WI0700123_Other Correspondence_20081017

MATERIAL SAFETY DATA SHEET
CAIROX® Potassium Permanganate
Section 1
Chemical Product and Company Identification
PRODUCT NAME:
SYNONYMS:
CAIROX3' potassium permanganate, KMnO,
Pemianganic acid potassium salt
Chameleon mineral
Condy's crystals
Permanganate of potash
MANUFACTURER'S NAME: CARUS CHEMICAL COMPANY
MANUFACTURER'S ADDRESS:
Carus Chemical Company
1500 Eighth Street
P. O. Box 1500
LaSalle, IL 61301
TRADE NAME: CAIROX' potassium permanganate
TELEPHONE NUMBER FOR INFORMATION: 815/223-1500
E�/MERGENCY TELEPHONE NO: 800/435.6856
AFTER HOURS NO. 615/223-1565
5:00 PM-8:00 AM Central Standard Time
Monday -Friday, Weekends and Holidays
CHEMTREC TELEPHONE NO.: 800/424-9300
Section 2
Composition/Information on Ingredients
Material or component CAS No,
Potassium permanganate 7722-647 ., 97%. ml . KMnO4
Hazard Data
PEL-C
TLV-TWA
5 mg Mn per cubic meter of air
0.2 mg Mn per cubic meter of air
Section 3
Hazards Identification
1. Fve Contact
Potassium permanganate Is damaging to eye tissue on contact It may cause severe bums that result in dam`ag to the eye.
2. Skin Contact
Contact of solutions at room temperature may be irritating to the skin, leaving brown stains. Concentrated -solutions at
elevated temperature and crystals aredamaging to the alti .
3. Inhalation
Acute Inhalation data are not available. However, airborne concentrations of potassium nnanganate In the form of dust or
mist may cause da
mage to the respiratory tract.
ingestion ,
4. Potassium perma
nganate, if swallowed, may cause severe bums to mucous memlxan of the mouth, throat esophagus, and stomach.

Section 4 First Aid Measures
1. Eyes
Immediately flush eyes with large amounts of water for at least 15 minutes holding lids apart to ensure flushing of the entire surface. Do not
attempt to neutralize chemically. Seek medical attention immediately. Note to physician: Soluble decomposition products are alkaline.
Insoluble decomposition product is brown manganese dioxide.
2. Skin
Immediately wash contaminated areas with large amounts of water. Remove contaminated clothing and footwear. Wash clothing and
decontaminate footwear before reuse. Seek medical attention immediately if irritation is severe or persistent.
3. Inhalation
Remove person from contaminated area to fresh air. If breathing has stopped, resuscitate and administer oxygen if readily available. Seek
medical attention immediately.
4. Ingestion
Never give anything by mouth to an unconscious or convulsing person. If person is conscious, give Large quantities of water. Seek medical
attention immediately.
Section 5 Fire Fighting Measures
NFPA' HAZARD SIGNAL
Health Hazard 1 = Materials which under fire conditions would give off irritating combustion products.
(less than 1 hour exposure) Materials which on the skin could cause irritation.
Flammability Hazard 0 = Materials that will not burn.
Reactivity Hazard 0 = Materials which in themselves are normally stable, even under fire exposure
conditions, and which are not reactive with water.
Special Hazard OX = Oxidizer
'National Fire Protection Association 704
FIRST RESPONDERS:
Wear protective gloves. boots, goggles, and respirator. In case of fire, wear positive pressure
breathing apparatus. Approach site of incident with caution. Use Emergency Response
Guide NAERG 96 (RSPA P5800.7). Guide No. 140.
FLASHPOINT None
FLAMMABLE OR EXPLOSIVE LIMITS Lower: Nonflammable Upper: Nonflammable
EXTINGUISHING MEDIA Use large quantities of water. Water will tum pink to purple if in contact with potassium
permanganate. Dike to contain. Do not use dry chemicals, CO.,, Halon" or foams.
SPECIAL FIREFIGHTING PROCEDURES
If material is involved in fire, flood with water. Cool all affected containers with large
quantities of water. Apply water from as far a distance as possible. Wear self-contained
breathing apparatus and full protective clothing.
Responsible Care
A Public Commitment
CARUS CHEMICAL COMPANY

Section 6 Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Clean up spills immediately by sweeping or shoveling up the material. Do not return spilled matenal to the original container. Transfer to a clean metal
drum. EPA banned the land disposal of D001 ignitable waste oxidizers. These wastes must be deactivated by reduction. To clean floors, flush with
abundant quantities of water into sewer, if permitted by Federal, State, and Local regulations. If not permitted, collect water and treat chemically
(Section 13).
PERSONAL PRECAUTIONS
Personnel should wear protective clothing suitable for the task. Remove all ignition sources and incompatible materials before attempting clean-up.
Section 7 Handling and Storage
WORK/HYGENIC PRACTICES
Wash hands thoroughly with soap and water after handling potassium permanganate, and before eating or smoking. Wear proper protective
equipment. Remove contaminated clothing.
VENTILATION REQUIREMENTS
Provide sufficient area or local exhaust to maintain exposure below the TLV-TWA.
CONDITIONS FOR SAFE STORAGE
Store in accordance with NFPA 430 requirements for Class II oxidizers. Protect containers from physical damage. Store in a cool, dry area in
dosed containers, Segregate from acids, peroxides, formaldehyde, and all combustible, organic or easily oxidizable materials including anti -freeze
and hydraulic fluid.
Section 8 Exposure Controls/Personal Protection
RESPIRATORY PROTECTION
In the case where overexposure may exist, the use of an approved NIOSH-MSHA dust respirator or an air supplied respirator is advised.
Engineering or administrative controls should be implemented to control dust.
EYE
Faceshield, goggles, or safety glasses with side shields should be worn. Provide eye wash in working area.
aLOVE�
Rubber or plastic gloves should be wom.
OTHER PROTECTIVE EQUIPMENT
Normal work clothing covering arms and legs, and rubber or plastic apron should be wom.
tiff
Responsible Care®
A Public Commitment
CARUS CHEMICAL COMPANY

Section 9 Physical and Chemical Properties
APPEARANCE AND ODOR Dark purple solid with a metallic luster, odorless
BOILING POINT, 760 mm Hg Not applicable
VAPOR PRESSURE (mm Hg) Not applicable
SOLUBILITY IN WATER % BY SOLUTION 6% at 20°C (68"F), and 20% at 65°C (149°F)
PERCENT VOLATILE BY VOLUME Not volatile
EVAPORATION RATE (BUTYL ACETATE=1) Not applicable
MELTING POINT Starts to decompose with evolution of oxygen (O,) at temperatures above 150°C
(302°F). Once initiated, the decomposition is exothermic and self-sustaining.
OXIDIZING PROPERTIES Strong oxidizer
SPECIFIC GRAVITY 2.7 @ 20°C (68°F)
VAPOR DENSITY (AIR=1) Not applicable
Section 10 Stability and Reactivity
STABILITY Under normal conditions. the material is stable.
CONDITIONS TO AVOID Contact with incompatible materials or heat (>150°C/302°F).
INCOMPATIBLE MATERIALS Acids, peroxides, formaldehyde, anti -freeze, hydraulic fluids, and all combustible organic or readily
oxidizable inorganic materials including metal powders. With hydrochloric acid, toxic chlorine gas is liberated.
HAZARDOUS DECOMPOSITION PRODUCTS When involved in a fire, potassium permanganate may liberate corrosive fumes.
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Material is not known to polymerize.
Section 11 Toxicological Information
Potassium permanganate: Acute oral LDSJ(rat) = 780 mg/kg Male (14 days); 525 mg/kg Female (14 days)
The fatal adult human dose by ingestion is estimated to be 10 grams. (Ref. Handbook of Poisoning:
Prevention, Diagnosis & Treatment, Twelfth Edition)
EFFECTS OF OVEREXPOSURE
1. Acute Overexposure
Irritating to body tissue with which it comes into contact.
2. Chronic Overexposure
No known cases of chronic poisoning due to potassium permanganate have been reported. Prolonged exposure, usually over many
years, to heavy concentrations of manganese oxides in the form of dust and fumes. may lead to chronic manganese poisoning, chiefly
involving the central nervous system.
3. Carcinogenicity
Potassium permanganate has not been classified as a carcinogen by OSHA, NTP, IARC.
4. Medical Conditions Generally Aggravated by Exposure
Potassium permanganate will cause further irritation of tissue, open wounds, burns or mucous membranes.
Registry of Toxic Effects of Chemical Substances
RTECS #S06476000
ResponsibleCare°
A Public CommfhneM
CARUS CHEMICAL COMPANY

Section 12 Ecological Information
Entry to the Environment
Potassium Permanganate has a low estimated lifetime in the environment, being readily converted by oxidizable materials to insoluble
manganese dioxide (MnO2).
Bioconcentration Potential
In non -reducing and non -acidic environments manganese dioxide (MnO2) is insoluble and has a very low bioaccumulative potential.
Aquatic Toxicity
Rainbow trout, 96 hour LC;,,: 1.8 mg/L
Bluegill sunfish, 96 hour LC,„: 2.3 mg/L
Section 13 Disposal Consideration
DEACTIVATION OF D001 IGNITABLE WASTE OXIDIZERS BY CHEMICAL REDUCTION
Reduce potassium permanganate in aqueous solutions with sodium thiosulfate (Hypo), or sodium bisulfite or ferrous salt solution. The
thiosulfite or ferrous salt may require some dilute sulfuric acid to promote rapid reduction. If acid was used, neutralize with sodium bicarbonate
to neutral pH. Decant or filter, and mix the sludge with sodium carbonate and deposit in an approved landfill. Where permitted, the sludge
can be drained into sewer with large quantities of water. Use caution when reacting chemicals. Contact Carus Chemical Company for
additional recommendations.
Section 14 Transport Information
U. S. DEPARTMENT OF TRANSPORTATION INFORMATION:
Proper Shipping Name
ID Number:
Hazard Class:
Division:
Packing Group:
49 CFR 172.101 Potassium Permanganate
49 CFR 172.101 UN 1490
49 CFR 172.101 Oxidizer
49 CFR 172.101 5.1
49CFR172.101 11
Section 15
Regulatory Information
TSCA
CERCLA
RC RA
Listed in the TSCA Chemical Substance Inventory
Hazardous Substance
Reportable Quantity: RQ - 100 lb
40 CFR 116.4; 40 CFR 302.4
Oxidizers such as potassium permanganate meet the criteria of ignitable waste. 40 CFR 261.21
SARA TITLE I11 Information
Section 302 Extremely hazardous substance: Not listed
Section 311/312 Hazard categories: Fire, acute and chronic toxicity
Section 313 CAIROX" potassium permanganate contains 97% Manganese Compound as part of the chemical
structure (manganese compounds CAS Reg. No. N/A) and is subject to the reporting requirements of
Section 313 of Title III, Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372.
�f1
Responsible Care°
A Public Commitment
CARUS CHEMICAL COMPANY

Section 15 Regulatory Information (cont.)
STATE LISTS
Michigan Critical Materials Register: Not listed
California Proposition 65: Not listed
Massachusetts Substance List: 5 F8
Pennsylvania Hazard Substance List: E
FOREIGN LISTS Canadian Domestic Substances List (DSL) Listed
Canadian Ingredient Disclosure List Listed
European Inventory of Existing Chemical Substances (EINECS) 2317603
Section 16 Other Information
NIOSH National Institute for Occupational Safety and Health
MSHA Mine Safety and Health Administration
OSHA Occupational Safety and Health Administration
NTP National Toxicology Program
IARC International Agency for Research on Cancer
TSCA Toxic Substances Control Act
CERCLA Comprehensive Environmental Response, Compensation and Liability Act of 1980
RCRA Resource Conservation and Recovery Act
SARA Superfund Amendments and Reauthorization Act of 1986
PEL-C OSHA Permissible Exposure Limit -OSHA Ceiling Exposure Limit
TLV-TWA Threshold Limit Value - Time Weighted Average (American Conference of Governmental Industrial Hygienists)
‘74-71.4
Kenneth Krogulski
May 2000
CARLIS
Responsible Care
A Public Commitment
The information contained is accurate to the best of our knowledge, However. data, safety standards and government regulations are subject to change;
and the conditions of handling, use or misuse of the product are beyond our control. Carus Chemical Company makes no warranty, either express or
implied including any warranties of merchantability and fitness fora particular purpose. Carus also disclaims all liability for reliance on the completeness
or confirming accuracy of any information included herein. Users should satisfy themselves that they are aware of all current data relevant to their
particular uses.
CAIROX" is registered trademark of Carus Corporation.
Responsible Care is a service mark of the Chemical Manufacturers Association. Rev. 5/ 00 Form # CX 1028

O 'C
Michael F. Easley, Governor
William G. Ross Jr., Secretary
North Carolina Department of Environment and Natural Resources
Coleen H. Sullins, Director
Division of Water Quality
December 31, 2008
Dennis Goodson, Deputy Base Civil Engineer
4 CES/CEV
1095 Peterson Avenue
Seymour Johnson AFB, NC 27531-2355
RE: Site FT-07, Fire Training Area #3
Seymour Johnson Air Force Base
UIC Program Tracking # WI0700123
Dear Mr. Goodson:
The Underground Injection Control (UIC) Program of the Aquifer Protection Section of the Division of Water
Quality has reviewed the proposal for injection of potassium permanganate for the chemical oxidation of jet fuel
and chlorinated ethenes, received on October 17, 2008. The proposed injection project as presented in the work
plan meets relevant state regulatory requirements (15A NCAC 2C.0200) for construction and operation of
injection wells, provided that RCRA Metals (arsenic, barium, cadmium, chromium, mercury, lead, selenium,
silver) are incorporated into the list of analytical parameters in the monitoring plan. Post -injection metals
monitoring should continue until concentrations return to background/pre-injection concentrations.
Due to the site's coverage under the Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA), the state's administrative permitting requirements have been waived for this project. A technical
report summarizing the project, including monitoring data, should be submitted to the UIC Program upon
completion of the injection project.
Please call me at 919-715-6164 or Debra Watts at 919-715-6699 if you have any questions regarding
this letter or the UIC Program.
Best Regards,
Thomas Slusser, L.G.
Underground Injection Control Program
cc: Elizabeth Hartzell, Division of Waste Management
Aquifer Protection Section — Washington Regional Office
UIC files
N Carolina
Naturally
Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 Phone [phone] Customer Service
Internet: http://h2o.enr.state.nc.us 2728 Capital Boulevard Raleigh, NC 27604 Fax [phone]
Fax [phone]
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