WI0700176_Monitoring (Report)_20210719

DocuSign Envelope ID: DB2C65E3-FB75-4225-B9E9-A4384FDBA093
ROY COOPER
Governor
ELIZABETH S. BISER
Secretary
S. DANIEL SMITH
Director
Thomas and Lana Brunk
1002 Coopers Court
Trent Woods, North Carolina 28562
NORTH CAROLINA
Environmental Quality
July 19, 2021
SUBJECT: Groundwater Sampling Results
UIC Permit No. WI0700176
Issued to Thomas and Lana Brunk
Trent Woods, Craven County, North Carolina
Dear Mr. and Mrs. Brunk:
Staff from the Washington Regional Office of the Water Quality Regional Operations
Section collected samples of the influent (supply well) and effluent (injection well) from your
geothermal heat pump system on June 9, 2021. The samples were analyzed for metals, nutrients,
and other inorganic constituents by the Division of Water Resources laboratory. A summary table
of the analytical results, as well as the laboratory reports, field sampling forms, and definitions of
laboratory data qualifiers are attached to this letter. The following three constituents were detected
above state groundwater standards in both samples from your system:
Parameter
Units
NC
Groundwater
Standard
Results
Total Coliform
Colony Forming Units
per 100 milliliters
(CFU/100m1)
1
37 (supply well -influent)
27 (injection well -effluent)
Iron
Micrograms per Liter
(ug/L)
300
660 (supply well -influent)
630 (injection well -effluent)
pH
Standard Units
6.5 to 8.5
6.0 (supply well -influent)
6.0 (injection well -effluent)
D_E
NORTH GAROIJNA
O. ,flnpnl pl EnWmnmenl$I 0 W III:
North Carolina Department of Environmental Quality I Division of Water Resources
Washington Regional Office 1943 Washington Square Mall I Washington, North Carolina 27889
252,946.6481

DocuSign Envelope ID: DB2C65E3-FB75-4225-B9E9-A4384FDBA093
Thomas and Lana Brunk
July 19, 2021
Page 2 of 2
These exceedances should not affect the use of the wells for your geothermal heat pump
system; however, it is recommended before using the water from these wells for personal
consumption that you consult with the Craven County Environmental Health Depailment. If you
have any questions regarding the sampling results or your permit, please feel free to contact me at
[phone].
Sincerely,
i.
D�h~ t Randy.G�H dro eolo ist
g Sipe, Y g g
Water Quality Regional Operations Section
Division of Water Resources, NCDEQ
Attachments
cc: Shristi Shrestha — DWR Groundwater Resources Section (electronic copy)
Craven County Environmental Health Depailiuent
Laserfiche
woRTH D_E
r,b
u.acARouto
.m m eualroumu.tar uu.r�
North Carolina Department of Environmental Quality I Division of Water Resources
Washington Regional Office 1943 Washington Square Mall I Washington, North Carolina 27889
252.946.6481

NC DIVISION OF WATER RESOURCES
LABORATORY ANALYTICAL RESULTS
GEOTHERMAL HEATING/COOLING RETURN WELL
PERMIT NO.: WI0700176
PERMITTEE(S): Thomas and Lana Brunk
SAMPLE COLLECTION DATE: 6/9/21
Parameter
Fecal Coliform
Total Coliform
Total Dissolved Solids
Chloride, CI
Fluoride, FL
Sulfate, SO4
units
CFU/100m1
CFU/100m1
mg/L
mg/L
mg/L
mg/L
NC GWS and/or EPA Standard
NC GWS = < 1
NC GWS = < 1
NC GWS = 500
NC GWS = 250
NC GWS = 2
NC GWS = 250
EPA SDWS = 500
EPA SDWS = 250
EPA PDWS = 4.0
EPA SDWS = 250
Influent Sample Results
<1
37
326
8.6
<0.4
34
Effluent Sample Results
<1
27
328
8.6
<0.4
34
Parameter
Nitrate + Nitrite
Nitrite
Hardness as CaCO3
(by Calculation) *
Aluminum, Al
Arsenic, As
Calcium, Ca
units
mg/L as N
mg/L as N
mg/L as CaCO3
pg/L
pg/L
mg/L
NC GWS and/or EPA Standard
NC GWS = 11
NC GWS = 1
NS
NS
NC GWS = 10
NS
EPA PDWS = 11
EPA PDWS = 1
EPA SDWS = 50 to 200
EPA PDWS = 10
Influent Sample Results
<0.02
<0.01
310
66
<2.0
120
Effluent Sample Results
<0.02
<0.01
310
54
<2.0
120
Parameter
Chromium, Cr
Copper, Cu
Iron, Fe
Potassium, K
Magnesium, Mg
Manganese, Mn
units
pg/L
pg/L
pg/L
mg/L
mg/L
pg/L
NC GWS and/or EPA Standard
NC GWS = 10
NC GWS = 1000
NC GWS = 300
NS
NS
NC GWS = 50
EPA PDWS = 100
EPA SDWS = 1000; PDWS = 1300
EPA SDWS = 300
EPA SDWS = 50
Influent Sample Results
<5.0
57
660
1.2
2.3
28
Effluent Sample Results
<5.0
30
630
1.2
2.3
27
Parameter
Sodium, Na
Nickel, Ni
Lead, Pb
Zinc, Zn
pH (field)
units
mg/L
pg/L
pg/L
pg/L
units
NC GWS and/or EPA Standard
NS
NC GWS = 100
NC GWS = 15
NC GWS = 1000
NC GWS = 6.5-8.5
EPA PDWS = 15
EPA SDWS = 5000
EPA SDWS = 6.5 to 8.5
Influent Sample Results
12
<2.0
2.4
44
6.0
Effluent Sample Results
12
<2.0
<2.0
<10
6.0
NC GWS = North Carolina Groundwater Standards per 15A NCAC 2L .0200
EPA PDWS = Environmental Protection Agency Primary Drinking Water Standards
EPA SDWS = Environmental Protection Agency Secondary Drinking Water Standards
NS = No Standard
* Calculation performed by WaRO

North Carolina Division of Water Resources
Laboratory (Water Sciences Section)
Water Sample Collection & Submittal Form
Visit ID:
(optional)
Tag
ID
Location Description:
County:
DWR Region:
(based on county)
River Basin:
Notes:
L. (-;t\ i
G E C-t 1\E (,;W,A
N40
Collector:
DWR Office:
(or agency name)
uate
(Again/end)
Time (24 hr):
(begin/end)
//:/
GCE (V AIs.
•
•
Location Code:
Priority:
Water Matrix:
Ambient
Routine
XCompliance
CDC
Emergency
QA
7C0(76
Surface
Ground
Waste
Blank
Solution
Location Type:
River/Stream
Estuary
Stormwater
Monitoring Well
Effluent
Field Blank
Filter Blank
Lake
Canal
Water Supply
Influent
Trip Blank
Other:
Lab Use Only:
Laboratory
Sample Number:
Date Received:
M/D/Y
Time Received:
(24 hr format)
•
Received By:
Delivery Method:
State Courier
Hand Delivered
Other:
Chlorinated
De -chlorinated in
Field
Sampling
Method:
Grab
Other:
Composite
Filtered in Dissolved analysis: Enter "D15" in check -
Field boxes for parameters
Sample
Depth:
fY /4
Temperature on
Arrival ("C):
•
Callector's Comments:
Field Parameters (optional) :
Preservative : Y
Water Temp (°C):
pH (s-u-):
(
Dissolved Oxygen
(ppm):
Conductivity
(p.mhos/cm):
Salinity
(ppt):
LAB COMMENTS
Microbiology Parameters:
Preservative (Wet Chemistry Parameters:
Preservative Metals Parameters:
Preservative Metals Parameters Con't:
Preservative
Alkalinity, as CaCO3, to pH 4.5/8.3
A
Bromide
None
)(
J
.Aluminum (Al)
E
Thallium (TI)
E
BOD: Biochemical Oxygen Demand, 5-day
A
✓(,
Chloride
None
Antimony (Sb)
E
Tin (Sn)
E
cBOD: Carbonaceous BOD, 5-day
A
Fluoride
None
Arsenic (As)
E
Titanium (Ti)
E
C `
Coliform: Fecal MF
B-C- L-N
Sulfate
A
Barium )Ba)
E
Vanadium (V)
E
Coliform: Total MF
B - C - L - N
Chlorophyll a
A
Beryllium (Be)
E
Zinc (Zn)
is
Specific Conductance, at 25 °C
A
Color: ADMI
A
Cadmium (Cd)
E
_
Mercury 1631, low-level
TOC - Total Organic Carbon
A - E - F - G
Color: Platinum Cobalt
A
Calcium (Ca)
E
Boron (B)
E
Turbidity
A
COD: Chemical Oxygen Demand
A - D
X.
Chromium (Cr), Total
E
Hardness, Total as CaCO3 - by titration
0 -E
Other Parameters:
Cyanide, Total
A - H - P
Cobalt (Co)
E
Organics Parameters:
pH
None
Hexavalent Chromium (Cr6+)
A - 0
Copper (Cu)
E
Acid Herbicides
A - C
MBAS (surfactants)
A
Iron (Fe)
E
Organochlorine Pesticides
A - C- K
Nut Tents Parameters:
Oil and Grease, HEM, Total Recoverable
A - 0 - F
xLead
(Pb)
E
Organonitrogen Pesticides
A - C - K
Ammonia as N (NH3-N)
A - D - Z
Phenols, Total Recoverable
A - 0
Lithium (Li)
E
Organophosphorus Pesticides
A - C - K
r
Nitrate -Nitrite as N )NO3+NO2-N)
A - D - Z
Residue: Total (Totot Solids) -
A
X.Magnesium
(Mg)
E
PCBs (polychlorinated biphenyls)
A - K
Total Kjeldahl Nitrogen as N {TKN}
A - D - Z
Residue: Volatile/Fixed, Total
A
�
Manganese (Mn)
E
Semi -Volatile Organics {BNAs)
A - C - K
Total Phosphorus as P (TP)
A - D - Z
Residue: Settleable
A
Mercury (Hg)
E
TPH Diesel Range
A - K
`f
x
`
Nitrite as N )NO2-N)
A
Residue: Suspended (Suspended Solids)
A
Molybdenum (Mo)
E
Volatile Organics (VOA)
A - C - F - 5
Nitrate as N )NO3-N calculated)
A
Residue: Volatile/Fixed, Suspended
A
(NI)
E
1,4-Dioxane
C
Orthophosphate as P (PD4)
A Z
TDS Total Dissolved Solids
A
*Nicke1
Potassium (K)
E
TPH Gasoline RangePer-Fluorinatedd
A - C -- S
ICyanotaxins:
Silica
A
Selenium (Se)
E
Compounds {PEAS)
A - T
Microcystin
A
Sulfide
A - 1
Silver (Ag)
Biological:
Tannin & Lignin
odium (Na)
Strontium (Sr)
IPhytopiankton / Algae
A -R
Preservative Legend (circle above as needed): (A) cool 56°C, (B) cool <10"C, (C) 0.008% NasS:03 [when chlorine is present[, (D) H2504 to pH <2, (E HNO3 to pH <2, (F) HCI to pH <2, )G) H3PO4 to pH <2, (H} 6N NaOH to pH >10<11, (I) pH=9.3-9.7, (J) zinc acetate & NaOH
to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) EDTA, (M) NaH50e to pH <2, (N)15% EDTA, (0) ammonium sulfate buffer pH= 9.3-9.7, (P) ascorbic acid [when chlorine is present[, (R) Lugols, (S) NaHSOe to pH <2, (T) Trizma [when chlorine is present],
(y) analyzed within 15 minutes of sample collection, (2) filtered in field within 15 minutes
Required: 1) Collector Initials and Date, 2) Circling of Utilized Preservative next to each Parameter
Revision: 9/29/2020

North Carolina Division of Water Resources u
Water Sample Collection & Submittal Form ECl lur (1
Laboratory (Water Sciences Section)
Visit ID:
(optional)
Tog
in
/ y
I u E J\ I
Lab Use Only:
laboratory
Sample Number:
;location Description:
6—C- ]� _ I, ' ! I
l l�. Sy.S,
j l LA l� I� f Ll—] IJ �� i i- C. 1 00 £ r L ( 5 y5
Location Code:
�--�
+�
C) % C) [ L/
t
Date Received:
M/D/Y / l
County:
1 \
('1 t- `
Collector: II, 1 AAA!!! ,,, ���
I y 1 u� a ..3 i Id C
Priority:
Ambient
Routine
COC
Emergency
QA
Water
Matrix:
Surface
Ground
Waste
Blank
Solution
Location
River/Stream
Estuary
Stormwater
Monitoring Well
Effluent
Field Blank
Filter Blank
Type:
d
Lake
Canal
Water Supply
Influent
Trip Blank
Other:
Time Received:
(24 hr format)
•
DWR Region:
(hosed an county)
! L.DWR
�" �� �\
Office:
(or agency name)
W.;
I y
f T!
`i
/ /
X
f
Z,NComptiance
—
—
Received
Received By:
River Basin:
j{
1,
666 I c Li. S E
udte
(m/d/yh
ill enin/vndl
( /r /.2 /
—
—
—
—
—
Delivery Method:
State Courier
Notes:
Time (24 hr):
(begin/end.,
�7
•
•
T
Hand Delivered
Other:
Chlorinated
De -chlorinated in Sampling
Field Method:
Grab
Other:
Comp osite
Filtered in Dissolved analysis: Enter "A15" in check-
Field boxes for parameters
Sample
DeP the
/N
Temperature on
Arrival (`CJ:
•
—
Collectors Comments:
Field Parameters (optional):
Preservative : Y
Water Temp (°C):
Ipl l (s.u.):
lIl
G r 6'
Dissolved Oxygen
{ppm]:
1Condu5tivity
(pmhos/cm):
I
Salinity
(ppt):
LAB COMMENTS :
Mic obiology Parameters:
Preservative
Wet Chemistry Parameters:
Preservative
Metals Parameters:
Preservative
Metals Parameters Can't:
Preservative
Alkalinity, as CaCO3, to pH 4.5/8.3
A
Bromide
None
Aluminum )Al)
E
Thallium (71)
L
BOD: Biochemical Oxygen Demand, 5-day
A
Chloride
None
Antimony (5b)
E
Tin (Sn)
is
cBOD: Carbonaceous BOD, 5-day
A
Fluoride
None
X
Arsenic (As)
E
Titanium (Ti)
XColiform:
Fecal MF
B - C - L - N
Sulfate
A
Barium (Be)
E
Vanadium (V)
E
v
Coliform: Total MF
B - C - L - N
Chlorophyll a
A
Beryllium (Be)
E
X
Zinc (Zn)
E
Specific Conductance, at 25 °C
A
Color: ADMI
A
Cadmium (Cd)
E
!
Mercury 1631, !ow -level
TOC - Total Organic Carbon
A - E - F - G
Color: Platinum Cobalt
A
Calcium (Ca)
E
Boron (8)
E
Turbidity
A
COD: Chemical Oxygen Demand
A - D
Chromium (Cr), Total
E
Hardness, Total as CaCO3 - by titration
0 -L
Other Parameters:
Cyanide, Total
A- H - P
Cobalt (Co)
11
Organics Parameters:
pH
None
Hexavalent Chromium (Cr6+)
A - 0
Copper (Cu]
I:
Acid Herbicides
A - C
MBAS (surfactants)
A
Iron (Fe)
E
Organochlorine Pesticides
A - C - K
Nutrients Parameters:
Oil anti Grease, HEM, Total Recoverable
A - D - F
)c
Lead (Pb)
I:
Organonitrogen Pesticides
A - C - K
Ammonia as N (NH3-N)
A - D - Z
Phenols, Total Recoverable
A - D
Lithium (Li)
F
Organophosphorus Pesticides
A - C - K
Nitrate -Nitrite as N (NO3+NO2-N)
A - D - Z
Residue: Total (Total Solids)
A ,*....Magnesium
(Mg)
L
PCBs (polychlorinated biphenyls)
A - K
Total Kjeldahl Nitrogen as N (TKN)
A - D - Z
Residue: Volatile/Fixed, Total
A
Manganese (Mn)
E
Semi -Volatile Organics (BNAs)
A - C - K
Total Phosphorus as P (7P)
A - D - Z
Residue: Settleable
A
Mercury (Fig)
E
TPH Diesel Range
A- K
XNitrite
as N (NO2-N)
A
Residue: Suspended (Suspended Solids)
A
Molybdenum (Mo)
E
Volatile Organics (VOA)
4- C - F - S
Nitrate as N (NO3-N calculated)
A
Residue: Volatile/Fixed, Suspended
A
Nickel (Ni)
F
1,4-Dioxane
C
Orthophosphate as P (PO4)
A - Z
u
/ `Silica
TDS - Total Dissolved Solids
A
f
Potassium (K)
E
TPH Gasoline Range
A - C - F - 5
Cyanotoxins:
A
Selenium (Se)
E
Perfluorinated Compounds (PFAS)
A T
Microcystin
Y
A
Sulfide
A-3
Silver{Ag}
E
Biological:
Tannin & Lignin
X
sodium (Na)
E
F
1Phytoplankton / Algae
A - R
Strontium (Sr)
E
reservatwe Legend (cucle above as needed): (A) cool 56'C, (9) cool <l0"C, (C] 0.0o8%Na2S203 [when chlorine is present], (D) H7504 to pH <2, (E HNo3 to pH <2, (F) HCI to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (1) pH=9.3-9.7, (J) zinc acetate & NaOH
to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine rs present], (L) EDTA, (M) NaHSO4 to pH <2, (N) 15% EDTA, (0) ammonium sulfate buffer pH-- 9-3-9.7, (P) ascorbic acid [when chlorine is present], (R) Lugots, (S) NaHSO4 to pH <2, (T) Trizma [when chlorine is present],
(Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes
Required: 1) Collector Initials and Date, 2) Circling of Utilized Preservative next to each Parameter
Revision: 9/29/2020

AC85353 North Carolina Division of Water Resources Water Sciences Section Laboratory Results
Loc. Descr.:
County:
Region:
River Basin
Emergency
COC Yes/No
THOMAS BRUNK: 1002 COOPER COURT TRENT WOODS, NC
Craven
Washington
NEU
Collector:
Report To
Collect Date:
Collect Time:
Sample Depth
R SIPE
WARO
06/09/2021
11_10
VisitiD
Location ID:
Priority
Sample Matrix:
Loc. Type:
Final Report
If this report is labeled preliminary report, the results have not been validated.
Result/
CAS # Analyte Name PQL Qualifier
LAB
Sample temperature at receipt by lab 1.1
W10700176
COMPLIANCE
GROUNDWATER
Water Supply
Sample ID:
PO Number #
Date Received:
Time Received:
Labworks LoginlD
Delivery Method
Final Report Date:
Report Print Date:
AC85353
06/10/2021
08_20
TASCENZOI
NC Courier
7/13/21
07/14/2021
Do not use for Regulatory purposes.
Units
oC
Method
Reference
Analysis
Date
6/10/21
Validated by
MSWIFT
Coliform, MF Fecal in liquid
1
MIC
1 B2,Q1
CFU/100m1
SM 9222 D-1997
6/10/21 JJURGEVICH
Coliform, MF Total in liquid
1
37 Q1
CFU/100m1
SM 9222 B-1997
6/10/21 JJURGEVICH
14797-55-8 Nitrate as N in liquid
0.02
NUT
0.02 U
mg/L as N
EPA 353.2 REV 2
6/11/21 ALWILLIAMS
14797-65-0 Nitrite as N in liquid
0.01
0.01 U
mg/L as N
EPA 353.2 REV 2
6/10/21 ALWILLIAMS
E701177
NO2+NO3 as N in liquid
0.02
0.02 U
mg/L as N
EPA 353.2 REV 2
6/11/21 ALWILLIAMS
24959-67-9 Bromide
0.4
WET
0.4 U
mg/L
EPA 300.0 rev2.1 6/18/21 ALWI LLIAMS
16887-00-6 Chloride
1.0
8.6
mg/L
EPA 300.0 rev2.1 6/18/21 ALWI LLIAMS
16984-48-8 Fluoride
0.4
0.4 U
mg/L
EPA 300.0 rev2.1 6/18/21 ALWI LLIAMS
14808-79-8 Sulfate
2.0
34
mg/L
EPA 300.0 rev2.1 6/18/21 ALWI LLIAMS
Total Dissolved Solids in liquid
12
326
mg/L
SM 2540 C-1997 6/16/21 ALWILLIAMS
7429-90-5 Al by ICP
50
MET
66
ug/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-38-2 As by ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7440-70-2
Ca by ICP
0.10
120
mg/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-47-3
Cr by ICPMS
5.0
5.0 U
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7440-50-8
Cu by ICPMS
2.0
57
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7439-89-6
Fe by ICP
50
660
ug/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-09-7 K by ICP
0.10
1.2
mg/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7439-95-4
Mg by ICP
0.10
2.3
mg/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7439-96-5
Mn by ICP
10
28
ug/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-23-5
Na by ICP
0.10
12
mg/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-02-0
Ni by ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7439-92-1
Pb by ICPMS
2.0
2.4
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7440-66-6 Zn by ICPMS
10
44
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
WSS Chemistry Laboratory» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 3

NC DW(R, Laboratory Section (Rgsurts/Sampre Comments/Qua4ifier (Definitions
Sample ID: AC85353
CAS # Analyte Name
PQL
Result/
Qualifier
Units
Method
Reference
Analysis
Date
Validated by
Sample Comments
MIC:Fecal Coliform-B2-Counts from all filters = 0.
MIC:Fecal Coliform-Q1-Sample exceeded holding time prior to receipt at lab.
NCDEQ-WSS-Chemistry Lab Data Qualifiers
Al The reported value is an average, where at least one result is qualified with a "U". The PQL is used for the qualified result(S) to call
B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters repor
B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been
B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smaller
B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported
B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies.
B6 Coliform-Estimated Value. Blank contamination evident.
B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this cc
BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than "<" valu
BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than ">" value.
C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated.
G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L.
G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at lea:
G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L.
G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration de
G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L.
G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated foi
G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for
G9 BOD-The DO depletion of the dilution water blank produced a negative value.
J1 Surrogate recovery limits have been exceeded.
J10 Unidentified peak; estimated value.
J11 The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
WSS Chemistry Laboratory» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 3

NC DW(R, Laboratory Section (Rgsurts/Sampre Comments/Quagfier (Definitions
Sample ID: AC85353
CAS # Analyte Name
PQL
Result/
Qualifier
Units
Method
Reference
Analysis
Date
Validated by
J12 The calibration verification did not meet the calibration acceptance criterion for field parameters.
J2 The reported value failed to meet the established quality control criteria for either precision or accuracy.
J3 The sample matrix interfered with the ability to make any accurate determination.
J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, p
J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-
J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate.
J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. Th
J8 Temperature limits exceeded (samples frozen or >6°C) during storage, the data may not be accurate.
J9 The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
M Sample and duplicate results are "out of control". The sample is non -homogenous (e.g., VOA soil). The reported value is the lower
N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library.
N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of
N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the labo
N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the labo
N5 The component has been tentatively identified based on a retention time standard.
P Elevated PQL* due to matrix interference and/or sample dilution.
Q1 Holding time exceeded prior to receipt by lab.
Q2 Holding time exceeded following receipt by lab.
S Not enough sample provided to prepare and/or analyze a method -required matrix spike (MS) and/or matrix spike duplicate (MSD).
U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value repot
U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate.
UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one -point estimation at t)
✓ Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be s
X1 Sample not screened for this compound.
X2 Sampled, but analysis lost or not performed -field error.
X3 Sampled, but analysis lost or not performed -lab error.
Y Elevated PQL* due to insufficient sample size.
Z1 Inability to analyze the sample.
Z2 Questions concerning data reliability.
WSS Chemistry Laboratory» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 3 of 3

AC85354 North Carolina Division of Water Resources Water Sciences Section Laboratory Results
Loc. Descr.:
County:
Region:
River Basin
Emergency
COC Yes/No
THOMAS BRUNK: 1002 COOPER COURT TRENT WOODS, NC
Craven
Washington
NEU
Collector:
Report To
Collect Date:
Collect Time:
Sample Depth
R SIPE
WARO
06/09/2021
11_20
VisitiD
Location ID:
Priority
Sample Matrix:
Loc. Type:
Final Report
If this report is labeled preliminary report, the results have not been validated.
Result/
CAS # Analyte Name PQL Qualifier
LAB
Sample temperature at receipt by lab 1.1
W10700176
COMPLIANCE
GROUNDWATER
Water Supply
Sample ID:
PO Number #
Date Received:
Time Received:
Labworks LoginlD
Delivery Method
Final Report Date:
Report Print Date:
AC85354
06/10/2021
08_20
TASCENZOI
NC Courier
7/13/21
07/14/2021
Do not use for Regulatory purposes.
Units
oC
Method
Reference
Analysis
Date
6/10/21
Validated by
MSWIFT
Coliform, MF Fecal in liquid
1
MIC
1 B2,Q1
CFU/100m1
SM 9222 D-1997
6/10/21 JJURGEVICH
Coliform, MF Total in liquid
1
27 Q1
CFU/100m1
SM 9222 B-1997
6/10/21 JJURGEVICH
14797-55-8 Nitrate as N in liquid
0.02
NUT
0.02 U
mg/L as N
EPA 353.2 REV 2
6/11/21 ALWILLIAMS
14797-65-0 Nitrite as N in liquid
0.01
0.01 U
mg/L as N
EPA 353.2 REV 2
6/10/21 ALWILLIAMS
E701177
NO2+NO3 as N in liquid
0.02
0.02 U
mg/L as N
EPA 353.2 REV 2
6/11/21 ALWILLIAMS
24959-67-9 Bromide
0.4
WET
0.4 U
mg/L
EPA 300.0 rev2.1 6/18/21 ALWI LLIAMS
16887-00-6 Chloride
1.0
8.6
mg/L
EPA 300.0 rev2.1 6/18/21 ALWI LLIAMS
16984-48-8 Fluoride
0.4
0.4 U
mg/L
EPA 300.0 rev2.1 6/18/21 ALWI LLIAMS
14808-79-8 Sulfate
2.0
34
mg/L
EPA 300.0 rev2.1 6/18/21 ALWI LLIAMS
Total Dissolved Solids in liquid
12
328
mg/L
SM 2540 C-1997 6/16/21 ALWILLIAMS
7429-90-5 Al by ICP
50
MET
54
ug/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-38-2 As by ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7440-70-2
Ca by ICP
0.10
120
mg/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-47-3
Cr by ICPMS
5.0
5.0 U
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7440-50-8
Cu by ICPMS
2.0
30
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7439-89-6
Fe by ICP
50
630
ug/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-09-7 K by ICP
0.10
1.2
mg/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7439-95-4
Mg by ICP
0.10
2.3
mg/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7439-96-5
Mn by ICP
10
27
ug/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-23-5
Na by ICP
0.10
12
mg/L
EPA200.7 Rev4.4
6/15/21 JJURGEVICH
7440-02-0
Ni by ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7439-92-1
Pb by ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
7440-66-6 Zn by ICPMS
10
10 U
ug/L
EPA200.8 Rev5.4
6/15/21 JJURGEVICH
WSS Chemistry Laboratory» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 3

NC DW(R, Laboratory Section (Rgsurts/Sampre Comments/Qua4ifier (Definitions
Sample ID: AC85354
CAS # Analyte Name
PQL
Result/
Qualifier
Units
Method
Reference
Analysis
Date
Validated by
Sample Comments
MIC:Fecal Coliform-B2-Counts from all filters = 0.
MIC:Fecal Coliform-Q1-Sample exceeded holding time prior to receipt at lab.
NCDEQ-WSS-Chemistry Lab Data Qualifiers
Al The reported value is an average, where at least one result is qualified with a "U". The PQL is used for the qualified result(S) to call
B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters repor
B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been
B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smaller
B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported
B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies.
B6 Coliform-Estimated Value. Blank contamination evident.
B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this cc
BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than "<" valu
BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than ">" value.
C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated.
G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L.
G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at lea:
G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L.
G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration de
G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L.
G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated foi
G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for
G9 BOD-The DO depletion of the dilution water blank produced a negative value.
J1 Surrogate recovery limits have been exceeded.
J10 Unidentified peak; estimated value.
J11 The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
WSS Chemistry Laboratory» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 3

NC DW(R, Laboratory Section (Rgsurts/Sampre Comments/Quagfier (Definitions
Sample ID: AC85354
CAS # Analyte Name
PQL
Result/
Qualifier
Units
Method
Reference
Analysis
Date
Validated by
J12 The calibration verification did not meet the calibration acceptance criterion for field parameters.
J2 The reported value failed to meet the established quality control criteria for either precision or accuracy.
J3 The sample matrix interfered with the ability to make any accurate determination.
J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, p
J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-
J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate.
J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. Th
J8 Temperature limits exceeded (samples frozen or >6°C) during storage, the data may not be accurate.
J9 The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
M Sample and duplicate results are "out of control". The sample is non -homogenous (e.g., VOA soil). The reported value is the lower
N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library.
N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of
N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the labo
N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the labo
N5 The component has been tentatively identified based on a retention time standard.
P Elevated PQL* due to matrix interference and/or sample dilution.
Q1 Holding time exceeded prior to receipt by lab.
Q2 Holding time exceeded following receipt by lab.
S Not enough sample provided to prepare and/or analyze a method -required matrix spike (MS) and/or matrix spike duplicate (MSD).
U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value repot
U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate.
UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one -point estimation at t)
✓ Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be s
X1 Sample not screened for this compound.
X2 Sampled, but analysis lost or not performed -field error.
X3 Sampled, but analysis lost or not performed -lab error.
Y Elevated PQL* due to insufficient sample size.
Z1 Inability to analyze the sample.
Z2 Questions concerning data reliability.
WSS Chemistry Laboratory» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 3 of 3