NCG030694_2021 DMR_20211012

14
hart hfckman
SMARTER ENVIRONMENTAL. SOLUTIONS
Via Online Portal & 2nd Day FedEx
September 29, 2021
North Carolina Department of Environmental Quality
Division of Energy, Mineral and Land Resources
450 West Hanes Mill Road, Suite 300
Winston-Salem, North Carolina 27105
Re: DMR September 2021 — NCG030694 — LLFIex, LLC
Oracle Flexible Packaging, Inc. (Former)
1300 Cunningham Avenue
Winston-Salem, Forsyth County
H&H Project No. LLF-007
Dear Madam/Sir:
On behalf of LLFIex, LLC (LLFIex), Hart & Hickman, PC (H&H) is submitting the enclosed semi-
annual stormwater Discharge Monitoring Report (DMR) for the site referenced above in
accordance with the industrial stormwater permit (NCG030694). Please note there are benchmark
value exceedances in Stormwater Discharge Outfall (SDO) samples SDO-001, SDO-002, and
SDO-004. Chemical Oxygen Demand (COD) was detected above the benchmark of 120 mg/L for
SDO-001 (139 mg/L) and SDO-002 (218 mg/L). Copper was detected above the benchmark of
0.010 mg/L for SDO-004 (0.011 mg/L). Historically, the Former Cunningham Plant outfalls have
exceeded the benchmark for copper.
In 2014, DEQ performed an inspection to assess compliance with the NPDES general stormwater
pen -nit to evaluate the drainage of the facility's five SDOs. The SDOs were found to be in excellent
condition and concluded in a letter dated June 5, 2014 that offsite sources have opportunities to
contaminate samples taken from outfalls 1, 2, 4 and 5. Considering the 2014 NC DEQ letter, none
of the metal exceedances require a tiered response.
Monitoring concentrations of COD in stormwater discharge is a new requirement under the new
general stormwater permit which became effective July 1, 2021. Because COD has not been
monitored prior to this sampling period, there have been no previously detected exceedances in
SDO-001 or SDO-002 above the benchmark for COD. Therefore, a Tier One response will be
documented in the Stormwater Pollution Prevention Plan (SWPPP) in accordance with the
industrial stormwater permit (NCG030694). This response will identify potential causes and
feasible actions to prevent exceedances in the future. The response will also list monitoring and
inspection details such as the date and value of the benchmark exceedance, the inspection date,
selected actions, and the date the selected actions are implemented.
2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301
Charlotte, NC 28203 Raleigh, NC 27607 www,harthickman.com
704.586.0007 main 919,847.4241 main

September 29, 2021
Page 2
Additionally, a stormwater management inspection will be conducted to evaluate potential
background sources of COD and whether conditions onsite can be improved to prevent
exceedancesin the future.
Should you have any questions or need any additional information, please feel free to contact us.
Sincerely,
Hart & Hickman, PC
�v4j&-
Matt Bramblett, PE
Principal
Enclosures
4'� a,
Gregory Kanellis, PE
Project Manager
CC: Mr. Jason Caple, LLFIex (PDF via email)
Mr. Shawn Sylvester, LLFIex (PDF via email)
Ms. Mary Katherine Stukes, Moore & Van Allen (PDF via email)
14
hart IN, hickman
https:1/harthick.sharepoinl. rontfsites/MaslerFiles-11Shued Doc=enlSWAAA-blaster Projects Ulex, LLC (LLFYLLF-007 SWPPP hfonitorin¢j MRS/Seplember SMARTER ENVIRONMu EMW SO[ IONS
2021 QO2107 DMR Cover Letter_doex

NCDEQ Division of Energy, Mineral and Land Resources
Stormwater Discharge Monitoring Report (DMR) Form for NCG030000
Metal Fabrication
Click here for instructions
Complete, sign, scan and submit the DMR via the Stormwater NPDES Permit Data Monitoring Report (DMR) Upload form within
30 days of receiving sampling results. Mail the original, signed hard copy of the DMR to the appropriate DEMLR Regional Office.
Certificate of Coverage No. NCG03 0694
Person Collecting Samples: Glenn Price (Pace Analytical)
Facility Name: Former Oracle 200 Facility
Laboratory Name: Pace Analytical
Facility County: Forsyth
Laboratory Cert. No.: Asheville, NC(40), Eden, NC (633), Huntersville, NC (12)
Discharge during this period:
M
Yes
No (if no, skip to signature and date)
Has your facility implemented mandatory Tier response actions this sample period for any benchmark exceedances? Elyes MNo
If so, which Tier (1, II, or III)? 1
A copy of this DMR has been uploaded electronically via htt s: edocs.de .nc. ov Forms SW-DMR E]Yes No
Date Uploaded: 09/27/2021
Analytical Monitoring Requirements for Outfalls with Industrial Activities - Benchmarks in (tied)
Parameter
Parameter
Outfall 01
Outfall02
Outfall03
Outfall04
Outfall05
Code
N/A
Receiving Stream Class
C
C
C
C
C
N/A
Date Sample Collected MM/DD/YYYY
09/01/2021
09/01/2021
09/01/2021
09/01/2021
09/01/2021
46529
24-Hour Rainfall in inches
2.9
2.9
2.9
2.9
2.9
C0530
TSS in mg/L (100 or 50*)
46.8
90.0
<3.2
4.6
3,8
pH in standard units (6.0- 9.0 FW,
00400
7.14
6.88
6.93
7.11
7.09
6.8-8.5 SW)
Copper, total recoverable in mg/L
01119
0.0057
0.010
0.0054
0,011
0.0052
(0.010 FW, 0.0058 SW)
Lead, total recoverable in mg/L
01051
(0.075 FW, 0.22 SW)
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
zinc, total recoverable in mg/ L (0.126
01094
FW, 0.095 SW)
0.040
0.062
0.039
0.063
0.039
Chemical Oxygen Demand (COD) in
00340
mg/L(120)
139
218
65.4
65.4
70.2
00552
Non -Polar Oil & Grease in mg/L (15)
<5.0
<5.0
<4.9
<5.0
<5.0
* Outfalls to Outstanding Resource Waters (ORW), High Quality Waters (HQW), Trout Waters (Tr) and Primary Nursery Areas (PNA)
have a benchmark TSS limit of 50 mg/L. All other water classifications have a benchmark of 100 mg/L
FW (Freshwater) SW (Saltwater)
Notes (optional):
"I certify by my signature below, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my
inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information
submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations."
Signature of
ssylvester@_Ilflex.com
Email Address
Delegated Authorized Individual
Date
[phone]
Phone Number

aceAnaIXical
wwtr.pacalabs.aan
September 10, 2021
Greg Kanellis
Hart & Hickman
3921 Sunset Ridge Rd.
Suite 301
Raleigh, NC 27607
RE: Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
Dear Greg Kanellis:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on September 02, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNIINELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
• Pace Analytical Services - Kernersville, NC
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
1(704)875-9092
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the w"en consent of Pace Analytical Services, LLC.
Page 1 of 26

aceAnalytical
www.pacelab3.com
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NFLAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
Pace Analytical Services Eden
205 Fast Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NFLAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiafVELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, rLC- Page 2 of 26

aceAna1j4ica1
www.picalabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 Kincey Ave_ Suite 100
Huntersville, NC 28078
[phone]
Project:
Hart & Hickman Oracle 200
Pace Project No.:
92559188
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92559188001
OUTFALL SD01
SM 2540D-2011
AED
1
PASI-E
EPA 1664E
TEG
1
PASI-C
EPA 200.7 Rev 4.4 1994
SH1
3
PASI-A
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92559188002
OUTFALL SD02
SM 254OD-2011
AED
1
PASI-E
EPA 1664B
TEG
1
PASI-C
EPA 200.7 Rev 4.4 1994
SH1
3
PASI-A
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92559188003
OUTFALL SD03
SM 2540D-2011
AED
1
PASI-E
EPA 1166413
TEG
1
PASI-C
EPA 200.7 Rev 4.4 1994
SH1
3
PASI-A
KRG
4
PAS[-KR
SM 5220D-2011
JP1
1
PASI-A
92559188004
OUTFALL SD04
SM 2540D-2011
AED
1
PASI-E
EPA 1664B
TEG
1
PASI-C
EPA 200.7 Rev 4.4 1994
SH1
3
PASI-A
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92559188005
OUTFALL Si
SM 2540D-2011
AED
1
PASI-E
EPA 1664B
TEG
1
PASI-C
EPA 200.7 Rev 4.4 1994
SH1
3
PASI-A
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
PASI-KR = Pace Analytical Services - Kernersville, NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 26

aceAnalytical
www.patelabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
Pace Analytical Services, LLC
9800 Kincey Ave_ Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL SD01 Lab ID: 92559188001 Collected: 09/01/21 17:01 Received: 09/02/21 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
46.8 mglL 8.1
1
09/07/21 16:23
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
N❑ mglL 5.0
1
09/08/21 07:53
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
0.0057 mglL 0,0050
1
09/08/2104:57 09109/2104:31 7440-50-8
Lead
ND mglL 0,0050
1
09/08/2104:57 09/09/2104:31 7439-92-1
Zinc
0.040 mglL 0.010
1
09/0812104:57 09/09/2104:31 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
09/01/21 17:01
Collected By
Glenn
1
09/01/21 17:01
Price
pH
7.14 Sid. Units
1
09/01/21 17:01
Temperature
28.6 deg C
1
09/01/21 17:01
5220D COD
Analytical Method: SM 5220D-2011 Preparation Method:
SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
139 mglL 25.0
1
09/08/21 02:56 09/08/21 06:32
Date: 09/10/2021 03:13 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytcal Services, LLC.
Page 4 of 26

aceAnalXical
www.patelabs.tam
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
Sample: OUTFALL SD02 Lab ID: 92559188002 Collected: 09/01121 17:12 Received: 09/02/21 12:00 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D-2011
Pace Analytical Services - Eden
Total Suspended Solids
90.0 mg/L 13.2
1
09/07/21 16:23
1664 SGT-HEM, TPH
Analytical Method: EPA 1664E
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg1L 5.0
1
09/08/21 07:53
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
0.010 mg1L 0.0050
1
09/0812104:57 09/09/2104:47 7440-50-8
Lead
NO mg1L 0.0050
1
09/0812104:57 09/09/2104:47 7439-92-1
Zinc
0.062 mg1L 0.010
1
0910812104:57 09/09/21 04:47 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
09/01/21 17:12
Collected By
Glenn
1
09/01/21 17:12
Price
pH
6.88 Std. Units
1
09/01/21 17:12
Temperature
27.9 deg C
1
09/01/21 17:12
5220D COD
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
218 mg/L 25.0
1
09/08/21 02:56 09/08/21 06:32
Date: 09/10/2021 03:13 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 26

ac6Analytical
www.pacelabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 2807E
[phone]
Sample: OUTFALL SD03 Lab ID: 92559188003 Collected: 09/01/21 17:19 Received: 09/02/21 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
ND mg/L
3.2
1
09/07/21 16:25
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg/L
4.9
1
09/08/21 07:53
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
0.0054 mg/L
0.0050
1
09/08/21 04:57 09/09/21 04:51 7440-50-8
Lead
ND mg/L
0.0050
1
09/0812104:57 09/09/21 04:51 7439-92-1
Zinc
0.039 mg/L
0.010
1
09/0812104:57 0910912104:51 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville,
NC
Performed by
Pace
1
09/01/21 17:19
Collected By
Glenn
1
09/01/21 17:19
Price
pH
6.93 Sid. Units
1
09/01/21 17;19
Temperature
28.1 deg C
1
09/01/21 17:19
5220D COD
Analytical Method: SM 5220D-2011
Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
65.4 mg1L
25.0
1
09108/21 02:56 09/08/21 06:33
Date: 09/10/2021 03:13 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 26

aceAnalyiical
www.pacalab3sars
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL SD04
Parameters
Lab ID: 92559188004 Collected: 09/01/21 17:29
Results Units Report Limit OF
Received: 09/02/21 12:00 Matrix: Water
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
4.6 mg/L 3.3
1
09/07/21 16:25
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
NO mg/L 5.0
1
09/08/21 07:53
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
Copper
0.011 mg1L 0.0050
1
09/08/2104:57 09109/2104:54 7440-50-8
Lead
ND mg1L 0.0050
1
09/08/2104:57 09/09/2104:54 7439-92-1
Zinc
0.063 mg1L 0.010
1
09/0812104:57 09109/2104:54 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
09/01/21 17:29
Collected By
Glenn
1
09/01/21 17:29
Price
pH
7.11 Std. Units
1
09/01/21 17:29
Temperature
28.1 deg C
1
09/01/21 17:29
5220D COD
Analytical Method: SM 5220D-2011 Preparation Method:
SM 5220D-2011
Pace Analytical Services - Asheville
Chemical Oxygen Demand
65.4 mg/L 25.0
1
09/08/21 02:56 09/08/21 06:33
Date: 09/10/2021 03:13 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC-
Page 7 of 26

Pace Analytical Services, LLG
aceAnalytieal g 9800 Kincey Ave, to 100
Huntersville, NCC 28078
www.pacelabs.can [phone]
ANALYTICAL RESULTS
Project: Hari & Hickman Oracle 200
Pace Project No.: 92559188
Sample: OUTFALL SD05 Lab ID: 92569188005 Collected: 09/01/21 17:36 Received: 09/02/21 12:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared
Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
3.8 mglL 3.2
1
09/07/21 16:25
1664 SGT HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg1L 5.0
1
09/08/21 07:53
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
Copper
0.0052 mglL 0.0050
1
09/0812104:57
09/09/21 04:57 7440-50-8
Lead
ND mglL 0.0050
1
09108I2104:57
09/09/21 04:57 7439-92-1
Zinc
0.039 mg1L 0.010
1
09/08/2104:57
09109/2104:57 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
09/01/21 17:36
Collected By
Glenn
1
09/01/21 17:36
Price
PH
7.09 Std. Units
1
09/01/21 17:36
Temperature
28.4 deg C
1
09/01/21 17:36
5220D GOD
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services - Asheville
Chemical Oxygen Demand
70.2 mglL 25.0
1
09/08/21 02:56
09/08/21 06:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 09/10/2021 03:13 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 26

aceAnalytr"cal
www.paealaba.t:oet
QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
QC Batch: 645551 Analysis Method: SM 254OD-2011
QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92559188001, 92559188002, 92559188003, 92559188004, 92559188005
METHOD BLANK: 3386444 Matrix: Water
Associated Lab Samples: 9255918800t, 92559188002, 92559188003, 92559188004, 92559188005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 09/07/21 16:21
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NO 28078
[phone]
LABORATORY CONTROL SAMPLE: 3386445
Spike LCS LIDS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Suspended Solids mg/L 250 228 91 90-110
SAMPLE DUPLICATE: 33,96447
92559063001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg1L ND ND
SAMPLE DUPLICATE: 3386465
92559148001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 110 118 7
Results presented an this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/10/2021 03:13 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 26

aceAnalytica!®
www.pacolobs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
QC Batch: 645591
Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B
Analysis Description: 1664 SGT-HEM, TPH
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92559188001, 92559188002, 92559188003, 92559188004, 92559188005
METHOD BLANK: 3386669
Matrix: Water
Associated Lab Samples: 92559188001, 92559188002, 92559188003, 92559188004, 92559188005
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Petroleum Hydrocarbons
mg1L
ND 5.0 09/08/21 07:53
LABORATORY CONTROL SAMPLE:
3386670
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Total Petroleum Hydrocarbons
mg/L
20 17.0 85 64-132
MATRIX SPIKE SAMPLE:
3386671
92558927001 Spike MS MS % Rec
Parameter
Units
Result Conc. Result % Rec Limits Qualifiers
Total Petroleum Hydrocarbons
mg1L
ND 19.8 8.5 38 64-132 M1
SAMPLE DUPLICATE: 3386672
92558788002 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Petroleum Hydrocarbons
mg/L
NO ND
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/10/2021 03:13 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 26

ac6Analytical
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QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
QC Batch: 645630 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92559188001, 92559188002, 92559188003, 92559188004, 92559188005
METHOD BLANK: 3386872
Matrix: water
Associated Lab Samples:
92559188001, 92559188002, 92559188003, 92559188004, 92559188005
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Copper
mg1L
ND 0.0050
09109/2104:24
Lead
mg1L
ND 0.0050
09109/2104:24
Zinc
mg1L
ND 0.010
09109/2104:24
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
3386873
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Copper
mglL
0.5
0.51 102 85-115
Lead
mglL
0.5
0.50 100 85-115
Zinc
mg1L
0.5
0.50 101 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3386874
3386875
MS
MSD
92559188001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Copper mglL
0.0057 0.5
0.5
0,60
0.50
100
98
70-130 2
Lead mg1L
ND 0.5
0.5
0.49
0.49
98
97
70-130 1
Zinc mg1L
0.040 0.5
0.5
0,54
0.54
100
99
70-130 1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/10/2021 03:13 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 26

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QUALITY CONTROL DATA
Project: ;-cart & Hickman Oracle 200
Pace Project No.: 92559188
QC Batch: 645642 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92559188001, 92559188002, 92559188003, 92559188004, 92559188005
METHOD BLANK: 3386916 Matrix: Water
Associated Lab Samples: 92559188001, 92559188002, 92559188003, 92559188004, 92559188005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mg1L ND 25.0 09/08/21 06:28
Pace Analytical services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3386917
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 750 748 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3386918 3386919
MS MSD
92558129002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua]
Chemical Oxygen Demand mg1L 397 100 100 507 507 110 110 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3386924 3386925
MS MSD
92559172001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg1L 34.4 100 100 135 147 100 112 90-110 8 M1,R1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/10/2021 03:13 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 26

aceAnalytical
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QUALIFIERS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92559188
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC -Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDT -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
POL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(0) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/10/2021 03:13 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 26

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
Hart 8 Hickman Oracle 200
92559188
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92559188001
OUTFALL SD01
SM 2540D-2011
645551
92559188002
OUTFALL SD02
SM 2540D-2011
645551
92569188003
OUTFALL SD03
SM 2540D-2011
645551
92559188004
OUTFALL SD04
SM 2540D-2011
645551
92559188005
OUTFALL S1305
SM 2540D-2011
645551
92559188001
OUTFALL SD01
EPA 1664B
645591
92559188002
OUTFALL SD02
EPA 1664B
645591
92559188003
OUTFALL SDO3
EPA 1664B
645591
92559188004
OUTFALL SD04
EPA1664B
645591
92559188005
OUTFALL SD05
EPA 1664B
645591
92559188001
OUTFALL SDO1
EPA 200.7 Rev 4.4 1994
645630
EPA 200.7 Rev 4.4 1994
645658
92559188002
OUTFALL SD02
EPA 200.7 Rev 4.4 1994
645630
EPA 200.7 Rev 4.4 1994
645658
92559188003
OUTFALL SD03
EPA 200.7 Rev 4.4 1994
645630
EPA 200.7 Rev 4.4 1994
645658
92559188004
OUTFALL SD04
EPA 200.7 Rev 4.4 1994
645630
EPA 200.7 Rev 4.4 1994
645658
92559188005
OUTFALL SD05
EPA 200.7 Rev 4.4 1994
645630
EPA 200.7 Rev 4.4 1994
645658
92559188001
OUTFALL SD01
92559188002
OUTFALL SD02
92659188003
OUTFALL SD03
92559188004
OUTFALL SD04
92559188005
OUTFALL SD05
92559188001
OUTFALL SD01
SM 5220D-2011
645642
SM 5220D-2011
645655
92559188002
OUTFALL SD02
SM 5220D-2011
645642
SM 5220D-2011
645655
92559188003
OUTFALL SD03
SM 5220D-2011
645642
SM 5220D-2011
645655
92559188004
OUTFALL S1304
SM 5220D-2011
645642
SM 5220D-2011
645655
92559188005
OUTFALL SDO5
SM 5220D-2011
645642
SM 5220D-2011
645655
Date: 09/10/2021 0113 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 26

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