WI0700012_Monitoring (Report)_20030826

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
County: Beaufort
Contact Person: Jimmy Hardy Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Or
Well Identification Number (from Permit): MWTF1-CR
Well Depth: 42.00 ft. Well Diamter:
2 inch
Screened Interval: 38.70 ft. to 40.70 ft.
Depth to Water Level: 10.72 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
MILILITERS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
2100
Field Analysis: pH 7.0 , Specific Conductance 645 uMhos
Temp. 23.9 oC, Odor NONE
Appearance: CLEAR
Mail Original
to:
DIVISION OF WATER QUALITY
GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT
P.O. BOX 29578
RALEIGH, NC 27626-0578 Phone [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon
Spray Field X Remediation :
EXPIRATION DATE:
01/15/08
UIC
Remediation: Infiltration Galley
W'
N
CJl
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 7/15/03
Date sample analyzed: 7/15/03 to 7/28/03
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
rr!
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A
Coliform: MF Fecal N/A
Coliform: MF Total <1.0
(Note. Use MPN method for highly turbid samples)
Dissolved Solids: Total N/A
pH (when analyzed) N/A
TOC N/A
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
N/A
N/A
NIA
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
N/A
N/A
N/A
mg/I
/100m1
/100m1
Yes n/a
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
mg/I Al - Aluminum
units Ba - Barium
mg/I Ca - Calcium
mg/I Cd- Cadmium
mg/I Chromium: Total
mg/I Cu - Copper
mg/I Fe - Iron
mg/I Hg - Mercury
No and field acidified
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/1
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
uMhos K- Potassium
mg/I Mg - Magnesium
mg/I Mn - Manganese
Ni - Nickel
Pb - Lead
Zn - Zinc
Yes n/a No )
N/A
N/A
N/A
Ammonia Nitrogen
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
0
w
N' 1
Ag -Silver tit;
iV
Organics: (GC, GC/MS, HPLC) 7=,--17
�'
(Specify test method #. Attach lab Pport.ki ,
N/A mg/I Report attached? Yes (1) Nor.? A T5 (2)
N/A mg/I VOC : methoi
ug/I
ug/I
ug/I
mg/I
N/A mg/I
Se- Selenium
Sodium
mg/I
mg/I
mg/I
mg/I
ug/I
metho' E
method#
I certify that, to the best of my knowledge and belief. the information submitted in this report is true, accurateand complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisionment for knowing violations.
NOTE:
Terry L. Baker - Manager, Environmental Affairs
Permittee (of Authorized .e Name and Title - Please type or print
7 .1 r (5'z6G3
GW-59 Rev 4/98
Signatup
Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jimmy Hardy Telephone: [phone]
Well Locations/Site Name: Tank Farm
No. of Wells to be Sampled
18
Well Identification Number (from Permit): CIW-7
Well Depth: 48.00 ft. Well Diamter:
Screened Interval: 31.00 ft. to 45.25 ft.
Depth to Water Level:
Measuring Point is
4 inch
N/A ft. below measuring point.
N/A ft above land surface.
MILILITERS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
X Influent (98)
Effluent (99)
N/A
Field Analysis: pH 7.3 , Specific Conductance 625 uMhos
Temp. 26.6 oC, Odor NONE
Appearance: CLEAR
Mail Original
to:
DIVISION OF WATER QUALITY
GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT
P.O. BOX 29578
RALEIGH, NC 27626-0578 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon
Spray Field X Remediation :
EXPIRATION DATE:
U I C X
01/15/08
Rotary Distributor
Other
Remediation: Infiltration Gallery
Land Application of Sludge
CA) I
0
CJl
01
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 7/15/03
Date sample analyzed: 7/15/03 to 7/28/03
Laboratory Name: PCS PHOSPHATE and
Certification No(s) 330 10
ENVIRONMENT 1
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD N/A
Coliform: MF Fecal N/A
Coliform: MF Total <1.0
(Note Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mg/I Nitrite (NO2 as N)
/100m1 Nitrate (NO3 as N)
/100m1 Phosphorus: Total as P
Orthophosphate
mg/I
units
mg/I Ca - Calcium
mg/I
mg/I
mg/I
mg/I Fe - Iron
mg/I Hg - Mercury
uMhos
mg/I
mg/I
Al - Aluminum
Ba - Barium
Cd- Cadmium
Chromium: Total
Cu - Copper
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified c,
N/A mg/I Ni - Nickel r ug/I
N/A mg/I Pb - Lead I j'c= ug/I
N/A mg/1 Zn - Zinc N -- ug/I
N/A mg/I Ammonia Nitrogen - mg/I
N/A mg/I Other (Specify Compounds and Concentration triEs) .1 r`
N/A mg/I Fluoride N mg/1
N/A mg/I MIBK v7 191A mg/l
N/A mg/I Ag - Silver al kI;iA mg/I
N/A mg/I Se- Selenium ttA mg/1
N/A ug/I
Yes n/a No )
N/A mg/I Sodium
N/A mg/1 Organics: (GC, GC/MS, HPLC)
N/A mg/1 (Specify test method #. Attach lab report.)
N/A mg/1 Report attached? Yes (1) No X (2)
N/A mg/I VOC : method#
method#
method#
N/A mg/1
I certify that, to the best of my knowledge and beliefthe information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisionment for knowing violations.
NOTE:
Terry L. Baker - Manager, Environmental Affairs
Permittee (of Authorized Agent)ame and Title - Please type or print
7/Z6/3
AJW lX
GW-59 Rev 4/98
Signature Permittee (or Authorized Agent)
(Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jimmy Hardy Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Well Identification Number (from Permit): WLCT
Well Depth: N/A ft. Well Diamter: N/A
Screened Interval: N/A ft. to N/A ft.
Depth to Water Level:
Measuring Point is
N/A ft. below measuring point.
N/A ft above land surface.
For Groundwater Treatment
Systems Check One:
X Influent (98)
Effluent (99)
GALLONS of water pumped/bailed before sampling: CONTINUOUS
Field Analysis: pH 7.0 , Specific Conductance 597 uMhos
Temp. 21.6 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DIVISION OF WATER QUALITY
GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT
P.O. BOX 29578
RALEIGH, NC 27626-0578 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
EXPIRATION DATE:
UIC X
01/15/08
Other
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
N
.C"
[.l'1
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
Certification No(s)
CJl
7/15/03
7/15/03 to 7/28/03
PCS PHOSPHATE and ENVIRONMENT 1
330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
<1.0
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/1
mg/l
mg/I Fe - Iron
mg/l Hg - Mercury
uMhos
mg/I
mg/I
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
No and field acidified
N/A mg/1 Ni - Nickel
N/A mg/I Pb - Lead
N/A mg/I
N/A mg/I
N/A mg/l
N/A mg/I
N/A mg/I
Yes n/a No )
Zn - Zinc
Ammonia Nitrogen
Other (Specify Compounds and Concentration nits) �G
Fluoride S 240
MIRK
N
w
/A
W
to
m
N
N/A mg/I Ag - Silver
N/A mg/I
CJ7
Se- Selenium 0"
N/A mg/I Sodium
K- Potassium
Mg - Magnesium
Mn - Manganese
�Al/A
avA
riWA
N/A mg/I Organics: (GC, GC/MS, HPLC)
N/A mg/I (Specify test method #. Attach lab report.)
N/A mg/I Report attached? Yes (1) No X
N/A mg/I VOC method#
method#
method#
N/A mg/I
ug/I
ug/I
ug/I
mg/I
mg/I
mg/I
mg/I
mg/I
ug/I
(2)
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisionment for knowing violations.
NOTE:
Terry L. Baker - Manager, Environmental Affairs
Per.. ttee (of Authorized A.yt) =me and Title - Please type or
rint
S z�
GW-59 Rev 4/98
Signatu;, o Permittee (or Authorized Agent)
( t• ate)

PCS
Phosphate
AURORA
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27806
August 25, 2003
EVAN O. KANE
GROUND WATER
DENR
1636 MAIL SERVICE CENTER
RALEIGH, NC 27626-1636
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
May 2003 — July 2003
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Evan:
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTF1CR, b) piezometer level monitoring field sheet, and c) the summary operational and
maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
404,,,,,a Ltit.v-ztaet,4 rir
D. Daniel Winstead III
Environmental Engineer
PCS Phosphate
Attachments
pc: Willie Hardison — DWQ- GWS, WaRO (w/ attachments)
R. M. Smith/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
W. A. Schimming

Date:
Time:
Tech:
PCS Phosphate Co., Inc. - Tank Farm Remediation System Quarterly Monitoring
7/23�03
tam
ee
System Gauge Pressures
SWW-1
*-4Q4✓C/S an- /.c es4', -
SWW-7
'F ••
.r
CWW-1•,
.,/.
CWW-7.t
.r
File: 12-07-02
pc: TLB
Reference
Point MSL
Level Rel
to MSL
Ditch
12.91
7.03
Barge Slip
Water Level
Control Tank
= MSL
10.59
a2/
0 /�
12.3r
Sand Layer Peizometers Level Indicators
Well ID
TOC
Elevation
MSL'
TOC
Ste Wtr
Level'
Level
Relative To
MSL Ft.
Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
Level'
Level
Relative To
MSL Ft.
Spz-1
10.47
41,, 00
6.4/7
Cpz-1
10.51
/O-o''
0,.26
Spz-2
11.21
B 96
or. BS
Cpz-2
10.25
//08
/Q,,S7_,
- a.33
/f 59
Spz-3
11.87
A S,j
,j;3.2-
Cpz-3
11.12
' Spz-4
11.45
7p, 47
4/ 9B
CPW
9.65
/O / 5
700
Spz-5
11.45
9 'YS
,, , 00
MWTF-1A •
14.35
9Q
/Q. I/3
Spz-6
11.23
/0. 00
/ot5
MWTF-1B •
14.36
'S,
'9,4/
9 9/
Spz-7
11.59
/0, of
/53-
MWTF-1C •
14.44
/Q V
.57- .
-_Spz-8 -
- - 14.57- - .
MWTF-2A__.
- - 14.05-
-_ _aa..a..0
- -04/O
t0.741
.11
Spz-9
11.01
A a
/ 79
MWTF-2B
14.02
/9, 97
,3"c,5-
Spz-10
12.16
.5,44/
6-C.?
MWTF-2C
14.08
/j 0.
-Q 925,
SPW
9.95
768
Ogot7
MWTF-3A
12.21
4 oy"
B/k
MWTF-3B
12.18
/Q /9
Z,©/
- /, 3
MWTF-3C
12.19
/ 3 4/9
Sand Layer And Croatan Formation Withdrawal Wells
Well ID
TOC
Elevation
MSL'
Max Stc
Wtr
Level Ft.
Pump
Activation Depth
Rel MSL
Max Level
Relative To
MSL Ft.
Control
Point
MSL'
Is Well
Pumping?
(Y)es/(N)o
Comments
SWW-1
10.70
9a5
6'
30.5-
+1 'to+2'
yet
CWW-1
10.60
Ain
9'
-2.s3
-2'to-1'
/y!S
SWW-2
9.99
77/
6'
/ V
+1' to+2'
e9
CWW-2
10.23
7.N2
9'
-/5S
-2'to-1'
SWW-3
9.97
04/
6'
/ 93.
+1 ' to+2'
yes
Nes
CVVW-3
9.95
7/Q
9'
-/i90
-2'to-1'
SWW-4
10.73
4. '79
6'
a 79
+1 ' to+2'
//['
!/n
CWW-4
- 10.73
6 RR
9'
-A 7.
-2'to-1'
yes
SWW-5
10.80
9,/I
6'
45/7
+1 'to+2'
yea
CWW-5
10.74
6-'g2
9'
",'.J8
-2'to-1'
SWW-6
10.66
9. is
6'
,3&
+1'to+2'
Ye'
�
CWW-6
9.92
Ito
9'
-/ f�p
-2'to-1'
/ e5
SWW-7
10.70
7 /4/
6'
7 /4/
+1 ' to+2'
ye_s
CWW-7
9.95
7S'6
9'
-/ 4/4/
-2'to-l'
te-5
Revised 7/29/02
• Riser length added to TOC elevation 1/24/97
DADataWorms\Well Form \Tank Farm Remed Wells.xls

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
May 2003 — July 2003
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Injection Water Well System
The injection water well system operated with the DPW Water - Anthracite Sand Filter / Ultraviolet Light
(ASF/UV) disinfection system throughout the period.
Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs
Department. The total monthly and quarterly volumes of water injected as well as the month end water
level in the Water Level Control Tank are:
x � _
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
LEVEL
FEET, MSL
May
584,940
0
584,940
13.1
14.4
June
577,530
0
577,530
13.4
2.7
July
603,400
0
603,400
13.5
12.6
TOTALS
1,765,870
0
1,765,870
C:\MyData\Reports\2003\Quarterly\TFRAS Report Second Quarter 2003.doc
3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
177.
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
May
449,888
163,988
524,921
13.5
June
391,744
124,747
617,299
15.3
July
400,618
124,913
566,517
13.1
TOTALS
1,242,250
413,648
1,655,898
Some additional-short-periods-of-plaLnied-downtime-for-preventative-maintenance pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWW) Pumps
SWW-1: On 7/3 changed counter.
SWW-2:
SWW-3:
SWW-4: On 7/1 changed counter. On 7/2 changed counter. On 7/30 changed pump.
SWW-5:
SWW-6: On 6/16 changed pump.
SWW-7:
C:\MyData\Reports\2003\Quarterly\TFRAS Report Second Quarter 2003.doc
4

Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1: On 6/10 washed pump.
CWW-2:
CWW-3: On 5/19 shook pump. On 6/10 washed well.
CWW-4:
CWW-5: On 5/8 changed pump and counter.
CWW-6: On 7/29 shook pump.
CWW-7:
C:\MyData\Reports\2003\Quarterly\TFRAS Report Second Quarter 2003.doc 5