WI0700012_Monitoring (Report)_20090218

Phosphate AURORA
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27806
February 18, 2009
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
November 2008 — January 2009
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Qi:
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTFICR, b) piezometer level monitoring field sheet, and c) the summary operational and
maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
/0406.(Lo N/bv-Le/t1_,v_e,,
D. Daniel Winstead II1
Environmental Engineer
PCS Phosphate
Attachments
RECEIVED / DENR / DWQ
Aquif« ^r-,f.rtior. Section
Z 6 2003
-EB l 9 ZGO9

pc: Allen Clark — Aquifer Protection DWQ, WaRO (w/ attachments)
R. M. Smith/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
Mike Brom (w/ attachments)
Anthony Shrewsbury (w/ attachments)
R. B. Lee (w/ attachments)
Total Two Conies
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
H:\Reports\TFRAS Report Fourth Quarter 2008.doc
2

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled
Well Identification Number (from Permit): CIW-7
Well Depth: 48.00 ft. Well Diamter: 4 inch
Screened Interval: 31.00 ft. to 45.25 ft.
Depth to Water Level:
Measuring Point is
N/A ft. below measuring point.
N/A ft above land surface.
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
GALLONS of water pumped/bailed before sampling: N/A
Field Analysis: pH 7.1 , Specific Conductance 586 uMhos
Temp. 16.9 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
EXPIRATION DATE:
UIC X
01/31/13
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon
Spray Field X Remediation
Remediation: Infiltration Gallery
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 1/29/2009
Date sample analyzed: 1/29/2009 to 1/30/2009
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD N/A
Coliform: MF Fecal N/A
Coliform: MF Total <1.0
(Note. Use MPN method for highly turbid samples)
mg/I
/100m1
/100m1
Dissolved Solids: Total N/A mg/I
pH (when analyzed) N/A units
TOC N/A mg/I
Chloride N/A mg/I
Arsenic N/A mg/I
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A mg/1
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
N/A mg/I Fe - Iron
N/A mg/1 Hg - Mercury
N/A uMhos K- Potassium
N/A mg/I Mg - Magnesium
N/A mg/I Mn - Manganese
No and field acidified
Yes n/a No )
N/A mg/I Ni - Nickel N/A ug/I
N/A mg/I Pb - Lead N/A ug/I
N/A mg/I Zn - Zinc N/A ug/I
N/A mg/I Ammonia Nitrogen mg/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A —tig/1
N/A • Iigll_
N/A ug/I
N/A ug/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
N/A mg/1
N/A ug/I
N/A ug/I
Se- Selenium N/A ug/I
Sodium N/A ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC : method#
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ `formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
Grt
GW-59 Rev 3/2000
r t H 1 9 2009
RECEIVED / DENR / Div�
Ac utf`:'r Prtt,aStio i Section
tE�. ''rySif� Unit } ('
.L6 LJ 3
Ross M. Smith - Manager, Environmental Affairs
P rmi ee (of uthorized Agent) Name and Title - Please type or print
% 2��1�- .e�. r ,:-/n S 2// 43 /D9
gnature of Permtttee (or Authorffed Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm
No. of Wells to be Sampled 3
Well Identification Number (from Permit): MWTF1-CR
Well Depth: 42.00 ft. Well Diamter: 2 inch
Screened Interval: 38.70 ft. to 40.70 ft.
Depth to Water Level: 13.73 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
MILILITERS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
2600
Field Analysis: pH 7.2 , Specific Conductance 695 uMhos
Temp. 19.6 oC, Odor NONE
Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
EXPIRATION DATE:
UIC X
01/31/13
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 1/29/2009
Date sample analyzed: 1/29/2009 to 1/30/2009
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD N/A
Coliform: MF Fecal N/A
Coliform: MF Total <1.0
(Note. Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/I
mg/I
mg/I
mg/I
uMhos
mg/I
mg/I
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified
N/A mg/I Ni - Nickel
N/A mg/I Pb - Lead
N/A mg/I Zn - Zinc
Yes nla No )
N/A mg/I Ammonia Nitrogen
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/l
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
Se- Selenium
mg/I
N/A mg/I
N/A ug/I
N/A ug/I
N/A ug/I
Sodium N/A ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report)
Report attached? Yes (1) No X (2)
VOC : method#
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
1 9
2009 Li
MAR 6Aqi2a
ED 1 DENR ! DIAr signature of
rotecticn Section
16LL
Ross M. Smith - Manager, Environmental Affairs
Pgrmitt (of Authorized-Ag nt) Name and Title - Please type or print
/L fj -Cr PN?S
'ermittee (or Authorized Agent)
/!
Date)
og

Date:
Time:
Tech:
PCS Phosphate Co., Inc. - Tank Farm Remediation System Quarterly Monitoring
/A.90-09
P/y/
"PS/(ems
System Gauge Pressures
SWW-1
r>oa.
SWW-7
Zi/>o:
CWW-1
L /1',/,'
cwW-7
LaOO •
File: 12-07-02
pc TLa
Rena
Point MSS .
Leal Re
to MIL
Ditch
12.91
AS/
Barge Stip
10.69
D.96
Water Level
Control Tank
%=MSL
.nr-
Sand Layer Pelzometers Level Indicators
Well ID
TOC
Elevation
MSL'-
TOC
Ste MI
Level' .
Level
Relative To
- MSL Ft.
Well ID
TOC
Elevation
. MSL'
TOC
Stc Wtr
Level'
Level
Relative To
MSL Ft.
Spz-1
10.47
. .3 /
708
Cps-1
10.51
a//
-/ 00//
Spz-2
1121
7 90
3.3/
Cpz-2
1025
//1/�9
-/a*
Spz-3
11.67
0.290
/,07
Cpz-3
11.12
//' 0
p
l®•/4C/
Spz-4
11.45
L5749
is 96
CPW
9.65
//7'
D'%'
Spz-5
11A5
8 89
Af3 4
MWTF-1A•
14.35
4//
9:50
Spz-9
1123
/i•/Q
/o
MWTF-1B•
14.36
Cy:o2.2
9- CI
Spz-7
.. 11.59
9 35-
.07,4/
MWTF-1C •
14.44
. /3• 7
a 7/
Spz-8
11.57
7 99
S. B
MWTF-2A
14.05
5• 90
6' •/.J
Spz-9
11.01
0�y96
3Sty
MWTF-2B
14.02
99.s
o 4/..7-
Spz-10 .
12.16
' '• 27
..5 •/9
MWTF-2C
14.08
/5 93
'-/ g5
SPW
9.95
9.0/
a.9e,
MWTF3A
1221 -
. id" .
c9• 83 ' '
MUWF3B
12.16
919
0779
MWTF-3C
12.19
/9 93
�-ac/
Sand Layer And Croatan Formation Withdrawal Wells
Well ID
TOC
Elevation
MSL'
Max Ste
Wtr
Level Ft.
Pump
Activation Depth
Rel MSL
Max Level
Relative To
MSL Ft.
Control
Point
MSL'
Is Well
Pumping?
(1)es/0N0o
Comments
SWW-1
10.70
B 03
6'
4'.0i
+19o+2'
CWW-1
10.60
</•/8
9'
-7/8.2
-2'to-1'
//
SWW-2
9.99
-
6'
-
+1 ' to+2'
�
/%%4�%21.4.291914
CWW-2
1023
/0?•39
e'
5,.3C%
-2'to -1'
/I/
SWW3
9.97
9 PO
6'
-
+1' to+2'
40e//7zo /WA
CWW-3
9.95
7• y//8
9'
i(5 .
-2'to-1'
/V
SWW-4
10.73
8-/4'
6'
A //
+1 'to+2'
CWW-4
10.73
a�JOi%/0
9'
-6, 80
-2'to-1'
•
/I/
swW-5
10.80
A09
6'
-J• 9/
+1'to+2'
CWW-5
10.74
et$Y
9'
-S• /6
-2'to-1'
/1
sww.s
10.66
e.fo7'
6'
J. 99
+1 'to+2'
CW1N-6
9.92
0 ..29
9'
.7/
-2'to-1'
/✓
SwW-7
10.70
715-7
6'
/-5-7
+1'to+2'
CWW-7
9.95
8.90
9'
--.5:/
-2'to-1'
/1%
Revised 729/02
• Riser length added to TOC elevation 124/97
D:IDatalFormslWe1I Form\Tank Farm Remed Wellsads

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CPze1
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.n
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CUT-OFF WALLSVA,
4
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SWwa
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MWTF3
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e
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LOCATION PLAN FOR TANK FAIIM:
AREA REMEDIAL ACTION SYS I I M.
WELLS AND PIEZOMETFII-.:
FIGURE 1

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
October 2008 — January 2009
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Injection Water Well System
The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system
during the period.
Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs
Department. The total monthly and quarterly volumes of water injected as well as the month end water
level in the Water Level Control Tank are:
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
LEVEL
FEET, MSL
November
899,296
0
899,296
20.8
15.0
December
961,603
0
961,603
21.5
15.0
January
774,304
0
774,304
17.3
15.0
TOTALS
2,635,203
0
2,635,203
H:\Reports\TFRAS Report Fourth Quarter 2008.doc
3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
November
177,798
0
177,798
4.7
December
51,535
0
51,535
1.2
January
208,421
0
208,421
4.8
TOTALS
437,754
0
437,754
Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWW) Pumps
On 11/21 changed filters on compressor. On 12/22 the Air Compressor was shutdown for replacement.
The system is currently operating on plant air.
SWW-1:
SWW-2: On 11/18 reset pump. On 12/3 changed pump. On 12/11 changed counter. On 12/16 reset head.
On 12/19 changed counter. On 12/30 reset pump head. On 1/12 reset head.
SWW-3:
SWW-4: On 11/3 changed pump. On 11/18 reset head. On 11/20 changed pump. On 12/11 changed
pump. On 1/5 acid washed well. On 1/9 changed pump.
SWW-5: On 12/30 changed pump.
SWW-6:
SWW-7:
H:\Reports\TFRAS Report Fourth Quarter 2008.doc
4

Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1:
CWW-2:
CWW-3:
CWW-4:
CWW-5:
CWW-6:
CWW-7:
H:\Reports\TFRAS Report Fourth Quarter 2008.doc
5
4