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HomeMy WebLinkAboutUnocal Corpartion at 4336 Park Road in Charlotte NC Groundwater incident #3633~ ~EN"'S::R: -a ~ l items 1 ar,..• · • 2 for additional services. I also wish to rece,vd the "iii •-'w ... , _,e items 3, L l 4b. following services (for an GI ■ Print your name and ~. ~ress on the reverse of this form so that we can return this extra fee): ~ ~~~ ~ GI._~ ■Attac~ this form to the front of the mailpiece, or Oll-j~ A~~ jf ~l!.'f; ~Q~r i1'?~ 1. □ Addressee's Address ·s. permit. . ''"-l,t ... 1.L/ 1"•·,1· .., GI ■Write'Return Receipt Requested' on the ma~RMlceft)ekJ,wlhe•;miqle 11uml>11~ ',-. r-2. 0 Restricted Delivery ~ ,S ■The Return Receipt will show to whom the'ai'ticle was delivered aruhhe'Clat~ ;:: C. .. CL c delivered. Consult postmaster for fee. 0 --------------,q.........,.,........-.._..---,m.....,,---=-==-'"-----------•i -a 3. Article Addressed to: cti1e]'Jumber G1 SGI MR A WAYNE HOT'[' a: ~ P 281 578 884 E t UNOCAL REFINlNG & MARKEI'Il~G DIV 4b. Service Ty e. .a o :r &! u UNOCAL CORP □ Register , ~~l Cf Ty,<-~ Certified ci w 13 CORPORA'IE SQUARE NORI'HEAST □ Expte s ' if "f~ Insured ·i ~ P O BOX . 414 7 D Re m Receipt for Merchandise COD : ~ A.TIANTA GA 39392 . 7. D~e of DelivAl'y ] o 19gl J:! (variance/CA. #36.33 ).tr 5/13/97 [ z a: ::::, 5. Received By: (Print Name) lij 8. Add fllss ,e's Ad~nly if. equested and f~ fs'.llaidJ ,.. .II: C al .c a: ... ::II 0 > .!! I- .Jrn Receipt , .. State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director AVA DEHNR May 13, 1997 CERTIFIED MAIL NUMBER: P 281 578 884 Mr. A. Wayne Holt Unocal Refining and Marketing Division ·. ·" Unocal Corporation 13 Corporate Square Northeast P.O. Box 4147 Atlanta, GA 30302 Subject: Request for Variance from Groundwater Quality Standards in 15A NCAC 2L .0202 and Corrective Action in 15A NCAC 2L .010_60) for the Unocal Corporation at 4336 Park Road in Charlotte, North Carolina {Groundwater Incident# 3633 }. This is to inform you that the Environmental Management Commission, at their May 8, 1997 meeting, approved the variance request by the Unocal Corporation for property it formerly owned at 4436 Park Road in Charlotte, North Carolina. The Commission granted this variance in accordance with the requirements of 15A NCAC 2L .0113 on the following conditions: (1) The Unocal Corporation shall be granted a variance pursuant to 15A NCAC 2L .0113 from the requirements of 15A NCAC 2L .0202 (g) and 15A NCAC 2L .0106(j) for entire 1.05 acres of property identified as 4336 Park Road in Charlotte, North Carolina. In addition, the Unocal Corporation shall obtain relief from twenty-four (24) specific Groundwater Quality Standards in 15A NCAC 2L .0202. Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd .. Raleigh, North Carolina 27604 N('JC !ffiti'f P®' Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50% recycles/lO"k post-consumer paper . 1 ; . ' (2) These substances are shown as follows: Benzene, Bromodichloromethane, Bromoform, Carbon Tetrachloride, Chlorobenzene, Chloroform, cis-1,3-Dichloropropene, Dibromochloromethane, 1,1-Dichloroethane, 1, 1-Dichloroethene, 1,2- Dichloroethane, 1, 4-Dichlorobenzene, 1,2-Dichloropropane, Ethylbenzene, Ethyl Dibromide (EDB), Isopropyl Ether, Methylene Chloride, Methyl-Tert Butyl Ether (MTBE), Naphthalene, 1,1,2,2-Tetrachloroethane, trans-1,3- Dichlorobenzene, 1,1,1-Trichloroethane, 1,1,2-Trichloroethane, Xylenes (o- ,m-, and p-). The letter to the Unocal Corporation granting the variance will include language that will state the following: "Should problems develop at or near this site as a result oftbe loss of petroleum by Unocal Corporation, the Division of Water Quality reserves the right to require Unocal Corporation to undertake additional investigations and corrective actions" (3) The Unocal Corporation will be required to sample wells Monitoring Well# 5, Monitoring Well# 7, Monitoring Well# 9, Recovery Well# 1, and Recovery Well# 4 two times per year for the next two years. Groundwater samples are to be analyzed using U.S. Environmental Protection Agency Method 601, Method 602 ( including MTBE), and Method 504.1 for EDB. Analytical results shall be submitted to the Groundwater Section staff of the Division of Water Quality, Mooresville Regional Office on or before March 1 and September 1 of each year. Should the results of this sampling or other sources of information reveal problems as a result of the loss of product by the Unocal Corporation at or near this site, the Groundwater Section staff at the Mooresville Regional Office may require additional groundwater sampling and analysis. In approving this variance request the Environmental Management Commission amended the hearing officer's recommendation to clarify that the conditions of the variance apply to off-site contamination as well as substances found at 4336 Park Road. The Commission added language stating that the Division can require the Unocal Corporation to take additional measures "at or near the site" in Condition # 2 above. This additional language was also applied in the last sentence of Condition # 3 which prescribes the groundwater sampling and· analysis requirements for this variance. Please note that 2 approval of this variance by the Environmental Management Commission represents final action on this request pursuant to the requirements of 15A NCAC 21.0113. If you need to discuss this letter further, please feel free to contact me at (919) 715-6170. cc: Preston Howard Arthur Mouberry Groundwater Section Assistant Chiefs Tom Warburton Mooresville Regional Groundwater Stewart Hines (S&ME, Inc) Sincerely, ~,,,;w~ Arthur Mouberry, P.E.,. Chief, Groundwater Section Sherri Knight Jennie Odette Allen Schiff Dr. Ken Rudo David Hance Ernie Seneca 3 02.27.1997 17:54 ,.. 4 - • :, :·. • ~ -i le d and opei1~ateC: ,i v ~;_cuu m axtractio~ syatem, . ~ · :.-.J 0f-':?:.'>\t".,_,c! an air i=.pa.rging: system .. drilled monitoring ,_ • .,,c. l J, ano cono.ui...:Led &xtensi ve a oil an4i groundwater monitoring. ,,·.-:,pr(:'i>':ima+-.ely 3,050 pounds of petrole'-1r hydrocarbons have been -·~t:O.,f fe!:>~ed at a total cost of $57Sl, 995 ;I All this at a site whi,ch is .... -.-, t-.. •.•w ,,.,~ r,tod.1.:cing as far as Unocal is concerned since the property w:=.:~ ,ticlci. j_n 198'7. .'r,.dditionally this ~lean-up was carried out without "''2$!~ ~tf'.1~c<'.? frT•l'fl ,r,r:i ~tat::P. trust fund }tie.cause the loss was diedove:red · -"+P. ~1u:ie: 30, ::.983 . The compan}' es~imates that the thrae-yEtar cost -:•t,t -r-at :'.t1 :.J r,1.1":":."' .,nfl trea. t, air spar~ing and soil vapor extraction ''.)'.~1 p ~-0;: $ i. eo , ~1 0 i:,. '(Tr,r")r1al has demons~rated that continued tri:;atment •_ ... -,,_'.lf i'-.,., p-rr-hl: ',1 '.".ively expensive with dno return for the money, 1r :~·-,J:d.i•Jat:~r ;\,1.-:.:•n~t".."rhz h~s demonstratfd that active 1.·emediatic>n haa :-•o~',.!~C~ the ~:!.ze c•-I th~ plume of cont~mination and will have iittle to n::; a!:lditic:--::"l?.l in:Eluer1ce on :reducing c(.jintaminant levels. Unoc'-1 has carrted out an excellent cleanup. Un~oal estimates that 9St of the l•:)EJt; petrvleum product has been recovt:red. This level of recovery ·.•.:;.'l'.'i'!"f"9Pr~,c; -f~:r ~bove. what we normally le.xpect to accomplish in terms of ' ··. _, •. ~~ '·✓ I -·I •.n ie-sp.:,n ~~ ln th~ concern expl'e:Ssed Ly thG attorney for the -;:-·~,~"'fH"'t n•.:n::n~:i'1 I 1'1rafted language whi¢h could appear as a par~ Of a -,;:,~i~,-,r.,'.'l wh:i ah wc-ulQ allow the Divisii:pn to reinvolve ·onocal should .,,, ·r ,l'"e r'"'"'h1 8'1'\'1~ h"" rli-<te~1ted, That laljlguage is aa follows: · "St--i~1 .ll".I p,.,.oblems develop at thisi site <18 a result of the lose of ,·,c-,, ,:,-:1,-m m b y !Jnocal Corporation, the ~ivision of Water Quality ,.,.,~:t"'P!~ ~h~ :eight to require Unocal forporation to undertake "'--1,:,,:r-.~r ,nr.1. 1nvest.iaatione and correct-ive action." -;I 'I _ S ctl-: vnoc£"1 and DH&S find this J,.janguage acceptable. As heai·ing .:::.. • '<""~!'" T f,~·,nti 1:h~t. the contaminanta remaining 1n the groundwater-at 41 ~~ '.0 -"'···\..· v.--..l'l~ 'In c'harlot.te do not en;~anger public health or safety, .,,.,..,.,::;t~ i ..,,r1:.., wi.'"'.h -;n.·oundwater standards:! cannot be achieved by ,;,9p 'l,1cat1 t•~. of the: best l'.vailable teqp.nology and would be '!.'·•.:-~i.~i~ c·•;.l~: -:-·x:;")Pr-•s1ve with no furt~~r bene:t:it being derived. :·n-~.n!; !~OC-'...12C':ir.g this va:r:I ance Unocal. asked that the reaul ts of ""!"> '.DP r:~rr l--~:r: ~1. J. 995 groundwater eampj'iing session. be su~stitu~ed fo'i.' .. -;; :~:!'.'0'-uJ.d".·~t~~· f-l !'"~f!di,,rds for the po~lutants under contndera~1on. I I~tt: 1~~t 9 ,:,, recc,m:oi~ncti:r.cr. One exceeda..i1ce of the substitute maximum l -•~ -~l l ,;;wable pollutant concentration woUjld throw the staff b~ck to i:=!':'fing 3. not1r<~ of violation. I wo\Wld prefer to use identifiable ,---.1·"-t}e:mi:, t--:, ti:-11 iw when to draw Unodja1 back into the investigation A,1 <l : el•~H1.;J at :..or: p::-oos as, ; ,I p . s .~ m ,· r·~c c,1 ;.!'•;ic,rJd&tion that: ; TJno :~~1 Corporation be gran~ed a 15A NC.AG 2L • 0113 variance ir~~ ~t ~ requirements of l~A NCAC 2L .0202{g) and ~s NCAC 2L 0inff{\ f or the 1.04 acre~ identified aa 4336 ParK Moad in r i-iip·-11".1rte. Norc.h Carolina .·i The apec1fic groundwater 'Jt~-~(:1~.::-d9 f".'Otll which Unooa.~ is obtaining relief are: NOTICE OF VARIANCE APPLICATION AND HEARING r DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES DIVISION OF WATER QUALITY Notice is hereby given of a variance application and public hearing to be held by the Department of Environment, Health and Natural Resources on behalf of the Environmental Management Commission. The hearing concerns a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and the Corrective Action requirements of 15A NCAC 2L .0106 G) for a site at 4336 Park Road in Charlotte, North Carolina. The Division of Water Quality refers to this site identified in the variance request as Groundwater Incident # 3633. This property, previously owned by the Unocal Corporation of Atlanta, Georgia, is now owned by the DH&S Company (Petro Express). The Unocal Corporation is entirely responsible for cleanup for Groundwater Incident # 3633. This variance application from the Unocal Corporation was received for review by the Department on September 29, 1995. The property where the release of petroleum product has occurred is located as follows: Inside the city limits of Charlotte, North Carolina. Take Interstate 85 to Interstate 77 south and travel four and one-half miles south on Interstate 77 and take the Woodlawn Road (City Highway 4) exit and travel east toward downtown Charlotte. This site at 4336 Park Road is located two miles east at the corner of Woodlawn Road and Park Road. This site is listed in Mecklenburg County tax records as Parcel Number 143-203-24. The Unocal Corporation requests that the Environmental Management Commission grant the following variance to its rules under the authority of 15A NCAC 2L .0113 so that it does the following: (1) Allow concentrations of Benzene, Toluene, Ethylbenzene, Xylene (-o,-m, and p), Naphthalene, Methyl Tert-Butyl Ether (MTBE), Isopropyl Ether, Ethylene Dibromide, 1,1-Dichloroethane, 1,1- Dichloroethene, 1,2-Dichloroethane, 1, 1, 1,-Trichloroethane, 1, 1,2,2,-Tetrachloroethane, 1, 1,2- Trichloroethane, 1,2-Dichloropropane, Bromodichloromethane, Bromoform, cis-1,3- Dichloropropene, Carbon Tetrachloride, Chloroform, Dibromochloromethane, Methylene Chloride, trans-1,3-Dichlorobenzene, 1,4-Dichlorobenzene, and Chlorobenzene to remain at levels above 15A NCAC 2L .0202 standards as analyzed in December 1995. These concentrations will be required to remain within the property boundaries of 4336 Park Road. The property at 4336 Park Road, for which the Unocal Corporation has cleanup responsibilities under Groundwater Incident Number 3633, consists of approximately 1.05 acres of land. The Unocal Corporation operated a retail gasoline station at this site from the 1950s to 1987. In 1987 the Unocal Corporation sold this property to DH&S Company. In 1988 this site was renovated and old tanks removed so that a new gasoline station, known as the Petro Express Gasoline Station # 7, could be built at this site. This property is located in an area with a mixture of commercial, industrial, and residential development. Almost all the land area at this site is covered by buildings and paved parking lots. 1 Pursuant to the transfer of property to the DH&S Company and the removal of the underground storage tanks at 4336 Park Road, the Unocal Corporation discovered a release of an unknown quantity of gasoline. A site assessment and corrective action plan for this site was submitted on March 18, 1993 and is kept on file at the Mooresville Regional Office. The site assessment revealed a plume of groundwater and soils contamination originating from free product gasoline near the south property line. The plume of substances that came from the release of gasoline was estimated to have covered an area of 61,250 square feet (1.406 acres), prior to the implementation of corrective actions. On August 12, 1993 the Unocal Corporation implemented cleanup at this site. The plan called for the implementation of a pump-and-treat groundwater cleanup system, an air sparging system for soils and subsurface materials, and soil vapor extraction. Pump-and-treat technology uses a pump to convey contaminated groundwaters from beneath the land, treats these groundwaters to remove contaminants, and returns the treated water to a permitted discharge. Air sparing relies on the introduction of air to separate volatile substances from subsurface materials. Soil vapor extraction uses suction to remove contaminants from soils. Use of soil vapor extraction is intended to reduce contaminant levels in soils without requiring the removal and treatment of soils offsite and the introduction of new or treated fill materials. The Charlotte-Mecklenburg Utility Department issued a permit to discharge treated water from the pump-and-treat groundwater remediation system into the nearby sanitary sewer. These cleanup technologies were in operation from August 12, 1993 through September 29, 1995. The Division of Water Quality required the Unocal Corporation to perform groundwater monitoring to determine the vertical and lateral extent of contamination. Since January 13, 1988 monitoring has been conducted at six on-site wells located at 4336 Park Road. Benzene was found in five of six on site monitoring wells on December 16, 1991. The highest concentration of Benzene found in a monitoring well, prior to implementation of groundwater cleanup, was 8.10 milligrams per liter found in Monitoring Well# 5 during the December 16, 1991 sampling event. The Groundwater Quality Standard for Benzene in ISA NCAC 21 .0202 is 0.0001 milligrams per liter. Concentrations of Ethylbenzene, Toluene, Xylene and Chloroform were also found in Monitoring Well # 5 significantly above the Groundwater Quality Standards in Title 15A NCAC 21 .0202. Monitoring well # 5 is located within 15 feet of the south property line and is located in the area in which the release of gasoline was discovered. On January 27, 1993 two additional monitoring wells were constructed off-site. A downgraidient monitoring well was located to the east at the Pop Shop (Parcel Number 175-181-06). Another off-site well was located to the south at Belle Investments (Parcel Number 171- 043-021). Analysis of groundwater samples from these two off-site wells have not shown concentrations of substances above the Groundwater Quality Standards in 1 SA NCAC 2L .0202 from the time these wells were installed in January 1993 through the December 1995 groundwater sampling. The Division also required Unocal Corporation to evaluate the effectiveness of groundwater cleanup efforts by examining concentrations of substances in recovery wells beginning December 16, 1991. Recovery wells at the 4336 Park Road site are used as sumps to collect groundwater, free product, and dissolved hydrocarbons from the site for treatment. Pumps convey this fluid to the treatment system. Samples were obtained from four recovery wells located beneath the parking lot and the area that formerly had the Unocal Corporation service station and pump islands. Since cleanup was initiated on August 12, 1993 significant reductions in concentrations of substances was observed in groundwater samples taken from the recovery wells . Results from 1994 demonstrated reductions in the concentrations of substances had occurred at this site since the implementation of cleanup. 2 From August 12. 1993 through September 13, 1994 the concentration of substances at this site were significantly reduced by groundwater cleanup technologies located at the site. Through 1995 analysis of samples from monitoring wells showed only marginal reductions in the concentration of substances in groundwater. Analysis of groundwater samples taken on February 23, 1995 and on June 2, 1995 showed there was no significant increase or decrease in concentrations of Benzene and other substances at on-site monitoring wells, while cleanup operations were being conducted. Except for Chloroform in Monitoring Well# 7 and 1,2-Dichloroethane in Monitoring Well# 9 at concentrations above the Groundwater Quality Standards, no other substances were reported in the other monitoring wells during this time. Based on groundwater analysis of samples from winter and summer monitoring events in 1995, the Division of Water Quality recommended that pump-and-treat, air sparging and soil vapor extraction technologies be turned off to determine if residual contaminants in the soils and subsurface would recontaminate the groundwater, if no treatment system were operating. In December 1995 groundwater monitoring was conducted at recovery wells and monitoring wells after the pump-and- treat system had been temporarily turned off. Only two of seven monitoring wells had concentrations of substances in exceedence of Groundwater Quality Standards in 15A NCAC 2L .0202. Monitoring well# 5 had Benzene at 0.00863 milligrams per liter, Ethylene Dibromide at 6.52 x 10-4 milligrams per liter, and 1,2-Dichloroethane at 0.00615 milligrams per liter. The maximum concentration of these substances allowed under the Groundwater Quality Standards pursuant to 15A NCAC 2L .0202 is as follows: Benzene at 0.0001 milligrams per liter, Ethylene Dibromide at 4.00 x 10-4 milligrams per liter, and 1,2-Dichloroethane at 0.0003 milligrams per liter. A sample from Monitoring Well# 9 showed 0.00447 milligrams per liter of 1,2-Dichloroethane. No substances were detected at Monitoring Well# 7 from the December 1, 1995 sampling event. Analysis of samples from the remaining monitoring wells reported Benzene, Chloroform, Ethylene Dibroniide, and 1,2- Dichloroethane at concentrations below quantitation limits. The downgradient monitoring well located offsite to the east at the Pop Shop and the monitoring well located to the south at Belle Investments have never shown concentrations of any substance above the groundwater Quality Standards in title 15A NCAC 2L .0202 (Groundwater Quality Standards). Concentrations of Benzene in all four recovery wells did not show a significant decrease or increase during December 1995. Samples from two of the four recovery wells continued to show levels of 1,2-Dichloroethane above Groundwater Quality Standards. The highest concentration of 1,2-Dichloroethane from a December 19, 1995 sampling event was 0.0197 milligrams per liter in Recovery Well# 4. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.0003 milligrams per liter. Monitoring wells at this site have shown insignificant reductions in Benzene as a result of using pump-and treat, air sparging, and soil vapor extraction technologies. Although concentrations of substances appear to be decreasing in recovery wells, significant reductions in the concentration of 1,2-Dichloroethane have not been observed in recovery wells. No significant increase in concentrations of substances was observed as a result of the temporary cessation of pump-and-treat operations. The Unocal Corporation has submitted supporting information showing that the variance will not endanger public health, safety, or the environment. No known sources of drinking water from water wells or surface water supplies are known to exist within a ½ mile radius of this property. Based on groundwater flow information obtained during the Comprehensive Site Assessment, it is believed that the contaminant plume is moving to the east. The Unocal Corporation has calculated the time it will take Benzene, Ethylbenzene and 1,2-Dichloroethane to reach Little Sugar Creek at 3 2) concJntration levels that would exceed Groundwater Quality Standards is between 93 and 280 years. Little Sugar Creek discharges into Sugar Creek which is a tributary of the Catawba River. All residents in the area are supplied drinking water from the City of Charlotte. Information provided by the Charlotte-Mecklenburg Utilities Department indicates that the public water supply lines in this area are at an average depth ofless than five feet from the ground surface. Groundwater occurs at 4336 Park Road at a depth of seventeen feet beneath the property. Water supply lines are not located deep enough in the ground to be impacted by this variance. Allow for the restoration of groundwater without requiring remedial actions in accordance with 15A NCAC 2L .01060). The Unocal Corporation has submitted supporting information demonstrating that the continued application of best available technology will not result in significant long term remediation of the site to the Groundwater Quality Standards contained in 15A NCAC 2L .0202. This is due to the high probability that continued remediation activities at the site will not significantly reduce contaminant levels below Groundwater Quality Standards in 15A NCAC 2L .0202. Since corrective actions were implemented on August 12, 1993 the Unocal Corporation has extracted a total of 3,050 pounds of petroleum hydrocarbons from contaminated soils and groundwater. The mass of petroleum extracted from soils and subsurface materials is approximately 3,000 pounds. The Unocal Corporation has treated an estimated 4.12 million gallons of groundwater via pump-and-treat technology which accounts for 50 pounds of material removed. The company reports that a total of $313,500 has been spent by the Unocal Corporation to cleanup the release described in Groundwater Incident # 3633. No claims for reimbursement through the state's Commercial Underground Storage Tank Trust Fund have ever been filed by the Unocal Corporation for funds spent on this site. The Unocal Corporation estimates that continued operation of the current groundwater and soil cleanup system over the next three years will be approximately $180,000. The Unocal Corporation has shown that when the operation of groundwater remediation systems at the site was temporarily interrupted, no increase in the concentration of any substance above groundwater standards was observed in off-site monitoring wells from monitoring data. The company asserts that marginal increases observed for some chemicals in two of the on-site monitoring wells, when the cleanup systems were not in operation, demonstrates that continued implementation of pump and treat, air sparging and soil vapor extraction will not result in a significant reduction in contaminant concentrations at this site. The Unocal Corporation has considered the use of air sparging as an alternate technology to the current groundwater remediation system. The company does not believe this technology is economically reasonable or practical to meet the requirements of ISA NCAC 2L .0l 13(c)(5). The estimated cost of implementing air sparging is approximately $45,000. The company asserts that continued reliance on air sparging is not economically justified due to the low residual concentrations of substances at this site with the lack of groundwater consumption by humans. 4 -2 - CONT.AMIN.ANT {CONTINUED) STANDARD {mg/1) {CONTINUED) ethylbenzene 0.029 ethyl dibromide (EDB; 1,2-4.0 X 10 -7 dibromoethane) isopropyl ether methylene chloride 0.005 (dichloromethane) methyl tert-butyl ether (MTBE) 0.2 napthalene 1,1,2,2 tetrachloroethane trans-1,3-dichlorobenzene 1,1,1-trichloroethane (methyl 0.2 chloroform) 1,1,2 trichloroethane xylenes (o-, m-, and p-) 0.53 Additionally Unocal is requesting a variance from 15A NCAC 2L.0106(j) which requires implementation of a Corrective Action Plan utilizing "best available technology for restoration of groundwater quality to the level of the standards." Beginning in the 1950's Unocal Corporation operated a convenience store at 4336 Park Road in Charlotte, North Carolina. This piece of property is located at the heavily developed intersection of Park and Woodlawn Roads in south Charlotte. The property is 1.05 acres in size and is identified on the Mecklenburg County tax maps as parcel number 149-203-24. In 1988 following sale of the property to DH&S associates Unocal removed the gasoline underground storage tanks (USTs) and discovered the presence of free product and soil and groundwater contamination. The free product was immediately removed. Following issuance of a Notice of Violation (NOV) Unocal developed a Comprehensive Site Assessment (CSA) and Corrective Action Plan (CAP) for the site. At time of preparation of the CSA moving groundwater had transported contaminants slightly off property. The CAP called for the sequential activation of a pump and treat system, a soil vapor extraction system and an air sparging system. Unocal installed and operated these various systems which were effective in remediation. Based upon groundwater sampling spanning the period of time January, 1988 until June, 1995 significant reductions in pollutant concentrations were achieved by utilization of these cleanup technologies. Most pollutants previously detectedable, had been -3 - reduced to below detection limits or to below groundwater standards. In June of 1995, responding to the recommendation of staff of the Division of Water Quality, Unocal shutdown its treatment facilities to determine the effect of such action on groundwater quality. No increase in contaminants was observed indicating that the remediation systems had achieved all that could reasonably be expected. Only four out of eleven groundwater monitoring wells were then showing contaminant levels in excess of the 2L standards. Authority of the North Carolina Environmental Management Commission to grant a variance to the groundwater standards is found in NCGS 143-215.3(e). In order to grant a variance, the commission must find that the contaminants in questions do not endanger human health or safety and compliance with the standards "cannot be achieved by application of the best available technology found to be economically reasonable" and "would produce serious hardship without equal or greater benefits to the public." Four people registered at the hearing. They were Bobby Cobb, Mecklenburg County Health Department; Stewart Hines, S&ME, consultant to Unocal; Holmes Eleazer, attorney to DHS Associates; and Douglas P. Drew, vice president, DHS Associates. Unocal's consultant, spoke in favor of granting the variance. Holmes Eleazer, attorney to DHS Associates expressed qualified opposition to the variance out of concern that DHS borrowed money using the Park Road property as collateral on the basis that Unocal would clean up the soil and groundwater to the state's satisfaction. He felt that issuance of a variance might cause the involved lending institution to question that the value of its collateral was impaired and call the loan. DHS is also concerned whether issuance of a variance might relieve Unocal of responsibility to the point that should future problems develop· relating to the loss of product by Unocal, the Division of Water Quality might not be able to reinvolve Unocal in investigations and cleanups. Mr. Eleazer went on to say that DH&S would not oppose the variance if it were worded in such a way that Unocal could be drawn back in should unforeseen problems develop. The former 1.05 acre Unocal property at 4336 Park Road in south Charlotte is located in a densely developed area. This part of Charlotte is served by the Charlotte Mecklenburg Utility District therefore no one in the immediate area is making potable use of groundwater. Investigation indicates that the nearest well drawing water for drinking purposes is more than 1500 feet from 4336 Park Road. There are no reports of petroleum vapors, either confined or unconfined as a result of Unocal's loss of product. The nearest surface water which would be a receptor for the contaminated groundwater is Little Sugar Creek which is 1,400 feet to the east and bears a Class "C" classification. Time required for the contaminants to reach Little Sugar Creek are estimated to be from 93 to 280 years. Unocal, following discovery of evidence of product loss at time of tank removal in 1988; has recovered free product, removed contaminated soil, prepared a CSA and a CAP, installed and operated a groundwater pump -4 - and treat system, installed and operated a vacuum extraction system, installed and operated an air sparging system, drilled monitoring wells and conducted extensive soil and groundwater monitoring. Approximately 3,050 pounds of petroleum hydrocarbons have been recovered at a total cost of $579,995. All this at a site which is non revenue producing as far as Unocal is concerned since the property was sold in 1987. Additionally this clean-up was carried out without assistance from the state trust fund because the loss was discovered before June 30, 1988. The company estimates that the three-year cost of operating pump and treat, air sparging and soil vapor extraction would be $180,000. Unocal has demonstrated that continued treatment would be prohibitively expensive with no return for the money. Groundwater monitoring has demonstrated that active remediation has reduced the size of the plume of contamination and will have little to no additional influence on reducing contaminant levels. Unocal has carried out an excellent cleanup. Unocal estimates that 95% of the lost petroleum product has been recovered. This level of recovery represents far above what we normally expect to accomplish in terms of recovery. In response to the concern expressed by the attorney for the present owners I drafted language which could appear as a part of a variance which would allow the Division to reinvolve Unocal should future problems be detected. That language is as follows: "Should problems develop at this site as a result of the loss of petroleum by Unocal Corporation, the Division of Water Quality reserves the right to require Unocal Corporation to undertake additional investigations and corrective action." Both Unocal and DH&S find this language acceptable. As hearing officer, I found that the contaminants remaining in the groundwater at 4336 Park Road in Charlotte do not endanger public health or safety, compliance with groundwater standards cannot be achieved by application of the best available technology and would be prohibitively expensive with no further benefit being derived. When requesting this variance Unocal asked that the results of the December 1, 1995 groundwater sampling session be substituted for the groundwater standards for the pollutants under consideration. I am not so recommending. One exceedance of the substitute maximum allowable pollutant concentration would throw the staff back to issuing a notice of violation. I would prefer to use identifiable problems to tell us when to draw Unocal back into the investigation and remediation process. It is my recommendation that: (1) Unocal Corporation be granted a 15A NCAC 2L .0113 variance from the requirements of 15A NCAC 2L .0202(g) and 15 NCAC 2L .0106(j) for the 1.04 acres identified as 4336 Park Road in Charlotte, North Carolina. The specific groundwater standards from which Unocal is obtaining relief are: -5 - CONTAMINANT STANDARD (mg/1) benzene 0.001 bromodichlorornethane bromoforrn (tribrornomethane) 0.00019 carbon tetrachloride 0.0003 chlorobenzene 0.05 Chloroform (trichloromethane) 0.00019 cis-1,3-dichloropropene dibrornochlorornethane 1,1 dichloroethane 0.07 1,1 dichloroethene . 1,2-dichloroethane (ethylene 0.00038 dichloride) 1,4-dichlorobenzene 1,2-dichloropropane 0.00056 ethylbenzene 0.029 ethyl dibrotnide (EDB; 1,2-4.0 X 10 -7 dibromoethane} isopropyl ether methylene chloride 0.005 (dichloromethane) methyl tert-butyl ether (MTBE) 0.2 napthalene 1,1,2,2 tetrachloroethane trans-1,3-dichlorobenzene 1,1,1-trichloroethane (methyl 0.2 chloroform) 1,1,2 trichloroethane xylenes (o-,m-, and p-) 0.53 Mr. David Hance ) December 6, 1996 Page 2 The facilities located at these sites were old, some dating back to the 1960's. As a condition to the purchase, DHS secured Unocal's agreement to remediate any contamination existing at the sites as of the sale date. (See letter of August 24, 1987, attached to Exhibit A.) DHS' business plan was to raze the old facilities as finances permitted and construct new retail units to be leased to Petro Express, Inc., an operating company in which the partner/members were shareholders. The construction of new facilities included removal of existing underground storage tanks, supply lines and pumps and replacement with new equipment that meet or exceeded the 1988 standards promulgated by DEHNR ("Department") for tanks and delivery systems. Tests performed by Unocal at each of the six sites showed the presence of petroleum and petroleum by-product contaminants in varying degrees in the soil and groundwater at all six sites. As construction proceeded ,at each site, Unocal reported the contamination to the Department, undertook site assessments, formulated and then implemented corrective action plans. In order to rebuild at the sites, DHS borrowed construction funds from banking inst~tutions operating in the Charlotte market. As time passed, some of the sites were re- financed to provide DHS funds to secure and build additional retail sites. In each loan transaction, DHS disclosed to the lender the existence of contamination and Unocal' s acknowledgement of responsibility therefore and Unocal's efforts to assess the extent of the prog.Iems and to remediate them. As you are aware, the Department's compliance procedures for assessing the extent of soil and, particularly, groundwater contamination and then developing and implementing appropriate remediation measures can take substantial time. The process was in varying stages at each of the six sites at any given time when DHS was approaching lenders for financing at the sites. DHS' lenders, on notice of the existence of contamination, obviously were concerned with the contamination situations at the sites. On November 1, 1991, DHS and Unocal entered into a remediation agreement applicable to five sites. (One of the original six was transferred to the McDonald's Corporation.) A copy of the Agreement is attached as Exhibit A. With respect to the subject party, 4336 Park Road, DHS refinanced the property with Branch Banking and Trust Company ("BB&T'') in December of 1993. The loan amount was Eight Hundred Fifty Thousand Dollars ($850,000.00). Copies of the Loan Agreement, Deed G:\DOCS\LHE\OGL TR\65064.1 Mr. David Hance December 6, 1996 Page 4 are protected not only by the U.S. Constitution but by the North Carolina Constitution. Whole bodies of law both case law and statutory law have developed in this State since the Revolution protecting the use and development of private property and the regulation and financing of commerce. DHS, in purchasing the subject property from Unocal, has incurred substantial liability with its lender in reliance on Unocal's agreement "to implement and perform, at its own expense and for such time as necessary, such remediation measures required by the appropriate government authorities until such time as the appropriate government agencies certify or otherwise agree that the contamination has been remedied as required by law. " (Exhibit A, paragraph 2, page 2.) This is an obligation freely m;idertaken by Unocal to induce DHS to purchase from it the subject property. It is also an obligation that directly benefits the public health, welfare and safety of the citizens of Mecklenburg County. The variance request seeks to absolve Unocal from remedying the contamination as required by law. Unocal is asking you to permit non-compliance. This situation is exacerbated by the fact that DHS, in reliance on Unocal's agreement · .to achieve compliance as required by law, has obligated itself with BB&T to achieve compliance or pay to BB&T by way of indemnity any loss or damage incurred by BB&T that res~ts from non-compliance. (See the highlighted portion of the Deed of Trust, Exhibit C.) Indeed, if BB&T deems its collateral (the value of the subject property) to be impaired, it can call the loan and foreclose on the property. @.) Thus, DHS' financial viability could be destroyed by the variance if BB&T determines that the value of the subject property is adversely impacted by a ruling that permits non-compliance in perpetuity. DHS' dilemma is this. DHS, who is not the responsible party, can be forced by its lender to pick up where Unocal wants to leave off and continue to spend remediation costs that it is far less able to bear financially than Unocal. If DHS cannot shoulder the cost, the BB&t has permanently contaminated property as collateral instead of property which is "being remediated." Then the bank must decide whether and how to enforce its rights to maximize the value of the property. With the horns of the dilemma thus defined, what is meaningfully realistic and practical can be considered. One alternative is simply to deny the variance. Denial would n to produce "serious financial hardship" on a company with the financial resources and not G:IDOCSILHE\OGLTR\65064.1 Mr. David Hance December 6, 1996 Page 5 worth of Unocal. However, such a decision does not seem to be an efficient allocation of resources. There really appears to be no immediate threat to public safety given the fact that drinking water supplies for nearby residents are not impacted. A cost-benefit analysis of continued application of the technologies used at the site indicates non-economic return for the costs that would be incurred. A second alternative would be to grant the variance. This is centra-indicated because of the adverse impact it would have on DHS. This adverse impact should not be discounted by the Department. No one knows the financial market and the real estate market will react to the granting of variances by the Department. It is our understanding that the present request is one of the first to come before the Department. Granting the variance will be ,a tacit acknowledgment by the Department that no technology exists that will result in compliance with the groundwater standards. That will open the flood gates of variance requests to the Department. Many of those will be by applicants with less financial resources that Unocal, thus intensifying the pressure on the Department to grant more and more variances until the groundwater standards are submerged in tp.e exceptions. The Department and DHS could expect four more such requests in short order from Unocal on the other former Unocal sites if this one is granted. Moreover, and equally compelling for your deliberations, is the fact that envtronmental indemnifications of purchasers and lenders on contaminated property are now well ensconced in commercial transactions. Granting variances will spawn substantial litigation as responsible parties seek to avoid the compliance they agreed to attain and indemnities seek to keep them in the loop. The costs involved in that kind of litigation are as inefficient and deleterious an allocation of financial resources as continued use of ineffective remediation technology. A third alternative is simply to permit a cessation of remediation technologies when the Department finds some of the factors indicated in 15A NCAC 2L.0113. This could be done in a variance application context but could be achieved with or without the granting of a variance. Without granting a variance, the Department could enter a ruling that the approved remediation measures in place at a site could he temporarily suspended. The Department clearly has this authority. It has done this on a general basis under the new categorization procedure implemented this summer. The advantage of this approach is that responsible G:IOOCS\LHEIOGL TR\65064.1 Mr. David Hance December 6, 1996 Page 6 parties would stay in the loop without having to expend money on technology applications that are no longer effective. The groundwater standards are not dilutedunder a tide of variance requests. As new and better technologies arise they could be put in place to achieve the purity standards required by law. Conversely, if the groundwater standards are revised in the future, closure could occur then without the need for a variance. A second approach would be to grant a conditional or temporary variance. For example, a variance could be granted for a period of time on condition that it would be reviewed at the end of the stated period. Monitoring could be included in such a conditional variance. If the level of contaminants remains static or decreases, the conditional variance could be renewed. If contamination increased, further remediation could be ordered. This approach has the advantages of keeping the responsible party in the loop but letting it avoid non-productive costs. It would also permit the later introduction of new technologies as they arise and allow for the possible revision of groundwater standards without diluting those presently in the books that guide the Department's efforts. _ Whether a conditional variance is within the Department's authority is a question for the Secretary and the Attorney General. The factor that recommends either of the approaches under the third alternative is that ackl}.owledged responsible parties avoid substantial, unproductive outlays but remain responsible for clean-up of the contamination they caused. That is a substantial advantage for them, while preserving the benefit to the public that underpins the environmental laws. Responsible parties, obviously desire finality and closure, but everybody in the remediation business knows that caring contamination is a lengthy endeavor. Responsible parties may be entitled to some financial relief in the appropriate circumstances. But they should not be permitted to shift their burden to others in the guise of cost-benefit analysis. Their closure should come when they achieve compliance by new technologies or the adoption of revised standards. A permanent variance, which is Department approval of non-compliance, should be reserved only for the most compelling circumstances. IV. Conclusion: For the reasons set forth above, DHS objects to the variance request of Unocal. Also, for the reasons stated above, DHS qualifies its objections. It would not object to a ruling by the Department under which Unocal could avoid costs deemed excessive or G:IDOCS\LHEIOGL TR\65064.1 .. Mr. David Hance December 6, 1996 Page 7 unreasonable by the Department but which retains Unocal as the responsible party. It is DHS' understanding that Unocal's variance request proposed that Unocal monitor the subject property for a further period of two years. DHS urges the Department to view this proposal with care, caution and some healthy skepticism. The variance requested permits permanent non-compliance with applicable groundwater standards. Nothing in the variance request requires or obligates Unocal to do anything but monitor. There is no requirement or undertaking for Unocal to resume remediation if contaminant levels or circumstances change in that two-year period. If Unocal's request is granted, it will be the final word on its remediation responsibilities. The monitoring wells are approximately 100 feet apart from one another. It is DHS' recollection that at the hearing, the SM&E representative stated groundwater flow at the site to be five to twelve feet per year. Thus, substantially higher contaminant concentrations could potentially exist due to subsurface soil conditions that might not show up during the two-year period. Unocal is the responsible party. But a variance with only a two-year monitoring tail would shift any clean-up burden off Unocal's shoulders to DHS. . This is an onerous burden and hardship not contemplated by the parties in their dealings with one another, nor by the UST statutes and regulations once a party, such as Unocal, acknowledges responsibility for the conditions. Respectfully submitted this the (p 'ti day of December, 1996. L. Holmes Elea.zer,i: r / ODOM & GROVES, P.C. 1100 South Tryon Street Charlotte, North Carolina 28203 (704) 372-4800 Counsel for DHS Associates, LLC G:IDOCS\LHEIOGL TR\65064.1 ... STATE OF NORTH CAROLINA COUNTY OF MECKLENBURG AGREEMENT CONCERNlNG REMEDIATION OF CONTAMINATION AT CERTAIN FUEL STATION SITES SOLD TOD. H. & S ASSOCIATES This Agreement is made effective as of November 1, 1991, by and between Union Oil Company cf California, doing business as UNOCAL ("Unocal") and D.H.& S. Associates ("DH&S) a North Carolina General Partnership. WITNESSETH WHEREAS on or about December 5, 1986, DH&S purchased from Unocal five filling station properties in Mecklenburg County, North Carolina, more particularly described in Exhibits A-1 through A-6 attached hereto and incorporated herein by reference; and, WHEREAS the said properties sold by Unocal toDH&S were to be leased by DH&S to operators of service stations or service station/convenience stores which purpose was known by Unocal at the time of the sale; and, WHEREAS prior to the operating of said properties by the lessees of DH&S and in preparation therefore, petroleum and petroleum by-product contamination of soil and grounifwater at the properties was discovered and duly reported to the environmental authorities as required by law; and WHEREAS by letter dated August 24, 1987, Unocal acknowledge responsibility for said contamination; s~id-letter attached as Exhibit"B;· and, . . . . WHEREAS Unocal has undertaken, · at its own expense, to assess the _extent of contamination and implement remedial action to abate said contamination at the properties as may be required by the ·government agencies exercising jurisdiction over remediation of such contamination; and, WHEREAS pursuant to its undertaking, Unocal has and is presently causing the extent of contamination to be assessed and is developing or causing to be developed remedial action plans to abate said contamination at the properties for approval by the appropriate government agencies and then implementation by Unocal. Since this process of remediation takes place over an extended period of time, the parties desire to set out, by further agreement, the responsibilities undertaken with aspect to said contamination. IT IS HEREBY AGREED AS FOLLOWS: 1. Unocal hereby reaffirms its acknowledgement of responsibility for petroleum and petroleum by-product contamination as of December 5, 1986, atthe properties sold to DH&S and identified in Exhibits A-1 through A-6. 2. Unocal reaffirms its undertaking and agrees to continue, at is own expense, the inve~tigation and assessment of contamination already underway at the properties; to formulate or cause to be formulated after completion of investigation and assessment, at its own expense, such remedial action plans as may be required by the government agencies with jurisdiction over said contamination; to negotiate and secure or cause to be negotiated and secured, at its own expense, approval of said remediation measures and remediation action plans with the appropriate governmental agencies; and to implement and perform, at its own expense and for such time as necessary, such remediation measures required by the appropriate government authorities until such time as the appropriate government agencies certify or otherwise agree that the contamination has been remedied as required by law. - 3. Unocal expressly agrees to indemnify and hold harmless DH&S, its heirs, successors or assigns and DH&S' principals, Kenneth Daniel Shaver, Jr., Thomas J. Hall, and Douglas P. Drew and their heirs, successors and assigns: a. against and from all claims, loss, cost, damage, liens or expense arising out of or from petroleum or petroleum by-product contamination existing at the properties identified in Exhibits A-1 through A-6 as of December 5, 1986; b. against and from any fine, penalty, sanction, damage, or charges imposed for any violations of any law, ordinance or regulation arising out of said petroleum or petroleum by-product contamination at the properties listed in Exhibits A-1 thr(?ugh A-6; and~ c. against and from any and all claims, loss, cost, damage, liens or expense arising out of any failure of Unocal to comply with and perform all the provisions and undertakings of this Agreement. Unocal further indemnifies DH&S for and agrees to pay any legal fees and legal costs incurred by DH&S in defending against any claim covered by this indemnity prov1s1on. 4. Because of the long period of time needed, including continuing monitoring and assessment, to achieve remediation, the parties expressly agree that, in the event of breach of this agreement, specific performance shall be an available remedy _ together with and not exclusive of any other remedies provided in law or equity. EXHIBIT A-1 Unocal ID Prooert y #57-9342-115 4500 Randolph Road, Charlotte, NC (See Ex. A-2) #57-9342-116 John & Trade Streets, M:_atthews, NC (See Ex. A-3) #57-9342-121 5340 Monroe Road, Charlotte, NC (See Ex. A-4) #57-9342-209 4336 Park Road, Charlotte, NC (See Ex. A-5) #57-9342-212 6500 Fairview Road, Charlotte, NC (See Ex. A-6) EXHIBIT A-2 Leoal Descriotion--Randoloh Road Prooerty: Being a11 · that certain tract or parcel of land lying, being and situate in the City of Charlotte, County of Mecklenburg, and State of North Carolina, and being more particularly described as follows: BEGINNING at an iron located in the westerly right-of-way margin of Randolph Road, said iron being the northeasterly corner of the property conveyed to Kiser Foundation by deed recorded in Book 5140 at Page 373 in the Mecklenburg County Public Registry; thence with the Kiser Foundation (now or formerly) South 74-15 West 124.86 feet to an iron in the line of John T Belk, Jr. (now or formerly); thence with the line·· of John T. Belk, Jr. (now or formerly) North 15-44-15.West 165.00 feet to a point in the southerly right-of-way margin of Sha.ran Amity Road; thence with the southerly right-of-way margin of Sharon Amit"y Road North 74-15 East .. 96.42 feet to a point; thence continuing with the southerly right-of-way margin of Sharon Amity Road and the westerly right 6t~way margin of Randolph Road, and following the arc of a circular curve to the right having a radius of 26.00 feet an arc distance of 40.84 feet to a point in the westerly right-of-way margin of Randolph Road; thence with the westerly right-of-way margin of Randolph Road (1) following the arc of a circular curve to the right having a radius of 642.00 feet an arc distance of 60.16 feet to a point, and (2) South 15-32 East 78.92 feet to the point and place of BEGINNING, as shown on that certain plat entitled "Property of D.H.& s. Associates" dated November 3, 1986, prepared by Robert A. Burns, Registered Land Surveyor. TOGETHER WITH AND INCLUDING all of Grantor's right, title and interest in and to any property lying within the rights-of-way of Sharon Amity Road and Randolph Road. Being a portion of the property conveyed to the Pure Oil Company by deed of Mary I. Randolph, et .s.1-, dated June 7, 1956 and recorded in Book 1860 at Page 398 in the Mecklenburg County Public Registry. Union Oil Company of California is successor by merger to the Pure Oil Company. Reference is made to that certain Affidavit and the attached Certificate of the Secretary of State of California filed July a, 1966 and recorded in Book 2766 at Page 263 in said Registry. Reference is further made to that certain deed to the City of Charlotte recorded in Book 2723 at Page 1 and that certain Consent Judgment recorded in Book 3891 at Page 568, both in the Mecklenburg County Public Registry. EXHIBIT A-3 Le g al Descrintion--Matthews Proner.t v : Being all that certain tract or parcel of land lying, being and situate in the Town of Matthews, County of Mecklenburg, and State of North Carolina, and being more par~icularly described as follows: BEGINNING at an iron located at the intersection of the southeasterly right-of-way margin of South Trade Street and the southwesterly right-of-way margin of John Street; thence from said beginning point with the southwesterly right-of-way margin of John Street South 52-26-30 East 200.00 feet to a point; thence South 38-00 West 140.00 feet to an iron; thence North 52-26-30 West 200.00 feet to a point in the southeasterly right-of-way margin of South Trade Street; thence with the southeasterly right-of-way margin of South Trade Street North 38-00 East 140.00 feet to the point and place of BEGINNING, as shown on that certain plat entitled "Property of D.H.& s~ Associates" dated November 10, 1986, prepared by Robert-A Burns, Registered Land Surveyor. TOGETHER WITH AND INCLUDING all of Granter.' s right, title and interest in and to any lands lying within the rights-of-way of John Street and South Trade Street. Being a portion of the property conveyed to Union Oil Company of California by deed of Sixty-Eight Scarteen Corporation dated February 28, 1979 and recorded in Book 4167 at Page 956 in the Meckle~burg County Public Registry. ·- EXHIBIT A-4 Legal Descriotion--Monroe Road Prooertv: Being all that certain tract or parcel of land lying, being and situate in the City of Charlotte, Coun_ty of Mecklenbur·g, and State of North Carolina, and being more paific~larly described as follows: BEGINNING at a nail in the northwesterly right-of-way margin of Sharon Amity Road,'said nail being located in the easterly corner of the property conveyed to William E. Borroughs by deed recorded in Book 4167 at Page 902 in the Mecklenburg County Public Registry; thence from said beginning point with the line of William E. Borroughs (now or formerly) North 61-59-22 West 126.76 feet to a point in the dividing lines between Lots 5 and 6 in Block 2 of Summey Heights as,shown on a map thereof recorded in Map Book 3 at Page 134 in the Mecklenburg County Public Registry; thence with said dividing line North 24-28-01 East 191.27 feet to an iron in the southwesterly right-of-way margin of Monroe Road; thence with the southwesterly right-of-way margin of Monroe Road South 57-49-35 East 124.57 feet to a point; thence continuing with the southwesterly right-of-way margin of Monroe Road and the northwesterly right-of-way margin o-f Sharon Amity Road, and following the arc of a circular curve to.the right having a radius of 15.00 feet, an arc distance of 22.51 feet to a point in the northwesterly right-of-way margin of Sharon Amity Road; thence with t~e northwesterly right-of-way margin of Sharon Amity Road (1) South 28-10-01 West 149.29 feet to a point, and (2) South 25-18-16 West 17.60 feet to the point and place of BEGINNING, as shown on that plat of survey entitled "Property of D.H.& $. Associates" dated November 10, 1986, prepared by Robert A: Burns, Registered Land Surveyor. TOGETHER WITH AND INCLUDING all of Grantor"s right, title and interest in and to any property lying within the rights-of-way of Monroe Road and Sharon Amity Road. The above~described property is a portion of Lots 6 and 7 in Block 2 of SUMMEY HEIGHTS as shown on a map thereof recorded in Map Book 3 at Page 134 in the Mecklenburg County, North Carolina, Public Registry. Being a portion of the property conveyed to Union Oil Company of California by deed of Scarteen Corporation dated July 8, 1977 and recorded in Book 3967 at Page 191 in said Registry. EXHIBIT A-5 Leoal Descriotion--Park Road Prooertv: Being all that certain tract or parcel of land lying, being and situate in the City of Charlotte, County of Mecklenburg, and State of North Carolina, and being more particularly described as follows: BEGINNING·at an iron in the westerly right-of-way margin of Park Road, said iron being located in the dividing line between Lots 2 and 3 of t~e property of David Alexander as shown on a plat thereof recorded in Map Book 1438 at Page 490 in the Mecklenburg County Public Registry, said iron being located South 83-37-30 East, approximately 30.67 feet from the common front corner of Lots 2 and 3, as shown on said map; thence with the westerly right-of-way margin of Park:Road South 04-04-38 East 133.84 feet to a point (see map recorded in Book 2757 at Page 534 in said Registry); thence with the westerly right-of-way margin of Park Road and the northerly right-of-way margin of Woodlawn Road and following the arc of a circular curve to the right having a radius of 30.00 feet an arc distance of 53.40 feet to a point in the westerly right-of-way margin of Woodlawn Road; thence with the weste~ly right-of-way margin of Woodlawn Road (1) North 84-44-23 West 124.89 feet to a point, and (2) North 87-36-13 West 105.42 feet to an iron; thence North 06-00 East 82.54 feet to a point; thence North 04-37-50 West 97.41 feet to an iron; thence South 83-37~30 East 253.52 feet to the point and place of BEGINNING, said fract being shown on that certain plat entitled nProperty of D.H.& S. Associates" dated November 12, 1986 prepared by Robert A. Burns, Registered Land Surveyor. TOGETHER WITH AND INCLUDING all of the area within the rights-of-way ~of Park Road and Woodlawn Road acquired by Union Oil Company of California by deed recorded in Book 2828 at Page 311 and by the Pure Oil Company by deed recorded in Book 2038 at Page 329, both in the Mecklenburg County Public Registry. · Being in all respects the same property conveyed to the Pure Oil Company by deed recorded in Book 2038 at Page 329 and to Union Oil Company of California by deed recorded in Book 2828 at Page 311 in the Mecklenburg County Public Registry, subject, however, to that certain right-of-way deed to the City of Charlotte recorded in Book 2757 at Page 531 in said Registry. Reference is made to that certain Affidavit recorded in Book 2766 at Page 263 in said Registry. EXHIBIT A-6 Leaal Descriotion--Fairview-Road Prooerty Being all that certain tract or parcel of land lying, being and situate in the City of Charlotte, County of Mecklenburg, and State of North Carolina, and being more particularly described as follows: BEGINNING at an iron in the southwesterly right-of-way margin of Fairview Road, said iron being a corner of the property conveyed to Center Properties, by deed record~d in"Book.4260 at Page 872 in said Registry, and also being in the northwesterly margin of that certain right-of-way granted to Pure Oil Company by instrument recorded in Book 2469 at Page 505 in said Registry; thence with the line of Center Properties (now or formerly) four (4) courses and distances as follows (1) South 24-15 West 67.65 feet to an iron; (2) South 60-41-30 West 150.00 feet to an iron; (3) North 77-11-34 West 139.79 feet to a point; {4) North 12-30-20 East 237.54 feet to a point in the southwesterly right-of-way margin of Fairview Road; thence continuing North 12-30-20 East 43.62 feet to a point in the original centerline of Fairview Road; thence with the original centerline of Fairview Road (1) South 61-50 East 266.68 feet to a point, and· l2) South 67-42 East 100.00 feet to a point; thence South 60-41-30 West 38.28 feet to a point; thence in a southwesterly direction following the arc of a circular curve to the right having a radius of 1,138.98 feet an arc distance of 60.00 feet to a point; thence South 24-15 West 12.00 feet to the point and place of BEGINNING, as shown on that certain plat entitled "Property of D.H.& s. Associates" dated November 23, 1986, ~repared by Robert A. Burns, Registered Land Surveyor. TOGETHER WITH a perpetual right-of-way and easement for ingress, egress and regress to and from the property hereinabove described into aod over the following strip of land 30 feet in width located in the.City of Charlotte, County of Mecklenburg and State of North Carolina, and being more particularly described as follows: BEGINNING at an iron in the southwesterly right-of-way margin of Fairview Road, said iron being the beginning point of the property · hereinabove described; thence from said beginning point South 24-15 West 67.65 feet to an iron; thence South 60-41-30 West 65.00 feet to a point; thence South 29-18-30 East 30.00 feet to a point; thence North 60-41-30 East 74.84 feet to a point; thence North 24-15 East 89.80 feet.to a point within the right-of-way margin of Fairview Road; thence in a southwesterly direction following the arc of a circular curve to the right have a radius of 1,138.98 feet an arc distance of 30.00 feet to a point; thence South 24-15 West 12.00 feet to the point and place of BEGINNING, as shown on that certain plat entitled "Property of D.H.& S. Associates" dated November 23, 1986, prepared by Robert A. Burns, Registered Land Surveyor. Being in all respects the same property conveyed to Union Oil ,company of California by deed of Burtis Corporation dated August 5, 1977 and recorded in Book 4000 at Page 508 in the Mecklenburg County Public Registry. PARTNERSHIP ACKNOWLEDGEMENT STATE OF NORTH CAROLINA ) ) COUNTY OF MECKLENBURG ) I, ---K ....... p...._._t_._h......,~-..J.../-{.,_,.---'--N--"---""'-o ,_,/ e""'-'-'rf'-----' a_-~ o t ~ ry Pub 1 i c , do hereby certify that Kenneth D. Shaver, Jr., Douglas P. Drew and Thomas J. Hall, being all of the partners in D.H.& S. ASSOCIATES, personally appeared before me this day and acknowledged the due execution of the foregoing instrument on behalf of D.H.& S. ASSOCIATES. Witness my hand and official seal this _!j___ day 0 f DJ_ µ_/'Ot,Ly/l,) I 19 91 • My commission expires: ,7. "h.n..luu tf ;qqs-1 J I KaJ:i-ud ff. f?,w(,A) (SEAL) Notary Publ/4 c in and for Mecklenburg County, NC ,;;·;.,..::.dliLil\ ••••••••••··• TI1e Uormwer covenants am.I agre•s that from the date her<of umil payment in full of all indcbtcJnc» and lhe performance of all ohliga1ions under the Loan Documents, the Borrower •hall al all times maintain lhe following financial position and ratios all in accordance with GAAP unless olherwi•e •pccilied: O 4 .01. Current Raliu. A ratio of total cum:nt asset> to 101al current liabilities of not less than ______ to ______ . O 4.02. Quick Ratio. A raliu of lhe tolal of cash plus readily marke1ablc United Stales securilies plus comm,rcial paper ra1c,d A-1 by S1andanl and Pours Corporation plus 1ra,k accounts receivable not mor• than _________ ( ) day• p.t•t du• tu total cum,111 liabilities nf nut less than _________ 10 ________ _ D 4 .03. Working Capilld. The different< between 101al current assets and total current liabilities shall not be less than $ ________ _ 1X1 4 .04. Tangible Net Wurth. A minimum tangible net wonh of not less than S SEE ATIACHED SCHEDULE D 4 .05. Debt To Worth. A ratio of total liabilities to tangible net worth of not grea1er 1han _________ to ________ _ D 4 .06. Cash Flow Margin. A margin of Net Income after taxes plus depreciation plus amortization less all long-term debl payments (excluding interest) due within the next twelse I 12) months nf al least S _________ . This ratio will be calculated based on the fiscal year-end financial statemems. Oil 4 .07. Capital Expendilures Limitation. Expendilures for fixed assets in any fiscal year •hall not exceed in the aggregale the >Um of$ SEE A'!"!ACHED without the prior wriucn consent of the Bank. SCHEDULE □ 4 .08. Other. Such other financial covenants listed on Schedule" _________ " hereto. Seclion 5 Ncgali,·e Co•enants The Borrower covenants and agrees that from the date hereof and until payment in full of all indebtedness and perfom1ance of all obligations under the Luan Documents, the Borrower shall not, without the prior wrinen consent of the Bank: 5.111 . l.iellli. Creale, im:ur, a.ssunte, or suffer to exist any lien upon or with respect tu uny uf its propcnies, now owned ur hcrc:ifler ac,,uircd, except: (a) Liens in favor of lhe Bank; (b) Liens fort.axes not yel due and payable or otherwise being contested in good faith and for which appropriate reserses ar.: maintained; (c) Other liens imposed by law not yet due and payable, or otherwise being contested in good faith and for which appropriate reser.cs arc maintained; (d) Liens on _____________________ securing an obliga1ion to ___________________ _ not lo exceed S ___________ , or described on Schedule" _______ .. hereto. (e) Purchase: Muney Liens on any property hcreafler acquired, provided 1hat such lien shall auach only to the propeny acquired. 5.02. Debi. Create, incur, assume, or suffer 10 exist any debl, except: (a) Debt to the Bank; (b) Debt presently ou1s1anding and shown on the most recent financial statements submilled to the Bank; (c) Accounts payable to trade creditors incurred in the ordinary course of business; (d) Debt secured by purchase money liens as outlined above in Section 5.01. (c); (e) Additional debt nol 10 exceed$ ________ _ 5.03. Mergers_ Merge or consolidate with or sell, assign, lease, or 01herwise dispose of all ur substantially all of its assets to any person, or acquire all or substantially all of the asscls or the business of any person. 5 .™. Leases. Crealc, incur, assume, or suffer to exist any leases, except: (al Leases prescn1ly outstanding and showing on the most recent financial sta1en1ent submiued to the Bank; (b) Operating u:ases for machinery and equipment which du not in the aggregate require payments in excess of$ ____________ _ in any fiscal year of the Borrower. 5.05. Di•idends. Declare or pay any dieidends; or purchase or redeem, retire or olherwise acquire any of its capilal stock now or hereafter oulslanding in excess of$ ___________ in any fiscal year of the Borrower. SEE ATIACI\ED SCHEDULE 5.06. Salaries.. Salaries and any other cash compensation to owners/officers shall be limited as follows: ===--------------- SEE ATIACI\ED SCHEDULE 5.07. Guaranties. Assume. guarantee, endorse, or otherw,isc be or become dir<ctly or comingenlly liable for obligations of any person , excepl guaranties by endorsemcm of negotiable instruments for deposit or collection or similar trJnsactions in the ordinary course of business. 5.08. Loans. Loans to owners/officers shall be limited as follows: SEE Al'TACHED SCHEDULE 5.0'J. Sale of Assets. Sell, lease, or 01herwisc dispose of uny of its assets or properties except in the ordinary and usual course of its husine,s. 5. I 0. Transfer uf Ownership. If Borrower is a cori1oration, transfer or sell more lhan 10% of the total number of share• of slock in Burrower priortu the maturity of the Note(s). 5.1 I. Other. Such 01her negative co,enants listed on Schedule" __________ " herelo. Section 6 Hazardous Materials and Environmental Compliance 6 .01. lnvestigation. Borrower her<by certifies that it has exercised due diligence, 10 asccnain whether its real property, inclmling wi1hou1 limi1a1ion 1hc Mortgaged Propeny, is ur has been affected by the presence of asbestos, oil or oil products, urea fom1aldehyde, PCBs. hazardous or nuclear waste, luxic chemicals and ,ubstances, or other hazardous materials, as tklincd in applicable Environmcn1al Laws. Borrower represents and warrams thal 1here are no such materials contaminating its real property, nor have any such materials been improperly slored un or disposed of nn its real propeny. llorruwer hereby agrees that it ,hall not pcnnit any such contamination as long as any indebtedness or obligalions to Bank under the Loan Documenls remains unpaid ur unfulfilled . In addition. Borrower doc, not hase or use any underground storage tanks on ii• property which are not registereJ wilh the appropriate Federal and/or State agencies and which are not properly equipped and maintained in accordance with all Environmental Laws. If requested by Bank, Borrower shall provide Bank with all necessary and reasonable assistance r"'!uired for purposes of de1errnining the exislence of hazardous materials on the Mortgaged ; Propeny, including allowing Bank access to the Mortgaged Property, and access to Borrower's employees having knowledge of, and lo files and records within Borrower's cun1rol relating to the exislcnce, siur,1ge or discharge of h•zardous materials on the Mon gaged Prop•ny. 6.02. Compliance. Borrower agrees tu comply wi1h all applicahle Environmental Laws, rules and regula1ions. including, wi1hout limit:uion, all those relating 10 hazardous materials. Borrower fun her agrees to provide Bunk, and all appropriale Federal and Stale authorities, with immedia1c nut ice in wri1ing of any hazardous or toxic materials released on the Mortgaged Property and to pursue diligently to completion all appropriate and/or required remedial action in the event of such release. 6.03. Remedial Action. !lank shall have the right, but nut the obligation, 10 undertake all or any pan of such remedial action in lhe event of a release of hazardous or toxic materials on the Mortgaged Property and lo add uny expendi1urcs so made to the principal indeb1edness s.ecurcd by the O.,ed(s) of Trust. Borrower agrees to indemnify and hold Bank harmless from any and all loss or liability arising oui of any violation of the rc.,presentalions, covenants and obligations contained in this Section 6, or resulting from the recording of the Dced(s) of Trust_ Section 7 Events or Default The following shall be Events of [>.,fault by Borrower or Guarantor: *within five (5) business days of when due 7 .0 I. The failure to make prompt payment of any installment of principal or interest on the Note(s1when due or payable; or 7 .02. Any representation or warranty made in the Loan Documents which shall prove to be false or misleading in any material respect; or- 7.03. Any repon, certificate, financial statement or other document furnished priorto the execution of or pursuant to the terms of this Agreemem shall prove to be false or misleading in any material respect; or 7 .04. The Borrower ur Guarantor shall default on the performance of any other obligation when due or in the performance of any obligation incurred for money borrowed: or 7 .05. The breach of any covenant, condition, ur agreement made by the Borrower or Guanm1or under lhe Loan Documents; or 7 .06. If a custodian shall be appointed forortake possession of any or all of the assets of the Borrower or Guarantor, or should the Borroweror Guarani or either voluntarily or involumarily become subject 10 any insolvency proceeding, any proceeding to dissolve the Borrower or Guarantor, any proceeding to have a receiser appointed, or should the Borrower or Guarantor make an assignment for the benefil of creditors, or should there be an auachment, execution or other judicial seizur< of all or any ponion of the Borrower's or Guan10tor's assets. and such seizure is not discharged within 20 days; or 7 .07. Final judgement for 1he payment of money •hall be rendered against ihe Borrower or Guanuuor which is not. covered by insurance and shall remain undischarged for a period of 30 days unless such judgement or execution thereon be effectively s1ayed; or 7 .08. If corpor..iions, the dissolution or termination of the existence of either the Burrower or Guarantor; or 7 .09. The Borroweror Guarantor shall become a deb1ur (as lhe term "debtor" is defined in the U.S. Bankruptcy Code). whe1her voluntarily or involuntarily; or 7.10. Should the Bank in good faith deem itself. its liens and security interes1, if any, or any debt hereunder unsafe or insecure, or should lhe Bank believe in good faith 1ha1 the prospect of payment or other performance by the Borrower ur Guaranlor is impaired. 7.11. _______________________________________ _ Section 8 Remedies Upon Default Upon the occurrence of any of the above listed esents of default. the Bank may at any 1imc thereafler, at its option, take any or all of the following actions, at lhe same or al different times: 8.0 I . Declare the balance of the Note(s) to be immedialely due and payable, both as to principal and interest, without presenlment, demand, protest, ornulke of any kind, all of which ar< hereby expressly waived by Borrower and Guarantor. and such balance shall accrue interest at the Default Rate; 8.02. Require the Borrower or Guarantor to pledge additional collateral to the Bank from the Borrower's or Guarantor's assels and propcnies, the .icccplabHity anJ suffi ck m:y ;,f !i!:.:h c ~11li.ltc: .. i :11 he d..!h:imiHcd in the Bank'.!t :-:•!h; Ui~1.:n:d.1 :1~ SCBEDVLS OP ADDITIONJU. PROVZSIOHS 'J:O LOAN AGR.BZXEH!r DAftD AS OJ' DECEMBER 30, l!il!ilJ Bn"HBIV D.K.&S. ASSOCIA~ES, A NORD CAROLINA GINE.RAL P~RSBIP, AS BORROWER, AND BRAHCB BANKIHQ AHi> 1'RUS!I! COHPAJIY :rBIS LOA!I AOREEMBJr.11 (the "&sreement") ia made thill 30t:.h day of Decamb~&'u l9~J, by 11nd between BRANCB BAl'i'JUMG 1UiD llUS~ COMPANY, ~ bankinq aaaociation organized and existin9 under the laws of Horth C4rolina (the •bnh"), and D.a,,s. ASSOCDL:rES, a Horth Carolina general po~nerahLp (the wgorfgyer•>, having it• principal office• at p.o. B~6S06, Charlotte, North Carolina 28221, ana :rHOMAS 3, BALL and apouae, SA p, BALL, DOUGLAS P. DIUSW, KJ!lNNff~ D. BBAVEK, JJt. and PORO BXPRBSS, IHC ••• more particularly defined herein, the •Guarantor••>• tha Bcrrciwer ha ■ applied to sank for and the Bank ha ■ agreed to make, aubject ta tile ~erm• of this Agreement, th• following loanr Loan Jl. A Tem Loan {"Loan 11~ or the ~'2!nff) in the principal arooun~ of EIGHT HUKl)RBD FinY ~BOVSAHD DOLIARS ($850,000) for the purpose O! refinancing existing indebtedness secured by Borrower'• property locate~ at 4336 Park Road, Charlotte, North Carolina {the "H9rtg,qed Property") tc ba evidenced by the Borrower•• P:omisaory Note datad •• of December 30, 1993 (&~ amendesd, modified, extended, renewed or replaced from ti.me to time, the •liQil."). The Loan ■hall b~ secured by (i) a Deed of Trust on tha Mortgaged Property, (ii) a collateral Aaaign!Mlnt of Leaaea and Renta relating to the Mortgaged Property (tha "Collateral Aeaign~ent ot Leage, and Rents"), (iii) a Collateral Aesignment of the Agreement Concerning Remediation of contamination at certain ruel Station Sitee Sold to D.H.&S. Aaaociatea dated as of November 1, 1991 between the Borrower and Union Oil company of California, doing buainaaa aa UNOCAL, together with an aclcnowladgmant of auch Collateral Assignment by Union Oil company of California thereof (the "Collateral Aaaignment gf Enyirorupentnl Indernnitxn>, (iv) a Security Agreement relating t@ furniture, ti.xtures, account• and contract• relating to tha MortQaqed Property and the 0peration1 rel&ting the~ato (the •iecurity lMJreement"), (v) cua~nty ,, Agraament• (th• "Guaranty Agree,nente~) f~om Thomas J. Hall and epouaa, ·i"raae7r- P. Hall, DouglA8 P. Drew, Xenneth D. Shaver, Jr. (herein•fta~ aomatimaa referred to aa the "Individual Qyaranto,a") and Pet:o Kxpraas, Inc. (hereinafter aometimes referred to as the "corporate Cuarant2E", and collectively together with the Individu~l Guarantors as •2~1ranto." o~ the 4 Guarantor9•), and (vi) subordination Agreqenta (the "§ubordina~ion Agreementf") from the Individual Guarantor• and othe~ partnera, •hareholderD and affiliated entities of the Borrower and the Cocporat• Guarantor relating to loan• ond indebtedness owing from time to tirae by them to the Borrc,wer o~ the Ccrpcrata Guarantor. Princlpal and IntereGt Inat•l!ment&. The principal balance of the to•n shall be payable in thirty-six (36) consecutive monthly installment• beginnln9 January 30, 1994 and continuing on the last day of each month the~eatter. Installments ona (l) through thirty-five (35), inclusive, shall (subject to adjustment as hereafter provided) each be in the amount of $8,625.00. The thirty-sixth (36th) and final installment shall be in the amount of the re~aining principal and accrued interest then outstanding. The payment amount for the first 35 installments is based on a 15 year 41D0rt1zation cf the original principal amount at 9.0\ per annum. Inasmuch•• tha Loan will bear interest at a fl0atin9, rather than fixed, rate of interest based on the Bank'• Prime Rate a ■ hereafter proyided, 1n the event the interest rate applicable to the Loan ahall at any time exceed 9.o, per annum, then the remaining installment payment amounts (other than the J6ch and final in•tallment) will ba recalculated, £rom time to time as necessary, to an atoount, rounded up to the next higheet $5 increment, which would represent Initiala Bank LO'.).! Borrower "fflj CHAR_t\F:\OOCS\WDB\BAH[[UG\84593_1 : Schedule to D.H.&S. Loan Agnit. d4tacl Dec. lO, 1993 allowance ■ and any other form of caah or non-cash payments to or for thelr benefit, but shall •~elude loana to atockholdere which •hall b• governed by Section 5.07 hai:-eof, and ab&ll include all 9uch gompenaatlon by or fro~ th• Borrower, the Corporate Guarantor and Cuolin~ Petroleum Distributor,, Inc. s.01 W!l!,, Neither the Borrower, the corporate Guarantor nor Carolina Petroleu11 Diatril>utora, Inc. ■hall, collectively in tha aggregate, maka loan• or advances; directly or indirac:tly, to parlnera, aharaholders or their tNDily cnecnbera in exce~e of $250,000 at any tiine outstanding. ADDl~IORS m SEC~IOB 9 DBPIHiflOHS 9.01 petinition ■• (d) •toan DgcumentaN •hall ~•an this Ag~eemant, the Note, the Deed o~ Trust, tha Collateral Assignment of Leaae• and Rants, the COllatar&l Aae19nmant of Environmental Indemni~y, th• Security ~9ree1Mnc, tha Subordination Agremnenta, all ccc-1 -Financing s~4tainanta, the Guaranty Agreement•, co11Witment lettter, and all other doc:ument•, certificate ■, and inetrumenta executed 1n connection herewith, and all renewal•, exten ■iona, ~odi!icatione, 1ubatitutiona, and replace~ents thereto and therefor. 9.11 Notieas. Any notice permitted or required by the provi1i0n1 of thie Agreement ahall be daamad to hav• been given when delivared in writing to the Preeident of ony Vice President of either party hereto at their respective gfficea u follow ■ when sent by certitlad mail and return receipt ~equeated: If to th ■ Borrower: D.H.&S. Associate ■ P.O. Box 26806 Chulotte, Hort.h Carolina 28221 Attn; tlougla• P. Draw Phone; (704) 598-0lOO Fax: (704) 597-9139 If to tha lank: Branch Banking & T~uat C0mpany 6869 Fairview Read Charlotte, North Carolina 28210-3384 Att:n, Gordon R. White Phone: (704) 362-4333 raxs (704) It to the Guarantor ■, Thomaa J. Ball and Teresa P. Hall 6921 ShiMacock Hill Lane Chulotte, North carolin• 28217 Phones (704) 376-8501 DouglQ• P. D:-ew 3723 Monique Lane Chulotte, North Carolina 28210 Phone: (704) S98-0300 Pax: (704) S97-9139 ~enneth c. Shaver, Jc. :P.O, Box 26806 Charlotte, North Carolina 28221 Phone: (704) 598-0300 rax: (704) 597-9139 Inltialp sank ~ Borrower CIIAll_1\F:\J)CC:S\W)B\SAWKJl;\~~93 .. 1 - 4 - Sohedula to D.R.QS. Loan J\9111:. dated Deo. 30, 1993 Patr0 Exprasa, Inc. ,.o. Box 26806 Charlotte, ~orth Carolina 28221 Attn: Douglas P. Drew Phones (704) 598-0300 Pax: (704) 597-9139 [R am.a inder of Paga lntentionally Left Blank] Initials Bank (;R__lJJ Borrower 1:!ttf-- CIIAl_l\l:\DOCS\YIBWNICING\84593_1 -s - i ... I~). A rH)RNEY::,· HlS.111 Ill£' l'vcn11hat Gr..inlor sh,111 dcl.ault in ils ubh~.111ons untkr lh1~ IJl•t•d u( I ru~I, lhc note ur otllcr Um:umcnl, Jru.J Hcnclici,;uy employs an atlorney lu assisl in lhe collection of lhe Debt ur IU enforce compliance of Granlor wilh any of the l"uvisions ul this Oeed ollrusl, the Nute or other Documenls or in rhe event Beneliciary or Truslee shall become parlies lo any suil or legal proceeding !including any proceeding conducled before any Uniled Stales Bankruptcy Courl) concerning 1he Properly, concerning rhe lien of lhis Deed of Trusl, concerning colleclion of lhe Debi or concerning rnmpliance by Granlor wilh any of lhe provisions of lhis Deed of Trusl, 1he Nole or olher Documenl, Granlor shall pay Beneficiary's reasonable allorneys' fees and all of the costs lhal may be incurred, and such fees and costs shall be secured by this Deed of Trust and its paymenl enforced as if ii were a parl of 1he Debi. Grantor shall be liable fur such allorneys' fees and coSIS whelher or nol any suit or proceeding is commenced. 17. ANTI-MARSHALLING PROVISIONS. Truslee and Beneficiary may granl releases al any lime and from lime to lime of all or any porlion of the Property (whether or not such releases are required by aw~emenl among the parliesl agr~eable lo Trustee and Beneficiary withoul nolice to or lhe rnnscnl, appruval or agreemenl of other parlies and inll!rests, including junior lienors and purchasers subject to the lien of this Oeedollrusl, and such releasesshall nol impair in any manner lhe validity of or priorily of lhis Deed ofTrust on lhal porlion of the Properly remaining subject 10 I his Deed of Trust, nor release Gran1or from personal liabilily for lhe Debi . Nolwithslanding lhe existence of any olher securily interests in 1he Properly held by Beneficiary or by any other party, Beneficiary shall have lhe right to determine 1he order in which any or all of the Property shall be subjecled lo the remedies available lo Beneficiary, and Beneficiary shall furl her have rhe right 10 delermine lhe order in which any or all portions of lhe Debt are satisfied from lhe proceeds realized upon 1he exercise of any remedy it has. Grantor, or any parly who consents to this, or any parly who has actual or constructive nolice hereof, hereby waives any and all righls lo require lhe marshalling ol assels in connection wilh the exercise of any ol lhe remedies pt!rmilled by applicable law or provided herein. 18. ENVIRONMENTAL ISSUES. Grantor for itself, ils successors and assigns represents, warran1s and agrees that (a) nei1her Granlor nor any other person has improperly used or ins1alled any Haza1dous Marerial (as hereinafter delined) on 1he Property or received any notice from any governmenral agency, entily or other person with regard lo Hazardous Materials on, from or affecling the Property; (b) neither Grantor or any olher person has violaled any applicable Environmental Laws (as hereinafter defined) rela1ing 10 or affecting the Properly; (c) the Property are,presenlly in compliance wilh all Environmental Laws; there are no circumstances presenlly exisling upon or under the Property, or relating to the Property which may violale any applicable Environmental Laws, and there is not now pending, or threatened, any aciion, suit, invesligarion or proceeding against Granto, relating 101he Properly (or against any other party relaring lo the Property) seeking to enforce any right or remedy under any of the Environmental Laws; (d) lhe Property shall be used lo genera1e, manufaclure, transport, treal, slore, handle, dispose, or process Hazardous Materials only in accordance wilh all applicable Environmen1al Laws; (e) Grantor shall not cause nor permil lhe improper installation of Hazardous Malerials In the Property nor a release of Hazardous Materials on 1he Property; (f) Granior shall at all limes comply with and ensure compliance by all other parlies wilh all applkable Environmenlal Laws relating lo or affecling the Property and shall keep lhe Property free and clear of any liens imposed pursuanl 10 any applicable Environmental Laws; lg) 1he Grantor has obtained and will at all times continue to oblain and/or maintain all lkenses. permils, and/or other governmenral or regulalory actions necessary to comply with Environmenlal Laws {lhe "Permirs") and the Granlor is in full compliance wilh lhe lerms and provisions of the Permits and will continue lo comply with the lerms and provisions of the Permits; (h) Granlor shall immedialely give the Beneficiary oral and wrillen notice in the event that Granto, receives any nolice from any governmental agency, enlity, or any other party with regard to Hazardous Malerials on, from or affecting 1he Properly and shall conducl and complete all invesligations, sampling, and 1es1ing, and all remedial, removal, and other aciions necessary to clean up and remove all Hazardous Materials on, from or affecling 1he Properly in accordance with all applicable Environmen1al Laws. The Granlor hereby agrees to indemnify 1he Beneficiary and hold 1he Beneficiary harmless from and against any and all losses, liabili1ies, damages, injuries (including, without limi1ation, auorneys' fees) and claims of any and every kind whatsoever paid, incurred or suffered by, or asserted against Beneficiary fpr, with respect to, or as a direct or indirect resull of (a) lhe presence on, or under, or the escape, spillage, emission or release from the Properly of any.Hazardous Maleria_l regardless of wherher or not caused by or within lhe conlrol of Grantor, (b) the violation of any Environmen1al Laws relaling to or affecting the Property, whelher or not caused by or wilhin the control of Grantor, jc) the failure by Granlor lo comply fully wilh the lerms and provisions of 1his paragraph, or (d) any warranty 01 repre,enlalion made by Granlor in 1his paraKraph being false or unlrue in any material rr.spr.cl. For purposes of this Deed of Tru'1, "Hazardous Malerial" means and includes pelroleum products, any flammable explosives, radioactive materials, asbestos or any malerial conlaining asheslos, and/or any hazardous, loxic or dangerous wane, subs1ance or malerial defined as such in (or for the purpose of) the Environmental Laws. For the purposes of rhis Deed of Trust, "Environmental Laws" means the Comprehensive Environmental Response, Compensalion and Liability Acl, the Hazardous Malerials Transpnrtaliun Acl, the Resource Conservation and Recu,yery Al1, any "Super Fund" or "Super Lien" law, or any other lr.,wral, slale, or local law, regulalion or decree regulaling, relaring 10 or imposing liablily or slandards of conduct concerning any petroleum producls, any flammable explosives, radioactive ma1erials, asbestos or any marerial containing asbestos, and/or hazardous, 1oxic or dangerous wasle, substance or malerial, u may now or al any lime hereafter be in effec1. The obligalions and liabili1ies of Grantor under this paragraph shall survive 1he foreclosure of 1he Deed of Trust, the delivery of a de~d in lieu of forr.closure, 1he cancellalion of the Nole; or ii olherwise expressly permilled in writing by 1he Bank, the sale or alienalion of any parl of the Property. 19. EVENTS OF DEFAULT. Grantor shall be in default under this Deed of Trusl upon lhe occurrence of any of the following: (al Default in the payment or performance of any of 1he obligations, or of any covenant or warranty, in lhis Deed of Trusl, in the Nnle or olher Document, ur in any olher nole of Grantor lo Beneliciary or any conlract belween Grantor and Beneficiary; or in any contract between any 1hird parry . and Beneficiary made for 1he benefit of Granlor; or (h) Any w.1rrJnly,. rt>pr(ISl!nl.1linn nr SlilU~mPnl m~1dr or furnished lo lkrl<'fidary hy or 1111 lwh.1,U of Grantor in nmrwt lion with thi!li transoll tion proving lo have hcl"n false in any material respecl whc..•11 made or furnished; or fcl Loss, theft, substanlial damage, destruction loor of the Property, or I he assertion or making of any levy, seizure, mechanic'sormaterialman's lien or attachment thereof or thereon; or · Id) Death, dissolution, termination of existence, insolvency, business failure, appoinlment of a Receiver for any part of the property of, assignmenl •tor lhe benefil of credilors by, or the inabilily to pay debls in the ordinary course of business of the Grantor or any co-maker, endorser, guaranlor or surely for Granlor; or (el Failure of a corporale Grantor or co-maker, endorser, guarantor or surety for Grantor to maintain its corporate exislence in good standing; or (f) Upon the enlry of any monetary judgmenl or the assessment or filing of any lax lien against Grantor; or upon the issuance of any writ of garnishmenl or allachment againsl any property of debts due or rights of Grantor; or (gl The sale (including sale by land conlracl upon delivery of possession), lransfer or encumbrance of all or any part of the Properly or any interesl therein, or any change in the ownership or control of any corporate or partnership Granlor, without Beneficiary's prior wrillen consenl; or (hi II Beneficiary should otherwise deem Itself, ils securily interests, the Property or the Debt unsafe or insecure; or should Beneficiary otherwise believe thal lhe prospect of payment or other performance is Impaired. 20. REMEDIES OF BENEFICIARY UPON DEFAULT. Upon the occurrence of any event of default, Beneficiary may, at its option, withou1 prior notice lo Granlor, declare the Debt lo be immediately due and payable in full; and, on application of Beneficiary, Trustee shall foreclose this Deed of·Trust in any manner permilled by North Carolina law, including selling the Property or any parl thereof at public sale to lhe last and highest bidder for cash, free of any equity of redemplion, homestead, dower, curtesy or other state or federal exemplion, all of which are expressly waived by Granlor, a lier compliance with applicable North Carolina laws relating to foreclosure sales under power of sale; and Trustee shall execute and deliver to lhe purchaser a Trustee's deed conveying the Properly so sold without any covenanl or warranty, expressed or implied. The recitals in the Trusree's deed shall be prima fade evidence of the truth of the statemenls made I herein. The proceeds of any such sale shall be applied in the manner and in the order prescribed by applicable North Carolina law, it being agreed that the expenses of any such sale shall include a commission of live per cent of the gross sales price to Trustee for holding such sale and for all services performed by him hereunder excluding expenses incurred In making sale. In the event a foreclosure suit or special proceeding is commenced, and no sale is held, then the Granlorshall pay to lhe Trustee: l)all expenses incurred by Trustee and 21a partial commission computed on live per cent of the balance of the unpaid Debt. Beneficiary may bid and become the purchaser at any sale under this Deed of Trust. Al any such sale Trustee may at his election require the successful bidder immedia1elyto deposit with Trustee cash in an amount equal to all or any parl of the successful bid, and notice of any such requirement need not·be included In the advertisement of the notice of such sale. If foreclosure proceedings are inslituled under I his Deed of Trust, T ruslee is hereby aulhorized lo take possession of the Property and collect any renlal, accrued or to accrue;orTruslee may lease lhe Properly or any part !hereof, receive lhe rents and profil• lherefrom, and hold the proceed, remaining after payment of the rxpense, ol managing and operating the Property subject to the order of lhe rnurl for the benefil ol Bl!nefkiary, prnding final disposilion of the fnrrclosure proceedings, and during any period allowl!d by applicable law lor lhe redemplion from any foreclosure sale ordered in such proceedings; and Truslee may act irrespective ol lhe value ol lhe rroperly or its adequacy or inadequacy to secure or discharge the indebredness then owing. 21. RELEASE AND CANCELLATION . Upon fulfillment of all of obligations, the performance of which is secured by this Deed of Trust, and upon paymenl of lhe Debt, this Deed of Trust and the Nole or other Document shall be marked "S;itisfiedft and returned to Grant or, and this conveyance shall be null and void and may be cancelled of record al the request and cost of Granlor, and tille to the Properly shall revest as provided by law. 22. MISCELLANEOUS. The caplinns and heading, of 1hr paragraphs of this Deed of Trust are for convenience only and shall nnl he used to inlerprrl or define any provision,. All remedies provided herein are dislinct and cumulalive lo any other right or remedy under this Deed of Trust or afforded by law or equily, and may be exercised concurrently, independenlly or successively. All covenants contained herein shall bind, and lhe benefils and advanlages shall inure lo, lhe respeclive heirs, execulors, administra1ors, successors or assigns ollhe parties to this Deed olTrusl, and the designalions "Granlor", "Trustee" and "Beneficiary" include the parties, their heirs, e*"eculors, adminislralors, successors and assigns. Whenever used, lhe singular number shall include the plural, and the plural the singular, and the use of any gender shall be applicable to all genders. This Deed of Trus1 shall be governed by and construed under Norlh Carolina law. Any forebearance by Beneficiary in exercising any right or remedy hereunder, or otherwise iilHord ,;-:i ;.~-r.p~;liral>ll• 1.?\V, ._ft.ill not bt•,) waiver n( nr prcc l,!d~ the e:,,Ncise of any ~uc h :iHhf or r~medy. The procurement or insu :-:!nce or the payment c1f l,n:·., ,r .,Ji : .. 1 li ,·n-. ''! t·h,·· .. ;1·, 1,v ,=. •. , ;.•.l r,uv ,,: .. :n not it.·., .,in·r -1; ;,,~ru•iid~ry'·. d1,!.' I:, ,, ,·ll'!•!',· 1;,--. m,H11 ; i1r ~ 111~·1..-, i h•i:1. I unt· i, n( :'.w ,,~_..,,_,r,, •• in fx.D . - COLLATERAL ASSIGMENT THIS COLLATERAL ASSIGNMENT, dated as of December 30, 1993, is given by D.H. & S. ASSOCIATES, a North Carolina general partnership (the "Borrower"), to BRANCH BANKING AND TRUST COMPANY (the "Bank"). W I T N E S S E T H WHEREAS, the Bank has agreed to make a term loan of $850,000 (the "Term Loan") to the Borrower to refinance existing indebtedness secured by the Borrower's real property located at 4336 Park Road, Charlotte, North Carolina (the IISubject Facility") pursuant to the terms of a Loan Agreement between the Borrower and the Bank (the "Loan Agreement"; terms used but not otherwise defined herein shall have the meanings provided in the Loan Agreement), as evidenced by a promissory note of the Borrower in the original principal amount of $850,000 (the "Note") and as secured by, among other things, a Deed of Trust on the Subject Facility (the "Deed of Trust"); , WHEREAS, the Borrower has entered into an Agreement Concerning Remediation of Contamination at Certain Fuel Station sites Sold to O.H.&S. Associates dated as of November 1, 1991 (the "Remediation Agreement") with Union Oil Company of California, doing business as UNOCAL ("UNOCAL") relating to certain properties, including the Subject Facility; WHEREAS, the Borrower has required that the Borrower give this Collateral Assignment as a condition to the making of the Term;Loan; NOW, THEREFORE, IN CONSIDERATION of the premises and other good and valuable consideration, the receipt and sufficiency of which is hereby acknowledged, the parties hereto agree as follows: 1. To secure payment of the Term Loan and other obligations under the Loan Documents, the Borrower hereby assigns and transfers to the Bank all right, title and interest it has or may have under the Remediation Agreement and any rights arising thereunder or relating thereto, to the extent they relate to the Subject Facility (the "Remediation Rights Relating to the Subject Facility"). 2. The Borrower represents that (i) it has given to the Bank copies of the Remediation Agreement and all amendments thereto, (ii) the Remediation Agreement has not been otherwise amended or terminated and remains in force and effect, and (iii) it not made any prior assignment or otherwise transferred or encumbered the Remediation Rights Relating to the Subject Facility, or any part thereof. The Borrower agrees that it will not, without the prior written consent of the Bank, further CHAR_1\F:\DOCS\lo0B\BANKING\85546_1 Attached is an information packet that contains the memoranda and the public notice for this proposed variance. The hearing will be held as follows: CHARLOTTE November 7, 1996 7:00 PM Mecklenburg County Courthouse-Criminal Courts Building 2nd Floor -Courtroom 2201 700 East Fourth Street Additional information about this variance will be provided at the public hearing. After the public hearing and comments have been addressed in accordance with 15A NCAC 2L .0113(f), the Environmental Management Commission will be provided all the necessary information to make a decision on this variance. If you have any questions, please call Mr. Arthur Mouberry at (919) 715-6170. cc: Dr. David Moreau Arthur Mouberry David Hance Jennie Odette DWQ-Public Information Officer 2 ... J. p Rule .Ol 13 (c )(l): Resolution by the County or goveminQ Board: The Unocal Corporation has always been a privately owned company. No resolution is necessary. Rule .Ol 13 (c)(2): A descri ption of past existin e or pro posed activities that would result in a dischanre of contaminants into Qroundwater: The former Unocal site (Petro Express) is located inside the city limits of Charlotte, North Carolina at 4336 Park Road (Parcel Number 143-203-24). The report titled "Variance Re q uest Incident No. 3633 Unocal Corporation Former Unocal Facility # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Pro iect No. 1354-92-397 (November 1995)" contains the relevant information about this site. This facility is at the corner of Park Road and Woodlawn Road as shown in Appendix V of the report. The Unocal site consists of approximately 1.05 acres of land. On February 18, 1988 a release of an unknown quantity of gasoline was discovered at the center of the property near the southern property line during tank removal and site renovation. A preliminary site assessment was sent to the Mooresville Regional Office on February 18, 1988. This was followed by the submittal of the an addenda to that original site assessment and a corrective action plan on March 16, 1993 for soils and groundwater. The final site assessment and the correction action plan was received by the Mooresville Regional Office on March 18, 1996 where it is currently kept on file. The Unocal Corporation began cleanup of this site on August 12, 1993. All potential sources of groundwater contamination were identified at this property by the company. This property at 4336 Park Road in Charlotte, North Carolina formerly owned by the Unocal Corporation and all adjacent properties are in an area with a mixture of commercial, industrial, and residential development. The comprehensive site assessment revealed a groundwater plume from a small area of free product contamination. This area of free product was located near the south property line approximately sixty feet southwest of the area where the Unocal Corporation retail outlet had it's gasoline pump islands. The area of free product was in the shape of an ellipse and was approximately 12 to 15 feet in diameter. The plume of dissolved gasoline that came from this area of free product contamination was roughly the shape of a circle that extended to adjacent properties to the south, southeast, and east. This plume was estimated to have covered an area of approximately 61,250 square feet (1.406 acres) prior to the implementation of corrective actions by the Unocal Company. Site assessment information on file in the Mooresville Regional Office shows that the vertical 2 extent of this plume to be approximately 55 feet below the ground surface. It is not believed that this plume contaminated the bedrock aquifer beneath this site. From the information contained in the site assessment, the company estimated that the total mass of petroleum hydrocarbons was approximately 2410 pounds (lbs). It is estimated that 35 lbs of this material was dissolved hydrocarbons in groundwater. The portion of this release that was adsorbed to the soils and in the vapor phase was estimated at 1,600 lbs. The remaining portion of this plume is believed to be phase-separated hydrocarbons and was estimated to account for 775 lbs (or 130 gallons) from this release. This release occurred in unconsolidated materials above the bedrock. The Unocal Corporation implemented cleanup of this site on August 12, 1993. From that date through March 17, 1995 approximately 3,050 lbs of petroleum hydrocarbons were extracted from contaminated soils and groundwater on and off-site. The company measured the mass of petroleum hydrocarbons extracted from soils at 3,000 lbs. A total of 4.12 million gallons of groundwater has been treated via pump-and-treat technology which accounts for approximately 50 lbs of the total amount of material removed. The Charlotte Mecklenburg Utility Department (CMUD) issued a permit to discharge treated water from the pump-and-treat groundwater remediation system into the nearby sanitary sewer. The cleanup system used by the Unocal Corporation consists of a combination of pump-and-treat technology to . cleanup groundwater, air sparging of soils and subsurface materials, soil vapor extraction to remove contaminants from the site. The Division of Environmental Management required the Unocal Corporation to perform groundwater monitoring to determine the vertical and lateral extent of contamination at the site. On December 15, 1991 and December 16, 1991 the company conducted comprehensive groundwater sampling at all six on-site monitoring wells. The deepest of the monitoring well constructed at this site was Monitoring Well # 8 and it is 55 feet deep below the land surface. Groundwater samples were analyzed using US Environmental Protection Methods 602, 625, and 504.1. Benzene was found in five of the six monitoring wells. The highest concentration found in a monitoring well in exceedence of the 15A NCAC 2L .0202 Groundwater Quality Standard for Benzene during this sampling event ~as 8.10 milligrams/Liter (mg/L) or 8,100 micrograms/Liter (ug/L) in Monitoring Well# 5. This sampling event also revealed the presence of Toluene at 3.2 milligrams per liter or 3,200 micrograms/Liter (ug/L) in Monitoring Well# 5. Ethylbenzene also appeared at a concentration level of 15.0 milligrams/liter (mg/L) or 15,000 micrograms/Liter (ug/L) in Monitoring Well# 5. No substances above detection limits were found in Monitoring Well# 8 during the December 15, 1991 analysis. In September 1993 Monitoring Well# 8 was converted into an air sparging well to assist in the cleanup effort at the site. In January 1993 the company constructed two additional monitoring wells located off-site of the .property at 4336 Park Road. These two wells are known as Monitoring Well# 10 at Belk Investments to the South of the Unocal Site and 3 ' ' ... < f Monitoring Well # 11 located to the East at a retail gasoline station known as the "The Pop Shop". Monitoring Well # 10 is located cross-gradient of the Unocal Corporation site and Monitoring Well # 11 is the downgradient well. The highest concentration of Benzene found at Monitoring Well # 10 was 0.002 milligrams per liter during the initial groundwater sampling on January 27, 1993. Monitoring Well# 11 has never shown concentrations of substances above the Groundwater Quality Standards of 15A NCAC 2L .0202. The Division also required the Unocal Corporation to evaluate the effectiveness of groundwater cleanup efforts by examining concentrations of substances in monitoring wells. In addition, an examination of concentrations in recovery wells used as sumps to collect free product and dissolved hydrocarbons from the site is also necessary to understand the effect puD]p-and-treat cleanup has had on concentrations of constituents at the site. From January 1988 through December 1995 analysis of groundwater samples has been conducted by the Unocal Corporation. The highest Benzene concentration ever found in a monitoring well showed 8.400 milligrams/Liter {mg/L) or 8,400 micrograms/Liter (ug/L) at Monitoring Well# 5 on March 5, 1990._ The highest concentration of Chloroform in this well was 4.20 milligrams/Liter (mg/L) or 4,200 micrograms/Liter (ug/L) on December 16, 1991. The highest concentration of 1,2- Dichloroethane in Monitoring Well# 5 was 0.00615 milligrams/Liter (mg/L) or 6.15 micrograms/Liter (ug/L) on December 1, 1995. The greatest concentration of Ethylene Dibromide that appeared in a sample from this well was 0.000928 milligrams/Liter (mg/L) or 0.928 micrograms/Liter (ug/L) on March 16, 1994. This well is located at the northwest side of the pump islands. Samples were obtained from four recovery wells January 1993 through December 1995. These wells are located around the area which formerly consisted of the Unocal Corporation's pump islands. The highest concentration of Benzene ever found in a recovery well showed 4.0 milligrams/Liter (mg/L) or 4,000 micrograms/Liter at Recovery Well# 4 on January 27, 1993. The highest concentration of Chloroform in this well was 0.00458 milligrams/Liter (mg/L) or 4.58 micrograms/Liter (ug/L) on February 23, 1995. The highest concentration of 1,2-Dichloroethane in Recovery Well# 4 was 1.40 milligrams/Liter (mg/L) or 1,400 micrograms/Liter (ug/L) on January 27, 1993. The greatest concentration of Ethylene Dibromide that appeared in a sample from this well was 0.0321 milligrams/Liter (mg/L) or 32.1 micrograms/Liter (ug/L) on September 13, 1994. The Unocal Corporation has also conducted monitoring at the influent for these four recovery wells. Table# 1 of the March 6, 1996 letter shows that the highest concentration of Benzene found in a composite sample at the influent for these wells to be 0.420 milligrams/Liter (mg/L) or 420 micrograms/Liter (ug/L) on June 3, 1993. The highest concentration for all substances monitored in the recovery wells at the site was 0.570 milligrams/liter (mg/L) or 570 micrograms/Liter (ug/L) of Methyl-Tert Butyl Ether (MTBE) on June 3, 1993. Groundwater monitoring results of influent samples since August 12, 1993 have shown considerable reduction of contaminants at this site. Analysis of these 4 j influent samples at the recovery wells on February 21, 1995 showed substances at either below detection limits or significantly below Groundwater Quality Standards in 15A NCAC 2L .0202. Since cleanup was initiated by Unocal levels of contaminants in groundwater have been significantly reduced in monitoring wells and recovery wells as shown in Table #1 of December 29 , 1995 "Letter Of Transmittal. On June 2, 1995 the Unocal Corporation conducted routine sampling of monitoring wells at this site. Except for the presence of Chloroform in Monitoring Well # 7 at a concentration level above the respective Groundwater Quality Standard, concentrations of substances in on-site and off-site monitoring wells was below detectable limits. Based on the results of the June 1995 monitoring, t,Jie Unocal Corporation informed the Mooresville Regional Office on September 29, 1995 that it intended to request a variance at this site. As shown in Appendix I of the report a letter from Mr. A. Wayne Holt of the Unocal Corporation stated in this letter that the company has utilized best available technology and has "aggressively pursued clean-up". They have specifically requested a variance that would consist of a " ...... site variance and monitor only plan leading to regulatory closure.". This variance encompasses the entire property at 4336 Park Road. Based on the results of June 2, 1996 monitoring event the Division of Environmental Management recommended the pump-and-treat system be turned off to determine if residual contaminants in the soils and subsurface would recontaminate the groundwater, if no treatment system were operating. On December 19, 1995 groundwater sampling was conducted at monitoring wells and recovery wells after the groundwater and soil cleanup system had been temporarily turned off. Seven monitoring wells, including offsite wells at Belk Investments (MW-10) and the Pop Shop (MW-11,) were sampled during this time. Except for Monitoring Well# 5, analysis of samples from these wells showed the Benzene concentration below detection limits. The concentration of Benzene in this well exceeded the Groundwater Quality Standard in 15A NCAC 2L .0202. Potential sources of groundwater contamination in the area are shown on maps located in Appendix V of the report titled "Variance Req uest Incident No. 3633 Unocal Corporation Former Unocal Facility # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Proiect No. 1354-92-397 (N ovember 1995 )" and include the following: 1) A retail gasoline station constructed in 1987 and presently owned by DH&S Company (Petro Express) located on the property once owned by the Unocal Corporation at 4336 Park Road; 5 ., r 2) A retail gasoline station presently owned by Park Road Shopping Center and locally known as the "Pop Shop". This gasoline station is located at 4323 Park Road to the east of the site; 3) A retail gasoline station presently owned by Exxon Company, USA located at 125 Woodlawn Road to the southeast of the site; 4) Property owned by Belk Investments at 4400 Park Road to the south of the site. This property once had a leaking fuel oil tank located near Monitoring Well# 10 and is mentioned in a Law Engineering Report dated 1/3/92. The responsible party for the release from this fuel oil tank is not the Unocal Corporation and it is being addressed under a separate Notice of Violation; 5) On-site wells at 4336 Park Road consisting of five monitoring wells, four recovery wells, and the air sparging well owned by the Unocal Corporation. These wells are in the site maps contained in Appendix V of the variance request. 6) 7) One monitoring well at Belk Investments. Six monitoring wells located at the Pop Shop gasoline station to the east of the site. The company describes two of these monitoring wells as having been "closed". 8) Two tank pit vapor point wells located at the Exxon Company gasoline station to the southeast. 9) Woodlawn Drive (a public roadway); 10) Park Road (a public roadway); 11) Water supply lines that run along Woodlawn Drive and Park Road. 12) Numerous storm drain lines and sewer lines that run along · Woodlawn Drive and Park Road and others located in the general area. 6 Attached to a letter dated March 6, 1996 titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements" is an aerial photograph of the site and adjacent properties in Figure 3. Also attached is Figure 1 a Topographic Map of the City of Charlotte showing contour intervals of the site and adjacent properties. Rule .0113(c)(3): Description of the proposed area for which the variance is requested: Maps of the area are shown in Appendix V of the report titled Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facilitv # 9342- 209 4336 Park Road Charlotte, North Carolina S&ME Proiect No. 1354-92-397 {November 1995)". A map showing identifying county parcel numbers is contained in the attachments to the March 6, 1996 letter titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements". The company has estimated that the area of groundwater contamination is roughly shaped in the form of a circle. It is believed that the plume of groundwater contamination once extended across Woodlawn Road, before cleanup began, and covered approximately two-thirds of the land to the south owned by Belk Investment (Mecklenburg County Parcel Number 171-043-21). Within this area of groundwater contamination is Monitoring Well # 10 at Belk Investments. In addition, a separate plume of contamination from a fuel oil release is present at the Belk Investment property near Monitoring Well# 10 and is being addressed under a separate Notice of Violation. The Unocal Corporation is not the responsible party for this fuel oil release on the Belk Investment land. The plume at 4336 Park Road that Unocal is responsible for extends to the southeast from the property and crosses Park Road going beneath a small portion of adjacent property owned by the Exxon Company (Mecklenburg County Parcel Number 175-141-01). The furthest extent of the contaminated area from 4336 Park Road to the east goes onto an adjacent property known as "The Pop Shop" owned by the Park Road Shopping Center (Mecklenburg County Parcel Number 175-181-06) but is not believed to have traveled as far as Monitoring Well #11. The furthest extent of this plume to the north, northeast, and west included two- thirds of the property at 4336 Park Road formerly owned by the Unocal Corporation (Mecklenburg County Parcel Number 149-203-24). No other adjacent properties are known to have been impacted by the release for which Unocal has cleanup responsibilities. This variance is for all the land entirely within the property boundaries of 4336 Park Road that was formerly owned by the Unocal Corporation. The groundwater that was impacted by the release is located in the original pump area and service station when Unocal owned the site. These structures have since been removed from the property by the present owner. Because groundwater 7 .. , monitoring results do not show that contaminants from Unocal's release at 4336 Park Road have migrated at concentration levels above standards, this variance request does not include any land adjacent to the property as 4336 Park Road. Table 1 in Appendix II of the variance request indicates that concentrations substances that have migrated outside the property boundaries of 4336 Park Road over the past three years have not exceeded the level of the Groundwater Quality Standards in 15A NCAC 2L .0202. Groundwater monitoring results in Monitoring Well# 11 (The Pop Shop) have shown the presence of Methyl Tert- Butyl Ether (MTBE) above detection limits. However, from January 27, 1993 through December 1, 1995 this substance has never appeared above the Groundwater Quality Standard for MTBE. No other substance has been observed in Monitoring Well# 11. Sampling at Monitoring Well# \0 (Belk Investments) during the same period has demonstrated that no substance at a concentration level exceeding laboratory detection limits. If at any time monitoring reveals that concentrations of substances exceed the Groundwater Quality Standards in 15A NCAC 2L .0202 on adjacent properties and it could be determined that the Unocal Corporation is responsible for the contamination, the Division could still require the Unocal Corporation bring these concentration levels in compliance with the standards in 15A NCAC 2L .0202. A variance granted by the Environmental Management Commission does not exempt the Unocal Corporation from being held jointly or severally responsible for cleanup. The concentration of contaminants in groundwater is primarily influenced by the direction and rate of groundwater flow. The estimated groundwater flow rate is contained in the site assessment and corrective action plan submitted by the Unocal Corporation to the Mooresville Regional Office. Based on this information the· Unocal Oil Company asserts that groundwater in the area flows from the site travels toward Little Sugar Creek which is 1,400 feet to the east. This small creek discharges into larger water body known as Sugar Creek. Based on an average hydraulic gradient of 0.0075 to 0.01 foot per foot, a hydraulic conductivity of 0.5 to 1.25 feet per day, and an effective soil porosity of 0.3 for sandy silt, the estimated groundwater flow velocity in the subsurface at this site is approximately 5 to 15 feet/year. The company used a range of groundwater flow velocities in calculations as a means to predict the rate of movement of contaminants from the site. The Unocal Corporation asserts that substances in the plume of dissolved petroleum hydrocarbons will enter Little Sugar Creek at concentration levels exceeding 15A NCAC 2L .0202 standards .for Benzene, Ethylene Dibromide, and 1,2-Dichloroethane between 93 and 280 years. This estimated range assumes no natural degradation or attenuation of the plume occurs. The last observed concentration levels of Benzene, Ethylene Dibromide, and 1,2 Dichloroethane from routine sampling in December 1995 were used to determine these projected times of travel to Little Sugar Creek. (See page 3-4 of the March 6, 1996 letter titled "Resp onses to 2/19/96 NCDEHNR Letter for Variance Re q uirements"). 8 ' l Rule .0113(c)(4): Supporting information to establish that the variance will not endanger the public health and safety ... : This part of the variance concerns Groundwater Quality Standards shown in 15A NCAC 2L. 0202 and has been requested for Benzene, Ethylbenzene, Toluene, Xylene(-o,-m, and p), Naphthalene, Methyl Tert-Butyl Ether (MTBE), Isopropyl Ether, Ethylene Dibromide, 1,1-Dichloroethane, 1,1-Dichloroethene, 1,2- Dichloroethane, 1,l,1,-Trichloroethane, 1,1,2,2,-Tetrachloroethane, 1,1,2 Trichloroethane, 1,2, Dichloropropane, Bromodicltloromethane, Bromoform, cis- 1,3-Dichloropropene, Carbon Tetrachloride, Chloroform, Dibromochloromethane, Methylene Chloride, trans-1,3-Dichloropropene, Chloroethane, and 1,2- Dichlorobenzene, 1,3-Dichlorobenzene, 1,4-Dichlorobenzene, and Chlorobenzene. In order to assess health impacts, monitoring wells were sampled at or near this site to assess the extent of contamination and concentration levels of substances. Concentrations of substances in recovery wells were also examined to determine the effectiveness of the pump and treat system at removing these chemicals. Groundwater monitoring data from the Unocal Corporation indicates that substances released by the Unocal Corporation at this site do not pose a hazard to the public. Sampling and analysis of on-site wells at 4336 Park Road has been conducted since January 13, 1988 at monitoring wells and is being continued at the present time. A total of eleven different sampling events occurred from 1988 through 1995 at five monitoring wells located at the site. A total of seven different sampling events occurred at Monitoring Well# 8 from January 13, 1988 through September 3, 1993 before this well was converted into an air sparging well pursuant to the specifications of the corrective action plan received by the Mooresville Regional Office on March 18, 1993. Analysis of off-site monitoring wells at Belk Investments (Monitoring Well# 10) and the Pop Shop (Monitoring Well # 11) began on January 27, 1993. Six different sampling events have occurred at these off-site wells on properties adjacent to the site at 4336 Park Road. The last sampling and analysis at all monitoring wells occurred on December 1, 1995. From January 27, 1993 through December 19, 1995 analysis of recovery wells was also conducted by the Unocal Corporation. Six sampling and analysis events have occurred at each of the four recovery wells since December 1991. In addition, when "effluent" sample are taken at the well head of these recovery wells, the Unocal Corporation also obtains a composite sample from the "influent" by taken samples from pump-and-treat system from the recovery wells. Composite samples are taken from untreated water within the groundwater recovery system or from the submersible pump. On six different occasions samples have been taken at the influent for these four recovery wells since June 3, 1993. USEP A Method 601 and Method 602, and 504.1 were the analytical methods used for samples collected at the Unocal Corporation site. USEP A Method 601 is used to assess the concentration levels of chlorinated hydrocarbons such as 1,2-Dichloroethane and Chloroform. USEPA Method 602 9 . . is used to assess the concentration levels of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE. USEP A Method 504.1 is used to determine the concentration level of Ethylene Dibromide. A comprehensive listing of all monitoring results from wells is shown in the December 29, 1995 Letter Of Transmittal. The December 29, 1995 Letter Of Transmittal includes all groundwater sampling results from monitoring wells through December 1, 1995 and all from recovery wells through December 19, 1995. The highest concentration of any substance found at this site was 15 milligrams per liter (mg/L) or 15,000 micrograms per liter (ug/L) of Ethylbenzene in Monitoring Well# 5 on December 16, 1991. The Groundwater Quality Standard for this substance is 0.029 milligrams per liter (29 micrograms per liter) pursuant to 15A NCAC 2L .0202(g)(40). The December 16; 1991 sampling and analysis of this well took place prior to the implementation of cleanup on August 12, 1993. Ethylbenzene was not detected in any other monitoring wells during this sampling event. Analysis · for Ethylbenzene was also conducted for recovery wells on December 16, 1991. Only Recovery Well# 4 showed Ethylbenzene in exceedence of the Groundwater Quality Standard on December 16, 1991. The concentration of this substance in this recovery well was 0.2 milligrams per liter (mg/L) or 200 micrograms per liter (ug/L). Analysis of subsequent groundwater samples from 1992 through 1995 has revealed that Ethylbenzene contamination in all monitoring wells, including Monitoring Well# 5, and the recovery wells had declined over time to the extent that Ethylbenzene concentrations no longer appear above the standard in 15A NCAC 2L .0202(g)(40) or can no longer be detected. , On February 23, 1995 routine groundwater sampling and analysis was conducted for the seven monitoring wells at this site. The highest concentration of any substance in any well during this sampling event was at Monitoring Well# 9. USEP A 601 analysis of a sample from this well showed 1,2-Dichloroethane at 0.02460 mg/L or 24.60 ug/L. The Groundwater Quality Standard for 1,2- Dichloroethane is 0.00038 mg/L or 0.38 ug/L. Analysis of a sample from Monitoring Well # 7 showed Chloroform at 0.0085 mg/L or 8.5 ug/L. The Groundwater Quality Standard for Chloroform is 0.00019 mg/L or 0.19 ug/L. Monitoring Well # 7 and # 9 did not show any other substances above detection limits when analyzed using the USEP A 601 Method. Concentrations of Chloroform and 1,2 Dichloroethane in the remaining monitoring wells were below detection limits. Analysis of samples from all seven monitoring wells by the USEP A 602 Method showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below detection limits. Analysis of samples using USEP A Method 504.1 did not reveal concentrations of Ethyl Dibromide in any of the seven monitoring wells above the detection limits. During the February 23, 1995 monitoring event the Unocal Corporation also conducted sampling of the four recovery wells. Samples taken from three of the four recovery wells had concentrations of substances in exceedence of Groundwater Quality Standards in 15A NCAC 2L .0202. Recovery Wells #1, # 3 ' ' ' i and # 4 all showed concentrations of 1,2-Dichloroethane in exceedence of the standards. Recovery Well# 1 and Recovery Well# 3 showed concentrations of 1,2 Dichloroethane above the groundwater standard for 1,2-Dichloroethane. Recovery Well# 1 showed 0.00298 milligrams/Liter (mg/L) or 2.98 micrograms/Liter of 1,2-Dichloroethane. The highest level of 1,l-Dichloroethane found during this sampling event was at Recovery Well # 3. USEP A 601 analysis of a sample from this well showed 1,2-Dichloroethane at 0.01550 mg/L or 15.50 ug/L. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.00038 mg/L or 0.38 ug/L. · Recovery Well # 1 and Recovery Well # 4 showed concentrations of Chloroform above the standards. Recovery Well # 1 showed 0.00218 milligrams/Liter (mg/L) or 2.18 micrograms/Liter of Chloroform. The highest concentration of Chloroform at the recovery wells.during this sampling period was 0.00458 mg/Lor 4.58 ug/L at Recovery Well# 4. The Groundwater Quality Standard for Chloroform is 0.00019 mg/L or 0.19 ug/L. Analysis of these four samples by USEP A 602 Method showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. None of the . recovery wells showed concentrations of these substances above practical quantitation limits. Analysis of recovery well samples using USEP A Method 504.1 showed concentrations of Ethylene Dibromide above the 15A NCAC 2L .0202 standards in two of the four recovery wells. Recovery well # 1 showed the highest concentration of Ethylene Dibromide at 2.48 x 104 mg/L or 0.248 ug/L. Recovery Well # 4 also showed a concentration level of Ethylene Dibromide above the Groundwater· Quality Standard at 5.26 x 10-5 mg/L or 0.0526 ug/L. The Groundwater Quality Standard for Ethylene Dibromide is 4.0 x 10-1 mg/L or 4.0 x 10-4 ug/L. The Unocal Corporation also conducted composite sampling of the influent for these recovery wells in February 1995. Analysis of this composite sample did not show the concentration of any substance above the Groundwater Quality Standards in 15A NCAC 2L .0202. The second groundwater sampling in 1995 was conducted at the seven monitoring wells on June 2, 1995. Only two monitoring wells showed concentration levels above the Groundwater Quality Standard in 15A NCAC 2L .0202 using USEPA Method 601. Monitoring Well# 9 revealed 1,2- Dichloroethane at 0.00955 mg/L or 9.55 ug/L. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.00038 mg/L or 0.38 ug/L. Groundwater analysis from Monitoring Well# 7 revealed Chloroform at 0.0116 mg/Lor 11.6 ug/L. The Groundwater Quality Standard for Chloroform is 0.00019 mg/L or 0.19 ug/L. Analysis of the samples from these wells by the USEP A Method 602 showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. None of the monitoring wells showed concentrations of these substances above practical quantitation limits. Analysis of samples using USEP A Method 504.1 did not reveal concentrations of Ethyl Dibromide in any of these monitoring wells above the detection limits. The company did not conduct any sampling of 11 ' I the recovery wells in June 1995. On December 1, 1995 the company conducted a third round of sampling at the request of the Mooresville Regional Office. The regional office wanted an analysis of samples from both monitoring wells and recovery wells since the time the pump-and-treat, soil vapor extraction, and air sparging devices were turned off in September 1995. This special monitoring was to determine the on-site and off-site concentration levels of substances when no groundwater cleanup technologies are in operation. Table # 1 of the December 29, 1995 Letter of Transmittal shows from USEP A Method 601, 602, and 504.1 analytical methods. Two of the seven monitoring wells had concentrations of substances in exceedence of the Groundwater Quality Standards in 15A NCAC 2L .0202. Analysis of samples using USEPA Method 601 revealed Monitoring Well# 5 with 1,2 Dichloroethane at 0.00615 mg/L or 6.15 ug/L. This analysis of a sample at Monitoring Well# 9 using USEPA Method 601 revealed the concentration level of 1,2-Dichloroethane at 0.00447 mg/Lor 4.47 ug/L. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.00038 mg/Lor 0.38 ug/L. No other monitoring well showed the presence of any substances that can be detected by USEP A Method 601. Analysis of the same samples from these seven monitoring wells by the USEP A Method 602 showed the presence of Benzene in Monitoring Well# 5 at 0.00863 mg/Lor 8.63 ug/L. The Groundwater Quality Standard for Benzene 0.00100 mg/Lor 1.00 ug/L. Analysis of the groundwater samples from the remaining six monitoring wells by the USEP A Method 602 showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. None of the monitoring wells showed concentrations of these substances above practical quantitation limits. Analysis of the samples using USEPA Method 504.1 revealed that Monitoring Well # 5 had a concentration of Ethylene Dibromide above the 15A NCAC 2L .0202 standards. The concentration of Ethylene Dibromide in this well was 6.52 x 104 mg/L or 0.652 ug/L. The Groundwater Quality Standard for Ethylene Dibromide is 4.0 x 10-7 mg/Lor 4.0 x 104 ug/L. None of the remaining six monitoring wells showed this substances above detection limits. On December 19, 1995 Unocal Corporation also conducted sampling of the four recovery wells. Table 1 shows that samples taken from two of the four recovery wells had concentrations of substances in exceedence of Groundwater Quality Standards in 15A NCAC 2L .0202. Recovery Well #1 and Recovery Well # 4 both showed concentrations of 1,2-Dichloroethane in exceedence of the standards. The concentration of 1,2-Dichloroethane in Recovery Well# 1 was 0.00298 mg/Lor 2.98 ug/L. The highest level of 1,2-Dichloroethane found during this sampling event was at Recovery Well# 4. USEPA 601 analysis of a sample from this well showed 1,2-Dichloroethane at 0.01970 mg/L or 19. 70 ug/L. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.00038 mg/L or 0.38 ug/L. Chloroform did not appear in these wells in concentrations above the practical quantitation level. Analysis of the same samples from these four recovery wells by the USEP A Method 602 showed the presence of Benzene in 12 Recovery Well# 4 at 0.00135 mg/Lor 1.35 ug/L. The Groundwater Quality Standard for Benzene 0.00100 mg/L or 1.00 ug/L. Analysis of the remaining three samples by USEP A 602 Method showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. None of the recovery wells showed concentrations of these substances above practical quantitation limits. Analysis of recovery well samples using USEP A Method 504.1 did not reveal concentrations of Ethyl Dibromide in any of these wells above the detection limits. The Unocal Corporation also conducted composite sampling of the influent for these recovery wells in December 1995. Analysis of this composite sample did not show the concentration of any substance above the Groundwater Quality Standards in 15A NCAC 2L .0202. The Unocal Corporation has attempted to define the vertical extent of groundwater contamination beneath the site. The deepest well Monitoring Well # 8 (MW # 8) and it is 55 feet below the ground surface. Groundwater sampling and analysis was conducted using USEP A Method 601, Method 602, and Method 504.1 at six separate times from January 13, 1988 through January 27, 1993 as shown in Table# 1. Analysis sample from this well over a six year period using USEP A Method 601 showed the concentrations of 1,2-Dichloroethane, Chloroform and other substances below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. The analysis of the January 13, 1988 sampling event for Monitoring Well # 8 using USEP A Method 602 showed a concentration of Benzene at 0.003 mg/L or 3 ug/L. This level is in exceedence of the Groundwater Quality Standard of 0.001 mg/L or 1 ug/L for this substance in 15A NCAC 2L .0202. The highest level Benzene that was ever found in this well in exceedence of the standard was on December 16, 1991. Analysis using USEP A Method 602 revealed Benzene at 0.010 mg/l or 10 ug/L. The last sample taken at this well was on January 27, 1993 and no Benzene was detected above the practical quantitation limit. The analysis of all other samples taken from this well from January 1988 through January 1993 did not reveal any other chemical constituent from the petroleum release. After January 1993 this monitoring well was converted into an air sparging well and no additional data can be obtained. Based on the low concentrations of Benzene found in samples from Monitoring Well # 8 over a five year period, the Mooresville Regional Office does not believe that the bedrock beneath 4336 Park Road was significantly impacted by this release prior to implementation of the corrective action plan in August 1993. On page# 3 of a letter dated March 6, 1995 titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements" downgradient monitoring at the well located at Monitoring Well# 11 (The Pop Shop) is discussed. The letter states that "No ..... dissolved hydrocarbons except MTBE (11 ug/L) !,ave ever been detected in Groundwater .... .from this well''. It must be noted that this concentration level in this monitoring well is well below the Groundwater Quality Standard in 15A NCAC 2L .0202. Analytical results from samples taken at Monitoring Well# 10 (Belk Investments) over the past 3 1/2 years have never 13 I) shown any chemical constituent above the detection limits. With respect to the site at 4336 Park Road, Monitoring Well # 10 is located cross-gradient from it. All samples from Monitoring Well# 10 were analyzed using EPA Methods 601, 602 and 504.1. Using site assessment information at the Mooresville Regional Office, the company has calculated the time it would take for residual contaminants to impact the down-gradient offsite monitoring well at the Pop Shop (Monitoring Well# 11) such that Groundwater Quality Standards would be exceeded. Based on a groundwater flow velocity between 5 feet to 15 feet per year, the Unocal Corporation estimates that amount of time it wil~ take both Benzene and Ethylene Dibromide to reach Monitoring Well# 11 are between 14 and 42 years. This estimated range is based on the maximum concentration for Benzene and Ethyl Dibromide found at the site that were obtained from the· analysis of a sample from Monitoring Well# 5 on December 1, 1995. The range of time estimated for 1,2-Dichloroethane to reach Monitoring Well# 11 is 9 to 28 years. This estimate is based on the maximum concentration of this substance that was obtained from the analysis of a sample from Recovery Well# 4 on December 19, 1995. Estimated time ranges are based on the conservative assumption that the plume will not be impacted by natural remedial processes and attenuation effects within the subsurface. It is not anticipated that rainfall events will significantly impact the movement of contaminants offsite. The area where groundwater monitoring results showed concentrations of Benzene, 1,2-Dichloroethane, and Ethylene Dibromide above the standards is beneath a concrete slab and the remaining property at 4336 Park Road is covered by an asphalt parking lot. Based on the calculations by the Unocal Corporation, it is not anticipated that groundwaters in the area will be impacted by a variance at this site within the near future. No sources of drinking water from water wells or surface water are known to exist within a 1/2 mile radius of the property at 4336 Park Road that was formerly owned by the Unocal Corporation. The requirements for variance applications in 15A NCAC 2L .0113(c)(4) specify that locations of drinking water wells and other water supply sources that are within one-half mile of the site must be shown on a map. The attachments to the "March 6, 1996 letter titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements" labeled Figure 4, Figure 5, and Figure 6 show that there are no drinking water wells in the vicinity of the property at 4336 Park Road. Figures 5 and 6 are maps showing utility and water use in the area. These maps show that properties around the site are serviced by the Charlotte Mecklenburg Utility Department. Page 2 of the March 6, 1996 letter it · states that the company conducted a survey of a 1/2 mile area around the site and did not find any drinking water wells that are presently in use or have been abandoned. Figure 7 in March 6, 1996 letter shows that there are no drinking water supply intakes at surface water bodies located within a 1/2 mile radius of the site. Drinking water for the City of Charlotte is obtained from Mountain Island Lake on the Catawba River twelve miles north-northwest of the site. All downgradient 14 V properties and other area properties are supplied drinking water from the City of Charlotte. In addition to monitoring wells and recovery wells previously discussed, there are a number of other wells on properties adjacent to 4336 Park Road. There are approximately six groundwater monitoring wells downgraident from the site. These wells are located at the "Pop Shop" and is across the road at 4323 Park Road. The Well Survey Map (Figure 4) attachment to the March 6, 1996 memorandum shows these six monitoring wells. Two of these wells are described in the map legend as "closed". The Unocal Corporation has submitted information on pages 3 and 4 of the March 6, 1996 letter showing that concentrations of contaminants will not impact these downgradient wells to the extent that an exceedence of Groundwater Quality Standards will occur in the near future. There are two "tank pit vapor point wells" located at the Exxon Company service station at 125 Woodlawn Road. These wells are to the south and the southeast respectively of the property at 4336 Park Road and are cross- gradient from the site. Since these wells are located cross-gradient from the site, is unlikely that migrating contaminants as a result of this release emanating from 4336 Park Road would degrade the construction materials used in these wells or impact groundwaters. It is highly improbable that public water supply lines will be impacted by this variance. Numerous water supply lines and other utilities are located along Park Road and Woodlawn Road. This piping ranges from 4 inches up to 16 inches in diameter. Page 8 of Appendix II in the report titled Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facilitv # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Pro ject No. 1354-92-397 (November 1995)" shows that the company contacted Charlotte Mecklenburg Utility Department and found that utilities are not a potential path for migration of petroleum hydrocarbons from the site. The depth to the groundwater in this area is approximately 17 feet. The utility department reported that area water lines and utilities are buried less than five (5) feet from the surface. Groundwater contamination from Incident Number 3633 that is beneath 4336 Park Road is too deep within the subsurface to impact these lines. In addition, page 8 also states the Unocal Corporation did not locate any buildings with basements that could serve as conduits for the buildup of explosive, flammable, or toxic vapors from this site. Rule .Ol 13 (c)(5): Supporting information to establish that requirements of the rule cannot be achieved b y providin g best available technolo uv economically reasonable: The part of the request that concerns variance to Corrective Action in 15A NCAC 2L .01060) will allow the Unocal Corporation to discontinue Corrective Action at this site. The company has submitted supporting information in the report and other documents demonstrating that the continued application of BAT 15 The. March 31, 1995 letter shown on page 9 of Appendix II shows that the Unocal Corporation has incurred the entire cost of cleanup of this site. Appendix I shows an itemized listing of costs to remediate this site. Groundwater analysis of samples from on-site monitoring wells showed significant reductions in the concentrations of substances from December 1991 through September 1994. On August 12, 1993 the Unocal Corporation implemented a corrective action plan to cleanup groundwaters at this site. From August 12, 1993 through September 29, 1995 the Unocal Corporation operated a groundwater remediation systems consisting of pump-and-treat cleanup, air sparging, and soil vapor extraction technologies. Groundwater monitoring up through the September 13, 1994 sampling event showed reductions in the concentrations of substances in the groundwater. Since that time analysis of samples from groundwater monitoring wells and recovery wells have not demonstrated a significant reduction in contaminant concentrations as shown in Table 1 of the "Letter of Transmittal" dated December 29, 1995. In September 1995 use of the pump-and-treat system was discontinued. On December 1, 1995 groundwater monitoring was conducted to determine the effect ~ temporary interruption of the operation of the pump-and-treat groundwater remediation system would have on contaminant concentrations. Except for Monitoring Well# 5, which showed Benzene, Ethylene Dibromide, and 1,2-Dichloroethane, no increase in the concentrations of substances was observed in the remaining groundwater monitoring wells. It is important to note that the concentration of Benzene in Monitoring Well# 5 had remained below detectible limits in 1995 when the cleanup systems were in operation. Significant reductions in the concentrations of Benzene and 1,2 Dichloroethane have not been observed in recovery wells since September 1994. It was only during the December 1, 1995 sampling event that Chloroform concentrations showed a reduction below detectable levels in Monitoring Well# 7. In order to demonstrate that the requirements of the rule cannot be achieved using best available technology, title 15A NCAC 2L .0113(c)(5) requires that specific technology considered be identified, the costs of implementing the technology be shown, and the impacts of the costs on the applicant be provided. On Page 8 of the report titled "Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facility # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Project No. 1354-92-397 (November 1995}" shows the cost of continuing to operate the present cleanup system. The company has estimated that it will cost approximately $180,000 over the next three years to continue operating the air sparging, pump and treat, and soil vapor extraction systems. This cost estimate assumes that the Charlotte Mecklenburg Utility Department will issue a new permit to continue allowing treated effluent from the pump-and- treat system to be discharged into the sanitary sewer system. If a permit to discharge treated wastewater into the city's sanitary sewer system cannot be obtained, then the costs to continue using pump-and-treat cleanup as a means of 17 remediation will drastically increase. This cost increase would occur as a result of the necessity for the Unocal Corporation to obtain the necessary NPDES permit to construct a discharge to Little Sugar Creek. The only other option the company may have is to have a discharge system constructed that meets the requirements of a non-discharge permit in accordance with 15A NCAC 2H .0200 (Waste Not Discharged to Surface Waters). The cost figures supplied by the Unocal Corporation also assumes that Mecklenburg County Department of Environmental Protection will issue a new air quality permit for air sparging and soil vapor extraction systems. The Unocal Corporation has considered the use of air sparging as an alternate technology to the present groundwater and soil remediation system. The comp_any does not believe that the use of this technolqgy by itself is practical to meet the requirements of 15A NCAC 2L .0113(c)(5). The company estimates the costs of operating an air sparging system for three years would be approximately $45,000. The Unocal Corporation believes that the low residual concentrations of substances in groundwater at the site and the lack of any human receptors does not warrant the additional expense of continuing reliance on air sparging. The company believes that the low residual levels of contaminants in soils at this site does not warrant the continued use of soil vapor extraction technology to cleanup this site. Table 1 in Appendix III of this same report titled "Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facilitv # 9342- 209 4336 Park Road Charlotte, North Carolina S&ME Proiect No. 1354-92-397 (November 1995)t' shows measurements of total petroleum hydrocarbons (TPH) in soil vapor and organic vapor analyzer (OVA) readings. Based on this information the company asserts that residual concentrations of petroleum in soils at 4336 Park Road in Charlotte, North Carolina will be below the state action level of 10 parts per million and not pose an impact to groundwaters such that a violation of Groundwater Quality Standards is anticipated to occur. The Unocal Corporation did not identify any technology, other than those already in use at the site, that would meet the requirements of 15A NCAC 2L .0106(j) as "best available technology". Pursuant to the requirements of 15A NCAC 2L .0113(c)(5), the company does not believe that continuing remediation with any of the technologies, or any combination of technologies, at the site are "economically reasonable". Rule .0113(c)(6): SupportinQ information to establish that compliance would produce serious financial hardship on the applicant: The Unocal Corporation has submitted information showing that compliance with the rules will result in a serious financial hardship. Page 8 of the report shows that the Unocal Corporation has demonstrated that the continued 18 application of best available technology to this location would be a prohibitively expensive method of remediating groundwater contamination. The report states on page 9. of Appendix II that "Unocal is no longer operating tltis gasoline retail facility or making a profit at tltis site .... ". Groundwater Section staff have examined the state trust fund status of this site and have found that a claim for reimbursement through the Commercial Underground Storage Tank Trust Fund has never been filed by the Unocal Corporation. The Unocal Corporation bas thus far spent $313,500 to cleanup this site. A March 6, 1996 letter titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements" further discusses cleanup activities at this site. Page 6 of this letter shows that the company is continuing to operate the air sparging system and will do so until " ... site closure ltas been approved". In Appendix I of the '~Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facility# 9342-209 4336 Park Road Charlotte, North Carolina S&ME Proiect No. 1354-92-397 (November 1995)" Mr. Wayne Holt asserts that unless a variance leading to closure of this site approved, ongoing remedial actions at 4336 Park Road will result in continual expenditures by the Unocal Corporation. The company believes that there is immense uncertainty that best available technology will remediate the groundwaters at this site to standards within a foreseeable period of time. Page 6 of the March 6, 1996 letter states that the that " ..... soil and groundwater restoration ltas occurred as close to tlte level of tlte state standards as economically and technically feasible". Allowing the persistence of low levels of contaminants in groundwaters that, after approximately 1 3/4 years of applying best available technologies, have asymptotically approached the Groundwater Quality Standards in 15A NCAC 2L .0106 through a variance is a prudent means of addressing Unocal's release at this site. It is no less effective a means of addressing residual concentrations of substances at this site than continuing the use of pump-and-treat, soil vapor extraction, and air sparging and is less expensive. Rule .0113(c)(7): Supporting information that compliance would produce serious financial hardship without equal or greater public benefit: The company has submitted information in the request demonstrating that the environment, safety and public health would not be impacted by this variance. The Groundwater Section believes that the public will not benefit from compelling the Unocal Corporation to continue remediating this site using pump- and-treat technology, other alternatives discussed, or a combination of these technologies. 19 Rule .0113(c)(8): "A copy of anv Special Order ... ": No Special Order by Consent has been issued for this site. Rule .Ol 13(c)(9): "A list of names and addresses of property owners ... ": The property owners within the proposed area of the variance are shown on pages 4 through 6 of the March 6, 1996 letter_ titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements". This listing includes the Hardees Restaurant, The Pop Shop, The Exxon Gas Station, Belk Investments, a vacant home owned by Mr. Duncan MaCrae, Jr., the Charlotte-Mecklenburg Utility Department, the NC Department of Transportation, the Park Chase Apartments, Nationwide Insurance, and the Petro Express Gasoline Station Number 7. Title 15A NCAC 2L .0113(e)(E) requires that notification of a public hearing on this variance be given to the owner or owners of these adjacent properties "at least 30 days prior to the date of the hearing". It is the recommendation of the Groundwater Section that the subject variance request to Corrective Action requirements of 15A NCAC 2L .0106G) and Groundwater Quality Standards contained in 15A NCAC 2L .0202 proceed to public notice in accordance with 15A NCAC 2L .0113(e). On November 28, 1995 the Division of Epidemiology completed their review of the risk assessment methodology for this site and recommended that this variance be granted for the Unocal Corporation at 4336 Park Road in Charlotte, North Carolina. Upon your concurrence with our recommendation, the Groundwater Section will proceed with the preparation of the required public notice and hearing. Upon completing of the requirements of 15A NCAC 2L .0113(d -f), with a recommendation to grant this variance from the Environmental Management Commission Groundwater Committee, this request will proceed to the Environmental Management Commission for final action in 15A NCAC 2L .Ol 13(g). If there are any questions regarding this matter or if any additional information is needed, please let me know. ATTACHMENTS: cc: Groundwater Section Assistant Chiefs Mooresville Regional Groundwater Supervisor Dr. Ken Rudo David Hance 20 --... ' installed at this site and sampling and analysis of wells be placed as conditions for approval of this variance. On July 24, 1996 Mr. James Ponder of S&ME Incorporated requested that the Groundwater Section review the necessity for recommending monitoring requirements as conditions for approval of this variance in light of the enactment of Senate Bill 1317. Mr. Ponder expressed the view that this law extends to monitoring requirements on variances under 15A NCAC 2L .0113 as well as monitoring requirements in corrective action plans established pursuant to lSANCAC 2L .0106. It is important to note that Senate Bill 1317 specifically includes cleanups at sites where petroleum has been discharged or released from underground storage tanks. This law does not specify any new requirements for variances propo"sed to the Environmental Management Commission pursuant to 15ANCAC 2L .0113. The statutory basis for the Environmental Management Commission to grant a variance is found in North Carolina General Statute (NCGS) 143-215.3(e). Senate Bill 1317 does not mention this statute nor does it effect any actions taken by the Environmental Management Commission pursuant to NCGS 143- 215.3(e). In addition to reviewing this issue for the Goodwill Industries of the Southern Piedmont, the Groundwater Section has also examined other variances to determine if they are "Class CDE pursuant to Senate Bill 1317. The only site that we have identified as being impacted by the legislation is the Unocal Corporation site at 4336 Park Road in Charlotte, North Carolina (Groundwater Incident Number 3633). Groundwater Section staff have identified three courses of action that the Unocal Corporation can take that will result in a corrective action plan that will satisfy the requirements the ISA NCAC 2L rules. These options are shown as follows: 1) The Unocal Corporation could withdraw the variance and discontinue cleanup for Groundwater Incident # 3633 until a risk assessment rule has been established. Senate Bill 1317 requires that by October 1, 1997 the Environmental Management Corpmission adopt a rule to implement the requirements of NCGS 143-215.94V(b). Please note that the deferment of cleanup requirements is a temporary,_ not a permanent deferment. It is not known at this time what requirements will be included in a new risk based rule. It must be further noted that if a risk assessment were conducted at this site and it showed that conditions are such that the site posses a higher risk than that of a site ranked Class CDE, this may result in a re- ranking to Class AB status. A higher ranking at a · site may result in the reinstatement of active groundwater and/ or soil remediation. A risk assessment 2 may also result in the necessity for expanded groundwater and soil monitoring requirements. After a risk assessment rule has been adopted, a new variance may also be requested only if the new rule allows responsible parties to obtain variances for releases from petroleum underground storage tanks. 2) The Unocal Corporation could withdraw the variance for Groundwater Incident # 3633 and cleanup the site pursuant to the requirements of 15A NCAC 2L. It must be noted that Senate Bill 1317 allows, but does not require, the temporary cessation of remediation actlvities. Although the Unocal Corporation has never received any payments for cleanup out of the state's underground storage tank cleanup funds, under the new legislation any future access to those funds is denied, unless the company can meet the criteria outlined in Section 1 (0 of the Senate Bill 1317. After a risk assessment rule has been adopted, a new variance may be requested only if the new risk based rule allows responsible parties to obtain variances for releases from petroleum underground storage tanks. 3) The Unocal Corporation could continue to pursue a variance at this property. If a variance is granted by the Environmental Manage~ent Commission for this site, any conditions upon the variance, including monitoring, would need to be adhered to by the company in order for the variance to remain legally valid. After a variance is granted the responsible party may be allowed to conduct a risk assessment under the new rules to determine if the variance is still necessary. If a risk assessment shows that the variance or monitoring requirements placed by the Environmental Management Commission as conditions for the approval of a variance are no longer needed, then the Unocal Corporation may request that the variance be rescinded. In order to complete activities shown in either Number 1 or 2 above to support a new variance request pursuant to 15A NCAC 2L .0113, the most up-to-date site information must be submitted with the information submitted through June 28, 1996. li a risk assessment is conducted pursuant to Senate Bill 1317 for any of these three scenarios, it must be in accordance with a new rule approved by the Environmental Management Commission. The most recent site information will need to be submitted in accordance to the requirements of the rule. At this time no risk assessment rule has been orooosed bv the Division of Water Oualitv. 3 The Groundwater Section staff has been in the process of completing the activities necessary to bring this variance to public notice and hearing. The Groundwater Section would like to know in writing if the Unocal Corporation desires to continue pursuing a variance for Groundwater Incident Number 3633 at this time so that we can arrange a public hearing and send notices pursuant to 15A NCAC ZL .0113. If possible, we would like to receive your response by September 20, 1996. Upon the completion of the hearing officers report and recommendation, this variance will be sent to the Environmental Management Commission for review and final action. Please send your response to Mr. David Hance, P.O. Box 29578, Raleigh, NC 27626-0578 {phone: (919) 715-6189; fax (919) 715-0588}. Information from the Mooresville Regional Office shows that all other sites for which variances have been requested through S& ME Incorporated, are "Class AB" in accordance with the legislation and are not impacted by legislative changes made during the 1996 Session of the North Carolina General Assembly. Staff are reviewing the information submitted for these variance requests. If you have any new information that will change the priority ranking of any of these sites to Class C, D, or E, or have questions concerning this letter, please feel free to contact myself at (919) 715-6170 or Mr. Hance. AM/dah cc: Arthur Mouberry Carl Bailey Dr. Burrie Boshoff Mooresville Regional Groundwater Supervisor Allen Schiff David Hance A. Wayne Holt (Unocal Corporation) Sincerely, ~~? Chief, Groundwater Section 4 PAGE 2"9-OCT-96 10,01 FROM,S AND ME CHARLOTTE ID,7045253953 ) NCDEHNR-Grounc:Nvater Section S&ME Project No. 1354-92-397 Proposed Groundwater Monitoring After Vartance Approval, Unocal-Park Rd. October 2, 1996 if you have any questions, please call me at 704-523--4726. S&ME, Inc. :::te~1vart t "iinDs~ L.C:A. Sen/1r HvdroQecloai:,:;t "' .... ·- -'~.l Ou::rlss, L. G. Assist ant Environment al Services Manager cc: ·.,t,J-:..J.y-:-,e Hrnt -Unocal Corporation i-<.:\ J :.:;~:;;; .. .i ~/l.t-J1.."';E . •.Jl. 2 3/B ,, ' State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director October 25, 1996 MEMQRANDUM TO: FROM: SUBJECT: Roy Davis Preston Howard ,Mf Designation as Hearing Officer AVA D E HNR I am hereby designating you as Hearing Officer for a public hearing concerning a variance request from the requirements of 15A NCAC 2L .0202 and 15A NCAC 2L .0106 0). The hearing concerns a variance for an area of petroleum contamination on property previously owned by the Unocal Corporation. In 1987 the Unocal Corporation sold this property to the DH&S Company. The person requesting this variance is the Unocal Corporation of Atlanta, Georgia. The hearing schedule is as.follows: CHARLOTTE . NORTH CAROLINA November 7, 1996 7:00 PM Mecklenburg County Courthouse -Criminal Courts Building Second Floor -Courtroom 2201 700 East Fourth Street Groundwater Section. P.O. Box 29578, Raleigh. North Carolina 27626-0578 2728 Capital Blvd., Raleigh. North Carolina 27604 N~iC tSNd'f@®' 1 Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50% recycles/10% post-consumer paper ... Included with this memorandum is an information packet which contains the Hearing Officer's speech and directions to the hearing location. Please be advised staff have not made arran gements for y our overni ght sta y . The written comment period for this variance will close at 12:00 PM (midnight) on December 9, 1996. I am requiring you to complete the hearing officers report and the recommendation to the Environmental Management Commission Groundwater Committee by March 11, 1997. This period of time is ninety (90) days after the closing date for written public comment and allows Division staff adequate time -to review your recommendation. Unless significant new site information becomes available after the public hearing or other extraordinary circumstances occur that dictate a longer review period by the hearing officer, the earliest date that this variance may be considered by the Groundwater Committee is April 9, 1997. If your review of the variance shows that there is a need for a longer evaluation period, please contact Arthur Mouberry at (919) 715-6170. I appreciate your taking the time to conduct this hearing. The staff will be glad to assist you through the proceedings. If you have any questions, feel free to call Carl Bailey at (919) 715-6169. Attachments. cc: Arthur Mouberry Carl Bailey David Hance 2 ,. Public Hearing-Variance Request November 7, 1996 Variance to 15A NCAC 2L .0202 and 15A NCAC 2L .0106(j) 4336 Park Road, Charlotte, North Carolina (Groundwater Incident Number 3633) HEARING LOCATED AT: Mecklenburg County Courthouse Criminal Courts Building -2nd Floor, Courtroom 2201 700 East Fourth Street -(at 7:00 PM) HEARING OFFICER'S SPEECH HEARING OFFICER: Roy Davis, Division of Water Quality, Regional Supervisor (Asheville Regional Office) HRARTNG OFFICER: GOOD EVENING, I WOULD LIKE TO CALL TIDS PUBLIC HEARING TO ORDER. MY NAI\1E IS ROY DA VIS, AND I AM THE DIVISION OF WATER QUALITY (FORMERLY THE DIVISION OF ENVIRONMENTAL MANAGEMENT) REGIONAL SUPERVISOR IN THE ASHEVILLE REGIONAL OFFICE. I HA VE BEEN DESIGNATED HEARING OFFICER FOR TIDS EVENING'S HEARING. TIDS HEARING IS BEING HELD PURSUANT TO NORTH CAROLINA GENERAL STATUTE lS0B-21.2. IN ACCORDANCE WITH THE GENERAL STATUTES, A PUBLIC NOTICE OF TIDS HEARING WAS PUBLISHED IN 1 .. "' CONFORMITY WITH 15A NCAC 2L .0113 OF THE GROUNDWATER RULES AND GENERAL NOTICE HAS BEEN GIVEN IN LOCAL PAPERS ACCORDING TO PROCEDURES IN 15A NCAC 2L .0113(e)(l). NOTICES WERE ALSO DISTRIBUTED TO THE PUBLIC AT LARGE, LOCAL GOVERNMENT OFFICIALS, AND PROPERTY HOLDERS WITHIN AND NEAR THE AREA OF THE PROPOSED VARIANCE. THE PURPOSE OF THIS HEARING IS TO OBTAIN PUBLIC CO:Ml\.fENT AND PARTICIPATION IN THE CONSIDERATION OF THE VARIANCE REQUEST FOR THE UNOCAL CORPORATION OF ATLANTA, GEORGIA. THE UNOCAL CORPORATION IS REQUESTING TIIIS VARIANCE FROM RULES CONTAINED IN 15A NCAC 2L GROUNDWATER CLASSIFICATION AND STANDARD S FOR THE PROPERTY LOCATED AT 4336 PARK ROAD. TIDS PROPERTY, PREVIOUSLY OWNED BY THE UNOCAL CORPORATION, IS NOW OWNED BY DH&S COMPANY. UPON TANK REMOVAL AND SITE RENOVATION BY THE UNOCAL CORPORATION, . DH&S CONSTRUCTED A RETAIL GASOLINE STATION KNOWN AS THE PETRO EXPRESS. THIS PROPOSED VARIANCE FOR THE UNOCAL CORPORATION WILL APPLY ONLY TO AN AREA CONSISTING OF THIS PROPERTY AT 4336 PARK ROAD (PARCEL NUMBER 143-203-24). THE 2 ... UNOCAL CORPORATION ESTIMATES THE TOTAL AREA OF LAND FOR WHICH THIS VARIANCE IS REQUESTED IS APPROXIMATELY 1.05 ACRES. IN THE SUPPORTING INFORMATION SUBMITTED IN TIIlS VARIANCE REQUEST, THE UNOCAL CORPORATION INFORMED THE DIVISION THAT THIS SITE IS LQ_CATED WITHIN AN AREA CONTAINING A MIXTURE OF COMMERCIAL, INDUSTRIAL AND RESIDENTIAL PROPERTIES. THE APPLICANT PROPOSES TO ALLOW THOSE CONCENTRATIONS OF BENZENE, TOLUENE, ETHYLBENZENE, XYLENES, NAPHTHALENE, METHYL-TERT BUTYL ETHER (MTBE), ISOPROPYL ETHER, E~ENE DIBROMIDE, 1,1-DICHLOROETHANE, 1,1-DICHLOROETHENE, 1,2- DICHLOROETHANE, 1,1,1,_;TRICHLOROETHANE, 1,1,2,2,- TETRACHLOROETHANE, 1,1,2-TRICHLOROETHANE, 1,2- DICHLOROPROPANE, BROMODICHLOROMETHANE, BROMOFORM, cis- 1,3-DICHLOROPROPENE, CARBON TETRACHLORIDE, CHLOROFORM, DIBROMOCHLOROMETHANE, METHYLENE CHLORIDE, trans-1,3- DICHLOROBENZENE, 1,4-DICHLOROBENZENE, AND CHLOROBENZENE TO REMAIN AT LEVELS AS FOUND DURING THE DECEMBER 1995 GROUNDWATER ANALYSIS, THESE CONCENTRATIONS WILL BE 3 REQUIRED TO REMAIN WITIIlN THE PROPERTY BOUNDARIES OF 4336 PARK ROAD. THE UNOCAL CORPORATION ALSO PROPOSES THAT CORRECTIVE ACTIONS REQUIRING THE APPLICATION OF BEST AVAILABLE TECHNOLOGY IN 15A NCAC 2L .0106 0) NOT BE APPLIED TO THE AREA WITHIN THE BOUNDARIES OF THE PROPOSED VARIANCE. THE UNOCAL CORPORATION HAS REPORTED THAT A TOTAL OF $ 313,500 HAS BEEN EXPENDED TO CLEANUP TlilS SITE. NO CLAIMS FOR REIMBURSEMENT THROUGH THE STATE'S COMl\.fERCIAL UNDERGROUND STORAGE TANK TRUST FUND HA VE EVER BEEN FILED BY THE UNOCAL CORPORATION FOR TIDS SITE. THE UNOCAL CORPORATION HAS SUBMITTED SUPPORTING INFORMATION DEMONSTRATING THAT THE CONTINUED APPLICATION OF BEST AVAILABLE TECHNOLOGY WILL NOT RESULT IN SIGNIFICANT LONG TERM REMEDIATION OF THE SITE TO THE GROUNDWATER QUALITY STANDARDS IN 15A NCAC 2L .0202. THE COMPANY BELIEVES THAT APPLICATION OF BEST AVAILABLE TECHNOLOGY AT THIS LOCATION IS A SERIOUS FINANCIAL IMPACT WITHOUT EQUAL OR GREATER PUBLIC BENEFIT. 4 TIDS HEARING WILL CONFORM TO PROCEDURES IN ISA NCAC 2L .0113_. ADDITIONAL COPIES OF THE NOTICE OF VARIANCE APPLICATION AND HEARING ARE LOCATED IN THIS B~DING AND ARE AVAILABLE FOR PUBLIC REVIEW. A WRITTEN RECORD OF TIDS HEARING WILL BE PREPARED WIDCH WILL INCLUDE ALL THE RELEVANT COMMENTS, QUESTIONS, AND DISCUSSIONS. FOR THIS REASON, THE HEARING IS BEING TAPE RECORDED. WRITTEN COMl\lIENTS RECEIVED THROUGH DECE1\1BER 9, 1996 WILL ALSO BE INCLUDED IN THE RECORD. BASED ON THESE PUBLIC COMMENTS AND ON ANALYSIS BY THE GROUNDWATER STAFF, I WILL MAKE A RECOMl\lIENDATION TO THE ENVIRONMENTAL MANAGEMENT COMMISSION. IN MAKING THE FINAL DECISION, THE ENVIRONMENTAL MANAGEMENT COMMISSION CONSIDERS THE WRITTEN RECORD, THE RECO:Ml\.fENDATION OF THE HEARING OFFICER, THE RECOMMENDATIONS OF DIVISION STAFF, AND THE CONCERNS OF ITS ~MBERS. THE COM1\.1ISSION MUST ALSO CONSIDER WHETHER THE APPLICANT HAS COMPLIED WITH lSA NCAC 2L .0113(g). 5 IF THE APPLICANT DECIDES THAT THE CO:Ml\1ISSION'S DECISION IS UNACCEPTABLE, A PETITION MAY BE FILED ACCORDING TO PROCEDURES IN 15A NCAC 2L .0113(h). THE DECISION ON THE VARIANCE BY THE ENVIRONMENTAL MANAGEMENT COMMISSION IS FINAL AND BINDING ACCORDING TO THE CONDITIONS SHOWN IN 15A NCAC 2L .0113(h). AT TIDS TIME I WOULD LIKE TO RECOGNIZE (names or local and state officials) AND THANK YOU FOR ATTENDING TffiS HEARING. I WOULD ALSO LIKE TO RECOGNIZE THE FOLLOWING PEOPLE FROM THE DIVISION OF WATER QUALITY (DWQ central office and DWQ regional office personnel). MR.(starr speaker) OF THE DIVISION OF WATER QUALITY- GROUNDWATER SECTION MOORESVILLE REGIONAL OFFICE WILL NOW SU1\1MARIZE THE PROPOSED VARIANCE wmcH IS THE SUBJECT OF TmS HEARING. STAFF SPEAKER: (sta~ speaker summarizes variance request). JIEARING ·omc~R:; THANK YOU. WE WILL NOW ACCEPT PUBLIC COMMENT ON THE PROPOSED VARIANCE. I WOULD LIKE TO 6 REQUEST THAT EVERYONE FILL OUT A REGISTRATION FORM. AFTER ALL REGISTERED SPEAKERS HA VE HAD AN OPPORTUNITY TO COMMENT, I Wll,L ALLOW ADDITIONAL SPEAKERS AS TIME PERMITS. WHEN YOUR NAME IS CALLED, PLEASE CO:ME UP TO THE MICROPHONE AND STATE YOUR NAME AND AFFILIATION. ALL COMMENTS SHOULD BE LIMITED TO MATTERS THAT ARE RELATIVE TO THE PROPOSED ADOPTION OF THIS VARIANCE. IF YOUR COMMENTS ARE LONGER THAN THREE MINUTES, I WOULD LIKE TO REQUEST THAT THEY BE SUBMITTED IN WRITING. I RESERVE THE RIGHT TO QUESTION SPEAKERS IF THE NEED SHOULD ARISE. , DIVISION OF WATER QUALITY STAFF WILL BE AVAILABLE TO ANSWER YOUR QUESTIONS IF NECESSARY. I WOULD NOW LIKE TO .. - CALL [first speaker]. [speakers .•• ] (the hearing officer, referring to THE REGISTRATION CARDS, calls each speaker to the microphone in turn ) HE;(R]NG OFFICER: THANK YOU [last speaker]. ARE THERE ANY MORE COMMENTS? SINCE THERE ARE NO MORE COMMENTS, I DECLARE THE HEARING CLOSED. THE HEARING RECORD WILL REMAIN OPEN 7 UNTIL 12:00 PM (MIDNIGHT) ON DECEMBER 9, 1996. ANYONE WISHING TO SUBMIT WRITTEN COMMENTS MAY DO SO UNTIL THAT DATE. AFTER WHICH TIME, THE COMMENTS WILL BE MADE PART OF THE PUBLIC RECORD AND I SHALL MAKE RECOMMENDATIONS TO THE ENVIRONMENTAL MANAGEMENT COMMISSION. WRITTEN COMMENTS MUST BE ADDRESSED TO DAVID HANCE AT THE DIVISION OF WATER QUALITY GROUNDWATER SECTION. THE ADDRESS WRITTEN COMMENTS NEED TO BE SENT TO IS SHOWN IN THE PUBLIC NOTICE AND IS AS FOLLOWS: David Hance EHNR-DWQ-Groundwater Section P.O. Box 29578 Raleigh, NC 27626-0578 A FACSl1\1ILE COPY OF WRITTEN CO:Ml\1ENTS MAY BE SENT TO MR. HANCE BY DIALING (919) 715-0588. ms TELEPHONE NUMBER IN RALEIGH IS (919) 715-6189 . . IT IS THE DESIRE OF THE COMl\.flSSION TO ALWAYS ACT IN THE BEST POSSIBLE INTEREST OF THE PUBLIC. THEREFORE, PUBLIC PARTICIPATION IS A VERY IMPORTANT PART OF THE RULE-MAKING PROCESS. I WOULD LIKE TO THANK YOU FOR ATTENDING THE HEARING AND OFFERING YOUR COMMENTS. 8 Directions to Variance Hearing for the Unocal Corporation (Site located at 4336 Park Road in Charlotte, NC) HEARING LOCATED AT: Mecklenburg County Courthouse Criminal Courts Building -2nd Floor, Courtroom 2201 700 East Fourth Street, Charlotte, NC (November 7, 1996 at 7:00 PM) MOORESVILLE REGIONAL OFFICE STAFF PRESENTER: Allen Schiff(704) 663-1699; fax -(704) 663-6040 RALEIGH GROUNDWATER SECTION STAFF RECORDER: David Hance (919) 715-6189; fax-(919) 715-0588 _ . HEARING OFFICER: ROY DA VIS (704) 251-6208 CONTACT PERSON AT TIIE COURT HOUSE -CAPT . DEATON (704) 336-3334 FROM ASHEVILLE, NC: Take 1-26 to US -74 then get on 1-85 before you reach Gastonia, NC and proceed toward Charlotte, NC. Take NC Z7 (Freedom Drive) Into Downtown Charlotte. Follow NC Z7 and get onto McDowell Street. Proceed five city blocks on McDowell Street and turn onto East Trade Street The Criminal Courts Building Is located adjacent to the Government Center. NOTE: East Fourth Street is a one way street going east to west. East Third Street is a one way street going west to east. FROM RALEIGH, NC: Take 1-85 Into Charlotte and exit onto NC 16 (Brookshire Freeway). NC 16wlll become 1-277. Take 1- 277 to S. Graham Street and then go onto East Trade Street The Criminal Courts Building ls located adjacent to the Government Center. NOTE: East Fourth Street is a one way street going east to west East Third Street is a one way street going west to east (See Attached Map) interoffice MEMORANDUM --------------------- to: Donna Pittman from: David A. Hance ~ subject: Designation of Hearing Officer for Unocal -Park Road Variance date: October 23, 1996 You will recall that on July 16, 1996 the Director gave approval for the Unocal Corporation variance at 4336 Park Road (GW incident 3633) to proceed to public hearing. Due to passage of the Senate Bill 1317 we delayed proceeding to public hearing at that time. Since this site is Class CDE according to the law, the Groundwater Section sent a letter on September 6 informing the responsible party that he did not need to cleanup the site. lbis letter also stated that he could still pursue this variance, ifhe wished to do so. On September 12, 1996 the Unocal Corporation informed us that they still wanted to pursue a variance at this site. On Octo her 2, 1996 the Groundwater Section sent notices out to the public informing them of the public hearing for this variance scheduled for November 7, 1996. Mr. Roy Davis from the Asheville Regional Office has volunteered to be the hearing officer for this meeting. Attached is a memo designating Mr. Davis as the hearing officer with instructions as to how he is to proceed. Also attached is his speech and a map to the public hearing in Charlotte. Upon completion of the Director's review and signature, I would be glad to get this mailed out to the hearing officer and other staff. If possible, we would like to get the signed packet by Friday October 25, 1996. My apologies for getting this to the Division so late, I was sick all last week. Ifwe need to talk call me at 715-6189 between 9 am and 6 pm. cc: Carl Bailey ). DIRECTIONS TO VARIANCE HEARING FOR THE GOODWILL INDUSTRIES OF THE soµTHERN PIEDMONT HEARING LOCATED AT: Mecklenburg County Courthouse -Criminal Courts Building 2nd Floor, Courtroom 2201, 700 East Fourth Street, Charlotte, NC March 19, 1999 at 7:00 PM MOORESVILLE REGIONAL OFFICE STAFF PRESENTER: Allen Schiff (704) 663-1699;/ax -(704) 663-6040 RALEIGH GROUNDWATER SECTION STAFF RECORDER: David Hance (919) 715-6189 or 733-3221; fax -(919) 715-0588 HEARING OFFICER -SHERRI KNIGHT (910) 771-4600 Contact Person at the Courthouse -Capt. Deaton (704) 336-3334 FROM WINSTON-SALEM, NC: Take US 52 in Winston-Salem to NC 8 and then go onto I-85 South and head toward Charlotte, NC. Take NC 16 (Brookshire Freeway) into downtown Charlotte. NC 16 will become I-277. Take I-277 to S. Graham Street and then go ont9 East Trade Street. The Criminal Courthouse is the building adjacent to the Government Center. NOTE: East Fourth Street is a one way street going east to west. East Third Street is a one way street going west to east. FROM RALEIGH, NC: Take I-85 into Charlotte and exit onto NC 16 (Brookshire Freeway). NC 16 will become I-277. Take I-277 to S. Graham Street and then go onto East Trade Street. The Criminal Courthouse is the building adjacent to the Government Center. NOTE: East Fourth Street is a one way street going east to west. East Third Street is a one way street going west to east. (MAPS ARE ATTACHED) DRAFT SUBJECT; TO REViSIONS CONFORMITY WITH 15A NCAC 2L .0113 OF THE GROUNDWATER RULES AND GENERAL NOTICE HAS BEEN GIVEN IN LOCAL PAPERS ACCORDING TO PROCEDURES IN 15A NCAC 2L .0113(e)(l). NOTICES WERE ALSO DISTRIBUTED TO THE PUBLIC AT LARGE, LOCAL GOVERNMENT OFFICIALS, AND PROPERTY HOLDERS WITHIN AND NEAR THE AREA OF THE PROPOSED VARIANCE. THE PURPOSE OF THIS HEARING IS TO OBTAIN PUBLIC COMMENT AND PARTICIPATION IN THE CONSIDERATION OF THE VARIANCE REQUEST FOR THE UNOCAL CORPORATION OF ATLANTA, GEORGIA. THE UNOCAL CORPORATION IS REQUESTING TIDS VARIANCE FROM RULES CONTAINED IN 15A NCAC 2L GROUNDWATER CLASSIFICATION AND STANDARD S FOR THE PROPERTY LOCATED AT 4336 PARK ROAD. THIS PROPERTY, PREVIOUSLY OWNED BY THE UNOCAL CORPORATION, IS NOW OWNED BY DH&S COMPANY. UPON TANK REMOVAL AND SITE RENOVATION BY THE UNOCAL CORPORATION, DH&S CONSTRUCTED A RETAIL GASOLINE STATION KNOWN AS THE PETRO EXPRESS. Tms PROPOSED VARIANCE FOR THE UNOCAL CORPORATION WILL APPLY ONLY TO AN AREA CONSISTING OF THIS PROPERTY AT 4336 PARK ROAD (PARCEL NUMBER 143-203-24). THE DRAFT_ SUBJECt 1'0 REVISlONS 2 RAFT SUBJECT;TO REVISIONS UNOCAL CORPORATION ESTIMATES THE TOTAL AREA OF LAND FOR WHICH TIDS VARIANCE IS REQUESTED IS APPROXIMATELY 1.05 ACRES. IN THE SUPPORTING INFORMATION SUBMITTED IN THIS VARIANCE REQUEST, THE UNOCAL CORPORATION INFORMED THE DIVISION THAT THIS SITE IS LOCATED WITHIN AN AREA CONTAINING A MIXTURE OF COMMERCIAL, INDUSTRIAL AND RESIDENTIAL PROPERTIES. THE APPLICANT PROPOSES TO ALLOW THOSE CONCENTRATIONS OF BENZENE, TOLUENE, ETHYLBENZENE, XYLENES, NAPHTHALENE, METHYL-TERT BUTYL ETHER (MTBE), ISOPROPYL ETHER, ETHYLENE DIBROMIDE, 1,1-DICHLOROETHANE, 1,1-DICHLOROETHENE, 1,2- DI CHLOROETHANE, 1,1,1,-TRICHLOROETHANE, 1,1,2,2,- TETRACHLOROETHANE, 1,1,2-TRICHLOROETHANE, 1,2- DICHLOROPROPANE, BROMODICHLOROMETHANE, BROMOFORM, cis- 1,3-DICHLOROPROPENE, CARBON TETRACHLORIDE, CHLOROFORM, DIBROMOCHLOROMETHANE, METHYLENE CHLORIDE, trans-1,3- DICHLOROBENZENE, 1,4-DICHLOROBENZENE, AND CHLOROBENZENE TO REMAIN AT LEVELS AS FOUND DURING THE DECEMBER 1995 GROUNDWATER ANALYSIS, THESE CONCENTRATIONS WILL BE 3 DRAFT SUBJECT--TO REVJSiONS DRAFT SUBJECT: TO REVJSIONS REQUIRED TO REMAIN WITHIN THE PROPERTY BOUNDARIES OF 4336 PARK ROAD. THE UNOCAL CORPORATION ALSO PROPOSES THAT CORRECTIVE ACTIONS REQUIRING THE APPLICATION OF BEST AVAILABLE TECHNOLOGY IN 15A NCAC 2L .0106 (j) NOT BE APPLIED TO THE AREA WITHIN THE BOUNDARIES OF THE PROPOSED VARIANCE. THE UNOCAL CORPORATION HAS REPORTED THAT A TOTAL OF $ 313,500 HAS BEEN EXPENDED TO CLEANUP THIS SITE. NO CLAIMS FOR REIMBURSEMENT THROUGH THE STATE'S COMMERCIAL UNDERGROUND STORAGE TANK TRUST FUND HA VE EVER BEEN FILED BY THE UNOCAL CORPORATION FOR THIS SITE. THE UNOCAL CORPORATION HAS SUBMITTED SUPPORTING INFORMATION DEMONSTRATING THAT THE CONTINUED APPLICATION OF BEST AVAILABLE TECHNOLOGY WILL NOT RESULT IN SIGNIFICANT LONG TERM REMEDIATION OF THE SITE TO THE GROUNDWATER QUALITY STANDARDS IN 15A NCAC 2L .0202. THE COMPANY BELIEVES THAT APPLICATION OF BEST AVAILABLE TECHNOLOGY AT TIDS LOCATION IS A SERIOUS FINANCIAL IMPACT WITHOUT EQUAL OR GREATER PUBLIC BENEFIT. TIDS HEARING WILL CONFORM TO PROCEDURES IN 15A NCAC 2L DRAFT 4 SUBJECT; TO REVISIONS RAFT SUBJEcr:ro REV!SiONS .0113. ADDITIONAL COPIES OF THE NOTICE OF VARIANCE APPLICATION AND HEARING ARE LOCATED IN TIDS BUILDING AND ARE AVAILABLE FOR PUBLIC REVIEW. A WRITTEN RECORD OF TIDS HEARING WILL BE PREPARED WHICH WILL INCLUDE ALL THE RELEVANT COMMENTS, QUESTIONS, AND DISCUSSIONS. FOR THIS REASON, THE HEARING IS BEING TAPE RECORDED. WRITTEN CO1\1MENTS RECEIVED THROUGH APRIL 19, 1996 WILL ALSO BE INCLUDED IN THE RECORD. BASED ON THESE PUBLIC COMMENTS AND ON ANALYSIS BY THE GROUNDWATER STAFF, I WILL MAKE A RECOMMENDATION TO THE ENVIRONMENTAL MANAGEMENT COMMISSION. IN MAKING THE FINAL DECISION, THE ENVIRONMENTAL MANAGEMENT COMMISSION CONSIDERS THE WRITTEN RECORD, THE RECOMMENDATION OF THE HEARING OFFICER, THE RECO1\1MENDATIONS OF DIVISION STAFF, AND THE CONCERNS OF ITS MEMBERS. THE COMMISSION MUST ALSO CONSIDER WHETHER THE APPLICANT HAS COMPLIED WITH 15A NCAC 2L .0113(g). IF THE APPLICANT DECIDES THAT THE COMMISSION'S DECISION . RAFT 5 SUBJECT; TO REVISIONS &ME October 4, 1996 Mr. David Hance P.O. Box 29578 Raleigh, NC 27626-0578 RE: Proposed Groundwater Sampling and Analyses Schedule After Variance Approval Incident #3633, Priority Ranking SOE Unocal Corporation (Former Station #9342-209) 4336 Park Road, Charlotte, NC- S&ME Project No. 1354-92-397 Dear Mr. Hance: -.. -i S&ME, Inc., on behalf of Unocal Corporation, hereby informs the North Carolina Environmental Management Commission that Unocal Corporation proposes . to monitor groundwater quality on-site and on two adjacent off-site properties for two years following Variance approval by the State. The State's October 1, 1996 Notice of Variance Application and Hearing requires the hydrocarbon compounds above the 2L groundwater standards to remain within the former Unocal property boundaries of 4336 Park Road. Our proposed monitoring would further evaluate groundwater compliance within the Variance boundary area (former Unocal facility) at selected on-site monitor and former recovery wells (M-5, MW-7, MW-9, RW-1, and RW-4). S&ME, Inc. proposes to sample groundwater ·from these 5 wells on a semi-annual basis for two years after Variance approval. Groundwater from these wells will be analyzed for EPA Methods 601, 602 (including MTBE) and 504.1 for EDB, since these compounds were detected above the 2L groundwater standards. The results will be added to the· attached historical groundwater and influent quality data Table 1 and presented to the State and Unocal Corporation. After the two years of groundwater nonitoring, no further monitoring or action may be requested. S&ME , Inc. 9751 Southern Pine Boulevard, Charlotte, North Carolina 28273, (704) 523-4726, Fax (704) 525-3953 Mailing address: P.O. Box 7668, Charlotte, North Carolina 28241-7668 -. MEMORANDUM TO: David Hance FROM: Allen Schiff SUBJECT: Answers to Questions regarding Former Unocal Station -# 9342-209, GW Incident~ 3633 1. Unocal operated the site from the 1950' s (probably 1952 according to Wayne Holt) until sometime in 1986. 2. On February 18, 1988 the MRO received a preliminary groundwater assessment that was performed on Unocal's behalf by Law Engineering. The report contained sampling results (groundwater) confirming that a .release had occurred at the site. There were several UST locations on-site (past and present) but the releases constituted one groundwater plUlile. 3. Petro Express acquired the site in January 1987 and started dispensing products in late 1988. 4. The site assessment addendum and remedial action plan was received by the MRO on March 18, 1993. The MRO acknowledged receipt and said continue on without further review (see attached). No formal approval was issued. 5. Soils were treated as part of CAP system that included SVE. 6. The CAP system was started up on 8/12/93 without a formal approval from MRO. 7. Bedrock was not contaminated. 8. Mr. Wayne Holt of Unocal stated that he calculated, from maps he has, that the site is 1.05 acres in size. If you should have any questions, I can be reached at (704) 663-1699, ext. 236. Attachment AJS/mc State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director CERTIFIED MAIL P 281 517 326 RETURN RECEIPT REQUESTED AVA DEHNR February 19, 1996 Mr. Stewart M. Hines S&ME Incorporated 9751 Southern Pines Blvd., Charlotte, NC 28273 Subject: Request for Variance Under 15A NCAC 2L .0113 for the Unocal Corporation at 4336 Park Road in Charlotte, North Carolina (Groundwater Incident # 3633) Dear Mr. Hines: The Division of Environmental Management has reviewed the information submitted in the variance request received on November 2, 1995. The information contained in your request does not meet the requirements for a variance application filed under 15A NCAC 2L .0113 for the following reasons: 1) Pursuant to 15ANCAC 2L .01 l3(c)(3) the description of the proposed area for which the variance was requested is incomplete. The rule requires that '~ detailed location map showing the orientation of the facility, ...... must' be included". The maps submitted did not show the location or identity of adjacent properties to the north, northwest, west, and southwest of the site. Revised maps showing these properties with any present or potential sources of groundwater contamination noted must be submitted. 1 Groundwater Section, ~TL~,., Voice 919-733-3221 FAX 919-715-0588 P.O . Box 29578, Raleigh, North Carolina 27626-05781 11 -~ '1 An Equal Opportunity/Affirmative Action Employer 2728 Capital Blvd., Raleigh, North Carolina 27604 50% recycled/10% post-consumer paper I 2) The description of the proposed area for the variance on a map does not adequately show 11 ... the potential for groundwater migration". A map showing the location of all water wells on adjacent properties that are NOT used to provide drinking water must be included. Please note if these wells are abandoned or still in use. The survey that was conducted to assess the presence of drinking water wells and basements within the area may be used to construct this map. If this information cannot be obtained from the survey it may be gathered from other sources. Please note on the map any additional drinking water wells that were not identified in the request sent on November 2, 1995. Also, in order to assist staff, please submit a map that contains the portion of the street map of the City of Charlotte with the site shown on it. 3) The supporting information to establish that the variance will not endanger the public health and safety, including "health and environmental effects ...... 11 was incomplete. In order to adequately assess the environmental impacts from this site, the request needs to demonstrate the potential for movement of substances off-site if the variance were granted. This demonstration must include the estimated groundwater flow velocity in feet per year beneath the site. The request must also show the projected time it will take for the plume of contaminants to reach the nearest downgradient off site monitoring well in concentrations that exceed the groundwater quality standards contained in 15A NCAC 2L .0202. In addition, the estimated time of trl:!,vel it will take for the contaminants to reach Little Sugar Creek needs to be included in the request. Previous submittals, such as the corrective action plan, should be used to obtain the estimated groundwater flow velocity and must be referenced in the response to this item. If other sources of site specific information are used these must be submitted to the Groundwater Section. 4) ·Tne supponing information to establish that the variance will not endanger the public health and safety, including health and environmental effects, from exposure to groundwater contaminants was incomplete. 15A NCAC 2L .0113(c)(4) requires that the " ..... Location of wells and other water su pp l y sources .... within 1/2 mile of (the) site must be shown on a map.". In order to meet this requirement it is necessary to provide the location of the nearest public water supply intake from surface water. Please show this feature on the map if it is within 1/2 mile of the site. 2 .. 5) The list of names and addresses of property owners as required by 15A NCAC 2L .0113(c)(9) was incomplete. The rule requires the listing of "any property owners ad;acent to the site .... ". Please submit names and addresses of all property owners adjacent to the site and the direction relative to the Unocal Corporation site. Please also include parcel numbers for each of these properties. The additional information in items # 1 through # 5 must be provided so that the Groundwater Section can properly evaluate the variance request and verify to the Director that it meets the requirements of 15A NCAC 2L .0113 (c). Once the Groundwater Section deems a variance request has met these requirements, it can proceed to the Director for review in accordance with lSA NCAC 2L .0113 (d). For these reasons the request is being returned to you. If you wish to continue pursuing a variance to the Subchapter 2L rules you will need to submit information that addresses items #1 through #5. If you have any questions concerning this letter, please contact Mr. Allen Schiff, Mooresville Regional Office, Groundwater Section, at (704) 663-1699. APH/AM/dah cc: Arthur Mouberry Carl Bailey Burtle Boshoff Sincerely, ~~? Arthur Mouberry, P.E., Chief, Groundwater Section Mooresville Regional Groundwater Supervisor David Hance 3 ,, 2) The description of the proposed area for the variance on a map does not adequately show" ... the potential/or groundwater migration". A map showing the location of all water wells on adjacent properties that are NOT used to provide drinking water must be included. Please note if these wells are abandoned or still in use. The survey that was conducted to assess the presence of drinking · water wells and basements within the area may be used to construct this map. If this information cannot be obtained from the survey it may be gathered from other sources. Please note on the map any additional drinking water wells that were not identified in the request sent on November 2, 1995. Also, in order to assist staff, please submit a map that contains the portion of the street map of the City of Charlotte with the site shown on it. 3) The supporting information to establish that the variance will not endanger the public health and safety, including "health and environmental effects ...... " was incomplete. In order to adequately assess the environmental impacts from this site, the request needs to demonstrate the potential for movement of substances off-site if the variance were granted. This demonstration must include the estimated groundwater flow velocity in feet per year beneath the site. The request must also show the projected time it will take for the plume of contaminants to reach the nearest downgradient offsite monitoring well in concentrations that exceed the groundwater quality standards contained in 15A NCAC 2L .0202. In addition, the estimated time of travel it will take for the contaminants to reach Little Sugar Creek needs to be included in the request. Previous submittals, such as the corrective action plan, should be used to obtain the estimated groundwater flow velocity and must be referenced in the response to this item. If other sources of site specific information are used these must be submitted to the Groundwater Section. 4) The supporting information to establish that the variance will not endanger the public health and safety, including health and environmental effects, from exposure to groundwater contaminants was incomplete. 15A NCAC 2L .0113(c)( 4) requires that the " ..... Location of wells and other water supply sources .... within 1/2 mile of (the) site must be shown on a map.". In order to meet this requirement it is necessary to provide the location of the nearest public water supply intake from surface water. Please show this feature on the map if it is within 1/2 mile of the site. 2 .I 5) The list of names and addresses of property owners as required by 15A NCAC 2L .0113(c)(9) was incomplete. The rule requires the listing of "any property owners ad;acent to the site .... ". Please submit names and addresses of all property owners adjacent to the site and the direction relative to the Unocal Corporation site. Please also include parcel numbers for each of these properties. The additional information in items # 1 through # 5 must be provided so that the Groundwater Section can properly evaluate the variance request and verify to the Director that it meets the requirements of lSA NCAC 2L .0113 (c). Once the Groundwater Section deems a variance request has met these requirements, it can proceed to the Director for review in accordance with lSA NCAC 2L .0113 (d). For these reasons the request is being returned to you. If you wish to continue pursuing a variance to the Subchapter 2L rules you will need to submit information that addresses items #1 through #5. If you have any questions concerning this letter, please contact Mr. Allen Schiff, Mooresville Regional Office, Groundwater Section, at (704) 663-1699. APH/AM/dah cc: Arthur Mouberry Carl Bailey Burtle Boshoff Sincerely, ~~~ Arthur Mouberry, P.E., Chief, Groundwater Section Mooresville Regional Groundwater Supervisor David Hance 3 DIVISION OF ENVIRONMENTAL MANAGEMENT January 24, 1996 MEMORANDUM TO: David Hance THROUGH: Barbara Christian h. Allen Schiff {,{_,J FROM: SUBJECT: Review of Variance Request for Former Unocal Facility #9342-209 ---4--336--Park---Road----- Mecklenburg County, N.C. Groundwater Incident #3633 Upon review of the November, 1995 variance request and th~" Groundwater Incident file for the subject site, the MRO recommends approval of the variance with the following comments: 1. The groundwater contaminant plume does not appear to extend past the boundaries of the former Unocal Station No. 9342-209. 2. No potable wells exist within a ;,. mile radius of the subject site. 3. The MRO agrees that continued operation of the air sparging, soil vapor extraction and pump and treat systems are neither cost effective nor practical since the contaminant plume has almost been completely remediated. The remediation systems were shut down on March 17 ,. 1995. The monitor and recovery wells were sampled on December 1, 1995. The results of the sampling indicate that only low levels of Benzene (9 ppb), 1, 2_- dichloroethane (19.7 ppb) and Ethylene Dibromide (0.65 ppb) currently exist at the site. If a variance is granted for the subject site, we would recommend that selected wells be sampled semi-annually for several years. If you should have any questions, I can be reached at (704} 663-1699, ext. 236. AJS/pl Attachment State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A Preston Howard, Jr., P.E., Director ir~--~A . --~ .. n an D E HNR November 9, 1995 MEMORANDUM: TO: FROM: SUBJECT: Dr. Ken Rudo, Ph.D, Toxicologist, Environmental Epidemiology Section Arthur Mouberry, P.E., Chief ~ Groundwater Section (._f;J/"' The Unocal Corporation Request for Variance from 15A NCAC 2L .0202 Groundwater Quality Standards for Property at 4336 Park Road in Charlotte, North Carolina. Attached is a variance request on behalf of the Unocal Corporation from SM&E Incorporated. The request for variance is to groundwater standards for Benzene, Ethylbenzene, Toluene, Xylene (-o,-m, and -p), Naphthalene, Methyl Tert-Butyl Ether, Isopropyl Ether, Ethylene Dibromide, 1, 1-Dichloroethane, 1, 1-Dichloroethene, 1,2- Dichloroethane, 1, 1, I-Trichloroethane, 1, 1,2,2-Tetrachloroethane, 1, 1,2-Trichloroethane, 1,2-Dichloropropane, Bromodichloromethane, Bromoform, cis-1,3-Dichloropropene, Carbon Tetrachloride, Chloroform, Dibromochloromethane, Methylene Chloride, trans-1,3- dichloropropene, Chloroethane, 1,2-Dichlorobenzene, 1,3-Dichlorobenzene, 1,4- Dichlorobenzene, and Chlorobenzene. The request is for a site contaminated by a release of gasoline from an underground storage tank pit. The area requested for variance is all the property formerly owned by the Unocal Corporation. This property is presently owned by DH&S (Petro Express) of 4718 N. Graham Street, Charlotte, North Carolina. This facility has been, and is presently in use as, a retail gasoline station. According to information submitted by the company, this facility is within the City of Charlotte in a heavily commercialized area. Monitoring well data indicates contamination in excess of groundwater standards in 15A NCAC 2L .0202. Extensive efforts have been made by the company to recover over the last few years to remove and recover free product, remediate soil, prevent the contamination of groundwater, and cleanup groundwater. The Unocal Corporation does not believe that any public benefit can be gained through continued groundwater remediation efforts. Please review the attached report and provide the Groundwater Section with a recommendation regarding this request. If possible, the Section would like to receive your recommended response by November 30, 1995. 1 P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-7015 FAX 919-733-2496 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post-consumer paper Upon receiving your recommendation, the Section will forward a recommendation to the Director of the Division of Environmental Management. If you need additional assistance or information please call me at 733-3221. cc: Carl Bailey Dr. Burrie Boshoff David Hance Mooresville Regional Office Groundwater Supervisor 2 DIVISION OF ENVIRONMENTAL MANAGEMENT January 24, 1996 MEMORANDUM TO: David Hance THROUGH: Barbara Christian!n- Allen Schiff a,,.J FROM: SUBJECT: Review of Variance Request for Former Unocal Facility #9342-209 4336 Park Road Mecklenburg County,, N.C. Groundwater Incident #3633 W U) rq Upon review of the November, 1995 variance request and th~~ Groundwater Incident file for the subject site, the MRO recommends approval of the variance with the following comments: 1. The groundwater contaminant plume does not appear to extend past the boundaries of the former Unocal station No. 9342-209. 2. No potable wells exist within a \ mile radius of the subject site. 3 . The MRO agrees that continued operation of the air sparging, soil vapor extraction and pump and treat systems are neither cost effective nor practical since the contaminant plume has almost been completely remediated. The remediation systems were shut down on March 17, 1995. The monitor and recovery wells were sampled on December 1, 1995. The results of the sampling indicate that only low levels of Benzene (9 ppb), 1,2- dichloroethane (19.7 ppb) and Ethylene Dibromide (0.65 ppb) currently exist at the site~ If a variance is granted for the subject site, we would recommend that selected wells be sampled semi-annually for several years. If you should have any questions, I can be reached at (704) 663-1699, ext. 236. AJS/pl Attachment ID,7045253853 r PAGE 2/10 (' t· r " I t: A L LU:c·r::-~ TC,J.:·U:--S I r\i C ;:. t. '°" :'• , A T ~ !:' 28-DEC-SS 11,47 FROM,S AND ME CHARLOTTE ID,7045253953 .. -: . ,_.. -.,. ..... PAGE 3/10 4'. r-f ~ I {: -~ L I. -~ff S:: .st.-■.-:. if!la:~ • -\ ' (, k. ~ ~-.. F• A l i D 28-DEC-SS 11,47 FROM,S AND ME CHARLOTTE ID,7045253853 PAGE 4/10 --=-=:1:J"-£, f ['~IC ~L I \H f.'_\-H:H~S 1 ~; c p, : ~ ,-, ~ .A T ~ 0 28-DEC-95 11 ,48 FROM,S AND ME CHARLOTTE ID,7045253953 • I 'J PAGE 5/10 ("ff~l{',~L I .\Hf;UTf.lH :!l'Ol!AT~D 28-DEC-95 11,48 FROM•S AND ME CHARLOTTE ID,7045253853 PAGE 7/10 State of North Carolina Department of Environment, Health and Natural Resources Division of Epidemiology James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary Michael Moser, M.D., M.P.H. November 28, 1995 MEMORANDUM TO: FROM: Arthur Mouberry, P.E., Chief Groundwater Section Division of Environinental Management Kenneth Rudo, Ph.D., Toxicologist /l..lkfl AVA DEHNR Medical Evaluation and Risk Assessment Branch Occupational and Environmental Epidemiology Section SUBJECT: Variance Request-Unocal Corporation 4336 Park Road, Charlotte, NC '''-" After reviewing the above variance request, the Occupational and Environmental Epidemiology Section (OEES) would like to offer the following observations and recommendations. The levels of petroleum contaminants detected in the various monitoring wells have decreased significantly from 1988 to the present time. The levels of petroleum contaminants are only slightly above the groundwater standards in several monitoring wells. This, coupled with the fact that there appear to be no private wells within 1400 feet of the site would indicate that the current levels of petroleum contaminants should not pose any public health risks at this time or in the future. The OEES would recommend granting Unocal Corporation this variance. If you have any further questions, please feel free to contact me at 715-6430. KR:lp P.O. Box 27687, Raleigh, North Carolina 27611-7687 An Equal Opportunity Affirmative Action Employer 50% recycled/ l 0% post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director NA DEHNA November 9, 1995 MEMORANDUM: TO: FROM: Dr. Ken Rudo, Ph.D, Toxicologist, Environmental Epidemiology Section Arthur Mouberry, P.E., Chief ~ Groundwater Section (_J;J/' SUBJECT: The Unocal Corporation Request for Variance from 15A NCAC 2L .0202 Groundwater Quality Standards for Property at 4336 Park Road in Charlotte, North Carolina. Attached is a variance request on behalf of the Unocal Corporation from SM&E Incorporated. The request for variance is to groundwater standards for Benzene, Ethylbenzene, Toluene, Xylene (-o,-m, and -p), Naphthalene, Methyl Tert-Butyl Ether, Isopropyl Ether, Ethylene Dibromide, 1,1-Dichloroethane, 1,1-Dichloroethene, 1,2- Dichloroethane, 1, 1, 1-Trichloroethane, 1, 1,2,2-Tetrachloroethane, 1, 1,2-Trichloroethane, 1,2-Dichloropropane, Bromodichloromethane, Bromoform, cis-1, 3-Dichloropropene, Carbon Tetrachloride, Chloroform, Dibromochloromethane, Methylene Chloride, trans-1,3- dichloropropene, Chloroethane, 1,2-Dichlorobenzene, 1,3-Dichlorobenzene, 1,4- Dichlorobenzene, and Chlorobenzene. The request is for a site contaminated by a release of gasoline from an underground storage tank pit. The _area requested for variance is all the property formerly owned by the Unocal Corporation. This property is presently owned by DH&S (Petro Express} of 4718 N. Graham Street, Charlotte, North Carolina. This facility has been, and is presently in use as, a retail gasoline station. According to information submitted by the company, this facility is within the City of Charlotte in a heavily commercialized area. Monitoring well data indicates contamination in excess of groundwater standards in 15A NCAC 2L .0202. Extensive efforts have been made by the company to recover over the last few years to remove and recover free product, remediate soil, prevent the contamination of groundwater, and cleanup groundwater. The Unocal Corporation does not believe that any public benefit can be gained through continued groundwater remediation efforts. Please review the attached report and provide the Groundwater Section with a recommendation regarding this request. If possible, the Section would like to receive your recommended response by November 30, 1995. 1 P.O. Box 29535. Raleigh. North Carolina 27626-0535 Telephone 919-733-7015 FAX 919-733-2496 An Equal Opportunity Affirmative Action Employer 50% recycled/ l 0% post-consumer paper Upon receiving your recommendation, the Section will forward a recommendation to the Director of the Division of Environmental Management. If you need additional assistance or information please call me at 733-3221. cc: Carl Bailey Dr. Burrie Boshoff David Hance Mooresville Regional Office Groundwater Supervisor 2 DMSION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION November 9, 1995 MEMORANDUM: TO: Barbara Christian, Regional Groundwater Hydrogeological Supervisor, Mooresville Regional Office FROM: Arthur Mouberry, P. E. , /Ji;:>, Chief, Groundwater Sectio~ SUBJECT: Review of Request for Variance from 15A NCAC 2L .0106 Corrective Action Plans and 15A NCAC 2L . 0202 Groundwater Quality Standards by the Unocal Corporation at 4336 Park Road in Charlotte, North Carolina (DEM Groundwater Incident Number 3633). Please review the attached request for a variance from the Corrective Action Plan (CAP) rules and the Groundwater Quality Standards. Review the request in terms of the requirements of 15A NCAC 2L .0106 Corrective Action to determine if a no corrective action would be as effective as continuing an active CAP to remediate groundwaters at this site. If a determination is made that a CAP involving active groundwater remediation is not necessary, please review the request for a variance in terms of the requirements itemized in 15A NCAC 2L .0113, (c) (1-9), and (d). Verify technical data provided in support of the request. The company is requesting that current remediation efforts at this site cease. Please prepare a letter for the Director's signature providing your conclusions regarding the request for relief from corrective action plans under 15A NCAC 2L . 0106, the variance request, and any additional requirements that are deemed appropriate. A copy of this request has been sent to Dr. Ken Rudo, Division of Epidemiology, for review of the risk assessment methodology. If possible please return your recommendation to me by Thursday, November 30, 1995. cc: Carl Bailey Burrie Boshoff David Hance State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management ir~-~A ---~ .. a a a James B. ·Hunt, Jr., Governor Jonathan B. Howes, Secretary D E HNA A Preston Howard, Jr., P.E., Director CERTIFIED MAIL P 067 735 510 RETURN RECEIPT REQUESTED Mr. Stewart M. Hines S&ME Incorporated 9751 Southern Pines Blvd ., Charlotte, NC 28273 September 14, 1995 Subject: Request for Variance Under 15A NCAC 2L .0113 for the Unocal Corporation at 4336 Park Road in Charlotte, North Carolina (Groundwater Incident# 3633) Dear Mr. Hines: The Division of Environmental Management has· reviewed the information submitted in the variance received on August 28, 1995. This information contained in your request does not meet the requirements for a variance application filed under 15A NCAC 2L .0113 for the following reasons: 1) 15A NCAC 2L .0113 (b) requires that a variance application ",,_shall be sent to the Chaimum. of the Environmental M1n~ment Commission in care of the Director, .. ,,. 11 as shown in 15A NCAC 2L .0113(b): Please properly address this variance request so that it is consistent with the requirements of the rules. 2) Supporting information from the responsible party to establish that the requirements of the rule cannot be achieved by providing the best available technology economically reasonable was incomplete. The variance request 1 P.O. Box 29535. Raleigh. North Carolina 27626-~5 Telephone 919-733-7015 FAX 919-733-2496 An Equal Opportunity Affirmative Action Employer 50% recycled/ l 0% post-consumer paper identified_ specific technology used at the site but did not elaborate on the costs of implementing that particular technology. This information must provide a projection of remediation costs if efforts were to continue for a period of years with the current technologies being used at the site. If other best available technologies exist and are deemed appropriate for this site, an evaluation of the cost of those technologies should also be examined. The additional information in items # 1 through # 2 must be provided so that the Groundwater Section can properly evaluate the variance request and verify to the Director that it meets the require,nents of 15A NCAC 2L .0113 (c). Once the Groundwater Section deems a variance request has met these requirements, it can proceed to the Director for review in accordance with 15A NCAC 2L .0113 (d). For these reasons the request is being returned to you. If you wish to pursue a variance to the Subchapter 2L rules you will need to submit information that addresses items #1 through #2. If you have any questions concerning this letter, please contact Mr. Allen Schiff, Mooresville Regional Office, Groundwater Section, at (704) 663-1699 . APH/AM/dah cc: Arthur Mouberry Carl Bailey Burrie Boshoff Sincerely, ~~~ Arthur Mouberry, P.E., Chief, Groundwater Section Mooresville Regional Groundwater Supervisor David Hance 2 • ) &ME June 14, 1995 Mr. Allen Schiff North Carolina Department of Environment, Health and Natural Resources 919 North Main Street Mooresville, N.C. 28115 Reference: Addendum to the 3/31/95 Request for Site Variance and Groundwater Sampling Results on 6/2/95 Incident #3633 Former Unocal Station #9342-209 4336 Park Road, Charlotte, NC S&ME Project No. 1354-92-397 Dear Mr. Schiff: Triangle Environmental Inc., on behalf of Unocal Corporation, purged and sampled groundwater from all on-site and off-site monitor wells (7) on June 2, 1995 for EPA Test Methods 601, 602 including MTBE and IPE and 504.1. The groundwater sampling event was performed prior to deactivation of the air sparging system on June 2, 1995. The purpose of the sampling event was to evaluate groundwater quality in comparison to the previous February 23, 1995 sampling event with the air sparging system on. The June 2, 1995 analytical results revealed that BTEX, MTBE, IPE and EDB in groundwater from all on-site monitor wells have remained below 2L s~andards and method detection limits (<0.5 ug/L) as were on February 23, 1995. BTEX and MTBE were also not detected in off-site downgradient monitor well MW-11 at the Pop Shop. Off- site monitor well MW-10 at the Belk Investments property exhibited 11.4 ug/L total xylenes, which is due to a separate release from a former fuel oil UST on-site. Trace levels of 1, 1-dichloroethene (1.27 ug/L) and chloroform (11.6 ug/L) were detected in groundwater from monitor well MW-7. Trace levels of 1,2-dichloroethane (9.55 ug/L) were detec .ed in groundwater from monitor well MW-9. The state 2L groundwater standards for these purgeable halocarbons are as follows: 7 ug/L for 1, 1-dichloroethene, 0.19 ug/L for chloroform and 0.38 ug/L for 1,2-dichloroethane. All other 601 compounds S&ME, Inc. 9751 Southern Pine Boulevard, Charlotte, North Carolina 28273, (704) 523-4726, Fax (704) 525-3953 Mailing addres.s: P.O. Box 7668, Charlotte, North Carolina 28241 -7668 NCDEHNR-Groundwater Section Addendum to 3/31 /95 Request for Variance S&M E Project No. 1354-92-397 June 14, 1995 were below method detection limits, as indicated on the laboratory analyses. Table 1 indicates historical groundwater and influent quality for the site and off-site monitor wells MW-1 O and MW-11. All seven monitor wells will be purged and sampled in August 1995 for the same -analyses to evaluate if any "rebounding" of dissolved hydrocarbon concentrations occurred with the air sparging system off. We believe that continued remediation, using best available technology (air sparging), will not result in significant further reduction in the groundwater concentration of these contaminants, and therefore, we petition for a variance to the 2L groundwater remediation guidelines (per 15A NCAC 2L .0113). We request that the state establish site-specific closure criteria, given that asymptotic contaminant concentrations for some purgeable halocarbons exceed the 2L or Class GA groundwater quality standards. We believe that soil and groundwater restoration has occurred as close to the level of the state standards as is economically and technically feasible. If you have any questions or need additional information, please call. Very truly yours, S&ME, INC. ~~.:..~ C/t<tl'lf {~,/' Stewart M. Hines, LG. Senior Hydrogeologist SMH\ Enclosures cc: Mr. A. Wayne Holt, P.G. -Unocal Corporation Mr. R. Holshouser, Jr. -S&ME, Charleston, S.C. P:\WP51\SCHIF95.613 2 I fABLE 1 HISTORICAL GROUNDWATER AN:l INFLUENT QUALITY DATA FORMER UNOCAL FACILITY #9342-209 4336 PAHK ROAD. CHARLOTTE, NC TOLUEN ~-1ETHYL- BENZENE !========.!._,===~~~=~=---1-~=- MONITOR WELL DATE BENZENE ~~. ~~; T ™ I .. I "'" t -0~-1~~:~r-OCEp:;:•1~9' '"~L ,c~_c7~ 1=-:,i===------; 5 -c=N=A==1e==N=A==-4===N=A==:c==N~A~0-= -NA-NA NA NA N~= -NA NA NA MW-1 MW-5 MW-6 ,__ 15ANCAC 21.. 1/13/88 7/15/91 12/15/91 3/11/92 6/26/92 1/27/93 3/16/94 9/13/94 2/23/95 6/2/95 1.3 3.6 s <1 <1 <1 <0.5 <0.5 <0.5 <0.5 2.2 <1 <1 <1 3 <1 <1 <1 <0.5 <0.5 <0.5 <0.5 <1 11 <1 <1 <1 <0.5 36 20 <1 <1 <1 <0.5 <0.5 <O 5 <0 5 <1 NA NA NA NA NA <1 <1 <1 14 <1 <1 <1 <1 NA <1 <1 <1 4 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 26 <1 <1 <1 <1 NA <1 <1 1 <1 <1 <1 <0.5 <0.5 <0.5 <0.5 <1 <1 NA <1 <1 <1 <1 NA <1 <1 <1 <1 NA <1 <1 <1 <1 <0.02 <1 <1 2.66 <1 <0.005 <1 <1 <0.5 <0.5 <0.5 <0.5 <0.5 <0.005 <1 1.16 <0.5 <1 <0.01 <1 <1 <0.5 <1 <0.01 <1 <1 -•-----+-----+----+--- 3/5/90 12/16/91 6/26/92 1/27/93 8400 8100 5600 17,000 3200 7300 2200 15,000 1300 11,000 21,000 38,600 47,300 NA NA NA NA NA 4200 <1 NA <1 <1 NA <1 <1 NA <1 <1 NA <1 <1 <1 <1 NA <1 10,100 24.300 <1 <1 NA <1 NOT SAM> L13J SINCE FF~E PROOUC DETECTED IN WELL 3/16/94 87.8 443 191 1310 2040 11 9/13/94 2.63 1.28 0.541 27.7 32.1 3.77 2/23/95 <0.5 c0.5 <0.5 <05 co 5 <0.5 -~6/2~/9_5_-+-__ <_o_.s_-+ __ c_o_._s _-+-__ c _o_.5_-+ __ c_o_._5 _-+-__ <_o_s __ ~ 1/13/88 1.5 <1 <1 2.6 4 1 NA 7/15/91 <1 <1 <1 <1 < 1 <1 12/16/91 . 2 2 5 1 10 <1 3/11/92 <1 <1 <1 <1 <1 <1 6/26/92 3.3 <1 <1 <1 33 <1 1/27/93 <1 <1 <1 <1 <1 <1 3/16/94 <0.5 <0.5 <0.5 <0.5 <O 5 2.93 9/13/94 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 2/23/95 <0.5 <0.5 <0.5 <0.5 <0 5 <0.5 6/2/95 <0.5 <0.5 <0.5 <0.5 <O 5 <0.5 1000 29 530 NA 200 <1 <0.5 <1 <1 NA NA <1 <1 <1 <1 <1 <0.5 <1 <1 NA 0.928 <10 <10 <10 <1 <10 <1 <1 <0.372 3.73 <1 <1 <1 <1 <1 <1 <0.01 <1 <1 <1 <1 <1 <1 <1 <0.01 <1 <1 <1 <1 <1 <1 <1 -m ~ ~ m m m m ~ m m ~ m ~ m m ~ NA <1 <1 <1 <1 <1 <1 <1 NA < 1 < 1 < 1 < 1 < 1 < 1 < 1 NA < 1 < 1 < 1 < 1 < 1 < 1 < 1 <0.02 <1 <1 <1 <1 <1 6 <1 c0.005 <1 <1 <1 <1 <1 <1 <1 <0.005 <1 <1 <1 <1 <1 <1 <1 <0.01 <1 <1 <1 <1 <1 <1 <1 +--c .;;o;.;.o .. 1_cj...c==<'=1'=--"-'-"-=~'=<='1==4-"-"<"1-4 _-"<"'1===-l-=<~1 =4 ==<=1--=-4= --~-!._a 4E-4 0.38 0.19 7 700 0.56 2.8 0.7 STANDARD (IN UGi\.) NA <1 <1 <1 53 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA NA <1 <1 <1 <1 <1 <1 <1 <1 200 NA NA NA NA <10 NA NA NA _N~--- 1600 NA NA NA NA NA NA NA NA NA NA NA <10 NA NA NA NA --- 21 ;,,.=.=-• B~NZENE ]TOLUENE - MONITOR WELL DATE ETHYL-TOTAL BENZENE XYLENES ---iA'!l-1 1/13/88 <1 <1 <1 <1 7/15/91 <1 <1 <1 <1 12/16/91 <1 <1 <1 <1 3/11/92 <1 <1 <1 <1 6/26/92 <1 <1 <1 <1 1/27/93 <1 <1 <1 <1 3/16/94 <0.5 <0.5 <0.5 <0 .5 9/13/94 <0.S <0.5 <0.S <0.S 2/23/95 <0.5 <0.5 <0.5 <0 .5 6/2/95 <0.5 <0.5 <0.5 <0 5 MW-8 1/13/66 3 7 .7 2.9 17 7/15/91 <1 <1 <1 <1 12/16/91 10 11 25 100 3/11/92 <1 <1 <1 <1 6/26/92 3.3 <1 <1 <1 1/27/93 <1 <1 <1 <1 _ 9/3/93 -----MW-9 1/13/88 170 <1 <1 <1 7/15/91 130 1.8 23 7.7 12/16/91 290 11 <1 <1 3/11/92 250 6 .4 24 7.3 6/26/92 270 20 12 4.1 1/27/93 180 <1 <1 <1 3/16/94 26.9 0 .944 1.3 1.32 9/13/94 <0.5 <0 .5 <0.5 <0.5 2/23/95 <0.5 <0.5 <0.5 <0.5 6 /2195 <0 .5 <0.5 <0.5 <:0 .5 ~ E 15ANCAC2L 1000 29 530 STAND.ARD (IN UG/l) rABLE 1 HISTORICAL GROUNDWATER AN> INFLUENT QUALITY DATA TO TAL EX BT ------- < < < < < < 1 0 0 0 . 0 0 .6 < 5 < 5 < 5 < ~ 3 < 1 < 46 1 3 <1 3 DEEP 1 16 3 28 T~ 5 1 70 2 D 7 .3 1 3 < < .1 5 5 306 eo 0 .5 0 0 .!: Q 5 N A FORMER UNOCAL FACILITY #93-42 -209 4336PARKROAO, CHARLOTTE, NC -·-·· MTBE l'E EDB 1,2-DCA -NA NA NA NA <1 NA NA NA <1 <1 NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 <0.02 <1 <0.5 <1 <0.005 <1 <0.5 <0.5 <0.005 <1 <0.5 <1 <0.01 <1 <0.5 <1 <0.01 <1 NA NA NA NA <1 NA NA NA <1 <1 NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 <0.02 2 _!ill WELL CC NVERTEDIN Q ANAIRS I ARGEWELL NA NA NA NA 80 NA NA NA <1 <1 NA <1 11 <1 NA 1li0 240 49 NA 110 220 97 <0.02 51 99 .4 <1 <0.005 68.1 4.46 <0.5 <0.005 25 .8 <0.5 <1 <0.01 24 6 <0.5 <1 <0 .01 11.55 -- 200 NA 4E-4 0 .36 ------- METHOO 601 COWOUN>S CHLORO-l 1, 1-DCE 1,1-0CA 1,2-DCP FORM - NA NA NA NA NA NA NA NA <1 <1 <1 <1 <1 <1 <1. <1 <1 <1 <1 <1 <1 <1 <1 <1 3 .38 <1 <1 <1 814 <1 <1 <1 853 1.96 <1 <1 11.11 _!A_ -~ <1 NA NA NA NA NA NA NA NA <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 --------------NA NA NA NA NA NA NA NA <1 <1 <1 <1 <1 <1 <1 2.2 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <!_ <1 <1 ~1 0.19 7 700 0.56 --- ·-... T~~-1 - P~~L~1-~cA NAPTHAj LENE NA NA NA NA NA NA NA NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 5 <10 <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 NA - NA NA NA NA NA NA NA NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 <10 NA NA NA NA NA NA NA NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 <10 <1 <1 <1 NA <1 <1 <1 NA <1 <1 <1 NA <1 .. .::1 <1 NA 28 0.7 200 21 ·- --=- MONITOR WELL DATE BENZENE TOLUENE ETHYL- BENZENE -MW-10 1/27/93 2 <1 1 (BB..K INVEST.) 3/16/94 1.58 <::0,5 <0,5 9/13/94 0.736 <0.5 1.14 2/23/95 1.12 <0.5 1.38 6/2/95 <0.5 <0.5 <0.5 MW-11 1/27/93 <1 <1 <1 (POP SHOP) 3/16/94 <0.5 <0.5 <0.5 9/13/94 <0.5 <0.5 <0.5 2/23/95 <0.5 <0.5 <0.5 -6/2/95 ~ ~ ~-.?. RW-1 1/27/93 NA NA NA 3/16/94 <0.5 <0.5 <::0.5 9/13/94 <0.5 <0.5 <0.5 2/23/95 <0.5 <0.5 <0.5 --RW-2 12/16/91 1300 <1 <1 1/27/93 1300 <1 <1 3/16/94 <0.5 <0.5 <0.5 9/13/94 <0.5 <0.5 <0.5 2/23/95 <0.5 <0.5 <0.5 RW-3 12/16/91 3 7 3 1/27/93 480 <1 <1 3/16/94 35.8 0.929 <0.5 9/13/94 45.4 2.10 <0.5 2/23/95 <'.0.5 <0.5 <0.5 - RW-4 1/27/93 4000 1200 200 3/16/94 36,5 56 10.5 9/13/94 49.1 41.7 1.32 Y,23/95 <0.5 <0.5 <0.5 ---·----INA.UENT 6/3/93 420 20 <1 (RW -1-4) 10/8/93 76 22 <1 1/13/94 76 <1 11 6/15/94 11.1 <0.5 <0.5 8/11/94 <8.10 <0.5 <0.5 c-~5 <0.5 1.13 <0.5 ·-- 15ANCACa 1 1000 29 STANDARD (IN UG,t.) TABLE 1 HISTORICAL GROUNDWAlEA ANl INFLUENT QUAUlY DATA FOAMER UNOCAL FACIUlY IJg342-209 4336PARKROAD, CHARLOTTE, NC -·---·-·---....:=:...,.=-·--~.-:-:--:::--·---•..: ___ j PE TOTAL XYlENES ~ 16 12.3 16.2 11.1 __ _!lL <1 <0.5 <::0.5 <0,5 <0.§_ NA <0.5 <0.5 <Q2__ <::1 300 <0.5 <0.5 _<05 __ 18 15 <0.5 <0 5 <0.5 3100 310 737 <0.5 -68 53 11 <0.5 <0.5 <0.5 530 TO TAL TEX e MTBE -~ -- - -- 1 1 1 2 1 3.9 8.1 36 11 < < < < N < < < 13 16 < < < 4 3 4 < 85 4 8 < -- - - -- <1 <0,5 <0.5 <0.5 <0.5 9 10.7 <5.24 6.54 <0.5 NA 4.94 0.86 7.98 880 860 4.46 6.16 11.3 <1 160 85.8 66.7 47.7 <1 11.1 41.1 2.76 ~-<1 <1 <0.5 <1 -__ <_1 <1 <1 <0.5 <1 <1 NA <1 <0.5 <1 <1 <1 <1 <0.5 <1 <1 67 5.62 6.23 4.12 <1 <1 <0.5 <1 4 <1 o 5 0 5 05 o s A 0.5 o s 0 5 00 00 05 05 05 31 95 6 7 7 5 05 00 13 29 05 08 51 8 -----5 1 9 11 8 1, 1 10 1~ NA -- 570 <1 170 16 120 NA 68.4 NA 31.2 3.71 5.99 NA 200 NA EDB 1,2-DCA CHLORO- FORM ---·-- 0.022 <1 <1 <0.005 <1 <1 <0.005 <1 <1 <0.01 <1 <1 ~ <1 <1 ----- <0.02 <1 <1 <0.005 <1 <1 o::0.005 <1 <1 <0.01 <1 <1 <0.01 <1 <1 - NA NA NA <0,005 1.33 <1 <0.005 2 32 1 22 0.2411 2.57 2.18 NA 230 1100 <0.02 68 <1 <0.005 <1 <1 <0,005 <1 <1 <0.01 <1 <1 --NA <1 <1 <0.02 520 <1 <0.005 20 <1 <0.005 14.8 13 -<0.01 15.5 _ <1 <0.02 1400 <1 4.05 13.1 2.21 32.1 41 7 1 29 0.052CI 4.44 4.511 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA .. 4E-4 0,311 0.19 ·-·---· ... METHOD ll01 COMPOUNlS 1,1-DCE 1,1-DCA 1,2-DCl" TCE -•--·- <1 <1 <::1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 ~!_ <1 <1 ----------· ~ -- <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 -~ <1 <1 <1 -------·- NA NA NA NA <1 <1 <1 <1 <1 <1 <1 <1 <::1 <::1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 ---- <1 <1 <1 1 <1 <1 7 <1 <1 <1 <1 <1 <1 <1 <::1 <1 <::1 <1 <1 <1 - <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 1.24 <1 <1 <1 <1 <1 ---- NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 7 700 0.56 2.8 ~~ ..;:.s..-=--....., ~~-~---~ ~ --- -.....:=:::-·--=--..==- NOTES: • ALL CONCENTRATIONS IN GROUNDWATER ARE IN UG/L • ANALYSES PERFORMED=METHOOS 602 (BTEX, MTBE AND IPE) METHOD 504 (EDB) • NA= NOT AVAILABLE METHOD 601 (PURGEABLE HALOCARBONS) METHOD 625 (BASE/NEUTRAL EXTRACTABLES) • THE 15A NCAC 2L GROUNDWATER STANDARD FOR COMPOUNDS NOT INCLUDED IN THE STANDARD IS THE METHOD DETECTION LIMIT 0.2411 = CONCENTRATION IS ABOVE THE STATE 15A NCAC 2L STANDARD PCE <1 <1 <1 <1 <1 <1 <1 <1 <1 <'.1 NA <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NA NA NA NA NA NA 0.7 1,1,1-TCA <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 ----- NA <1 <1 <1 ------ <1 <1 <1 <1 <1 <'.1 <1 <1 <1 <1 <1 <1 <1 <1 NA NA NA NA NA NA 200 NAPTHA- LENE 33 NA NA NA NA <10 NA NA NA NA <10 NA NA NA NA 74 NA NA NA NA <10 NA NA NA <10 NA NA NA NA NA NA NA NA NA 21 --'~ .• 2670 ' FLOWERS CHEMICAL LABORATORIES I ANALYTICAL RESULTS FORM HRS Nu rrt>e r 83 119 a -~ MW-7 MW-6 MW-10 MW-11 MW -1 MW-5 -MW-9 tr p blk. QA Section Paramet er Sv!Tbcl Unit 10061 10062 10063 10064 10065 10066 10067 10068 Method MDL %RSD %Rec Anal "' Date Dllullon Faci01 # 1 1 1 1 1 1 1 1 EP A60 1 1 DD 06-05-95 1 1 1-trichloroelhane . Ulll\. <1 <1 <1 <1 <1 <1 <1 EPA60I I 2.89 92.2 DD 06-05-95 1 1.2 2-telrachloroethano • uaA. <1 <1 <I <1 <1 <I <1 EPA60 1 1 2.12 87.2 DD 06-05-95 1 1 2-trlch loroelhane . uQ/1. <1 <1 <1 <1 <1 <1 <1 i::PA601 t 2.06 M.9 nn ""-"5-95 1 1-dlchlo/oethane . uni\. <1 <1 <1 <1 <I <1 <1 EPA60 1 1 4.35 85.2 00 06-05-95 1 1-dlchloroelhene . uaA. 1.27 <1 <1 <1 <1 <1 <I EP .t.60 1 1 0.0367 82.6 DD 06-05-95 1 2-dlchlor,:,elhane . unll. <1 <1 <1 <1 <I <1 9.55 EP"""l 1 2.75 85 .1 DD 06-05-95 1 2-dlchlcirm.,....,ne . ,...,,. <1 <1 <1 <1 <1 <1 <1 EP .t.80 1 1 3.16 87 DD 06-05-95 2-chloroeihvMn'llether . ltJllll <1 <1 <1 <1 <1 <1 <1 EPAa>1 1 00 06-05-95 Bromod k:hlommalhane . luan. <1 <1 <1 <1 1<1 <1 <1 FPilll1 I 2.37 86 on 06-05-95 Bromol01 m . IUQ/1._ <1 1<1 <1 <1 <1 <1 <1 EPA601 1 4.95 82.3 DD 06-05-95 ds-1 3-d ich1,vnn,"""'"" . luai\. <1 <1 <1 <1 <1 <1 <1 EP A60 1 1 1.74 M.8 IX) 06-05-95 Carbon lelrachlorlde . lun/1 <1 <1 <1 <1 <1 <1 <1 IEP.......,1 t 4.97 89,2 nn ""-05-95 Chlordorm . '""' 11.6 <1 <1 <1 <1 <1 <1 EPA601 1 3.48 88.1 00 06-05-95 Dl>romoc!>loromem ane . UM <1 <1 <1 <1 <1 <1 <1 EPA601 1 1.79 86.3 DD 06-05-95 Met hvlen• chloride . ua/1. <1 <1 <1 <1 <1 <1 <1 EPA601 1 2.8 87.2 DD 06-05-95 trans-1 .3.-dlch lDmnr,....n, • unit <1 <1 <1 <1 <1 <1 <1 EPA601 1 1.64 86.5 DD 06-05-95 Trk:hlorotluoromethane . ,.,,n <2 <2 <2 <2 <2 <2 <2 EPA601 2 0,384 80.1 00 OfH>5-95 1-1 . 2-dk:hlcroetha ne . '""' <1 <1 <1 <1 <1 <1 <1 IE PA601 1 4.73 86.4 rn 06-05-95 Trk:hloroelhene . ua/1. <1 <1 <1 <1 <1 <1 <1 EPA601 1 2.04 86.2 00 06-05-95 Telrachloroelhene . ,...,,. <1 <1 <1 <1 <1 <1 <1 EPA601 1 3.1 85.9 DD 06-05-95 1 ?-dbr-"-cll""""'"" • ,.,,. <1 <1 <1 <1 <1 <1 <1 IEP""'"1 1 2.59 101 DD 06-05-95 Bromorne!hana . nru\ <5 <5 <5 <5 <5 ,5 <5 EPA601 s DD 06-05-95 Chloroelhane . ,.,,. <3 <3 <3 <3 <3 <3 <3 EPA601 J 1.33 90.9 DD 06-05-95 Chlorornet ha ne . '""' d, <5 <5 <~ <5 <~ <5 FPAM1 Is DD 06-05-95 Olchlorodlfluoromethane . , ... <2 <2 <2 <2 <2 <2 <2 EPA601 2 IX) 06-05-95 Vln vl clllorlde . '""' <0,5 <0.5 <0.5 <0.5 <0 5 <0 5 <0.5 EPA601 0,5 IX) 06-05-95 Hal Snlke . , ... 100 98.7 97.7 97.6 97.3 97 .6 98.7 94.6 EP -"""1 05 1.83 104 DD ""-""'-0~ o-dk:hlorooenzane . lurut <0.5 <0.5 <0,5 <0,5 <0.5 <0.5 <0.5 <0.5 EPA602 0.5 2.19 83.7 00 06-05-95 m-dlchlorobenzene . unl1. <0.5 <0.5 <0.5 <0.5 <0.5 <0 .5 <0.5 <0.5 EPA602 0,5 1.55 83.3 DD OfH>5-95 Para-dlchlorobenzene . ,.,,. <0 .5 <0.5 <0.5 <0.5 <05 <0 ,5 <0.5 <0 .5 EPARIY.> 0.5 1.18 84 DD 06-05-95 Benzene . luan. <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 EPA602 05 3.37 84.8 DO 06-05-95 Chlordle nzene . .... <0.5 <0.5 <0.5 <0.5 ,:0.5 <0.5 <0.5 <0.5 EPA602 0.5 3.95 85.5 DO 06-05-95 Elhllhnzene . ua/L l,0,5 <0.5 <0.5 <0.5 .n s <0 .5 <0.5 <0.5 i:pun~ 0,5 3.37 82.2 DO 06-05-95 Toluene . ua/1. <0.5 <0.5 <0,5 <0.5 <0.5 <0 .5 <0.5 <0.5 EPA602 0.5 3.13 83.8 DO 06-05-95 xvw.e . , .... <0.5 <0.5 11.4 <0.5 <0,5 <0 ,5 <0.5 <0.5 EPJ\602 0 .5 3.34 81.8 DO 06-05-95 Meth\l ~ten-bulvlAl her . uo11 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 EPA""' 0.5 3.41 103 DO 06-05-95 Total BTEX ,,,,~ <0.5 <0.5 11.4 <0.5 <0.5 <0.5 <0.5 <0.5 EPA602 0.5 3.31 82.7 DD 06-05-95 I knnm,wlether . U<II\.. <1 <1 <1 <1 <I <1 <1 <1 EPA602 1 DO 06-05-95 PIO Solke . un~ 105 104 104 103 103 103 104 102 EP.t.602 0 ,5 1.82 105 DO 06-05-95 . -- Eth ylene dlbrorride . uoll. <0.01 <0.01 <0.01 <0.01 <0.01 <0 .01 <0.01 -EPA!i<l'.1 0.01 027'1Yv:N 93.22448, m 06-06-95 Date Received: 06-05-95 Tvoed: 06-06-95 Sent: 06-06-95 Projec1 Number UNOC 9342-209 PO Number AFE#35893143 Dale Sampled 1 06-02-95 ' Dale Analyzed 0 'Compacted 1 Format NormRR Unit Cost Exted ~1/602/IPE 11000 7 • :mFI . .,,,, 7 • IEPA602 Discount 000 'iOO -.,1950 1. 1. ·. ~ r=LOW~l2§ Ct-f~IC~L ~ LAl30l?AT0l21~§~1~C. Section 3 Method Blank Report Analyte ii -~ . ,~ . -~-.,;. "'1~ • Eth y l benzene Toluene Xylene Client: S&ME-Charlotte Project Number: UNOC 9342-209 P.O. Number: AFE#35893143 Date Sampled: 2-Jun-95 Lab Numbers: 10061 -10068 Unit Method . , -- Date pt. -.. ' ' '' ugJ L EPA602 06-05-95 ug/L EPA602 06-05-95 ug/L EPA602 06-05-95 Meth y l-tert-buty lether ug/L EPA602 06-05-95 Total BTEX UQ/L EPA602 06-05-95 lso p ro py lether ug/L EPA602 06-05-95 Eth y lene dibromide ug/L EPA504.1 06-06-95 Conc~ntr~ <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 MEMORANDUM: DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION September 14, 1995 TO: Barbara Christian, Regional Hydrogeologist FROM: Arthur Mouberry, P.E., Chief ~ SUBJECT: Request for a Variance from the 15A NCAC 2L Corrective Action Requirements and Groundwater Standards for the Unocal Corporation (Groundwater Incident# 3633). On March 31, 1995 the S&ME Corporation submitted a request for a "variance" on behalf of Unocal Corporation to the Mooresville Regional Office. You will recall this request was for a variance from Corrective Action requirements of 15A NCAC 2L .01060) and Groundwater Quality Standards in 15A NCAC 2L .0202. On August 25, 1995 the environmental consultant sent the request addressed to the Mooresville Regional Office to the Director of the Division of Environmental Management for review .. Pursuant to 15A NCAC 2L .0113 (b) and the March 18, 1993 memorandum 11 2L Variance Request" this variance application does not meet the requirements of 15A NCAC 2L .0113. This rule specifically states that a variance application " ... shall be sent to the Chairman of the Environmental Management Commission in care of the Director, ..... " as shown in 15A NCAC 2L .0113(b). In addition, the consultant did not provide the necessary information to.meet the requirements of 15A NCAC 2L .0113(c)(5). In providing supporting information to establish that the requirements of the rule cannot be achieved using best available technology, the person requesting -the variance did not give an estimate of the costs of implementing that technology as required in the rule. The variance request must provide a projection of remediation costs if efforts were to continue for a period of years with the current technologies being use~ at the site. If other best available technologies exist and are deemed appropriate for this site, an evaluation of the cost of those technologies should also be examined. For these reasons, this request will be returned to the responsible party. Attached is a response letter informing the environmental consultant for the Unocal Corporation that this variance does not conform with the requirements of 15A NCAC 2L .0113. If you need additional information, please contact David Hance at (919) 715-6189 . cc: Arthur Mouberry Carl Bailey David Hance Allen Schiff identified specific technology used at the site but did not elaborate on the costs of implementing that particular technology. This information must provide a projection of remediation costs if efforts were to continue for a period of years with the current technologies being used at the site. If other best available technologies exist and are deemed appropriate for this site, an evaluation of the cost of those technologies should also be examined. The additional information in items # 1 through # 2 must be provided so that the Groundwater Section can properly evaluate the variance request and verify to the Director that it meets the requirements of 15A NCAC 2L .0113 (c). Once the Groundwater Sectfon deems a variance request has met these requirements, it can proceed to the Director for review in accordance with 15A NCAC 2L .0113 (d). For these reasons the request is being returned to you. If you wish to pursue a variance to the Subchapter 2L rules you will need to submit information that addresses items #1 through #2. If you have any questions concerning this letter, please contact Mr. Allen Schiff, Mooresville Regional Office, Groundwater Section, at (704) 663-1699. APH/AM/dah cc: Arthur Mou berry Carl Bailey Burrie Boshoff Sincerely, Arthur Mouberry, P. E., Chief, Groundwater Section Mooresville Regional Groundwater Supervisor David Hance 2 T R A I·-~ 5 M l ::. '·, l 1 ~ ~ ~: E F' I) F.'. T ~1 1 • •?l 1 • 2 ~:1 (1 (1 .•• E October 4, 1996 Mr. David Hance P.O. Box 29578 Raleigh, NC 27626-0578 RE: Proposed Groundwater Sampling and Analyses Schedule After Variance Approval Incident #3633, Priority Ranking BOE Unocal Corporation (Former Station #9342-209) 4336 Park Road, Charlotte, NC · S&ME Project No. 1354-92-397 Dear Mr. Hance: ..... ,. '.,C') ( -~ - S&ME, Inc., on behalf of Unocal Corporation; hereby informs the North Carolina Environmental Management Commission that Unocal Corporation proposes.to monitor groundwater quality on-site and on two adjacent off-site properties for two years following Variance approval by the State. The State's October 1, 1996 Notice of Variance Application and Hearing requires the hydrocarbon compounds above the 2L groundwater standards to remain within the former Unocal property boundaries of 4336 Park Road. Our proposed monitoring would further evaluate groundwater compliance within the Variance boundary area (former Unocal facility) at selected on-site monitor and former recovery wells (M-5, MW-7, MW-9, RW-1, and RW-4). S&ME, Inc. proposes to sample groundwater from these 5 wells on a semi-annual basis for two years after Variance approval. Groundwater from these wells will be analyzed for EPA Methods 601, 602 (including MTBE) and 504. 1 for EDB, since these compounds were detected above the 2L groundwater standards. The results will be added to the attached historical groundwater and influent quality data Table 1 and presented to the State and Unocal Corporation. After the two years of groundwater nonitoring, no further monitoring or action may be requested. S&ME, Inc. 9751 Southern Pine Boulevard, Chorlorte, North Carolina 28273, (704) 523-4726, Fox (704) 525-3953 Moiling address: P.O. Box 7668, Chorlorte, North Carolina 28241-7668 NCDEHNR-Groundwater Section S&ME Project No. 1354-92-397 Proposed Groundwater Monitoring After Variance Approval, Un~cal-Park Rd. October 2, 1996 If you have any questions, please call me at 704-523-4726. Sincerely, S&ME, Inc. Stewart Hines, LG. Senior Hydrogeologist ~~ Al Quarles, LG. Assistant Environmental Services Manager cc: Wayne Holt -Unocal Corporation K:\. .. \1996\HANCE.02 2 State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director A~A D E HNR October 3, 1996 Dear Groundwater Rules Mailing List Recipient, Attached is a public notice to inform you that the Division of Water Quality (DWQ) is holding a public hearing on a proposed variance by the Unocal Corporation (DWQ Groundwater Incident Number 3633). This proposed variance is for property located at 4336 Park Road in Charlotte, North Carolina. This notice is being sent to persons, firms and corporations on the Groundwater Rules Mailing List who work or reside within the Charlotte metropolitan area and Mecklenburg County. The notice is being sent to persons with an interest in environmental protection, groundwater cleanup, environmental consulting, trade and industrial regulatory issues, and persons with an interest in proposed variances that affect the petroleum industry. Additional information about the proposed variance and the procedures necessary to contact the agency are found in the attached notice. If you have any questions, please contact David Hance at (919) 715-6189. cc: Arthur Mouberry Dr. Burrie Boshoff Sincerely, *M~ M. Carl Bailey, Jr. Assistant Chief for Planning, Groundwater Section Mooresville Regional Groundwater Supervisor David Hance Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N!iC !fMtf1r1iW Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/Affirmative Action Employer 50°1o recycles/10"/o post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A Preston Howard, Jr., P.E., Director Tucker Pearsall Legal Advertising The Charlotte Observer P.O. Box 32188-28232 Charlotte, NC 28232 Dear Mr. Pearsall: .A.VA DEHNR October 1, 1996 The Department of Environment, Health, and Natural Resources will be holding a Public Hearing on behalf of the Division of Water Quality to receive public comment on a proposed variance to groundwater rules for the Unocal Corporation site at 4336 Park Road in Charlotte, North Carolina. You will find enclosed a Public Notice regarding the meeting. It is requested that you publish the Public Notice in the Sunday, October 6, 1996 issue. Publication charges will be paid by this office upon receipt of your invoice, affidavit, and proof of publication. Please send the invoice in triplicate and the affidavit in duplicate to the following individual: Enclosure cc: David Hance Ms. Francis Cotten, DWQ-Budget Office 512 N. Salisbury Street P.O. Box 29535 Raleigh, NC 27606-0535 (919) 733-7015 (ext# 231) Sincerely, /171~~ M. Carl Bailey, Jr., Assistant Chief for Planning, Groundwater Section DWQ-Public Information Officer Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N!JC ,,emaee Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50% recycles/10% post-consumer paper NOTICE OF VARIANCE APPLICATION AND HEARING DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES DIVISION OF WATER QUALITY Notice is hereby given of a variance application and public hearing to be held by the Depart.ment of Environment, Health and Natural Resources on behalf of the Environmental Management Commission. The hearing concerns a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and the Corrective Action requirements of 15A NCAC 2L .0106 (j) for a site at 4336 Park Road in Charlotte, North Carolina. The Division of Water Quality refers to this site identified in the variance request as Groundwater Incident # 3633. This property, previously owned by the Unocal Corporation of Atlanta, Georgia, is now owned by the DH&S Company (Petro Express). The Unocal Corporation is entirely responsible for cleanup for Groundwater Incident # 3633. This variance application from the Unocal Corporation was received for review by the Department on September 29, 1995. The property where the release of petroleum product has occurred is located as follows: Inside the city limits of Charlotte, North Carolina. Take Interstate 85 to Interstate 77 south and travel four and one-half miles south on Interstate 77 and take the Woodlawn Road (City Highway 4) exit and travel east toward downtown Charlotte. This site at 4336 Park Road is located two miles east at the comer of Woodlawn Road and Park Road. This site is listed in Mecklenburg County tax records as Parcel Number 143-203-24. The Unocal Corporation requests that the Environmental Management Commission grant the following variance to its rules under the authority of 15A NCAC 2L .0113 so that it does the following: (1) Allow concentrations of Benzene, Toluene, Ethylbenzene, Xylene (-o,-m, and p), Naphthalene, Methyl Tert-Butyl Ether (MTBE), Isopropyl Ether, Ethylene Dibromide, 1,1-Dichloroethane, 1,1- Dichloroethene, 1,2-Dichloroethane, l,l,1,-Trichloroethane, l ,l,2,2,-Tetrachloroethane, 1,1,2- Trichloroethane, 1,2-Dichloropropane, Bromodichloromethane, Bromoform, cis-1,3- Dichloropropene, Carbon Tetrachloride, Chloroform, Dibromochloromethane, Methylene Chloride, trans-1,3-Dichlorobenzene, 1,4-Dichlorobenzene, and Chlorobenzene to remain at levels above 15A NCAC 2L .0202 standards as analyzed in December 1995. These concentrations will be required to remain within the property boundaries of 4336 Park Road. The property at 4336 Park Road, for which the Unocal Corporation has cleanup responsibilities under Groundwater Incident Number 3633, consists of approximately 1.05 acres of land. The Unocal Corporation operated a retail gasoline station at this site from the 1950s to 1987. In 1987 the Unocal Corporation sold this property to DH&S Company. In 1988 this site was renovated and old tanks removed so that a new gasoline station, known as the Petro Express Gasoline Station # 7, could be built at this site. This property is located in an area with a mixture of commercial, industrial, and residential development. Almost all the land area at this site is covered by buildings and paved parking lots. 1 Pursuant to the transfer of property to the DH&S Company and the removal of the underground storage tanks at 4336 Park Road, the Unocal Corporation discovered a release of an unknown quantity of gasoline. A site assessment and corrective action plan for this site was submitted on March 18, 1993 and is kept on file at the Mooresville Regional Office. The site assessment revealed a plume of groundwater and soils contamination originating from free product gasoline near the south property line. The plume of substances that came from the release of gasoline was estimated to have covered an area of 61,250 square feet (1.406 acres), prior to the implementation of corrective actions. On August 12, 1993 the Unocal Corporation implemented cleanup at this site. The plan called for the implementation of a pump-and-treat groundwater cleanup system, an air sparging system for soils and subsurface materials, and soil vapor extraction. Pump-and-treat technology uses a pump to convey contaminated groundwaters from beneath the land, treats these groundwaters to remove contaminants, and returns the treated water to a permitted discharge. Air sparing relies on the introduction of air to separate volatile substances from subsurface materials. Soil vapor extraction uses suction to remove contaminants from soils. Use of soil vapor extraction is intended to reduce contaminant levels in soils without requiring the removal and treatment of soils offsite and the introduction of new or treated fill materials. The Charlotte-Mecklenburg Utility Department issued a permit to discharge treated water from the pump-and-treat groundwater remediation system into the nearby sanitary sewer. These cleanup technologies were in operation from August 12, 1993 through September 29, 1995. The Division of Water Quality required the Unocal Corporation to perform groundwater monitoring to determine the vertical and lateral extent of contamination. Since January 13, 1988 monitoring has been conducted at six on-site wells located at 4336 Park Road. Benzene was found in five of six on site monitoring wells on December 16, 1991. The highest concentration of Benzene found in a monitoring well, prior to implementation of groundwater cleanup, was 8 .10 milligrams per liter found in Monitoring Well# 5 during the December 16, 1991 sampling event. The Groundwater Quality Standard for Benzene in 15A NCAC 2L .0202 is 0.0001 milligrams per liter. Concentrations of Ethylbenzene, Toluene, Xylene and Chloroform were also found in Monitoring Well # 5 significantly above the Groundwater Quality Standards in Title 15A NCAC 2L .0202. Monitoring well # 5 is located within 15 feet of the south property line and is located in the area in which the release of gasoline was discovered. On January 27, 1993 two additional monitoring wells were constructed off-site. A downgraidient monitoring well was located to the east at the Pop Shop (Parcel Number 17 5-181-06). Another off-site well was located to the south at Belk Investments (Parcel Number 171- 043-021 ). Analysis of groundwater samples from these two off-site wells have not shown concentrations of substances above the Groundwater Quality Standards in 15A NCAC 2L .0202 from the time these wells were installed in January 1993 through the December 1995 groundwater sampling. The Division also required Unocal Corporation to evaluate the effectiveness of groundwater cleanup efforts by examining concentrations of substances in recovery wells beginning December 16, 1991. Recovery wells at the 4336 Park Road site are used as sumps to collect groundwater, free product, and dissolved hydrocarbons from the site for treatment. Pumps convey this fluid to the treatment system. Samples were obtained from four recovery wells located beneath the parking lot and the area that formerly had the Unocal Corporation service station and pump islands. Since cleanup was initiated on August 12, 1993 significant reductions in concentrations of substances was observed in groundwater samples taken from the recovery wells . Results from 1994 demonstrated reductions in the concentrations of substances had occurred at this site since the implementation of cleanup. 2 From August 12. 1993 through September 13, 1994 the concentration of substances at this site were significantly reduced by groundwater cleanup technologies located at the site. Through 1995 analysis of samples from monitoring wells showed only marginal reductions in the concentration of substances in groundwater. Analysis of groundwater samples taken on February 23, 1995 and on June 2, 1995 showed there was no significant increase or decrease in concentrations of Benzene and other substances at on-site monitoring wells, while cleanup operations were being conducted. Except for Chloroform in Monitoring Well# 7 and 1,2-Dichloroethane in Monitoring Well# 9 at concentrations above the Groundwater Quality Standards, no other substances were reported in the other monitoring wells during this time. Based on groundwater analysis of samples from winter and summer monitoring events in 1995, the Division of Water Quality recommended that pump-and-treat, air sparging and soil vapor extraction technologies be turned off to determine if residual contaminants in the soils and subsurface would recontaminate the groundwater, if no treatment system were operating. In December 1995 groundwater monitoring was conducted at recovery wells and monitoring wells after the pump-and- treat system had been temporarily turned off. Only two of seven monitoring wells had concentrations of substances in exceedence of Groundwater Quality Standards in 15A NCAC 2L .0202. Monitoring well# 5 had Benzene at 0.00863 milligrams per liter, Ethylene Dibromide at 6.52 x 10-4 milligrams per liter, and 1,2-Dichloroethane at 0.00615 milligrams per liter. The maximum concentration of these substances allowed under the Groundwater Quality Standards pursuant to 15A NCAC 2L .0202 is as follows: Benzene at 0.0001 milligrams per liter, Ethylene Dibromide at 4.00 x 10-4 milligrams per liter, and 1,2-Dichloroethane at 0.0003 milligrams per liter. A sample from Monitoring Well# 9 showed 0.00447 milligrams per liter of 1,2-Dichloroethane. No substances were detected at Monitoring Well# 7 from the December 1, 1995 sampling event. Analysis of samples from the remaining monitoring wells reported Benzene, Chloroform, Ethylene Dibromide, and 1,2- Dichloroethane at concentrations below quantitation limits. The downgradient monitoring well located offsite to the east at the Pop Shop and the monitoring well located to the south at Belk Investments have ne¥er shown concentrations of any substance above the groundwater Quality Standards in title 15A NCAC 2L .0202 (Groundwater Quality Standards). Concentrations of Benzene in all four recovery wells did not show a significant decrease or increase during December 1995. Samples from two of the four recovery wells continued to show levels of 1,2-Dichloroethane above Groundwater Quality Standards. The highest concentration of 1,2-Dichloroethane from a December 19, 1995 sampling event was 0.0197 milligrams per liter in Recovery Well# 4. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.0003 milligrams per liter. Monitoring wells at this site have shown insignificant reductions in Benzene as a result of using pump-and treat, air sparging, and soil vapor extraction technologies. Although concentrations of substances appear to be decreasing in recovery wells, significant reductions in the concentration of 1,2-Dichloroethane have not been observed in recovery wells. No significant increase in concentrations of substances was observed as a result of the temporary cessation of pump-and-treat operations. The Unocal Corporation has submitted supporting information showing that the variance will not endanger public health, safety, or the environment. No known sources of drinking water from water wells or surface water supplies are known to exist within a ½ mile radius of this property. Based on groundwater flow information obtained during the Comprehensive Site Assessment, it is believed that the contaminant plume is moving to the e&1. The Unocal Corporation has calculated the time it will take Benzene, Ethylbenzene and 1,2-Dichloroethane to reach Little Sugar Creek at 3 concentration levels that would exceed Groundwater Quality Standards is between 93 and 280 years. Little Sugar Creek discharges into Sugar Creek which is a tributary of the Catawba River. All residents in the area are supplied drinking water from the City of Charlotte. Information provided by the Charlotte-Mecklenburg Utilities Department indicates that the public water supply lines in this area are at an average depth ofless than five feet from the ground surface. Groundwater occurs at 4336 Park Road at a depth of seventeen feet beneath the property. Water supply lines are not located deep enough in the ground to be impacted by this variance. 2) Allow for the restoration of groundwater without requiring remedial actions in accordance with ISA NCAC 2L .01060). The Unocal Corporation has submitted supporting information demonstrating that the continued application of best available technology will not result in significant long term remediation of the site to the Groundwater Quality Standards contained in ISA NCAC 2L .0202. This is due to the high probability that continued remediation activities at the site will not significantly reduce contaminant levels below Groundwater Quality Standards in 15A NCAC 2L .0202. Since corrective actions were implemented on August 12, 1993 the Unocal Corporation has extracted a total of 3,050 pounds of petroleum hydrocarbons from contaminated soils and groundwater. The mass of petroleum extracted from soils and subsurface materials is approximately 3,000 pounds. The Unocal Corporation has treated an estimated 4.12 million gallons of groundwater via pump-and-treat technology which accounts for 50 pounds of material removed. The company reports that a total of $313,500 has been spent by the Unocal Corporation to cleanup the release described in Groundwater Incident # 3633. No claims for reimbursement through the state's Commercial Underground Storage Tank Trust Fund have ever been filed by the Unocal Corporation for funds spent on this site. The Unocal Corporation estimates that continued operation of the current groundwater and soil cleanup system over the next three years will be approximately $180,000. The Unocal Corporation has shown that when the operation of groundwater remediation systems at the site was temporarily interrupted, no increase in the concentration of any substance above groundwater standards was observed in off-site monitoring wells from monitoring data. The company asserts that marginal increases observed for some chemicals in two of the on-site monitoring wells, when the cleanup systems were not in operation, demonstrates that continued implementation of pump and treat, air sparging and soil vapor extraction will not result in a significant reduction in contaminant concentrations at this site. The Unocal Corporation has considered the use of air sparging as an alternate technology to the current groundwater remediation system. The company does not believe this technology is economically reasonable or practical to meet the requirements of ISA NCAC 2L .0113(c)(5). The estimated cost of implementing air sparging is approximately $45,000. The company asserts that continued reliance on air sparging is not economically justified due to the low residual concentrations of substances at this site with the lack of groundwater consumption by humans. 4 .... _..... State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Park Road Shopping Center, Inc. 4201-A Park Road Charlotte, NC 28209 AVA D E HNR October 2, 1996 REGARDING: Parcel Number 175-181-07 (Hardees Restaurant) and Parcel Number 175-181- 06 (The Pop Shop) TO WHOM IT MAY CONCERN: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and Corrective Action requirements of 15A NCAC 2L .0106(j). 15A NCAC 21 .0113(e)(l)(E) requires adequate notice be given to area properties and adjacent property owners prior to hearing. You will find enclosed a Public Notice regarding the variance hearing. Please refer to the enclosure for additional information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189. Enclosure Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 Nlf)C !fftti'ft«e Sincerely, ~(02_~ M. Carl Bailey, Jr. Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50% recycles/lCl°k post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Mr. John Petoskey Tax Administrator City of Charlotte -Tax Office 720 E. Fourth Street Charlotte, NC 28202 Dear Mr. Petoskey: NA DEHNR October 2, 1996 The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and Corrective Action requirements of 15A NCAC 2L .0106G) {Groundwater Classifications and Standards). 15A NCAC 2L .0113(e){l){E) requires adequate notice be given to area properties and adjacent property owners prior to hearing. A vacant house is located adjacent to the property for which the variance has been requested. This property is located at 1348 Woodlawn Road (Parcel Number 171-044-15) The only information available to us is that this house has been vacant for many years. You will find enclosed a Public Notice regarding the variance hearing. Please refer to the enclosure for additional information. If the city tax listing reveals an owner or owners for this property, please forward this public notice to them so that they may be advised of the variance request and hearing in the attached notice. Enclosure Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N{;C frZT&'tli®' Sincerely, ~::1~~ Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirnative Action Employer 50"/o recycles/10"/o post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director The Pop Shop 4323 Park Road Charlotte, NC 28209 .AVA DEHNR October 2, 1996 REGARDING: 4323 Park Road j Parcel Number 175- 181-06 ! TO WHOM IT MAY CONCERN: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and Corrective Action requirements of 15A NCAC 21 .0106(j). 15A NCAC 21 . 0113( e )( 1 )(E) requires adequate not ice be given to area properties and adjacent property owners prior to hearing. You will find enclosed a Public Notice regarding the variance hearing . Please refer to the enclosure for additional information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189. Enclosure Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0S78 2728 Capital Blvd., Raleigh, North Carolina 27604 N~C ·mm1t1?W1 Sincerely, /j//l~~ M. Carl Bailey, Jr . Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50'/o recycles/ l O"/o post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Nationwide Insurance 4320 Park Road Charlotte, NC 28209 AVA D E HNR October 2, 1996 REGARDING: 4320 Park Road In Charlotte, NC l Parcel Number 149-203-25 ! TO WHOM IT MAY CONCERN: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 21 .0202 and Corrective Action requirements of 15A NCAC 21 .0106(j). 15A NCAC 21 .0113(e)(l)(E) requires adequate notice be given to area properties and adjacent property owners prior to hearing. You will find enclosed a Public Notice regarding the variance hearing. Please refer to the enclosure for additional information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189. Enclosure Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N~JC ·1e1.aee, Sincerely, ~M &:;;}, M. Carl Bailey, Jr. Assis t an t Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 AA Equal Opportunity/ Affirmative Action Employer 50% recycles/10"/4, post-consumer paper . . State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Marian Bass Properties 4000 Park Road Charlotte, NC 28209 .AWA D E HNR October 2, 1996 REGARDING : Park Chase Apa r tmen t s at 1351 Wood lawn Road in Charlotte, NC l Parcel Number 149-203-20! TO WHOM IT MAY CONCERN: The Department of Environment , Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and Corrective Action requirements of 15A NCAC 2L .0106(j). 15A NCAC 2L .0113( e )( 1 )(E) requires adequate no ti ce be given to area properties and adjacent property owners prior to heari_ng . You will find enclosed a Public Not ice regarding the variance hearing. Please refer to the enclosure for additiona l information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189 . Enclosur e Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N!;C f&iWiifsmmee Sincere ly, ?te..t!~ M. Carl Bailey , Jr . Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affinnative Action Employer 50% recycles/ 10% post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Kilian Realty 12700 Statesville Road Huntersville, NC 28078 AVA DEHNR October 2, 1996 REGARDING : 4320 Park Road In Char lotte , NC j Parce l Number 149-203-25 ! TO WHOM IT MAY CO NCERN: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 21 .0202 and Corrective Action requirements of 15A NCAC 21 .0106(j). 15A NCAC 21 .0113( e )( 1 )(E) requ ires adequate not ice be given to area properti es and adjacent property owners prior to hearing . You will fi nd enclosed a Publi c Not ice regarding the va r iance hea ring . Pleas e refer to the enclosure for additional information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189. Enclosur e Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N(;C uzmth@t!ilil Sincerely, -'},//{!,,,__(}~ M. Carl Bailey, Jr. Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50% recycles/ 10"/4 post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Hardees Restaurant 4335 Park Road Charlotte, NC 28209 AVA DEHNR Octa ber 2, 1996 REGARDING: 4335 Park Road l Parcel Number 175- 181-07 ! TO WHOM IT MAY CONCERN: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and Corrective Action requirements of 15A NCAC 2L .0106(j). 15A NCAC 2L . 0113( e )( 1 )(E) requires adequate notice be given to area properties and adjacent property owners prior to hearing. You will find enclosed a Public Notice regarding the variance hearing. Please refer to the enclosure for additional information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189. Enclosure Groundwater Section, P.O. Box 29578, Raleigh , North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N{'JC f1Tfi'NttiW Sincerely, /JI-?~~ M. Carl Bailey, Jr. Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50"/4 recycles/ l 0% post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Exxon Company, USA P.O. Box 30451 Charlotte, NC 28230 AVA DEHNR October 2, 1996 REGARDING: Exxon Gasoline Station at 125 Woodlawn Drive jParcel Number 175-141-0l! TO WHOM IT MAY CONCERN: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 21 .0202 and Corrective Action requirements of 15A NCAC 21 .0106(j). 15A NCAC 21 .0113(e}(1)(E) requires adequate notice be given to area properties and adjacent property owners prior to hearing. You will find enclosed a Public Notice regarding the variance hearing. Please refer to the enclosure for additional information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189. Enclosure Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N!)C ,,ma·ee, Sincerely, ~c!....c ~ M. Carl Bailey, Jr. Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50% recycles/ l O"k post-consumer paper . . State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A, Preston Howard, Jr., P.E., Director .A.VA DEHNR October 2, 1996 North Carolina Department of Transportation P.O. Box 190 Newell, NC 28126 ATTENTION: Mr. Don Spence Dear Mr. Spence, REGARDING: The Corner of Woodlawn Road and Park Road at 4336 Park Road in Charlotte, N.C. The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and Corrective Action requirements of 15A NCAC 2L .0106(j). 15A NCAC 2L .0113(e)(l)(E) requires adequate notice be given to area properties and adjacent property owners prior to hearing. You will find enclosed a Public Notice regarding the variance hearing. Please ref er to the enclosure for additional information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189. Enclosure Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N!)C f1W1'f@1M Sincerely, ~~~ M. Carl Bailey, Jr. Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/ Affirmative Action Employer 50"k recycles/10"/o post-consumer paper . ' State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Belk Investments 4400 Park Road Charlotte, NC 28209 -A.~A DEHNR October 2, 1996 REGARDING: Parcel Number 171-043 -21 j 4400 Park Road! TO WHOM IT MAY CONCERN: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 21 .0202 and Corrective Action requirements of 15A NCAC 21 .0106(j). 15A NCAC 21 .0113( e )( 1 )(E) requires adequate notice be given to area properties and adjacent property owners prior to hearing. You will find enclosed a Public Notice regarding the variance hearing. Please refer to the enclosure for additional information. If you have any questions concerning this variance request, please contact David Hance at (919) 715-6189. Enclosure Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N!)C ffMtd'rifflJ Sincerely , ¢~~ M. Carl Bailey, Jr. Assistant Chief for Planning Groundwater Section Voice 919-733-3221 FAX 919-715-0588 An Equal Opportunity/Affinnative Action Employer 50% recycles/10% post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director A.VA DEHNR October 2, 1996 Mr. Peter Safir Mecklenburg County Health Department Office of the Health Director Area Mental Health 429 Billingsly Road Charlotte, NC 28211 Dear Mr. Safir: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and Corrective Action requirements of 1 SA NCAC 2L .01060) (Groundwater Classifications and Standards). 15A NCAC 2L .0113(e)(1)(8) requires adequate notice be given to the local health agency units having jurisdiction over the geographical area covered by the variance prior to hearing. You will find enclosed a Public Notice regarding the variance hearing. Please refer to the enclosure for additional information. Enclosure Groundwater Section, P.O. Box 29578, Raleigh, North Carolina 27626-0578 2728 Capital Blvd., Raleigh, North Carolina 27604 N{;C !fM&'i'itWI Sincerely, ::Ca:i/J;<J Assistant Chief for Planning Groundwater Section Voice 919-733-322 l FAX 919-715-0588 An Equal Opportuni1y/Affirmative Action Employer 50% recycles/lO"k post-consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director AVA D E HNR October 2, 1996 Mr. Wendell White Office of the City Manager City of Charlotte 600 E. Fourth Street -Government Center Charlotte, NC 28202-2244 Dear Mr. White: The Department of Environment, Health and Natural Resources has received a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and Corrective Action requirements of 15A NCAC 2L .01060) (Groundwater Classifications and Standards). 15A NCAC 2L .0113(e)(1 )(D) requires adequate notice be given to governmental units having jurisdiction over the geographical area covered by the variance prior to hearing. You will find enclosed a Public Notice regarding the variance hearing. Please refer to the enclosure for additional information. Enclosure Sincerely, 4J,tt:Jl_l!r{J M. Carl Bailey, Jr. Assistant Chief for Planning Groundwater Section Groundwater Section, N,-r.1"1 Voice 919-733-3221 FAX 919-715-0588 P.O . Box 29578, Raleigh, North Carolina 27626-0578 'ill+;''-.; An Equal Opportunity/Affirmative Action Employer 2728 Capital Blvd., Raleigh, North Carolina 27604 !?itifiid'l'@ee 50% recycles/10% post-consumer paper • · NOTICE OF VARIANCE APPLICATION AND HEARING DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES DIVISION OF WATER QUALITY Notice is hereby given of a variance application and public hearing to be held by the Department of Environment, Health and Natural Resources on behalf of the Environmental Management Commission. The hearing concerns a request for a variance from the Groundwater Quality Standards of 15A NCAC 2L .0202 and the Corrective Action requirements of 15A NCAC 2L .0106 G) for a site at 4336 Park Road in Charlotte, North Carolina. The Division of Water Quality refers to this site identified in the variance request as Groundwater Incident # 3633. This property, previously owned by the Unocal Corporation of Atlanta, Georgia, is now owned by the DH&S Company (Petro Express). The Unocal Corporation is entirely responsible for cleanup for Groundwater Incident # 3633. This variance application from the Unocal Corporation was received for review by the Department on September 29, 1995. The property where the release of petroleum product has occurred is located as follows: Inside the city limits of Charlotte, North Carolina. Take Interstate 85 to Interstate 77 south and travel four and one-half miles south on Interstate 77 and take the Woodlawn Road (City Highway 4) exit and travel east toward downtown Charlotte. This site at 4336 Park Road is located two miles east at the corner of Woodlawn Road and Park Road. This site is listed in Mecklenburg County tax records as Parcel Number 143-203-24. The Unocal Corporation requests that the Environmental Management Commission grant the following variance to its rules under the authority of 15A NCAC 2L .0113 so that it does the following: (1) Allow concentrations of Benzene, Toluene, Ethylbenzene, Xylene (-o,-m, and p), Naphthalene, Methyl Tert-Butyl Ether (MTBE), Isopropyl Ether, Ethylene Dibromide, 1,1-Dichloroethane, 1,1- Dichloroethene, 1,2-Dichloroethane, 1, 1, 1,-Trichloroethane, 1, 1,2,2,-Tetrachloroethane, 1, 1,2- Trichloroethane, 1,2-Dichloropropane, Bromodichloromethane, Bromoform, cis-1,3- Dichloropropene, Carbon Tetrachloride, Chloroform, Dibromochloromethane, Methylene Chloride, trans-1,3-Dichlorobenzene, 1,4-Dichlorobenzene, and Chlorobenzene to remain at levels above 15A NCAC 2L .0202 standards as analyzed in December 1995. These concentrations will be required to remain within the property boundaries of 4336 Park Road. The property at 4336 Park Road, for which the Unocal Corporation has cleanup responsibilities under Groundwater Incident Number 3633, consists of approximately 1.05 acres of land. The Unocal Corporation operated a retail gasoline station at this site from the 1950s to 1987. In 1987 the Unocal Corporation sold this property to DH&S Company. In 1988 this site was renovated and old tanks removed so that a new gasoline station, known as the Petro Express Gasoline Station # 7, could be built at this site. This property is located in an area with a mixture of commercial, industrial, and residential development. Almost all the land area at this site is covered by buildings and paved parking lots. 1 Pursuant to the transfer of property to the DH&S Company and the removal of the underground storage tanks at 4336 Park Road, the Unocal Corporation discovered a release of an unknown quantity of gasoline. A site assessment and corrective action plan for this site was submitted on March 18, 1993 and is kept on file at the Mooresville Regional Office. The site assessment revealed a plume of groundwater and soils contamination originating from free product gasoline near the south property line. The plume of substances that came from the release of gasoline was estimated to have covered an area of 61,250 square feet (1.406 acres), prior to the implementation of corrective actions. On August 12, 1993 the Unocal Corporation implemented cleanup at this site. The plan called for the implementation of a pump-and-treat groundwater cleanup system, an air sparging system for soils and subsurface materials, and soil vapor extraction. Pump-and-treat technology uses a pump to convey contaminated groundwaters from beneath the land, treats these groundwaters to remove contaminants, and returns the treated water to a permitted discharge. Air sparing relies on the introduction of air to separate volatile substances from subsurface materials. Soil vapor extraction uses suction to remove contaminants from soils. Use of soil vapor extraction is intended to reduce contaminant levels in soils without requiring the removal and treatment of soils offsite and the introduction of new or treated fill materials. The Charlotte-Mecklenburg Utility Department issued a permit to discharge treated water from the pump-and-treat groundwater remediation system into the nearby sanitary sewer. These cleanup technologies were in operation from August 12, 1993 through September 29, 1995. The Division of Water Quality required the Unocal Corporation to perform groundwater monitoring to determine the vertical and lateral extent of contamination. Since January 13, 1988 monitoring has been conducted at six on-site wells located at 4336 Park Road. Benzene was found in five of six on site monitoring wells on December 16, 1991. The highest concentration of Benzene found in a monitoring well, prior to implementation of groundwater cleanup, was 8 .10 milligrams per liter found in Monitoring Well# 5 during the December 16, 1991 sampling event. The Groundwater Quality Standard for Benzene in ISA NCAC 2L .0202 is 0.0001 milligrams per liter. Concentrations of Ethylbenzene, Toluene, Xylene and Chloroform were also found in Monitoring Well # 5 significantly above the Groundwater Quality Standards in Title 15A NCAC 2L .0202. Monitoring well # 5 is located within 15 feet of the south property line and is located in the area in which the release of gasoline was discovered. On January 27, 1993 two additional monitoring wells were constructed off-site. A downgraidient monitoring well was located to the east at the Pop Shop (Parcel Number 175-181-06). Another off-site well was located to the south at Belk Investments (Parcel Number 171- 043-021). Analysis of groundwater samples from these two off-site wells have not shown concentrations of substances above the Groundwater Quality Standards in 15A NCAC 2L .0202 from the time these wells were installed in January 1993 through the December 1995 groundwater sampling. The Division also required Unocal Corporation to evaluate the effectiveness of groundwater cleanup efforts by examining concentrations of substances in recovery wells beginning December 16, 1991. Recovery wells at the 4336 Park Road site are used as sumps to collect groundwater, free product, and dissolved hydrocarbons from the site for treatment. Pumps convey this fluid to the treatment system. Samples were obtained from four recovery wells located beneath the parking lot and the area that formerly had the Unocal Corporation service station and pump islands. Since cleanup was initiated on August 12, 1993 significant reductions in concentrations of substances was observed in groundwater samples taken from the recovery wells. Results from 1994 demonstrated reductions in the concentrations of substances had occurred at this site since the implementation of cleanup. 2 From August 12. 1993 through September 13, 1994 the concentration of substances at this site were significantly reduced by groundwater cleanup technologies located at the site. Through 1995 analysis of samples from monitoring wells showed only marginal reductions in the concentration of substances in groundwater. Analysis of groundwater samples taken on February 23, 1995 and on June 2, 1995 showed there was no significant increase or decrease in concentrations of Benzene and other substances at on-site monitoring wells, while cleanup operations were being conducted. Except for Chloroform in Monitoring Well# 7 and 1,2-Dichloroethane in Monitoring Well# 9 at concentrations above the Groundwater Quality Standards, no other substances were reported in the other monitoring wells during this time. Based on groundwater analysis of samples from winter and summer monitoring events in 1995, the Division of Water Quality recommended that pump-and-treat, air sparging and soil vapor extraction technologies be turned off to determine if residual contaminants in the soils and subsurface would recontaminate the groundwater, if no treatment system were operating. In December 1995 groundwater monitoring was conducted at recovery wells and monitoring wells after the pump-and- treat system had been temporarily turned off. Only two of seven monitoring wells had concentrations of substances in exceedence of Groundwater Quality Standards in I SA NCAC 2L .0202. Monitoring well # 5 had Benzene at 0.00863 milligrams per liter, Ethylene Dibromide at 6.52 x 10-4 milligrams per liter, and 1,2-Dichloroethane at 0.00615 milligrams per liter. The maximum concentration of these substances allowed under the Groundwater Quality Standards pursuant to 15A NCAC 2L .0202 is as follows: Benzene at 0.0001 milligrams per liter, Ethylene Dibromide at 4.00 x 10-4 milligrams per liter, and 1,2-Dichloroethane at 0.0003 milligrams per liter. A sample from Monitoring Well# 9 showed 0.00447 milligrams per liter of 1,2-Dichloroethane. No substances were detected at Monitoring Well# 7 from the December 1, 1995 sampling event. Analysis of samples from the remaining monitoring wells reported Benzene, Chloroform, Ethylene Dibromide, and 1,2- Dichloroethane at concentrations below quantitation limits. The downgradient monitoring well located offsite to the east at the Pop Shop and the monitoring well located to the south at Belk Investments have never shown concentrations of any substance above the groundwater Quality Standards in title 15A NCAC 2L .0202 (Groundwater Quality Standards). Concentrations of Benzene in all four recovery wells did not show a significant decrease or increase during December 1995. Samples from two of the four recovery wells continued to show levels of 1,2-Dichloroethane above Groundwater Quality Standards. The highest concentration of 1,2-Dichloroethane from a December 19, 1995 sampling event was 0.0197 milligrams per liter in Recovery Well# 4. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.0003 milligrams per liter. Monitoring wells at this site have shown insignificant reductions in Benzene as a result of using pump-and treat, air sparging, and soil vapor extraction technologies. Although concentrations of substances appear to be decreasing in recovery wells, significant reductions in the concentration of 1,2-Dichloroethane have not been observed in recovery wells. No significant increase in concentrations of substances was observed as a result of the temporary cessation of pump-and-treat operations. The Unocal Corporation has submitted supporting information showing that the variance will not endanger public health, safety, or the environment. No known sources of drinking water from water wells or surface water supplies are known to exist within a ½ mile radius of this property. Based on groundwater flow information obtained during the Comprehensive Site Assessment, it is believed that the contaminant plume is moving to the east. The Unocal Corporation has calculated the time it will take Benzene, Ethylbenzene and 1,2-Dichloroethane to reach Little Sugar Creek at 3 • 2) concentration levels that would exceed Groundwater Quality Standards is between 93 and 280 years . Little Sugar Creek discharges into Sugar Creek which is a tributary of the Catawba River. All residents in the area are supplied drinking water from the City of Charlotte. Information provided by the Charlotte-Mecklenburg Utilities Department indicates that the public water supply lines in this area are at an average depth ofless than five feet from the ground surface. Groundwater occurs at 4336 Park Road at a depth of seventeen feet beneath the property. Water supply lines are not located deep enough in the ground to be impacted by this variance. Allow for the restoration of groundwater without requiring remedial actions in accordance with 15A NCAC 2L .01060). The Unocal Corporation has submitted supporting information demonstrating that the continued application of best available technology will not result in significant long term remediation of the site to the Groundwater Quality Standards contained in 15A NCAC 2L .0202. This is due to the high probability that continued remediation activities at the site will not significantly reduce contaminant levels below Groundwater Quality Standards in 15A NCAC 2L .0202. Since corrective actions were implemented on August 12, 1993 the Unocal Corporation has extracted a total of 3,050 pounds of petroleum hydrocarbons from contaminated soils and groundwater. The mass of petroleum extracted from soils and subsurface materials is approximately 3,000 pounds. The Unocal Corporation has treated an estimated 4.12 million gallons of groundwater via pump-and-treat technology which accounts for 50 pounds of material removed. The company reports that a total of $313,500 has been spent by the Unocal Corporation to cleanup the release described in Groundwater Incident # 3633. No claims for reimbursement through the state's Commercial Underground Storage Tank Trust Fund have ever been filed by the Unocal Corporation for funds spent on this site. The Unocal Corporation estimates that continued operation of the current groundwater and soil cleanup system over the next three years will be approximately $180,000. The Unocal Corporation has shown that when the operation of groundwater remediation systems at the site was temporarily interrupted, no increase in the concentration of any substiµice above groundwater standards was observed in off-site monitoring wells from monitoring data. The company asserts that marginal increases observed for some chemicals in two of the on-site monitoring wells, when the cleanup systems were not in operation, demonstrates that continued implementation of pump and treat, air sparging and soil vapor extraction will not result in a significant reduction in contaminant concentrations at this site. The Unocal Corporation has considered the use of air sparging as an alternate technology to the current groundwater remediation system. The company does not believe this technology is economically reasonable or practical to meet the requirements of 15A NCAC 2L .0l 13(c)(5). The estimated cost of implementing air sparging is approximately $45,000. The company asserts that continued reliance on air sparging is not economically justified due to the low residual concentrations of substances at this site with the lack of groundwater consumption by humans. 4 installed at this site and sampling and analysis of wells be placed as conditions for approval of this variance. On July 24, 1996 Mr. James Ponder of S&ME Incorporated requested that the Groundwater Section review the necessity for recommending monitoring requirements as conditions for approval of this variance in light of the enactment of Senate Bill 1317. Mr. Ponder expressed the view that this law extends to monitoring requirements on variances under 15A NCAC 2L .0113 as well as monitoring requirements in corrective action plans established pursuant to lSANCAC 2L .0106. It is important to note that Senate Bill 1317 specifically includes cleanups at sites where petroleum has been discharged or released from underground storage tanks. This law does not specify any new requirements for variances propo"sed to the Environmental Management Commission pursuant to l SA NCAC 2L .0113. The statutory basis for the Environmental Management Ccmmission to grant a variance is found in North Carolina General Statute (NCGS) 143-215.3(e). Senate Bill 1317 does not mention this statute nor does it effect any actions taken by the Environmental Management Commission pursuant to NCGS 143- 215.3(e). In addition to reviewing this issue for the Goodwill Industries of the Southern Piedmont, the Groundwater Section has also examined other variances to determine if they are "Class CDE pursuant to Senate Bill 1317. The only site that we have identified as being impacted by the legislation is the Unocal Corporation site at 4336 Park Road in Charlotte, North Carolina (Groundwater Incident Number 3633). Groundwater Section staff have identified three courses of action that the Unocal Corporation can take that will result in a corrective action plan that will satisfy the requirements the 15A NCAC 2L rules. These options are shown as follows: l) The Unocal Ccrporation could withdraw the variance and discontinue cleanup for Groundwater Incident # 3633 until a risk assessment rule has been established. Senate Bill 1317 requires that by October 1, 1997 the Environmental Management Commission adopt a rule to implement the requirements of NCGS 143-215.94V(b). Please note that the deferment of cleanup requirements is a temporary,_ not a permanent deferment. It is not known at this time what requirements will be included in a new risk based rule. It must be further noted that if a risk assessment were conducted at this site and it showed that conditions are such that the site posses a higher risk than that of a site ranked Class CDE, this may result in a re- ranking to Class AB s tatus. A higher ranking at a · site may result in the reinstatement of active groundwater and/ or soil remediation. A risk assessment 2 may also result in the necessity for expanded groundwater and soil monitoring requirements. After a risk assessment rule has been adopted, a new variance may also be requested only if the new rule allows responsible parties to obtain variances for releases from petroleum underground storage tanks. 2) The Unocal Corporation could withdraw the variance for Groundwater Incident # 3633 and cleanup the site pursuant to the requirements of 15A NCAC 2L. It must be noted that Senate Bill 1317 allows, but does not require, the temporary cessation of remediation activities. Although the Unocal Corporation has never received any payments for cleanup out of the state's underground storage tank cleanup funds, under the new legislation any future access to those funds is denied, unless the company can meet the criteria outlined in Section l(f) of the Senate Bill 1317. After a risk assessment rule has been adopted, a new variance may be requested only if the new risk based rule allows responsible parties to obtain variances for releases from petroleum underground storage tanks. 3) The Unocal Corporation could continue to pursue a variance at this property. If a variance is granted by the Environmental Management Commission for this site, any conditions upon the variance, including monitoring, would need to be adhered to by the company in order for the variance to remain legally valid. After a variance is granted the responsible party may be allowed to conduct a risk assessment under the new rules to determine if the variance is still necessary. If a risk assessment shows that the variance or monitoring requirements placed by the Environmental Management Commission as conditions for the approval of a variance are no longer needed, then the Unocal Corporation may request that the variance be rescinded. In order to complete activities shown in either Number 1 or 2 above to support a new variance request pursuant to 15A NCAC 2L .0113, the most up-to-date site information must be submitted with the information submitted through June 28, 1996. If a risk assessment is conducted pursuant to Senate Bill 1317 for any of these three scenarios, it must be in accordance with a new rule approved by the Environmental Management Commission. The most recent site information will need to be submitted in accordance to the requirements of the rule. At this time no risk assessment rule has been orooosed b v the Division of Water Quality. 3 The Groundwater Section staff has been in the process of completing the activities necessary to bring this variance to public notice and hearing. The Groundwater Section would like to know in writing if the Unocal Corporation desires to continue pursuing a variance for Groundwater Incident Number 3633 at this time so that we can arrange a public hearing and send notices pursuant to 15A NCAC 2L .0113. If possible, we would like to receive your response by September 20, 1996. Upon the completion of the hearing officers report and recommendation, this variance will be sent to the Environmental Management Commission for review and final action. Please send your response to Mr. David Hance, P.O. Box 29578, Raleigh, NC 27626-0578 {phone: (919) 715-6189; fax (919) 715-0588}. Information from the Mooresville Regional Office shows that all other sites for which variances have been requested through S& ME Incorporated, are "Class AB" in accordance with the legislation and are not impacted by legislative changes made during the 1996 Session of the North Carolina General Assembly. Staff are reviewing the information submitted for these variance requests. If you have any new information that will change the priority ranking of any of these sites to Class C, D, or E, or have questions concerning this letter, please feel free to contact myself at (919) 715-6170 or Mr. Hance. AM/dah cc: Arthur Mouberry Carl Bailey Dr. Burrie Boshoff Mooresville Regional Groundwater Supervisor Allen Schiff David Hance A. Wayne Holt (Unocal Corporation) Sincerely, ~~~ Chief, Groundwater Section 4 AecycledPaptr E September 11, 1996 Mr. David Hance P.O. Box 29578 Raleigh, NC 27626-0578 RE: Request to Continue Pursuing Variance Incident #3633 Unocal Corporation (Former Station #9342-209) 4336 Park Road, Charlotte, NC S&ME Project No. 1354-92-397 Dear Mr. Hance: -.. -.J .. , S&ME, Inc., on behalf of Unocal Corporation, hereby informs the North Carolina Environmental Management Commission that Unocal Corporation desires to continue pursuing a variance for the subject site, as requested in your September 6, 1996 letter to S&ME, Inc. Please proceed with arranging a public hearing and sending notices, as needed. If you have any questions, please call me at 704-523-4726. Sincerely, S&ME, Inc. ~~ Al Quarles, L.G. Assistnat Environmental Services Manager cc: Wayne Holt -Unocal Corporation S&ME, Inc. 9751 Southern Pine l3oulevard, Charlotte , North Carolina 28273, (704) 523-4726, Fax (704) 525-3953 Mailing address: P.0.13ox 7668, Charlotte, North Carolina 28241 -7668 Dear Mr. Hance; Unocal Refining & Marketing Division Unocal Corporation q Corporate Square Northeast, P.O. Box 4147 At ianta, GP,orgia 30302 Telephone (404) 321-7600 UNOCAL@ 12 September 1996 Mr. David Hance NC DEHNR -DEM PO BOX 29578 Raleigh, NC 27626 -0578 Re: Request for Variance Former Unocal SS 9342 -209 4336 Park Road Charlotte, NC -.. In response to your letter of September 6, 1996, UNOCAL respectfully request to continue pursuing variance of 2L standards for the above referenced site. The site has been actively rehabilitated to 2L standards for the constituents present from past UNOCAL operations. Trace constituents of other contaminants exist which UNOCAL was not responsible for. The trace contaminants pose no threat to human health or the environment. It is recognized that UNOCAL will be required to continue monitoring the site for approximately two years after the variance request is granted. This is still more economically feasible than having to complete an entire RBCA assessment and still be required to monitor for two to three years. With the above factors in mind we respectfully request to continue pursuing the variance. If further information is needed or you wish to discuss this personally please call me at (404) 320 -2207. Thank you for you cooperation and understanding. cc: R E Oehlerts Stewart Hines {]."""'~r.,c,,-~_..112..jU A. Wayne Holt " . 'StO'te of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director CERTIF1ED MAIL P 281 5 78 936 RETURN RECEIPT RE QUESTED AVA DEHNR September 6, 1996 Mr. Stewart M. Hines S&ME, Inc. 9751 Southern Pines Blvd. P.O. Box 7668 Charlotte, NC 28241-7668 Dear Mr . Hines: Regarding: The Impact of Senate Bill 1317 and the Variance Request at the Unocal Corporation Park Road Site (GW Incident # 3633) On June 21, 1996 the North Carolina General Assembly enacted Senate Bill 1317 which allows for the temporary cessation of groundwater cleanup at sites classified as Class CDE where releases of petroleum have occurred from underground storage tanks. The new law also restricts owners and operators of underground storage tanks from receiving payments from the Commercial and Non-Commercial Underground Storage Tank Trust Funds, unless the responsible party can meet the criteria outlined in Section l(f) of Senate Bill 1317. The General Assembly enacted this bill with the intent to provide for the continued solvency of the state trust funds. Under this bill sites that have a priority ranking of "E", which is defined in the legislation as "Class CDE", will no longer be required to conduct cleanup or continue cleanup until risk assessment rules are enacted by the Environmental Management Commission. Groundwater and soil monitoring may also be suspended at these sites. In July 1995 S& ME Incorporated, on behalf of Goodwill Industries of the Southern Piedmont, submitted a variance request for a site priority ranked as "E". This site is identified as Groundwater Incident Number 8094. Pursuant to the Mooresville Regional Office staff review and a public hearing held on March 19, 1996, is has been recommended to the hearing officer that a new groundwater monitoring well be Groundwater Section, •r CJ1""'1 P.O. Box 29578, Raleigh, North Carolina 27626-0578, 111 ,,..,., '1 2728 Capital Blvd., Raleigh, North Carolina 27604 •Gfi@•f@®' 1 Voice 919-733-3221 FAX 919-715-0588 AA Equal Opportunity/ Affirmative Action Employer 50% recycles/10% post-consumer paper installed at this site and sampling and analysis of wells be placed as conditions for approval of this variance. On July 24, 1996 Mr. James Ponder of S&ME Incorporated requested that the Groundwater Section review the necessity for recommending monitoring requirements as conditions for approval of this variance in light of the enactment of Senate Bill 1317. Mr. Ponder expressed the view that this law extends to monitoring requirements on variances under 15A NCAC 2L .0113 as well as monitoring requirements in corrective action plans established pursuant to 15A NCAC 2L .0106. It is important to note that Senate Bill 1317 specifically includes cleanups at sites where petroleum has been discharged or released from underground storage tanks. This law does not specify any new requirements for variances propo'sed to the Environmental Management Commission pursuant to 15ANCAC 2L .0113. The statutory basis for the Environmental Management Commission to grant a variance is found in North Carolina General Statute (NCGS) 143-215.3(e). Senate Bill 1317 does not mention this statute nor does it effect any actions taken by the Environmental Management Commission pursuant to NCGS 143- 215.3(e). In addition to reviewing this issue for the Goodwill Industries of the Southern Piedmont, the Groundwater Section has also examined other variances to determine if they are "Class CDE pursuant to Senate Bill 1317. The only site that we have identified as being impacted by the legislation is the Unocal Corporation site at 4336 Park Road in Charlotte, North Carolina (Groundwater Incident Number 3633). Groundwater Section staff have identified three courses of action that the Unocal Corporation can take that will result in a corrective action plan that will satisfy the requirements the 15A NCAC 2L rules. These options are shown as follows: 1) The Unocal Corporation could withdraw the variance and discontinue cleanup for Groundwater Incident # 3633 until a risk assessment rule has been established. Senate Bill 1317 requires that by October 1, 1997 the Environmental Management Commission adopt a rule to implement the requirements of NCGS 143-215.94V(b). Please note that the deferment of cleanup requirements is a temporary, not a permanent deferment. It is not known at this time what requirements will be included in a new risk based rule. It must be further noted that if a risk assessment were conducted at this site and it showed that conditions are such that the site posses a higher risk than that of a site ranked Class CDE, this may result in a re- ranking to Class AB status. A higher ranking at a site may result in the reinstatement of active groundwater and/ or soil remediation. A risk assessment 2 may also result in the necessity for expanded groundwater and soil monitoring requirements. After a risk assessment rule has been adopted, a new variance may also be requested only if the new rule allows responsible parties to obtain variances for releases from petroleum underground storage tanks. 2) The Unocal Corporation could withdraw the variance for Groundwater Incident # 3633 and cleanup the site pursuant to the requirements of 15A NCAC 2L. It must be noted that Senate Bill 1317 allows, but does not require, the temporary cessation of remediation actlvities. Although the Unocal Corporation has never received any payments for cleanup out of the state's underground storage tank cleanup funds, under the new legislation any future access to those funds is denied, unless the company can meet the criteria outlined in Section 1 (f) of the Senate Bill 1317. After a risk assessment rule has been adopted, a new variance may be requested only if the new risk based rule allows responsible parties to obtain variances for releases from petroleum underground storage tanks. 3) The Unocal Corporation could continue to pursue a variance at this property. If a variance is granted by the Environmental Management Commission for this site, any conditions upon the variance, including monitoring, would need to be adhered to by the company in order for the variance to remain legally valid. After a variance is granted the responsible party may be allowed to conduct a risk assessment under the new rules to determine if the variance is still necessary. If a risk assessment shows that the variance or monitoring requirements placed by the Environmental Management Commission as conditions for the approval of a variance are no longer needed, then the Unocal Corporation may request that the variance be rescinded. In order to complete activities shown in either Number 1 or 2 above to support a new variance request pursuant to 15A NCAC 2L .0113, the most up-to-date site information must be submitted with the information submitted through June 28, 1996. If a risk assessment is conducted pursuant to Senate Bill 1317 for any of these three scenarios, it must be in accordance with a new rule approved by the Environmental Management Commission. The most recent site information will need to be submitted in accordance to the requirements of the rule. At this time no risk assessment rule has been nrop osed b y the Division of Water Quality. 3 The Groundwater Section staff has been in the process of completing the activities necessary to bring this variance to public notice and hearing. The Groundwater Section would like to know in writing if the Unocal Corporation desires to continue pursuing a variance for Groundwater Incident Number 3633 at this time so that we can arrange a public hearing and send notices pursuant to 15A NCAC 2L .0113. If possible, we would like to receive your response by September 20, 1996. Upon the completion of the hearing officers report and recommendation, this variance will be sent to the Environmental Management Commission for review and final action. Please send your response to Mr. David Hance, P.O. Box 29578, Raleigh, NC 27626-0578 {phone: (919) 715-6189; fax (919) 715-0588}. Information from the Mooresville Regional Office shows that all other sites for which variances have been requested through S& ME Incorporated, are "Class AB" in accordance with the legislation and are not impacted by legislative changes made during the 1996 Session of the North Carolina General Assembly. Staff are reviewing the information submitted for these variance requests. li you have any new information that will change the priority ranking of any of these sites to Class C, D, or E, or have questions concerning this letter, please feel free to contact myself at (919) 715-6170 or Mr. Hance. AM/dah cc: Arthur Mouberry Carl Bailey Dr. Burrie Boshoff Mooresville Regional Groundwater Supervisor Allen Schiff David Hance A. Wayne Holt (Unocal Corporation) Sincerely, ~~~ Chief, Groundwater Section 4 DIVISION OF WATER QUALITY Groundwater Section July 8, 1996 MEMORANDUM TO: A. Preston Howard, Jr. P.E. THROUGH: Arthur Mouberry, P.E. ~ Chief, Groundwater Sectio~ FROM: Carl Bailey ~ Assistant Chief for Planning, Groundwater Section SUBJECT: Variance Request for the Former Unocal Facility at 4336 Park Road in Charlotte, North Carolina (Groundwater Incident Number 3633). The Groundwater Section is in the process of reviewing a request for variance from Title 15A North Carolina General Statutes, Subchapter 2L "Classi fi cations and Water Oualirv Standards A pplicable to the Groundwaters o(North Carolina" for the subject site. The petitioner, the Unocal Corporation of Atlanta, Georgia, requests a variance from 15A NCAC 2L .0202 (Groundwater Quality Standards) and 15A NCAC 2L .0106(j) (Corrective Action Plans). Attached for your consideration is a memorandum in which staff have provided comments concerning the information required to be submitted in support of the request in accordance with 15A NCAC 2L. 0113(c) and which must be considered by the Environmental Management Commission (EMC) prior to granting a variance. Based on the information received thus far, this facility seems to be a good candidate for a variance. Your concurrence is needed so that the Division can proceed with public notice of hearing in accordance with procedures set out in 15A NCAC 2L .Ol 13(d) and (e) and for subsequent review by the Environmental Management Commission. 1 The Groundwater Section would like present this request as an information item to the Groundwater Committee at the September 11, 1996 meeting, if the Committee Chairman chooses to hold a meeting. If you have any questions concerning this matter . please contact me at 715-6169 . Attachments cc: Arthur Mouberry Groundwater Section Assistant Chiefs David Hance 2 ; ...... DIVISION OF WATER QUALITY GROUNDWATER SECTION July 16 , 1996 MEMORANDUM To: From: Subject: Preston Howard Arthur Mouberry ~ Request for Variance from ISA NCAC 2L .0202 and ISA NCAC 2L .01060) for a Site Owned by the Unocal Corporation of Atlanta, Georgia at 4336 Park Road in Charlotte, North Carolina (Mecklenburg County) {Groundwater Incident Number 3633}. Unocal Corporation operated a retail gasoline station at 4336 Park Road in Charlotte North Carolina from the 1950's to 1986. In January 1987 the Unocal Corporation sold this property to DH & S Company of Charlotte, North Carolina. The Unocal Corporation gasoline station was demolished in February 1988 and a new gasoline station was built on this site. This new gasoline station is known as the Petro Express. It was discovered during tank removal and site renovation that an unknown quantity of gasoline had been released from one or more of the underground storage tanks at the site. The Unocal Corporation is entirely responsible for cleanup of this release which is shown in Division of Environmental Management files as Groundwater Incident Number 3633. Pursuant to title ISA NCAC 2L .0113(c) variance applications are required to contain specific information in order to adequately review a request. The Unocal Corporation variance request is contained in a report titled "Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facility # 9342-209 4336 Park Road Charlotte. North Carolina S&ME Project No. 1354-92-397 (November 1995)". In addition, the Groundwater Section requested the Unocal Corporation provide clarifying information, additional laboratory analysis, and editorial corrections to some of the information submitted in the report. This information is shown in memoranda submitted on December 29, 1995 and March 6, 1996. A "Letter Of Transmittal" from the Unocal Corporation's environmental consultant dated for December 29, 1995 shows the results from the most recent groundwater monitoring at the site that the Groundwater Section has on record. The site assessment and corrective action plan for this site was submitted on March 16, 1993 and is on file at the Mooresville Regional Office. The information submitted by S&ME Incorporated on behalf of Unocal Corporation appears to meet the requirements of 15A NCAC 2L .0113(c) and is summarized as follows: 1 Rule .0113 (c){l ): Resolution b v the County or govemine Board: The Unocal Corporation has always been a privately owned company. No resolution is necessary. Rule .0113 (c)(2): A descri ption of past. existin g or pro posed activities that would result in a dischar ge of contaminants into gr oundwater: The former Unocal site (Petro Express) is located inside the city limits of Charlotte, North Carolina at 4336 Park Road (Parcel Number 143-203-24). The report titled "Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facility# 9342-209 4336 Park Road Charlotte, North Carolina S&ME Project No. 1354-92-397 (November 1995)" contains the relevant information about this site. This facility is at the corner of Park Road and Woodlawn Road as shown in Appendix V of the report. The Unocal site consists of approximately 1.05 acres of land. On February 18, 1988 a release of an unknown quantity of gasoline was discovered at the center of the property near the southern property line during tank removal and site renovation. A preliminary site assessment was sent to the Mooresville Regional Office on February 18, 1988. This was followed by the submittal of the an addenda to that original site assessment and a corrective action plan on March 16, 1993 for soils and groundwater. The final site assessment and the correction action plan was received by the Mooresville Regional Office on March 18, 1996 where it is currently kept on file. The Unocal Corporation began cleanup of this site on August 12, 1993. All potential sources of groundwater contamination were identified at this property by the company. This property at 4336 Park Road in Charlotte, North Carolina formerly owned by the Unocal Corporation and all adjacent properties are in an area with a mixture of commercial, industrial, and residential development. The comprehensive site assessment revealed a groundwater plume from a small area of free product contamination. This area of free product was located near the south property line approximately sixty feet southwest of the area where the Unocal Corporation retail outlet had it's gasoline pump islands. The area of free product was in the shape of an ellipse and was approximately 12 to 15 feet in diameter. The plume of dissolved gasoline that came from this area of free product contamination was roughly the shape of a circle that extended to adjacent properties to the south, southeast, and east. This plume was estimated to have covered an area of approximately 61,250 square feet (1.406 acres) prior to the implementation of corrective actions by the Unocal Company. Site assessment information on file in the Mooresville Regional Office shows that the vertical 2 extent of this plume to be approximately 55 feet below the ground surface. It is not believed that this plume contaminated the bedrock aquifer beneath this site. From the information contained in the site assessment, the company estimated that the total mass of petroleum hydrocarbons was approximately 2410 pounds (lbs). It is estimated that 35 lbs of this material was dissolved hydrocarbons in groundwater. The portion of this release that was adsorbed to the soils and in the vapor phase was estimated at 1,600 lbs. The remaining portion of this plume is believed to be phase-separated hydrocarbons and was estimated to account for 775 lbs (or 130 gallons) from this release. This release occurred in unconsolidated materials above the bedrock. The Unocal Corporation implemented cleanup of this site on August 12, 1993. From that date through March 17, 1995 approximately 3,050 lbs of petroleum hydrocarbons were extracted from contaminated soils and groundwater on and off-site. The company measured the mass of petroleum hydrocarbons extracted from soils at 3,000 lbs. A total of 4.12 million gallons of groundwater has been treated via pump-and-treat technology which accounts for approximately 50 lbs of the total amount of material removed. The Charlotte Mecklenburg Utility Department (CMUD) issued a permit to discharge treated water from the pump-and-treat groundwater remediation system into the nearby sanitary sewer. The cleanup system used by the Unocal Corporation consists of a combination of pump-and-treat technology to cleanup groundwater, air sparging of soils and subsurface materials, soil vapor extraction to remove contaminants from the site. The Division of Environmental Management required the Unocal Corporation to perform groundwater monitoring to determine the vertical and lateral extent of contamination at the site. On December 15, 1991 and December 16, 1991 the company conducted comprehensive groundwater sampling at all six on-site monitoring wells. The deepest of the monitoring well constructed at this site was Monitoring Well # 8 and it is 55 feet deep below the land surface. Groundwater samples were analyzed using US Environmental Protection Methods 602, 625, and 504.1. Benzene was found in five of the six monitoring wells. The highest concentration found in a monitoring well in exceedence of the 15A NCAC 2L .0202 Groundwater Quality Standard for Benzene during this sampling event was 8.10 milligrams/Liter (mg/L) or 8,100 micrograms/Liter (ug/L) in Monitoring Well# 5. This sampling event also revealed the presence of Toluene at 3.2 milligrams per liter or 3,200 micrograms/Liter {ug/L) in Monitoring Well# 5. Ethylbenzene also appeared at a concentration level of 15.0 milligrams/liter (mg/L) or 15,000 micrograms/Liter (ug/L) in Monitoring Well# 5. No substances above detection limits were found in Monitoring Well# 8 during the December 15, 1991 analysis. In September 1993 Monitoring Well# 8 was converted into an air sparging well to assist in the cleanup effort at the site. In January 1993 the company constructed two additional monitoring wells located off-site of the property at 4336 Park Road. These two wells are known as Monitoring Well# 10 at Belk Investments to the South of the Unocal Site and 3 Monitoring Well # 11 located to the East at a retail gasoline station known as the "The Pop Shop". Monitoring Well# 10 is located cross-gradient of the Unocal Corporation site and Monitoring ·Well # 11 is the downgradient well. The highest concentration of Benzene found at Monitoring Well # 10 was 0.002 milligrams per liter during the initial groundwater sampling on January 27, 1993. Monitoring Well # 11 has never shown concentrations of substances above the Groundwater Quality Standards of 15A NCAC 2L .0202. The Division also required the Unocal Corporation to evaluate the effectiveness of groundwater cleanup efforts by examining concentrations of substances in monitoring wells. In addition, an examination of concentrations in recovery wells used as sumps to collect free product and dissolved hydrocarbons from the site is also necessary to understand the effect pump-and-treat cleanup has had on concentrations of constituents at the site. From January 1988 through December 1995 analysis of groundwater samples has been conducted by the Unocal Corporation. The highest Benzene concentration ever found in a monitoring well showed 8.400 milligrams/Liter (mg/L) or 8,400 micrograms/Liter (ug/L) at Monitoring Well# 5 on March 5, 1990. The highest concentration of Chloroform in this well was 4.20 milligrams/Liter (mg/L) or 4,200 micrograms/Liter (ug/L) on December 16, 1991. The highest concentration of 1,2- Dichloroethane in Monitoring Well# 5 was 0.00615 milligrams/Liter (mg/L) or 6.15 micrograms/Liter (ug/L) on December 1, 1995. The greatest concentration of Ethylene Dibromide that appeared in a sample from this well was 0.000928 milligrams/Liter (mg/L) or 0.928 micrograms/Liter (ug/L) on March 16, 1994. This well is located at the northwest side of the pump islands. Samples were obtained from four recovery wells January 1993 through December 1995. These wells are located around the area which formerly consisted of the Unocal Corporation's pump islands. The highest concentration of Benzene ever found in a recovery well showed 4.0 milligrams/Liter (mg/L) or 4,000 micrograms/Liter at Recovery Well# 4 on January 27, 1993. The highest concentration of Chloroform in this well was 0.00458 milligrams/Liter (mg/L) or 4.58 micrograms/Liter (ug/L) on February 23, 1995. The highest concentration of 1,2-Dichloroethane in Recovery Well# 4 was 1.40 milligrams/Liter (mg/L) or 1,400 micrograms/Liter (ug/L) on January 27, 1993. The greatest concentration of Ethylene Dibromide that appeared in a sample from this well was 0.0321 milligrams/Liter (mg/L) or 32.1 micrograms/Liter (ug/L) on September 13, 1994. The Unocal Corporation has also conducted monitoring at the influent for these four recovery wells. Table # 1 of the March 6, 1996 letter shows that the highest concentration of Benzene found in a composite sample at the influent for these wells to be 0.420 milligrams/Liter (mg/L) or 420 micrograms/Liter (ug/L) on June 3, 1993. The highest concentration for all substances monitored in the recovery wells at the site was 0.570 milligrams/liter (mg/L) or 570 micrograms/Liter (ug/L) of Methyl-Tert Butyl Ether (MTBE) on June 3, 1993. Groundwater monitoring results of influent samples since August 12, 1993 have shown considerable reduction of contaminants at this site. Analysis of these 4 influent samples at the recovery wells on February 21, 1995 showed substances at either below detection limits or significantly below Groundwater Quality Standards in 15A NCAC 2L .0202. Since cleanup was initiated by Unocal levels of contaminants in groundwater have been significantly reduced in monitoring wells and recovery wells as shown in Table #1 of December 29, 1995 "Letter Of Transmittal. On June 2, 1995 the Unocal Corporation conducted routine sampling of monitoring wells at this site. Except for the presence of Chloroform in Monitoring Well# 7 at a concentration level above the respective Groundwater Quality Standard, concentrations of substances in on-site and off-site monitoring wells was below detectable limits. Based on the results of the June 1995 monitoring, the Unocal Corporation informed the Mooresville Regional Office on September 29, 1995 that it intended to request a variance at this site. As shown in Appendix I of the report a letter from Mr. A. Wayne Holt of the Unocal Corporation stated in this letter that the company has utilized best available technology and has "aggressively pursued clean-up". They have specifically requested a variance that would consist of a " ...... site variance and monitor only plan leading to regulatory closure.". This variance encompasses the entire property at 4336 Park Road. Based on the results of June 2, 1996 monitoring event the Division of Environmental Management recommended the pump-and-treat system be turned off to determine if residual contaminants in the soils and subsurface would recontaminate the groundwater, if no treatment system were operating. On December 19, 1995 groundwater sampling was conducted at monitoring wells and recovery wells after the groundwater and soil cleanup system had been temporarily turned off. Seven monitoring wells, including offsite wells at Belk Investments (MW-10) and the Pop Shop (MW-11,) were sampled during this time. Except for Monitoring Well # 5, analysis of samples from these wells showed the Benzene concentration below detection limits. The concentration of Benzene in this well exceeded the Groundwater Quality Standard in 15A NCAC 2L .0202. Potential sources of groundwater contamination in the area are shown on maps located in Appendix V of the report titled "Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facilitv # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Project No. 1354-92-397 (November 1995)" and include the following: 1) A retail gasoline station constructed in 1987 and presently owned by DH&S Company (Petro Express) located on the property once owned by the Unocal Corporation at 4336 Park Road; 5 2) A retail gasoline station presently owned by Park Road Shopping Center and locally known as the "Pop Shop". This gasoline station is located at 4323 Park Road to the east of the site; 3) A retail gasoline station presently owned by Exxon Company, USA located at 125 Woodlawn Road to the southeast of the site; 4) Property owned by Belk Investments at 4400 Park Road to the south of the site. This property once had a leaking fuel oil tank located near Monitoring Well# 10 and is mentioned in a Law Engineering Report dated 1/3/92. The responsible party for the release from this fuel oil tank is not the Unocal Corporation and it is being addressed under a separate Notice of Violation; 5) On-site wells at 4336 Park Road consisting of five monitoring wells, four recovery wells, and the air sparging well owned by the Unocal Corporation. These wells are in the site maps contained in Appendix V of the variance request. 6) One monitoring well at Belk Investments. 7) Six monitoring wells located at the Pop Shop gasoline station to the east of the site. The company describes two of these monitoring wells as having been "closed". 8) Two tank pit vapor point wells located at the Exxon Company gasoline station to the southeast. 9) Woodlawn Drive (a public roadway); 10) Park Road (a public roadway); 11) Water supply lines that run along Woodlawn Drive and Park Road. 12) Numerous storm drain lines and sewer lines that run along Woodlawn Drive and Park Road and others located in the general area. 6 Attached to a letter dated March 6, 1996 titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements" is an aerial photograph of the site and adjacent properties in Figure 3. Also attached is Figure 1 a Topographic Map of the City of Charlotte showing contour intervals of the site and adjacent properties. Rule .0113 {c){3): Description of the pro posed area for which the variance is requested: Maps of the area are shown in Appendix V of the report titled Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facility# 9342- 209 4336 Park Road Charlotte. North Carolina S&ME Proiect No. 1354-92-397 (November 1995)". A map showing identifying county parcel numbers is contained in the attachments to the March 6, 1996 letter titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements". The company has estimated that the area of groundwater contamination is roughly shaped in the form of a circle. It is believed that the plume of groundwater contamination once extended across Woodlawn Road, before cleanup began, and covered approximately two-thirds of the land to the south owned by Belk Investment (Mecklenburg County Parcel Number 171-043-21). Within this area of groundwater contamination is Monitoring Well# 10 at Belk Investments. In addition, a separate plume of contamination from a fuel oil release is present at the Belk Investment property near Monitoring Well # 10 and is being addressed under a separate Notice of Violation. The Unocal Corporation is not the responsible party for this fuel oil release on the Belk Investment land. The plume at 4336 Park Road that Unocal is responsible for extends to the southeast from the property and crosses Park Road going beneath a small portion of adjacent property owned by the Exxon Company (Mecklenburg County Parcel Number 175-141-01). The furthest extent of the contaminated area from 4336 Park Road to the east goes onto an adjacent property known as "The Pop Shop" owned by the Park Road Shopping Center (Mecklenburg County Parcel Number 175-181-06) but is not believed to have traveled as far as Monitoring Well #11. The furthest extent of this plume to the north, northeast, and west included two- thirds of the property at 4336 Park Road formerly owned by the Unocal Corporation (Mecklenburg County Parcel Number 149-203-24). No other adjacent properties are known to have been impacted by the release for which Unocal has cleanup responsibilities. This variance is for all the land entirely within the property boundaries of 4336 Park Road that was formerly owned by the Unocal Corporation. The groundwater that was impacted by the release is located in the original pump area and service station when Unocal owned the site. These structures have since been removed from the property by the present owner. Because groundwater 7 monitoring results do not show that contaminants from Unocal's release at 4336 Park Road have migrated at concentration levels above standards, this variance request does not include any land adjacent to the property as 4336 Park Road. Table 1 in Appendix II of the variance request indicates that concentrations substances that have migrated outside the property boundaries of 4336 Park Road over the past three years have not exceeded the level of the Groundwater Quality Standards in 15A NCAC 2L .0202. Groundwater monitoring results in Monitoring Well# 11 (The Pop Shop) have shown the presence of Methyl Tert- Butyl Ether (MTBE) above detection limits. However, from January 27, 1993 through December 1, 1995 this substance has never appeared above the Groundwater Quality Standard for MTBE. No other substance has been observed in Monitoring Well# 11. Sampling at Monitoring Well# 10 (Belk Investments) during the saine period has demonstrated that no substance at a concentration . level exceeding laboratory detection limits. If at any time monitoring reveals that concentrations of substances exceed the Groundwater Quality Standards in 15A NCAC 2L .0202 on adjacent properties and it could be determined that the Unocal Corporation is responsible for the contamination, the Division could still require the Unocal Corporation bring these concentration levels in compliance with the standards in 15A NCAC 2L .0202. A variance granted by the Environmental Management Commission does not exempt the Unocal Corporation from being held jointly or severally responsible for cleanup. The concentration of contaminants in groundwater is primarily influenced by the direction and rate of groundwater flow. The estimated groundwater flow rate is contained in the site assessment and corrective action plan submitted by the Unocal Corporation to the Mooresville Regional Office. Based on this information the Unocal Oil Company asserts that groundwater in the area flows from the site travels toward Little Sugar Creek which is 1,400 feet to the east. This small creek discharges into larger water body known as Sugar Creek. Based on an average hydraulic gradient of 0.0075 to 0.01 foot per foot, a hydraulic conductivity of 0.5 to 1.25 feet per day, and an effective soil porosity of 0.3 for sandy silt, the estimated groundwater flow velocity in the subsurface at this site is approximately 5 to 15 feet/year. The company used a range of groundwater flow velocities in calculations as a means to predict the rate of movement of contaminants from the site. The Unocal Corporation asserts that substances in the plume of dissolved petroleum hydrocarbons will enter Little Sugar Creek at concentration levels exceeding 15A NCAC 2L .0202 standards for Benzene, Ethylene Dibromide, and 1,2-Dichloroethane between 93 and 280 years. This estimated range assumes no natural degradation or attenuation of the plume occurs. The last observed concentration levels of Benzene, Ethylene Dibromide, and 1,2 Dichloroethane from routine sampling in December 1995 were used to determine these projected times of travel to Little Sugar Creek. (See page 3-4 of the March 6, 1996 letter titled "Resp onses to 2/19/96 NCDEHNR Letter for Variance Req uirements"). 8 Rule . 0113 ( c )( 4 ): Supp ortimz information to establish that the variance will not endanger the public health and safety ... : This part of the variance concerns Groundwater Quality Standards shown in 15A NCAC 2L. 0202 and has been requested for Benzene, Ethylbenzene, Toluene, Xylene(-o,-m, and p), Naphthalene, Methyl Tert-Butyl Ether (MTBE), Isopropyl Ether, Ethylene Dibromide, 1,1-Dichloroethane, 1,1-Dichloroethene, 1,2- Dichloroethane, 1,1,1,-Trichloroethane, 1,1,2,2,-Tetrachloroethane, 1,1,2 Trichloroethane, 1,2, Dichloropropane, Bromodichloromethane, Bromoform, cis- 1,3-Dichloropropene, Carbon Tetrachloride, Chloroform, Dibromochloromethane, Methylene Chloride, trans-1,3-Dichloropropene, Chloroethane, and 1,2- Dichlorobenzene, 1,3-Dichlorobenzene, 1,4-Dichlorobenzene, and Chlorobenzene. In order to assess health impacts, monitoring wells were sampled at or near this site to assess the extent of contamination and concentration levels of substances~ Concentrations of substances in recovery wells were also examined to determine the effectiveness of the pump and treat system at removing these chemicals. Groundwater monitoring data from the Unocal Corporation indicates that substances released by the Unocal Corporation at this site do not pose a hazard to the public. Sampling and analysis of on-site wells at 4336 Park Road has been conducted since January 13, 1988 at monitoring wells and is being continued at the present time. A total of eleven different sampling events occurred from 1988 through 1995 at five monitoring wells located at the site. A total of seven different sampling events occurred at Monitoring Well# 8 from January 13, 1988 through September 3, 1993 before this well was converted into an air sparging well pursuant to the specifications of the corrective action plan received by the Mooresville Regional Office on March 18, 1993. Analysis of off-site monitoring wells at Belk Investments (Monitoring Well # 10) and the Pop Shop (Monitoring Well# 11) began on January 27, 1993. Six different sampling events have occurred at these off-site wells on properties adjacent to the site at 4336 Park Road. The last sampling and analysis at all monitoring wells occurred on December 1, 1995. From January 27, 1993 through December 19, 1995 analysis of recovery wells was also conducted by the Unocal Corporation. Six sampling and analysis events have occurred at each of the four recovery wells since December 1991. In addition, when "effluent" sample are taken at the well head of these recovery wells, the Unocal Corporation also obtains a composite sample from the "influent" by taken samples from pump-and-treat system from the recovery wells. Composite samples are taken from untreated water within the groundwater recovery system or from the submersible pump. On six different occasions samples have been taken at the influent for these four recovery wells since June 3, 1993. USEP A Method 601 and Method 602, and 504.1 were the analytical methods used for samples collected at the Unocal Corporation site. USEP A Method 601 is used to assess the concentration levels of chlorinated hydrocarbons such as 1,2-Dichloroethane and Chloroform. USEP A Method 602 9 is used to assess the concentration levels of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE. USEP A Method 504.1 is used to determine the concentration level of Ethylene Dibromide. A comprehensive listing of all monitoring results from wells is shown in the December 29 , 19'95 Letter Of Transmittal. The December 29 , 1995 Letter Of Transmittal includes all groundwater sampling results from monitoring wells through December 1, 1995 and all from recovery wells through December 19, 1995. The highest concentration of any substance found at this site was 15 milligrams per liter (mg/L) or 15,000 micrograms per liter (ug/L) of Ethylbenzene in Monitoring Well# 5 on December 16, 1991. The Groundwater Quality Standard for this substance is 0.029 milligrams per liter (29 micrograms per liter) pursuant to 15A NCAC 2L .0202(g)(40). The December 16, 1991 sampling and analysis of this well took place prior to the implementation of cleanup on August 12, 1993. Ethylbenzene was not detected in any other monitoring wells during this sampling event. Analysis for Ethylbenzene was also conducted for recovery wells on December 16, 1991. Only Recovery Well# 4 showed Ethylbenzene in exceedence of the Groundwater Quality Standard on December 16, 1991. The concentration of this substance in this recovery well was 0.2 milligrams p~r liter (mg/L) or 200 micrograms per liter (ug/L). Analysis of subsequent groundwater samples from 1992 through 1995 has revealed that Ethylbenzene contamination in all monitoring wells, including Monitoring Well# 5, and the recovery wells had declined over time to the extent that Ethylbenzene concentrations no longer appear above the standard in 15A NCAC 2L .0202(g)(40) or can no longer be detected. On February 23, 1995 routine groundwater sampling and analysis was conducted for the seven monitoring wells at this site. The highest concentration of any substance in any well during this sampling event was at Monitoring Well# 9. USEPA 601 analysis of a sample from this well showed 1,2-Dichloroethane at 0.02460 mg/L or 24.60 ug/L. The Groundwater Quality Standard for 1,2- Dichloroethane is 0.00038 mg/L or 0.38 ug/L. Analysis of a sample .from Monitoring Well# 7 showed Chloroform at 0.0085 mg/Lor 8.5 ug/L. The Groundwater Quality Standard for Chloroform is 0.00019 mg/L or 0.19 ug/L. Monitoring Well# 7 and # 9 did not show any other substances above detection limits when analyzed using the USEP A 601 Method. Concentrations of Chloroform and 1,2 Dichloroethane in the remaining monitoring wells were below detection limits. Analysis of samples from all seven monitoring wells by the USEP A 602 Method showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below detection limits. Analysis of samples using USEP A Method 504.1 did not reveal concentrations of Ethyl Dibromide in any of the seven monitoring wells above the detection limits. During the February 23, 1995 monitoring event the Unocal Corporation also conducted sampling of the four recovery wells. Samples taken from three of the four recovery wells had concentrations of substances in exceedence of Groundwater Quality Standards in 15A NCAC 2L .0202. Recovery Wells #1, # 3 10 and # 4 all showed concentrations of 1,2-Dichloroethane in exceedence of the standards. Recovery Well# 1 and Recovery Well# 3 showed concentrations of 1,2 Dichloroethane above the groundwater standard for 1,2-Dichloroethane. Recovery Well# 1 showed 0.00298 milligrams/Liter (mg/L) or 2.98 micrograms/Liter of 1,2-Dichloroethane. The highest level of 1,2-Dichloroethane found during this sampling event was at Recovery Well# 3. USEPA 601 analysis of a sample from this well showed 1,2-Dichloroethane at 0.01550 mg/L or 15.50 ug/L. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.00038 mg/Lor 0.38 ug/L. Recovery Well# 1 and Recovery Well# 4 showed concentrations of Chloroform above the standards. Recovery Well # 1 showed 0.00218 milligrams/Liter (mg/L) or 2.18 micrograms/Liter of Chloroform. The highest concentration of Chloroform at the recovery wells during this sampling period was 0.00458 mg/Lor 4.58 ug/L at Recovery Well# 4. The Groundwater Quality Standard for Chloroform is 0.00019 mg/L or 0.19 ug/L. Analysis of these four samples by USEP A 602 Method showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. None of the recovery wells showed concentrations of these substances above practical quantitation limits. Analysis of recovery well samples using USEPA Method 504.1 showed concentrations of Ethylene Dibromide above the 15A NCAC 2L .0202 standards in two of the four recovery wells. Recovery well # 1 showed the highest concentration of Ethylene Dibromide at 2.48 x 10-4 mg/L or 0.248 ug/L. Recovery Well # 4 also showed a concentration level of Ethylene Dibromide above the Groundwater Quality Standard at 5.26 x 10-5 mg/Lor 0.0526 ug/L. The Groundwater Quality Standard for Ethylene Dibromide is 4.0 x 10-7 mg/L or 4.0 x 10-4 ug/L. The Unocal Corporation also conducted composite sampling of the influent for these recovery wells in February 1995. Analysis of this composite sample did not show the concentration of any substance above the Groundwater Quality Standards in 15A NCAC 2L .0202. The second groundwater sampling in 1995 was conducted at the seven monitoring wells on June 2, 1995. Only two monitoring wells showed concentration levels above the Groundwater Quality Standard in 15A NCAC 2L .0202 using USEPA Method 601. Monitoring Well# 9 revealed 1,2- Dichloroethane at 0.00955 mg/L or 9.55 ug/L. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.00038 mg/L or 0.38 ug/L. Groundwater analysis from Monitoring Well# 7 revealed Chloroform at 0.0116 mg/Lor 11.6 ug/L. The Groundwater Quality Standard for Chloroform is 0.00019 mg/L or 0.19 ug/L. Analysis of the samples from these wells by the USEPA Method 602 showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. None of the monitoring wells showed concentrations of these substances above practical quantitation limits. Analysis of samples using USEP A Method 504.1 did not reveal concentrations of Ethyl Dibromide in any of these monitoring wells above the detection limits. The company did not conduct any sampling of 11 the recovery wells in June 1995. On December 1, 1995 the company conducted a third round of sampling at the request of the Mooresville Regional Office. The reg~onal office wanted an analysis of samples from both monitoring wells and recovery wells since the time the pump-and-treat, soil vapor extraction, and air sparging devices were turned off in September 1995. This special monitoring was to determine the on-site and off-site concentration levels of substances when no groundwater cleanup technologies are in operation. Table # 1 of the December 29, 1995 Letter of Transmittal shows from USEP A Method 601, 602, and 504.1 analytical methods. Two of the seven monitoring wells had concentrations of substances in exceedence of the Groundwater Quality Standards in 15A NCAC 2L .0202. Analysis of samples using USEPA Method 601 revealed Monitoring Well# 5 with 1,2 Dichloroethane at 0.00615 mg/L or 6.15 ug/L. This analysis of a sample at Monitoring Well# 9 using USEPA Method 601 revealed the concentration level of 1,2-Dichloroethane at 0.00447 mg/Lor 4.47 ug/L. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.00038 mg/L or 0.38 ug/L. No other monitoring well showed the presence of any substances that can be detected by USEP A Method 601. Analysis of the same samples from these seven monitoring wells by the USEP A Method 602 showed the presence of Benzene in Monitoring Well# 5 at 0.00863 mg/Lor 8.63 ug/L. The Groundwater Quality Standard for Benzene 0.00100 mg/Lor 1.00 ug/L. Analysis of the groundwater samples from the remaining six monitoring wells by the USEP A Method 602 showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. None of the monitoring wells showed concentrations of these substances above practical quantitation limits. Analysis of the samples using USEP A Method 504.1 revealed that Monitoring Well # 5 had a concentration of Ethylene Dibromide above the 15A NCAC 2L .0202 standards. The concentration of Ethylene Dibromide in this well was 6.52 x 10-4 mg/L or 0.652 ug/L. The Groundwater Quality Standard for Ethylene Dibromide is 4.0 x 10-1 mg/Lor 4.0 x 10-4 ug/L. None of the remaining six monitoring wells showed this substances above detection limits. On December 19, 1995 Unocal Corporation also conducted sampling of the four recovery wells. Table 1 shows that samples taken from two of the four recovery wells had concentrations of substances in exceedence of Groundwater Quality Standards in 15A NCAC 2L .0202. Recovery Well #1 and Recovery Well # 4 both showed concentrations of 1,2-Dichloroethane in exceedence of the standards. The concentration of 1,2-Dichloroethane in Recovery Well# 1 was 0.00298 mg/L or 2.98 ug/L. The highest level of 1,2-Dichloroethane found during this sampling event was at Recovery Well # 4. USEPA 601 analysis of a sample from this well showed 1,2-Dichloroethane at 0.01970 mg/L or 19.70 ug/L. The Groundwater Quality Standard for 1,2-Dichloroethane is 0.00038 mg/L or 0.38 ug/L. Chloroform did not appear in these wells in concentrations above the practical quantitation level. Analysis of the same samples from these four recovery wells by the USEP A Method 602 showed the presence of Benzene in 12 Recovery Well# 4 at 0.00135 mg/Lor 1.35 ug/L. The Groundwater Quality Standard for Benzene 0.00100 mg/L or 1.00 ug/L. Analysis of the remaining three samples by USEP A 602 Method showed the concentrations of Benzene, Toluene, Ethylbenzene, Xylenes, and MTBE below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. None of the recovery wells showed concentrations of these substances above practical quantitation limits. Analysis of recovery well samples using USEP A Method 504.1 did not reveal concentrations of Ethyl Dibromide in any of these wells above the detection limits. The Unocal Corporation also conducted composite sampling of the influent for these recovery wells in December 1995. Analysis of this composite sample did not show the concentration of any substance above the Groundwater Quality Standards in 15A NCAC 2L .0202. The Unocal Corporation has attempted to define the vertical extent of groundwater contamination beneath the site. The deepest well Monitoring Well # 8 (MW # 8) and it is 55 feet below the ground surface. Groundwater sampling and analysis was conducted using USEP A Method 601, Method 602, and Method 504.1 at six separate times from January 13, 1988 through January 27, 1993 as shown in Table # 1. Analysis sample from this well over a six year period using USEP A Method 601 showed the concentrations of 1,2-Dichloroethane, Chloroform and other substances below their respective Groundwater Quality Standards in 15A NCAC 2L .0202. The analysis of the January 13, 1988 sampling event for Monitoring Well # 8 using USEP A Method 602 showed a concentration of Benzene at 0.003 mg/L or 3 ug/L. This level is in exceedence of the Groundwater Quality Standard of 0.001 mg/L or 1 ug/L for this substance in 15A NCAC -2L .0202. The highest level Benzene that was ever found in this well in exceedence of the standard was on December 16, 1991. Analysis using USEP A Method 602 revealed Benzene at 0.010 mg/I or 10 ug/L. The last sample taken at this well was on January 27, 1993 and no Benzene was detected above the practical quantitation limit. The analysis of all other samples taken from this well from January 1988 through January 1993 did not reveal any other chemical constituent from the petroleum release. After January 1993 this monitoring well was converted into an air sparging well and no additional data can be obtained. Based on the low concentrations of Benzene found in samples from Monitoring Well # 8 over a five year period, the Mooresville Regional Office does not believe that the bedrock beneath 4336 Park Road was significantly impacted by this release prior to implementation of the corrective action plan in August 1993. On page # 3 of a letter dated March 6 , 1995 titled "Responses to 2/19/96 NCDEHNR Letter for Variance Req uirements" downgradient monitoring at the well located at Monitoring Well# 11 (The Pop Shop) is discussed. The letter states that "No ..... dissolved hydrocarbons except MTBE (11 ug/L) have ever been detected in Groundwater .... .from this well''. It must be noted that this concentration level in this monitoring well is well below the Groundwater Quality Standard in 15A NCAC 2L .0202. Analytical results from samples taken at Monitoring Well# 10 (Belk Investments) over the past 3 1/2 years have never 13 shown any chemical constituent above the detection limits. With respect to the site at 4336 Park Road, Monitoring Well # 10 is located cross-gradient from it. All samples from Monitoring Well# 10 were analyzed using EPA Methods 601, 602 and 504.1. Using site assessment information at the Mooresville Regional Office, the company has calculated the time it would take for residual contaminants to impact the down-gradient offsite monitoring well at the Pop Shop (Monitoring Well# 11) such that Groundwater Quality Standards would be exceeded. Based on a groundwater flow velocity between 5 feet to 15 feet per year, the Unocal Corporation estimates that amount of time it will take both Benzene and Ethylene Dibromide to reach Monitoring Well# 11 are between 14 and 42 years. This estimated range is based on the maximum concentration for Benzene and Ethyl Dibromide found at the site that were obtained from the analysis of a sample from Monitoring Well# 5 on December 1, 1995. The range of time estimated for 1,2-Dichloroethane to reach Monitoring Well# 11 is 9 to 28 years. This estimate is based on the maximum concentration of this substance that was obtained from the analysis of a sample from Recovery Well# 4 on December 19, 1995. Estimated time ranges are based on the conservative assumption that the plume will not be impacted by natural remedial processes and attenuation effects within the subsurface. It is not anticipated that rainfall events will significantly impact the movement of contaminants offsite. The area where groundwater monitoring results showed concentrations of Benzene, 1,2-Dichloroethane, and Ethylene Dibromide above the standards is beneath a concrete slab and the remaining property at 4336 Park Road is covered by an asphalt parking lot. Based on the calculations by the Unocal Corporation, it is not anticipated that groundwaters in the area will be impacted by a variance at this site within the near future. No sources of drinking water from water wells or surface water are known to exist within a 1/2 mile radius of the property at 4336 Park Road that was formerly owned by the Unocal Corporation. The requirements for variance applications in 15A NCAC 2L .0113(c)(4) specify that locations of drinking water wells and other water supply sources that are within one-half mile of the site must be shown on a map. The attachments to the "March 6, 1996 letter titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements" labeled Figure 4, Figure 5, and Figure 6 show that there are no drinking water wells in the vicinity of the property at 4336 Park Road. Figures 5 and 6 are maps showing utility and water use in the area. These maps show that properties around the site are serviced by the Charlotte Mecklenburg Utility Department. Page 2 of the March 6, 1996 letter it states that the company conducted a survey of a 1/2 mile area around the site and did not find any drinking water wells that are presently in use or have been abandoned. Figure 7 in March 6, 1996 letter shows that there are no drinking water supply intakes at surface water bodies located within a 1/2 mile radius of the site. Drinking water for the City of Charlotte is obtained from Mountain Island Lake on the Catawba River twelve miles north-northwest of the site. All downgradient 14 properties and other area properties are supplied drinking water from the City of Charlotte. In addition to monitoring wells and recovery wells previously discussed, there are a number of other wells on properties adjacent to 4336 Park Road. There are approximately six groundwater monitoring wells downgraident from the site. These wells are located at the "Pop Shop" and is across the road at 4323 Park Road. The Well Survey Map (Figure 4) attachment to the March 6, 1996 memorandum shows these six monitoring wells. Two of these wells are described in the map legend as "closed". The Unocal Corporation has submitted information on pages 3 and 4 of the March 6, 1996 letter showing that concentrations of contaminants will not impact these downgradient wells to the extent that an exceedence of Groundwater Quality Standards will occur in the near future. There are two "tank pit vapor point wells" located at the Exxon Company service station at 125 Woodlawn Road. These wells are to the south and the southeast respectively of the property at 4336 Park Road and are cross- gradient from the site. Since these wells are located cross-gradient from the site, is unlikely that migrating contaminants as a result of this release emanating from 4336 Park Road would degrade the construction materials used in these wells or impact groundwaters. It is highly improbable that public water supply lines will be impacted by this variance. Numerous water supply lines and other utilities are located along Park Road and Woodlawn Road. This piping ranges from 4 inches up to 16 inches in diameter. Page 8 of Appendix II in the report titled Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facility # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Project No. 1354-92-397 {November 1995)" shows that the company contacted Charlotte Mecklenburg Utility Department and found that utilities are not a potential path for migration of petroleum hydrocarbons from the site. The depth to the groundwater in this area is approximately 17 feet. The utility department reported that area water lines and utilities are buried less than five (5) feet from the surface. Groundwater contamination from Incident Number 3633 that is beneath 4336 Park Road is too deep within the subsurface to impact these lines. In addition, page 8 also states the Unocal Corporation did not locate any buildings with basements that could serve as conduits for the buildup of explosive, flammable, or toxic vapors from this site. Rule .0113(c)(5): Supporting information to establish that requirements of the rule cannot be achieved by providin!l best available technology economicall v reasonable: The part of the request that concerns variance to Corrective Action in 15A NCAC 2L .0106(j) will allow the Unocal Corporation to discontinue Corrective Action at this site. The company has submitted supporting information in the report and other documents demonstrating that the continued application of BAT 15 will not result in significant long term remediation of the site to the Groundwater Quality Standards contained in 15A NCAC 2L .0202. The is due to the high probability that continued cleanup activities at the site will not significantly reduce contaminant levels below Groundwater Quality Standards in 15A NCAC 2L .0202. Since discovery of the release on February 18, 1988 the Unocal Corporation has disposed of a total of 3,000 pounds of petroleum contaminated soil. The company has treated approximately 4.12 million gallons of groundwater to comply with the cleanup requirements of the Corrective Action Plan that implemented on August 12, 1993. Pages 5 through 8 of the report titled "Variance Req uest Incident No. 3633 Unocal Corp oration Former Unocal Facility # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Proiect No. 1354- 92-397 (November 1995)" states that a total of $579,995 has been expended to remove tanks, conduct site assessments, and cleanup this site. The amount of money that has been spent by the Unocal Corporation at this site is summarized as follows: Activitv Total Cost ($) Total Cost of Tank Removal, Property Renovation, and Initial Abatement of the Release $135,000 Total Costs to Complete a Comprehensive Site Assessment $ 95,000 Total Costs of Completing a Corrective Action Plan and Local Permitting $ 36,495 TOTAL COST TO COMPLETE ACTIVITIES REQUIRED BY 15A NCAC 2L .0106 (A-, AND F-1) $)Jij6.;4:,t Total Cost to Install Cleanup Systems (pump-and-treat, soil vapor extraction, and air sparging technologies) $198,500 Total Cost of Operating and Maintaining Cleanup Technologies Over the Last Three Years $115,000 TOTAL COST TO IMPLEMENT CORRECTIVE ACTIONS AS REQUIRED BY 15A NCAC 2L .0106(J) ~)~~~;$:9:~ 16 .. The March 31, 1995 letter shown on page 9 of Appendix II shows that the Unocal Corporation has incurred the entire cost of cleanup of this site. Appendix I shows an itemized listing of costs to remediate this site. Groundwater analysis of samples from on-site monitoring wells showed significant reductions in the concentrations of substances from December 1991 through September 1994. On August 12, 1993 the Unocal Corporation implemented a corrective action plan to cleanup groundwaters at this site. From August 12, 1993 through September 29, 1995 the Unocal Corporation operated a groundwater remediation systems consisting of pump-and-treat cleanup, air sparging, and soil vapor extraction technologies. Groundwater monitoring up through the September 13, 1994 sampling event showed reductions in the concentrations of substances in the groundwater. Since that time analysis of samples from groundwater monitoring wells and recovery wells have not demonstrated a significant reduction in contaminant concentrations as shown in Table 1 of the "Letter of Transmittal" dated December 29, 1995. In September 1995 use of the pump-and-treat system was discontinued. On December 1, 1995 groundwater monitoring was conducted to determine the effect a temporary interruption of the operation of the pump-and-treat groundwater remediation system would have on contaminant concentrations. Except for Monitoring Well # 5, which showed Benzene, Ethylene Dibromide, and 1,2-Dichloroethane, no increase in the concentrations of substances was observed in the remaining groundwater monitoring wells. It is important to note that the concentration of Benzene in Monitoring Well# 5 had remained below detectible limits in 1995 wben the cleanup systems were in operation. Significant reductions in the concentrations of Benzene and 1,2 Dichloroethane have not been observed in recovery wells since September 1994. It was only during the December 1, 1995 sampling event that Chloroform concentrations showed a reduction below detectable levels in Monitoring Well# 7. In order to demonstrate that the requirements of the rule cannot be achieved using best available technology, title 15A NCAC 2L .0113(c)(5) requires that specific technology considered be identified, the costs of implementing the technology be shown, and the impacts of the costs on the applicant be provided. On Page 8 of the report titled "Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facilitv # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Project No. 1354-92-397 (November 1995)" shows the cost of continuing to operate the present cleanup system. The company has estimated that it will cost approximately $180,000 over the next three years to continue operating the air sparging, pump and treat, and soil vapor extraction systems. This cost estimate assumes that the Charlotte Mecklenburg Utility Department will issue a new permit to continue allowing treated effluent from the pump-and- treat system to be discharged into the sanitary sewer system. If a permit to discharge treated wastewater into the city's sanitary sewer system cannot be obtained, then the costs to continue using pump-and-treat cleanup as a means of 17 .. remediation will drastically increase. This cost increase would occur as a result of the necessity for the Unocal Corporation to obtain the necessary NPDES permit to construct a discharge to Little Sugar Creek. The only other option the company may have is to have a discharge system constructed that meets the requirements of a non-discharge permit in accordance with 15A NCAC 2H .0200 (Waste Not Discharged to Surface Waters). The cost figures supplied by the Unocal Corporation also assumes that Mecklenburg County Department of Environmental Protection will issue a new air quality permit for air sparging and soil vapor extraction systems. The Unocal Corporation has considered the use of air sparging as an alternate technology to the present groundwater and soil remediation system. The company does not believe that the use of this technology by itself is practical to meet the requirements of 15A NCAC 2L .0113(c)(5). The company estimates the costs of operating an air sparging system for three years would be approximately $45,000. The Unocal Corporation believes that the low residual concentrations of substances in groundwater at the site and the lack of any human receptors does not warrant the additional expense of continuing reliance on air sparging. The company believes that the low residual levels of contaminants in soils at this site does not warrant the continued use of soil vapor extraction technology to cleanup this sit~. Table 1 in Appendix III of this same report titled "Variance Req uest Incident No. 3633 Unocal Corp oration Former Unocal Facility # 9342- 209 4336 Park Road Charlotte, North Carolina S&ME Project No. 1354-92-397 (November 1995)" shows measurements of total petroleum hydrocarbons (TPH) in soil vapor and organic vapor analyzer (OVA) readings. Based on this information the company asserts that residual concentrations of petroleum in soils at 4336 Park Road in Charlotte, North Carolina will be below the state action level of 10 parts per million and not pose an impact to groundwaters such that a violation of Groundwater Quality Standards is anticipated to occur. The Unocal Corporation did not identify any technology, other than those already in use at the site, that would meet the requirements of 15A NCAC 2L .0106(j) as "best available technology". Pursuant to the requirements of 15A NCAC 2L .0113(c)(5), the company does not believe that continuing remediation with any of the technologies, or any combination of technologies, at the site are "economically reasonable". Rule .0113 (c )(6): Supp orting information to establish that compliance would produce serious financial hardship on the a pp licant: The Unocal Corporation has submitted information showing that compliance with the rules will result in a serious financial hardship. Page 8 of the report shows that the Unocal Corporation has demonstrated that the continued 18 .. application of best available technology to this location would be a prohibitively expensive method of remediating groundwater contamination. The report states on page 9. of Appendix II that "Unocal is no longer operating this gasoline retail facility or making a profit at this site ...• ". Groundwater Section staff have examined the state trust fund status of this site and have found that a claim for reimbursement through the Commercial Underground Storage Tank Trust Fund has never been filed by the Unocal Corporation. The Unocal Corporation has thus far spent $313,500 to cleanup this site. A March 6, 1996 letter titled "Responses to 2/19/96 NCDEHNR Letter for Variance Requirements" further discusses cleanup activities at this site. Page 6 of this letter shows that the company is continuing to operate the air sparging system and will do so until " ... site closure has been approved". In Appendix I of the "Variance Request Incident No. 3633 Unocal Corporation Former Unocal Facility # 9342-209 4336 Park Road Charlotte, North Carolina S&ME Project No. 1354-92-397 {November 1995)" Mr. Wayne Holt asserts that unless a variance leading to closure of this site approved, ongoing remedial actions at 4336 Park Road will result in continual expenditures by the Unocal Corporation .. The company believes that there is immense uncertainty that best available technology will remediate the groundwaters at this site to standards within a foreseeable period of time. Page 6 of the March 6, 1996 letter states that the that " ..... soil and groundwater restoration has occurred as close to the level of the state standards as economically and technically feasible". Allowing the persistence of low levels of contaminants in groundwaters that, after approximately 1 3/4 years of applying best available technologies, have asymptotically approached the Groundwater Quality Standards in 15A NCAC 2L .0106 through a variance is a prudent means of addressing Unocal's release at this site. It is no less effective a means of addressing residual concentrations of substances at this site than continuing the use of pump-and-treat, soil vapor extraction, and air sparging and is less expensive. Rule .0113(c)(7): Supporting information that compliance would produce serious financial hardship without equal or greater public benefit: The company has submitted information in the request demonstrating that the environment, safety and public health would not be impacted by this variance. The Groundwater Section believes that the public will not benefit from compelling the Unocal Corporation to continue remediating this site using pump- and-treat technology, other alternatives discussed, or a combination of these technologies. 19 .. Rule .0l 13 (c)(8): "A co py of any Special Order ... ": No Special Order by Consent has been issued for this site. Rule .0l 13 (c)(9): "A list of names and addresses of pro perty owners ... ": The property owners within the proposed area of the variance are shown on pages 4 through 6 of the March 6, 1996 letter titled "Res ponses to 2/19/96 NCDEHNR Letter for Variance Re quirements". This listing includes the Hardees Restaurant, The Pop Shop, The Exxon Gas Station, Belk Investments, a vacant home owned by Mr. Duncan MaCrae, Jr., the Charlotte-Mecklenburg Utility Department, the NC Department of Transportation, the Park Chase Apartments, Nationwide Insurance, and the Petro Express Gasoline Station Number 7. Title 15A NCAC 2L .0113(e)(E) requires that notification of a public hearing on this variance be given to the owner or owners of these adjacent properties "at least 30 days prior to the date of the hearing". It is the recommendation of the Groundwater Section that the subject variance request to Corrective Action requirements of 15A NCAC 2L .0106G) and Groundwater Quality Standards contained in 15A NCAC 2L .0202 proceed to public notice in accordance with 15A NCAC 2L .0113(e). On November 28, 1995 the Division of Epidemiology completed their review of the risk assessment methodology for this site and recommended that this variance be granted for the Unocal Corporation at 4336 Park Road in Charlotte, North Carolina. Upon your concurrence with our recommendation, the Groundwater Section will proceed with the preparation of the required public notice and hearing. Upon completing of the requirements of 15A NCAC 2L .0l 13(d -t), with a recommendation to grant this variance from the Environmental Management Commission Groundwater Committee, this request will proceed to the Environmental Management Commission for final action in 15A NCAC 2L .0l 13(g). If there are any questions regarding this matter or if any additional information is needed, please let me know. ATTACHMENTS: cc: Groundwater Section Assistant Chiefs Mooresville Regional Groundwater Supervisor Dr. Ken Rudo David Hance 20 NOTE: 07/08/96 TO: Donna, SUBJECT: UNOCAL-PARK ROAD VARIANCE REQUEST WITH JUSTIFICATION (GW Incident# 3633). Here is a variance request for Unocal Oil Company at 4336 Park Road in Charlotte, NC. Preston Howard returned this variance request to us because he wanted a justification included that will explain why this site needs a variance over an alternate CAP. S&ME Incorporated has provided a letter to this effect with · attached materials obtained from the Groundwater Section. This information is included with this packet requesting that a variance be granted for this site. If changes are needed to the memoranda please let me know. Once the Director is satisfied that this site meets the criteria of 15A NCAC 2L .0113(d), please make sure he has signed the memorandum before this request is returned to me. If possible, we would like the review of this package completed by July 16, 1996. If you need additional information or assistance, please feel free to contact me at 715- 6189. My normal office hours are from 9am to 6pm. David Hance cc: Carl Bailey N OTE: 06/11/96 URGENT ..... ATTACHMENTS NEED REVIEW & SIGNATURE!!! TO: Donna, SUBJECT: VARIANCE REQUEST FOR FORMER UNOCAL FACILITY ON 4336 PARK ROAD IN CHARLOTTE, NC (gw INCIDENT# 3633). Attached is a variance request from the Unocal Corporation for a site in downtown Charlotte, NC. Unocal is the responsible party for cleanup of a site where a gasoline station was once located. When the company sold the property to the owners of a new retail gasoline chain, Petro Express, the old tanks were removed and release was discovered. The Unocal Corporation has aggressively cleaned-up this site using SVE, pump-and-treat, and air sparging technologies for over two years and believes a variance is appropriate for this site. Pursuant to 1 SA NCAC 2L .0113(d), the Director of DEM must review all variance requests for "completeness". The memo with a yellow post-it note marked summary provides a detailed review of the attached materials. ONCE the Director deems this variance request meets the requirements of 1 SA NCAC 2L .0113(d), then the Groundwater Section will proceed with scheduling a hearing, develop a public notice, and get a hearing officer from Division staff. Upon receiving the Director's signarure on the memo to Arthur Moubeny, please contact me so . I can pick it up. If you need to discuss this with me or any changes are needed please feel free to call 715-6189. David Hance 11= cc: Carl Bailey 1 ) NOTE: 06/10/96 URGENT ..... ATTACHMENTS NEED REVIEW & SIGNATURE!!! TO: Arthur Mouberry, SUBJECT: VARIANCE REQUEST FOR FORMER UNOCAL FACILITY ON 4336 PARK ROAD IN CHARLOTTE, NC (gw INCIDENT# 3633). Attached is a variance request from the Unocal Corporation for a site in downtown Charlotte, NC. Unocal is the responsible party for cleanup of a site where a gasoline station was once located. When the company sold the property to the owners of a new retail gasoline chain, Petro Express, the old tanks were removed and release was discovered. The Unocal Corporation has aggressively cleaned-up this site using SVE, pump-and-treat, and air sparging technologies for over two years and believes a variance is appropriate for this site. Two of the attached memos are to Preston Howard. One of these memos gives a detailed description of the activities that have been conducted to meet the requirements of 1 SA NCAC 2L .0113. The other memo informs the Director that this variance should go forward. In addition, a third memo is from the Director to you giving us permission to proceed with scheduling a hearing and public notice. Carl Bailey has completed his review and is satisfied with this information. UPON COMPLETING YOUR REVIEW OF THIS INFORMATION, please sign the memos with yellow post-it notes attached. I will get this entire packet to the Director for his approval in accordance with 1 SA NCAC 2L .0113 (d). Please note that the responsible party's consultant S&ME Inc., has made a number of inquires on the status of this packet in the last two weeks. Once we have the Director's approval, I will get together a public notice and schedule a hearing. We will also need to discuss a hearing officer for this meeting. If you need to discuss this with me please feel free to call 715-6189. cc: Carl Bailey 1 "TH ½ ~ --··/ David Hance I ) Recycled Paper June 14, 1995 Mr. Allen Schiff North Carolina Department of Environment, Health and Natural Resources 919 North Main Street Mooresville, N.C. 28115 N.C. DEPT. OF ENVIRONMENT, HEAL TH , & NATURAL RESOURCES JUN 1 5 1995 ,wi~ Cf £f1N1~.0!·.::;r:i1,\1 ;i:.~-\,4..U mv~ml~ii~ ri~;H~~L ,1rim~ Reference: Addendum to the 3/31/95 Request for Site Variance and Groundwater Sampling Results on 6/2/95 Incident #3633 Former Unocal Station #9342-209 4336 Park Road, Charlotte, NC S&ME Project No. 1354-92-397 Dear Mr. Schiff: Triangle Environmental Inc., on behalf of Unocal Corporation, purged and sampled _groundwater from all on-site and off-site monitor wells (7) on June 2, 1995 for EPA Test Methods 601, 602 including MTBE and IPE and 504.1. The groundwater sampling event was performed prior to deactivation of the air ~parging system on June 2, 1995. The purpose of the sampling event was to evaluate groundwater quality in comparison to the previous February 23, 1995 sampling event with the air sparging system on. The June 2, 1995 analytical results revealed that BTEX, MTBE, IPE and EDB in groundwater from all on-site monitor wells have remained below 2L standards and method detection limits ( < 0.5 ug/L) as were on February 23, 1995. BTEX and MTBE were also not detected in off-site downgradient monitor well MW-11 at the Pop Shop. Off- site monitor well MW-1 O at the Belk Investments property exhibited 11.4 ug/L total xylenes, which is due to a separate release from a former fuel oil UST on-site. Trace levels of 1, 1-dichloroethene (1.27 ug/L) and chloroform (11.6 ug/L) were detected in groundwater from monitor well MW-7. Trace levels of 1,2-dichloroethane (9.55 ug/L) were detected in groundwater from monitor well MW-9. The state 2L groundwater standards for these purgeable halocarbons are as follows: 7 ug/L for 1, 1-dichloroethene, 0.19 ug/L for chloroform and 0.38 ug/L for 1,2-dichloroethane. All other 601 compounds S&ME, Inc. 9751 Southern Pine Boulevard, Charlotte, North Carolina 28273, (704) 523-4726, Fax (704) 525-3953 Mailing address: P.O. Box 7668, Charlotte, North Carolina 28241-7668 I NCDEHNR-Groundwater Section Addendum to 3/31 /95 Request for Variance S&ME Project No. 1354-92-397 June 14, 1995 were below method detection limits, as indicated on the laboratory analyses. Table 1 indicates historical groundwater and influent quality for the site and off-site monitor wells MW-1 o and MW-11. All seven monitor wells will be purged and sampled in August 1995 for the same analyses to evaluate if any "rebounding" of dissolved hydrocarbon concentrations occurred with the air sparging system off. We believe that continued remediation, using best available technology (air sparging), will not result in significant further reduction in the groundwater concentration of these contaminants, and therefore, we petition for a variance to the 2L groundwater remediation guidelines (per 15A NCAC 2L .0113). We request that the state establish site-specific closure criteria, given that asymptotic contaminant concentrations for some purgeable halocarbons exceed the 2L or Class GA groundwater quality standards. We believe that soil and groundwater restoration has occurred as close to the level of the state standards as is e,conomically and technically feasible. If you have any questions or need additional information, please call. Very truly yours, S&ME, INC~ ~ &/1'{/'fS Stewart M. Hines, LG. Senior Hydrogeologist SMH\ Enclosures cc: Mr. A. Wayne Holt, P.G. -Unocal Corporation Mr. R. Holshouser, Jr. -S&ME, Charleston, S.C. P:\WP51\SCHIF95.613 2 T. _..-1 HISTORICAL GROUNDWATER ANO INFLUENT QUALITY DATA _) FOAMER UNOCAL FACILITY #9342-209 4336 PARK ROAD, CHARLOTTE. NC -·-, ,c, HOO 601 COWOUNOS MONITOR WELL DATE BENZENE TOLUENE ETHYL-TOTAL TOTAL MIBE I l'E EDB 1,2-DCA CHLORO-1, 1--0CE 1,1-0CA 1,2-DCP TCE L CE r ,1,1-TCA NAPTHA- BENZENE XYLENES BTEX FORM LENE MW-1 1/13/88 1.3 2.2 <1 <1 3.5 NA NA NA NA NA NA NA NA NA NA NA NA 7/15/91 3.6 <1 <1 <1 3,6 <1 NA NA NA NA NA NA NA NA NA NA NA 12/15/91 5 1 3 11 20 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 3/11/92 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 . <1 <1 <1 <1 <1 NA 6/26/92 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 1/27/93 <1 <1 <1 <1 <1 <1 <1 <0.02 <1 <1 14 4 <1 <1 26 53 <10 3/16/94 <0.5 <0.5 <0.5 <0.5 <0.5 2.66 <1 <0.005 <1 <1 <1 <1 <1 <1 <1 <1 NA 9/13/94 <0.5 <0.5 <0,5 <0.5 <0.5 <0.5 <0.5 <0.005 <1 1.16 <1 <1 <1 <1 <1 <1 NA 2/23/95 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 <1 <1 <1 <1 <1 <1 <1 <1 NA 6/2/95 <0,5 <0,5 <0,5 <0.5 <0.5 <0.5 <1 <0.01 <1 <1 <1 <1 <1 <1 <1 <1 NA 1,W{"~. 3/5/90 6400 17 ,000 2200 11 ,000 36,600 NA NA NA NA NA NA NA NA NA NA NA 1600 12/16/91 6100 3200 15,000 21,000 47 ,300 <1 <1 NA <1 4200 <1 <1 <r <1 <1 <1 NA 6/26/92 5600 7300 1300 10,100 24,300 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 1/27/93 NOT SAIJP L i:I) SINCE FF EEPROOUC DETECTED IN WELL 3/16/94 67.6 443 191 1310 2040 11 <1 0.926 <10 <10 <10 <1 <10 <1 <1 <1 NA 9/13/94 2.63 1.28 0.541 27.7 32.1 3.77 <0.5 <0.372 3.73 <1 <1 <1 <1 <1 <1 <1 NA 2/23/95 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 <1 <1 <1 <1 <1 <1 <1 <1 NA 6/2/95 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 <J_ <1 <1 <1 <1 <1 <1 <1 NA MW--'6 1/13/88 1.5 <1 <1 2.6 4.1 NA NA NA NA NA NA NA NA NA NA NA NA 7/15/91 <1 <1 <1 <1 <1 <1 NA NA NA NA NA NA NA NA NA NA NA 12/16/91 2 2 5 1 10 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 3/11/92 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 6/26/92 3.3 <1 <1 <1 3.3 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 1/27/93 <1 <1 <1 <1 <1 <1 <1 <0.02 <1 <1 <1 <1 <1 6 <1 <1 <10 3/16/94 <0.5 <0.5 <0.5 <0.5 <0.5 2.93 <1 <0.005 <1 <1 <1 <1 <1 <1 <1 <1 NA 9/13/94 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.005 <1 <1 <1 <1 <1 <1 <1 <1 NA 2/23/95 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 <1 <1 <1 <1 <1 <1 <1 <1 NA i;..;.;.. 6/2/95 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 <1 <1 <1 <1 <1 <1 <1 <1 NA · 15ANCAC2L 1 1000 29 530 NA 200 NA 4E-4 0.38 0.19 7 71X1 0.56 28 0.7 200 21 STANl>Aft[) (IN UG/\.) TABLE 1 HISTORICAL GROUNDWATER AI\D INFLUENT QUALllYDATA FORMER UNOCAL FACILllY #9342-209 4336 PARK ROAD, CHARLOTTE, NC METHOD 601 COWOUI\DS - MONITOff WELL DATE BENZENE TOLUENE ETHYL-TOTAL TOTAL MTBE l'E EDB 1,2-DCA CHLORO-1,1-DCE 1,1-DCA 1,2-DCP TCE PCE 1,1,1-TCA NAPTHA- BENZENE XYLENES BTEX FORM LENE M.W-7 1/13/88 <1 <1 <1 <1 <1 NA NA NA NA NA NA NA NA NA NA NA NA 7/15/91 <1 <1 <1 <1 <1 <1 NA NA NA NA NA NA NA NA NA NA NA 12/16/91 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 3/11/92 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 6/26/92 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 1/27/93 <1 <1 <1 <1 <1 <1 <1 <0.02 <1 <1 <1 <1 <1 <1 <1 5 <10 3/16/94 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.005 <1 3.38 <1 <1 <1 <1 <1 <1 NA 9/13/94 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.005 <1 8.14 <1 <1 <1 <1 <1 <1 NA 2/23/95 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 <1 8.53 1.96 <1 <1 <1 <1 <1 NA 6/2/95 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 <1 11.11 1.27 <1 <1 <1 <1 <1 NA M.W~8 1/13/88 3 7.7 2.9 17 30.6 NA NA NA NA NA NA NA NA NA NA NA NA 7/15/91 <1 <1 <1 <1 <1 <1 NA NA NA NA NA NA NA NA NA NA NA 12/16/91 10 11 25 100 146 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 3/11/92 <1 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 6/26/92 3.3 <1 <1 <1 3.3 <1 <1 NA <1 <1 ·<1 <1 <1 <1 <1 <1 NA 1/27/93 <1 <1 <1 <1 <1 <1 <1 <0.02 2 <1 <1 <1 <1 <1 <1 <1 <10 ~ 9/3/93 DEEP ITWE ll ll WELLCC NVERTEDIN OANAIR Sf ARGEWELL Mw:...9 1/13/88 170 <1 <1 <1 170 NA NA NA NA NA NA NA NA NA NA NA NA 7/15/91 130 1.8 23 7.7 162.5 60 NA NA NA NA NA NA NA NA NA NA NA 12/16/91 290 11 <1 <1 301 <1 <1 NA <1 <1 <1 <1 <1 <1 <1 <1 NA 3/11/92 250 6.4 24 7.3 267.3 11 <1 NA 190 <1 <1 <1 2.2 <1 <1 <1 NA 6/26/92 270 20 12 4.1 306.1 240 49 NA 110 <1 <1 <1 <1 <1 <1 <1 NA 1/27/93 160 <1 <1 <1 180 220 97 <0.02 51 <1 <1 <1 <1 <1 <1 <1 <10 3/16/94 26.9 0.944 1.3 1.32 30.5 99,4 <1 <0.005 68.1 <1 <1 <1 <1 <1 <1 <1 NA 9/13/94 <0.5 <0.5 <0.5 <0.5 <0.5 4.46 <0.5 <0.005 25.8 <1 <1 <1 <1 <1 <1 <1 NA 2/23/95 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 24.6 <1 <1 <1 <1 <1 <1 <1 NA 5 m o5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.01 ll.55 <1 <1 <1 <1 <1 <1 <1 NA 15~NCAC~ 1 1000 29 530 NA 200 NA 4E-4 0.36 0.19 7 700 0.56 2.6 0.7 200 21 $TANOAAO (ltfV~M MONITOR WELL DATE BENZENE TOLUENE ETHYL-TOTAL BENZENE XYLENES MW'-10 1/27/93 2 <1 1 18 (BEl,.KINVEST.) 3/16/94 1.58 <0.5 <0.5 12.3 9/13/94 0.736 <0.5 1.14 16.2 2/23/95 1.12 <0.5 1.38 11 .1 6/2/95 <0.5 <0.5 <0.5 11 .4 MW-11 1/27/93 <1 <1 <1 <1 (PQPSl10P) 3/16/94 <0.5 <0.5 <0.5 <0.5 9/13/94 <0.5 <0.5 <0.5 <0.5 2/23/95 <0.5 <0.5 <0.5 <0.5 6/2/95 <0.5 <0.5 <0.5 <0.5 RW-1 1/27/93 NA NA NA NA 3/16/94 <0.5 <0.5 <0.5 <0.5 9/13/94 <0.5 <0.S <0.S <0.5 2/23/95 <0.5 <0.5 <0.5 <0.S --RW-2 12/16/91 1300 <1 <1 <1 1/27/93 1300 <1 <1 300 3/16/94 <0.5 <0.5 <0.5 <0.5 9/13/94 <0.5 <0.5 <0.5 <0,5 2/23/95 <0.5 <0.5 <0.5 <0.5 mv-3 12/16/91 3 7 3 18 1/27/93 480 <1 <1 15 3/16/94 35.8 0.929 <0.5 <0.5 9/13/94 45.4 2.10 <0.5 <0.5 2/23/95 <0.5 <0.5 <0.5 <0.5 RW-'-4 1/27/93 4000 1200 200 3100 3/16/94 36.5 56 10.5 310 9/13/94 49.1 41.7 1.32 737 2/23/95 <0.5 <0.5 <0.5 <0.5 INR.:UENT 6/3/93 420 20 <1 68 (RW.., 1-4) 10/8/93 76 22 <1 53 1/13/94 76 <1 11 11 6/15/94 11 .1 <0.5 <0,5 <0,5 8/11/94 <6.10 <0.5 <0.5 <0.5 2/21195 <0.5 1.13 ~ <0.5 .. 15ANCAC2l 1 1®0 29 530 STANl>Aab (11\1 UG/1..} NOTES: • ALL CONCENTRATIONS IN GROUNDWATER ARE IN UG/L •ANALYSES PEAFORMED=METHOOS 602 (BTEX MTBE AND IPE) METHOD 504 (EOB) •NA= NOT AVAILABLE METHOD 601 (PURGEABLE HALOCARBONS} METHOD 625 (BASE/NEUTRAL EXTRACTABLES) TABLE 1 HISTORICAL GROUNDWATER AND INFLUENT QUALITY DATA TOTAL BTEX 21 13.9 18.1 13.6 11 .4 <1 <0.5 <0.5 <0.5 <0.5 NA <0.5 <0.5 <0.5 1300 1600 <0.5 <0.5 <0.5 31 495 36.7 47.5 <0.5 8500 413 829 <0.5 508 151 98 11.1 6.10 1.13 NA FORMER UNOCAL FACILITY #9342-209 4336PARKROAD, CHARLOTTE, NC MTBE PE EDB 1,2-DCA I CHLORO- FORM <1 <1 0.022 <1 <1 <0.5 <1 <0.005 <1 <1 <0.5 <0.5 <0.005 <1 <1 <0.5 <1 <0.01 <1 <1 <0.5 <1 <0.01 <1 <1 --9 <1 <0.02 <1 <1 10.7 <1 <0.005 <1 <1 <5.24 <0.5 <0.005 <1 <1 6.54 <1 <0.01 <1 <1 <0.5 <1 <0.01 <1 <1 NA NA NA NA NA 4.94 <1 <0.005 1.33 <1 0.86 <0.5 <0.005 2.32 1.22 7.98 <1 0.24'1 2.57 2.18 880 <1 NA 230 1100 860 <1 <0.02 68 <1 4.46 <1 <0.005 <1 <1 6.18 <0.5 <0.005 <1 <1 11.3 <1 <0.01 <1 <1 <1 <1 NA <1 <1 160 67 <0.02 520 <1 85.6 5.62 <0.005 20 <1 66.7 6.23 <0.005 14.8 1.3 47.7 4 .12 <0.01 15.5 <1 <1 <1 <0.02 1400 <1 11.1 <1 4.05 13.1 2.21 41.1 <0.5 32.1 41.7 1.29 2.76 <1 0.05211 4.44 •-511 570 <1 NA NA NA 170 16 NA NA NA 120 NA NA NA NA 68.4 NA NA NA NA 31.2 3.71 NA NA NA 5.99 NA NA NA NA 200 NA 4E-4 0.38 0.19 * THE 15A NCAC 2L GROUIIOWATER STANDARD FOR COMPOUNDS NOT INCLUDED IN THE STAIIDARD IS THE METHOD DETECTION LIMIT. Q.24e = CONCENTRATION IS ABOVE THE STATE 15A NCAC 2L STANDARD METHOD 601 COW'OUNDS 1,1-DCE 1,1-0CA 1,2-DCP TCE PCE 1,1,1-TCA NAPlliA- LENE <1 <1 <1 <1 <1 <1 33 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA - <1 <1 <1 <1 <1 <1 <10 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA NA NA NA NA NA NA <10 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA t--- <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 74 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 ~ <1 <1 <1 1 <1 <1 NA <1 <1 7 <1 <1 <1 <10 <1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA '<1 <1 <1 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 <10 <1 <1 <1 <1 <1 <1 NA <1 <1 1.24 <1 <1 <1 NA <1 <1 <1 <1 <1 <1 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 7 700 0.56 2.8 0.7 200 21 ~ 2670 FLOWERS CHEM ICAL LABORATORIES ANALYTICAL RESULTS FORM HAS Nun"ber 83139 - MW-7 MW-6 MW-10 MW-11 MW-1 MW -5 MW-9 trio blk. QA Section Paramet or Syrrbcl Unh 10061 10062 10063 10064 10065 10068 10067 10068 Method MOL o/oRSD %Rec Anal v, Dale DIiution Factor . # 1 1 1 1 1 1 1 1 li=PA60 1 1 DO 06-0S-95 1 1 1-trlchloroethane . un/L <1 <1 <1 <1 <1 <1 <1 EPA601 1 2.89 92 .2 DO 06-0S-95 1 1.2 2-twachloroethane • unll. <1 <1 <1 <1 <1 <1 <1 EPA601 I 2.12 87 .2 DO 06-05-95 11 1 2-trkhtorn.othane . un/L <1 <1 <1 <1 <1 <1 <1 IFPAM! 1 2.1'11'. 114,Q DO 06-0S-9§ 1 1-dlch!oroelhane . ua/l <1 1<1 <1 <1 <1 cl <1 EP A.601 1 4 .35 85.2 DO 06-0S-95 1 1-dlchloroethene . un11 1.27 <1 <1 <1 <1 <1 <1 EPA601 1 0.0067 82.6 DO 06-0S-95 1 2-dlc hloroethana . unit <1 <1 <1 <1 <1 <1 9 .55 i=PA601 1 ?,7!i. a.5 .1 DO ,,.,_n.._a~ 1 2-dlchlot C()rnnane . un/1 <1 <1 <1 <1 <1 <1 <1 . EPA601 1 3.16 87 DO 06-05-95 2-chloroettwlvln """her . 1 ..... <1 <1 <1 <1 <1 <1 <1 EPA&II 1 DO 06-05-95 Bromodlchloromelh ane . .. nA <1 <1 <1 <1 <1 <1 <1 IEPA601 1 2.37 as DO 06-05-95 Bromclonn . l,u,A <1 <1 <1 <1 <I <1 <1 EPA601 1 4.95 82.3 DO 06-05-95 cls-1 3-dlchlamr,r~ . '"'" <1 <1 <1 <1 <1 <1 <1 EPA601 1 1.74 84.8 DO 0&-05-95 Carbon 1811'111:hlol\cle . .... <1 <1 <1 <1 <1 <1 <1 EP A60 1 1 4 ,!17 89,2 DO ""-05-95 Chlorcform . '"'" 11 .6 <1 <1 <1 <1 <1 <1 EP A601 1 3.48 88.1 DO 06-05-95 Dl:>romochloromelh ane . u nll <1 <1 <1 <1 <1 <1 <1 EPA601 1 1.79 86.3 DO 0&-05-95 Methv lene chloride . l, .. n <1 , .. , <1 ,.,, <1 cl <1 EPA601 1 2.8 87.2 DO 0&-05-95 trans-1 3 -dlchloroofa>em • l,..n <1 <1 <1 <1 <1 <1 <1 EPA60t I 1.64 86.5 DO 06-05-95 Trlchlorofluorometha oa . l, .. n <2 <2 <2 <2 <2 <2 <2 EPA601 2 0.384 80.1 DO 06-05-95 lt-1.2-<II~ . , ... <1 <1 <1 <1 <1 <1 <1 . EPASOI I 4.7 ~ 86.4 nn 0&-05-95 Trlchloroethene . ,Ill/I <1 <1 <1 <1 <1 <1 <1 EPA601 1 2.04 86.2 DO 06-05-95 T•rachlomell,ene . 1, ... <1 <1 <1 <1 <1 <1 <1 EP A60 1 1 3.1 85.9 DO 06-05-95 ,--Ch.........,,.,,.• l,.,,a "'1 1,,1 <1 <1 <1 <1 <1 l=P A6C)I 1 2.59 10 1 nn 06-05-95 Bromcmethane . 1,..n <5 <5 <5 <5 <5 <5 <5 EPA601 5 DO 06-0S-95 Chloroelhane . 1, ... <3 <3 <3 <3 <3 <3 <3 EPA60 1 3 1.33 90.9 DO 06-0S-95 Chloromelhane . Inn/\ <5 <'-<5 <~ <5 <5 <5 . 1,p.u:111 5 DO 06-0S-95 DlchlorOIMfk""""""hane • 1 ..... <2 1<2 <2 <2 <2 <2 <2 EPAE01 • DO 06-0S-95 Vln-4 ChJoride . 1,.,,a <0 .5 <0.5 <0 .5 <0.5 <0.5 <0.5 <0 .5 EPA601 0.5 DO 06-05-95 Ha l !lDlka . 1 ..... 100 98.7 97 .7 97.6 97 .3 97.6 98 i 94 .6 FPA60 1 0.5 1.83 104 DO 06-05-95 o-dldlllxobenzene . , ... <0.5 <0.5 <0.5 <0 .5 <0.5 <0 .5 <0.5 <0.5 EPA602 0.5 2.19 83.7 DO 06-05-95 m-<llch lorobenz ene . 1,..n <0.5 <0.5 <0.5 <0.5 <(),5 <0 .5 <0.5 <0.5 EPA602 0.5 1.55 83.3 DO 06-05-95 ParA..rl lc,hN,...nzene . , ... <0.5 <0.5 <0 .5 <0 .5 <0 ,5 <0 .5 <0 .5 <0.5 IEPAM? 0.5 1.18 84 DO 06-05-95 Benzen e . un/1 <0.5 c0.5 <0.5 <0 .5 <0 ,5 <0.5 <0 .5 <0.5 EPA602 0.5 3.37 84.8 DO 00-05-95 Chlorcbenz .. . uall <0.5 <0.5 <0.5 <0 .5 <0.5 <0.5 <0 .5 <0.5 EPAS02 0.5 3.95 85.5 DO 06-0S-95 Fthvlbenl-. un11 <0.5 ~o.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0 .5 EP A""" o.s 3.37 82.2 00 00-05-95 Toluene . ua/l <0.5 <0.!5 <0.5 <0.5 <0 .5 <0.5 <0 .5 <0 .5 EP A602 0.5 3.13 83.8 00 06-05-95 XwlAne . ua/l <0.5 <0 .5 11.4 <0.5 <0.5 <0.5 <0 .5 <0 .5 EPA602 0.5 3.34 81.8 00 06-05-95 Met hY ~lert-hl~~lether . uni! <0.5 <0 .5 <0.5 <0.5 <0.5 <0 5 <0.5 <0.5 l"PA602 0,5 3.41 103 00 06-05-95 Total BTEX . unll. <0.5 <0 .5 11 .4 <0 .5 <0 .5 <0.5 <0 .5 <0.5 EPA602 0.5 3.31 82 .7 DO 06-0S-95 knnmnvlether . ua/L <1 <1 <1 <1 <1 <1 <1 <1 EPA602 I DO 06-0S-95 PO Solks . ua/l 105 104 104 103 103 103 104 102 IEPA602 0.5 1.82 105 DO 06-05-95 . . . Eth vlene dlbrornde . ullll <0.01 <0 .01 <0.01 <0.01 <0.01 <0.01 <0.01 -EPAso-1 .1 0.01 0.27<llWl.1 93 .22 44Bli FG 06-06-95 Dale Received : 06-05-95 Tvneo: 06-06-95 Senl: 06-06-95 Project Number UNOC 9342-209 PO Number AFE#35893143 Date Sampled 1 06-02-95' Date Analyzed 0 tcompacted 1 Formal NormRR Unil Cost Exted !,l()l/602/IPE 11000 7. l i:r-.o """ 7 .