1
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 47
Pace Analytical Services,LLC
it 9800 Kincey Ave. Suite100
aceAnalytical Huntersville,NC 28078078
www.pacalabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-2 Lab ID: 92464666002 Collected: 02/11/20 12:40 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method: EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 18:56 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 18:56 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 18:56 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 18:56 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 18:56 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 18:56 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 18:56 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 18:56 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 18:56 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 18:56 95-47-6
Surrogates
4-Bromofluorobenzene(S) 101 70-130 1 02/12/20 18:56 460-00-4
1,2-Dichloroethane-d4(S) 101 70-130 1 02/12/20 18:56 17060-07-0
Toluene-d8(S) 100 70-130 1 02/12/20 18:56 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
UIiG/'l/1G' 1[1''
9800 Kincey Ave. Suite 100
ace AnalyticalIL Huntersville,NC 28078
www.pacelahs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-3 Lab ID: 92464666003 Collected: 02/11/20 11:15 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:18 7440-38-2
Barium 261 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:18 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:18 7440-43-9
Chromium 128 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:18 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:18 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:18 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:18 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:17 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:00 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:00 51-28-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 9800unterysv lle,C28070g
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f
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-3 Lab ID: 92464666003 Collected: 02/11/20 11:15 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 20:00 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:00 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 88-06-2
Surrogates
Nitrobenzene-d5(S) 81 13-130 1 02/12/20 10:23 02/12/20 20:00 4165-60-0
2-Fluorobiphenyl(S) 76 13-130 1 02/12/20 10:23 02/12/20 20:00 321-60-8
Terphenyl-d14(S) 92 25-130 1 02/12/20 10:23 02/12/20 20:00 1718-51-0
Phenol-d6(S) 52 10-130 1 02/12/20 10:23 02/12/20 20:00 13127-88-3
2-Fluorophenol(S) 66 10-130 1 02/12/20 10:23 02/12/20 20:00 367-12-4
2,4,6-Tribromophenol(S)97 10-137 1 02/12/20 10:23 02/12/20 20:00 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 19:14 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 19:14 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 19:14 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 19:14 74-97-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 47
Pace Analytical Services,LLC
fo 9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.paeNabs.eas 704)875-9092
i
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-3 Lab ID: 92464666003 Collected: 02/11/20 11:15 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Bromodichloromethane ND ug/L 1.0 1 02/12/20 19:14 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 19:14 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 19:14 74-83-9 IK
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 19:14 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 19:14 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 19:14 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 19:14 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 19:14 75-00-3
Chloroform ND ug/L 5.0 1 02/12/20 19:14 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 19:14 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 19:14 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 19:14 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 19:14 96-12-8
Dibromochloromethane ND ug/L 1.0 1 02/12/20 19:14 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 19:14 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 19:14 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:14 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:14 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:14 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 19:14 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 19:14 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 19:14 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 19:14 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 19:14 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 19:14 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 19:14 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 19:14 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 19:14 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 19:14 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 19:14 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 19:14 10061-02-6
Diisopropyl ether ND ug/L 1.0 1 02/12/20 19:14 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 19:14 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 19:14 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 19:14 591-78-6
p-Isopropyltoluene ND ug/L 1.0 1 02/12/20 19:14 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 19:14 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 19:14 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 19:14 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 19:14 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 19:14 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 19:14 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 19:14 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 19:14 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 19:14 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 19:14 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 19:14 120-82-1
REPORT OF LABORATORY ANALYSIS
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1
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
www.pacalabs.cem 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-3 Lab ID: 92464666003 Collected: 02/11/20 11:15 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method: EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 19:14 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 19:14 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 19:14 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 19:14 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 19:14 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 19:14 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 19:14 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 19:14 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 19:14 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 19:14 95-47-6
Surrogates
4-Bromofluorobenzene(S) 104 70-130 1 02/12/20 19:14 460-00-4
1,2-Dichloroethane-d4(S) 99 70-130 1 02/12/20 19:14 17060-07-0
Toluene-d8(S) 99 70-130 1 02/12/20 19:14 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
QQ n//n !/ +
9800 Kincey Ave. Suite 1009icalHuntersville,NC 28078
www.pacelabs.rne 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
1 Pace Project No.: 92464666
Sample: TW-4 Lab ID: 92464666004 Collected: 02/10/20 15:35 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:27 7440-38-2
Barium 39.6 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:27 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:27 7440-43-9
Chromium ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:27 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:27 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:27 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:27 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method: EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:19 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:25 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:25 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:25 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:25 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:25 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:25 51-28-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
ace nl l' fC 1
9800 Kincey Ave. Suite 100
l, I1 li Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-4 Lab ID: 92464666004 Collected: 02/10/20 15:35 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 20:25 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:25 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:25 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:25 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:25 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:25 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:25 88-06-2
Surrogates
Nitrobenzene-d5(S) 46 13-130 1 02/12/20 10:23 02/12/20 20:25 4165-60-0
2-Fluorobiphenyl(S) 41 13-130 1 02/12/20 10:23 02/12/20 20:25 321-60-8
Terphenyl-d14(S) 65 25-130 1 02/12/20 10:23 02/12/20 20:25 1718-51-0
Phenol-d6(S) 30 10-130 1 02/12/20 10:23 02/12/20 20:25 13127-88-3
2-Fluorophenol(S) 38 10-130 1 02/12/20 10:23 02/12/20 20:25 367-12-4
2,4,6-Tribromophenol(S)50 10-137 1 02/12/20 10:23 02/12/20 20:25 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 19:32 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 19:32 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 19:32 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 19:32 74-97-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 47
A
aceAnalytical
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-4 Lab ID: 92464666004 Collected: 02/10/20 15:35 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Bromodichloromethane ND ug/L 1.0 1 02/12/20 19:32 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 19:32 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 19:32 74-83-9 IK
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 19:32 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 19:32 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 19:32 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 19:32 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 19:32 75-00-3
Chloroform ND ug/L 5.0 1 02/12/20 19:32 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 19:32 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 19:32 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 19:32 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 19:32 96-12-8
Dibromochloromethane ND ug/L 1.0 1 02/12/20 19:32 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 19:32 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 19:32 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:32 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:32 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:32 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 19:32 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 19:32 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 19:32 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 19:32 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 19:32 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 19:32 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 19:32 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 19:32 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 19:32 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 19:32 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 19:32 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 19:32 10061-02-6
Di isopropyl ether ND ug/L 1.0 1 02/12/20 19:32 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 19:32 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 19:32 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 19:32 591-78-6
p-Isopropyltoluene ND ug/L 1.0 1 02/12/20 19:32 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 19:32 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 19:32 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 19:32 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 19:32 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 19:32 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 19:32 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 19:32 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 19:32 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 19:32 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 19:32 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 19:32 120-82-1
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 47
Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacalabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-4 Lab ID: 92464666004 Collected: 02/10/20 15:35 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 19:32 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 19:32 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 19:32 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 19:32 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 19:32 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 19:32 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 19:32 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 19:32 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 19:32 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 19:32 95-47-6
Surrogates
4-Bromofluorobenzene(S) 103 70-130 1 02/12/20 19:32 460-00-4
1,2-Dichloroethane-d4(S) 101 70-130 1 02/12/20 19:32 17060-07-0
Toluene-d8(S) 103 70-130 1 02/12/20 19:32 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 47
Pace Analytical Services,LLC
9800 Kiney Ave. Suite 100
aceAnalytical Huntersville,NC 28078
wirc/aulabs.can 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-5 Lab ID: 92464666005 Collected: 02/10/20 17:00 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:30 7440-38-2
Barium 17.7 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:30 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:30 7440-43-9
Chromium 9.3 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:30 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:30 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:30 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:30 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:22 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:51 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:51 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:51 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 53-70-3 1
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:51 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:51 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:51 51-28-5
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-5 Lab ID: 92464666005 Collected: 02/10/20 17:00 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 20:51 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:51 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:51 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:51 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:51 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:51 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 120-82-1
2,4,5-Trichiorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:51 88-06-2
Surrogates
Nitrobenzene-d5(S) 59 13-130 1 02/12/20 10:23 02/12/20 20:51 4165-60-0
2-Fluorobiphenyl(S) 54 13-130 1 02/12/20 10:23 02/12/20 20:51 321-60-8
Terphenyl-d14(S) 94 25-130 1 02/12/20 10:23 02/12/20 20:51 1718-51-0
Phenol-d6(S) 39 10-130 1 02/12/20 10:23 02/12/20 20:51 13127-88-3
2-Fluorophenol(S) 49 10-130 1 02/12/20 10:23 02/12/20 20:51 367-12-4
2,4,6-Tribromophenol(S)82 10-137 1 02/12/20 10:23 02/12/20 20:51 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 19:50 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 19:50 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/2019:50 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 19:50 74-97-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 Kinsey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
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ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-5 Lab ID: 92464666005 Collected: 02/10/20 17:00 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Bromodichloromethane ND ug/L 1.0 1 02/12/20 19:50 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 19:50 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 19:50 74-83-9 IK
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 19:50 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 19:50 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 19:50 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 19:50 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 19:50 75-00-3
Chloroform ND ug/L 5.0 1 02/12/20 19:50 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 19:50 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 19:50 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 19:50 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 19:50 96-12-8
Dibromochloromethane ND ug/L 1.0 1 02/12/20 19:50 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 19:50 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 19:50 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:50 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:50 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 19:50 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 19:50 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 19:50 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 19:50 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 19:50 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 19:50 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 19:50 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 19:50 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 19:50 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 19:50 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 19:50 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 19:50 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 19:50 10061-02-6
Diisopropyl ether ND ug/L 1.0 1 02/12/20 19:50 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 19:50 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 19:50 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 19:50 591-78-6
p-lsopropyltoluene ND ug/L 1.0 1 02/12/20 19:50 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 19:50 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 19:50 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 19:50 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 19:50 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 19:50 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 19:50 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 19:50 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 19:50 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 19:50 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 19:50 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 19:50 120-82-1
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
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ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-5 Lab ID: 92464666005 Collected: 02/10/20 17:00 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 19:50 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 19:50 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 19:50 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 19:50 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 19:50 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 19:50 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 19:50 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 19:50 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 19:50 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 19:50 95-47-6
Surrogates
4-Bromofluorobenzene(S) 103 70-130 1 02/12/20 19:50 460-00-4
1,2-Dichloroethane-d4(S) 103 70-130 1 02/12/20 19:50 17060-07-0
Toluene-d8(S) 99 70-130 1 02/12/20 19:50 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
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ANALYTICAL RESULTS
Project: Central&Pecan
1 Pace Project No.: 92464666
Sample: TW-6 Lab ID: 92464666006 Collected: 02/10/20 13:25 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:33 7440-38-2
Barium 43.1 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:33 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:33 7440-43-9
Chromium ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:33 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:33 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:33 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:33 7440-22-4
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:24 7439-97-6
8270E RVE Analytical Method: EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 21:16 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:16 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:16 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:16 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:16 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 21:16 51-28-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 47
Pace Analytical Services,LLC
nQ Analytical 9800 Kincey Ave. Suite 100
lrr An lr Huntersville,NC 28078
www.pacelabs.com 704)875-9092
I
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-6 Lab ID: 92464666006 Collected: 02/10/20 13:25 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 21:16 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 87-68-3
Hexachlorobenzene N D ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:16 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:16 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:16 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 21:16 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:16 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:16 88-06-2
Surrogates
Nitrobenzene-d5(S) 60 13-130 1 02/12/20 10:23 02/12/20 21:16 4165-60-0
2-Fluorobiphenyl(S) 56 13-130 1 02/12/20 10:23 02/12/20 21:16 321-60-8
Terphenyl-d14(S) 87 25-130 1 02/12/20 10:23 02/12/20 21:16 1718-51-0
Phenol-d6(S) 39 10-130 1 02/12/20 10:23 02/12/20 21:16 13127-88-3
2-Fluorophenol(S) 48 10-130 1 02/12/20 10:23 02/12/20 21:16 367-12-4
2,4,6-Tribromophenol(S)71 10-137 1 02/12/20 10:23 02/12/20 21:16 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 20:08 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 20:08 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 20:08 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 20:08 74-97-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 25 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aeAnaIica/ Huntersville,NC 28078
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ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-6 Lab ID: 92464666006 Collected: 02/10/20 13:25 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method: EPA 8260D
Bromodichloromethane ND ug/L 1.0 1 02/12/20 20:08 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 20:08 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 20:08 74-83-9 IK
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 20:08 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 20:08 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 20:08 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 20:08 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 20:08 75-00-3
Chloroform ND ug/L 5.0 1 02/12/20 20:08 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 20:08 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 20:08 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 20:08 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 20:08 96-12-8
Dibromochloromethane ND ug/L 1.0 1 02/12/20 20:08 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 20:08 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 20:08 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 20:08 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 20:08 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 20:08 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 20:08 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 20:08 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 20:08 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 20:08 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 20:08 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 20:08 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 20:08 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 20:08 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 20:08 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 20:08 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 20:08 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 20:08 10061-02-6
Diisopropyl ether ND ug/L 1.0 1 02/12/20 20:08 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 20:08 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 20:08 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 20:08 591-78-6
p-lsopropyltoluene ND ug/L 1.0 1 02/12/20 20:08 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 20:08 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 20:08 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 20:08 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 20:08 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 20:08 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 20:08 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 20:08 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 20:08 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 20:08 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 20:08 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 20:08 120-82-1
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 47
Pace Analytical Services,LLC
ac e Analytical' 9800 Kincey Ave. Suite 100
li Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-6 Lab ID: 92464666006 Collected: 02/10/20 13:25 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 20:08 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 20:08 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 20:08 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 20:08 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 20:08 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 20:08 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 20:08 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 20:08 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 20:08 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 20:08 95-47-6
Surrogates
4-Bromofluorobenzene(S) 102 70-130 1 02/12/20 20:08 460-00-4
1,2-Dichloroethane-d4(S) 100 70-130 1 02/12/20 20:08 17060-07-0
Toluene-d8(S) 101 70-130 1 02/12/20 20:08 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 27 of 47
r
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.peNebs.eom 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-7 Lab ID: 92464666007 Collected: 02/10/20 13:35 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:36 7440-38-2
Barium 23.9 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:36 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:36 7440-43-9
Chromium ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:36 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:36 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:36 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:36 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method: EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:27 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 21:42 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:42 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:42 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:42 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:42 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 21:42 51-28-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 28 of 47
Pace Analytical Services,LLC
ace Analytical 9800 Kinsey Ave. Suite 100
fill Analytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-7 Lab ID: 92464666007 Collected: 02/10/20 13:35 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 21:42 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:42 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:42 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:42 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 21:42 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 21:42 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 21:42 88-06-2
Surrogates
Nitrobenzene-d5(S) 54 13-130 1 02/12/20 10:23 02/12/20 21:42 4165-60-0
2-Fluorobiphenyl(S) 48 13-130 1 02/12/20 10:23 02/12/20 21:42 321-60-8
Terphenyl-d14(S) 79 25-130 1 02/12/20 10:23 02/12/20 21:42 1718-51-0
Phenol-d6(S) 53 10-130 1 02/12/20 10:23 02/12/20 21:42 13127-88-3
2-Fluorophenol(S) 58 10-130 1 02/12/20 10:23 02/12/20 21:42 367-12-4
2,4,6-Tribromophenol(S)71 10-137 1 02/12/20 10:23 02/12/20 21:42 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 20:26 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 20:26 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 20:26 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 20:26 74-97-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 29 of 47
Pace Analytical Services,LLC
ace Analytical
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-7 Lab ID: 92464666007 Collected: 02/10/20 13:35 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Bromodichloromethane ND ug/L 1.0 1 02/12/20 20:26 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 20:26 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 20:26 74-83-9 IK
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 20:26 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 20:26 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 20:26 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 20:26 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 20:26 75-00-3
Chloroform ND ug/L 5.0 1 02/12/20 20:26 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 20:26 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 20:26 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 20:26 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 20:26 96-12-8
Dibromochloromethane ND ug/L 1.0 1 02/12/20 20:26 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 20:26 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 20:26 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 20:26 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 20:26 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 20:26 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 20:26 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 20:26 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 20:26 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 20:26 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 20:26 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 20:26 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 20:26 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 20:26 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 20:26 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 20:26 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 20:26 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 20:26 10061-02-6
Diisopropyl ether ND ug/L 1.0 1 02/12/20 20:26 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 20:26 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 20:26 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 20:26 591-78-6
p-Isoprapyltoluene ND ug/L 1.0 1 02/12/20 20:26 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 20:26 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 20:26 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 20:26 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 20:26 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 20:26 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 20:26 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 20:26 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 20:26 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 20:26 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 20:26 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 20:26 120-82-1
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 30 of 47
aceAnalyticalPace
Analytical Services,LLC
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.paeelaha.catn 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-7 Lab ID: 92464666007 Collected: 02/10/20 13:35 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method: EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 20:26 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 20:26 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 20:26 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 20:26 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 20:26 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 20:26 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 20:26 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 20:26 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 20:26 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 20:26 95-47-6
Surrogates
4-Bromofluorobenzene(S) 103 70-130 1 02/12/20 20:26 460-00-4
1,2-Dichloroethane-d4(S) 100 70-130 1 02/12/20 20:26 17060-07-0
Toluene-d8(S) 100 70-130 1 02/12/20 20:26 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 31 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
QC Batch: 524683 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
METHOD BLANK: 2804610 Matrix: Water
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 02/17/20 14:48
LABORATORY CONTROL SAMPLE: 2804611
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Mercury ug/L 2.5 3.0 118 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2804612 2804613
MS MSD
92463692001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 3.1 2.8 123 112 75-125 9
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 32 of 47
Pace Analytical Services,LLC
ac Analytical 9800KinceyAve. Suite 100
G{ Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
QC Batch: 524564 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
METHOD BLANK: 2804221 Matrix: Water
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Arsenic ug/L ND 10.0 02/12/20 11:57
Barium ug/L ND 5.0 02/12/20 11:57
Cadmium ug/L ND 1.0 02/12/20 11:57
Chromium ug/L ND 5.0 02/12/20 11:57
Lead ug/L ND 5.0 02/12/20 11:57
Selenium ug/L ND 10.0 02/12/20 11:57
Silver ug/L ND 5.0 02/12/20 11:57
LABORATORY CONTROL SAMPLE: 2804222
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Arsenic ug/L 500 459 92 80-120
Barium ug/L 500 484 97 80-120
Cadmium ug/L 500 482 96 80-120
Chromium ug/L 500 484 97 80-120
Lead ug/L 500 481 96 80-120
Selenium ug/L 500 470 94 80-120
Silver ug/L 250 243 97 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2804223 2804224
MS MSD
92464666001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Arsenic ug/L ND 500 500 478 467 96 93 75-125 2
Barium ug/L 104 500 500 601 592 100 98 75-125 2
Cadmium ug/L ND 500 500 496 488 99 98 75-125 2
Chromium ug/L ND 500 500 497 488 99 97 75-125 2
Lead ug/L ND 500 500 489 485 98 97 75-125 1
Selenium ug/L ND 500 500 511 504 102 101 75-125 1
Silver ug/L ND 250 250 239 236 96 94 75-125 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 33 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.paeelabs.can 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
QC Batch: 524737 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
METHOD BLANK: 2804863 Matrix: Water
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/12/20 17:07
1,1,1-Trichloroethane ug/L ND 1.0 02/12/20 17:07
1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/12/20 17:07
1,1,2-Trichloroethane ug/L ND 1.0 02/12/20 17:07
1,1-Dichloroethane ug/L ND 1.0 02/12/20 17:07
1,1-Dichloroethene ug/L ND 1.0 02/12/20 17:07
1,1-Dichloropropene ug/L ND 1.0 02/12/20 17:07
1,2,3-Trichlorobenzene ug/L ND 1.0 02/12/20 17:07
1,2,3-Trichloropropane ug/L ND 1.0 02/12/20 17:07
1,2,4-Trichlorobenzene ug/L ND 1.0 02/12/20 17:07
1,2-Dibromo-3-chloropropane ug/L ND 5.0 02/12/20 17:07
1,2-Dibromoethane(EDB) ug/L ND 1.0 02/12/20 17:07
1,2-Dichlorobenzene ug/L ND 1.0 02/12/20 17:07
1,2-Dichloroethane ug/L ND 1.0 02/12/20 17:07
1,2-Dichloropropane ug/L ND 1.0 02/12/20 17:07
1,3-Dichlorobenzene ug/L ND 1.0 02/12/20 17:07
1,3-Dichloropropane ug/L ND 1.0 02/12/20 17:07
1,4-Dichlorobenzene ug/L ND 1.0 02/12/20 17:07
2,2-Dichloropropane ug/L ND 1.0 02/12/20 17:07
2-Butanone(MEK) ug/L ND 5.0 02/12/20 17:07
2-Chlorotoluene ug/L ND 1.0 02/12/20 17:07
2-Hexanone ug/L ND 5.0 02/12/20 17:07
4-Chlorotoluene ug/L ND 1.0 02/12/20 17:07
4-Methyl-2-pentanone(MIBK)ug/L ND 5.0 02/12/20 17:07
Acetone ug/L ND 25.0 02/12/20 17:07
Benzene ug/L ND 1.0 02/12/20 17:07
Bromobenzene ug/L ND 1.0 02/12/20 17:07
Bromochloromethane ug/L ND 1.0 02/12/20 17:07
Bromodichloromethane ug/L ND 1.0 02/12/20 17:07
Bromoform ug/L ND 1.0 02/12/20 17:07
Bromomethane ug/L ND 2.0 02/12/20 17:07 IK
Carbon tetrachloride ug/L ND 1.0 02/12/20 17:07
Chlorobenzene ug/L ND 1.0 02/12/20 17:07
Chloroethane ug/L ND 1.0 02/12/20 17:07
Chloroform ug/L ND 5.0 02/12/20 17:07
Chloromethane ug/L ND 1.0 02/12/20 17:07
cis-1,2-Dichloroethene ug/L ND 1.0 02/12/20 17:07
cis-1,3-Dichloropropene ug/L ND 1.0 02/12/20 17:07
Dibromochloromethane ug/L ND 1.0 02/12/20 17:07
Dibromomethane ug/L ND 1.0 02/12/20 17:07
Dichlorodifluoromethane ug/L ND 1.0 02/12/20 17:07
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 34 of 47
Pace Analytical Services,LLC
f 9800 Kincey Ave. Suite 100acernalJ`'1al Huntersville,NC 28078
www.pacelabs.com
704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
METHOD BLANK: 2804863 Matrix: Water
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Diisopropyl ether ug/L ND 1.0 02/12/20 17:07
Ethylbenzene ug/L ND 1.0 02/12/20 17:07
Hexachloro-1,3-butadiene ug/L ND 1.0 02/12/20 17:07
m&p-Xylene ug/L ND 2.0 02/12/20 17:07
Methyl-tert-butyl ether ug/L ND 1.0 02/12/20 17:07
Methylene Chloride ug/L ND 5.0 02/12/20 17:07
n-Butylbenzene ug/L ND 1.0 02/12/20 17:07
Naphthalene ug/L ND 1.0 02/12/20 17:07
o-Xylene ug/L ND 1.0 02/12/20 17:07
p-lsopropyltoluene ug/L ND 1.0 02/12/20 17:07
Styrene ug/L ND 1.0 02/12/20 17:07
Tetrachloroethene ug/L ND 1.0 02/12/20 17:07
Toluene ug/L ND 1.0 02/12/20 17:07
trans-1,2-Dichloroethene ug/L ND 1.0 02/12/20 17:07
trans-1,3-Dichloropropene ug/L ND 1.0 02/12/20 17:07
Trichloroethene ug/L ND 1.0 02/12/20 17:07
Trichlorofluoromethane ug/L ND 1.0 02/12/20 17:07
Vinyl acetate ug/L ND 2.0 02/12/20 17:07
Vinyl chloride ug/L ND 1.0 02/12/20 17:07
Xylene(Total) ug/L ND 1.0 02/12/20 17:07
1,2-Dichloroethane-d4(S) 99 70-130 02/12/20 17:07
4-Bromofluorobenzene(S) 101 70-130 02/12/20 17:07
Toluene-d8(S)100 70-130 02/12/20 17:07
LABORATORY CONTROL SAMPLE: 2804864
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane ug/L 50 51.1 102 70-130
1,1,1-Trichloroethane ug/L 50 47.3 95 70-130
1,1,2,2-Tetrachloroethane ug/L 50 50.7 101 70-130
1,1,2-Trichloroethane ug/L 50 51.3 103 70-130
1,1-Dichloroethane ug/L 50 46.0 92 70-130
1,1-Dichloroethene ug/L 50 46.5 93 70-130
1,1-Dichloropropene ug/L 50 51.1 102 70-130
1,2,3-Trichlorobenzene ug/L 50 52.6 105 70-130
1,2,3-Trichloropropane ug/L 50 51.3 103 70-130
1,2,4-Trichlorobenzene ug/L 50 52.9 106 70-130
1,2-Dibromo-3-chloropropane ug/L 50 51.4 103 70-130
1,2-Dibromoethane(EDB) ug/L 50 52.1 104 70-130
1,2-Dichlorobenzene ug/L 50 50.7 101 70-130
1,2-Dichloroethane ug/L 50 46.9 94 70-130
1,2-Dichloropropane ug/L 50 49.9 100 70-130
1,3-Dichlorobenzene ug/L 50 51.0 102 70-130
1,3-Dichloropropane ug/L 50 51.1 102 70-131
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 35 of 47
I
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
ww.puNatbs.com 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
LABORATORY CONTROL SAMPLE: 2804864
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,4-Dichlorobenzene ug/L 50 49.3 99 70-130
2,2-Dichloropropane ug/L 50 46.8 94 69-130
2-Butanone(MEK) ug/L 100 101 101 64-135
2-Chlorotoluene ug/L 50 48.4 97 70-130
2-Hexanone ug/L 100 102 102 66-135
4-Chlorotoluene ug/L 50 49.4 99 70-130
4-Methyl-2-pentanone(MIBK)ug/L 100 101 101 70-130
Acetone ug/L 100 121 121 61-157
Benzene ug/L 50 48.7 97 70-130
Bromobenzene ug/L 50 51.4 103 70-130
Bromochloromethane ug/L 50 47.2 94 70-130
Bromodichloromethane ug/L 50 45.8 92 70-130
Bromoform ug/L 50 46.2 92 70-130
Bromomethane ug/L 50 57.0 114 38-130 IK
Carbon tetrachloride ug/L 50 48.8 98 70-130
Chlorobenzene ug/L 50 49.2 98 70-130
Chloroethane ug/L 50 44.6 89 37-142
Chloroform ug/L 50 46.1 92 70-130
Chloromethane ug/L 50 39.1 78 48-130
cis-1,2-Dichloroethene ug/L 50 46.4 93 70-130
cis-1,3-Dichloropropene ug/L 50 48.1 96 70-130
Dibromochloromethane ug/L 50 49.8 100 70-130
Dibromomethane ug/L 50 50.6 101 70-130
Dichlorodifluoromethane ug/L 50 43.6 87 53-134
Diisopropyl ether ug/L 50 50.1 100 70-135
Ethylbenzene ug/L 50 48.0 96 70-130
Hexachloro-1,3-butadiene ug/L 50 52.2 104 68-132
m&p-Xylene ug/L 100 95.2 95 70-130
Methyl-tert-butyl ether ug/L 50 49.9 100 70-130
Methylene Chloride ug/L 50 45.9 92 67-132
n-Butylbenzene ug/L 50 48.9 98 70-132
Naphthalene ug/L 50 49.9 100 70-130
o-Xylene ug/L 50 48.0 96 70-131
p-Isopropyltoluene ug/L 50 49.2 98 70-130
Styrene ug/L 50 48.4 97 70-130
Tetrachloroethene ug/L 50 51.1 102 69-130
Toluene ug/L 50 47.4 95 70-130
trans-1,2-Dichloroethene ug/L 50 46.6 93 70-130
trans-1,3-Dichloropropene ug/L 50 47.8 96 70-130
Trichloroethene ug/L 50 51.2 102 70-130
Trichlorofluoromethane ug/L 50 43.5 87 63-130
Vinyl acetate ug/L 100 112 112 55-143
Vinyl chloride ug/L 50 50.2 100 70-131
Xylene(Total) ug/L 150 143 95 70-130
1,2-Dichloroethane-d4(S) 92 70-130
4-Bromofluorobenzene(S) 98 70-130
Toluene-d8(S)98 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 36 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2804865 2804866
MS MSD
92464666001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.3 20.7 102 104 73-134 2
1,1,1-Trichloroethane ug/L ND 20 20 21.8 21.8 109 109 82-143 0
1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.7 20.6 104 103 70-136 1
1,1,2-Trichloroethane ug/L ND 20 20 21.6 21.2 108 106 70-135 2
1,1-Dichloroethane ug/L ND 20 20 20.9 21.0 105 105 70-139 0
1,1-Dichloroethene ug/L ND 20 20 21.7 21.9 108 110 70-154 1
1,1-Dichloropropene ug/L ND 20 20 23.1 22.7 115 114 70-149 1
1,2,3-Trichlorobenzene ug/L ND 20 20 21.8 21.5 109 108 70-135 1
1,2,3-Trichloropropane ug/L ND 20 20 20.2 20.3 101 102 71-137 1
1,2,4-Trichlorobenzene ug/L ND 20 20 21.4 21.4 107 107 73-140 0
1,2-Dibromo-3-chloropropane ug/L ND 20 20 20.9 19.6 105 98 65-134 7
1,2-Dibromoethane(EDB) ug/L ND 20 20 20.9 21.1 105 105 70-137 1
1,2-Dichlorobenzene ug/L ND 20 20 21.7 21.3 109 107 70-133 2
1,2-Dichloroethane ug/L ND 20 20 20.8 20.6 104 103 70-137 1
1,2-Dichloropropane ug/L ND 20 20 21.6 21.5 108 108 70-140 1
1,3-Dichlorobenzene ug/L ND 20 20 22.1 22.0 111 110 70-135 1
1,3-Dichloropropane ug/L ND 20 20 21.1 21.6 105 108 70-143 2
1,4-Dichlorobenzene ug/L ND 20 20 21.0 21.0 105 105 70-133 0
2,2-Dichloropropane ug/L ND 20 20 21.5 21.4 108 107 61-148 1
2-Butanone(MEK) ug/L ND 40 40 42.1 38.5 105 96 60-139 9
2-Chlorotoluene ug/L ND 20 20 19.3 20.6 96 103 70-144 7
2-Hexanone ug/L ND 40 40 39.3 37.8 98 94 65-138 4
4-Chlorotoluene ug/L ND 20 20 20.9 21.0 104 105 70-137 1
4-Methyl-2-pentanone(MIBK)ug/L ND 40 40 39.6 37.1 99 93 65-135 7
Acetone ug/L ND 40 40 50.6 48.4 127 121 60-148 5
Benzene ug/L ND 20 20 21.7 21.7 108 109 70-151 0
Bromobenzene ug/L ND 20 20 21.9 21.9 109 110 70-136 0
Bromochloromethane ug/L ND 20 20 21.4 21.5 107 107 70-141 0
Bromodichloromethane ug/L ND 20 20 20.0 19.9 100 100 70-138 0
Bromoform ug/L ND 20 20 16.8 17.3 84 87 63-130 3
Bromomethane ug/L ND 20 20 31.7 31.7 158 159 15-152 0 IK,M1
Carbon tetrachloride ug/L ND 20 20 22.1 22.4 110 112 70-143 1
Chlorobenzene ug/L ND 20 20 21.6 21.5 108 107 70-138 1
Chloroethane ug/L ND 20 20 22.7 22.4 114 112 52-163 2
Chloroform ug/L ND 20 20 21.3 21.1 106 106 70-139 1
Chloromethane ug/L ND 20 20 18.8 18.3 94 92 41-139 2
cis-1,2-Dichloroethene ug/L ND 20 20 20.9 20.9 104 104 70-141 0
cis-1,3-Dichloropropene ug/L ND 20 20 19.4 19.5 97 97 70-137 0
Dibromochloromethane ug/L ND 20 20 19.4 19.8 97 99 70-134 2
Dibromomethane ug/L ND 20 20 22.0 22.6 110 113 70-138 3
Dichlorodifluoromethane ug/L ND 20 20 20.0 20.1 100 101 47-155 0
Diisopropyl ether ug/L ND 20 20 20.4 19.9 102 100 63-144 3
Ethylbenzene ug/L ND 20 20 21.2 21.4 106 107 66-153 1
Hexachloro-1,3-butadiene ug/L ND 20 20 22.4 22.3 112 111 65-149 1
m&p-Xylene ug/L ND 40 40 42.1 42.7 105 107 69-152 1
Methyl-tert-butyl ether ug/L ND 20 20 21.2 20.3 106 102 54-156 4
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 37 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
www.pacelabs.cam 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2804865 2804866
MS MSD
92464666001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Methylene Chloride ug/L ND 20 20 18.9 19.1 94 96 42-159 1
n-Butylbenzene ug/L ND 20 20 20.8 20.4 104 102 70-139 2
Naphthalene ug/L ND 20 20 19.9 19.8 100 99 61-148 1
o-Xylene ug/L ND 20 20 20.7 20.8 104 104 70-148 0
p-lsopropyltoluene ug/L ND 20 20 21.1 20.7 105 104 70-146 2
Styrene ug/L ND 20 20 20.6 21.0 103 105 70-135 2
Tetrachloroethene ug/L ND 20 20 22.0 22.1 110 110 59-143 0
Toluene ug/L ND 20 20 21.0 20.8 105 104 59-148 1
trans-1,2-Dichloroethene ug/L ND 20 20 21.5 21.3 107 106 70-146 1
trans-1,3-Dichloropropene ug/L ND 20 20 19.2 19.0 96 95 70-135 1
Trichloroethene ug/L ND 20 20 23.0 22.4 115 112 70-147 3
Trichlorofluoromethane ug/L ND 20 20 21.9 22.0 110 110 70-148 0
Vinyl acetate ug/L ND 40 40 46.7 44.7 117 112 49-151 4
Vinyl chloride ug/L ND 20 20 23.3 23.3 117 116 70-156 0
Xylene(Total) ug/L ND 60 60 62.8 63.5 105 106 63-158 1
1,2-Dichloroethane-d4(S) 102 104 70-130
4-Bromofluorobenzene(S) 97 99 70-130
Toluene-d8(S) 99 99 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 38 of 47
Pace Analytical Services,LLC
aceAnalytical
s
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com
704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
QC Batch: 524609 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water MSSV RVE
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
METHOD BLANK: 2804298 Matrix: Water
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 10.0 02/12/20 14:39
1,2-Dichlorobenzene ug/L ND 10.0 02/12/20 14:39
1,3-Dichlorobenzene ug/L ND 10.0 02/12/20 14:39
1,4-Dichlorobenzene ug/L ND 10.0 02/12/20 14:39
1-Methylnaphthalene ug/L ND 10.0 02/12/20 14:39
2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 02/12/20 14:39
2,4,5-Trichlorophenol ug/L ND 10.0 02/12/20 14:39
2,4,6-Trichlorophenol ug/L ND 10.0 02/12/20 14:39
2,4-Dichlorophenol ug/L ND 10.0 02/12/20 14:39
2,4-Dimethylphenol ug/L ND 10.0 02/12/20 14:39
2,4-Dinitrophenol ug/L ND 50.0 02/12/20 14:39
2,4-Dinitrotoluene ug/L ND 10.0 02/12/20 14:39
2,6-Dinitrotoluene ug/L ND 10.0 02/12/20 14:39
2-Chloronaphthalene ug/L ND 10.0 02/12/20 14:39
2-Chlorophenol ug/L ND 10.0 02/12/20 14:39
2-Methylnaphthalene ug/L ND 10.0 02/12/20 14:39
2-Methylphenol(o-Cresol) ug/L ND 10.0 02/12/20 14:39
2-Nitroaniline ug/L ND 20.0 02/12/20 14:39
2-Nitrophenol ug/L ND 10.0 02/12/20 14:39
3&4-Methylphenol(m&p Cresol) ug/L ND 10.0 02/12/20 14:39
3,3'-Dichlorobenzidine ug/L ND 20.0 02/12/20 14:39
3-Nitroaniline ug/L ND 20.0 02/12/20 14:39
4,6-Dinitro-2-methylphenol ug/L ND 20.0 02/12/20 14:39
4-Bromophenylphenyl ether ug/L ND 10.0 02/12/20 14:39
4-Chloro-3-methylphenol ug/L ND 10.0 02/12/20 14:39
4-Chloroaniline ug/L ND 20.0 02/12/20 14:39
4-Chlorophenylphenyl ether ug/L ND 10.0 02/12/20 14:39
4-Nitroaniline ug/L ND 20.0 02/12/20 14:39
4-Nitrophenol ug/L ND 50.0 02/12/20 14:39
Acenaphthene ug/L ND 10.0 02/12/20 14:39
Acenaphthylene ug/L ND 10.0 02/12/20 14:39
1 Aniline ug/L ND 10.0 02/12/20 14:39
Anthracene ug/L ND 10.0 02/12/20 14:39
Benzo(a)anthracene ug/L ND 10.0 02/12/20 14:39
Benzo(a)pyrene ug/L ND 10.0 02/12/20 14:39
Benzo(b)fluoranthene ug/L ND 10.0 02/12/20 14:39
Benzo(g,h,i)perylene ug/L ND 10.0 02/12/20 14:39
Benzo(k)fluoranthene ug/L ND 10.0 02/12/20 14:39
Benzoic Acid ug/L ND 50.0 02/12/20 14:39
Benzyl alcohol ug/L ND 20.0 02/12/20 14:39
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/12/20 14:39
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 39 of 47
r
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.palab$.Com 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
METHOD BLANK: 2804298 Matrix: Water 1
Associated Lab Samples: 92464666001,92464666002,92464666003,92464666004,92464666005,92464666006,92464666007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
bis(2-Chloroethyl)ether ug/L ND 10.0 02/12/20 14:39
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 02/12/20 14:39
Butylbenzylphthalate ug/L ND 10.0 02/12/20 14:39
Chrysene ug/L ND 10.0 02/12/20 14:39
Di-n-butylphthalate ug/L ND 10.0 02/12/20 14:39
Di-n-octylphthalate ug/L ND 10.0 02/12/20 14:39
Dibenz(a,h)anthracene ug/L ND 10.0 02/12/20 14:39
Dibenzofuran ug/L ND 10.0 02/12/20 14:39
Diethylphthalate ug/L ND 10.0 02/12/20 14:39
Dimethylphthalate ug/L ND 10.0 02/12/20 14:39
Fluoranthene ug/L ND 10.0 02/12/20 14:39
Fluorene ug/L ND 10.0 02/12/20 14:39
Hexachloro-1,3-butadiene ug/L ND 10.0 02/12/20 14:39
Hexachlorobenzene ug/L ND 10.0 02/12/20 14:39
Hexachlorocyclopentadiene ug/L ND 10.0 02/12/20 14:39
Hexachloroethane ug/L ND 10.0 02/12/20 14:39
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 02/12/20 14:39
Isophorone ug/L ND 10.0 02/12/20 14:39
N-Nitroso-di-n-propylamine ug/L ND 10.0 02/12/20 14:39
N-Nitrosodimethylamine ug/L ND 10.0 02/12/20 14:39
N-Nitrosodiphenylamine ug/L ND 10.0 02/12/20 14:39
Naphthalene ug/L ND 10.0 02/12/20 14:39
Nitrobenzene ug/L ND 10.0 02/12/20 14:39
Pentachlorophenol ug/L ND 20.0 02/12/20 14:39
Phenanthrene ug/L ND 10.0 02/12/20 14:39
Phenol ug/L ND 10.0 02/12/20 14:39
Pyrene ug/L ND 10.0 02/12/20 14:39
2,4,6-Tribromophenol(S) 71 10-137 02/12/20 14:39
2-Fluorobiphenyl(S) 56 13-130 02/12/20 14:39
2-Fluorophenol(S) 61 10-130 02/12/20 14:39
Nitrobenzene-d5(S) 62 13-130 02/12/20 14:39
Phenol-d6(S)49 10-130 02/12/20 14:39
Terphenyl-d14(S) 83 25-130 02/12/20 14:39
LABORATORY CONTROL SAMPLE: 2804299
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,2,4-Trichlorobenzene ug/L 50 29.9 60 30-130
1,2-Dichlorobenzene ug/L 50 29.7 59 30-130
1,3-Dichlorobenzene ug/L 50 28.5 57 20-130
1,4-Dichlorobenzene ug/L 50 29.2 58 30-130
1-Methylnaphthalene ug/L 50 36.9 74 30-130
2,2'-Oxybis(1-chloropropane) ug/L 50 34.0 68 20-130
2,4,5-Trichlorophenol ug/L 50 41.2 82 40-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 40 of 47
Pace Analytical Services,LLC
aC(, n' ' 9800 Kincey Ave. Suite 100
lit, 1 Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
LABORATORY CONTROL SAMPLE: 2804299
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
2,4,6-Trichlorophenol ug/L 50 41.6 83 40-130
2,4-Dichlorophenol ug/L 50 41.4 83 31-130
2,4-Dimethylphenol ug/L 50 45.0 90 30-130
2,4-Dinitrophenol ug/L 250 216 86 30-130
2,4-Dinitrotoluene ug/L 50 46.2 92 49-130
2,6-Dinitrotoluene ug/L 50 46.6 93 50-130
2-Chloronaphthalene ug/L 50 35.6 71 30-130
2-Chlorophenol ug/L 50 41.4 83 30-130
2-Methylnaphthalene ug/L 50 34.9 70 30-130
2-Methylphenol(o-Cresol) ug/L 50 38.6 77 30-130
2-Nitroaniline ug/L 100 88.1 88 40-130
2-Nitrophenol ug/L 50 40.6 81 20-130
3&4-Methylphenol(m&p Cresol) ug/L 50 37.9 76 20-130
3,3'-Dichlorobenzidine ug/L 100 93.4 93 10-150
3-Nitroaniline ug/L 100 92.1 92 40-130
4,6-Dinitro-2-methylphenol ug/L 100 96.3 96 40-130
4-Bromophenylphenyl ether ug/L 50 38.0 76 30-130
4-Chloro-3-methylphenol ug/L 100 84.9 85 30-130
4-Chloroaniline ug/L 100 86.2 86 20-130
4-Chlorophenylphenyl ether ug/L 50 36.3 73 20-130
4-Nitroaniline ug/L 100 99.1 99 40-130
4-Nitrophenol ug/L 250 180 72 10-130
Acenaphthene ug/L 50 38.2 76 30-130
Acenaphthylene ug/L 50 42.6 85 30-130
Aniline ug/L 50 35.1 70 20-130
Anthracene ug/L 50 45.4 91 50-130
Benzo(a)anthracene ug/L 50 47.0 94 50-130
Benzo(a)pyrene ug/L 50 48.5 97 50-130
Benzo(b)fluoranthene ug/L 50 51.7 103 50-130
Benzo(g,h,i)perylene ug/L 50 50.1 100 50-130
Benzo(k)fluoranthene ug/L 50 47.0 94 50-130
Benzoic Acid ug/L 250 142 57 10-130
Benzyl alcohol ug/L 100 80.0 80 20-130
bis(2-Chloroethoxy)methane ug/L 50 37.2 74 30-130
bis(2-Chloroethyl)ether ug/L 50 38.9 78 30-130
bis(2-Ethylhexyl)phthalate ug/L 50 42.0 84 50-130
Butylbenzylphthalate ug/L 50 45.5 91 50-150
Chrysene ug/L 50 45.5 91 50-130
Di-n-butylphthalate ug/L 50 43.8 88 50-130
Di-n-octylphthalate ug/L 50 47.0 94 50-130
Dibenz(a,h)anthracene ug/L 50 49.5 99 40-130
Dibenzofuran ug/L 50 38.3 77 40-130
Diethylphthalate ug/L 50 43.0 86 40-130
Dimethylphthalate ug/L 50 42.8 86 40-130
Fluoranthene ug/L 50 46.8 94 30-130
Fluorene ug/L 50 41.9 84 20-130
Hexachloro-1,3-butadiene ug/L 50 26.1 52 10-130
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 41 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
ww.paeslabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Central&Pecan
Pace Project No.: 92464666
LABORATORY CONTROL SAMPLE: 2804299
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Hexachlorobenzene ug/L 50 40.6 81 30-130
Hexachlorocyclopentadiene ug/L 50 28.9 58 10-150
Hexachloroethane ug/L 50 26.9 54 10-130
Indeno(1,2,3-cd)pyrene ug/L 50 49.8 100 40-130
Isophorone ug/L 50 39.7 79 30-130
N-Nitroso-di-n-propylamine ug/L 50 39.9 80 30-130
N-Nitrosodimethylamine ug/L 50 36.7 73 10-130
N-Nitrosodiphenylamine ug/L 50 42.1 84 30-130
Naphthalene ug/L 50 35.3 71 20-130
Nitrobenzene ug/L 50 39.5 79 20-130
Pentachlorophenol ug/L 100 89.3 89 10-140
Phenanthrene ug/L 50 43.9 88 50-130
Phenol ug/L 50 29.4 59 10-130
Pyrene ug/L 50 43.6 87 50-130
2,4,6-Tribromophenol(S) 95 10-137
2-Fluorobiphenyl(S) 67 13-130
2-Fluorophenol(S) 73 10-130
Nitrobenzene-d5(S) 73 13-130
Phenol-d6(S)60 10-130
Terphenyl-d14(S) 82 25-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 42 of 47
Pace Analytical Services,LLC
to
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
ww.paeNabs.cam 704)875-9092
QUALIFIERS
Project: Central&Pecan
Pace Project No.: 92464666
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
I MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services-Asheville
PASI-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s)did not meet method acceptance criteria;this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 43 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacslsbs.cmn 704)875-9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Central&Pecan
Pace Project No.: 92464666
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92464666001 TW-1 EPA 3010A 524564 EPA 6010D 524593
92464666002 TW-2 EPA 3010A 524564 EPA 6010D 524593
92464666003 TW-3 EPA 3010A 524564 EPA 6010D 524593
92464666004 TW-4 EPA 3010A 524564 EPA 6010D 524593
92464666005 TW-5 EPA 3010A 524564 EPA 6010D 524593
92464666006 TW-6 EPA 3010A 524564 EPA 6010D 524593
92464666007 TW-7 EPA 3010A 524564 EPA 6010D 524593
92464666001 1W-1 EPA 7470A 524683 EPA 7470A 524747
92464666002 TW-2 EPA 7470A 524683 EPA 7470A 524747
92464666003 TW-3 EPA 7470A 524683 EPA 7470A 524747
92464666004 TW-4 EPA 7470A 524683 EPA 7470A 524747
92464666005 TIN-5 EPA 7470A 524683 EPA 7470A 524747
92464666006 TW-6 EPA 7470A 524683 EPA 7470A 524747
92464666007 TW-7 EPA 7470A 524683 EPA 7470A 524747
92464666001 1W-1 EPA 3510C 524609 EPA 8270E 524717
92464666002 TW-2 EPA 3510C 524609 EPA 8270E 524717
92464666003 TW-3 EPA 3510C 524609 EPA 8270E 524717
92464666004 TW-4 EPA 3510C 524609 EPA 8270E 524717
92464666005 TW-5 EPA 3510C 524609 EPA 8270E 524717
92464666006 TW-6 EPA 3510C 524609 EPA 8270E 524717
92464666007 TW-7 EPA 3510C 524609 EPA 8270E 524717
92464666001 TW-1 EPA 8260D 524737
92464666002 TW-2 EPA 8260D 524737
92464666003 TW-3 EPA 8260D 524737
92464666004 TW-4 EPA 8260D 524737
92464666005 TW-5 EPA 8260D 524737
92464666006 TW-6 EPA 8260D 524737
92464666007 TW-7 EPA 8260D 524737
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 44 of 47
Document Name: Document Revised:February 7,2018
Sample Condition Upon Receipt(SCUR) Page 1 of 22ceAnalytical'Document No.: Issuing Authority:
F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville [ Eden[1] Greenwood Huntersville Raleigh Mechanicsville
Sample Condition - Client Name: WO# : 92464666UponReceiptI • Project r$:
1=CN C,1 { c .
Courier: Fed Ex UPS
Other:
Llient II Ill!II III I I III IIICommercialPace
92454566
Custody Seal Present? Yes 12f1-6. Seals Intact? Yes f-"
Date/Initials Person Examining Contents:' G J//-"70
Packing Material: Bubble Wrap Bubble Bags None Other Biological Tissue Frozen?
Thermometer Yes 0/1 ON/A
41 R Gun ID: 92T058 Type of Ice: plArel etue ['None
Cooler Temp(%): ...7C 62 Correction Factor:Add/Subtract(°C) 0.0°C
Temp should be above freezing to VC
Cooler Temp Corrected CC): (.- lJc
Samples out of temp criteria.Samples on ice,cooling process
has begun
USDA Regulated Soil ( N/A,water sample)
Did samples o rigin a in a quarantine zone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign source(internationally,
Yes Including Hawaii and Puerto Rico)?Oyes No
Comments/Discrepancy:
Chain of Custody Present? yes :No ON/A 1.
Samples Arrived within Hold Time? tQres No ON/A 2.
Short Hold Time Analysis(<72 hr.)? Des No N/A 3.
Rush Turn Around Time Requested? es No ON/A 4.
Sufficient Volume? ji]' No ON/A 5.
Correct Containers Used? yes No ON/A 6.
Pace Containers Used? yes No ON/A
Containers Intact? 1s No ON/A 7.
Dissolved analysis:Samples Field Filtered? Y s No &." 8.
Sample Labels Match COC? Yes ONo ON/A 9.
I Cl iiatritu nalysi> Mali IA, 1`v +
Headspace in VOA Vials(>5-6mm)? Dees No ON/A 10.
Trip Blank Present? Des L 3ri7 ON/A 11.
Trip Blank Custody Seals Present? Dyes ONO /A
COMMENTS/SAMPLE DISCREPANCY Field Data Required? Des No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Page 45 of 47
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SAMPLER NAME AND SIGNATURE
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Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pac.Iaba.com 704)875-9092
August 14, 2020
Chris Orrell
ECS Southeast, LLP
1900 Center Park Dr
Suite D
Charlotte, NC 28217
RE: Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Dear Chris Orrell:
Enclosed are the analytical results for sample(s)received by the laboratory on August 07,2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
Pace National-Mt. Juliet
Pace Analytical Services-Asheville
Pace Analytical Services-Charlotte
A revised report is being submitted on 8/14/2020 to update all units to mg/kg..
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
704)875-9092
Project Manager
Enclosures
cc: ECS Southeast Reporting,ECS Southeast
REPORT OF LABORATORY ANALYSISilli
40 This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 1 of 111
Pace Analytical Services,LLC2ce9800KinceyAve. Suite 100AnalyticalHuntersville,NC 28078
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CERTIFICATIONS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Pace Analytical Services National
12065 Lebanon Road,Mt.Juliet,TN 37122 Nevada Certification#:TN-03-2002-34
Alabama Certification#:40660 New Hampshire Certification#: 2975
Alaska Certification 17-026 New Jersey Certification#:TN002
Arizona Certification#:AZ0612 New Mexico DW Certification
Arkansas Certification#:88-0469 New York Certification#: 11742
California Certification#:2932 North Carolina Aquatic Toxicity Certification#:41
Canada Certification#:1461.01 North Carolina Drinking Water Certification#:21704
Colorado Certification#:TN00003 North Carolina Environmental Certificate#:375
Connecticut Certification#:PH-0197 North Dakota Certification#:R-140
DOD Certification:#1461.01 Ohio VAP Certification#:CL0069
EPA#TN00003 Oklahoma Certification#:9915
Florida Certification#:E87487 Oregon Certification#:TN200002
Georgia DW Certification#:923 Pennsylvania Certification#:68-02979
Georgia Certification:NELAP Rhode Island Certification#:LA000356
Idaho Certification#:TN00003 South Carolina Certification#:84004
Illinois Certification#:200008 South Dakota Certification
Indiana Certification#:C-TN-01 Tennessee DW/Chem/Micro Certification#: 2006
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Kansas Certification#:E-10277 Texas Mold Certification#:LAB0152
Kentucky UST Certification#:16 USDA Soil Permit#:P330-15-00234
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Montana Certification#:CERT0086 AIHA-LAP/LLC EMLAP Certification#:100789
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Pace Analytical Services Charlotte
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Certification#:99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
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Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
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REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 KinceyAve. Suite 100
aceAnalytical Huntersville,NC 28078
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SAMPLE SUMMARY
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Lab ID Sample ID Matrix Date Collected Date Received
92489806001 SS-1A Solid 08/04/20 15:00 08/07/20 10:00
92489806002 SS-2B Solid 08/04/20 14:15 08/07/20 10:00
92489806003 SS-3C Solid 08/05/20 10:40 08/07/20 10:00
92489806004 SS-4D Solid 08/06/20 16:00 08/07/20 10:00
92489806005 SS-5E Solid 08/06/20 16:30 08/07/20 10:00
92489806006 SS-6F Solid 08/06/20 17:00 08/07/20 10:00
92489806007 SS-7G Solid 08/06/20 17:30 08/07/20 10:00
92489806008 SS-8H Solid 08/06/20 18:00 08/07/20 10:00
92489806009 SS-DUP Solid 08/06/20 00:00 08/07/20 10:00
92489806010 SS-1 Solid 08/04/20 13:00 08/07/20 10:00
92489806011 SS-2 Solid 08/05/20 13:45 08/07/20 10:00
92489806012 SS-3 Solid 08/05/20 14:00 08/07/20 10:00
92489806013 SS-4 Solid 08/06/20 16:00 08/07/20 10:00
92489806014 SS-5 Solid 08/06/20 16:30 08/07/20 10:00
92489806015 SS-6 Solid 08/06/20 17:00 08/07/20 10:00
92489806016 SS-7 Solid 08/06/20 17:30 08/07/20 10:00
92489806017 SS-8 Solid 08/06/20 18:00 08/07/20 10:00
92489806018 Trip Blank Water 08/06/20 00:00 08/07/20 10:00
92489806019 TW-1 Water 08/05/20 15:40 08/07/20 10:00
92489806020 TW-2 Water 08/05/20 16:30 08/07/20 10:00
92489806021 TW-DUP Water 08/05/20 16:30 08/07/20 10:00
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
www.paeelabs.com 704)875-9092
i
SAMPLE ANALYTE COUNT
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92489806001 SS-1A EPA8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
92489806002 SS-2B EPA 8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
92489806003 SS-3C EPA 8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
92489806004 SS-4D EPA 8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
92489806005 SS-5E EPA 8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
92489806006 SS-6F EPA 8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
92489806007 SS-7G EPA 8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
92489806008 SS-8H EPA 8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
92489806009 SS-DUP EPA6010D SH1 7 PASI-A
EPA7471B SOO 1 PASI-A
EPA 8270E BPJ 75 PASI-C
EPA 8260D SAS 70 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806010 SS-1 EPA6010D SH1 7 PASI-A
EPA 7471 B SOO 1 PASI-A
EPA 8270E BPJ 75 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806011 SS-2 EPA6010D SH1 7 PASI-A
EPA 7471 B SOO 1 PASI-A
EPA 8270E BPJ 75 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806012 SS-3 EPA6010D SH1 7 PASI-A
EPA 7471 B SOO 1 PASI-A
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.paeNabs.com 704)875-9092
SAMPLE ANALYTE COUNT
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
EPA 8270E BPJ 75 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806013 SS-4 EPA 6010D SH1 7 PASI-A
EPA7471B SOO 1 PASI-A
EPA 8270E BPJ 75 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806014 SS-5 EPA6010D SH1 7 PASI-A
EPA 7471B SOO 1 PASI-A
EPA 8270E BPJ 75 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806015 SS-6 EPA 6010D SH1 7 PASI-A
EPA 7471B SOO 1 PASI-A
EPA 8270E BPJ 75 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806016 SS-7 EPA 6010D SH1 7 PASI-A
EPA7471B SOO 1 PASI-A
EPA 8270E BPJ 75 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806017 SS-8 EPA6010D SH1 7 PASI-A
EPA 7471B SOO 1 PASI-A
EPA 8270E BPJ 75 PASI-C
ASTM D2974-87 KDF 1 PASI-C
SM 2540G KBC 1 PAN
EPA 7199 MSP 1 PAN
92489806018 Trip Blank EPA 8260D CL 63 PASI-C
92489806019 TW-1 EPA 8270E PKS 74 PASI-C
EPA 8260D CL 63 PASI-C
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 980o Kincey Ave. Suite100
Huntersville,NC 28078078
www.pacelabs.com 704)875-9092
SAMPLE ANALYTE COUNT
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92489806020 TW-2 EPA 8270E PKS 74 PASI-C
EPA 8260D CL 63 PASI-C
92489806021 TW-DUP EPA 8270E PKS 74 PASI-C
EPA 8260D CL 63 PASI-C
PAN=Pace National-Mt.Juliet
PASI-A=Pace Analytical Services-Asheville
PASI-C=Pace Analytical Services-Charlotte
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 KinceyAve. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-1A Lab ID: 92489806001 Collected: 08/04/20 15:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.054 0.020 1 08/10/20 10:28 08/10/20 15:14 67-64-1 IK
Benzene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:14 71-43-2
Bromobenzene ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 15:14 108-86-1
Bromochloromethane ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 15:14 74-97-5
Bromodichloromethane ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 15:14 75-27-4
Bromoform ND mg/kg 0.0027 0.0014 1 08/10/20 10:28 08/10/20 15:14 75-25-2
Bromomethane ND mg/kg 0.0054 0.0042 1 08/10/20 10:28 08/10/20 15:14 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.054 0.023 1 08/10/20 10:28 08/10/20 15:14 78-93-3
n-Butylbenzene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:14 104-51-8
sec-Butylbenzene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:14 135-98-8
tert-Butylbenzene ND mg/kg 0.0027 0.0014 1 08/10/20 10:28 08/10/20 15:14 98-06-6
Carbon tetrachloride ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 15:14 56-23-5
Chlorobenzene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:14 108-90-7
Chloroethane ND mg/kg 0.0054 0.0028 1 08/10/20 10:28 08/10/20 15:14 75-00-3
Chloroform ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 15:14 67-66-3
Chloromethane ND mg/kg 0.0054 0.0038 1 08/10/20 10:28 08/10/20 15:14 74-87-3
2-Chlorotoluene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:14 95-49-8
4-Chlorotoluene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:14 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.0027 0.0025 1 08/10/20 10:28 08/10/20 15:14 96-12-8
Dibromochloromethane ND mg/kg 0.0027 0.0014 1 08/10/20 10:28 08/10/20 15:14 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:14 106-93-4
Dibromomethane ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 15:14 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 15:14 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.0027 0.0022 1 08/10/20 10:28 08/10/20 15:14 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 15:14 106-46-7
Dichlorodifluoromethane ND mg/kg 0.0054 0.00092 1 08/10/20 10:28 08/10/20 15:14 75-71-8
1,1-Dichloroethane ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 15:14 75-34-3
1,2-Dichloroethane ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 15:14 107-06-2
1,1-Dichloroethene ND mg/kg 0.0027 0.00084 1 08/10/20 10:28 08/10/20 15:14 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:14 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 15:14 156-60-5
1,2-Dichloropropane ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:14 78-87-5
1,3-Dichloropropane ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:14 142-28-9
2,2-Dichloropropane ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:14 594-20-7
1,1-Dichloropropene ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 15:14 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:14 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.0027 0.0023 1 08/10/20 10:28 08/10/20 15:14 10061-02-6
Diisopropyl ether ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 15:14 108-20-3
Ethylbenzene ND mg/kg 0.0027 0.0025 1 08/10/20 10:28 08/10/20 15:14 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.0027 0.0025 1 08/10/20 10:28 08/10/20 15:14 87-68-3
2-Hexanone ND mg/kg 0.027 0.0053 1 08/10/20 10:28 08/10/20 15:14 591-78-6
I
Isopropylbenzene(Cumene) ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:14 98-82-8
p-Isopropyltoluene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:14 99-87-6
Methylene Chloride ND mg/kg 0.011 0.0040 1 08/10/20 10:28 08/10/20 15:14 75-09-2
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
ace Analytical
N 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-1A Lab ID: 92489806001 Collected: 08/04/20 15:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.027 0.023 1 08/10/20 10:28 08/10/20 15:14 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:14 1634-04-4
Naphthalene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:14 91-20-3
n-Propylbenzene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:14 103-65-1
Styrene ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 15:14 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 15:14 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.0027 0.0024 1 08/10/20 10:28 08/10/20 15:14 79-34-5
Tetrachloroethene ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 15:14 127-18-4
Toluene 0.0019J mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:14 108-88-3
1,2,3-Trichlorobenzene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 15:14 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:14 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 15:14 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 15:14 79-00-5
Trichloroethene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:14 79-01-6
Trichlorofluoromethane ND mg/kg 0.0027 0.00066 1 08/10/20 10:28 08/10/20 15:14 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.0027 0.0022 1 08/10/20 10:28 08/10/20 15:14 96-18-4
1,2,4-Trimethylbenzene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:14 95-63-6
1,3,5-Trimethylbenzene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 15:14 108-67-8
Vinyl acetate ND mg/kg 0.027 0.0023 1 08/10/20 10:28 08/10/20 15:14 108-05-4
Vinyl chloride ND mg/kg 0.0054 0.0010 1 08/10/20 10:28 08/10/20 15:14 75-01-4
Xylene(Total) ND mg/kg 0.0054 0.0015 1 08/10/20 10:28 08/10/20 15:14 1330-20-7
m&p-Xylene ND mg/kg 0.0054 0.0041 1 08/10/20 10:28 08/10/20 15:14 179601-23-1
o-Xylene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:14 95-47-6
Surrogates
Toluene-d8(S) 104 % 70-130 1 08/10/20 10:28 08/10/20 15:14 2037-26-5
4-Bromofluorobenzene(S) 104 % 70-130 1 08/10/20 10:28 08/10/20 15:14 460-00-4
1,2-Dichloroethane-d4(S) 105 % 70-132 1 08/10/20 10:28 08/10/20 15:14 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 21.2 % 0.10 0.10 1 08/07/20 17:25
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
Kincey Ave.100te
ace Analytical 9800Huntersv lle,NC128078lJwwww.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-2B Lab ID: 92489806002 Collected: 08/04/20 14:15 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.056 0.021 1 08/10/20 10:28 08/10/20 15:32 67-64-1 IK
Benzene ND mg/kg 0.0028 0.0020 1 08/10/20 10:28 08/10/20 15:32 71-43-2
Bromobenzene ND mg/kg 0.0028 0.0019 1 08/10/20 10:28 08/10/20 15:32 108-86-1
Bromochloromethane ND mg/kg 0.0028 0.0021 1 08/10/20 10:28 08/10/20 15:32 74-97-5
Bromodichloromethane ND mg/kg 0.0028 0.0018 1 08/10/20 10:28 08/10/20 15:32 75-27-4
Bromoform ND mg/kg 0.0028 0.0015 1 08/10/20 10:28 08/10/20 15:32 75-25-2
Bromomethane ND mg/kg 0.0056 0.0044 1 08/10/20 10:28 08/10/20 15:32 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.056 0.024 1 08/10/20 10:28 08/10/20 15:32 78-93-3
n-Butylbenzene ND mg/kg 0.0028 0.0015 1 08/10/20 10:28 08/10/20 15:32 104-51-8
sec-Butylbenzene ND mg/kg 0.0028 0.0018 1 08/10/20 10:28 08/10/20 15:32 135-98-8
tert-Butylbenzene ND mg/kg 0.0028 0.0015 1 08/10/20 10:28 08/10/20 15:32 98-06-6
Carbon tetrachloride ND mg/kg 0.0028 0.0012 1 08/10/20 10:28 08/10/20 15:32 56-23-5
Chlorobenzene ND mg/kg 0.0028 0.0018 1 08/10/20 10:28 08/10/20 15:32 108-90-7
Chloroethane ND mg/kg 0.0056 0.0030 1 08/10/20 10:28 08/10/20 15:32 75-00-3
Chloroform ND mg/kg 0.0028 0.0014 1 08/10/20 10:28 08/10/20 15:32 67-66-3
Chloromethane ND mg/kg 0.0056 0.0039 1 08/10/20 10:28 08/10/20 15:32 74-87-3
2-Chlorotoluene ND mg/kg 0.0028 0.0020 1 08/10/20 10:28 08/10/20 15:32 95-49-8
4-Chlorotoluene ND mg/kg 0.0028 0.0018 1 08/10/20 10:28 08/10/20 15:32 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.0028 0.0026 1 08/10/20 10:28 08/10/20 15:32 96-12-8
Dibromochloromethane ND mg/kg 0.0028 0.0015 1 08/10/20 10:28 08/10/20 15:32 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.0028 0.0020 1 08/10/20 10:28 08/10/20 15:32 106-93-4
Dibromomethane ND mg/kg 0.0028 0.0014 1 08/10/20 10:28 08/10/20 15:32 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.0028 0.0017 1 08/10/20 10:28 08/10/20 15:32 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.0028 0.0023 1 08/10/20 10:28 08/10/20 15:32 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.0028 0.0021 1 08/10/20 10:28 08/10/20 15:32 106-46-7
Dichlorodifluoromethane ND mg/kg 0.0056 0.00096 1 08/10/20 10:28 08/10/20 15:32 75-71-8
1,1-Dichloroethane ND mg/kg 0.0028 0.0012 1 08/10/20 10:28 08/10/20 15:32 75-34-3
1,2-Dichloroethane ND mg/kg 0.0028 0.0011 1 08/10/20 10:28 08/10/20 15:32 107-06-2
1,1-Dichloroethene ND mg/kg 0.0028 0.00088 1 08/10/20 10:28 08/10/20 15:32 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.0028 0.0016 1 08/10/20 10:28 08/10/20 15:32 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.0028 0.0012 1 08/10/20 10:28 08/10/20 15:32 156-60-5
1,2-Dichloropropane ND mg/kg 0.0028 0.0017 1 08/10/20 10:28 08/10/20 15:32 78-87-5
1,3-Dichloropropane ND mg/kg 0.0028 0.0019 1 08/10/20 10:28 08/10/20 15:32 142-28-9
2,2-Dichloropropane ND mg/kg 0.0028 0.0015 1 08/10/20 10:28 08/10/20 15:32 594-20-7
1,1-Dichloropropene ND mg/kg 0.0028 0.0013 1 08/10/20 10:28 08/10/20 15:32 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.0028 0.0018 1 08/10/20 10:28 08/10/20 15:32 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.0028 0.0024 1 08/10/20 10:28 08/10/20 15:32 10061-02-6
Diisopropyl ether ND mg/kg 0.0028 0.0011 1 08/10/20 10:28 08/10/20 15:32 108-20-3
Ethylbenzene ND mg/kg 0.0028 0.0026 1 08/10/20 10:28 08/10/20 15:32 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.0028 0.0026 1 08/10/20 10:28 08/10/20 15:32 87-68-3
2-Hexanone ND mg/kg 0.028 0.0055 1 08/10/20 10:28 08/10/20 15:32 591-78-6
Isopropylbenzene(Cumene) ND mg/kg 0.0028 0.0018 1 08/10/20 10:28 08/10/20 15:32 98-82-8
p-Isopropyltoluene ND mg/kg 0.0028 0.0015 1 08/10/20 10:28 08/10/20 15:32 99-87-6
Methylene Chloride ND mg/kg 0.011 0.0041 1 08/10/20 10:28 08/10/20 15:32 75-09-2
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-2B Lab ID: 92489806002 Collected: 08/04/20 14:15 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.028 0.024 1 08/10/20 10:28 08/10/20 15:32 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.0028 0.0018 1 08/10/20 10:28 08/10/20 15:32 1634-04-4
Naphthalene ND mg/kg 0.0028 0.0016 1 08/10/20 10:28 08/10/20 15:32 91-20-3
n-Propylbenzene ND mg/kg 0.0028 0.0019 1 08/10/20 10:28 08/10/20 15:32 103-65-1
Styrene ND mg/kg 0.0028 0.0013 1 08/10/20 10:28 08/10/20 15:32 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.0028 0.0018 1 08/10/20 10:28 08/10/20 15:32 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.0028 0.0025 1 08/10/20 10:28 08/10/20 15:32 79-34-5
Tetrachloroethene ND mg/kg 0.0028 0.0014 1 08/10/20 10:28 08/10/20 15:32 127-18-4
Toluene 0.0019J mg/kg 0.0028 0.0016 1 08/10/20 10:28 08/10/20 15:32 108-88-3
1,2,3-Trichlorobenzene ND mg/kg 0.0028 0.0017 1 08/10/20 10:28 08/10/20 15:32 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.0028 0.0016 1 08/10/20 10:28 08/10/20 15:32 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.0028 0.0011 1 08/10/20 10:28 08/10/20 15:32 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.0028 0.0021 1 08/10/20 10:28 08/10/20 15:32 79-00-5
Trichloroethene ND mg/kg 0.0028 0.0017 1 08/10/20 10:28 08/10/20 15:32 79-01-6
Trichlorofluoromethane ND mg/kg 0.0028 0.00069 1 08/10/20 10:28 08/10/20 15:32 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.0028 0.0023 1 08/10/20 10:28 08/10/20 15:32 96-18-4
1,2,4-Trimethylbenzene ND mg/kg 0.0028 0.0020 1 08/10/20 10:28 08/10/20 15:32 95-63-6
1,3,5-Trimethylbenzene ND mg/kg 0.0028 0.0017 1 08/10/20 10:28 08/10/20 15:32 108-67-8
Vinyl acetate ND mg/kg 0.028 0.0024 1 08/10/20 10:28 08/10/20 15:32 108-05-4
Vinyl chloride ND mg/kg 0.0056 0.0011 1 08/10/20 10:28 08/10/20 15:32 75-01-4
Xylene(Total) ND mg/kg 0.0056 0.0016 1 08/10/20 10:28 08/10/20 15:32 1330-20-7
m&p-Xylene ND mg/kg 0.0056 0.0043 1 08/10/20 10:28 08/10/20 15:32 179601-23-1
o-Xylene ND mg/kg 0.0028 0.0016 1 08/10/20 10:28 08/10/20 15:32 95-47-6
Surrogates
Toluene-d8(S) 101 % 70-130 1 08/10/20 10:28 08/10/20 15:32 2037-26-5
4-Bromofluorobenzene(S) 102 % 70-130 1 08/10/20 10:28 08/10/20 15:32 460-00-4
1,2-Dichloroethane-d4(S) 106 % 70-132 1 08/10/20 10:28 08/10/20 15:32 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 24.6 % 0.10 0.10 1 08/07/20 17:25
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-3C Lab ID: 92489806003 Collected: 08/05/20 10:40 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035AJ5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.055 0.020 1 08/10/20 10:28 08/10/20 15:51 67-64-1 IK
Benzene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:51 71-43-2
Bromobenzene ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 15:51 108-86-1
Bromochloromethane ND mg/kg 0.0027 0.0021 1 08/10/20 10:28 08/10/20 15:51 74-97-5
Bromodichloromethane ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 15:51 75-27-4
Bromoform ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:51 75-25-2
Bromomethane ND mg/kg 0.0055 0.0043 1 08/10/20 10:28 08/10/20 15:51 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.055 0.023 1 08/10/20 10:28 08/10/20 15:51 78-93-3
n-Butylbenzene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:51 104-51-8
sec-Butylbenzene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:51 135-98-8
tert-Butylbenzene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:51 98-06-6
Carbon tetrachloride ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 15:51 56-23-5
Chlorobenzene ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 15:51 108-90-7
Chloroethane ND mg/kg 0.0055 0.0029 1 08/10/20 10:28 08/10/20 15:51 75-00-3
Chloroform ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 15:51 67-66-3
Chloromethane ND mg/kg 0.0055 0.0038 1 08/10/20 10:28 08/10/20 15:51 74-87-3
2-Chlorotoluene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:51 95-49-8
4-Chlorotoluene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:51 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.0027 0.0025 1 08/10/20 10:28 08/10/20 15:51 96-12-8
Dibromochloromethane ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:51 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:51 106-93-4
Dibromomethane ND mg/kg 0.0027 0.0014 1 08/10/20 10:28 08/10/20 15:51 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 15:51 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.0027 0.0023 1 08/10/20 10:28 08/10/20 15:51 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 15:51 106-46-7
Dichlorodifluoromethane ND mg/kg 0.0055 0.00094 1 08/10/20 10:28 08/10/20 15:51 75-71-8
1,1-Dichloroethane ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 15:51 75-34-3
1,2-Dichloroethane ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 15:51 107-06-2
1,1-Dichloroethene ND mg/kg 0.0027 0.00086 1 08/10/20 10:28 08/10/20 15:51 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 15:51 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 15:51 156-60-5
1,2-Dichloropropane ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:51 78-87-5
1,3-Dichloropropane ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:51 142-28-9
2,2-Dichloropropane ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:51 594-20-7
1,1-Dichloropropene ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 15:51 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 15:51 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.0027 0.0023 1 08/10/20 10:28 08/10/20 15:51 10061-02-6
Diisopropyl ether ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 15:51 108-20-3
Ethylbenzene ND mg/kg 0.0027 0.0026 1 08/10/20 10:28 08/10/20 15:51 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.0027 0.0026 1 08/10/20 10:28 08/10/20 15:51 87-68-3
2-Hexanone ND mg/kg 0.027 0.0054 1 08/10/20 10:28 08/10/20 15:51 591-78-6
Isopropylbenzene(Cumene) ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:51 98-82-8
i
p-Isopropyltoluene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:51 99-87-6
Methylene Chloride ND mg/kg 0.011 0.0040 1 08/10/20 10:28 08/10/20 15:51 75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 111
Pace Analytical Services,LLC
accAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-3C Lab ID: 92489806003 Collected: 08/05/20 10:40 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.027 0.023 1 08/10/20 10:28 08/10/20 15:51 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:51 1634-04-4
Naphthalene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:51 91-20-3
n-Propylbenzene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 15:51 103-65-1
Styrene ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 15:51 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 15:51 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.0027 0.0024 1 08/10/20 10:28 08/10/20 15:51 79-34-5
Tetrachloroethene ND mg/kg 0.0027 0.0014 1 08/10/20 10:28 08/10/20 15:51 127-18-4
Toluene 0.0030 mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 15:51 108-88-3
mg/kg1.2 3-Trichlorobenzene ND m /k 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:51 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 15:51 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 15:51 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 15:51 79-00-5
Trichloroethene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 15:51 79-01-6
Trichlorofluoromethane ND mg/kg 0.0027 0.00068 1 08/10/20 10:28 08/10/20 15:51 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.0027 0.0022 1 08/10/20 10:28 08/10/20 15:51 96-18-4
1,2,4-Trimethylbenzene ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 15:51 95-63-6
1,3,5-Trimethylbenzene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 15:51 108-67-8
Vinyl acetate ND mg/kg 0.027 0.0024 1 08/10/20 10:28 08/10/20 15:51 108-05-4
Vinyl chloride ND mg/kg 0.0055 0.0010 1 08/10/20 10:28 08/10/20 15:51 75-01-4
Xylene(Total) ND mg/kg 0.0055 0.0016 1 08/10/20 10:28 08/10/20 15:51 1330-20-7
m&p-Xylene ND mg/kg 0.0055 0.0042 1 08/10/20 10:28 08/10/20 15:51 179601-23-1
o-Xylene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 15:51 95-47-6
Surrogates
Toluene-d8(S) 103 % 70-130 1 08/10/20 10:28 08/10/20 15:51 2037-26-5
4-Bromofluorobenzene(S) 115 % 70-130 1 08/10/20 10:28 08/10/20 15:51 460-00-4
1,2-Dichloroethane-d4(S) 111 % 70-132 1 08/10/20 10:28 08/10/20 15:51 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 20.5 % 0.10 0.10 1 08/07/20 17:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.paeelaha.eom 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-4D Lab ID: 92489806004 Collected: 08/06/20 16:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.054 0.020 1 08/10/20 13:47 08/10/20 17:05 67-64-1 IK
Benzene ND mg/kg 0.0027 0.0019 1 08/10/20 13:47 08/10/20 17:05 71-43-2
Bromobenzene ND mg/kg 0.0027 0.0018 1 08/10/20 13:47 08/10/20 17:05 108-86-1
Bromochloromethane ND mg/kg 0.0027 0.0020 1 08/10/20 13:47 08/10/20 17:05 74-97-5
Bromodichloromethane ND mg/kg 0.0027 0.0018 1 08/10/20 13:47 08/10/20 17:05 75-27-4
Bromoform ND mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 75-25-2
Bromomethane ND mg/kg 0.0054 0.0042 1 08/10/20 13:47 08/10/20 17:05 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.054 0.023 1 08/10/20 13:47 08/10/20 17:05 78-93-3
n-Butylbenzene ND mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 104-51-8
sec-Butylbenzene ND mg/kg 0.0027 0.0017 1 08/10/20 13:47 08/10/20 17:05 135-98-8
tert-Butylbenzene ND mg/kg 0.0027 0.0014 1 08/10/20 13:47 08/10/20 17:05 98-06-6
Carbon tetrachloride ND mg/kg 0.0027 0.0012 1 08/10/20 13:47 08/10/20 17:05 56-23-5
Chlorobenzene ND mg/kg 0.0027 0.0017 1 08/10/20 13:47 08/10/20 17:05 108-90-7
Chloroethane ND mg/kg 0.0054 0.0029 1 08/10/20 13:47 08/10/20 17:05 75-00-3
Chloroform ND mg/kg 0.0027 0.0013 1 08/10/20 13:47 08/10/20 17:05 67-66-3
Chloromethane ND mg/kg 0.0054 0.0038 1 08/10/20 13:47 08/10/20 17:05 74-87-3
2-Chlorotoluene ND mg/kg 0.0027 0.0019 1 08/10/20 13:47 08/10/20 17:05 95-49-8
4-Chlorotoluene ND mg/kg 0.0027 0.0017 1 08/10/20 13:47 08/10/20 17:05 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.0027 0.0025 1 08/10/20 13:47 08/10/20 17:05 96-12-8
Dibromochloromethane ND mg/kg 0.0027 0.0014 1 08/10/20 13:47 08/10/20 17:05 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.0027 0.0019 1 08/10/20 13:47 08/10/20 17:05 106-93-4
Dibromomethane ND mg/kg 0.0027 0.0013 1 08/10/20 13:47 08/10/20 17:05 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.0027 0.0016 1 08/10/20 13:47 08/10/20 17:05 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.0027 0.0022 1 08/10/20 13:47 08/10/20 17:05 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.0027 0.0020 1 08/10/20 13:47 08/10/20 17:05 106-46-7
Dichlorodifluoromethane ND mg/kg 0.0054 0.00093 1 08/10/20 13:47 08/10/20 17:05 75-71-8
1,1-Dichloroethane ND mg/kg 0.0027 0.0012 1 08/10/20 13:47 08/10/20 17:05 75-34-3
1,2-Dichloroethane ND mg/kg 0.0027 0.0011 1 08/10/20 13:47 08/10/20 17:05 107-06-2
1,1-Dichloroethene ND mg/kg 0.0027 0.00085 1 08/10/20 13:47 08/10/20 17:05 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.0027 0.0012 1 08/10/20 13:47 08/10/20 17:05 156-60-5
1,2-Dichloropropane ND mg/kg 0.0027 0.0017 1 08/10/20 13:47 08/10/20 17:05 78-87-5
1,3-Dichloropropane ND mg/kg 0.0027 0.0019 1 08/10/20 13:47 08/10/20 17:05 142-28-9
2,2-Dichloropropane ND mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 594-20-7
1,1-Dichloropropene ND mg/kg 0.0027 0.0013 1 08/10/20 13:47 08/10/20 17:05 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.0027 0.0018 1 08/10/20 13:47 08/10/20 17:05 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.0027 0.0023 1 08/10/20 13:47 08/10/20 17:05 10061-02-6
Diisopropyl ether ND mg/kg 0.0027 0.0011 1 08/10/20 13:47 08/10/20 17:05 108-20-3
Ethylbenzene 0.0055 mg/kg 0.0027 0.0025 1 08/10/20 13:47 08/10/20 17:05 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.0027 0.0026 1 08/10/20 13:47 08/10/20 17:05 87-68-3
2-Hexanone ND mg/kg 0.027 0.0053 1 08/10/20 13:47 08/10/20 17:05 591-78-6
Isopropylbenzene(Cumene) 0.0058 mg/kg 0.0027 0.0017 1 08/10/20 13:47 08/10/20 17:05 98-82-8
p-Isopropyltoluene 0.0055 mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 99-87-6
Methylene Chloride ND mg/kg 0.011 0.0040 1 08/10/20 13:47 08/10/20 17:05 75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 111
Pace Analytical Services,LLC
CG /I n l,,}'' 9800 Kincey Ave. Suite 100
G/`11 l /( Huntersville,NC 28078
www.pacelabs_com
704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-4D Lab ID: 92489806004 Collected: 08/06/20 16:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.027 0.023 1 08/10/20 13:47 08/10/20 17:05 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.0027 0.0017 1 08/10/20 13:47 08/10/20 17:05 1634-04-4
Naphthalene 0.015 mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 91-20-3
n-Propylbenzene ND mg/kg 0.0027 0.0019 1 08/10/20 13:47 08/10/20 17:05 103-65-1
Styrene ND mg/kg 0.0027 0.0013 1 08/10/20 13:47 08/10/20 17:05 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.0027 0.0018 1 08/10/20 13:47 08/10/20 17:05 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.0027 0.0024 1 08/10/20 13:47 08/10/20 17:05 79-34-5
Tetrachloroethene ND mg/kg 0.0027 0.0013 1 08/10/20 13:47 08/10/20 17:05 127-18-4
Toluene 0.012 mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 108-88-3
1,2,3-Trichlorobenzene ND mg/kg 0.0027 0.0016 1 08/10/20 13:47 08/10/20 17:05 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.0027 0.0011 1 08/10/20 13:47 08/10/20 17:05 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.0027 0.0020 1 08/10/20 13:47 08/10/20 17:05 79-00-5
Trichloroethene ND mg/kg 0.0027 0.0017 1 08/10/20 13:47 08/10/20 17:05 79-01-6
Trichlorofluoromethane ND mg/kg 0.0027 0.00067 1 08/10/20 13:47 08/10/20 17:05 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.0027 0.0022 1 08/10/20 13:47 08/10/20 17:05 96-18-4
1,2,4-Trimethylbenzene 0.043 mg/kg 0.0027 0.0019 1 08/10/20 13:47 08/10/20 17:05 95-63-6
1,3,5-Trimethylbenzene 0.017 mg/kg 0.0027 0.0016 1 08/10/20 13:47 08/10/20 17:05 108-67-8
Vinyl acetate ND mg/kg 0.027 0.0023 1 08/10/20 13:47 08/10/20 17:05 108-05-4
Vinyl chloride ND mg/kg 0.0054 0.0010 1 08/10/20 13:47 08/10/20 17:05 75-01-4
Xylene(Total) 0.034 mg/kg 0.0054 0.0015 1 08/10/20 13:47 08/10/20 17:05 1330-20-7
m&p-Xylene 0.022 mg/kg 0.0054 0.0041 1 08/10/20 13:47 08/10/20 17:05 179601-23-1
o-Xylene 0.012 mg/kg 0.0027 0.0015 1 08/10/20 13:47 08/10/20 17:05 95-47-6
Surrogates
Toluene-d8(S) 101 % 70-130 1 08/10/20 13:47 08/10/20 17:05 2037-26-5
4-Bromofluorobenzene(S) 104 % 70-130 1 08/10/20 13:47 08/10/20 17:05 460-00-4
1,2-Dichloroethane-d4(S) 105 % 70-132 1 08/10/20 13:47 08/10/20 17:05 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 22.1 % 0.10 0.10 1 08/07/20 17:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 111
ace Analytical®
Pace Analytical Services,LLC
9800 Ku ceyAve. Suite 100
Huntersville,NC 28078
www.pacelahs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-5E Lab ID: 92489806005 Collected: 08/06/20 16:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.69 0.26 12.5 08/11/20 15:28 08/11/20 21:47 67-64-1 IK
Benzene ND mg/kg 0.035 0.024 12.5 08/11/20 15:28 08/11/20 21:47 71-43-2
Bromobenzene ND mg/kg 0.035 0.023 12.5 08/11/20 15:28 08/11/20 21:47 108-86-1
Bromochloromethane ND mg/kg 0.035 0.026 12.5 08/11/20 15:28 08/11/20 21:47 74-97-5
Bromodichloromethane ND mg/kg 0.035 0.023 12.5 08/11/20 15:28 08/11/20 21:47 75-27-4
Bromoform ND mg/kg 0.035 0.019 12.5 08/11/20 15:28 08/11/20 21:47 75-25-2
Bromomethane ND mg/kg 0.069 0.054 12.5 08/11/20 15:28 08/11/20 21:47 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.69 0.29 12.5 08/11/20 15:28 08/11/20 21:47 78-93-3
n-Butylbenzene ND mg/kg 0.035 0.019 12.5 08/11/20 15:28 08/11/20 21:47 104-51-8
sec-Butylbenzene ND mg/kg 0.035 0.022 12.5 08/11/20 15:28 08/11/20 21:47 135-98-8
tert-Butylbenzene ND mg/kg 0.035 0.019 12.5 08/11/20 15:28 08/11/20 21:47 98-06-6
Carbon tetrachloride ND mg/kg 0.035 0.015 12.5 08/11/20 15:28 08/11/20 21:47 56-23-5
Chlorobenzene ND mg/kg 0.035 0.022 12.5 08/11/20 15:28 08/11/20 21:47 108-90-7
Chloroethane ND mg/kg 0.069 0.037 12.5 08/11/20 15:28 08/11/20 21:47 75-00-3
Chloroform ND mg/kg 0.035 0.017 12.5 08/11/20 15:28 08/11/20 21:47 67-66-3
Chloromethane ND mg/kg 0.069 0.049 12.5 08/11/20 15:28 08/11/20 21:47 74-87-3
2-Chlorotoluene ND mg/kg 0.035 0.025 12.5 08/11/20 15:28 08/11/20 21:47 95-49-8
4-Chlorotoluene ND mg/kg 0.035 0.022 12.5 08/11/20 15:28 08/11/20 21:47 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.035 0.032 12.5 08/11/20 15:28 08/11/20 21:47 96-12-8
Dibromochloromethane ND mg/kg 0.035 0.019 12.5 08/11/20 15:28 08/11/20 21:47 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.035 0.024 12.5 08/11/20 15:28 08/11/20 21:47 106-93-4
Dibromomethane ND mg/kg 0.035 0.017 12.5 08/11/20 15:28 08/11/20 21:47 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.035 0.020 12.5 08/11/20 15:28 08/11/20 21:47 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.035 0.029 12.5 08/11/20 15:28 08/11/20 21:47 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.035 0.026 12.5 08/11/20 15:28 08/11/20 21:47 106-46-7
Dichlorodifluoromethane ND mg/kg 0.069 0.012 12.5 08/11/20 15:28 08/11/20 21:47 75-71-8
1,1-Dichloroethane ND mg/kg 0.035 0.015 12.5 08/11/20 15:28 08/11/20 21:47 75-34-3
1,2-Dichloroethane ND mg/kg 0.035 0.014 12.5 08/11/20 15:28 08/11/20 21:47 107-06-2
1,1-Dichloroethene ND mg/kg 0.035 0.011 12.5 08/11/20 15:28 08/11/20 21:47 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.035 0.020 12.5 08/11/20 15:28 08/11/20 21:47 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.035 0.015 12.5 08/11/20 15:28 08/11/20 21:47 156-60-5
1,2-Dichloropropane ND mg/kg 0.035 0.022 12.5 08/11/20 15:28 08/11/20 21:47 78-87-5
1,3-Dichloropropane ND mg/kg 0.035 0.024 12.5 08/11/20 15:28 08/11/20 21:47 142-28-9
2,2-Dichloropropane ND mg/kg 0.035 0.019 12.5 08/11/20 15:28 08/11/2021:47 594-20-7
1,1-Dichloropropene ND mg/kg 0.035 0.017 12.5 08/11/20 15:28 08/11/20 21:47 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.035 0.022 12.5 08/11/20 15:28 08/11/20 21:47 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.035 0.029 12.5 08/11/20 15:28 08/11/20 21:47 10061-02-6
Diisopropyl ether ND mg/kg 0.035 0.014 12.5 08/11/20 15:28 08/11/20 21:47 108-20-3
Ethylbenzene 0.71 mg/kg 0.035 0.032 12.5 08/11/20 15:28 08/11/20 21:47 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.035 0.033 12.5 08/11/20 15:28 08/11/20 21:47 87-68-3
2-Hexanone ND mg/kg 0.35 0.069 12.5 08/11/20 15:28 08/11/20 21:47 591-78-6
Isopropylbenzene(Cumene) ND mg/kg 0.035 0.022 12.5 08/11/20 15:28 08/11/20 21:47 98-82-8
p-lsopropyltoluene ND mg/kg 0.035 0.019 12.5 08/11/20 15:28 08/11/20 21:47 99-87-6
Methylene Chloride 0.10J mg/kg 0.14 0.051 12.5 08/11/20 15:28 08/11/20 21:47 75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 111
Pace Analytical Services,LLC
nQ /n', i-9800 Kincey Ave. Suite 100
CIr/'-I/ y( Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-5E Lab ID: 92489806005 Collected: 08/06/20 16:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.35 0.29 12.5 08/11/20 15:28 08/11/20 21:47 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.035 0.022 12.5 08/11/20 15:28 08/11/20 21:47 1634-04-4
Naphthalene 5.1 mg/kg 0.035 0.019 12.5 08/11/20 15:28 08/11/20 21:47 91-20-3
n-Propylbenzene 1.0 mg/kg 0.035 0.024 12.5 08/11/20 15:28 08/11/20 21:47 103-65-1
Styrene ND mg/kg 0.035 0.016 12.5 08/11/20 15:28 08/11/20 21:47 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.035 0.023 12.5 08/11/20 15:28 08/11/20 21:47 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.035 0.031 12.5 08/11/20 15:28 08/11/20 21:47 79-34-5
Tetrachloroethene ND mg/kg 0.035 0.017 12.5 08/11/20 15:28 08/11/20 21:47 127-18-4
Toluene 0.21 mg/kg 0.035 0.020 12.5 08/11/20 15:28 08/11/20 21:47 108-88-3
1,2,3-Trichlorobenzene ND mg/kg 0.035 0.021 12.5 08/11/20 15:28 08/11/20 21:47 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.035 0.019 12.5 08/11/20 15:28 08/11/20 21:47 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.035 0.014 12.5 08/11/20 15:28 08/11/20 21:47 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.035 0.026 12.5 08/11/20 15:28 08/11/20 21:47 79-00-5
Trichloroethene ND mg/kg 0.035 0.022 12.5 08/11/20 15:28 08/11/20 21:47 79-01-6
Trichlorofluoromethane ND mg/kg 0.035 0.0086 12.5 08/11/20 15:28 08/11/20 21:47 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.035 0.028 12.5 08/11/20 15:28 08/11/20 21:47 96-18-4
1,2,4-Trimethylbenzene 14.3 mg/kg 0.035 0.025 12.5 08/11/20 15:28 08/11/20 21:47 95-63-6
1,3,5-Trimethylbenzene 4.8 mg/kg 0.035 0.021 12.5 08/11/20 15:28 08/11/20 21:47 108-67-8
Vinyl acetate ND mg/kg 0.35 0.030 12.5 08/11/20 15:28 08/11/20 21:47 108-05-4
Vinyl chloride ND mg/kg 0.069 0.013 12.5 08/11/20 15:28 08/11/20 21:47 75-01-4
Xylene(Total) 5.6 mg/kg 0.069 0.020 12.5 08/11/20 15:28 08/11/20 21:47 1330-20-7
m&p-Xylene 3.8 mg/kg 0.069 0.053 12.5 08/11/20 15:28 08/11/20 21:47 179601-23-1
o-Xylene 1.8 mg/kg 0.035 0.020 12.5 08/11/20 15:28 08/11/20 21:47 95-47-6
Surrogates
Toluene-d8(S) 100 % 70-130 12.5 08/11/20 15:28 08/11/20 21:47 2037-26-5
4-Bromofluorobenzene(S) 100 % 70-130 12.5 08/11/20 15:28 08/11/20 21:47 460-00-4
1,2-Dichloroethane-d4(S) 108 04 70-132 12.5 08/11/20 15:28 08/11/20 21:47 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 21.4 % 0.10 0.10 1 08/07/20 17:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
www.pacelabs.cem 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-6F Lab ID: 92489806006 Collected: 08/06/20 17:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.037 0.014 1 08/10/20 13:47 08/10/20 17:24 67-64-1 IK
Benzene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 17:24 71-43-2
Bromobenzene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 17:24 108-86-1
Bromochloromethane ND mg/kg 0.0019 0.0014 1 08/10/20 13:47 08/10/20 17:24 74-97-5
Bromodichloromethane ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 75-27-4
Bromoform ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 17:24 75-25-2
Bromomethane ND mg/kg 0.0037 0.0029 1 08/10/20 13:47 08/10/20 17:24 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.037 0.016 1 08/10/20 13:47 08/10/20 17:24 78-93-3
n-Butylbenzene ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 17:24 104-51-8
sec-Butylbenzene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 135-98-8
tert-Butylbenzene ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 17:24 98-06-6
Carbon tetrachloride ND mg/kg 0.0019 0.00083 1 08/10/20 13:47 08/10/20 17:24 56-23-5
Chlorobenzene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 108-90-7
Chloroethane ND mg/kg 0.0037 0.0020 1 08/10/20 13:47 08/10/20 17:24 75-00-3
Chloroform ND mg/kg 0.0019 0.00092 1 08/10/20 13:47 08/10/20 17:24 67-66-3
Chloromethane ND mg/kg 0.0037 0.0026 1 08/10/20 13:47 08/10/20 17:24 74-87-3
2-Chlorotoluene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 17:24 95-49-8
4-Chlorotoluene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.0019 0.0017 1 08/10/20 13:47 08/10/20 17:24 96-12-8
Dibromochloromethane ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 17:24 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 17:24 106-93-4
Dibromomethane ND mg/kg 0.0019 0.00093 1 08/10/20 13:47 08/10/20 17:24 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 17:24 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.0019 0.0015 1 08/10/20 13:47 08/10/20 17:24 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.0019 0.0014 1 08/10/20 13:47 08/10/20 17:24 106-46-7
Dichlorodifluoromethane ND mg/kg 0.0037 0.00064 1 08/10/20 13:47 08/10/20 17:24 75-71-8
1,1-Dichloroethane ND mg/kg 0.0019 0.00082 1 08/10/20 13:47 08/10/20 17:24 75-34-3
1,2-Dichloroethane ND mg/kg 0.0019 0.00076 1 08/10/20 13:47 08/10/20 17:24 107-06-2
1,1-Dichloroethene ND mg/kg 0.0019 0.00058 1 08/10/20 13:47 08/10/20 17:24 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 17:24 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.0019 0.00081 1 08/10/20 13:47 08/10/20 17:24 156-60-5
1,2-Dichloropropane ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 78-87-5
1,3-Dichloropropane ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 17:24 142-28-9
2,2-Dichloropropane ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 17:24 594-20-7
1,1-Dichloropropene ND mg/kg 0.0019 0.00089 1 08/10/20 13:47 08/10/20 17:24 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.0019 0.0016 1 08/10/20 13:47 08/10/20 17:24 10061-02-6
Diisopropyl ether ND mg/kg 0.0019 0.00075 1 08/10/20 13:47 08/10/20 17:24 108-20-3
Ethylbenzene ND mg/kg 0.0019 0.0017 1 08/10/20 13:47 08/10/20 17:24 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.0019 0.0018 1 08/10/20 13:47 08/10/20 17:24 87-68-3
2-Hexanone ND mg/kg 0.019 0.0037 1 08/10/20 13:47 08/10/20 17:24 591-78-6
Isopropylbenzene(Cumene) ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 98-82-8
p-Isopropyltoluene ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 17:24 99-87-6
Methylene Chloride ND mg/kg 0.0074 0.0028 1 08/10/20 13:47 08/10/20 17:24 75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 111
Pace Analytical Services,LLC
ace Analytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelsbs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-6F Lab ID: 92489806006 Collected: 08/06/20 17:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.019 0.016 1 08/10/20 13:47 08/10/20 17:24 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 1634-04-4
Naphthalene 0.0045 mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 17:24 91-20-3
n-Propylbenzene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 17:24 103-65-1
Styrene ND mg/kg 0.0019 0.00088 1 08/10/20 13:47 08/10/20 17:24 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.0019 0.0016 1 08/10/20 13:47 08/10/20 17:24 79-34-5
Tetrachloroethene ND mg/kg 0.0019 0.00092 1 08/10/20 13:47 08/10/20 17:24 127-18-4
Toluene 0.0012J mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 17:24 108-88-3
1,2,3-Trichlorobenzene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 17:24 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 17:24 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.0019 0.00075 1 08/10/20 13:47 08/10/20 17:24 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.0019 0.0014 1 08/10/20 13:47 08/10/20 17:24 79-00-5
Trichloroethene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 17:24 79-01-6
Trichlorofluoromethane ND mg/kg 0.0019 0.00046 1 08/10/20 13:47 08/10/20 17:24 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.0019 0.0015 1 08/10/20 13:47 08/10/20 17:24 96-18-4
1,2,4-Trimethylbenzene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 17:24 95-63-6
1,3,5-Trimethylbenzene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 17:24 108-67-8
Vinyl acetate ND mg/kg 0.019 0.0016 1 08/10/20 13:47 08/10/20 17:24 108-05-4
Vinyl chloride ND mg/kg 0.0037 0.00071 1 08/10/20 13:47 08/10/20 17:24 75-01-4
Xylene(Total) ND mg/kg 0.0037 0.0011 1 08/10/20 13:47 08/10/20 17:24 1330-20-7
m&p-Xylene ND mg/kg 0.0037 0.0029 1 08/10/20 13:47 08/10/20 17:24 179601-23-1
o-Xylene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 17:24 95-47-6
Surrogates
Toluene-d8(S) 101 % 70-130 1 08/10/20 13:47 08/10/20 17:24 2037-26-5
4-Bromofluorobenzene(S) 102 % 70-130 1 08/10/20 13:47 08/10/20 17:24 460-00-4
1,2-Dichloroethane-d4(S) 104 % 70-132 1 08/10/20 13:47 08/10/20 17:24 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 14.1 % 0.10 0.10 1 08/07/20 17:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-7G Lab ID: 92489806007 Collected: 08/06/20 17:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.043 0.016 1 08/10/20 13:47 08/10/20 17:43 67-64-1 IK
Benzene ND mg/kg 0.0022 0.0015 1 08/10/20 13:47 08/10/20 17:43 71-43-2
Bromobenzene ND mg/kg 0.0022 0.0015 1 08/10/20 13:47 08/10/20 17:43 108-86-1
Bromochloromethane ND mg/kg 0.0022 0.0016 1 08/10/20 13:47 08/10/20 17:43 74-97-5
Bromodichloromethane ND mg/kg 0.0022 0.0014 1 08/10/20 13:47 08/10/20 17:43 75-27-4
Bromoform ND mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 75-25-2
Bromomethane ND mg/kg 0.0043 0.0034 1 08/10/20 13:47 08/10/20 17:43 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.043 0.018 1 08/10/20 13:47 08/10/20 17:43 78-93-3
n-Butylbenzene ND mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 104-51-8
sec-Butylbenzene ND mg/kg 0.0022 0.0014 1 08/10/20 13:47 08/10/20 17:43 135-98-8
tert-Butylbenzene ND mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 98-06-6
Carbon tetrachloride ND mg/kg 0.0022 0.00096 1 08/10/20 13:47 08/10/20 17:43 56-23-5
Chlorobenzene ND mg/kg 0.0022 0.0014 1 08/10/20 13:47 08/10/20 17:43 108-90-7
Chloroethane ND mg/kg 0.0043 0.0023 1 08/10/20 13:47 08/10/20 17:43 75-00-3
Chloroform ND mg/kg 0.0022 0.0011 1 08/10/20 13:47 08/10/20 17:43 67-66-3
Chloromethane ND mg/kg 0.0043 0.0030 1 08/10/20 13:47 08/10/20 17:43 74-87-3
2-Chlorotoluene ND mg/kg 0.0022 0.0015 1 08/10/20 13:47 08/10/20 17:43 95-49-8
4-Chlorotoluene ND mg/kg 0.0022 0.0014 1 08/10/20 13:47 08/10/20 17:43 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.0022 0.0020 1 08/10/20 13:47 08/10/20 17:43 96-12-8
Dibromochloromethane ND mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.0022 0.0015 1 08/10/20 13:47 08/10/20 17:43 106-93-4
Dibromomethane ND mg/kg 0.0022 0.0011 1 08/10/20 13:47 08/10/20 17:43 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.0022 0.0013 1 08/10/20 13:47 08/10/20 17:43 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.0022 0.0018 1 08/10/20 13:47 08/10/20 17:43 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.0022 0.0016 1 08/10/20 13:47 08/10/20 17:43 106-46-7
Dichlorodifluoromethane ND mg/kg 0.0043 0.00074 1 08/10/20 13:47 08/10/20 17:43 75-71-8
1,1-Dichloroethane ND mg/kg 0.0022 0.00095 1 08/10/20 13:47 08/10/20 17:43 75-34-3
1,2-Dichloroethane ND mg/kg 0.0022 0.00088 1 08/10/20 13:47 08/10/20 17:43 107-06-2
1,1-Dichloroethene ND mg/kg 0.0022 0.00068 1 08/10/20 13:47 08/10/20 17:43 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.0022 0.00094 1 08/10/20 13:47 08/10/20 17:43 156-60-5
1,2-Dichloropropane ND mg/kg 0.0022 0.0013 1 08/10/20 13:47 08/10/20 17:43 78-87-5
1,3-Dichloropropane ND mg/kg 0.0022 0.0015 1 08/10/20 13:47 08/10/20 17:43 142-28-9
2,2-Dichloropropane ND mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 594-20-7
1,1-Dichloropropene ND mg/kg 0.0022 0.0010 1 08/10/20 13:47 08/10/20 17:43 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.0022 0.0014 1 08/10/20 13:47 08/10/20 17:43 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.0022 0.0018 1 08/10/20 13:47 08/10/20 17:43 10061-02-6
Diisopropyl ether ND mg/kg 0.0022 0.00087 1 08/10/20 13:47 08/10/20 17:43 108-20-3
Ethylbenzene ND mg/kg 0.0022 0.0020 1 08/10/20 13:47 08/10/20 17:43 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.0022 0.0020 1 08/10/20 13:47 08/10/20 17:43 87-68-3
2-Hexanone ND mg/kg 0.022 0.0043 1 08/10/20 13:47 08/10/20 17:43 591-78-6
Isopropylbenzene(Cumene) ND mg/kg 0.0022 0.0014 1 08/10/20 13:47 08/10/20 17:43 98-82-8
p-Isopropyltoluene ND mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 99-87-6
Methylene Chloride ND mg/kg 0.0086 0.0032 1 08/10/20 13:47 08/10/20 17:43 75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 111
Pace Analytical Services,LLC11
9800 ncey Ave. Suite 100aenna/ytical Huntersville,NC 28078
www.pacelabs.com
704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-7G Lab ID: 92489806007 Collected: 08/06/20 17:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.022 0.018 1 08/10/20 13:47 08/10/20 17:43 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.0022 0.0014 1 08/10/20 13:47 08/10/20 17:43 1634-04-4
Naphthalene 0.0060 mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 91-20-3
n-Propylbenzene ND mg/kg 0.0022 0.0015 1 08/10/20 13:47 08/10/20 17:43 103-65-1
Styrene ND mg/kg 0.0022 0.0010 1 08/10/20 13:47 08/10/20 17:43 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.0022 0.0014 1 08/10/20 13:47 08/10/20 17:43 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.0022 0.0019 1 08/10/20 13:47 08/10/20 17:43 79-34-5
Tetrachloroethene ND mg/kg 0.0022 0.0011 1 08/10/20 13:47 08/10/20 17:43 127-18-4
Toluene 0.0043 mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 108-88-3
1,2,3-Trichlorobenzene ND mg/kg 0.0022 0.0013 1 08/10/20 13:47 08/10/20 17:43 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.0022 0.00087 1 08/10/20 13:47 08/10/20 17:43 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.0022 0.0016 1 08/10/20 13:47 08/10/20 17:43 79-00-5
Trichloroethene ND mg/kg 0.0022 0.0013 1 08/10/20 13:47 08/10/20 17:43 79-01-6
Trichlorofluoromethane ND mg/kg 0.0022 0.00053 1 08/10/20 13:47 08/10/20 17:43 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.0022 0.0018 1 08/10/20 13:47 08/10/20 17:43 96-18-4
1,2,4-Trimethylbenzene 0.0028 mg/kg 0.0022 0.0015 1 08/10/20 13:47 08/10/20 17:43 95-63-6
1,3,5-Trimethylbenzene 0.0013J mg/kg 0.0022 0.0013 1 08/10/20 13:47 08/10/20 17:43 108-67-8
Vinyl acetate ND mg/kg 0.022 0.0019 1 08/10/20 13:47 08/10/20 17:43 108-05-4
Vinyl chloride ND mg/kg 0.0043 0.00083 1 08/10/20 13:47 08/10/20 17:43 75-01-4
Xylene(Total) 0.0079 mg/kg 0.0043 0.0012 1 08/10/20 13:47 08/10/20 17:43 1330-20-7
m&p-Xylene 0.0048 mg/kg 0.0043 0.0033 1 08/10/20 13:47 08/10/20 17:43 179601-23-1
o-Xylene 0.0032 mg/kg 0.0022 0.0012 1 08/10/20 13:47 08/10/20 17:43 95-47-6
Surrogates
Toluene-d8(S) 100 % 70-130 1 08/10/20 13:47 08/10/20 17:43 2037-26-5
4-Bromofluorobenzene(S) 103 % 70-130 1 08/10/20 13:47 08/10/20 17:43 460-00-4
1,2-Dichloroethane-d4(S) 108 % 70-132 1 08/10/20 13:47 08/10/20 17:43 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 17.3 % 0.10 0.10 1 08/07/20 17:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-8H Lab ID: 92489806008 Collected: 08/06/20 18:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.037 0.014 1 08/10/20 13:47 08/10/20 18:01 67-64-1 IK
Benzene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 18:01 71-43-2
Bromobenzene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 18:01 108-86-1
Bromochloromethane ND mg/kg 0.0019 0.0014 1 08/10/20 13:47 08/10/20 18:01 74-97-5
Bromodichloromethane ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 75-27-4
Bromoform ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 18:01 75-25-2
Bromomethane ND mg/kg 0.0037 0.0029 1 08/10/20 13:47 08/10/20 18:01 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.037 0.016 1 08/10/20 13:47 08/10/20 18:01 78-93-3
n-Butylbenzene ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 18:01 104-51-8
sec-Butylbenzene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 135-98-8
tert-Butylbenzene ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 18:01 98-06-6
Carbon tetrachloride ND mg/kg 0.0019 0.00083 1 08/10/20 13:47 08/10/20 18:01 56-23-5
Chlorobenzene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 108-90-7
Chloroethane ND mg/kg 0.0037 0.0020 1 08/10/20 13:47 08/10/20 18:01 75-00-3
Chloroform ND mg/kg 0.0019 0.00092 1 08/10/20 13:47 08/10/20 18:01 67-66-3
Chloromethane ND mg/kg 0.0037 0.0026 1 08/10/20 13:47 08/10/20 18:01 74-87-3
2-Chlorotoluene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 18:01 95-49-8
4-Chlorotoluene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.0019 0.0017 1 08/10/20 13:47 08/10/20 18:01 96-12-8
Dibromochloromethane ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 18:01 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 18:01 106-93-4
Dibromomethane ND mg/kg 0.0019 0.00093 1 08/10/20 13:47 08/10/20 18:01 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 18:01 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.0019 0.0015 1 08/10/20 13:47 08/10/20 18:01 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.0019 0.0014 1 08/10/20 13:47 08/10/20 18:01 106-46-7
Dichlorodifluoromethane ND mg/kg 0.0037 0.00064 1 08/10/20 13:47 08/10/20 18:01 75-71-8
1,1-Dichloroethane ND mg/kg 0.0019 0.00082 1 08/10/20 13:47 08/10/20 18:01 75-34-3
1,2-Dichloroethane ND mg/kg 0.0019 0.00077 1 08/10/20 13:47 08/10/20 18:01 107-06-2
1,1-Dichloroethene ND mg/kg 0.0019 0.00059 1 08/10/20 13:47 08/10/20 18:01 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 18:01 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.0019 0.00081 1 08/10/20 13:47 08/10/20 18:01 156-60-5
1,2-Dichloropropane ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 78-87-5
1,3-Dichloropropane ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 18:01 142-28-9
2,2-Dichloropropane ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 18:01 594-20-7
1,1-Dichloropropene ND mg/kg 0.0019 0.00089 1 08/10/20 13:47 08/10/20 18:01 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.0019 0.0016 1 08/10/20 13:47 08/10/20 18:01 10061-02-6
Diisopropyl ether ND mg/kg 0.0019 0.00075 1 08/10/20 13:47 08/10/20 18:01 108-20-3
Ethylbenzene ND mg/kg 0.0019 0.0017 1 08/10/20 13:47 08/10/20 18:01 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.0019 0.0018 1 08/10/20 13:47 08/10/20 18:01 87-68-3
2-Hexanone ND mg/kg 0.019 0.0037 1 08/10/20 13:47 08/10/20 18:01 591-78-6
lsopropylbenzene(Cumene) ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 98-82-8
p-lsopropyltoluene ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 18:01 99-87-6
Methylene Chloride ND mg/kg 0.0075 0.0028 1 08/10/20 13:47 08/10/20 18:01 75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com
704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-8H Lab ID: 92489806008 Collected: 08/06/20 18:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"thy weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.019 0.016 1 08/10/20 13:47 08/10/20 18:01 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 1634-04-4
Naphthalene 0.0098 mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 18:01 91-20-3
n-Propylbenzene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 18:01 103-65-1
Styrene ND mg/kg 0.0019 0.00088 1 08/10/20 13:47 08/10/20 18:01 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.0019 0.0016 1 08/10/20 13:47 08/10/20 18:01 79-34-5
Tetrachloroethene 0.027 mg/kg 0.0019 0.00093 1 08/10/20 13:47 08/10/20 18:01 127-18-4
Toluene 0.0022 mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 18:01 108-88-3
1,2,3-Trichlorobenzene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 18:01 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.0019 0.0010 1 08/10/20 13:47 08/10/20 18:01 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.0019 0.00075 1 08/10/20 13:47 08/10/20 18:01 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.0019 0.0014 1 08/10/20 13:47 08/10/20 18:01 79-00-5
Trchloroethene 0.073 mg/kg 0.0019 0.0012 1 08/10/20 13:47 08/10/20 18:01 79-01-6
Trichlorofluoromethane ND mg/kg 0.0019 0.00046 1 08/10/20 13:47 08/10/20 18:01 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.0019 0.0015 1 08/10/20 13:47 08/10/20 18:01 96-18-4
1,2,4-Trimethylbenzene ND mg/kg 0.0019 0.0013 1 08/10/20 13:47 08/10/20 18:01 95-63-6
1,3,5-Trimethylbenzene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 18:01 108-67-8
Vinyl acetate ND mg/kg 0.019 0.0016 1 08/10/20 13:47 08/10/20 18:01 108-05-4
Vinyl chloride ND mg/kg 0.0037 0.00072 1 08/10/20 13:47 08/10/20 18:01 75-01-4
Xylene(Total) ND mg/kg 0.0037 0.0011 1 08/10/20 13:47 08/10/20 18:01 1330-20-7
m&p-Xylene ND mg/kg 0.0037 0.0029 1 08/10/20 13:47 08/10/20 18:01 179601-23-1
o-Xylene ND mg/kg 0.0019 0.0011 1 08/10/20 13:47 08/10/20 18:01 95-47-6
Surrogates
Toluene-d8(S) 102 % 70-130 1 08/10/20 13:47 08/10/20 18:01 2037-26-5
4-Bromofluorobenzene(S) 100 % 70-130 1 08/10/20 13:47 08/10/20 18:01 460-00-4
1,2-Dichloroethane-d4(S) 108 % 70-132 1 08/10/20 13:47 08/10/20 18:01 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 12.2 % 0.10 0.10 1 08/07/20 17:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-DUP Lab ID: 92489806009 Collected: 08/06/20 00:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3050B
Pace Analytical Services-Asheville
Arsenic 3.1 mg/kg 1.0 0.51 1 08/10/20 08:39 08/11/20 19:35 7440-38-2
Barium 56.2 mg/kg 0.51 0.26 1 08/10/20 08:39 08/11/20 19:35 7440-39-3 M1
Cadmium ND mg/kg 0.10 0.051 1 08/10/20 08:39 08/11/20 19:35 7440-43-9
Chromium 29.4 mg/kg 0.51 0.26 1 08/10/20 08:39 08/11/20 19:35 7440-47-3 M1,R1
Lead 12.0 mg/kg 0.51 0.26 1 08/10/20 08:39 08/11/20 19:35 7439-92-1 M1
Selenium 2.1 mg/kg 1.0 0.51 1 08/10/20 08:39 08/11/20 19:35 7782-49-2 M1
Silver 0.47J mg/kg 0.51 0.26 1 08/10/20 08:39 08/11/20 19:35 7440-22-4
7471 Mercury Analytical Method:EPA 7471 B Preparation Method:EPA 7471 B
Pace Analytical Services-Asheville
Mercury 0.018 mg/kg 0.0071 0.0055 1 08/10/20 10:10 08/11/20 16:45 7439-97-6 M1
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 83-32-9
Acenaphthylene ND mg/kg 0.42 0.099 1 08/10/20 17:24 08/11/20 11:09 208-96-8
Aniline ND mg/kg 0.42 0.094 1 08/10/20 17:24 08/11/20 11:09 62-53-3
Anthracene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 120-12-7
Benzo(a)anthracene ND mg/kg 0.42 0.13 1 08/10/20 17:24 08/11/20 11:09 56-55-3
Benzo(a)pyrene ND mg/kg 0.42 0.18 1 08/10/20 17:24 08/11/20 11:09 50-32-8
Benzo(b)fluoranthene ND mg/kg 0.42 0.17 1 08/10/20 17:24 08/11/20 11:09 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.42 0.16 1 08/10/20 17:24 08/11/20 11:09 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.42 0.18 1 08/10/20 17:24 08/11/20 11:09 207-08-9
Benzoic Acid ND mg/kg 2.1 0.45 1 08/10/20 17:24 08/11/20 11:09 65-85-0
Benzyl alcohol ND mg/kg 0.84 0.22 1 08/10/20 17:24 08/11/20 11:09 100-51-6
4-Bromophenylphenyl ether ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 101-55-3
Butylbenzylphthalate ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.84 0.26 1 08/10/20 17:24 08/11/20 11:09 59-50-7
4-Chloroaniline ND mg/kg 0.84 0.26 1 08/10/20 17:24 08/11/20 11:09 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.42 0.089 1 08/10/20 17:24 08/11/20 11:09 111-44-4
2-Chloronaphthalene ND mg/kg 0.42 0.093 1 08/10/20 17:24 08/11/20 11:09 91-58-7
2-Chlorophenol ND mg/kg 0.42 0.097 1 08/10/20 17:24 08/11/20 11:09 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 7005-72-3
Chrysene ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 11:09 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.42 0.17 1 08/10/20 17:24 08/11/20 11:09 53-70-3 v1
Dibenzofuran ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 11:09 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.42 0.091 1 08/10/20 17:24 08/11/20 11:09 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.42 0.094 1 08/10/20 17:24 08/11/20 11:09 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.42 0.092 1 08/10/20 17:24 08/11/20 11:09 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.84 0.29 1 08/10/20 17:24 08/11/20 11:09 91-94-1
2,4-Dichlorophenol ND mg/kg 0.42 0.14 1 08/10/20 17:24 08/11/20 11:09 120-83-2
Diethylphthalate ND mg/kg 0.42 0.091 1 08/10/20 17:24 08/11/20 11:09 84-66-2
2,4-Dimethylphenol ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 11:09 105-67-9
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-DUP Lab ID: 92489806009 Collected: 08/06/20 00:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.42 0.095 1 08/10/20 17:24 08/11/20 11:09 131-11-3
Di-n-butylphthalate ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 11:09 84-74-2
4,6-Dinitro-2-methylphenol ND mg/kg 0.84 0.68 1 08/10/20 17:24 08/11/20 11:09 534-52-1
2,4-Dinitrophenol ND mg/kg 2.1 1.3 1 08/10/20 17:24 08/11/20 11:09 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.42 0.24 1 08/10/20 17:24 08/11/20 11:09 117-84-0 v1
bis(2-Ethylhexyl)phthalate ND mg/kg 0.42 0.14 1 08/10/20 17:24 08/11/20 11:09 117-81-7
Fluoranthene ND mg/kg 0.42 0.13 1 08/10/20 17:24 08/11/20 11:09 206-44-0
Fluorene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 11:09 87-68-3
Hexachlorobenzene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.42 0.17 1 08/10/20 17:24 08/11/20 11:09 77-47-4
Hexachloroethane ND mg/kg 0.42 0.095 1 08/10/20 17:24 08/11/20 11:09 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.42 0.19 1 08/10/20 17:24 08/11/20 11:09 193-39-5 v1
Isophorone ND mg/kg 0.42 0.091 1 08/10/20 17:24 08/11/20 11:09 78-59-1
1-Methylnaphthalene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 90-12-0
2-Methylnaphthalene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.42 0.093 1 08/10/20 17:24 08/11/20 11:09 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 15831-10-4
Naphthalene ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 11:09 91-20-3
2-Nitroaniline ND mg/kg 2.1 0.21 1 08/10/20 17:24 08/11/20 11:09 88-74-4
3-Nitroaniline ND mg/kg 2.1 0.22 1 08/10/20 17:24 08/11/20 11:09 99-09-2
4-Nitroaniline ND mg/kg 0.84 0.21 1 08/10/20 17:24 08/11/20 11:09 100-01-6
Nitrobenzene ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 11:09 98-95-3
2-Nitrophenol ND mg/kg 0.42 0.13 1 08/10/20 17:24 08/11/20 11:09 88-75-5
4-Nitrophenol ND mg/kg 2.1 0.67 1 08/10/20 17:24 08/11/20 11:09 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 11:09 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 11:09 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 11:09 108-60-1
Pentachlorophenol ND mg/kg 0.84 0.19 1 08/10/20 17:24 08/11/20 11:09 87-86-5
Phenanthrene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 85-01-8
Phenol ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 11:09 108-95-2
Pyrene ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 11:09 129-00-0
Pyridine ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.42 0.096 1 08/10/20 17:24 08/11/20 11:09 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 11:09 88-06-2
Surrogates
Nitrobenzene-d5(S) 53 % 23-110 1 08/10/20 17:24 08/11/20 11:09 4165-60-0
2-Fluorobiphenyl(S) 57 % 30-110 1 08/10/20 17:24 08/11/20 11:09 321-60-8
Terphenyl-d14(S) 70 % 28-110 1 08/10/20 17:24 08/11/20 11:09 1718-51-0
Phenol-d6(S) 58 % 22-110 1 08/10/20 17:24 08/11/20 11:09 13127-88-3
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-DUP Lab ID: 92489806009 Collected: 08/06/20 00:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 55 % 13-110 1 08/10/20 17:24 08/11/20 11:09 367-12-4
2,4,6-Tribromophenol(S) 61 % 27-110 1 08/10/20 17:24 08/11/20 11:09 118-79-6
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Acetone ND mg/kg 0.054 0.020 1 08/10/20 10:28 08/10/20 16:09 67-64-1 IK
Benzene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 16:09 71-43-2
Bromobenzene ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 16:09 108-86-1
Bromochloromethane ND mg/kg 0.0027 0.0021 1 08/10/20 10:28 08/10/20 16:09 74-97-5
Bromodichloromethane ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 16:09 75-27-4
Bromoform ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 16:09 75-25-2
Bromomethane ND mg/kg 0.0054 0.0043 1 08/10/20 10:28 08/10/20 16:09 74-83-9 IK
2-Butanone(MEK) ND mg/kg 0.054 0.023 1 08/10/20 10:28 08/10/20 16:09 78-93-3
n-Butylbenzene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 16:09 104-51-8
sec-Butylbenzene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 16:09 135-98-8
tert-Butylbenzene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 16:09 98-06-6
Carbon tetrachloride ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 16:09 56-23-5
Chlorobenzene ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 16:09 108-90-7
Chloroethane ND mg/kg 0.0054 0.0029 1 08/10/20 10:28 08/10/20 16:09 75-00-3
Chloroform ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 16:09 67-66-3
Chloromethane ND mg/kg 0.0054 0.0038 1 08/10/20 10:28 08/10/20 16:09 74-87-3
2-Chlorotoluene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 16:09 95-49-8
4-Chlorotoluene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 16:09 106-43-4
1,2-Dibromo-3-chloropropane ND mg/kg 0.0027 0.0025 1 08/10/20 10:28 08/10/20 16:09 96-12-8
Dibromochloromethane ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 16:09 124-48-1
1,2-Dibromoethane(EDB) ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 16:09 106-93-4
Dibromomethane ND mg/kg 0.0027 0.0014 1 08/10/20 10:28 08/10/20 16:09 74-95-3
1,2-Dichlorobenzene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 16:09 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.0027 0.0023 1 08/10/20 10:28 08/10/20 16:09 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 16:09 106-46-7
Dichlorodifluoromethane ND mg/kg 0.0054 0.00094 1 08/10/20 10:28 08/10/20 16:09 75-71-8
1,1-Dichloroethane ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 16:09 75-34-3
1,2-Dichloroethane ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 16:09 107-06-2
1,1-Dichloroethene ND mg/kg 0.0027 0.00086 1 08/10/20 10:28 08/10/20 16:09 75-35-4
cis-1,2-Dichloroethene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 16:09 156-59-2
trans-1,2-Dichloroethene ND mg/kg 0.0027 0.0012 1 08/10/20 10:28 08/10/20 16:09 156-60-5
1,2-Dichloropropane ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 16:09 78-87-5
1,3-Dichloropropane ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 16:09 142-28-9
2,2-Dichloropropane ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 16:09 594-20-7
1,1-Dichloropropene ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 16:09 563-58-6
cis-1,3-Dichloropropene ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 16:09 10061-01-5
trans-1,3-Dichloropropene ND mg/kg 0.0027 0.0023 1 08/10/20 10:28 08/10/20 16:09 10061-02-6
Diisopropyl ether ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 16:09 108-20-3
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 25 of 111
1
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F.
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
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704)875-9092
1
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-DUP Lab ID: 92489806009 Collected: 08/06/20 00:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D/5035A/5030B Volatiles Analytical Method:EPA 8260D Preparation Method:EPA 5035A/5030B
Pace Analytical Services-Charlotte
Ethylbenzene ND mg/kg 0.0027 0.0025 1 08/10/20 10:28 08/10/20 16:09 100-41-4
Hexachloro-1,3-butadiene ND mg/kg 0.0027 0.0026 1 08/10/20 10:28 08/10/20 16:09 87-68-3
2-Hexanone ND mg/kg 0.027 0.0054 1 08/10/20 10:28 08/10/20 16:09 591-78-6
Isopropylbenzene(Cumene) ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 16:09 98-82-8
p-lsopropyltoluene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 16:09 99-87-6
Methylene Chloride ND mg/kg 0.011 0.0040 1 08/10/20 10:28 08/10/20 16:09 75-09-2
4-Methyl-2-pentanone(MIBK) ND mg/kg 0.027 0.023 1 08/10/20 10:28 08/10/20 16:09 108-10-1
Methyl-tert-butyl ether ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 16:09 1634-04-4
Naphthalene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 16:09 91-20-3
n-Propylbenzene ND mg/kg 0.0027 0.0019 1 08/10/20 10:28 08/10/20 16:09 103-65-1
Styrene ND mg/kg 0.0027 0.0013 1 08/10/20 10:28 08/10/20 16:09 100-42-5
1,1,1,2-Tetrachloroethane ND mg/kg 0.0027 0.0018 1 08/10/20 10:28 08/10/20 16:09 630-20-6
1,1,2,2-Tetrachloroethane ND mg/kg 0.0027 0.0024 1 08/10/20 10:28 08/10/20 16:09 79-34-5
Tetrachloroethene ND mg/kg 0.0027 0.0014 1 08/10/20 10:28 08/10/20 16:09 127-18-4
Toluene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 16:09 108-88-3
1,2,3-Trichlorobenzene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 16:09 87-61-6
1,2,4-Trichlorobenzene ND mg/kg 0.0027 0.0015 1 08/10/20 10:28 08/10/20 16:09 120-82-1
1,1,1-Trichloroethane ND mg/kg 0.0027 0.0011 1 08/10/20 10:28 08/10/20 16:09 71-55-6
1,1,2-Trichloroethane ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 16:09 79-00-5
Trichloroethene ND mg/kg 0.0027 0.0017 1 08/10/20 10:28 08/10/20 16:09 79-01-6
Trichlorofluoromethane ND mg/kg 0.0027 0.00068 1 08/10/20 10:28 08/10/20 16:09 75-69-4
1,2,3-Trichloropropane ND mg/kg 0.0027 0.0022 1 08/10/20 10:28 08/10/20 16:09 96-18-4
1,2,4-Trimethylbenzene ND mg/kg 0.0027 0.0020 1 08/10/20 10:28 08/10/20 16:09 95-63-6
1,3,5-Trimethylbenzene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 16:09 108-67-8
Vinyl acetate ND mg/kg 0.027 0.0024 1 08/10/20 10:28 08/10/20 16:09 108-05-4
Vinyl chloride ND mg/kg 0.0054 0. 1 1ygg000 08/10/20 10:28 08/10/20 16:09 75-01-4
Xylene(Total) ND mg/kg 0.0054 0.0016 1 08/10/20 10:28 08/10/20 16:09 1330-20-7
m&p-Xylene ND mg/kg 0.0054 0.0042 1 08/10/20 10:28 08/10/20 16:09 179601-23-1
o-Xylene ND mg/kg 0.0027 0.0016 1 08/10/20 10:28 08/10/20 16:09 95-47-6
Surrogates
Toluene-d8(S) 100 % 70-130 1 08/10/20 10:28 08/10/20 16:09 2037-26-5
4-Bromofluorobenzene(S) 101 % 70-130 1 08/10/20 10:28 08/10/20 16:09 460-00-4
1,2-Dichloroethane-d4(S) 112 % 70-132 1 08/10/20 10:28 08/10/20 16:09 17060-07-0
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 21.2 % 0.10 0.10 1 08/07/20 17:26
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G
Pace National-Mt.Juliet
Total Solids 73.1 % 1 08/13/20 10:30 08/13/20 10:42
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-DUP Lab ID: 92489806009 Collected: 08/06/20 00:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Wet Chemistry 7199 Analytical Method: EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium,Hexavalent ND mg/kg 1.37 0.349 1 08/12/20 10:20 08/12/20 17:07 18540-29-9
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 27 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite100
Huntersville,NC 28078078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-1 Lab ID: 92489806010 Collected: 08/04/20 13:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "d weight"basis and are forpercent moisture,sample size and anydilutions.P dry 9 adjustedP
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method:EPA 3050B
Pace Analytical Services-Asheville
Arsenic 2.8 mg/kg 0.77 0.38 1 08/10/20 08:39 08/11/20 19:48 7440-38-2
Barium 75.0 mg/kg 0.38 0.19 1 08/10/20 08:39 08/11/20 19:48 7440-39-3
Cadmium 0.039J mg/kg 0.077 0.038 1 08/10/20 08:39 08/11/20 19:48 7440-43-9
Chromium 2.1 mg/kg 0.38 0.19 1 08/10/20 08:39 08/11/20 19:48 7440-47-3
Lead 7.7 mg/kg 0.38 0.19 1 08/10/20 08:39 08/11/20 19:48 7439-92-1
Selenium 0.99 mg/kg 0.77 0.38 1 08/10/20 08:39 08/11/20 19:48 7782-49-2
Silver ND mg/kg 0.38 0.19 1 08/10/20 08:39 08/11/20 19:48 7440-22-4
7471 Mercury Analytical Method: EPA 7471 B Preparation Method:EPA 7471 B
Pace Analytical Services-Asheville
Mercury ND mg/kg 0.0069 0.0053 1 08/10/20 10:10 08/11/20 16:57 7439-97-6
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 83-32-9
Acenaphthylene ND mg/kg 0.41 0.097 1 08/10/20 17:24 08/11/20 11:36 208-96-8
Aniline ND mg/kg 0.41 0.092 1 08/10/20 17:24 08/11/20 11:36 62-53-3
Anthracene ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 120-12-7
Benzo(a)anthracene ND mg/kg 0.41 0.13 1 08/10/20 17:24 08/11/20 11:36 56-55-3
Benzo(a)pyrene ND mg/kg 0.41 0.18 1 08/10/20 17:24 08/11/20 11:36 50-32-8
Benzo(b)fluoranthene ND mg/kg 0.41 0.17 1 08/10/20 17:24 08/11/20 11:36 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.41 0.16 1 08/10/20 17:24 08/11/20 11:36 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.41 0.17 1 08/10/20 17:24 08/11/20 11:36 207-08-9
Benzoic Acid ND mg/kg 2.0 0.44 1 08/10/20 17:24 08/11/20 11:36 65-85-0
Benzyl alcohol ND mg/kg 0.82 0.22 1 08/10/20 17:24 08/11/20 11:36 100-51-6
4-Bromophenylphenyl ether ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 101-55-3
Butylbenzylphthalate ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.82 0.25 1 08/10/20 17:24 08/11/20 11:36 59-50-7
4-Chloroaniline ND mg/kg 0.82 0.25 1 08/10/20 17:24 08/11/20 11:36 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.41 0.087 1 08/10/20 17:24 08/11/20 11:36 111-44-4
2-Chloronaphthalene ND mg/kg 0.41 0.091 1 08/10/20 17:24 08/11/20 11:36 91-58-7
2-Chlorophenol ND mg/kg 0.41 0.095 1 08/10/20 17:24 08/11/20 11:36 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 7005-72-3
Chrysene ND mg/kg 0.41 0.12 1 08/10/20 17:24 08/11/20 11:36 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.41 0.16 1 08/10/20 17:24 08/11/20 11:36 53-70-3 v1
Dibenzofuran ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.41 0.089 1 08/10/20 17:24 08/11/20 11:36 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.41 0.092 1 08/10/20 17:24 08/11/20 11:36 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.41 0.090 1 08/10/20 17:24 08/11/20 11:36 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.82 0.29 1 08/10/20 17:24 08/11/20 11:36 91-94-1
2,4-Dichlorophenol ND mg/kg 0.41 0.14 1 08/10/20 17:24 08/11/20 11:36 120-83-2
Diethylphthalate ND mg/kg 0.41 0.089 1 08/10/20 17:24 08/11/20 11:36 84-66-2
2,4-Dimethylphenol ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 105-67-9
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-1 Lab ID: 92489806010 Collected: 08/04/20 13:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.41 0.093 1 08/10/20 17:24 08/11/20 11:36 131-11-3
Di-n-butylphthalate ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 84-74-2
4,6-Dinitro-2-methylphenol ND mg/kg 0.82 0.66 1 08/10/20 17:24 08/11/20 11:36 534-52-1
2,4-Dinitrophenol ND mg/kg 2.0 1.3 1 08/10/20 17:24 08/11/20 11:36 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.41 0.23 1 08/10/20 17:24 08/11/20 11:36 117-84-0 v1
bis(2-Ethylhexyl)phthalate ND mg/kg 0.41 0.13 1 08/10/20 17:24 08/11/20 11:36 117-81-7
Fluoranthene ND mg/kg 0.41 0.12 1 08/10/20 17:24 08/11/20 11:36 206-44-0
Fluorene ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 87-68-3
Hexachlorobenzene ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.41 0.16 1 08/10/20 17:24 08/11/20 11:36 77-47-4
Hexachloroethane ND mg/kg 0.41 0.093 1 08/10/20 17:24 08/11/20 11:36 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.41 0.19 1 08/10/20 17:24 08/11/20 11:36 193-39-5 v1
Isophorone ND mg/kg 0.41 0.089 1 08/10/20 17:24 08/11/20 11:36 78-59-1
1-Methylnaphthalene ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 90-12-0
2-Methylnaphthalene ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.41 0.091 1 08/10/20 17:24 08/11/20 11:36 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 15831-10-4
Naphthalene ND mg/kg 0.41 0.098 1 08/10/20 17:24 08/11/20 11:36 91-20-3
2-Nitroaniline ND mg/kg 2.0 0.21 1 08/10/20 17:24 08/11/20 11:36 88-74-4
3-Nitroaniline ND mg/kg 2.0 0.22 1 08/10/20 17:24 08/11/20 11:36 99-09-2
4-Nitroaniline ND mg/kg 0.82 0.20 1 08/10/20 17:24 08/11/20 11:36 100-01-6
Nitrobenzene ND mg/kg 0.41 0.098 1 08/10/20 17:24 08/11/20 11:36 98-95-3
2-Nitrophenol ND mg/kg 0.41 0.13 1 08/10/20 17:24 08/11/20 11:36 88-75-5
4-Nitrophenol ND mg/kg 2.0 0.65 1 08/10/20 17:24 08/11/20 11:36 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.41 0.12 1 08/10/20 17:24 08/11/20 11:36 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 108-60-1
Pentachlorophenol ND mg/kg 0.82 0.19 1 08/10/20 17:24 08/11/20 11:36 87-86-5
Phenanthrene ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 85-01-8
Phenol ND mg/kg 0.41 0.098 1 08/10/20 17:24 08/11/20 11:36 108-95-2
Pyrene ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 129-00-0
Pyridine ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.41 0.094 1 08/10/20 17:24 08/11/20 11:36 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.41 0.11 1 08/10/20 17:24 08/11/20 11:36 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.41 0.10 1 08/10/20 17:24 08/11/20 11:36 88-06-2
Surrogates
Nitrobenzene-d5(S) 45 % 23-110 1 08/10/20 17:24 08/11/20 11:36 4165-60-0
2-Fluorobiphenyl(S) 49 % 30-110 1 08/10/20 17:24 08/11/20 11:36 321-60-8
Terphenyl-d14(S) 63 % 28-110 1 08/10/20 17:24 08/11/20 11:36 1718-51-0
Phenol-d6(S) 50 0/
0 22-110 1 08/10/20 17:24 08/11/20 11:36 13127-88-3
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 29 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-1 Lab ID: 92489806010 Collected: 08/04/20 13:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 50 % 13-110 1 08/10/20 17:24 08/11/20 11:36 367-12-4
2,4,6-Tribromophenol(S) 57 % 27-110 1 08/10/20 17:24 08/11/20 11:36 118-79-6
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 20.7 % 0.10 0.10 1 08/07/20 17:26
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G
Pace National-Mt.Juliet
Total Solids 71.2 % 1 08/13/20 10:30 08/13/20 10:42
Wet Chemistry 7199 Analytical Method: EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium, Hexavalent 0.446J mg/kg 1.41 0.358 1 08/12/20 10:20 08/12/20 17:12 18540-29-9 J
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 30 of 111
Pace Analytical Services,LLC
0 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-2 Lab ID: 92489806011 Collected: 08/05/20 13:45 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3050B
Pace Analytical Services-Asheville
Arsenic 2.9 mg/kg 1.1 0.54 1 08/10/20 08:39 08/11/20 19:51 7440-38-2
Barium 49.2 mg/kg 0.54 0.27 1 08/10/20 08:39 08/11/20 19:51 7440-39-3
Cadmium ND mg/kg 0.11 0.054 1 08/10/20 08:39 08/11/20 19:51 7440-43-9
Chromium 5.2 mg/kg 0.54 0.27 1 08/10/20 08:39 08/11/20 19:51 7440-47-3
Lead 12.4 mg/kg 0.54 0.27 1 08/10/20 08:39 08/11/20 19:51 7439-92-1
Selenium 1.3 mg/kg 1.1 0.54 1 08/10/20 08:39 08/11/20 19:51 7782-49-2
Silver 0.41J mg/kg 0.54 0.27 1 08/10/20 08:39 08/11/20 19:51 7440-22-4
7471 Mercury Analytical Method:EPA 7471B Preparation Method:EPA 7471B
Pace Analytical Services-Asheville
Mercury 0.016 mg/kg 0.0076 0.0059 1 08/10/20 10:10 08/11/20 16:59 7439-97-6
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 83-32-9
Acenaphthylene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:03 208-96-8
Aniline ND mg/kg 0.44 0.098 1 08/10/20 17:24 08/11/20 12:03 62-53-3
Anthracene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 120-12-7
Benzo(a)anthracene ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:03 56-55-3
Benzo(a)pyrene ND mg/kg 0.44 0.19 1 08/10/20 17:24 08/11/20 12:03 50-32-8
Benzo(b)fluoranthene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:03 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.44 0.17 1 08/10/20 17:24 08/11/20 12:03 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:03 207-08-9
Benzoic Acid ND mg/kg 2.2 0.47 1 08/10/20 17:24 08/11/20 12:03 65-85-0
Benzyl alcohol ND mg/kg 0.87 0.23 1 08/10/20 17:24 08/11/20 12:03 100-51-6
4-Bromophenylphenyl ether ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 101-55-3
Butylbenzylphthalate ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.87 0.27 1 08/10/20 17:24 08/11/20 12:03 59-50-7
4-Chloroaniline ND mg/kg 0.87 0.27 1 08/10/20 17:24 08/11/20 12:03 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.44 0.092 1 08/10/20 17:24 08/11/20 12:03 111-44-4
2-Chloronaphthalene ND mg/kg 0.44 0.097 1 08/10/20 17:24 08/11/20 12:03 91-58-7
2-Chlorophenol ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:03 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 7005-72-3
Chrysene ND mg/kg 0.44 0.13 1 08/10/20 17:24 08/11/20 12:03 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.44 0.17 1 08/10/20 17:24 08/11/20 12:03 53-70-3 v1
Dibenzofuran ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.44 0.094 1 08/10/20 17:24 08/11/20 12:03 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.44 0.098 1 08/10/20 17:24 08/11/20 12:03 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.44 0.096 1 08/10/20 17:24 08/11/20 12:03 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.87 0.30 1 08/10/20 17:24 08/11/20 12:03 91-94-1
2,4-Dichlorophenol ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:03 120-83-2
Diethylphthalate ND mg/kg 0.44 0.094 1 08/10/20 17:24 08/11/20 12:03 84-66-2
2,4-Dimethylphenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 105-67-9
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 31 of 111
Pace Analytical Services,LLC
F
ace Analyticaln 'n 9800 Kincey Ave. Suite 100
I eA f l Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-2 Lab ID: 92489806011 Collected: 08/05/20 13:45 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.44 0.098 1 08/10/20 17:24 08/11/20 12:03 131-11-3
Di-n-butylphthalate ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 84-74-2
4,6-Dinitro-2-methylphenol ND mg/kg 0.87 0.70 1 08/10/20 17:24 08/11/20 12:03 534-52-1
2,4-Dinitrophenol ND mg/kg 2.2 1.4 1 08/10/20 17:24 08/11/20 12:03 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.44 0.25 1 08/10/20 17:24 08/11/20 12:03 117-84-0 vi
bis(2-Ethylhexyl)phthalate ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:03 117-81-7
Fluoranthene ND mg/kg 0.44 0.13 1 08/10/20 17:24 08/11/20 12:03 206-44-0
Fluorene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 87-68-3
Hexachlorobenzene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.44 0.17 1 08/10/20 17:24 08/11/20 12:03 77-47-4
Hexachloroethane ND mg/kg 0.44 0.099 1 08/10/20 17:24 08/11/20 12:03 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.44 0.20 1 08/10/20 17:24 08/11/20 12:03 193-39-5 v1
Isophorone ND mg/kg 0.44 0.095 1 08/10/20 17:24 08/11/20 12:03 78-59-1
1-Methylnaphthalene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 90-12-0
2-Methylnaphthalene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.44 0.096 1 08/10/20 17:24 08/11/20 12:03 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 15831-10-4
Naphthalene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:03 91-20-3
2-Nitroaniline ND mg/kg 2.2 0.22 1 08/10/20 17:24 08/11/20 12:03 88-74-4
3-Nitroaniline ND mg/kg 2.2 0.23 1 08/10/20 17:24 08/11/20 12:03 99-09-2
4-Nitroaniline ND mg/kg 0.87 0.21 1 08/10/20 17:24 08/11/20 12:03 100-01-6
Nitrobenzene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:03 98-95-3
2-Nitrophenol ND mg/kg 0.44 0.13 1 08/10/20 17:24 08/11/20 12:03 88-75-5
4-Nitrophenol ND mg/kg 2.2 0.69 1 08/10/20 17:24 08/11/20 12:03 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 108-60-1
Pentachlorophenol ND mg/kg 0.87 0.20 1 08/10/20 17:24 08/11/20 12:03 87-86-5
Phenanthrene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 85-01-8
Phenol ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:03 108-95-2
Pyrene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:03 129-00-0
Pyridine ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:03 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:03 88-06-2
Surrogates
Nitrobenzene-d5(S) 47 % 23-110 1 08/10/20 17:24 08/11/20 12:03 4165-60-0
2-Fluorobiphenyl(S) 49 % 30-110 1 08/10/20 17:24 08/11/20 12:03 321-60-8
Terphenyl-d14(S) 61 % 28-110 1 08/10/20 17:24 08/11/20 12:03 1718-51-0
Phenol-d6(S) 51 % 22-110 1 08/10/20 17:24 08/11/20 12:03 13127-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 32 of 111
Pace Analytical Services,LLC
aceAnalytical
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacalabs.cam 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-2 Lab ID: 92489806011 Collected: 08/05/20 13:45 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 50 % 13-110 1 08/10/20 17:24 08/11/20 12:03 367-12-4
2,4,6-Tribromophenol(S) 61 % 27-110 1 08/10/20 17:24 08/11/20 12:03 118-79-6
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 23.9 % 0.10 0.10 1 08/07/20 17:26
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G
Pace National-Mt.Juliet
Total Solids 78.3 %1 08/13/20 10:30 08/13/20 10:42
Wet Chemistry 7199 Analytical Method:EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium,Hexavalent 0.349J mg/kg 1.28 0.326 1 08/12/20 10:20 08/12/20 17:17 18540-29-9 J
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 33 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
wWW.pacslabs.Com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-3 Lab ID: 92489806012 Collected: 08/05/20 14:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3050B
Pace Analytical Services-Asheville
Arsenic 5.9 mg/kg 1.1 0.54 1 08/10/20 08:39 08/11/20 19:55 7440-38-2
Barium 36.0 mg/kg 0.54 0.27 1 08/10/20 08:39 08/11/20 19:55 7440-39-3
Cadmium 0.080J mg/kg 0.11 0.054 1 08/10/20 08:39 08/11/20 19:55 7440-43-9
Chromium 26.0 mg/kg 0.54 0.27 1 08/10/20 08:39 08/11/20 19:55 7440-47-3
Lead 6.3 mg/kg 0.54 0.27 1 08/10/20 08:39 08/11/20 19:55 7439-92-1
Selenium 2.1 mg/kg 1.1 0.54 1 08/10/20 08:39 08/11/20 19:55 7782-49-2
Silver 0.89 mg/kg 0.54 0.27 1 08/10/20 08:39 08/11/20 19:55 7440-22-4
7471 Mercury Analytical Method:EPA 7471B Preparation Method: EPA 7471B
Pace Analytical Services-Asheville
Mercury 0.062 mg/kg 0.0070 0.0054 1 08/10/20 10:10 08/11/20 17:01 7439-97-6
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 83-32-9
Acenaphthylene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:30 208-96-8
Aniline ND mg/kg 0.44 0.098 1 08/10/20 17:24 08/11/20 12:30 62-53-3
Anthracene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 120-12-7
Benzo(a)anthracene ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:30 56-55-3
Benzo(a)pyrene ND mg/kg 0.44 0.19 1 08/10/20 17:24 08/11/20 12:30 50-32-8
Benzo(b)fluoranthene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:30 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.44 0.17 1 08/10/20 17:24 08/11/20 12:30 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:30 207-08-9
Benzoic Acid ND mg/kg 2.2 0.47 1 08/10/20 17:24 08/11/20 12:30 65-85-0
Benzyl alcohol ND mg/kg 0.88 0.23 1 08/10/20 17:24 08/11/20 12:30 100-51-6
4-Bromophenylphenyl ether ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 101-55-3
Butylbenzylphthalate ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.88 0.27 1 08/10/20 17:24 08/11/20 12:30 59-50-7
4-Chloroaniline ND mg/kg 0.88 0.27 1 08/10/20 17:24 08/11/20 12:30 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.44 0.093 1 08/10/20 17:24 08/11/20 12:30 111-44-4
2-Chloronaphthalene ND mg/kg 0.44 0.098 1 08/10/20 17:24 08/11/20 12:30 91-58-7
2-Chlorophenol ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:30 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 7005-72-3
Chrysene ND mg/kg 0.44 0.13 1 08/10/20 17:24 08/11/20 12:30 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:30 53-70-3 v1
Dibenzofuran ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.44 0.095 1 08/10/20 17:24 08/11/20 12:30 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.44 0.099 1 08/10/20 17:24 08/11/20 12:30 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.44 0.096 1 08/10/20 17:24 08/11/20 12:30 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.88 0.31 1 08/10/20 17:24 08/11/20 12:30 91-94-1
2,4-Dichlorophenol ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:30 120-83-2
Diethylphthalate ND mg/kg 0.44 0.095 1 08/10/20 17:24 08/11/20 12:30 84-66-2
2,4-Dimethylphenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 105-67-9
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 34 of 111
Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacNabstam 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-3 Lab ID: 92489806012 Collected: 08/05/20 14:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.44 0.099 1 08/10/20 17:24 08/11/20 12:30 131-11-3
Di-n-butylphthalate ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 84-74-2
4,6-Dinitro-2-methylphenol ND mg/kg 0.88 0.71 1 08/10/20 17:24 08/11/20 12:30 534-52-1
2,4-Dinitrophenol ND mg/kg 2.2 1.4 1 08/10/20 17:24 08/11/20 12:30 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.44 0.25 1 08/10/20 17:24 08/11/20 12:30 117-84-0 v1
bis(2-Ethylhexyl)phthalate ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:30 117-81-7
Fluoranthene ND mg/kg 0.44 0.13 1 08/10/20 17:24 08/11/20 12:30 206-44-0
Fluorene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 87-68-3
Hexachlorobenzene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:30 77-47-4
Hexachloroethane ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:30 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.44 0.20 1 08/10/20 17:24 08/11/20 12:30 193-39-5 v1
Isophorone ND mg/kg 0.44 0.095 1 08/10/20 17:24 08/11/20 12:30 78-59-1
1-Methylnaphthalene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 90-12-0
2-Methylnaphthalene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.44 0.097 1 08/10/20 17:24 08/11/20 12:30 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 15831-10-4
Naphthalene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:30 91-20-3
2-Nitroaniline ND mg/kg 2.2 0.22 1 08/10/20 17:24 08/11/20 12:30 88-74-4
3-Nitroaniline ND mg/kg 2.2 0.23 1 08/10/20 17:24 08/11/20 12:30 99-09-2
4-Nitroaniline ND mg/kg 0.88 0.22 1 08/10/20 17:24 08/11/20 12:30 100-01-6
Nitrobenzene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:30 98-95-3
2-Nitrophenol ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:30 88-75-5
4-Nitrophenol ND mg/kg 2.2 0.70 1 08/10/20 17:24 08/11/20 12:30 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 108-60-1
Pentachlorophenol ND mg/kg 0.88 0.20 1 08/10/20 17:24 08/11/20 12:30 87-86-5
Phenanthrene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 85-01-8
Phenol ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:30 108-95-2
Pyrene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:30 129-00-0
Pyridine ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:30 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:30 88-06-2
Surrogates
Nitrobenzene-d5(S) 55 % 23-110 1 08/10/20 17:24 08/11/20 12:30 4165-60-0
2-Fluorobiphenyl(S) 58 % 30-110 1 08/10/20 17:24 08/11/20 12:30 321-60-8
Terphenyl-d14(S) 73 % 28-110 1 08/10/20 17:24 08/11/20 12:30 1718-51-0
Phenol-d6(S) 61 % 22-110 1 08/10/20 17:24 08/11/20 12:30 13127-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 35 of 111
Pace Analytical Services,LLC
itt
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.cma 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-3 Lab ID: 92489806012 Collected: 08/05/20 14:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 60 % 13-110 1 08/10/20 17:24 08/11/20 12:30 367-12-4
2,4,6-Tribromophenol(S) 73 % 27-110 1 08/10/20 17:24 08/11/20 12:30 118-79-6
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 24.6 % 0.10 0.10 1 08/07/20 17:27
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G
Pace National-Mt.Juliet
Total Solids 72.2 % 1 08/13/20 10:30 08/13/20 10:42
Wet Chemistry 7199 Analytical Method: EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium, Hexavalent ND mg/kg 1.39 0.353 1 08/12/20 10:20 08/12/20 17:22 18540-29-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 36 of 111
Pace Analytical Services,LLC
aceAnalytical
9800 Kincey Ave. Suite100
Huntersville,NC 28078078
www.pacelabs.cae 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-4 Lab ID: 92489806013 Collected: 08/06/20 16:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3050B
Pace Analytical Services-Asheville
Arsenic 5.6 mg/kg 1.0 0.50 1 08/10/20 08:39 08/11/20 19:58 7440-38-2
Barium 15.9 mg/kg 0.50 0.25 1 08/10/20 08:39 08/11/20 19:58 7440-39-3
Cadmium ND mg/kg 0.10 0.050 1 08/10/20 08:39 08/11/20 19:58 7440-43-9
Chromium 40.5 mg/kg 0.50 0.25 1 08/10/20 08:39 08/11/20 19:58 7440-47-3
Lead 12.5 mg/kg 0.50 0.25 1 08/10/20 08:39 08/11/20 19:58 7439-92-1
Selenium 2.0 mg/kg 1.0 0.50 1 08/10/20 08:39 08/11/20 19:58 7782-49-2
Silver 0.74 mg/kg 0.50 0.25 1 08/10/20 08:39 08/11/20 19:58 7440-22-4
7471 Mercury Analytical Method:EPA 7471 B Preparation Method:EPA 7471 B
Pace Analytical Services-Asheville
Mercury 0.043 mg/kg 0.0078 0.0060 1 08/10/20 10:10 08/11/20 17:04 7439-97-6
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 83-32-9
Acenaphthylene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:57 208-96-8
Aniline ND mg/kg 0.44 0.099 1 08/10/20 17:24 08/11/20 12:57 62-53-3
Anthracene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 120-12-7
Benzo(a)anthracene ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:57 56-55-3
Benzo(a)pyrene ND mg/kg 0.44 0.19 1 08/10/20 17:24 08/11/20 12:57 50-32-8
Benzo(b)fluoranthene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:57 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.44 0.17 1 08/10/20 17:24 08/11/20 12:57 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.44 0.19 1 08/10/20 17:24 08/11/20 12:57 207-08-9
Benzoic Acid ND mg/kg 2.2 0.48 1 08/10/20 17:24 08/11/20 12:57 65-85-0
Benzyl alcohol ND mg/kg 0.88 0.23 1 08/10/20 17:24 08/11/20 12:57 100-51-6
4-Bromophenylphenyl ether ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 101-55-3
Butylbenzylphthalate ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.88 0.27 1 08/10/20 17:24 08/11/20 12:57 59-50-7
4-Chloroaniline ND mg/kg 0.88 0.27 1 08/10/20 17:24 08/11/20 12:57 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.44 0.094 1 08/10/20 17:24 08/11/20 12:57 111-44-4
2-Chloronaphthalene ND mg/kg 0.44 0.098 1 08/10/20 17:24 08/11/20 12:57 91-58-7
2-Chlorophenol ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:57 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 7005-72-3
Chrysene ND mg/kg 0.44 0.13 1 08/10/20 17:24 08/11/20 12:57 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:57 53-70-3 v1
Dibenzofuran ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.44 0.095 1 08/10/20 17:24 08/11/20 12:57 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.44 0.099 1 08/10/20 17:24 08/11/20 12:57 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.44 0.097 1 08/10/20 17:24 08/11/20 12:57 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.88 0.31 1 08/10/20 17:24 08/11/20 12:57 91-94-1
2,4-Dichlorophenol ND mg/kg 0.44 0.15 1 08/10/20 17:24 08/11/20 12:57 120-83-2
Diethylphthalate ND mg/kg 0.44 0.096 1 08/10/20 17:24 08/11/20 12:57 84-66-2
2,4-Dimethylphenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 105-67-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 37 of 111
Pace Analytical Services,LLC
a,e /Ina'yt'caI 9800 KinceyAve. Suite 100
1 1 Huntersville,NC 28078
www.pacelahs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-4 Lab ID: 92489806013 Collected: 08/06/20 16:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:57 131-11-3
Di-n-butylphthalate ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 84-74-2
4,6-Dinitro-2-methylphenol ND mg/kg 0.88 0.71 1 08/10/20 17:24 08/11/20 12:57 534-52-1
2,4-Dinitrophenol ND mg/kg 2.2 1.4 1 08/10/20 17:24 08/11/20 12:57 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.44 0.25 1 08/10/20 17:24 08/11/20 12:57 117-84-0 v1
bis(2-Ethylhexyl)phthalate ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:57 117-81-7
Fluoranthene ND mg/kg 0.44 0.13 1 08/10/20 17:24 08/11/20 12:57 206-44-0
Fluorene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 87-68-3
Hexachlorobenzene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.44 0.18 1 08/10/20 17:24 08/11/20 12:57 77-47-4
Hexachloroethane ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:57 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.44 0.20 1 08/10/20 17:24 08/11/20 12:57 193-39-5 v1
Isophorone ND mg/kg 0.44 0.096 1 08/10/20 17:24 08/11/20 12:57 78-59-1
1-Methylnaphthalene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 90-12-0
2-Methylnaphthalene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.44 0.098 1 08/10/20 17:24 08/11/20 12:57 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 15831-10-4
Naphthalene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 91-20-3
2-Nitroaniline ND mg/kg 2.2 0.22 1 08/10/20 17:24 08/11/20 12:57 88-74-4
3-Nitroaniline ND mg/kg 2.2 0.23 1 08/10/20 17:24 08/11/20 12:57 99-09-2
4-Nitroaniline ND mg/kg 0.88 0.22 1 08/10/20 17:24 08/11/20 12:57 100-01-6
Nitrobenzene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 98-95-3
2-Nitrophenol ND mg/kg 0.44 0.14 1 08/10/20 17:24 08/11/20 12:57 88-75-5
4-Nitrophenol ND mg/kg 2.2 0.70 1 08/10/20 17:24 08/11/20 12:57 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 108-60-1
Pentachlorophenol ND mg/kg 0.88 0.20 1 08/10/20 17:24 08/11/20 12:57 87-86-5
Phenanthrene ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 85-01-8
Phenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 108-95-2
Pyrene ND mg/kg 0.44 0.12 1 08/10/20 17:24 08/11/20 12:57 129-00-0
Pyridine ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.44 0.10 1 08/10/20 17:24 08/11/20 12:57 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.44 0.11 1 08/10/20 17:24 08/11/20 12:57 88-06-2
Surrogates
Nitrobenzene-d5(S) 52 % 23-110 1 08/10/20 17:24 08/11/20 12:57 4165-60-0
2-Fluorobiphenyl(S) 56 % 30-110 1 08/10/20 17:24 08/11/20 12:57 321-60-8
Terphenyl-d14(S) 72 % 28-110 1 08/10/20 17:24 08/11/20 12:57 1718-51-0
Phenol-d6(S) 56 % 22-110 1 08/10/20 17:24 08/11/20 12:57 13127-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 38 of 111
Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-4 Lab ID: 92489806013 Collected: 08/06/20 16:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 55 % 13-110 1 08/10/20 17:24 08/11/20 12:57 367-12-4
2,4,6-Tribromophenol(S) 67 % 27-110 1 08/10/20 17:24 08/11/20 12:57 118-79-6
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 25.4 % 0.10 0.10 1 08/07/20 17:27
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G
Pace National-Mt.Juliet
Total Solids 78.8 % 1 08/13/20 10:30 08/13/20 10:42
Wet Chemistry 7199 Analytical Method: EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium, Hexavalent ND mg/kg 1.27 0.324 1 08/12/20 10:20 08/12/20 17:28 18540-29-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 39 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-5 Lab ID: 92489806014 Collected: 08/06/20 16:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA3050B
Pace Analytical Services-Asheville
Arsenic 3.6 mg/kg 1.0 0.52 1 08/10/20 08:39 08/11/20 20:01 7440-38-2
Barium 37.0 mg/kg 0.52 0.26 1 08/10/20 08:39 08/11/20 20:01 7440-39-3
Cadmium 0.056J mg/kg 0.10 0.052 1 08/10/20 08:39 08/11/20 20:01 7440-43-9
Chromium 4.5 mg/kg 0.52 0.26 1 08/10/20 08:39 08/11/20 20:01 7440-47-3
Lead 4.9 mg/kg 0.52 0.26 1 08/10/20 08:39 08/11/20 20:01 7439-92-1
Selenium 0.92J mg/kg 1.0 0.52 1 08/10/20 08:39 08/11/20 20:01 7782-49-2
Silver 0.38J mg/kg 0.52 0.26 1 08/10/20 08:39 08/11/20 20:01 7440-22-4
7471 Mercury Analytical Method:EPA 7471B Preparation Method:EPA 7471B
Pace Analytical Services-Asheville
Mercury 0.0051J mg/kg 0.0065 0.0050 1 08/10/20 10:10 08/11/20 17:07 7439-97-6
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546Ytp
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 83-32-9
Acenaphthylene ND mg/kg 0.42 0.098 1 08/10/20 17:24 08/11/20 13:24 208-96-8
Aniline ND mg/kg 0.42 0.093 1 08/10/20 17:24 08/11/20 13:24 62-53-3
Anthracene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 120-12-7
Benzo(a)anthracene ND mg/kg 0.42 0.13 1 08/10/20 17:24 08/11/20 13:24 56-55-3
Benzo(a)pyrene ND mg/kg 0.42 0.18 1 08/10/20 17:24 08/11/20 13:24 50-32-8
Benzo(b)fluoranthene ND mg/kg 0.42 0.17 1 08/10/20 17:24 08/11/20 13:24 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.42 0.16 1 08/10/20 17:24 08/11/20 13:24 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.42 0.18 1 08/10/20 17:24 08/11/20 13:24 207-08-9
Benzoic Acid ND mg/kg 2.1 0.45 1 08/10/20 17:24 08/11/20 13:24 65-85-0
Benzyl alcohol ND mg/kg 0.83 0.22 1 08/10/20 17:24 08/11/20 13:24 100-51-6
4-Bromophenylphenyl ether ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 101-55-3
Butylbenzylphthalate ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.83 0.25 1 08/10/20 17:24 08/11/20 13:24 59-50-7
4-Chloroaniline ND mg/kg 0.83 0.25 1 08/10/20 17:24 08/11/20 13:24 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.42 0.088 1 08/10/20 17:24 08/11/20 13:24 111-44-4
2-Chloronaphthalene ND mg/kg 0.42 0.093 1 08/10/20 17:24 08/11/20 13:24 91-58-7
2-Chlorophenol ND mg/kg 0.42 0.097 1 08/10/20 17:24 08/11/20 13:24 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 7005-72-3
Chrysene ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 13:24 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.42 0.17 1 08/10/20 17:24 08/11/20 13:24 53-70-3 v1
Dibenzofuran ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 13:24 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.42 0.090 1 08/10/20 17:24 08/11/20 13:24 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.42 0.094 1 08/10/20 17:24 08/11/20 13:24 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.42 0.091 1 08/10/20 17:24 08/11/20 13:24 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.83 0.29 1 08/10/20 17:24 08/11/20 13:24 91-94-1
2,4-Dichlorophenol ND mg/kg 0.42 0.14 1 08/10/20 17:24 08/11/20 13:24 120-83-2
Diethylphthalate ND mg/kg 0.42 0.090 1 08/10/20 17:24 08/11/20 13:24 84-66-2
2,4-Dimethylphenol ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 13:24 105-67-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 40 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.paeelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-5 Lab ID: 92489806014 Collected: 08/06/20 16:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.42 0.094 1 08/10/20 17:24 08/11/20 13:24 131-11-3
Di-n-butylphthalate ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 13:24 84-74-2
4,6-Dinitro-2-methylphenol ND mg/kg 0.83 0.67 1 08/10/20 17:24 08/11/20 13:24 534-52-1
2,4-Dinitrophenol ND mg/kg 2.1 1.3 1 08/10/20 17:24 08/11/20 13:24 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.42 0.24 1 08/10/20 17:24 08/11/20 13:24 117-84-0 v1
bis(2-Ethylhexyl)phthalate ND mg/kg 0.42 0.14 1 08/10/20 17:24 08/11/20 13:24 117-81-7
Fluoranthene ND mg/kg 0.42 0.13 1 08/10/20 17:24 08/11/20 13:24 206-44-0
Fluorene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 13:24 87-68-3
Hexachlorobenzene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.42 0.17 1 08/10/20 17:24 08/11/20 13:24 77-47-4
Hexachloroethane ND mg/kg 0.42 0.095 1 08/10/20 17:24 08/11/20 13:24 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.42 0.19 1 08/10/20 17:24 08/11/20 13:24 193-39-5 v1
Isophorone ND mg/kg 0.42 0.090 1 08/10/20 17:24 08/11/20 13:24 78-59-1
1-Methylnaphthalene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 90-12-0
2-Methylnaphthalene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.42 0.092 1 08/10/20 17:24 08/11/20 13:24 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 13:24 15831-10-4
Naphthalene ND mg/kg 0.42 0.099 1 08/10/20 17:24 08/11/20 13:24 91-20-3
2-Nitroaniline ND mg/kg 2.1 0.21 1 08/10/20 17:24 08/11/20 13:24 88-74-4
3-Nitroaniline ND mg/kg 2.1 0.22 1 08/10/20 17:24 08/11/20 13:24 99-09-2
4-Nitroaniline ND mg/kg 0.83 0.21 1 08/10/20 17:24 08/11/20 13:24 100-01-6
Nitrobenzene ND mg/kg 0.42 0.099 1 08/10/20 17:24 08/11/20 13:24 98-95-3
2-Nitrophenol ND mg/kg 0.42 0.13 1 08/10/20 17:24 08/11/20 13:24 88-75-5
4-Nitrophenol ND mg/kg 2.1 0.66 1 08/10/20 17:24 08/11/20 13:24 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 13:24 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 13:24 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.42 0.12 1 08/10/20 17:24 08/11/20 13:24 108-60-1
Pentachlorophenol ND mg/kg 0.83 0.19 1 08/10/20 17:24 08/11/20 13:24 87-86-5
Phenanthrene ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 13:24 85-01-8
Phenol ND mg/kg 0.42 0.099 1 08/10/20 17:24 08/11/20 13:24 108-95-2
Pyrene ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 129-00-0
Pyridine ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.42 0.095 1 08/10/20 17:24 08/11/20 13:24 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.42 0.11 1 08/10/20 17:24 08/11/20 13:24 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.42 0.10 1 08/10/20 17:24 08/11/20 13:24 88-06-2
Surrogates
Nitrobenzene-d5(S) 49 % 23-110 1 08/10/20 17:24 08/11/20 13:24 4165-60-0
2-Fluorobiphenyl(S) 52 % 30-110 1 08/10/20 17:24 08/11/20 13:24 321-60-8
Terphenyl-d14(S) 66 % 28-110 1 08/10/20 17:24 08/11/20 13:24 1718-51-0
Phenol-d6(S) 54 % 22-110 1 08/10/20 17:24 08/11/20 13:24 13127-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 41 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
www.pacalabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-5 Lab ID: 92489806014 Collected: 08/06/20 16:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 52 % 13-110 1 08/10/20 17:24 08/11/20 13:24 367-12-4
2,4,6-Tribromophenol(S) 64 % 27-110 1 08/10/20 17:24 08/11/20 13:24 118-79-6
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 20.6 % 0.10 0.10 1 08/07/20 17:27
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G
Pace National-Mt.Juliet
Total Solids 78.2 % 1 08/13/20 10:30 08/13/20 10:42
Wet Chemistry 7199 Analytical Method:EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium,Hexavalent ND mg/kg 1.28 0.326 1 08/12/20 10:20 08/12/20 17:33 18540-29-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 42 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100
aceAnalytical Huntersville,NC 28078078
www.pacelabs.caa 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-6 Lab ID: 92489806015 Collected: 08/06/20 17:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method:EPA 3050E
Pace Analytical Services-Asheville
Arsenic 2.4 mg/kg 0.96 0.48 1 08/10/20 08:39 08/11/20 20:04 7440-38-2
Barium 35.1 mg/kg 0.48 0.24 1 08/10/20 08:39 08/11/20 20:04 7440-39-3
Cadmium ND mg/kg 0.096 0.048 1 08/10/20 08:39 08/11/20 20:04 7440-43-9
Chromium 15.8 mg/kg 0.48 0.24 1 08/10/20 08:39 08/11/20 20:04 7440-47-3
Lead 4.9 mg/kg 0.48 0.24 1 08/10/20 08:39 08/11/20 20:04 7439-92-1
Selenium ND mg/kg 0.96 0.48 1 08/10/20 08:39 08/11/20 20:04 7782-49-2
Silver 0.30J mg/kg 0.48 0.24 1 08/10/20 08:39 08/11/20 20:04 7440-22-4
7471 Mercury Analytical Method:EPA 7471 B Preparation Method:EPA 7471 B
Pace Analytical Services-Asheville
Mercury 0.014 mg/kg 0.0059 0.0045 1 08/10/20 10:10 08/11/20 17:09 7439-97-6
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 83-32-9
Acenaphthylene ND mg/kg 0.43 0.10 1 08/10/20 17:24 08/11/20 13:52 208-96-8
Aniline ND mg/kg 0.43 0.096 1 08/10/20 17:24 08/11/20 13:52 62-53-3
Anthracene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 120-12-7
Benzo(a)anthracene ND mg/kg 0.43 0.14 1 08/10/20 17:24 08/11/20 13:52 56-55-3
Benzo(a)pyrene ND mg/kg 0.43 0.19 1 08/10/20 17:24 08/11/20 13:52 50-32-8
Benzo(b)fluoranthene ND mg/kg 0.43 0.17 1 08/10/20 17:24 08/11/20 13:52 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.43 0.17 1 08/10/20 17:24 08/11/20 13:52 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.43 0.18 1 08/10/20 17:24 08/11/20 13:52 207-08-9
Benzoic Acid ND mg/kg 2.1 0.46 1 08/10/20 17:24 08/11/20 13:52 65-85-0
Benzyl alcohol ND mg/kg 0.85 0.23 1 08/10/20 17:24 08/11/20 13:52 100-51-6
4-Bromophenyiphenyl ether ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 101-55-3
Butylbenzylphthalate ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.85 0.26 1 08/10/20 17:24 08/11/20 13:52 59-50-7
4-Chloroaniline ND mg/kg 0.85 0.26 1 08/10/20 17:24 08/11/20 13:52 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.43 0.091 1 08/10/20 17:24 08/11/20 13:52 111-44-4
2-Chloronaphthalene ND mg/kg 0.43 0.095 1 08/10/20 17:24 08/11/20 13:52 91-58-7
2-Chlorophenol ND mg/kg 0.43 0.099 1 08/10/20 17:24 08/11/20 13:52 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 7005-72-3
Chrysene ND mg/kg 0.43 0.12 1 08/10/20 17:24 08/11/20 13:52 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.43 0.17 1 08/10/20 17:24 08/11/20 13:52 53-70-3 v1
Dibenzofuran ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.43 0.092 1 08/10/20 17:24 08/11/20 13:52 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.43 0.096 1 08/10/20 17:24 08/11/20 13:52 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.43 0.094 1 08/10/20 17:24 08/11/20 13:52 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.85 0.30 1 08/10/20 17:24 08/11/20 13:52 91-94-1
2,4-Dichlorophenol ND mg/kg 0.43 0.14 1 08/10/20 17:24 08/11/20 13:52 120-83-2
Diethylphthalate ND mg/kg 0.43 0.093 1 08/10/20 17:24 08/11/20 13:52 84-66-2
2,4-Dimethylphenol ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 105-67-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC, Page 43 of 111
Pace Analytical Services,LLC
aceAnalytical,, 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com
704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-6 Lab ID: 92489806015 Collected: 08/06/20 17:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.43 0.097 1 08/10/20 17:24 08/11/20 13:52 131-11-3
Di-n-butylphthalate ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 84-74-2
1 4,6-Dinitro-2-methylphenol ND mg/kg 0.85 0.69 1 08/10/20 17:24 08/11/20 13:52 534-52-1
2,4-Dinitrophenol ND mg/kg 2.1 1.4 1 08/10/20 17:24 08/11/20 13:52 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.43 0.24 1 08/10/20 17:24 08/11/20 13:52 117-84-0 v1
bis(2-Ethylhexyl)phthalate ND mg/kg 0.43 0.14 1 08/10/20 17:24 08/11/20 13:52 117-81-7
Fluoranthene ND mg/kg 0.43 0.13 1 08/10/20 17:24 08/11/20 13:52 206-44-0
Fluorene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.43 0.10 1 08/10/20 17:24 08/11/20 13:52 87-68-3
Hexachlorobenzene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.43 0.17 1 08/10/20 17:24 08/11/20 13:52 77-47-4
Hexachloroethane ND mg/kg 0.43 0.097 1 08/10/20 17:24 08/11/20 13:52 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.43 0.20 1 08/10/20 17:24 08/11/20 13:52 193-39-5 v1
Isophorone ND mg/kg 0.43 0.093 1 08/10/20 17:24 08/11/20 13:52 78-59-1
1-Methylnaphthalene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 90-12-0
2-Methylnaphthalene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.43 0.095 1 08/10/20 17:24 08/11/20 13:52 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 15831-10-4
Naphthalene ND mg/kg 0.43 0.10 1 08/10/20 17:24 08/11/20 13:52 91-20-3
2-Nitroaniline ND mg/kg 2.1 0.21 1 08/10/20 17:24 08/11/20 13:52 88-74-4
3-Nitroaniline ND mg/kg 2.1 0.23 1 08/10/20 17:24 08/11/20 13:52 99-09-2
4-Nitroaniline ND mg/kg 0.85 0.21 1 08/10/20 17:24 08/11/20 13:52 100-01-6
Nitrobenzene ND mg/kg 0.43 0.10 1 08/10/20 17:24 08/11/20 13:52 98-95-3
2-Nitrophenol ND mg/kg 0.43 0.13 1 08/10/20 17:24 08/11/20 13:52 88-75-5
4-Nitrophenol ND mg/kg 2.1 0.68 1 08/10/20 17:24 08/11/20 13:52 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.43 0.12 1 08/10/20 17:24 08/11/20 13:52 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.43 0.12 1 08/10/20 17:24 08/11/20 13:52 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.43 0.12 1 08/10/20 17:24 08/11/20 13:52 108-60-1
Pentachlorophenol ND mg/kg 0.85 0.20 1 08/10/20 17:24 08/11/20 13:52 87-86-5
Phenanthrene ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 85-01-8
Phenol ND mg/kg 0.43 0.10 1 08/10/20 17:24 08/11/20 13:52 108-95-2
Pyrene ND mg/kg 0.43 0.12 1 08/10/20 17:24 08/11/20 13:52 129-00-0
Pyridine ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.43 0.098 1 08/10/20 17:24 08/11/20 13:52 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.43 0.11 1 08/10/20 17:24 08/11/20 13:52 88-06-2
Surrogates
Nitrobenzene-d5(S) 47 % 23-110 1 08/10/20 17:24 08/11/20 13:52 4165-60-0
2-Fluorobiphenyl(S) 54 % 30-110 1 08/10/20 17:24 08/11/20 13:52 321-60-8
Terphenyl-d14(S) 53 % 28-110 1 08/10/20 17:24 08/11/20 13:52 1718-51-0
Phenol-d6(S) 50 % 22-110 1 08/10/20 17:24 08/11/20 13:52 13127-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 44 of 111
Pace Analytical Services,LLC
ft 9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-6 Lab ID: 92489806015 Collected: 08/06/20 17:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 48 % 13-110 1 08/10/20 17:24 08/11/20 13:52 367-12-4
2,4,6-Tribromophenol(S) 66 % 27-110 1 08/10/20 17:24 08/11/20 13:52 118-79-6
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 21.9 % 0.10 0.10 1 08/07/20 18:34
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G i
Pace National-Mt.Juliet
Total Solids 76.6 % 1 08/13/20 10:30 08/13/20 10:42
Wet Chemistry 7199 Analytical Method:EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium,Hexavalent ND mg/kg 1.31 0.333 1 08/12/20 10:20 08/12/20 17:38 18540-29-9
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 45 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pace18bs.co n 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-7 Lab ID: 92489806016 Collected: 08/06/20 17:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3050B
Pace Analytical Services-Asheville
Arsenic 1.9 mg/kg 0.90 0.45 1 08/10/20 08:39 08/11/20 20:14 7440-38-2
Barium 107 mg/kg 0.45 0.23 1 08/10/20 08:39 08/11/20 20:14 7440-39-3
Cadmium 0.057J mg/kg 0.090 0.045 1 08/10/20 08:39 08/11/20 20:14 7440-43-9
Chromium 128 mg/kg 0.45 0.23 1 08/10/20 08:39 08/11/20 20:14 7440-47-3
Lead 9.3 mg/kg 0.45 0.23 1 08/10/20 08:39 08/11/20 20:14 7439-92-1
Selenium 1.2 mg/kg 0.90 0.45 1 08/10/20 08:39 08/11/20 20:14 7782-49-2
Silver ND mg/kg 0.45 0.23 1 08/10/20 08:39 08/11/20 20:14 7440-22-4
7471 Mercury Analytical Method:EPA 7471 B Preparation Method:EPA 7471B
Pace Analytical Services-Asheville
Mercury 0.083 mg/kg 0.0059 0.0045 1 08/10/20 10:10 08/11/20 17:11 7439-97-6
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 83-32-9
Acenaphthylene ND mg/kg 0.40 0.095 1 08/10/20 17:24 08/11/20 14:19 208-96-8
Aniline ND mg/kg 0.40 0.090 1 08/10/20 17:24 08/11/20 14:19 62-53-3
Anthracene ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 120-12-7
Benzo(a)anthracene ND mg/kg 0.40 0.13 1 08/10/20 17:24 08/11/20 14:19 56-55-3
Benzo(a)pyrene ND mg/kg 0.40 0.17 1 08/10/20 17:24 08/11/20 14:19 50-32-8
Benzo(k)fluoranthene ND mg/kg 0.40 0.16 1 08/10/20 17:24 08/11/20 14:19 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.40 0.16 1 08/10/20 17:24 08/11/20 14:19 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.40 0.17 1 08/10/20 17:24 08/11/20 14:19 207-08-9
Benzoic Acid ND mg/kg 2.0 0.43 1 08/10/20 17:24 08/11/20 14:19 65-85-0
Benzyl alcohol ND mg/kg 0.80 0.21 1 08/10/20 17:24 08/11/20 14:19 100-51-6
4-Bromophenylphenyl ether ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 101-55-3
Butylbenzylphthalate ND mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.80 0.24 1 08/10/20 17:24 08/11/20 14:19 59-50-7
4-Chloroaniline ND mg/kg 0.80 0.24 1 08/10/20 17:24 08/11/20 14:19 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.40 0.085 1 08/10/20 17:24 08/11/20 14:19 111-44-4
2-Chloronaphthalene ND mg/kg 0.40 0.089 1 08/10/20 17:24 08/11/20 14:19 91-58-7
2-Chlorophenol ND mg/kg 0.40 0.093 1 08/10/20 17:24 08/11/20 14:19 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 7005-72-3
Chrysene ND mg/kg 0.40 0.12 1 08/10/20 17:24 08/11/20 14:19 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.40 0.16 1 08/10/20 17:24 08/11/20 14:19 53-70-3 v1
Dibenzofuran ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.40 0.087 1 08/10/20 17:24 08/11/20 14:19 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.40 0.090 1 08/10/20 17:24 08/11/20 14:19 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.40 0.088 1 08/10/20 17:24 08/11/20 14:19 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.80 0.28 1 08/10/20 17:24 08/11/20 14:19 91-94-1
2,4-Dichlorophenol ND mg/kg 0.40 0.13 1 08/10/20 17:24 08/11/20 14:19 120-83-2
Diethylphthalate ND mg/kg 0.40 0.087 1 08/10/20 17:24 08/11/20 14:19 84-66-2
2,4-Dimethylphenol ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 105-67-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 46 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacalabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-7 Lab ID: 92489806016 Collected: 08/06/20 17:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.40 0.090 1 08/10/20 17:24 08/11/20 14:19 131-11-3
Di-n-butylphthalate ND mg/kg 0.40 0.099 1 08/10/20 17:24 08/11/20 14:19 84-74-2
4,6-Dinitro-2-methylphenol ND mg/kg 0.80 0.65 1 08/10/20 17:24 08/11/20 14:19 534-52-1
2,4-Dinitrophenol ND mg/kg 2.0 1.3 1 08/10/20 17:24 08/11/20 14:19 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.40 0.23 1 08/10/20 17:24 08/11/20 14:19 117-84-0 v1
bis(2-Ethylhexyl)phthalate ND mg/kg 0.40 0.13 1 08/10/20 17:24 08/11/20 14:19 117-81-7
Fluoranthene 0.19J mg/kg 0.40 0.12 1 08/10/20 17:24 08/11/20 14:19 206-44-0
Fluorene ND mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.40 0.097 1 08/10/20 17:24 08/11/20 14:19 87-68-3
Hexachlorobenzene ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.40 0.16 1 08/10/20 17:24 08/11/20 14:19 77-47-4
Hexachloroethane ND mg/kg 0.40 0.091 1 08/10/20 17:24 08/11/20 14:19 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.40 0.18 1 08/10/20 17:24 08/11/20 14:19 193-39-5 v1
Isophorone ND mg/kg 0.40 0.087 1 08/10/20 17:24 08/11/20 14:19 78-59-1
1-Methylnaphthalene ND mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 90-12-0
2-Methylnaphthalene ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.40 0.089 1 08/10/20 17:24 08/11/20 14:19 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 15831-10-4
Naphthalene ND mg/kg 0.40 0.096 1 08/10/20 17:24 08/11/20 14:19 91-20-3
2-Nitroaniline ND mg/kg 2.0 0.20 1 08/10/20 17:24 08/11/20 14:19 88-74-4
3-Nitroaniline ND mg/kg 2.0 0.21 1 08/10/20 17:24 08/11/20 14:19 99-09-2
4-Nitroaniline ND mg/kg 0.80 0.20 1 08/10/20 17:24 08/11/20 14:19 100-01-6
Nitrobenzene ND mg/kg 0.40 0.096 1 08/10/20 17:24 08/11/20 14:19 98-95-3
2-Nitrophenol ND mg/kg 0.40 0.12 1 08/10/20 17:24 08/11/20 14:19 88-75-5
4-Nitrophenol ND mg/kg 2.0 0.64 1 08/10/20 17:24 08/11/20 14:19 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 108-60-1
Pentachlorophenol ND mg/kg 0.80 0.18 1 08/10/20 17:24 08/11/20 14:19 87-86-5
Phenanthrene 0.16J mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 85-01-8
Phenol ND mg/kg 0.40 0.096 1 08/10/20 17:24 08/11/20 14:19 108-95-2
Pyrene 0.17J mg/kg 0.40 0.11 1 08/10/20 17:24 08/11/20 14:19 129-00-0
Pyridine ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.40 0.092 1 08/10/20 17:24 08/11/20 14:19 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.40 0.10 1 08/10/20 17:24 08/11/20 14:19 88-06-2
Surrogates
Nitrobenzene-d5(S) 52 % 23-110 1 08/10/20 17:24 08/11/20 14:19 4165-60-0
2-Fluorobiphenyl(S) 58 % 30-110 1 08/10/20 17:24 08/11/20 14:19 321-60-8
Terphenyl-d14(S) 71 % 28-110 1 08/10/20 17:24 08/11/20 14:19 1718-51-0
Phenol-d6(S) 58 % 22-110 1 08/10/20 17:24 08/11/20 14:19 13127-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 47 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelaba.emn 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-7 Lab ID: 92489806016 Collected: 08/06/20 17:30 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a "dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 55 % 13-110 1 08/10/20 17:24 08/11/20 14:19 367-12-4
2,4,6-Tribromophenol(S) 80 % 27-110 1 08/10/20 17:24 08/11/20 14:19 118-79-6
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 17.5 % 0.10 0.10 1 08/07/20 18:35
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G
Pace National-Mt.Juliet
Total Solids 84.3 % 1 08/13/20 10:30 08/13/20 10:42
Wet Chemistry 7199 Analytical Method:EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium,Hexavalent ND mg/kg 1.19 0.303 1 08/12/20 10:20 08/12/20 17:43 18540-29-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 48 of 111
Pace Analytical Services,LLC
0 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.cem 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-8 Lab ID: 92489806017 Collected: 08/06/20 18:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
1 Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method:EPA 3050B
Pace Analytical Services-Asheville
Arsenic 4.7 mg/kg 0.98 0.49 1 08/10/20 08:39 08/11/20 20:17 7440-38-2
Barium 24.8 mg/kg 0.49 0.25 1 08/10/20 08:39 08/11/20 20:17 7440-39-3
Cadmium 0.080J mg/kg 0.098 0.049 1 08/10/20 08:39 08/11/20 20:17 7440-43-9
Chromium 11.5 mg/kg 0.49 0.25 1 08/10/20 08:39 08/11/20 20:17 7440-47-3
Lead 3.6 mg/kg 0.49 0.25 1 08/10/20 08:39 08/11/20 20:17 7439-92-1
Selenium 1.2 mg/kg 0.98 0.49 1 08/10/20 08:39 08/11/20 20:17 7782-49-2
Silver 0.51 mg/kg 0.49 0.25 1 08/10/20 08:39 08/11/20 20:17 7440-22-4
7471 Mercury Analytical Method: EPA 7471 B Preparation Method:EPA 7471 B
Pace Analytical Services-Asheville
Mercury 0.016 mg/kg 0.0070 0.0053 1 08/10/20 10:10 08/11/20 17:14 7439-97-6
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Acenaphthene ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 83-32-9
Acenaphthylene ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 208-96-8
Aniline ND mg/kg 0.45 0.10 1 08/10/20 17:24 08/11/20 14:46 62-53-3
Anthracene ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 120-12-7
Benzo(a)anthracene ND mg/kg 0.45 0.14 1 08/10/20 17:24 08/11/20 14:46 56-55-3
Benzo(a)pyrene ND mg/kg 0.45 0.20 1 08/10/20 17:24 08/11/20 14:46 50-32-8 I
Benzo(b)fluoranthene ND mg/kg 0.45 0.18 1 08/10/20 17:24 08/11/20 14:46 205-99-2
Benzo(g,h,i)perylene ND mg/kg 0.45 0.18 1 08/10/20 17:24 08/11/20 14:46 191-24-2 v1
Benzo(k)fluoranthene ND mg/kg 0.45 0.19 1 08/10/20 17:24 08/11/20 14:46 207-08-9
Benzoic Acid ND mg/kg 2.3 0.49 1 08/10/20 17:24 08/11/20 14:46 65-85-0
Benzyl alcohol ND mg/kg 0.91 0.24 1 08/10/20 17:24 08/11/20 14:46 100-51-6
4-Bromophenylphenyl ether ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 101-55-3
Butylbenzylphthalate ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 85-68-7
4-Chloro-3-methylphenol ND mg/kg 0.91 0.28 1 08/10/20 17:24 08/11/20 14:46 59-50-7
4-Chloroaniline ND mg/kg 0.91 0.28 1 08/10/20 17:24 08/11/20 14:46 106-47-8
bis(2-Chloroethoxy)methane ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 111-91-1
bis(2-Chloroethyl)ether ND mg/kg 0.45 0.097 1 08/10/20 17:24 08/11/20 14:46 111-44-4
2-Chloronaphthalene ND mg/kg 0.45 0.10 1 08/10/20 17:24 08/11/20 14:46 91-58-7
2-Chlorophenol ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 95-57-8
4-Chlorophenylphenyl ether ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 7005-72-3
Chrysene ND mg/kg 0.45 0.13 1 08/10/20 17:24 08/11/20 14:46 218-01-9
Dibenz(a,h)anthracene ND mg/kg 0.45 0.18 1 08/10/20 17:24 08/11/20 14:46 53-70-3 v1
Dibenzofuran ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 132-64-9
1,2-Dichlorobenzene ND mg/kg 0.45 0.098 1 08/10/20 17:24 08/11/20 14:46 95-50-1
1,3-Dichlorobenzene ND mg/kg 0.45 0.10 1 08/10/20 17:24 08/11/20 14:46 541-73-1
1,4-Dichlorobenzene ND mg/kg 0.45 0.10 1 08/10/20 17:24 08/11/20 14:46 106-46-7
3,3'-Dichlorobenzidine ND mg/kg 0.91 0.32 1 08/10/20 17:24 08/11/20 14:46 91-94-1
2,4-Dichlorophenol ND mg/kg 0.45 0.15 1 08/10/20 17:24 08/11/20 14:46 120-83-2
Diethylphthalate ND mg/kg 0.45 0.099 1 08/10/20 17:24 08/11/20 14:46 84-66-2
2,4-Dimethylphenol ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 105-67-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 49 of 111
Pace Analytical Services,LLC
aceAnalytical
9800 KinceyAve. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-8 Lab ID: 92489806017 Collected: 08/06/20 18:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method:EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Dimethylphthalate ND mg/kg 0.45 0.10 1 08/10/20 17:24 08/11/20 14:46 131-11-3
Di-n-butylphthalate ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 84-74-2
4,6-Dinitro-2-methylphenol ND mg/kg 0.91 0.73 1 08/10/20 17:24 08/11/20 14:46 534-52-1
2,4-Dinitrophenol ND mg/kg 2.3 1.5 1 08/10/20 17:24 08/11/20 14:46 51-28-5
2,4-Dinitrotoluene ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 121-14-2
2,6-Dinitrotoluene ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 606-20-2 L2
Di-n-octylphthalate ND mg/kg 0.45 0.26 1 08/10/20 17:24 08/11/20 14:46 117-84-0 v1
bis(2-Ethylhexyl)phthalate ND mg/kg 0.45 0.15 1 08/10/20 17:24 08/11/20 14:46 117-81-7
Fluoranthene ND mg/kg 0.45 0.14 1 08/10/20 17:24 08/11/20 14:46 206-44-0
Fluorene ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 86-73-7
Hexachloro-1,3-butadiene ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 87-68-3
Hexachlorobenzene ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 118-74-1
Hexachlorocyclopentadiene ND mg/kg 0.45 0.18 1 08/10/20 17:24 08/11/20 14:46 77-47-4
Hexachloroethane ND mg/kg 0.45 0.10 1 08/10/20 17:24 08/11/20 14:46 67-72-1
Indeno(1,2,3-cd)pyrene ND mg/kg 0.45 0.21 1 08/10/20 17:24 08/11/20 14:46 193-39-5 v1
Isophorone ND mg/kg 0.45 0.099 1 08/10/20 17:24 08/11/20 14:46 78-59-1
1-Methylnaphthalene ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 90-12-0
2-Methylnaphthalene ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 91-57-6
2-Methylphenol(o-Cresol) ND mg/kg 0.45 0.10 1 08/10/20 17:24 08/11/20 14:46 95-48-7
3&4-Methylphenol(m&p Cresol) ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 15831-10-4
Naphthalene ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 91-20-3
2-Nitroaniline ND mg/kg 2.3 0.23 1 08/10/20 17:24 08/11/20 14:46 88-74-4
3-Nitroaniline ND mg/kg 2.3 0.24 1 08/10/20 17:24 08/11/20 14:46 99-09-2
4-Nitroaniline ND mg/kg 0.91 0.22 1 08/10/20 17:24 08/11/20 14:46 100-01-6
Nitrobenzene ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 98-95-3
2-Nitrophenol ND mg/kg 0.45 0.14 1 08/10/20 17:24 08/11/20 14:46 88-75-5
4-Nitrophenol ND mg/kg 2.3 0.72 1 08/10/20 17:24 08/11/20 14:46 100-02-7
N-Nitrosodimethylamine ND mg/kg 0.45 0.13 1 08/10/20 17:24 08/11/20 14:46 62-75-9
N-Nitroso-di-n-propylamine ND mg/kg 0.45 0.13 1 08/10/20 17:24 08/11/20 14:46 621-64-7
N-Nitrosodiphenylamine ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 86-30-6
2,2'-Oxybis(1-chloropropane)ND mg/kg 0.45 0.13 1 08/10/20 17:24 08/11/20 14:46 108-60-1
Pentachlorophenol ND mg/kg 0.91 0.21 1 08/10/20 17:24 08/11/20 14:46 87-86-5
Phenanthrene ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 85-01-8
Phenol ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 108-95-2
Pyrene ND mg/kg 0.45 0.13 1 08/10/20 17:24 08/11/20 14:46 129-00-0
Pyridine ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 110-86-1
1,2,4-Trichlorobenzene ND mg/kg 0.45 0.10 1 08/10/20 17:24 08/11/20 14:46 120-82-1
2,4,5-Trichlorophenol ND mg/kg 0.45 0.12 1 08/10/20 17:24 08/11/20 14:46 95-95-4
2,4,6-Trichlorophenol ND mg/kg 0.45 0.11 1 08/10/20 17:24 08/11/20 14:46 88-06-2
Surrogates
Nitrobenzene-d5(S) 45 % 23-110 1 08/10/20 17:24 08/11/20 14:46 4165-60-0
2-Fluorobiphenyl(S) 48 % 30-110 1 08/10/20 17:24 08/11/20 14:46 321-60-8
Terphenyl-d14(S) 62 % 28-110 1 08/10/20 17:24 08/11/20 14:46 1718-51-0
Phenol-d6(S) 50 % 22-110 1 08/10/20 17:24 08/11/20 14:46 13127-88-3
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 50 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
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ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: SS-8 Lab ID: 92489806017 Collected: 08/06/20 18:00 Received: 08/07/20 10:00 Matrix: Solid
Results reported on a"dry weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method:EPA 3546
Pace Analytical Services-Charlotte
Surrogates
2-Fluorophenol(S) 49 % 13-110 1 08/10/20 17:24 08/11/20 14:46 367-12-4
2,4,6-Tribromophenol(S) 65 % 27-110 1 08/10/20 17:24 08/11/20 14:46 118-79-6
Percent Moisture Analytical Method:ASTM D2974-87
Pace Analytical Services-Charlotte
Percent Moisture 26.2 % 0.10 0.10 1 08/07/20 18:35
Total Solids 2540 G-2011 Analytical Method:SM 2540G Preparation Method:SM 2540 G
Pace National-Mt.Juliet
Total Solids 79.7 % 1 08/13/20 10:30 08/13/20 10:42
Wet Chemistry 7199 Analytical Method:EPA 7199 Preparation Method:3060A
Pace National-Mt.Juliet
Chromium,Hexavalent ND mg/kg 1.26 0.320 1 08/12/20 10:20 08/12/20 17:48 18540-29-9
REPORT OF LABORATORY ANALYSIS
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r mei
Pace Analytical Services,LLC
aceAnalytical
s 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: Trip Blank Lab ID: 92489806018 Collected: 08/06/20 00:00 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Acetone 52.3 ug/L 25.0 6.2 1 08/11/20 21:33 67-64-1
Benzene ND ug/L 1.0 0.15 1 08/11/20 21:33 71-43-2
Bromobenzene ND ug/L 1.0 0.22 1 08/11/20 21:33 108-86-1
Bromochloromethane ND ug/L 1.0 0.34 1 08/11/20 21:33 74-97-5
Bromodichloromethane ND ug/L 1.0 0.26 1 08/11/20 21:33 75-27-4
Bromoform ND ug/L 1.0 0.62 1 08/11/20 21:33 75-25-2
Bromomethane ND ug/L 2.0 0.62 1 08/11/20 21:33 74-83-9 v2
2-Butanone(MEK) ND ug/L 5.0 3.3 1 08/11/20 21:33 78-93-3
Carbon tetrachloride ND ug/L 1.0 0.22 1 08/11/20 21:33 56-23-5
Chlorobenzene ND ug/L 1.0 0.23 1 08/11/20 21:33 108-90-7
Chloroethane ND ug/L 1.0 0.49 1 08/11/20 21:33 75-00-3 IK
Chloroform ND ug/L 5.0 2.3 1 08/11/20 21:33 67-66-3
Chloromethane ND ug/L 1.0 0.39 1 08/11/20 21:33 74-87-3 v2
2-Chlorotoluene ND ug/L 1.0 0.20 1 08/11/20 21:33 95-49-8
4-Chlorotoluene ND ug/L 1.0 0.20 1 08/11/20 21:33 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 08/11/20 21:33 96-12-8
Dibromochloromethane ND ug/L 1.0 0.41 1 08/11/20 21:33 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 0.26 1 08/11/20 21:33 106-93-4
Dibromomethane ND ug/L 1.0 0.46 1 08/11/20 21:33 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 08/11/20 21:33 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 0.22 1 08/11/20 21:33 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 08/11/20 21:33 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 0.23 1 08/11/20 21:33 75-71-8
1,1-Dichloroethane ND ug/L 1.0 0.27 1 08/11/20 21:33 75-34-3
1,2-Dichloroethane ND ug/L 1.0 0.34 1 08/11/20 21:33 107-06-2
1,1-Dichloroethene ND ug/L 1.0 0.24 1 08/11/20 21:33 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 08/11/20 21:33 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 08/11/20 21:33 156-60-5
1,2-Dichloropropane ND ug/L 1.0 0.19 1 08/11/20 21:33 78-87-5
1,3-Dichloropropane ND ug/L 1.0 0.16 1 08/11/20 21:33 142-28-9
2,2-Dichloropropane ND ug/L 1.0 0.27 1 08/11/20 21:33 594-20-7
1,1-Dichloropropene ND ug/L 1.0 0.21 1 08/11/20 21:33 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 08/11/20 21:33 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 0.31 1 08/11/20 21:33 10061-02-6
Diisopropyl ether ND ug/L 1.0 0.22 1 08/11/20 21:33 108-20-3
Ethylbenzene ND ug/L 1.0 0.26 1 08/11/20 21:33 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 08/11/20 21:33 87-68-3
2-Hexanone ND ug/L 5.0 0.57 1 08/11/20 21:33 591-78-6
p-Isopropyltoluene ND ug/L 1.0 0.21 1 08/11/20 21:33 99-87-6
Methylene Chloride ND ug/L 5.0 3.7 1 08/11/20 21:33 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 4.5 1 08/11/20 21:33 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 0.28 1 08/11/20 21:33 1634-04-4
Naphthalene ND ug/L 1.0 0.35 1 08/11/20 21:33 91-20-3
Styrene ND ug/L 1.0 0.27 1 08/11/20 21:33 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 08/11/20 21:33 630-20-6
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.paealabs.cam 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: Trip Blank Lab ID: 92489806018 Collected: 08/06/20 00:00 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method: EPA 8260D
Pace Analytical Services-Charlotte
1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 08/11/20 21:33 79-34-5
Tetrachloroethene ND ug/L 1.0 0.16 1 08/11/2021:33 127-18-4
Toluene ND ug/L 1.0 0.24 1 08/11/2021:33 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 08/11/2021:33 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 08/11/20 21:33 120-82-1
1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 08/11/20 21:33 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 08/11/20 21:33 79-00-5
Trichloroethene ND ug/L 1.0 0.22 1 08/11/20 21:33 79-01-6
Trichlorofluoromethane ND ug/L 1.0 0.31 1 08/11/20 21:33 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 08/11/20 21:33 96-18-4
Vinyl acetate ND ug/L 2.0 1.4 1 08/11/20 21:33 108-05-4
Vinyl chloride ND ug/L 1.0 0.24 1 08/11/20 21:33 75-01-4
Xylene(Total) ND ug/L 1.0 0.63 1 08/11/20 21:33 1330-20-7
m&p-Xylene ND ug/L 2.0 0.41 1 08/11/20 21:33 179601-23-1
o-Xylene ND ug/L 1.0 0.22 1 08/11/2021:33 95-47-6
Surrogates
4-Bromofluorobenzene(S) 94 % 70-130 1 08/11/20 21:33 460-00-4
1,2-Dichloroethane-d4(S) 100 % 70-130 1 08/11/20 21:33 17060-07-0
Toluene-d8(S) 101 % 70-130 1 08/11/20 21:33 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-1 Lab ID: 92489806019 Collected: 08/05/20 15:40 Received: 08/07/20 10.00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Pace Analytical Services-Charlotte
Acenaphthene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 83-32-9
Acenaphthylene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 208-96-8
Aniline ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 62-53-3
Anthracene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1.8 1 08/11/20 21:35 08/13/20 13:59 50-32-8 L1
Benzo(b)fluoranthene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 13:59 205-99-2 L1
Benzo(g,h,i)perylene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 207-08-9 L1
Benzoic Acid ND ug/L 50.0 19.5 1 08/11/20 21:35 08/13/20 13:59 65-85-0 L2
Benzyl alcohol ND ug/L 20.0 2.6 1 08/11/20 21:35 08/13/20 13:59 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 13:59 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1.9 1 08/11/20 21:35 08/13/20 13:59 85-68-7 L1
4-Chloro-3-methylphenol ND ug/L 10.0 2.8 1 08/11/20 21:35 08/13/20 13:59 59-50-7
4-Chloroaniline ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 13:59 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 13:59 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 13:59 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 91-58-7
2-Chlorophenol ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 7005-72-3
Chrysene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 218-01-9 Li
Dibenz(a,h)anthracene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 53-70-3
Dibenzofuran ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 13:59 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 2.7 1 08/11/20 21:35 08/13/20 13:59 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 120-83-2
Diethylphthalate ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 105-67-9
Dimethylphthalate ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 84-74-2 L1
4,6-Dinitro-2-methylphenol ND ug/L 20.0 4.5 1 08/11/20 21:35 08/13/20 13:59 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 7.3 1 08/11/20 21:35 08/13/20 13:59 51-28-5
2,4-Dinitrotoluene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 13:59 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 13:59 606-20-2
Di-n-octylphthalate ND ug/L 10.0 2.2 1 08/11/20 21:35 08/13/20 13:59 117-84-0 L1,v1
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 2.0 1 08/11/20 21:35 08/13/20 13:59 117-81-7 L1
Fluoranthene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 206-44-0
Fluorene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 87-68-3
Hexachlorobenzene ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 13:59 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 2.4 1 08/11/20 21:35 08/13/20 13:59 77-47-4
Hexachloroethane ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 13:59 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 13:59 193-39-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
is 9800 KinceyAve. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-1 Lab ID: 92489806019 Collected: 08/05/20 15:40 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method: EPA 8270E Preparation Method:EPA 3510C
Pace Analytical Services-Charlotte
Isophorone ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 13:59 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 13:59 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 13:59 15831-10-4
Naphthalene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 91-20-3
2-Nitroaniline ND ug/L 20.0 3.0 1 08/11/20 21:35 08/13/20 13:59 88-74-4 L1
3-Nitroaniline ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 13:59 99-09-2
4-Nitroaniline ND ug/L 20.0 3.1 1 08/11/20 21:35 08/13/20 13:59 100-01-6 L1
Nitrobenzene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 98-95-3
2-Nitrophenol ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 13:59 88-75-5
4-Nitrophenol ND ug/L 50.0 9.4 1 08/11/20 21:35 08/13/20 13:59 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1.8 1 08/11/20 21:35 08/13/20 13:59 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 13:59 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 86-30-6
2,2'-Oxybis(1-chloropropane)ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 13:59 108-60-1
Pentachlorophenol ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 13:59 87-86-5
Phenanthrene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 85-01-8
Phenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 108-95-2
Pyrene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 129-00-0 L1
1,2,4-Trichlorobenzene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 13:59 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 13:59 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 13:59 88-06-2
Surrogates
Nitrobenzene-d5(S) 92 % 13-130 1 08/11/20 21:35 08/13/20 13:59 4165-60-0
2-Fluorobiphenyl(S) 83 % 13-130 1 08/11/20 21:35 08/13/20 13:59 321-60-8
Terphenyl-d14(S) 118 % 25-130 1 08/11/20 21:35 08/13/20 13:59 1718-51-0
Phenol-d6(S) 49 % 10-130 1 08/11/20 21:35 08/13/20 13:59 13127-88-3
2-Fluorophenol(S) 63 % 10-130 1 08/11/20 21:35 08/13/20 13:59 367-12-4
2,4,6-Tribromophenol(S) 79 % 10-137 1 08/11/20 21:35 08/13/20 13:59 118-79-6
8260D MSV Low Level Analytical Method: EPA 8260D
Pace Analytical Services-Charlotte
Acetone ND ug/L 25.0 6.2 1 08/11/20 21:51 67-64-1
Benzene ND ug/L 1.0 0.15 1 08/11/20 21:51 71-43-2
Bromobenzene ND ug/L 1.0 0.22 1 08/11/20 21:51 108-86-1
Bromochloromethane ND ug/L 1.0 0.34 1 08/11/20 21:51 74-97-5
Bromodichloromethane ND ug/L 1.0 0.26 1 08/11/20 21:51 75-27-4
Bromoform ND ug/L 1.0 0.62 1 08/11/20 21:51 75-25-2
Bromomethane ND ug/L 2.0 0.62 1 08/11/20 21:51 74-83-9 v2
2-Butanone(MEK) ND ug/L 5.0 3.3 1 08/11/20 21:51 78-93-3
Carbon tetrachloride ND ug/L 1.0 0.22 1 08/11/20 21:51 56-23-5
Chlorobenzene ND ug/L 1.0 0.23 1 08/11/20 21:51 108-90-7
Chloroethane ND ug/L 1.0 0.49 1 08/11/2021:51 75-00-3 IK
Chloroform ND ug/L 5.0 2.3 1 08/11/20 21:51 67-66-3
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 55 of 111
Pace Analytical Services,LLC
74 aceAnalytical,„ 9800100
Huntersv Ile,NC
Kincey Ave. '
28078
www.pacelahs.corn
704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-1 Lab ID: 92489806019 Collected: 08/05/20 15:40 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Chloromethane ND ug/L 1.0 0.39 1 08/11/20 21:51 74-87-3 v2
2-Chlorotoluene ND ug/L 1.0 0.20 1 08/11/2021:51 95-49-8
4-Chlorotoluene ND ug/L 1.0 0.20 1 08/11/20 21:51 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 08/11/20 21:51 96-12-8
Dibromochloromethane ND ug/L 1.0 0.41 1 08/11/20 21:51 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 0.26 1 08/11/20 21:51 106-93-4
Dibromomethane ND ug/L 1.0 0.46 1 08/11/20 21:51 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 08/11/20 21:51 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 0.22 1 08/11/20 21:51 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 08/11/20 21:51 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 0.23 1 08/11/20 21:51 75-71-8
1,1-Dichloroethane ND ug/L 1.0 0.27 1 08/11/20 21:51 75-34-3
1,2-Dichloroethane ND ug/L 1.0 0.34 1 08/11/20 21:51 107-06-2
1,1-Dichloroethene ND ug/L 1.0 0.24 1 08/11/20 21:51 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 08/11/20 21:51 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 08/11/20 21:51 156-60-5
1,2-Dichloropropane ND ug/L 1.0 0.19 1 08/11/20 21:51 78-87-5
1,3-Dichloropropane ND ug/L 1.0 0.16 1 08/11/20 21:51 142-28-9
2,2-Dichloropropane ND ug/L 1.0 0.27 1 08/11/20 21:51 594-20-7
1,1-Dichloropropene ND ug/L 1.0 0.21 1 08/11/20 21:51 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 08/11/20 21:51 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 0.31 1 08/11/20 21:51 10061-02-6
Diisopropyl ether ND ug/L 1.0 0.22 1 08/11/20 21:51 108-20-3
Ethylbenzene ND ug/L 1.0 0.26 1 08/11/20 21:51 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 08/11/20 21:51 87-68-3
2-Hexanone ND ug/L 5.0 0.57 1 08/11/20 21:51 591-78-6
p-Isopropyltoluene ND ug/L 1.0 0.21 1 08/11/20 21:51 99-87-6
Methylene Chloride ND ug/L 5.0 3.7 1 08/11/20 21:51 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 4.5 1 08/11/20 21:51 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 0.28 1 08/11/20 21:51 1634-04-4
Naphthalene ND ug/L 1.0 0.35 1 08/11/20 21:51 91-20-3
Styrene ND ug/L 1.0 0.27 1 08/11/20 21:51 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 08/11/20 21:51 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 08/11/20 21:51 79-34-5
Tetrachloroethene ND ug/L 1.0 0.16 1 08/11/20 21:51 127-18-4
Toluene ND ug/L 1.0 0.24 1 08/11/20 21:51 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 08/11/20 21:51 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 08/11/20 21:51 120-82-1
1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 08/11/2021:51 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 08/11/20 21:51 79-00-5
Trchloroethene ND ug/L 1.0 0.22 1 08/11/20 21:51 79-01-6
Trichlorofluoromethane ND ug/L 1.0 0.31 1 08/11/20 21:51 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 08/11/20 21:51 96-18-4
Vinyl acetate ND ug/L 2.0 1.4 1 08/11/20 21:51 108-05-4
Vinyl chloride ND ug/L 1.0 0.24 1 08/11/20 21:51 75-01-4
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 56 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
ww.picelabs corn 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-1 Lab ID: 92489806019 Collected: 08/05/20 15:40 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method: EPA 8260D
Pace Analytical Services-Charlotte
Xylene(Total) ND ug/L 1.0 0.63 1 08/11/20 21:51 1330-20-7
m&p-Xylene ND ug/L 2.0 0.41 1 08/11/20 21:51 179601-23-1
o-Xylene ND ug/L 1.0 0.22 1 08/11/20 21:51 95-47-6
Surrogates
4-Bromofluorobenzene(S) 96 % 70-130 1 08/11/20 21:51 460-00-4
1,2-Dichloroethane-d4(S) 102 % 70-130 1 08/11/20 21:51 17060-07-0
Toluene-d8(S) 101 % 70-130 1 08/11/20 21:51 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
ace Analytical
F, 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-2 Lab ID: 92489806020 Collected: 08/05/20 16:30 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Pace Analytical Services-Charlotte
Acenaphthene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 83-32-9
Acenaphthylene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 208-96-8
Aniline ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 62-53-3
Anthracene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1.8 1 08/11/20 21:35 08/13/20 14:25 50-32-8 Li
Benzo(b)fluoranthene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 14:25 205-99-2 Li
Benzo(g,h,i)perylene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 191-24-2 M1
Benzo(k)fluoranthene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 207-08-9 Li
Benzoic Acid ND ug/L 50.0 19.5 1 08/11/20 21:35 08/13/20 14:25 65-85-0 L2,M0
Benzyl alcohol ND ug/L 20.0 2.6 1 08/11/20 21:35 08/13/20 14:25 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 14:25 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1.9 1 08/11/20 21:35 08/13/20 14:25 85-68-7 L1
4-Chloro-3-methylphenol ND ug/L 10.0 2.8 1 08/11/20 21:35 08/13/20 14:25 59-50-7
4-Chloroaniline ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 14:25 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 14:25 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 14:25 111-44-4 M1
2-Chloronaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 91-58-7
2-Chlorophenol ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 7005-72-3
Chrysene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 218-01-9 L1
Dibenz(a,h)anthracene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 53-70-3 M1
Dibenzofuran ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 14:25 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 2.7 1 08/11/20 21:35 08/13/20 14:25 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 120-83-2
Diethylphthalate ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 84-66-2
1 2,4-Dimethylphenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 105-67-9
Dimethylphthalate ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 131-11-3
ug/LIPhthalateNDu /L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 84-74-2 L1 MO
4,6-Dinitro-2-methylphenol ND ug/L 20.0 4.5 1 08/11/20 21:35 08/13/20 14:25 534-52-1 R1
2,4-Dinitrophenol ND ug/L 50.0 7.3 1 08/11/20 21:35 08/13/20 14:25 51-28-5 M1
2,4-Dinitrotoluene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 14:25 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 08/11/2021:35 08/13/20 14:25 606-20-2
Di-n-octylphthalate ND ug/L 10.0 2.2 1 08/11/20 21:35 08/13/20 14:25 117-84-0 L1,MO,
v1
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 2.0 1 08/11/20 21:35 08/13/20 14:25 117-81-7 L1,M0
Fluoranthene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 206-44-0
Fluorene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 87-68-3
Hexachlorobenzene ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 14:25 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 2.4 1 08/11/20 21:35 08/13/20 14:25 77-47-4
Hexachloroethane ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 14:25 67-72-1
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 58 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. SuiteaceAnalyticalHuntersville,NC 2807878
www.pacelabs.cwa 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-2 Lab ID: 92489806020 Collected: 08/05/20 16:30 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method: EPA 8270E Preparation Method:EPA 3510C
Pace Analytical Services-Charlotte
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 14:25 193-39-5 M1
Isophorone ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 14:25 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 14:25 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 14:25 15831-10-4
Naphthalene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 91-20-3
2-Nitroaniline ND ug/L 20.0 3.0 1 08/11/20 21:35 08/13/20 14:25 88-74-4 L1
3-Nitroaniline ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 14:25 99-09-2 I
4-Nitroaniline ND ug/L 20.0 3.1 1 08/11/20 21:35 08/13/20 14:25 100-01-6 L1,M0
Nitrobenzene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 98-95-3
2-Nitrophenol ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 14:25 88-75-5
4-Nitrophenol ND ug/L 50.0 9.4 1 08/11/20 21:35 08/13/20 14:25 100-02-7 R1
N-Nitrosodimethylamine ND ug/L 10.0 1.8 1 08/11/20 21:35 08/13/20 14:25 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 14:25 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 86-30-6
2,2'-Oxybis(1-chloropropane)ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 14:25 108-60-1
Pentachlorophenol ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 14:25 87-86-5
Phenanthrene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 85-01-8
Phenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 108-95-2
Pyrene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 129-00-0 L1
1,2,4-Trichlorobenzene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 14:25 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 14:25 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 14:25 88-06-2
Surrogates
Nitrobenzene-d5(S) 80 % 13-130 1 08/11/20 21:35 08/13/20 14:25 4165-60-0
2-Fluorobiphenyl(S) 74 % 13-130 1 08/11/20 21:35 08/13/20 14:25 321-60-8
Terphenyl-d14(S) 117 % 25-130 1 08/11/20 21:35 08/13/20 14:25 1718-51-0
Phenol-d6(S) 43 % 10-130 1 08/11/20 21:35 08/13/20 14:25 13127-88-3
2-Fluorophenol(S) 53 % 10-130 1 08/11/20 21:35 08/13/20 14:25 367-12-4
2,4,6-Tribromophenol(S) 70 % 10-137 1 08/11/20 21:35 08/13/20 14:25 118-79-6
8260D MSV Low Level Analytical Method: EPA 8260D
Pace Analytical Services-Charlotte
Acetone ND ug/L 25.0 6.2 1 08/11/20 22:08 67-64-1
Benzene ND ug/L 1.0 0.15 1 08/11/20 22:08 71-43-2
Bromobenzene ND ug/L 1.0 0.22 1 08/11/20 22:08 108-86-1
Bromochloromethane ND ug/L 1.0 0.34 1 08/11/20 22:08 74-97-5
Bromodichloromethane ND ug/L 1.0 0.26 1 08/11/20 22:08 75-27-4
Bromoform ND ug/L 1.0 0.62 1 08/11/20 22:08 75-25-2
Bromomethane ND ug/L 2.0 0.62 1 08/11/20 22:08 74-83-9 v2
2-Butanone(MEK) ND ug/L 5.0 3.3 1 08/11/20 22:08 78-93-3
Carbon tetrachloride ND ug/L 1.0 0.22 1 08/11/20 22:08 56-23-5
Chlorobenzene ND ug/L 1.0 0.23 1 08/11/20 22:08 108-90-7
Chloroethane ND ug/L 1.0 0.49 1 08/11/20 22:08 75-00-3 IK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 59 of 111
Pace Analytical Services,LLC
9800 KinceyAve. Suite 100
ace Analytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-2 Lab ID: 92489806020 Collected: 08/05/20 16:30 Received: 08/07/20 10:00 Matrix:Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Chloroform ND ug/L 5.0 2.3 1 08/11/20 22:08 67-66-3
Chloromethane ND ug/L 1.0 0.39 1 08/11/20 22:08 74-87-3 v2
2-Chlorotoluene ND ug/L 1.0 0.20 1 08/11/20 22:08 95-49-8
4-Chlorotoluene ND ug/L 1.0 0.20 1 08/11/20 22:08 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 08/11/20 22:08 96-12-8
Dibromochloromethane ND ug/L 1.0 0.41 1 08/11/20 22:08 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 0.26 1 08/11/20 22:08 106-93-4
Dibromomethane ND ug/L 1.0 0.46 1 08/11/20 22:08 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 08/11/20 22:08 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 0.22 1 08/11/20 22:08 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 08/11/20 22:08 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 0.23 1 08/11/20 22:08 75-71-8
1,1-Dichloroethane ND ug/L 1.0 0.27 1 08/11/20 22:08 75-34-3
1,2-Dichloroethane ND ug/L 1.0 0.34 1 08/11/20 22:08 107-06-2
1,1-Dichloroethene ND ug/L 1.0 0.24 1 08/11/20 22:08 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 08/11/20 22:08 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 08/11/20 22:08 156-60-5
1,2-Dichloropropane ND ug/L 1.0 0.19 1 08/11/20 22:08 78-87-5
1,3-Dichloropropane ND ug/L 1.0 0.16 1 08/11/20 22:08 142-28-9
2,2-Dichloropropane ND ug/L 1.0 0.27 1 08/11/20 22:08 594-20-7
1,1-Dichloropropene ND ug/L 1.0 0.21 1 08/11/20 22:08 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 08/11/20 22:08 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 0.31 1 08/11/20 22:08 10061-02-6
Diisopropyl ether ND ug/L 1.0 0.22 1 08/11/20 22:08 108-20-3
Ethylbenzene ND ug/L 1.0 0.26 1 08/11/20 22:08 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 08/11/20 22:08 87-68-3
2-Hexanone ND ug/L 5.0 0.57 1 08/11/20 22:08 591-78-6
p-lsopropyltoluene ND ug/L 1.0 0.21 1 08/11/20 22:08 99-87-6
Methylene Chloride ND ug/L 5.0 3.7 1 08/11/20 22:08 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 4.5 1 08/11/20 22:08 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 0.28 1 08/11/20 22:08 1634-04-4
Naphthalene ND ug/L 1.0 0.35 1 08/11/20 22:08 91-20-3
Styrene ND ug/L 1.0 0.27 1 08/11/20 22:08 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 08/11/20 22:08 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 08/11/20 22:08 79-34-5
Tetrachloroethene ND ug/L 1.0 0.16 1 08/11/20 22:08 127-18-4
Toluene ND ug/L 1.0 0.24 1 08/11/20 22:08 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 08/11/20 22:08 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 08/11/20 22:08 120-82-1
1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 08/11/20 22:08 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 08/11/20 22:08 79-00-5
Trichloroethene ND ug/L 1.0 0.22 1 08/11/20 22:08 79-01-6
Trichlorofluoromethane ND ug/L 1.0 0.31 1 08/11/20 22:08 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 08/11/20 22:08 96-18-4
Vinyl acetate ND ug/L 2.0 1.4 1 08/11/20 22:08 108-05-4
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-2 Lab ID: 92489806020 Collected: 08/05/20 16:30 Received: 08/07/20 10:00 Matrix: Water
1 Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Vinyl chloride ND ug/L 1.0 0.24 1 08/11/20 22:08 75-01-4
Xylene(Total) ND ug/L 1.0 0.63 1 08/11/20 22:08 1330-20-7
m&p-Xylene ND ug/L 2.0 0.41 1 08/11/20 22:08 179601-23-1
o-Xylene ND ug/L 1.0 0.22 1 08/11/20 22:08 95-47-6
Surrogates
4-Bromofluorobenzene(S) 96 % 70-130 1 08/11/20 22:08 460-00-4
1,2-Dichloroethane-d4(S) 104 % 70-130 1 08/11/20 22:08 17060-07-0
Toluene-d8(S) 101 % 70-130 1 08/11/20 22:08 2037-26-5
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-DUP Lab ID: 92489806021 Collected: 08/05/20 16:30 Received: 08/07/20 10:00 Matrix:Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Pace Analytical Services-Charlotte
Acenaphthene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 83-32-9
Acenaphthylene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 208-96-8
Aniline ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 62-53-3
Anthracene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1.8 1 08/11/20 21:35 08/13/20 15:42 50-32-8 L1
Benzo(b)fluoranthene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 15:42 205-99-2 L1
Benzo(g,h,i)perylene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 207-08-9 L1
Benzoic Acid ND ug/L 50.0 19.5 1 08/11/20 21:35 08/13/20 15:42 65-85-0 L2
Benzyl alcohol ND ug/L 20.0 2.6 1 08/11/20 21:35 08/13/20 15:42 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 15:42 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1.9 1 08/11/20 21:35 08/13/20 15:42 85-68-7 L1
4-Chloro-3-methylphenol ND ug/L 10.0 2.8 1 08/11/20 21:35 08/13/20 15:42 59-50-7
4-Chloroaniline ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 15:42 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 15:42 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 15:42 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 91-58-7
2-Chlorophenol ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 7005-72-3
Chrysene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 218-01-9 L1
Dibenz(a,h)anthracene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 53-70-3
Dibenzofuran ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 15:42 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 2.7 1 08/11/20 21:35 08/13/20 15:42 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 120-83-2
Diethylphthalate ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 105-67-9
Dimethylphthalate ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 84-74-2 L1
4,6-Dinitro-2-methylphenol ND ug/L 20.0 4.5 1 08/11/20 21:35 08/13/20 15:42 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 7.3 1 08/11/20 21:35 08/13/20 15:42 51-28-5
2,4-Dinitrotoluene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 15:42 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 15:42 606-20-2
Di-n-octylphthalate ND ug/L 10.0 2.2 1 08/11/20 21:35 08/13/20 15:42 117-84-0 L1,v1
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 2.0 1 08/11/20 21:35 08/13/20 15:42 117-81-7 L1
Fluoranthene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 206-44-0
Fluorene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 87-68-3
Hexachlorobenzene ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 15:42 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 2.4 1 08/11/20 21:35 08/13/20 15:42 77-47-4
Hexachloroethane ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 15:42 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 15:42 193-39-5
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-DUP Lab ID: 92489806021 Collected: 08/05/20 16:30 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Pace Analytical Services-Charlotte
Isophorone ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 15:42 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 15:42 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1.2 1 08/11/20 21:35 08/13/20 15:42 15831-10-4
Naphthalene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 91-20-3
2-Nitroaniline ND ug/L 20.0 3.0 1 08/11/20 21:35 08/13/20 15:42 88-74-4 L1
3-Nitroaniline ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 15:42 99-09-2
4-Nitroaniline ND ug/L 20.0 3.1 1 08/11/20 21:35 08/13/20 15:42 100-01-6 L1
Nitrobenzene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 98-95-3
2-Nitrophenol ND ug/L 10.0 1.7 1 08/11/20 21:35 08/13/20 15:42 88-75-5
4-Nitrophenol ND ug/L 50.0 9.4 1 08/11/20 21:35 08/13/20 15:42 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1.8 1 08/11/20 21:35 08/13/20 15:42 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 15:42 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 86-30-6
2,2'-Oxybis(1-chloropropane)ND ug/L 10.0 1.3 1 08/11/20 21:35 08/13/20 15:42 108-60-1
Pentachlorophenol ND ug/L 20.0 2.8 1 08/11/20 21:35 08/13/20 15:42 87-86-5
Phenanthrene ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 85-01-8
Phenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 108-95-2
Pyrene ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 129-00-0 L1
1,2,4-Trichlorobenzene ND ug/L 10.0 1.6 1 08/11/20 21:35 08/13/20 15:42 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1.5 1 08/11/20 21:35 08/13/20 15:42 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1.4 1 08/11/20 21:35 08/13/20 15:42 88-06-2
Surrogates
Nitrobenzene-d5(S) 54 % 13-130 1 08/11/20 21:35 08/13/20 15:42 4165-60-0
2-Fluorobiphenyl(S) 49 % 13-130 1 08/11/20 21:35 08/13/20 15:42 321-60-8
Terphenyl-d14(S) 103 % 25-130 1 08/11/20 21:35 08/13/20 15:42 1718-51-0
Phenol-d6(S) 27 % 10-130 1 08/11/20 21:35 08/13/20 15:42 13127-88-3
2-Fluorophenol(S) 36 % 10-130 1 08/11/20 21:35 08/13/20 15:42 367-12-4
2,4,6-Tribromophenol(S) 47 % 10-137 1 08/11/20 21:35 08/13/20 15:42 118-79-6
8260D MSV Low Level Analytical Method: EPA 8260D
Pace Analytical Services-Charlotte
Acetone ND ug/L 25.0 6.2 1 08/11/20 22:26 67-64-1
Benzene ND ug/L 1.0 0.15 1 08/11/20 22:26 71-43-2
Bromobenzene ND ug/L 1.0 0.22 1 08/11/20 22:26 108-86-1
Bromochloromethane ND ug/L 1.0 0.34 1 08/11/20 22:26 74-97-5
Bromodichloromethane ND ug/L 1.0 0.26 1 08/11/20 22:26 75-27-4
Bromoform ND ug/L 1.0 0.62 1 08/11/20 22:26 75-25-2
Bromomethane ND ug/L 2.0 0.62 1 08/11/20 22:26 74-83-9 v2
2-Butanone(MEK) ND ug/L 5.0 3.3 1 08/11/20 22:26 78-93-3
Carbon tetrachloride ND ug/L 1.0 0.22 1 08/11/20 22:26 56-23-5
Chlorobenzene ND ug/L 1.0 0.23 1 08/11/20 22:26 108-90-7
Chloroethane ND ug/L 1.0 0.49 1 08/11/20 22:26 75-00-3 IK
Chloroform ND ug/L 5.0 2.3 1 08/11/20 22:26 67-66-3
REPORT OF LABORATORY ANALYSIS
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I
ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-DUP Lab ID: 92489806021 Collected: 08/05/20 16:30 Received: 08/07/20 10:00 Matrix:Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Chloromethane ND ug/L 1.0 0.39 1 08/11/2022:26 74-87-3 v2
2-Chlorotoluene ND ug/L 1.0 0.20 1 08/11/2022:26 95-49-8
4-Chlorotoluene ND ug/L 1.0 0.20 1 08/11/20 22:26 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 08/11/20 22:26 96-12-8
Dibromochloromethane ND ug/L 1.0 0.41 1 08/11/20 22:26 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 0.26 1 08/11/20 22:26 106-93-4
Dibromomethane ND ug/L 1.0 0.46 1 08/11/20 22:26 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 08/11/20 22:26 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 0.22 1 08/11/20 22:26 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 08/11/20 22:26 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 0.23 1 08/11/20 22:26 75-71-8
1,1-Dichloroethane ND ug/L 1.0 0.27 1 08/11/20 22:26 75-34-3
1,2-Dichloroethane ND ug/L 1.0 0.34 1 08/11/20 22:26 107-06-2
1,1-Dichloroethene ND ug/L 1.0 0.24 1 08/11/20 22:26 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 08/11/20 22:26 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 08/11/20 22:26 156-60-5
1,2-Dichloropropane ND ug/L 1.0 0.19 1 08/11/20 22:26 78-87-5
1,3-Dichloropropane ND ug/L 1.0 0.16 1 08/11/20 22:26 142-28-9
2,2-Dichloropropane ND ug/L 1.0 0.27 1 08/11/20 22:26 594-20-7
1,1-Dichloropropene ND ug/L 1.0 0.21 1 08/11/20 22:26 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 08/11/20 22:26 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 0.31 1 08/11/20 22:26 10061-02-6
Diisopropyl ether ND ug/L 1.0 0.22 1 08/11/20 22:26 108-20-3
Ethylbenzene ND ug/L 1.0 0.26 1 08/11/20 22:26 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 08/11/20 22:26 87-68-3
2-Hexanone ND ug/L 5.0 0.57 1 08/11/20 22:26 591-78-6
p-Isopropyltoluene ND ug/L 1.0 0.21 1 08/11/20 22:26 99-87-6
Methylene Chloride ND ug/L 5.0 3.7 1 08/11/20 22:26 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 4.5 1 08/11/20 22:26 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 0.28 1 08/11/20 22:26 1634-04-4
Naphthalene ND ug/L 1.0 0.35 1 08/11/20 22:26 91-20-3
Styrene ND ug/L 1.0 0.27 1 08/11/20 22:26 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 08/11/20 22:26 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 08/11/20 22:26 79-34-5
Tetrachloroethene ND ug/L 1.0 0.16 1 08/11/20 22:26 127-18-4
Toluene ND ug/L 1.0 0.24 1 08/11/20 22:26 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 08/11/20 22:26 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 08/11/20 22:26 120-82-1
1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 08/11/20 22:26 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 08/11/20 22:26 79-00-5
Trichloroethene ND ug/L 1.0 0.22 1 08/11/20 22:26 79-01-6
Trichlorofluoromethane ND ug/L 1.0 0.31 1 08/11/20 22:26 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 08/11/20 22:26 96-18-4
Vinyl acetate ND ug/L 2.0 1.4 1 08/11/20 22:26 108-05-4
Vinyl chloride ND ug/L 1.0 0.24 1 08/11/20 22:26 75-01-4
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05 08 PM without the written consent of Pace Analytical Services,LLC. Page 64 of 111
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aceAnalytical Huntersville,NC 28078
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ANALYTICAL RESULTS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Sample: TW-DUP Lab ID: 92489806021 Collected: 08/05/20 16:30 Received: 08/07/20 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Xylene(Total) ND ug/L 1.0 0.63 1 08/11/20 22:26 1330-20-7
m&p-Xylene ND ug/L 2.0 0.41 1 08/11/20 22:26 179601-23-1
o-Xylene ND ug/L 1.0 0.22 1 08/11/20 22:26 95-47-6
Surrogates
4-Bromofluorobenzene(S) 96 % 70-130 1 08/11/20 22:26 460-00-4
1,2-Dichloroethane-d4(S) 107 % 70-130 1 08/11/20 22:26 17060-07-0
Toluene-d8(S) 102 % 70-130 1 08/11/20 22:26 2037-26-5
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 558827 Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471B Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
METHOD BLANK: 2965346 Matrix: Solid
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury mg/kg ND 0.0060 0.0046 08/11/20 16:40
LABORATORY CONTROL SAMPLE: 2965347
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Mercury mg/kg 0.083 0.088 106 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2965348 2965349
MS MSD
92489806009 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Mercury mg/kg 0.018 0.084 0.09 0.13 0.14 133 132 75-125 6 20 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical Huntersville,NC 28078
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QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 558825 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
METHOD BLANK: 2965342 Matrix: Solid
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Arsenic mg/kg ND 1.0 0.50 08/11/20 19:22
Barium mg/kg ND 0.50 0.25 08/11/20 19:22
Cadmium mg/kg ND 0.10 0.050 08/11/20 19:22
Chromium mg/kg ND 0.50 0.25 08/11/20 19:22
Lead mg/kg ND 0.50 0.25 08/11/20 19:22
Selenium mg/kg ND 1.0 0.50 08/11/20 19:22
Silver mg/kg ND 0.50 0.25 08/11/20 19:22
LABORATORY CONTROL SAMPLE: 2965343
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Arsenic mg/kg 50 49.4 99 80-120
Barium mg/kg 50 50.0 100 80-120
Cadmium mg/kg 50 48.1 96 80-120
Chromium mg/kg 50 50.6 101 80-120
Lead mg/kg 50 48.6 97 80-120
Selenium mg/kg 50 44.6 89 80-120
Silver mg/kg 25 24.8 99 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2965344 2965345
MS MSD
92489806009 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Arsenic mg/kg 3.1 51.2 49.6 42.0 43.5 76 81 75-125 3 20
Barium mg/kg 56.2 51.2 49.6 79.4 76.4 45 41 75-125 4 20 M1
Cadmium mg/kg ND 51.2 49.6 41.9 42.8 82 86 75-125 2 20
Chromium mg/kg 29.4 51.2 49.6 78.7 117 96 176 75-125 39 20 M1,R1
Lead mg/kg 12.0 51.2 49.6 44.6 46.6 64 70 75-125 4 20 M1
Selenium mg/kg 2.1 51.2 49.6 36.6 37.7 67 72 75-125 3 20 M1
Silver mg/kg 0.47J 25.6 24.8 22.1 23.1 84 91 75-125 4 20
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 67 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 KinceyAve. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 558879 Analysis Method: EPA 8260D
QC Batch Method: EPA 5035A/5030B Analysis Description: 8260D 5035A 5030B
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92489806001,92489806002,92489806003,92489806004,92489806006,92489806007,92489806008,
92489806009
METHOD BLANK: 2965567 Matrix: Solid
Associated Lab Samples: 92489806001,92489806002,92489806003,92489806004,92489806006,92489806007,92489806008,
92489806009
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 0.0033 08/10/20 11:48
1,1,1-Trichloroethane mg/kg ND 0.0050 0.0020 08/10/20 11:48
1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 0.0044 08/10/20 11:48
1,1,2-Trichloroethane mg/kg ND 0.0050 0.0037 08/10/20 11:48
1,1-Dichloroethane mg/kg ND 0.0050 0.0022 08/10/20 11:48
1,1-Dichloroethene mg/kg ND 0.0050 0.0016 08/10/20 11:48
1,1-Dichloropropene mg/kg ND 0.0050 0.0024 08/10/20 11:48
1,2,3-Trichlorobenzene mg/kg ND 0.0050 0.0031 08/10/20 11:48
1,2,3-Trichloropropane mg/kg ND 0.0050 0.0041 08/10/20 11:48
1,2,4-Trichlorobenzene mg/kg ND 0.0050 0.0028 08/10/20 11:48
1,2,4-Trimethylbenzene mg/kg ND 0.0050 0.0036 08/10/20 11:48
1,2-Dibromo-3-chloropropane mg/kg ND 0.0050 0.0046 08/10/20 11:48
1,2-Dibromoethane(EDB) mg/kg ND 0.0050 0.0035 08/10/20 11:48
1,2-Dichlorobenzene mg/kg ND 0.0050 0.0030 08/10/20 11:48
1,2-Dichloroethane mg/kg ND 0.0050 0.0020 08/10/20 11:48
1,2-Dichloropropane mg/kg ND 0.0050 0.0031 08/10/20 11:48
1,3,5-Trimethylbenzene mg/kg ND 0.0050 0.0030 08/10/20 11:48
1,3-Dichlorobenzene mg/kg ND 0.0050 0.0041 08/10/20 11:48
1,3-Dichloropropane mg/kg ND 0.0050 0.0035 08/10/20 11:48
1,4-Dichlorobenzene mg/kg ND 0.0050 0.0038 08/10/20 11:48
2,2-Dichloropropane mg/kg ND 0.0050 0.0028 08/10/20 11:48
2-Butanone(MEK) mg/kg ND 0.10 0.042 08/10/20 11:48
2-Chlorotoluene mg/kg ND 0.0050 0.0036 08/10/20 11:48
2-Hexanone mg/kg ND 0.050 0.0099 08/10/20 11:48
4-Chlorotoluene mg/kg ND 0.0050 0.0032 08/10/20 11:48
4-Methyl-2-pentanone(MIBK) mg/kg ND 0.050 0.042 08/10/20 11:48
Acetone mg/kg ND 0.10 0.037 08/10/20 11:48 IK
Benzene mg/kg ND 0.0050 0.0035 08/10/20 11:48
Bromobenzene mg/kg ND 0.0050 0.0034 08/10/20 11:48
Bromochloromethane mg/kg ND 0.0050 0.0038 08/10/20 11:48
Bromodichloromethane mg/kg ND 0.0050 0.0033 08/10/20 11:48
Bromoform mg/kg ND 0.0050 0.0027 08/10/20 11:48
Bromomethane mg/kg ND 0.010 0.0079 08/10/20 11:48 IK
Carbon tetrachloride mg/kg ND 0.0050 0.0022 08/10/20 11:48
Chlorobenzene mg/kg ND 0.0050 0.0032 08/10/20 11:48
Chloroethane mg/kg ND 0.010 0.0053 08/10/20 11:48
Chloroform mg/kg ND 0.0050 0.0025 08/10/20 11:48
Chloromethane mg/kg ND 0.010 0.0070 08/10/20 11:48
cis-1,2-Dichloroethene mg/kg ND 0.0050 0.0029 08/10/20 11:48
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 68 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.paeelabs.tam 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
METHOD BLANK: 2965567 Matrix: Solid
Associated Lab Samples: 92489806001,92489806002,92489806003,92489806004,92489806006,92489806007,92489806008,
92489806009
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
cis-1,3-Dichloropropene mg/kg ND 0.0050 0.0032 08/10/20 11:48
Dibromochloromethane mg/kg ND 0.0050 0.0027 08/10/20 11:48
Dibromomethane mg/kg ND 0.0050 0.0025 08/10/20 11:48
Dichlorodifluoromethane mg/kg ND 0.010 0.0017 08/10/20 11:48
Diisopropyl ether mg/kg ND 0.0050 0.0020 08/10/20 11:48
Ethylbenzene mg/kg ND 0.0050 0.0047 08/10/20 11:48
Hexachloro-1,3-butadiene mg/kg ND 0.0050 0.0047 08/10/20 11:48
lsopropylbenzene(Cumene)mg/kg ND 0.0050 0.0032 08/10/20 11:48
m&p-Xylene mg/kg ND 0.010 0.0077 08/10/20 11:48
Methyl-tert-butyl ether mg/kg ND 0.0050 0.0032 08/10/20 11:48
Methylene Chloride mg/kg ND 0.020 0.0074 08/10/20 11:48
n-Butylbenzene mg/kg ND 0.0050 0.0027 08/10/20 11:48
n-Propylbenzene mg/kg ND 0.0050 0.0034 08/10/20 11:48
Naphthalene mg/kg ND 0.0050 0.0028 08/10/20 11:48
o-Xylene mg/kg ND 0.0050 0.0028 08/10/20 11:48
p-Isopropyltoluene mg/kg ND 0.0050 0.0028 08/10/20 11:48
sec-Butylbenzene mg/kg ND 0.0050 0.0032 08/10/20 11:48
Styrene mg/kg ND 0.0050 0.0024 08/10/20 11:48
tert-Butylbenzene mg/kg ND 0.0050 0.0027 08/10/20 11:48
Tetrachloroethene mg/kg ND 0.0050 0.0025 08/10/20 11:48
Toluene mg/kg ND 0.0050 0.0029 08/10/20 11:48
trans-1,2-Dichloroethene mg/kg ND 0.0050 0.0022 08/10/20 11:48
trans-1,3-Dichloropropene mg/kg ND 0.0050 0.0042 08/10/20 11:48
Trichloroethene mg/kg ND 0.0050 0.0031 08/10/20 11:48
Trichlorofluoromethane mg/kg ND 0.0050 0.0012 08/10/20 11:48
Vinyl acetate mg/kg ND 0.050 0.0043 08/10/20 11:48
Vinyl chloride mg/kg ND 0.010 0.0019 08/10/20 11:48
Xylene(Total) mg/kg ND 0.010 0.0028 08/10/20 11:48
1,2-Dichloroethane-d4(S) 107 70-132 08/10/20 11:48
4-Bromofluorobenzene(S) 101 70-130 08/10/20 11:48
Toluene-d8(S)100 70-130 08/10/20 11:48
LABORATORY CONTROL SAMPLE: 2965568
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane mg/kg 1.2 1.2 99 70-130
1,1,1-Trichloroethane mg/kg 1.2 1.3 100 70-130
1,1,2,2-Tetrachloroethane mg/kg 1.2 1.2 94 55-130
1,1,2-Trichloroethane mg/kg 1.2 1.4 112 70-130
1,1-Dichloroethane mg/kg 1.2 1.2 97 68-130
1,1-Dichloroethene mg/kg 1.2 1.3 104 70-130
1,1-Dichloropropene mg/kg 1.2 1.3 101 70-130
1,2,3-Trichlorobenzene mg/kg 1.2 1.1 90 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS i
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 69 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 10019eAnalyticalHuntersville,NC 28078
www.pacelabs.corn 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2965568
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,2,3-Trichloropropane mg/kg 1.2 1.2 99 70-130
1,2,4-Trichlorobenzene mg/kg 1.2 1.2 93 70-130
1,2,4-Trimethylbenzene mg/kg 1.2 1.1 86 69-130
1,2-Dibromo-3-chloropropane mg/kg 1.2 1.3 101 57-141
1,2-Dibromoethane(EDB) mg/kg 1.2 1.3 100 70-130
1,2-Dichlorobenzene mg/kg 1.2 1.1 92 70-130
1,2-Dichloroethane mg/kg 1.2 1.2 97 70-130
1,2-Dichloropropane mg/kg 1.2 1.2 97 70-130
1,3,5-Trimethylbenzene mg/kg 1.2 1.1 92 70-130
1,3-Dichlorobenzene mg/kg 1.2 1.1 91 70-130
1,3-Dichloropropane mg/kg 1.2 1.2 97 70-130
1,4-Dichlorobenzene mg/kg 1.2 1.2 93 70-130
2,2-Dichloropropane mg/kg 1.2 1.2 95 70-130
2-Butanone(MEK) mg/kg 2.5 2.5 101 60-130
2-Chlorotoluene mg/kg 1.2 1.2 95 70-130
2-Hexanone mg/kg 2.5 2.6 105 70-132
4-Chlorotoluene mg/kg 1.2 1.1 90 70-130
4-Methyl-2-pentanone(MIBK) mg/kg 2.5 2.9 117 69-130
Acetone mg/kg 2.5 2.4 97 49-148 1K
Benzene mg/kg 1.2 1.2 94 70-130
Bromobenzene mg/kg 1.2 1.2 94 70-130
Bromochloromethane mg/kg 1.2 1.3 102 70-130
Bromodichloromethane mg/kg 1.2 1.2 96 70-130
Bromoform mg/kg 1.2 1.3 102 68-136
Bromomethane mg/kg 1.2 1.1 87 60-140 1K
Carbon tetrachloride mg/kg 1.2 1.3 106 70-130
Chlorobenzene mg/kg 1.2 1.2 94 70-130
Chloroethane mg/kg 1.2 1.3 103 51-147
Chloroform mg/kg 1.2 1.2 95 70-130
Chloromethane mg/kg 1.2 1.0 81 48-130
cis-1,2-Dichloroethene mg/kg 1.2 1.2 98 70-130
cis-1,3-Dichloropropene mg/kg 1.2 1.4 112 70-130
Dibromochloromethane mg/kg 1.2 1.3 104 70-130
Dibromomethane mg/kg 1.2 1.4 109 70-130
Dichlorodifluoromethane mg/kg 1.2 1.3 106 49-130
Diisopropyl ether mg/kg 1.2 1.2 93 66-130
Ethylbenzene mg/kg 1.2 1.1 88 70-130
Hexachloro-1,3-butadiene mg/kg 1.2 1.1 92 70-130
Isopropylbenzene(Cumene)mg/kg 1.2 1.1 92 70-130
m&p-Xylene mg/kg 2.5 2.3 91 70-130
Methyl-tert-butyl ether mg/kg 1.2 1.2 95 70-130
Methylene Chloride mg/kg 1.2 1.1 86 50-137
n-Butylbenzene mg/kg 1.2 1.1 89 70-130
n-Propylbenzene mg/kg 1.2 1.2 93 70-130
Naphthalene mg/kg 1.2 1.2 96 70-131
o-Xylene mg/kg 1.2 1.2 94 70-130
p-Isopropyltoluene mg/kg 1.2 1.1 88 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 70 of 111
Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2965568
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
sec-Butylbenzene mg/kg 1.2 1.1 89 70-130
Styrene mg/kg 1.2 1.2 99 70-130
tert-Butylbenzene mg/kg 1.2 1.1 86 69-130
Tetrachloroethene mg/kg 1.2 1.2 97 56-130
Toluene mg/kg 1.2 1.3 105 70-130
trans-1,2-Dichloroethene mg/kg 1.2 1.2 98 70-130
trans-1,3-Dichloropropene mg/kg 1.2 1.4 109 70-130
Trichloroethene mg/kg 1.2 1.3 101 70-141
Trichlorofluoromethane mg/kg 1.2 1.2 97 67-130
Vinyl acetate mg/kg 2.5 2.3 93 10-136
Vinyl chloride mg/kg 1.2 1.2 95 67-130
Xylene(Total) mg/kg 3.8 3.5 92 70-130
1,2-Dichloroethane-d4(S) 95 70-132
4-Bromofluorobenzene(S) 100 70-130
Toluene-d8(S)114 70-130
MATRIX SPIKE SAMPLE: 2965570
92489692002 Spike MS MS Rec
Parameter Units Result Conc. Result Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane mg/kg ND 0.39 0.42 109 52-133
1,1,1-Trichloroethane mg/kg ND 0.39 0.45 116 49-137
1,1,2,2-Tetrachloroethane mg/kg ND 0.39 0.37 96 39-150
1,1,2-Trichloroethane mg/kg ND 0.39 0.42 107 48-140
1,1-Dichloroethane mg/kg ND 0.39 0.42 109 46-135
1,1-Dichloroethene mg/kg ND 0.39 0.37 95 38-149
1,1-Dichloropropene mg/kg ND 0.39 0.46 118 41-140
1,2,3-Trichlorobenzene mg/kg ND 0.39 0.39 99 10-158
1,2,3-Trichloropropane mg/kg ND 0.39 0.38 96 33-157
1,2,4-Trichlorobenzene mg/kg ND 0.39 0.40 102 10-155
1,2,4-Trimethylbenzene mg/kg ND 0.39 0.39 101 24-154
1,2-Dibromo-3-chloropropane mg/kg ND 0.39 0.36 92 33-158
1,2-Dibromoethane(EDB) mg/kg ND 0.39 0.40 102 40-136
1,2-Dichlorobenzene mg/kg ND 0.39 0.38 99 27-146
1,2-Dichloroethane mg/kg ND 0.39 0.43 110 49-140
1,2-Dichloropropane mg/kg ND 0.39 0.40 102 44-143
1,3,5-Trimethylbenzene mg/kg ND 0.39 0.39 101 40-144
1,3-Dichlorobenzene mg/kg ND 0.39 0.39 101 33-140
1,3-Dichloropropane mg/kg ND 0.39 0.46 119 47-147
1,4-Dichlorobenzene mg/kg ND 0.39 0.39 99 35-139
2,2-Dichloropropane mg/kg ND 0.39 0.37 95 41-140
2-Butanone(MEK) mg/kg ND 0.78 0.57 73 10-181
2-Chlorotoluene mg/kg ND 0.39 0.40 101 38-147
2-Hexanone mg/kg ND 0.78 0.60 77 18-169
4-Chlorotoluene mg/kg ND 0.39 0.39 101 36-145
4-Methyl-2-pentanone(MIBK) mg/kg ND 0.78 0.77 98 16-175
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 71 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
MATRIX SPIKE SAMPLE: 2965570
92489692002 Spike MS MS Rec
Parameter Units Result Conc. Result Rec Limits Qualifiers
Acetone mg/kg ND 0.78 0.55 70 10-200 1K
Benzene mg/kg ND 0.39 0.41 105 46-136
Bromobenzene mg/kg ND 0.39 0.40 101 38-149
Bromochloromethane mg/kg ND 0.39 0.45 115 44-142
Bromodichloromethane mg/kg ND 0.39 0.38 98 41-140
Bromoform mg/kg ND 0.39 0.39 100 34-145
Bromomethane mg/kg ND 0.39 0.43 111 14-162 1K
Carbon tetrachloride mg/kg ND 0.39 0.47 121 44-141
Chlorobenzene mg/kg ND 0.39 0.40 102 39-141
Chloroethane mg/kg ND 0.39 0.21 54 10-182
Chloroform mg/kg ND 0.39 0.42 108 45-140
Chloromethane mg/kg ND 0.39 0.39 101 19-149
cis-1,2-Dichloroethene mg/kg ND 0.39 0.42 108 38-150
cis-1,3-Dichloropropene mg/kg ND 0.39 0.41 106 30-144
Dibromochloromethane mg/kg ND 0.39 0.43 109 36-145
Dibromomethane mg/kg ND 0.39 0.44 114 41-145
Dichlorodifluoromethane mg/kg ND 0.39 0.51 130 16-146
Diisopropyl ether mg/kg ND 0.39 0.40 101 41-143
Ethylbenzene mg/kg ND 0.39 0.39 99 35-144
Hexachloro-1,3-butadiene mg/kg ND 0.39 0.42 108 10-160
Isopropylbenzene(Cumene)mg/kg ND 0.39 0.41 105 30-152
m&p-Xylene mg/kg ND 0.78 0.80 103 33-145
Methyl-tert-butyl ether mg/kg ND 0.39 0.41 104 49-140
Methylene Chloride mg/kg ND 0.39 0.38 98 10-174
n-Butylbenzene mg/kg ND 0.39 0.40 102 10-160
n-Propylbenzene mg/kg ND 0.39 0.40 102 24-159
Naphthalene mg/kg ND 0.39 0.41 105 10-171
o-Xylene mg/kg ND 0.39 0.40 102 31-150
p-lsopropyltoluene mg/kg ND 0.39 0.39 100 21-154
sec-Butylbenzene mg/kg ND 0.39 0.40 101 19-159
Styrene mg/kg ND 0.39 0.41 104 15-152
tert-Butylbenzene mg/kg ND 0.39 0.39 100 31-141
Tetrachloroethene mg/kg ND 0.39 0.43 109 19-141
Toluene mg/kg 3.4J ug/kg 0.39 0.40 102 31-146
trans-1,2-Dichloroethene mg/kg ND 0.39 0.45 115 28-157
trans-1,3-Dichloropropene mg/kg ND 0.39 0.38 98 25-146
Trichloroethene mg/kg ND 0.39 0.45 114 34-149
Trichlorofluoromethane mg/kg ND 0.39 0.17 43 10-167
Vinyl acetate mg/kg ND 0.78 0.65 83 10-200
Vinyl chloride mg/kg ND 0.39 0.47 121 36-155
Xylene(Total) mg/kg ND 1.2 1.2 102 29-148
1,2-Dichloroethane-d4(S) 112 70-132
4-Bromofluorobenzene(S) 102 70-130
Toluene-d8(S)101 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 72 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
SAMPLE DUPLICATE: 2965569
92489692001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
1,1,1,2-Tetrachloroethane mg/kg ND ND 30
1,1,1-Trichloroethane mg/kg ND ND 30
1,1,2,2-Tetrachloroethane mg/kg ND ND 30
1,1,2-Trichloroethane mg/kg ND ND 30
1,1-Dichloroethane mg/kg ND ND 30
1,1-Dichloroethene mg/kg ND ND 30
1,1-Dichloropropene mg/kg ND ND 30
1 2 3-Trichlorobenzene mg/kg ND ND 3099
1,2,3-Trichloropropane mg/kg ND ND 30
1,2,4-Trichlorobenzene mg/kg ND ND 30
1,2,4-Trimethylbenzene mg/kg ND ND 30
1,2-Dibromo-3-chloropropane mg/kg ND ND 30
1,2-Dibromoethane(EDB) mg/kg ND ND 30
1,2-Dichlorobenzene mg/kg ND ND 30
1,2-Dichloroethane mg/kg ND ND 30
1,2-Dichloropropane mg/kg ND ND 30
1,3,5-Trimethylbenzene mg/kg ND ND 30
1,3-Dichlorobenzene mg/kg ND ND 30
1,3-Dichloropropane mg/kg ND ND 30
1,4-Dichlorobenzene mg/kg ND ND 30
2,2-Dichloropropane mg/kg ND ND 30
2-Butanone(MEK) mg/kg ND ND 30
2-Chlorotoluene mg/kg ND ND 30
2-Hexanone mg/kg ND ND 30
4-Chlorotoluene mg/kg ND ND 30
4-Methyl-2-pentanone(MIBK) mg/kg ND ND 30
Acetone mg/kg ND ND 30 1K
Benzene mg/kg ND ND 30
Bromobenzene mg/kg ND ND 30
Bromochloromethane mg/kg ND ND 30
Bromodichloromethane mg/kg ND ND 30
Bromoform mg/kg ND ND 30
Bromomethane mg/kg ND ND 30 IK
Carbon tetrachloride mg/kg ND ND 30
Chlorobenzene mg/kg ND ND 30
Chloroethane mg/kg ND ND 30
Chloroform mg/kg ND ND 30
Chloromethane mg/kg ND ND 30
cis-1,2-Dichloroethene mg/kg ND ND 30
cis-1,3-Dichloropropene mg/kg ND ND 30
Dibromochloromethane mg/kg ND ND 30
Dibromomethane mg/kg ND ND 30
Dichlorodifluoromethane mg/kg ND ND 30
Diisopropyl ether mg/kg ND ND 30
Ethylbenzene mg/kg ND ND 30
Hexachloro-1,3-butadiene mg/kg ND ND 30
Isopropylbenzene(Cumene)mg/kg ND ND 30
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 73 of 111
Pace Analytical Services,LLC
CB /I n/,,}'G,a'` 9800 Ki ncey Ave. Suite 100
li A ly Huntersville,NC 28078
www.pacelabs.com 704)875-9092
I
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
SAMPLE DUPLICATE: 2965569
92489692001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
m&p-Xylene mg/kg ND ND 30
Methyl-tert-butyl ether mg/kg ND ND 30
Methylene Chloride mg/kg ND ND 30
n-Butylbenzene mg/kg ND ND 30
n-Propylbenzene mg/kg ND ND 30
Naphthalene mg/kg ND ND 30
o-Xylene mg/kg ND ND 30
p-Isopropyltoluene mg/kg ND ND 30
sec-Butylbenzene mg/kg ND ND 30
Styrene mg/kg ND ND 30
tert-Butylbenzene mg/kg ND ND 30
Tetrachloroethene mg/kg ND ND 30
Toluene mg/kg 4.2 ug/kg 0.0050 16 30
trans-1,2-Dichloroethene mg/kg ND ND 30
trans-1,3-Dichloropropene mg/kg ND ND 30
Trichloroethene mg/kg ND ND 30
Trichlorofluoromethane mg/kg ND ND 30
Vinyl acetate mg/kg ND ND 30
Vinyl chloride mg/kg ND ND 30
Xylene(Total) mg/kg ND ND 30
1,2-Dichloroethane-d4(S) 101 105
4-Bromofluorobenzene(S) 103 87
Toluene-d8(S)100 101
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 74 of 111
Pace Analytical Services,LLC
12ce Analytical
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
j
078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 559241 Analysis Method: EPA 8260D
QC Batch Method: EPA 5035A/5030B Analysis Description: 8260D 5035A 5030E
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92489806005
METHOD BLANK: 2967391 Matrix: Solid
Associated Lab Samples: 92489806005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 0.0033 08/11/20 12:45
1,1,1-Trichloroethane mg/kg ND 0.0050 0.0020 08/11/20 12:45
1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 0.0044 08/11/20 12:45
1,1,2-Trichloroethane mg/kg ND 0.0050 0.0037 08/11/20 12:45
1,1-Dichloroethane mg/kg ND 0.0050 0.0022 08/11/20 12:45
1,1-Dichloroethene mg/kg ND 0.0050 0.0016 08/11/20 12:45
1,1-Dichloropropene mg/kg ND 0.0050 0.0024 08/11/20 12:45
1,2,3-Trichlorobenzene mg/kg ND 0.0050 0.0031 08/11/20 12:45
1,2,3-Trichloropropane mg/kg ND 0.0050 0.0041 08/11/20 12:45
1,2,4-Trichlorobenzene mg/kg ND 0.0050 0.0028 08/11/20 12:45
1,2,4-Trimethylbenzene mg/kg ND 0.0050 0.0036 08/11/20 12:45
1,2-Dibromo-3-chloropropane mg/kg ND 0.0050 0.0046 08/11/20 12:45
1,2-Dibromoethane(EDB) mg/kg ND 0.0050 0.0035 08/11/20 12:45
1,2-Dichlorobenzene mg/kg ND 0.0050 0.0030 08/11/20 12:45
1,2-Dichloroethane mg/kg ND 0.0050 0.0020 08/11/20 12:45
1,2-Dichloropropane mg/kg ND 0.0050 0.0031 08/11/20 12:45
1,3,5-Trimethylbenzene mg/kg ND 0.0050 0.0030 08/11/20 12:45
1,3-Dichlorobenzene mg/kg ND 0.0050 0.0041 08/11/20 12:45
1,3-Dichloropropane mg/kg ND 0.0050 0.0035 08/11/20 12:45
1,4-Dichlorobenzene mg/kg ND 0.0050 0.0038 08/11/20 12:45
2,2-Dichloropropane mg/kg ND 0.0050 0.0028 08/11/20 12:45
2-Butanone(MEK) mg/kg ND 0.10 0.042 08/11/20 12:45
2-Chlorotoluene mg/kg ND 0.0050 0.0036 08/11/20 12:45
2-Hexanone mg/kg ND 0.050 0.0099 08/11/20 12:45
4-Chlorotoluene mg/kg ND 0.0050 0.0032 08/11/20 12:45
4-Methyl-2-pentanone(MIBK) mg/kg ND 0.050 0.042 08/11/20 12:45
Acetone mg/kg ND 0.10 0.037 08/11/20 12:45 IK
Benzene mg/kg ND 0.0050 0.0035 08/11/20 12:45
Bromobenzene mg/kg ND 0.0050 0.0034 08/11/20 12:45
Bromochloromethane mg/kg ND 0.0050 0.0038 08/11/20 12:45
Bromodichloromethane mg/kg ND 0.0050 0.0033 08/11/20 12:45
Bromoform mg/kg ND 0.0050 0.0027 08/11/20 12:45
Bromomethane mg/kg ND 0.010 0.0079 08/11/20 12:45 IK
Carbon tetrachloride mg/kg ND 0.0050 0.0022 08/11/20 12:45
Chlorobenzene mg/kg ND 0.0050 0.0032 08/11/20 12:45
Chloroethane mg/kg ND 0.010 0.0053 08/11/20 12:45
Chloroform mg/kg ND 0.0050 0.0025 08/11/20 12:45
Chloromethane mg/kg ND 0.010 0.0070 08/11/20 12:45
cis-1,2-Dichloroethene mg/kg ND 0.0050 0.0029 08/11/20 12:45
cis-1,3-Dichloropropene mg/kg ND 0.0050 0.0032 08/11/20 12:45
Results presented on this page are in the units indicated by the''Unite column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 75 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 KinceyAve. Suite 100
Huntersville,NC 28078
www.pacelabs.corn 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
METHOD BLANK: 2967391 Matrix: Solid
Associated Lab Samples: 92489806005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Dibromochloromethane mg/kg ND 0.0050 0.0027 08/11/20 12:45
Dibromomethane mg/kg ND 0.0050 0.0025 08/11/20 12:45
Dichlorodifluoromethane mg/kg ND 0.010 0.0017 08/11/20 12:45
Diisopropyl ether mg/kg ND 0.0050 0.0020 08/11/20 12:45
Ethylbenzene mg/kg ND 0.0050 0.0047 08/11/20 12:45
Hexachloro-1,3-butadiene mg/kg ND 0.0050 0.0047 08/11/20 12:45
Isopropylbenzene(Cumene)mg/kg ND 0.0050 0.0032 08/11/20 12:45
m&p-Xylene mg/kg ND 0.010 0.0077 08/11/20 12:45
Methyl-tert-butyl ether mg/kg ND 0.0050 0.0032 08/11/20 12:45
Methylene Chloride mg/kg ND 0.020 0.0074 08/11/20 12:45
n-Butylbenzene mg/kg ND 0.0050 0.0027 08/11/20 12:45
n-Propylbenzene mg/kg ND 0.0050 0.0034 08/11/20 12:45
Naphthalene mg/kg ND 0.0050 0.0028 08/11/20 12:45
o-Xylene mg/kg ND 0.0050 0.0028 08/11/20 12:45
p-Isopropyltoluene mg/kg ND 0.0050 0.0028 08/11/20 12:45
sec-Butylbenzene mg/kg ND 0.0050 0.0032 08/11/20 12:45
Styrene mg/kg ND 0.0050 0.0024 08/11/20 12:45
tert-Butylbenzene mg/kg ND 0.0050 0.0027 08/11/20 12:45
Tetrachloroethene mg/kg ND 0.0050 0.0025 08/11/20 12:45
Toluene mg/kg ND 0.0050 0.0029 08/11/20 12:45
trans-1,2-Dichloroethene mg/kg ND 0.0050 0.0022 08/11/20 12:45
trans-1,3-Dichloropropene mg/kg ND 0.0050 0.0042 08/11/20 12:45
Trichloroethene mg/kg ND 0.0050 0.0031 08/11/20 12:45
Trichlorofluoromethane mg/kg ND 0.0050 0.0012 08/11/20 12:45
Vinyl acetate mg/kg ND 0.050 0.0043 08/11/20 12:45
Vinyl chloride mg/kg ND 0.010 0.0019 08/11/20 12:45
Xylene(Total) mg/kg ND 0.010 0.0028 08/11/20 12:45
1,2-Dichloroethane-d4(S) 104 70-132 08/11/20 12:45
4-Bromofluorobenzene(S) 102 70-130 08/11/20 12:45
Toluene-d8(S)107 70-130 08/11/20 12:45
LABORATORY CONTROL SAMPLE: 2967392
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane mg/kg 1.2 1.1 90 70-130
1,1,1-Trichloroethane mg/kg 1.2 1.2 96 70-130
1,1,2,2-Tetrachloroethane mg/kg 1.2 1.1 86 55-130
1,1,2-Trichloroethane mg/kg 1.2 0.97 77 70-130
1,1-Dichloroethane mg/kg 1.2 1.2 93 68-130
1,1-Dichloroethene mg/kg 1.2 1.3 104 70-130
1,1-Dichloropropene mg/kg 1.2 1.2 97 70-130
1,2,3-Trichlorobenzene mg/kg 1.2 1.0 82 70-130
1,2,3-Trichloropropane mg/kg 1.2 1.1 89 70-130
1,2,4-Trichlorobenzene mg/kg 1.2 1.1 84 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 76 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.caa 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2967392
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,2,4-Trimethylbenzene mg/kg 1.2 0.98 78 69-130
1,2-Dibromo-3-chloropropane mg/kg 1.2 1.2 94 57-141
1,2-Dibromoethane(EDB) mg/kg 1.2 1.1 89 70-130
1,2-Dichlorobenzene mg/kg 1.2 1.0 83 70-130
1,2-Dichloroethane mg/kg 1.2 1.1 85 70-130
1,2-Dichloropropane mg/kg 1.2 1.1 90 70-130
1,3,5-Trimethylbenzene mg/kg 1.2 1.0 83 70-130
1,3-Dichlorobenzene mg/kg 1.2 1.1 84 70-130
1,3-Dichloropropane mg/kg 1.2 1.1 87 70-130
1,4-Dichlorobenzene mg/kg 1.2 1.0 81 70-130
2,2-Dichloropropane mg/kg 1.2 1.1 90 70-130
2-Butanone(MEK) mg/kg 2.5 2.4 97 60-130
2-Chlorotoluene mg/kg 1.2 1.1 85 70-130
2-Hexanone mg/kg 2.5 2.3 90 70-132
4-Chlorotoluene mg/kg 1.2 1.0 84 70-130
4-Methyl-2-pentanone(MIBK) mg/kg 2.5 2.0 79 69-130
Acetone mg/kg 2.5 2.5 101 49-148 1K
Benzene mg/kg 1.2 1.1 90 70-130
Bromobenzene mg/kg 1.2 1.1 85 70-130
Bromochloromethane mg/kg 1.2 1.2 97 70-130
Bromodichloromethane mg/kg 1.2 1.1 85 70-130
Bromoform mg/kg 1.2 1.2 92 68-136
Bromomethane mg/kg 1.2 1.0 81 60-140 IK
Carbon tetrachloride mg/kg 1.2 1.3 101 70-130
Chlorobenzene mg/kg 1.2 1.0 83 70-130
Chloroethane mg/kg 1.2 1.2 99 51-147
Chloroform mg/kg 1.2 1.1 91 70-130
Chloromethane mg/kg 1.2 0.90 72 48-130
cis-1,2-Dichloroethene mg/kg 1.2 1.2 93 70-130
cis-1,3-Dichloropropene mg/kg 1.2 1.2 95 70-130
Dibromochloromethane mg/kg 1.2 1.1 92 70-130
Dibromomethane mg/kg 1.2 1.2 99 70-130
Dichlorodifluoromethane mg/kg 1.2 1.2 95 49-130
Diisopropyl ether mg/kg 1.2 1.1 89 66-130
Ethylbenzene mg/kg 1.2 0.98 78 70-130
Hexachloro-1,3-butadiene mg/kg 1.2 1.1 86 70-130
Isopropylbenzene(Cumene)mg/kg 1.2 1.1 84 70-130
m&p-Xylene mg/kg 2.5 2.1 83 70-130
Methyl-tert-butyl ether mg/kg 1.2 1.1 91 70-130
Methylene Chloride mg/kg 1.2 1.2 92 50-137
n-Butylbenzene mg/kg 1.2 1.0 82 70-130
n-Propylbenzene mg/kg 1.2 1.0 84 70-130
Naphthalene mg/kg 1.2 1.1 87 70-131
o-Xylene mg/kg 1.2 1.1 85 70-130
p-Isopropyltoluene mg/kg 1.2 1.0 80 70-130
sec-Butylbenzene mg/kg 1.2 1.0 82 70-130
Styrene mg/kg 1.2 1.1 90 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 77 of 111
Pace Analytical Services,LLCceAnalytical9800KinceyAve. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092r
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2967392
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
tert-Butylbenzene mg/kg 1.2 1.0 81 69-130
Tetrachloroethene mg/kg 1.2 1.1 88 56-130
Toluene mg/kg 1.2 1.1 87 70-130
trans-1,2-Dichloroethene mg/kg 1.2 1.2 96 70-130
trans-1,3-Dichloropropene mg/kg 1.2 0.96 77 70-130
Trichloroethene mg/kg 1.2 1.2 95 70-141
Trichlorofluoromethane mg/kg 1.2 1.1 88 67-130
Vinyl acetate mg/kg 2.5 2.2 90 10-136
Vinyl chloride mg/kg 1.2 1.1 86 67-130
Xylene(Total) mg/kg 3.8 3.1 84 70-130
1,2-Dichloroethane-d4(S) 96 70-132
4-Bromofluorobenzene(S) 100 70-130
Toluene-d8(S)101 70-130
MATRIX SPIKE SAMPLE: 2967394
92489862002 Spike MS MS Rec
Parameter Units Result Conc. Result Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane mg/kg ND 0.29 0.27 94 52-133
1,1,1-Trichloroethane mg/kg ND 0.29 0.27 94 49-137
1,1,2,2-Tetrachloroethane mg/kg ND 0.29 0.25 87 39-150
1,1,2-Trichloroethane mg/kg ND 0.29 0.26 92 48-140
1,1-Dichloroethane mg/kg ND 0.29 0.26 91 46-135
1,1-Dichloroethene mg/kg ND 0.29 0.26 92 38-149
1,1-Dichloropropene mg/kg ND 0.29 0.28 97 41-140
1,2,3-Trichlorobenzene mg/kg ND 0.29 0.26 91 10-158
1,2,3-Trichloropropane mg/kg ND 0.29 0.26 90 33-157
1,2,4-Trichlorobenzene mg/kg ND 0.29 0.27 93 10-155
1,2,4-Trimethylbenzene mg/kg ND 0.29 0.26 91 24-154
1,2-Dibromo-3-chloropropane mg/kg ND 0.29 0.24 84 33-158
1,2-Dibromoethane(EDB) mg/kg ND 0.29 0.26 91 40-136
1,2-Dichlorobenzene mg/kg ND 0.29 0.26 91 27-146
1,2-Dichloroethane mg/kg ND 0.29 0.26 92 49-140
1,2-Dichloropropane mg/kg ND 0.29 0.26 91 44-143
1 1,3,5-Trimethylbenzene mg/kg ND 0.29 0.27 93 40-144
1,3-Dichlorobenzene mg/kg ND 0.29 0.27 95 33-140
1,3-Dichloropropane mg/kg ND 0.29 0.27 93 47-147
1,4-Dichlorobenzene mg/kg ND 0.29 0.26 92 35-139
2,2-Dichloropropane mg/kg ND 0.29 0.23 81 41-140
2-Butanone(MEK) mg/kg ND 0.58 0.40 69 10-181
2-Chlorotoluene mg/kg • ND 0.29 0.27 94 38-147
2-Hexanone mg/kg ND 0.58 0.49 86 18-169
4-Chlorotoluene mg/kg ND 0.29 0.27 94 36-145
4-Methyl-2-pentanone(MIBK) mg/kg ND 0.58 0.52 90 16-175
Acetone mg/kg ND 0.58 0.35 62 10-200 1K
Benzene mg/kg ND 0.29 0.26 92 46-136
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 78 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelaba.eom 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
MATRIX SPIKE SAMPLE: 2967394
92489862002 Spike MS MS Rec
Parameter Units Result Conc. Result Rec Limits Qualifiers
Bromobenzene mg/kg ND 0.29 0.27 93 38-149
Bromochloromethane mg/kg ND 0.29 0.27 95 44-142
Bromodichloromethane mg/kg ND 0.29 0.25 87 41-140
Bromoform mg/kg ND 0.29 0.26 89 34-145
Bromomethane mg/kg ND 0.29 0.21 74 14-162 IK
Carbon tetrachloride mg/kg ND 0.29 0.29 102 44-141
Chlorobenzene mg/kg ND 0.29 0.26 92 39-141
Chloroethane mg/kg ND 0.29 0.11 37 10-182
Chloroform mg/kg ND 0.29 0.26 89 45-140
Chloromethane mg/kg ND 0.29 0.21 75 19-149
cis-1,2-Dichloroethene mg/kg ND 0.29 0.27 93 38-150
cis-1,3-Dichloropropene mg/kg ND 0.29 0.27 93 30-144
Dibromochloromethane mg/kg ND 0.29 0.26 91 36-145
Dibromomethane mg/kg ND 0.29 0.28 96 41-145
Dichlorodifluoromethane mg/kg ND 0.29 0.26 92 16-146
Diisopropyl ether mg/kg ND 0.29 0.25 86 41-143
Ethylbenzene mg/kg ND 0.29 0.25 87 35-144
1
Hexachloro-1,3-butadiene mg/kg ND 0.29 0.27 95 10-160
lsopropylbenzene(Cumene)mg/kg ND 0.29 0.27 95 30-152
m&p-Xylene mg/kg ND 0.58 0.53 92 33-145
Methyl-tert-butyl ether mg/kg ND 0.29 0.25 86 49-140
Methylene Chloride mg/kg ND 0.29 0.24 83 10-174
n-Butylbenzene mg/kg ND 0.29 0.27 94 10-160
n-Propylbenzene mg/kg ND 0.29 0.27 96 24-159
Naphthalene mg/kg ND 0.29 0.27 94 10-171
o-Xylene mg/kg ND 0.29 0.26 91 31-150
p-Isopropyltoluene mg/kg ND 0.29 0.26 90 21-154
sec-Butylbenzene mg/kg ND 0.29 0.28 96 19-159
Styrene mg/kg ND 0.29 0.27 94 15-152
tert-Butylbenzene mg/kg ND 0.29 0.26 91 31-141
Tetrachloroethene mg/kg 2.8J ug/kg 0.29 0.29 99 19-141
Toluene mg/kg 2.5J ug/kg 0.29 0.26 90 31-146
trans-1,2-Dichloroethene mg/kg ND 0.29 0.27 95 28-157
trans-1,3-Dichloropropene mg/kg ND 0.29 0.25 87 25-146
Trichloroethene mg/kg ND 0.29 0.29 99 34-149
Trichlorofluoromethane mg/kg ND 0.29 0.091 32 10-167
Vinyl acetate mg/kg ND 0.58 0.42 74 10-200
Vinyl chloride mg/kg ND 0.29 0.25 88 36-155
Xylene(Total) mg/kg ND 0.86 0.79 92 29-148
1,2-Dichloroethane-d4(S) 108 70-132
4-Bromofluorobenzene(S) 100 70-130
Toluene-d8(S)98 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 79 of 111
Pace Analytical Services,LLC
ace Analytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com
704)875-9092
i
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
SAMPLE DUPLICATE: 2967393
92489862001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
1,1,1,2-Tetrachloroethane mg/kg ND ND 30
1,1,1-Trichloroethane mg/kg ND ND 30
1,1,2,2-Tetrachloroethane mg/kg ND ND 30
1,1,2-Trichloroethane mg/kg ND ND 30
1,1-Dichloroethane mg/kg ND ND 30
1,1-Dichloroethene mg/kg ND ND 30
1,1-Dichloropropene mg/kg ND ND 30
1,2,3-Trichlorobenzene mg/kg ND ND 30
1,2,3-Trichloropropane mg/kg ND ND 30
1,2,4-Trichlorobenzene mg/kg ND ND 30
1,2,4-Trimethylbenzene mg/kg 2.0J ug/kg ND 30
1,2-Dibromo-3-chloropropane mg/kg ND ND 30
1,2-Dibromoethane(EDB) mg/kg ND ND 30
1,2-Dichlorobenzene mg/kg ND ND 30
1,2-Dichloroethane mg/kg ND ND 30
1,2-Dichloropropane mg/kg ND ND 30
1,3,5-Trimethylbenzene mg/kg ND ND 30
1,3-Dichlorobenzene mg/kg ND ND 30
1,3-Dichloropropane mg/kg ND ND 30
1,4-Dichlorobenzene mg/kg ND ND 30
2,2-Dichloropropane mg/kg ND ND 30
2-Butanone(MEK) mg/kg ND ND 30
2-Chlorotoluene mg/kg ND ND 30
2-Hexanone mg/kg ND ND 30
4-Chlorotoluene mg/kg ND ND 30
4-Methyl-2-pentanone(MIBK) mg/kg ND ND 30
Acetone mg/kg ND ND 30 1K
Benzene mg/kg ND ND 30
Bromobenzene mg/kg ND ND 30
Bromochloromethane mg/kg ND ND 30
Bromodichloromethane mg/kg ND ND 30
Bromoform mg/kg ND ND 30
Bromomethane mg/kg ND ND 30 1K
Carbon tetrachloride mg/kg ND ND 30
Chlorobenzene mg/kg ND ND 30
Chloroethane mg/kg ND ND 30
Chloroform mg/kg ND ND 30
Chloromethane mg/kg ND ND 30
cis-1,2-Dichloroethene mg/kg ND ND 30
cis-1,3-Dichloropropene mg/kg ND ND 30
Dibromochloromethane mg/kg ND ND 30
Dibromomethane mg/kg ND ND 30
Dichlorodifluoromethane mg/kg ND ND 30
Diisopropyl ether mg/kg ND ND 30
Ethylbenzene mg/kg ND ND 30
Hexachloro-1,3-butadiene mg/kg ND ND 30
Isopropylbenzene(Cumene)mg/kg ND ND 30
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 80 of 111
Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelaba.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
SAMPLE DUPLICATE: 2967393
92489862001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
m&p-Xylene mg/kg ND ND 30
Methyl-tert-butyl ether mg/kg ND ND 30
Methylene Chloride mg/kg ND ND 30
n-Butylbenzene mg/kg ND ND 30
n-Propylbenzene mg/kg ND ND 30
Naphthalene mg/kg ND ND 30
o-Xylene mg/kg ND ND 30
p-Isopropyltoluene mg/kg ND ND 30
sec-Butylbenzene mg/kg ND ND 30
Styrene mg/kg ND ND 30
tert-Butylbenzene mg/kg ND ND 30
Tetrachloroethene mg/kg ND ND 30
Toluene mg/kg 2.7 ug/kg 0.0024J 30
trans-1,2-Dichloroethene mg/kg ND ND 30
trans-1,3-Dichloropropene mg/kg ND ND 30
Trichloroethene mg/kg ND ND 30
Trichlorofluoromethane mg/kg ND ND 30
Vinyl acetate mg/kg ND ND 30
Vinyl chloride mg/kg ND ND 30
Xylene(Total) mg/kg ND ND 30
1,2-Dichloroethane-d4(S) 104 101
4-Bromofluorobenzene(S) 102 101
Toluene-d8(S)102 100
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 81 of 111
Pace Analytical Services,LLC
aceAnalytical
9800 KinceyAve. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 559313 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92489806018,92489806019,92489806020,92489806021
METHOD BLANK: 2967659 Matrix: Water
Associated Lab Samples: 92489806018,92489806019,92489806020,92489806021
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 08/11/20 18:15
1,1,1-Trichloroethane ug/L ND 1.0 0.18 08/11/20 18:15
1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 08/11/20 18:15
1,1,2-Trichloroethane ug/L ND 1.0 0.24 08/11/20 18:15
1,1-Dichloroethane ug/L ND 1.0 0.27 08/11/20 18:15
1,1-Dichloroethene ug/L ND 1.0 0.24 08/11/20 18:15
1,1-Dichloropropene ug/L ND 1.0 0.21 08/11/20 18:15
1,2,3-Trichlorobenzene ug/L ND 1.0 0.34 08/11/20 18:15
1,2,3-Trichloropropane ug/L ND 1.0 0.35 08/11/20 18:15
1,2,4-Trichlorobenzene ug/L ND 1.0 0.22 08/11/20 18:15
1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 08/11/20 18:15
1,2-Dibromoethane(EDB) ug/L ND 1.0 0.26 08/11/20 18:15
1,2-Dichlorobenzene ug/L ND 1.0 0.29 08/11/20 18:15
1,2-Dichloroethane ug/L ND 1.0 0.34 08/11/20 18:15
1,2-Dichloropropane ug/L ND 1.0 0.19 08/11/20 18:15
1,3-Dichlorobenzene ug/L ND 1.0 0.22 08/11/20 18:15
1,3-Dichloropropane ug/L ND 1.0 0.16 08/11/20 18:15
1,4-Dichlorobenzene ug/L ND 1.0 0.26 08/11/20 18:15
2,2-Dichloropropane ug/L ND 1.0 0.27 08/11/20 18:15
2-Butanone(MEK) ug/L ND 5.0 3.3 08/11/20 18:15
2-Chlorotoluene ug/L ND 1.0 0.20 08/11/20 18:15
2-Hexanone ug/L ND 5.0 0.57 08/11/20 18:15
4-Chlorotoluene ug/L ND 1.0 0.20 08/11/20 18:15
4-Methyl-2-pentanone(MIBK)ug/L ND 5.0 4.5 08/11/20 18:15
Acetone ug/L ND 25.0 6.2 08/11/20 18:15
Benzene ug/L ND 1.0 0.15 08/11/20 18:15
Bromobenzene ug/L ND 1.0 0.22 08/11/20 18:15
Bromochloromethane ug/L ND 1.0 0.34 08/11/20 18:15
Bromodichloromethane ug/L ND 1.0 0.26 08/11/20 18:15
Bromoform ug/L ND 1.0 0.62 08/11/20 18:15
Bromomethane ug/L ND 2.0 0.62 08/11/20 18:15 v2
Carbon tetrachloride ug/L ND 1.0 0.22 08/11/20 18:15
Chlorobenzene ug/L ND 1.0 0.23 08/11/20 18:15
Chloroethane ug/L ND 1.0 0.49 08/11/20 18:15 IK
Chloroform ug/L ND 5.0 2.3 08/11/20 18:15
Chloromethane ug/L ND 1.0 0.39 08/11/20 18:15 v2
cis-1,2-Dichloroethene ug/L ND 1.0 0.29 08/11/20 18:15
cis-1,3-Dichloropropene ug/L ND 1.0 0.30 08/11/20 18:15
Dibromochloromethane ug/L ND 1.0 0.41 08/11/20 18:15
Dibromomethane ug/L ND 1.0 0.46 08/11/20 18:15
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 82 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.cam 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
METHOD BLANK: 2967659 Matrix: Water
Associated Lab Samples: 92489806018,92489806019,92489806020,92489806021
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Dichlorodifluoromethane ug/L ND 1.0 0.23 08/11/20 18:15
Diisopropyl ether ug/L ND 1.0 0.22 08/11/20 18:15
Ethylbenzene ug/L ND 1.0 0.26 08/11/20 18:15
Hexachloro-1,3-butadiene ug/L ND 1.0 0.44 08/11/20 18:15
m&p-Xylene ug/L ND 2.0 0.41 08/11/20 18:15
Methyl-tert-butyl ether ug/L ND 1.0 0.28 08/11/20 18:15
Methylene Chloride ug/L ND 5.0 3.7 08/11/20 18:15
Naphthalene ug/L ND 1.0 0.35 08/11/20 18:15
o-Xylene ug/L ND 1.0 0.22 08/11/20 18:15
p-Isopropyltoluene ug/L ND 1.0 0.21 08/11/20 18:15
Styrene ug/L ND 1.0 0.27 08/11/20 18:15
Tetrachloroethene ug/L ND 1.0 0.16 08/11/20 18:15
Toluene ug/L ND 1.0 0.24 08/11/20 18:15
trans-1,2-Dichloroethene ug/L ND 1.0 0.25 08/11/20 18:15
trans-1,3-Dichloropropene ug/L ND 1.0 0.31 08/11/20 18:15
Trichloroethene ug/L ND 1.0 0.22 08/11/20 18:15
Trichlorofluoromethane ug/L ND 1.0 0.31 08/11/20 18:15
Vinyl acetate ug/L ND 2.0 1.4 08/11/20 18:15
Vinyl chloride ug/L ND 1.0 0.24 08/11/20 18:15
Xylene(Total) ug/L ND 1.0 0.63 08/11/20 18:15
1,2-Dichloroethane-d4(S) 103 70-130 08/11/20 18:15
4-Bromofluorobenzene(S) 98 70-130 08/11/20 18:15
Toluene-d8(S) 100 70-130 08/11/20 18:15
LABORATORY CONTROL SAMPLE: 2967660
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane ug/L 50 48.4 97 70-130
1,1,1-Trichloroethane ug/L 50 48.1 96 70-130
1,1,2,2-Tetrachloroethane ug/L 50 47.1 94 70-130
1,1,2-Trichloroethane ug/L 50 47.8 96 70-130
1,1-Dichloroethane ug/L 50 45.5 91 70-130
1,1-Dichloroethene ug/L 50 46.2 92 70-130
1,1-Dichloropropene ug/L 50 44.7 89 70-130
1,2,3-Trichlorobenzene ug/L 50 51.3 103 70-130
1,2,3-Trichloropropane ug/L 50 48.1 96 70-130
1,2,4-Trichlorobenzene ug/L 50 49.0 98 70-130
1,2-Dibromo-3-chloropropane ug/L 50 52.5 105 70-130
1,2-Dibromoethane(EDB) ug/L 50 48.6 97 70-130
1,2-Dichlorobenzene ug/L 50 47.4 95 70-130
1,2-Dichloroethane ug/L 50 45.6 91 70-130
1,2-Dichloropropane ug/L 50 47.1 94 70-130
1,3-Dichlorobenzene ug/L 50 48.8 98 70-130
1,3-Dichloropropane ug/L 50 48.1 96 70-131
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 83 of 111
Pace Analytical Services,LLC
ro4.
9800 Kinsey Ave. Suite 100
aLcAna' ILai Huntersville,NC 28078
www.pacelabs.com
704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2967660
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,4-Dichlorobenzene ug/L 50 47.7 95 70-130
2,2-Dichloropropane ug/L 50 46.3 93 69-130
2-Butanone(MEK) ug/L 100 92.3 92 64-135
2-Chlorotoluene ug/L 50 49.7 99 70-130
2-Hexanone ug/L 100 90.9 91 66-135
4-Chlorotoluene ug/L 50 48.3 97 70-130
4-Methyl-2-pentanone(MIBK)ug/L 100 92.5 93 70-130
Acetone ug/L 100 101 101 61-157
Benzene ug/L 50 45.9 92 70-130
Bromobenzene ug/L 50 47.9 96 70-130
Bromochloromethane ug/L 50 46.6 93 70-130
Bromodichloromethane ug/L 50 45.7 91 70-130
Bromoform ug/L 50 49.8 100 70-130
Bromomethane ug/L 50 38.1 76 38-130 v3
Carbon tetrachloride ug/L 50 47.8 96 70-130
Chlorobenzene ug/L 50 45.3 91 70-130
Chloroethane ug/L 50 47.5 95 37-142 1K
Chloroform ug/L 50 45.9 92 70-130
Chloromethane ug/L 50 32.7 65 48-130 v3
cis-1,2-Dichloroethene ug/L 50 45.5 91 70-130
cis-1,3-Dichloropropene ug/L 50 49.9 100 70-130
Dibromochloromethane ug/L 50 49.7 99 70-130
Dibromomethane ug/L 50 48.0 96 70-130
Dichlorodifluoromethane ug/L 50 41.5 83 53-134
Diisopropyl ether ug/L 50 44.1 88 70-135
Ethylbenzene ug/L 50 45.7 91 70-130
Hexachloro-1,3-butadiene ug/L 50 45.6 91 68-132
m&p-Xylene ug/L 100 92.3 92 70-130
Methyl-tert-butyl ether ug/L 50 47.6 95 70-130
Methylene Chloride ug/L 50 45.1 90 67-132
Naphthalene ug/L 50 54.2 108 70-130
o-Xylene ug/L 50 45.5 91 70-131
p-Isopropyltoluene ug/L 50 47.1 94 70-130
Styrene ug/L 50 48.2 96 70-130
Tetrachloroethene ug/L 50 44.4 89 69-130
Toluene ug/L 50 46.2 92 70-130
trans-1,2-Dichloroethene ug/L 50 46.6 93 70-130
trans-1,3-Dichloropropene ug/L 50 49.0 98 70-130
Trichloroethene ug/L 50 46.1 92 70-130
Trichlorofluoromethane ug/L 50 41.5 83 63-130
Vinyl acetate ug/L 100 94.2 94 55-143
Vinyl chloride ug/L 50 39.2 78 70-131
Xylene(Total) ug/L 150 138 92 70-130
1,2-Dichloroethane-d4(S) 98 70-130
4-Bromofluorobenzene(S) 100 70-130
Toluene-d8(S)98 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 84 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacNsbs.cas 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2967661 2967662
MS MSD
92489806020 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.4 20.0 102 100 73-134 2 30
1,1,1-Trichloroethane ug/L ND 20 20 21.7 21.2 108 106 82-143 2 30
1,1,2,2-Tetrachloroethane ug/L ND 20 20 18.9 19.2 94 96 70-136 2 30
1,1,2-Trichloroethane ug/L ND 20 20 20.2 19.6 101 98 70-135 3 30
1,1-Dichloroethane ug/L ND 20 20 20.4 19.9 102 99 70-139 3 30
1,1-Dichloroethene ug/L ND 20 20 21.8 21.3 109 107 70-154 2 30
1,1-Dichloropropene ug/L ND 20 20 20.9 20.6 104 103 70-149 1 30
1,2,3-Trichlorobenzene ug/L ND 20 20 20.6 18.5 103 93 70-135 11 30
1,2,3-Trichloropropane ug/L ND 20 20 19.0 19.6 95 98 71-137 3 30
1,2,4-Trichlorobenzene ug/L ND 20 20 20.2 19.3 101 96 73-140 5 30
1,2-Dibromo-3- ug/L ND 20 20 20.3 20.2 102 101 65-134 1 30
chloropropane
1,2-Dibromoethane(EDB)ug/L ND 20 20 19.8 19.7 99 98 70-137 1 30
1,2-Dichlorobenzene ug/L ND 20 20 19.6 19.2 98 96 70-133 2 30
1,2-Dichloroethane ug/L ND 20 20 19.6 19.4 98 97 70-137 1 30
1,2-Dichloropropane ug/L ND 20 20 19.6 20.2 98 101 70-140 3 30
1,3-Dichlorobenzene ug/L ND 20 20 19.7 19.6 99 98 70-135 1 30
1,3-Dichloropropane ug/L ND 20 20 19.9 19.6 99 98 70-143 1 30
1,4-Dichlorobenzene ug/L ND 20 20 19.9 19.7 99 99 70-133 1 30
2,2-Dichloropropane ug/L ND 20 20 23.0 22.3 115 112 61-148 3 30
2-Butanone(MEK) ug/L ND 40 40 35.9 36.5 90 91 60-139 2 30
2-Chlorotoluene ug/L ND 20 20 21.0 20.7 105 104 70-144 1 30
2-Hexanone ug/L ND 40 40 36.6 36.7 92 92 65-138 0 30
4-Chlorotoluene ug/L ND 20 20 20.7 20.2 104 101 70-137 2 30
4-Methyl-2-pentanone ug/L ND 40 40 37.2 37.2 93 93 65-135 0 30
MIBK)
Acetone ug/L ND 40 40 40.8 42.0 102 105 60-148 3 30
Benzene ug/L ND 20 20 20.7 19.7 104 99 70-151 5 30
Bromobenzene ug/L ND 20 20 19.9 20.0 99 100 70-136 1 30
Bromochloromethane ug/L ND 20 20 19.6 19.1 98 95 70-141 2 30
Bromodichloromethane ug/L ND 20 20 19.2 18.8 96 94 70-138 2 30
Bromoform ug/L ND 20 20 19.1 19.0 96 95 63-130 1 30
Bromomethane ug/L ND 20 20 21.9 20.4 110 102 15-152 7 30
Carbon tetrachloride ug/L ND 20 20 21.7 21.2 109 106 70-143 3 30
Chlorobenzene ug/L ND 20 20 19.5 19.3 98 97 70-138 1 30
Chloroethane ug/L ND 20 20 27.2 26.1 136 131 52-163 4 30 IK
Chloroform ug/L ND 20 20 20.1 19.6 101 98 70-139 3 30
Chloromethane ug/L ND 20 20 16.4 15.3 82 76 41-139 7 30 v3
cis-1,2-Dichloroethene ug/L ND 20 20 20.2 19.3 101 97 70-141 4 30
cis-1,3-Dichloropropene ug/L ND 20 20 21.5 20.7 107 103 70-137 4 30
Dibromochloromethane ug/L ND 20 20 20.3 19.7 102 98 70-134 3 30
Dibromomethane ug/L ND 20 20 19.4 19.3 97 97 70-138 1 30
Dichlorodifluoromethane ug/L ND 20 20 18.8 18.3 94 92 47-155 3 30
Diisopropyl ether ug/L ND 20 20 18.7 18.4 93 92 63-144 1 30
Ethylbenzene ug/L ND 20 20 20.1 19.9 101 100 66-153 1 30
Hexachloro-1,3-butadiene ug/L ND 20 20 22.7 20.6 113 103 65-149 9 30
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 85 of 111
Pace Analytical Services,LLC
ace Analytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2967661 2967662
MS MSD
92489806020 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
m&p-Xylene ug/L ND 40 40 40.6 40.8 101 102 69-152 1 30
Methyl-tert-butyl ether ug/L ND 20 20 19.7 19.3 98 96 54-156 2 30
Methylene Chloride ug/L ND 20 20 19.8 19.1 99 95 42-159 3 30
Naphthalene ug/L ND 20 20 20.3 18.5 101 93 61-148 9 30
o-Xylene ug/L ND 20 20 19.0 19.4 95 97 70-148 2 30
p-lsopropyltoluene ug/L ND 20 20 21.4 21.0 107 105 70-146 2 30
Styrene ug/L ND 20 20 19.6 19.4 98 97 70-135 1 30
Tetrachloroethene ug/L ND 20 20 19.9 19.7 99 98 59-143 1 30
Toluene ug/L ND 20 20 19.9 19.9 99 99 59-148 0 30
trans-1,2-Dichloroethene ug/L ND 20 20 21.1 20.5 106 103 70-146 3 30
trans-1,3-Dichloropropene ug/L ND 20 20 20.6 20.6 103 103 70-135 0 30
Trichloroethene ug/L ND 20 20 20.5 19.8 102 99 70-147 3 30
Trichlorofluoromethane ug/L ND 20 20 21.7 21.1 108 105 70-148 3 30
Vinyl acetate ug/L ND 40 40 39.6 38.3 99 96 49-151 3 30
Vinyl chloride ug/L ND 20 20 18.4 17.9 92 90 70-156 3 30
Xylene(Total) ug/L ND 60 60 59.6 60.2 99 100 63-158 1 30
1,2-Dichloroethane-d4(S) 101 100 70-130
4-Bromofluorobenzene(S) 96 99 70-130
Toluene-d8(S) 99 98 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 86 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
wrrw.paeelabs.eom 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 559317 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water MSSV RVE
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92489806019,92489806020,92489806021
METHOD BLANK: 2967686 Matrix: Water
Associated Lab Samples: 92489806019,92489806020,92489806021
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 10.0 1.6 08/12/20 23:11
1,2-Dichlorobenzene ug/L ND 10.0 1.4 08/12/20 23:11
1,3-Dichlorobenzene ug/L ND 10.0 1.4 08/12/20 23:11
1,4-Dichlorobenzene ug/L ND 10.0 1.5 08/12/2023:11
1-Methylnaphthalene ug/L ND 10.0 1.4 08/12/20 23:11
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 1.3 08/12/20 23:11
2,4,5-Trichlorophenol ug/L ND 10.0 1.5 08/12/20 23:11
2,4,6-Trichlorophenol ug/L ND 10.0 1.4 08/12/20 23:11
2,4-Dichlorophenol ug/L ND 10.0 1.5 08/12/20 23:11
2,4-Dimethylphenol ug/L ND 10.0 1.5 08/12/20 23:11
2,4-Dinitrophenol ug/L ND 50.0 7.3 08/12/20 23:11
2,4-Dinitrotoluene ug/L ND 10.0 1.7 08/12/20 23:11
2,6-Dinitrotoluene ug/L ND 10.0 1.7 08/12/20 23:11
2-Chloronaphthalene ug/L ND 10.0 1.4 08/12/20 23:11
2-Chlorophenol ug/L ND 10.0 1.4 08/12/20 23:11
2-Methylnaphthalene ug/L ND 10.0 1.4 08/12/20 23:11
2-Methylphenol(o-Cresol) ug/L ND 10.0 1.2 08/12/20 23:11
2-Nitroaniline ug/L ND 20.0 3.0 08/12/20 23:11
2-Nitrophenol ug/L ND 10.0 1.7 08/12/20 23:11
3&4-Methylphenol(m&p Cresol) ug/L ND 10.0 1.2 08/12/20 23:11
3,3'-Dichlorobenzidine ug/L ND 20.0 2.7 08/12/20 23:11
3-Nitroaniline ug/L ND 20.0 2.8 08/12/20 23:11
4,6-Dinitro-2-methylphenol ug/L ND 20.0 4.5 08/12/20 23:11
4-Bromophenylphenyl ether ug/L ND 10.0 1.2 08/12/20 23:11
4-Chloro-3-methylphenol ug/L ND 10.0 2.8 08/12/20 23:11
4-Chloroaniline ug/L ND 20.0 2.8 08/12/20 23:11
4-Chlorophenylphenyl ether ug/L ND 10.0 1.5 08/12/20 23:11
4-Nitroaniline ug/L ND 20.0 3.1 08/12/20 23:11
4-Nitrophenol ug/L ND 50.0 9.4 08/12/20 23:11
Acenaphthene ug/L ND 10.0 1.4 08/12/20 23:11
Acenaphthylene ug/L ND 10.0 1.5 08/12/20 23:11
Aniline ug/L ND 10.0 1.6 08/12/20 23:11
Anthracene ug/L ND 10.0 1.6 08/12/20 23:11
Benzo(a)anthracene ug/L ND 10.0 1.5 08/12/20 23:11
Benzo(a)pyrene ug/L ND 10.0 1.8 08/12/20 23:11
Benzo(b)fluoranthene ug/L ND 10.0 1.7 08/12/20 23:11
Benzo(g,h,i)perylene ug/L ND 10.0 1.6 08/12/20 23:11
Benzo(k)fluoranthene ug/L ND 10.0 1.5 08/12/20 23:11
Benzoic Acid ug/L ND 50.0 19.5 08/12/20 23:11
Benzyl alcohol ug/L ND 20.0 2.6 08/12/20 23:11
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 87 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
i
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
METHOD BLANK: 2967686 Matrix: Water
Associated Lab Samples: 92489806019,92489806020,92489806021
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
bis(2-Chloroethoxy)methane ug/L ND 10.0 1.3 08/12/20 23:11
bis(2-Chloroethyl)ether ug/L ND 10.0 1.7 08/12/20 23:11
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 2.0 08/12/20 23:11
Butylbenzylphthalate ug/L ND 10.0 1.9 08/12/20 23:11
Chrysene ug/L ND 10.0 1.4 08/12/2023:11
Di-n-butylphthalate ug/L ND 10.0 1.6 08/12/20 23:11
Di-n-octylphthalate ug/L ND 10.0 2.2 08/12/20 23:11
Dibenz(a,h)anthracene ug/L ND 10.0 1.6 08/12/20 23:11
Dibenzofuran ug/L ND 10.0 1.3 08/12/20 23:11
Diethylphthalate ug/L ND 10.0 1.6 08/12/20 23:11
Dimethylphthalate ug/L ND 10.0 1.4 08/12/20 23:11
Fluoranthene ug/L ND 10.0 1.6 08/12/20 23:11
Fluorene ug/L ND 10.0 1.4 08/12/2023:11
Hexachloro-1,3-butadiene ug/L ND 10.0 1.6 08/12/20 23:11
Hexachlorobenzene ug/L ND 10.0 1.3 08/12/20 23:11
Hexachlorocyclopentadiene ug/L ND 10.0 2.4 08/12/20 23:11
Hexachloroethane ug/L ND 10.0 1.3 08/12/20 23:11
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 1.7 08/12/20 23:11
Isophorone ug/L ND 10.0 1.3 08/12/20 23:11
N-Nitroso-di-n-propylamine ug/L ND 10.0 1.3 08/12/20 23:11
N-Nitrosodimethylamine ug/L ND 10.0 1.8 08/12/20 23:11
N-Nitrosodiphenylamine ug/L ND 10.0 1.4 08/12/20 23:11
Naphthalene ug/L ND 10.0 1.6 08/12/20 23:11
Nitrobenzene ug/L ND 10.0 1.5 08/12/20 23:11
Pentachlorophenol ug/L ND 20.0 2.8 08/12/20 23:11
Phenanthrene ug/L ND 10.0 1.4 08/12/20 23:11
Phenol ug/L ND 10.0 1.5 08/12/20 23:11
Pyrene ug/L ND 10.0 1.5 08/12/20 23:11
2,4,6-Tribromophenol(S) 36 10-137 08/12/20 23:11
2-Fluorobiphenyl(S) 48 13-130 08/12/20 23:11
2-Fluorophenol(S) 38 10-130 08/12/20 23:11
Nitrobenzene-d5(S) 54 13-130 08/12/20 23:11
Phenol-d6(S)30 10-130 08/12/20 23:11
Terphenyl-d14(S) 76 25-130 08/12/20 23:11
LABORATORY CONTROL SAMPLE: 2967687
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,2,4-Trichlorobenzene ug/L 50 43.9 88 30-130
1,2-Dichlorobenzene ug/L 50 46.0 92 30-130
1,3-Dichlorobenzene ug/L 50 44.2 88 20-130
1,4-Dichlorobenzene ug/L 50 46.4 93 30-130
1-Methylnaphthalene ug/L 50 49.2 98 30-130
2,2'-Oxybis(1-chloropropane) ug/L 50 58.4 117 20-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 88 of 111
Pace Analytical Services,LLC
it 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2967687
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
2,4,5-Trichlorophenol ug/L 50 56.0 112 40-130
2,4,6-Trichlorophenol ug/L 50 55.5 111 40-130
2,4-Dichlorophenol ug/L 50 55.1 110 31-130
2,4-Dimethylphenol ug/L 50 62.0 124 30-130
2,4-Dinitrophenol ug/L 250 178 71 30-130
2,4-Dinitrotoluene ug/L 50 63.1 126 49-130
2,6-Dinitrotoluene ug/L 50 61.6 123 50-130
2-Chloronaphthalene ug/L 50 53.1 106 30-130
2-Chlorophenol ug/L 50 54.1 108 30-130
2-Methylnaphthalene ug/L 50 51.0 102 30-130
2-Methylphenol(o-Cresol) ug/L 50 53.1 106 30-130
2-Nitroaniline ug/L 100 134 134 40-130 L1
2-Nitrophenol ug/L 50 56.8 114 20-130
3&4-Methylphenol(m&p Cresol) ug/L 50 51.4 103 20-130
3,3'-Dichlorobenzidine ug/L 100 128 128 10-150
3-Nitroaniline ug/L 100 127 127 40-130
4,6-Dinitro-2-methylphenol ug/L 100 128 128 40-130
4-Bromophenylphenyl ether ug/L 50 53.8 108 30-130
4-Chloro-3-methylphenol ug/L 100 116 116 30-130
4-Chloroaniline ug/L 100 117 117 20-130
4-Chlorophenylphenyl ether ug/L 50 54.5 109 20-130
4-Nitroaniline ug/L 100 138 138 40-130 L1
4-Nitrophenol ug/L 250 192 77 10-130
Acenaphthene ug/L 50 55.8 112 30-130
Acenaphthylene ug/L 50 56.6 113 30-130
Aniline ug/L 50 50.8 102 20-130
Anthracene ug/L 50 56.5 113 50-130
Benzo(a)anthracene ug/L 50 63.3 127 50-130
Benzo(a)pyrene ug/L 50 65.9 132 50-130 L1
Benzo(b)fluoranthene ug/L 50 66.0 132 50-130 L1
Benzo(g,h,i)perylene ug/L 50 59.1 118 50-130
Benzo(k)fluoranthene ug/L 50 65.8 132 50-130 L1
Benzoic Acid ug/L 250 ND 3 10-130 L2
Benzyl alcohol ug/L 100 112 112 20-130
bis(2-Chloroethoxy)methane ug/L 50 57.6 115 30-130
bis(2-Chloroethyl)ether ug/L 50 57.7 115 30-130
bis(2-Ethylhexyl)phthalate ug/L 50 78.1 156 50-130 L1
Butylbenzylphthalate ug/L 50 78.0 156 50-150 L1
Chrysene ug/L 50 67.2 134 50-130 L1
Di-n-butylphthalate ug/L 50 70.0 140 50-130 L1
Di-n-octylphthalate ug/L 50 75.8 152 50-130 L1
Dibenz(a,h)anthracene ug/L 50 61.9 124 40-130
Dibenzofuran ug/L 50 56.4 113 40-130
Diethylphthalate ug/L 50 63.0 126 40-130
Dimethylphthalate ug/L 50 58.4 117 40-130
Fluoranthene ug/L 50 62.5 125 30-130
Fluorene ug/L 50 57.2 114 20-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 89 of 111
Pace Analytical Services,LLC
ace Analytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2967687
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Hexachloro-1,3-butadiene ug/L 50 38.9 78 10-130
Hexachlorobenzene ug/L 50 52.5 105 30-130
Hexachlorocyclopentadiene ug/L 50 40.6 81 10-150
Hexachloroethane ug/L 50 45.4 91 10-130
Indeno(1,2,3-cd)pyrene ug/L 50 61.9 124 40-130
Isophorone ug/L 50 61.0 122 30-130
N-Nitroso-di-n-propylamine ug/L 50 64.5 129 30-130
N-Nitrosodimethylamine ug/L 50 51.1 102 10-130
N-Nitrosodiphenylamine ug/L 50 62.8 126 30-130
Naphthalene ug/L 50 50.2 100 20-130
Nitrobenzene ug/L 50 58.8 118 20-130
Pentachlorophenol ug/L 100 117 117 10-140
Phenanthrene ug/L 50 61.4 123 50-130
Phenol ug/L 50 34.2 68 10-130
Pyrene ug/L 50 66.6 133 50-130 L1
2,4,6-Tribromophenol(S) 103 10-137
2-Fluorobiphenyl(S) 98 13-130
2-Fluorophenol(S) 76 10-130
Nitrobenzene-d5(S) 109 13-130
Phenol-d6(S)62 10-130
Terphenyl-d14(S) 134 25-130 SO
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2967688 2967689
MS MSD
92489806020 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
1,2,4-Trichlorobenzene ug/L ND 50 50 45.1 44.7 90 89 30-130 1 30
1,2-Dichlorobenzene ug/L ND 50 50 46.3 46.7 93 93 30-130 1 30
1,3-Dichlorobenzene ug/L ND 50 50 44.7 45.0 89 90 20-130 1 30
1,4-Dichlorobenzene ug/L ND 50 50 47.2 47.6 94 95 30-130 1 30
1-Methylnaphthalene ug/L ND 50 50 50.6 47.4 101 95 30-130 6 30
2,2'-Oxybis(1- ug/L ND 50 50 56.7 53.7 113 107 20-130 5 30
chloropropane)
2,4,5-Trichlorophenol ug/L ND 50 50 54.4 50.9 109 102 40-130 7 30
2,4,6-Trichlorophenol ug/L ND 50 50 53.3 47.7 107 95 40-130 11 30
2,4-Dichlorophenol ug/L ND 50 50 53.7 49.2 107 98 31-130 9 30
2,4-Dimethylphenol ug/L ND 50 50 60.1 56.1 120 112 30-130 7 30
2,4-Dinitrophenol ug/L ND 250 250 117 11.8J 47 5 30-130 30 M1
2,4-Dinitrotoluene ug/L ND 50 50 61.8 58.4 124 117 49-130 6 30
2,6-Dinitrotoluene ug/L ND 50 50 59.6 57.3 119 115 50-130 4 30
2-Chloronaphthalene ug/L ND 50 50 52.0 50.4 104 101 30-130 3 30
2-Chlorophenol ug/L ND 50 50 52.0 48.6 104 97 30-130 7 30
2-Methylnaphthalene ug/L ND 50 50 52.6 49.8 105 100 30-130 6 30
2-Methylphenol(o-Cresol) ug/L ND 50 50 50.6 47.0 101 94 30-130 7 30
2-Nitroaniline ug/L ND 100 100 128 122 128 122 40-130 5 30
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 90 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2967688 2967689
MS MSD
92489806020 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
2-Nitrophenol ug/L ND 50 50 56.8 52.0 114 104 20-130 9 30 1
3&4-Methylphenol(m&p ug/L ND 50 50 50.0 46.5 100 93 20-130 7 30
Cresol)
3,3'-Dichlorobenzidine ug/L ND 100 100 123 119 123 119 10-150 3 30
3-Nitroaniline ug/L ND 100 100 123 118 123 118 40-130 4 30
4,6-Dinitro-2-methylphenol ug/L ND 100 100 117 56.7 117 57 40-130 70 30 R1
4-Bromophenylphenyl ether ug/L ND 50 50 50.4 49.4 101 99 30-130 2 30
4-Chloro-3-methylphenol ug/L ND 100 100 116 104 116 104 30-130 10 30
4-Chloroaniline ug/L ND 100 100 101 101 101 101 20-130 0 30
4-Chlorophenylphenyl ether ug/L ND 50 50 50.5 48.9 101 98 20-130 3 30
4-Nitroaniline ug/L ND 100 100 136 126 136 126 40-130 7 30 MO
4-Nitrophenol ug/L ND 250 250 180 71.7 72 29 10-130 86 30 R1
Acenaphthene ug/L ND 50 50 53.7 51.0 107 102 30-130 5 30
Acenaphthylene ug/L ND 50 50 54.7 51.9 109 104 30-130 5 30
Aniline ug/L ND 50 50 41.2 31.8 82 64 20-130 26 30
Anthracene ug/L ND 50 50 53.8 50.8 108 102 50-130 6 30
Benzo(a)anthracene ug/L ND 50 50 61.9 58.2 124 116 50-130 6 30
Benzo(a)pyrene ug/L ND 50 50 64.8 59.2 130 118 50-130 9 30
Benzo(b)fluoranthene ug/L ND 50 50 62.6 58.6 125 117 50-130 7 30
Benzo(g,h,i)perylene ug/L ND 50 50 67.9 58.0 136 116 50-130 16 30 M1
Benzo(k)fluoranthene ug/L ND 50 50 63.2 59.0 126 118 50-130 7 30
Benzoic Acid ug/L ND 250 250 ND ND 2 1 10-130 30 MO
Benzyl alcohol ug/L ND 100 100 108 102 108 102 20-130 6 30
bis(2- ug/L ND 50 50 55.9 51.6 112 103 30-130 8 30
Chloroethoxy)methane
bis(2-Chloroethyl)ether ug/L ND 50 50 58.9 68.5 118 137 30-130 15 30 M1
bis(2-Ethylhexyl)phthalate ug/L ND 50 50 70.0 65.9 140 132 50-130 6 30 MO
Butylbenzylphthalate ug/L ND 50 50 74.5 69.2 149 138 50-150 7 30
Chrysene ug/L ND 50 50 63.3 59.3 127 119 50-130 6 30
Di-n-butylphthalate ug/L ND 50 50 66.8 62.2 134 124 50-130 7 30 MO
Di-n-octylphthalate ug/L ND 50 50 73.4 68.9 147 138 50-130 6 30 MO,v1
Dibenz(a,h)anthracene ug/L ND 50 50 67.7 58.4 135 117 40-130 15 30 M1
Dibenzofuran ug/L ND 50 50 54.5 52.2 109 104 40-130 4 30
Diethylphthalate ug/L ND 50 50 60.8 57.0 122 114 40-130 7 30
Dimethylphthalate ug/L ND 50 50 56.4 53.2 113 106 40-130 6 30
Fluoranthene ug/L ND 50 50 65.0 60.1 130 120 30-130 8 30
Fluorene ug/L ND 50 50 54.1 51.5 108 103 20-130 5 30
Hexachloro-1,3-butadiene ug/L ND 50 50 39.3 39.8 79 80 10-130 1 30
Hexachlorobenzene ug/L ND 50 50 48.5 46.7 97 93 30-130 4 30
Hexachlorocyclopentadiene ug/L ND 50 50 39.9 40.9 80 82 10-150 3 30
Hexachloroethane ug/L ND 50 50 44.9 45.4 90 91 10-130 1 30
Indeno(1,2,3-cd)pyrene ug/L ND 50 50 67.8 58.7 136 117 40-130 14 30 M1
Isophorone ug/L ND 50 50 60.4 55.5 121 111 30-130 9 30
N-Nitroso-di-n-propylamine ug/L ND 50 50 61.7 57.2 123 114 30-130 8 30
N-Nitrosodimethylamine ug/L ND 50 50 49.1 46.7 98 93 10-130 5 30
N-Nitrosodiphenylamine ug/L ND 50 50 58.0 55.9 116 112 30-130 4 30
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 91 of 111
Pace Analytical Services,LLC
ID 9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacelabs.com 704)875-9092
I
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2967688 2967689
MS MSD
92489806020 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Naphthalene ug/L ND 50 50 51.5 49.2 103 98 20-130 5 30
Nitrobenzene ug/L ND 50 50 57.6 53.3 115 107 20-130 8 30
Pentachlorophenol ug/L ND 100 100 112 89.4 112 89 10-140 23 30
Phenanthrene ug/L ND 50 50 58.6 55.8 117 112 50-130 5 30
Phenol ug/L ND 50 50 31.6 30.0 63 60 10-130 5 30
Pyrene ug/L ND 50 50 63.6 61.0 127 122 50-130 4 30
2,4,6-Tribromophenol(S) 91 84 10-137
2-Fluorobiphenyl(S) 89 86 13-130
2-Fluorophenol(S)66 64 10-130
Nitrobenzene-d5(S) 100 95 13-130
Phenol-d6(S) 55 52 10-130
Terphenyl-d14(S) 115 110 25-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 92 of 111
Pace Analytical Services,LLC
aceAnalytical
s 9800 KinceyAve. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 559018 Analysis Method: EPA 8270E
QC Batch Method: EPA 3546 Analysis Description: 8270E Solid MSSV Microwave
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
METHOD BLANK: 2966159 Matrix: Solid
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,2,4-Trichlorobenzene mg/kg ND 0.33 0.076 08/11/20 09:28
1,2-Dichlorobenzene mg/kg ND 0.33 0.071 08/11/20 09:28
1,3-Dichlorobenzene mg/kg ND 0.33 0.074 08/11/20 09:28
1,4-Dichlorobenzene mg/kg ND 0.33 0.073 08/11/20 09:28
1-Methylnaphthalene mg/kg ND 0.33 0.088 08/11/20 09:28
2,2'-Oxybis(1-chloropropane)mg/kg ND 0.33 0.092 08/11/20 09:28
2,4,5-Trichlorophenol mg/kg ND 0.33 0.086 08/11/20 09:28
2,4,6-Trichlorophenol mg/kg ND 0.33 0.083 08/11/20 09:28
2,4-Dichlorophenol mg/kg ND 0.33 0.11 08/11/20 09:28
2,4-Dimethylphenol mg/kg ND 0.33 0.082 08/11/20 09:28
2,4-Dinitrophenol mg/kg ND 1.6 1.1 08/11/20 09:28
2,4-Dinitrotoluene mg/kg ND 0.33 0.087 08/11/20 09:28
2,6-Dinitrotoluene mg/kg ND 0.33 0.086 08/11/20 09:28 v2
2-Chloronaphthalene mg/kg ND 0.33 0.074 08/11/20 09:28
2-Chlorophenol mg/kg ND 0.33 0.077 08/11/20 09:28
2-Methylnaphthalene mg/kg ND 0.33 0.084 08/11/20 09:28
2-Methylphenol(o-Cresol) mg/kg ND 0.33 0.073 08/11/20 09:28
2-Nitroaniline mg/kg ND 1.6 0.17 08/11/20 09:28
2-Nitrophenol mg/kg ND 0.33 0.10 08/11/20 09:28
3&4-Methylphenol(m&p Cresol) mg/kg ND 0.33 0.083 08/11/20 09:28
3,3'-Dichlorobenzidine mg/kg ND 0.66 0.23 08/11/20 09:28
3-Nitroaniline mg/kg ND 1.6 0.18 08/11/20 09:28
4,6-Dinitro-2-methylphenol mg/kg ND 0.66 0.53 08/11/20 09:28
4-Bromophenylphenyl ether mg/kg ND 0.33 0.087 08/11/20 09:28
4-Chloro-3-methylphenol mg/kg ND 0.66 0.20 08/11/20 09:28
4-Chloroaniline mg/kg ND 0.66 0.20 08/11/20 09:28
4-Chlorophenylphenyl ether mg/kg ND 0.33 0.086 08/11/20 09:28
4-Nitroaniline mg/kg ND 0.66 0.16 08/11/20 09:28
4-Nitrophenol mg/kg ND 1.6 0.53 08/11/20 09:28
Acenaphthene mg/kg ND 0.33 0.085 08/11/20 09:28
Acenaphthylene mg/kg ND 0.33 0.078 08/11/20 09:28
Aniline mg/kg ND 0.33 0.074 08/11/20 09:28
Anthracene mg/kg ND 0.33 0.086 08/11/20 09:28
Benzo(a)anthracene mg/kg ND 0.33 0.10 08/11/20 09:28
Benzo(a)pyrene mg/kg ND 0.33 0.14 08/11/20 09:28
Benzo(b)fluoranthene mg/kg ND 0.33 0.13 08/11/20 09:28
Benzo(g,h,i)perylene mg/kg ND 0.33 0.13 08/11/20 09:28
Benzo(k)fluoranthene mg/kg ND 0.33 0.14 08/11/20 09:28
Benzoic Acid mg/kg ND 1.6 0.36 08/11/20 09:28
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 93 of 111
Pace Analytical Services,LLC
ace Analytical 9800 neyAve Suite 100
Huntersville,NC 28078
www.paceiabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
METHOD BLANK: 2966159 Matrix: Solid
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Benzyl alcohol mg/kg ND 0.66 0.18 08/11/20 09:28
bis(2-Chloroethoxy)methane mg/kg ND 0.33 0.088 08/11/20 09:28
bis(2-Chloroethyl)ether mg/kg ND 0.33 0.070 08/11/20 09:28
bis(2-Ethylhexyl)phthalate mg/kg ND 0.33 0.11 08/11/20 09:28
Butylbenzylphthalate mg/kg ND 0.33 0.088 08/11/20 09:28
Chrysene mg/kg ND 0.33 0.096 08/11/20 09:28
Di-n-butylphthalate mg/kg ND 0.33 0.081 08/11/20 09:28
Di-n-octylphthalate mg/kg ND 0.33 0.19 08/11/20 09:28
Dibenz(a,h)anthracene mg/kg ND 0.33 0.13 08/11/20 09:28
Dibenzofuran mg/kg ND 0.33 0.082 08/11/20 09:28
Diethylphthalate mg/kg ND 0.33 0.072 08/11/20 09:28
Dimethylphthalate mg/kg ND 0.33 0.075 08/11/20 09:28
Fluoranthene mg/kg ND 0.33 0.10 08/11/20 09:28
Fluorene mg/kg ND 0.33 0.088 08/11/20 09:28
Hexachloro-1,3-butadiene mg/kg ND 0.33 0.080 08/11/20 09:28
Hexachlorobenzene mg/kg ND 0.33 0.084 08/11/20 09:28
Hexachlorocyclopentadiene mg/kg ND 0.33 0.13 08/11/20 09:28 v2
Hexachloroethane mg/kg ND 0.33 0.075 08/11/20 09:28
Indeno(1,2,3-cd)pyrene mg/kg ND 0.33 0.15 08/11/20 09:28
Isophorone mg/kg ND 0.33 0.072 08/11/20 09:28
N-Nitroso-di-n-propylamine mg/kg ND 0.33 0.092 08/11/20 09:28
N-Nitrosodimethylamine mg/kg ND 0.33 0.093 08/11/20 09:28
N-Nitrosodiphenylamine mg/kg ND 0.33 0.084 08/11/20 09:28
Naphthalene mg/kg ND 0.33 0.079 08/11/20 09:28
Nitrobenzene mg/kg ND 0.33 0.079 08/11/20 09:28
Pentachlorophenol mg/kg ND 0.66 0.15 08/11/20 09:28
Phenanthrene mg/kg ND 0.33 0.083 08/11/20 09:28
Phenol mg/kg ND 0.33 0.079 08/11/20 09:28
Pyrene mg/kg ND 0.33 0.091 08/11/20 09:28
Pyridine mg/kg ND 0.33 0.084 08/11/20 09:28
2,4,6-Tribromophenol(S) 72 27-110 08/11/20 09:28
2-Fluorobiphenyl(S) 64 30-110 08/11/20 09:28
2-Fluorophenol(S) 65 13-110 08/11/20 09:28
Nitrobenzene-d5(S) 53 23-110 08/11/20 09:28
Phenol-d6(S)66 22-110 08/11/20 09:28
Terphenyl-d14(S) 76 28-110 08/11/20 09:28
LABORATORY CONTROL SAMPLE: 2966160
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,2,4-Trichlorobenzene mg/kg 1.7 1.2 73 52-130
1,2-Dichlorobenzene mg/kg 1.7 1.3 79 51-130
1,3-Dichlorobenzene mg/kg 1.7 1.3 79 50-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 94 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2966160
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
1,4-Dichlorobenzene mg/kg 1.7 1.4 83 49-130
1-Methylnaphthalene mg/kg 1.7 1.2 71 55-130
2,2'-Oxybis(1-chloropropane)mg/kg 1.7 1.6 96 30-130
2,4,5-Trichlorophenol mg/kg 1.7 1.5 86 55-130
2,4,6-Trichlorophenol mg/kg 1.7 1.5 90 57-130
2,4-Dichlorophenol mg/kg 1.7 1.3 76 56-130
2,4-Dimethylphenol mg/kg 1.7 1.2 71 51-130
2,4-Dinitrophenol mg/kg 8.5 5.5 65 27-133
2,4-Dinitrotoluene mg/kg 1.7 1.3 80 61-130
mg/kg 1.7 0.97 57 60-130 L2 v32,6 Dlnitrotoluene g g
2-Chloronaphthalene mg/kg 1.7 1.4 82 52-130
2-Chlorophenol mg/kg 1.7 1.5 86 54-130
2-Methylnaphthalene mg/kg 1.7 1.3 74 54-130
2-Methylphenol(o-Cresol) mg/kg 1.7 1.4 82 51-130
2-Nitroaniline mg/kg 3.4 2.2 66 51-130
2-Nitrophenol mg/kg 1.7 1.3 75 49-130
3&4-Methylphenol(m&p Cresol) mg/kg 1.7 1.4 81 11-163
3,3'-Dichlorobenzidine mg/kg 3.4 2.5 73 10-132
3-Nitroaniline mg/kg 3.4 2.5 73 55-130
4,6-Dinitro-2-methylphenol mg/kg 3.4 2.6 78 47-142
4-Bromophenylphenyl ether mg/kg 1.7 1.5 87 59-130
4-Chloro-3-methylphenol mg/kg 3.4 2.4 70 55-130
4-Chloroaniline mg/kg 3.4 2.6 77 54-130
4-Chlorophenylphenyl ether mg/kg 1.7 1.4 83 58-130
4-Nitroaniline mg/kg 3.4 2.8 84 54-130
4-Nitrophenol mg/kg 8.5 5.4 64 48-130
Acenaphthene mg/kg 1.7 1.3 77 60-130
Acenaphthylene mg/kg 1.7 1.3 79 60-130
Aniline mg/kg 1.7 1.3 76 43-130
Anthracene mg/kg 1.7 1.2 70 63-130
Benzo(a)anthracene mg/kg 1.7 1.3 79 59-130
Benzo(a)pyrene mg/kg 1.7 1.4 82 57-130
Benzo(b)fluoranthene mg/kg 1.7 1.3 79 54-130
Benzo(g,h,i)perylene mg/kg 1.7 1.4 83 59-130
Benzo(k)fluoranthene mg/kg 1.7 1.4 82 54-130
Benzoic Acid mg/kg 8.5 4.4 52 19-130
Benzyl alcohol mg/kg 3.4 2.8 81 50-130
bis(2-Chloroethoxy)methane mg/kg 1.7 1.2 72 54-130
bis(2-Chloroethyl)ether mg/kg 1.7 1.3 78 48-130
bis(2-Ethylhexyl)phthalate mg/kg 1.7 1.2 70 45-134
Butylbenzylphthalate mg/kg 1.7 1.2 69 46-138
Chrysene mg/kg 1.7 1.4 80 58-130
Di-n-butylphthalate mg/kg 1.7 1.3 77 60-130
Di-n-octylphthalate mg/kg 1.7 1.2 72 53-130
Dibenz(a,h)anthracene mg/kg 1.7 1.4 80 59-130
Dibenzofuran mg/kg 1.7 1.4 80 60-130
Diethylphthalate mg/kg 1.7 1.3 78 60-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 95 of 111
I
Pace Analytical Services,LLC
ace Analytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
LABORATORY CONTROL SAMPLE: 2966160
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Dimethylphthalate mg/kg 1.7 1.3 78 60-130
Fluoranthene mg/kg 1.7 1.4 85 65-130
Fluorene mg/kg 1.7 1.3 77 63-130
Hexachloro-1,3-butadiene mg/kg 1.7 1.3 79 46-130
Hexachlorobenzene mg/kg 1.7 1.5 88 58-130
Hexachlorocyclopentadiene mg/kg 1.7 0.87 51 23-130 v3
Hexachloroethane mg/kg 1.7 1.3 76 47-130
Indeno(1,2,3-cd)pyrene mg/kg 1.7 1.4 82 60-130
Isophorone mg/kg 1.7 1.1 64 49-130
N-Nitroso-di-n-propylamine mg/kg 1.7 1.1 65 47-130
N-Nitrosodimethylamine mg/kg 1.7 1.2 72 45-130
N-Nitrosodiphenylamine mg/kg 1.7 1.4 80 59-130
Naphthalene mg/kg 1.7 1.3 75 55-130
Nitrobenzene mg/kg 1.7 1.1 65 49-130
Pentachlorophenol mg/kg 3.4 3.0 88 10-132
Phenanthrene mg/kg 1.7 1.3 78 62-130
Phenol mg/kg 1.7 1.5 91 46-130
Pyrene mg/kg 1.7 1.3 75 53-130
Pyridine mg/kg 1.7 1.1 65 37-130
2,4,6-Tribromophenol(S) 82 27-110
2-Fluorobiphenyl(S) 69 30-110
2-Fluorophenol(S) 75 13-110
Nitrobenzene-d5(S) 57 23-110
Phenol-d6(S)75 22-110
Terphenyl-d14(S) 78 28-110
MATRIX SPIKE SAMPLE: 2966161
92489422005 Spike MS MS Rec
Parameter Units Result Conc. Result Rec Limits Qualifiers
1,2,4-Trichlorobenzene mg/kg ND 1.8 0.96 55 18-130
1,2-Dichlorobenzene mg/kg ND 1.8 1.0 60 14-130
1,3-Dichlorobenzene mg/kg ND 1.8 1.0 58 12-130
1,4-Dichlorobenzene mg/kg ND 1.8 1.1 61 10-130
1-Methylnaphthalene mg/kg ND 1.8 0.86 49 12-130
2,2'-Oxybis(1-chloropropane)mg/kg ND 1.8 1.2 70 10-130
2,4,5-Trichlorophenol mg/kg ND 1.8 1.1 64 13-130
2,4,6-Trichlorophenol mg/kg ND 1.8 1.1 65 17-130
2,4-Dichlorophenol mg/kg ND 1.8 0.97 55 10-130
2,4-Dimethylphenol mg/kg ND 1.8 0.92 53 10-130
2,4-Dinitrophenol mg/kg ND 8.7 4.3 49 10-130
2,4-Dinitrotoluene mg/kg ND 1.8 1.0 58 24-130
2,6-Dinitrotoluene mg/kg ND 1.8 0.74 42 23-130 v3
2-Chloronaphthalene mg/kg ND 1.8 1.1 60 19-130
2-Chlorophenol mg/kg ND 1.8 1.1 64 10-130
2-Methylnaphthalene mg/kg ND 1.8 0.94 54 18-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05.08 PM without the written consent of Pace Analytical Services,LLC. Page 96 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
MATRIX SPIKE SAMPLE: 2966161
92489422005 Spike MS MS Rec
Parameter Units Result Conc. Result Rec Limits Qualifiers
2-Methylphenol(o-Cresol) mg/kg ND 1.8 1.0 59 10-130
2-Nitroaniline mg/kg ND 3.5 1.7 50 17-130
2-Nitrophenol mg/kg ND 1.8 0.99 57 10-130
3&4-Methylphenol(m&p Cresol) mg/kg ND 1.8 1.0 60 10-130
3,3'-Dichlorobenzidine mg/kg ND 3.5 1.9 53 10-130
3-Nitroaniline mg/kg ND 3.5 1.8 53 24-130
4,6-Dinitro-2-methylphenol mg/kg ND 3.5 1.9 55 10-152
4-Bromophenylphenyl ether mg/kg ND 1.8 1.1 63 29-130
4-Chloro-3-methylphenol mg/kg ND 3.5 1.8 52 17-130
4-Chloroaniline mg/kg ND 3.5 2.0 57 14-130
4-Chlorophenylphenyl ether mg/kg ND 1.8 1.1 61 25-130
4-Nitroaniline mg/kg ND 3.5 2.1 60 22-130
4-Nitrophenol mg/kg ND 8.7 4.2 48 10-130
Acenaphthene mg/kg ND 1.8 0.99 57 20-130
Acenaphthylene mg/kg ND 1.8 1.0 58 25-130
Aniline mg/kg ND 1.8 0.96 55 10-130
Anthracene mg/kg ND 1.8 0.89 51 29-130
Benzo(a)anthracene mg/kg ND 1.8 0.98 56 19-130
Benzo(a)pyrene mg/kg ND 1.8 1.0 57 12-130
Benzo(b)fluoranthene mg/kg ND 1.8 0.96 55 14-130
Benzo(g,h,i)perylene mg/kg ND 1.8 1.0 58 10-130
Benzo(k)fluoranthene mg/kg ND 1.8 1.0 57 14-130
Benzoic Acid mg/kg ND 8.7 4.4 50 10-130
Benzyl alcohol mg/kg ND 3.5 2.1 61 13-130
bis(2-Chloroethoxy)methane mg/kg ND 1.8 0.93 53 16-130
bis(2-Chloroethyl)ether mg/kg ND 1.8 0.99 57 11-130
bis(2-Ethylhexyl)phthalate mg/kg ND 1.8 0.89 51 21-130
Butylbenzylphthalate mg/kg ND 1.8 0.87 50 23-130
Chrysene mg/kg ND 1.8 1.0 57 22-130
Di-n-butylphthalate mg/kg ND 1.8 0.95 54 30-130
Di-n-octylphthalate mg/kg ND 1.8 0.91 52 23-142
Dibenz(a,h)anthracene mg/kg ND 1.8 0.97 55 10-130
Dibenzofuran mg/kg ND 1.8 1.0 58 24-130
Diethylphthalate mg/kg ND 1.8 1.0 58 26-130
Dimethylphthalate mg/kg ND 1.8 1.0 59 22-130
Fluoranthene mg/kg ND 1.8 1.0 60 33-130
Fluorene mg/kg ND 1.8 0.98 56 22-130
Hexachloro-1,3-butadiene mg/kg ND 1.8 1.0 58 13-130
Hexachlorobenzene mg/kg ND 1.8 1.1 61 29-130
Hexachlorocyclopentadiene mg/kg ND 1.8 0.63 36 10-130 v3
Hexachloroethane mg/kg ND 1.8 0.99 57 10-130
Indeno(1,2,3-cd)pyrene mg/kg ND 1.8 1.0 58 10-130
Isophorone mg/kg ND 1.8 0.82 47 13-130
N-Nitroso-di-n-propylamine mg/kg ND 1.8 0.86 49 12-130
N-Nitrosodimethylamine mg/kg ND 1.8 0.88 50 11-130
N-Nitrosodiphenylamine mg/kg ND 1.8 1.0 57 15-130
Naphthalene mg/kg ND 1.8 1.0 57 15-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 97 of 111
Pace Analytical Services,LLC
aceAnalytical
F.
9800 Kincey Ave. Suite 100
Hunteraville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
MATRIX SPIKE SAMPLE: 2966161
92489422005 Spike MS MS Rec
Parameter Units Result Conc. Result Rec Limits Qualifiers
Nitrobenzene mg/kg ND 1.8 0.83 48 12-130
Pentachlorophenol mg/kg ND 3.5 2.2 63 10-130
Phenanthrene mg/kg ND 1.8 0.98 56 27-130
Phenol mg/kg ND 1.8 1.1 65 10-130
Pyrene mg/kg ND 1.8 0.94 54 19-130
Pyridine mg/kg ND 1.8 0.52 30 10-130
2,4,6-Tribromophenol(S) 57 27-110
2-Fluorobiphenyl(S) 50 30-110
2-Fluorophenol(S) 54 13-110
Nitrobenzene-d5(S) 41 23-110
Phenol-d6(S)54 22-110
Terphenyl-d14(S) 56 28-110
SAMPLE DUPLICATE: 2966162
92489694001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
1,2,4-Trichlorobenzene mg/kg ND ND 30
1,2-Dichlorobenzene mg/kg ND ND 30
1,3-Dichlorobenzene mg/kg ND ND 30
1,4-Dichlorobenzene mg/kg ND ND 30
1-Methylnaphthalene mg/kg ND ND 30
2,2'-Oxybis(1-chloropropane)mg/kg ND ND 30
2,4,5-Trichlorophenol mg/kg ND ND 30
2,4,6-Trichlorophenol mg/kg ND ND 30
2,4-Dichlorophenol mg/kg ND ND 30
2,4-Dimethylphenol mg/kg ND ND 30
2,4-Dinitrophenol mg/kg ND ND 30
2,4-Dinitrotoluene mg/kg ND ND 30
2,6-Dinitrotoluene mg/kg ND ND 30 v2
2-Chloronaphthalene mg/kg ND ND 30
2-Chlorophenol mg/kg ND ND 30
2-Methylnaphthalene mg/kg ND ND 30
2-Methylphenol(o-Cresol) mg/kg ND ND 30
2-Nitroaniline mg/kg ND ND 30
1 2-Nitrophenol mg/kg ND ND 30
3&4-Methylphenol(m&p Cresol) mg/kg ND ND 30
3,3'-Dichlorobenzidine mg/kg ND ND 30
3-Nitroaniline mg/kg ND ND 30
4,6-Dinitro-2-methylphenol mg/kg ND ND 30
4-Bromophenylphenyl ether mg/kg ND ND 30
4-Chloro-3-methylphenol mg/kg ND ND 30
4-Chloroaniline mg/kg ND ND 30
4-Chlorophenylphenyl ether mg/kg ND ND 30
4-Nitroaniline mg/kg ND ND 30
4-Nitrophenol mg/kg ND ND 30
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 98 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
SAMPLE DUPLICATE: 2966162
92489694001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Acenaphthene mg/kg ND ND 30
Acenaphthylene mg/kg ND ND 30
Aniline mg/kg ND ND 30
Anthracene mg/kg ND ND 30
Benzo(a)anthracene mg/kg ND ND 30
Benzo(a)pyrene mg/kg ND ND 30
Benzo(b)fluoranthene mg/kg ND ND 30
Benzo(g,h,i)perylene mg/kg ND ND 30
Benzo(k)fluoranthene mg/kg ND ND 30
Benzoic Acid mg/kg ND ND 30
Benzyl alcohol mg/kg ND ND 30
bis(2-Chloroethoxy)methane mg/kg ND ND 30
bis(2-Chloroethyl)ether mg/kg ND ND 30
bis(2-Ethylhexyl)phthalate mg/kg ND ND 30
Butylbenzylphthalate mg/kg ND ND 30
Chrysene mg/kg ND ND 30
Di-n-butylphthalate mg/kg ND ND 30
Di-n-octylphthalate mg/kg ND ND 30
Dibenz(a,h)anthracene mg/kg ND ND 30
Dibenzofuran mg/kg ND ND 30
Diethylphthalate mg/kg ND ND 30
Dimethylphthalate mg/kg ND ND 30
Fluoranthene mg/kg ND ND 30
Fluorene mg/kg ND ND 30
Hexachloro-1,3-butadiene mg/kg ND ND 30
Hexachlorobenzene mg/kg ND ND 30
Hexachlorocyclopentadiene mg/kg ND ND 30 v2
Hexachloroethane mg/kg ND ND 30
Indeno(1,2,3-cd)pyrene mg/kg ND ND 30
Isophorone mg/kg ND ND 30
N-Nitroso-di-n-propylamine mg/kg ND ND 30
N-Nitrosodimethylamine mg/kg ND ND 30
N-Nitrosodiphenylamine mg/kg ND ND 30
Naphthalene mg/kg ND ND 30
Nitrobenzene mg/kg ND ND 30
Pentachlorophenol mg/kg ND ND 30
Phenanthrene mg/kg ND ND 30
Phenol mg/kg ND ND 30
Pyrene mg/kg ND ND 30
Pyridine mg/kg ND ND 30
2,4,6-Tribromophenol(S) 74 74
2-Fluorobiphenyl(S) 66 64
2-Fluorophenol(S) 62 64
Nitrobenzene-d5(S) 51 52
Phenol-d6(S)64 66
Terphenyl-d14(S) 79 84
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
I
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 558717 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92489806001,92489806002,92489806003,92489806004,92489806005,92489806006,92489806007,
92489806008,92489806009,92489806010,92489806011,92489806012,92489806013,92489806014
SAMPLE DUPLICATE: 2964835
92489692001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Percent Moisture 12.7 12.8 1 25
SAMPLE DUPLICATE: 2964836
92489806014 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Percent Moisture 20.6 18.0 14 25
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 100 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 558718 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92489806015,92489806016,92489806017
SAMPLE DUPLICATE: 2964892
92489806015 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Percent Moisture 21.9 23.6 7 25
SAMPLE DUPLICATE: 2964970
92489876010 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Percent Moisture 10.2 10.2 1 25
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
1
www.pacelabs.com
704)875-9092
i
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 1525099 Analysis Method: SM 2540G
QC Batch Method: SM 2540 G Analysis Description: Total Solids 2540 G-2011
Laboratory: Pace National-Mt.Juliet
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
METHOD BLANK: R3559684-1 Matrix: Solid
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Solids ND 08/13/20 10:42
LABORATORY CONTROL SAMPLE: R3559684-2
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Total Solids 50.0 50.0 100 85.0-115
SAMPLE DUPLICATE: R3559684-3
92489806012 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Solids 72.2 73.3 1.55 10
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 102 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
QC Batch: 1523269 Analysis Method: EPA 7199
QC Batch Method: 3060A Analysis Description: Wet Chemistry 7199
Laboratory: Pace National-Mt.Juliet
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
METHOD BLANK: R3559334-1 Matrix: Solid
Associated Lab Samples: 92489806009,92489806010,92489806011,92489806012,92489806013,92489806014,92489806015,
92489806016,92489806017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chromium,Hexavalent mg/kg ND 1.00 0.255 08/12/20 15:01
LABORATORY CONTROL SAMPLE: R3559334-2
Spike LCS LCS Rec
Parameter Units Conc. Result Rec Limits Qualifiers
Chromium,Hexavalent mg/kg 10.0 9.69 96.9 80.0-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: R3559334-3 R3559334-4
MS MSD
L1248482-02 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Chromium,Hexavalent mg/kg ND 20.0 20.0 15.2 14.6 76.2 72.9 75.0-125 4.47 20 ML
MATRIX SPIKE SAMPLE: R3559334-5
L1248482-02 Spike MS MS Rec
Parameter Units Result Conc. Result Rec Limits Qualifiers
Chromium,Hexavalent mg/kg ND 643 644 100 75.0-125
SAMPLE DUPLICATE: R3559334-7
L1248482-05 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Chromium,Hexavalent mg/kg ND ND 0.00 20
SAMPLE DUPLICATE: R3559334-8
L1248894-01 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Chromium,Hexavalent mg/kg ND ND 0.00 20
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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I Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 103 of 111
Pace Analytical Services,LLC
aceAnalytical 9800 KinceyAve. Suite 100
Huntersville,NC 28078
www.pacelabs.com 704)875-9092
1
QUALIFIERS
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s)did not meet method acceptance criteria;this result should
be considered an estimated value.
J Analyte detected below the reporting limit,therefore result is an estimate.This qualifier is also used for all TICs.
L1 Analyte recovery in the laboratory control sample(LCS)was above QC limits. Results for this analyte in associated
samples may be biased high.
L2 Analyte recovery in the laboratory control sample(LCS)was below QC limits. Results for this analyte in associated
samples may be biased low.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
ML Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits.Result may be biased
low.
R1 RPD value was outside control limits.
SO Surrogate recovery outside laboratory control limits.
v1 The continuing calibration verification was above the method acceptance limit.Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit.The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit.Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com 704)875-9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92489806009 SS-DUP EPA3050B 558825 EPA6010D 558982
92489806010 SS-1 EPA 3050B 558825 EPA 6010D 558982
92489806011 SS-2 EPA 3050B 558825 EPA 6010D 558982
92489806012 SS-3 EPA 3050B 558825 EPA 6010D 558982
92489806013 SS-4 EPA 3050B 558825 EPA 6010D 558982
92489806014 SS-5 EPA 3050B 558825 EPA 6010D 558982
92489806015 SS-6 EPA 3050E 558825 EPA 6010D 558982
92489806016 SS-7 EPA 3050B 558825 EPA 6010D 558982
92489806017 SS-8 EPA 3050B 558825 EPA 6010D 558982
92489806009 SS-DUP EPA 7471 B 558827 EPA 7471 B 558922
92489806010 SS-1 EPA 7471 B 558827 EPA 7471 B 558922
92489806011 SS-2 EPA 7471 B 558827 EPA 7471 B 558922
92489806012 SS-3 EPA 7471 B 558827 EPA 7471 B 558922
92489806013 SS-4 EPA 7471 B 558827 EPA 7471 B 558922
92489806014 SS-5 EPA 7471 B 558827 EPA 7471 B 558922
92489806015 SS-6 EPA 7471 B 558827 EPA 7471 B 558922
92489806016 SS-7 EPA 7471 B 558827 EPA 7471 B 558922
92489806017 SS-8 EPA 7471 B 558827 EPA 7471 B 558922
92489806019 TW-1 EPA 3510C 559317 EPA 8270E 559569
92489806020 TW-2 EPA 3510C 559317 EPA 8270E 559569
92489806021 TW-DUP EPA 3510C 559317 EPA 8270E 559569
92489806009 SS-DUP EPA3546 559018 EPA8270E 559086
92489806010 SS-1 EPA 3546 559018 EPA 8270E 559086
92489806011 SS-2 EPA 3546 559018 EPA 8270E 559086
92489806012 55-3 EPA 3546 559018 EPA 8270E 559086
92489806013 SS-4 EPA 3546 559018 EPA 8270E 559086
92489806014 SS-5 EPA 3546 559018 EPA 8270E 559086
92489806015 SS-6 EPA 3546 559018 EPA 8270E 559086
92489806016 SS-7 EPA 3546 559018 EPA 8270E 559086
92489806017 SS-8 EPA 3546 559018 EPA 8270E 559086
92489806001 SS-1A EPA 5035A/5030B 558879 EPA 8260D 558902
92489806002 SS-2B EPA 5035A/5030B 558879 EPA 8260D 558902
92489806003 SS-3C EPA 5035A/5030B 558879 EPA 8260D 558902
92489806004 SS-4D EPA 5035A/5030B 558879 EPA 8260D 558902
92489806005 SS-5E EPA 5035A/5030B 559241 EPA 8260D 559260
92489806006 SS-6F EPA 5035A/5030B 558879 EPA 8260D 558902
92489806007 SS-7G EPA 5035A/5030B 558879 EPA 8260D 558902
92489806008 SS-8H EPA 5035A/5030B 558879 EPA 8260D 558902
92489806009 SS-DUP EPA 5035A/5030B 558879 EPA 8260D 558902
92489806018 Trip Blank EPA 8260D 559313
92489806019 1W-1 EPA 8260D 559313
92489806020 TW-2 EPA 8260D 559313
92489806021 TW-DUP EPA 8260D 559313
92489806001 SS-1A ASTM 02974-87 558717
92489806002 SS-2B ASTM D2974-87 558717
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 105 of 111
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacelabs.tam 704)875-9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Former Sherwin Williams BFSite
Pace Project No.: 92489806
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92489806003 SS-3C ASTM D2974-87 558717
92489806004 SS-4D ASTM D2974-87 558717
92489806005 SS-5E ASTM D2974-87 558717
92489806006 SS-6F ASTM D2974-87 558717
92489806007 SS-7G ASTM D2974-87 558717
92489806008 SS-8H ASTM D2974-87 558717
92489806009 SS-DUP ASTM D2974-87 558717
92489806010 SS-1 ASTM D2974-87 558717
92489806011 SS-2 ASTM D2974-87 558717
92489806012 SS-3 ASTM D2974-87 558717
92489806013 SS-4 ASTM D2974-87 558717
92489806014 SS-5 ASTM D2974-87 558717
92489806015 SS-6 ASTM D2974-87 558718
92489806016 SS-7 ASTM D2974-87 558718
92489806017 SS-8 ASTM D2974-87 558718
92489806009 SS-DUP SM 2540 G 1525099 SM 2540G 1525099
92489806010 SS-1 SM 2540 G 1525099 SM 2540G 1525099
92489806011 SS-2 SM 2540 G 1525099 SM 2540G 1525099
92489806012 SS-3 SM 2540 G 1525099 SM 2540G 1525099
92489806013 SS-4 SM 2540 G 1525099 SM 2540G 1525099
92489806014 SS-5 SM 2540 G 1525099 SM 2540G 1525099
92489806015 SS-6 SM 2540 G 1525099 SM 2540G 1525099
92489806016 SS-7 SM 2540 G 1525099 SM 2540G 1525099
92489806017 SS-8 SM 2540 G 1525099 SM 2540G 1525099
92489806009 SS-DUP 3060A 1523269 EPA 7199 1523269
92489806010 SS-1 3060A 1523269 EPA 7199 1523269
92489806011 SS-2 3060A 1523269 EPA 7199 1523269
92489806012 SS-3 3060A 1523269 EPA 7199 1523269
92489806013 SS-4 3060A 1523269 EPA 7199 1523269
92489806014 SS-5 3060A 1523269 EPA 7199 1523269
92489806015 SS-6 3060A 1523269 EPA 7199 1523269
92489806016 SS-7 3060A 1523269 EPA 7199 1523269
92489806017 SS-8 3060A 1523269 EPA 7199 1523269
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/14/2020 05:08 PM without the written consent of Pace Analytical Services,LLC. Page 106 of 111
Document Name: Document Revised:February 7,2018
Sample Condition Upon Receipt(SCUR) Page 1 of 2
12ace Analyticaln Document No.: Issuing Authority:
l F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office
Laboratory receiving samples:
gf h Mechanicsville
Asheville L Eden Greenwood IIFuntersville Ralp
Sample Condition Client Name:
Project# ^0'• : 92489$Q6
Upon Receipt
Courier: Fed Ex
S
CUPS CUSPS Client tIIII 11111 UU ll Ili
Commercial BRace Other: g2489806
Custody Seal Present? FIYes FIND Seals Intact? Fives FIN0
Date/initials Person Examining Contents:
r, sBubble Bags fill Biological TIssue Azen? 0 /o10
Packing Material: Bubble Wrap g None u
Thermometgr:92.1061 Type of Ice: Wet Blue ['None
R Gun ID:
Cooler Temp(CC): 3. if Correction Factor:Add/Subtract(°C( 0.0 Temp should be above freezing to 6°C
Cooler Temp Corrected(CC): 3°N` Samples out of temp criteria.Samples on ice,cooling process
has begun
USDA Regulated Soil (0 N/A,water sample)
Did samples originate in a quarantine zone within the United States CA,NY,or SC(check maps)? Did
l samplesll
e
d Pueom
a
rto
foreign
ore g Yersource lint rQnationally,
Yes `+
1 Comments/Discrepancy:
fT
Chain of Custody Present? Oyes No ON/A 1.
Samples Arrived within Hold Time? 4es No ON/A 2.
Short Hold Time Analysis(<72 hr.)? ves No ON/A 3.
Rush Turn Around Time Requested? Ones ( No ON/A 4.
Sufficient Volume?
yes No ON/A 5.
Correct Containers Used? EYes No ON/A 6.
Pace Containers Used? I 1es No ON/A
Containers Intact? I YYes flea ON/A 7.
Dissolved analysis:Samples Field Filtered? Yes o ON/A 8.
Sample Labels Match COC? Eres Ono ON/A 9.
Includes Date/Time/ID/Analysis Matrix: V S L
Headspace in VOA Vials(>5-6mm)? Des °ON/A 10.
Trip Blank Present? byes UNo ON/A 11.
Trip Blank Custody Seals Present? Yes N° ON/A
Fled Dote Required? Dues No
COMMENTS/SAMPLE DISCREPANCY
I
l' G`t i 1 .t\ 1(,)U91 CLC S \rl(tU-E YL N .p .41 n' o ( v v )
4- Vvve tj,,-e ye, -0(c i i-E‘l -\'\ If 4,( 1 e -t 71 14. ' °
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
11r \ I iz,I i --he CI '-ft) -T"LU- --
Person contacted: I 1
I IC i I I`"C- I )` ( I 16Z t ``( ( ) Date/Time: 1 ) I C i (( (t
t,i Li
i E. -el— W 2.0
f rill Date: e' G.,170
Project Manager SCURF Review:
Project Manager SRF Review:16 Date: J "tc—7'NO
Page 107 of 111
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7 CHAIN-OF-CUSTODY/ Analytical Request Document
6FaceAnalytical. The Chain-of-Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately.o
Section A Section B Section C mm
Required Client Information: Required Project Information: Invoice Information: Page: 1 Of a
Company. ECS Carolinas Report To Chris Orrell Attention
Address 1812 Center P;rk Dr Copy To Company Name
Suite D.Charlotte,NC 28217 Address Regulatory Agency
Email [e-mail] Purchase Order S Pace Quote
Phone. IFax Project Name Former Sherwin Williams BF Sae Pace Project Manager angels baioni e@pacelabs corn. State/Location
Requested Due Date Project 8 Pace Profile R 2558.2,3 NC
Requested Analysis Filtered(YIN)
z
unrrur coot - 3 COLLECTED Preservatives
Dunking Water DW O
CcaSWnr., WT
U
al w
Wait.Water WW - G
E
Prod°d P JO N 3--
SAMPLE ID s...„u START END o a l
cv
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One Character per box. Wit• We „
S
w 0af(
N
O =
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A-Z,f-91 -j
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Uo >zp
xSampleIdsmustbeuniquere Si p ,,, OP m
2 a'''. a 'U wa O z = N L tQUO 0UOo
a
I-gy obS -eDATE TIME DATE TIME < o ' _ z z O
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1 7 I A A.CI. /fIG; I C 3(CC./
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11 Sc') •- i /Z; i 34147 x x Q7o—UII
12 5 ' 3 1 1`
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00 C \ V t
ADDITIONAL COMMENTS REUNOUISHED BY/AFFILIATION DATE TIME ACCEPTED BY i AFFILIATION DATE TIME /
I
SAMPLE CONDITIONS
i0C" C'6 (,5 5 i i'I'-7- I - . t 1 D 6 Li p'C C. (/ G" i c P —3 4 '1 i I
J
SAMPLER NAME AND SIGNATURE r=
U o
I.I mPRINTNameofSAMPLER: mJt'1.`-tL t(-.
I
4'LL 1 r1.
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d'-, o v S. n—
SIGNATURE of SAMPLER: DATE Signed: ci m y ci rn 0
F.
to c}
O
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CHAIN-OF-CUSTODY / Analytical Request Document
aeeAnalytieal The Chain-of-Custody is a LEGAL DOCUMENT.All relevant Gelds must be completed accurately.
www.pacdxbs.com
Page: of
Section A Section B Section C
Required Client Information; Required Project Information: Invoice Information:
Company: - Report To: `
fi> Or f kit.
Attention:
t.
Address: •`J;
L. D ,,_
Copy To:Company Name:
7 REGULATORY AGENCY
Address:T NPDES I- GROUND WATER r DRINKING WATER
7,,k-C-. CLtiy: . N ',,AZ. c- 1.,y
Email To: • ri ',, { t,Purchase Order No.:Paco Dome E UST r RCRA r OTHERL.0 i A\-Z.LS\,I+"t.\(J\,.; -;'' Reference.
o
Pace Prn nc1
Slto Location
tPhone:Fax: Projnct Name '-
I,.fG,`v. V 1i\tc\,s ,Ye Manager) iAla \tc Lr i,.
Re quea led Duo Do to ITA P Protect Nu hnr: Paco Prol In tt.
J'
STATE:
Requested Analysis Filtered(YIN)
Section D Matrix Codes - z
RngulrodChent Informtt on MATRIX r CODE - 2 COLLECTED Preservatives i
Drinking Water DW O 6
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Water WT $ U
COMPOSITE COMPOSITE ~
Waste Water WW u 1 l'
Product P n
m
START END,GRAB w Z
SoiVSolid SL E' 0 d u,
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25 rti
SAMPLE ID 01pe wP ? w d "
A-Z.D-g/.-) Air AR p w a ZQ '0
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Sample IDs MUST BE UNIQUE Tissue TS 0 > w I- m N J U
Other OT U 1- r- Z
a m ..)C 73
X J w 0 Q C 7+
a a NaO to L 4 - ') '2 0 cvO U
O n -c
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ADDITIONAL COMMENTS RELINQUISHED BY!AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS
anl 1 k.L`.f L L\ ST q.17: S.,`,-c )' 1)Cc(L _ 1! f o' I S ,
Charlotte-Mecklenburg
r =~ STORM 600 E. Fourth Street
WATERCharlotte, NC 28202
Services
Fax [phone]
May 13,2021
NC Depaitiiient of Environmental Quality
Mooresville Regional Office
Division of Water Resources—Water Quality Permitting Unit
610 E. Center Avenue
Suite 301
Mooresville,NC 28115
Re: NPDES permit application-request to discharge into the City of Charlotte
municipal stormwater system at Central Avenue and Pecan Avenue
Division of Water Resources:
Regarding TGACSE Central Square,LLC's request in their NPDES permit application to
discharge treated water from a remediation system at the above-referenced location into
Charlotte's stormwater system, Charlotte Mecklenburg Storm Water Services (CMSWS)
approves the discharge.
CMSWS would like to make the permittee and NC DEQ aware of the following
considerations and information:
CMSWS does not guarantee adequate capacity is available to permitted
dischargers to keep any property or street free of water or harm as a result of this
discharge.
CMSWS takes no responsibility for backflows from the public drainage system
into the permitted discharger's system.
CMSWS requires notification upon discovery of any contravention of permit
terms or evidence of such contravention such as a sheen or odor at the discharge
location.
If you have any questions,please contact Craig Miller at(704) 351-5472 or
[e-mail].
Sincerely,
Adee
Craig Miller
NPDES Permit Supervisor
cc: ECS Southeast, LLP
CHARLOTTE To report pollution or drainage problems, call: 311
http://stormwater.charmeck.org
El:PS.
11m
ECS SOUTHEAST, LLP Setting the Standard for Service"
a milmon Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F-1078
NC Registered Geologists Firm C-553
SC Registered Engineering Firm 3239
April 14, 2021
Craig Miller
NPDES Program Supervisor
Charlotte-Mecklenburg Stormwater Services
600 East 4th Street
Charlotte, NC 28202
RE: Request for Permission to Discharge to Stormwater System
NPDES Permit Application
Central Square
Property Located Southwest of Intersection of Central Avenue and Pecan Avenue
Charlotte, Mecklenburg County, North Carolina
ECS Project No. 10756-C
Dear Mr. Miller:
ECS Southeast, LLP (ECS) prepared this correspondence on behalf of its client TGACSE Central Square, LLC.
TGACSE Central Square, LLC intends to submit a National Pollutant Discharge Elimination System (NPDES)
Permit Application to the North Carolina Department of Environmental Quality (NCDEQ) for the discharge of
treated groundwater produced during construction dewatering and permanent building dewatering to an
unnamed tributary of Little Sugar Creek.
Attached is a Draft NPDES Permit Application for the proposed discharge. As indicated in the Draft NPDES
Permit Application, the proposed discharge is to a drop inlet of the municipal stormwater system. The
NCDEQ application process requires that written permission be obtained from the municipality which owns the
stormwater system.Consequently,we are requesting such written permission with this correspondence.
Please let us know if you have any questions or would like additional information. We look forward to
hearing from you.
Respectfully submitted,
ECS SOUTHEAST, LLP
P.
oseph P. Nestor, P.G., P.E. Roger A._Smith,
Environmental Principal Principal Geologist
[e-mail] [e-mail]
704-280-7422 704-378-9015
Attachments: Draft NPDES Permit Application
ECS Capitol Services,PLLC • ECS Florida,LLC • ECS Mid-Atlantic,LLC • ECS Midwest,LLC • ECS Southeast,LLP • ECS Southwest,LLP
www.ecslimited.com
ITSECS SOUTHEAST, SettingLLP the Standard for Service"
moismimm. Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F-1078
NC Registered Geologists Firm C-553
SC Registered Engineering Firm 3239
May 19, 2021
Derek Denard
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section - NPDES
1617 Mail Service Center
Raleigh, NC 27699-1617
Reference: Engineering Alternatives Analysis(EAA)
Submitted in Support of National Pollutant Discharge Elimination System (NPDES)
Permit Application for Construction and Permanent Dewatering
Central Square
Located Southwest of Intersection of Central Avenue and Pecan Avenue
Charlotte, North Carolina
ECS Project No. 10756-C
Dear Mr. Denard:
ECS Southeast, LLP (ECS) prepared the enclosed Engineering Alternatives Analysis(EAA) on behalf of
TGACSE Central Square, LLC in support of a National Pollutant Discharge Elimination System (NPDES)
Permit Application which is being submitted concurrently. ECS prepared the EAA following the
guidelines and template (Revised October 2019) found on NCDEQ's webpage at
https://deq.nc.gov/about/divisions/water-resources/water-quality-permitting/npdes-
wastewater/npdes-permitting on March 31, 2021. If you have any questions or comments
concerning the contents of the enclosed documents or other related topics,please feel free to contact
us.
Respectfully submitted,
ECS SOUTHEAST, LLP
seph P. Nestor, P.G., P.E. Roger A. smith, P.G.
Environmental Principal Principal Geologist
[e-mail] [e-mail]
704-280-7422 704-552-5152
Enclosure: Engineering Alternatives Analysis
ECS Capitol Services,PLLC • ECS Florida,LLC • ECS Mid-Atlantic,LLC • ECS Midwest,LLC • ECS Southeast,LLP • ECS Southwest,LLP
www.ecslimited.com
ENGINEERING ALTERNATIVES ANALYSIS(EAA)
Submitted in Support of
National Pollutant Discharge Elimination System(NPDES)Permit
For
Construction and Permanent Dewatering
Central Square Project
Located Southwest of Intersection of Central Avenue and Pecan Avenue
Charlotte, North Carolina
Charlotte, North Carolina 28205
May 19, 2021
Prepared for:
Mr. Barry James
Construction Project Manager
TGACSE Central Square, LLC
c/o Crosland Southeast
201 South College Street, Suite 1300
Charlotte, North Carolina 28244
Prepared by:
ECS Southeast, LLP
1812 Center Park Drive, Suite D
Charlotte, North Carolina 28217
704) 525-5125
ENGINEERING ALTERNATIVES ANALYSIS(EAA)
TABLE OF CONTENTS
1.0 GENERAL INFORMATION 1
2.0 OTHER CONSIDERATIONS 6
3.0 REMARKS 7
FIGURES
Figure 1 Topographic Location Map
Figure 2 Discharge Location Map
APPENDICES
Appendix A Summary Tables for Groundwater Monitoring Performed in February and August
2020 and Maps Showing Sample Locations
Appendix B Process and Instrumentation Diagram
Appendix C Description of Low-Flow Characteristics for Unnamed Tributary to Irwin in
Charlotte, North Carolina Prepared by J. Curtis Weaver of the United States
Geological Survey—March 26, 2021
Appendix D Screenshot NCDEQ's Stream Classification Webpage
Appendix E Excerpts from Final Category 5 Assessments—303(d) List(2018—Final &2020 Draft)
Appendix F Records of Communication
Appendix G Copy of City of Charlotte which Prohibits the Discharge of Groundwater to POTW
Appendix H Documentation Regarding Local Government Review Forms
1.0 GENERALINFORMATION
A. Project Identification
o Facility Name: Central Square
o Contact:Mr.Barry James;TGACSE Central Square, LLC c/o Crosland Southeast
o Facility County: Mecklenburg
o Facility Mailing Address: 201 South College Street,Suite 1300
Charlotte, North Carolina 28244
o Facility Physical Address: Multiple Addresses Associated with Facility
1314 1318, 1322, 1324, 1326, 1330, 1332,
1334, 1336, 1400, and 1426 Central
Avenue
1111, 1113, and 1235 Pecan Avenue
Charlotte,North Carolina 28205
o Facility Telephone Number: Not Applicable
o EAA Preparer's Name:ESC Southeast, LLP
o EAA Preparer's Mailing Address: 1812 Center Park Drive; Suite D
Charlotte,North Carolina 28217
o EAA Preparer's Telephone Number: 704-525-5152 (Office)
704-280-7422 (Mobile)
o EAA Preparer's E-mail Address: [e-mail]
B. Project Description
o TGACSE Central Square is redeveloping an approximately 12-acre property
located southwest of the intersection of Central and Pecan Avenue in Charlotte,
Mecklenburg County, North Carolina. The property will be redeveloped as
apartments, green space, offices, and retail buildings. The property is a North
Carolina Brownfields site (Brownfields ID No. 24002-20-060). According to the
Mecklenburg Property Ownership and Land Records Site (POLARIS), the
Brownfields Property consists of parcel numbers: 08117722 (4.545 acres);
08117723(6.320 acres);and 08117724A/08117724B(1.145 acres)and is owned
by TGACSE Central Square, LLC.
o The depth to the water table at the subject property has been measured at
depths range from less than 3 feet to approximately 17 feet below ground
surface (bgs). A summary table is included in Appendix A and shows
groundwater elevation data. During the course of construction, groundwater
may be encountered.
o Groundwater monitoring of seven temporary monitoring wells was performed
in February 2020 and in two additional temporary monitoring wells in August
2020 as part of the Brownfields process. Several volatile organic compounds
VOCs) were detected in one groundwater sample including
bromodichloromethane (maximum concentration of 1.9 micrograms per liter
ug/I]), chloroform (maximum concentration of 9.2 ug/l), and
dichlorobromomethane (maximum concentration of 1.3 ug/l). ECS did not
identify North Carolina surface water standards for these three VOCs. The
detected concentrations of bromodichloromethane and
dichlorobromomethane exceed their respective North Carolina groundwater
standards of 0.6 and 0.4 ug/I. The detected concentration chloroform did not
exceed North Carolina groundwater standards. In addition, barium was
detected in each of seven groundwater samples (maximum concentration of
261 ug/l) and chromium was detected in three of seven groundwater samples
maximum concentration of 128 ug/l). ECS did not identify North Carolina
surface water standards for barium. ECS did identify North Carolina surface
water standards for trivalent and hexavalent chromium. The analysis of the
groundwater samples collected by ECS were not speciated for trivalent and
hexavalent chromium. The North Carolina surface water standard for trivalent
chromium is dependent upon measured hardness in the receiving stream which
was not determined. Therefore, it is indeterminate whether the detected
concentrations of chromium in groundwater exceed North Carolina surface
water standards. The concentration of chromium exceeded the North Carolina
groundwater standard for this parameter (15 ug/l) in two of the samples. The
chromium exceedances may be the results of turbidity in the samples and may
not be representative of actual groundwater quality. The detected
concentration of barium did not exceed North Carolina groundwater standards.
Appendix A includes a summary table of the groundwater analytical data.
o There are several documented pollution incidents sites in the area which are
located upgradient of the subject site. Groundwater dewatering could affect
naturally groundwater flow patterns and cause contaminants not previously
detected on the site to be drawn onto the site by pumping influences.Such sites
include, but are not necessarily limited to:
Auto Verks at 1800 Commonwealth Avenue (Inactive Hazardous Sites
ID No. NONCD0001301) which was impacted by petroleum and
chlorinated solvents (tetrachloroethene or perchloroethene [PCE] and
trichloroethene [TCE]).
Commonwealth Avenue Dry Cleaners at 1809 Commonwealth Avenue
Inactive Hazardous Sites ID No. NONCD0003103).
Sunoco at 1231 Pecan Avenue (LUST Incident No. 8617) which was
impacted by petroleum.
o During construction, TGACSE Central Square, LLC proposes to collect
groundwater from the construction areas where excavations are expected to
intersect the water table using lateral drains and/or sumps. Sump pump(s)
which will discharge to an 18,000-gallon settling/holding tank equipped with
overflow and underflow weirs. A float-actuated pump will move water from the
18,000-gallon settling/holding tank to a 1,000-gallon polyethylene surge tank.
A pH sensor will be located upstream of the surge tank and will submit data to
a programmable logic controller (PLC). A carbon dioxide cylinder and flow
assembly will be plumbed to the influent line to the surge tank. Program logic
will be set such that if the pH in the influent is above a set point,carbon dioxide
will be dosed into the influent line via a solenoid valve to lower pH. The surge
tank will be outfitted with a recirculation loop and recirculation pump (1-
horspower centrifugal) for mixing of the influent after dosing with carbon
dioxide. A pH sensor will be located on the recirculation loop to provide data to
PLC to control carbon dioxide dosing rate and terminate dosing when not
needed.
Two 3-horsepower centrifugal pumps will be located downstream of the surge
tank to move water through two particulate bag filter housings plumbed in
parallel configuration; through two 1,000-pound granular activated carbon
GAC) vessels plumbed in parallel configuration; through an inverted "U" loop
with a siphon break; through a magnetic flow meter with totalizer; and then
through a discharge line to a drop inlet to the municipal stormwater system.
The surge tank will be outfitted with a 3-level float assembly to provide data to
the PLC. The PLC will be programmed to activate one pump when the lowest
float is actuated and the second pump when the next float is actuated (so both
pumps will run simultaneously). The highest float will actuate an alarm
condition and will notify the operator via telemetry.
The two particulate bag filters housings will be 32-inch with 3-bolt covers. Filter
size is anticipated to be 10 to 25 microns. The filter housings will be plumbed
and valved such that one or both may be on line at a given time and to provide
a means to change out bag filters without taking system off line.
The two GAC vessels will each contain approximately 1,000 pounds of virgin
coconut carbon with a 12 by 40 mesh size. The vessels will be plumbed and
valved such that one or both may be on line at a given time and to provide a
means to change out GAC media without taking system off line. In addition,the
plumbing and valving will be such to permit backwashing of the vessels.
Stormwater drop basins are located on the subject property and flow in
subsurface piping to a discharge point on an unnamed tributary to Little Sugar
Creek approximately 1,620 feet northwest of the subject property at a location
west of Hawthorne Lane and east of Louise Avenue at latitude 35.22364 north
and longitude 80.81916 west.
Appendix B is a Process and Instrumentation Diagram (PID) showing the main
components of the proposed water treatment system with the exception of the
18,000-gallon settling/holding tank and associated pump and controls.
o The construction dewatering activity is expected to occur over a period of
approximately seven months. After construction dewatering is completed,
permanent dewatering will be performed.
o During construction underslab and perimeter drains will be installed at the
foundations of buildings to be constructed on site. After foundation
construction is completed, groundwater which is collected in the drains will be
conveyed to a treatment system similar to that described previously except that
the 18,000-gallon settling/holding tank and carbon dioxide dosing system will
not be provided.
The Engineering Alternatives Analysis (EAA) guidance (revised October 2019) indicates that four
steps are to be followed in evaluating alternatives. The following paragraphs summarize these steps.
STEP 1-DETERMINE IF THE PROPOSED DISCHARGE WILL BE ALLOWED
Zero flow stream restrictions (15A NCAC 2B .0206[d][(2]) apply to oxygen-consuming
waste in zero-flow streams.
Although a determination has been made by the United States Geological
Survey (USGS) that the unnamed tributary to Little Sugar Creek where the
discharge will occur is most likely a zero-flow stream under 7Q10 conditions,
this restriction is not applicable because the wastewater is not an oxygen-
consuming waste. A copy of an email from the USGS regarding stream flow
characteristics is attached as Appendix C.
Receiving stream classification restrictions (e.g., ORW, WS, SA, NSW, and HQ class waters
have various discharge restrictions or require stricter treatment standards).
ECS determined that the stream classification for Little Sugar Creek is Class C
by reviewing data on NCDEQ's stream classification webpage on March 23,
2021. Therefore, restrictions based on stream classification are not applicable.
Appendix D includes a screenshot NCDEQ's stream classification webpage.
Basinwide Water Quality Plans. These basin-specific plans list NPDES permitting
strategies that may limit wastewater discharges to particular streams within the basin
due to lack of stream assimilative capacity,etc.
ESC reviewed the 2007 final draft basin specific water quality plan for the
Catawba River Basin found through the NCDEQ website at
https://files.nc.gov/ncdeq/Water%20Resources/files/publications/Final Draft
Catawba River Basin Plan 2007.pdf. This document does not contain any
specific discharge recommendations for Little Sugar Creek.
Impaired waters and TMDLs. Certain waterbodies listed as impaired on the 303(d) list
and/or subject to impending TMDLs may have wastewater discharge restrictions.
ESC reviewed the 303(d) lists for calendar years 2018 (final) and 2020 (draft)
found through the NCDEQ website
https://files.nc.gov/ncdeq/Water%20Quality/Planning/TM DL/303d/2016/2016
NC Category 5 303d list.pdf). Both the 2018 final listing and the 2020 draft
listing indicatehat Little Sugar Creek from the source to Archdale Road (in
Charlotte) is listed as impaired because of issues with copper. An excerpt of
this document is included as Appendix E. ESC contacted Ms. Pamela Behm
of the NCDEQ, Division of Water Quality, Modelling and Assessment Branch by
email on March 29, 2021 to make an inquiry regarding TDMLs and how they may
affect the proposed discharge. Ms. Behm forwarded an email on March 31,2021
in which she indicated if the discharge does not contain pollutants listed in the
TDMLs,the permitting process should be a straightforward process. Appendix F
includes a copy of the referenced email.
Presence of Endangered Species. If endangered species are present in the proposed
discharge location,there may be wastewater discharge restrictions.
ESC contacted Ms.Olivia Munzer of the North Carolina Wildlife Resource Commission
by email on March 29, 2021. ESC also contacted Mr. David Cox of the North Carolina
Wildlife Resource Commission by email on March 31,2021. On April 1,2021, Mr.Cox
responded by email. He indicated that an historic (1987) record for Carolina
heelsplitter (Lasmigona decorada) was identified and a more recent surveys
identified the Asiatic clam (Corbicula sp.). Mr. Cox indicated that he did not expect
impacts to listed aquatic species. Appendix F includes copies of email
correspondence with these individuals.
o STEP 2- PROVIDE REASONABLE PROJECTIONS FOR POPULATION AND FLOW
Information provided by United States Census Bureau indicates the estimated population of
Mecklenburg County was 1,110,356 in July 2019
https://www.census.gov/quickfacts/fact/table/mecklenburgcountynorthcarolina/PST0452
19). According to information from the North Carolina Office of State
Budget and Management fo und on the internet atgg
https://files.nc.gov/ncosbm/demog/countygrowth 2040.html the population of
Mecklenburg is projected to increase to County 1,329,914 by July 2030 and to 1,540,320 by
July 2040.
The expected population increase will not increase the anticipated flow rate because the
flow rate is not dependent upon the size of the population.
STEP 3-EVALUATE TECHNOLOGICALLY FEASIBLE ALTERNATIVES
Connection to an existing wastewater treatment plant(public or private)
The City of Charlotte prohibits the discharge of groundwater to its POTW under
Chapter 23, Section 79 of its Code of Ordinances. A copy of an excerpt from this
section is attached as Appendix G.
No private wastewater treatment plants are located near the subject site so
connection to a private wastewater treatment plant is not practical.
Land application alternatives, such as individual/community onsite subsurface systems,
drip irrigation,spray irrigation and/or high-rate infiltration galleries.
Land application is not feasible land available constraints in this urban area of
Charlotte. The EAA guidelines include the following verbiage: ". . . it would not be a
feasible alternative in downtown Charlotte, where there is no land available for
wastewater application."
Wastewater reuse
It is not practical to reuse the extracted groundwater on this project because the
Brownfields Agreement for this property is expected to prohibit the reuse of
extracted groundwater.
Surface water discharge through the NPDES program
ECS believes discharge to surface water through the NPDES program is the most viable option for
the proposed discharge given the nature of the project, prohibitions to other discharge options, and
financial considerations. ECS is aware of several similar dewatering projects in the area which
NCDEQ approved for NPDES discharges in recent years. These include the construction dewatering
projects: Charlotte Area Transit System Construction project (Permit No. NC008371), the
Myrtle/Morehead Storm Drainage Improvement project (Permit Nos. NC0089443 and NC0089729),
Dimensional Place Construction project (Permit No. NC0089656). Permanent dewatering projects
include: Carillon Building Dewatering System (Permit No. NC0085731), Gateway Village (Permit No
NC0086517), Wells Fargo Tryon Street (Permit No NC0088226), BB&T Ballpark (Permit No
NC0089273).
Combinations of the aforementioned alternatives
As discussed previously, connection to an existing wastewater facility, land
application (surface and subsurface), and water reuse are not feasible alternatives.
Therefore, a combination of the aforementioned alternatives is not a feasible
alternative.
STEP 4-EVALUATE ECONOMIC FEASIBILITY OF ALTERNATIVES
According to guidelines for the Engineering Alternatives Analysis, a 20-year Present Value of
Costs Analysis (PVCA) should be performed to provide valid cost comparisons among all
technologically feasible wastewater alternatives identified in Step 3. As indicated in Step 3, ECS
believes discharge to surface water through the NPDES program is the single viable option for
the proposed discharge given the nature of the project, prohibitions to other discharge options,
and financial considerations. Therefore, therefore since there are no options to compare, this
step is not applicable.
2.0 OTHERCONSIDERATIONS
According to guidelines for the Engineering Alternatives Analysis, the Environmental
Management Commission may not act on an application for a new non- municipal domestic
wastewater discharge facility until it has received a written statement from each city and county
government having jurisdiction over any part of the lands on which the proposed facility and
its appurtenances are to be located. The guidelines indicate that the applicant must submit
requests for this information by certified mail, return-receipt-requested.The written statement
shall document whether the city or county has a zoning or subdivision ordinance in effect and (if
such an ordinance is in effect)whether the proposed facility is consistent with the ordinance. The
guidelines indicate that if the applicant does not receive a response from one or both of these
local government entities within 15 days of receiving the request, the applicant may submit an
application for a new non-municipal domestic wastewater discharge facility provided it can
document that these entities received the requests and were allowed at least 15 days to respond.
ECS has not received responses from either of the two local government entities at this time.
Appendix H includes copies the request letters and certified mail receipts. These documents
demonstrate that ESC provided proper notification to these government entities and
responses were not received within the specified time. (If ECS receives responses from either of
these entities at a later, it will forward them to NCDEQ.)
3.0 REMARKS
The activities and evaluative approaches used in this assessment are consistent with those normally
employed in environmental assessment projects of this type. Our evaluation of site conditions has
been based on our understanding of the site project information and the data obtained during our
field activities.
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SITE TOPOGRAPHIC LOCATION MAP
CAHRLOTTE EAST CENTRAL SQUARE
7.5 MINUTE QUADRANGLE Central Avenue at Pecan Avenue
DATED 2019 Charlotte, Mecklenburg, North Carolina
ECS PROJECT NO.49-10756-C
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SOURCE: FIGURE 2
VIRTUAL CHARLOTTE WEB MAPPING APPLICATION DISCHARGE LOCATION MAP
ACCESSED APRIL 5,2021 CENTRAL SQUARE
AS Central Avenue at Pecan Avenue
APPROXIMATE SCALE: Charlotte, Mecklenburg, North Carolina
1 INCH=382 FEET
p 382 FEET ECS PROJECT NO.49-10756-C
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APPENDICES
APPENDIX A
SUMMARY TABLES FOR GROUNDWATER MONITORING PERFORMED
IN FEBRUARY AND AUGUST 2020
AND MAPS SHOWING SAMPLE LOCATIONS
TABLE 1: TEMPORARY MONITORING WELL CONSTRUCTION AND WATER ELEVATIONS
PECAN & CENTRAL AVENUE
CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA
ECS PROJECT NO. 49-10756-A
Well Date TOC Depth to
Calculated
ID Installed
Total Depth Groundwater
Elevation Water
Elevation
TW-1 2/7/2020 20 715.64 7.98 707.66
TW-2 2/7/2020 28 718.64 7.19 711 .45
TW-3 2/7/2020 20 718.40 2.12 716.28
TW-4 2/7/2020 35 737.42 19.95 717.47
TW-5 2/7/2020 30 735.96 16.94 719.02
TW-6 2/7/2020 26 733.58 10.80 722.78
TW-7 2/7/2020 20 734.24 13.15 721 .09
Notes: Measurements are in feet.
TOC = Top of Casing
Depth to Water & Calculated Groundwater Elevation based on the TOC elevation
TABLE 3:SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
PECAN&CENTRAL AVENUE
CHARLOTTE,MECKLENBURG COUNTY,NORTH CAROLINA
ECS PROJECT NO.49-10756-A
Parameter ANALYTICAL RESULTS COMPARISON CRITERIA
Sample ID TW-1 TW-2 TW-3 TW-4 TW-S TW-6 TW-7
NC2LGWg5 GCL NCDEQ RESIDENTIAL NCDEQ NON-RESIDENTIAL
Collection Date 2/11/2020 2/11/2020 2/11/2020 2/10/2020 2/10/2020 _ 2/10/2020 2/10/2020 VIOL VIOL
Volatile Organic Compounds(VOCs)by EPA Method 8260
Bromodichloromethane BRL 1.9 BRL BRL BEL BRL BRL 0.6 NS 8.8 38
Chloroform BRL 9.2 BRL BRL BRL BRL BRL 70 70,000 8.1 36
Dibromochloromethane BRL 1.3 BRL BRL BRL BRL BRL 0.4 400 N5 NS
Seml-Volatile Organic Compounds(SVOCs)by EPA Method 8270
For All I BRL I BRL I BRL I SRL I BRL i BRL I BRL I NS I NS NS I NS
Resource Conservation and Recovery Act(RCRA)Metals by EPA Methods 6020,7471,and 7199
Mercury BRL BRL BRL BRL BRL BRL BRL 1 NS 0.18 0.75
Barium 104 218 261 39.6 17.7 43.1 23.9 700 700,000 NS NS
Chromium BRL 94.0 128 BRL 9.3 BRL BRL 10 10,000 NS NS
Notes:
Results presented in micrograms per liter(ug/L),analogous to parts per billion(ppb)
NC2LGWQ5=North Carolina 2L Groundwater Quality Standards
NCDEQ=North Carolina Department of Environmental Quality
VISL=Vapor Intrusion Screening Levels
DUP-3 is a duplicate sample collected front MW-3
NS=No Standard
1 Flag denotes an estimated concentration between the laboratory reporting limit and the laboratory detection limit
GCL=Gross Contamination Limit
Bold denotes an exceedance of the NC2IGWQS
troika denotes an exceedance of the NCDEQ Residential VISL
Underline denotes an exceedance of the NCDEQ Non-Residential VISL
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t APPROXIMATE TEMPOARY MONITORING WELL LOCATION
XXX•XX — — — — — CALCULATED WATER SURFACE CONTOUR
707.66 GROUNDWATER SRUFACE ELVATION l2 i10 i20 l ESTIMATED GROUNDWATER FLOW DIRECTION
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I FIGURE 4
SOURCE: GROUNDWATER ELEVATIONS AND FLOW
DIRECTION
GOOGLE EARTH AERIAL IMAGERY,2019 C CENTRAL AVENUE PROPERTY
SCALE: CHARLOTTE,NORTH CAROLINA
AS SHOWN
CS PROJECT NO.49-10756-A
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TABLE 3: SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
FORMER SHERWIN WILLIAMS-ADDITIONAL BROWNFIELDS ASSESSMENT
CENTRAL AVENUE&PECAN AVENUE
CHARLOTTE,MECKLENBURG COUNTY,NORTH CAROLINA
NCDEQ BROWNFIELDS PROJECT NO.24002-20-060
ECS PROJECT NO.49-10756-DO
PARAMETER ANALYTICAL RESULTS SCREENING LEVEL
Sample ID TW-1 TW-2 TW-DUP Trip Blank
NC2LGWQS
Collection Date 8/5/20
Semi-Volatile Organic Compounds(SVOCs)By EPA Method 8270
For All ND ND ND ND Various
Volatile Organic Compounds(VOCs)By EPA Method 8260
Acetone 25.0 25.0 25.0 52.3 6,000
All other VOCs ND ND ND ND Various
Notes:
Results presented in micrograms per liter(ug/L),analogous to parts per billion(ppb)
NC2LGWQS=North Carolina 2L Groundwater Quality Standard as of April 1,2013
NS=No Standard
ND=Not detected at or above adjusted reporting limit.
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LEGEND
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APPROXIMATE GROUNDWATER SAMPLE LOCATION r 11,,,, r
I FIGURE 5
SOURCE: GROUNDWATER SAMPLE LOCATION MAP
GOOGLE EARTH AERIAL IMAGERY,2019 Former Sherwin Williams Brownfields Site
Central Avenue at Pecan Avenue
SCALE: Charlotte, Mecklenburg, North Carolina
AS SHOWN
ECS PROPOSAL NO.49-10756-D
Brownfields Project No.:24002-20-060
PA PENDIX B
SCHEMATIC DRAWING OF THE PROPOSED TREATMENT EQUIPMENT
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APPENDIX C
DESCRIPTION OF LOW-FLOW CHARACTERISTICS FOR UNNAMED TRIBUTARY TO IRWIN IN
CHARLOTTE, NORTH CAROLINA PREPARED BY J. CURTIS WEAVER OF THE UNITED STATES
GEOLOGICAL SURVEY-MARCH 26,2021
Joseph Patrick Nestor
From: Weaver,John C <[e-mail]>
Sent: Friday, March 26, 2021 11:05 AM
To: Joseph Patrick Nestor
Cc: Hill, David A; [e-mail]; Montebello, Michael J;Albertin, Klaus P;
Weaver,John C
Subject:USGS response to DWR USGS Low Flows request#2021-115 (dated 2021/03/21)for UT
Little Sugar Creek Mecklenburg County...RE: [EXTERNAL] Low-flow request approval
Mr. Nestor,
In response to your inquiry about the low-flow characteristics for a location on an unnamed tributary to Little Sugar
Creek between Hawthorne Lane and Louise Avenue in downtown Charlotte in Mecklenburg County,the following
information is provided:
A check of the low-flow files here at the USGS South Atlantic Water Science Center(Raleigh office) does not indicate a
previous low-flow determination for the point of interest, identified by the lat/long coordinates (35.22363,-80.81879)
provided via email dated 03/24/2021 from the DWR USGS Low Flow portal following your request submission.
No USGS discharge records are known to exist for this point of interest.
A basin delineation completed using the online USGS StreamStats application for North Carolina
https://streamstats.usgs.gov/ss/) indicates the drainage area for the point of interest(StreamStats adjusted
coordinates 35.22362, -80.81878 NAD83) is 0.51 sqmi, which confirms the drainage area submitted as part of the
request information.
For the record:
1) Initial site information submitted via the low-flow request portal indicated the point of interest as being located on
Little Sugar Creek. However,supplementary information included with the request as well as plotting the above
location coordinates places the point of interest on an unnamed tributary to Little Sugar Creek between Hawthorne
Lane and Louise Avenue in downtown Charlotte. The low-flow characteristics provided below are for the point of
interest on the unnamed tributary to Little Sugar Creek.
2) Please be aware a degree of uncertainty exists in the low-flow estimates provided below because of the high
percentage of impervious area arising from urbanization in the basin upstream from the point of interest, including the
possibility of low flows being affected by diversion(s)to or from the stream upstream from the point of interest. While
no formal USGS study has been conducted in North Carolina to examine the effects of development and(or) urbanization
on low-flow characteristics,the general thought within the hydrologic community is that development has the potential
to reduce base flow characteristics. Base flow is the portion of the streamflow sustained by discharge from the adjacent
surficial aquifers into the streams and is governed by the amount of runoff that infiltrates into the ground for later
discharge to streams. As noted below,there is a wide range in the low-flow yields based on the nearby USGS sites used
as index sites.
For streams in Mecklenburg County, low-flow characteristics published by the USGS are provided in the following
reports:
1
1)The first is a statewide report completed in the early 1990's. It is USGS Water-Supply Paper 2403, "Low-flow
characteristics of streams in North Carolina" (Giese and Mason, 1993). An online version of the report is available at
https://pubs.usgs.gov/wsp/2403/report.pdf. The report provides the low-flow characteristics (based on data through
1988)via regional relations and at-site values for sites with drainage basins between 1 and 400 sqmi and not considered
or known to be affected by regulation and/or diversions.
2)The second is a statewide report published in March 2015. It is USGS Scientific Investigations Report 2015-5001,
Low-flow characteristics and flow-duration statistics for selected USGS continuous-record streamgaging stations in
North Carolina through 2012" (Weaver, 2015). The report is available online at
https://pubs.usgs.gov/sir/2015/5001/. The report provides updated low-flow characteristics and flow-duration statistics
for 266 active (as of 2012 water year) and discontinued streamgages across the state where a minimum of 10 climatic
years discharge records were available for flow analyses.
Low-flow characteristics estimated for point of interest:
Inspection of the second above-referenced report indicates the presence of ten (10)continuous-record streamgages
10) in the general vicinity of the point of interest where low-flow characteristics were published. Among these 10 index
sites,the low-flow discharge yields for the indicated flow statistics are as follows:
Annual 7Q10 low-flowyields==>from 0 to 0.16 cfsm (average about 0.039 cfsm, median about1g0.0 2 cfsm) (zero flow at
3 of 10 index sites)
Annual 30Q2 low-flow yields==>from 0.082 to 0.36 cfsm (average about 0.17 cfsm, median about 0.14 cfsm)
Winter 7Q10 low-flow yields==>from 0.016 to 0.25 cfsm (average about 0.087 cfsm, median about 0.07 cfsm)
Annual 7Q2 low-flow yields==>from 0.012 to 0.25 cfsm (average about 0.081 cfsm, median about 0.045 cfsm)
Average annual discharge yields==>from 0.9 to 1.6 cfsm (average about 1.2 cfsm, median about 1.1 cfsm)
Application of the above range in yields to the drainage area (0.51 sqmi)for the point of interest results in the following
estimated low-flow discharges:
Annual 7Q10 low-flow discharges==>from 0 to 0.082 cfs(average about 0.02 cfs, median about 0.0061 cfs) 4 rounded
down to zero flow
Annual 30Q2 low-flow discharges==>from 0.042 to 0.18 cfs (average about 0.087 cfs, median about 0.071 cfs) 4
rounded to 0.08 cfs
Winter 7Q10 low-flow discharges==>from 0.0082 to 0.13 cfs(average about 0.044 cfs, median about 0.036 cfs) 4
characterized as "<0.05 cfs"
Annual 7Q2 low-flow discharges==>from 0.0061 to 0.13 cfs(average about 0.041 cfs, median about 0.023 cfs) 4
characterized as"<0.05 cfs"
Average annual discharge discharges==>from 0.46 to 0.82 cfs(average about 0.61 cfs, median about 0.56 cfs) 4
rounded to 0.6 cfs
Please note there is a wide range in the low-flow yields for each of the statistics. The range in yields is considered
reflective of the unknown effects that development and(or) urbanization may have on low flows in streams, resulting in
a higher degree of uncertainty or lack of confidence in the estimates.
Please note:
1)The estimated flows are provided in units of cubic feet per second (cfs).
2
2)The low-flow yields provided above are rounded to 2 significant figures. Estimated low-flow discharges less than 1
cfs are rounded to 2 significant figures. If between 1 and 100 cfs,then rounded to 1 decimal place; if greater than 100,
then rounded to the nearest whole number(zero decimal places).
3)The information provided in this message is based on a preliminary assessment and considered provisional, subject
to revision pending collection of future data and further analyses.
These provisional streamflow statistics are provided via the DWR USGS Low Flows cooperative agreement between
the USGS and the N.C. Department of Environmental Quality, Division of Water Resources.
Hope this information is helpful.
Thank you.
Curtis Weaver
3.Curtis Weaver, Hydrologist,PE Email:icweaver(&usas.aov
USGS South Atlantic Water Science Center Online:httns://www.usgs.gov/centers/sa-water
North Carolina-South Carolina-Georgia
3916 Sunset Ridge Road
Raleigh,NC 27607
Phone:[phone] // Fax:[phone]
From:Albertin, Klaus P<[e-mail]>
Sent:Wednesday, March 24, 2021 8:21 AM
To:[e-mail]
Cc:Albertin, Klaus P<[e-mail]>; Hill, David A<[e-mail]>; [e-mail];
Weaver,John C<[e-mail]>; Montebello, Michael J <[e-mail]>
Subject: [EXTERNAL] Low-flow request approval
This email has been received from outside of DOI-Use caution before clicking on links,opening attachments,or responding.
Your request has been approved and will be forwarded to USGS. A response from USGS usually takes 7- 10 business
days.
Request Flow Statistic Approval
Request ID: 115
Requestor:Joseph Nestor
Requestor e-mail:[e-mail]
Requestor Phone: [phone]
3
Local Government:
Public Water Supply:
Consultant: ECS Southeast, LLP
Contact:Joseph Nestor
Reason: Permit
River/Stream: Little Sugar Creek
Drainage Area (sq. mi.): 0.51 square miles
Latitude: 35.22363
Longitude: -80.81879
Other Information: We are proposing to discharge treated water which will be generated from construction dewatering
into the municipal storm water system near Central and Pecan Avenues in Charlotte.The groundwater at the site has
been determined to contain volatile organic compounds which will be treated prior to discharge to the stormwater
system.The water will flow by gravity through the storm water system and will daylight and discharge into an unnamed
tributary of Little Sugar Creek West of Hawthorne Lane at latitude 35.22363 N and longitude 80.81879 W.
Statististics: ["7Q10","30Q21
Approved by: Albertin, Klaus P
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4
APPENDIX D
SCREENSHOT NCDEQ'S STREAM CLASSIFICATION WEBPAGE
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6:16 PM
3 23 2021
APPENDIX E
EXCERPT FROM FINAL CATEGORY 5 ASSESSMENTS-303(D) LIST
APPENDIX F
RECORDS OF COMMUNICATION
Joseph Patrick Nestor
From: Behm, Pamela <[e-mail]>
Sent: Wednesday, March 31, 2021 2:53 PM
To: Joseph Patrick Nestor
Cc: Roger A Smith, P.G.
Subject: Re: [External] FW: Impaired waters and TMDLs - Information for NPDES Permit
Application to be Prepared for Central Square Project
I am sorry your first email was never delivered to my inbox. Not sure what happened there.
permitting branch about this proposal? Generally, your consultation wouldHaveyoutalkedwiththeNPDESpegpp
begin there. I'm not very familiar with the type of project you propose or how it is usually permitted. If a TMDL
is in place, NPDES will just make sure to follow the allocations within the TMDL. NPDES will follow up with my
group in the case of any questions about permit limits. In your case, if you don't think your discharge is going
to contain the pollutants outlined in the TMDLs,then it should be a straightforward process.
You can find the actual TMDL documents on our website (https://deq.nc.gov/about/divisions/water-
resources/planning/modeling-assessment/tmdls/draft-and-approved-tmdls#Catawba), which should provide
additional information on allocations.
Regards,
Pam
From:Joseph Patrick Nestor<[e-mail]>
Sent:Wednesday, March 31, 2021 2:19 PM
To: Behm, Pamela <[e-mail]>
Cc: Roger A Smith, P.G. <[e-mail]>
Subject: [External] FW: Impaired waters and TMDLs- Information for NPDES Permit Application to be Prepared for
Central Square Project
CAUTION:External email. Do not click links or open attachments unless you verify.Send all suspicious email as an attachment to
Report Spam.
Ms. Behm:
Our client has asked that we follow up on this inquiry.We have included the original attachments with this email.The
project has a tight timeline and client wishes to have NPDES permit application submitted for processing as soon as
possible.
Can you confirm receipt of the inquiry and let us know when we may expect a response?
Thank you.
JOSEPH PATRICK NESTORI Environmental Principal
ECS SOUTHEAST, LLP I T 704.525.51521C 704.280.7422
www.ecslimited.com
Confidential/proprietary message/attachments. Delete message/attachments if not intended recipient.
From:Joseph Patrick Nestor<[e-mail]>
Sent: Monday, March 29, 2021 4:43 PM
1
To: '[e-mail]'<[e-mail]>
Subject: Impaired waters and TMDLs-Information for NPDES Permit Application to be Prepared for Central Square
Project
Ms. Behm:
ECS Southeast, LLP (ECS) has been requested by a client to prepare NPDES permit application for construction
dewatering at a property located Southwest of the intersection of Pecan and Central Avenues in Charlotte. If approved,
treated groundwater from the dewatering operation will be discharged to an unnamed tributary to Little Sugar Creek in
Charlotte A guidance document provided by the NPDES permitting group indicates we should investigate Impaired
waters and TMDLs to determine if such a discharge would be prohibited before making the effort to prepare the
application. An excerpt from that guidance is below:
Impaired waters and TMDLs. Certain waterbodies listed as impaired on the 303(d) list and/or subject to impending
TMDLs may have wastewater discharge restrictions. The list of 303(d) impaired waters is located on the DWR
website, or you may contact the DWR Modeling and Assessment Branch
http://portal.ncdenr.org/web/wq/ps/mtu).
We have reviewed the TMDL interactive map found on the NCDQ website. We found that TMDLS are in place for (1)
fecal coliform, (2) low dissolved oxygen, and (3) turbidity for Little Sugar Creek in addition to a statewide TMDL for
Mercury.Screenshots from the NCDEQwebpage regarding TDMLs for fecal coliform, low dissolved oxygen,and turbidity
are attached. We do not believe our proposed discharge would be restricted based upon the aforementioned
parameters.
Please let us know if there are any impending TMDLs which may have wastewater discharge restrictions with respect to
the proposed discharge.
If you have questions, please contact us.
Thank you.
JOSEPH PATRICK NESTOR'Environmental Principal
T 704.525.5152 I C 704.280.7422
1812 Center Park Drive, Suite D'Charlotte j NC 128217
ECS SOUTHEAST, LLP
www.ecslimited.com
Linkedln I Facebook I Twitter
Confidential/proprietary message/attachments. Delete message/attachments if not intended recipient.
This message has been analyzed by Deep Discovery Email Inspector.
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Joseph Patrick Nestor
From: Hill, David A <[e-mail]>
Sent: Wednesday, March 31, 2021 3:24 PM
To: Joseph Patrick Nestor; Roger A Smith, P.G.
Cc: Behm, Pamela;Templeton, Mike; Montebello, Michael J; Coco, Nick A; Basinger, Corey
Subject: Impaired waters and TMDLs - Information for NPDES Permit Application to be Prepared
for Central Square Project
Hello Mr. Nestor,
I was forwarded your TMDL/discharge inquiry from Pam Behm in our Modeling unit. Your question implies
that your project is proposing to discharge construction related dewatering wastewater to an UT to Little
Sugar Creek in Charlotte. According to 15A NCAC 2H .0106(f)(7) groundwater generated by well construction
or other construction activities are deemed permitted "...provided that no water quality standards are
contravened, or are expected to be contravened....". You believe that your activities do not trigger the TMDL
requirements that you identified, but for the discharge to qualify as deemed permitted, all water quality
standards in 15A NCAC 2B, EPA National Recommended Water Quality Standards, and NC Protective instream
values would also need to be met. If that is the case, you could proceed with the deemed permitted discharge
activity, but all potential sources of groundwater contamination should be characterized through a thorough
site assessment. The Division of Waste Management maintains project/incident maps at:
https://deq.nc.gov/about/divisions/waste-management/waste-management-rules-data/waste-management-
gis-maps that may assist you in evaluating if your project activities may have reasonable potential to trigger
NPDES permitting requirements. You can also contact Corey Basinger(cc'd above) from our Mooresville
Regional Office for local assistance.
If you determine that your project activities would require an NPDES permit, please review our application
requirements at: https://deq.nc.gov/about/divisions/water-resources/water-qualitv-permitting/npdes-
wastewater/npdes-permitting-process. An application for proposed discharge should be submitted at least
180 days from the proposed date of discharge.
Feel free to contact me if you have any further questions.
Sincerely,
David Hill
Environmental Specialist II
Industrial Permitting Unit
Email preferred during this time*
NC DEQ/ Division of Water Resources/Water Quality Permitting Section
NPDES Industrial Permitting Unit
919 707 3612 office
919 707 9000 main office
david.hilk ncdenr.gov
Physical Address: 512 North Salisbury St.,Raleigh, NC, 27604
Mailing Address: 1617 Mail Service Center, Raleigh, NC, 27699-1617
Email correspondence to and from this address is subject to the
North Carolina Public Records Law and may be disclosed to third parties.
1
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2
Joseph Patrick Nestor
From: Cox, David R. <[e-mail]>
Sent: Thursday, April 1, 2021 11:39 AM
To: Joseph Patrick Nestor
Cc: Munzer, Olivia; Roger A Smith, P.G.
Subject: RE: [External] Engineering Alternatives Evaluation for NPDES Permitting
Importance: High
We took a quick look in the NC Natural Heritage data and NCWRC database for listed aquatic species in Little Sugar
Creek. We found only a historic(1987) record for Carolina heelsplitter(Lasmigona decorada).The more recent surveys
only found Asiatic clam (Corbicula sp.). We don't expect any impacts to listed aquatic species.—David
David R. Cox, Supervisor
Habitat Conservation Division
NC Wildlife Resources Commission
NCWRC—Rogers Depot
1718 NC Hwy.56 West
Creedmoor, NC 27522
Phone:[phone]
Fax:[phone]
[e-mail]
Get NC Wildlife Update--news including season dates, bag limits, legislative updates and more--delivered to your
Inbox from the N.C.Wildlife Resources Commission.
From:Joseph Patrick Nestor<[e-mail]>
Sent:Wednesday, March 31, 2021 2:14 PM
To:Cox, David R. <[e-mail]>
Cc: Munzer, Olivia <[e-mail]>; Roger A Smith, P.G.<[e-mail]>
Subject: RE: [External] Engineering Alternatives Evaluation for NPDES Permitting
CAUTION: External email. Do not click links or open attachments unless you verify.Send all suspicious email as an attachment to
Report Spam.
David
Our client asked that we make an inquiry to your agency to see if anyone else may be able to respond to our request for
information regarding endangered species while Olivia is on vacation.The project has a tight timeline and client wishes
to have NPDES permit application submitted for processing as soon as possible.
You were listed as an alternate contact on Olivia's automatic out of office replay and that is why we are reaching out to
you.
Thank you.
JOSEPH PATRICK NESTORI Environmental Principal
ECS SOUTHEAST, LLP I T 704.525.51521C 704.280.7422
www.ecslimited.com
1
Confidential/proprietary message/attachments. Delete message/attachments if not intended recipient.
From: Munzer, Olivia<[e-mail]>
Sent: Monday, March 29, 2021 7:24 AM
To:Joseph Patrick Nestor<[e-mail]>
Subject: RE: [External] Engineering Alternatives Evaluation for NPDES Permitting
Thank you. I will provide you a review probably next week when I get back from vacation.
Olivia Munzer
Western Piedmont Habitat Conservation Coordinator
NC Wildlife Resources Commission
From:Joseph Patrick Nestor<[e-mail]>
Sent:Thursday, March 25, 2021 7:30 AM
To: Munzer, Olivia<[e-mail]>
Cc: Roger A Smith, P.G. <[e-mail]>; Chris Orrell, P.G.<[e-mail]>; Matthew H. McDuffie,
P.G. <[e-mail]>
Subject: RE: [External] Engineering Alternatives Evaluation for NPDES Permitting
CAUTION: External email. Do not click links or open attachments unless you verify.Send all suspicious email as an attachment to
Report Spam.
Olivia
The information you provide will be used as part of application.An application is being prepared but has not been
submitted at this time.
The name on permit will likely be Central Square
Thank you for your help.
JOSEPH PATRICK NESTOR'Environmental Principal
ECS SOUTHEAST, LLP I T 704.525.5152 I C 704.280.7422
www.ecslimited.com
Confidential/proprietary message/attachments. Delete message/attachments if not intended recipient.
From: Munzer, Olivia <[e-mail]>
Sent:Wednesday, March 24, 2021 12:23 PM
To:Joseph Patrick Nestor<[e-mail]>
Cc: Roger A Smith, P.G. <[e-mail]>; Chris Orrell, P.G. <[e-mail]>; Matthew H. McDuffie,
P.G. <[e-mail]>
Subject: RE: [External] Engineering Alternatives Evaluation for NPDES Permitting
Hi Mr. Nestor,
Yes, I can look at the project to see if it has any direct impacts on species. We also like to look at the permit application.
Could you provide the project name so I can look at it online, or if you can provide the permit application?
Thank you,
2
Olivia
Olivia Munzer
Western Piedmont Habitat Conservation Coordinator
NC Wildlife Resources Commission
From:Joseph Patrick Nestor<[e-mail]>
Sent:Tuesday, March 23, 2021 4:46 PM
To: Munzer,Olivia<[e-mail]>
Cc: Roger A Smith, P.G.<[e-mail]>; Chris Orrell, P.G.<[e-mail]>; Matthew H. McDuffie,
P.G.<[e-mail]>
Subject: [External] Engineering Alternatives Evaluation for NPDES Permitting
CAUTION:External email. Do not click links or open attachments unless you verify.Send all suspicious email as an attachment to
Report Spam.
Olivia
ESC Southeast, LLP (ECS)am working on a National Pollutant Discharge Elimination System (NPDES) permit application
for a construction dewatering project in an urbanized area Charlotte.The NPDES permit branch of the North Carolina
Department of Environmental Quality(NCDEQ) has indicated that we should check with your agency to determine if
your rules would impose restrictions for the proposed discharge. Hence that is why we are contacting you.
The NPDES permitting process requires that an Engineering Alternatives Evaluation (EAA) be performed. NCDEQ
guidance indicates that the proponent must first determine if the discharge may be allowed.The guidance indicates that
the proponent should determine if there are any limitations as a result of the presence of endangered species.
Specifically the guidance states:
Presence of Endangered Species. If endangered species are present in the proposed discharge location, there may
be wastewater discharge restrictions. Endangered species
information may be included in the Basinwide Water Quality Plan, or you may contact the U.S.Fish and Wildlife
Service (919-856-4520), N.C. Wildlife Resources Commission (919-733-
3633), or the N.C. Natural Heritage Program (919-733-7701).
Analysis of groundwater samples collected from monitoring wells constructed at the site in 2020 indicated low levels of
VOCs and metals were detected in this sample.See attached table.We suspect the levels of chromium were turbidity
related and are not reflective of the quality of water which would be discharge if a NPDES permit is issued.
We anticipate treating extracted ground water to low(Non—detect to single digit part per billion levels) using granular
activated carbon. Discharge at the subject site will be to the City stormwater system.The stormwater system will
discharge to an unnamed tributary to Little Sugar Creek is within the Catawba River basin. Attached is an excerpt of the
USGS 7.5 minute topographic map (Charlotte East 2019)which shows the discharge point.We anticipate flow rates of 50
gpm or 72,000 gpd or less.
We would like to determine if there are endangered species in the basin downstream of the discharge point which may
cause wastewater discharge restrictions with respect to the proposed discharge.
Can you or another member of your staff help me on this matter, please?
Thanks
JOSEPH PATRICK NESTOR'Environmental Principal
T 704.525.51521C 704.280.7422
1812 Center Park Drive, Suite D I Charlotte I NC 128217
3
ECS SOUTHEAST, LLP
www.ecslimited.com
LinkedIn I Facebook I Twitter
Confidential/proprietary message/attachments. Delete message/attachments if not intended recipient.
Email correspondence to and from this sender is subject to the N.C.Public Records Law and may be disclosed to third parties.
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3/31/2021 Charlotte,NC Code of Ordinances
Sec. 23-79. - Prohibited discharge standards.
a) Genera/prohibitions. No user shall discharge or cause to be discharged into the POTW any pollutant or
wastewater which causes interference or pass through.The general prohibitions in this section apply to all
users of the POTW.
b) Specific prohibitions. No user shall discharge or cause to be discharged into the POTW the following:
1) Any pollutants which, either alone or by interaction with other pollutants, create a fire or explosive
hazard in the POTW, including, but not limited to,waste streams with a closed cup flashpoint of less than
140 degrees Fahrenheit(60 degrees Celsius) using the test methods specified in 40 CFR 261.21.
2) Solid or viscous pollutants,fats, oils, or greases from animal or vegetable origin in amounts which may
cause obstruction to the flow or other interference in the POTW.
3) Any wastewater having a pH less than 6.0 or greater than 12.0, or having any other corrosive property
capable of causing damage or hazard to the POTW.
4) Pollutants, including oxygen demanding pollutants(cBOD 5, BOD 5, COD, etc.), released in a discharge at
a flow volume,flow rate and/or pollutant concentration which, either singly or by interaction with other
pollutants,will cause interference with the POTW.
5) Any noxious or malodorous liquids,gases or solids which, either singly or by interaction with other
pollutants, are sufficient to create a public nuisance or hazard to life or are sufficient to prevent entry into
the sewers for maintenance and repair.
6) Any pollutant released in a discharge at a flow volume,flow rate and/or pollutant concentration which,
either singly or by interaction with other pollutants, may cause the POTWs effluent or any product of the
POTW, such as residues, sludges or scums,to be unsuitable for reclamation and recycling or to interfere
with the reclamation process. In no case shall a substance discharged to a POTW cause the POTW to be in
noncompliance with applicable local, state or federal sludge use or disposal guidelines.
7) Any pollutant released in a discharge at a flow volume,flow rate and/or pollutant concentration,which
will, either singly or by interaction with other pollutants, cause the POTW to violate any of its NPDES
and/or state disposal system permits or the receiving water quality standards.
8) Any discharge having a temperature greater than 150 degrees Fahrenheit(66 degrees Celsius) or which
will inhibit biological activity in the POTW treatment plant resulting in interference but, in no case, a
discharge which causes the temperature at the introduction into the POTW treatment plant to exceed 40
degrees Celsius(104 degrees Fahrenheit).
9) Any pollutant which results in the presence of toxic gases,vapors, or fumes within the POTW in a quantity
that may cause acute or chronic worker health and safety problems.
10) Any wastewater containing any radioactive wastes or isotopes except as specifically approved by CMUD in
compliance with applicable state or federal regulations.
11) Any discharge at a flow rate which will cause interference with the POTW.
12) Any pump and haul waste, except at discharge points designated by CMUD in accordance with section 23-
81 of this article.
13) Any waste stream which imparts color and passes through the POTW treatment plant, including, but not
limited to, dye wastes and vegetable tanning solutions,which consequently imparts sufficient color to the
POTW treatment plant's effluent,thereby violating any state or federal regulations pertaining to the
1/3
3/31/2021 Charlotte,NC Code of Ordinances
effluent from the plant or the receiving water.
14) Stormwater, surface water,groundwater, artisan well water, roof runoff, subsurface drainage,and
swimming pool drainage, unless specifically authorized by CMUD.
15) Any removed substances to include, but not be limited to, sludges,screening, or other residues from the
pretreatment of wastewater.
16) Petroleum oil, nonbiodegradable cutting oil, synthetic oil, or products of mineral oil origin, in amounts
that will cause interference or pass through.
17) Any indirect discharge which, alone or in combination with other wastewater, causes the treatment plant
effluent to violate state water quality standards for toxic substances as described in 15 A NCAC 2B .0200.
18) Any pollutant that will emulsify grease or oil or cause grease or oil to solidify or become more viscous.
19) At no time shall two successive readings on an explosion hazard meter, at the point of discharge into the
POTW, or at any point in the POTW, be neither more than five percent nor any single reading over ten
percent of the lower explosive limit(LEL).
20) Any material that would be identified as hazardous waste according to 40 CFR Part 261 if not disposed of
in a sewer, except as may be specifically authorized by CMUDD.
c) Processing and storage. Pollutants, substances or wastewaters prohibited by this section shall not be
processed or stored in such a manner that they could be discharged to the POTW.
When CMUD determines that a user(s) is contributing to the POTW, any of the above enumerated substances in such
amounts which may cause or contribute to interference of POTW operation or pass through, CMUD shall:
1) Advise the user(s)of the potential impact of the contribution on the POTW in accordance with section 23-
95. and
2) Take appropriate actions in accordance with article Ill,and the sections contained therein,for such user
to protect the POTW from interference or pass through.
d) National categorical pretreatment standards. Users subject to categorical pretreatment standards are
required to comply with applicable standards as set out in 40 CFR Chapter 1,Subchapter N, Parts 405-471:
1) Where a categorical pretreatment standard is expressed only in terms of either the mass or the
concentration of a pollutant in wastewater, CMUD may impose equivalent concentration or mass limits in
accordance with 40 CFR 403.6(c).
2) When wastewater subject to a categorical pretreatment standard is mixed with wastewater not regulated
by the same standard, CMUD shall impose an alternate limit using the combined wastestream formula in
40 CFR 403.6(e).
3) A user may obtain a variance from a categorical pretreatment standard if the user can prove, pursuant to
the procedural and substantive provisions in 40 CFR 403.13, that factors relating to its discharge are
fundamentally different from the pretreatment standard.
4) A user may obtain a net gross adjustment to a categorical standard in accordance with 40 CFR 403.15.
e) Specific pollutant limitations.An industrial waste survey is required prior to a user discharging wastewater
containing in excess of the following average discharge limits:
CBOD 250.0 mg/I
2/3
3/31/2021 Charlotte,NC Code of Ordinances
COD 500.0 mg/I
TSS 250.0 mg/I
NH 3 25.0 mg/I
Ammonia as N 20.0 mg/I
Arsenic 0.003 mg/I
Cadmium 0.003 mg/I
Chromium 0.05 mg/I (total chromium)
Copper 0.061 mg/I
Cyanide 0.015 mg/I
Lead 0.049 mg/I
Mercury 0.0003 mg/I
Nickel 0.021 mg/I
Silver 0.005 mg/I
Total Petroleum hydrocarbons 100.0 mg/I
Zinc 0.175 mg/I
Industrial waste survey information will be used to develop user-specific local limits when necessary to ensure that
the POTWs maximum allowable headworks loading are not exceeded for particular pollutants of concern.
User-specific local limits for appropriate pollutants of concern shall be included in wastewater permits. CMUD may
impose mass based limits in addition to, or in place of concentration based limits.
Ord. No. 5230, § 1(Exh.A), 10-28-2013)
3/3
APPENDIX H
DOCUMENTATION REGARDING LOCAL GOVERNMENT REVIEW FORMS
ECS SOUTHEAST LLP Setting the Standard for Service"
Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F-1078
NC Registered Geologists Firm C-553
SC Registered Engineering Firm 3239
April 28, 2021
VIA CERTIFIED MAIL
Stephanie C. Kelly
Clerk of the City of Charlotte
City of Charlotte
Charlotte-Mecklenburg Government Center
600 East 4th Street
Charlotte, NC 28202
RE: Local Government Review Form
NPDES Permit Application
Central Square
Property Located Southwest of Intersection of Central Avenue and Pecan Avenue
1318 and 1336 Central Avenue
Charlotte, Mecklenburg County, North Carolina
ECS Project No. 10756-C
Dear Ms. Kelly:
ECS Southeast, LLP (ECS) prepared this correspondence on behalf of its client TGACSE Central Square, LLC.
TGACSE Central Square, LLC intends to submit a National Pollutant Discharge Elimination System (NPDES)
Permit Application to the North Carolina Department of Environmental Quality (NCDEQ) for the discharge of
treated groundwater produced during construction dewatering and permanent building dewatering to an
unnamed tributary of Little Sugar Creek.The NCDEQ application process requires a review by local government
to verify the proposed discharge complies with local ordinances.
Attached please find a Local Government Review Form to be completed by a representative of the City of
Charlotte. The NCDEQ requires that the signature of the official signing the form be notarized. Included
with this Review Form is a copy of the Draft NPDES Permit Application for your review. Upon receipt of
the returned Review Form, ECS will finalize the Permit Application for submission to the NCDEQ.
Please complete the attached Review Form and return it to me at the following address.
Joseph P. Nestor, P.G., P.E.
ECS Southeast, LLP
1812 Center Park Drive,Suite D
Charlotte, NC 28217
ECS Capitol Services,PLLC • ECS Florida,LLC • ECS Mid-Atlantic,LLC • ECS Midwest,LLC • ECS Southeast,LLP • ECS Southwest,LLP
www.ecslimited.com
April 28, 2021
Please let us know if you have any questions or would like additional information.We look forward to
hearing from you.
Respectfully submitted,
ECS SOUTHEAST, LLP
r•seph P. Nestor, P.G., P.E.
Environmental Principal
[e-mail]
704-280-7422
ger A. ith, P.G.
Principal Geologist
[e-mail]
704-378-9015
Attachments: Local Government Review Form
Draft NPDES Permit Application
Wage
SENDER: COMPLETE THIS SECTION COMPLETE THIS SECTION ON DELIVERY
Complete items 1,2,and 3.A. Signature
Print your name and address on the reverse X
Agent
so that we can return the card to you. Addressee
Attach this card to the back of the mailpiece,
B. Received by(Printed Name) C. Date of Delivery
or on the front if space permits.
1. Article Addressed to: D. Is delivery address different from item 1? 0 Yes
J-PVh,,,t C - t If YES,enter delivery address below: 0 No
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2. Article Number(Transfer from service label) 0 Collect on Delivery Restricted Delivery Signature Confirmation
lsured Mail 0 Signature Confirmation
7020 0640 0002 0703 2960 mired Mail Restricted Delivery Restricted Delivery
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PS Form 3811,July 2015 PSN 7530-02-000-9053 Domestic Return Receipt
U.S. Postal Service`"'
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CERTIFIED MAIL® RECEIPT
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PS Form 3800,April 2015 PSN 7530-02.000.9047 See Reverse for Instructions
Attachment A. Local Government Review Form
General Statute Overview: North Carolina General Statute 143-215.1 (c)(6)allows input from local governments in the issuance
of NPDES Permits for non-municipal domestic wastewater treatment facilities. Specifically, the Environmental Management
Commission (EMC) may not act on an application for a new non-municipal domestic wastewater discharge facility until it has
received a written statement from each city and county government having jurisdiction over any part of the lands on which the
proposed facility and its appurtenances are to be located. The written statement shall document whether the city or county has a
zoning or subdivision ordinance in effect and (if such an ordinance is in effect) whether the proposed facility is consistent with
the ordinance. The EMC shall not approve a permit application for any facility which a city or county has determined to be
inconsistent with zoning or subdivision ordinances unless the approval of such application is determined to have statewide
significance and is in the best interest of the State.
Instructions to the Applicant: Prior to submitting an application for a NPDES Permit for a proposed facility, the applicant
shall request that both the nearby city and county government complete this form. The applicant must:
Submit a copy of the permit application(with a written request for this form to be completed) to the clerk of the city and
the county by certified mail,return receipt requested.
If either (or both) local government(s) fail(s) to mail the completed form, as evidenced by the postmark on the certified
mail card(s),within 15 days after receiving and signing for the certified mail, the applicant may submit the application to
the NPDES Unit.
As evidence to the Commission that the local government(s) failed to respond within 15 days,the applicant shall submit a
copy of the certified mail card along with a notarized letter stating that the local government(s) failed to respond within
the 15-day period.
Instructions to the Local Government: The nearby city and/or county government which may have or has jurisdiction over
any part of the land on which the proposed facility or its appurtenances are to be located is required to complete and return this
form to the applicant within 15 days of receipt. The form must be signed and notarized.
Name of local government
City/County)
Does the city/county have jurisdiction over any part of the land on which the proposed facility and its appurtenances are to be
located? Yes [ ] No[ ] If no,please sign this form,have it notarized,and return it to the applicant.
Does the city/county have in effect a zoning or subdivision ordinance? Yes [ ] No [
If there is a zoning or subdivision ordinance in effect,is the plan for the proposed facility consistent with the ordinance? Yes[ ]
No [ ]
Date Signature
City Manager/County Manager)
State of County of
On this day of personally appeared before me,the said
name to me known and known to me to be the person described in
and who executed the foregoing document and he(or she)acknowledged that he(or she)executed the same and being duly sworn
by me,made oath that the statements in the foregoing document are true.
My Commission expires Signature of Notary Public)
Notary Public(Official Seal)
EAA Guidance Document Revision:April 2014
Page 9of10
ErsECS SOUTHEAST, LLP Setting the Standard for Service"
maloommmi. Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F-1078
NC Registered Geologists Firm C-553
SC Registered Engineering Firm 3239
April 27,2021
Derek Denard
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section-NPDES
1617 Mail Service Center
Raleigh, NC 27699-1617
Reference: Application Package for a National Pollutant Discharge Elimination System(NPDES)Permit
for Construction and Permanent Dewatering
Central Square
Located Southwest of Intersection of Central Avenue and Pecan Avenue
Charlotte,North Carolina
NCDEQ Brownfields Project No.24002-20-060
ECS Project No. 10756-C
Dear Mr. Denard:
ECS Southeast, LLP (ECS) prepared the enclosed application package for a National Pollutant Discharge
Elimination System (NPDES) Permit on behalf of TGACSE Central Square, LLC for the discharge of treated
groundwater produced by construction and permanent dewatering. Also enclosed is the payment for the
Minor Individual Permit Fee($860.00)
If you have any questions or comments concerning the contents of the enclosed documents or other related
topics,please feel free to contact us.
Respectfully submitted,
ECS SOUTHEAST,LLP
P y
seph P. Nestor,P.G.,P.E. Roger A.Smith, P.G.
Environmental Principal Principal Geologist
[e-mail] [e-mail]
704-280-7422 704-552-5152
Enclosure: NPDES Permit Application—Forms 1,2C,&2E
Letter from Charlotte Stormwater Services
Topographic Maps
Request for Waiver of Requirement to Monitor Certain Conventional Parameters
Line Drawing
Description of System Components
Tables for Groundwater Monitoring Data from February 2020 and August 2020
Analytical Reports-Groundwater Sample Collected in February 2020 and August 2020
Engineering Alternative Analysis
ECS Capitol Services,PLLC • ECS Florida,LLC • ECS Mid-Atlantic,LLC • ECS Midwest,LLC • ECS Southeast,LLP • ECS Southwest,LLP
www.ecslimited.com
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
Form U.S.Environmental Protection Agency
1 EPA Application for NPDES Permit to Discharge Wastewater
NPDES GENERAL INFORMATION
SECTION 1.ACTIVITIES REQUIRING AN NPDES PERMIT(40 CFR 122.21(f)and(f)(1))
1.1 Applicants Not Required to Submit Form 1
Is the facility a new or existing publicly owned Is the facility a new or existing treatment works1.1.1
treatment works?
1.1.2
treating domestic sewage?
If yes,STOP.Do NOT complete No If yes,STOP.Do NOT l No
Form 1.Complete Form 2A. complete Form 1.Complete
Form 2S.
1.2 Applicants Required to Submit Form 1
1.2.1 Is the facility a concentrated animal feeding 1.2.2 Is the facility an existing manufacturing,
F. operation or a concentrated aquatic animal commercial,mining,or silvicultural facility that is
a. production facility? currently discharging process wastewater?
c Yes 4 Complete Form 1 0 No Yes 4 Complete Form 0 No
and Form 2B. 1 and Form 2C.
0 1.2.3 Is the facility a new manufacturing,commercial, 1.2.4 Is the facility a new or existing manufacturing,
mining,or silvicultural facility that has not yet commercial,mining,or silvicultural facility that
commenced to discharge? discharges only nonprocess wastewater?
0 Yes 4 Complete Form 1 Ei No n Yes 4 Complete Form No
and Form 2D. 1 and Form 2E.
At 1.2.5 Is the facility a new or existing facility whose
discharge is composed entirely of stormwater
associated with industrial activity or whose
discharge is composed of both stormwater and
non-stormwater?
Yes 4 Complete Form 1 No
and Form 2F
unless exempted by
40 CFR
122.26(b)(14)(x)or
b 15.
SECTION 2.NAME, MAILING ADDRESS.AND LOCATION(40 CFR 122.21(f)(2))
2.1 Facility Name
Central Square
0 2.2 EPA Identification Number
U
New Facilty
2.3 Facility Contact
Name(first and last) Title Phone number
Barry James Construction Project Manager 704)414-7477
Email address
[e-mail]
2.4 Facility Mailing Address
Street or P.O.box
c/o Crosland Southeast;201 South College Street,Suite 1300
City or town State ZIP code
Charlotte NC 28244
EPA Form 3510-1(revised 3-19) Page 1
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
H 2.5 Facility Location
c Street,route number,or other specific identifier
a U 1314 1318,1322,1324,1326,1330,1332,1334,1336,1400,and 1426 Central Av&1111,1113,and 1235 Pecan Av
c c County name County code(if known)
Mecklenburg
0
E City or town State ZIP code
16
R Charlotte NC 28205z
SECTION 3.SIC AND NAICS CODES(40 CFR 122.21(f)(3))
3.1 SIC Code(s) Description(optional)
653100100 Real Estate Agents and Mangers
62829905 Manager Of Mutual Funds,Contract or Fee Basis
TBD Tentants for retail space have not leased space
o
rn 6513 Operators of Apartment Buildings
3.2 NAICS Code(s) Description(optional)
m 531190 Lessors of Other Real Estate Property
U_
523920 Portfolio Management
TBD Tentants for retail space have not leased space
531311 Residential Property Managers
SECTION 4.OPERATOR INFORMATION(40 CFR 122.21(f)(4))
4.1 Name of Operator
TGACSE Central Square,LLC(Attn.Mr.Barry James)
0 4.2 Is the name you listed in Item 4.1 also the owner?
Yes No
4.3 Operator Status
Public—federal Public—state Other public(specify)
Private Other(specify)
4.4 Phone Number of Operator
704)414-7477
4.5 Operator Address
Street or P.O.Box
E m c/o Crosland Southeast;201 South College Street,Suite 1300
c City or town State ZIP code
0 Charlote NC 28244
TO
a Email address of operator
[e-mail]
SECTION 5.INDIAN LAND(40 CFR 122.21(f)(5))
5.1 Is the facility located on Indian Land?CO
J Yes No
EPA Form 3510-1(revised 3-19) Page 2
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 6.EXISTING ENVIRONMENTAL PERMITS(40 CFR 122.21(f)(6))
6.1 Existing Environmental Permits(check all that apply and print or type the corresponding permit number for each)76
d NPDES(discharges to surface RCRA(hazardous wastes) UIC(underground injection of
water) fluids)
o v)
E
a PSD(air emissions) Nonattainment program(CAA)NESHAPs(CAA)
01
Ocean dumping(MPRSA) 0 Dredge or fill(CWA Section 404) 0 Other(specify)w
SECTION 7.MAP(40 CFR 122.21(f)(7))
7.1 Have you attached a topographic map containing all required information to this application?(See instructions for
specific requirements.)as
0 Yes 0 No CAFO—Not Applicable(See requirements in Form 2B.)
SECTION 8.NATURE OF BUSINESS(40 CFR 122.21(f)(8))
8.1 Describe the nature of your business.
The site is being redeveloped as a vertically integrated mixed used project. The site will be used for office,parking
surface and below grade),retail,commercial,multifamily residential,recreational,and entertainment
8 m
3
m
O
m
io
Z
SECTION 9.COOLING WATER INTAKE STRUCTURES(40 CFR 122.21(f)(9))
9.1 Does your facility use cooling water?
m Yes No 4 SKIP to Item 10.1.
o 9.2 Identify the source of cooling water.(Note that facilities that use a cooling water intake structure as described at
co40 CFR 125,Subparts I and J may have additional application requirements at 40 CFR 122.21(r).Consult with your
6Y NPDES permitting authority to determine what specific information needs to be submitted and when.)
o ,a
SECTION 10.VARIANCE REQUESTS(40 CFR 122.21(f)(10))
10.1 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(m)?(Check all that
apply.Consult with your NPDES permitting authority to determine what information needs to be submitted and
when.)
CD Fundamentally different factors(CWA Water quality related effluent limitations(CWA Section
m
Section 301(n)) 302(b)(2))
W Non-conventional pollutants(CWA Thermal discharges(CWA Section 316(a))
Section 301(c)and(g))
Not applicable
EPA Form 3510-1(revised 3-19) Page 3
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 11.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d))
11.1 In Column 1 below, mark the sections of Form 1 that you have completed and are submitting with your application.
For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note
that not all applicants are required to provide attachments.
Column 1 Column 2
Section 1:Activities Requiring an NPDES Permit w/attachments
Section 2:Name, Mailing Address.and Location w/attachments
Section 3:SIC Codes w/attachments
0 Section 4:Operator Information w/attachments
Section 5:Indian Land w/attachments
Section 6: Existing Environmental Permits w/attachments
0 Section 7:Map map pographic 1 w/additional attachments
co
o 0Section 8:Nature of Business w/attachments
Section 9:Cooling Water Intake Structures w/attachments
CD
a 0Section 10:Variance Requests w/attachments
Section 11:Checklist and Certification Statement w/attachments
m 11.2 Certification Statement
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief,true,accurate, and complete,lam aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations.
Name(print or type first and last name) Official title
Signature Date signed
EPA Form 3510-1(revised 3-19) Page 4
TOPOGRAPHIC MAP
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ECS PROJECT NO.49-10756-C
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e t.D
ti m.,y 'wgT:h-,am ,...n.-fir ,Y •":w.:;'Nt.
Eiizsb•tlr
LEGEND
N
APPROXIMATE SITE BOUNDARY STORM WATER PIPE
r ,
STORM WATER STRUCTURE FLOW DIRECTION
SOURCE: t,„. ,.. FIGURE 2
VIRTUAL CHARLOTTE WEB MAPPING APPLICATION DISCHARGE LOCATION MAP
ACCESSED APRIL 5,
2021S
CENTRAL SQUARE
Central Avenue at Pecan Avenue
APPROXIMATE SCALE: Charlotte, Mecklenburg, North Carolina
1 INCH=382 FEET
0 382 FEETS ECS PROJECT NO.49 10756 C
I I W. i!",
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
Form U.S.Environmental Protection Agency
2C "EPA Application for NPDES Permit to Discharge Wastewater
NPDES EXISTING MANUFACTURING,COMMERCIAL,MINING,AND SILVICULTURE OPERATIONS
SECTION 1.OUTFALL LOCATION(40 CFR 122.21(g)(1))
1.1 Provide information on each of the facility's outfalls in the table below.
o
Numbelr Receiving Water Name Latitude Longitude
o0
001 Trib.to Little Sugar Creek 35° 13' 25.0"80° 19' 7.7"
0
SECTION 2.LINE DRAWING(40 CFR 122.21(g)(2))
a, 2.1 Have you attached a line drawing to this application that shows the water flow through your facility with a water
f .3 balance?(See instructions for drawing requirements.See Exhibit 2C-1 at end of instructions for example.)
J
r Yes No
SECTION 3.AVERAGE FLOWS AND TREATMENT(40 CFR 122.21(g)(3))
3.1 For each outfall identified under Item 1.1,provide average flow and treatment information.Add additional sheets if
necessary.
Outfall Number** 0o1
Operations Contibuting to Flow
Operation Average Flow
Dewatering
Projected to Be Less than 0.050 mgd
c
mgd
mgd
mgd
o Treatment Units
Description
Code from
Final Disposal of Solid or
include size,flow rate through each treatment unit,
Table 2C-1
Liquid Wastes Other Than
retention time,etc.) by Discharge
18,000 Gallon Frac Tank 1-U Landfill
1,000 Gallon Surge Tank 1-0
Two 1,000 pound GAC vessels 2-A Landfill
EPA Form 3510-2C(Revised 3-19)Page
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
3.1 Outfall Number**
cont. Operations Contributing to Flow
Operation Average Flow
mgd
mgd
mgd
mgd
Treatment Units
Description
Code from Final Disposal of Solid or
include size,flow rate through each treatment unit, Liquid Wastes Other Than
retention time,etc.)
Table 2C 1
by Discharge
am
c
c
0
U
cm
E
is
m
Outfall Number**
Operations Contributing to Flow
o Operation Average Flow
13) mgd
L
a'mgd
mgd
mgd
Treatment Units
Description
Code from
Final Disposal of Solid or
include size,flow rate through each treatment unit, Liquid Wastes Other Than
retention time,etc.)
Table 2C-1
by Discharge
3.2 Are you applying for an NPDES permit to operate a privately owned treatment works?
d in 0 Yes No+ SKIP to Section 4.
3.3 Have you attached a list that identifies each user of the treatment works?
Yes 0 No
EPA Form 3510-2C(Revised 3-19)Page 2
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 4.INTERMITTENT FLOWS(40 CFR 122.21(g)(4))
4.1 Except for storm runoff,leaks,or spills,are any discharges described in Sections 1 and 3 intermittent or seasonal?
Yes r No 4 SKIP to Section 5.
4.2 Provide information on intermittent or seasonal flows for each applicable outfall.Attach additional pages,if necessary.
Outfall Operation Frecuency Flow Rate
Number list)
Average Average Long-Term Maximum Duration
Days/Week Months/Year Average Daily
days/week months/year mgd mgd days
30 days/week months/year mgd mgd days
LL
c days/week months/year mgd mgd days
m
E
m
days/week months/year mgd mgd days
c
days/week months/year mgd mgd days
days/week months/year mgd mgd days
days/week months/year mgd mgd days
days/week months/year mgd mgd days
days/week months/year mgd mgd days
SECTION 5.PRODUCTION(40 CFR 122.21(g)(5))
5.1 Do any effluent limitation guidelines(ELGs)promulgated by EPA under Section 304 of the CWA apply to your facility?
Yes No 4 SKIP to Section 6.
u, 5.2 Provide the following information on applicable ELGs.
w ELG Category ELG Subcategory Regulatory Citation
01
co
o-
a
5.3 Are any of the applicable ELGs expressed in terms of production(or other measure of operation)?
c Yes r No 4 SKIP to Section 6.
0
A 5.4 Provide an actual measure of daily production expressed in terms and units of applicable ELGs.
J Outfall Unit of
Operation,Product,or Material Quantity per Day
0 Number Measure
00)Om
0
0
0
d
EPA Form 3510-2C(Revised 3-19)Page 3
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 6.IMPROVEMENTS(40 CFR 122.21(g)(6))
6.1 Are you presently required by any federal,state,or local authority to meet an implementation schedule for constructing,
upgrading,or operating wastewater treatment equipment or practices or any other environmental programs that could
affect the discharges described in this application?
Yes No 4 SKIP to Item 6.3.
6.2 Briefly identify each applicable project in the table below.
Affected Final Compliance Dates
Brief Identification and Description of Outfalls Source(s)of
Project list outfall Discharge Required Projected
number)
c
cuNaea
rna
6.3 Have you attached sheets describing any additional water pollution control programs(or other environmental projects
that may affect your discharges)that you now have underway or planned?(optional item)
ElYesi`lc Brownfields Program No Not applicable
SECTION 7.EFFLUENT AND INTAKE CHARACTERISTICS(40 CFR 122.21(g)(7))
See the instructions to determine the pollutants and parameters you are required to monitor and,in turn,the tables you must
complete.Not all applicants need to complete each table.
Table A.Conventional and Non-Conventional Pollutants
7.1 Are you requesting a waiver from your NPDES permitting authority for one or more of the Table A pollutants for any of
your outfalls?
Yes No 4 SKIP to Item 7.3.
7.2 If yes,indicate the applicable outfalls below.Attach waiver request and other required information to the application.
Outfall Number 001 Outfall Number Outfall Number
7.3 Have you completed monitoring for all Table A pollutants at each of your outfalls for which a waiver has not been
L requested and attached the results to this application package?
No;a waiver has been requested from myNPDESVyeswiththeexceptionofTSSforwhichq
l9 sampling not practicable at this time. permitting authority for all pollutants at all outfalls.
i5 Table B.Toxic Metals,Cyanide,Total Phenols,and Organic Toxic Pollutants
CD 7.4 Do any of the facility's processes that contribute wastewater fall into one or more of the primary industry categories
listed in Exhibit 2C-3?(See end of instructions for exhibit.)
a
Yes El No 4 SKIP to Item 7.8.co
7.5 Have you checked"Testing Required"for all toxic metals,cyanide,and total phenols in Section 1 of Table B?
uu Yes No
7.6 List the applicable primaryindustindustrycategories and check the boxes indicating the required GC/MS fraction(s)iidentified
in Exhibit 2C-3.
Primary Industry Category
Required GC/MS Fraction(s)
Check applicable boxes.)
Volatile 0 Acid 0 Base/Neutral 0 Pesticide
0 Volatile 0 Acid 0 Base/Neutral 0 Pesticide
Volatile 0 Acid 0 Base/Neutral 0 Pesticide
EPA Form 3510-2C(Revised 3-19)Page 4
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
7.7 Have you checked"Testing Required"for all required pollutants in Sections 2 through 5 of Table B for each of the
GC/MS fractions checked in Item 7.6?
Yes No
7.8 Have you checked"Believed Present"or"Believed Absent"for all pollutants listed in Sections 1 through 5 of Table B
where testing is not required?
O Yes No
7.9 Have you provided(1)quantitative data for those Section 1,Table B,pollutants for which you have indicated testing is
required or(2)quantitative data or other required information for those Section 1,Table B,pollutants that you have
indicated are"Believed Present"in your discharge?
r Yes No
7.10 Does the applicant qualify for a small business exemption under the criteria specified in the instructions?
Yes 4 Note that you qualify at the top of Table B,
No
then SKIP to Item 7.12.
CD
C 7.11 Have you provided(1)quantitative data for those Sections 2 through 5,Table B,pollutants for which you have
c determined testing is required or(2)quantitative data or an explanation for those Sections 2 through 5,Table B,
y pollutants you have indicated are"Believed Present"in your discharge?
N 0 Yes El No
a; Table C.Certain Conventional and Non-Conventional Pollutants
e 7.12 Have you indicated whether pollutants are`Believed Present"or"Believed Absent"for all pollutants listed on Table C
al
for all outfalls?
Yes No
c 7.13 Have you completed Table C by providing(1)quantitative data for those pollutants that are limited either directly or
indirectly in an ELG and/or(2)quantitative data or an explanation for those pollutants for which you have indicated
Believed Present"?
El Yes No
w Table D.Certain Hazardous Substances and Asbestos
7.14 Have you indicated whether pollutants are"Believed Present"or"Believed Absent"for all pollutants listed in Table D for
all outfalls?
El Yes No
7.15 Have you completed Table D by(1)describing the reasons the applicable pollutants are expected to be discharged
and(2)by providing quantitative data,if available?
El Yes No
Table E.2,3,7,8-Tetrachlorodibenzo-p-Dioxin(2,3,7,8-TCDD)
7.16 Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the instructions,or do you
know or have reason to believe that TCDD is or may be present in the effluent?
Yes 4 Complete Table E. El No 4 SKIP to Section 8.
7.17 Have you completed Table E by reporting qualitative data for TCDD?
Yes No
SECTION 8.USED OR MANUFACTURED TOXICS(40 CFR 122.21(g)(9))
8.1 Is any pollutant listed in Table B a substance or a component of a substance used or manufactured at your facility as
an intermediate or final product or byproduct?
3 Yes El No 4 SKIP to Section 9.
8.2 List the pollutants below.
2 o 4. 7.
LQ
2. 5. 8.
3. 6. 9.
EPA Form 3510-2C(Revised 3-19)Page 5
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 9.BIOLOGICAL TOXICITY TESTS(40 CFR 122.21(g)(11))
9.1 Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made
within the last three years on(1)any of your discharges or(2)on a receiving water in relation to your discharge?
Yes No-) SKIP to Section 10.
9.2 Identify the tests and their purposes below.
Test(s) Purpose of Test(s)
Submitted to NPDES
Date Submitted
0
Permitting Authority?
I-
Yes No
0
0
m Yes No
Yes No
SECTION 10.CONTRACT ANALYSES(40 CFR 122.21(g)(12))
10.1 Were any of the analyses reported in Section 7 performed by a contract laboratory or consulting firm?
Yes No+SKIP to Section 11.
10.2 Provide information for each contract laboratory or consulting firm below.
Laboratory Number 1 Laboratory Number 2 Laboratory Number 3
Name of laboratory/firm
Pace Analytical Services,t.LC
U'
Laboratory address
9800 Kincey Ave;Suite 100CO
Huntersville,NC 208078
f0
C
Phone number
704)875-9092
Pollutant(s)analyzed
COCs,SVOCs,metals
SECTION 11.ADDITIONAL INFORMATION(40 CFR 122.21(g)(13))
11.1 Has the NPDES permitting authority requested additional information?
o Yes No+SKIP to Section 12.
E 11.2 List the information requested and attach it to this application.
1. 4.
COC0
2. 5.
3. 6.
EPA Form 3510-2C(Revised 3-19)Page 6
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Central Square
OMB No.2040-0004
SECTION 12.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d))
12.1 In Column 1 below,mark the sections of Form 2C that you have completed and are submitting with your application.
For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note
that not all applicants are required to complete all sections or provide attachments.
Column 1 Column 2
El Section 1:Outfall Location wl attachments
El Section 2:Line Drawing El w/line drawing Q w/additional attachments
Di Section 3:Average Flows and
w/list of each user of
Treatment
wl attachments El privately owned treatment
works
ElSection 4:Intermittent Flows w/attachments
Section 5:Production w/attachments
w/optional additional
0 Section 6:Improvements w/attachments
sheets describing any
additional pollution control
plans
0 w/request for a waiver and w/explanation for identical
supporting information outfalls
d w/small business exemption
w/other attachments
d request
Section 7:Effluent and Intake
w/Table A wl Table B
Characteristics
0
w/Table C w/Table D
w/Table E
w/analytical results as an
c attachment
c0 Section 8:Used or Manufactured
w/attachments
Toxics
Section 9:Biological Toxicity w/attachments
Tests
v
ElSection 10:Contract Analyses w/attachments
ElSection 11:Additional Information wl attachments
171 Section 12:Checklist and wl attachments
Certification Statement
12.2 Certification Statement
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted.Based on my inquiry of the person or persons who manage the system,or those persons directly
responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,
accurate,and complete.I am aware that there are significant penalties for submitting false information,including the
possibility of fine and imprisonment for knowing violations.
Name(print or type first and last name) Official title
Signature Date signed
EPA Form 3510-2C(Revised 3-19)Page 7
This page intentionally left blank.
3 f
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE A.CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(iii))1
Effluent
Intake
Waiver
Optional)
Pollutant Requested
Units Maximum Maximum Long-Term
if applicable
este
specify) Daily Monthly Average Daily Number of Long-Term Number of
Discharge Discharge Discharge Analyses Average Value Analyses
required) if available) if available)
Check here if you have applied to your NPDES permitting authority for a waiver for all of the pollutants listed on this table for the noted outfall.
Biochemical oxygen demand
Concentration
r1' (
BOD5)Mass
Chemical oxygen demand
Concentration
2' (
COD)
Mass
Concentration
3. Total organic carbon(TOC) r
Mass
Concentration It is not practical to sample collect samples for TSS until dewatering apperatus
4. Total suspended solids(TSS) is in place. We anticipate maximum daily and monthly TSS to be less than 45 -Mass
and 30 mg/L, respectively.
Concentration
5. Ammonia(as N)
Mass
6. Flow Rate It is not practical to monitor flow until dewatering apperatus is in place. We
anticipate maximum daily flow to be less than 50.000GPD or 0.05 MGD.
Temperature(winter) r °C C
7.
Temperature(summer) El °C C
pH(minimum) Standard units S.U.
8.
pH(maximum) Standard units s.u.
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2C(Revised 3-19) Page 9
This page intentionally left blank.
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
Discharge Discharge
Di c harge Analyses Average Analyses
required) (if available) Value
if available)
Check here if you qualify as a small business per the instructions to Form 2C and,therefore,do not need to submit quantitative data for any of the organic toxic pollutants in Sections
2 through 5 of this table.Note,however,that you must still indicate in the appropriate column of this table if you believe any of the pollutants listed are present in your discharge.
Section 1.Toxic Metals,Cyanide,and Total Phenols
1.1 Antimony,total Concentration
7440-36-0) Mass
1.2
Arsenic,total Concentration
7440-38-2) Mass
1.3
Beryllium,total 0 ElConcentration
7440-41-7) Mass
1.4
Cadmium,total 0
Concentration
It is not practical to collect effluent samples until dewatering744043s) Mass
apperatus is in place. The maximum Chromium detected in
1.5
Chromium,total u
Concentration
Groundwater is 128 ug/L.7440-47-3) Mass
1.6
Copper,total 0 0 ii
Concentration
7440-50-8) Mass
1.7
Lead,total Concentration
7439-92-1) Mass
1.8 Mercury,total 0
Concentration
7439-97-6) Mass
1 9
Nickel,total Concentration
7440-02-0) Mass
1.10
Selenium,total 0 0
Concentration
7782-49-2) Mass
1.11
Silver,total Concentration
7440-22-4) Mass
EPA Form 3510-2C(Revised 3-19)Page 11
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001 OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term Long-and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Present Absent Daily Monthly
Average Number
Term
Number
egui ifavailablle) Discharge Analyses
Daily of
AValuee
of
DiAnalyses
if available)
Thallium,total
tEl
Concentration
1.12 El 07440-28-0) Mass
Zinc,total Concentration
1.13 (
7440-66-6) 0 El El
Mass
1.14
Cyanide,total Concentration
57-12-5) Mass
Concentration
1.15 Phenols,total 0 0 1=1Mass
Section 2.Organic Toxic Pollutants(GC/MS Fraction—Volatile Compounds)
Acrolein
0
Concentration
2.1 0107-02-8)0
Mass
Acrylonitrile
0
Concentration
2.2 0 0107-13-1) Mass
2.3
Benzene Concentration
0 071-43-2) Mass
2.4
Bromoform Concentration
El 0 El
75-25-2) Mass
2.5
Carbon tetrachloride
0
Concentration
0 El56-23-5) Mass
Chlorobenzene Concentration
2.6 (
108-90-7) 0 0
Mass
Chlorodibromomethane Concentration
2.7 El(
124-48-1)El
Mass
2.8
Chloroethane 0
Concentration
75-00-3) Mass
EPA Form 3510-2C(Revised 3-19)Page 12
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))'
Presence or Absence
Intake
check one) Effluent
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Daily of
Term
of
Discharge(
required) (ifavalablle) Discharge Analyses Averageischarge
Value
Analyses
q ) (
if available)
2.9
2-chloroethylvinyl ether Concentration
110-75-8) Mass
Concentration
2.10 Chloroform(67-66-3) <n ElJit is not practical to collect effluent samples until dewatering
2.11
Dichlorobromomethane E Concentration apperatus is in place. The maximum Chloroform detected in
LJ 075274) Mass Groundwater is 9.2 ug/L. The maximum Dichlorobromethane
2.12
1,1-dichloroethane Concentration detected in Groundwater is 1.9 ug/L.
75-34-3) Mass
2.13
12-dichloroethane 0
Concentration
107-06-2) Mass
2.14
1,1-dichloroethylene Concentration
75-35-4) Mass
2.15
1,2-dichloropropane Concentration
0 El El78-87-5) Mass
1,3-dichloropropylene
2
Concentration
2.16 (
542-75-6)
0
Mass
2.17
Ethylbenzene Concentration
100-41-4) Mass
2.18
Methyl bromide Concentration
74-83-9) Mass
2.19
Methyl chloride Concentration
74-87-3) Mass
2.20
Methylene chloride Concentration
75-09-2) Mass
2.21
1 1,2,2-tetrachloroethane 0
Concentration
79-34-5) Mass
EPA Form 3510-2C(Revised 3.19)Page 13
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square ow_ OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
aily of of
Discharge Discharge
Discharge
D
Analyses
Average
Analyses
required) (if available) (
if available)
Value
2.22
Tetrachloroethylene 0 ElConcentration127-18-4) Mass
2.23
Toluene Concentration
108-88-3) Mass
2.24
1,2-trans-dichloroethylene
0
Concentration
156-60-5) Mass
2.25
1,1,1-trichloroethane Concentration
0 El(71-55-6) Mass
2.26
1,1,2-trichloroethane Concentration
79-00-5) Mass
2.27
Trichloroethylene 0 0
Concentration
79-01-6) Mass
2 28
Vinyl chloride Concentration
75-01-4) Mass
Section 3.Organic Toxic Pollutants(GC/MS Fraction—Acid Compounds)
3.1
2-chlorophenol 0
Concentration
0 El95-57-8) Mass
2,4-dichlorophenol Concentration
3.2 (
120-83-2)
ID El
Mass
2,4-dimethylphenol Concentration
3.3 ID105679)0
Mass
4,6-dinitro-o-cresol Concentration
3.4 (
534-52-1)0
Mass
3.5
2 4-dinitrophenol El ID 0
Concentration
51-28-5) Mass
EPA Form 3510-2C(Revised 3-19)Page 14
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent
Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Daily of
Term
of
Discharge iischarge
availablle
Discharge Analyses Analyses
required) (if ) Value
Average(
if available)
3.6
2-nitrophenol Concentration
88-75-5) Mass
3.7
4-nitrophenol 0 13
Concentration
100-02-7) Mass
3.8 p-chloro-m-cresol Concentration
59-50-7) Mass
3.9
Pentachlorophenol E3 0
Concentration
87-86-5) Mass
Phenol Concentration
3.10 (
108-95-2) 0
Mass
3.11
2,4,6-trichlorophenol 0
Concentration
88-05-2) Mass
Section 4.Organic Toxic Pollutants(GC/MS Fraction—Base/Neutral Compounds)
Acenaphthene Concentration
4.1 El(83-32-9) Mass
Acenaphthylene Concentration
4.2 (
208-96-8) Mass
4.3
Anthracene Concentration
0 0 0
120-12-7) Mass
4.4
Benzidine 0
Concentration
0 0
92-87-5) Mass
Benzo(a)anthracene 0
Concentration
4.5 El56-55-3) 0
Mass
4.6
Benzo(a)pyrene El
Concentration
50-32-8) Mass
EPA Form 3510-2C(Revised 3-19) Page 15
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units I Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
DailyDischargeDischarge
Dischargechara Analyses
Average
Analyses
required) (if available) (
if available)
Value
3,4-benzofluoranthene Concentration
4.7 (
205-99-2) Mass
Benzo(ghi)perylene 0
Concentration
4.8 (
191-24-2) Mass
Benzo(k)fluoranthene 0
Concentration
4.9 (
207-08-9) Mass
Bis(2-chloroethoxy)methane 0
Concentration
4.10 (
111-91-1) 0
Mass
4.11
Bis(2-chloroethyl)ether ElConcentration111-44-4) Mass
Bis(2-chloroisopropyl)ether 0
Concentration
4.12 (
102-80-1) Mass
4.13
Bis(2-ethylhexyl)phthalate Concentration
117-81-7) Mass
4.14
4-bromophenyl phenyl ether 0 0
Concentration
101-55-3) Mass
4.15
Butyl benzyl phthalate Concentration
85-68-7) Mass
4.16
2-chloronaphthalene Concentration
91-58-7) Mass
4-chlorophenyl phenyl ether 0
Concentration
4.17 (
7005 72 3) Mass
Chrysene Concentration
4.18 (
218 01 9) 0 0
Mass
4.19
Dibenzo(a,h)anthracene 0 0 0
Concentration
53-70-3) Mass
EPA Form 3510-2C(Revised 3.19)Page 16
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Daily of
Term
of
Discharge Discharge
Discharge Analyses
Average
Analyses
required) (if available) Value
if available)
4.20
1,2-dichlorobenzene a
Concentration
95-50-1) Mass
1,3-dichlorobenzene Concentration
4.21 (
541-73-1) Mass
4.22
1,4-dichlorobenzene El 0
Concentration
106-46-7) Mass
4.23
3,3-dichlorobenzidine Concentration
0 El91-94-1) Mass
4.24
Diethyl phthalate 0
Concentration
84-66-2) Mass
4.25
Dimethyl phthalate 0 a 0
Concentration
131-11-3) Mass
4.26
Di-n-butyl phthalate Concentration
84-74-2) Mass
2,4-dinitrotoluene Concentration
4.27 (
121-14-2) Mass
4.28
2,6-dinitrotoluene Concentration
606-20-2) Mass
Di-n-octyl phthalate 0
Concentration
4.29 0 El
117-84-0) Mass
4.30
1,2-Diphenylhydrazine 0 a 0
Concentration
as azobenzene)(122-66-7) _ Mass
4.31
Fluoranthene 0
Concentration
0 0
206-44-0) Mass
4.32
Fluorene 0
Concentration
86-73-7) Mass
EPA Form 3510-2C(Revised 3-19)Page 17
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))'
Presence or Absence
check one) Effluent
Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
DailyDiscargeDischarge(
required) (if available)
Discharge Analyses AverageValue Analyses
if available)
4.33
Hexachlorobenzene
o
Concentration
0 0118-74-1) Mass
4.34
Hexachlorobutadiene
0
Concentration
0 087-68-3) Mass
4.35
Hexachlorocyclopentadiene
0
Concentration
77-47-4) Mass
4.36
Hexachloroethane
0
Concentration
0 0(67-72-1) Mass
4.37
Indeno(1,2,3-cd)pyrene 0
Concentration
193-39-5) Mass
4.38
Isophorone Concentration
78-59-1) Mass
4.39
Naphthalene Concentration
91-20-3) Mass
4.40
Nitrobenzene 0
Concentration
0 0
98-95-3) Mass
4.41
N-nitrosodimethylamine o
Concentration
62-75-9) Mass
4.42
N-nitrosodi-n-propylamine 0
Concentration
621-64-7) Mass
4.43
N-nitrosodiphenylamine 0
Concentration
86-30-6) Mass
4.44
Phenanthrene Concentration
0 0 085-01-8) Mass
Pyrene Concentration
4.45 0 0 0129-00-0)Mass
EPA Form 3510-2C(Revised 3-19)Page 18
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-TermMaximum Long-
and CAS Number,if available) Required Believed Believed specify) Average Number Number
Present Absent Daily Daily of
Term
of
Discharge DischargeDischarge Analyses Average Analyses
required)
if available)
Value
1,2,4-trichlorobenzene Concentration
4.46 (
120-82-1)
El El
Mass
Section 5.Organic Toxic Pollutants(GC/MS Fraction—Pesticides)
5.1
Aldrin Concentration
309-00-2) Mass
5.2
a-BHC 0
Concentration
319-84-6) Mass
R-BHC Concentration
5.3 0 El El
319-85-7) Mass
5.4 y-BHC Concentration
58-89-9) Mass
b-BHC 0
Concentration
5.5 0 0
319-86-8) Mass
5.6
Chlordane Concentration
57-74-9) Mass
4,4'-DDT 0
Concentration
5.7 0 0
50-29-3) Mass
4,4'-DDE El
Concentration
5.8 (
72-55-9) Mass
5.9
4,4'-DDD Concentration
72-54-8) Mass
5.10
Dieldrin 0
Concentration
60-57-1) Mass
5.11
a-endosulfan 0
Concentration
0 El115-29-7) Mass
EPA Form 3510-2C(Revised 3-19)Page 19
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))l
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Term
aily of of
O(,
eq ied a (ifavalablle) Di(
ifDavailable)
harge Analyses
ischarge AValuee
Analyses
5.12 )-
endosulfan
0 0 0
Concentration
115-29-7) Mass
Endosulfan sulfate Concentration
5.13 (
1031 07 8) 0 0 0
Mass
Endrin Concentration
5.14 (
72-20-8) 0 0
Mass
5.15
Endrin aldehyde 0 0
Concentration
7421-93-4) Mass
5.16
Heptachlor El 0 ElConcentration76-44-8) Mass
Heptachlor epoxide Concentration
5.17 (1024-57-3) 0
Mass
PCB-1242
0
Concentration
5.18 (53469-21-9)Mass
PCB-1254 Concentration
5.19 (11097-69-1) 0 0
Mass
PCB-1221
El
Concentration
5.20 (11104-28-2)Mass
PCB-1232 Concentration
5.21 (11141-16-5) 0
Mass
PCB-1248 Concentration
5.22 (12672-29-6) 0
Mass
PCB-1260 Concentration
5.23 (11096-82-5) 0 0 0
Mass
PCB-1016 Concentration
5.24 (12674-11-2) 0 0 0
Mass
EPA Form 3510-2C(Revised 3.19)Page 20
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))l
Presence or Absence
check one) Effluent Intake
optional)
Pollutant/Parameter Testing Units Long-Term
and CAS Number,if available) Required Believed Believed specify)
Maximum Maximum
Average Number Long- Number
Present Absent Daily Monthly Daily of
Term
of
qire
Discharge (ifavailabl)ischarge
Discharge Analyses AverageValue Analyses
required)re ) (
if available)
Toxaphene Concentration
5.25 (8001-35-2) 0 0 0
Mass
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2C(Revised 3-19)Page 21
This page intentionally left blank.
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square
OMB No.2040-0004
TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1
Presence or Absence
check one) Effluent Intake
Optional)
Units
Pollutant Maximum Long-TermBelievedBelievedspecify) Maximum DailyLong-Term
Present Absent Discharge Monthly Average Daily Number of
Average
Number of
Discharge Discharge Analyses Analyses
required)Value
if available)if available)
in Check here if you believe all pollutants on Table C to be present in your discharge from the noted outfall.You need not complete the'Presence or Absence"column of Table C for
each pollutant.
Check here if you believe all pollutants on Table C to be absent in your discharge from the noted outfall.You need not complete the"Presence or Absence"column of Table C for
each pollutant.
Bromide El
Concentration
1. (
24959-67-9)Mass
2
Chlorine,total Concentration
residual Mass
Concentration
3. Color 0 0
Mass
Concentration
4. Fecal coliform 0 0
Mass
Fluoride El
Concentration
5. (
16984-48-8)Mass
Concentration
6 Nitrate-nitrite 0Mass
7
Nitrogen,total Concentration
organic(as N) Mass
Concentration
8. Oil and grease 0 0Mass
9
Phosphorus(as Concentration
P),total(7723-14-0)Mass
Sulfate(as SO4) Concentration
10. (
14808 79 8) Mass
Concentration
11. Sulfide(as S) 0 0
Mass
EPA Form 3510-2C(Revised 3.19)Page 23
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square OMB No.2040-0004
TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))'
Presence or Absence
check one) Effluent Intake
Optional)
UnitsPollutant Maximum Long-TermBelievedBelievedspecify) Maximum Daily Monthly Average Daily Number of Long-Term
Number of
Present Absent Discharge
Discharge Discharge Analyses
Average
Analyses
required)Valueifavailable)if available)
12.Sulfite(as SO3) 0
Concentration
14265-45-3)Mass
13. Surfactants 0 0
Concentration
Mass
14.
Aluminum,total Concentration
7429-90-5) Mass
15.
Barium,total Concentration i`.
7440-39-3) Mass
16. Boron,total Concentration
7440-42-8) Mass
17. Cobalt,total 0
Concentration
7440-48-4) Mass
18.Iron,total CI IDConcentration7439-89-6) Mass
19.
Magnesium,total Concentration
7439-95-4) Mass
Molybdenum, Concentration
20. total
Mass7439-98-7)
21 Manganese,total El ElConcentration7439-96-5) Mass
22 Tin,total Concentration
7440-31-5) Mass
23.
Titanium,total Concentration
7440-32-6) Mass
EPA Form 3510-2C(Revised 3-19)Page 24
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square
OMB No.2040-0004
TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1
Presence or Absence
check one) Effluent
Intake
Optional)
Pollutant Units Maximum Long-TermBelievedBelievedspecify) Maximum Daily Long-Term
Present Absent Discharge Monthly Average Daily Number of
Average
Number of
Discharge Discharge Analyses Analyses
required)Value
if available)if available)
24. Radioactivity
Alpha,total
Concentration
Mass
Beta,total El
Mass
Concentration
Radium,total
Mass
Radium 226,total
Concentration
El
Mass
I Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2C(Revised 3-19)Page 25
This page intentionally left blank.
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))1
Presence or Absence
Pollutant check one)
Reason Pollutant Believed Present in Discharge Available Quantitative Data
Believed Believed specify units)
Present Absent
1. Asbestos El
2. Acetaldehyde 2
3. Allyl alcohol r
4. Allyl chloride 0
5. Amyl acetate
6. Aniline 0
7. Benzonitrile
8. Benzyl chloride 0
9. Butyl acetate r
10. Butylamine 0
11. Captan
12. Carbaryl 0
13. Carbofuran 0 El
14. Carbon disulfide El
15. Chlorpyrifos 0 0
16. Coumaphos
17. Cresol 0 CI
18. Crotonaldehyde 0 El
19. Cyclohexane El
EPA Form 3510-2C(Revised 3-19)Page 27
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))1
Presence or Absence
Pollutant check one)
Reason Pollutant Believed Present in Discharge Available Quantitative Data
Believed Believed specify units)
Present Absent
20. 2,4-D(2,4-dichlorophenoxyacetic acid) 0
21. Diazinon 0
22. Dicamba U
23. Dichlobenil U
24. Dichlone El
25. 2,2-dichloropropionic acid 0
26. Dichlorvos El
27. Diethyl amine El
28. Dimethyl amine El
29. Dintrobenzene El
30. Diquat El
31. Disulfoton El
32. Diuron U
33. Epichlorohydrin 0
34. Ethion U
35. Ethylene diamine 0 U
36. Ethylene dibromide U
37. Formaldehyde U
38. Furfural U
EPA Form 3510-2C(Revised 3-19)Page 28
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))1
Presence or Absence
Pollutant check one)
Reason Pollutant Believed Present in Discharge Available Quantitative Data
Believed Believed specify units)
Present Absent
39. Guthion 0
40. Isoprene 0
41. Isopropanolamine 0
42. Kelthane 0
43. Kepone 0
44. Malathion 0 0
45. Mercaptodimethur 0 El
46. Methoxychlor 0 0
47. Methyl mercaptan 0 El
48. Methyl methacrylate 0 El
49. Methyl parathion 0
50. Mevinphos 0 0
51. Mexacarbate 0 El
52. Monoethyl amine 0 r
53. Monomethyl amine 0 El
54. Naled 0
55. Naphthenic acid 0 El
56. Nitrotoluene 0
57. Parathion
EPA Form 3510-2C(Revised 3-19)Page 29
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 12221(g)(7)(vii))1
Presence or Absence
Pollutant check one)
Reason Pollutant Believed Present in Discharge Available Quantitative Data
Believed Believed specify units)
Present Absent
58. Phenolsulfonate 0
59. Phosgene 0 0
60. Propargite 0 0
61. Propylene oxide 0 0
62. Pyrethrins 0
63. Quinoline E
64. Resorcinol 0 0
65. Strontium 0 0
66. Strychnine 0 0
67. Styrene 0
68.
2,4 5-T(2,4,5-trichlorophenoxyacetic
acid)
69. TDE(tetrachlorodiphenyl ethane) 0
70 2,4,5-TP[2-(2,4,5-trichlorophenoxy)
propanoic acid]
71. Trichlorofon 0 0
72. Triethanolamine 0 0
73. Triethylamine 0
74. Trimethylamine 0 0
75. Uranium 0 0
76. Vanadium E
EPA Form 3510-2C(Revised 3.19)Page 30
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square 001
OMB No.2040-0004
TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))1
Presence or Absence
Pollutant check one)
Reason Pollutant Believed Present in Discharge Available Quantitative Data
Believed Believed specify units)
Present Absent
77. Vinyl acetate
78. Xylene
79. Xylenol r
80. Zirconium
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2C(Revised 3-19)Page 31
This page intentionally left blank.
EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
Central Square
OMB No.2040-0004
TABLE E.2,3,7,8 TETRACHLORODIBENZO P DIOXIN (2,3,7,8 TCDD)(40 CFR 122.21(g)(7)(viii))
TCDD Presence or
Congeners
Absence
Pollutant
Used or
check one) Results of Screening Procedure
Manufactured
Believed Believed
Present Absent
2.3,7,8-TCDD w
EPA Form 3510-2C(Revised 3-19)Page 33
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DATED 2019 Charlotte, Mecklenburg, North Carolina
ECS PROJECT NO.49-10756-C
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1 INCH=382 FEET
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ECS PROJECT NO.49-10756-C
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ua lwnan rdroPYr Updated March 27,2020 by ECD
MI• ECS SOUTHEAST, SettingLLP the Standard for Service"
misimmim Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F..1098
NC Registered Geologists Farm C-553
SC Registered Engineering Firm 3239
April 27, 2021
Derek Denard
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section - NPDES
1617 Mail Service Center
Raleigh, NC 27699-1617
Reference: Request for Waiver for Monitoring of Certain Conventional Parameters
Submitted with Application for
National Pollutant Discharge Elimination System (NPDES) Permit for Construction and
Permanent Dewatering
Central Square
Located Southwest of Intersection of Central Avenue and Pecan Avenue
Charlotte, North Carolina
ECS Project No. 10756-C
Dear Mr. Denard:
ECS Southeast, LLP (ECS) requests on behalf of its client TGACSE Central Square, LLC that certain
conventional parameters not be required for the proposed discharge as shown in NPDES Permit
Application Form 2C. Specifically, it is requested that monitoring for Biological Oxygen Demand,
Chemical Oxygen Demand, Total Organic Carbon, Ammonia, Temperature (winter), and Temperature
summer) not be required as part of the permit.
As described in the application package the discharge is for construction and permanent dewatering
and the aforementioned parameters are not applicable for the indicated discharge. Summary data
tables and laboratory results are included in the application package for groundwater monitoring that
has been performed at the site.
If you have any questions or comments concerning this waiver request or other related topics, please feel
free to contact us.
Respectfully submitted,
ECS SOUTHEAST, LLP
111,4: 7
seph P. Nestor, P.G., P.E.Rmith, P.G.g
Environmental Principal Principal Geologist
[e-mail] [e-mail]
704-280-7422 704-552-5152
ECS Capitol Services.PLLC • ECS Florida.LLC • ECS Mid-Atlantic,LLC • ECS Midwest.LLC • ECS Southeast.LLP • ECS Southwest.LLP
www.ecslimited.con
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Crown Central
OMB No.2040-0004
U.S.Environmental Protection Agency
FORM Application for NPDES Permit to Discharge Wastewater
2E
NPDES
coEPA MANUFACTURING,COMMERCIAL,MINING,AND SILVICULTURAL FACILITIES WHICH
DISCHARGE ONLY NONPROCESS WASTEWATER
SECTION 1.OUTFALL LOCATION (40 CFR 122.21(h)(1))
1.1 Provide information on each of the facility's outfalls in the table below.
Outfall
Receiving Water Name Latitude Longitude
Number
J 001 Trib.to Little Sugar Creek 35° 13' 25.0"80* 19' 7.7"
0
SECTION 2. DISCHARGE DATE(40 CFR 122.21(h)(2))
2.1 Are you a new or existing discharger?(Check only one response.)
m CD Q New discharger Existing discharger 4 SKIP to Section 3.
H 2.2 Specify your anticipated discharge date:
11/01/2021
SECTION 3.WASTE TYPES(40 CFR 122.21(h)(3))
3.1 What types of wastes are currently being discharged if you are an existing discharger or will be discharged if you are a
new discharger?(Check all that apply.)
Sanitary wastes Other nonprocess wastewater(describe/explain
Restaurant or cafeteria waste directly below)
El cooling water
Groundwater from dewatering
E— 3.2 Does the facility use cooling water additives?
Yes No 4 SKIP to Section 4.
3.3 List the cooling water additives used and describe their composition.
Cooling Water Additives Composition of Additives
list) if available to you)
SECTION 4.EFFLUENT CHARACTERISTICS(40 CFR 122.21(h)(4))
4.1 Have you completed monitoring for all parameters in the table below at each of your outfalls and attached the results to
this application package?
El Yes
No;a waiver has been requested from my NPDES permitting authority
attach waiver request and additional information)4 SKIP to Section 5.
4.2 Provide data as requested in the table below)(See instructions for specifics.)
Number of Maximum Daily Average Daily Source
Parameter or Pollutant Analyses Discharge Discharge (use codes
if actual data specify units) sped units) per
reported) Mass Conc. Mass Conc. instructions)
Biochemical oxygen demand(BOD5)
c) Total suspended solids(TSS)
Oil and grease
w Ammonia(as N)
Discharge flow
pH(report as range)
Temperature(winter)
Temperature(summer)
Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant
parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2E(revised 3-19) Page 1
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Crown Central
OMB No.2040-0004
4.3 Is fecal coliform believed present,or is sanitary waste discharged(or will it be discharged)?
0 Yes Cl No 4 SKIP to Item 4.5.
4.4 Provide data as requested in the table below.' (See instructions for specifics.)
Number of Maximum Daily Average Daily Source
Parameter or Pollutant Analyses Discharge Discharge (Use codes
if actual data specify units) specify units) per
reported) Mass Conc. Mass Conc. Instructions.)
Fecal coliform
0 E.coli
w
Enterococci
c
4.5 Is chlorine used(or will it be used)?
to ElYes No 4 SKIP to Item 4.7.
N 4.6 Provide data as requested in the table below., (See instructions for specifics.)
5 Number of Maximum Daily Average Daily Source
La
Parameter or Pollutant Analyses Discharge Discharge (use codes
s if actual data specify units) specify units) per
v
reported) Mass Conc. Mass Conc. instructions)
c
Total Residual Chlorine
w 4.7 Is non-contact cooling water discharged(or will it be discharged)?
0 Yes No. SKIP to Section 5.
4.8 Provide data as requested in the table below., (See instructions for specifics.)
Number of Maximum Daily Average Daily Source
Parameter or Pollutant Analyses Discharge Discharge (use codes
if actual data specif units) speci units) per
reported) Mass Conc. Mass Conc. instructions)
Chemical oxygen demand(COD)
Total organic carbon(TOC)
SECTION 5.FLOW(40 CFR 122.21(h)(5))
5.1 Except for stormwater water runoff,leaks,or spills,are any of the discharges you described in Sections 1 and 3 of this
application intermittent or seasonal?
Yes 4 Complete this section. El No 4 SKIP to Section 6.
0 5.2 Briefly describe the frequency and duration of flow.
LL' The flow is expected to be continuous and less than 50,000 GPO or 0.05 MGD.
SECTION 6.TREATMENT SYSTEM(40 CFR 122.21(h)(6))
6.1 Briefly describe any treatment system(s)used(or to be used).E
a) The system will include an 18,000-gal frac tank for settling and grit removal followed by a 1,00-gallon surge/mixing tank,
followed by two particulate filters in series,followed by two 1,000-pound carbon vessels in series. A line drawing and
P&ID drawing are included with permit application package.
A carbon dioxide gas dosing system will used up stream of the mixing/surge tank during construction dewatering. The
E carbon dioxide gas dosing system and 18,000-gal frac tank will be removed when project transitions from construction
u dewatering to permanent building dewatering.cu
it
Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant
parameters or required under 40 CFR chapter I,subchapter N or 0.See instruction and 40 CFR 122.21(eX3).
EPA Form 3510-2E(revised 3-19) Page 2
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
Crown Central
OMB No.2040-0004
SECTION 7.OTHER INFORMATION(40 CFR 122.21(h)(7))
7.1 Use the space below to expand upon any of the above items. Use this space to provide any information you believe the
reviewer should consider in establishing permit limitations.Attach additional sheets as needed.
o Groundwater at the site has been monitored as part of the North Carolina Brownfileds Program. The triahalomethance
io compounds(THMs)were detected(Bromodichloromethane,Chloroform,&Dibromochloromethane). The THMs
potentially could be the result of a municipal water line leak since THMs are associated with disinfection of municpal
c water supplies. The metals Barium and Chromium were detected in groundwater. The concentrations of the detected
CD metals may have been biased high due to sediment potentally being present in samples as a result of c\sample
0 collection methods.
Summary data tables and laboratory results are attached to permit application package.
SECTION 8.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d))
8.1 In Column 1 below,mark the sections of Form 2E that you have completed and are submitting with your application.
For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note that
not all applicants are required to provide attachments.
Column 1 Column 2
r Section 1:Outfall Location r w/attachments(e.g.,responses for additional outfalls)
r Section 2:Discharge Date w/attachments
ElSection 3:Waste Types w/attachments
ElSection 4:Effluent Characteristics r w/attachments
ElSection 5:Flow w/attachments
c Section 6:Treatment System El w/attachments
ElSection 7:Other Information r wl attachments
0
r Section 8:Checklist and Certification Statement El w/attachments
8.2 Certification Statement
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted.Based on my inquiry of the person or persons who manage the system,or those persons directly
responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,
accurate,and complete.I am aware that there are significant penalties for submitting false information,including the
possibility of fine and imprisonment for knowing violations.
Name(print or type first and last name) Official title
Signature Date signed
EPA Form 3510-2E(revised 3-19) Page 3
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i FIGURE 1
USGS TOPOGRAPHIC MAP SITE TOPOGRAPHIC LOCATION MAP
CAHRLOTTE EAST CENTRAL SQUARE
7.5 MINUTE QUADRANGLE Central Avenue at Pecan Avenue
DATED 2019 Charlotte, Mecklenburg, North Carolina
ECS PROJECT NO.49-10756-C
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LEGEND
APPROXIMATE SITE BOUNDARY STORMWATER PIPE yy'
w -y e
STORMWATER STRUCTURE FLOW DIRECTION s
SOURCE: C I FIGURE 2
VIRTUAL CHARLOTTE WEB MAPPING APPLICATION DISCHARGE LOCATION MAP
ACCESSED APRIL 5, 2021 CENTRAL SQUARE
Central Avenue at Pecan Avenue
APPROXIMATE SCALE: Charlotte, Mecklenburg, North Carolina
1 INCH=382 FEET
p 382 FEETIlligi ECS PROJECT NO.49-10756-C
I I
M
TABLE 3:SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
PECAN&CENTRAL AVENUE
CHARLOTTE,MECKLENBURG COUNTY,NORTH CAROLINA
ECS PROJECT NO.49-10756-A
Parameter ANALYTICAL RESULTS COMPARISON CRITERIA
Sample ID TW-1 TW-2 TW-3 TW-4 TW-S TW-6 TW-7 NCDEQ RESIDENTIAL NCDEQ NON-RESIDENTIAL
Collection Date 2/11/2020 2/11/2020 2/11/2020 2/10/2020 2/10/2020 2/10/2020 2/10/2020
NC2LGWQS GCL
VISL VISL
Volatile Organic Compounds(VOCs)by EPA Method 8260
Bromodichloromethane kw_ 1.9 BRL BRL 0.6 NS 8.8 38
Chloroform e«i 9.2 BRL IiYL 70 70,000 8.1 36
Dibromochloromethane BR, 1.3 BRL BRL 0.4 400 N5 NS
Semi-Volatile Organic Compounds(SVOCs)by EPA Method 8270
For All I t, I :,,t I Iii-i. I I I BRL I I NS I NS I NS I NS
Resource Conservation and Recovery Act(RCRA)Metals by EPA Methods 6020,7471,and 7199
Mercury BRL 61t_ 00, okL BRL 1 N5 0.18 0.75
Barium 104 218 261 39.6 17.7 43.1 23.9 700 700,000 NS NS
Chromium BRL 94.0 128 BRL 9.3 BRL 10 10,000 NS NS
Notes:
Results presented in micrograms per liter(ug/L),analogous to parts per billion(ppb)
NC2LGWQS=North Carolina 2L Groundwater Quality Standards
NCDEQ=North Carolina Department of Environmental Quality
VIOL=Vapor Intrusion Screening Levels
DUP-3 is a duplicate sample collected from MW-3
NS=No Standard
1 Flag denotes an estimated concentration between the laboratory reporting limit and the laboratory detection limit
GCL=Gross Contamination Limit
Bold denotes an exceedance of the NC2LGWQS
Italics denotes an exceedance of the NCDEQ Residential VIOL
Underline denotes an exceedance of the NCDEQ Non-Residential VIOL
TABLE 3: SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
FORMER SHERWIN WILLIAMS-ADDITIONAL BROWNFIELDS ASSESSMENT
CENTRAL AVENUE&PECAN AVENUE
CHARLOTTE,MECKLENBURG COUNTY,NORTH CAROLINA
NCDEQ BROWNFIELDS PROJECT NO.24002-20-060
ECS PROJECT NO.49-10756-DD
PARAMETER ANALYTICAL RESULTS SCREENING LEVEL
Sample ID TW-1 TW-2 TW-DUP Trip Blank
NC2LGWQS
Collection Date 8/5/20
Semi-Volatile Organic Compounds(SVOCs)By EPA Method 8270
For All ND ND ND ND Various
Volatile Organic Compounds(VOCs)By EPA Method 8260
Acetone 25.0 25.0 25.0 52.3 6,000
All other VOCs ND ND ND ND Various
Notes:
Results presented in micrograms per liter(ug/L),analogous to parts per billion(ppb)
NC2LGWQS=North Carolina 2L Groundwater Quality Standard as of April 1,2013
NS=No Standard
ND=Not detected at or above adjusted reporting limit.
Pace Analytical Services,LLC
9800 KinceyAve. Suite 100aceAnalyticalHuntersville,NC 28078
www.pacelabs.com 704)875-9092
February 17, 2020
Chris Orrell
ECS Southeast, LLP
1900 Center Park Dr
Suite D
Charlotte, NC 28217
RE: Project: Central & Pecan
Pace Project No.: 92464666
Dear Chris Orrell:
Enclosed are the analytical results for sample(s) received by the laboratory on February 11, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni for
Taylor Ezell
[e-mail]
704)875-9092
Project Manager
Enclosures
cc: ECS Southeast Reporting,ECS Southeast
P ,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
9 without the written consent of Pace Analytical Services,LLC. Page 1 of 47
ea `
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.cam 704)875-9092
CERTIFICATIONS
Project: Central&Pecan
Pace Project No.: 92464666
Pace Analytical Services Charlotte
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Certification#:99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 VirginiaNELAP Certification#:460221
North Carolina Wastewater Certification#:12
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 VirginiaNELAP Certification#:460222
North Carolina Drinking Water Certification#:37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 47
Pace Analytical Services,LLC
aceAnwww.pacatabs.com
9800 Kincey Ave. Suite 100alyticalHuntersville,NC 28078
704)875-9092
SAMPLE ANALYTE COUNT
Project: Central&Pecan
Pace Project No.: 92464666
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92464666001 TW-1 EPA6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666002 TW-2 EPA 6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666003 TW-3 EPA 6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666004 TW-4 EPA 6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666005 TW-5 EPA6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666006 TW-6 EPA 6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
92464666007 TW-7 EPA 6010D SH1 7 PASI-A
EPA 7470A SOO 1 PASI-A
EPA 8270E PKS 74 PASI-C
EPA 8260D SAS 64 PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.paeelaba.eom 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-1 Lab ID: 92464666001 Collected: 02/11/20 14:20 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:03 7440-38-2
Barium 104 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:03 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:03 7440-43-9
Chromium ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:03 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:03 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:03 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:03 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:07 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:09 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:09 51-28-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 47
Pace Analytical Services,LLC
aceAnalytical 9800 Kincey Ave. Suite100
Huntersville,NC 28078078
www.pacelabs.cme 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-1 Lab ID: 92464666001 Collected: 02/11/20 14:20 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 19:09 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:09 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:09 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:09 88-06-2
Surrogates
Nitrobenzene-d5(S) 55 13-130 1 02/12/20 10:23 02/12/20 19:09 4165-60-0
2-Fluorobiphenyl(S) 49 13-130 1 02/12/20 10:23 02/12/20 19:09 321-60-8
Terphenyl-d14(S) 87 25-130 1 02/12/20 10:23 02/12/20 19:09 1718-51-0
Phenol-d6(S) 37 10-130 1 02/12/20 10:23 02/12/20 19:09 13127-88-3
2-Fluorophenol(S) 46 10-130 1 02/12/20 10:23 02/12/20 19:09 367-12-4
2,4,6-Tribromophenol(S)58 10-137 1 02/12/20 10:23 02/12/20 19:09 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 18:37 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 18:37 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 18:37 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 18:37 74-97-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 47
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e 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
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ANALYTICAL RESULTS I
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-1 Lab ID: 92464666001 Collected: 02/11/20 14:20 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Bromodichloromethane ND ug/L 1.0 1 02/12/20 18:37 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 18:37 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 18:37 74-83-9 IK,M1
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 18:37 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 18:37 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 18:37 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 18:37 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 18:37 75-00-3
Chloroform ND ug/L 5.0 1 02/12/20 18:37 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 18:37 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 18:37 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 18:37 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 18:37 96-12-8
Dibromochloromethane ND ug/L 1.0 1 02/12/20 18:37 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 18:37 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 18:37 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 18:37 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 18:37 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 18:37 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 18:37 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 18:37 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 18:37 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 18:37 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 18:37 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 18:37 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 18:37 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 18:37 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 18:37 10061-02-6
Diisopropyl ether ND ug/L 1.0 1 02/12/20 18:37 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 18:37 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 18:37 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 18:37 591-78-6
p-lsopropyltoluene ND ug/L 1.0 1 02/12/20 18:37 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 18:37 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 18:37 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 18:37 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 18:37 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 18:37 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 18:37 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 18:37 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 18:37 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 18:37 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 18:37 120-82-1
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 47
Pace Analytical Services,LLC
aceAnalytical 9800 KinceyAve. Suite 100
Huntersville,NC 28078
www.pacataba.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-1 Lab ID: 92464666001 Collected: 02/11/20 14:20 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 18:37 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 18:37 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 18:37 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 18:37 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 18:37 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 18:37 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 18:37 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 18:37 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 18:37 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 18:37 95-47-6
Surrogates
4-Bromofluorobenzene(S) 102 70-130 1 02/12/20 18:37 460-00-4
1,2-Dichloroethane-d4(S) 99 70-130 1 02/12/20 18:37 17060-07-0
Toluene-d8(S) 99 70-130 1 02/12/20 18:37 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.cam 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-2 Lab ID: 92464666002 Collected: 02/11/20 12:40 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:15 7440-38-2
Barium 218 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:15 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:15 7440-43-9
Chromium 94.0 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:15 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:15 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:15 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:15 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:09 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:34 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:34 51-28-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite100aceAnalyticalHuntersville,NC 28078078
www.pacelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-2 Lab ID: 92464666002 Collected: 02/11/20 12:40 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 19:34 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 88-75-5
4-Nitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 19:34 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 19:34 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 19:34 88-06-2
Surrogates
Nitrobenzene-d5(S) 83 13-130 1 02/12/20 10:23 02/12/20 19:34 4165-60-0
2-Fluorobiphenyl(S) 80 13-130 1 02/12/20 10:23 02/12/20 19:34 321-60-8
Terphenyl-d14(S) 105 25-130 1 02/12/20 10:23 02/12/20 19:34 1718-51-0
Phenol-d6(S) 58 10-130 1 02/12/20 10:23 02/12/20 19:34 13127-88-3
2-Fluorophenol(S) 71 10-130 1 02/12/20 10:23 02/12/20 19:34 367-12-4
2,4,6-Tribromophenol(S) 106 10-137 1 02/12/20 10:23 02/12/20 19:34 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 18:56 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 18:56 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 18:56 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 18:56 74-97-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100aceAnalyticalHuntersville,NC 28078
www.paeelabs.com 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-2 Lab ID: 92464666002 Collected: 02/11/20 12:40 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
Bromodichloromethane 1.9 ug/L 1.0 1 02/12/20 18:56 75-27-4
Bromoform ND ug/L 1.0 1 02/12/20 18:56 75-25-2
Bromomethane ND ug/L 2.0 1 02/12/20 18:56 74-83-9 IK
2-Butanone(MEK) ND ug/L 5.0 1 02/12/20 18:56 78-93-3
n-Butylbenzene ND ug/L 1.0 1 02/12/20 18:56 104-51-8
Carbon tetrachloride ND ug/L 1.0 1 02/12/20 18:56 56-23-5
Chlorobenzene ND ug/L 1.0 1 02/12/20 18:56 108-90-7
Chloroethane ND ug/L 1.0 1 02/12/20 18:56 75-00-3
Chloroform 9.2 ug/L 5.0 1 02/12/20 18:56 67-66-3
Chloromethane ND ug/L 1.0 1 02/12/20 18:56 74-87-3
2-Chlorotoluene ND ug/L 1.0 1 02/12/20 18:56 95-49-8
4-Chlorotoluene ND ug/L 1.0 1 02/12/20 18:56 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 02/12/20 18:56 96-12-8
Dibromochloromethane 1.3 ug/L 1.0 1 02/12/20 18:56 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 1.0 1 02/12/20 18:56 106-93-4
Dibromomethane ND ug/L 1.0 1 02/12/20 18:56 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 1 02/12/20 18:56 75-71-8
1,1-Dichloroethane ND ug/L 1.0 1 02/12/20 18:56 75-34-3
1,2-Dichloroethane ND ug/L 1.0 1 02/12/20 18:56 107-06-2
1,1-Dichloroethene ND ug/L 1.0 1 02/12/20 18:56 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 18:56 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 1 02/12/20 18:56 156-60-5
1,2-Dichloropropane ND ug/L 1.0 1 02/12/20 18:56 78-87-5
1,3-Dichloropropane ND ug/L 1.0 1 02/12/20 18:56 142-28-9
2,2-Dichloropropane ND ug/L 1.0 1 02/12/20 18:56 594-20-7
1,1-Dichloropropene ND ug/L 1.0 1 02/12/20 18:56 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 18:56 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 1 02/12/20 18:56 10061-02-6
Diisopropyl ether ND ug/L 1.0 1 02/12/20 18:56 108-20-3
Ethylbenzene ND ug/L 1.0 1 02/12/20 18:56 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 1 02/12/20 18:56 87-68-3
2-Hexanone ND ug/L 5.0 1 02/12/20 18:56 591-78-6
p-Isopropyltoluene ND ug/L 1.0 1 02/12/20 18:56 99-87-6
Methylene Chloride ND ug/L 5.0 1 02/12/20 18:56 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 1 02/12/20 18:56 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 1 02/12/20 18:56 1634-04-4
Naphthalene ND ug/L 1.0 1 02/12/20 18:56 91-20-3
Styrene ND ug/L 1.0 1 02/12/20 18:56 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 18:56 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 02/12/20 18:56 79-34-5
Tetrachloroethene ND ug/L 1.0 1 02/12/20 18:56 127-18-4
Toluene ND ug/L 1.0 1 02/12/20 18:56 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 1 02/12/20 18:56 120-82-1
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 47
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aceAnalytical 9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-2 Lab ID: 92464666002 Collected: 02/11/20 12:40 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Analytical Method:EPA 8260D
1,1,1-Trichloroethane ND ug/L 1.0 1 02/12/20 18:56 71-55-6
1,1,2-Trichloroethane ND ug/L 1.0 1 02/12/20 18:56 79-00-5
Trichloroethene ND ug/L 1.0 1 02/12/20 18:56 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 02/12/20 18:56 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 1 02/12/20 18:56 96-18-4
Vinyl acetate ND ug/L 2.0 1 02/12/20 18:56 108-05-4
Vinyl chloride ND ug/L 1.0 1 02/12/20 18:56 75-01-4
Xylene(Total) ND ug/L 1.0 1 02/12/20 18:56 1330-20-7
m&p-Xylene ND ug/L 2.0 1 02/12/20 18:56 179601-23-1
o-Xylene ND ug/L 1.0 1 02/12/20 18:56 95-47-6
Surrogates
4-Bromofluorobenzene(S) 101 70-130 1 02/12/20 18:56 460-00-4
1,2-Dichloroethane-d4(S) 101 70-130 1 02/12/20 18:56 17060-07-0
Toluene-d8(S) 100 70-130 1 02/12/20 18:56 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 47
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
ww.pacelabs.cem 704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-3 Lab ID: 92464666003 Collected: 02/11/20 11:15 Received: 02/11/20 15:00 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method:EPA 6010D Preparation Method:EPA 3010A
Arsenic ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:18 7440-38-2
Barium 261 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:18 7440-39-3
Cadmium ND ug/L 1.0 1 02/12/20 00:56 02/12/20 12:18 7440-43-9
Chromium 128 ug/L 5.0 1 02/12/20 00:56 02/12/20 12:18 7440-47-3
Lead ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:18 7439-92-1
Selenium ND ug/L 10.0 1 02/12/20 00:56 02/12/20 12:18 7782-49-2
Silver ND ug/L 5.0 1 02/12/20 00:56 02/12/20 12:18 7440-22-4
7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A
Mercury ND ug/L 0.20 1 02/12/20 13:10 02/17/20 15:17 7439-97-6
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
Acenaphthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 83-32-9
Acenaphthylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 208-96-8
Aniline ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 62-53-3
Anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 120-12-7
Benzo(a)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 56-55-3
Benzo(a)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 50-32-8
Benzo(b)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 205-99-2
Benzo(g,h,i)perylene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 191-24-2
Benzo(k)fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 207-08-9
Benzoic Acid ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:00 65-85-0
Benzyl alcohol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 100-51-6
4-Bromophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 101-55-3
Butylbenzylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 85-68-7
4-Chloro-3-methylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 59-50-7
4-Chloroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 106-47-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 111-44-4
2-Chloronaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 91-58-7
2-Chlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 95-57-8
4-Chlorophenylphenyl ether ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 7005-72-3
Chrysene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 218-01-9
Dibenz(a,h)anthracene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 53-70-3
Dibenzofuran ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 132-64-9
1,2-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 106-46-7
3,3'-Dichlorobenzidine ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 91-94-1
2,4-Dichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 120-83-2
Diethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 105-67-9
Dimethylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 131-11-3
Di-n-butylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 02/12/20 10:23 02/12/20 20:00 51-28-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 47
aceAnalytical
www.pecelabs.com
Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
704)875-9092
ANALYTICAL RESULTS
Project: Central&Pecan
Pace Project No.: 92464666
Sample: TW-3 Lab ID: 92464666003 Collected: 02/11/20 11:15 Received: 02/11/20 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
2,4-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 606-20-2
Di-n-octylphthalate ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 6.0 1 02/12/20 10:23 02/12/20 20:00 117-81-7
Fluoranthene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 206-44-0
Fluorene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 86-73-7
Hexachloro-1,3-butadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 87-68-3
Hexachlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 77-47-4
Hexachloroethane ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 193-39-5
Isophorone ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 78-59-1
1-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 90-12-0
2-Methylnaphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 95-48-7
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 15831-10-4
Naphthalene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 91-20-3
2-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 88-74-4
3-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 99-09-2
4-Nitroaniline ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 100-01-6
Nitrobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 98-95-3
2-Nitrophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 88-75-5
4-Nitro phenol ND ug/Lpg 50.0 1 02/12/20 10:23 02/12/20 20:00 100-02-7
N-Nitrosodimethylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 108-60-1
Pentachlorophenol ND ug/L 20.0 1 02/12/20 10:23 02/12/20 20:00 87-86-5
Phenanthrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 85-01-8
Phenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 108-95-2
Pyrene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 120-82-1
2,4,5-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 95-95-4
2,4,6-Trichlorophenol ND ug/L 10.0 1 02/12/20 10:23 02/12/20 20:00 88-06-2
Surrogates
Nitrobenzene-d5(S) 81 13-130 1 02/12/20 10:23 02/12/20 20:00 4165-60-0
2-Fluorobiphenyl(S) 76 13-130 1 02/12/20 10:23 02/12/20 20:00 321-60-8
Terphenyl-d14(S) 92 25-130 1 02/12/20 10:23 02/12/20 20:00 1718-51-0
Phenol-d6(S) 52 10-130 1 02/12/20 10:23 02/12/20 20:00 13127-88-3
2-Fluorophenol(S) 66 10-130 1 02/12/20 10:23 02/12/20 20:00 367-12-4
2,4,6-Tribromophenol(S)97 10-137 1 02/12/20 10:23 02/12/20 20:00 118-79-6
8260D MSV Low Level Analytical Method:EPA 8260D
Acetone ND ug/L 25.0 1 02/12/20 19:14 67-64-1
Benzene ND ug/L 1.0 1 02/12/20 19:14 71-43-2
Bromobenzene ND ug/L 1.0 1 02/12/20 19:14 108-86-1
Bromochloromethane ND ug/L 1.0 1 02/12/20 19:14 74-97-5
REPORT OF LABORATORY ANALYSIS
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Date:02/17/2020 05:12 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 47