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HomeMy WebLinkAboutWQ0013419_Sludge Landfill Monitoring Report July 2021_20211004 (6)#=CL# August 18, 2021 LIMS USE: FR - MIKE CODY LIMS OBJECT ID: 92549145 92549145 Project: Pace Project No.: RE: Mr. Mike Cody Glatfelter Corp. 228 South Main Street Spring Grove, PA 17362 Sludge Landfill July 2021 Dear Mr. Cody: Enclosed are the analytical results for sample(s) received by the laboratory between July 12, 2021 and July 13, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Chris Derouen for lorri.patton@pacelabs.com Project Manager Lorri Patton 1(828)254-7176 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 1 of 106 #=CP# CERTIFICATIONS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 2 of 106 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92549145001 WQ0013419-SWP1 EPA 6010D 18 PASI-ASH1 EPA 1631E 1 PASI-ARDT EPA 8270E 74 PASI-CPKS EPA 8260D 63 PASI-CCL EPA 8260D Mod.3 PASI-CLMB SM 2320B-2011 1 PASI-AECH SM 2540C-2011 1 PASI-AZMC EPA 300.0 Rev 2.1 1993 1 PASI-ACDC SM 4500-Cl-E-2011 1 PASI-AHMH SM 5310B-2011 1 PASI-AMDW 92549145002 WQ0013419-SWP2 EPA 6010D 18 PASI-ASH1 EPA 1631E 1 PASI-ARDT EPA 8270E 74 PASI-CPKS EPA 8260D 63 PASI-CCL EPA 8260D Mod.3 PASI-CLMB SM 2320B-2011 1 PASI-AECH SM 2540C-2011 1 PASI-AZMC EPA 300.0 Rev 2.1 1993 1 PASI-ACDC SM 4500-Cl-E-2011 1 PASI-AHMH SM 5310B-2011 1 PASI-AMDW 92549145003 WQ0013419-Q06V09 EPA 6010D 18 PASI-ACBV, DS EPA 1631E 1 PASI-ARDT EPA 8270E 74 PASI-CPKS EPA 8260D 63 PASI-CPM1 EPA 8260D Mod.3 PASI-CLMB SM 2320B-2011 1 PASI-AECH SM 2540C-2011 1 PASI-AMJP EPA 300.0 Rev 2.1 1993 1 PASI-ACDC SM 4500-Cl-E-2011 1 PASI-AHMH SM 5310B-2011 1 PASI-AMDW 92549145004 WQ0013419-Q06V10 EPA 6010D 18 PASI-ADS EPA 1631E 1 PASI-ARDT EPA 8270E 74 PASI-CPKS EPA 8260D 63 PASI-CPM1 EPA 8260D Mod.3 PASI-CLMB SM 2320B-2011 1 PASI-AECH SM 2540C-2011 1 PASI-AMJP REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 3 of 106 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 300.0 Rev 2.1 1993 1 PASI-ACDC SM 4500-Cl-E-2011 1 PASI-AHMH SM 5310B-2011 1 PASI-AMDW 92549145005 WQ0013419-Q06V11 EPA 6010D 18 PASI-ADS EPA 1631E 1 PASI-ARDT EPA 8270E 74 PASI-CPKS EPA 8260D 63 PASI-CSAS EPA 8260D Mod.3 PASI-CLMB SM 2320B-2011 1 PASI-AECH SM 2540C-2011 1 PASI-AMJP EPA 300.0 Rev 2.1 1993 1 PASI-ACDC SM 4500-Cl-E-2011 1 PASI-AHMH SM 5310B-2011 1 PASI-AMDW 92549145006 WQ0013419-Field Blank EPA 1631E 1 PASI-ARDT 92549145007 Trip Blank EPA 8260D 63 PASI-CSAS EPA 8260D Mod.3 PASI-CLMB PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 4 of 106 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92549145001 WQ0013419-SWP1 Performed by Pace 07/26/21 21:05 Collected By Danielle Schuler 07/26/21 21:05 Collected Date 7/12/21 07/26/21 21:05 Collected Time 12:10 07/26/21 21:05 pH 7.1 Std. Units 07/26/21 21:05 Temperature 20.1 deg C 07/26/21 21:05 Specific Conductance 845 umhos/cm 07/26/21 21:05 Oxygen, Dissolved 7.75 mg/L 07/26/21 21:05 REDOX -143.6 mV 07/26/21 21:05 Turbidity 61.02 NTU 07/26/21 21:05 Odor No odor 07/26/21 21:05 Appearance Rusty color, sediment buildup 07/26/21 21:05 Barium 184 ug/L 07/23/21 05:015.0EPA 6010D Calcium 70500 ug/L 07/23/21 05:01100EPA 6010D Cobalt 18.2 ug/L 07/23/21 05:015.0EPA 6010D Magnesium 37400 ug/L 07/23/21 05:01100EPA 6010D Potassium 6360 ug/L 07/23/21 05:015000EPA 6010D Sodium 28900 ug/L 07/23/21 05:015000EPA 6010D Mercury 0.658 ng/L 07/21/21 17:490.50EPA 1631E Alkalinity, Total as CaCO3 415 mg/L 07/15/21 23:365.0SM 2320B-2011 Total Dissolved Solids 409 mg/L 07/16/21 19:1225.0SM 2540C-2011 Sulfate 0.52J mg/L 07/21/21 06:581.0EPA 300.0 Rev 2.1 1993 Chloride 24.2 mg/L 07/20/21 11:24 M11.0SM 4500-Cl-E-2011 Total Organic Carbon 5.4 mg/L 07/21/21 18:441.0SM 5310B-2011 92549145002 WQ0013419-SWP2 Performed by Pace 07/26/21 21:07 Collected By Danielle Schuler 07/26/21 21:07 Collected Date 7/12/21 07/26/21 21:07 Collected Time 12:30 07/26/21 21:07 pH 7.0 Std. Units 07/26/21 21:07 Temperature 17.1 deg C 07/26/21 21:07 Specific Conductance 241 umhos/cm 07/26/21 21:07 Oxygen, Dissolved 8.95 mg/L 07/26/21 21:07 REDOX -89.9 mV 07/26/21 21:07 Turbidity 5.16 NTU 07/26/21 21:07 Odor No odor 07/26/21 21:07 Appearance Clear 07/26/21 21:07 Barium 85.6 ug/L 07/23/21 05:055.0EPA 6010D Calcium 24500 ug/L 07/23/21 05:05100EPA 6010D Cobalt 11.6 ug/L 07/23/21 05:055.0EPA 6010D Magnesium 5260 ug/L 07/23/21 05:05100EPA 6010D Sodium 9570 ug/L 07/23/21 05:055000EPA 6010D Mercury 0.912 ng/L 07/21/21 17:570.50EPA 1631E Alkalinity, Total as CaCO3 109 mg/L 07/16/21 14:295.0SM 2320B-2011 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 5 of 106 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92549145002 WQ0013419-SWP2 Total Dissolved Solids 121 mg/L 07/16/21 19:1225.0SM 2540C-2011 Sulfate 3.1 mg/L 07/21/21 07:131.0EPA 300.0 Rev 2.1 1993 Chloride 3.8 mg/L 07/20/21 11:271.0SM 4500-Cl-E-2011 92549145003 WQ0013419-Q06V09 Performed by Pace 07/27/21 07:35 Collected By Mark Swann 07/27/21 07:35 Collected Date 7/13/21 07/27/21 07:35 Collected Time 12:50 07/27/21 07:35 pH 6.3 Std. Units 07/27/21 07:35 Temperature 18.0 deg C 07/27/21 07:35 Static Water Level 28.55 feet 07/27/21 07:35 Specific Conductance 1450 umhos/cm 07/27/21 07:35 Oxygen, Dissolved 2.52 mg/L 07/27/21 07:35 REDOX -7.2 mV 07/27/21 07:35 Turbidity 4.84 NTU 07/27/21 07:35 Odor No odor 07/27/21 07:35 Appearance Clear 07/27/21 07:35 Barium 285 ug/L 07/25/21 21:425.0EPA 6010D Calcium 168000 ug/L 07/26/21 08:59500EPA 6010D Cobalt 10.2 ug/L 07/25/21 21:425.0EPA 6010D Magnesium 80300 ug/L 07/25/21 21:42100EPA 6010D Nickel 14.2 ug/L 07/25/21 21:425.0EPA 6010D Potassium 4760J ug/L 07/25/21 21:425000EPA 6010D Sodium 31100 ug/L 07/25/21 21:425000EPA 6010D Mercury 0.572 ng/L 07/21/21 18:050.50EPA 1631E Alkalinity, Total as CaCO3 829 mg/L 07/16/21 16:115.0SM 2320B-2011 Total Dissolved Solids 824 mg/L 07/17/21 13:1650.0SM 2540C-2011 Sulfate 3.5 mg/L 07/22/21 01:521.0EPA 300.0 Rev 2.1 1993 Chloride 48.1 mg/L 07/20/21 11:383.0SM 4500-Cl-E-2011 Total Organic Carbon 4.2 mg/L 07/21/21 19:211.0SM 5310B-2011 92549145004 WQ0013419-Q06V10 Performed by Pace 07/27/21 07:36 Collected By Mark Swann 07/27/21 07:36 Collected Date 7/13/21 07/27/21 07:36 Collected Time 11:50 07/27/21 07:36 pH 6.0 Std. Units 07/27/21 07:36 Temperature 15.3 deg C 07/27/21 07:36 Static Water Level 27.97 feet 07/27/21 07:36 Specific Conductance 29 umhos/cm 07/27/21 07:36 Oxygen, Dissolved 4.85 mg/L 07/27/21 07:36 REDOX 102.6 mV 07/27/21 07:36 Turbidity 6.85 NTU 07/27/21 07:36 Odor No odor 07/27/21 07:36 Appearance Clear 07/27/21 07:36 Barium 4.7J ug/L 07/25/21 21:455.0EPA 6010D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 6 of 106 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92549145004 WQ0013419-Q06V10 Calcium 1980 ug/L 07/25/21 21:45100EPA 6010D Magnesium 718 ug/L 07/25/21 21:45100EPA 6010D Sodium 1670J ug/L 07/25/21 21:455000EPA 6010D Mercury 4.61J ng/L 07/21/21 18:125.0EPA 1631E Alkalinity, Total as CaCO3 8.3 mg/L 07/16/21 16:215.0SM 2320B-2011 Sulfate 0.77J mg/L 07/22/21 02:071.0EPA 300.0 Rev 2.1 1993 Chloride 3.0 mg/L 07/20/21 11:401.0SM 4500-Cl-E-2011 92549145005 WQ0013419-Q06V11 Performed by Pace 07/27/21 07:38 Collected By Mark Swann 07/27/21 07:38 Collected Date 7/13/21 07/27/21 07:38 Collected Time 12:20 07/27/21 07:38 pH 5.8 Std. Units 07/27/21 07:38 Temperature 15.3 deg C 07/27/21 07:38 Static Water Level 30.43 feet 07/27/21 07:38 Specific Conductance 66 umhos/cm 07/27/21 07:38 Oxygen, Dissolved 6.64 mg/L 07/27/21 07:38 REDOX 93.2 mV 07/27/21 07:38 Turbidity 8.75 NTU 07/27/21 07:38 Odor No odor 07/27/21 07:38 Appearance Clear 07/27/21 07:38 Barium 5.7 ug/L 07/25/21 21:485.0EPA 6010D Calcium 4620 ug/L 07/25/21 21:48100EPA 6010D Magnesium 2140 ug/L 07/25/21 21:48100EPA 6010D Sodium 4000J ug/L 07/25/21 21:485000EPA 6010D Mercury 1.52 ng/L 07/21/21 18:200.50EPA 1631E Alkalinity, Total as CaCO3 24.5 mg/L 07/16/21 16:375.0SM 2320B-2011 Total Dissolved Solids 40.0 mg/L 07/17/21 13:1625.0SM 2540C-2011 Sulfate 3.5 mg/L 07/22/21 02:231.0EPA 300.0 Rev 2.1 1993 Chloride 1.6 mg/L 07/20/21 11:411.0SM 4500-Cl-E-2011 92549145006 WQ0013419-Field Blank Mercury 0.334J ng/L 07/26/21 12:000.50EPA 1631E REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 7 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP1 Lab ID:92549145001 Collected:07/12/21 12:10 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: Pace Analytical Services - Charlotte Monitoring Well Data Performed by Pace 07/26/21 21:051 Collected By Danielle Schuler 07/26/21 21:051 Collected Date 7/12/21 07/26/21 21:051 Collected Time 12:10 07/26/21 21:051 pH 7.1 Std. Units 07/26/21 21:051 Temperature 20.1 deg C 07/26/21 21:051 Specific Conductance 845 umhos/cm 07/26/21 21:051 Oxygen, Dissolved 7.75 mg/L 07/26/21 21:05 7782-44-71 REDOX -143.6 mV 07/26/21 21:051 Turbidity 61.02 NTU 07/26/21 21:051 Odor No odor 07/26/21 21:051 Appearance Rusty color, sediment buildup 07/26/21 21:051 Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services - Asheville 6010 MET ICP Antimony ND ug/L 07/23/21 05:01 7440-36-007/22/21 17:295.0 1 Arsenic ND ug/L 07/23/21 05:01 7440-38-207/22/21 17:2910.0 1 Barium 184 ug/L 07/23/21 05:01 7440-39-307/22/21 17:295.0 1 Cadmium ND ug/L 07/23/21 05:01 7440-43-907/22/21 17:291.0 1 Calcium 70500 ug/L 07/23/21 05:01 7440-70-207/22/21 17:291001 Chromium ND ug/L 07/23/21 05:01 7440-47-307/22/21 17:295.0 1 Cobalt 18.2 ug/L 07/23/21 05:01 7440-48-407/22/21 17:295.0 1 Copper ND ug/L 07/23/21 05:01 7440-50-807/22/21 17:295.0 1 Lead ND ug/L 07/23/21 05:01 7439-92-107/22/21 17:295.0 1 Magnesium 37400 ug/L 07/23/21 05:01 7439-95-407/22/21 17:291001 Nickel ND ug/L 07/23/21 05:01 7440-02-007/22/21 17:295.0 1 Potassium 6360 ug/L 07/23/21 05:01 7440-09-707/22/21 17:2950001 Selenium ND ug/L 07/23/21 05:01 7782-49-207/22/21 17:2910.0 1 Silver ND ug/L 07/23/21 05:01 7440-22-407/22/21 17:295.0 1 Sodium 28900 ug/L 07/23/21 05:01 7440-23-507/22/21 17:2950001 Thallium ND ug/L 07/23/21 05:01 7440-28-007/22/21 17:2910.0 1 Vanadium ND ug/L 07/23/21 05:01 7440-62-207/22/21 17:295.0 1 Zinc ND ug/L 07/23/21 05:01 7440-66-607/22/21 17:2910.0 1 Analytical Method: EPA 1631E Preparation Method: EPA 1631E Pace Analytical Services - Asheville 1631E Mercury,Low Level Mercury 0.658 ng/L 07/21/21 17:49 7439-97-607/17/21 15:080.50 1 Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 07/19/21 19:59 83-32-907/19/21 08:0010.0 1 Acenaphthylene ND ug/L 07/19/21 19:59 208-96-807/19/21 08:0010.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 8 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP1 Lab ID:92549145001 Collected:07/12/21 12:10 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Aniline ND ug/L 07/19/21 19:59 62-53-307/19/21 08:0010.0 1 Anthracene ND ug/L 07/19/21 19:59 120-12-707/19/21 08:0010.0 1 Benzo(a)anthracene ND ug/L 07/19/21 19:59 56-55-307/19/21 08:0010.0 1 Benzo(a)pyrene ND ug/L 07/19/21 19:59 50-32-807/19/21 08:0010.0 1 Benzo(b)fluoranthene ND ug/L 07/19/21 19:59 205-99-207/19/21 08:0010.0 1 Benzo(g,h,i)perylene ND ug/L 07/19/21 19:59 191-24-207/19/21 08:0010.0 1 Benzo(k)fluoranthene ND ug/L 07/19/21 19:59 207-08-907/19/21 08:0010.0 1 Benzoic Acid ND ug/L 07/19/21 19:59 65-85-0 M107/19/21 08:0050.0 1 Benzyl alcohol ND ug/L 07/19/21 19:59 100-51-607/19/21 08:0020.0 1 4-Bromophenylphenyl ether ND ug/L 07/19/21 19:59 101-55-307/19/21 08:0010.0 1 Butylbenzylphthalate ND ug/L 07/19/21 19:59 85-68-707/19/21 08:0010.0 1 4-Chloro-3-methylphenol ND ug/L 07/19/21 19:59 59-50-707/19/21 08:0010.0 1 4-Chloroaniline ND ug/L 07/19/21 19:59 106-47-807/19/21 08:0020.0 1 bis(2-Chloroethoxy)methane ND ug/L 07/19/21 19:59 111-91-107/19/21 08:0010.0 1 bis(2-Chloroethyl) ether ND ug/L 07/19/21 19:59 111-44-407/19/21 08:0010.0 1 2-Chloronaphthalene ND ug/L 07/19/21 19:59 91-58-707/19/21 08:0010.0 1 2-Chlorophenol ND ug/L 07/19/21 19:59 95-57-807/19/21 08:0010.0 1 4-Chlorophenylphenyl ether ND ug/L 07/19/21 19:59 7005-72-307/19/21 08:0010.0 1 Chrysene ND ug/L 07/19/21 19:59 218-01-907/19/21 08:0010.0 1 Dibenz(a,h)anthracene ND ug/L 07/19/21 19:59 53-70-307/19/21 08:0010.0 1 Dibenzofuran ND ug/L 07/19/21 19:59 132-64-907/19/21 08:0010.0 1 1,2-Dichlorobenzene ND ug/L 07/19/21 19:59 95-50-107/19/21 08:0010.0 1 1,3-Dichlorobenzene ND ug/L 07/19/21 19:59 541-73-107/19/21 08:0010.0 1 1,4-Dichlorobenzene ND ug/L 07/19/21 19:59 106-46-707/19/21 08:0010.0 1 3,3'-Dichlorobenzidine ND ug/L 07/19/21 19:59 91-94-107/19/21 08:0020.0 1 2,4-Dichlorophenol ND ug/L 07/19/21 19:59 120-83-207/19/21 08:0010.0 1 Diethylphthalate ND ug/L 07/19/21 19:59 84-66-207/19/21 08:0010.0 1 2,4-Dimethylphenol ND ug/L 07/19/21 19:59 105-67-907/19/21 08:0010.0 1 Dimethylphthalate ND ug/L 07/19/21 19:59 131-11-307/19/21 08:0010.0 1 Di-n-butylphthalate ND ug/L 07/19/21 19:59 84-74-207/19/21 08:0010.0 1 4,6-Dinitro-2-methylphenol ND ug/L 07/19/21 19:59 534-52-1 M107/19/21 08:0020.0 1 2,4-Dinitrophenol ND ug/L 07/19/21 19:59 51-28-5 M107/19/21 08:0050.0 1 2,4-Dinitrotoluene ND ug/L 07/19/21 19:59 121-14-207/19/21 08:0010.0 1 2,6-Dinitrotoluene ND ug/L 07/19/21 19:59 606-20-207/19/21 08:0010.0 1 Di-n-octylphthalate ND ug/L 07/19/21 19:59 117-84-007/19/21 08:0010.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 07/19/21 19:59 117-81-707/19/21 08:006.0 1 Fluoranthene ND ug/L 07/19/21 19:59 206-44-007/19/21 08:0010.0 1 Fluorene ND ug/L 07/19/21 19:59 86-73-707/19/21 08:0010.0 1 Hexachloro-1,3-butadiene ND ug/L 07/19/21 19:59 87-68-307/19/21 08:0010.0 1 Hexachlorobenzene ND ug/L 07/19/21 19:59 118-74-107/19/21 08:0010.0 1 Hexachlorocyclopentadiene ND ug/L 07/19/21 19:59 77-47-407/19/21 08:0010.0 1 Hexachloroethane ND ug/L 07/19/21 19:59 67-72-107/19/21 08:0010.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/19/21 19:59 193-39-507/19/21 08:0010.0 1 Isophorone ND ug/L 07/19/21 19:59 78-59-107/19/21 08:0010.0 1 1-Methylnaphthalene ND ug/L 07/19/21 19:59 90-12-007/19/21 08:0010.0 1 2-Methylnaphthalene ND ug/L 07/19/21 19:59 91-57-607/19/21 08:0010.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 9 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP1 Lab ID:92549145001 Collected:07/12/21 12:10 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE 2-Methylphenol(o-Cresol)ND ug/L 07/19/21 19:59 95-48-707/19/21 08:0010.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 07/19/21 19:59 15831-10-407/19/21 08:0010.0 1 Naphthalene ND ug/L 07/19/21 19:59 91-20-307/19/21 08:0010.0 1 2-Nitroaniline ND ug/L 07/19/21 19:59 88-74-407/19/21 08:0020.0 1 3-Nitroaniline ND ug/L 07/19/21 19:59 99-09-207/19/21 08:0020.0 1 4-Nitroaniline ND ug/L 07/19/21 19:59 100-01-607/19/21 08:0020.0 1 Nitrobenzene ND ug/L 07/19/21 19:59 98-95-307/19/21 08:0010.0 1 2-Nitrophenol ND ug/L 07/19/21 19:59 88-75-507/19/21 08:0010.0 1 4-Nitrophenol ND ug/L 07/19/21 19:59 100-02-7 M107/19/21 08:0050.0 1 N-Nitrosodimethylamine ND ug/L 07/19/21 19:59 62-75-9 v107/19/21 08:0010.0 1 N-Nitroso-di-n-propylamine ND ug/L 07/19/21 19:59 621-64-707/19/21 08:0010.0 1 N-Nitrosodiphenylamine ND ug/L 07/19/21 19:59 86-30-607/19/21 08:0010.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 07/19/21 19:59 108-60-107/19/21 08:0010.0 1 Pentachlorophenol ND ug/L 07/19/21 19:59 87-86-5 M107/19/21 08:0020.0 1 Phenanthrene ND ug/L 07/19/21 19:59 85-01-807/19/21 08:0010.0 1 Phenol ND ug/L 07/19/21 19:59 108-95-207/19/21 08:0010.0 1 Pyrene ND ug/L 07/19/21 19:59 129-00-007/19/21 08:0010.0 1 1,2,4-Trichlorobenzene ND ug/L 07/19/21 19:59 120-82-107/19/21 08:0010.0 1 2,4,5-Trichlorophenol ND ug/L 07/19/21 19:59 95-95-407/19/21 08:0010.0 1 2,4,6-Trichlorophenol ND ug/L 07/19/21 19:59 88-06-207/19/21 08:0010.0 1 Surrogates Nitrobenzene-d5 (S)86 %07/19/21 19:59 4165-60-007/19/21 08:0010-144 1 2-Fluorobiphenyl (S)73 %07/19/21 19:59 321-60-807/19/21 08:0010-130 1 Terphenyl-d14 (S)105 %07/19/21 19:59 1718-51-007/19/21 08:0034-163 1 Phenol-d6 (S)40 %07/19/21 19:59 13127-88-307/19/21 08:0010-130 1 2-Fluorophenol (S)38 %07/19/21 19:59 367-12-407/19/21 08:0010-130 1 2,4,6-Tribromophenol (S)48 %07/19/21 19:59 118-79-607/19/21 08:0010-144 1 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Acetone ND ug/L 07/14/21 20:46 67-64-125.0 1 Benzene ND ug/L 07/14/21 20:46 71-43-21.0 1 Bromobenzene ND ug/L 07/14/21 20:46 108-86-11.0 1 Bromochloromethane ND ug/L 07/14/21 20:46 74-97-51.0 1 Bromodichloromethane ND ug/L 07/14/21 20:46 75-27-41.0 1 Bromoform ND ug/L 07/14/21 20:46 75-25-21.0 1 Bromomethane ND ug/L 07/14/21 20:46 74-83-92.0 1 2-Butanone (MEK)ND ug/L 07/14/21 20:46 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/14/21 20:46 56-23-51.0 1 Chlorobenzene ND ug/L 07/14/21 20:46 108-90-71.0 1 Chloroethane ND ug/L 07/14/21 20:46 75-00-31.0 1 Chloroform ND ug/L 07/14/21 20:46 67-66-31.0 1 Chloromethane ND ug/L 07/14/21 20:46 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/14/21 20:46 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/14/21 20:46 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/14/21 20:46 96-12-82.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 10 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP1 Lab ID:92549145001 Collected:07/12/21 12:10 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Dibromochloromethane ND ug/L 07/14/21 20:46 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/14/21 20:46 106-93-41.0 1 Dibromomethane ND ug/L 07/14/21 20:46 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/14/21 20:46 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/14/21 20:46 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/14/21 20:46 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/14/21 20:46 75-71-81.0 1 1,1-Dichloroethane ND ug/L 07/14/21 20:46 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/14/21 20:46 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/14/21 20:46 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/14/21 20:46 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/14/21 20:46 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/14/21 20:46 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/14/21 20:46 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/14/21 20:46 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/14/21 20:46 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/14/21 20:46 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/14/21 20:46 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/14/21 20:46 108-20-31.0 1 Ethylbenzene ND ug/L 07/14/21 20:46 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/14/21 20:46 87-68-32.0 1 2-Hexanone ND ug/L 07/14/21 20:46 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/14/21 20:46 99-87-61.0 1 Methylene Chloride ND ug/L 07/14/21 20:46 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/14/21 20:46 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/14/21 20:46 1634-04-41.0 1 Naphthalene ND ug/L 07/14/21 20:46 91-20-31.0 1 Styrene ND ug/L 07/14/21 20:46 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/14/21 20:46 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/14/21 20:46 79-34-51.0 1 Tetrachloroethene ND ug/L 07/14/21 20:46 127-18-41.0 1 Toluene ND ug/L 07/14/21 20:46 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/14/21 20:46 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/14/21 20:46 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/14/21 20:46 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/14/21 20:46 79-00-51.0 1 Trichloroethene ND ug/L 07/14/21 20:46 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/14/21 20:46 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/14/21 20:46 96-18-41.0 1 Vinyl acetate ND ug/L 07/14/21 20:46 108-05-42.0 1 Vinyl chloride ND ug/L 07/14/21 20:46 75-01-41.0 1 Xylene (Total)ND ug/L 07/14/21 20:46 1330-20-71.0 1 m&p-Xylene ND ug/L 07/14/21 20:46 179601-23-12.0 1 o-Xylene ND ug/L 07/14/21 20:46 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)101 %07/14/21 20:46 460-00-470-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 11 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP1 Lab ID:92549145001 Collected:07/12/21 12:10 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Surrogates 1,2-Dichloroethane-d4 (S)105 %07/14/21 20:46 17060-07-070-130 1 Toluene-d8 (S)104 %07/14/21 20:46 2037-26-570-130 1 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 8260D MSV SIM 1,4-Dioxane (p-Dioxane)ND ug/L 07/14/21 17:08 123-91-12.0 1 Surrogates 1,2-Dichloroethane-d4 (S)99 %07/14/21 17:08 17060-07-070-130 1 Toluene-d8 (S)100 %07/14/21 17:08 2037-26-566-133 1 Analytical Method: SM 2320B-2011 Pace Analytical Services - Asheville 2320B Alkalinity Alkalinity, Total as CaCO3 415 mg/L 07/15/21 23:365.0 1 Analytical Method: SM 2540C-2011 Pace Analytical Services - Asheville 2540C Total Dissolved Solids Total Dissolved Solids 409 mg/L 07/16/21 19:1225.0 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville 300.0 IC Anions 28 Days Sulfate 0.52J mg/L 07/21/21 06:58 14808-79-81.0 1 Analytical Method: SM 4500-Cl-E-2011 Pace Analytical Services - Asheville 4500 Chloride Chloride 24.2 mg/L 07/20/21 11:24 16887-00-6 M11.0 1 Analytical Method: SM 5310B-2011 Pace Analytical Services - Asheville 5310B TOC Total Organic Carbon 5.4 mg/L 07/21/21 18:44 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 12 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP2 Lab ID:92549145002 Collected:07/12/21 10:30 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: Pace Analytical Services - Charlotte Monitoring Well Data Performed by Pace 07/26/21 21:071 Collected By Danielle Schuler 07/26/21 21:071 Collected Date 7/12/21 07/26/21 21:071 Collected Time 12:30 07/26/21 21:071 pH 7.0 Std. Units 07/26/21 21:071 Temperature 17.1 deg C 07/26/21 21:071 Specific Conductance 241 umhos/cm 07/26/21 21:071 Oxygen, Dissolved 8.95 mg/L 07/26/21 21:07 7782-44-71 REDOX -89.9 mV 07/26/21 21:071 Turbidity 5.16 NTU 07/26/21 21:071 Odor No odor 07/26/21 21:071 Appearance Clear 07/26/21 21:071 Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services - Asheville 6010 MET ICP Antimony ND ug/L 07/23/21 05:05 7440-36-007/22/21 17:295.0 1 Arsenic ND ug/L 07/23/21 05:05 7440-38-207/22/21 17:2910.0 1 Barium 85.6 ug/L 07/23/21 05:05 7440-39-307/22/21 17:295.0 1 Cadmium ND ug/L 07/23/21 05:05 7440-43-907/22/21 17:291.0 1 Calcium 24500 ug/L 07/23/21 05:05 7440-70-207/22/21 17:291001 Chromium ND ug/L 07/23/21 05:05 7440-47-307/22/21 17:295.0 1 Cobalt 11.6 ug/L 07/23/21 05:05 7440-48-407/22/21 17:295.0 1 Copper ND ug/L 07/23/21 05:05 7440-50-807/22/21 17:295.0 1 Lead ND ug/L 07/23/21 05:05 7439-92-107/22/21 17:295.0 1 Magnesium 5260 ug/L 07/23/21 05:05 7439-95-407/22/21 17:291001 Nickel ND ug/L 07/23/21 05:05 7440-02-007/22/21 17:295.0 1 Potassium ND ug/L 07/23/21 05:05 7440-09-707/22/21 17:2950001 Selenium ND ug/L 07/23/21 05:05 7782-49-207/22/21 17:2910.0 1 Silver ND ug/L 07/23/21 05:05 7440-22-407/22/21 17:295.0 1 Sodium 9570 ug/L 07/23/21 05:05 7440-23-507/22/21 17:2950001 Thallium ND ug/L 07/23/21 05:05 7440-28-007/22/21 17:2910.0 1 Vanadium ND ug/L 07/23/21 05:05 7440-62-207/22/21 17:295.0 1 Zinc ND ug/L 07/23/21 05:05 7440-66-607/22/21 17:2910.0 1 Analytical Method: EPA 1631E Preparation Method: EPA 1631E Pace Analytical Services - Asheville 1631E Mercury,Low Level Mercury 0.912 ng/L 07/21/21 17:57 7439-97-607/17/21 15:080.50 1 Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 07/19/21 21:39 83-32-907/19/21 08:0010.0 1 Acenaphthylene ND ug/L 07/19/21 21:39 208-96-807/19/21 08:0010.0 1 Aniline ND ug/L 07/19/21 21:39 62-53-307/19/21 08:0010.0 1 Anthracene ND ug/L 07/19/21 21:39 120-12-707/19/21 08:0010.0 1 Benzo(a)anthracene ND ug/L 07/19/21 21:39 56-55-307/19/21 08:0010.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 13 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP2 Lab ID:92549145002 Collected:07/12/21 10:30 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Benzo(a)pyrene ND ug/L 07/19/21 21:39 50-32-807/19/21 08:0010.0 1 Benzo(b)fluoranthene ND ug/L 07/19/21 21:39 205-99-207/19/21 08:0010.0 1 Benzo(g,h,i)perylene ND ug/L 07/19/21 21:39 191-24-207/19/21 08:0010.0 1 Benzo(k)fluoranthene ND ug/L 07/19/21 21:39 207-08-907/19/21 08:0010.0 1 Benzoic Acid ND ug/L 07/19/21 21:39 65-85-0 v107/19/21 08:0050.0 1 Benzyl alcohol ND ug/L 07/19/21 21:39 100-51-607/19/21 08:0020.0 1 4-Bromophenylphenyl ether ND ug/L 07/19/21 21:39 101-55-307/19/21 08:0010.0 1 Butylbenzylphthalate ND ug/L 07/19/21 21:39 85-68-707/19/21 08:0010.0 1 4-Chloro-3-methylphenol ND ug/L 07/19/21 21:39 59-50-707/19/21 08:0010.0 1 4-Chloroaniline ND ug/L 07/19/21 21:39 106-47-807/19/21 08:0020.0 1 bis(2-Chloroethoxy)methane ND ug/L 07/19/21 21:39 111-91-107/19/21 08:0010.0 1 bis(2-Chloroethyl) ether ND ug/L 07/19/21 21:39 111-44-407/19/21 08:0010.0 1 2-Chloronaphthalene ND ug/L 07/19/21 21:39 91-58-707/19/21 08:0010.0 1 2-Chlorophenol ND ug/L 07/19/21 21:39 95-57-807/19/21 08:0010.0 1 4-Chlorophenylphenyl ether ND ug/L 07/19/21 21:39 7005-72-307/19/21 08:0010.0 1 Chrysene ND ug/L 07/19/21 21:39 218-01-907/19/21 08:0010.0 1 Dibenz(a,h)anthracene ND ug/L 07/19/21 21:39 53-70-307/19/21 08:0010.0 1 Dibenzofuran ND ug/L 07/19/21 21:39 132-64-907/19/21 08:0010.0 1 1,2-Dichlorobenzene ND ug/L 07/19/21 21:39 95-50-107/19/21 08:0010.0 1 1,3-Dichlorobenzene ND ug/L 07/19/21 21:39 541-73-107/19/21 08:0010.0 1 1,4-Dichlorobenzene ND ug/L 07/19/21 21:39 106-46-707/19/21 08:0010.0 1 3,3'-Dichlorobenzidine ND ug/L 07/19/21 21:39 91-94-107/19/21 08:0020.0 1 2,4-Dichlorophenol ND ug/L 07/19/21 21:39 120-83-207/19/21 08:0010.0 1 Diethylphthalate ND ug/L 07/19/21 21:39 84-66-207/19/21 08:0010.0 1 2,4-Dimethylphenol ND ug/L 07/19/21 21:39 105-67-907/19/21 08:0010.0 1 Dimethylphthalate ND ug/L 07/19/21 21:39 131-11-307/19/21 08:0010.0 1 Di-n-butylphthalate ND ug/L 07/19/21 21:39 84-74-207/19/21 08:0010.0 1 4,6-Dinitro-2-methylphenol ND ug/L 07/19/21 21:39 534-52-1 v107/19/21 08:0020.0 1 2,4-Dinitrophenol ND ug/L 07/19/21 21:39 51-28-5 v107/19/21 08:0050.0 1 2,4-Dinitrotoluene ND ug/L 07/19/21 21:39 121-14-207/19/21 08:0010.0 1 2,6-Dinitrotoluene ND ug/L 07/19/21 21:39 606-20-2 v107/19/21 08:0010.0 1 Di-n-octylphthalate ND ug/L 07/19/21 21:39 117-84-007/19/21 08:0010.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 07/19/21 21:39 117-81-707/19/21 08:006.0 1 Fluoranthene ND ug/L 07/19/21 21:39 206-44-007/19/21 08:0010.0 1 Fluorene ND ug/L 07/19/21 21:39 86-73-707/19/21 08:0010.0 1 Hexachloro-1,3-butadiene ND ug/L 07/19/21 21:39 87-68-307/19/21 08:0010.0 1 Hexachlorobenzene ND ug/L 07/19/21 21:39 118-74-107/19/21 08:0010.0 1 Hexachlorocyclopentadiene ND ug/L 07/19/21 21:39 77-47-407/19/21 08:0010.0 1 Hexachloroethane ND ug/L 07/19/21 21:39 67-72-107/19/21 08:0010.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/19/21 21:39 193-39-507/19/21 08:0010.0 1 Isophorone ND ug/L 07/19/21 21:39 78-59-107/19/21 08:0010.0 1 1-Methylnaphthalene ND ug/L 07/19/21 21:39 90-12-007/19/21 08:0010.0 1 2-Methylnaphthalene ND ug/L 07/19/21 21:39 91-57-607/19/21 08:0010.0 1 2-Methylphenol(o-Cresol)ND ug/L 07/19/21 21:39 95-48-707/19/21 08:0010.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 07/19/21 21:39 15831-10-407/19/21 08:0010.0 1 Naphthalene ND ug/L 07/19/21 21:39 91-20-307/19/21 08:0010.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 14 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP2 Lab ID:92549145002 Collected:07/12/21 10:30 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE 2-Nitroaniline ND ug/L 07/19/21 21:39 88-74-407/19/21 08:0020.0 1 3-Nitroaniline ND ug/L 07/19/21 21:39 99-09-2 v107/19/21 08:0020.0 1 4-Nitroaniline ND ug/L 07/19/21 21:39 100-01-607/19/21 08:0020.0 1 Nitrobenzene ND ug/L 07/19/21 21:39 98-95-307/19/21 08:0010.0 1 2-Nitrophenol ND ug/L 07/19/21 21:39 88-75-5 v107/19/21 08:0010.0 1 4-Nitrophenol ND ug/L 07/19/21 21:39 100-02-707/19/21 08:0050.0 1 N-Nitrosodimethylamine ND ug/L 07/19/21 21:39 62-75-907/19/21 08:0010.0 1 N-Nitroso-di-n-propylamine ND ug/L 07/19/21 21:39 621-64-707/19/21 08:0010.0 1 N-Nitrosodiphenylamine ND ug/L 07/19/21 21:39 86-30-607/19/21 08:0010.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 07/19/21 21:39 108-60-107/19/21 08:0010.0 1 Pentachlorophenol ND ug/L 07/19/21 21:39 87-86-507/19/21 08:0020.0 1 Phenanthrene ND ug/L 07/19/21 21:39 85-01-807/19/21 08:0010.0 1 Phenol ND ug/L 07/19/21 21:39 108-95-207/19/21 08:0010.0 1 Pyrene ND ug/L 07/19/21 21:39 129-00-007/19/21 08:0010.0 1 1,2,4-Trichlorobenzene ND ug/L 07/19/21 21:39 120-82-107/19/21 08:0010.0 1 2,4,5-Trichlorophenol ND ug/L 07/19/21 21:39 95-95-407/19/21 08:0010.0 1 2,4,6-Trichlorophenol ND ug/L 07/19/21 21:39 88-06-207/19/21 08:0010.0 1 Surrogates Nitrobenzene-d5 (S)79 %07/19/21 21:39 4165-60-007/19/21 08:0010-144 1 2-Fluorobiphenyl (S)67 %07/19/21 21:39 321-60-807/19/21 08:0010-130 1 Terphenyl-d14 (S)101 %07/19/21 21:39 1718-51-007/19/21 08:0034-163 1 Phenol-d6 (S)33 %07/19/21 21:39 13127-88-307/19/21 08:0010-130 1 2-Fluorophenol (S)51 %07/19/21 21:39 367-12-407/19/21 08:0010-130 1 2,4,6-Tribromophenol (S)78 %07/19/21 21:39 118-79-607/19/21 08:0010-144 1 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Acetone ND ug/L 07/14/21 21:04 67-64-125.0 1 Benzene ND ug/L 07/14/21 21:04 71-43-21.0 1 Bromobenzene ND ug/L 07/14/21 21:04 108-86-11.0 1 Bromochloromethane ND ug/L 07/14/21 21:04 74-97-51.0 1 Bromodichloromethane ND ug/L 07/14/21 21:04 75-27-41.0 1 Bromoform ND ug/L 07/14/21 21:04 75-25-21.0 1 Bromomethane ND ug/L 07/14/21 21:04 74-83-92.0 1 2-Butanone (MEK)ND ug/L 07/14/21 21:04 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/14/21 21:04 56-23-51.0 1 Chlorobenzene ND ug/L 07/14/21 21:04 108-90-71.0 1 Chloroethane ND ug/L 07/14/21 21:04 75-00-31.0 1 Chloroform ND ug/L 07/14/21 21:04 67-66-31.0 1 Chloromethane ND ug/L 07/14/21 21:04 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/14/21 21:04 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/14/21 21:04 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/14/21 21:04 96-12-82.0 1 Dibromochloromethane ND ug/L 07/14/21 21:04 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/14/21 21:04 106-93-41.0 1 Dibromomethane ND ug/L 07/14/21 21:04 74-95-31.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 15 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP2 Lab ID:92549145002 Collected:07/12/21 10:30 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill 1,2-Dichlorobenzene ND ug/L 07/14/21 21:04 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/14/21 21:04 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/14/21 21:04 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/14/21 21:04 75-71-81.0 1 1,1-Dichloroethane ND ug/L 07/14/21 21:04 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/14/21 21:04 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/14/21 21:04 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/14/21 21:04 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/14/21 21:04 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/14/21 21:04 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/14/21 21:04 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/14/21 21:04 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/14/21 21:04 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/14/21 21:04 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/14/21 21:04 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/14/21 21:04 108-20-31.0 1 Ethylbenzene ND ug/L 07/14/21 21:04 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/14/21 21:04 87-68-32.0 1 2-Hexanone ND ug/L 07/14/21 21:04 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/14/21 21:04 99-87-61.0 1 Methylene Chloride ND ug/L 07/14/21 21:04 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/14/21 21:04 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/14/21 21:04 1634-04-41.0 1 Naphthalene ND ug/L 07/14/21 21:04 91-20-31.0 1 Styrene ND ug/L 07/14/21 21:04 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/14/21 21:04 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/14/21 21:04 79-34-51.0 1 Tetrachloroethene ND ug/L 07/14/21 21:04 127-18-41.0 1 Toluene ND ug/L 07/14/21 21:04 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/14/21 21:04 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/14/21 21:04 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/14/21 21:04 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/14/21 21:04 79-00-51.0 1 Trichloroethene ND ug/L 07/14/21 21:04 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/14/21 21:04 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/14/21 21:04 96-18-41.0 1 Vinyl acetate ND ug/L 07/14/21 21:04 108-05-42.0 1 Vinyl chloride ND ug/L 07/14/21 21:04 75-01-41.0 1 Xylene (Total)ND ug/L 07/14/21 21:04 1330-20-71.0 1 m&p-Xylene ND ug/L 07/14/21 21:04 179601-23-12.0 1 o-Xylene ND ug/L 07/14/21 21:04 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %07/14/21 21:04 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %07/14/21 21:04 17060-07-070-130 1 Toluene-d8 (S)101 %07/14/21 21:04 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 16 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-SWP2 Lab ID:92549145002 Collected:07/12/21 10:30 Received:07/12/21 18:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 8260D MSV SIM 1,4-Dioxane (p-Dioxane)ND ug/L 07/14/21 17:27 123-91-12.0 1 Surrogates 1,2-Dichloroethane-d4 (S)97 %07/14/21 17:27 17060-07-070-130 1 Toluene-d8 (S)100 %07/14/21 17:27 2037-26-566-133 1 Analytical Method: SM 2320B-2011 Pace Analytical Services - Asheville 2320B Alkalinity Alkalinity, Total as CaCO3 109 mg/L 07/16/21 14:295.0 1 Analytical Method: SM 2540C-2011 Pace Analytical Services - Asheville 2540C Total Dissolved Solids Total Dissolved Solids 121 mg/L 07/16/21 19:1225.0 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville 300.0 IC Anions 28 Days Sulfate 3.1 mg/L 07/21/21 07:13 14808-79-81.0 1 Analytical Method: SM 4500-Cl-E-2011 Pace Analytical Services - Asheville 4500 Chloride Chloride 3.8 mg/L 07/20/21 11:27 16887-00-61.0 1 Analytical Method: SM 5310B-2011 Pace Analytical Services - Asheville 5310B TOC Total Organic Carbon ND mg/L 07/21/21 19:02 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 17 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V09 Lab ID:92549145003 Collected:07/13/21 12:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: Pace Analytical Services - Charlotte Monitoring Well Data Performed by Pace 07/27/21 07:351 Collected By Mark Swann 07/27/21 07:351 Collected Date 7/13/21 07/27/21 07:351 Collected Time 12:50 07/27/21 07:351 pH 6.3 Std. Units 07/27/21 07:351 Temperature 18.0 deg C 07/27/21 07:351 Static Water Level 28.55 feet 07/27/21 07:351 Specific Conductance 1450 umhos/cm 07/27/21 07:351 Oxygen, Dissolved 2.52 mg/L 07/27/21 07:35 7782-44-71 REDOX -7.2 mV 07/27/21 07:351 Turbidity 4.84 NTU 07/27/21 07:351 Odor No odor 07/27/21 07:351 Appearance Clear 07/27/21 07:351 Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services - Asheville 6010 MET ICP Antimony ND ug/L 07/25/21 21:42 7440-36-007/24/21 01:025.0 1 Arsenic ND ug/L 07/25/21 21:42 7440-38-207/24/21 01:0210.0 1 Barium 285 ug/L 07/25/21 21:42 7440-39-307/24/21 01:025.0 1 Cadmium ND ug/L 07/25/21 21:42 7440-43-907/24/21 01:021.0 1 Calcium 168000 ug/L 07/26/21 08:59 7440-70-207/24/21 01:025005 Chromium ND ug/L 07/25/21 21:42 7440-47-307/24/21 01:025.0 1 Cobalt 10.2 ug/L 07/25/21 21:42 7440-48-407/24/21 01:025.0 1 Copper ND ug/L 07/25/21 21:42 7440-50-807/24/21 01:025.0 1 Lead ND ug/L 07/25/21 21:42 7439-92-107/24/21 01:025.0 1 Magnesium 80300 ug/L 07/25/21 21:42 7439-95-407/24/21 01:021001 Nickel 14.2 ug/L 07/25/21 21:42 7440-02-007/24/21 01:025.0 1 Potassium 4760J ug/L 07/25/21 21:42 7440-09-707/24/21 01:0250001 Selenium ND ug/L 07/25/21 21:42 7782-49-207/24/21 01:0210.0 1 Silver ND ug/L 07/25/21 21:42 7440-22-407/24/21 01:025.0 1 Sodium 31100 ug/L 07/25/21 21:42 7440-23-507/24/21 01:0250001 Thallium ND ug/L 07/25/21 21:42 7440-28-007/24/21 01:0210.0 1 Vanadium ND ug/L 07/25/21 21:42 7440-62-207/24/21 01:025.0 1 Zinc ND ug/L 07/25/21 21:42 7440-66-607/24/21 01:0210.0 1 Analytical Method: EPA 1631E Preparation Method: EPA 1631E Pace Analytical Services - Asheville 1631E Mercury,Low Level Mercury 0.572 ng/L 07/21/21 18:05 7439-97-607/17/21 15:080.50 1 Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 07/21/21 23:23 83-32-907/20/21 17:4910.0 1 Acenaphthylene ND ug/L 07/21/21 23:23 208-96-807/20/21 17:4910.0 1 Aniline ND ug/L 07/21/21 23:23 62-53-307/20/21 17:4910.0 1 Anthracene ND ug/L 07/21/21 23:23 120-12-707/20/21 17:4910.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 18 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V09 Lab ID:92549145003 Collected:07/13/21 12:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Benzo(a)anthracene ND ug/L 07/21/21 23:23 56-55-3 v107/20/21 17:4910.0 1 Benzo(a)pyrene ND ug/L 07/21/21 23:23 50-32-807/20/21 17:4910.0 1 Benzo(b)fluoranthene ND ug/L 07/21/21 23:23 205-99-207/20/21 17:4910.0 1 Benzo(g,h,i)perylene ND ug/L 07/21/21 23:23 191-24-2 v107/20/21 17:4910.0 1 Benzo(k)fluoranthene ND ug/L 07/21/21 23:23 207-08-907/20/21 17:4910.0 1 Benzoic Acid ND ug/L 07/21/21 23:23 65-85-007/20/21 17:4950.0 1 Benzyl alcohol ND ug/L 07/21/21 23:23 100-51-607/20/21 17:4920.0 1 4-Bromophenylphenyl ether ND ug/L 07/21/21 23:23 101-55-307/20/21 17:4910.0 1 Butylbenzylphthalate ND ug/L 07/21/21 23:23 85-68-707/20/21 17:4910.0 1 4-Chloro-3-methylphenol ND ug/L 07/21/21 23:23 59-50-707/20/21 17:4910.0 1 4-Chloroaniline ND ug/L 07/21/21 23:23 106-47-807/20/21 17:4920.0 1 bis(2-Chloroethoxy)methane ND ug/L 07/21/21 23:23 111-91-107/20/21 17:4910.0 1 bis(2-Chloroethyl) ether ND ug/L 07/21/21 23:23 111-44-407/20/21 17:4910.0 1 2-Chloronaphthalene ND ug/L 07/21/21 23:23 91-58-707/20/21 17:4910.0 1 2-Chlorophenol ND ug/L 07/21/21 23:23 95-57-807/20/21 17:4910.0 1 4-Chlorophenylphenyl ether ND ug/L 07/21/21 23:23 7005-72-307/20/21 17:4910.0 1 Chrysene ND ug/L 07/21/21 23:23 218-01-907/20/21 17:4910.0 1 Dibenz(a,h)anthracene ND ug/L 07/21/21 23:23 53-70-307/20/21 17:4910.0 1 Dibenzofuran ND ug/L 07/21/21 23:23 132-64-907/20/21 17:4910.0 1 1,2-Dichlorobenzene ND ug/L 07/21/21 23:23 95-50-107/20/21 17:4910.0 1 1,3-Dichlorobenzene ND ug/L 07/21/21 23:23 541-73-107/20/21 17:4910.0 1 1,4-Dichlorobenzene ND ug/L 07/21/21 23:23 106-46-707/20/21 17:4910.0 1 3,3'-Dichlorobenzidine ND ug/L 07/21/21 23:23 91-94-107/20/21 17:4920.0 1 2,4-Dichlorophenol ND ug/L 07/21/21 23:23 120-83-207/20/21 17:4910.0 1 Diethylphthalate ND ug/L 07/21/21 23:23 84-66-207/20/21 17:4910.0 1 2,4-Dimethylphenol ND ug/L 07/21/21 23:23 105-67-907/20/21 17:4910.0 1 Dimethylphthalate ND ug/L 07/21/21 23:23 131-11-307/20/21 17:4910.0 1 Di-n-butylphthalate ND ug/L 07/21/21 23:23 84-74-207/20/21 17:4910.0 1 4,6-Dinitro-2-methylphenol ND ug/L 07/21/21 23:23 534-52-107/20/21 17:4920.0 1 2,4-Dinitrophenol ND ug/L 07/21/21 23:23 51-28-507/20/21 17:4950.0 1 2,4-Dinitrotoluene ND ug/L 07/21/21 23:23 121-14-207/20/21 17:4910.0 1 2,6-Dinitrotoluene ND ug/L 07/21/21 23:23 606-20-207/20/21 17:4910.0 1 Di-n-octylphthalate ND ug/L 07/21/21 23:23 117-84-007/20/21 17:4910.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 07/21/21 23:23 117-81-707/20/21 17:496.0 1 Fluoranthene ND ug/L 07/21/21 23:23 206-44-007/20/21 17:4910.0 1 Fluorene ND ug/L 07/21/21 23:23 86-73-707/20/21 17:4910.0 1 Hexachloro-1,3-butadiene ND ug/L 07/21/21 23:23 87-68-307/20/21 17:4910.0 1 Hexachlorobenzene ND ug/L 07/21/21 23:23 118-74-107/20/21 17:4910.0 1 Hexachlorocyclopentadiene ND ug/L 07/21/21 23:23 77-47-407/20/21 17:4910.0 1 Hexachloroethane ND ug/L 07/21/21 23:23 67-72-107/20/21 17:4910.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/21/21 23:23 193-39-507/20/21 17:4910.0 1 Isophorone ND ug/L 07/21/21 23:23 78-59-107/20/21 17:4910.0 1 1-Methylnaphthalene ND ug/L 07/21/21 23:23 90-12-007/20/21 17:4910.0 1 2-Methylnaphthalene ND ug/L 07/21/21 23:23 91-57-607/20/21 17:4910.0 1 2-Methylphenol(o-Cresol)ND ug/L 07/21/21 23:23 95-48-707/20/21 17:4910.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 07/21/21 23:23 15831-10-407/20/21 17:4910.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 19 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V09 Lab ID:92549145003 Collected:07/13/21 12:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Naphthalene ND ug/L 07/21/21 23:23 91-20-307/20/21 17:4910.0 1 2-Nitroaniline ND ug/L 07/21/21 23:23 88-74-407/20/21 17:4920.0 1 3-Nitroaniline ND ug/L 07/21/21 23:23 99-09-207/20/21 17:4920.0 1 4-Nitroaniline ND ug/L 07/21/21 23:23 100-01-607/20/21 17:4920.0 1 Nitrobenzene ND ug/L 07/21/21 23:23 98-95-307/20/21 17:4910.0 1 2-Nitrophenol ND ug/L 07/21/21 23:23 88-75-507/20/21 17:4910.0 1 4-Nitrophenol ND ug/L 07/21/21 23:23 100-02-707/20/21 17:4950.0 1 N-Nitrosodimethylamine ND ug/L 07/21/21 23:23 62-75-9 v107/20/21 17:4910.0 1 N-Nitroso-di-n-propylamine ND ug/L 07/21/21 23:23 621-64-707/20/21 17:4910.0 1 N-Nitrosodiphenylamine ND ug/L 07/21/21 23:23 86-30-607/20/21 17:4910.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 07/21/21 23:23 108-60-107/20/21 17:4910.0 1 Pentachlorophenol ND ug/L 07/21/21 23:23 87-86-507/20/21 17:4920.0 1 Phenanthrene ND ug/L 07/21/21 23:23 85-01-807/20/21 17:4910.0 1 Phenol ND ug/L 07/21/21 23:23 108-95-207/20/21 17:4910.0 1 Pyrene ND ug/L 07/21/21 23:23 129-00-007/20/21 17:4910.0 1 1,2,4-Trichlorobenzene ND ug/L 07/21/21 23:23 120-82-107/20/21 17:4910.0 1 2,4,5-Trichlorophenol ND ug/L 07/21/21 23:23 95-95-407/20/21 17:4910.0 1 2,4,6-Trichlorophenol ND ug/L 07/21/21 23:23 88-06-207/20/21 17:4910.0 1 Surrogates Nitrobenzene-d5 (S)87 %07/21/21 23:23 4165-60-007/20/21 17:4910-144 1 2-Fluorobiphenyl (S)76 %07/21/21 23:23 321-60-807/20/21 17:4910-130 1 Terphenyl-d14 (S)95 %07/21/21 23:23 1718-51-007/20/21 17:4934-163 1 Phenol-d6 (S)39 %07/21/21 23:23 13127-88-307/20/21 17:4910-130 1 2-Fluorophenol (S)21 %07/21/21 23:23 367-12-407/20/21 17:4910-130 1 2,4,6-Tribromophenol (S)34 %07/21/21 23:23 118-79-607/20/21 17:4910-144 1 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Acetone ND ug/L 07/16/21 13:49 67-64-125.0 1 Benzene ND ug/L 07/16/21 13:49 71-43-21.0 1 Bromobenzene ND ug/L 07/16/21 13:49 108-86-11.0 1 Bromochloromethane ND ug/L 07/16/21 13:49 74-97-51.0 1 Bromodichloromethane ND ug/L 07/16/21 13:49 75-27-41.0 1 Bromoform ND ug/L 07/16/21 13:49 75-25-21.0 1 Bromomethane ND ug/L 07/16/21 13:49 74-83-9 IH,IK,v12.0 1 2-Butanone (MEK)ND ug/L 07/16/21 13:49 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/16/21 13:49 56-23-51.0 1 Chlorobenzene ND ug/L 07/16/21 13:49 108-90-71.0 1 Chloroethane ND ug/L 07/16/21 13:49 75-00-31.0 1 Chloroform ND ug/L 07/16/21 13:49 67-66-31.0 1 Chloromethane ND ug/L 07/16/21 13:49 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/16/21 13:49 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/16/21 13:49 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/16/21 13:49 96-12-82.0 1 Dibromochloromethane ND ug/L 07/16/21 13:49 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/16/21 13:49 106-93-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 20 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V09 Lab ID:92549145003 Collected:07/13/21 12:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Dibromomethane ND ug/L 07/16/21 13:49 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/16/21 13:49 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/16/21 13:49 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/16/21 13:49 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/16/21 13:49 75-71-81.0 1 1,1-Dichloroethane ND ug/L 07/16/21 13:49 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/16/21 13:49 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/16/21 13:49 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/16/21 13:49 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/16/21 13:49 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/16/21 13:49 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/16/21 13:49 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/16/21 13:49 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/16/21 13:49 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/16/21 13:49 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/16/21 13:49 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/16/21 13:49 108-20-31.0 1 Ethylbenzene ND ug/L 07/16/21 13:49 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/16/21 13:49 87-68-32.0 1 2-Hexanone ND ug/L 07/16/21 13:49 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/16/21 13:49 99-87-61.0 1 Methylene Chloride ND ug/L 07/16/21 13:49 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/16/21 13:49 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/16/21 13:49 1634-04-41.0 1 Naphthalene ND ug/L 07/16/21 13:49 91-20-31.0 1 Styrene ND ug/L 07/16/21 13:49 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/16/21 13:49 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/16/21 13:49 79-34-51.0 1 Tetrachloroethene ND ug/L 07/16/21 13:49 127-18-41.0 1 Toluene ND ug/L 07/16/21 13:49 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/16/21 13:49 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/16/21 13:49 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/16/21 13:49 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/16/21 13:49 79-00-51.0 1 Trichloroethene ND ug/L 07/16/21 13:49 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/16/21 13:49 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/16/21 13:49 96-18-41.0 1 Vinyl acetate ND ug/L 07/16/21 13:49 108-05-42.0 1 Vinyl chloride ND ug/L 07/16/21 13:49 75-01-41.0 1 Xylene (Total)ND ug/L 07/16/21 13:49 1330-20-71.0 1 m&p-Xylene ND ug/L 07/16/21 13:49 179601-23-12.0 1 o-Xylene ND ug/L 07/16/21 13:49 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)100 %07/16/21 13:49 460-00-470-130 1 1,2-Dichloroethane-d4 (S)104 %07/16/21 13:49 17060-07-070-130 1 Toluene-d8 (S)100 %07/16/21 13:49 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 21 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V09 Lab ID:92549145003 Collected:07/13/21 12:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 8260D MSV SIM 1,4-Dioxane (p-Dioxane)ND ug/L 07/15/21 19:52 123-91-12.0 1 Surrogates 1,2-Dichloroethane-d4 (S)98 %07/15/21 19:52 17060-07-070-130 1 Toluene-d8 (S)98 %07/15/21 19:52 2037-26-566-133 1 Analytical Method: SM 2320B-2011 Pace Analytical Services - Asheville 2320B Alkalinity Alkalinity, Total as CaCO3 829 mg/L 07/16/21 16:115.0 1 Analytical Method: SM 2540C-2011 Pace Analytical Services - Asheville 2540C Total Dissolved Solids Total Dissolved Solids 824 mg/L 07/17/21 13:1650.0 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville 300.0 IC Anions 28 Days Sulfate 3.5 mg/L 07/22/21 01:52 14808-79-81.0 1 Analytical Method: SM 4500-Cl-E-2011 Pace Analytical Services - Asheville 4500 Chloride Chloride 48.1 mg/L 07/20/21 11:38 16887-00-63.0 3 Analytical Method: SM 5310B-2011 Pace Analytical Services - Asheville 5310B TOC Total Organic Carbon 4.2 mg/L 07/21/21 19:21 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 22 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V10 Lab ID:92549145004 Collected:07/13/21 11:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: Pace Analytical Services - Charlotte Monitoring Well Data Performed by Pace 07/27/21 07:361 Collected By Mark Swann 07/27/21 07:361 Collected Date 7/13/21 07/27/21 07:361 Collected Time 11:50 07/27/21 07:361 pH 6.0 Std. Units 07/27/21 07:361 Temperature 15.3 deg C 07/27/21 07:361 Static Water Level 27.97 feet 07/27/21 07:361 Specific Conductance 29 umhos/cm 07/27/21 07:361 Oxygen, Dissolved 4.85 mg/L 07/27/21 07:36 7782-44-71 REDOX 102.6 mV 07/27/21 07:361 Turbidity 6.85 NTU 07/27/21 07:361 Odor No odor 07/27/21 07:361 Appearance Clear 07/27/21 07:361 Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services - Asheville 6010 MET ICP Antimony ND ug/L 07/25/21 21:45 7440-36-007/24/21 01:025.0 1 Arsenic ND ug/L 07/25/21 21:45 7440-38-207/24/21 01:0210.0 1 Barium 4.7J ug/L 07/25/21 21:45 7440-39-307/24/21 01:025.0 1 Cadmium ND ug/L 07/25/21 21:45 7440-43-907/24/21 01:021.0 1 Calcium 1980 ug/L 07/25/21 21:45 7440-70-207/24/21 01:021001 Chromium ND ug/L 07/25/21 21:45 7440-47-307/24/21 01:025.0 1 Cobalt ND ug/L 07/25/21 21:45 7440-48-407/24/21 01:025.0 1 Copper ND ug/L 07/25/21 21:45 7440-50-807/24/21 01:025.0 1 Lead ND ug/L 07/25/21 21:45 7439-92-107/24/21 01:025.0 1 Magnesium 718 ug/L 07/25/21 21:45 7439-95-407/24/21 01:021001 Nickel ND ug/L 07/25/21 21:45 7440-02-007/24/21 01:025.0 1 Potassium ND ug/L 07/25/21 21:45 7440-09-707/24/21 01:0250001 Selenium ND ug/L 07/25/21 21:45 7782-49-207/24/21 01:0210.0 1 Silver ND ug/L 07/25/21 21:45 7440-22-407/24/21 01:025.0 1 Sodium 1670J ug/L 07/25/21 21:45 7440-23-507/24/21 01:0250001 Thallium ND ug/L 07/25/21 21:45 7440-28-007/24/21 01:0210.0 1 Vanadium ND ug/L 07/25/21 21:45 7440-62-207/24/21 01:025.0 1 Zinc ND ug/L 07/25/21 21:45 7440-66-607/24/21 01:0210.0 1 Analytical Method: EPA 1631E Preparation Method: EPA 1631E Pace Analytical Services - Asheville 1631E Mercury,Low Level Mercury 4.61J ng/L 07/21/21 18:12 7439-97-607/17/21 15:085.0 1 Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 07/20/21 01:05 83-32-907/19/21 08:0010.0 1 Acenaphthylene ND ug/L 07/20/21 01:05 208-96-807/19/21 08:0010.0 1 Aniline ND ug/L 07/20/21 01:05 62-53-307/19/21 08:0010.0 1 Anthracene ND ug/L 07/20/21 01:05 120-12-707/19/21 08:0010.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 23 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V10 Lab ID:92549145004 Collected:07/13/21 11:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Benzo(a)anthracene ND ug/L 07/20/21 01:05 56-55-307/19/21 08:0010.0 1 Benzo(a)pyrene ND ug/L 07/20/21 01:05 50-32-807/19/21 08:0010.0 1 Benzo(b)fluoranthene ND ug/L 07/20/21 01:05 205-99-207/19/21 08:0010.0 1 Benzo(g,h,i)perylene ND ug/L 07/20/21 01:05 191-24-207/19/21 08:0010.0 1 Benzo(k)fluoranthene ND ug/L 07/20/21 01:05 207-08-907/19/21 08:0010.0 1 Benzoic Acid ND ug/L 07/20/21 01:05 65-85-0 v107/19/21 08:0050.0 1 Benzyl alcohol ND ug/L 07/20/21 01:05 100-51-607/19/21 08:0020.0 1 4-Bromophenylphenyl ether ND ug/L 07/20/21 01:05 101-55-307/19/21 08:0010.0 1 Butylbenzylphthalate ND ug/L 07/20/21 01:05 85-68-707/19/21 08:0010.0 1 4-Chloro-3-methylphenol ND ug/L 07/20/21 01:05 59-50-707/19/21 08:0010.0 1 4-Chloroaniline ND ug/L 07/20/21 01:05 106-47-807/19/21 08:0020.0 1 bis(2-Chloroethoxy)methane ND ug/L 07/20/21 01:05 111-91-107/19/21 08:0010.0 1 bis(2-Chloroethyl) ether ND ug/L 07/20/21 01:05 111-44-407/19/21 08:0010.0 1 2-Chloronaphthalene ND ug/L 07/20/21 01:05 91-58-707/19/21 08:0010.0 1 2-Chlorophenol ND ug/L 07/20/21 01:05 95-57-807/19/21 08:0010.0 1 4-Chlorophenylphenyl ether ND ug/L 07/20/21 01:05 7005-72-307/19/21 08:0010.0 1 Chrysene ND ug/L 07/20/21 01:05 218-01-907/19/21 08:0010.0 1 Dibenz(a,h)anthracene ND ug/L 07/20/21 01:05 53-70-307/19/21 08:0010.0 1 Dibenzofuran ND ug/L 07/20/21 01:05 132-64-907/19/21 08:0010.0 1 1,2-Dichlorobenzene ND ug/L 07/20/21 01:05 95-50-107/19/21 08:0010.0 1 1,3-Dichlorobenzene ND ug/L 07/20/21 01:05 541-73-107/19/21 08:0010.0 1 1,4-Dichlorobenzene ND ug/L 07/20/21 01:05 106-46-707/19/21 08:0010.0 1 3,3'-Dichlorobenzidine ND ug/L 07/20/21 01:05 91-94-107/19/21 08:0020.0 1 2,4-Dichlorophenol ND ug/L 07/20/21 01:05 120-83-207/19/21 08:0010.0 1 Diethylphthalate ND ug/L 07/20/21 01:05 84-66-207/19/21 08:0010.0 1 2,4-Dimethylphenol ND ug/L 07/20/21 01:05 105-67-907/19/21 08:0010.0 1 Dimethylphthalate ND ug/L 07/20/21 01:05 131-11-307/19/21 08:0010.0 1 Di-n-butylphthalate ND ug/L 07/20/21 01:05 84-74-207/19/21 08:0010.0 1 4,6-Dinitro-2-methylphenol ND ug/L 07/20/21 01:05 534-52-1 v107/19/21 08:0020.0 1 2,4-Dinitrophenol ND ug/L 07/20/21 01:05 51-28-5 v107/19/21 08:0050.0 1 2,4-Dinitrotoluene ND ug/L 07/20/21 01:05 121-14-207/19/21 08:0010.0 1 2,6-Dinitrotoluene ND ug/L 07/20/21 01:05 606-20-2 v107/19/21 08:0010.0 1 Di-n-octylphthalate ND ug/L 07/20/21 01:05 117-84-007/19/21 08:0010.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 07/20/21 01:05 117-81-707/19/21 08:006.0 1 Fluoranthene ND ug/L 07/20/21 01:05 206-44-007/19/21 08:0010.0 1 Fluorene ND ug/L 07/20/21 01:05 86-73-707/19/21 08:0010.0 1 Hexachloro-1,3-butadiene ND ug/L 07/20/21 01:05 87-68-307/19/21 08:0010.0 1 Hexachlorobenzene ND ug/L 07/20/21 01:05 118-74-107/19/21 08:0010.0 1 Hexachlorocyclopentadiene ND ug/L 07/20/21 01:05 77-47-407/19/21 08:0010.0 1 Hexachloroethane ND ug/L 07/20/21 01:05 67-72-107/19/21 08:0010.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/20/21 01:05 193-39-507/19/21 08:0010.0 1 Isophorone ND ug/L 07/20/21 01:05 78-59-107/19/21 08:0010.0 1 1-Methylnaphthalene ND ug/L 07/20/21 01:05 90-12-007/19/21 08:0010.0 1 2-Methylnaphthalene ND ug/L 07/20/21 01:05 91-57-607/19/21 08:0010.0 1 2-Methylphenol(o-Cresol)ND ug/L 07/20/21 01:05 95-48-707/19/21 08:0010.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 07/20/21 01:05 15831-10-407/19/21 08:0010.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 24 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V10 Lab ID:92549145004 Collected:07/13/21 11:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Naphthalene ND ug/L 07/20/21 01:05 91-20-307/19/21 08:0010.0 1 2-Nitroaniline ND ug/L 07/20/21 01:05 88-74-407/19/21 08:0020.0 1 3-Nitroaniline ND ug/L 07/20/21 01:05 99-09-2 v107/19/21 08:0020.0 1 4-Nitroaniline ND ug/L 07/20/21 01:05 100-01-607/19/21 08:0020.0 1 Nitrobenzene ND ug/L 07/20/21 01:05 98-95-307/19/21 08:0010.0 1 2-Nitrophenol ND ug/L 07/20/21 01:05 88-75-5 v107/19/21 08:0010.0 1 4-Nitrophenol ND ug/L 07/20/21 01:05 100-02-707/19/21 08:0050.0 1 N-Nitrosodimethylamine ND ug/L 07/20/21 01:05 62-75-907/19/21 08:0010.0 1 N-Nitroso-di-n-propylamine ND ug/L 07/20/21 01:05 621-64-707/19/21 08:0010.0 1 N-Nitrosodiphenylamine ND ug/L 07/20/21 01:05 86-30-607/19/21 08:0010.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 07/20/21 01:05 108-60-107/19/21 08:0010.0 1 Pentachlorophenol ND ug/L 07/20/21 01:05 87-86-507/19/21 08:0020.0 1 Phenanthrene ND ug/L 07/20/21 01:05 85-01-807/19/21 08:0010.0 1 Phenol ND ug/L 07/20/21 01:05 108-95-207/19/21 08:0010.0 1 Pyrene ND ug/L 07/20/21 01:05 129-00-007/19/21 08:0010.0 1 1,2,4-Trichlorobenzene ND ug/L 07/20/21 01:05 120-82-107/19/21 08:0010.0 1 2,4,5-Trichlorophenol ND ug/L 07/20/21 01:05 95-95-407/19/21 08:0010.0 1 2,4,6-Trichlorophenol ND ug/L 07/20/21 01:05 88-06-207/19/21 08:0010.0 1 Surrogates Nitrobenzene-d5 (S)71 %07/20/21 01:05 4165-60-007/19/21 08:0010-144 1 2-Fluorobiphenyl (S)61 %07/20/21 01:05 321-60-807/19/21 08:0010-130 1 Terphenyl-d14 (S)74 %07/20/21 01:05 1718-51-007/19/21 08:0034-163 1 Phenol-d6 (S)32 %07/20/21 01:05 13127-88-307/19/21 08:0010-130 1 2-Fluorophenol (S)49 %07/20/21 01:05 367-12-407/19/21 08:0010-130 1 2,4,6-Tribromophenol (S)67 %07/20/21 01:05 118-79-607/19/21 08:0010-144 1 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Acetone ND ug/L 07/16/21 14:07 67-64-125.0 1 Benzene ND ug/L 07/16/21 14:07 71-43-21.0 1 Bromobenzene ND ug/L 07/16/21 14:07 108-86-11.0 1 Bromochloromethane ND ug/L 07/16/21 14:07 74-97-51.0 1 Bromodichloromethane ND ug/L 07/16/21 14:07 75-27-41.0 1 Bromoform ND ug/L 07/16/21 14:07 75-25-21.0 1 Bromomethane ND ug/L 07/16/21 14:07 74-83-9 IH,IK,v12.0 1 2-Butanone (MEK)ND ug/L 07/16/21 14:07 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/16/21 14:07 56-23-51.0 1 Chlorobenzene ND ug/L 07/16/21 14:07 108-90-71.0 1 Chloroethane ND ug/L 07/16/21 14:07 75-00-31.0 1 Chloroform ND ug/L 07/16/21 14:07 67-66-31.0 1 Chloromethane ND ug/L 07/16/21 14:07 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/16/21 14:07 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/16/21 14:07 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/16/21 14:07 96-12-82.0 1 Dibromochloromethane ND ug/L 07/16/21 14:07 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/16/21 14:07 106-93-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 25 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V10 Lab ID:92549145004 Collected:07/13/21 11:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Dibromomethane ND ug/L 07/16/21 14:07 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/16/21 14:07 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/16/21 14:07 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/16/21 14:07 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/16/21 14:07 75-71-81.0 1 1,1-Dichloroethane ND ug/L 07/16/21 14:07 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/16/21 14:07 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/16/21 14:07 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/16/21 14:07 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/16/21 14:07 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/16/21 14:07 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/16/21 14:07 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/16/21 14:07 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/16/21 14:07 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/16/21 14:07 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/16/21 14:07 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/16/21 14:07 108-20-31.0 1 Ethylbenzene ND ug/L 07/16/21 14:07 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/16/21 14:07 87-68-32.0 1 2-Hexanone ND ug/L 07/16/21 14:07 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/16/21 14:07 99-87-61.0 1 Methylene Chloride ND ug/L 07/16/21 14:07 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/16/21 14:07 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/16/21 14:07 1634-04-41.0 1 Naphthalene ND ug/L 07/16/21 14:07 91-20-31.0 1 Styrene ND ug/L 07/16/21 14:07 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/16/21 14:07 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/16/21 14:07 79-34-51.0 1 Tetrachloroethene ND ug/L 07/16/21 14:07 127-18-41.0 1 Toluene ND ug/L 07/16/21 14:07 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/16/21 14:07 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/16/21 14:07 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/16/21 14:07 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/16/21 14:07 79-00-51.0 1 Trichloroethene ND ug/L 07/16/21 14:07 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/16/21 14:07 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/16/21 14:07 96-18-41.0 1 Vinyl acetate ND ug/L 07/16/21 14:07 108-05-42.0 1 Vinyl chloride ND ug/L 07/16/21 14:07 75-01-41.0 1 Xylene (Total)ND ug/L 07/16/21 14:07 1330-20-71.0 1 m&p-Xylene ND ug/L 07/16/21 14:07 179601-23-12.0 1 o-Xylene ND ug/L 07/16/21 14:07 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %07/16/21 14:07 460-00-470-130 1 1,2-Dichloroethane-d4 (S)104 %07/16/21 14:07 17060-07-070-130 1 Toluene-d8 (S)99 %07/16/21 14:07 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 26 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V10 Lab ID:92549145004 Collected:07/13/21 11:50 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 8260D MSV SIM 1,4-Dioxane (p-Dioxane)ND ug/L 07/15/21 20:11 123-91-12.0 1 Surrogates 1,2-Dichloroethane-d4 (S)99 %07/15/21 20:11 17060-07-070-130 1 Toluene-d8 (S)98 %07/15/21 20:11 2037-26-566-133 1 Analytical Method: SM 2320B-2011 Pace Analytical Services - Asheville 2320B Alkalinity Alkalinity, Total as CaCO3 8.3 mg/L 07/16/21 16:215.0 1 Analytical Method: SM 2540C-2011 Pace Analytical Services - Asheville 2540C Total Dissolved Solids Total Dissolved Solids ND mg/L 07/17/21 13:1625.0 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville 300.0 IC Anions 28 Days Sulfate 0.77J mg/L 07/22/21 02:07 14808-79-81.0 1 Analytical Method: SM 4500-Cl-E-2011 Pace Analytical Services - Asheville 4500 Chloride Chloride 3.0 mg/L 07/20/21 11:40 16887-00-61.0 1 Analytical Method: SM 5310B-2011 Pace Analytical Services - Asheville 5310B TOC Total Organic Carbon ND mg/L 07/21/21 19:41 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 27 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V11 Lab ID:92549145005 Collected:07/13/21 12:20 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: Pace Analytical Services - Charlotte Monitoring Well Data Performed by Pace 07/27/21 07:381 Collected By Mark Swann 07/27/21 07:381 Collected Date 7/13/21 07/27/21 07:381 Collected Time 12:20 07/27/21 07:381 pH 5.8 Std. Units 07/27/21 07:381 Temperature 15.3 deg C 07/27/21 07:381 Static Water Level 30.43 feet 07/27/21 07:381 Specific Conductance 66 umhos/cm 07/27/21 07:381 Oxygen, Dissolved 6.64 mg/L 07/27/21 07:38 7782-44-71 REDOX 93.2 mV 07/27/21 07:381 Turbidity 8.75 NTU 07/27/21 07:381 Odor No odor 07/27/21 07:381 Appearance Clear 07/27/21 07:381 Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services - Asheville 6010 MET ICP Antimony ND ug/L 07/25/21 21:48 7440-36-007/24/21 01:025.0 1 Arsenic ND ug/L 07/25/21 21:48 7440-38-207/24/21 01:0210.0 1 Barium 5.7 ug/L 07/25/21 21:48 7440-39-307/24/21 01:025.0 1 Cadmium ND ug/L 07/25/21 21:48 7440-43-907/24/21 01:021.0 1 Calcium 4620 ug/L 07/25/21 21:48 7440-70-207/24/21 01:021001 Chromium ND ug/L 07/25/21 21:48 7440-47-307/24/21 01:025.0 1 Cobalt ND ug/L 07/25/21 21:48 7440-48-407/24/21 01:025.0 1 Copper ND ug/L 07/25/21 21:48 7440-50-807/24/21 01:025.0 1 Lead ND ug/L 07/25/21 21:48 7439-92-107/24/21 01:025.0 1 Magnesium 2140 ug/L 07/25/21 21:48 7439-95-407/24/21 01:021001 Nickel ND ug/L 07/25/21 21:48 7440-02-007/24/21 01:025.0 1 Potassium ND ug/L 07/25/21 21:48 7440-09-707/24/21 01:0250001 Selenium ND ug/L 07/25/21 21:48 7782-49-207/24/21 01:0210.0 1 Silver ND ug/L 07/25/21 21:48 7440-22-407/24/21 01:025.0 1 Sodium 4000J ug/L 07/25/21 21:48 7440-23-507/24/21 01:0250001 Thallium ND ug/L 07/25/21 21:48 7440-28-007/24/21 01:0210.0 1 Vanadium ND ug/L 07/25/21 21:48 7440-62-207/24/21 01:025.0 1 Zinc ND ug/L 07/25/21 21:48 7440-66-607/24/21 01:0210.0 1 Analytical Method: EPA 1631E Preparation Method: EPA 1631E Pace Analytical Services - Asheville 1631E Mercury,Low Level Mercury 1.52 ng/L 07/21/21 18:20 7439-97-607/17/21 15:080.50 1 Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 07/20/21 01:35 83-32-907/19/21 08:0010.0 1 Acenaphthylene ND ug/L 07/20/21 01:35 208-96-807/19/21 08:0010.0 1 Aniline ND ug/L 07/20/21 01:35 62-53-307/19/21 08:0010.0 1 Anthracene ND ug/L 07/20/21 01:35 120-12-707/19/21 08:0010.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 28 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V11 Lab ID:92549145005 Collected:07/13/21 12:20 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Benzo(a)anthracene ND ug/L 07/20/21 01:35 56-55-307/19/21 08:0010.0 1 Benzo(a)pyrene ND ug/L 07/20/21 01:35 50-32-807/19/21 08:0010.0 1 Benzo(b)fluoranthene ND ug/L 07/20/21 01:35 205-99-207/19/21 08:0010.0 1 Benzo(g,h,i)perylene ND ug/L 07/20/21 01:35 191-24-207/19/21 08:0010.0 1 Benzo(k)fluoranthene ND ug/L 07/20/21 01:35 207-08-907/19/21 08:0010.0 1 Benzoic Acid ND ug/L 07/20/21 01:35 65-85-0 v107/19/21 08:0050.0 1 Benzyl alcohol ND ug/L 07/20/21 01:35 100-51-607/19/21 08:0020.0 1 4-Bromophenylphenyl ether ND ug/L 07/20/21 01:35 101-55-307/19/21 08:0010.0 1 Butylbenzylphthalate ND ug/L 07/20/21 01:35 85-68-707/19/21 08:0010.0 1 4-Chloro-3-methylphenol ND ug/L 07/20/21 01:35 59-50-707/19/21 08:0010.0 1 4-Chloroaniline ND ug/L 07/20/21 01:35 106-47-807/19/21 08:0020.0 1 bis(2-Chloroethoxy)methane ND ug/L 07/20/21 01:35 111-91-107/19/21 08:0010.0 1 bis(2-Chloroethyl) ether ND ug/L 07/20/21 01:35 111-44-407/19/21 08:0010.0 1 2-Chloronaphthalene ND ug/L 07/20/21 01:35 91-58-707/19/21 08:0010.0 1 2-Chlorophenol ND ug/L 07/20/21 01:35 95-57-807/19/21 08:0010.0 1 4-Chlorophenylphenyl ether ND ug/L 07/20/21 01:35 7005-72-307/19/21 08:0010.0 1 Chrysene ND ug/L 07/20/21 01:35 218-01-907/19/21 08:0010.0 1 Dibenz(a,h)anthracene ND ug/L 07/20/21 01:35 53-70-307/19/21 08:0010.0 1 Dibenzofuran ND ug/L 07/20/21 01:35 132-64-907/19/21 08:0010.0 1 1,2-Dichlorobenzene ND ug/L 07/20/21 01:35 95-50-107/19/21 08:0010.0 1 1,3-Dichlorobenzene ND ug/L 07/20/21 01:35 541-73-107/19/21 08:0010.0 1 1,4-Dichlorobenzene ND ug/L 07/20/21 01:35 106-46-707/19/21 08:0010.0 1 3,3'-Dichlorobenzidine ND ug/L 07/20/21 01:35 91-94-107/19/21 08:0020.0 1 2,4-Dichlorophenol ND ug/L 07/20/21 01:35 120-83-207/19/21 08:0010.0 1 Diethylphthalate ND ug/L 07/20/21 01:35 84-66-207/19/21 08:0010.0 1 2,4-Dimethylphenol ND ug/L 07/20/21 01:35 105-67-907/19/21 08:0010.0 1 Dimethylphthalate ND ug/L 07/20/21 01:35 131-11-307/19/21 08:0010.0 1 Di-n-butylphthalate ND ug/L 07/20/21 01:35 84-74-207/19/21 08:0010.0 1 4,6-Dinitro-2-methylphenol ND ug/L 07/20/21 01:35 534-52-1 v107/19/21 08:0020.0 1 2,4-Dinitrophenol ND ug/L 07/20/21 01:35 51-28-5 v107/19/21 08:0050.0 1 2,4-Dinitrotoluene ND ug/L 07/20/21 01:35 121-14-207/19/21 08:0010.0 1 2,6-Dinitrotoluene ND ug/L 07/20/21 01:35 606-20-2 v107/19/21 08:0010.0 1 Di-n-octylphthalate ND ug/L 07/20/21 01:35 117-84-007/19/21 08:0010.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 07/20/21 01:35 117-81-707/19/21 08:006.0 1 Fluoranthene ND ug/L 07/20/21 01:35 206-44-007/19/21 08:0010.0 1 Fluorene ND ug/L 07/20/21 01:35 86-73-707/19/21 08:0010.0 1 Hexachloro-1,3-butadiene ND ug/L 07/20/21 01:35 87-68-307/19/21 08:0010.0 1 Hexachlorobenzene ND ug/L 07/20/21 01:35 118-74-107/19/21 08:0010.0 1 Hexachlorocyclopentadiene ND ug/L 07/20/21 01:35 77-47-407/19/21 08:0010.0 1 Hexachloroethane ND ug/L 07/20/21 01:35 67-72-107/19/21 08:0010.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/20/21 01:35 193-39-507/19/21 08:0010.0 1 Isophorone ND ug/L 07/20/21 01:35 78-59-107/19/21 08:0010.0 1 1-Methylnaphthalene ND ug/L 07/20/21 01:35 90-12-007/19/21 08:0010.0 1 2-Methylnaphthalene ND ug/L 07/20/21 01:35 91-57-607/19/21 08:0010.0 1 2-Methylphenol(o-Cresol)ND ug/L 07/20/21 01:35 95-48-707/19/21 08:0010.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 07/20/21 01:35 15831-10-407/19/21 08:0010.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 29 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V11 Lab ID:92549145005 Collected:07/13/21 12:20 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Naphthalene ND ug/L 07/20/21 01:35 91-20-307/19/21 08:0010.0 1 2-Nitroaniline ND ug/L 07/20/21 01:35 88-74-407/19/21 08:0020.0 1 3-Nitroaniline ND ug/L 07/20/21 01:35 99-09-2 v107/19/21 08:0020.0 1 4-Nitroaniline ND ug/L 07/20/21 01:35 100-01-607/19/21 08:0020.0 1 Nitrobenzene ND ug/L 07/20/21 01:35 98-95-307/19/21 08:0010.0 1 2-Nitrophenol ND ug/L 07/20/21 01:35 88-75-5 v107/19/21 08:0010.0 1 4-Nitrophenol ND ug/L 07/20/21 01:35 100-02-707/19/21 08:0050.0 1 N-Nitrosodimethylamine ND ug/L 07/20/21 01:35 62-75-907/19/21 08:0010.0 1 N-Nitroso-di-n-propylamine ND ug/L 07/20/21 01:35 621-64-707/19/21 08:0010.0 1 N-Nitrosodiphenylamine ND ug/L 07/20/21 01:35 86-30-607/19/21 08:0010.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 07/20/21 01:35 108-60-107/19/21 08:0010.0 1 Pentachlorophenol ND ug/L 07/20/21 01:35 87-86-507/19/21 08:0020.0 1 Phenanthrene ND ug/L 07/20/21 01:35 85-01-807/19/21 08:0010.0 1 Phenol ND ug/L 07/20/21 01:35 108-95-207/19/21 08:0010.0 1 Pyrene ND ug/L 07/20/21 01:35 129-00-007/19/21 08:0010.0 1 1,2,4-Trichlorobenzene ND ug/L 07/20/21 01:35 120-82-107/19/21 08:0010.0 1 2,4,5-Trichlorophenol ND ug/L 07/20/21 01:35 95-95-407/19/21 08:0010.0 1 2,4,6-Trichlorophenol ND ug/L 07/20/21 01:35 88-06-207/19/21 08:0010.0 1 Surrogates Nitrobenzene-d5 (S)71 %07/20/21 01:35 4165-60-007/19/21 08:0010-144 1 2-Fluorobiphenyl (S)60 %07/20/21 01:35 321-60-807/19/21 08:0010-130 1 Terphenyl-d14 (S)74 %07/20/21 01:35 1718-51-007/19/21 08:0034-163 1 Phenol-d6 (S)30 %07/20/21 01:35 13127-88-307/19/21 08:0010-130 1 2-Fluorophenol (S)47 %07/20/21 01:35 367-12-407/19/21 08:0010-130 1 2,4,6-Tribromophenol (S)69 %07/20/21 01:35 118-79-607/19/21 08:0010-144 1 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Acetone ND ug/L 07/15/21 13:04 67-64-125.0 1 Benzene ND ug/L 07/15/21 13:04 71-43-21.0 1 Bromobenzene ND ug/L 07/15/21 13:04 108-86-11.0 1 Bromochloromethane ND ug/L 07/15/21 13:04 74-97-51.0 1 Bromodichloromethane ND ug/L 07/15/21 13:04 75-27-41.0 1 Bromoform ND ug/L 07/15/21 13:04 75-25-21.0 1 Bromomethane ND ug/L 07/15/21 13:04 74-83-92.0 1 2-Butanone (MEK)ND ug/L 07/15/21 13:04 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/15/21 13:04 56-23-51.0 1 Chlorobenzene ND ug/L 07/15/21 13:04 108-90-71.0 1 Chloroethane ND ug/L 07/15/21 13:04 75-00-31.0 1 Chloroform ND ug/L 07/15/21 13:04 67-66-31.0 1 Chloromethane ND ug/L 07/15/21 13:04 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/15/21 13:04 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/15/21 13:04 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/15/21 13:04 96-12-82.0 1 Dibromochloromethane ND ug/L 07/15/21 13:04 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/15/21 13:04 106-93-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 30 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V11 Lab ID:92549145005 Collected:07/13/21 12:20 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Dibromomethane ND ug/L 07/15/21 13:04 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/15/21 13:04 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/15/21 13:04 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/15/21 13:04 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/15/21 13:04 75-71-81.0 1 1,1-Dichloroethane ND ug/L 07/15/21 13:04 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/15/21 13:04 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/15/21 13:04 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/15/21 13:04 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/15/21 13:04 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/15/21 13:04 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/15/21 13:04 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/15/21 13:04 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/15/21 13:04 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/15/21 13:04 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/15/21 13:04 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/15/21 13:04 108-20-31.0 1 Ethylbenzene ND ug/L 07/15/21 13:04 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/15/21 13:04 87-68-32.0 1 2-Hexanone ND ug/L 07/15/21 13:04 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/15/21 13:04 99-87-61.0 1 Methylene Chloride ND ug/L 07/15/21 13:04 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/21 13:04 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/15/21 13:04 1634-04-41.0 1 Naphthalene ND ug/L 07/15/21 13:04 91-20-31.0 1 Styrene ND ug/L 07/15/21 13:04 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/15/21 13:04 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/15/21 13:04 79-34-51.0 1 Tetrachloroethene ND ug/L 07/15/21 13:04 127-18-41.0 1 Toluene ND ug/L 07/15/21 13:04 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/15/21 13:04 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/15/21 13:04 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/15/21 13:04 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/15/21 13:04 79-00-51.0 1 Trichloroethene ND ug/L 07/15/21 13:04 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/15/21 13:04 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/15/21 13:04 96-18-41.0 1 Vinyl acetate ND ug/L 07/15/21 13:04 108-05-42.0 1 Vinyl chloride ND ug/L 07/15/21 13:04 75-01-41.0 1 Xylene (Total)ND ug/L 07/15/21 13:04 1330-20-71.0 1 m&p-Xylene ND ug/L 07/15/21 13:04 179601-23-12.0 1 o-Xylene ND ug/L 07/15/21 13:04 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)102 %07/15/21 13:04 460-00-470-130 1 1,2-Dichloroethane-d4 (S)107 %07/15/21 13:04 17060-07-070-130 1 Toluene-d8 (S)105 %07/15/21 13:04 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 31 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Q06V11 Lab ID:92549145005 Collected:07/13/21 12:20 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 8260D MSV SIM 1,4-Dioxane (p-Dioxane)ND ug/L 07/15/21 20:30 123-91-12.0 1 Surrogates 1,2-Dichloroethane-d4 (S)98 %07/15/21 20:30 17060-07-070-130 1 Toluene-d8 (S)99 %07/15/21 20:30 2037-26-566-133 1 Analytical Method: SM 2320B-2011 Pace Analytical Services - Asheville 2320B Alkalinity Alkalinity, Total as CaCO3 24.5 mg/L 07/16/21 16:375.0 1 Analytical Method: SM 2540C-2011 Pace Analytical Services - Asheville 2540C Total Dissolved Solids Total Dissolved Solids 40.0 mg/L 07/17/21 13:1625.0 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville 300.0 IC Anions 28 Days Sulfate 3.5 mg/L 07/22/21 02:23 14808-79-81.0 1 Analytical Method: SM 4500-Cl-E-2011 Pace Analytical Services - Asheville 4500 Chloride Chloride 1.6 mg/L 07/20/21 11:41 16887-00-61.0 1 Analytical Method: SM 5310B-2011 Pace Analytical Services - Asheville 5310B TOC Total Organic Carbon ND mg/L 07/21/21 19:57 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 32 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:WQ0013419-Field Blank Lab ID:92549145006 Collected:07/13/21 13:05 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 1631E Preparation Method: EPA 1631E Pace Analytical Services - Asheville 1631E Mercury,Low Level Mercury 0.334J ng/L 07/26/21 12:00 7439-97-607/20/21 21:230.50 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 33 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:Trip Blank Lab ID:92549145007 Collected:07/13/21 00:00 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Acetone ND ug/L 07/15/21 12:29 67-64-125.0 1 Benzene ND ug/L 07/15/21 12:29 71-43-21.0 1 Bromobenzene ND ug/L 07/15/21 12:29 108-86-11.0 1 Bromochloromethane ND ug/L 07/15/21 12:29 74-97-51.0 1 Bromodichloromethane ND ug/L 07/15/21 12:29 75-27-41.0 1 Bromoform ND ug/L 07/15/21 12:29 75-25-21.0 1 Bromomethane ND ug/L 07/15/21 12:29 74-83-92.0 1 2-Butanone (MEK)ND ug/L 07/15/21 12:29 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/15/21 12:29 56-23-51.0 1 Chlorobenzene ND ug/L 07/15/21 12:29 108-90-71.0 1 Chloroethane ND ug/L 07/15/21 12:29 75-00-31.0 1 Chloroform ND ug/L 07/15/21 12:29 67-66-31.0 1 Chloromethane ND ug/L 07/15/21 12:29 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/15/21 12:29 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/15/21 12:29 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/15/21 12:29 96-12-82.0 1 Dibromochloromethane ND ug/L 07/15/21 12:29 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/15/21 12:29 106-93-41.0 1 Dibromomethane ND ug/L 07/15/21 12:29 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/15/21 12:29 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/15/21 12:29 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/15/21 12:29 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/15/21 12:29 75-71-81.0 1 1,1-Dichloroethane ND ug/L 07/15/21 12:29 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/15/21 12:29 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/15/21 12:29 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/15/21 12:29 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/15/21 12:29 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/15/21 12:29 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/15/21 12:29 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/15/21 12:29 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/15/21 12:29 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/15/21 12:29 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/15/21 12:29 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/15/21 12:29 108-20-31.0 1 Ethylbenzene ND ug/L 07/15/21 12:29 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/15/21 12:29 87-68-32.0 1 2-Hexanone ND ug/L 07/15/21 12:29 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/15/21 12:29 99-87-61.0 1 Methylene Chloride ND ug/L 07/15/21 12:29 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/21 12:29 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/15/21 12:29 1634-04-41.0 1 Naphthalene ND ug/L 07/15/21 12:29 91-20-31.0 1 Styrene ND ug/L 07/15/21 12:29 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/15/21 12:29 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/15/21 12:29 79-34-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 34 of 106 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Sample:Trip Blank Lab ID:92549145007 Collected:07/13/21 00:00 Received:07/13/21 17:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualPQL Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Landfill Tetrachloroethene ND ug/L 07/15/21 12:29 127-18-41.0 1 Toluene ND ug/L 07/15/21 12:29 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/15/21 12:29 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/15/21 12:29 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/15/21 12:29 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/15/21 12:29 79-00-51.0 1 Trichloroethene ND ug/L 07/15/21 12:29 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/15/21 12:29 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/15/21 12:29 96-18-41.0 1 Vinyl acetate ND ug/L 07/15/21 12:29 108-05-42.0 1 Vinyl chloride ND ug/L 07/15/21 12:29 75-01-41.0 1 Xylene (Total)ND ug/L 07/15/21 12:29 1330-20-71.0 1 m&p-Xylene ND ug/L 07/15/21 12:29 179601-23-12.0 1 o-Xylene ND ug/L 07/15/21 12:29 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)101 %07/15/21 12:29 460-00-470-130 1 1,2-Dichloroethane-d4 (S)104 %07/15/21 12:29 17060-07-070-130 1 Toluene-d8 (S)106 %07/15/21 12:29 2037-26-570-130 1 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 8260D MSV SIM 1,4-Dioxane (p-Dioxane)ND ug/L 07/15/21 13:31 123-91-12.0 1 Surrogates 1,2-Dichloroethane-d4 (S)95 %07/15/21 13:31 17060-07-070-130 1 Toluene-d8 (S)99 %07/15/21 13:31 2037-26-566-133 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 35 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633945 EPA 1631E EPA 1631E 1631E Mercury,Low Level Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145001, 92549145002, 92549145003, 92549145004, 92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3329637 Associated Lab Samples:92549145001, 92549145002, 92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Mercury ng/L ND 0.50 07/21/21 16:39 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3329638 Associated Lab Samples:92549145001, 92549145002, 92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Mercury ng/L ND 0.50 07/21/21 17:10 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3329639 Associated Lab Samples:92549145001, 92549145002, 92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Mercury ng/L ND 0.50 07/21/21 18:28 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3329640LABORATORY CONTROL SAMPLE: LCSSpike Mercury ng/L 5.165 103 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 3329641MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549148001 3329642 MSD Result MSD % Rec RPD MSDMS Spike Conc. Mercury ng/L 25 93 71-12593 0250.296J 23.6 23.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 36 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 634548 EPA 1631E EPA 1631E 1631E Mercury,Low Level Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3332341 Associated Lab Samples:92549145006 Matrix:Water Analyzed Mercury ng/L ND 0.50 07/26/21 11:45 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3332342 Associated Lab Samples:92549145006 Matrix:Water Analyzed Mercury ng/L ND 0.50 07/22/21 12:41 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3332343 Associated Lab Samples:92549145006 Matrix:Water Analyzed Mercury ng/L ND 0.50 07/22/21 14:37 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3332344LABORATORY CONTROL SAMPLE: LCSSpike Mercury ng/L 5.555 111 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 3332345MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549218004 3332346 MSD Result MSD % Rec RPD MSDMS Spike Conc. Mercury ng/L 250 91 71-12592 2250ND228232 Parameter Units MS Result % Rec Limits Qual% RecConc. 3332347MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549965009 3332348 MSD Result MSD % Rec RPD MSDMS Spike Conc. Mercury ng/L 250 86 71-12588 2250ND218222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 37 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 635293 EPA 3010A EPA 6010D 6010 MET Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145001, 92549145002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3336041 Associated Lab Samples:92549145001, 92549145002 Matrix:Water Analyzed Antimony ug/L ND 5.0 07/23/21 04:19 Arsenic ug/L 4.8J 10.0 07/23/21 04:19 Barium ug/L ND 5.0 07/23/21 04:19 Cadmium ug/L ND 1.0 07/23/21 04:19 Calcium ug/L ND 100 07/23/21 04:19 Chromium ug/L ND 5.0 07/23/21 04:19 Cobalt ug/L ND 5.0 07/23/21 04:19 Copper ug/L ND 5.0 07/23/21 04:19 Lead ug/L ND 5.0 07/23/21 04:19 Magnesium ug/L ND 100 07/23/21 04:19 Nickel ug/L ND 5.0 07/23/21 04:19 Potassium ug/L ND 5000 07/23/21 04:19 Selenium ug/L ND 10.0 07/23/21 04:19 Silver ug/L ND 5.0 07/23/21 04:19 Sodium ug/L ND 5000 07/23/21 04:19 Thallium ug/L ND 10.0 07/23/21 04:19 Vanadium ug/L ND 5.0 07/23/21 04:19 Zinc ug/L ND 10.0 07/23/21 04:19 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3336042LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 507500 101 80-120 Arsenic ug/L 507500 101 80-120 Barium ug/L 491500 98 80-120 Cadmium ug/L 507500 101 80-120 Calcium ug/L 47405000 95 80-120 Chromium ug/L 508500 102 80-120 Cobalt ug/L 494500 99 80-120 Copper ug/L 515500 103 80-120 Lead ug/L 500500 100 80-120 Magnesium ug/L 51405000 103 80-120 Nickel ug/L 515500 103 80-120 Potassium ug/L 5000J5000 100 80-120 Selenium ug/L 496500 99 80-120 Silver ug/L 246250 98 80-120 Sodium ug/L 50705000 101 80-120 Thallium ug/L 511500 102 80-120 Vanadium ug/L 511500 102 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 38 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3336042LABORATORY CONTROL SAMPLE: LCSSpike Zinc ug/L 490500 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 3336043MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549106001 3336044 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 101 75-125100 1500ND505498 Arsenic ug/L 500 104 75-125103 1500ND519514 Barium ug/L 500 100 75-125100 05008.7 507 507 Cadmium ug/L 500 102 75-125102 1500ND513509 Calcium ug/L 5000 97 75-12597 0500089457305740 Chromium ug/L 500 104 75-125104 0500ND519519 Cobalt ug/L 500 98 75-12597 1500ND490485 Copper ug/L 500 103 75-125103 0500ND515516 Lead ug/L 500 99 75-12598 1500ND495491 Magnesium ug/L 5000 104 75-125104 0500038456005590 Nickel ug/L 500 102 75-125101 1500ND512507 Potassium ug/L 5000 102 75-125102 05000ND55905570 Selenium ug/L 500 106 75-125104 1500ND528521 Silver ug/L 250 99 75-125100 1250ND248250 Sodium ug/L 5000 103 75-125103 050001130J62806260 Thallium ug/L 500 100 75-12599 1500ND500494 Vanadium ug/L 500 103 75-125103 0500ND516515 Zinc ug/L 500 100 75-12598 1500ND499494 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 39 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 635491 EPA 3010A EPA 6010D 6010 MET Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145003, 92549145004, 92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3336916 Associated Lab Samples:92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Antimony ug/L ND 5.0 07/25/21 20:17 Arsenic ug/L ND 10.0 07/25/21 20:17 Barium ug/L ND 5.0 07/25/21 20:17 Cadmium ug/L ND 1.0 07/25/21 20:17 Calcium ug/L ND 100 07/25/21 20:17 Chromium ug/L ND 5.0 07/25/21 20:17 Cobalt ug/L ND 5.0 07/25/21 20:17 Copper ug/L ND 5.0 07/25/21 20:17 Lead ug/L ND 5.0 07/25/21 20:17 Magnesium ug/L ND 100 07/25/21 20:17 Nickel ug/L ND 5.0 07/25/21 20:17 Potassium ug/L ND 5000 07/25/21 20:17 Selenium ug/L ND 10.0 07/25/21 20:17 Silver ug/L ND 5.0 07/25/21 20:17 Sodium ug/L ND 5000 07/25/21 20:17 Thallium ug/L ND 10.0 07/25/21 20:17 Vanadium ug/L ND 5.0 07/25/21 20:17 Zinc ug/L ND 10.0 07/25/21 20:17 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3336917LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 486500 97 80-120 Arsenic ug/L 475500 95 80-120 Barium ug/L 473500 95 80-120 Cadmium ug/L 480500 96 80-120 Calcium ug/L 46405000 93 80-120 Chromium ug/L 473500 95 80-120 Cobalt ug/L 468500 94 80-120 Copper ug/L 496500 99 80-120 Lead ug/L 475500 95 80-120 Magnesium ug/L 47605000 95 80-120 Nickel ug/L 482500 96 80-120 Potassium ug/L 4800J5000 96 80-120 Selenium ug/L 481500 96 80-120 Silver ug/L 238250 95 80-120 Sodium ug/L 4860J5000 97 80-120 Thallium ug/L 479500 96 80-120 Vanadium ug/L 481500 96 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 40 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3336917LABORATORY CONTROL SAMPLE: LCSSpike Zinc ug/L 468500 94 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 3336918MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549106005 3336919 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 98 75-12599 1500ND489493 Arsenic ug/L 500 96 75-12596 0500ND478480 Barium ug/L 500 92 75-12594 2500104563573 Cadmium ug/L 500 98 75-12598 0500ND488489 Calcium ug/L M150005375-12554 05000521005470054800 Chromium ug/L 500 95 75-12595 1500ND474477 Cobalt ug/L 500 92 75-12593 0500ND463466 Copper ug/L 500 98 75-12599 1500ND491496 Lead ug/L 500 93 75-12594 15005.3 472 476 Magnesium ug/L 5000 92 75-12591 1500066401120011200 Nickel ug/L 500 95 75-12595 0500ND474474 Potassium ug/L 5000 96 75-12596 050003780J85608560 Selenium ug/L 500 100 75-125100 0500ND498500 Silver ug/L 250 99 75-12598 1250ND248246 Sodium ug/L 5000 96 75-12597 150001620J64306490 Thallium ug/L 500 94 75-12594 0500ND473471 Vanadium ug/L 500 96 75-12597 0500ND482484 Zinc ug/L 500 94 75-12594 1500ND473475 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 41 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633353 EPA 8260D EPA 8260D 8260D MSV Low Level Landfill Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92549145001, 92549145002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3326713 Associated Lab Samples:92549145001, 92549145002 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 07/14/21 19:33 1,1,1-Trichloroethane ug/L ND 1.0 07/14/21 19:33 1,1,2,2-Tetrachloroethane ug/L ND 1.0 07/14/21 19:33 1,1,2-Trichloroethane ug/L ND 1.0 07/14/21 19:33 1,1-Dichloroethane ug/L ND 1.0 07/14/21 19:33 1,1-Dichloroethene ug/L ND 1.0 07/14/21 19:33 1,1-Dichloropropene ug/L ND 1.0 07/14/21 19:33 1,2,3-Trichlorobenzene ug/L ND 1.0 07/14/21 19:33 1,2,3-Trichloropropane ug/L ND 1.0 07/14/21 19:33 1,2,4-Trichlorobenzene ug/L ND 1.0 07/14/21 19:33 1,2-Dibromo-3-chloropropane ug/L ND 2.0 07/14/21 19:33 1,2-Dibromoethane (EDB)ug/L ND 1.0 07/14/21 19:33 1,2-Dichlorobenzene ug/L ND 1.0 07/14/21 19:33 1,2-Dichloroethane ug/L ND 1.0 07/14/21 19:33 1,2-Dichloropropane ug/L ND 1.0 07/14/21 19:33 1,3-Dichlorobenzene ug/L ND 1.0 07/14/21 19:33 1,3-Dichloropropane ug/L ND 1.0 07/14/21 19:33 1,4-Dichlorobenzene ug/L ND 1.0 07/14/21 19:33 2,2-Dichloropropane ug/L ND 1.0 07/14/21 19:33 2-Butanone (MEK)ug/L ND 5.0 07/14/21 19:33 2-Chlorotoluene ug/L ND 1.0 07/14/21 19:33 2-Hexanone ug/L ND 5.0 07/14/21 19:33 4-Chlorotoluene ug/L ND 1.0 07/14/21 19:33 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 07/14/21 19:33 Acetone ug/L ND 25.0 07/14/21 19:33 Benzene ug/L ND 1.0 07/14/21 19:33 Bromobenzene ug/L ND 1.0 07/14/21 19:33 Bromochloromethane ug/L ND 1.0 07/14/21 19:33 Bromodichloromethane ug/L ND 1.0 07/14/21 19:33 Bromoform ug/L ND 1.0 07/14/21 19:33 Bromomethane ug/L ND 2.0 07/14/21 19:33 Carbon tetrachloride ug/L ND 1.0 07/14/21 19:33 Chlorobenzene ug/L ND 1.0 07/14/21 19:33 Chloroethane ug/L ND 1.0 07/14/21 19:33 Chloroform ug/L ND 1.0 07/14/21 19:33 Chloromethane ug/L ND 1.0 07/14/21 19:33 cis-1,2-Dichloroethene ug/L ND 1.0 07/14/21 19:33 cis-1,3-Dichloropropene ug/L ND 1.0 07/14/21 19:33 Dibromochloromethane ug/L ND 1.0 07/14/21 19:33 Dibromomethane ug/L ND 1.0 07/14/21 19:33 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 42 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3326713 Associated Lab Samples:92549145001, 92549145002 Matrix:Water Analyzed Dichlorodifluoromethane ug/L ND 1.0 07/14/21 19:33 Diisopropyl ether ug/L ND 1.0 07/14/21 19:33 Ethylbenzene ug/L ND 1.0 07/14/21 19:33 Hexachloro-1,3-butadiene ug/L ND 2.0 07/14/21 19:33 m&p-Xylene ug/L ND 2.0 07/14/21 19:33 Methyl-tert-butyl ether ug/L ND 1.0 07/14/21 19:33 Methylene Chloride ug/L 2.1J 5.0 07/14/21 19:33 Naphthalene ug/L ND 1.0 07/14/21 19:33 o-Xylene ug/L ND 1.0 07/14/21 19:33 p-Isopropyltoluene ug/L ND 1.0 07/14/21 19:33 Styrene ug/L ND 1.0 07/14/21 19:33 Tetrachloroethene ug/L ND 1.0 07/14/21 19:33 Toluene ug/L ND 1.0 07/14/21 19:33 trans-1,2-Dichloroethene ug/L ND 1.0 07/14/21 19:33 trans-1,3-Dichloropropene ug/L ND 1.0 07/14/21 19:33 Trichloroethene ug/L ND 1.0 07/14/21 19:33 Trichlorofluoromethane ug/L ND 1.0 07/14/21 19:33 Vinyl acetate ug/L ND 2.0 07/14/21 19:33 Vinyl chloride ug/L ND 1.0 07/14/21 19:33 Xylene (Total)ug/L ND 1.0 07/14/21 19:33 1,2-Dichloroethane-d4 (S)%107 70-130 07/14/21 19:33 4-Bromofluorobenzene (S)%103 70-130 07/14/21 19:33 Toluene-d8 (S)%99 70-130 07/14/21 19:33 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3326714LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 51.750 103 70-130 1,1,1-Trichloroethane ug/L 52.250 104 70-130 1,1,2,2-Tetrachloroethane ug/L 51.250 102 70-130 1,1,2-Trichloroethane ug/L 51.650 103 70-130 1,1-Dichloroethane ug/L 50.250 100 70-130 1,1-Dichloroethene ug/L 50.450 101 70-132 1,1-Dichloropropene ug/L 48.450 97 70-131 1,2,3-Trichlorobenzene ug/L 55.650 111 70-134 1,2,3-Trichloropropane ug/L 50.350 101 70-130 1,2,4-Trichlorobenzene ug/L 55.450 111 70-130 1,2-Dibromo-3-chloropropane ug/L 51.950 104 70-132 1,2-Dibromoethane (EDB)ug/L 50.850 102 70-130 1,2-Dichlorobenzene ug/L 52.450 105 70-130 1,2-Dichloroethane ug/L 47.350 95 70-130 1,2-Dichloropropane ug/L 50.950 102 70-130 1,3-Dichlorobenzene ug/L 52.450 105 70-130 1,3-Dichloropropane ug/L 49.050 98 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 43 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3326714LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dichlorobenzene ug/L 52.450 105 70-130 2,2-Dichloropropane ug/L 52.550 105 70-130 2-Butanone (MEK)ug/L 102100 102 70-133 2-Chlorotoluene ug/L 51.150 102 70-130 2-Hexanone ug/L 108100 108 70-130 4-Chlorotoluene ug/L 49.650 99 70-130 4-Methyl-2-pentanone (MIBK)ug/L 108100 108 70-130 Acetone ug/L 108100 108 70-144 Benzene ug/L 49.850 100 70-130 Bromobenzene ug/L 50.850 102 70-130 Bromochloromethane ug/L 48.950 98 70-130 Bromodichloromethane ug/L 51.350 103 70-130 Bromoform ug/L 51.250 102 70-131 Bromomethane ug/L 44.450 89 30-177 Carbon tetrachloride ug/L 53.250 106 70-130 Chlorobenzene ug/L 50.550 101 70-130 Chloroethane ug/L 48.350 97 46-131 Chloroform ug/L 50.050 100 70-130 Chloromethane ug/L 47.850 96 49-130 cis-1,2-Dichloroethene ug/L 48.550 97 70-130 cis-1,3-Dichloropropene ug/L 51.150 102 70-130 Dibromochloromethane ug/L 52.450 105 70-130 Dibromomethane ug/L 52.050 104 70-130 Dichlorodifluoromethane ug/L 58.650 117 52-134 Diisopropyl ether ug/L 47.750 95 70-131 Ethylbenzene ug/L 50.650 101 70-130 Hexachloro-1,3-butadiene ug/L 57.150 114 70-131 m&p-Xylene ug/L 102100 102 70-130 Methyl-tert-butyl ether ug/L 47.650 95 70-130 Methylene Chloride ug/L 50.350 101 68-130 Naphthalene ug/L 54.950 110 70-133 o-Xylene ug/L 50.950 102 70-130 p-Isopropyltoluene ug/L 52.850 106 70-130 Styrene ug/L 52.350 105 70-130 Tetrachloroethene ug/L 50.250 100 70-130 Toluene ug/L 51.250 102 70-130 trans-1,2-Dichloroethene ug/L 50.350 101 70-130 trans-1,3-Dichloropropene ug/L 51.450 103 70-130 Trichloroethene ug/L 50.150 100 70-130 Trichlorofluoromethane ug/L 59.050 118 61-130 Vinyl acetate ug/L 109100 109 70-140 Vinyl chloride ug/L 50.050 100 59-142 Xylene (Total)ug/L 153150 102 70-130 1,2-Dichloroethane-d4 (S)%96 70-130 4-Bromofluorobenzene (S)%99 70-130 Toluene-d8 (S)%100 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 44 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3326715MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549106001 3326716 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 121 70-135114 620ND24.2 22.8 1,1,1-Trichloroethane ug/L 20 127 70-148108 1620ND25.5 21.7 1,1,2,2-Tetrachloroethane ug/L 20 122 70-131111 1020ND24.4 22.1 1,1,2-Trichloroethane ug/L 20 122 70-136109 1120ND24.4 21.8 1,1-Dichloroethane ug/L 20 119 70-147108 1020ND23.7 21.5 1,1-Dichloroethene ug/L 20 129 70-158108 1820ND25.9 21.7 1,1-Dichloropropene ug/L 20 125 70-149109 1420ND24.9 21.7 1,2,3-Trichlorobenzene ug/L 20 112 68-140106 520ND22.4 21.2 1,2,3-Trichloropropane ug/L 20 118 67-137108 920ND23.6 21.6 1,2,4-Trichlorobenzene ug/L 20 113 70-139106 620ND22.7 21.2 1,2-Dibromo-3-chloropropane ug/L 20 130 69-136120 820ND26.0 24.0 1,2-Dibromoethane (EDB)ug/L 20 118 70-137109 820ND23.6 21.8 1,2-Dichlorobenzene ug/L 20 115 70-133109 520ND23.0 21.8 1,2-Dichloroethane ug/L 20 112 67-13899 1220ND22.4 19.8 1,2-Dichloropropane ug/L 20 124 70-138110 1120ND24.8 22.1 1,3-Dichlorobenzene ug/L 20 113 70-133108 520ND22.7 21.6 1,3-Dichloropropane ug/L 20 117 70-136110 620ND23.5 22.0 1,4-Dichlorobenzene ug/L 20 111 70-133107 420ND22.2 21.4 2,2-Dichloropropane ug/L 20 117 52-155102 1420ND23.5 20.4 2-Butanone (MEK)ug/L 40 122 61-147109 1140ND48.6 43.7 2-Chlorotoluene ug/L 20 112 70-141107 420ND22.3 21.4 2-Hexanone ug/L 40 121 67-139109 1040ND48.5 43.8 4-Chlorotoluene ug/L 20 108 70-135101 620ND21.6 20.3 4-Methyl-2-pentanone (MIBK)ug/L 40 121 67-136108 1140ND48.4 43.1 Acetone ug/L 40 119 55-15996 2140ND47.6 38.6 Benzene ug/L 20 107 67-150108 120ND21.4 21.5 Bromobenzene ug/L 20 118 70-134110 720ND23.7 22.0 Bromochloromethane ug/L 20 124 70-146106 1620ND24.8 21.1 Bromodichloromethane ug/L 20 122 70-138109 1120ND24.4 21.8 Bromoform ug/L 20 121 57-138111 920ND24.2 22.2 Bromomethane ug/L 20 129 10-200112 1420ND25.8 22.4 Carbon tetrachloride ug/L 20 126 70-147115 920ND25.2 23.0 Chlorobenzene ug/L 20 116 70-137110 620ND23.2 21.9 Chloroethane ug/L 20 144 51-166127 1320ND28.8 25.4 Chloroform ug/L 20 124 70-144105 1720ND24.9 21.1 Chloromethane ug/L 20 118 24-16196 2020ND23.5 19.2 cis-1,2-Dichloroethene ug/L 20 125 67-148105 1820ND25.1 21.0 cis-1,3-Dichloropropene ug/L 20 123 70-142108 1320ND24.6 21.6 Dibromochloromethane ug/L 20 119 68-138111 720ND23.9 22.2 Dibromomethane ug/L 20 125 70-134116 820ND25.0 23.2 Dichlorodifluoromethane ug/L 20 120 43-155104 1520ND24.1 20.8 Diisopropyl ether ug/L 20 115 65-14699 1520ND23.0 19.8 Ethylbenzene ug/L 20 115 68-143108 620ND22.9 21.6 Hexachloro-1,3-butadiene ug/L 20 113 62-151109 320ND22.6 21.8 m&p-Xylene ug/L 40 114 53-157107 740ND45.5 42.6 Methyl-tert-butyl ether ug/L 20 114 59-15695 1820ND22.8 19.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 45 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3326715MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549106001 3326716 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L M1207164-14853 2920ND14.1 10.6 Naphthalene ug/L 20 118 57-150111 720ND23.7 22.1 o-Xylene ug/L 20 113 68-143107 620ND22.6 21.4 p-Isopropyltoluene ug/L 20 113 70-141106 620ND22.6 21.3 Styrene ug/L 20 117 70-136107 920ND23.3 21.4 Tetrachloroethene ug/L 20 110 70-139108 220ND22.0 21.6 Toluene ug/L 20 117 47-157107 920ND23.4 21.3 trans-1,2-Dichloroethene ug/L 20 118 70-149106 1120ND23.7 21.2 trans-1,3-Dichloropropene ug/L 20 119 70-138107 1120ND23.8 21.4 Trichloroethene ug/L 20 117 70-149111 620ND23.5 22.2 Trichlorofluoromethane ug/L 20 117 61-154101 1520ND23.5 20.1 Vinyl acetate ug/L 40 114 48-15698 1540ND45.4 39.2 Vinyl chloride ug/L 20 125 55-172107 1620ND25.0 21.3 Xylene (Total)ug/L 60 114 66-145107 660ND68.1 64.0 1,2-Dichloroethane-d4 (S)%95 70-13093 4-Bromofluorobenzene (S)%101 70-130100 Toluene-d8 (S)%103 70-130100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 46 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633616 EPA 8260D EPA 8260D 8260D MSV Low Level Landfill Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92549145003, 92549145004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3327966 Associated Lab Samples:92549145003, 92549145004 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 07/16/21 11:43 1,1,1-Trichloroethane ug/L ND 1.0 07/16/21 11:43 1,1,2,2-Tetrachloroethane ug/L ND 1.0 07/16/21 11:43 1,1,2-Trichloroethane ug/L ND 1.0 07/16/21 11:43 1,1-Dichloroethane ug/L ND 1.0 07/16/21 11:43 1,1-Dichloroethene ug/L ND 1.0 07/16/21 11:43 1,1-Dichloropropene ug/L ND 1.0 07/16/21 11:43 1,2,3-Trichlorobenzene ug/L ND 1.0 07/16/21 11:43 1,2,3-Trichloropropane ug/L ND 1.0 07/16/21 11:43 1,2,4-Trichlorobenzene ug/L ND 1.0 07/16/21 11:43 1,2-Dibromo-3-chloropropane ug/L ND 2.0 07/16/21 11:43 1,2-Dibromoethane (EDB)ug/L ND 1.0 07/16/21 11:43 1,2-Dichlorobenzene ug/L ND 1.0 07/16/21 11:43 1,2-Dichloroethane ug/L ND 1.0 07/16/21 11:43 1,2-Dichloropropane ug/L ND 1.0 07/16/21 11:43 1,3-Dichlorobenzene ug/L ND 1.0 07/16/21 11:43 1,3-Dichloropropane ug/L ND 1.0 07/16/21 11:43 1,4-Dichlorobenzene ug/L ND 1.0 07/16/21 11:43 2,2-Dichloropropane ug/L ND 1.0 07/16/21 11:43 2-Butanone (MEK)ug/L ND 5.0 07/16/21 11:43 2-Chlorotoluene ug/L ND 1.0 07/16/21 11:43 2-Hexanone ug/L ND 5.0 07/16/21 11:43 4-Chlorotoluene ug/L ND 1.0 07/16/21 11:43 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 07/16/21 11:43 Acetone ug/L ND 25.0 07/16/21 11:43 Benzene ug/L ND 1.0 07/16/21 11:43 Bromobenzene ug/L ND 1.0 07/16/21 11:43 Bromochloromethane ug/L ND 1.0 07/16/21 11:43 Bromodichloromethane ug/L ND 1.0 07/16/21 11:43 Bromoform ug/L ND 1.0 07/16/21 11:43 Bromomethane ug/L ND 2.0 IH,IK,v107/16/21 11:43 Carbon tetrachloride ug/L ND 1.0 07/16/21 11:43 Chlorobenzene ug/L ND 1.0 07/16/21 11:43 Chloroethane ug/L ND 1.0 07/16/21 11:43 Chloroform ug/L ND 1.0 07/16/21 11:43 Chloromethane ug/L ND 1.0 07/16/21 11:43 cis-1,2-Dichloroethene ug/L ND 1.0 07/16/21 11:43 cis-1,3-Dichloropropene ug/L ND 1.0 07/16/21 11:43 Dibromochloromethane ug/L ND 1.0 07/16/21 11:43 Dibromomethane ug/L ND 1.0 07/16/21 11:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 47 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3327966 Associated Lab Samples:92549145003, 92549145004 Matrix:Water Analyzed Dichlorodifluoromethane ug/L ND 1.0 07/16/21 11:43 Diisopropyl ether ug/L ND 1.0 07/16/21 11:43 Ethylbenzene ug/L ND 1.0 07/16/21 11:43 Hexachloro-1,3-butadiene ug/L ND 2.0 07/16/21 11:43 m&p-Xylene ug/L ND 2.0 07/16/21 11:43 Methyl-tert-butyl ether ug/L ND 1.0 07/16/21 11:43 Methylene Chloride ug/L ND 5.0 07/16/21 11:43 Naphthalene ug/L ND 1.0 07/16/21 11:43 o-Xylene ug/L ND 1.0 07/16/21 11:43 p-Isopropyltoluene ug/L ND 1.0 07/16/21 11:43 Styrene ug/L ND 1.0 07/16/21 11:43 Tetrachloroethene ug/L ND 1.0 07/16/21 11:43 Toluene ug/L ND 1.0 07/16/21 11:43 trans-1,2-Dichloroethene ug/L ND 1.0 07/16/21 11:43 trans-1,3-Dichloropropene ug/L ND 1.0 07/16/21 11:43 Trichloroethene ug/L ND 1.0 07/16/21 11:43 Trichlorofluoromethane ug/L ND 1.0 07/16/21 11:43 Vinyl acetate ug/L ND 2.0 07/16/21 11:43 Vinyl chloride ug/L ND 1.0 07/16/21 11:43 Xylene (Total)ug/L ND 1.0 07/16/21 11:43 1,2-Dichloroethane-d4 (S)%99 70-130 07/16/21 11:43 4-Bromofluorobenzene (S)%99 70-130 07/16/21 11:43 Toluene-d8 (S)%101 70-130 07/16/21 11:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3327967LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 51.150 102 70-130 1,1,1-Trichloroethane ug/L 50.550 101 70-130 1,1,2,2-Tetrachloroethane ug/L 49.450 99 70-130 1,1,2-Trichloroethane ug/L 50.550 101 70-130 1,1-Dichloroethane ug/L 50.150 100 70-130 1,1-Dichloroethene ug/L 48.350 97 70-132 1,1-Dichloropropene ug/L 49.850 100 70-131 1,2,3-Trichlorobenzene ug/L 47.250 94 70-134 1,2,3-Trichloropropane ug/L 48.650 97 70-130 1,2,4-Trichlorobenzene ug/L 46.450 93 70-130 1,2-Dibromo-3-chloropropane ug/L 52.150 104 70-132 1,2-Dibromoethane (EDB)ug/L 49.350 99 70-130 1,2-Dichlorobenzene ug/L 45.250 90 70-130 1,2-Dichloroethane ug/L 46.850 94 70-130 1,2-Dichloropropane ug/L 48.250 96 70-130 1,3-Dichlorobenzene ug/L 44.050 88 70-130 1,3-Dichloropropane ug/L 49.250 98 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 48 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3327967LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dichlorobenzene ug/L 44.750 89 70-130 2,2-Dichloropropane ug/L 51.750 103 70-130 2-Butanone (MEK)ug/L 105100 105 70-133 2-Chlorotoluene ug/L 45.150 90 70-130 2-Hexanone ug/L 102100 102 70-130 4-Chlorotoluene ug/L 43.750 87 70-130 4-Methyl-2-pentanone (MIBK)ug/L 101100 101 70-130 Acetone ug/L 100100 100 70-144 Benzene ug/L 48.450 97 70-130 Bromobenzene ug/L 48.050 96 70-130 Bromochloromethane ug/L 53.450 107 70-130 Bromodichloromethane ug/L 50.150 100 70-130 Bromoform ug/L 57.350 115 70-131 Bromomethane ug/L 71.3 IH,IK,v15014330-177 Carbon tetrachloride ug/L 50.250 100 70-130 Chlorobenzene ug/L 48.950 98 70-130 Chloroethane ug/L 55.050 110 46-131 Chloroform ug/L 50.850 102 70-130 Chloromethane ug/L 53.750 107 49-130 cis-1,2-Dichloroethene ug/L 48.750 97 70-130 cis-1,3-Dichloropropene ug/L 53.150 106 70-130 Dibromochloromethane ug/L 54.450 109 70-130 Dibromomethane ug/L 49.050 98 70-130 Dichlorodifluoromethane ug/L 43.650 87 52-134 Diisopropyl ether ug/L 50.350 101 70-131 Ethylbenzene ug/L 47.150 94 70-130 Hexachloro-1,3-butadiene ug/L 46.250 92 70-131 m&p-Xylene ug/L 92.2100 92 70-130 Methyl-tert-butyl ether ug/L 52.750 105 70-130 Methylene Chloride ug/L 47.550 95 68-130 Naphthalene ug/L 47.950 96 70-133 o-Xylene ug/L 47.250 94 70-130 p-Isopropyltoluene ug/L 40.850 82 70-130 Styrene ug/L 49.350 99 70-130 Tetrachloroethene ug/L 47.250 94 70-130 Toluene ug/L 47.850 96 70-130 trans-1,2-Dichloroethene ug/L 49.950 100 70-130 trans-1,3-Dichloropropene ug/L 53.150 106 70-130 Trichloroethene ug/L 48.150 96 70-130 Trichlorofluoromethane ug/L 47.050 94 61-130 Vinyl acetate ug/L 113100 113 70-140 Vinyl chloride ug/L 50.550 101 59-142 Xylene (Total)ug/L 139150 93 70-130 1,2-Dichloroethane-d4 (S)%100 70-130 4-Bromofluorobenzene (S)%98 70-130 Toluene-d8 (S)%98 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 49 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3327968MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549471013 3327969 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L M12013770-135112 2020ND27.5 22.4 1,1,1-Trichloroethane ug/L M12015470-148128 1820ND30.8 25.6 1,1,2,2-Tetrachloroethane ug/L 20 130 70-131108 1820ND25.9 21.7 1,1,2-Trichloroethane ug/L M12014470-136116 2120ND28.9 23.3 1,1-Dichloroethane ug/L M12015670-147125 2220ND31.2 25.0 1,1-Dichloroethene ug/L 20 154 70-158128 1820ND30.8 25.6 1,1-Dichloropropene ug/L M12015770-149129 2020ND31.4 25.8 1,2,3-Trichlorobenzene ug/L 20 108 68-14099 920ND21.5 19.8 1,2,3-Trichloropropane ug/L 20 133 67-137111 1820ND26.5 22.2 1,2,4-Trichlorobenzene ug/L 20 107 70-13995 1220ND21.5 18.9 1,2-Dibromo-3-chloropropane ug/L M12014069-136113 2220ND28.1 22.6 1,2-Dibromoethane (EDB)ug/L 20 137 70-137111 2120ND27.5 22.2 1,2-Dichlorobenzene ug/L 20 110 70-13395 1520ND22.1 19.0 1,2-Dichloroethane ug/L M12014167-138114 2120ND28.2 22.8 1,2-Dichloropropane ug/L M12014670-138119 2020ND29.2 23.9 1,3-Dichlorobenzene ug/L 20 113 70-13393 2020ND22.5 18.5 1,3-Dichloropropane ug/L M12013770-136111 2220ND27.5 22.1 1,4-Dichlorobenzene ug/L 20 113 70-13395 1720ND22.6 19.0 2,2-Dichloropropane ug/L M12015952-155133 1820ND31.9 26.6 2-Butanone (MEK)ug/L M14014961-147121 2140ND59.6 48.2 2-Chlorotoluene ug/L 20 115 70-14197 1720ND23.0 19.4 2-Hexanone ug/L 40 133 67-139109 2040ND53.4 43.6 4-Chlorotoluene ug/L 20 112 70-13595 1620ND22.3 19.0 4-Methyl-2-pentanone (MIBK)ug/L M14013767-136112 2040ND54.7 44.6 Acetone ug/L 40 135 55-159114 1740ND54.1 45.7 Benzene ug/L 20 145 67-150121 1820ND29.0 24.2 Bromobenzene ug/L 20 125 70-134100 2220ND25.1 20.1 Bromochloromethane ug/L M12016070-146132 1920ND32.1 26.4 Bromodichloromethane ug/L M12014970-138119 2320ND29.9 23.7 Bromoform ug/L M12015557-138123 2320ND31.0 24.6 Bromomethane ug/L IH,IK,M1, v1 20 242 10-200200 1920ND48.5 40.0 Carbon tetrachloride ug/L M12015570-147124 2220ND31.1 24.9 Chlorobenzene ug/L 20 134 70-137110 1920ND26.8 22.1 Chloroethane ug/L M12017951-166152 1720ND35.9 30.4 Chloroform ug/L M12015370-144121 132023.4 54.1 47.6 Chloromethane ug/L 20 155 24-161130 1720ND30.9 26.0 cis-1,2-Dichloroethene ug/L M12015267-148126 1920ND30.4 25.1 cis-1,3-Dichloropropene ug/L M12015170-142124 2020ND30.2 24.7 Dibromochloromethane ug/L M12014568-138120 1920ND29.1 24.0 Dibromomethane ug/L M12014070-134117 1820ND28.1 23.3 Dichlorodifluoromethane ug/L 20 139 43-155114 1920ND27.7 22.8 Diisopropyl ether ug/L 20 146 65-146117 2220ND29.1 23.3 Ethylbenzene ug/L 20 129 68-143108 1820ND25.8 21.6 Hexachloro-1,3-butadiene ug/L 20 124 62-151105 1720ND24.8 20.9 m&p-Xylene ug/L 40 126 53-157106 1740ND50.3 42.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 50 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3327968MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549471013 3327969 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methyl-tert-butyl ether ug/L 20 153 59-156123 2220ND30.7 24.6 Methylene Chloride ug/L 20 143 64-148118 2020ND28.6 23.5 Naphthalene ug/L 20 104 57-15092 1220ND20.8 18.4 o-Xylene ug/L 20 131 68-143108 1920ND26.3 21.7 p-Isopropyltoluene ug/L 20 105 70-14191 1320ND20.9 18.3 Styrene ug/L 20 130 70-136106 2020ND25.9 21.3 Tetrachloroethene ug/L 20 132 70-139108 2020ND26.4 21.6 Toluene ug/L 20 139 47-157114 2020ND27.9 22.8 trans-1,2-Dichloroethene ug/L M12015570-149128 1920ND31.0 25.7 trans-1,3-Dichloropropene ug/L M12015170-138122 2120ND30.1 24.4 Trichloroethene ug/L 20 143 70-149120 1720ND28.7 24.0 Trichlorofluoromethane ug/L M12015661-154129 2020ND31.3 25.7 Vinyl acetate ug/L M14016348-156133 2140ND65.3 53.1 Vinyl chloride ug/L 20 162 55-172136 1820ND32.4 27.1 Xylene (Total)ug/L 60 128 66-145107 1860ND76.6 64.0 1,2-Dichloroethane-d4 (S)%99 70-130101 4-Bromofluorobenzene (S)%99 70-13098 Toluene-d8 (S)%99 70-13098 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 51 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633626 EPA 8260D EPA 8260D 8260D MSV Low Level Landfill Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92549145005, 92549145007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3328046 Associated Lab Samples:92549145005, 92549145007 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 07/15/21 11:54 1,1,1-Trichloroethane ug/L ND 1.0 07/15/21 11:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 07/15/21 11:54 1,1,2-Trichloroethane ug/L ND 1.0 07/15/21 11:54 1,1-Dichloroethane ug/L ND 1.0 07/15/21 11:54 1,1-Dichloroethene ug/L ND 1.0 07/15/21 11:54 1,1-Dichloropropene ug/L ND 1.0 07/15/21 11:54 1,2,3-Trichlorobenzene ug/L ND 1.0 07/15/21 11:54 1,2,3-Trichloropropane ug/L ND 1.0 07/15/21 11:54 1,2,4-Trichlorobenzene ug/L ND 1.0 07/15/21 11:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 07/15/21 11:54 1,2-Dibromoethane (EDB)ug/L ND 1.0 07/15/21 11:54 1,2-Dichlorobenzene ug/L ND 1.0 07/15/21 11:54 1,2-Dichloroethane ug/L ND 1.0 07/15/21 11:54 1,2-Dichloropropane ug/L ND 1.0 07/15/21 11:54 1,3-Dichlorobenzene ug/L ND 1.0 07/15/21 11:54 1,3-Dichloropropane ug/L ND 1.0 07/15/21 11:54 1,4-Dichlorobenzene ug/L ND 1.0 07/15/21 11:54 2,2-Dichloropropane ug/L ND 1.0 07/15/21 11:54 2-Butanone (MEK)ug/L ND 5.0 07/15/21 11:54 2-Chlorotoluene ug/L ND 1.0 07/15/21 11:54 2-Hexanone ug/L ND 5.0 07/15/21 11:54 4-Chlorotoluene ug/L ND 1.0 07/15/21 11:54 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 07/15/21 11:54 Acetone ug/L ND 25.0 07/15/21 11:54 Benzene ug/L ND 1.0 07/15/21 11:54 Bromobenzene ug/L ND 1.0 07/15/21 11:54 Bromochloromethane ug/L ND 1.0 07/15/21 11:54 Bromodichloromethane ug/L ND 1.0 07/15/21 11:54 Bromoform ug/L ND 1.0 07/15/21 11:54 Bromomethane ug/L ND 2.0 07/15/21 11:54 Carbon tetrachloride ug/L ND 1.0 07/15/21 11:54 Chlorobenzene ug/L ND 1.0 07/15/21 11:54 Chloroethane ug/L ND 1.0 07/15/21 11:54 Chloroform ug/L ND 1.0 07/15/21 11:54 Chloromethane ug/L ND 1.0 07/15/21 11:54 cis-1,2-Dichloroethene ug/L ND 1.0 07/15/21 11:54 cis-1,3-Dichloropropene ug/L ND 1.0 07/15/21 11:54 Dibromochloromethane ug/L ND 1.0 07/15/21 11:54 Dibromomethane ug/L ND 1.0 07/15/21 11:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 52 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3328046 Associated Lab Samples:92549145005, 92549145007 Matrix:Water Analyzed Dichlorodifluoromethane ug/L ND 1.0 07/15/21 11:54 Diisopropyl ether ug/L ND 1.0 07/15/21 11:54 Ethylbenzene ug/L ND 1.0 07/15/21 11:54 Hexachloro-1,3-butadiene ug/L ND 2.0 07/15/21 11:54 m&p-Xylene ug/L ND 2.0 07/15/21 11:54 Methyl-tert-butyl ether ug/L ND 1.0 07/15/21 11:54 Methylene Chloride ug/L ND 5.0 07/15/21 11:54 Naphthalene ug/L ND 1.0 07/15/21 11:54 o-Xylene ug/L ND 1.0 07/15/21 11:54 p-Isopropyltoluene ug/L ND 1.0 07/15/21 11:54 Styrene ug/L ND 1.0 07/15/21 11:54 Tetrachloroethene ug/L ND 1.0 07/15/21 11:54 Toluene ug/L ND 1.0 07/15/21 11:54 trans-1,2-Dichloroethene ug/L ND 1.0 07/15/21 11:54 trans-1,3-Dichloropropene ug/L ND 1.0 07/15/21 11:54 Trichloroethene ug/L ND 1.0 07/15/21 11:54 Trichlorofluoromethane ug/L ND 1.0 07/15/21 11:54 Vinyl acetate ug/L ND 2.0 07/15/21 11:54 Vinyl chloride ug/L ND 1.0 07/15/21 11:54 Xylene (Total)ug/L ND 1.0 07/15/21 11:54 1,2-Dichloroethane-d4 (S)%107 70-130 07/15/21 11:54 4-Bromofluorobenzene (S)%103 70-130 07/15/21 11:54 Toluene-d8 (S)%105 70-130 07/15/21 11:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3328047LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.950 102 70-130 1,1,1-Trichloroethane ug/L 52.850 106 70-130 1,1,2,2-Tetrachloroethane ug/L 49.150 98 70-130 1,1,2-Trichloroethane ug/L 49.550 99 70-130 1,1-Dichloroethane ug/L 51.450 103 70-130 1,1-Dichloroethene ug/L 52.550 105 70-132 1,1-Dichloropropene ug/L 53.750 107 70-131 1,2,3-Trichlorobenzene ug/L 49.150 98 70-134 1,2,3-Trichloropropane ug/L 45.050 90 70-130 1,2,4-Trichlorobenzene ug/L 49.750 99 70-130 1,2-Dibromo-3-chloropropane ug/L 49.450 99 70-132 1,2-Dibromoethane (EDB)ug/L 50.650 101 70-130 1,2-Dichlorobenzene ug/L 48.750 97 70-130 1,2-Dichloroethane ug/L 48.650 97 70-130 1,2-Dichloropropane ug/L 52.150 104 70-130 1,3-Dichlorobenzene ug/L 49.150 98 70-130 1,3-Dichloropropane ug/L 49.050 98 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 53 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3328047LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dichlorobenzene ug/L 49.150 98 70-130 2,2-Dichloropropane ug/L 57.750 115 70-130 2-Butanone (MEK)ug/L 95.8100 96 70-133 2-Chlorotoluene ug/L 49.950 100 70-130 2-Hexanone ug/L 93.4100 93 70-130 4-Chlorotoluene ug/L 48.150 96 70-130 4-Methyl-2-pentanone (MIBK)ug/L 98.0100 98 70-130 Acetone ug/L 101100 101 70-144 Benzene ug/L 51.950 104 70-130 Bromobenzene ug/L 48.350 97 70-130 Bromochloromethane ug/L 58.450 117 70-130 Bromodichloromethane ug/L 51.650 103 70-130 Bromoform ug/L 52.450 105 70-131 Bromomethane ug/L 46.850 94 30-177 Carbon tetrachloride ug/L 53.450 107 70-130 Chlorobenzene ug/L 47.650 95 70-130 Chloroethane ug/L 63.950 128 46-131 Chloroform ug/L 53.550 107 70-130 Chloromethane ug/L 49.650 99 49-130 cis-1,2-Dichloroethene ug/L 52.150 104 70-130 cis-1,3-Dichloropropene ug/L 54.550 109 70-130 Dibromochloromethane ug/L 52.750 105 70-130 Dibromomethane ug/L 51.850 104 70-130 Dichlorodifluoromethane ug/L 55.750 111 52-134 Diisopropyl ether ug/L 51.550 103 70-131 Ethylbenzene ug/L 48.850 98 70-130 Hexachloro-1,3-butadiene ug/L 49.750 99 70-131 m&p-Xylene ug/L 97.6100 98 70-130 Methyl-tert-butyl ether ug/L 50.950 102 70-130 Methylene Chloride ug/L 55.150 110 68-130 Naphthalene ug/L 47.450 95 70-133 o-Xylene ug/L 48.350 97 70-130 p-Isopropyltoluene ug/L 52.350 105 70-130 Styrene ug/L 49.250 98 70-130 Tetrachloroethene ug/L 49.050 98 70-130 Toluene ug/L 50.150 100 70-130 trans-1,2-Dichloroethene ug/L 52.850 106 70-130 trans-1,3-Dichloropropene ug/L 56.150 112 70-130 Trichloroethene ug/L 52.650 105 70-130 Trichlorofluoromethane ug/L 50.250 100 61-130 Vinyl acetate ug/L 117100 117 70-140 Vinyl chloride ug/L 53.950 108 59-142 Xylene (Total)ug/L 146150 97 70-130 1,2-Dichloroethane-d4 (S)%101 70-130 4-Bromofluorobenzene (S)%99 70-130 Toluene-d8 (S)%100 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 54 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3328048MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145005 3328049 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 108 70-135110 220ND21.5 22.0 1,1,1-Trichloroethane ug/L 20 121 70-148122 120ND24.1 24.4 1,1,2,2-Tetrachloroethane ug/L 20 108 70-131108 020ND21.7 21.7 1,1,2-Trichloroethane ug/L 20 113 70-136109 420ND22.7 21.9 1,1-Dichloroethane ug/L 20 123 70-147120 220ND24.6 24.0 1,1-Dichloroethene ug/L 20 124 70-158116 620ND24.8 23.2 1,1-Dichloropropene ug/L 20 128 70-149123 420ND25.7 24.7 1,2,3-Trichlorobenzene ug/L 20 101 68-140106 520ND20.2 21.3 1,2,3-Trichloropropane ug/L 20 103 67-137104 120ND20.6 20.7 1,2,4-Trichlorobenzene ug/L 20 96 70-139102 520ND19.2 20.3 1,2-Dibromo-3-chloropropane ug/L 20 116 69-136108 820ND23.3 21.5 1,2-Dibromoethane (EDB)ug/L 20 108 70-137109 120ND21.7 21.8 1,2-Dichlorobenzene ug/L 20 101 70-133101 020ND20.3 20.2 1,2-Dichloroethane ug/L 20 112 67-138114 320ND22.3 22.9 1,2-Dichloropropane ug/L 20 121 70-138119 120ND24.1 23.8 1,3-Dichlorobenzene ug/L 20 104 70-133101 220ND20.7 20.2 1,3-Dichloropropane ug/L 20 104 70-136107 320ND20.9 21.4 1,4-Dichlorobenzene ug/L 20 102 70-133104 220ND20.4 20.9 2,2-Dichloropropane ug/L 20 117 52-155121 320ND23.4 24.1 2-Butanone (MEK)ug/L 40 128 61-147128 040ND51.3 51.3 2-Chlorotoluene ug/L 20 104 70-141101 220ND20.7 20.2 2-Hexanone ug/L 40 111 67-139113 140ND44.5 45.0 4-Chlorotoluene ug/L 20 102 70-135101 120ND20.4 20.2 4-Methyl-2-pentanone (MIBK)ug/L 40 120 67-136115 440ND47.8 46.1 Acetone ug/L 40 135 55-159132 340ND54.0 52.6 Benzene ug/L 20 119 67-150118 120ND23.9 23.5 Bromobenzene ug/L 20 106 70-134102 320ND21.2 20.5 Bromochloromethane ug/L 20 125 70-146132 620ND25.0 26.4 Bromodichloromethane ug/L 20 114 70-138116 120ND22.8 23.1 Bromoform ug/L 20 109 57-138108 220ND21.9 21.5 Bromomethane ug/L 20 83 10-20096 1420ND16.6 19.1 Carbon tetrachloride ug/L 20 115 70-147117 220ND22.9 23.5 Chlorobenzene ug/L 20 107 70-137109 120ND21.4 21.7 Chloroethane ug/L 20 148 51-166144 320ND29.7 28.7 Chloroform ug/L 20 115 70-144113 220ND23.0 22.5 Chloromethane ug/L 20 120 24-161117 320ND24.0 23.4 cis-1,2-Dichloroethene ug/L 20 122 67-148128 420ND24.5 25.5 cis-1,3-Dichloropropene ug/L 20 111 70-142110 120ND22.2 22.0 Dibromochloromethane ug/L 20 109 68-138108 120ND21.8 21.6 Dibromomethane ug/L 20 114 70-134112 220ND22.9 22.5 Dichlorodifluoromethane ug/L 20 116 43-155114 220ND23.2 22.7 Diisopropyl ether ug/L 20 118 65-146123 420ND23.6 24.6 Ethylbenzene ug/L 20 108 68-143110 120ND21.6 21.9 Hexachloro-1,3-butadiene ug/L 20 88 62-151100 1220ND17.7 20.0 m&p-Xylene ug/L 40 107 53-157108 140ND42.9 43.4 Methyl-tert-butyl ether ug/L 20 110 59-156114 420ND22.0 22.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 55 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3328048MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145005 3328049 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L 20 126 64-148120 520ND25.1 23.9 Naphthalene ug/L 20 99 57-150105 520ND19.8 20.9 o-Xylene ug/L 20 107 68-143107 020ND21.4 21.3 p-Isopropyltoluene ug/L 20 103 70-141105 120ND20.7 20.9 Styrene ug/L 20 105 70-136107 220ND21.0 21.5 Tetrachloroethene ug/L 20 108 70-139109 120ND21.6 21.9 Toluene ug/L 20 117 47-157112 420ND23.3 22.4 trans-1,2-Dichloroethene ug/L 20 115 70-149119 320ND23.0 23.7 trans-1,3-Dichloropropene ug/L 20 108 70-138110 220ND21.7 22.0 Trichloroethene ug/L 20 115 70-149116 120ND23.0 23.3 Trichlorofluoromethane ug/L 20 114 61-154116 220ND22.8 23.2 Vinyl acetate ug/L 40 124 48-156120 340ND49.4 48.1 Vinyl chloride ug/L 20 124 55-172124 020ND24.8 24.8 Xylene (Total)ug/L 60 107 66-145108 160ND64.3 64.7 1,2-Dichloroethane-d4 (S)%108 70-130101 4-Bromofluorobenzene (S)%99 70-130101 Toluene-d8 (S)%99 70-130100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 56 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633344 EPA 8260D Mod. EPA 8260D Mod. 8260D MSV SIM Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92549145001, 92549145002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3326636 Associated Lab Samples:92549145001, 92549145002 Matrix:Water Analyzed 1,4-Dioxane (p-Dioxane)ug/L ND 2.0 07/14/21 12:22 1,2-Dichloroethane-d4 (S)%97 70-130 07/14/21 12:22 Toluene-d8 (S)%99 66-133 07/14/21 12:22 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3326637LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dioxane (p-Dioxane)ug/L 18.820 94 70-130 1,2-Dichloroethane-d4 (S)%92 70-130 Toluene-d8 (S)%99 66-133 Parameter Units MS Result % Rec Limits Qual% RecConc. 3326638MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549106001 3326639 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,4-Dioxane (p-Dioxane)ug/L 20 91 64-14191 120ND18.9 18.7 1,2-Dichloroethane-d4 (S)%100 70-13098 Toluene-d8 (S)%100 66-133100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 57 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633637 EPA 8260D Mod. EPA 8260D Mod. 8260D MSV SIM Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92549145003, 92549145004, 92549145007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3328108 Associated Lab Samples:92549145003, 92549145004, 92549145007 Matrix:Water Analyzed 1,4-Dioxane (p-Dioxane)ug/L ND 2.0 07/15/21 12:15 1,2-Dichloroethane-d4 (S)%94 70-130 07/15/21 12:15 Toluene-d8 (S)%98 66-133 07/15/21 12:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3328109LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dioxane (p-Dioxane)ug/L 18.820 94 70-130 1,2-Dichloroethane-d4 (S)%93 70-130 Toluene-d8 (S)%100 66-133 Parameter Units MS Result % Rec Limits Qual% RecConc. 3328110MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549106004 3328111 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,4-Dioxane (p-Dioxane)ug/L 20 89 64-14191 220ND18.4 18.7 1,2-Dichloroethane-d4 (S)%99 70-13099 Toluene-d8 (S)%97 66-13398 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 58 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633644 EPA 8260D Mod. EPA 8260D Mod. 8260D MSV SIM Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3328159 Associated Lab Samples:92549145005 Matrix:Water Analyzed 1,4-Dioxane (p-Dioxane)ug/L ND 2.0 07/15/21 12:34 1,2-Dichloroethane-d4 (S)%95 70-130 07/15/21 12:34 Toluene-d8 (S)%99 66-133 07/15/21 12:34 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3328160LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dioxane (p-Dioxane)ug/L 18.920 95 70-130 1,2-Dichloroethane-d4 (S)%94 70-130 Toluene-d8 (S)%99 66-133 Parameter Units MS Result % Rec Limits Qual% RecConc. 3328161MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145005 3328162 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,4-Dioxane (p-Dioxane)ug/L 20 89 64-14191 220ND18.5 18.8 1,2-Dichloroethane-d4 (S)%97 70-13098 Toluene-d8 (S)%97 66-13398 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 59 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 634169 EPA 3510C EPA 8270E 8270E Water MSSV RVE Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92549145001, 92549145002, 92549145004, 92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3330701 Associated Lab Samples:92549145001, 92549145002, 92549145004, 92549145005 Matrix:Water Analyzed 1,2,4-Trichlorobenzene ug/L ND 10.0 07/19/21 17:55 1,2-Dichlorobenzene ug/L ND 10.0 07/19/21 17:55 1,3-Dichlorobenzene ug/L ND 10.0 07/19/21 17:55 1,4-Dichlorobenzene ug/L ND 10.0 07/19/21 17:55 1-Methylnaphthalene ug/L ND 10.0 07/19/21 17:55 2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 v107/19/21 17:55 2,4,5-Trichlorophenol ug/L ND 10.0 07/19/21 17:55 2,4,6-Trichlorophenol ug/L ND 10.0 07/19/21 17:55 2,4-Dichlorophenol ug/L ND 10.0 07/19/21 17:55 2,4-Dimethylphenol ug/L ND 10.0 07/19/21 17:55 2,4-Dinitrophenol ug/L ND 50.0 v107/19/21 17:55 2,4-Dinitrotoluene ug/L ND 10.0 07/19/21 17:55 2,6-Dinitrotoluene ug/L ND 10.0 07/19/21 17:55 2-Chloronaphthalene ug/L ND 10.0 07/19/21 17:55 2-Chlorophenol ug/L ND 10.0 07/19/21 17:55 2-Methylnaphthalene ug/L ND 10.0 07/19/21 17:55 2-Methylphenol(o-Cresol)ug/L ND 10.0 07/19/21 17:55 2-Nitroaniline ug/L ND 20.0 07/19/21 17:55 2-Nitrophenol ug/L ND 10.0 07/19/21 17:55 3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 07/19/21 17:55 3,3'-Dichlorobenzidine ug/L ND 20.0 07/19/21 17:55 3-Nitroaniline ug/L ND 20.0 07/19/21 17:55 4,6-Dinitro-2-methylphenol ug/L ND 20.0 07/19/21 17:55 4-Bromophenylphenyl ether ug/L ND 10.0 07/19/21 17:55 4-Chloro-3-methylphenol ug/L ND 10.0 07/19/21 17:55 4-Chloroaniline ug/L ND 20.0 07/19/21 17:55 4-Chlorophenylphenyl ether ug/L ND 10.0 07/19/21 17:55 4-Nitroaniline ug/L ND 20.0 07/19/21 17:55 4-Nitrophenol ug/L ND 50.0 07/19/21 17:55 Acenaphthene ug/L ND 10.0 07/19/21 17:55 Acenaphthylene ug/L ND 10.0 07/19/21 17:55 Aniline ug/L ND 10.0 07/19/21 17:55 Anthracene ug/L ND 10.0 07/19/21 17:55 Benzo(a)anthracene ug/L ND 10.0 07/19/21 17:55 Benzo(a)pyrene ug/L ND 10.0 07/19/21 17:55 Benzo(b)fluoranthene ug/L ND 10.0 07/19/21 17:55 Benzo(g,h,i)perylene ug/L ND 10.0 07/19/21 17:55 Benzo(k)fluoranthene ug/L ND 10.0 07/19/21 17:55 Benzoic Acid ug/L ND 50.0 07/19/21 17:55 Benzyl alcohol ug/L ND 20.0 07/19/21 17:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 60 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3330701 Associated Lab Samples:92549145001, 92549145002, 92549145004, 92549145005 Matrix:Water Analyzed bis(2-Chloroethoxy)methane ug/L ND 10.0 07/19/21 17:55 bis(2-Chloroethyl) ether ug/L ND 10.0 07/19/21 17:55 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 07/19/21 17:55 Butylbenzylphthalate ug/L ND 10.0 07/19/21 17:55 Chrysene ug/L ND 10.0 07/19/21 17:55 Di-n-butylphthalate ug/L ND 10.0 07/19/21 17:55 Di-n-octylphthalate ug/L ND 10.0 07/19/21 17:55 Dibenz(a,h)anthracene ug/L ND 10.0 07/19/21 17:55 Dibenzofuran ug/L ND 10.0 07/19/21 17:55 Diethylphthalate ug/L ND 10.0 07/19/21 17:55 Dimethylphthalate ug/L ND 10.0 07/19/21 17:55 Fluoranthene ug/L ND 10.0 07/19/21 17:55 Fluorene ug/L ND 10.0 07/19/21 17:55 Hexachloro-1,3-butadiene ug/L ND 10.0 07/19/21 17:55 Hexachlorobenzene ug/L ND 10.0 07/19/21 17:55 Hexachlorocyclopentadiene ug/L ND 10.0 07/19/21 17:55 Hexachloroethane ug/L ND 10.0 07/19/21 17:55 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 07/19/21 17:55 Isophorone ug/L ND 10.0 07/19/21 17:55 N-Nitroso-di-n-propylamine ug/L ND 10.0 07/19/21 17:55 N-Nitrosodimethylamine ug/L ND 10.0 07/19/21 17:55 N-Nitrosodiphenylamine ug/L ND 10.0 07/19/21 17:55 Naphthalene ug/L ND 10.0 07/19/21 17:55 Nitrobenzene ug/L ND 10.0 07/19/21 17:55 Pentachlorophenol ug/L ND 20.0 07/19/21 17:55 Phenanthrene ug/L ND 10.0 07/19/21 17:55 Phenol ug/L ND 10.0 07/19/21 17:55 Pyrene ug/L ND 10.0 07/19/21 17:55 2,4,6-Tribromophenol (S)%74 10-144 07/19/21 17:55 2-Fluorobiphenyl (S)%76 10-130 07/19/21 17:55 2-Fluorophenol (S)%54 10-130 07/19/21 17:55 Nitrobenzene-d5 (S)%84 10-144 07/19/21 17:55 Phenol-d6 (S)%36 10-130 07/19/21 17:55 Terphenyl-d14 (S)%96 34-163 07/19/21 17:55 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3330702LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene ug/L 30.650 61 18-130 1,2-Dichlorobenzene ug/L 31.450 63 20-130 1,3-Dichlorobenzene ug/L 30.350 61 18-130 1,4-Dichlorobenzene ug/L 31.350 63 18-130 1-Methylnaphthalene ug/L 35.850 72 29-130 2,2'-Oxybis(1-chloropropane)ug/L 42.9 v1508628-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 61 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3330702LABORATORY CONTROL SAMPLE: LCSSpike 2,4,5-Trichlorophenol ug/L 42.050 84 35-130 2,4,6-Trichlorophenol ug/L 39.650 79 31-130 2,4-Dichlorophenol ug/L 39.950 80 35-130 2,4-Dimethylphenol ug/L 39.750 79 34-130 2,4-Dinitrophenol ug/L 225 v12509010-153 2,4-Dinitrotoluene ug/L 43.350 87 37-136 2,6-Dinitrotoluene ug/L 42.350 85 33-136 2-Chloronaphthalene ug/L 35.950 72 26-130 2-Chlorophenol ug/L 36.250 72 37-130 2-Methylnaphthalene ug/L 35.550 71 29-130 2-Methylphenol(o-Cresol)ug/L 35.950 72 35-130 2-Nitroaniline ug/L 88.0100 88 37-130 2-Nitrophenol ug/L 39.050 78 32-130 3&4-Methylphenol(m&p Cresol)ug/L 34.150 68 34-130 3,3'-Dichlorobenzidine ug/L 84.1100 84 34-136 3-Nitroaniline ug/L 87.7100 88 37-138 4,6-Dinitro-2-methylphenol ug/L 95.5100 95 21-157 4-Bromophenylphenyl ether ug/L 44.150 88 38-130 4-Chloro-3-methylphenol ug/L 82.9100 83 37-130 4-Chloroaniline ug/L 79.7100 80 38-130 4-Chlorophenylphenyl ether ug/L 40.850 82 33-130 4-Nitroaniline ug/L 88.8100 89 42-137 4-Nitrophenol ug/L 126250 51 10-130 Acenaphthene ug/L 40.450 81 33-130 Acenaphthylene ug/L 41.150 82 35-130 Aniline ug/L 30.850 62 22-130 Anthracene ug/L 43.650 87 48-130 Benzo(a)anthracene ug/L 45.450 91 48-137 Benzo(a)pyrene ug/L 45.950 92 49-138 Benzo(b)fluoranthene ug/L 47.050 94 52-138 Benzo(g,h,i)perylene ug/L 47.050 94 48-140 Benzo(k)fluoranthene ug/L 48.550 97 48-139 Benzoic Acid ug/L 115250 46 10-130 Benzyl alcohol ug/L 71.4100 71 35-130 bis(2-Chloroethoxy)methane ug/L 41.350 83 34-130 bis(2-Chloroethyl) ether ug/L 42.050 84 36-130 bis(2-Ethylhexyl)phthalate ug/L 50.150 100 32-165 Butylbenzylphthalate ug/L 50.150 100 34-161 Chrysene ug/L 47.350 95 47-131 Di-n-butylphthalate ug/L 46.150 92 39-144 Di-n-octylphthalate ug/L 51.250 102 30-170 Dibenz(a,h)anthracene ug/L 46.850 94 49-138 Dibenzofuran ug/L 40.050 80 33-130 Diethylphthalate ug/L 44.250 88 38-131 Dimethylphthalate ug/L 43.350 87 37-130 Fluoranthene ug/L 44.650 89 46-137 Fluorene ug/L 42.250 84 37-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 62 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3330702LABORATORY CONTROL SAMPLE: LCSSpike Hexachloro-1,3-butadiene ug/L 30.250 60 11-130 Hexachlorobenzene ug/L 41.050 82 38-130 Hexachlorocyclopentadiene ug/L 27.450 55 10-130 Hexachloroethane ug/L 30.750 61 14-130 Indeno(1,2,3-cd)pyrene ug/L 47.350 95 41-130 Isophorone ug/L 40.350 81 33-130 N-Nitroso-di-n-propylamine ug/L 41.250 82 36-130 N-Nitrosodimethylamine ug/L 32.950 66 34-130 N-Nitrosodiphenylamine ug/L 45.350 91 37-130 Naphthalene ug/L 34.950 70 30-130 Nitrobenzene ug/L 39.450 79 36-130 Pentachlorophenol ug/L 84.5100 85 23-149 Phenanthrene ug/L 44.750 89 44-130 Phenol ug/L 23.950 48 18-130 Pyrene ug/L 45.450 91 47-134 2,4,6-Tribromophenol (S)%102 10-144 2-Fluorobiphenyl (S)%85 10-130 2-Fluorophenol (S)%59 10-130 Nitrobenzene-d5 (S)%90 10-144 Phenol-d6 (S)%44 10-130 Terphenyl-d14 (S)%103 34-163 Parameter Units MS Result % Rec Limits Qual% RecConc. 3330703MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145001 3330704 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,2,4-Trichlorobenzene ug/L 50 60 10-13051 1650ND29.8 25.3 1,2-Dichlorobenzene ug/L 50 61 10-13054 1250ND30.5 27.1 1,3-Dichlorobenzene ug/L 50 59 10-13052 1350ND29.6 26.0 1,4-Dichlorobenzene ug/L 50 60 10-13055 850ND30.0 27.5 1-Methylnaphthalene ug/L 50 72 10-13064 1250ND35.9 32.0 2,2'-Oxybis(1-chloropropane)ug/L 50 76 12-14267 1350ND38.2 33.7 2,4,5-Trichlorophenol ug/L 50 56 10-14355 150ND28.1 27.7 2,4,6-Trichlorophenol ug/L 50 34 10-14732 550ND16.9 16.1 2,4-Dichlorophenol ug/L 50 75 10-13867 1150ND37.4 33.5 2,4-Dimethylphenol ug/L 50 95 25-13080 1850ND47.6 39.9 2,4-Dinitrophenol ug/L M1250110-1651250NDNDND 2,4-Dinitrotoluene ug/L 50 80 29-14881 050ND40.2 40.3 2,6-Dinitrotoluene ug/L 50 88 26-14682 750ND43.9 40.9 2-Chloronaphthalene ug/L 50 71 11-13062 1450ND35.7 30.9 2-Chlorophenol ug/L 50 71 10-13365 1050ND35.6 32.3 2-Methylnaphthalene ug/L 50 72 13-13064 1250ND35.8 31.8 2-Methylphenol(o-Cresol)ug/L 50 79 20-13074 650ND39.5 37.0 2-Nitroaniline ug/L 100 82 24-13678 6100ND82.3 77.7 2-Nitrophenol ug/L 50 79 10-15370 1250ND39.4 34.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 63 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3330703MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145001 3330704 MSD Result MSD % Rec RPD MSDMS Spike Conc. 3&4-Methylphenol(m&p Cresol) ug/L 50 74 16-13068 950ND37.1 33.9 3,3'-Dichlorobenzidine ug/L 100 98 10-15386 12100ND97.7 86.3 3-Nitroaniline ug/L 100 81 22-15181 0100ND81.4 81.3 4,6-Dinitro-2-methylphenol ug/L M1100810-1809100ND8.0J 8.9J 4-Bromophenylphenyl ether ug/L 50 102 25-13097 550ND51.2 48.5 4-Chloro-3-methylphenol ug/L 100 88 25-13381 8100ND87.7 81.3 4-Chloroaniline ug/L 100 77 14-13270 10100ND76.8 69.6 4-Chlorophenylphenyl ether ug/L 50 86 19-13078 1050ND43.1 38.8 4-Nitroaniline ug/L 100 69 29-15075 7100ND69.4 74.6 4-Nitrophenol ug/L M1250310-1304250NDND9.2J Acenaphthene ug/L 50 83 16-13071 1550ND41.4 35.6 Acenaphthylene ug/L 50 85 15-13773 1550ND42.4 36.4 Aniline ug/L 50 70 10-13064 950ND35.1 31.9 Anthracene ug/L 50 88 37-13686 250ND44.0 43.1 Benzo(a)anthracene ug/L 50 112 40-145110 250ND56.1 54.8 Benzo(a)pyrene ug/L 50 96 41-14693 450ND48.2 46.4 Benzo(b)fluoranthene ug/L 50 99 39-15197 350ND49.6 48.3 Benzo(g,h,i)perylene ug/L 50 89 40-14785 550ND44.7 42.4 Benzo(k)fluoranthene ug/L 50 100 40-14698 250ND50.2 49.0 Benzoic Acid ug/L M1250010-1300250NDNDND Benzyl alcohol ug/L 100 83 25-13076 8100ND82.6 76.5 bis(2-Chloroethoxy)methane ug/L 50 93 23-13081 1350ND46.3 40.4 bis(2-Chloroethyl) ether ug/L 50 102 25-13093 950ND51.0 46.3 bis(2-Ethylhexyl)phthalate ug/L 50 99 28-16698 150ND49.4 49.0 Butylbenzylphthalate ug/L 50 102 33-165106 450ND50.9 53.0 Chrysene ug/L 50 90 38-14189 250ND45.1 44.3 Di-n-butylphthalate ug/L 50 90 32-15393 450ND44.8 46.4 Di-n-octylphthalate ug/L 50 90 30-17587 450ND45.2 43.3 Dibenz(a,h)anthracene ug/L 50 89 39-14883 750ND44.6 41.6 Dibenzofuran ug/L 50 84 20-13073 1450ND42.1 36.7 Diethylphthalate ug/L 50 87 28-14286 250ND43.6 42.9 Dimethylphthalate ug/L 50 86 26-13681 650ND42.9 40.5 Fluoranthene ug/L 50 87 39-14387 150ND43.3 43.6 Fluorene ug/L 50 86 24-13280 750ND43.2 40.2 Hexachloro-1,3-butadiene ug/L 50 54 10-13046 1650ND27.1 23.1 Hexachlorobenzene ug/L 50 87 29-13082 550ND43.3 41.2 Hexachlorocyclopentadiene ug/L 50 44 10-13038 1450ND22.0 19.1 Hexachloroethane ug/L 50 57 10-13051 1250ND28.6 25.3 Indeno(1,2,3-cd)pyrene ug/L 50 89 39-14886 450ND44.6 42.8 Isophorone ug/L 50 93 23-13081 1450ND46.6 40.7 N-Nitroso-di-n-propylamine ug/L 50 89 25-13084 650ND44.3 41.9 N-Nitrosodimethylamine ug/L v1508422-13078 850ND42.1 39.0 N-Nitrosodiphenylamine ug/L 50 88 26-13483 650ND44.2 41.6 Naphthalene ug/L 50 70 14-13060 1550ND35.1 30.1 Nitrobenzene ug/L 50 89 25-13078 1450ND44.4 38.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 64 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3330703MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145001 3330704 MSD Result MSD % Rec RPD MSDMS Spike Conc. Pentachlorophenol ug/L M1100210-1751100NDNDND Phenanthrene ug/L 50 86 36-13383 450ND43.1 41.5 Phenol ug/L 50 51 10-13047 950ND25.7 23.5 Pyrene ug/L 50 98 40-143102 450ND49.1 50.9 2,4,6-Tribromophenol (S)%63 10-14460 2-Fluorobiphenyl (S)%87 10-13074 2-Fluorophenol (S)%45 10-13044 Nitrobenzene-d5 (S)%100 10-14486 Phenol-d6 (S)%50 10-13046 Terphenyl-d14 (S)%107 34-163109 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 65 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 634666 EPA 3510C EPA 8270E 8270E Water MSSV RVE Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92549145003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3333088 Associated Lab Samples:92549145003 Matrix:Water Analyzed 1,2,4-Trichlorobenzene ug/L ND 10.0 07/21/21 13:51 1,2-Dichlorobenzene ug/L ND 10.0 07/21/21 13:51 1,3-Dichlorobenzene ug/L ND 10.0 07/21/21 13:51 1,4-Dichlorobenzene ug/L ND 10.0 07/21/21 13:51 1-Methylnaphthalene ug/L ND 10.0 07/21/21 13:51 2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 07/21/21 13:51 2,4,5-Trichlorophenol ug/L ND 10.0 07/21/21 13:51 2,4,6-Trichlorophenol ug/L ND 10.0 07/21/21 13:51 2,4-Dichlorophenol ug/L ND 10.0 07/21/21 13:51 2,4-Dimethylphenol ug/L ND 10.0 07/21/21 13:51 2,4-Dinitrophenol ug/L ND 50.0 07/21/21 13:51 2,4-Dinitrotoluene ug/L ND 10.0 07/21/21 13:51 2,6-Dinitrotoluene ug/L ND 10.0 07/21/21 13:51 2-Chloronaphthalene ug/L ND 10.0 07/21/21 13:51 2-Chlorophenol ug/L ND 10.0 07/21/21 13:51 2-Methylnaphthalene ug/L ND 10.0 07/21/21 13:51 2-Methylphenol(o-Cresol)ug/L ND 10.0 07/21/21 13:51 2-Nitroaniline ug/L ND 20.0 07/21/21 13:51 2-Nitrophenol ug/L ND 10.0 07/21/21 13:51 3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 07/21/21 13:51 3,3'-Dichlorobenzidine ug/L ND 20.0 07/21/21 13:51 3-Nitroaniline ug/L ND 20.0 07/21/21 13:51 4,6-Dinitro-2-methylphenol ug/L ND 20.0 07/21/21 13:51 4-Bromophenylphenyl ether ug/L ND 10.0 07/21/21 13:51 4-Chloro-3-methylphenol ug/L ND 10.0 07/21/21 13:51 4-Chloroaniline ug/L ND 20.0 07/21/21 13:51 4-Chlorophenylphenyl ether ug/L ND 10.0 07/21/21 13:51 4-Nitroaniline ug/L ND 20.0 07/21/21 13:51 4-Nitrophenol ug/L ND 50.0 07/21/21 13:51 Acenaphthene ug/L ND 10.0 07/21/21 13:51 Acenaphthylene ug/L ND 10.0 07/21/21 13:51 Aniline ug/L ND 10.0 07/21/21 13:51 Anthracene ug/L ND 10.0 07/21/21 13:51 Benzo(a)anthracene ug/L ND 10.0 v107/21/21 13:51 Benzo(a)pyrene ug/L ND 10.0 07/21/21 13:51 Benzo(b)fluoranthene ug/L ND 10.0 07/21/21 13:51 Benzo(g,h,i)perylene ug/L ND 10.0 v107/21/21 13:51 Benzo(k)fluoranthene ug/L ND 10.0 07/21/21 13:51 Benzoic Acid ug/L ND 50.0 07/21/21 13:51 Benzyl alcohol ug/L ND 20.0 07/21/21 13:51 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 66 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3333088 Associated Lab Samples:92549145003 Matrix:Water Analyzed bis(2-Chloroethoxy)methane ug/L ND 10.0 07/21/21 13:51 bis(2-Chloroethyl) ether ug/L ND 10.0 07/21/21 13:51 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 07/21/21 13:51 Butylbenzylphthalate ug/L ND 10.0 07/21/21 13:51 Chrysene ug/L ND 10.0 07/21/21 13:51 Di-n-butylphthalate ug/L ND 10.0 07/21/21 13:51 Di-n-octylphthalate ug/L ND 10.0 07/21/21 13:51 Dibenz(a,h)anthracene ug/L ND 10.0 07/21/21 13:51 Dibenzofuran ug/L ND 10.0 07/21/21 13:51 Diethylphthalate ug/L ND 10.0 07/21/21 13:51 Dimethylphthalate ug/L ND 10.0 07/21/21 13:51 Fluoranthene ug/L ND 10.0 07/21/21 13:51 Fluorene ug/L ND 10.0 07/21/21 13:51 Hexachloro-1,3-butadiene ug/L ND 10.0 07/21/21 13:51 Hexachlorobenzene ug/L ND 10.0 07/21/21 13:51 Hexachlorocyclopentadiene ug/L ND 10.0 07/21/21 13:51 Hexachloroethane ug/L ND 10.0 07/21/21 13:51 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 07/21/21 13:51 Isophorone ug/L ND 10.0 07/21/21 13:51 N-Nitroso-di-n-propylamine ug/L ND 10.0 07/21/21 13:51 N-Nitrosodimethylamine ug/L ND 10.0 v107/21/21 13:51 N-Nitrosodiphenylamine ug/L ND 10.0 07/21/21 13:51 Naphthalene ug/L ND 10.0 07/21/21 13:51 Nitrobenzene ug/L ND 10.0 07/21/21 13:51 Pentachlorophenol ug/L ND 20.0 07/21/21 13:51 Phenanthrene ug/L ND 10.0 07/21/21 13:51 Phenol ug/L ND 10.0 07/21/21 13:51 Pyrene ug/L ND 10.0 07/21/21 13:51 2,4,6-Tribromophenol (S)%72 10-144 07/21/21 13:51 2-Fluorobiphenyl (S)%61 10-130 07/21/21 13:51 2-Fluorophenol (S)%46 10-130 07/21/21 13:51 Nitrobenzene-d5 (S)%70 10-144 07/21/21 13:51 Phenol-d6 (S)%31 10-130 07/21/21 13:51 Terphenyl-d14 (S)%110 34-163 07/21/21 13:51 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3333089LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene ug/L 37.950 76 18-130 1,2-Dichlorobenzene ug/L 36.950 74 20-130 1,3-Dichlorobenzene ug/L 34.950 70 18-130 1,4-Dichlorobenzene ug/L 35.050 70 18-130 1-Methylnaphthalene ug/L 44.450 89 29-130 2,2'-Oxybis(1-chloropropane)ug/L 43.650 87 28-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 67 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3333089LABORATORY CONTROL SAMPLE: LCSSpike 2,4,5-Trichlorophenol ug/L 45.750 91 35-130 2,4,6-Trichlorophenol ug/L 44.050 88 31-130 2,4-Dichlorophenol ug/L 47.050 94 35-130 2,4-Dimethylphenol ug/L 50.150 100 34-130 2,4-Dinitrophenol ug/L 195250 78 10-153 2,4-Dinitrotoluene ug/L 45.350 91 37-136 2,6-Dinitrotoluene ug/L 49.650 99 33-136 2-Chloronaphthalene ug/L 40.750 81 26-130 2-Chlorophenol ug/L 41.550 83 37-130 2-Methylnaphthalene ug/L 44.450 89 29-130 2-Methylphenol(o-Cresol)ug/L 42.350 85 35-130 2-Nitroaniline ug/L 86.0100 86 37-130 2-Nitrophenol ug/L 47.250 94 32-130 3&4-Methylphenol(m&p Cresol)ug/L 38.750 77 34-130 3,3'-Dichlorobenzidine ug/L 72.4100 72 34-136 3-Nitroaniline ug/L 84.9100 85 37-138 4,6-Dinitro-2-methylphenol ug/L 91.1100 91 21-157 4-Bromophenylphenyl ether ug/L 54.450 109 38-130 4-Chloro-3-methylphenol ug/L 95.0100 95 37-130 4-Chloroaniline ug/L 83.2100 83 38-130 4-Chlorophenylphenyl ether ug/L 48.150 96 33-130 4-Nitroaniline ug/L 79.0100 79 42-137 4-Nitrophenol ug/L 132250 53 10-130 Acenaphthene ug/L 46.850 94 33-130 Acenaphthylene ug/L 47.450 95 35-130 Aniline ug/L 36.450 73 22-130 Anthracene ug/L 45.450 91 48-130 Benzo(a)anthracene ug/L 59.2 v15011848-137 Benzo(a)pyrene ug/L 47.650 95 49-138 Benzo(b)fluoranthene ug/L 48.250 96 52-138 Benzo(g,h,i)perylene ug/L 53.9 v15010848-140 Benzo(k)fluoranthene ug/L 52.650 105 48-139 Benzoic Acid ug/L 149250 59 10-130 Benzyl alcohol ug/L 86.6100 87 35-130 bis(2-Chloroethoxy)methane ug/L 50.450 101 34-130 bis(2-Chloroethyl) ether ug/L 54.450 109 36-130 bis(2-Ethylhexyl)phthalate ug/L 54.950 110 32-165 Butylbenzylphthalate ug/L 57.150 114 34-161 Chrysene ug/L 46.650 93 47-131 Di-n-butylphthalate ug/L 49.850 100 39-144 Di-n-octylphthalate ug/L 47.850 96 30-170 Dibenz(a,h)anthracene ug/L 51.250 102 49-138 Dibenzofuran ug/L 45.550 91 33-130 Diethylphthalate ug/L 47.850 96 38-131 Dimethylphthalate ug/L 46.850 94 37-130 Fluoranthene ug/L 45.650 91 46-137 Fluorene ug/L 48.150 96 37-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 68 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3333089LABORATORY CONTROL SAMPLE: LCSSpike Hexachloro-1,3-butadiene ug/L 37.050 74 11-130 Hexachlorobenzene ug/L 45.250 90 38-130 Hexachlorocyclopentadiene ug/L 31.850 64 10-130 Hexachloroethane ug/L 34.350 69 14-130 Indeno(1,2,3-cd)pyrene ug/L 53.950 108 41-130 Isophorone ug/L 52.850 106 33-130 N-Nitroso-di-n-propylamine ug/L 52.450 105 36-130 N-Nitrosodimethylamine ug/L 46.2 v1509234-130 N-Nitrosodiphenylamine ug/L 46.350 93 37-130 Naphthalene ug/L 43.550 87 30-130 Nitrobenzene ug/L 48.250 96 36-130 Pentachlorophenol ug/L 70.1100 70 23-149 Phenanthrene ug/L 45.950 92 44-130 Phenol ug/L 28.450 57 18-130 Pyrene ug/L 53.350 107 47-134 2,4,6-Tribromophenol (S)%104 10-144 2-Fluorobiphenyl (S)%87 10-130 2-Fluorophenol (S)%67 10-130 Nitrobenzene-d5 (S)%98 10-144 Phenol-d6 (S)%54 10-130 Terphenyl-d14 (S)%108 34-163 Parameter Units MS Result % Rec Limits Qual% RecConc. 3334193MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92547490007 3334194 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,2,4-Trichlorobenzene ug/L 50 95 10-13089 750ND47.7 44.4 1,2-Dichlorobenzene ug/L 50 91 10-13069 2850ND45.6 34.5 1,3-Dichlorobenzene ug/L R1508610-13063 3250ND43.2 31.3 1,4-Dichlorobenzene ug/L 50 88 10-13066 2950ND44.2 33.0 1-Methylnaphthalene ug/L 50 116 10-130114 150ND57.9 57.1 2,2'-Oxybis(1-chloropropane)ug/L 50 114 12-142105 850ND56.8 52.6 2,4,5-Trichlorophenol ug/L M1509210-143850ND45.8 4.1J 2,4,6-Trichlorophenol ug/L M1506110-147250ND30.5 ND 2,4-Dichlorophenol ug/L 50 107 10-1381850ND53.7 8.9J 2,4-Dimethylphenol ug/L 50 128 25-130117 950ND64.0 58.4 2,4-Dinitrophenol ug/L M1250110-1650250NDNDND 2,4-Dinitrotoluene ug/L 50 108 29-148110 250ND53.9 54.8 2,6-Dinitrotoluene ug/L 50 120 26-146118 150ND59.9 59.2 2-Chloronaphthalene ug/L 50 103 11-130103 050ND51.7 51.7 2-Chlorophenol ug/L 50 101 10-1331950ND50.3 9.4J 2-Methylnaphthalene ug/L 50 112 13-130115 350ND55.9 57.6 2-Methylphenol(o-Cresol)ug/L 50 111 20-13089 2250ND55.4 44.3 2-Nitroaniline ug/L 100 109 24-136111 2100ND109111 2-Nitrophenol ug/L 50 112 10-1531550ND56.2 7.6J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 69 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3334193MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92547490007 3334194 MSD Result MSD % Rec RPD MSDMS Spike Conc. 3&4-Methylphenol(m&p Cresol) ug/L R15010416-13068 4250ND52.2 34.0 3,3'-Dichlorobenzidine ug/L 100 126 10-153112 12100ND126112 3-Nitroaniline ug/L 100 113 22-151110 2100ND113110 4,6-Dinitro-2-methylphenol ug/L M11001710-1800100ND17.3J ND 4-Bromophenylphenyl ether ug/L M15013225-130131 150ND66.2 65.6 4-Chloro-3-methylphenol ug/L R110012025-13387 32100ND12086.6 4-Chloroaniline ug/L 100 109 14-132103 6100ND109103 4-Chlorophenylphenyl ether ug/L 50 119 19-130118 150ND59.6 59.1 4-Nitroaniline ug/L 100 97 29-150100 3100ND96.5 99.6 4-Nitrophenol ug/L M1250810-1300250ND19.2J ND Acenaphthene ug/L 50 116 16-130111 450ND58.2 55.7 Acenaphthylene ug/L 50 117 15-137117 050ND58.4 58.6 Aniline ug/L 50 97 10-13095 350ND48.7 47.5 Anthracene ug/L 50 114 37-136113 150ND56.8 56.3 Benzo(a)anthracene ug/L M1,v15014440-145146 250ND71.8 73.0 Benzo(a)pyrene ug/L 50 120 41-146122 250ND60.0 61.1 Benzo(b)fluoranthene ug/L 50 120 39-151122 150ND60.2 61.1 Benzo(g,h,i)perylene ug/L v15012940-147136 550ND64.6 67.8 Benzo(k)fluoranthene ug/L 50 126 40-146128 150ND63.1 63.8 Benzoic Acid ug/L M1250010-1300250NDNDND Benzyl alcohol ug/L 100 113 25-130113 1100ND113113 bis(2-Chloroethoxy)methane ug/L 50 125 23-130122 250ND62.4 61.2 bis(2-Chloroethyl) ether ug/L M15013825-130135 250ND68.8 67.7 bis(2-Ethylhexyl)phthalate ug/L 50 134 28-166130 450ND67.1 64.8 Butylbenzylphthalate ug/L 50 140 33-165139 050ND69.9 69.7 Chrysene ug/L 50 117 38-141118 150ND58.3 58.8 Di-n-butylphthalate ug/L 50 121 32-153119 150ND60.3 59.5 Di-n-octylphthalate ug/L 50 119 30-175119 150ND59.3 59.7 Dibenz(a,h)anthracene ug/L 50 128 39-148130 150ND64.1 65.0 Dibenzofuran ug/L 50 114 20-130112 250ND56.9 55.8 Diethylphthalate ug/L 50 118 28-142117 150ND59.2 58.4 Dimethylphthalate ug/L 50 116 26-136116 050ND57.8 57.9 Fluoranthene ug/L 50 115 39-143114 150ND57.5 57.2 Fluorene ug/L 50 118 24-132114 350ND59.1 57.1 Hexachloro-1,3-butadiene ug/L 50 90 10-13074 2050ND45.2 37.0 Hexachlorobenzene ug/L 50 113 29-130115 250ND56.3 57.6 Hexachlorocyclopentadiene ug/L 50 88 10-13086 250ND44.2 43.1 Hexachloroethane ug/L R1508410-13056 4050ND42.1 28.1 Indeno(1,2,3-cd)pyrene ug/L 50 131 39-148136 450ND65.3 68.1 Isophorone ug/L 50 130 23-130128 150ND64.9 64.2 N-Nitroso-di-n-propylamine ug/L 50 130 25-130128 250ND65.1 64.1 N-Nitrosodimethylamine ug/L v15011722-130119 150ND58.5 59.4 N-Nitrosodiphenylamine ug/L 50 110 26-134112 250ND55.2 56.1 Naphthalene ug/L 50 107 14-130100 650ND53.3 50.2 Nitrobenzene ug/L 50 116 25-130117 150ND57.9 58.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 70 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3334193MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92547490007 3334194 MSD Result MSD % Rec RPD MSDMS Spike Conc. Pentachlorophenol ug/L M11003210-1751100ND32.0 ND Phenanthrene ug/L 50 108 36-133111 250ND54.1 55.3 Phenol ug/L R1507110-13026 9350ND35.7 13.0 Pyrene ug/L 50 134 40-143132 150ND66.8 66.1 2,4,6-Tribromophenol (S)%S011010-1447 2-Fluorobiphenyl (S)%107 10-130105 2-Fluorophenol (S)%S07110-1304 Nitrobenzene-d5 (S)%119 10-144120 Phenol-d6 (S)%68 10-13023 Terphenyl-d14 (S)%135 34-163133 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 71 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633600 SM 2320B-2011 SM 2320B-2011 2320B Alkalinity Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3327836 Associated Lab Samples:92549145001 Matrix:Water Analyzed Alkalinity, Total as CaCO3 mg/L ND 5.0 07/15/21 17:38 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3327837LABORATORY CONTROL SAMPLE: LCSSpike Alkalinity, Total as CaCO3 mg/L 50.850 102 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 3327838MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549284001 3327839 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 mg/L 50 99 80-12099 05021.4 70.8 71.1 Parameter Units MS Result % Rec Limits Qual% RecConc. 3328838MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549367003 3328839 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 mg/L 50 98 80-120107 250136185190 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 72 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633602 SM 2320B-2011 SM 2320B-2011 2320B Alkalinity Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145002, 92549145003, 92549145004, 92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3327842 Associated Lab Samples:92549145002, 92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Alkalinity, Total as CaCO3 mg/L ND 5.0 07/16/21 14:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3327843LABORATORY CONTROL SAMPLE: LCSSpike Alkalinity, Total as CaCO3 mg/L 51.150 102 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 3327844MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145002 3327845 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 mg/L 50 100 80-120103 150109159161 Parameter Units MS Result % Rec Limits Qual% RecConc. 3327846MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145004 3327847 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 mg/L 50 104 80-120105 0508.3 60.5 60.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 73 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 633996 SM 2540C-2011 SM 2540C-2011 2540C Total Dissolved Solids Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145001, 92549145002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3329913 Associated Lab Samples:92549145001, 92549145002 Matrix:Water Analyzed Total Dissolved Solids mg/L ND 25.0 07/16/21 19:11 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3329914LABORATORY CONTROL SAMPLE: LCSSpike Total Dissolved Solids mg/L 238251 95 90-110 Parameter Units Dup Result QualifiersRPDResult 92549106003 3329915SAMPLE DUPLICATE: Total Dissolved Solids mg/L NDND Parameter Units Dup Result QualifiersRPDResult 92549301001 3329916SAMPLE DUPLICATE: Total Dissolved Solids mg/L 1020 71090 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 74 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 634118 SM 2540C-2011 SM 2540C-2011 2540C Total Dissolved Solids Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145003, 92549145004, 92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3330526 Associated Lab Samples:92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Total Dissolved Solids mg/L ND 25.0 07/17/21 13:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3330527LABORATORY CONTROL SAMPLE: LCSSpike Total Dissolved Solids mg/L 250250 100 90-110 Parameter Units Dup Result QualifiersRPDResult 92549110013 3330528SAMPLE DUPLICATE: Total Dissolved Solids mg/L 57.0 057.0 Parameter Units Dup Result QualifiersRPDResult 92549532006 3330529SAMPLE DUPLICATE: Total Dissolved Solids mg/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 75 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 634530 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 300.0 IC Anions Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145001, 92549145002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3332265 Associated Lab Samples:92549145001, 92549145002 Matrix:Water Analyzed Sulfate mg/L ND 1.0 07/21/21 01:18 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3332266LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 49.450 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 3332267MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549942001 3332268 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate mg/L M1507690-11075 050101139138 Parameter Units MS Result % Rec Limits Qual% RecConc. 3332269MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549110002 3332270 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate mg/L M1508490-11082 150125167166 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 76 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 634970 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 300.0 IC Anions Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145003, 92549145004, 92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3334438 Associated Lab Samples:92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Sulfate mg/L ND 1.0 07/21/21 19:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3334439LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 49.450 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 3334440MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92550549001 3334441 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate mg/L M1507790-11074 050682681 Parameter Units MS Result % Rec Limits Qual% RecConc. 3334442MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92550578010 3334443 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate mg/L 50 101 90-110105 450ND50.6 52.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 77 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 634459 SM 4500-Cl-E-2011 SM 4500-Cl-E-2011 4500 Chloride Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145001, 92549145002, 92549145003, 92549145004, 92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3331884 Associated Lab Samples:92549145001, 92549145002, 92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Chloride mg/L ND 1.0 07/20/21 11:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3331885LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 20.320 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 3331886MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92548313003 3331887 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chloride mg/L M110-46 90-110-141 210427422413 Parameter Units MS Result % Rec Limits Qual% RecConc. 3331888MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549145001 3331889 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chloride mg/L M11011890-110121 11024.2 36.0 36.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 78 of 106 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 634588 SM 5310B-2011 SM 5310B-2011 5310B TOC Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92549145001, 92549145002, 92549145003, 92549145004, 92549145005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3332674 Associated Lab Samples:92549145001, 92549145002, 92549145003, 92549145004, 92549145005 Matrix:Water Analyzed Total Organic Carbon mg/L ND 1.0 07/21/21 11:12 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3332675LABORATORY CONTROL SAMPLE: LCSSpike Total Organic Carbon mg/L 23.825 95 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 3332676MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549110001 3332677 MSD Result MSD % Rec RPD MSDMS Spike Conc. Total Organic Carbon mg/L 25 101 90-110102 1252.7 28.0 28.2 Parameter Units MS Result % Rec Limits Qual% RecConc. 3332678MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92549110002 3332679 MSD Result MSD % Rec RPD MSDMS Spike Conc. Total Organic Carbon mg/L 25 102 90-110101 0251.8 27.3 27.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 79 of 106 #=QL# QUALIFIERS Pace Project No.: Project: 92549145 Sludge Landfill July 2021 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value.IH The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value.IK Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 RPD value was outside control limits.R1 Surrogate recovery outside laboratory control limits.S0 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias.v1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 80 of 106 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92549145001 WQ0013419-SWP1 92549145002 WQ0013419-SWP2 92549145003 WQ0013419-Q06V09 92549145004 WQ0013419-Q06V10 92549145005 WQ0013419-Q06V11 92549145001 635293 635407WQ0013419-SWP1 EPA 3010A EPA 6010D 92549145002 635293 635407WQ0013419-SWP2 EPA 3010A EPA 6010D 92549145003 635491 635694WQ0013419-Q06V09 EPA 3010A EPA 6010D 92549145004 635491 635694WQ0013419-Q06V10 EPA 3010A EPA 6010D 92549145005 635491 635694WQ0013419-Q06V11 EPA 3010A EPA 6010D 92549145001 633945 634875WQ0013419-SWP1 EPA 1631E EPA 1631E 92549145002 633945 634875WQ0013419-SWP2 EPA 1631E EPA 1631E 92549145003 633945 634875WQ0013419-Q06V09 EPA 1631E EPA 1631E 92549145004 633945 634875WQ0013419-Q06V10 EPA 1631E EPA 1631E 92549145005 633945 634875WQ0013419-Q06V11 EPA 1631E EPA 1631E 92549145006 634548 634893WQ0013419-Field Blank EPA 1631E EPA 1631E 92549145001 634169 634387WQ0013419-SWP1 EPA 3510C EPA 8270E 92549145002 634169 634387WQ0013419-SWP2 EPA 3510C EPA 8270E 92549145003 634666 634921WQ0013419-Q06V09 EPA 3510C EPA 8270E 92549145004 634169 634387WQ0013419-Q06V10 EPA 3510C EPA 8270E 92549145005 634169 634387WQ0013419-Q06V11 EPA 3510C EPA 8270E 92549145001 633353WQ0013419-SWP1 EPA 8260D 92549145002 633353WQ0013419-SWP2 EPA 8260D 92549145003 633616WQ0013419-Q06V09 EPA 8260D 92549145004 633616WQ0013419-Q06V10 EPA 8260D 92549145005 633626WQ0013419-Q06V11 EPA 8260D 92549145007 633626Trip Blank EPA 8260D 92549145001 633344WQ0013419-SWP1 EPA 8260D Mod. 92549145002 633344WQ0013419-SWP2 EPA 8260D Mod. 92549145003 633637WQ0013419-Q06V09 EPA 8260D Mod. 92549145004 633637WQ0013419-Q06V10 EPA 8260D Mod. 92549145005 633644WQ0013419-Q06V11 EPA 8260D Mod. 92549145007 633637Trip Blank EPA 8260D Mod. 92549145001 633600WQ0013419-SWP1 SM 2320B-2011 92549145002 633602WQ0013419-SWP2 SM 2320B-2011 92549145003 633602WQ0013419-Q06V09 SM 2320B-2011 92549145004 633602WQ0013419-Q06V10 SM 2320B-2011 92549145005 633602WQ0013419-Q06V11 SM 2320B-2011 92549145001 633996WQ0013419-SWP1 SM 2540C-2011 92549145002 633996WQ0013419-SWP2 SM 2540C-2011 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 81 of 106 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92549145 Sludge Landfill July 2021 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92549145003 634118WQ0013419-Q06V09 SM 2540C-2011 92549145004 634118WQ0013419-Q06V10 SM 2540C-2011 92549145005 634118WQ0013419-Q06V11 SM 2540C-2011 92549145001 634530WQ0013419-SWP1 EPA 300.0 Rev 2.1 1993 92549145002 634530WQ0013419-SWP2 EPA 300.0 Rev 2.1 1993 92549145003 634970WQ0013419-Q06V09 EPA 300.0 Rev 2.1 1993 92549145004 634970WQ0013419-Q06V10 EPA 300.0 Rev 2.1 1993 92549145005 634970WQ0013419-Q06V11 EPA 300.0 Rev 2.1 1993 92549145001 634459WQ0013419-SWP1 SM 4500-Cl-E-2011 92549145002 634459WQ0013419-SWP2 SM 4500-Cl-E-2011 92549145003 634459WQ0013419-Q06V09 SM 4500-Cl-E-2011 92549145004 634459WQ0013419-Q06V10 SM 4500-Cl-E-2011 92549145005 634459WQ0013419-Q06V11 SM 4500-Cl-E-2011 92549145001 634588WQ0013419-SWP1 SM 5310B-2011 92549145002 634588WQ0013419-SWP2 SM 5310B-2011 92549145003 634588WQ0013419-Q06V09 SM 5310B-2011 92549145004 634588WQ0013419-Q06V10 SM 5310B-2011 92549145005 634588WQ0013419-Q06V11 SM 5310B-2011 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/18/2021 04:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 82 of 106 Page 83 of 106 Page 84 of 106 Page 85 of 106 Page 86 of 106 Page 87 of 106 Page 88 of 106 Thisreportshould notbe reproduced,exceptinfull, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlytothesamples included inthisreport. Report of Laboratory Analysis www.pacelabs.com Pace Analytical Services,LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Client - Charlotte PACE Charlotte 9800 Kincey Ave. Huntersville NC 28078 REPORT OF LABORATORY ANALYSIS FOR TCDD This report has been reviewed by: Invoicing & Reporting Options: Report Information: Report Prepared Date: August 12, 2021 Pace Project #:10569980 Sample Receipt Date:07/15/2021 Client Project #:92549145 Glatfelter Cor Client Sub PO #:N/A The report provided has been invoiced as a Level 2 2,3,7,8-TCDD Report. If an upgrade of this report package is requested,an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Ashley Williams,your Pace Project Manager. State Cert #:530 Report Prepared for: Page 1 of 18Report No.....10569980_1613TCDD_DFR August 12, 2021 Ashley Williams, Project Manager (612) 346-8158 (612) 607-6444 (fax) ashley.williams@pacelabs.com Page 89 of 106 Pace Analytical Services,LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. This report presents the results from the analyses performed on five samples submitted by a representative of Pace Analytical Services, LLC. The samples were analyzed for the presence or absence of 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) using USEPA Method 1613B. The reporting limits were set to correspond to the lowest calibration points and a nominal 1-liter sample amount, and the sensitivity was verified by signal-to-noise measurements. The quantitation limits, adjusted for sample extraction amount, may be somewhat higher or lower than the reporting limits provided in this report. The recoveries of the isotopically-labeled TCDD internal standard in the sample extracts ranged from 56-79%. All of the labeled standard recoveries obtained for this project were within the target ranges specified in Method 1613B. Also, since the quantification of the native TCDD was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show the blank to be free of 2,3,7,8-TCDD at the reporting limit. Laboratory spike samples were also prepared using clean reference matrix that had been fortified with native standard material. The results show that the spiked native TCDD was recovered at 101-109% with a relative percent difference of 7.6%. These results were within the target ranges for the method. Matrix spikes were not prepared with the sample batch. DISCUSSION Page 2 of 18Report No.....10569980_1613TCDD_DFR Page 90 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Report No.....10569980 Minnesota Laboratory Certifications Authority Certificate #Authority Certificate # Missouri 10100 A2LA 2926.01 Montana CERT0092 Alabama 40770 Nebraska NE-OS-18-06 Alaska-DW MN00064 Nevada MN00064 Alaska-UST 17-009 New Hampshire 2081 Arizona AZ0014 New Jersey MN002 Arkansas - WW 88-0680 New York 11647 Arkansas-DW MN00064 North Carolina-27700 California 2929 North Carolina-530 Colorado MN00064 North Dakota R-036 Connecticut PH-0256 Ohio-DW 41244 Florida E87605 Ohio-VAP (170 CL101 Georgia 959 Ohio-VAP (180 CL110 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon- rimary MN300001 Illinois 200011 Oregon-Second MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky-DW 90062 Tennessee TN02818 Kentucky-WW 90062 Texas T104704192 Louisiana-DEQ AI-84596 Utah MN00064 Louisiana-DW MN00064 Vermont VT-027053137 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Michigan 9909 West Virginia-D 382 Minnesota 027-053-137 West Virginia-D 9952C Minnesota-Ag via MN 027-053 Wisconsin 999407970 Minnesota-Petr 1240 Wyoming-UST via A2LA 2926. Mississippi MN00064 Page 3 of 18Report No.....10569980_1613TCDD_DFR Page 91 of 106 Appendix A Sample Management Pace Analytical Services, Inc.Page 4 of 18Report No.....10569980_1613TCDD_DFR Page 92 of 106 Page 5 of 18Report No.....10569980_1613TCDD_DFR Page 93 of 106 7/15/21 Page 6 of 18Report No.....10569980_1613TCDD_DFR Page 94 of 106 Page 7 of 18Report No.....10569980_1613TCDD_DFR Page 95 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Report No.....10569980 Reporting Flags A = B = C = D = E = I = J = L = Nn = P = R = S = U = V = X = Y = * = Reporting Limit based on signal to noise (EDL) Less than 10x higher than method blank level Result obtained from confirmation analysis Result obtained from analysis of diluted sample Exceeds calibration range Interference present Estimated value Suppressive interference,analyte may be biased low Value obtained from additional analysis PCDEInterference Recovery outside target range Peak saturated Analyte not detected Result verified by confirmation analysis %D Exceeds limits Calculated using average of daily RFs SeeDiscussion Page 8 of 18Report No.....10569980_1613TCDD_DFR Page 96 of 106 Appendix B Sample Analysis Summary Pace Analytical Services, Inc.Page 9 of 18Report No.....10569980_1613TCDD_DFR Page 97 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Lab Sample ID Injected By Filename Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Client's Sample ID WQ0013419-SWP1 92549145001 F210808B_11 JRH NA 990 mL NA F210611 F210808A_17 BLANK-92029 Matrix Dilution Collected Received Extracted Analyzed Water NA 07/12/2021 12:10 07/15/2021 08:50 08/02/2021 16:30 08/09/2021 02:03 Client - PACE Charlotte Method 1613B Sample Analysis Results Native Isomers Conc pg/L pg/L Internal Standards Added ng's Percent Recovery EMPC pg/L RL 2,3,7,8-TCDD ND 10 2,3,7,8-TCDD-13C 2.00 79----- Recovery Standard 1,2,3,4-TCDD-13C 2.00 NA Cleanup Standard 2,3,7,8-TCDD-37Cl4 0.20 106 Conc =Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration ND = Not Detected NA = Not Applicable NC = Not Calculated R =Recovery outside target range E =Exceeds calibration range RL = Reporting Limit Page 10 of 18Report No.....10569980_1613TCDD_DFR Page 98 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Lab Sample ID Injected By Filename Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Client's Sample ID WQ0013419-SWP2 92549145002 F210808B_12 JRH NA 974 mL NA F210611 F210808A_17 BLANK-92029 Matrix Dilution Collected Received Extracted Analyzed Water NA 07/12/2021 10:30 07/15/2021 08:50 08/02/2021 16:30 08/09/2021 02:47 Client - PACE Charlotte Method 1613B Sample Analysis Results Native Isomers Conc pg/L pg/L Internal Standards Added ng's Percent Recovery EMPC pg/L RL 2,3,7,8-TCDD ND 10 2,3,7,8-TCDD-13C 2.00 74----- Recovery Standard 1,2,3,4-TCDD-13C 2.00 NA Cleanup Standard 2,3,7,8-TCDD-37Cl4 0.20 95 Conc =Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration ND = Not Detected NA = Not Applicable NC = Not Calculated R =Recovery outside target range E =Exceeds calibration range RL = Reporting Limit Page 11 of 18Report No.....10569980_1613TCDD_DFR Page 99 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Lab Sample ID Injected By Filename Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Client's Sample ID WQ0013419-Q06V09 92549145003 F210808B_13 JRH NA 1000 mL NA F210611 F210808A_17 BLANK-92029 Matrix Dilution Collected Received Extracted Analyzed Water NA 07/13/2021 12:50 07/15/2021 08:50 08/02/2021 16:30 08/09/2021 03:32 Client - PACE Charlotte Method 1613B Sample Analysis Results Native Isomers Conc pg/L pg/L Internal Standards Added ng's Percent Recovery EMPC pg/L RL 2,3,7,8-TCDD ND 10 2,3,7,8-TCDD-13C 2.00 76----- Recovery Standard 1,2,3,4-TCDD-13C 2.00 NA Cleanup Standard 2,3,7,8-TCDD-37Cl4 0.20 92 Conc =Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration ND = Not Detected NA = Not Applicable NC = Not Calculated R =Recovery outside target range E =Exceeds calibration range RL = Reporting Limit Page 12 of 18Report No.....10569980_1613TCDD_DFR Page 100 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Lab Sample ID Injected By Filename Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Client's Sample ID WQ0013419-Q06V10 92549145004 F210808B_14 JRH NA 977 mL NA F210611 F210808A_17 BLANK-92029 Matrix Dilution Collected Received Extracted Analyzed Water NA 07/13/2021 11:50 07/15/2021 08:50 08/02/2021 16:30 08/09/2021 04:16 Client - PACE Charlotte Method 1613B Sample Analysis Results Native Isomers Conc pg/L pg/L Internal Standards Added ng's Percent Recovery EMPC pg/L RL 2,3,7,8-TCDD ND 10 2,3,7,8-TCDD-13C 2.00 56----- Recovery Standard 1,2,3,4-TCDD-13C 2.00 NA Cleanup Standard 2,3,7,8-TCDD-37Cl4 0.20 80 Conc =Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration ND = Not Detected NA = Not Applicable NC = Not Calculated R =Recovery outside target range E =Exceeds calibration range RL = Reporting Limit Page 13 of 18Report No.....10569980_1613TCDD_DFR Page 101 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Lab Sample ID Injected By Filename Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Client's Sample ID WQ0013419-Q06V11 92549145005 F210808B_15 JRH NA 1000 mL NA F210611 F210808A_17 BLANK-92029 Matrix Dilution Collected Received Extracted Analyzed Water NA 07/13/2021 12:20 07/15/2021 08:50 08/02/2021 16:30 08/09/2021 05:01 Client - PACE Charlotte Method 1613B Sample Analysis Results Native Isomers Conc pg/L pg/L Internal Standards Added ng's Percent Recovery EMPC pg/L RL 2,3,7,8-TCDD ND 10 2,3,7,8-TCDD-13C 2.00 65----- Recovery Standard 1,2,3,4-TCDD-13C 2.00 NA Cleanup Standard 2,3,7,8-TCDD-37Cl4 0.20 92 Conc =Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration ND = Not Detected NA = Not Applicable NC = Not Calculated R =Recovery outside target range E =Exceeds calibration range RL = Reporting Limit Page 14 of 18Report No.....10569980_1613TCDD_DFR Page 102 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Lab Sample ID Injected By Filename Total Amount Extracted ICAL ID CCal Filename(s) BLANK-92029 F210805B_06 SMT 1030 mL F210611 F210805A_17 Matrix Dilution Extracted Analyzed Water 08/02/2021 16:30 08/05/2021 18:58 NA Method 1613B Blank Analysis Results Lab Sample Name DFBLKEG Native Isomers pg/L Conc EMPC pg/L pg/L Internal Standards Added ng's Percent Recovery RL 2,3,7,8-TCDD ND -----10 2,3,7,8-TCDD-13C 2.00 41 Recovery Standard 1,2,3,4-TCDD-13C 2.00 NA Cleanup Standard 2,3,7,8-TCDD-37Cl4 0.20 75 Conc =Concentration (Totals include 2,3,7,8-substituted isomers). EMPC =Estimated Maximum Possible Concentration RL =Reporting Limit Page 15 of 18Report No.....10569980_1613TCDD_DFR Page 103 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Method 1613B Laboratory Control Spike Results Lab Sample ID Injected By Filename Total Amount Extracted ICAL ID CCal Filename LCS-92030 F210805B_01 SMT 982 mL F210611 F210805A_17 Matrix Dilution Extracted Analyzed Water 08/02/2021 16:30 08/05/2021 15:16 NA Method Blank ID BLANK-92029 Compound Cs Cr Lower Upper Limit Limit % Rec. 2,3,7,8-TCDD 10 10 7.3 14.6 101 2,3,7,8-TCDD-37Cl4 10 9.5 3.7 15.8 95 2,3,7,8-TCDD-13C 100 70 25.0 141.0 70 Cs =Concentration Spiked (ng/mL) Cr =Concentration Recovered (ng/mL) Rec.=Recovery (Expressed as Percent) Control Limit Reference:Method 1613,Table 6,10/94 Revision R =Recovery outside of control limits Nn =Value obtained from additional analysis *=See Discussion Page 16 of 18Report No.....10569980_1613TCDD_DFR Page 104 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Method 1613B Laboratory Control Spike Results Lab Sample ID Injected By Filename Total Amount Extracted ICAL ID CCal Filename LCSD-92031 F210805B_02 SMT 993 mL F210611 F210805A_17 Matrix Dilution Extracted Analyzed Water 08/02/2021 16:30 08/05/2021 15:59 NA Method Blank ID BLANK-92029 Compound Cs Cr Lower Upper Limit Limit % Rec. 2,3,7,8-TCDD 10 11 7.3 14.6 109 2,3,7,8-TCDD-37Cl4 10 8.0 3.7 15.8 80 2,3,7,8-TCDD-13C 100 54 25.0 141.0 54 Cs =Concentration Spiked (ng/mL) Cr =Concentration Recovered (ng/mL) Rec.=Recovery (Expressed as Percent) Control Limit Reference:Method 1613,Table 6,10/94 Revision R =Recovery outside of control limits Nn =Value obtained from additional analysis *=See Discussion Page 17 of 18Report No.....10569980_1613TCDD_DFR Page 105 of 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc. Pace Analytical Services,LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax:612-607-6444 Client Spike 1 ID Spike 1 Filename F210805B_01 LCS-92030 PACE Charlotte Spike Recovery Relative Percent Difference (RPD) Results Spike 2 ID Spike 2 Filename F210805B_02 LCSD-92031 Method 1613B Spike 1 Spike 2 Compound %REC %REC %RPD 2,3,7,8-TCDD 101 109 7.6 %REC = Percent Recovered RPD =The difference between the two values divided by the mean value Page 18 of 18Report No.....10569980_1613TCDD_DFR Page 106 of 106