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HomeMy WebLinkAboutNCG240016_2021 DMR_20210927MECKLENBURG COUNTY Land Use & Environmental Services Agency Solid Waste September 24, 2021 DEQ Mooresville Regional Office Attn: DEMLR Stormwater Program 610 East Center Avenue Suite 301 Mooresville, NC 28115 Attention: DEMLR Stormwater Program Subject: Discharge Monitoring Report Mecklenburg County Compost Central — Certificate of Coverage No. NCG240016 Dear Central Files: Please find enclosed the Discharge Monitoring Report, August 2021, for Mecklenburg County Compost Central, a Type I facility located at 5631 West Blvd, North Carolina. If you have any questions, please contact me at 704-634-7705 or by email at khaliem.adams@meckleliburjzcounlync.gov. Sincerely, Khaliem Adams Solid Waste Environmental Specialist Enclosed: 2021 DMR PEOPLE • PRIDE PROGRESS • PARTNERSHIP 2145 Suttle Avenue Charlotte, North Carolina 28208 www.wipeoutwaste.com NCDEQ Division of Energy, Mineral and Land Resources Stormwater Discharge Monitoring Report (DMR) Form for NCG240000 Compost Operations Click here for instructions Complete, sign, scan and submit the DMR via the Stormwater NPDES Permit Data Monitoring Report (DMR) Upload form within 30 days of receiving sampling results. Mail the original, signed hard copy of the DMR to the appropriate DEMLR Regional Office. Certificate of Coverage No. NCG24 0016 Person Collecting Samples: Khaliem Adams Facility Name: Mecklenburg County Compost Central Laboratory Name: Pace Analytical Facility County: Mecklenburg Laboratory Cert. No.: Discharge during this period: ✓❑ Yes ❑ No (if no, skip to signature and date) Has your facility implemented mandatory Tier response actions this sample period for any benchmark exceedances? ❑✓ Yes ❑ No If so, which Tier (I, II, or III)? Tier 1 A copy of this DMR ha been pI aded electronically via https://edocs.deg.nc.gov/Forms/SW-DMR ❑✓ Yes ❑ No Date Uploaded: q dqW Analytical Monitoring Requirements for Outfalls with Industrial Activities — Benchmarks in (Red) Parameter Parameter Outfall2 Outfall Outfall Outfall Outfall Code N/A Receiving Stream Class N/A Date Sample Collected MM/DD/YYYY 08/19/2021 46529 24-Hour Rainfall in inches 0.27in C0530 TSS in mg/L (100) 3.7 00340 Chemical Oxygen Demand (120) 87.2 31615 Fecal Coliform in colonies per 100 ml 2400 (1000) 600 Total Nitrogen in mg/L (30) 2.0 665 Total Phosphorus in mg/L (2) 0.20 400 pH in standard units (6.0-9.0) 7.40 Copper, total recoverable in mg/L 01119 (0.030) 0.0056 Lead, total recoverable in mg/ L 01051 (0.075) <0.0050 Zinc, total recoverable in mg/ L 01094 (0.126) < 0.010 Additional parameters for outfalls in drainage areas that use >55 gallons per month of new hydraulic oil on average 00552 Non -Polar Oil & Grease in mg/L (15) <5.0 Estimated New Motor/Hydraulic Oil NCOIL Usage in gal/month 75gal/month Notes (optional): "I certify by my signature below, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false info r, including the possibility of fines and imprisonment for knowing violations." Signature of Wmittee or Delegated Authorized Individual Date Email Address Phone Number ✓ C�, I,.- Z r . �C E_ , ,-I N ` /J e✓ ILA k, C 611- 1? L 1 -5— '✓ rjF-c-,-3/7-j�-17 Facility Name I Sample Location Sample Time pH I Date Device Used to Sample Mecklenburg County Compost Central I Outfall 2 1127 7.40 1 8/19/2021 Horiba pH meter (�Ia'ne Analytical www.pacelabs.com August 26, 2021 Darren Steinhilber Mecklenburg County Solid Waste 2145 Suttle Ave Charlotte, NC 28208 RE: Project: Compost Central 1 Pace Project No.: 92556646 Dear Darren Steinhilber: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on August 19, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Khaliem Adams, Meclenburg County Solid Waste REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Compost Central 1 Pace Project No.: 92556646 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Compost Central 1 Pace Project No.: 92556646 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92556646001 Outfall 2 EPA 1664B CJM 1 PASI-C EPA 1664B CJM 1 PASI-C EPA 200.7 Rev 4.4 1994 CBV 3 PASI-A SM 9222D-2006 KDF 1 PASI-C SM 254OD-2011 MJP 1 PASI-A TKN+NO3+NO2 Calculation DMN 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 5220D-2011 JP1 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Compost Central 1 Pace Project No.: 92556646 Sample: Outfall 2 Lab ID: 92556646001 Collected: 08/19/21 11:41 Received: 08/19/21 12:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 08/24/21 10:50 M1 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 08/24/21 10:50 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper 0.0056 mg/L 0.0050 1 08/25/21 12:19 08/26/21 10:29 7440-50-8 Lead ND mg/L 0.0050 1 08/25/21 12:19 08/26/21 10:29 7439-92-1 Zinc ND mg/L 0.010 1 08/25/21 12:19 08/26/21 10:29 7440-66-6 MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services - Charlotte Fecal Coliforms 2400 CFU/100 mL 1.0 1 08/19/21 17:24 08/20/21 15:38 D6,u2 2540D Total Suspended Solids Analytical Method: SM 2540D-2011 Pace Analytical Services - Asheville Total Suspended Solids 3.7 mg/L 2.5 1 08/25/21 12:41 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services - Asheville Total Nitrogen 2.0 mg/L 0.52 1 08/26/21 14:41 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Kjeldahl, Total 2.0 mg/L 0.50 1 08/25/21 22:09 08/26/21 04:55 7727-37-9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, NO2 plus NO3 ND mg/L 0.040 1 08/25/21 10:19 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 0.20 mg/L 0.050 1 08/25/21 19:05 08/25/2122:43 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services - Asheville Chemical Oxygen Demand 87.2 mg/L 25.0 1 08/26/21 00:26 08/26/21 06:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 642347 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92556646001 METHOD BLANK: 3371321 Associated Lab Samples: 92556646001 Parameter Units Oil and Grease mg/L LABORATORY CONTROL SAMPLE: 3371322 Parameter Units Oil and Grease mg/L MATRIX SPIKE SAMPLE: 3371323 Parameter Units Oil and Grease mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 5.0 08/24/2110:50 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 40 33.8 84 78-114 92556646001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 39.6 31.2 77 78-114 M1 SAMPLE DUPLICATE: 3371324 70184515001 Dup Parameter Units Result Result Oil and Grease mg/L 22.3 17.9 RPD Qualifiers 22 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 642348 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92556646001 METHOD BLANK: 3371325 Associated Lab Samples: 92556646001 Parameter Units Total Petroleum Hydrocarbons mg/L LABORATORY CONTROL SAMPLE: 3371326 Parameter Units Total Petroleum Hydrocarbons mg/L MATRIX SPIKE SAMPLE: 3371327 Parameter Units Total Petroleum Hydrocarbons mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 5.0 08/24/2110:50 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 20 19.8 99 64-132 92556646001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 19.8 14.6 69 64-132 SAMPLE DUPLICATE: 3371328 70184515001 Dup Parameter Units Result Result Total Petroleum Hydrocarbons mg/L 9.7 8.6 RPD Qualifiers 12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 642830 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92556646001 METHOD BLANK: 3373202 Matrix: Water Associated Lab Samples: 92556646001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg/L ND 0.0050 08/26/2109:31 Lead mg/L ND 0.0050 08/26/2109:31 Zinc mg/L ND 0.010 08/26/2109:31 LABORATORY CONTROL SAMPLE: 3373203 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Copper mg/L 0.5 0.48 95 85-115 Lead mg/L 0.5 0.46 93 85-115 Zinc mg/L 0.5 0.43 86 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3373204 3373205 MS MSD 92555994002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper mg/L 0.0059 0.5 0.5 0.49 0.49 97 96 70-130 1 Lead mg/L ND 0.5 0.5 0.48 0.48 97 96 70-130 1 Zinc mg/L 0.049 0.5 0.5 0.51 0.51 92 92 70-130 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3373206 3373207 MS MSD 92556646001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper mg/L 0.0056 0.5 0.5 0.50 0.50 99 98 70-130 1 Lead mg/L ND 0.5 0.5 0.47 0.47 94 94 70-130 0 Zinc mg/L ND 0.5 0.5 0.46 0.45 90 89 70-130 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 641744 Analysis Method: SM 9222D-2006 QC Batch Method: SM 9222D-2006 Analysis Description: 9222D Fecal Coliform(MF) - CHT Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92556646001 METHOD BLANK: 3368290 Associated Lab Samples: 92556646001 Parameter Fecal Coliforms SAMPLE DUPLICATE: 3368291 Parameter Fecal Coliforms Matrix: Water Blank Reporting Units Result Limit Analyzed Qualifiers CFU/100 mL ND 1.0 08/20/21 15:38 92556646001 Dup Units Result Result RPD Qualifiers CFU/100 mL 2400 600 120 D6,u2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 642803 Analysis Method: SM 2540D-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92556646001 METHOD BLANK: 3373128 Associated Lab Samples: 92556646001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3373129 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3373604 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 08/25/2112:39 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 250 100 90-110 92556934001 Dup Result Result RPD Qualifiers 164 152 8 SAMPLE DUPLICATE: 3373605 92556647001 Dup Parameter Units Result Result Total Suspended Solids mg/L 77.3 84.7 RPD Qualifiers 9 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 642921 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92556646001 METHOD BLANK: 3373750 Associated Lab Samples: 92556646001 Parameter Units Nitrogen, Kjeldahl, Total mg/L LABORATORY CONTROL SAMPLE: 3373751 Parameter Units Nitrogen, Kjeldahl, Total mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.50 08/26/2104:37 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 10 9.8 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3373752 3373753 MS MSD 92556375002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 4.5 10 10 16.3 15.8 118 113 90-110 3 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3373754 3373755 MS MSD 92556397001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 0.98 10 10 11.1 11.3 101 103 90-110 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 642731 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92556646001 METHOD BLANK: 3373000 Associated Lab Samples: 92556646001 Parameter Units Nitrogen, NO2 plus NO3 mg/L LABORATORY CONTROL SAMPLE: 3373001 Parameter Units Nitrogen, NO2 plus NO3 mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.040 08/25/2109:57 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3373002 3373003 MS MSD 92554781001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L ND 2.5 2.5 2.5 2.5 98 100 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3373004 3373005 MS MSD 92556164004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 22.2 2.5 2.5 24.5 24.2 93 80 90-110 1 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 642698 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92556646001 METHOD BLANK: 3372910 Associated Lab Samples: 92556646001 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 3372911 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 08/25/2122:25 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3372912 3372913 MS MSD 92554588001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 4.3 2.5 2.5 7.1 7.2 112 117 90-110 2 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3372914 3372915 MS MSD 92554588003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 4.7 2.5 2.5 7.3 7.4 104 109 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 1 Pace Project No.: 92556646 QC Batch: 642951 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92556646001 METHOD BLANK: 3373892 Associated Lab Samples: 92556646001 Parameter Units Chemical Oxygen Demand mg/L LABORATORY CONTROL SAMPLE: 3373893 Parameter Units Chemical Oxygen Demand mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 08/26/2106:28 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 750 751 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3373894 3373895 MS MSD 92556451001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 2310 100 100 2430 2560 118 245 90-110 5 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Compost Central 1 Pace Project No.: 92556646 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. u2 Colonies are too numerous to count. Actual result may be greater than reported. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/26/2021 04:10 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Compost Central 1 92556646 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92556646001 Outfall 2 EPA 1664B 642347 92556646001 Outfall 2 EPA 1664B 642348 92556646001 Outfall 2 EPA 200.7 Rev 4.4 1994 642830 EPA 200.7 Rev 4.4 1994 642920 92556646001 Outfall 2 SM 9222D-2006 641744 SM 9222D-2006 641745 92556646001 Outfall 2 SM 254OD-2011 642803 92556646001 Outfall2 TKN+NO3+NO2 643289 Calculation 92556646001 Outfall 2 EPA 351.2 Rev 2.0 1993 642921 EPA 351.2 Rev 2.0 1993 643080 92556646001 Outfall 2 EPA 353.2 Rev 2.0 1993 642731 92556646001 Outfall 2 EPA 365.1 Rev 2.0 1993 642698 EPA 365.1 Rev 2.0 1993 643050 92556646001 Outfall 2 SM 5220D-2011 642951 SM 5220D-2011 643092 Date: 08/26/2021 04:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 18 aeeAnalytical j Document Name: Sample Condition Upon Receipt(SCUR) Document Revised: October 28, 2020 Page 1 of 2 Document No.: F-CA4-CS-033-Rev.07 Issuing Authority: Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville %Raleigh❑ Mechanicsville❑ Atlanta❑ xernersville❑ SampleodoClient Upon Receipt P *et WO# :92556646 A06. i r. A" - �ut .1 ftt: I I II f Courier: ❑Fed Ex ❑UPS ❑U5P5 J bXIent ❑ Commercial ❑Pate [:]Other: Ills lii II I j i 92556646 Custody Seal Present? ❑Yes � Seals Intact? ❑yes Date/Initials Person Examining Contents: AA $�Z f Packing Material: ❑Bubble Wrap ❑Bubble Bags lone ❑ Other Blofoglcal Tissue Frozen? Thermomete : [:]Yes [:]No V/A I P-r— in. g"_'i'" fAF` It et ❑Blue (—]None YPe ui ue: Correction Factor: Cooler Temp: Add/Subtract (*Q > i Temp should be above freezing to 6'C ❑Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('C_ { _ has begun USDA Regulated Soil ( v/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate From a foreign Source (Internationally, nYes FIN❑ .-..a:.._ -.._ _..., o.._w_ o _- I M. n.._ Comments/Discrepancy: Chain of Custody Present? Syes ❑No ❑N/A 1. 50m les Arrived within Hold Time? bC ❑No ❑N/A 2. Short Hold Time Analysis J<72 hr.)? es []NO ❑N/A 3. Rush Turn Around Time Requested? Elves o ❑N/A 4. Sufficient Volume? *aes No []N/A 5. Correct Containers Used? -Pace Containers Used? 12fes QXs ❑No ❑No ❑N/A ❑N/A 6. Containers Intact? es ❑No ❑N/A 7. Dissolved analysis; Samples Field Filtered? ❑Yes []No '@I/A B. Sample Labels Match COC? -includes Date/Time/ID/Analysis Matrix: \N1— 'Yes []No ❑N/A 9. Headspaee in VOA Vials (>5-5mm)? Yes [-]No N/A 10. Trip Blank Present? Trip Blank Custody Seats Present? []Yes ❑Yes []NO EJNo QVIA - lA 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION —Person-cont-acted. OaWrime: Project Manager SCURF Review: Date: Project Manager SRF Review: Date: Field Data Required? []Yes ❑No Document Name: Document Revised! October 28, 2020 _r ace Analytical' Sample Condition Upon Recelpt(SCUR) Page 2 of 2 Document No.: Issuing Authority: F-CAR-CS-0334Rev.07 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles Project WO# : 92556646 PM: MWB Due Date: 08/26/21 CLIENT: 92-MECK CO u z a Z v m a c V a 2 v v Q c V Z v v a c V Z Z d N v a O yr U .-, y n 0 V 0 z m a V u — n n T O ? v v C 0 l7 u a z v is d a v n z IV V n G ry = YQJ V O N v a 0 N z z z E z z z O 2 a do ¢ 2 m o Z Y ro X eo I �-, ,n _� ¢ z ,� m g x d Z c C 2 c z 7 a a 29 E m M a E 3 a m a 1 E M0 > rn 0. m a E > N a m a 4 a`i _ 7 .1 rL m a NN v7 O a m n E z m 4 m s E 4 a 4 N 0 V a ro 5 G 0 3 a E ¢ 7 ri l7 a v E a = .ti l7 a E ¢ N m lJ a E ¢ N to C9 a E a E LA Jf M o ,�.� m 4 M l7 a a 0 61 `� a O > oq Q l7 > a 0 > O M Q C7 > a D > E It a Q t7 o Y Q O > y, .2 Y V > E ry F u1 6 �+ E N d Ln O no a m d m c oE > 4 t7 a c v' E p > r, > ¢ E 0 C W a 1 6� ! 6 2 4 5 6 7 8 9 10 . I 11 12 N, pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservatlan adjusted Amount of Preservative added Lot p Note:-Wheneverthere-is-a-discrepancy-affecting North-C-aralina-compliance-samp les,-a ropy -of this -Form -will -tie sent -to tha-North 6arofina-OEMNR-Gertihcation-Office (La. Out of hold, Incorrect preservative, out of temp, incorrect containers. � c � R 17 O W o J_ J Z z N a 6 m� � C 7 c6 w Z LU1 O. 9 `u C Ol = iz C E E .9 m v s O @ ❑ E u E a If « � +y O cr a a1 - 7 � � N n ? W -D 0 � � c c M — Q 2 m V F N n` } Ti.0 u m cc E C 0 U 1 cl G N i" Q E q � O❑ O F-it Z y U N C ❑ 13 d ° O O D a �¢ m m U o ui 0 a U a EL a. i LL Q U m O CL CZ C tG � Q L a = m � U F- v rn v 3 c Y O E m u U H a O E r N c E P U O v 'O Y di m T v IL sc � O y vomit V O T U W d ❑ d G m 0 j 0 0 L L m 0 0 n E � V1 9 eo m u T � � � n c o o 0 j E21 a d N oU 0 a m a E R , m ro C? � m € C c m vi E d N m ❑ U L) Z ❑ r v a a a E° aPi V) ix U Q c) w a x 699i "3H'J°JS Hdi VM `J80 SIMO N d01 L'OOZ );UA!u+NNl) ue8oJl!N lalol ROO leant SSi snjoydsoyd IQlo.U000 NIA 3s$1 sosAleuV jay10 IoueyleW £OMON m HOeN y MH EONH 4OSZH pamesaldun SU3NIV1NO0 SO # 1401LO311001V dW3i 3ldYNVS w H Z uj LL ❑LU 4 U W J O U � } !Q N LL C (dW00=0 imo-07 3dA131dWVS (yal ay sapw piles aas) 3000 X181vlN 0. Uit ��� u d'St `u� N p 0 3 3 d v°l 0 3 a S r 2 ❑ o O' '� a � W CL -J `m m 3 JL ` c E N L Q L Q U"a N D E N N # W311 I -I -1 MI CI -I -1 tit '01 '1 C-'I - r a ❑ N 2 w (NIA) Izelul seldLueS --(N-1),T Japoo paleaS Apo)sno (NIA) and ua penie0ed 3 Ui dW31 D V W d LU J J c7 a. N Q 4 ZN Vl Q O O m E � z z a: LU Z Z a a. N Page 18 of 18 N'r-110 Environmental Quality Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit https://deg.nc.izov/about/divisions/enerayy-mineral-land- resources/energy-mri�neral-land-permits/stormwater-permits/npdes-industrial-sw#tab-4 / tj Permit No.: N/C/%/ �/�/ a Vl _ olPl or Certificates of Coverage No.: N/C/G/,/ 7 ��/ Ul Facility Name: / V1 ( County: c ?4 Inspector: + Date of Inspection: Time of Inspection: _ Total Event Precipitation (inches) 1G 21 D-d,-7/� 'a 5+ r !% % d All permits require qualitative monitoring to be performed during a "measurable storm event." A"measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DEMLR Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: 11-'VfJL (Signature of Permittee or Designee) 1. Outfall escription: ' Outfall 1 Structure (pipe, ditch, etc.): e' Receiving Stream: ibe the industrial activities that occur within the outfall drainage area: �' Page 1 of 2 SWU-242, Last modified 07/28/2017 2. Color: Describe the color of (light, medium, dark) as descriptors: _ 3. Odor: Des chlorine odor, etc.): colors (red, brown, blue, etc.) and tint istinct odors that the discharge may have (i.e., smells strongly of oil, weak �-r d o lP r-+p li 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 3 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no soli and 5 is extremely muddy: 1 2 3 4 5 r' 7. Is there an foam in the stormwater discharge? O Yes No. y g 8. Is there an oil sheen in the stormwater discharge? OYes c5 No. t� 9. Is there evidence of erosion or deposition at the outfall? O Yes 4240. 10. Other Obvious Indicators of StormwatJerPollution: List and describe n (!fi t d f -S Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242, Last modified 07/28/2017 m