WI0700012_Monitoring (Report)_20080205

•
PCS
Phosphatee AURORA
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27806
February 5, 2008
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
November 2007 — January 2008
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Qi:
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTF1CR, b) piezometer level monitoring field sheet, and c) the summary operational and
maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
N• I4AZdtJ2zrA
D. Daniel Winstead III
Environmental Engineer
PCS Phosphate
Attachments
RECEIVE[:
-�l 0 6 70fR

pc: Will Hart — Aquifer Protection DWQ, WaRO (w/ attachments)
R. M. Smith/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
W. A. Schimming (w/ attachments)
Mike Brom (w/ attachments)
Anthony Shrewsbury (w/ attachments)
R. B. Lee (w/ attachments)
Total Two Copies
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
\\aurdata2\users\AURIDDW\Reports\2008\Quarterly\TFRAS Report Fourth Quarter 2007.doc
2

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
011
Well Identification Number (from Permit): CIW-7
Well Depth: 48.00 ft. Well Diamter: 4 inch
Screened Interval: 31.00 ft. to 45.25 ft.
Depth to Water Level: N/A ft. below measuring point.
For Groundwater Treatment
Systems Check One:
X Influent (98)
Effluent (99)
Measuring Point is N/A ft above land surface.
GALLONS of water pumped/bailed before sampling: N/A
Field Analysis: pH 7.3 , Specific Conductance 594 uMhos
Temp. 18.4 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
Certification No(s)
1/15/2008
1/15/2008 to 1/16/2008
PCS PHOSPHATE and ENVIRONMENT 1
330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
<1.0
mg/I
/100m1
/100m1
(Note. Use MPN method for highly turbid samples)
Dissolved Solids: Total N/A mg/I
pH (when analyzed) N/A units
TOC N/A mg/I
Chloride N/A mg/I
Arsenic N/A mg/I
Grease and Oils N/A mg/I
Phenol N/A mg/I
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A mg/I
N/A uMhos
N/A mg/I
N/A mg/I
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified
Yes n/a No )
N/A mg/I Ni - Nickel N/A ug/l
N/A mg/I Pb - Lead N/A ug/I
N/A mg/1 Zn - Zinc N/A ug/I
N/A mg/I Ammonia Nitrogen mg/I
N/A ug/I
N/A ug/l
N/A ug/I
N/A ug/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
N/A ug/I Se- Selenium
N/A ug/I Sodium
N/A
N/A
N/A
N/A
N/A
mg/1
ug/I
ug/I
ug/I
ug/I
N/A ug/I Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A ug/l VOC : method#
method#
method#
N/A ug/I
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
RECEIVE
FFR, u 6 7nnR
Information Unit
DWQ/BOG
Ross M. Smith - Manager, Environmental Affairs
P rmi ee (ol Authorized Agent)) Name and Title - Please type or rint
r�✓�d�2�C 41r � N1 S 2 5-/o
Signature of Permittee (or Authorized Agent)
(Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Well Identification Number (from Permit): MWTF1-CR
Well Depth: 42.00 ft. Well Diamter: 2 inch
Screened Interval: 38.70 ft. to 40.70 ft.
Depth to Water Level: 14.06 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
MILILITERS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
X Influent (98)
Effluent (99)
2700
Field Analysis: pH 7.3 , Specific Conductance 632 uMhos
Temp. 19.2 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
1/15/2008
1/15/2008 to 1/16/2008
PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A mg/I Nitrite (NO2 as N)
Coliform: MF Fecal N/A /100m1 Nitrate (NO3 as N)
Coliform: MF Total <1.0 /100m1 Phosphorus: Total as P
(Note: Use MPN method for highly turbid samples) Orthophosphate
Dissolved Solids: Total N/A mg/I Al - Aluminum
pH (when analyzed) N/A units Ba - Barium
TOC N/A mg/I Ca - Calcium
Chloride N/A mg/I
Arsenic N/A mg/1
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A mg/I
N/A mg/I
N/A mg/I
N/A uMhos
N/A mg/I
N/A mg/I
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
Yes n/a
No and field acidified
N/A mg/I Ni - Nickel
N/A mg/I Pb - Lead
N/A mg/I Zn - Zinc
Yes n/a No )
N/A
N/A
N/A
N/A mg/I Ammonia Nitrogen
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
N/A ug/I Se- Selenium
N/A ug/I Sodium
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A
N/A
N/A
N/A
N/A
ug/I
ug/I
ug/I
mg/I
mg/I
ug/I
ug/I
ug/I
ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC • method#
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment fur knowing violations.
NOTE:
GW-59 Rev 3/2000
✓= F n t i b) O O R
Information Processing Unit
DWQ/80G
Ross M. Smith - Manager, Environmental Affairs
PermA-
(o Authorized Agent) N me and Title - Please type or print
- /. � r /ti7s 2�s 0
Signature of Permittee (or Authorized Agent)
(Date)

Date:
Time:
Tech:
PCS Phosphate Co., Inc. - Tank Farm Remediation System Quarterly Monitoring
/-/8-aB
987
System Oauae
Pressures
SWW-,
rNo/7.
SwW-7
...7-41o/1-
CWW-1
L ..N•°?
CW W-7'
,/✓‘7, •
File:12-07-02
p=: TLB
Point n
Level Rd
to WI
Ditch
12.91
79/
Barge Slip
10.69
/. /7
Water Level
Control Tank
% e MSL
/OD/
(PS/.
/s. /y
Sand Layer Pelzometers Level Indicators
Well ID
TOC
Elevation
MSL'
TOC
Ste Wtr
Level'
Level
Relative To
MSL Ft.
Well ID
TOC
Elevation
MSL'
TOC
Stc WIT
Level'
Level
Relative To
MSL Ft.
Spz-1
10.47
«98
s 99
Cpz-1
10.51
/o/-,30
- /. 79
Spz-2
1121
95l0
/, 45
Cpz-2
1025
/o%•&S
- /. 8O
Spz-3
11.87
0•0?0
//'//,/07
Cpz3
11.12
/c2./ol
-/.00
Spz-4
11.45
A. 63
7, Li
CPW
9.65
/00Jo
-, ..SS-
SpzS
11A5
-- 9' 90
/, Si"
MWTF-1A•
14.35
\} 057''
9079
Spz-6
11.23
/Q 49
E2.57
MWTF-1e•
14.36
LS 99
67,87
0 5B"
Spz-7
11.59
/0..-9/
/ Jo
MWTF-1C•
14.44
}1C/, o/7
Spz-8
11.57
BD-8,0
� .7/
MWTF-2A
14.05
4.40
7 «/Jr
Spz-9
11.01
p - !O/ •
g.. qo
MWTF-2B
14.02
//,?
ce • 70
Spz-10
12.16
9. `J-8
I/cr,,c9
MWTF-2C
14.08
//. Qy
-/: %/p
.. SPW
9.95
8, /S- .
/, 6'O
MWTF3A
1221
'O3
A /&,
MWTF3B
12.18
/0 6,2
/ 5-4'
-. -
MWTF3C
12.19
9-
-44.90
t Sand Layer And Croatan Formatlon Withdrawal Wells
Well ID
TOC
Elevation
MSL'
Max Stc
Mr
Ft.
Pump
Activation Depth
Rel MSL
Max Level
Relative To
MSL Ft.
Control
Point
MSL'
Is Well
Pumping?
�y)eslgt•0o
Comments
SwW-1
10.70
.Leevel
/. 7
e
' /c' 9
+1 ' to+2'
/5
-
CWW-,.
10.60
•o
? ?
e
- .77
-29o-1'
/!
No
SWW-2
9.99
7. 9o3
e
9?
+1' to+z
yes
CW -2
W
1023 -
7 •, 9
�
9'
"/
- y, 7//
-2'to -1'
44
SWW3
9.97
7. L/4
e
///7a
+1'to+2.
ye5
CWW3
9.954/
4/9
g
- 3/457
-2'to-,'
447
SWW-4
10.73
-29
9'
0,079
+1'to-Fr
vey
CWW-4
10.73
/, /l9
9' _
- 7 .52
-2'to-l'
//1%O
Sww-s
10.80
/O'//• 7a�9
S'
0, 7
+1 . to+2'
L�/P�
CwwS
10.74
'7', %Bp
e
- 7'014
-2 ' to-,'
/l//0
Sww-6
10.66
7,o7[J
S'-
/_cte
+1'to+2'
y.�(9�fjJ
CWW-6
9.92
1a7
et-
e .'7_
-2'to-1'
/�4J
SWW-7
10.70
7,/o3
e
/./at
+1 'to +2'
et -
Cywv-7
9.95
e3. /o/i
9'
-. 90
-2'to-1'
/"o
Revised 729102
• Riser length added to TOC elevation 124/97
R\DafalFonns\Well Fo m\Tank Farm Rend Wellsjds

SPZ
sPZ-1
CPZ.1
CUT-OFF WALL SWUM
CPIW
s ASPHALT ROAD cW-e
SWW4 cwWJ
SPZ-2 p
SWW-2 CV/WA
CY YR \1
W CWS1ETE
R
1 DRAINAGE DITCH
SPZ-5
Q
MWTF4
CLUSTER _
SPL7-SPZ-6 •
r
CPW SPW cWWW+
/ \ SWW
WITHDRAWAL WELL
FIOWTOTANERS
AND CONTROL VALVES
CPZ-9 fi
.SPZ-6
PIPERACK SPILL CONTAINMENT PAD
WATER LEVEL
CONTROL TANK
crxa
clw-Iool
T
O �..
SPZ-10
1
.
IN t
1 I ❑1 NU
SYNCH UI L1 51 ❑1.'1IUN
• 1•0•0100,0111.
• ...N. Aryl ....w...... wnm.N wp win
• ..... Ina ....Mu.... Wn.N...AWM 1101111
. w..u.0 nas.O.. M.p .uN Will
1. .. r...... W1 .. N nit PM.. IAN 001
(1) Mr. I..N .0.. .....M 10.110 un1
LOCATION PLAN FOR TANK FAIIM:
AREA .REMEDIAL ACTION SYS I I M
WELLS AND PIEZOMETIIP;

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
October 2007 — January 2008
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Injection Water Well System
The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system
during the period.
Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs
Department. The total monthly and quarterly volumes of water injected as well as the month end water
level in the Water Level Control Tank are:
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
LEVEL
FEET, MSL
November
1,141,855
0
1,141,855
26.4
15.0
December
1,285,918
0
1,285,918
28.8
15.0
January
1,166,853
0
1,166,853
27.0
15.0
TOTALS
3,594,626
0
3,594,626
\\aurdata2\users\AUR1DDW\Reports\2008\Quarterly\TFRAS Report Fourth Quarter 2007.doc
3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
November
305,214
0
305,214
7.1
December
179,155
0
179,155
4.0
January
205,566
0
205,566
4.6
TOTALS
689,935
0
689,935
Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWW) Pumps
All Pumps were flushed on 11/1, 11/20, 11/30, 12/13, 1/15 and 1/23. On 12/4 and 1/21 changed filters on
compressor.
SWW-1:
SWW-2: On 11/2 reset pump. On 11/13 reset, head. On 12/4 air blast well. On 12/12 changed pump. On
12/27 changed pump. On 1/24 reset pump head. On 1/28 changed pump.
SWW-3:
SWW-4: On 12/27 reset pump. On 1/3 changed pump. On 1/21 air blast well.
SWW-5:
SWW-6:
SWW-7:
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Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1:
CWW-2:
CWW-3:
CWW-4:
CWW-5:
CWW-6:
CWW-7:
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