WI0700012_Monitoring (Report)_20080821

PCS
Phosphate AURORA SEP 2 6 n
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27806
August 21, 2008
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
May 2008 — July 2008
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Qi:
Ktv:JVED / DENR' ^l;
AQUIFFR'PROTECTION SECT04
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTF 1 CR, b) piezometer level monitoring field sheet, and c) the summary operational and
maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
W„-u-A-7t2_,,_d
D. Daniel Winstead III
Environmental Engineer
PCS Phosphate
Attachments
RECEIVE
A U G 2 6 2008
Inform t:o1 *'f0,c€_:;Sifg tiro
JV'Q.f.:;O

pc: Will Hart — Aquifer Protection DWQ, WaRO (w/ attachments)
R. M. Smith/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
Mike Brom (w/ attachments)
Anthony Shrewsbury (w/ attachments)
R. B. Lee (w/ attachments)
Total Two Copies
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
\\aurdata2\users\AUR1DDW\Reports\2008\Quarterly\TFRAS Report Second Quarter 2008.doc
2

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
3
Well Identification Number (from Permit): MWTF1-CR
Well Depth: 42.00 ft. Well Diamter:
Screened Interval: 38.70 ft. to 40.70 ft.
Depth to Water Level: 14.50 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
MILILITERS of water pumped/bailed before sampling:
2 inch
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
2100
Field Analysis: pH 7.1 , Specific Conductance 700 uMhos
Temp. 23.6 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone' [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/31/13
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
Certification No(s)
7/10/2008
7/10/2008 to 7/11/2008
PCS PHOSPHATE and ENVIRONMENT 1
330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A
Coliform: MF Fecal N/A
Coliform: MF Total <1.0
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/I
mg/I
mg/I
mgll
uMhos
mg/I
mg/I
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Yes n/a
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified
N/A mg/I
N/A mg/I
Ni - Nickel
Pb - Lead
N/A mg/l Zn - Zinc
Yes n/a No )
N/A mg/I Ammonia Nitrogen
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/l
N/A ug/I
N/A ug/l
N/A ug/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
Se- Selenium
mg/I
N/A mg/I
N/A ug/I
N/A ug/I
N/A ug/I
Sodium N/A ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC method#
method#
method#
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
E I ED
AUG 2 8 2008
Information Processing Unit
DWQ/BOG
Ross M. Smith - Manager Environmental Affairs
Permittee (of Authorizedpgent) Name and Title - Please type or print
/(11,-.7S
Signature of Permittee (or Authorizes' Agent) Ell (D e)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
3
Well Identification Number (from Permit):
Well Depth: 48.00 ft. Well Diamter:
CIW-7
Screened Interval: 31.00 ft. to 45.25 ft.
Depth to Water Level:
Measuring Point is
4 inch
N/A ft. below measuring point.
N/A ft above land surface.
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
GALLONS of water pumped/bailed before sampling: 0
Field Analysis: pH 7.0 , Specific Conductance 690 uMhos
Temp. 24.6 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/31/13
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 7/22/2008
Date sample analyzed: 7/22/2008 to 7/23/2008
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
<1.0
mg/I
/100m1
/100m1
(Note. Use MPN method for highly turbid samples)
Dissolved Solids: Total N/A mg/I
pH (when analyzed) N/A units
TOC N/A mg/I
Chloride N/A mg/I
Arsenic N/A mg/I
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A mg/I
N/A mg/1
N/A mg/I
N/A uMhos
N/A mg/1
N/A mg/I
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
nla
Se- Selenium
Sodium
No and field acidified
Yes n/a No )
N/A mg/I Ni - Nickel N/A ug/I
ug/I
ug/I
N/A mg/I Ammonia Nitrogen mg/I
N/A ug/I Other (Specify Compounds and Concentration Units)
N/A ug/I Fluoride N/A mg/I
N/A ug/I MIBK N/A ug/I
N/A ug/I Ag - Silver N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A mg/I Pb - Lead N/A
N/A mg/I Zn - Zinc N/A
N/A ug/I
N/A ug/I
N/A ug/I VOC : method#
method#
method#
N/A ug/I
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
AUG Z 6 2008
nformat,on Processing Unit
DWQ/BOG
ELJ
SEP 1 5 2008
Ross M. Smith - Manager, Environmental Affairs
Permittee (of Authorized Agent) Name and Title - Please type «(/
61%-� -4 r- 2�s C
Signature of Permittee (or Autkforized Agent) (Date)

PCS Phosphate Co., Inc. - Tank Farm Remediation System Quarterly Monitoring
Date: 7///1/4 K
Time:
Tech:
System Gauge Pressures
SWw-1
SW W-7
cwW-1
CW W-7
File: 12-07-02
pe: TLB
Reference
Point MSL
Level Rel
to MSL
Ditch
12.91
Boy
Barge Slip
Water Level
Control Tank
%= MSL
10.59
0.9,9
Sand Layer Peizometers Level Indicators
Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
Level'
Level
Relative To
MSL Ft.
_ Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
Level'
Level
Relative To
MSL Ft.
Spz-1
10.47
7, (p/
V° -go,
Cpz-1
10.51
io?' 522
-/. 99'
Spz-2
11.21
B, 3
z276-le,n
Cpz-2
10.25
/,�-VLS"
- °" ?O
Spz-3
11.87
O. /0
/'//, / 7
Cpz-3
11.12
/t ..5 7
- / 4'<
Spz-4
11.45
6-2.7,A
'/7' 73
CPW
9.65
/4•V7
oo-86
Spz-5
11.45
960
/t7�zs
MWTF-IA'
14.35
6 •/7
A -it
Spz-6
11.23
0 /_5
MWTF-1B •
14.36
5: 7a
�9.
B 0e
p�
/D.vj70
Spz-7
11.59
/0•a/
/3a
MWTF-1C•
14.44
/-/.,50
-004°
Spz-8
11.57
6p.0/
`L7 , s b
W MTF-2A
14.05
6, 3/
779
at ea g
Spz-9
11.01
0..5/
a, bO
MTF-2B
W
14.02
//„ �3
Spz-10
12.16
/�
/ • 5-6)
7 4,0
MWTF-2C
14.08
/6,,3b
S .8/,
07.30
1 S.S
SPW
9.95
eC0/
/i 91/
W
MTF-3A
12.21
MWTF-3B
12.18
/09- 4%p
/ 70
MWTF-3C
219
/
/5 /0
4 9/
Sand Layer And Croatan Formation Withdrawal Wells
Well ID
TOC
Elevation
MSL'
Max Ste
Wtr
Level Ft.
Pump
Activation Depth
Rel MSL
Max Level
Relative To
MSL Ft.
Control
Point
MSL'
Is Well
Pumping?
(Y)es/(N)o
Comments
SWW-1
10.70
7',/ (p(p
6'
/'/66
+1'to+2'
,ye✓`
-
W
CW-1
10.60
, , 0�
9'
- 71 9g
-2'to-1'
SWW-2
9.99
t',�/at
6'
D. lot.
+1. to +2'
yes
y l.$
W
CW-2
10.23
/ 9
9'
- 7• o��
-2'to-1'
W SW-3
9.97
N•llR
6'
-71/8
+1. to+2'
yf�`
Vej
CINW-3
9.95
(0.217
9'
2.53
-2'to-1'
Ye-5
SWW-4
10.73
,5.06
6'
- O. 9,Z
+1 ' to+2'
Ejr
CW-4
W
10.73
5371
9'
-�: d'ee,
-2'to-1'
/y<s
swW-s
10.80
028
6'
//.ge
+1' to +2'
e_s
CWW-5
10.74
�D,,o2
9'
oi,491
-2to-1
y"
SWW-6
10.66
3t 75Y
6'
- 0. o2SS
+1' to +2'
7e5
CWW-6
9.92
(O-/.
9'
.2,81j
-2'to-1'
SWW-7
10.70
5 l00
6'
-0.. 4/0
+1' to +2'
y"
yes
CWW-7
9.95
11.351
9'
-71104,
-2'to-l'
tics
Revised 7/29/02
• Riser length added to TOC elevation 1/24/97
D:\Data\Fomis\Well Form\Tank Fann Ramer] Wellsxis

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
May 2008 — July 2008
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Injection Water Well System
The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system
during the period.
Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs
Department. The total monthly and quarterly volumes of water injected as well as the month end water
level in the Water Level Control Tank are:
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
LEVEL
FEET, MSL
May
1,102,806
0
1,102,806
24.7
15.0
June
1,028,944
0
1,028,944
23.8
15.0
July
976,650
0
976,650
22.6
15.0
TOTALS
3,108,400
0
3,108,400
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3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
_
TOTAL
GALLONS
AVERAGE
GPM
May
127,039
12,626
139,665
3.2
June
234,024
0
234,024
5.4
July •
90,998
0
90,998
2.1
TOTALS
452,060
12,626
464,687
Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWW) Pumps
On 6/19 replaced drive belts on compressor.
SWW-1: On 5/15 changed pump.
SWW-2: On 5/21 changed pump. On 5/26 replaced counter. On 7/9 changed pump.
SWW-3: On 5/21 reset counter.
SWW-4: On 5/12 changed counter. On 7/25 replaced pump.
SWW-5: On 5/15 replaced pump. On 7/22 reset head. On 7/31 replaced pump.
SWW-6:
SWW-7: On 5/28 flushed well.
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4

Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1:
CWW-2:
CWW-3: On 5/28 flushed well.
CWW-4:
CWW-5:
CWW-6:
CWW-7: On 5/28 flushed pump.
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