NC0001899_monitoring report_19871116

•
Allied fibers
Allied-Signal Inc.
Fibers Division
P.O. Box 166
Moncure, NC 27559
Telephone [phone]
November-1 ,'1987
Mr. Dale 0vercash.,
NPDES Group Leader
Division of Environmental Management
Dept. of Natural Resources &
Community Development
512 North Salisbury St.
Raleigh, N. C. 27611
Dear Mr. 0vercash:
Enwright Associates, Inc., conducted priority pollutant
monitoring for Allied-Signal's Moncure Plant (NPDES Permit No.
NC0001899) on June 2-4, 1987.
Two 24-hour composite samples and daily grab samples were
collected from the wastewater treatment plant influent, 001 outfall
and 002 outfall. A 24-hour composite sample and grab sample were
taken of intake (drinking) water.
Enclosed is a copy of the priority pollutant monitoring
report for your information and file.
Please call me at the following telephone number if you have
any questions about the report [phone].
WLB/khh
Enclosure
cc: B. G. Casey
D. A. McCaig
A. T. Roy
Sincerely, '
;2 , / v c —.
W. L. Boyer, Supervisor
Environmental & Industrial Hygiene
Allied
Signal

ENWRIGHT
ASSOCIATES INC.
PRIORITY POLLUTANT MONITORING REPORT
for the
RLL IEIJ SItiNAL PLANT 51 TE
Moncure. NC
June 1987
C 0 N T
PLANNERS, ARCHITECTS, ENGINEERS AND SCIENTISTS SPECIALIZING IN LAND, BUILDING AND ENVIRONMENTAL SERVICES

INDEX
I. Sample Preparation and Methodology
II. Analytical Results
III. Field Sampling Reports

I. Sample Preparation and Methodology

Sample Preparation and Preservatives:
The sampling program was conducted by Mr. Robert Mabry of Enwright
Laboratories, Inc. All sample bottles for this project were purchased
new and scrupulously cleaned with soap and warm water, an acetone
rinse, a hydrochloric acid rinse and several deionized water rinses.
In addition, sample bottles for organic analysis were baked in a
convection oven at 105 °C for two hours. The following is a synopsis
of the sample bottle requirements and preservatives used for this
project.
Parameter Container
Preservatives
Anions (Sulfate, MBAS
Fluoride, Bromide,
Nitrate) } gal. plastic Cool to 4 °C
Sulfite BOD bottle Cool to 4 °C
Cyanide
Total Phenolics
Metals
Total Coliform
Pesticides
Volatile Organics
++ gal. plastic Ascorbic acid,
NaOH to pH > 12,
Cool to 4 °C
quart glass H2SO4 to pH < 2,
Cool to 4 °C
250 ml plastic HNO3 to pH < 2,
Cool to 4 °C
150 ml glass, Sodium Thiosul-
autoclaved fate, Coal to
4 °C
quart amber glass Cool to 4 °C
100 ml amber glass Cool to 4 °C
with teflon septum
Non -Volatile Organics quart amber glass Cool to 4 °C
These water samples were delivered to Enwright Laboratories by Robert
Mabry on June 4, 1987. The samples were stored on ice overnight and
logged in on June 5, 1987.

Methodology:
Enwright Laboratories, Inc. analyzed seven water samples for various
priority pollutant parameters. The following report represents
state-of-the-art technology in analytical instrumentation using EPA
approved methodology, as outlined below:
Parameter EPA Method No.
Sulfate 375.4
MBAS 425.1
Fluoride 340.2
Bromide 320.1
Boron 212.3
Sulfite 377.1
Cyanide 335.2
Sulfide 376.1
Nitrate 352.1
Total Phenolics 420.1
Antimony 204.1
Beryllium 210.1
Chromium 218.1
Lead 239.1, 239.2
Nickel 249.1
Silver 272.1
Zinc 289.1
Aluminum 202.1
Barium 208.1
Cobalt 219.1
Iron 236.1
Magnesium 242.1
Molybdenum 246.1
Manganese 243.1
Tin 282.1
Titanium 283.1
Arsenic 206.2
Cadmium 213.1
Copper 220.1
Mercury 245.1

Parameter EPA Method No.
Selenium 270.2
Thallium 279.1
Total Coliform SM 909 A
Drinking Water Pesticides SM 509 A
Volatile Organics 624
Non -Volatile Organics 625
* From EPA 600/4-79-020 "Methods for Chemical Analysis of Water
and Wastes", "Standard Methods for the Examination of Water and
Wastewater", and 40 CFR 136.
Metals analyses were conducted using Flame Atomic Absorption for most
metals. Furnace Atomic Absorption was used for lead, chromium,
cadmium, arsenic, and selenium. Cold vapor atomic absorption was used
for mercury analysis. All metals analyses were performed on either
model 551 or 951 instrumentation laboratories atomic absorption
spectrophotometer.
Volatile organic analyses were performed by purging 5 ml of the sample
with nitrogen gas. The purged organics were trapped onto a Tenax
column. The Tenax column was rapidly heated desorbing the organics
onto the analytical column, a DB-5 capillary. Quantitation and
identification were by model 5970 Hewlett Packard Mass Selective
Detector.
Non-volatile organics were extracted into methylene chloride,
concentrated, and injected directly onto the DB-5 analytical column.
The Mass Selective Detector was employed for quantitation and
identification.
As part of Enwright Laboratories routine quality control, 10 percent
spikes and duplicates were analyzed with these samples. Precision and
accuracy were within quality control limits.
A less than value indicates that the parameter of interest was below
the detection limit of the method and that, within the sensitivity of
the method, nothing was found.

II. Analytical Results
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ENWRIGHT
LABORATORIES
CERTIFICATE OF ANALYSIS
Second Amended Report
CLIENT: Allied Fibers - Moncure Plant DATE RECEIVED: 6/5/87
PROJECT: Priority Pollutant Analysis DATE COMPLETED: 7/15/87
DATE AMENDED: 8/18/87 DATE REPORTED: 7/24/87
Second Amended Report: 9/9/87
LAB NO. 87-41500 87-41501
SAMPLE ID: Finished Drinking Water Comp. Finished Drinking Water Grab
Parameters:
Fluoride <0.2
Nitrate Nitrogen 0.7
Arsenic (ug/1) <1
Barium <0.1
Cadmium (ug/1) <1
Chromium (ug/1) 1
Lead (ug/1) <1
Mercury (ug/1) <0.2
Selenium (ug/l) <3
Silver <0.01
Total Coliform
(Colonies/100 ml)
Volatile Organics: (Method 624) (ug/1)
<1
Chloromethane <10
Vinyl Chloride <5
Bromomethane <10
Chloroethane <10
1,1-Dichloroethylene <5
Methylene Chloride <5
Trans-1,2-Dichloroethylene <5
1,1-Dichloroethane <5
Chloroform 270
1,1,1-Trichloroethane <5
1,2-Dichloroethane <1
Benzene <5
to
44
25 Woods Lake Road (29607) • Post Office Box 5287 • Greenville, South Carolina 29606 • [phone]

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Allied Fibers - Moncure Plant
Priority Pollutant Analysis
Laboratory Report, Page 2
LAB NO. 87-41500 87-41501
SAMPLE ID: Finished Drinking Water Comp. Finished Drinking Water Grab
Parameters:
Volatile organics: (Method 624) (ug/1) (Can't)
Carbon Tetrachloride <1
Trichloroethylene <1
1,2-Dichloropropene <1
Bromodichloromethane 24
2-Chloroethylvinylether <5
Cis-1,3-Dichloropropene <5
Toluene <5
Trans-1,3-Dichloropropene <5
1,1,2-Trichloroethane <5
Dibromochloromethane <5
Tetrachloroethylene <5
Chlorobenzene <5
Ethylbenzene <5
Bromoform <5
1,1,2,2-Tetrachloroethane <5
1,3-Dichlorobenzene <5
1,4-Dichlorobenzene <5
1,2-Dichlorobenzene <5
Trichlorofluoromethane <5
Acrylonitrile
Acrolein
Pesticides: (ug/1)
Endrin <0.1
Lindane <0.1
Methoxychlor <0.2
Toxaphene <0.5
Herbicides: (ug/1)
2,4-D <0.1
2,4,5-TP (silvex) <0.1
<10
<10
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Allied Fibers - Irbrtu a Plant
Priority Pollutant Analysis
Laboratory Report, Page 3
LAB M. 87-41502 8741503 87-41504 87-41505 87-41506
SAMPLE ID: Inf. Camp. 6-3 Inf. Grab 6-3 Inf. Camp. 6-4 Inf. Grab 6-4 001/003 Corp. 6-3
Parameters:
Sulfate 240 270 180
I+BAS 4.2 7.8 0.3
Fluoride 0.29 0.28 0.33
Bromide 2.3 9.0 <1.0
Baron 0.3 0.4 0.4
Sulfite 6.6 5.2 -
Cyanide - <0.02 <0.02 -
Sulfide <0.1 <0.1 -
Total Phenolics 0.053 0.035 -
Total Antimony <0.01 <0.01 <0.01
Total Beryllium <0.01 <0.01 <0.01
Total Chromium <0.05 <0.05 <0.05
Total Lead 0.3 0.4 <0.1
Total Nid<el <0.05 - <0.05 - <0.05
Total Silver <0.01 <0.01 <0.01
Total Zinc 0.77 0.40 - 0.18
Total Aluminum 0.7 0.8 0.3
Total Barium <0.1 <0.1 <0.1
Total rrhalt <0.05 <0.05 <0.05
Total Iron 3.3 2.3 0.56
Total Magnesium 5.0 1.5 5.1
Total Iblybderxm <0.3 <0.3 <0.3
Total Manganese 0.20 0.27 0.04
Total Tin <1.0 <1.0 <1.0
Total Titanium <1.0 <1.0 <1.0
Total Arsenic (ug/1) <1 <1 <1
Total Caotnum <0.01 <0.01 <0.01
Total Capper 0.22 0.31 - 0.09
Total Merwry (ug/1) <0.2 <0.2 <0.2
Total Selenium (ug/1) <3 <3 - <3
Total Thallium <0.1 <0.1 <0.1
Pesticides: (ug/1)
Erdrin
Lindane
Methoxychlor
Toxaphene
<0.1 - <0.1 <0.1
<0.1 <0.1 <0.1
<0.2 <0.2 <0.2
<0.5 <0.5 <0.5

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Allied Fibers - P'ku ure Plant
Priority Pollutant Analysis
Laboratory Report, Page 4
LAB NO.
SANPLE ID:
Parameters:
87-41502 87-41503 87-41504 87-41505 87-41506
Inf. Comp. 6-3 Inf. Grab 6-3 Inf. Carp. 6-4 Inf. Grab 6-4 001/003 Camp. 6-3
Volatile Organics: (Method 624) (ug/1)
Chlarametfane <10 <10
Vinyl Chloride <10 <10
Bramamethane <10 <10
Chloroethene <10 <10
1,1-0ichloraethylene <5 <5
Methylene Chloride <5 — <5
Trans-1,2-0iclloraethylene <5 <5
1,1-0ith1or ehane <5 <5
Chloroform 48 77
1,1,1 Trichlornethane 20 10
1,2-0ichloroethene <5 <5
Benzene <5 <5
Carbon Tetrachloride — <1 <1
Tridiioraetf ylene 3 3
1, 2-Dithloraprapene <1 <1
Bromodichlorarethane <5 <5
2-Chloraettylvinylether — <5 <5
Cis-1,3-0ith1oroprapene <5 <5
Toluene <5 <5
Trans-1,3-0ichlorapropone <5 <5
1,1,2-Trich1 methane <5 <5
DibramochlarnnEthene <5 <5
Tetrachlaroethylene 6 <5
Chlorobenzene <5 <5
Ethylbenzere <5 <5
O�oNJform <5 <5
1,1,2,2 T <5 <5
1, 3-0ichlorabenzene <5 <5
1, 4-0id11orcbenzene <5 <5
1, 2-0ithlorabenzene <5 <5
Trichlorofiuorcuethane <5 — <5
Acrylanitrile <10 <10
Acrolein <10 <10

Allied Fibers - (%xEure Plant
Priority Pollutant Analysis
Laboratory Report, Page 5
LAB N3. 87-41502 87-41503 87-41504 87-41505 87-41506
SAMPLE ID: Inf. Comp. 6-3 Inf. Grab 6-3 Inf. Crnp. 6-4 Inf. Grab 6-4 001/003 Colo. 6-3
Parameters:
Arids: (Method 625) (ug/1)
Phenol 65
2- Chlarnphanl <10
2-Nitrcphenol <10
2,4-0imett yl.pheno1 <10
2,4-0ichloraphenol <10
4-0ilaro-3-Plethyipheno1 <10
2,4,6-Trici1orcphenol <10
2,4-0initrap- -oi <10
4-Nitrapha-o1 <10
4,6-0initro-2-Methyipheiol <10
Penlachloraphenol <10
Base/Neutrals: (Method 625 (ug/1)
310 <10
<10 <10
<10 — <10
<10 <10
<10 <10
<10 — <10
<10 <10
<10 — <10
<10 <10
<10 <10
<10 <10
N- itrosodinethylamine <10 <10 — <10
8is(2-01Loroethyl)Ether <10 — <10 <10
Bis(2-Ch1oroisaprc yi)Ether <10 <10 <10
N-Nitrosodipr°pylamine <10 <10 <10
Hexathiaroethane <10 <10 —
<10
Nitrobenzene <10 <10 <10
Isophorine <10 <10 <10
Bis(2-0hloroethoxy)Methane <10 <10 <10
1, 2, 4-Tridtl.orabeizene <10 <10 <10
Naphthalene <10 — <10 — <10
Hexachlorcbutadiene <10 <10 <10
Hexachlorocyclopentadiene <10 <10 <10
2-Chloranaphthale-ie <10 <10 — <10
Dinethyl Phthalate <10 <10 <10
Acenaphthyme <10 — <10 <10
Acenaphtheie <10 <10 <10
2,4-Dinitrotolueie <10 <10 <i0
2,6 Dinitrotoluene <10 <10 <10
Diethyl Phthalate <10 <10 <10

Allied Fibers - I''bncure Plant
Priority Pollutant Analysis
Laboratory Report, page 6
LAB M). 87-41502 87-41503 87-41504 87-41505 87-415C6
SAMPLE ID: Inf. Carp. 6-3 Inf. Grab 6-3 Inf. Comp. 6-4 Inf. Grab 6-4 001/003 Corte. 6-3
Parameters:
Base/Neutrals: (Method 625) (ug/1)
4- hl.oropheryl Phenyl Ether <10 <10 — <10
Fluorate <10 <10 <10
N-Nitrosodiphenylamine <10 <10 <10
4--Branophenyl Phenyl Ether <10 <10 <10
Hexachlorabeizene <10 <10 — <10
Phenanthrene <10 <10 <10
Anthraoene <10 <10 <10
Di-N-Butyl Phthalate 18 35 <10
Fl.uaranthe-e <10 <10 <10
Benzidine <50 <50 <50
Pyrate <10 — <10 <10
Butyl Beizyl Phthalate <10 <10 <10
3+ <20 <20 <20
Benzo(a)Anthracene <10 — <10 <10
Bis(2-Ethylhexyl) Phthalate 43 60 — <10
at ysene <10 <10 <10
Di-N-Octyl Phthalate 33 <10 <10
Benzo(b)Fluorathene <10 <10 <10
Benzo(k)Fluorartbhe a <10 <10 <10
Benzo(a)Pyre a <10 <10 <10
Indeno(1,2,3-cd)Pyrene <10 <10 <10
Dibenzo(ah)Anthracene <10 <10 <10
Benzo(ghi)Perylene <10 <10 <10
1,2-Diphenyl Hydrazine <10 <10 <10
Pl-ti ri da/H ti r s: (method 625) (ug/1)
<20 — <20 <20
QO <20 <20
<20 <23 <20
<20 QO <20
<23 <20 — <20

Allied Fibers - ffbmuce Plant
Priority Pollutant Analysis
Laboratory Report, Page 7
LAB IAA. 87-41502 87-41503 87-41504 87-41505 87-41506
SAMPLE ID: Inf. Coop. 6-3 Inf. Grab 6-3 Inf. Camp. 6-4 Inf. Grab 6-4 001/033 Comp. 6-3
Parameters
Chlordane QO — <20 QO
4,4-00E <20 <20 <20
4, 4-0OT <20 <20 <20
Dieldrin <20 <23 <20
Endosulfan I <50 <50 <50
Endosuslfan II <50 <50 <SO
Endosu]San Sulfate <50 <50 <50
Erdrin <20 <20 QO
Erdrin Aldehyde <20 <20 <20
Heptachlor <20 <20 QO
Heptachlor Epoxide QO <20 QO
Toxaphene <100 <100 <100
PC8 1016 <50 <50 <50
PC8 1221 <50 — <50 <50
PCB 1737 <50 <50 ____ <50
PC8 1242 <50 <50 <50
PCB 1248 <50 <50 <50
PCB 1254 <50 <50 <50
PCB 1260 <50 <50 <50
4,4-000 QO <20 QO

Allied Fibers - Monaure Plant
Priority Pollutant Analysis
Laboratory Bart, Page 8
LAB N3. 87-41507 87-41508 87-41509 87-41510 87-41511
SMRE ID: 0:1/033 Grab 6-3 031/003 Comp. 6-4 001/003 Grab 6_4 002 Camp. 6-3 CO2 Grab 6-3
Parameters:
Sulfate 180 6.8 -
(rBAS 0.2 0.1 -
Fluoride 0.33 <0.2 -
8ramide 0.9 1.4 -
Boron 0.45 - <0.1 -
Sulfite <2 <2 <2
Cyanide <0.02 - <3.02 <0.02
Sulfide <1 - <1 <1
Total Phenolics 0.032 - 0.032 - 0.006
Total Antintny <0.01 <0.01 -
Total Berylliun <0.01 <0.01 -
Total Chromium <0.05 <0.05 -
Total Lead <0.1 <0.1
Total Nickel <0.05 <0.05 -
Total Silver - <0;01 <0.01 -
Total Zinc 0.15 0.02 -
Total Aluninun 0.2 0.6 -
Total Bariun <0.1 <0.1 -
Total Cobalt <0.05 <0.05 -
Total Iran 0.35 5.5 -
Total magnesiun 4.9 -- 1.6
Total Maly m <0.3 <0.3 -
Total Manganese 0.03 0.44 -
Total Tin <1.0 <1.0 -
Total Titanium - <1.0 - <1.0 -
Total Arsenic (ug/1) -- 3 4 -
Total Cadniun <0.01 <0.01 -
Total Capper 0.07 <0.03 -
Total Mercury (ug/i) - <0.2 <0.2 -
Total Selenium (ug/i) <3 <3
Total Thallium <0.1 <0.1 -
Pc ticides: (ug/1)
Erdrin
Lindane
Methoxychior
Toxaph ne
<0.1 <0.1 <0.1
<0.1 <0.1 <0.1
<0.2 - <0.2 <0.2
<0.5 <0.5 <0.5

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Allied Fibers - Monc re Plant
Priority Pallutant Analysis
Laboratory Report, Page 9
LAB ND. 87-41507 87-41 SE 87-41509 87-41510 87-41511
SPORE ID: 031/003 Grab 6-3 001/003 Cap. 6-4 001/033 Grab 6-4 002 Cap. 6-3 032 Grab 6-3
Parameters:
Volatile Organics: (Method 624) (ug/1)
Chlorcaethane <10 <10 <10
Vinyl Chloride <10 <10 <10
Brnmuet1 ene <10 --- <10 <10
Chloraethane <10 <10 <10
1,1-0ichlaroethylene <5 <5 <5
Methylene Chloride <5 --- <5 <5
Trans-1,2-0ichloroethylene <5 <5 <5
1,1 <5 <5 <5
Chloroform 37 11 29
1,1,1-Trichlaroethane <5 6 6
1,2 <5 <5 <5
Benzene <5 <5 <5
Carbon Tetrachloride <1 <1 <1
Trichloroet ylene <1 <1 <1
1,2-0i.chlarapropene <1 — <1 —
<1
Branodichloromethane 10 <5 <5
2-0iloroethylvinylether 6 — <5 <5
Cis-1,3-0idh1arcprcpene <5 6 <5
Toluene 6 <5 <5
Trans-1,3-0ichlorcpropene <5 -- <5 <5
1 ,1 ,2-Trichloroethane <5 6 <5
DibromochLararethare <5 <5 <5
Tetra±loroethyiene <5 6 6
Chiorabenzene <5 <5 <5
Ethylbenzene 6 <5 <5
8 J1jf'orm <5 <5 <5
1 ,1 ,2,2-Tetrachloroethane <5 '— <5 <5
1►3-Dichlorcbenze-ie <5 <5 6
1,4-0ichlarabenzene <5 6 <5
1,2-0ichlorcbenzeie <5 <5 <5
Trichlarofluoranethane 6 6 <5
Acrylanitrile
Acrolein
<10
<10
<10 <10
<10 <10

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Allied Fibers - Mbncure Plant
Priority Pollutant Analysis
Laboratory Report, Page 10
LAB N0. 87-41507 87-41506 87-41503 87-41510 87-41511
SPIRE ID: 001/003 Grab 6-3 031/003 Carp 6-4 031/003 Grab 6-4 002 Crnp.6-3 002 Grab 6-3
Parameters:
Acids: (Method 625) (ug/1)
Phenol <10 <10
2-0hlcrapha of <10 <10
2-Nitr:phenol <10 <10
2,4- Dinethj'l he o1 <10 <10
2,4 DichlargPhenol <10 — <10
4-O-II,oro-3-1Y thylpharol <10 — <10
2,4,6-Trichlarcpha-u1 <10 <10
2,4-0initrqphenol — <10 <10
4- Nitrcphen l <10 <10
4,6-0initro-24nethylpherol. <10 <10
Paitachloraphenol -- <10 <10
Base/Neutrals: (Method 625) (ug/1)
N-Nitrosodimethylam ne <10 <10
Bis(2-0hloraet yl)Ether <10 <10
Bis(2-Q-]nraisapropy1)Ether <10 <10
N-NiqPYlarnine <10 <10
Hexachloroettrone <10 <10
Nitrabenzene <10 <10
Isophorone <10 <10
Bis(2-0hlaroethoxy)I+1ethane <10 <10
1,2,4-Trichloraba-zene <10 <10
Naphthalene <10 <10
Hexadllorcbutadiene — <10 <10
Hexachlarccyclopentadiene — <10 <10
2 <10 <10
Dimzthyl Phthalate — <10 <10
Acerephthylene <10 <10
Acenaphthe a <10 <10
2, 4-0initrotnluene <10 <10
2,6-0initrotoluene <10 <10
Diethyl Phthalate — <10 <10

Allied Fibers - Mbncure Plant
Priority Pollutant Analysis
Laboratory Report, page 11
LAB NO. 87-41507 87-41508 87-41509 87-41510 87-41511
SAWLE ID: 001/003 Gab 6-3 001/003 Carp. 6-4. 001/003 Grab 6-4 002 Ca p.6-3 CO2 Grab 6-3
PET1-100 625
Base/Neutrals: (ug/1)
4-011arapharyl Phenyl Ether <10 <10
F1uarene <10 <10
N-Nitrosodiphenylamine <10 <10
4-Brarnphenyl Phenyl Ether <10 — <10
Hexachlorcbe,zeie <10 <10
PI rdf EH ithrene — <10 <10
Anthracene <10 <10
Di-N-Butyl Phthalate <10 <10
Fluorantheie <10 <10
Benzidine <50 <50
Pyre e <10 <10
Butyl Benzyl Phthalate <10 ' <10
3,3-Diclorabenzidine <20 <20
Benzo(a)Anthracene <10 <10
Bis(2-Ethylhexyl)Phthalate <10 <10
Chrysene <10 <10
Di$}-0ctyl Phthalate <10 <10
Benzo(b)Fluoranthene <10 <10
Benzo(k)Fl.uoranthene <10 <10
Berzo(a)Pyrene — <10 <10
Inde (1,2,3-cd)Pyraie <10 <10
Dibenzo(ah)Anthracene <10 <10
Benzo(ghi)Perylene <10 <10
1,2-Diphaiyl Hydrazine <10 <10
Pestiride/PCB's: (Method 625) (ug/1)
Aldrin — <20 <20
a- l C QO QO
b-B-C <20 <20
9-BFC <20 <20
d-BI-C <20 — <20

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Allied Fibers - Moncure Plant
Priority Pollutant Analysis
Laboratory Report, Page 12
LAB M. 87-41507 87-41508 87-41509 87-41510 87-41511
SAMPLE ID: 001/003 Grab 6-3 001/033 Comp. 6-4. 0311:003 Grab 6-4 CO2 Corp.6-3 002 Grab 6-3
Parameters
Chlordane
4,4-DDE
4,4-DDT
Dieldrin
Erdosulfan I
Erdosulfan II
Errd,sulfan Sulfate
Erdrin
Endrin Aldehyde
Heptachlor
Heptachlor Epoxide
Toxaphene
PCB 1016
PCB 1221
PCB 1232
PCB 1242
PCB 1248
PCB 1254
PCB 1260
4,4-009
<20
<20
l20
<20
<93
<59
<53
<20
23
<3
<2D
<100
<50
<50
<50
<50-
<50
<50
<50
<20
<20
<20
<20
<20
<50
<50
<50
<20
<20
<20
<20
<100
<50
<50
<50
<50
<50
<50
<50

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Allied Fibers - (nitre Plait
Priority Pollutant Analysis
Laboratory Rtu t, Page 13
LAB NO. 87-41512 87-41513 87-41514
SAMPLE ID: 002 Caip. 6-4 002 Grab 6-4 Trip Blank
Parameters:
Sulfate 7.4 -
MBAS 0.1 -
Fluoride <0.2 Bromide 2.2
2.2 Boron 0.3
0.3 -
Sulfite - <2
Cyanide <0.02
Sulfide - <1
Total Phenolics <0.004
Total Antimony <0.01 -
Total Beryllium <0.01 -
Total p auniuil <0.05 -
Total Lead <0.1 .--
Total Nickel <0.05 -
Total Silver <0.01 -
Total Zinc 0.02 -
Total Aluminum 0.4 -
Total Rariun <0.1 -
Total rjhal t <0.05 -
Total Iran 5.5 -
Total IIagnesiun 1.6 -
Total f blybderua <0.3 -
Total Manganese 0.40 -
Total Tin <1.0 -
Total Titanium <1.0
Total Arsenic (ug/l) 2 -
Total Cadmium <0.Q1 -
Total Capper <0.03 -
Total Mercury (ug/i) <0.2 -
Total Selenium (ug/1) <3 -
Total Thalltm <0.1 -
Pesticides: (ug/i)
Endrin <0.1 --- <0.1
Lindane <0.1 <0.1
Methoxydilor <0.2 <0.2
Toxaphene <0.5 <0.5
i

Allied Fibers - Ilu ure Plant
Priority Pollutant Analysis
Laboratory Repui1, Page 14
LAB NO. 87-41512 87-41513 87-41514
SAI'PLE 10: 032 Camp. 6-44 002 Grab 6-4 Trip Blanc
Parameters.
Volatile Organics: (Method 624) (ug/1)
Chloroiethane <10 <10
Vinyl Chloride <10 <10
Brrn°methane <10 <10
Chloroetl-ene <10 <10
1 ,1-Dichoroethylene <5 <5
Methylene Chloride -- <5 <5
Trams-1, 2-0ichl oroethylene <5 <5
1,1-0ichloroethane <5 <5
Chloroform — <5 <5
1 ,1 ,1-Trichlomethane <5 <5
1,2-0ichhloraethane — <5 <5
Benzene — <5 <5
Carbon Tetrachloride <1 - <1
Tri.chl.oroethylene .— <1 <1
1, 2-Didilorapropeie <1 <1
Bromodichlorcnethane <5 <5
2-Chl.oroethylvinylether <5 <5
Cis-1,3-0ichlorcpropene <5 <5
Toluene <5 <5
Trans-1, 3-0ichloroprope,e <5 <5
1,1,2-Trichloroethane -- <5 <5
Dibrarochlorarethane <5 <5
Tetrachloroethylene <5 <5
Chlorcberrzene <5 <5
Ethylbenzene <5 <5
[1rouuform -- <5 <5
1,1,2,2-Tetrachloroethane -- <5 <5
1, 3-0ichiombeizene -- <5 <5
1, 4-0ic i1arabenze-ie <5 <5
1,2-Dichlorobenzene <5 <5
Trich]arofluoranethane <5 <5

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Allied Fibers - ftrcure Plant
Priority Pollutant Analysis
Laboratory Report, Page 15
LAB M. 87-41512 87-41513 87-41514
SAS ID: 002 Camp. 6-4 002 Grab 6-4 Trip 8laric
Parameters.
Arids: (Method 699) (ug/1)
Phenol <10
2-allaraphanol <10
2-Nitropha-io1 <10
2,4-Dinethylphnenol <10
2,4-Dichlaraphenol <10
4-Chlaro-3-- thyiPhenal <10
2,4,6-Tr l <10
2,4-Dinitraph mol <10
4-Mito4heno1 <10
4,6-Dinitro-2-1%thylphenol <10
Pentachlarophenol <10
Base/Neutrals: (ihethod325) (ug/1)
N-Nitrosadirrethylamine <10
Bis(2-0tLaroethyl)Ether <10
Bis(2-{hloroisaprcpyl)Ether <10
N-Nitrosodiprcpylamine <10
Nexachlaroethane <10
Nitrobenzene <10
Isophnrone <10
8is(2-Chlaroethoxy)Meth one <10
1,2,4-Trichlorobe nze ne <10
Naphthalene <10
Hexachlorthutadiene <10
Hexachlorocyclwentadiene <10
2-Chlorcnaphthalene <10
Dimethyl Phthalate <10
Acernaphthylene <10
Acenaphthane <10
2,4-Dinitrotoluene <10
2,6-Dinitrotoluene <10
Diethyl Phthalate <10

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Allied Fibers - Moncure Plant
Priority Pollutant Analysis
Laboratory Report, page 16
LAB NO. 87-41512 87-41513 87-41514
SAPtE ID: 002 Camp. 6=4 002 Grab 6_4 Trip Blank
PET} O 625
Base/Neutrals: (ug/1)
4 Ch1 raphenyl Phenyl Ether <10
Fiuorare <10
1,2-Diphenyl Hydrazine <10
4-Bromapheryl Phenyl Ether <10
Hexachlo¢obenzene <10
Phenanthrene <10
Anthracene <10
Di-N-Butyl Phthalate <10
Fluoranthene <10
Bazjdine <50
Pyrena <50
Butyl Baizyl Phthalate <50
3, 3-0iclondbauidine <20
Benzo(a)Anthracene <10
Bis(2-Ethylhexyl)Phthalate <10
Chrysene <10
Di-N-Octyl Phthalate <10
Benzo(b)Fluoranthene <10
Be o(k)Fluoranthene <10
Baizo(a)Pyraie <10
lndeno(1,2,3-cd)Pyrene <10
Dibenzo(ah)Anthrace- <10
Benzo(ghi)Pery].ene <10
1, 2-Diph nyi Hydrazine <10
Pestiride/PCB's: (Method 625) (ug/l)
Aldrin <20
a- 8 C QO
b-8FC <20
g-81-C <20
d-BFC <20

Allied Fibers - Mbncure Plant
Priority Pollutant Analysis
Laboratory Rgxu t, Page 17
LAB NO. 87-41512 87-41513 87-41514
SAPPLE ID: 002 Cop. 6-4 002 Grab 6-4 Trip Blank
Parameters
Chlordane <20
4, 4-00E QD
4, 4-00T <20
Dieldrin <20
Endosulfan I <50
Erxiosuslfan II <S0
Endosulfan Sulfate <50
Endrin <20
Endrin Aldehyde Q0
Heptachlor c20
Heptachlor Epoxide Q0
Toxephene <100
PCB 1016 <50
PC8 1221 <50
PC8 1232 <50
PCB 1242 <50
PCB 1248 <50
PC8 1254 <50
PC6 1260 60
4,4-000 d0
The results on this report are reported in milligrams per liter wile otherwise noted.
Analytiral methods are those moved by the U.S. Environmental Protection Agency.
tfully submitted,
ENiRIGHT LABQRAT47TF'S,
(C/4:/a rles H. Wove, Ph.D.
Laboratory Manager
CHI/rwz

III. Field Sampling Reports
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ENWRIGHT
ASSOCIATES INC.
CLIENT / LOCATION:
ENWRIG.HT LABORATORIES, INC.
25 WOODS LAKE ROAD
GREENVILLE, SC 29607
[phone]
FIELD SAMPLING REPORT
Page of _-7_
Po-x-IED - s\GNAL / t�oNcuR� , NC
SAMPLING DATE: L6-3-4C37
SAMPLE TYPE: _j/ 24-HOUR COMPOSITE
Weather: _ C. -_
Time Interval: _ Lie>_ Volume per Sample: 1 411
SAMPLING FREQUENCY:
GRAB ONLY
5? EC1 faL
DeEloyment Data
Site Description:_ Mt4rk2.42 ]:
Date : __/6_ caZ Time: __ 4.�
Container: __14� _Cz1�RSS
Retrieval Data
Time: Weather: C-EZL.a
Composite Temperature:°(.1. Composite Volume:
Field pH: O2._ Meter Paper
SAMPLES COLLECTED
Location
Time/Tyne
Container
Preservative Parameters
__ p %E,BX..PV-1Q,3 1-1__c it XDE
_Naga'D_ --_r - c.--E1a ____
__S: SSA arAQom____ __1= _E1CS_
_cl E:&_ tNLoNE t,L_
14QL _Pt'111----tA4rLE. \ion
Y.21 . Rt eE ____T o1y— L4A
CHAIN OF CUSTODY RECORD
Sampled By: _)7.,ry5L2.7 T ?x__51, _ Total Number of Containers:
Relinquished by:-- �.: ' Date: _ _L_Q:_ Time: _E_L4T --_
(�
Received by: j ��N_2A C'!nAr y/ Date: ---2 - L1 Time: 30 ,1^,\
'J
NOTE: All information concerning the date, time, analyst, and method of
analysis is recorded in bound log books at Enwright Laboratories and is
available upon request.

ENWRIGHT
ASSOCIATES INC.
CLIENT
LOCATION:
ENWRIGHT LABORATORIES,
25 WOODS LAKE ROAD
GREENVILLE, SC 29607
[phone]
FIELD SAMPLING
Page Z of
REPORT
Pc1 L1—SIGNRL / MONC,Q1Z,E.ANC
SAMPLING DATE: 6-7:5-57
SAMPLE TYPE:
24-HOUR COMPOSITE
INC.
SAMPLING FREQUENCY: c_...IC��AL
GRAB ONLY
Deployment Data
Site Description:__Q0j1OQ
Date:__ (Q='2I= la Time: 9=ISiA_
Weather: __CA R„a \b.Z�gM Container: \.1 („.1.11 a
Time Interval: �Q�1L�L____ Volume per Sample: _ L3r�121�
Retrieval Data
Time:
'YI=,12-1., Weather: c.,)=E} eDIT
Composite Temperature: _..,5o(1_ Composite Volume:
Field pH: _ -2_1_ Meter Paper
SAMPLES COLLECTED
Location
Container
N2Y---
Y _BQsSAMQ
_- -
Preservative Parameters
_hIcasM— _5aLA,Sglst6+'E:aati t E
CHAIN OF CUSTODY RECORD
Sampled By: _gtca,‘,-`_Dx___ Total
Relinquished by:cC'(�1 Date:
Received by: '_
� i} �:�9 �J�,��. Date:
NOTE: A11 information concerning the date, time, analyst, and method of
analysis is recorded in bound log books at
available upon request.
Number of Containers: \O--_-
Time:
Time:
Enwright Laboratories and is

ENWRIGHT
ASSOCIATES INC.
FIELD
ENWRIGHT LABORATORIES,
25 WOODS LAKE ROAD
GREENVILLE, SC 29607
[phone]
SAMPLING
Page of
REPORT
CLIENT / LOCATION: PtyL\E.D-5 NflL/ t4\01JcAE.,NC-
SAMPLING DATE: C7-3-Q7
SAMPLE TYPE: _1Z24-HOUR COMPOSITE
DeEloxment Data
Site Description: tXQ2
Date: 6-z
SAMPLING FREQUENCY:
GRAB ONLY
Time: 4•_35{t(n
INC.
SPFr-1PN
e-
Weather: _ (.2LILj�.42eF Container: \Q L_
Time Interval: __1Or1N Volume per Sample: \2 _y..\-_
Retrieval Data
Time: LQ110 Weather: C,.. v_} T
Composite Temperatur-: Sod+ Composite Volume:
Field pH: (q �u' Paper
SAMPLES COLLECTED
Location Time/TZr2e
---S:20 co, r
----O"L GBH_
- StRft$_
�z- c2R
Container
Preservative Parameters
,4 a3Ft\OE
�2R3{1fl�1`� C`�Ri�\DEL
--_-moo- ��LFliC
I i QL1c s
NONE
\LO
Noa
Sampled
CHAIN OF CUSTODY RECORD
B y :
Relinquished
Received by:
Total
ate:
Date:
Number of Containers:
- Time: _ 5
--'-\-----
Time: `3' 30 AA-'\
NOTE: All information concerning the date, time, analyst, and method of
analysis is recorded in bound log books at Enwright Laboratories and is
available upon request.

,
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NWRJGHT
ASSOCIATES INC.
ENWRIGHT LABORATORIES, INC.
25 W000S LAKE ROAD
GREENVILLE, SC 29607
[phone]
FIELD SAMPLING REPORT
Page yof �—
CLIENT / LOCATION: pru _sy;NL/ r�otvcv��,Nc
SAMPLING DATE: 6._+-1_cc0 SAMPLING FREQUENCY: S'c'F.C.1AL
SAMPLE TYPE:
„/_
24-HOUR COMPOSITE
GRAB ONLY
Deployment Data
Site Description:__ '14..)n.Q-C
Date:__ (2- 0 Time: 9_2- .p r
Weather: ��53� -�_—_—_— Container: __,c�„.. f-
Time Interval: _ )sysLe1la Volume per Sample: ZZ ,t1_
Retrieval Data
Time:
Composite
Field pH:
cl.- QE?i L
Temperature: _ oC.
_1Q_Z t Paper
SAMPLES COLLECTED
Location
Weather:
Composite
Container
�W�FItfL
Volume:
Preservative Parameters
1L53-1VE
1,x2)
CHAIN OF CUSTODY
RECORD
Sampled By: _.FO SZ3 _2._ $ _ Total Number of Containers: ---
Relinquished by: _ Date:
Received by:-3�C�\�'� QS-27-=`\-`L Lt Date:
Time:
(0- 5` g l Time: g• Zo AM
NOTE: All information concerning the date, time, analyst, and method
analysis is recorded in bound log books at Enwright Laboratories and is
available upon request.

ENVVRIGHT
ASSOCIATES INC.
ENWRIGHT LABORATORIES, INC.
25 W00DS LAKE ROAD
GREENVILLE, SC 29607
[phone]
FIELD SAMPLING REPORT
Page 5 of
CLIENT / LOCATION: iztu..)EQ-1GNA1_1 MOMCOIXE,NC.
SAMPLING DATE: C_y_$cr
SAMPLE TYPE: _.17/ 24-HOUR
COMPOSITE
SAMPLING FREQUENCY: SPEC \__
GRAB ONLY
DeEloxment Data
Site Description:____c c3
Oate:___ _al Time: q:,5S_ei
Weather: _r.. X,.f.Y„ilS Container: ,5›\.. Cz a..
Time Interval: _7(--u.Aj�1 Volume per Sample: ym,t.7.,_n\.,_
Retrieval Data
Time: _cs.35f Weather:
Composite Temperature: _SfLC., Composite Volume: 10V.
Field pH: (Mete Paper
SAMPLES COLLECTED
Location
Time/Tape
Container
cw11 fYE\
Preservative Parameters
_ Z saLP___ ___ C ___------f_'Lz_Zt ----
QQS_J3le$----..SQI. MINA`
AccIr _i3Maitit, ___ s yQA_
Sampled
CHAIN OF CUSTODY RECORD
BY: _RtgliCCrc_ _OYBoY`Total
Relinquished by:—` sye �\Date:
Received by; 14'`9—ems. (� Date:
Number of Containers:
5 - 1
Time:
Time:
A&.
NOTE: A11 information concerningthedate, time, analyst, and method of
analysis is recorded in bound log books at Enwright Laboratories and is
available upon request.

4
ENWRJG f ` T
ASSOCIATES INC.
CLIENT / LOCATION:
ENWRIGHT LABORATORIES,
25 W00DS LAKE ROAD
GREENVILLE, SC 29607
[phone]
FIELD SAMPLING REPORT
Page _ % _ of _-Z_
Pala_ - S`St'* / riNckcssicE.NC
SAMPLING DATE:
SAMPLE TYPE: Y 24-HOUR COMPOSITE
Deeloyment Data
Site Description: _ c -
D
Weather: _ Gj,zily __
Time Interval: _
SAMPLING
INC.
FREQUENCY: sFC.. f _
GRAB ONLY
Time: _--LQ?
Container: 14 \_ SzL
Volume per Sample: \,Q.,n...
Retrieval Data
Time: __1D'_\a__Br o Weather: �LI`., Sty?
Composite Temperature: y� Composite Volume: __ LQ1
Field pH: b.c\ Meter Paper
SAMPLES COLLECTED
Location
rc
----trY-)2 C��P<$•--
--- sooz. Co w---
Qoz
Time/Type
5
Container
Preservative Parameters
^i 0 tSJvf"IIce
CHAIN OF CUSTODY RECORD
Sampled By: cSQn:Ecy.— _ g`L Total Numher of Containers:
Relinquished by: `���.�Date: ime:
Received by: �.C{�;���5� (`�.G� -- Date:Lc�- r r`
�'r� Time:
3 AA
NOTE: All information concerning the date, time,
analysis is recorded in bound log books at analyst, and method of
available upon request.
Enwright Laboratories and is

CLIENT / LOCATION:
SAMPLING DATE:
ENWRIGHT LABORATORIES, INC.
25 WOODS LAKE ROAD
GREENVILLE, SC 29607
[phone]
FIELD SAAMPLING REPORT
Page _ 1__ of _7_
l `7\5D0)
SAMPLING FREQUENCY: �T=C...1QyL
SAMPLE TYPE: _" 24-HOUR COMPOSITE GRAB ONLY
Oeeloxment Data
Site Description:__T11.11 __ 1.1_ __y.r?il--C-Yfl
Date: --.)
Time: 1Q_lj.�Z13�
Weather: L.1...Ag.„‘_30- Container: a01_ G1-f.5S
Time Interval: __�2.3�11,1 Volume per Sample:
11SJ_rnL
Retrieval Data
Time: __ICCraa` n_ Weather:
Composite Temperature: � o� Composite Volume: 1OL
`2.,
Field pH: -_ e er _ Paper
SAMPLES COLLECTED
Location Time/Txpe
c nr1Y_----
---�-
--
Container
Preservative Parameters
ALE
Sampled
Sampled
� " ENWRJGHT
ASSOCIATES INC.
C
CHAIN OF CUSTODY RECORD
B y °
Relinquished by: `?(.��`���JL�S Date:
( Received by: 0_,\Q4.,Z. � ��� Date:
30An*.
NOTE: All information concerning the date, time, analyst, and method of
analysis is recorded in bound log books at Enwright Laboratories and is
available upon request.
i.tal Number of Containers:
-`�-��-- Time:
- Time: