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HomeMy WebLinkAboutNC0024911_Solube BOD and Tox Results_20210624Action History (UTC-05:00) Eastern Time (US & Canada) Submit by Anonymous User 6/24/2021 9:50:27 AM (Supplemental Submittal) Submit by Bennett, Tilman B 11/24/2021 9:24:04 AM (Supplemental Info Submittal) IN Tox Lab Reports and Soluble BOD Results Bennett, Tilman B assigned the task to Bennett, Tilman B 11/24/2021 9:23 AM • The task was assigned to Thedford, Wren, Bennett, Tilman B 6/24/2021 9:50 AM Initial Review Information Updated ID#: * IMPORTANT: REVIEWER SHOULD VERIFY and revise here if necessary. NCO024911 How should this project be handled?* File Discard Information Submitted on 6/24/2021 Submitter Information Name: Roger Edwards Who is submitting the information? Email Address:* RogerE@msdbc.org Submittal Information The Division of Water Resources (DWR) is providing this site to allow for the upload of required supplemental information associated with discharge monitoring reports (DMR). All DMR data is required to be submitted electronically through the eDMR system and should not be submitted here. Division staff will review all uploaded documents and will only maintain required information. Documents such as laboratory reports are not required to be submitted and will not be maintained in the system. Project Information: Please supply the permit number for this project. ...................................................................................................................................................................................................................................................................................................................................................................................................... Existing ID#* Permit Number NCO024911 Examples: NCxxxxxxx or NCGxxxxxx Facility Name: * Metropolitan Sewerage District of Buncombe County County: Buncombe Please upload all files that need to be submited.* Click the upload button or drag and drop files here to attach document May 2021 Toxicity.pdf 971.83KB 5 - May 2021 Soluble BOD Results.pdf 25.51 KB Only pdf files are accepted. Comments about the attachments: * By checking the box and signing box below, I certify that: o I have given true, accurate, and complete information on this form; a I agree that submission of this Supplemental Information form is a "transaction" subject to Chapter 66, Article 40 of the NC General Statutes (the "Uniform Electronic Transactions Act) a I agree to conduct this transaction by electronic means pursuant to Chapter 66, Article 40 of the NC General Statutes (the "Uniform Electronic Transactions Act'); a I understand that an electronic signature has the same legal effect and can be enforced in the same way as a written signature; AND o I intend to electronically sign and submit the Supplemental Information form." Full Name: Roger Edwards Signature: Date Submitted: 06/24/2021 Metropolitan Sewerage District of Buncombe County Soluble BOD Results Date Effluent Soluble BOD (Mg/L 5/5/2021 7.7 5/12/2021 4.6 5/19/2021 5.0 5/26/2021 6.4 Average 5.9 Analytical www,pecelebs.com June 08, 2021 Mr. Roger Edwards Metropolitan Sewerage District 2028 Riverside Drive Asheville, NC 28804 RE: Project: MSD NC0024911 Pace Project No.: 92537883 Dear Mr. Edwards: Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Enclosed are the analytical results for samples) received by the laboratory between May 11, 2021 and May 13, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is attached to this report in its entirety. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorri Patton lorri.patton@pacelabs, com 1(828)254-7176 Project Manager Enclosures cc: Ms. Shannon Bergeron, Metropolitan Sewerage District Mr. John Gosnell, Metropolitan Sewerage District Mr. Chad Ledford, Metropolitan Sewerage District Mr. Dwayne Martin, Metropolitan Sewerage District Ms. Cassandra McKnight, MSD of Buncombe County Patrick Smith, MSD of Buncombe County, NC Mr. Alan Taylor, Metropolitan Sewerage District REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, out the written consent of Pace Analytical Services, LLC. Page 1 of 13 Document Name: Sample Condition Upon Recei Document No.: F-CAR-CS*033•Rev,07 Document Revised: October 28, 2020 Page 1 of 2 issuing Authority: Pace Carolinas Quality Office Laboratory receiving samples; Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[]Atlanta❑ Kernersyilie❑ III • � II, � Client Name; 11 r W0# 0 92537883 _. \ Project #: il Courier: ❑Fed Ex LJUPS UUSPS �(Cli ❑ Commercial ❑Pace ❑Other:_ Custody Seal Present? ❑Yes 496 Seals Intact? ❑Yes ^ joNo Packing Material: ❑Bubble Wrap ❑Bubble Bags�ne ❑ Other Thermometer:+l�vet ❑Blue ❑ IR Gun ID: q 3 ((j 7 I Type of Ice: Correction Factor: Cooler Temp: 't 'Ed Add/Subtract (°C) r' Cooler Temp Corrected ('C); USDA Regulated Soil (M N/A, water sample) Did samples originate in a quarantine zone within the United States, CA, NY, or SC (check maps)? Chain of Custody Present? Samples Arrived within Hold Time? Short Hold Time Analysis (<72 hr,)' Rush Turn Around Time Requester Sufficient Volume? Correa ontalners lJsod? -Pace Containers Used? Intact? Sample Labels Match COC1 -Includes Headspace in Trip Blank Present? Blank Custody Seals COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFI[ATIO Person contacted: Mona SCURF Review: Project Manager SRF Review: 1. Yes ❑No ❑N/A )Yes ❑No ❑N/A —I 6. �res ❑No ❑N/A 7. ❑Yes ❑No j�N/A 8. Yes []No❑N/A 9, 1111111111111111 37883 Dale/Initials Person EKamining Contents: ( T, 11 I giologicaiTissue Frozen? ❑Yes ❑No EMN/A ❑None Tempshould be above freezing to 6°C ]Samples out of temp criteria. Samples on Ice, cooling process hasbegun ❑Yes ❑No. INN/A 10. ❑Yes ❑No �]NJA 11, Date/Time: Did In samples originate from a foreign source (Internationally, dingHawali and Puerto Rico)? ❑Yes No it containers: Date: Date: Field Data Required? ❑Yes ❑Nd Page 2 of 13 Document Name: Condition Upon Recei Document No,, F-CAR-CS-033-Rev.07 *Check mark top half of box if pH and/ dechlorination is verified and within the acceptance range for preservation samples, Exceptions; VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg *Bottom half of box is to list number of bottles g r� 3 4 5 6 7 8 9 rTr: it Document Revised: October 28, 2 t(SCUR) Page 2 of 2 Issuing Authority: Pace Carolinas Quality Office Project # WO# : 92537 PM: LJP Due Date; 05/25/21 CLIENT: 93vii ^ !A v V U 2 v .0 Z Z r U 0 Z V a Q z d b j z z z _ W N v ? y V ^ O .n al Nv Z Q cr Z ` v Z 2 2 v x x °+ x N v r a z ¢ m z z O N m N m ai v a a N d `^ ti 2 a ? Q z vi u u�^ '^ 0 m u S ra v a a v O � Q m rn x 'N N a c c °c• v O O d O a c O ry E Z Z it o a m v o c 7 C = = N Z a j = _ N S j U N CL O N N U N N 'w U U. U V U U V L N N 1�] E i Z 5 i Y MW _ 'N A �� ,� •� '� � ,N � 9 E 9 6 b d d d Q w `w m °; `� 6 E a a a a a a a ° E E d E d O 0 O O a n J J J LL J E d d J d _, > r1 �J % ..�. N J J J E -� J E E E � E E E E v v 0) of w E m E E E E y E of o bo of of V1 O b ._ Ln 101� V1 N 3 O l7 O O O O to H N q N N 1� H N N H N = ''� _H N H N O q Y a Y ¢ D j a U O M '� Ln Z N U LL O 1 ? t% :il d = F- O X h= F= O 1p a1 V M N H 7 M a a Ur H rl M M M Ol OI a1 Lo O CL M m Q V O m m m m m m m m 3 a a a a a a o>>>> pH Adjustment Sample ID Type of Preservative pH upon receipt Log for Preserved Samples Date preservation adjusted Time preseivation Amount of Preservative LotB adjusted added __u__ n[u A10 re.flftrofinn nffirP lip. Note; Whenever there is a discrepancy affecting Norm Laronna compnance sarnpiea, d LUNY Ul "ll;e :uj ill •Vill Ur a_: i<<_ Ltl� l•�%••; ��•-••••- --• - _ ..__ Out of hold, incorrect preservative, out of temp, incorrect containers. Page 3 of 13 ' 7 C Z4 0 Cal �o� 0 o �. O 5, 0 y f ( O 7 N a " " n " o e N O z b a ti C 0 a 0 EL K C� V1 � N � d �j to `! `''' (C) Grab(C)13 Composilc O n d a n n 3 o 3 ® G � a r o t 3 � d � o�3a 3 K: Water t\cl Slor Moler _ Sediment lion -Regulator) # of Contolners Plastic Glass VOIUn1C Ice N ��poCO Acute Possf'nil 4 t\eutc t\lnlli-Cone, Clironic Ms/Foil a— Chroiticiblolli-Colic. n C, dnbin D, mnbigun p n arsidc a Chironomus —r—�—�—�-�1 �lncroinverlebrale ID � m 5 a 9 rn � N ns N -+ i n pN1 n v N n CO N N �m o m V1 p� " 10 I 0 171"f r1S51 GNM LAB ID U Page 4 of 13 1 0 Document Name: Document Revised: October 28, 2020 Sample Condition Upon Recelpt(SCUR) Page 1 of 2 aceAnalytical Document No,: issuing Authority: 1 F•CAR•CS-033•Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheviile�o*4�Eden❑ Greenwood ❑ Huntersviile ❑ Raleigh❑ Mechanicsville❑ Atlanta[] Kernersville❑ w � Sample condition " �` Upon Receipt .: ' <` Courlent ■.. Ex ■ commercial []Pace ustody■ Project : Seals Intact? ❑Yes �lo Packing Material; ❑eubbie Wrap ❑Bubble Bags -}None ❑ Other Thermometer; ❑ IR Gun ID• 3Tt;� ( i@Wet ❑Blue • Type office: Correction Factor: ,e Cooler Temp: �' �- Add/Subtract (°C)y Cooler Temp Corrected (°C): � . / o C USDA U5 (®T�/A, water Did C� 5 Z 4 � Date/Initials Person Examining Contents: s' Biological Tissue Frozen? ❑Yes ❑No +RN/A ❑None Temp should be above freezing to 6°C ❑samples out of temp criteria, Samples on ice, cooling process fiasbegun Regulated Soil sample) samples originate in a quarantine zone within the United States: CA, NY, or SC(check maps)? Did samples originate from a foreign source (internationally, []Yes ❑No IncludingHawaii and Puerto Rico)? ❑Yes ❑No Comments/Discrepancy: Chain of Custody Present? &Yes []NO ❑N/A 1. Samples Arrived within Hold Time? Yes ❑No ❑N/A 2. Short Hold Time Analysis (02 hr.)? []Yes &o ❑N/A 3. Rush Turn Around Time Requested? []Yes &No ❑N/A 4. Sufficient Volume? ayes []No ❑N/A 5. Correct Containers Used? 4Tes ❑No ❑N/A 61 *Pace Containers Used? &Yes []No ❑NIA Containers Intact? (�rYes j[3No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes o [Bt/A 8. Sample Labels Match COC? Des ❑No ❑N/A 9. •Includes Date/Time/ID/Analysis Matrix: W Headspace in VOA Vials (>5.6mm)? ❑Yes ❑Pin N/A 10. Trip Blank Present? ❑Yes []No i O/A Trip Blank Custody Seals Present? Des ❑No ®N?A COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFI Person contacted: Project Manager SCURF Review: Project Manager SRF Raview; Date/Time; Lot ID of split contain Date:. CJ bate: Field Data Required? ❑Yes ❑No Page 6 of 13 COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFI Person contacted: Project Manager SCURF Review: Project Manager SRF Raview; Date/Time; Lot ID of split contain Date:. CJ bate: Field Data Required? ❑Yes ❑No Page 6 of 13 Document Name; Sample Condition Upon Recell Document No.: F•CAR-CS-033,,Rev07 *Check mark top half of box If pH and/or dechlorination is verified and within the acceptance range for preservation samples, Exceptions; VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottles Project if Docume October 28, 2020 Page 2 of 2 Issuing Authority, nsi.o rnrnlinas Quality Office PH u Z z z v u O U �` df A d 9 Z w AOOO`FZ N otS `� v N V U Z I ¢ K Z Z W a•Oi d V w Z V z Y � ON Z Z Z v Z N T ,,, z N N v 2 � T a Z W h Z Q. C' N FL -'11'1 W V Z - V N W ? d U` .d. V a Idol p u T u a c i o a, G y ° p c C a O Q 0 uO E Z O Z a Mo O c c c a z 0 C7 C O vl N _... N� 0 Z t > g ii U 7 C T 2 N Z V U N T Q 0. C H �' '�• U W (G D N a Z w 2 J V h! c Al PJ y k• A q C! u U U E V u « v E Z N O 2 x a }u G `a Q m m R m id ❑ OQ .n E � E ¢ ¢ d Q t>. rJ LL E E Q io�nn O 0 O > C C 'J CA 4 4 1 �y [1 C Q (�7 J J J J J J J J p. J '•� J J IWO,Q V C a E J J ) J E E E O F E E E E E E E E 'o E E E 0 O i Y o v M E > > o o 0 0 N v N rNi N � N N it H N O q q a 5 y rt Q. ; in ' 4 Z T 0. N p�t� tl in O 7 D Ji '2 N U u�. X �n F- Q lX7 Gi M l7 M l7 N r•1 M M M m m O, V 4 v 0. n, a a a a a a l7 t7 l7 l7 C7 l9 l7 W 0 0 > m d > Q m m m m m m m m 3 a a a a a a o>> 11r NNI N I \NNNI I \1 N 3 I \NNN I \d 4\6WA \ 5 \ 6 Opii`�`Oiii 7 I \NN 3 9 NNN 10 NN 11 12 Adjustment Sample ID Type of Preservative pH upon receipt Log for Preserved Samples Date preservation adjusted Time preservation Amount of Preservative Lot tf adjusted added rif thin fnrm will b ont to rhp North Carolina DEHNR Certification Office (La, ivoce;vvnenevercnereisaaiscrepancyanc�.uu6ivul,1 1•.•,I••j4P I•••.W"I,."�•----•••�•__,___,_, _. Out of hold, incorrect preservative, out of tamp, Incorrect containers, Page 7 of 13 Ceriodaphilia dubia Survival and Reproduction Test EPA-821-R-02-013 Method 1002 Client: MSD OF BUNCOMBE COUNTY Facility: WRF NPDES #: NC0024911 Test Date: 12-May-21 Laboratory ID #: T59190 Test Reviewed and Approved By: Robert W, Kelley, Ph.D. Ifficer Certification #E87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Certification #23104 Florida Dept. of Health, Included results pertain only to provided sam les. rage 1 of 6 Certification # 022 Page 8 of 13 Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date 31-May-21 Facility: MSD OF BUNCOMBE CO. WRF NPDES#NCO024911 Pipe# 001 County: Buncombe Laboratory Performing Test: Comments X Signatu e o Aerator in Responsible Charge X Signature of Laboratory Supervisor MAIL ORIGINAL TO Environmental Sciences Branch Div. of Water Quality N.C. DENR 1621 Mail Service Center Raleigh, North Carolina 27699-1621 North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test FChron!cTestsults 0 2.508 CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 0.0% # Young Produced 22 17 21 22 19 20 22 18 21 22 21 17 Adult (L)Ive (D)ead L L L L L L L L L L L L Effluent % TREATMENT 2 ORGANISMS # Young Produced Adult (L)Ive (D)ead pH Control Treatment 2 D.O. Control Treatment 2 23 18 22 19 22 17 22 19 20 19 22 19 L L L L L L L L L L I L L 1st sample 7.8 7.9 8.0 8.1 start end 1 sl samola 8.2 7.8 8.2 7.8 LC50IAcute Toxicity Test (Mortality expressed as %, combining replicates) 1 sl sample 7.8 8.3 7.8 8.5 start and lslsam le 7.5 8,1 7.6 8.6 2nd sample 7.8 8.3 8.0 8.5 start end 9nd samola 8.0 7,9 7.7 8.5 �n (Startl Date 1 10-May-21 to This for Either Test Sample 1 X 24hrs. Sample 2 X 24hrs. Hardness (mg/L) Spec. Cond. (pmhos) Chlorine (mg/L) at 0% 20.2 Control Control 0% 20.2 Treatment 2 Treatment 2 Control CV 9.7% 3rd Brood PASS FAIL 1 1st 2nd Tox Tox Dilution Sample Sample 85.1 326 500 489 <0.05 <0.05 1.7 0.9 slart/end slart/end Control High Cone. pH D.O. Page 9 of 13 DEM Form AT-1 Page 2 of 6 STATISTICAL ANALYSIS RESULTS Facility: MSD xPOESa NCO024911 Sample 11): WWTP LTTH T59190 Date; 12-May-21 Laborato : i Certification #: NCO22 Ex . Date: l l/1/2021 val Data 7 Day Survival Test Used: FISHERS TEST Control 100% Test Statistic: P= 1.000 Effluent 100% Critical Value: P= 0.01 PASS: The effluent does not reduce survival of the test organisms. Reproduction Data Raw Data Test for Normality Mean young/female Std. Dev. Test Used: Shapiro-Willcs Test; Control 20.2 1,95 Effluent 20.2 1.95 W: 0.889 Critical Value: 0.884 Analysis for Differences in Reproduction Test for Homogeneity of Variance Test Used: Equal Variance t Test, Test Used: F Test Calculated t= 0.00 F= 1.00 Critical Value= 2.51 Critical Value= 5.32 The data are homogeneous in variance PASS: The effluent is not chronically toxic. Page 10 of 13 Page 3 of 6 1 Control 2 Mortality 3 and Reproduction by 4 5 Test Day 6 7 8 Total source rep 115 5-5 1 +4+7 11 22 W24-30 2 +3+5 9 17 02 4-29 3 +4+7 101 21 HH6 5-5 4 +4+6 121 22 V1 4-30 5 +3+5 111 19 N14-29 6 4 +7+9 20 B8 4-28 7 4 +8+10 22 P2 4-29 8 3 +7+8 18 V2 4.30 9 +4+6 11 21 O1 4-29 10 +3+7 12 22 A10 4-30 11 +4+6 11 21 LL9 5-5 12 +3+5 9 17 13 N/A 0 14 N/A 0 15 N/A 0 16 N/A 0 17 N/A 0 18 N/A 0 19 N/A o Mean 20 N/A 0 20.2 12 1 % Effluent 2 Mortality and Reproduction by Test Day 3 4 5 6 7 8 Total 115 5-5 1 +4+7 12 23 W2 4-3 2 +3+6 9 18 02 4-2 3 +4+7 11 22 HH6 5- 4 +3+6 10 19 V1 4-30 5 +4+7 11E22 N1 4 29 s 3 +s+6 B8 4-28 7 q +7+11 P2 4-29 8 3 +7+9 V2 4-30 9 +3+7 10Q1 4-2 10 3 +6+10A10 4-3 11 +4+6 12 LL9 5-5 12 +3+7 9 19 0 13 N/A 0 0 14 N/A 0 0 15 N/A 0 0 16 N/A 0 0 17 N/A 0 0 18 N/A 0 0 19 N/A o Mean 0 20 NIA 0 20.2 rd11a4v AM AM fSi JC AM AM JC AM JC 19-May-21 y 07:46 AM 02:06 PM 06:56 AM 0614 AM 11:20 AM 17:36 AM 12:54 PM JC A7a1v lam , . 24.9 25.2 Old temp. °C 25.3 25.3 24.9 Control New tamp. °C 24.6 24.8 190 5-2200 Comments inl dubia JID=Dead N/A•Losl or not used I� Page 4 of 6 Page 11 of 13 N b II CII flvl Cldt`fUISSN •L.l.tCool IJ U G C� It U A. u " rel at ra no N -:� Itz —J—-- u cc�l F >, C ° N O w V a A Ei U i U I] yo CII CD� E a d. -- o _ 21i:1h\ hl N to snuunlo.IIIIJ 4� CJ ,ID m rn to w c ltlolll;,(I.1 r-IIi N 0 .h ol)IS.IOA�IS� G� c N o dtuI,ILIS pls,fp� n N .r o o � a ntouull,� puagllt,i o fool vignp - uAt,- - 1-6 G IIO�IISSl1rI alliQll17 U L.I.Julmd I. i auo�"!III)bV autos _ IIOtIIS51;4I alnaV --- O (, > `rU � � p im [� bit N ,V OoI � Con U •u N N N a aLLu110AQVI Cc 4 [ 7� a '� SSltl� o a~i E Ual lSl;l� o s.laulaWo� ,lo Ip d.loluln9a�-uoly C, N )llalLlll)as C1 � o �° daltMuu.la)S � o � lov.lalUJ\,\ u11010 .n o Rl� outi N to u N w � r II i n CD m u a C� o �� o Cd o ( c IN O �' a o o QpI;b _ W Q o � E ~dN, %R. a o v m ;h W Q Cool b 0. 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