WI0700012_Monitoring (Report)_20050209

PCS
Phosphate
AURORA
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27806
February 9, 2005
EVAN O. KANE
GROUND WATER
DENR
1636 MAIL SERVICE CENTER
RALEIGH, NC 27626-1636
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
November 2004 — January 2005
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Evan:
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTF 1 CR, b) piezometer level monitoring field sheet, and c) the summary operational and
maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
flLk,Q `W.4.vaket_0(
D. Daniel Winstead III
Environmental Engineer
PCS Phosphate
Attachments
Pc:
Annalee Harris — DWQ- GWS, WaRO (w/ attachments)
R. M. Smith/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
W. A. Schimming

E-Mail: M. D. Johnson
Doug Koeppen
R. B. Lee
H:\Reports\2005\Quarterly\TFRAS Report Fourth Quarter 2004.doc
2

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
November 2004 — January 2005
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Injection Water Well System
The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system
during the period.
Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs
Department. The total monthly and quarterly volumes of water injected as well as the month end water
level in the Water Level Control Tank are:
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
LEVEL
FEET, MSL
Nov
462,375
0
462,375
9.7
15.0
Dec
264,500
0
264,500
6.6
15.0
Jan
575,639
0
575,639
16.5
15.0
TOTALS
1,302,514
0
1,302,514
H:\Reports\2005\Quarterly\TFRAS Report Fourth Quarter 2004.doc
3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
Nov
359,390
107,463
466,853
10.8
Dec
323,314
76,953
400,267
9.3
Jan
299,497
118,653
418,150
9.5
TOTALS
1,153,651
303,069
1,285,270
Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWV) Pumps
SWW-1: On 11/1 flushed pump. On 11/2 changed counter. On 12/22 flushed pump. On 1/5 flushed
pump•
SWW-2: On 11/1 flushed pump. On 12/22 flushed pump. On 12/30 changed counter. On 1/5 flushed
pump•
SWW-3: On 11/1 flushed pump. On 12/22 flushed pump. On 1/5 flushed pump.
SWW-4: On 11/1 flushed pump. On 12/1 changed counter. On 12/22 flushed pump. On 1/5 flushed
pump. On 1/12 changed pump. On 1/18 repaired pump. On 1/25 changed counter. On 1/28 changed
counter. On 1/31 repaired pump.
SWW-5: On 11/1 flushed pump. On 12/22 flushed pump. On 1/5 flushed pump.
SWW-6: On 11/1 flushed pump. On 12/22 flushed pump. On 1/5 flushed pump.
SWW-7: On 11/1 flushed pump. On 11/4 changed pump. On 11/5 changed counter. On 12/22 flushed
R:\Reports\2005\Quarterly\TFRAS Report Fourth Quarter 2004.doc
4

pump. On 1/5 flushed pump.
Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1: On 11/1 flushed pump. On 11/18 repaired counter. On 12/6 flushed pump. On 12/22 flushed
pump. On 1/5 flushed pump.
CWW-2: On 11/1 flushed pump. On 12/22 flushed pump. On 1/5 flushed pump.
CWW-3: On 11/1 flushed pump. On 12/22 flushed pump. On 1/5 flushed pump.
CWW-4: On 11/1 flushed pump. On 12/16 flushed pump. On 12/22 flushed pump. On 1/5 flushed pump.
On 1/25 changed pump.
CWW-5: On 11/1 flushed pump. On 11/23 changed pump. On 12/22 flushed pump. On 1/5 flushed
pump.
CWW-6: On 11/1 flushed pump. On 11/18 flushed pump. On 11/29 changed pump. On 12/22 flushed
pump. On 1/5 flushed pump.
CWW-7: On 11/1 flushed pump. On 12/22 flushed pump. On 1/5 flushed pump.
H:\Reports\2005\Quarterly\TFRAS Report Fourth Quarter 2004.doc
5

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
County: Beaufort
Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
Well Identification Number (from Permit):
Well Depth: N/A ft. Well Diamter: N/A
Screened Interval: N/A ft. to N/A ft.
Depth to Water Level: N/A ft. below measuring point.
Measuring Point is N/A ft above land surface.
WLCT
For Groundwater Treatment
Sys ems Check One:
X Influent (98)
Effluent (99)
GALLONS of water pumped/bailed before sampling: CONTINUOUS
Field Analysis: pH 7.0 , Specific Conductance 532 uMhos
Temp. 16.2 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
EXPIRATION DATE:
UIC X
01/15/08
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
Certification No(s)
1/26/05
1/26/05 to 1/27/05
PCS PHOSPHATE and ENVIRONMENT 1
330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
2
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/I
mg/I
mg/I
mg/I
uMhos
mg/I
mg/I
Yes n/a No and field acidified
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
Yes n/a No )
N/A mg/I Ni - Nickel
N/A mg/I Pb - Lead
N/A mg/I Zn - Zinc
N/A mg/I Ammonia Nitrogen
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A
N/A
N/A
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
N/A mg/I Se- Selenium
N/A mg/I Sodium
N/A mg/I Organics: (GC, GC/MS, HPLC)
N/A mg/I (Specify test method #. Attach lab report.)
N/A mg/I Report attached? Yes (1) No X
N/A mg/I VOC : method#
N/A
N/A
N/A
N/A
N/A
N/A mg/I
: method#
method#
mg/I
mg/I
mg/I
mg/I
mg/I
ug/I
ug/I
ug/I
ug/I
(2)
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 03/2000
Ross M. Smith - Manager, Environmental Affairs
Perrn6tle f Autsoriz A nt a and Title - Plea
Signature of Permittee (or Auth zed Agent)
typeo pint
2//® /o
(Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
County: Beaufort
Telephone: [phone]
Well Locations/Site Name: Tank Farm
No. of Wells to be Sampled
3
Well Identification Number (from Permit):
Well Depth: 48.00 ft. Well Diamter:
CIW-7
4 inch
Screened Interval: 31.00 ft. to 45.25 ft.
Depth to Water Level: N/A ft. below measuring point.
Measuring Point is N/A ft above land surface.
GALLONS of water pumped/bailed before sampling:
Field Analysis: pH 7.0 , Specific Conductance 528 uMhos
For Groundwater Treatment
Sys ems Check One:
X Influent (98)
Effluent (99)
N/A
Temp. 16.1 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Remediation: Infiltration Gallery
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
Certification No(s)
1/26/05
1/26/05 to 1/27/05
PCS PHOSPHATE and ENVIRONMENT 1
330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
12
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
mg/I
/100m1
/100m1
N/A mg/1
N/A units
N/A mg/1 Ca - Calcium
N/A mg/I
N/A mg/I
N/A mg/I
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
Al - Aluminum
Ba - Barium
Cd- Cadmium
Chromium: Total
Cu - Copper
N/A mg/I Fe - Iron
N/A mg/I Hg - Mercury
N/A uMhos K- Potassium
N/A mg/I Mg - Magnesium
N/A mg/I Mn - Manganese
No and field acidified
Yes nla No )
N/A mg/I Ni - Nickel
N/A mg/I Pb - Lead
N/A mg/I Zn - Zinc
N/A mg/I Ammonia Nitrogen
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A
N/A
N/A
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
N/A mg/I Se- Selenium
N/A mg/I Sodium
N/A mg/I Organics: (GC, GC/MS, HPLC)
N/A mg/I (Specify test method #. Attach lab report.)
N/A mg/I Report attached? Yes (1) No X
N/A
N/A
N/A
N/A
N/A
N/A mg/I VOC
N/A mg/1
: method#
method#
method#
mg/I
mg/I
mg/I
mg/I
mg/I
ug/I
ug/I
ug/I
ug/I
(2)
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisionment for knowing violations.
NOTE:
GW-59 Rev 03/2000
.-
Per rYj to ofAuth�dri�ed
Ross M. Smith - Mana
r, Environmental Affairs
1t ,N,ame and Title -
A thorized
Agent) Signature of Permittee (or g )
print �/fD�,f
(Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled 3
Well Identification Number (from Permit): MWTF1-CR
Well Depth: 42.00 ft. Well Diamter: 2 inch
Screened Interval: 38.70 ft. to 40.70 ft,
Depth to Water Level: 11.60 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
GALLONS of water pumped/bailed before sampling: 139
For Groundwater Treatment
Systems Check One:
X Influent (98)
Effluent (99)
Field Analysis: pH 6.8 , Specific Conductance 674 uMhos
Temp. 19.1 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION. GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
EXPIRATION DATE:
UIC X
01 /15/08
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
Certification No(s)
1/26/06
1/26/06 to 1/27/05
PCS PHOSPHATE and ENVIRONMENT 1
330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A Nitrite (NO2 as N)
Coliform: MF Fecal N/A Nitrate (NO3 as N)
Coliform: MF Total 160 Phosphorus: Total as P
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mg/I
/100m1
/100m1
Orthophosphate
mg/I Al - Aluminum
units Ba - Barium
mg/I Ca - Calcium
mg/I Cd- Cadmium
mg/I Chromium: Total
mg/I Cu - Copper
mg/I Fe - Iron
mg/I Hg - Mercury
uMhos K- Potassium
mg/I Mg - Magnesium
mg/I Mn - Manganese
Yes n/a No and field
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/I
N/A mg/1
N/A mg/I
acidified
Ni - Nickel
Pb - Lead
Zn - Zinc
Ammonia Nitrogen
Yes n/a No )
N/A
N/A
N/A
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
Se- Selenium
N/A mg/I Sodium
N/A mg/I Organics: (GC, GC/MS, HPLC)
N/A mg/I (Specify test method #. Attach lab report.)
N/A mg/I Report attached? Yes (1) No X
N/A
N/A
N/A
N/A
N/A
N/A mg/I
N/A mg/I
VOC
method#
method#
method#
mg/I
mg/I
mg/I
mg/I
mg/I
ug/I
ug/I
ug/I
ug/I
(2)
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false informationincluding the possibility of fines and imprisionment for knowing violations.
NOTE:
GW-59 Rev 03/2000
Ross M. Smith - Manager, Environmental Affairs
Per to (o Au prize g nt) Name and Title Please ty or prin
z�.
Signature of Permittee (or'Authorized Agent)
(Date)

Date:
Time:
Tech:
PCS Phosphate Co., In • Tank Farm Remediation Im Quarterly Monitoring
�Q,QG
System Gauge Pressures
SWW-1
'�
SW W-7
0 - 6
,31
CWW-1
CWW-7
//)- /0
)962"
File: 12-07-02
pc: TLB
Recianc.
Point MSL
Laval Rol
to MBL
Ditch
12.91
76y
Barge Slip
10.59
Water Level
Control Tank
%=MSL
mot
/;o9
Sand Layer Pelzometers Level Indicators
Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
Level'
Level
Relative To
MSL Ft.
Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
Level'
Level
Relative To
MSL Ft.
Spz-1
10.47
S. 98
4.99
Cpz-1
10.51
/O. yy
0. 0 %
Spz-2
11.21
B 3D
3. 9/
Cpz-2
10.25
//. /6
- O. 9/
Spz-3
11.87
6. 76
-: / %
Cpz-3
11.12
/0. 6-9
0. S3
Spz-4
11.45
6.0er
..537
CPW
9.65
/0.O
- 0'87
Spz-5
11.45
I
Q.33
MWTF-1A•
14.35
4<&/
/Q. /r/
Spz-6
11.23
9.67
/.4 q
MWTF-1B•
14.36
y 83
9 5:1
Spz-7
11.59
9. 90
/,4q
MWTF-1C•
14.44
//•of,
cf. Bz!
Spz-8
11.57
9:74
/.1/
MWTF-2A
14.05
4- '/7
76:9
Spz-9
11.01
7 9-4
S. (04
MWTF-2B
14.02
/0- 76
Sc96,
Spz-10
12.16
6.of'P
S.90
MWTF-2C
14.08
/e/.93
-6%9S
SPW
9.95
'713
og52,
MWTF-3A
12.21
I.F.75
8 4/O3
MWTF-3B
12.18
9 94
G96
MWTF-3C
12.19
/.31/R
- A&3
Sand Layer And Croatan Formation Withdrawal Wells
Well ID
TOC
Elevation
MSL'
Max Stc
Wtr
Level Ft.
Pump
Activation Depth
Rel MSL
Max Level
Relative To
MSL Ft.
Control
Point
MSL'
Is Well
Pumping?
_(y9)es/(N)o
Comments
SWW-1
10.70
B. 70
6'
of. 9G
+1'to+2'
/
CWW-1
10.60
6. 015.
9'
o%b.S
-2'to-1'
Y
SWW-2
9.99
7 %/
6'
/. 9/
+1'to+2'
Y
CWW-2
10.23
9. 87
9'
0-87
-2'to-1'
a,
9.97
7 %/
6'
/ 7/
+1'to+2'
i
VW-3
CW-3
CV
9.95
6.97
9'
69-5/
-2'to-1'
pt
$1
SWW-4
10.73
6'
A 6 /
+1'to+2'
%
CWW-4
10.73
'7'/..5>'
9' .L5-a
9'
-1,4"€
-2'to-1'
SWW-5
10.80
%So?
6'
/Jof
+1'to+2'
;r
CWW-5
10.74
6-:0.3
9'
3'/9/7
-2'to-1'
I
S1AW-6
10.66
7 4/4
6'
/ VG
+1 to+2
CWW-8
9.92
a.41,
9'
-�.3/
-2'to-,'
SWW-7
10.70
7 O
6'
/ re
+1 'to+2'
CWW-7
9.95
‘.6-1-4/9/4/9
9'
-, -57
-2'to-1'
1
Revised 7/29/02
• Riser length added to TOC elevation 1/24/97
DAData1Forms\Well Foml\Tank Farm Reined Wellsads

'4.
-•
•
!