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HomeMy WebLinkAboutNC0001899_wasteload allocation_19910612NPDES WASTE LOAD ALLOCATION PERMIT NO.: NC0001899 PERMITTEE NAME: Allied-Signal, Inc. / Allied Fibers Facility Status: Existing Permit Status: Renewal Major Minor Pipe No.: 001 Design Capacity: 0.244 MGD Domestic (% of Flow): 11.4 % Industrial (% of Flow): 88.6 % Comments: no more 003 outfall, flow (potable water treatment) is contained in 001 flow . Note: long term avg. flow of 0.088 MGD used to calculate % domestic and industrial RECEIVING STREAM: Haw River Class: C Sub -Basin: 03-06-07 Reference USGS Quad: E 22 SE (please attach) County: Chatham Re gional Office: Raleigh Regional • r` ar' Previous Exp. Date: 10/31/90 reatment Plant Class: Class 2 Classification changes within e miles PLOTTEC Requested b • , Rosanne Barona Date: 6/26/90 Prepared " . Date: (_/ Reviewed by: ) Sc.)Date: 3 LoVe EL Modeler Date Rec. # (o/Z7i4 o 577-7 Drainage Area (mi ) /(. 8o Avg. S 1Q-(cfs) Winter 7Q10 (cfs Toxicity Limits: IWC q % Instream Monitoring: Parameters ow (cfs): /YYef 30Q2 (cfs) hronic JAP, APR.,Jut ,OCX Upstre . ,% Location //Qw Z;;.- .SZ I !l • stream ✓ Location/g-✓j ,,,,; jL effluent Characteristics Mo 14.kly Averaap. 1)0., t Y Ayl ax BOD { tbs/ ) 3.1 10 5—. q lbsf d3 1 S L. olb Cbtis/ciiiy) 3 T. 5" 1.5 TSS ( = `_) 3.7 Z (p F. Col. (/100 nil) a DQ yv 0 9 30 pH (SU) _ D,1 t..el 0u6ld) ao Ann,,aL gross bd. ?atke(e dd- u;' Sikoli. naf ecpci - nc.?F iloc,+ t tl ifcv4-eo VirD fat i Caren <. , Pests C(k(d) -- 0.31 Comments: 1401; Tea., Suppo i-c a sckociu kP is FOR APPROPRIATE DISCHARGERS, LIST COMPLETE GUIDELINE LIMITATIONS BELOW Effluent Characteristics Monthly Average Daily Maximum Comments B o D. c3. / `f DcPSF C° `fl'. 3o TSS 3,7 7. n c.,t305rys ®4 ‘+0 i C 0 D 56. 5 %. ,1 q5'/ &f .det j 3t's Type of Product�^Produced Lbs./Day Produced Effluent Guideline Reference rof F. e5fer d PI- n0f ji JPM, -Ft Ott) Dc PS C T) • 3 0 `�' used r Oct .s 1- Y/ 9, lc0 1 'L del/hes 4 OVERFLOW DISCHARGE NO. 002 (156k GPD) r 6 91 HAW RIVER 308 , FIRE PONDS 209 POTABLE WATER TREATMENT 4 4 1 200 ALUM SETTLING POND ► WATER -► ••••D EVAPORATION D ----* STEAM � ---► OIL ---♦ 94 V STEAM BOILERS 17 4 138 61 PROCESS 4 77 92 COOLING TOWERS 25 4 67 10 SANITARY 10 HVAC and AIR OMPRESSORS STORM WATER 18 AIR DRYER File: WA7'ER FL.DRW 16 OIL TREATMENT OIL TO BURNING (ENERGY RECOVERY) r (90 kGPD) SCHEMATIC OF WATER FLOW ALLIED -SIGNAL , INC . MONCURE , CHATHAM COUNTY NORTH CAROLINA 0 10 WASTE WATER TREATMENT -4 PLANT 80 All values are in Thousands of Gallons Per Day. DISCHARGE NO. 001 (88 kCPD) OCPSF Subpart I t1 .coo-7LI 111,6141 r,-n I3(i 1061 A B C D E F 1 OCPSF Regulations Subpart I 2 Daily Max Monthly Avg Flow Daily Max Monthly Avg 3 Effluent Characteristics (ug/I) (ug/I) (MGD) (lb/day) (lb/day) 4 5 Acenapthene 59 22 0.004 0.002 0.001 6 Acrylonitrile 242 96 0.008 0.003 7 Benzene 136 37 0.005 0.001 8 Carbon Tetrachloride 38 18 0.001 0.001 9 Chlorobenzene 28 15 0.001 0.001 1 0 1,2,4-Trichlorobenzene 140 68 0.005 0.002 1 1 Hexachlorobenzene 28 15 0.001 0.001 1 2 1,2-Dichloroethane 211 68 0.007 0.002 1 3 1,1,1-Trichloroethane 54 21 0.002 0.001 1 4 Hexachloroethane 54 21 0.002 0.001 15 1,1-Dichloroethane 59 22 0.002 0.001 16 1 ,1,2-Trichloroethane 54 21 0.002 0.001 17 Chloroethane 268 104 0.009 0.003 18 Chloroform 46 21 0.002 0.001 1.9 2-Chlorophenol 98 31 0.003 0.001 20 21 1,2-Dichlorobenzene 163 1,3-Dichlorobenzene 44 77 31 0.005 0.001 0.003 0.001 22 1,4-Dichlorobenzene 28 15 0.001 0.001 23 24 25 26 27 28 29 1,1-Dichloroethylene 25 1,2-trans-Dichloroethylene 54 2,4-Dichlorophenol 112 1,2-Dichloropropane 230 1,3-Dichloropropylene 44 2,4-Dimethylphenol 36 2,4-Dinitrotoluene 285 16 21 39 153 29 18 113 0.001 0.002 0.004 0.008 0.001 0.001 0.010 0.001 0.001 0.001 0.005 0.001 0.001 0.004 30 2,6-Dinitrotoluene 641 255 0.021 0.009 31 Ethylbenzene 1 08 32 0.004 0.001 32 Fluoranthene 68 25 0.002 0.001 33 34 Bis(2-Chloroisopropyl)ethe 757 Methylene Chloride 89 301 40 0.025 0.003 0.010 0.001 35 36 Methyl Chloride 190 Hexachlorobutadiene 49 86 20 0.006 0.002 0.003 0.001 37 Naphthalene 59 22 0.002 0.001 38 Nitrobenzene 68 27 0.002 0.001 39 401 41 42 2-Nitrophenol 69 4-Nitrophenol 1 24 2,4-Dintrophenol 123 4,6-Dintro-o-cresol 277 41 72 71 78 0.002 0.004 0.004 0.009 0.001 0.002 0.002 0.003 43 Phenol 26 15 0.001 0.001 44 45 46 Bis(2-ethylhexyl)phthalate 279 Di-n-butyl phthalate 57 Diethyl phthalate 203 103 27 81 0.009 0.002 0.007 0.003 0.001 0.003 47 48 Dimethyl phthalate 47 Benzo(a)anthracene 59 19 22 0.002 0.002 0.001 0.001 Page 1 OCPSF Subpart I •Q \ .01! ta SO A B C D E F 4 9 Benzo(a)pyrene 61 23 0.002 0.001 5 0 3,4-Benzofluoranthene 61 23 0.002 0.001 51 Benzo(k)fluoranthene 59 22 0.002 0.001 5 2 Chrysene 59 22 0.002 0.001 5 3 Acenaphthylene 59 22 0.002 0.001 5 4 Anthracene 59 22 0.002 0.001 5 5�Fluorene 59 22 0.002 0.001 5 6 Phenanthrene 59 22 0.002 0.001 5 7 Pyrene 67 25 0.002 0.001 5 8 Tetrachloroethylene 56 22 0.002 0.001 5 9 Toluene 80 26 0.003 0.001 6 0 Trichloroethylene 54 21 0.002 0.001 6 1 Vinyl Chloride 268 104 0.009 0.003 r 6 2 Total Chromium 2770 1 1 1 0 0.092 0.037 6 3 Total Copper PIC- 3380 1450 0.113 0.048 6 4 Total Cyanide 1200 420 0.040 0.014 6 5 Total Lead 690 320 0.023 0.011 6 6 Total Nickel 3980 1 690 0.133 0.056 6 7 Total Zinc w� 2610 1 050 0.087 0.035 Page 2 Ple: se print Qr,typtt in the unshaded areas only. EPA I.D. N UMBER (COI)), front item 1 of Form 1) ru/ell M/)p/uvtlu. OMB No. 2040-0086 Approval expires 7-31-88 NCD053488409 -FORM NPDES C Int coEPA U.S. ENVIRONMENTAL PROTECTION AGENCY APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program I. OUTFALL LOCATION For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. OUTFALL NUMBER B. LATITUDE C. LONGITUDE (list, 1. OEG. 2. MIN. 3. SEC. 1. DEG. 2. MIN. 3. SEC. D. RECEIVING WATER (name) 001 35 37 01 79 03 25 Haw River 002 i 35 37 00 79 02 36 Shaddox Creek II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES - A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatment units, and outfalis. If a water balance cannot be determined (e.g., for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary. L O U T FALLNO (list) 2. OPERATION(S) CONTRIBUTING FLOW 3. TREATMENT a. OPERATION (lisf) b. AVERAGE FLOW (include units) a. DESCRIPTION b. LIST CODES FROM TABLE 2C-1 001 Process Wastewater 4,000 GPD Oil Pretreatment XX Sanitary Wastewater Cooling Water Blowdown Boiler Blowdown HVAC, Air Compressors and Steam Condensate 10,000 GPD Grinding 25,000 GPD Neutralization 17,000 GPD Activated Sludge 18,000 GPD Clarifier 1-L 2- K 3-A 1-U Storm Water Runoff Potable Water Plant Filter Backwash & 16,000 GPD Polishing Pond Alum Settling Pond Disinfection XX 5-T 2-F Clarifier Blowdown 9,000 GPD Discharge to Surface Water Sludge Drying Off -site Landfill 4-A 5-H 5-Q 002 Firepond Overflow Storm Water Runoff Steam & HVAC Condensate 91,000 GPD Oil Baffles & Weirs 63,500 GPD Emergency Containment 1,000 GPD Discharge to Surface Water 1-H XX 4- A Air Dryer 500 GPD Or-r ICIAL USE ONLY (effluent guidelines sub categories) e ' J I?FVC"-c;c EPA I.D. NUMBER (copy from Item 1 of Form 1) CONTINUED'FROM PAGE 2 rV. INTAKE AND EFFLUENT CHARACTERISTICS NCD053488409 Form Approved. OMB No. 2040-0086 Approval expires 7-31-88 A, B, & C: See instructions before proceeding — Complete one set of tables for each outfall — Annotate the outfall number in the space provided. NOTE: Tables V-A, V-B, and V-C are included on separate sheets numbered V-1 through V-9. D. Use the space below to list any of the pollutants listed in Table 2c-3 of the instructions, which you know or have reason to believe is discharged or may be discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and report any analytical data in your possession. 1. POLLUTANT 2. SOURCE 1. POLLUTANT 2. SOURCE Asbestos Acetaldehyde Cresol Crotonaldehyde Cyclohexane Formaldehyde Pipe & Vessel Insulation Possible process byproduct Used in Q.C. lab Possible process byproduct Used in Q.C. lab Used in Q.C. lab VI. POTENTIAL DISCHARGES NOT.COVERED BY ANALYSIS 4s anypollutant listed)n Item V Ca substance or,a com •qyp rodUct7�' �,`;r • Xylene Used in Q.C. lab pent ofa substance which you currently use or manufacture as an intermediate or final product or YES (list all such pollutants below) Ono (go to Item VI-B) Antimony Phthalate Esters (Possible process byproduct) (Refer to Supplementary Information Item VI.) i EPA Form 3510.2C (Rev. 2-85) PAGE 3 OF 4 CONTINUE ON REVERSE Section V - D FORM 2C NPDES HAZARDOUS SUBSTANCES (SECTION 311) EXEMPTION REQUEST The Moncure Plant stores and uses various materials listed under Section 311 - Hazardous Substances. The accompanying list shows which materials are on site in more than laboratory quantities, the approximate total amount stored, and the size of the individual unit being stored for use. The receiving, unloading, and storage methods used are consistent with accepted spill prevention and control practices which are designed to prevent any discharge. All surface drainage from the developed areas is collected and dis- charged through either the wastewater treatment plant outfall 001 or the stormwater, firepond overflow outfall 002. The outfall 002 drainage system includes a series of baffles and weirs designed to contain accidental spills. Spills that get beyond the baffle/weir system can be contained in a holding pond and pumped to a storage tank or the wastewater treatment plant. All personnel that handle raw materials receive both classroom and on the job training in their job functions and on spill and pollution control. In addition, personnel are kept current through daily contact with their supervisors and through monthly safety meetings. HAZARDOUS SUBSTANCES (SECTION 311), EXTREMELY HAZARDOUS SUBSTANCES (SARA TITLE III), and CERCLA SUBSTANCES SPILL CONTROL INFORMATION APPROX. CONTAINER SUBSTANCES AMT. (LB) SIZE STORAGE METHOD Acetone 725 5 gal. drum Curbed areas inside buildings Aluminum 6,500 50 lb. bags Inside building Antimony Compound 12,000 35 lb. bucket Inside building Chlorine 1,800 150 lb. Cylinder storge area & cylinders inside water and wastewater treatment plant buildings Cresol/ Chloroform 1,300 15 gal. drums Curbed area & inside building Cyclohexane 1,000 55 gal. drum Curbed area & inside building Dichlorodifluoro- methane 11,700 Various Used in refrigeration units inside buildings Mercury 4 1 qt. bottle Inside building Methyl Chloroform 1,500 Phenol/1,1,2,2- Tetrachloro- ethane 55 gal. drums Curbed areas & inside & degreasing buildings in areas without baths floor drains 1,160 15 gal. drums Curbed area & inside building Polychlorinated Biphenyl 68,000 Various Size Transformers Potassium Hydroxide Sodium Hydroxide 109,000 45,000 Outside transformer areas 12,000 gal. Curbed areas & inside tank & drums buildings 12,000 gal. Curbed areas & inside tank & drums buildings (CONTINUED) SUBSTANCES Sodium Nitrite HAZARDOUS SUBSTANCES (SECTION 311), EXTREMELY HAZARDOUS SUBSTANCES (SARA TITLE III), and CERCLA SUBSTANCES SPILL CONTROL INFORMATION AMT. (LB) SIZE STORAGE METHOD 1,700 55 gal. drums Curbed areas & inside building Sulfuric Acid 3,000 Trichlorotri- fluoromethane 1,500 15 ga. drums Curbed areas & inside building Various Used in refrigeration units inside buildings -1- Request FACT SHEET FOR WASTELOAD ALLOCATIONS Facility Name :Allied Fibers - Outfall 001 NPDES No. :NC0001899 Type of Waste :11.4% Domestic/88.6% Industrial Facility Status :Existing Permit Status :Renewal Receiving Stream :Haw River Stream Classification:C Subbasin :03-06-07 County :Chatham Regional Office :Raleigh Requestor :Rosanne Barona Drainage Area:1680 sq.mi. ' Date of Request :6/26/90 Summer 7Q10: cfs 1{0 rek Topo Quad :E22SE Winter 7Q10: 157 cfs Average Flow:1848 cfs 30Q2: 218 cfs FFR Wasteload Allocation Summary USGS # estimated Stream Characteristics: Date 1987 Complex wastewater consisting of process wastewater (.004 MGD), sanitary sewage (.01 MGD), cooling water, boiler blowdown, HVAC condensate, and filter backwash (.069 MGD). Permit limits were derived from the OCPSF guidelines for the production of polyester fiber. The BOD5 and TSS limits were calculated using the OCPSF guidelines for the process wastewater and assuming secondary treatment of the sanitary sewage. All limits must be met at the end -of -pipe. WASTELOAD SENT TO EPA?(Major) _Y_ (Y or N) (if yes, then attach schematic, toxics spreadsheet, copy of model, or if not modeled, then old assumptions that were made, and description of how fits into basinwide plan) Recommended by: ids Reviewed by Instream Assessment: Regional Supervisor: Permits & Engineering: Date: kILILLf 3). SW:LA Date: 1i t6 (et{ till. • urr-r a14.1.1 RETURN TO TECHNICAL SERVICES BY: A.),Pe is ff ate : ; /"7A, .(9 1tr,4 / Date: a /1 abrcr. J4.4 14k4a tQ tf,L d TSS MAR O1 11 vicets ✓ eu=s, gin} c)," C a� Si -2 - Request No. 5777 Existing Limits Monthly Average Wasteflow (MGD) : BOD5 (lbs/day): TSS (lbs/day): COD (lbs/day) : Fecal Coliform (/100 ml): pH (SU) : Oil & Grease (lbs/day): TKN (lbs/day): Recommended Limits Wasteflow (MGD) : BOD5 (lbs/day) : TSS (lbs/day): COD (lbs/day): Fecal Coliform (/100 ml): pH (SU) : Oil & Grease (lbs/day): TKN (lbs/day): Limits Changes Due To: OCPFS guidelines New standard cob CONVENTIONAL PARAMETERS Daily Maximum .244 359 239 5382 1000 6-9 20 10 644 437 9890 2000 30 15 Request No. 5777 Monthly Average Daily Maximum .244 3.1 3.7 38.5 200 6-9 20 30 10 15 Parameter(s) Affected seco mom." -1. Toxicty Limit: Acute, quarterly 5.4 7.6 95 400 BOD5, TSS, COD Fecal Coliform / TOXICS Monitoring Schedule: ,,,�'uti ` e• JAN, APR, JUL, OCT IWC = 0 . .9H - -Tof( Caru.,apic t`AH 3 ` 0.31 Ids/da,� O Toxics or metals limits Toxics limits based on the OCPSF guidelines are required. Since OCPSF parameters were below detectable levels on the annual pollutant analysis, the OCPSF guidelines should be sufficient to protect water quality. See attachment for limits. alato t jq•ncq. VGnaed ..hat eF )'ebo.f. . (,gyp,. Annual gross beta particle activity shall not exceed 50 pCi/L. ,ii�. opt.. /pt l`P H''�G'r+.•r'U°e ...s R. trw 4%4 %"' s e% <Cr. A rt- tkl sa,.u,.�. • -3- Request No. 5777 MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS Miscellaneous information pertinent to the renewal or new permit for this discharge. Include relationship to the Basinwide management plan. INSTREAM MONITORING REQUIRMENTS: Upstream: Y Location: Haw River at SR 1011 Donwstream: Y Location: Haw River, 1 mile below discharge, above confluence with Deep River it raw(ers : "Da, Temp • ! Cond., F eea( SPECIAL INSTRUCTIONS OR CONDITIONS SCHEDULE REQUIREMENTS: :/ c /.4.7 . /n fX ` aG .ct yam,'fitg�.�- ..� G . ✓ s.. . 7X .,- /A-• c.,,7 s 'Cr o/ dam-, J 4 c.:. c.. �O G✓L ! � �!'' r%( /4-1,C-u4, so (for P&E or reg on to recomxftend time frame for implementing new limits) ADDITIONAL "REVIEWER" COMMENTS: Additional Information attached? (yes or no) If yes, explain attachments. 1. Toxicity testing requirement. 2. OCPSF guidelines. OCPSF Subpart I 1 A OCPSF Regulations Subpart I B C ! D ! E F 2 3 4 Daily Max Effluent Characteristics (u g / I ) Monthly Avg (ug/I) Flow Daily Max (MGD) (lb/day) 5 6 7 8 9 10 Acenapthene Acrylonitrile Benzene Carbon Tetrachloride Chlorobenzene 1,2,4-Trichlorobenzene 59 242 136 38 28 140 22 96 37 18 15 68 0.004 0.0020 0.0081 0.0045 0.0013 0.0009 0.0047 1 1 12 13 14 Hexachlorobenzene 1,2-Dichloroethane 1,1,1-Trichloroethane Hexachloroethane 28 211 54 54 15 68 21 21 0.0009 0.0070 0.0018 0.0018 Monthly Avp (lb/day) 0.0007 0.0032 0.0012 0.0006 0.0005 0.0023 0.0005 0.0023 0.0007 0.0007 15 1,1-Dichloroethane 59 22 0.0020 0.0007 16 1 7 1,1,2-Trichloroethane Chloroethane 54 268 21 104 0.0018 0.0089 0.0007 0.0035 18 Chloroform 46 21 0.0015 0.0007 19 2-Chlorophenol 98 31 0.0033 0.001 0 20 1,2-Dichlorobenzene 163 77 0.0054 0.0026 21 22 23 24 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,1-Dichloroethylene 1,2-trans-Dichloroethylene 44 28 25 54 31 15 16 21 0.0015 0.0009 0.0008 0.0018 0.0010 0.0005 0.0005 0.0007 25 2,4-Dichlorophenol 112 39 0.0037 0.0013 26 1 ,2-Dichloropropane 230 153 0.0077 0.0051 27 1,3-Dichloropropylene 44 29 0.0015 0.0010 28 29 2,4-Dimethylphenol 2,4-Dinitrotoluene 36 285 18 113 0.0012 0.0095 0.0006 0.0038 30 31 2,6-Dinitrotoluene Ethylbenzene 641 108 255 32 0.0214 0.0036 0.0085 0.001 1 32 Fluoranthene 68 25 0.0023 0.0008 33 Bis(2-Chloroisopropyl)ether 757 301 0.0253 0 .01 00 34 35 Methylene Chloride Methyl Chloride 89 190 40 86 0.0030 0.0063 0.0013 0.0029 36 37 38 39 40 41 42 43 44 45 46 47 48 Hexachlorobutadiene Naphthalene Nitrobenzene 2-Nitrophenol 4-Nitrophenol 2,4-Dintrophenol 4,6-Dintro-o-cresol Phenol Bis(2-ethylhexyl)phthalate Di-n-butyl phthalate Diethyl phthalate 49 59 68 69 124 123 277 26 279 57 203 Dimethyl phthalate 4 7 Benzo(a)anthracene 5 9 20 22 27 41 72 71 78 15 103 27 81 19 22 0.0016 0.0020 0.0023 0.0023 0.0041 0.0041 0.0092 0.0009 0.0093 0.0019 0.0068 0.0016 0.0020 0.0007 0.0007 0.0009 0.0014 0.0024 0.0024 0.0026 0.0005 0.0034 0.0009 0.0027 0.0006 0.0007 Page 1 OCPSF Subpart I A B ` C D 1 E F 4 9 Benzo(a)pyrene 61 23 0.0020 0.0008 5 0 3,4-Benzofluoranthene 61 23 0.0020 0.0008 51 Benzo(k)fluoranthene 59 22 0.0020 0.0007 5 2 Chrysene 59 22 0.0020 0.0007 5 3 Acenaphthylene 59 22 0.0020 0.0007 5 4 Anthracene 59 22 0.0020 0.0007 5 5 Fluorene 59 22 0.0020 0.0007 5 6 Phenanthrene 59 22 0.0020 0.0007 5 7 Pyrene 67 25 0.0022 0.0008 5 8 Tetrachloroethylene 56 22 0.0019 0.0007 5 9 Toluene 80 26 0.0027 0.0009 6 0 Trichloroethylene 54 21 0.0018 0.0007 6 1 Vinyl Chloride 268 104 0.0089 0.0035 6 2 Total Chromium 2770 1 110 0.0924 0.0370 6 3 Total Copper 3380 1450 0.1128 0.0484 6 4 Total Cyanide 1200 420 0.0400 0.0140 6 5 Total Lead 690 320 0.0230 0.0107 6 6 Total Nickel 3980 1 690 0.1328 0.0564 6 7 Total Zinc 2610 1 050 0.0871 0.0350 Page 2 l/Plied 7 berms - ocv 1'7a 41 Tii vet rSter 1, P2 , Vttcrytie✓ a 44_ _565JY�Grvi.�5 F.4J 115 1si 13-04,- p7 cof4h�-�� a. 4- 4i/k7"P *Loi-L 4. ygdn"-) • PrZ7cos s kr.,as ��Z. = 4004) G ;,;-; .SCn,11/j w4.5c-A = iGy 060 G Pe e0o /i-s:5 6v@i / f f9/� �e'� dl fig f T� l/�� )L:? / baC " 1-,4 ,Gri/is m '44re5c re Ja8-on Ochs t h.1,s a... oo CPD pfoca r r.✓� stv�v c . L/m17'5 - ; ,eabj ; 755 ce,/? 4/Q74e/ vs', (cPsR e hu j ,s'raet0 7 'die) s- - f.. 4.41 _ .0/ f!e¢2 (6 y/,) (i, ,0 , oa$1 /to (. - �0//) (8: 3 y) 30 / /bs/'al f , l\ 755 - men- 1.-4, �� = 4.00 sv)(Js 34) * ODY43) ,) C8%3 1) C o!> A n t f3 are P. s 44.c r f fs t a r del /7„._ 38, S /6 /d47 - �IGw2,ve• • 416-eaf 6.2 0 ) E;11--J i//c/9/ 1. POLLUTANT. AND CAS NUMBER : fit available) . 2. MARK 'X' • ' a;W:1- 2i,i,7,:- 0, L•j,t-r, 8. MAXIMUM r o'6%- F-0 i:.•,- 5^0.-T 01 CONCLNTRATIONL GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS ( :226:11;47Dichloro- Xaniene:(1.06-46-71 X LT 10 2313,3,3!-Dichloro- banzldine.::-: (91.-94.1) ' ;,24B. Diethyl, 'Phthalate ' .!;(8466-2) .,, .,256". Dimethyl Phthalate'''. (131-11-3) LT 20 •:2613:!:DI7N-Butyl .:Phthatat0:-i; :.; 84,4-Dinitro• - tbluione1121:14-3) X 2;6-.Dinitro- ."'.ialt2ane:(606-20-2) X 2913D i-N-Octyl 'Phthalate (117-84-0) X 3013..1,2-Dtphenyl- hydrailne (as Azo- benzene) (122-66-7' 31B. Fluoranthene ,(206-44-0) X '3213:.Fluorene ;486-7.3-7); X LT 10 LT 10 LT 10 LT 10 LT 10 338.HexaChlorobenzene 1119.7A-11 X LT 10 343. Hexa- *chIcrobutadiene (87-68-3) LT 10 35111Mexachloro- ,iycl9pentadiene , ,171:47-4)• ' - LT 10 35 li: i-ix OCh loro- Athena (67-72-1) LT 10 3713..Indeno 4(1;2,3-cd) Pyrene (193-39-5) A LT 10 388. lsophorone 1) X LT 10 39B. Naphthalene (91-20-3) X LT 10 406. Nitrobenzene (98-95-3) X LT 10 41B. N-Nitro- sodimethylamine (62-75-9) LT 10 42B. N-N itrosodl- 1 N-propyiemineX 1621-64-7) _1 LT 10 att -6A-1e-4,1715 , WI)/ ocFSF CONTINUED FROM PAGE V-4 I 1. POLLUTANT 2. MARK AND'CAS : NUMBER a ;r,..fr' LliVWE:-0 4%tEE- a. MAXIMUM E ''. (iraviiilab lc) ED CONCE NTRATION PC/MS'FRACTION - VOLATILE COMPOUNDS (contir 22V. Methylene Ctiloilde175.-09-2)- X LT 10 23y..1,12,2r ra- Chroricethine') (7.9:=4-5)1V4X:'.:.-,. X LT 10 9q*J. 24V.7.13tra0 h 10 l'11::- liaznii,(127:18-4) , X LT 10 ?AY.-tTr/luene • ,7-,..,... 4430,8A8-3)Licy..F,'Ai':z. X LT 10 26.VM;2•Trans-.; CildhIaroetItYlene't'; y LT 10 27V:(1;11,-Tr(- , chloroethane'r : x LT 10 28W,,1,1,2-Trl- chi& °ethane ”; ' 20V. Triehloro. ath1..,,,ylene (79-01-6) i-,4,0 X LT 10 30V7r,ichloro-' ftuorornethane (75-694)z x • LT 10 .31V: Vinil Vilorlde,(75-01-4) X LT 10 GCNIS FRACTION - ACID COMPOUNDS 1A. 2-Chforopheno) (95_5 7,-8) X . LT 10 2A. 2,4-Dichloro- phenol (120-832) x LT 10 3A. 2,4-oimethYl- phenol (105-67-9) • X LT 10 4A. 4,6-Din itro-0- Cresol (534-52-1) X LT 50 5A. 2,4-Dinitro- phenol (51-28-5) ' X LT 50 6A. 2-Nitrophenol (88-75-5) X LT 10 7A'. 4-N itrophenol e•,•,,,,, • ..- X LT 50 8A. P-Chloro-M- Cresol (59-50-7) X LT 10 9A. Pentachloro• phenol (87-86.5) X LT 50 10A. Phenol (108-95-2) X LT 10 11A. 2,4,6-Tri- chlorophenol (88-06-2) X LT 10 • .4a7f46.e-i —3 I.' POLLUTANT 2. MARK 'X' ?' AND•CAS ' )'NUMBER„ • ,. yC r� (!f"arailabie).: },., •. a •TEST- INo QUCR- EG b. ea- LIEVEouEVEo SENT CBE- SENT 8. MAXIMUM D CONCENTRATION METALS;CYANIDE, AND TOTAL PHENOLS :+lYi y...::. gym,:: ,:....• ;1., 'Total (7440-36-0):.: X 46 2M:,Arse6le T'6ta1 `(7440-3872)' X LT 5 .3i4Beryll)um,• Tota1;7440.41.7) X LT 1 4M ;Cadm)um, Tata)'(7440.43.9) X X LT 5 LT 8 5M. Chromium, Total (7440-47-3) 6M. Copper, Total' (7440.60.8) X • 29 7M. Lead: Total ,(7439-92.1) X LT 5 8M. Mercury, Total (7439.97,-6) X LT 0.2 9M. Nickel, Total (7449-02-0) X LT 50 10M:•' Selenium, Total.(7782-49.2) X LT 10 '11M:`;SiI er, Total (7440.22.4) X LT 5 12M, Thallium, Total (7440.28.0) X LT 65 13M. Zinc, Total (7440-6.6). X 205 14M; Cyan)da, Total.(67.1241) X LT 20 !To aI Phanolel X LT 5 DIOXIN 2,3,7,8-Tetra- chlorodibenzo-P- Dioxin (1764-01-6) DESCRIBE RES AL .CO AL oN l ,4-4,nawy) coffer, 2r"L a6av?. DI_ u5-t L%C Ps..r q u,:t l a2 Lk .. v ytp c S ✓ 7�` �o-fa1 P4146 — 5k1 = 31.1 ✓15 MI BDL "r°f -1,, ('Orc;Prerf ?A-te 3 a `¶ 119s7,441 -ro+rQ =39L 0-71(o (yr° PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information on separate sheets (use the same format) instead of completing these pages. SEE INSTRUCTIONS. EPA I.D. NUMBER (copy from Item 1 of Form I) NCD053488409 Form Approved. OMB No. 2040-0086 Approval expires 7-31-88 V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) "PART•A - You must provide the results of at feast one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2. EFFLUENT I.'POLLUTANT a, Biochemical.. Oxygenbemand 0101.4Wsr;,( b.. Chemical Oxygen Demand (COD) a. MAXIMUM DAILY VALUE (I ) CONCENTRATION 58 (2) MASS 46 b. MAXIMl.1M 30 pAY VALUE C.LONG Tfi}2 �VRf, VALUE ([ ava a e) i bl (I) CONCENTRATION 30 (2) MASS 24 (+I CONCENTRATION 5.9 (2) MASS 4.8 d. NO. OF ANALYSES 32 3. UN TS (specify if blank) a.CONCEN- TRATION mg/L b. MASS lb/day OUTFALL NO'. 001 4. INTAKE (optional) a. LONG TERM AVEFIAGVALUE, (1) (2) MASS CONCENTRATION b. NO. OF ANALYSES • c. Total O.rgartic. Carbon (TOC) d. Total Suspended Solids (TSS) e. Ammonia (as Al.) 120 71 95 84 74 29 56 32 45.5 21 38.5 32 mg/L lb/day 18 32 mg/L lb/day f. Flow g. Temperature (winter) '. h. Temperature (summer) i. pH 29 27 LT 0.3 VALUE VALUE VALUE 0.178. 14 VALUE 0.109 14.2 9.4 VALUE 0.088 8.1 32 mg/L lb/day 1 365 mg/L MGD VALUE MINIMUM 6.6 22 29 MAXIMUM 8.2 VALUE VALUE MINIMUM 7.0 17 26 MAXIMUM 8.2 VALUE VALUE 12 113 oC VALUE 24 125 oC STANDARD UNITS VALUE PART B - Mark "X" in column 2-a for each pollutant you know or have reason to believe is present. Mark "X" in column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirect y but expressly, in an effluent lim itations guidel ine, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details and requirements. 1. POLLUT- ANT AND CAS NO. (if available) 2. MA a. BE- LIEV EC PRE. SENT RK 'X' b. BE- LIEVER AB- SENT a. MAXIMUM DAILY VALUE CONCENTRATION (2) MASS 3. EFFLUENT b. MAXIMI.IMava' 30a e) DAY VALUE (e CONCENTRATION (2) MASS a. Bromide (24959-67-9) b. Chlorine, Total Residual X X 1.2 1.3 0.7 0.8 1.0 0.8 C. LONG T tBaI a able) . VALUE CONCENTRATION 0.9 (2) MASS d. NO. OF ANAL- YSES 4. UNITS a. LONCEN- RATION b. MASS 5. INTAKE (optional) a. LONG TERM AVERAGE VALUE 11 CONCENTRATION (2) MASS b. NO. OF ANAL- YSES 0.7 1 348 mg/L lb/day mg/L lb/day c. Color d. Fecal Coliform X LT 5 1 e. Fluoride (16984-48-8 ) X X f. Nitrate - Nitrite (as N) X EPA Form 3510-2C (Rev. 2-85) 10 0.2 0.12 1.2 0.7 3 1 LT 1.5 31 PCU COL/ 100 ml 1 mg/L lb/day 1 mg/L lb/day 'AGE V-1 CONTINUE ON REVERSE EPA I.D. NUMBER (copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NCD053488409 001 Form Approved. OMB No. 2040-0086 Approval expires 7-31-88 PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary industries, nonprocess wastewater outtalk, and nonrequired GC/MS fractions), mark "X" in column 2-b for each pollutant you know or have reason to believe is present. Mark "X" in column 2-c for each pollutant you • believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4' dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in -concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements. ' POLLUTANT 2. MARK 'X' 1. AND CAS NUMBER (if available) - 3. EFFLUENT a. MAXIMUM DAILY VALUE (I) CONCENTRATION METALS,CYANIDE, AND TOTAL PHENOLS a.TEST• INC RE- DUIR- ED 1M. Antimony, Total (7440-36-0) X 2M. Arsenic, Total (7440-38-2) _ 3M. Beryllium, Total, 7440-41-7) X b. BE- LIEVED PRE- SENT a BE- LIEV EI AB- SENT 46 LT 5 LT 1 (2) MASS 0.03 b. MAXIMSJM 31) DAY VALUE hf auailab(e) (I) CONCENTRATION (2) MASS c.LONG TXt ailabl) - VALUE (I) CONCENTRATION (2) MASS d. NO.OF ANAL- YSES 4. UNITS a. CONCEN- TRATION b. MASS 5. INTAKE (optional) a. LONG TERM AVERAGE VALUE (1) CONCEN- (2) MA55 TRATION b. NO.OF ANAL- YSES 4M. Cadmium, Total (7440-43-9) 5M. Chromium, Total (7440-47-3) 6M. Copper, Total (7440-50-8) 7M. Lead, Total (7439.92.11 8M, Mercury, Total (7439-97-6) X X X LT 5 LT 8 -29 LT 5 LT 0.2 9M. Nickel, Total (7440-02-0) 10M. Selenium, Total (7782-49-2). 11M. Silver, Total (7440-22-4) 12M. Thallium, Total (7440-28-0) 13M. Zinc, Total (7440-66-6) 14M. Cyanide, Total (57-12-5) X X X X X LT 50 LT 10 LT 5 LT 65 0.02 205 0.12 1 1 1 1 1 1 1 1 1 1 1 1 ug/L uq/L ug/L ug//L ug/L ug/L ug/L ug/L ug/L ug/L ug/1 lb/day lb/day ug/L 1 X LT 20 15M. Phenols, Total X LT 5 DIOXIN 2,3,7,8-Tetra- chlorodibenzo-P- Dioxin (1764-01-6) X DESCRIBE RESULTS 1 1 ug/L ug/L uq/L lb/day EPA Form 3510-2C (Rev. 2-85) PAGE V-3 CONTINUE ON REVERSE EPA 1.D. NUMBER (copy from Item 1 of Form 1) Otr fFALL NUMBER L CONTINUED FROM PAGE V-4 1. POLLUTANT AND CAS NUMBER (if available) 2. MARK 'X' a.TEST• ING R E- OUIR- .�D b. sE- LIEV EO PRE- SENT C. BE- LIEV EO AB- SENT a. MAXIMUM DAILY VALUE (1) CONCENTRATION (2) MA55 GC/MS FRACTION — VOLATILE COMPOUNDS (continued) 22V. Methylene Chloride (75-09-2) X 23V.1,1,2,2-Tetra- chloroethane X (79-34.5)' 24V. Tetrachloro- ethylene.(127-18-4) X 25V:Toluene (:1,08 88=3y 26V. 1,2-Trans-. Dichloroethylene (156-60-5) 27V. 1,1,1-Tri= chloroethane. (71.55-6)- 28 V. 1,1,2-Tri= chloroethane (79-00-5) X X LT 10 LT 10 NCD053488409 3. EFFLUENT b. MAXIM(JM 3 Y VALUE (if available) CONCENITRATION (2) MASS c.LONG CONCEN LT 10 LT 10 LT 10 LT 5 X LT 10 LT 10 29V. Trichloro- ethylene (79-01-6) 30V. Trichloro fluoromethane (75-69-4) LT 10 LT 5 LT 5 X 31V, Vinyl Chloride (75-01-4) X LT 10 GC/MS FRACTION — ACID COMPOUNDS 1A. 2-Chlorophenol (95-57-8 ) X 2A. 2,4-Dichloro- phenol (120-83-2) 3A. 2,4-Dimethyl- phenol(105-67-9) 4A. 4,6-Dinitro-0- Cresol (534-52-1) 5A. 2,4-Dinitro- phenol (51.28-5) • 6A. 2-N itrophenol (88-75-5) LT 10 F LT 10 LT 10 LT 10 LT 50 LT 50 X 7A. 4-N itrophenol (100-02-7) X 8A. P-Chloro-M= Cresol (59-50-7) LT 10 9A. Pentachloro- phenol (87-86-5) LT 50 LT 10 LT 50 10A. Phenol (108-95-2) 11A. 2,4,6-Tri- chlorophenol (88-06-2) x EPA Form 3510-2C (Rev. 2-85) LT 10 LT 10 PAGE V-5 001 OMB No. 2040-0086 Approval expires 7-31-88 4. UNITS 5. INTAKE �/ � TERua able?. VALUE (�1lii �a ble) d NO.OF ANAL- YSES _ e. CONCEN- TRATION b, MASS • (optional) a. LONG TERM AVERAGE ygLUE b. N45.Or I (z) MASS (1) conc EN- TRATION (2) MASS ANAL - YES RATION 1 ug/L 1 ug/L 2 ug/L 1 ug/L 1 ug/L 2 ug/L 1 ug/L 2 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L i- 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L CONTINUE ON REVERSE CONTINUED FROM PAGE V-6 IEPA 1.0. NUMBER (copy from Item 1 of Form 1) Ifl NCD053488409 OUTFALL NUMBER • 1. POLLUTANT AND CAS NUMBER (if available) 001 Form Approved. OMB No. 2040-0086 Approval expires 7-31-88 2. MARK 'X' a.TEST ING RE- GUIR- F-n b. BE- C. BE- LIEVEOLIEVEI PRE- AB- SENT SENT a. MAXIMUM DAILY VALUE CONCL N1 RATION (z) MA55 GC/MS FRACTION — BASE/NEUTRAL COMPOUNDS (continued, 22B. 1,4-Dichloro- benzene'(106-46-7 23B. 3,3'-Dichloro benzidine (91-94-1) x LT 10 3. EFFLUENT b. MAXI 30 pAY VALUE (r aum a e) CONCENTRATION 12) .Ass c.LONG TlIua'iable) CONCENTRATION d, NO.OF a. CONCEN- (z) MASS YSES ANAL- TRATION b. MASS 4. UNITS . VALUE 5. INTAKE (optional), a. LONG TERM AVERA EVALUE (II CONCEN- TRATION (2) MASS b. Nt.i.OF A4-SAL- YSES x 246. Diethyl. Phthalate (84-66-2) 25B. Dimethyl Phthalate (131-11-3) 26B:,Di-N-Butyl Phthalate (84-74-2) x LT 10 LT 10 LT 20 x LT 10 1 ug/L 1 ug/L 1 ug/L 278." 2,4 Din(tro- -toluene (121-14-2) x LT 10 28B. 2,6-Din itro- toluene (606-20-2) x LT 10 29B. Di-N-Octyl Phthalate (117-84-0) x LT 10 308. 1,2-D ipheny (- hydrazine (as Azo- benzene) (122-66-7) 316. Fluoranthene (206-44-0) 328. Fluorene (86-73-7) x x LT 10 LT 10 1 ug/L 2 ug/L 1 ug/L 1 ug/L 1 ug/L ug/L 338. Hexacnlorobenzene (11R-74-11 346. Hexa- chlorobutadiene (87-68-3) x LT 10 LT 10 35B. Hexachloro- cyciopentad iene (77-47-4) x LT 10 36B. Hexachloro- ethane (67-72-1) 37s.Indeno (1,2,3-cd) Pyrene (193-39-5) LT 10 x LT 10 386.Isophorone (78-59-1) x LT 10 39B. Naphthalene (91-20-3) 408. Nitrobenzene (98-95-3) LT 10 LT 10 41B. N-Nitro- sodimethylamine (62-75-9) 42B. N-Nitrosodi- N-Propylamine (621-64.7 ) x LT 10 LT 10 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L EPA Form 3510-2C (Rev. 2-85) *Refer to Supplemental Information PAGE V-7 Attachment Section V, Part C CONTINUE ON REVERSE CONTINUED FROM PAGE V-8 EPA I.D. NUMBER (copy from Win 1 of Form 1) OUTFALL NUMBER NCD053488409 • J• 1. POLLUTANT AND CAS NUMBER (i/ auailable) 2. MARK 'X' aTESTb. BE- C. BE- ING LIEVEOLIEVEI Re- PRE- AB- OIJIR- SENT SENT L-O , 8. MAXIMUM DAILY VALUE (I) (2) MASS CONCENTRATION GC/MS FRACTION — PESTICIDES (continued) 17P. Heptachlor Epoxide (1024-57-3) 18P. PCB-1242 (53469-21-9) X LT 0.05 LT 0.5 19P. PCB-1254 (11097-69-1) 20P. PCB-1221 (1 1104-28-2 ) 3.EFFLUENT b. MAXIMUM 30 DAY VALUE (if ova table) CONCENTRATION (2) MASS 001 c.LONG Tgrel a QAa'[Re5. VALUE (iil (I) ONCENTR ATION (2) MASS d, NO.OI ANAL- YSES 4. UNITS - CONCEN- TRATION LT 1.0 LT 0.5 21P. PCB-1232 (11141-16-5) LT 0.5 22P. PCB-1248 (12672-29-6) LT 0.5 23P. PCB-1260 (11098-82-5) 24P. PCB-1016 (12674-11-2) LT 1.0 LT 0.5 25P.Toxaphene (8001-35-2) LT 1.0 1 1 1 1 1 1 ug/L ug/L ug/L uq/L ug/L ug/L Form Approved VMS No. 204(10086 Approval expires 7-31-88 b. MASS 5. INTAKE (optional). a. LONG TERM Al[RAGE VALUE (1) CONCEN- TRATION (2) MASS b. NO.OF ANAL- Y0E.S ' 1 ug/L 1 ug/L 1 PAGE V-9 ug/L EPA Form 3510-2C (Rev 2-85) FORM 2C SUPPLEMENTARY INFORMATION ITEM II. B: Outfall 001: Sanitary wastewater flows to a pumping station equipped with a comminutor, a bar screen bypass and a Parshall flume for flow recording. Waste is pumped to the aeration basin, entering about 40 feet from the process waste influent point. Fiber finish oil, which is primarily composed of fatty acid esters, organo- silane esters, and alkylamine, oleate and trioleate emulsifiers, is segregated from other process waste for pretreatment. An ultrafiltration unit is used to separate the oil from the water. The water is pumped to the wastewater treatment plant and the oil is burned on -site for energy recovery. Process wastewater flows to a pumping station equipped with a manually cleaned bar screen and a Parshall flume for flow recording. It is pumped to a 1200 gallon mixing chamber which allows for pH adjustment. During emergencies, the flow can be diverted to a 600,000 gallon holding pond. The aeration basin has a volumeof approximately 650,000 gallons and is equipped with four (4) 20 HP floating aerators. The waste then flows to a 20 feet diameter clarifier with a design overflow rate of 440 gallons per square foot per day. A surface skimmer and holding sump are provided. Pumps are provided to return settled sludge to the aeration basin or to a sludge drying bed. Clarifier overflow is piped to a one acre polishing pond operating at a 3 foot depth. A .4 acre alum settling pond is provided for the potable water plant backwash and. blowdown. The clarified discharge from the alum pond is pumped to the polishing pond. Effluent from the polishing pond flows through a 3600 gallon retention chamber for chlorine disinfection. A V-notch weir at the effluent end of the chamber provides for flow recording. During the summer months, algae activity increased the pH of the polishing pond above 9.0 standard units. When this occurs, clarifier overflow is valved directly to the chlorine contact chamber where it is blended with 'polishing pond effluent prior to entering the chamber. Approximately 8,000 pounds of sludge is wasted during the year to a sand drying bed. Wastewater that drains through the sand is pumped back to the aeration basin. On October 26, 1989 approval was received (Permit #19-01) from the Department of Environment, Health and Natural Resources, Division of Solid Waste Management for the continued disposal of dried wastewater treatment plant sludge at the Chatham County landfill. Based on the submitted information (EP-TOX, pH, paint filter test, total petroleum hydrocarbon analysis, GC/MS purgeable [SW-846 Method 8240], and base/neutral/acid extractables [SW-846 Method 8270]), the sludge was determined by the Division to be non -hazardous. The approval requires submittal of a waste determination form and supportive analytical data on the third anniversary of the permit. As an alternative disposal method, the plant is examining an on -site land treatment or utilization/nutrient transfer program. Should the plant -2- decide to pursue this option, a permit application per 15NCAC2H.0200 Waste Not Discharged to Surface Water will be submitted to the Division of En- vironmental Management, Department of Environment, Health and Natural Resources. Outfall 002: This drainage system includes a series of baffles and weirs designed to contain accidental spills of oil and Dowtherm. In an emergency, flow can be contained in a holding pond and pumped to storage or the wastewater treatment plant. Storm water runoff from most of the manufacturing areas and chemical storage areas of the plant is discharged through permitted outfalls 001 and 002. Storm Water Other storm water discharges are described in the permit application submitted to the N.C. Division of Environmental Management on April 16, 1985. Storm water information will be updated when final storm water regulations are promulgated by the EPA. ITEM III. A & B: On November 5, 1987 EPA issued regulations establishing effluent limitations and standards for the Organic Chemicals, Plastics, and Synthetic Fibers (OCPSF) industrial category. Provisions of Subpart C (414.31) and Subpart I (414.90) Direct Discharge Point Sources That Use End -of -Pipe Biological Treatment are applicable to process wastewater discharges from the manufacture of polyester fiber and resin. OCPSF effluent guidelines are not expressed in terms of production. No metal -bearing waste streams or cyanide -bearing waste streams listed in Appendix A to Part 414 exist in the manufacture of polyester fiber and resin. ITEM V. A-C: Wastewater characteristics tabulated in item V reflect data from the period January 1, 1989 to December 31, 1989. For some parameters, testing was conducted throughout the year and for other parameters testing was done on a more limited basis. Special tests were conducted for most of the parameters. Bis-chloro-methyl ether (FR 2/4/81) and dichlorodifluoromethane (FR 1/1/81) have been dropped from the 2C GC/MS Fraction -Volatile Compound list by the EPA. 1,2-Diphenylhydrazine as azobenzene was not detected in the influent, outfall 002 or outfall O 01. A precise determination of a reporting limit was not made since azobenzene is not a target constituent in EPA's CG/MS methods 624 or 625. ITEM V. D: This list is as complete as possible; however, since some manufacturers consider their products proprietary they will not release information on the composition. Therefore, there may be other materials on the plant site that contain one or more of the chemicals in Table 2C-3. In addition, new materials may be obtained that may have one or more of the chemicals listed and whose composition may or may not be known. -3 ITEM VI: The following is a list of Part V. C pollutants that are present on the plant site. None of these materials are used as a raw material or inter- mediate and none of these materials are manufactured as a product or are a by-product of the manufacturing process. The list may not be exhaustive because some commercial products are considered proprietary by the manufacturer and their composition is not known to us. In addition, some new materials may be obtained in the future that contain one or more of the listed chemicals and whose composition may not be known to us. Pollutant Use on Site Antimony Chromium Copper Lead Mercury Nickel Silver Zinc Cyanide Phenols Carbon Tetrachloride Chloroform Dichlorodifluoromethane Methylene Chloride Methyl Chloride 1,1,2,2-Tetrachloroethane Tetrachloroethylene Toluene 1,1,1-Trichloroethane Trichloroethylene Phenol Benzidine Dichlorobenzene 1,2,4-Trichlorobenzene PCB ITEM V. PART C: IIV. Chloroform Lab Reagents Lab Reagents Lab Reagents Lab Reagents Lab Reagents, Instrumentation Lab Reagent Lab Reagents, Electrical Equipment Lab Reagents Lab Reagents Lab Reagents Lab Reagents Lab Reagents Lab Reagents, Refrigerant, Leak Checks Adhesive Ingredient Solvent Lab Reagent Solvent Lab Reagent Solvent Solvent Lab Reagent Lab Reagent Lab Reagent Electrical Equipment Electrical Equipment In December, 1988 and April, 1989 studies were conducted on OCPSF process related wastewater sources and wastewater treatment plant influent, clarifier overflow and effluent to determine if chloroform carries through the treat- ment plant or is formed during effluent disinfection. Chloroform was not detected in either the OCPSF process related wastewater sources or the clarifier overflow. Chloroform was detected in the influent and the effluent from the treatment plant. -4- Chloroform in the influent is due to the chlorination of river water in the site's potable water treatment plant. Analytical data has been compiled on the formation of trihalomethanes in the potable water and we are tracking the effectiveness of carbon filters on drinking water coolers. The risk of wastewater contamination with chloroform is minimal since the only area of the plant that handles chloroform is the Quality Control Laboratory, which uses a cresol/chloroform solution for polyester fiber testing. Handling procedures require that all waste solvent be placed in a hazardous waste drum for off -site incineration at an EPA approved facility. Actions are being taken to reduce the chlorine dosage and the resulting residual chlorine level in the effluent. This should decrease the level of chloroform in the effluent. NPDES WASTE LOAD ALLOCATION PERMIT NO.: NCOO 0/9 9 9 Modeler Date Rec. FACILITY NAME: A Ili er% SJna 1, / F,'der, Facility Status: �� PROPOSED (circle on.) ~ Permit Status: 1�lEWAt) MODIFICAMON tNPERMITIED NEW (circle one) Major _ v Minor Pipe No: OD et Design Capacity (MGD): Domestic (% of Flow): Industrial Comments: 0 (% of Flow): /0 0 SligevrvuLatt. tr42#, 94111 64A-e4e4A4), RECEIVING STREAM: %/ adDcA Cr Class - Sub -Basin: Q3-0G-67 Reference USGS Quad: 'a�� (please attach) County: calla. tA 61-rn Regional Office: As Fa Mo . Wa Wi WS (elyd. •.•) Requested By: P9 S&thhe_ �4rortl��Date: Prepared By: Date: %/l2 /`l Reviewed By: liff14.1 Date- 6[ (Zig( /o- tack Drainage Area (m12) G _ Avg. Streamflow (cfs): b MP5 S77 g 7Q10 (cfs) . 0 Winter 7Q10 (cfs) 30Q2 (cfs) Toxicity Limits: IWC /- O % (ctrel. on.) Instream Monitoring: Parameters T Me P k, )6 Cow cf Upstream Downstream ✓ Location S/`" 11°A Creek S2 loll Chronic rs�eC c. Location 'h'4hK (I' I" 4G.14-e Effluent Characteristics D,4,y� ,s Ale BOD5 (mg/I) NHj N (mg/I) D.O. (mg/I) TSS (mg/I) F. Col. (/ 100ml) pH (SU) r- 6,/ �2 Po wi tip (v,. 1 1 f) ��? (0 L.X/4, �1�Ct�SII) . fr t( rt?'k( vc ) laps L shtrat Hot—r..u5e Ie.., 7 2 t qc,0 o.se d y 'i a ii-esKeeta... , a-4r'C s . 6 ck 4 a �� 1 Comments: e s ci' a dto case a ceicf be . APPENDIX A CHEMICAL INVENTORY The attached is a listing of process and non -process chemicals used at the plant. Many of these chemicals are not routinely monitored for and are not normally present in our discharge, but they could at times appear as a result of events beyond our control. APPENDIX A PROCESS CHEMICAL INVENTORY RAW MATERIALS Ethylene Glycol Terephthalic Acid CATALYSTS Antimony trisethylene glycoxide Titanium Chelate PROCESSING AID Diisopropylamine Dow Corning Antifoam Polyphosphoric Acid PRODUCTS Polyethylene Terephthalate (Polyester) BYPRODUCTS Aldehydes (i.e., acetaldehyde & crotonaldehyde) Diethylene Glycol Spent Ethylene Glycol FINISH OIL COMPONENTS Alizarine Cyanine Green GN Caplube 8337 Caplube 8369 Coconut Oil Decaglycerol Monoleate Giv-Gard DXN Glycerol Monoleate Hexadecyl Stearate Mineral Oil Polyethylene Nonyl Phenol Pentaerythritol Ester Polyoxyethlene, Alkanol Ethers Polyoxyethlene, Alkyl Amine Polyethylene Glycol Monotallate Santowhite Crystals Silane A-187 Sodium Petroleum Sulfonate & Mineral Oil Sulfonated Aliphatic Polyester Tridecyl Phosphate Yellow SV Tint R & D CHEMICALS A pilot plant is operated at the site for research and development work. This work periodically involves the use of small quantities of a variety of chemicals as polymer additives and finish components. APPENDIX A NON -PROCESS CHEMICAL INVENTORY Page No. 1 03 / 22 /90 Product Company Ingredients uA-9" Reiton Corporation White Mlinerai Oil #100 Red Unity Oil Mariam Instrument Monochlorona.pht ialene * Naphthalene Dichloronaphthalene * Petroleum Distillate * Petroleum Lube Oil * Red Dye #1000 Green Concentrate #104 Hi -Vac Red Fluid #120 Yellow Oil #175 Blue Fluid #190 Red Fluid Meriam Instrument Butyl Cellosolve * Ethylene Glycol Dater * Green Dye Meriam Instrument' Dibutyl Phthalate * Red Dye Meriam Instrument t1onochloronaphthalene * Naphthalene Dichloronaphthalene * Yellow Dye Meriam Instrument Brominated Ethylbenzene Isomers * Blue Dye Meriam Instrument Chlorotrifluoroethylene Polymer * Red Dye #200 Red Dye tier i arm Instrument #295 Fluid Meriam Instrument #6 Residual Fuel Amerada Hess Oil, H/S Corporation #827 Red Oil Meriam Instrument 1 Gal 707 Activator Loctite Corporation Item 70770 1,1,1,3,3,3-Hexaflua Fisher Scientific r o-2-Pr opa r o t 1 ,1 , 2 , 2-Tetrach 1 oroe Eastman Kodak thane Company 10 NL Bearing/MT/ADH Loctite Corporation Sealant - Item 8521 10-8109 Silicone GC Electronics Heat Sink Compound 10NL EV Item 7921 Braminated Ethylbenzene Isomers * Red Dye Acetylene Tetrabromide * Ar-Ethly Bromobenzines * Red Dye Petroleum Distillates (NBC) * Sulfur Deodorized Kerosine * Petroleum Distillate * Petroleum Lube Oil * Red Dye 1,1,1-Trichloroethane * Butanal-aniline condensate * t-Butyl alcohol Dimethoxymeth-ane 1 , 1 , 1 , 3. 3, 3-Hexaf loom-2-Pr opanol i 8 2 T-i.___ hloroethane Polyglycol Dimethacrylate * Polyglycol Dioctanoate * Cumene Hydroperoxide Cellulose ester * Saccharin N,N_Dialk:yltcluidines Polysiioxaine * Zinc Oxide Loctite Corporation Polyglycol Direthacrylate * Polyglycol Diocanoate * Cumeiie Hydroperoxide Cellulose ester * Trial.k:y'la :ine Page No. 2 03/22/90 Product 1250 Almaso1 High Temp Lubricant Company Lubrication Engineers, Inc. 170 Aluminum Asphalt Porter Paint Co. Roof Coating 2- (2-Methoxye thoxy ) Ethanol 2-Propano1 Ingredient=_. Nitrous Acid * Sodium Salt * Hydroily-4-Methy1-2--F'entanone (Daicetone Alcohol) * Oil Mist (Mineral) Mineral Spirits * Aluminum * Mica Eastman Kodak 2-(2-Methoxyethoxy) Ethanol Company Fisher Scientific 2-F'ropanol 3M Brand Super 77-N 3M Center Spray Adhesive 3M Feathering Disc Adhesive Fart Nos. 05041 / 05043 3M Center Methylene Chloride * 1-1-1-trichioroethane * Diethylene Ether * Chlorodif luoromethiane Propellant n-hexane * other hexane isomers * styrene-butadiene polymer * hydrocarbon resin glycerol esters of rosin acids 4 Oz 404 Item 46548 Loctite Corporation Ethyl cyanoacrylate * Poly (methyl methacrylate) * Hydroguinone 4-Carboxybenzaidehyd Aldrich Chemical 4-Carboxybensaldehyde e Company 454 Sandy Beige Tennant Company Urethane Color Coat 50 ML Small Screw Thrd lcker 222 Item 50 ML Speedbonder 319 Adh. 50ML Hydraulic Sealant Item 56931 5OML Removable TL 242 Item 24231 Xylene * n-Butyl Acetate * Mineral Spirits * Modified Alkyd Resin* TaaniulTi Dioxide * Yellow Iron Oxide * Red Iron Oxide * Carbon Black Loctite Corporation Polyglycol Dimethacrylate * F'olyglycol Oleate * Saccharin * Cumene Hydroperoxide Methanol * Silicon dioxide, amorphous * N.N-Dialk:yitoluidines * Titanium Dioxide Loctite Corporation Polyurethane Methacrylate Resins * Hydroxyaikyl Methacrylate * Polymeric Plasticizer * Acrylic acid * ! umene hydroperoxide * Substituted silane * 1-Acety1- phenylhydrazine * Saccharin Loctite Corporation Polyglycol Dimethacrylate * Polyglyco1 Dioctoate * Poly(butyl methacrylate) * Cumene hydroperoxide * Saccharin * N,N-Di alkyltoluidines Loctite Corporation Polyglycol Dimethacrylate * Polyglycol Oleate * Saccharin * Cumene hydroperoxide Methanol * Silicon dioxide, amorphous * N,N-Dialkyltolui.dines * Titanium Dioxide F Page No. 03: 22 / 9 r_' 0-1 Product Company 6305 Monolec Rack Lubrication Drill Lubricant Engineers, Inc. 690 Penetrant and Chesterton, A. W. Lubricant (Aerosol) Company 7130 Thin Coat Resurfacer Part A 7130 Thin Coat Resurfacer Part B 7140 Thin Coat Resurfacer Part A Tennant Company Tennant Company Tennant Company 7140 Thin Coat Tennant Company Resurfacer Part B 7200 Thick Coat Tennant Company Resurfacer Part A 7200 Thick Coat Resurfacer Part 2 Tennant Company 720017210 Thick Coat Tennant Company Resurfacer Part C 7210 Thick Coat Resurfacer Part A 7210 Thick Coat Resurfacer Part B 75435 Texacar EC GOML Tar: Pak Accelerator (Item) 11525) and 20riL Adhesive (Item 12292) 921 Sealant (Stick Grade) A-100 Flat Latex House & Trim Paint Company A6 R 17 Base D (Woadb1n) Tennant Company Tennant Company Texaco Chemical Company Locti.te Corporation Ingredients Mineral Oil Mist Propane Bisphenol * A-Epichlor-ohydrin Resin * Aliphatic Polyglycidal Ether Aliphatic Ether Amine * Proprietary Curing Promoter A-Epichlorohydrin Resin * Aliphatic Polyclycidal Ether * Titanium Dioxide Yellow Iron Oxide * Carbon Black. Aliphatic Ether Amine * Proprietary Curing Promoter s Bisphenol * A-Epichlorohydrin Resin * Aliphatic Polyglycidal Ether * Titanium Dioxide * Yellow Iron Oxide * Carbon Black Aliphatic Ether Amine * Proprietary Curing Promoter" Silicon Dioxide Bisphenol * A-Epichlarohydrin Resin * Aliphatic Polyglycidal Ether Aliphatic Ether Amine 1 .3-Diaxolan-2-cone Trichlorotrifluoroethane * Acetone * N,N-Dialk:yitoluidiiie * Hydroquinone * Ethyl cyanoacrylate * Poly (methyl rnethacr ylate) E.TR Valve Sealants, F'olybutanes * Mineral Oil * Polyethylene Inc. * Mixed Terphenyls * Mica * Anti -Oxidant Sherwin --Williams Ethylene Glycol Page No. 4 03/22/90 Product Company A-100 Gloss Latex Sherwin-Williams House Paint A8 R 27 Company Base D (Woodbin) A-100 Stain & Finish Sherwin-Williams B22 R 1 Rooster- Red Company AO Superclear Lens Cleaning Fluid -Aerosol Product Code 851F AD Superclear Lens Cleaning Fluid -Liquid American Optical Corporation American Optical Corporation Absolute Strip Maintenance Supply Company, Inc. Accudri SF6 Ingredients 2-Buto tyethanol * Ethyf'i`i' Ethylene Glycol Isopropyl Alcohol * Isobutane * Propane Isopropyl Alcohol * Glycerin Potassium Hydroxide * 2-Buto;y'ethanol * 2-Amino-Ethanol Allied Signal, Inc.- Sulfur Hexaflcuuride Engineered Materials Sector Acetic Acid, Glacial Fisher Scientific Acetone Ac etonitrile Acetylene Airco Marvel 162 Alkaline Cleaner 8755 Alkaline Iodide Sodium ALide Solution Alum (Dry) Aluminum. Liquid (F-2) - Resin Aluminum Putty (F) Resin Aluminum Putty Hardener (Putty Hardner 0200) L' f Fisher Scientific Fisher Scientific National Welders American Solder Flux Co., Inc. Acetic Acid Glacial Acetone Acetonitrile Acetylene Borax Intex Chemical , Inc. Sodium Hydroxide * Dipropylene Glycol Methylether * Isopropyl Alcohol Fisher Scientific General Chemical Corporation Devcon Corporation - Devcon Corporation Devcon Corporation Potassium Hydroxide * Potassium Iodide * Sodium Azide Aluminum Sulfate Bisphenol A Diglycidyl Ether Resin Bisphenol A Diglycidly Ether Resin Tri.ethylenetetranine (TETA) * F'olyamide of C18 Fatty Acid Dieters and TETA* Aimincethyl Fiperazine Adduct * Aminoethylpioera 1rn,e * Nonyi Phenol Page No. 5 -• 1?ji cc; 9l7 Product Aluver 3 A1LrminUa Reagent Ammonium Hydroxide Ammonium Phosphate Amoco TA-33 MP (Purified Terephthalic Acid) Anderol ** 500 OIL Antimony Potassium Tartrate Antimony Reference Standard Solution Antiseize Thread Compound Part No. W7 Apexior #1 Apexior No. 3 Argon Ascarite II Ascorbic Acid B Line Anti -Spat Bering B16200 BL-15 Cell Fluid BSTFA, 25t1L Ballotini Impact Beads Bar Belt Dressing #100731#10075 Company Hach Company Fisher Scientific Fisher Scientific Amoco Chemical Company Nuodex Inc. Fisher Scientific Fisher Scientific Ingredients Succinic Acid * Disodium Succ inate, Andhydrous * Aurintricarboxylic Acid, Calcium Sal Ammonium Hydroxide Ammonium Phosphate Purified Terepthalic Acid (PTA) None listed on MSDS Antimony Potassium Tartrate Hydrochloric Acid * Antimony Trichloride Lactite Corporation Mineral Oil * Capper * Graphite _ Aluminum * Silicon Dioxide * Lithium Soap Dampney Co., Inc. Dampney Co., Inc. National Welders Thomas Scientific Hach Company Bering Sales Inc. Emery, A. H., Company, , The Supelco Inc. Potters Industries Cling Surface Company: Mineral Spirits Mineral Spirits Argon Sodium Hydroxide Non -fibrous Silicate Ascorbic Acid MSDS missing Petroleum Hydrocarbon, .. Hindered Phenol Antioxidant * Aromatic Amine .. Succinic Acid Derivative * Sulfurized Fatty Acid Dimethyl Benzenes 2* ,ylene 2 N,O-Bis(Trimethylsilyl)trifluoroacetamide Glass Oxide Asphalt * Resin-paradine !lax-microcrystal 1 i ne Barium Chloride Fisher Scientific Barium Chloride Page No. 6 90 Product Company Bausch & Lomb Anti -Fog Liquid Catalog No' S 224, 25, 68, 69 Bausch Lomb Belt Dressing 00607 Sprayon Products Benzoic Acid Ingredients Isopropanol Odorless Min Spirits * Methyl Chloroform * A Isobutane * A Propane Fisher Scientific Benzoic Acid Bi,(2-(2-Methaxyetho Eastman Kodak sty) ethyl) Ether Company Black: F. Decker Band Tech -Lobe Sate Gear Box Corporation Lubricant Bleaching 3 Reagent Hach Company Baraxa Pondered Hand Dial Corporation, Soap The Bottom Layer Brazing Fluxes Stay Silv White, Stay Silv Black Bromocresol Green Bromocresol Purple, Sodium Salt Bramoth`mol Blue Bran:ochrom 10185 Bis(2-(2-methoxyetnoxy)ethyl) Ether Molybdenum Disulfide Potassium Pyr asulfate * Sodium Purophosphate, And' roes - Magnesium Sulfate Hept_.hydra e Sodium Tetrabarate Maintenance Supply Ammonia * 2-(2-Methaxyeth_,xy) Ethanol Company, Inc. Harris, J. W. , Co., Boric Acid * Borates * Fluorides, • Inc. Fluoborates as F Fisher Scientific Fisher Scientific Fisher Scientific Bromocresol Green Bromocresol Purple, Sodium Salt Bromothymol Blue Eutectic Ca'p_rat ial Nickel * Iron * Silicon Boron Brown Aluminum Oxide Washington Mills Electro Minerals Company Buffer Solutions Buffing Polish Fisher Scientific Maintenance Supply Company, Inc. Aluminum Oxide T itaniur Dioxide Sodium Phosphate Dibasic f Potassium Phosphate Monobasic * Potassium Phosphate Dibasic * Ammonium Chloride Formaldehyde Ammonia * Formaldehyde -- Dibutyl Phthalate * Dipropylene Glycol Monomethyl Ether } Caustic Potash Page No. 7 03/22/90 Product vduct Company Ingredients C-10 Calgon Corporation Zinc Chloride * Phosphoric Acid C. I. Mastic (Spray) Fuller, H. B., Petroleum Asphalt * Stoddard Solvent Company C. I. Mastic (Trowel) CGR #30 Packing CHICO A Sealing Compound CHICO X Fiber CO Contact Cleaner (Aerosol) #3015,#22016 Calcium Carbonate Calcium Chloride Carbon Black: Carbon Dioxide Fuller-, H. B., Petroleum Asphalt * Stoddard Solvent Company CGR Products, Inc PTFE Dispersion * Dupont T-130 Crouse -Hinds ECM Div. Cooper Industries Aluminum Oxide * Calcium Oxide * Ferric Oxide * Ferrous Oxide * Silicon Dioxide Titanium Dioxide Crouse -Hinds EMC Aluminosilicate (Vitreous) Div. Cooper Industries CRC Chemicals Trichlorotr-iflauroethane * Carbon Dioxide Fisher Scientific Calcium Carbonate Fisher Scientific Calcium Chloride Fisher Scientific Carbon Black Annul Fire Carbon Dioxide Protection Carbon Dioxide National Welders Carbon Dioxide Carbon Tetrachloride Fisher Scientific Carbon Tetrachloride Caustic Potash Alcad Inc. Potassium Hydroxide - 20% * Lithium Hydroxide - 0.9% i Caustic Soda Liquid Continental MSDS missing 50% Industries Caustic Soda Liquid Suffolk Chemical Sodium Hydroxide 30% Company Certanium 707-SP Certanium Allays Research Co. Titanium Dioxide * Calcium Carbonate Calcium Oxide * Calcium Fluoride * Manganese r Potassium Aluminum Silicate Sodium Potassium Oxide * Chromium Nickel * Carbon * Carbon Dioxide Silicon * Iran * Aluminum Oxide Molybdenum Page No. 8 F i3 /22 i9t Product Company Ingredients Certas gray 2040 Certanium Alloys & Silicon * Boron * iron * Chromium * Research Co. Carbon * Nickel Channel Master Contact Sheild ## 9100 / 9101 Channel Master, Division of Avnet, Inc. Dichlorodifluoromethane * Trichloromonofluoromethane Chisel(TM) Gasket Loctite Corporation Methylene Chloride * Propane * Isobutane Remover * Methanol Chlorine National Welders Chlorine Chlorine Liquified Van Waters & Rogers Chlorine uc Inc. Chloroform Fisher Scientific Chloroform Chloroform Technical Ashland Chemical Chloroform Company Citric Acid Mallinck:rodt 2-Hydroxy-1,2,3-propanetricarboxylic acid, monohvdrate Clean Up Solvent For Loctite Corporation N-Methyl Pyrrolidone Instant Adhesives Part No. 753-53 Cleaner Detergent, Sun Light Cleaner, Ajax Lever Brothers Missing MSDS Colgate-Palmolive MSDS Missing Clear Cement #999125 New Hermes, Inc. Cyclahexane * Acetone * Toluol Clover Lappint Compound Complete Compressed essed Air Contact Cleaner (Aerosol) #3070 Cool -Amp Copaltite Clover Manufacturing Silicon Carbide * Petroleum Grease Company Johnson, S. C. Wax Modified Acrylic Polymer * Diethylene Glycol Monoethyl Ether * Ethylene Glycol * Ammonium Hydroxide National Welders Compressed Air Supply Company, Inc. CRC Chemicals lt`ichlc' otrifluoi oethaiie * Carbon Dioxide Cool -Amp Sodium Chloride * Calcium Carbonate * Coducto-Lube Co. Silver Chloride National Engineering Phenolic Resin * Mixed Cresol * Ethanol * Products, Inc. Formaldehyde * Methanol * Toluene * Page No. 03i22 ,9 Product Company Ingredient Corona Dope GC Electronics Toluene * Methyl Isobutyl Keytone * Ethanol * Methanol * Acetone * Corona Dope GC Electronics Acetone * Butyl Acetate * Ethyl Acetate * (Aerosol) Toluene * Isabutane * Propane Cresol Red, Aldrich Chemical Cresol Red Indicator Grade Company Cronabraze 21 - Cronatron Welding Zinc * Tin * Iron * Silicon * Copper $r aziiig Wire Systems, Inc. Cronabraze 3iiF - Cronatron Welding Nickel * Silicon * Zinc * Copper :alloy Wire Systems, Inc. Cronabraze 55 - Cronatron Welding Silicon * Iron * Copper * Aluminum Alloy Wire Systems, Inc. Cronabraze 99 (CW Cronatron Welding Carbon * Chromium * Iran * Silicon * 1026) Systems, Inc. Boron * Nickel Cronacast- 211 - Cronatron Welding Strontium Carbonate * Calcium Fluoride * Welding Electrode Systems, Inc. Aluminum * Iron * Sodium Silicate * Nickel * Carbon Cronacast 222 - Weldiilg Electrode Cronamig 321M - Cronatron Welding Strontium Carbonate * Calsium Fluoride * Systems, Inc. Aluminum * Sodium Silicate * Nickel Cronatron Welding Manganese * Carbon * Iron * Silicon Allay Wire for Iiig Systems, Inc. Cronamig 3880M (CW Cronation Welding Chromium * Nickel * Molybdenum * 1938) Systems, Inc. Manganese * Silicon * Cooper * Iron Cronasil 43F (CW Cronatron Welding Zinc Cadmium * Copper * Silver 1024) Systems, Inc. Cronatig 333T - Iron Cronatron Welding Carbon Silicon * Manganese * Chromium * Base Al loy Wire Systems, Inc. Nickel * Iron Cronatig Earle 665T Cronatron Welding Mangenese * Silicon Cooper- (CW 1840) Systems, Inc. Cronatig Eagle 665T Cronatron Welding Mangenses * Silicon * Capper (CW 1841) Systems, Inc. Cronaweld 311 (CW Cronatian Welding Sodium Carbonate * Titanium Dioxide * 1852) Systems, Inc. Calcium Fluoride * Sodium Silicute Manganese * Iron Cronaweld 321 - Weldirg Electrode Cronatron Welding Titanium Dioxide * Sodium Silicate * Systems, Inc. Sodium Carbonate * Manganese * Iran Page Ni Icy 0r3/22: 90 Product Company Cronaweld 344 (CW Cronati can Welding 1068) Systems, Inc. Cronaweld 344 T (CW Cr-onation Welding 1886) Systems, Inc. Cronaweld 344T (CW Crc'natron Welding 1887) Systems, Inc. Cronaweld 510 (CW Crcinatron Welding 1039) Systems, Inc. Cronaweld 510 (CW Cranatron Welding 1826) Systems, Inc. Cronaweld Eagle 3880 Cronatron Welding Systems, Inc. Cupric Sulfate-Sulfamic Acid Solution Fisher- Scientific Cyclohexane Fisher Scientific DPD Total Chlorine Hach Company Reagent Datakoat Protective Datak. Corporation Coating Kit Cat. 1# 04176 Deco -Rex Epoxy Resin General Polymers Glaze 3561 Part A Corporation Deco-Rez Epoxy Resin General Polymers Glaze 3561 Part B Corporation Deco-Rez Epoxy: -Cote General Polymers 3544 Part A Corporation Deco-Rez Epoxy -Cate General Polymers Hardener 3544 Part B Corporation Deco-Rez High General Polymers Performance Epoxy Corporation Coating 3548E Part A Incgredients Carbon * Tungsten * Vanadium * Molybdenum • Chromium * Silicate * Iron Carbon * Tungsten * Vanadium * Molybdenum * Chromium * Silicon * Manganese * Iron Carbon * Tungsten * Vanadium * Molybdenum • Chromium * Silicon * Manganese * Iron Silicon * Aluminum Fluoride * Aluminum Chlorate * Aluminum Silicon * Aluminum Fluoride - Aluminum Chlorate * Aluminum Titanium Dioxide •• Potassium Silicate Calcium Fluoride * Manganese } Chromium * Iron * Silicon * Nickel Cupric Sulfate Peritahydrate * Sulfalnic Acid * Glacial Acetic Acid Cyclohexane Organic Salt Sodium Phosphate, Dibasic, Anhydrous . F'tassiue Iodide * DF'D Salt Toluene * Xylene 4,4'-Isopropul idenediphenol Epichlorohydrin Resin * Alkyl Glycidal Ether * Hexylene Glycol * Xylene (Aromatic Hydrocarbon) Aliphatic Ether Amine * Diethylene Triamine * Modified Aliphatic Amine * Tris-2,46-Dimethylaminomethyi Phenol 4,4'Isopropylenediphenol Epichlorohydrin Resin * Hexylene Glycol f Alkyl Glycidal Ether * Urea Formaldehyde Solution Benzyl Alcohol. Aliphatic Ether Amine * Hexylene Glycol Activated Heterocyclic Amine 4,4' Isopropylidenediphenol Epichlorohydrin Resin * Alkyl Glycidal Ether * Hexylene. Glycol Page No. 3'22/ t_• i LL. _ Product 11 Company Deco-Rez High General Polymers Performance Epoxy Corporation Coating 3548P Part 8 Devcon Flexane 80 Putty Curing Agent Devcon Flexane 80 Putty Resin Dichloromethane Diethylene Glycol Diethylene Glycol Monornethyl Ether Dow Corning 111 Valve Lub and Sealant (Pails) Dow Corning 111 Valve Lub. and Sealant (Tubes) Dow Corning 200 Fluid 50 CS Dow Corning 41 EXT High Temp. Bearing Grease Ingredients Aliphatic Ether Amine * Modified Amine Alkyl Phenol Devcon Corporation Polyamine Solution Devcon Corporation Fisher Scientific Fisher Scientific Eastman Kodak Company Dow Corning Corporation Doi: Corning Corporat ion Dow Corning Corporat ion Dow Corning Corporation Dow Corning 44 High Dow Corning Temp Bearing Corporation Grease -Light Dow Corning 732 Multi -Purpose Sealant Clear Dow Corning Corporation Dow Corning 736 Heat Dow Corning Resistant Sealant Corporation Dort Corning G-N Doti Corning Metal Assembly Paste Corporation s Methylene bis(cyclohexyli_ocyanate) Polyether prepolymers of PICM * biphenyl methane diisacyanate * Oiigo:mers of MDI Dichloromethane Diethylene Glycol Diethylene Glycol M onomet;:yl Ether None listed an MSDS None listed on MSDS None listed Carbon Black * Properietary Ingredient 2,6-Cis • Diphenylhexamethylc-clotetrasiloxane* Heptamethylmonophenylcyclotetrasiloxane None listed on MSDS Methyltria_etoxysilane Ethyltriacetoxsiiane * silica Methyltriacetoxysilane f Ethyl tr iacetoxysi lane * Amorphous Silica Iron Oxide Mineral Oil * Molybdenmu,m Disulfide * Silica, Amorphous * Proprietary Aluminum, Calcium, and Zinc Compounds and organic lubricants Page No. 12 _:.�. ma 03 2c:9C Product Company Dow Corning Medical Dow Corning r,r. _ i:tifoam AF Emulsion Corporation Dow Corning 60 0 Dow Corning Si lane Corporation Ingredients None listed on MSDS Glycidoxypropyltrimethaxysilane Dos therm (R-)—A Heat Dow Ch-emi-c l_'.GEripany Diphr=ny?Gxidi= * DipJm ny1 Transfer Fluid Drierite Hammond, W. A., Company Dry-Kleen Missing MSDS GC Electronics 1,1,1 Trichlorethane } Carbon Dioxide Propellant Dural 337, 200% Fast Dural Internation & Slow Set Corporation Epoxy Resin (Bisphenol A and Epichlorohydrin) * Aliphatic Monaepoxide * TIOP Dyke:.: Hi -Spot Blue Dykem Corporation Dye: Victoria Pure Blue Bo Base No. 107 EPDXO 1000B Non -Skid American Abrasive Floor & Deck Coating Metals Company FART A EPY 500 (Part B) Petrolatum * Wax Mineral Oil Epoxy Resins * Xylene * Propylene Glycol Manornethyl Ether * Silicon Dioxide, Crystalline (Part A) and BLH Electronics Inc. Polyglycidyl Ether Phenolformaldehyde Novalac-Epoxy * Silicon Dioxide, Magnesiumoxide * Aromatic Dianhydride Mixture EZ Weld Clear PVC P. C. I. Industries Tetrahydrofuran * 2-Dutanone Solvent Cement Inc. Cyclohexanane E? Weld Gray PVC P. C. I. Industries, Tetrahydrafuran :- Methyl Ethyl Ketone Solvent Cement Eclipse Neutral Cleaner/Very N. Cleaner Elastomeric 10 - Fine Electro-Sole Endusst Dusting and Cleaning Spray - Retail Inc. Cyclohexancne Pioneer/Eclipse Corp. F'rok:o Industries, Inc. Marchem Company Drackett Products Company Potassium Pyrophosphate * Sodium Phosphate, Tribasic Ethylene Glycol .. Titanium Dioxide .- Attapulgite Clay * Acrylic Latexes Hydrous Aluminum Silicate - Calcium Carbonate * Mica * Clay, Aluminum Silicate * Plasticizer * Pumice 390# 1,1,1-Trichloroethane Isobutane * Hydrocarbon Solvent Page No. 13 0 3/ 22 /90 Product Company Epoxy Kit # 1 (EK-1) Devcon Corporation - Hardener Epoxy Kit #i (EK-1) Devcon Corporation - Resin Ethyl Alcohol, Denatured Ethylene Glycol -Polyester Grade :5019 Eutecto-Mask Compound Eutector 190 Flux Fastbond Errand 900 Duct Sealer/New Formula Fe1-Pro C-30t) (Aerosol) Fel-Pro C-300 (Lead Free) F F'r _ C-670 Fel-Pro C5-A High Temperature Antiseize Compound Fel-Pro C5-A High Temperature Antiseize Compound Aerosol Ferric Chloride Solution - tiastewater Treatment Grade Fisher Scientific Texaco Chemical Company Ingredients Diethylene Trialnine (DETA) * Mixed Composition Curativex• 2,4,6-- i (Dimethylaminomethyl) Phenol None listed on MSDS Ethyl Alcohol * Methyl Alcohol * Ethyl Acetate * Methyl Isobutyl Ke tone Aviation Gas 1,2-Ethanediol Eutectic Corporation Zircon * Silicon Dioxide * Glycerine Eutectic Corporation Zinc Chloride Lithium Chloride * Sodium fluoride. ide. * Potassium Fluoride * Lithium Fluoride 3M Center synthetic rubber and resins * calcium carbonate * aluminum silicate (clay) * hexane * n-hexane Fel-Pro Incorporated 1,1,1 Trichloroethane * Iscprc-panol * Dipropylene Glycol Mcrnomethyl Ether Molybdenum Disulfide * Isobutane Propane Fel-Pro Incorporated Aromatic Petroleum Distillate * Toluene Molybdenum Disulfide Fel-Pro Incorporated Molybdenum Disulfide Fel--Prcr Incorporated Copper * Graphite flakes * Petroleum Fel-Pro Incorporated 1 , 1 , 1-Trichloroethane * Propane Isobutane ie K. A. Steel Chemicals Ferric Chloride * Hydrochloric Acid Fiberglass Insulation Owens/Corning_ Fiberglas Corporation Fibrous Glass • Page No. 14 tio; 3 :cc-;/9( ) _ Product First Step Sealer IT/W Bottom Layer Flexane 94 Liquid - Hardner Flexane 94 Liquid - Resin Flexane Putty Hardener Flexboard II - Autoclaved Company Pioneer/Eclipse Corp. Devcon Corporation Devcon Corporation Devcon Corporation Manville Building Materials Corp. FoamGlas Insulation Pittsburgh Corning Foray Dry Chemical Ansul Fire Extinguishing Agent Protection Form -a -Thread Strip Thread Repair Activator Part No. 81668 Forward DC Foxboro 1500 Ink Foxboro 1600 Ink: Foxboro 1800 Ink Garlock: 101-S Soft Set Gasketing Compound Genescly D Solvent Loctite Corporation Johnson, S. C. u: Son, Inc. Graphic Controls Graphic Controls_. Graphic Controls Garlock, Inc. Ingredients Ammonia * E-(2-Methr>.yethox ) Ethanol 4,4'-Diaminodiphenylniethane (MDA) Methylene Bis (4-Cyclohexylisocyanate) Related Polymers None listed on MODS Calcium Silicate * Calcium Silicate Reinforcing Filler * Manmade Organic Fiber * Natural Organic Fiber * Quartz as Unreacted By-product Hydrogen Sulfide * Carbon Monoxide Glass Dust Muscovite Talc * Magnesium Aluminum Silicate * Monoammoniurn F'hsophate Ammonium Sulfate ate * Methyl Hydrogen F'olysi loxane * Yellow Pigment Dimethacrylate Esters * Aluminum Silicon Dioxide - Heterocyclic Methacrylate * Oxide Fillers N-Alkyl Dirnethyl Benzyl Ammonium Chloride Sodium Metasilicate * Sodium Tripolyphosphate Nonylphenol Polyethylene Glycol Ether Formaldehyde * Ethylene Glycol .. Acid Dyes h-, glycol * Acid FFormaldehydeEt�;��ler';e C Dyes Formaldehyde * Ethylene Glycol * Acid Dyes 1,1,1 ti ichloroethane * Red Iron Oxide Allied-Signal Inc. - Trichlorotrifluor_thanle Engineered Materials Sector Gulf Iransgear Lubricant E.F. 220 Page No. 15 03/22/90 Product Compan;, Ingredients Genetron 12 Allied Corporation - Dichlorcdiflucroethane dichlarodif lourc:ineth Chemical Sector arse Genetron 22 Allied-Signal Inc. - Clorodifluorcethasie chlorodiflucromethan Engineered Materials • e Sector Glycerin Glyptal Fisher Scientific Glycerin Clyptal, Inc. Go -Jo Original Hand Go -Jo Industries Cleaner Graphite Rust Preventative C-732 Great Grape Concentrate Grinding Compound, Clover Grade A Methyl Ethyl Ketone * Acetone * Xylene Toluene * V M & P Naphtha * Butyl Alcohol Propellant Nonolyriol-10 * Petroleum Distillates Stoner Incorporated Methylene Chloride Maintenance Supply Guarternary Ammonium Halides * Sodium Service Corporation Metasilirate Pentahydrate * Tetr-asodiuf;i Pyrophosphate Clover Manufacturing MSDS missing Company. Gulf E. P. Lubricant Chevron HDi50 Gulf E. P. Lubricant Chevron HD460 Gulf Harmony 115 Chevron Gulf Harmony 46 AW Chevron Gulf Harmony 68 \W Chevron Chevron Gulfcrcwn Grease E. Chevron P. No. 2 Gulflube Single 20W/220 Chevron Highly refined base ails Highly refined base oils HIghly refined base ails calcium phenate * zinc dialk:yldithiophosphate calcium phenate * zinc dialkyldithiophosphate Highlt refined base oils Chlorinated Paraffin * Zinc Dialk:yldithiophosphate magnesium lcngchain alk:aryl _ulfonate * zinc alkyl dithiophosphate Gulfway 68 Chevron Highly refined base oils • Page No. 03 /22 -. 0 16 Product Company H-300 Microbiocide Calgon Corporation H-510 Micrcbiccide Calgon Corporation H.I. Mastic, Trowel Fuller, H. B., Co. HMDS,100ML Supelco Inc. NTH Dry Chlorinator Olin Corporation Tablets H3lon 1211, BCF Ansul Fire Protection Halon 1301, Freon FE Ansul Fire 1 301 Protection Heat TSr a.n , er Cement Grade E-1 Thermon Manufacturing_ Company Heat Transfer Cement Thermon Grade T-3 Manufacturing Company Heat Transfer Thermon Cement, Grade T-63 Manufacturing Company Heat Transfer Thermon Cement, Grade T-80 Manufacturing Company. Heat Transfer Cement, Grade T-85 Thermos Manufacturing Company Heavy Duty Degreaser CRC Chemicals (Aerosol) #3095, ,,QeT Heavy Duty Silicone Helium Heptane Heresite VR-502 Finish Ingredients 1,5-Pentanedial * Glutaraldehyde S-Ch for ci-2-methyl.-4-i sc'thiazol isle-3-one * E-Meth°y1-4-isothia2oline-3-one solution Petroleum Asphalt Hexamethyldisilarane Calcium Hypochlcrite * Sodium Chloride Calcium Chlorate * Calcium Chlorate Calcium Hydroxide * Calcium Carbonate Bromochlorodifluoromethane Monobromotriflt_toromethane Natural Graphite * Granular Petroleum Coke, Desulphirired Natural Graphite * Sodium Silicate, liquid Natural Graphite * Sodium Silicate, liquid Natural Graphite = Boron Trifluciride Epichlorohydrin•Resin * Butyl glycidyl ether .- Natural Graphite * Boron Triflucride * Epichlorohydrin Resin 1 . 1 , 1 Trichloroet have * Tert Butyl Alcohol * 1,2 butyloxide cide * Dimethoxyrethane * Carbon Dioxide Bowman Distribution Silicone * Mineral Spirits * Hexane * Propane! I sobu tine National Welders Helium Fisher Scientific Heptane Heresite Protective Mineral Spirits * Aromatics 100 Coatings, Inc. Page No. 17 03/22 /90 Product Company Ingredients Heresite VR-502 Heresite Protective Mineral Spirits * Solvent naphtha Primer Coatings, Inc. (petroleum)i7tedl!i:i aliph Hg Absorb Hi -Speed Coating High Heat Coating • Horizon General Purpose Cleaner Hydraulic Handgun Fluid Hydraulic Sealant Part 69 Hydraulic Sealant, 250 ML Bottle Science Related Materials Maintenance Supply Company, Inc. Porter Paint Co. Johnson, S. C. Son, Inc. Lead * Proprietary Organic Acid Ammonia * Formaldehyde * Dibutyl Phthalate * Dipropylet e Glycol M onomethyl Ether Mineral Spirits * Hi Flash VM&F' NapthaA * Aluminum Powder Sodium Hydroxide * Nonylphenol Polyethylene Glycol Ether BTR Valve Sealants, Polyalkylene Glycol Inc. Loctite Corporation Dimethacrylate Esters * Klkyl Aryl Amine * Methanol * Catalyst * Aliphatic Esdter Placticier * Sulfimide * Resin Loctitie Corporation MSDS missing Hydrobromic Acid 48% Fisher Scientific Hydrobromic Acid In Acetic Acid Hydrochloric Acid 36-37% Hydrogen Hydrogen Peroxide Hysol-l-C Epoxy Patch Kit Ice -Foe In Focus Hydrobromic Acid 48% Fisher Scientific Glacial Acetic Acid * Hydrobromic Acid Fisher Scientific Hydrochloric Acid 36-37% National Welders Hydrogen Fisher Scientific Hydrogen Peroxide 304 Hysol Missing MSDS Walton -March, Inc. Calcium Chloride Maintenance Supply Company, Inc. Industrial Enamel Sherwin-Williams B54 T 104 Ultradeep Company Base (OSHA Green) Isopropyl Alcohol * F'olydimethylsilo:,ane * Propellant: Propane/Butane Mineral Spirits * Titanium Dioxide * Chromium Oxide * Chromium III Paae No. 18 03 / 22 / 90 Product Company Ingredients Industrial Enamel Sherwin-Williams Mineral Spirits * Titanium Dioxide * B54 t4 101 Pure White Company Chromium Oxide * Chromium III Industrial Enamel Sherwin-Williams Mineral Spirits * Titanium Dioxide B54 W 103 Deeptone Company Chromium Oxide * Chromium III Base .(McCoy Ellison Green) Industrial Enamel Sherwin-Williams Mineral Spirits * Titanium Dioxide B54 Y 27 Safety Company Chromium Oxide * Chromium III Yellow Industrial Enamel Sherwin-Williams Non -Lead Colors B54 Company T 104 (OSHA Green) Industrial Enamel Sherwin-Williams Non -Lead Colors B54 Company. W 101 (Gulf Blue) Industrial Enamel Sherwin-Williams Non_lead Colors E54 Company W 103 (McCoy -Ellison Green) Inland-19 Mineral Spirits * Titanium Dioxide Chromium Oxide Mineral Cpirits * Titanium Dioxide Chromium Oxide Mineral Spirits * Titanium Dioxide * Chromium Oxide Inland Vacuum Neutral Paraffinic Oil (100%) Industries Iodine Solutions 1N Fisher Scientific Iodine 12 : Potassium Iodide K-I and Concentrate Nf100 Iron Reference Fisher Scientific Ferric Nitrate, Nonahydrate * Nitric Acid Standard Solution * Water Isoflex NBU 15 Klueber Lubrication ester/Ba soap Corporation Isof lex Tel 3000 Kluber Lubrication Ester Oil f Lithium Soap Altemp r-iemp Corporation Issoflex Topa= L Jt_ 32 K.luber- Lubrication Lithium Soap * Hydrocarbons Corporation K-156 Nonfluid Oil Corp. None listed on MSDS k :EM A&A Epoxy Enamel Sherwin-Williams B61 E 19 OSHA Yellow Company VM&:F' Naptha * Mineral Spirit_ * Mineral Spirits 140-Flash * Xylene * Titanium Dioxide * Lead Chromate * Nolybdate !Orange* Lead * Chromium VI Page No. 19 03 2.2; 90 Product Company KEM ALA Epoxy Enamel Sherwin-Williams B61 R 18 OSHA Red Company KEM ALA Epoxy Enamel Sherwin-Williams B61 T 104 Ultradeep Company Base F:::EM AB:A Epoxy Enamel Sherwin-Williams B61 W 101 (Flint Company Gray) KEN A&A Epoxy Enamel Sherwin-Williams B6I W 102 Midtone Company Base (English Gray) KEM ALA Epoxy Enamel Sherwin-Williams B61 L4 104 Company KEM ALA Epoxy Primer Sherwin-Williams B61 N 1 Company KEM Lustral Enamel F65 B 50 Wrought Company Iran Flat Black Sherwin-Williams KEM Lustral Enamel Sherwin-Williams F65 6 16 S-G Company Machinery Green Karl Fisher Reagent Fisher Scientific K::aylc 10 AF Insulation Owens/Corning Fiberglas Corporation Kem ALA Epoxy Enamel Sherwin-Williams Non -Lead Colors B61 Company T 104 (OSHA Blue) Kem ALA Epoxy Enamel Sherwin-Williams Non -Lead Colors B61 Company: T 104 (OSHA Green) Kem Lustral Enamel Non -Lead Colors F65 Company G 16 S-G Machinery Greer Sherwin-Williams Ingredients VM&P Naphtha * Mineral Spirits * Mineral Spirits 140-Flash * Xylene * Titanium Dioxide * Lead Chromate * Lead Chromate * Molybdate Orange VM&P Naphtha * Minera.l Spirits * Mineral Spirits 140-Flash * Xylene * 2-B!ttoxyethainol Titaniun Dioxide VM&P Naphtha * Mineral Spirits * Mineral Spirits 140-Flash * Xylene * 2-Butoxyethanol * Titanium Dioxide VM&P Naphtha * Mineral Spirits * Mineral Spirits 140-Flash * Xylene * 2-Butoxyethanol * Titanium Dioxide VM&P Naphtha * Mineral Spirits * Mineral Spirits 140-Flash * Xylene * 2-Butoxyethanol * Titanium Dioxide Mineral Spirits * Potassium Zinc Chromate * Barium * Chromium VI VM&P Naphtha * Mineral Spirits * Mineral Spirits 140-Flash * 2-Methoxymethylethoxypropanol * 2-Butoxyethanol * Titanium Dioxide VM&P Naphtha * Mineral Spirits * Mineral Spirits 140-Flash * 2-Methoxyrnethylethaxypropanol * 2-Butoxyethanol * Titanium Dioxide Ethylene Glycol Moriornethyl Ether * Pyridine * Iodine * Sulfur Dioxide Calcium Silicate V.M.B:P. Naphtha * Mineral 'Spirits * Mineral Spirits 140-Flash * Xylene * 2-Butoxyethanol * Titanium Dioxide V.M.B:F'. Naphtha * Mineral Spirits * Mineral Spirits 140-Flash * Xylene * 2-Butoxyethanol * Titanium Dioxide V. M. B: P. Naphtha * Mineral Spirits * Mineral Spirits 140-Flash * 2-Methoxymethyiethoxypropanol * 2-8utoxyethanol * Titanium Dioxide Page No. 20 03I22/90 Product Kilz r•.�: 1 ee't t-Ko 0 K:lingerit (Red) Company Ingredients Caldwell Paint Mfg. VM & Naptha (Aliphatic Hydrocarbon) * Co., Spirits �_ Inc. Mineral ,Nil i DcAll Company Tviethanolamine Richard Klinger Inc. Chrysotile Asbestos * Styrene Butadiene Polymer * Iron (III) Oxide Kiingerit Universal Richard Klinger Inc. Phthalocyanine Blue * Chrysotile Asbestos Blue * Nitrile Butadiene Polymer Kolene KGC Kolene No. 6 Kolene Corporation Kolene Corporation Kromik Metal Primer Sherwin-Williams E41 N 1 Company Krytox 240 Series & Du Pont GPL Fluorinated Creases L-Ascorbic Acid LPS 3 Heavy Duty Rust Inhibitor Lagfas Adhesive Leak Tracy LS-77 Leak-Tec 415 Lectra Cleant (Aerosol)#f2018, 2018T Fisher Scientific Halt Loyd Corporation Fuller, H. B., Company Citric Acid Sodium Gluconate * Tartaric Acid * Sodium Benzoate Trade Secret Mineral Spirits * Potassium Zinc Chromate < I :> Fluorine * Tetraf luoroethlene L-Ascorbic Acid Aliphatic. Hydrocarbon * Carbon Dioxide Propellant Chlorinated Paraffin * Ethyl Alcohol Residual •vinayl acetate monomer * Calcium Carbonate * Titanium dioxide Leak Chemicals None listed on MSDS (HeITlan & Associates) American Gas and Chemical Company, Ltd. CRC Chemicals Lectra Clean (Bulk) CRC Chemicals 1*02020 , 02021 , 02023 Liquid Fire Quick Radiator Specialty Starting Fluid Company Diethylene Glycol 1,1,1 Trichloroethane * Tert Butyl tt• Alcohol * 1,2 Butylene Oxide * Dimethox:'methane * Carbon Dioxide 1 , 1 , 1 Trichloroethane .. Tert-Butyl Alcohol * 1,2, Butylene Oxide Dimethoxymethane Diethyl Ether * Aliphatic Petroleum Distillate * petroleum-Dexaxed Heavy Paraffinic Solvent * Carbon Dioxide Page Nc'. 21 03/22/90 Product Company Liquid Hardener 0202 Devr_on Corporation Liquid Hardener 0203 Devcon Corporation Liquid Nitrogen Liquid Wrench Super Lubricant (Aerosol) National Welders Radiator Specialty Company Liquid Wrench Super Radiator Specialty Lubricant Company (Non-Aerosol)L2-04,- 34 Lithium Chloride Locquic Primer N (Aerosol) Part 764-56 Locquic Primer T (Aerosol) Part 747-47, 747-56 Lubriclens Fisher Scientific Loctite Corporation Loctite Corporation Ingredients Triethylenetetramine (TETA) * Polyamide of C1E fatty -acid dieters and TETA * Nonyl phenol/amineoethylpiperazine adduct Nonyl phenol * Aminoethyl piperazi.ne Diethylene (DETA) TetraethyleneperntaiTiine (TEPA) * Tall Oil fatty -acid adduct of TEPA Liquid Nitrogen Aliphatic Petroleum Distillate * Naphthenic Petroleum Oil * 2-Bute' y Ethanol * Alkyl Amine Derivative * Carbon Dioxide Propellant Aliphatic Petroleum Distillate Naphthenic Petroleum Oil * 2-Butoxy Ethanol f Alkyl Amine Derivative Lithium Chloride 1,1,1-Trichloroethane * organc'-Copper Salt * Trialkylamine Carboxylate Aliphatic Carboxylic Acid 1,1,1-Trichlorethane * N,N-Dialk::yltoiuidine ercap thiazole �'iCi l.d� Lc'b$�G Isopropyl Alcohol Carter, A. B., Inc. 1,1,2 Trichloro-1,2,2 Trifluoroetharne Freon 11-Trichloromonof luoromethane Freon 12-DichlorodiflLtoromethane LLlbriplate "130" Fiske Brothers Series Refining Co. MOL-SIEVE (Act) Supelcc' Inc. 8/12 Mesh 1/2 lb MR-778 Modern Research Corporation Maintenance No -Scrub Maintenance Supply Emulsifier Company, Inc. Manganese Sulfate Fisher Scientific Solution Calcium Soap * Mineral Oil Silicic Acid, Aluminum Calcium Sodium Salt Trichlorotrifluoroethane Ehtylene Glycol N-Butyl Ether * Isopropyl Acloh of * Monoethanolamine * Organic and Inorganic Detergents Manganese Sulfate 4�� • Page No. 03/.22!90 Product Marinite 1 Company Manville Building Materials Corp. Mar lotherm S Huls America Inc. Master Gasket Sealant Part 00203, 00204 Loctite Corporation Mercuric Oxide Solid Fisher Scientific Mercury Fisher Scientific Mercury Mer iam Instrument Metalastic II Enamel Sher: -.in -Williams 853 W 101 Pure White Company Metalatex Semi -Gloss Sherwin-Williams Enamel 842 B 3 Black Company Metalatex Semi -Gloss Sherwin-Williams Enamel B42 R o Company Safety Red Metalatex Semi -Gloss Sherwin-Williams Enamel B42 T 104 Company Ultradeep Base Metalatex Semi -Gloss Sherwin-Williams Enamel B42 W 101 Company Pure White Metalatex Semi -Glass Sherwin-Williams 2 Enamel B42 W 104 Company Metalatex Semi -Gloss Sherwin-Williams Enamel Non -Lead Company Colors B42 T 104 (OSHA Blue) Metalatex Semi -Gloss Sherwin-Williams Enamel Non -Lead Company Colors B42 T 104 (OSHA Green) Metalatex Semi -Gloss Sherwin-Williams Enamel Non -Lead Colors 1842 W 101 (i1ai!dbi 1I t ) Company Ingredients Calcium Silicate * Calcium Silicate Reinforcing Filler * Natural Organic Fiber * Pigments Dibenzyl to luene Polyurethane Methacrylate Resin * Polyglycol Dimethacrylates * Silicon Dioxide * Acrylic Acid •• Cumene Hydroperoxide * Ethylene Glycol Saccharin 8 1-Acety1-2Phenylhydrazine Mercuric Oxide Soild Mercury Mercury Mineral Spirits * Titanium Dioxide * Chromium Ox ide * Chromium III 2-(2-Butoxyethoxy)-Ethanol * Ethylene Glycol * Titanium Dioxide 2-(2-Butoxyethoxy)-Ethanol * Ethylene Glycol * Titanium Dioxide 2-(2-Butoxyethoxy)-Ethanol * Ethylene Glycol * Titanium Dioxide 2-(2-Butoxyethoxy)-Ethanol* Ethylene Glycol * Titanium Dioxide 2-(2-Butoxyethoxy)-ethanol * Ethylene Glycol Tit.anium Dioxide 2-(2-Butoxyethoxy)-ethanol * Ethylene Glycol * Titanium Dioxide 2-(2-Butoxyethoxy)-ethanol * Ethylene Glycol * Titanium Dioxide Page No • • 03/22/ 90 Product Company Ingredients Metalatex Semi -Glass Sherwin-Williams Enamel ton -Lead Company Colors B42 W 102 (Blue -Gray) 2-(2-Butc>y%ethci ;y')-ethainol Ethylene Glycol * Titanium Dioxide Metco 102 Metco Titanium Dioxide Metco 130,130SF Metco Titanium Dioxide * Silicon Dioxide * Aluminum Oxide * Organic Binder Metco 14E, 15E Metco Carbon * Silicon * Boron * Iron * Cobalt • Chromium * Nickel Metco 185 Metco Petroleum Hydrocarbon Microcryrstalline Wax Metro 442 Metco Nickel * Chromium * Silicon = Boron Titanium Bioxide Aluminum * Molybdenum * Organic Binder Metco 444 Metco Nickel * Chromium * Iron * Organic Binder * Molybdenum * Aluminum Metco 447, 447NS Metco Nickel * Aluminum * Molybdenum * Organic Binder Metco 448 Metco Iron * Carbon * Organic Binder * Aluminum • Molybdenum Metco 449, 449P Metco Iron * Carbon * Aluminum * Molybdenum Boron; * Organic Binder Metco 450, 45ONS Metco Nickel * Aluminum * Organic Binder Metco 451 Metco Carbon * Silicon * Manganese * Chromiumm Nickel * Iron * Aluminum * Boron * Cobalt • Organic Binder Metco 505, 501 Metco Molybdenums * Carbon * Silicon * Boron * Iron * Cobalt * Chromium * Nickel Metco 51, 51NS, Metco Copper * Aluminum Iron 51F-NS Metco 52C Metco Aluminum * Silicon Metco Anti -Bond Metco Dextrins * Carbon * Glycerine Metco Cleaning Metro 1,1,1-Trichloroethane (Stabilized) Solvent Page No. 24 03/22/90 Product Methyl Alcohol Methyl Isobutyl Ketone Methyl Orange Methyl Red Methylene Blue Methylparabin ABA + Misty Glycol Air Sanitizers Mobil Velocite Oil No. 10 Molykote C-40 Hi Temp Chain Lub Company Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific FendAll Company Amrep, Inc. Mobile Oil Corp. Dow Corning Corporation N,N-Dimethylformamid Fisher Scientific Nalclean 8900 Alkaline Cleaner Nalclean 8910 Alkaline Cleaner Nalclean 8940 Acid Cleaner Nalco 1720 Oxygen Scavenger Nalco 2593 Microbiocide Nalco 2807 Cooling_ Treatment Nalco Chemical Company Nalco Chemical Company Nalco Chemical Company Nalco Chemical company Nalco Chemical Company Nalco Chemical Company Nalco 356 Corrosion Nalco Chemical Inhibitor- Company Nalco 39M Corrosion Nalco Chemical Inhibitor Company Ingredients Methyl Alcohol Methyl Isobutyl Keytone Methyl Orange Methyl Red Methylene Blue p-hydroxybenzaic acid, methyl ester Methylene Chloride * Ethanol * Methyl Alcohol Isabutane/Propane Blend Triethylene Glycol * Propylene Glycol. Refined Mineral Oils None listed on MSDS N,N-Dimethylformamide Sodium Hydroxide Sodium Metalilicate * 2-Butoxyethanal Hydrochloric Acid Sodium Bisulfate * Potassium Bisulfite 5-chloro-2-methy1-4 i.sothiazolin-3-one * 2-methy1-4-isothiazolin--3-0 ne Sodium tetraborate Cyclohexylamine * Morphaline Sodium Nitrate * Sodium Mercaptobenzothiazole * Sodium Tetraborate Page No. 03: 28 40 25 CJ Product Company Ingredients Nalco 7310 Nalco Chemical Ethoxylated Octylphenol Dispersant Company Nalco 7320 Nalco Chemical 2,2-Dibromo-3-Nitrilopropionamide Microbiocide Company Nalco 7330 Microbiocide Nalco 7348 Nalco Chemical 5-Chloro-2-Methyl-4 Isothiazolin-3-one Company 2-Methyl-4-Isothiazolin-3-one Nalco Chemical Acqueous polyglycol Company Nalco 7460 Antifoam Nalco Chemical Hydrotreated Heavy Naphthenic Distillate Company Nalco 750 Boiler 4n`ifc n. Nalco 780 Oxygen Nalco Chemical Aqueous solution of monbutyl ethers of Company glycols Nalco Chemical Sodium Bisulfite Scavenger Company Nalco 8258 Fuel Oil Nalco Chemical Paraffinic/Naphthenic Solvent Treatment Company Nalco 8361 Nalco Chemical Sodium Hydroxide * Sodium tetraborate Company Nalco Resin Rinse Nalco Chemical 7290 Company Nalco Solution 8745A Nalco Chemical Company None listed on MSDS Acetic Acid Nalco Solution S0295 Nalco Chemical 0.4 sulfuric acid solution Company Nalco Solution S03221 Nalco Chemical Silver Nitrate * Nitric Acid Company Nalco Solution S0322 Nalco Chemical Ammonium F'erssulfate Company Nalco Solution S03223 Nalco Chemical solution of sodium chloride Company Nalco Solution S0746 Nalco Chemical Xylenol orange indicator in sodium Company chloride carrier Nalco Sur -Gard Nalco Chemical Ammonia Company Page No. t'3 /22/90 co Product Company N.alcolyte 7107 Coagulant Nalco Chemical Company Nalcool 7397 Scale Nalco Chemical Inhibitor Neutra Rust 661 Neutral Red Nitec 10224 'Nitric Acid Nitrogen Nitrous Oxide Company New York Bronze Co. Fisher' Scientific Ingredients Sodium Chloride Ammonium Hydroxide * Ammonium Chloride Zinc Chloride 2 Butoxyethanal * Isopropyl Alcohol Reducing Agent * Polymer Vinyl Acrylic Neutral Red Eutectic Corporation Nickel * Iron * Boron * Silicon Fisher Scientific National Welders National Welders Noalox Anti -Oxidant. Ideal Industries, Inc. Nitric Acid Nitrogen Nitrous Oxide F'olybutene * Zinc Dust * Silicon Dioxide Nokorode Soldering Dunton, M. W. Supply Zinc Chloride * Ammonia Chloride Paste Petrolatum 0-Cresol Fisher Scientific 0-Cresol 0-cresol General Electric 2-Methyl Phenol Company OTC Hydraulic Oil Owatoona Oil Company Solvent refined ptroleue base oil * Zinc * Olefin co-polymer- Oakite 202 Oakite 220 NP Oakite Penetrant Oakite Products, Incorporated Oakite Products_, Incorporated Oakite Products, Incorporated Ope> Lacquer Thinner Sherwin-Williams R7 K 120 Company, 2-Bute <yethano l * Sodium Dodecylbenzenesulfonate * Diethylene Glycol Butyl Ether * Sodium Silicate Sodium Silicate * Nonylphenoxy Polyetho yethanol * Sodium Xylenesulfonate * Sodium Hydroxide Sodium Metasilicate Pentahydrate * Sodium Carbonate * Dipentene * Pine Oil * Tall Oil Bottoms Lt. Aliphatic Hydrocarbon Solvent V.M.&P. Naphtha * Toluene * Xylene Methanol * Ethanol * 2-Methyl-l-Propanoi 2-Butoxyethanol * Acetone * Methyl n-Amyl Ketone • Isobutyl Acetate f a Page No. 27 f9 _i 8 �!.�! Cam. • l_ Product Company Optimer 7125 Cation Nalco Chemical Flocculant Company Organic Phosphorous Calgon Corporation Reagent A Organic Phosphorous Calgon Corporation Reagent Organic Phosphorous Calgon Corporation Reagent C Organic Phosphorous Calgon Corporation Reagent D Oxalic Acid Fisher Scientific Oxygen National Welders Ingredient Cationic Acrylamide Polymer Beryllium Sulfate.4H20 None listed on MSDS Hydrochloric Acid None listed on MSDS Oxalic Acid Oxygen n PG 2089 Part A - Permagile Industries Liquid Epoxy Resin Epoxy Resin - Filled Inc. PG 2089 Part B - Epoxy Hardener - Inc. p . Filled PRO -MAR 400 Latex Sherwin-Williams Flat Paint B30 W 404 Company Antique White PRO -MAR 400 Latex Semi -Gloss Enamel Company B31 W 404 Antique White Sherwin-Williams PRO -MAR Block Filler Sherwin-Williams B25 W 1 Company PRO -MAR Traffic Sherwin-Williams Marking Paint, White Company 824W 1 PRO -MAR Traffic Sherwin-Williams Marking Faint, Company Yellow B29 Y 2 PST(R) H Ternp Anti -Galling Pipe Sint Loctite Corporation F'ermagile Industries Modofied Polyamine * Amiaoamine Crystalline Silica 2-(2-Butoxyethoxy)-Ethanol * Ethylene Glycol Hexane * 2-Methylpentane * VM P Naphtha * Xylene * Titanium Dioxide * Lead * Crystalline Silica Hexane * 2-Methylpentane * VM&P Naphtha * Xylene * Titanium Dioxide * Lead Chromate Lead * Chromium VI Polyglycol Dimethacrylate * BisPhenol A Fumarate Resin * Polyglycol Laurate * Poly(tetrafluaraethylene) * Titanium Dioxide * Silicon Dioxide, amorphous * Saccharin * Epoxy Resin * Cunene Hydroperoxide p--- cixide * N,N-Diaikytoluidines * Poly(ethylene) Page No. 28 03/22/9f Product Company Ingredients Patton's 0SI Oil F'atton's Inc. Petroleum Hydrocarbons * i dditivies containing Ca, Cu, Mg, Na, N P, S. Zn Pen -Green Robert Shaw Controls Missing MSDS Pen -Red Robert Shaw Controls Missing MSDS Penetrating Oil No. Penwait Corporation Stoddard Solvent * Mineral Gil 1 Penetrating Oil No. Penwa.lt Corporation Mineral Oils * Stoddard Solvent 0 Permatex Aviation Loctite Corporation Isopropyl Alcohol * Talc * Modified Fore -A -Gasket Natural Resins Sealant Liquid Permatex Lcctite Corporation Isopropyl Alcohol * Clay (Kaolin) * Red Form -A -Gasket No. 1 Iron Oxide * Modified Natural Resins Sealant Permatex Lactite Corporation Issopropyl Alcohol * Clay (kaolin) Form -A -Gasket No. 2 Modified Natural Resins Sealant Phenol Harrell Industries, Phenol Inc. Phenol Red Solution Fisher Scientific Phenol Red Sodium Salt 0.02% Phenolphthalein Phosphoric Acid Platinum Cobalt Color Standard Solution Fisher Scientific Fisher Scientific Fisher Scientific Plus -Fifty C Dry Ansul Fire Chemical Protection Pneumatic/Hydraulic Seal 545 Phenolphthalein M-Phosphoric Acid Hydrogen Chloride * Cobalt Chloride, Hexahydrate * Potassium Plaintinic Chloride Muscovite Talc * Magnesium Aluminum Silicate * Sodium Bicarbonate * Methyl Hydrogen Polysiloxane * Blue Pigment (Ho_taperm Blue) Lactite Corporation Fblyglycol Dioctanaates * Po1vglycol Dimethacrylates * Hydroxyalkyl Methacrylate * Cumene Hydroperoxide * Silicon Dioxide * N,N-Dialk:yltc'lui:dines * Maleic Acid * Saccharin 1-Acetyl-2-Phenylhydrazine page No. 29 03 /222 /9 ( } Product Company Polar Chip 347L Polar Chip Inc. Polvyn Crack Filler Master Builders, Inc. Polychlorinated Monsanto Biphenyls (PCB's) Polyurethane Clear Sherwin-Williams Spray Varnish Company 140-0B29 Clear Gloss Polyurethane Floor Sherwin-Williams Enamel A33 A 34 Company Light Gray Potassium Bisulfate Fisher Scientific Potassium Bromide Potassium Chloride Potassium Chloride Solution Potassium Hydrogen Phthalate Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Potassium Hydroxide Fisher Scientific (Dry Solid, Flake, Bead or Granular) Potassium Iodide Potassium Permanganate Potassium Thiocyanate Pow R Tox Insect Killer Power -Cut No. 360 Prism 410 Instant Adhesive Part No. 410 Fisher Scientific Fisher Scientific Fisher Scientific Ingredients Polyakalene Glycol * 2 Amino-2-Methyl-1-Propanol * Triet„anc.i Amine Salt of C6 to C12 Carboxyiicacid Silica, Crystalise Quartz * Ethylene Glycol Polychlorinated Biphenyls (F'CB's) Propane * 2-tlethylpropane * Mineral Spirits * Mineral Spirits (Odorless) Dichloromethane * 1-Butariol * Acetone * Methyl Ethyl Ketone Mineral Spirits * Mineral Spirits 140-Flash = Chromium Oxide Potassium Bisulfate Potassium Bromide Potassium Chloride Potassium Chloride * Silver Chloride * Hydrochloric Acid Potassium Hydrogen Phthalate Potassium Hydroxide Potassium Iodide Potassium Permanganate Anderson, James H., Petroleum distillates * Propane;Isobutane Company, Inc. Blend * Insecticide (tetramethrin phenothrin) DoAll Company Severly hydratreated petroleum oil (only as Mist) * Hexylene Glycol Loctite Corporation Ethyl Cyanoacrylate * Ethylene Copolymer Rubber * Silicon Dioxide * Hydroquinane * F'hthalic Anhydride a Page No. 30 03/22/9 I Product Company Pro Mar 400 Latex Sherwin-Williams Flat Paint B30 W 401 Company Pure White (Base X) Pro Mar 400 Latex Sherwin-Williams Flat Paint B30 W 404 Company Antique White Propane Bernzomat i c Purple-K: Dry Ansul Fire Chemical Protection Extinguishing Agent Pyridine Fisher Scientific 0-Dope GC Electronics RP Super Filter Coat Research Products tt418 Corporation R T V6O Rapid Tap General Electric Company Reltcnn Corporation Refined Petroleum Sargent -Welch Oil Scientific Company. Refractive Index Liquid Series AA Range 1.400-1.458 Refractive Index Liquid Series AAA Rance 1.300-1.395 Regular Clorox Bleach R. P. Cargille Laboratories, Inc. R. P. Cargille Laboratories, Inc. Clorox Company Replacement Charcoal Supelco, Inc. 4 E_x 0 c c SK:C-NF/ZC-7B Cleaner/Remover SKD-NF Developer Magnaf lux Magnaf lux: Corporation Ingredients Crystalline Silica (Quartz) Crystalline Silica (Quartz) Propane Muscovite Mica * Magnesium Aluminum Silicate * Potassium Bicarbonate * Methyl Hydrogen Polysiloxane * Purple Pigment Red Pigment Pyridine Toluene * Polystyrene Resin Hydrocarbon ❑i1 * 1,1,1-Trichloroethane Polyethylene * Anti -Microbial Agent Propane * Isobutane Ethyl Silicate 1,1,1-Trichloroethane * Glycol Methylene Ether Saturated Aliphatic Hydrocarbons Aliphatic/Alicyclic Hyrocarvons Chlorofluorocarbons Sodium Hypochlorite Charcoal (Activated) 1,1,1-Trichlc'roethane 8 Carbon Dioxide * Diaxane 1, 1, 1-Trichlc'roethane Chlcnrodiflucnrmethome * tleyhylal 2-Methyl, 2-propanol Page No. 31 03 /22/ 90 Product Company SF:::D Spotcheck Developer Magnaflux Corporation SKL-HF/S Spotcheck Magnaflux Penetrant Corporation SKL-W Water Washable Magnaflux Spotcheck: Penetrant Corporation SN60 WRAP3 Solder Muiticore Solders, Inc. SSR Ultra Coolant Ingersoll-Rand STA-FIL Revere Products STP Oil Treatment First Brands Corporation Safetap Safetec, Ltd. Safety -Walk Brand Edge Sealing Compound 3M Center Sani-Tuff Heavy Duty Sani-Fresh Cleanser, Sani-Fresh International, Inc. Heavy Duty Cleanser - Scotch Brand 1607 Heavy Duty Contact Cleaner 3N Center Scotch -Seal SOO 3M Center Industrial Sealant Scotchkote Brand 3M Center Electrical Coating Ingredient Ethyl acetate * Et ha io1 * Acetone* Carbon Dioxide Distillates * Kerosene * Carbon Dioxide * Napthalene Distillates * Kerosene .. Carbon Dioxide * Napthalene Lead * Tin * Rosin Inhibited polyoxya1kylene !_ t ester 1 ,? gl}'coi�NEiitaer}'thril.��l blend (1!;(1:F) SS1-Asphalt Emulsion * Ball Clay Chemically Neutralized Heavy Naptheni'= Petroleum Distillates * Solvent-Dewaxed Heavy Paraffinic Petroleum Distillates * Zinc Dialkyldithiaphosphate * Calcuim Sulfonate * Amine Grafted Ethylene/Propylene Copolymer - None listed on MSDS Acrylic resin * Napthol Spirits * Toluene Sodium Laureth Sulfate * Sodium C14-16 Olefin Sulfonate * Sodium Chloride * MIF'A-Dodecylbenzensulfonate 1,1,1-Trichloroethane * Dimethoxymethane * 1,4-Dioxane * Carbon Dioxide synthetic rubber * calcium carbonate * organic salt * antioxidant * phosphate plasticizer * rosin ester * iron oxide and filler * methyl ethyl ketone (MEK) * methyl isabutyl ketone (MIBK) * titanium dioxide Acetone * Methyl Ethyl Ketone * Tolune * Acrylonitrile/Butadiene Polymer * Phenol Formaldehyde Polymer * Glycerol Esters of Rosin Acids * Salicylic Acid * Zinc Oxide * Alkylated Diphenylamine Page No. 03: 22: 90 Product Silica Gel Silver Goop JC Silver Nitrate Solutions Company Fisher Scientific Crawford Fitting Company Ingredients Silica Gel Silver Flake Fisher Scientific Silver Nitrate * Nitric Acid Silver-Brite Sherwin-Williams Aluminum Faint B59 S Company 3 Hi -Heat Resisting Silver-Brite Aluminum Paint Hi -Heat Silicone Alkyd B59 S 8 Simple Green Concentrated Industrial Strength Cleaner and Degreaser Sherwin-Williams Company Sunshine Makers Smooth Kote Insulation Insulating Finishing Industries. Cement Snoop Sodium Bicarbonate Sodium Bicarbonate Sodium 8isulfite Solution Sodium Carbonate Nupro Inc. Mineral Spirits * Toluene * Light Aromatic Naphtha Mineral Spirits * Xylene * Light Aromatic p h N ia�ii. is Glycol Ether Mineral Fibers * Silica Portland Cement None listed on MSDS Church & Dwight Co., Sodium Bicarbonate Inc. Fisher Scientific Sodium Biocarbonate General Chemical Corporation Sodium 8i_ulfite Fisher- Scientific Sodium Carbonate Sodium Hydroxide Dry Fisher Scientific Solid, Flake, Bead, or Granular Sodium Metabilsulfite Sodium Persulfate Sodium Hydroxide General Chemical Sodium Metabisulfite Corporation FMC Corporation Disodium Feroxydisulfate Sodium Thiosulfate Fisher- Scientific Sodium Thiosulfate Pentahydrate Solution 0.25N to 1N Tetrasodium Ethylenediamine Tetraacetate Faye No. 03 l 2 2 J 9 0 Product 00 Solar Salt Pellets Solder Seal Liquid Wrench No. 1 Solder Seal Liquid Wrench No. 1 (Aerosol) Solution S0102 M Indicator DRO Solution S0222 P Indicator (PH) l2/ Solution Scco Sulfuric Acid N Solution S0243 N/1 H2SO4 Solution S0260 Special Indicator Solution S0274 H-1 Titrant Hiq Solution S0275 H-2 Total Hardn Solution S02277 H-3 Total Hardn Solution S0279 H-6 Calcium Har Solution S0280 H-7 COMpaii Cargill Salt - Leslie Salt - A Cargill Company Radiator Specialty Company Radiator Specialty Company Nalco Chemical. Company Nalco Chemical Company Nalco Chemical Company Nalco Chemical Company Nalco Chemical Company Nalco Chemical Company Nalco Chemical Company Nalco. Chemical Company Nalco Chemical Company Nalco Chemical Har CalciumCompany Solution S0294 Nalco Nalco Chemical 39-1 Company Solution S0297 3000 Nalco Chemical Micrcnco S Company Solution S0298 600 Nalco Chemical Micrombh ST Company Solution S0299 40 Nalco Chemical Mi.chroi,iho Sta Company Ingredients Sodium Chloride Aliphatic Petroleum * Distillate * Petroleum Mineral Oil Aliphatic Petroleum Distillate * Petroleum Mineral Oil * Carbon Dioxide Ethanol Ethanol -Denatured None listed None listed on MSDS Isapropano l None listed Manoethanalamine Blend of superchrame black: TS indicator in potassium salts Sodium Hydroxide None listed Isopropanol Dilute Sodium Chloride Solution Dilute aqueous sodium chloride solution Dilute aqueous soldium chloride solution a Page No. 34 03/222/90 Product Company Solution 50613 ST-1 Nalco Chemical Company Solution S0614 ST-2 Nalco Chemical Company Solution S0635 PA-1 Nalco Chemical Company Solution S0636 PA-2 Nalco Chemical Company Solution S0770 1 Nalco Chemical Indicator Company Solution S0771 2 Nalco Chemical Titrant Company Solution S0793 B-1 Solution S0794 B-2 Solution SF'274 H-1 Titrant HIS Nalco Chemical Company Nalco Chemical Company Nalco Chemical Company Sparkleen Calgon Corporation Speedball Power Cleaner Ingredients __ _ SLIT Ir�nll� Acid Aqueous solution of potassium iodide/iodate Monoethanolamine Dilute solution of quarternary amine None listed on MSDS Sulfuric Acid None listed None listed A hardness titrating solution Sodium Hei amethapfiosphate * Sodium Bicarbonate * Sodium Carbonate * Nonylphenoxypoly (ethyieneoxy) Ethanol Sodium Alkyl Aryl Sul f onate - 40% Active * Sodium Sulfate Butcher Polish Co., 2 butoxy ethanol - Nonoetflanolam i fie The Speedbonder 324 Loctite Corporation Structural Adhesive Spinerette Lubricant Chesterton, A. W. (Aerosol) Company Spray Kleen 10-8666, GC Electronics 10-8666-16 Polyurethane Methacrylate Resins Hydi o: alky1 Methacrylate * t-Butyl F'erben sate * Acrylic Acid * Saccharin * Higher Boiling Methacrylate 1,1,1-Trichloroethaie 1,1,2-Trichlorci-1,2,2-Trif louroethane Missing MSDS Staintec 10670 Eutectic Corporation Nickel * Boron * Silicon * Iron Starch Fisher Scientific Starch Page No. 03,122 / 90 Product JJ Starch Indicator Company Fisher Scientific Stay Clean Soldering Harris, J. W., Co.. Fluxes Inc. Steel Ink Remover Aerosol Step Off Stripper Stic-Safe Adhesive (Flammable -Brush) Stop Leak # ROOSL DcA11 Corportion Johnson, S. C. ° u Son, Inc. Fuller, H. B., Company Centima'rk Corp. Stude Pull Electrode Duratrode Style Perfect Interior Latex Enamel A20 W 101 Dover White Style Perfect Interior Latex Enamel A20 W 81 (Base X) (Mint Patty) Style Perfect Interior Latex Enamel A20 W 81 (Base X) (Mushroom) Style Perfect Interior Latex Enamel A20 W 81 (Base X) (Mystic Green) Style Perfect Interior Latex Enamel A20 W 81 Pure White Sul -Fury Drain Opener Sherwin-Williams Company Sherwin-Williams Company Sherwin-Williams Comp -any; Sherwin-Williams Company Sherwin-Williams Company Carroll Company Ingredients Starch * Glacial Acetic Acid Zinc Chloride * Hydrochloric Acid Ammonium Chloride * Petrolatum Butyl Cellosolve, 2-Butcxyethanol Toluene, Toluol, Methylbenzene * Acetone Propane, Dimethylrnethane * I_obutane. Tr- i methylmethane Sodium Hydroxide * Monoethanolamine Sodium Silicate Hexanes * Toluene Respirable Crystalline Quartz Chromium * Manganese * Molybdenum * Iron Nickel * Calcium Car bonatesc.urce-3*)Sect 2-(2-Butoxyethoxy)-Ethanol * Ethylene Glycol 2-(2-auto:yethoxy)-ethanol * Ethylene Glycol 2-(2-Butcxyethoxy)-ethanol * Ethylene Glycol 2-(tox- ethoxy)-ethanol * Ethylene Glycol 2-(2-Butoxyethoxy)-Ethanol * Ethylene Glycol Sulfuric Acid Page Nc, 03/22/90 Product Sulfuric Acid Company Fisher Scientific Sulfuric Acid Fisher Scientific Solutions, 0.05-4.9% Sulfuric Acid, 77 to Du Pont 100 Super -Set Solder .025 X _ Lb Wt Superbonder -!. r95 Instant Adhesive Superbonder G1uematic Pen Superflex(R) H Temp Silicone Adh/Sint (Red) Sure-Poxy Hi-Bild clear & colors Swen Sonic Dirl Strip TAT'L Leak Detector TPD Thinner TREMFIX A.F TRI-DEX MSP-21 Tempilstik: Temperature Indicator Premier Industial CorporationN Ingredients Sulfuric ur is Acid Sulfuric Acid Sulfuric Acid Tin * Lead * Silver * Gum Rosin Loctite Corporation Ethyl Cyanoacrylate # Poly (Methyl Methacry.late) * Hydroguinone Loctite Corporation Poly(dimethylsiloxane) * Silicon dioxide, amorphous * Ethyl tr iacetoxysi l ane * Ferric Oxide * Methyltriacetoxysilane Kaufman Products, Inc. Swen Sonic Corporation Blend J ofviscosity . L 1eepoxy resins and Vi�L.f��: modifying agents Sodium Hydroxide Shamrock Specialties Missing MSDS PDI, Inc. Tremco Trion, Inc. Chlorinated Hydrocarbon * Aliphatic Hydrocarbons * Chlorinated Hydrocarbons * Aromatic Hydrocarbons Coal Tar and Pitch * Calcium Carbonate Limestone * Aluminum Silicates * Pine Tar * Creosote Oil Sodium Metasilicate Tempil Division, Big Acetanilide * Aromatic Amine Three Industries, 1,3-Di-o-tolyl Guanidine * Phenoiphtalein Inc. * Alkali Chrrorr;ates * Lithium Compound Tennant STS (440)- Tennant Company Standard Traffic One -Coat System Part 08512 Tetrahydrofuran Thermal Arc Torch Coolant (Concentrate) Propylene Glycol Monomethyl Ether Acetate * Aliphatic Hydrocarbon * Urethane Prepoiymer * Toluene-2,4 diissocyanate Fisher Scientific Tetrahydrofuran Thermal Dynamics Ethylene Glycol Corporation page No. 37 03/ P2/ 90 Product Thermal Wave Extender L e'_ d _ . _ Thereinol VP-1 Heat Transfer Fluid Titanium Dioxide Titanium Reference Standard Solution 1000 PPM TI Total Eclipse/T/W Hi -Speed Floor Coating Traction Grit 295 Transport -Plus 7200 Tri.-Ethane Triethylene Glycol Triethylene Glycol Triethylene Glycol Triethylene Glycol Company Maintenance Supply Company, Inc. Monsanto Fisher Scientific Fisher Scientific Pioneer/Eclipse Corp. Tennant Company Nalco Chemical Compai ly PPG Industires Fisher Scientific Hoechst Celanese Chemical Group ICI Americas Inc. Union Carbide Trifluoroacetic Acid AguAir Corporation Tri=_. (nvdi Gi:ylrle I yl) Fisher Scientific Aminomethane UCON Heat Transfer Fluid 500 Ultra Blak(TM) RTV Silicone Union Carbide Loctite Corporation Ultrion 8109 Potable Nalco Chemical Coagulant Company. Unisilkon TV 017/200 Kluber Lubrication Ingredients Ammonia * Dibutyl Phthalate Diphenyl Oxide * Biphenyl Titanium Dioxide Hydrogen Chloride * Titanium Metal Ammonia Silicon Dioxide * Aluminum Oxide Ac:rylamide/acrylate polymer * modified acrylate polymer * carboxylate 1, 1, 1-T richloroethane Triethylene Glycol Triethylene Glycol Triethylene Glycol Triethylene Glycol * Ethylene Glycol Trifluoroacetic Acid Tris (Hydroxymethyl) Aminomethane F'olyalkylene Glycol Pc'ly(dimethylsilo `ane), Hydroxy * Calcium Carbonate * Poly(dimet hylsiloxane) Modified Silicon Dioxide + Vinyl oximinasilane * Substituted alk:ylsil'yl Urea Aluminum Hydrexychioride * Aluminum Sulfate silicone oil (methylphenylpolysiloxane Therm Corporation fluid) Page No. 2rIi9 {rJ:GC7(_1 Product }�l Company Ingredient_ Uniweld 100 Part A - Permagile Industries Epc+:;yr Resin 100% Solids Inc. Uniweld 100 Part B - Permagile Industries Amide+ Amine 100% Solids Inc. Uniweld Part A Uniweld Part B Vaseline Petroleum Jelly Velodur Metal Standard Activator 1001 VEL Velodur Metal Standard Base 1002 VEL Velodur Rapid Activator 1003 Velodur Rapid Base 1004 VEL Velodur Special Permagile Industries, Inc. Permagile Industries, Inc. Ch esebrough-Pand's Inc. American Durweld Sales Inc. American Durweld Sales Inc. American Durweld Sales Inc. American Durweld Sales Inc. American Durweld Bio-Cleaner 1000 VEL Sales Inc. Viscosity Standard Fluid 10 (10 CPS) WD-40 Aerosol Wasp/Hornet Jet Stream Wax Emulsifier Wolfracoat C Brookfield Engineering Laboratories, Inc. WD-40 Company Carroll Company Carroll Company Kluber Lubrication Corporation Epoxy Resin * Xyiene F'olyamine Resin * Modified F'olyamine Xylene None listed on MSDS Modified Pc+lyamines, Polyamines Polyamide Resin - 1-(2-Aminoethtyl ) Pipera ine * TETA - Triethylenetetraeine Digly=idyl Ether of Bispheinol A Resin 2,4,E-Tri(Dieethylaninc+methyl) Fenol Po lyeercap tel l Dinlycidyl Ether of Bisphenol A Resin Nokomis AO Oil Dispersants tru...�+mi.s o Polydimethylsiloxane Aliphatic Petroleum Distillates Petroleum Base Oil :r A-70 Hydrocarbon Propellant Corrosion Inhibitor * Wetting Agent * Fragrance 1,1,1-Trichloroeth.ane * Odorless Base Oil Propellant Sodium Hydroxide + Isopropanc+i 2-Butoxyethancl * Butoxy-Ethoxy-F'ropanol Copper Alloy * Synthetic hydrocarbon coil graphite X-MNS(TM) Clean up Loctite Corporation Solvent for Irist Adh N t ivlromethaile * Toluene Page No. 39 03/22/90 Product Company Ingredients Xylenes Fisher Scientific Xylenes Yellow 77 Wire Ideal Industries, Paraffin Wax * Petrolatum * Naphthenic Pulling Lubricant Inc. Mineral Oil * Polyethylene Glycol Ester Ethoxylated Alkul Amine * Cellulose Gum Sodium Benzoate * Yellow Pigment Yellow:/Green Liquid Formulabs, Inc. None listed on MSDS Concentrate Zero Mist Circuit GC Electronics Trichloromonofluor-o;methane * Coller Dichlorodifluoronethane Zinc Acetate Dihydrate Fisher Scientific Zinc Acetate Dihydrate Zonc'lite: Masonry Grace, W. R. 2 Insulation Block and Company Cavity Fill Magnesium—Aluminosilicate Mineral m—Cresol Eastman) Kodak m—Cresol Company p—Toluic Acid Eastman Kodak p—Toluic Acid Company pHreeGuard 1000N Calgon Corporation None listed on MSDS pHreeGuard 2350 Calgon Corporation Sodium Hydroxide * Ethylene Glycol REC E VED -1- Facility Name NPDES No. Type of Waste Facility Status Permit Status Receiving Stream Request No. 5778 FFR FACT SHEET FOR WASTELOAD ALLOCATIONS :Allied Fibers - Outfall :NC0001899 :Industrial :Existing :Renewal :Shaddox Creek Stream Classification:C Subbasin :03-06-07 County :Chatham Regional Office Requestor Date of Request Topo Quad :Raleigh :Rosanne Barona :6/26/90 :E22SE Wasteload Allocation Summary 002 Stream Characteristics: USGS # estimated Date Drainage Area: 0 sq.mi. Summer 7Q10: 0 cfs Winter 7Q10: 0 cfs Average Flow: 0 cfs 30Q2: 0 cfs Discharge consists of firepond overflow, stormwater runoff from industrial plant, steam and HVAC condensate, and air dryer. The discharge is to a swampy area which drains to Shaddox Creek. There is substantial algae growth in the effluent channels. WASTELOAD SENT TO EPA?(Major) _Y_ (Y or N) (if yes, then attach schematic, toxics spreadsheet, copy of model, or if not modeled, then old assumptions that were made, and description of how fits into basinwide plan) Recommended by: Reviewed by Instream Assessment: Regional Supervisor: Permits & Engineering: ID A. SGO:iG RETURN TO TECHNICAL SERVICES BY: MAR O i Date: Date: Date: A/7/9i 2/h -2- Request No. 5778 CONVENTIONAL PARAMETERS Existing Limits Request No. 5778 Monthly Average Daily Maximum Wasteflow (MGD): monitor pH (SU): 6-9 Temperature (C): The discharge shall not cause the temperature of the receiving stream to exceed 2.8 C above background and in no case cause it to exceed 32 C. Recommended Limits Monthly Average Daily Maximum Wasteflow (MGD): monitor pH (SU) : 6-9 Fluoride (mg/1): 1.8 Zinc (ug/l): monitor Temperature (C): The discharge shall not cause the temperature of the receiving stream to exceed 2.8 C above background and in no case cause it to exceed 32 C. Limits Changes Due To; Parameter(s) Affected Annual Pollutant Analysis Fluoride, Zinc TOXICS Toxicty Limit: Acute, episodic Monitoring Schedule: 1st five events INSTREAM MONITORING REQUIRMENTS: Upstream: Y Location: Shaddox Creek above discharge Donwstream: Y Location: Shaddox Creek at SR 1011 Parameters: Temp, pH, DO, Cond SPECIAL INSTRUCTIONS OR CONDITIONS ADDITIONAL REVIEWER COMMENTS: 11/89 Facility Name Allied i; berg - O of 4( 6n L Permit # /�%L 06 O ! 8 9 9 ACUTE TOXICITY TESTING REQUIREMENT Fathead Minnow 24 hr - Monitoring (Annual) for Episodic Events The permittee shall conduct FIVE acute toxicity tests using protocols defined as definitive in E.P.A. Document 600/4-85/013 entitled "The Acute Toxicity of Effluents to Freshwater and Marine Organisms". The monitoring shall be performed as a Fathead Minnow (Pimephales promelas) 24 hour static test, using effluent collected as a single grab sample. Effluent samples for self -monitoring purposes must be obtained below all waste treatment. Sampling and subsequent testing will occur during the first five discrete discharge events after the effective date of this permit. After monitoring of the first five toxicity tests, the permittee will conduct one test annually, with the annual period beginning in January of the next calendar year. The annual test requirement must be performed and reported by June 30. If no discharge occurs by June 30, notification will be made to the Division by this date. Toxicity testing will be performed on the next discharge event for the annual test requirement. The parameter code for this test is TAE6C. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Form (MR-1) for the month in which it was performed, using the appropriate parameter code. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management P.O. Box 27687 Raleigh, N.C. 27611 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any test data from either these monitoring requirements or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test. Failure to submit suitable test results will constitute noncompliance with monitoring requirements. 7Q10 cfs Permitted low KV.0— MGD IWC% /00 Basin & Sub -Basin D3 - o4. - D I Receiving Stream Aaddox C'-eek County C17.aj-k�.,.— Recommended by: Date U j/.t 31/ 40 **Acute Toxicity(Fathead Minnow 24 hr) Monitoring, EPISODIC, See Part 3 , Condition 43 YNOCuO% cree_k 7 0. ✓ G o w�] �P � U-rS 7 -r� c� c Lt P� S t� t r�r� A , etA n tvo L. ;.,-. r2 ,t' C .v�r�a \5 ` a.t,P p r�1 - y / I Al t - NJ O 3 � /► TG i • 1L, ! I -Fee c ( (Cori) Vo s-� 1- Vs',31( zc)g 4.)411 — Can Ur?y. YL Tz/J„/,/ C1fv3; T5 ��ow - h- n✓ PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information on separate sheets (use the same format) instead of completing these pages. SEE INSTRUCTIONS. Vi^INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-0 EPA I.D. NUMBER (copy from Item I of Form I)1 NCD053488409 Form Approved. OMB No. 2040-0086 Approval expires 7-31-88 PART.A --You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2. EFFLUENT i:-POLLUTANT IT MAXIM M 30 pAY VALUE C. LONG T ja A VR� .VALUE ( auai a e) i available a:• Biochemical Oxygen'Demand b: Chemical:. Oxygen Demand (COD) c..Total Organic Carbon (TOC) a. MAXIMUM DAILY VALUE ICONCENTRATION LT 4 (2) MASS ICONCENTRATION (2) MASS CONCENITRATION (2) MASS d. NO. OF ANALYSES 1 d. Total Suspended Solids (TSS) 30 4 10 82.6 11 27.5 1 1 1 e. Ammonia (as N) f. Flow LT 0.3 VALID 1 0.910 VALUE 0.524 g. Temperature (winter) VALUE h. Temperature (summer) i. pH VALUE MINIMUM 6.8 VALUE 19 VALUE 29 MAXIMUM MINIMUM 8.0 7.0 18 VALUE 0.156 52 VALUE VALUE 12 27 24 MAXIMUM 8.0 3. UNITS (specify if blank) a. CONCEN- TRATION mg/L mg/L mg/L mg/L mg/L b. MASS 4. INTAKE (optional) a. LONG TERM AVEHAG4 VALUE fl) CONCENTRATION (2) MASS b. NO. OF ANALYSES r lb/day lb/day lb/day MG D 26 oC VALUE VALUE 26 oc VALUE STANDARD UNITS PART B - Mark "X" in column 2-a for each pollutant you know or have reason to believe is present. Mark "X" in column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pol lutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details and requirements. 2. MARK 'X' 1. POLLUT- ANT AND CAS NO. (if available) a. Bromide (24959-67-9) b. Chlorine, Total Residual a. BE- b. BE- LIEVE LIEVEI PRE- AB- SENT SENT x X 3. EFFLUENT a. MAXIMUM DAILY VALUE b• MAXIMUM 30 pqj VALUE O (i aua" a e CONCENTRATION 1.0 (2) mass 2.8 ICONCENTRATION (2) MASS C.LONG TERM AVRj . VALUE i availabblle (1) (2) MASS CONCENTRATION d.NO. OF ANAL- YSES 4. UNITS a. LONCEN- RATION b. MASS 5. INTAKE (optional) a. LONG TERM AVERAGE VALUE {1) CONCENTRATION (2) MASS b. NO. OF ANAL- YSES 1 LT 0.1 c. Color d. 'Fecal Coliform X 1 mg/L lb/day mg/L 20 PC u e. Fluoride (16984-48-8) x X 10 0.2 f. Nitrate — Nitrite (as N) EPA Form 3510-2C (Rev. 2-85) 1.4 0.6 1 COL/100 ml 1 mg/L lh/day 3.8 PAGE V-1 1 mg/L lb/day CONTINUE ON REVERSE EPA I.D. NUMBER (copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NCD053488409 PART C If you are a primary industry and this outfall contains process wastewater, refer to b e 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary industries, nonprocess wastewater outtalk, andnonrequired GC/MS fractions), mark "X" in column 2-b for each pollutant you know or have reason to believe is present. Mark "X" in column 2-c for each pollutantyou believe is absent. If you mark column 2a for any pollutant, you must provide the results of at (east one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at (east one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (a// 7 pages) for each outfall. See instructions for additional details and requirements. 1. POLLUTANT 2. MARK 'X' 3.EFFLUENT 002 AND CAS NUMBER (if available) METALS, CYANIDE, 1M. Antimony, Total (7440-36-0) 2M. Arsenic, Total (7440-38-2) a.resr b. BE- a BE- a. MAXIMUM DAILY VALUE ING LIEVEDLIEVEq,__ RE- PRE- AB- (I) OUIR- SENT SENT (2) MASS ED CONCENTRATION AND TOTAL PHENOLS LT 40 LT 5 CO NCE NTI7A TI ON 3M. Beryllium, Total, 7440-41-7) X LT1 4M. Cadmium, Total (7440-43-9) 5M. Chromium, Total (7440-47-3) X LT 5 X LT 8 6M. Copper, Total (7440-50-8) 7M. Lead, Total (7439-92-1) X LT9 X LT5 8M. Mercury, Total (7439-97-6) 9M. Nickel, Total (7 440-02-0) X LT 0.2 X LT 50 10M. Selenium, Total (7782-49-2) 11M. Silver, Total (7 440-22-4 ) 12M. Thallium Total (7440-28-0) X LT 10 X LT 5 X LT 65 b. MAXIMUM 3Y VALUE (if available) (I) (2) MASS C.LONG T5at'13M wl(%a e-VRj . VALUE e (I) (2) MASS CONCENTRATION d. NO.OF ANAL- YSES 4. UNITS a. CONCEN- TRATION Form Approved OMB No. 2040-0086 Approval expires 7-31-88 b. MASS 5. INTAKE (optional) a. LONG TERM AVERAGE VALUE (I) CONCEN- (2) MASS TRATION b. NO.OF ANAL- YSES 1 1 1 1 1 1 ug/L ug/L ug/L ug/L ug/L ug/L ug/L 13M. Zinc, Total (7440-66-6 ) 11 14M. Cyanide, Total (57-12-5) 15M. Phenols, Total DIOXIN LT 20 LT 5 0.03 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 2,3,7,8-Tetra- chlorodibenzo-P- Dioxin (1764-01-6) X DESCRIBE RESULTS 1 1 1 ug/L ug/L ug/L lb/day EPA Form 3510-2C (Rev. 2-85) PAGE V-3 CONTINUE ON REVERSE CONTINUED FROM PAGE V-4 1. POLLUTANT AND CAS NUMBER (if available) 2. MARK 'X' '� '•"^' {«NY !rorn .1 WIN 1 (.11 1 orm 1)jUU i Y-ALL NUMSE .1 NCD053488409 I 002 wrest- b. DE- C. DE- a. MAXIMUM DAILY VALUE Inc LIE'1EOLIEV Ed _ OUEIRAB- - SENT ENT III (2) MASS ER CONCENTRATION GC/MS FRACTION - VOLATILE COMPOUNDS (continued) 22V. Methylene Chloride (75-09.2) X LT 10 23V, 1,1,2,2-Tetra- chloroethane (78.34-5) X X L LT 10 24V. Tetrachloro- ethylene (127-18-4) LT 10 25V. Toluene (108-88-3) 26V: 1,2-Trans- X LT 10 Dichloroethylene (156-60-5) 27V. 1,1,1-Tri- X LT 10 chloroethane (71-55-6) X LT 10 28V. 1,1,2-Tr i- chloroethene (79-00-5) X LT 10 29V. Trichloro- ethylene (79-01-6) X LT 10 30V. Trichloro- fluoromethane (75.69-4) _ i X X LT 10 LT 10 31V. Vinyl Chloride (75-01-4) S FRACTION - AC D COMPOUNDS 3. EFFLUENT b. MAXIMUM 39 DAY VALUE (if available) (II CONCENTRATION (2) MASS C.LONG T(}?M fra e;. VALUE 3 avarla e CONCENTRATION (2) MASS OMB No. 2040-0086 Approval expires 7-31-88 .ter 4. UNITS d. NO.OF a. CONCEN- TRATION YSES b. MASS 5. INTAKE (optional) a, LONG TERM b. NO.OF (I) GONG En- (2) MASS AVERAGE VALUE ANAL- ' TR ATI ON ug/L ug/L ug/L 1 ug/L 1A. 2-Chlorophenol (95-57-8) 2A. 2,4-Dichloro- phenol (120-83-2) X LT 10 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L uq/L 3A. 2,4-Dimethyl- phenol(105-67-9) X LT 10 LT 10 4A. 4,6-Dinitro-O- Cresol (534-52-1) X LT 50 ug/L 1 ug/L 1 ug/L 5A. 2,4-Dinitro- phenol (51-28-5) 6A. 2-Nitrophanol (88 -7 5.5 ) 7A. 4-N itrophenol (100-02-7) X LT 50 LT 10 8A. P-Chloro-M- Cresol (59-50-7) 9A. Pentachlorc- phenol (87-86-5) 10A. Phenol (108-95-2) 11A. 2,4,6-Tri- chlorophenol (88-06-2) X X LT 50 LT 10 LT 50 LT 10 LT 10 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L 1 ug/L EPA Form 3510-2C (Rev. 2-85) PAGE V-5 CONTINUE ON REVERSE Tlnnrc (copy from item 1 of Form 1) CONTINUED FROM PAGE V-6 NCD053488409 OUTFACE NUMBER 002 OMB No. 2040-0086 Approval expires 7-31-88 1. POLLUTANT 2.MARK 'x•3. AND CAS EFFLUENT NUMBER aT L'ST• b, eE- G UE- b. MAXIM M 30 4. UNITS 5- INTAKE (Ioptional) INc et- ' LIEV C4 °Ne- LIEV e�� we- a. MAXIMUM DAILY VALUE DAY VALUE (l QUQtQ e)r C.LONG T pM I QUQ a��r• VALUE tj NO.OF a. LONG TERM (if available) o - SENT 1fENT III (zI mwss A ANAL- a. CONCEN• b. MASS AYER ACE VALUE �. NO.<,F to GC/MS FRACTION CONCENTRATION e eoNC a NTla w T.ON (al mn.... — -- CONCENTRATION (°) MASS YSES TRATION (I) coNe en" lzl mwss _ YSE$. —BASE/NEUTRAL COMPOUNDS (continued( --- TRATION 22 B. 1,4-D ich to ro- benzene (106-46-7) X LT 10 23B.3,3'-Dichloro• — -- .—. --- - - 1 Ug/L benzidine (91-94-1) X LT 10 - --- 24B. Diethyl '1 --..._.-..--------- - -- --- 1 ug/L Phthalate (84-66-2) X LT 10 258. DimethYl 1 uqLL Phthalate (131-11-3) X LT 20 268. DI-N-Butyl —. 1 .--.---._--- (% /L g Phthalate (84-74.2) X LT 10 - --- — — 1 ug/L 27B. 2,4 Dinitro- toluene (121-14-2) X LT 10 — 1 ug/L — 28B. 2,6-Dinitro- toluene (606-20-2) LT 10 29B. Di-N-OctYl -- -- 1 ug/L Phthalate (117-84-0) X LT 10 30B. 1,2-Diphenyl- — - --- 1 ug/L hydrazine (as Azo- benzene)(122-66-7)* _ 4 7 318. Fluoranthene (206-44-0) X LT 10 328. Fluorene 1 ug/L (86a3-7) X LT 10 338. Hexacnlorobenzenej _ 1 ug/L I11R-741I Il X LT 10 1 346. Hexa- ug/L chlorobutadiene (87-68-3) X LT 10 35B. Hexachloro- 1 ug/L cyclopentadiene (77-47-4) X LT 10 36B. Hexachloro- 1 ug/L ethane (67-72-1) X LT 10 37B.Indeno - 1 ug/L (I,2,3-cd) Pyrene (193-39-5) X LT 10 - -_ 1 383.Isophorone--- ug/_L~ (78-59-1) X LT 10 /I 3913. Naphthalene (91-20-3) X LT 10 II 0 4OB. Nitrobenzene (98-95-3) X LT 10 - — - 1 -- -u.g/L ---• •--- ___. ______.___ 416. N-Nitro- 1 ug/L sodimethylamine (62-75-9) X LT 10 l 42B. N-Nitrosodi- 1 ug/L N-Propylamine (621-64-7) X _ LT 10 EPA Form 3510-2C (Rev. 2-85) *D.,-c,,,,. 4--c,. - ._._ , __.L_, T._ ,-_ '� - - -- _ 1 ua/L ation 7 Attachment Section V, Part C CONTINUE ON REVERSE CONTINUED FROM PAGE V-8 EPA I.D. NUMBER (copy from Item I of Form I) OUTFALL NUMBER 1. POLLUTANT AND CAS NUMBER (if available) 2. MARK 'X' a.resr INC ae- O'2R- GC/MS FRACTION — PE 17P. Heptachlor Epoxide (102457-3 ) NCD053488409 002 b. se- Gee- a. MAXIMUM DAILY VALUE LIE,/ EO LICV eo PRE- AS (�l Be NT 4CNT C ONCE NTIIATI ON ICIDES (continued) (2) mass 3. EFFLUENT b. MAXIMUM 3 AY VALUE (if aua table) CON C L NITH A I'1 ON (2I MA.z LT 0.05 18P. PCB-1242 (53469-21-9) 19P. PCB-1254 (11097-69-1) 20P. PCB-1221 (11104-28-2) X LT 0.5 LT 1.0 LT 0.5 21P. PCB-1232 (11141-16-5) 22P. PCB-1248 (12672-29-6) X LT 0.5 LT 0.5 23P- PCB-1260 (11096-82-5) 24P. PCB-1016 (12674-11-2) 25P. Toxaphene (8 001-35-2 ) LT 1.0 LT 0.5 LT 1.0 Form Approved. OMB No. 2040-0086 Approval expires 7-31-88 • C.LONG TR MAaVRe?. VALUE CONC. E!TNAT ION (.1 MALs 1, NO.OF ANAL- YSES 4. UNITS a. CONCEN- TRATION b. MASS 5. INTAKE (optional) a. LONG TERM AV ERA •E VALVE (1) CONCEN- (2) mass THATION b, NC. O F I AN`AL-, YSES PAGE V-9 1 1 1 ug/L ug/L ug/L ug/L uq/L 1 1 1 ug/L ug/L ug/L uq/L EPA Form 3510-2C (Rev. 2-85) Ir li-5. GOV1.:RNME T 1'1tTNTTNC: OM' ICF. _ 11)81, ( - 4')1-191 (4(.11(.) FORM 2C SUPPLEMENTARY INFORMATION ITEM II. B: Outfall 001: Sanitary wastewater flows to a pumping station equipped with a comminutor, a bar screen bypass and a Parshall flume for flow recording. Waste is pumped to the aeration basin, entering about 40 feet from the process waste influent point. Fiber finish oil, which is primarily composed of fatty acid esters, organo- silane esters, and alkylamine, oleate and trioleate emulsifiers, is segregated from other process waste for pretreatment. An ultrafiltration unit is used to separate the oil from the water. The water is pumped to the wastewater treatment plant and the oil is burned on -site for energy recovery. Process wastewater flows to a pumping station equipped with a manually cleaned bar screen and a Parshall flume for flow recording. It is pumped to a 1200 gallon mixing chamber which allows for pH adjustment. During emergencies, the flow can be diverted to a 600,000 gallon holding pond. The aeration basin has a volume of approximately 650,000 gallons and is equipped with four (4) 20 HP floating aerators. The waste then flows to a 20 feet diameter clarifier with a design overflow rate of 440 gallons per square foot per day. A surface skimmer and holding sump are provided. Pumps are provided to return settled sludge to the aeration basin or to a sludge drying bed. Clarifier overflow is piped to a one acre polishing pond operating at a 3 foot depth. A .4 acre alum settling pond is provided for the potable water plant backwash and blowdown. The clarified discharge from the alum pond is pumped to the polishing pond. Effluent from the polishing pond flows through a 3600 gallon retention chamber for chlorine disinfection. A V-notch weir at the effluent end of the chamber provides for flow recording. During the summer months, algae activity increased the pH of the polishing pond above 9.0 standard units. When this occurs, clarifier overflow is valved directly to the chlorine contact chamber where it is blended with polishing pond effluent prior to entering the chamber. Approximately 8,000 pounds of sludge is wasted during the year to a sand drying bed. Wastewater that drains through the sand is pumped back to the aeration basin. On October 26, 1989 approval was received (Permit #19-01) from the Department of Environment, Health and Natural Resources, Division of Solid Waste Management for the continued disposal of dried wastewater treatment plant sludge at the Chatham County landfill. Based on the submitted information (EP-TOX, pH, paint filter test, total petroleum hydrocarbon analysis, GC/MS purgeable [SW-846 Method 8240], and base/neutral/acid extractables [SW-846 Method 8270]), the sludge was determined by the Division to be non -hazardous. The approval requires submittal of a waste determination form and supportive analytical data on the third anniversary of the permit. As an alternative disposal method, the plant is examining an on -site land treatment or utilization/nutrient transfer program. Should the plant -2- decide to pursue this option, a permit application per 15NCAC2H.0200 Waste Not Discharged to Surface Water will be submitted to the Division of En- vironmental Management, Department of Environment, Health and Natural Resources. Outfall 002: This drainage system includes a series of baffles and weirs designed to contain accidental spills of oil and Dowtherm. In an emergency, flow can be contained in a holding pond and pumped to storage or the wastewater treatment plant. Storm water runoff from most of the manufacturing areas and chemical storage areas of the plant is discharged through permitted outfalls 001 and 002. Storm Water Other storm water discharges are described in the permit application submitted to the N.C. Division of Environmental Management on April 16, 1985. Storm water information will be updated when final storm water regulations are promulgated by the EPA. ITEM III. A & B: On November 5, 1987 EPA issued regulations establishing effluent limitations and standards for the Organic Chemicals, Plastics, and Synthetic Fibers (OCPSF) industrial category. Provisions of Subpart C (414.31) and Subpart I (414.90) Direct Discharge Point Sources That Use End -of -Pipe Biological Treatment are applicable to process wastewater discharges from the manufacture of polyester fiber and resin. OCPSF effluent guidelines are not expressed in terms of production. No metal -bearing waste streams or cyanide -bearing waste streams listed in Appendix A to Part 414 exist in the manufacture of polyester fiber and resin. ITEM V. A-C: Wastewater characteristics tabulated in item V reflect data from the period January 1, 1989 to December 31, 1989. For some parameters, testing was conducted throughout the year and for other parameters testing was done on a more limited basis. Special tests were conducted for most of the parameters. Bis-chloro-methyl ether (FR 2/4/81) and dichlorodifluoromethane (FR 1/1/81) have been dropped from the 2C GC/MS Fraction -Volatile Compound list by the EPA. 1,2-Diphenylhydrazine as azobenzene was not detected in the influent, outfall 002 or outfall_001. A precise determination of a reporting limit was not made since azobenzene is not a target constituent in EPA's CG/MS methods 624 or 625. ITEM V. D: This list is as complete as possible; however, since some manufacturers consider their products proprietary they will not release information on the composition. Therefore, there may be other materials on the plant site that contain one or more of the chemicals in Table 2C-3. In addition, new materials may be obtained that may have one or more of the chemicals listed and whose composition may or may not be known. -3 ITEM VI: The following is a list of Part V. C pollutants that are present on the plant site. None of these materials are used as a raw material or inter- mediate and noire of these materials are manufactured as a product or are a by-product of the manufacturing process. The list may not be exhaustive because some commercial products are considered proprietary by the manufacturer and their composition is not known to us. In addition, some new materials may be obtained in the future that contain one or more of the listed chemicals and whose composition may not be known to us. Pollutant Use on Site Antimony Chromium Copper Lead Mercury Nickel Silver Zinc Cyanide Phenols Carbon Tetrachloride Chloroform Dichlorodifluoromethane Methylene Chloride Methyl Chloride 1,1,2,2-Tetrachloroethane Tetrachloroethylene Toluene 1,1,1-Trichloroethane Trichloroethylene Phenol Benzidine Dichlorobenzene 1,2,4-Trichlorobenzene PCB ITEM V. PART C: IIV. Chloroform Lab Reagents Lab Reagents Lab Reagents Lab Reagents Lab Reagents, Instrumentation Lab Reagent Lab Reagents, Electrical Equipment Lab Reagents Lab Reagents Lab Reagents Lab Reagents Lab Reagents Lab Reagents, Refrigerant, Leak Checks Adhesive Ingredient Solvent Lab Reagent Solvent Lab Reagent Solvent Solvent Lab Reagent Lab Reagent Lab Reagent Electrical Equipment Electrical Equipment In December, 1988 and April, 1989 studies were conducted on OCPSF process related wastewater sources and wastewater treatment plant influent, clarifier overflow and effluent to determine if chloroform carries through the treat- ment plant or is formed during effluent disinfection. Chloroform was not detected in either the OCPSF process related wastewater sources or the clarifier overflow. Chloroform was detected in the influent and the effluent from the treatment plant. -4- Chloroform in the influent is due to the chlorination of river water in the site's potable water treatment plant. Analytical data has been compiled on the formation of trihalomethanes in the potable water and we are tracking the effectiveness of carbon filters on drinking water coolers. The risk of wastewater contamination with chloroform is minimal since the only area of the plant that handles chloroform is the Quality Control Laboratory, which uses a cresol/chloroform solution for polyester fiber testing. Handling procedures require that all waste solvent be placed in a hazardous waste drum for off -site incineration at an EPA approved facility. Actions are being taken to reduce the chlorine dosage and the resulting residual chlorine level in the effluent. This should decrease the level of chloroform in the effluent.