HomeMy WebLinkAboutWI0600074_Other Correspondence_201105263-D Microemulsion (3DMe)TM
MATERIALS SAFETY DATA SHEET
Last Revised: March 26, 2007
RECEIVED / DENR / DWQ
Aquifer Protection Section
MAY 26 2011
Section 1— Material Identification
Supplier:
c4)
REGENESIS
1011 Calle Sombra
San Clemente, CA 92673
Phone:
Fax:
E-mail:
949.366.8000
949.366.8090
info@regenesis.com
Chemical Name(s):
Chemical Family:
Trade Name:
Synonyms:
Product Use:
• Glycerides, di-, mono [2-[2-[2-(2-hydroxy- l -oxopropoxy)-1-oxopropoxyl]-1-
oxopropoxy]propanoates]
• Propanoic acid, 2-[2-[2-(2-hydroxy-1-oxopropoxy)-1-oxopropoxy]-1-
oxopropoxy]-I,2,3-propanetriyl ester
• Glycerol
Organic Chemical
3-D Microemulsion (3DMe)TM
HRC AdvancedTM HRC-PED (Hydrogen Release Compound — Partitioning
Electron Donor)
Used to remediate contaminated groundwater (environmental applications)
Section 2 — Chemical Identification
CAS#
823190-10-9
61790-12-3 or
112-80-1
201167-72-8
56-81-5
Chemical
HRC-PED
Fatty Acids (neutralized)
Glycerol Tripolylactate
Glycerol
Regenesis — 3-D Microemulsion MSDS
Section 3 — Physical Data
Melting Point: Not Available (NA)
Boiling Point: Not determined (ND)
Flash Point: > 200 °F using the Closed Cup method
Density: 0.9 -1.1 g/cc
Solubility: Slightly soluble in acetone. Insoluble in water.
Appearance: Amber semi -solid.
Odor: Not detectable
Vapor Pressure: None
Section 4 — Fire and Explosion Hazard Data
Extinguishing Media:
Use water spray, carbon dioxide, dry chemical powder or appropriate foam
to extinguish fires.
Water May be used to keep exposed containers cool.
For large quantities involved in a fire, one should wear full protective clothing and a NIOSH approved
self contained breathing apparatus with full face piece operated in the pressure demand or positive
pressure mode as for a situation where lack of oxygen and excess heat are present.
Section 5 — Toxicological Information
Acute Effects:
RTECS#
Irritation Data:
May be harmful by inhalation, ingestion, or skin absorption. May cause
irritation. To the best of our knowledge, the chemical, physical, and
toxicological properties of the 3-D Microemulsion have not been
investigated. Listed below are the toxicological information for glycerol,
lactic acid and fatty acid.
MA8050000
Glycerol
SKN-RBT 500 MG/24H MLD
EYE-RBT 126 MG MLD
EYE-RBT 500 MG/24H MLD
85JCAE-,207,1986
BIOFX* 9-4/1970
85JCAE-,207,1986
Regenesis — 3-D Microemulsion MSDS
c:EIVED / DENR / DWQ
Aquifer Protection Section
MAY 26 2011
Section 5 — Toxicological Information (cont)
Toxicity Data:
Target Organ Data:
ORL-MUS LD50:4090 MG/KG
SCU-RBT LD50:100 MG/KG
ORL-RAT LD50:12,600 MG/KG
IHL-RAT LC50: >570 MG/M3/1H
IPR-RAT LD50: 4,420 MG/KG
IVN-RAT LD50:5,566 MG/KG
IPR-MUS LD50: 8,700 MG/KG
SCU-MUS LD50:91 MG/KG
IVN-MUS LD50:4,250 MG/KG
ORL-RBT LD50: 27 MG/KG
SKN-RBT LD50: >10 MG/KG
IVN-RBT LD50: 53 MG/KG
ORL-GPG LD50: 7,750 MG/KG
FRZKAP (6),56,1977
NIIRDN 6,215,1982
FEPRA7 4,142,1945
BIOFX* 9-4/1970
RCOCB8 56,125,1987
ARZNAD 26,1581,1976
ARZNAD 26,1579,1978
NIIRDN 6,215,1982
JAPMA8 39,583,1950
DMDJAP 31,276,1959
BIOFX* 9-4/1970
NIIRDN 6,215,1982
JIHTAB 23,259,1941
Behavioral (headache), gastrointestinal (nausea or vomiting), Paternal
effects (spermatogenesis, testes, epididymis, sperm duct), effects of fertility
(male fertility index, post -implantation mortality).
Only selected registry of toxic effects of chemical substances (RTECS) data is presented here. See
actual entry in RTECS for complete information on lactic acid and glycerol.
Fatty Acids
Acute oral (rat) LD50 value for fatty acids is 10000 mg/kg. Aspiration of liquid may cause
pneumonitis. Repeated dermal contact may cause skin sensitization.
Section 6 — Health Hazard Data
One should anticipate the potential for eye irritation and skin irritation with large scale exposure or in
sensitive individuals. Product is not considered to be combustible. However, after prolonged contact
with highly porous materials in the presence of excess heat, this product may spontaneously combust.
Handling: Avoid continued contact with skin. Avoid contact with eyes.
In any case of any exposure which elicits a response, a physician should be consulted immediately.
First Aid Procedures
Inhalation:
Ingestion:
Remove to fresh air. If not breathing give artificial respiration. In case of
labored breathing give oxygen. Call a physician.
No effects expected. Do not give anything to an unconscious person. Call a
Regenesis — 3-D Microemulsion MSDS
physician immediately. DO NOT induce vomiting.
Section 6 — Health Hazard Data (cont)
Skin Contact:
Eye Contact:
Flush with plenty of water. Contaminated clothing may be washed or dry
cleaned normally.
Wash eyes with plenty of water for at least 15 minutes lifting both upper
and lower lids. Call a physician.
Section 7 — Reactivity Data
Conditions to Avoid: Strong oxidizing agents, bases and acids
Hazardous Will not occur.
Polymerization:
Further Information: Hydrolyses in water to form lactic acid, glycerol and fatty acids.
Hazardous Decomposition Thermal decomposition or combustion may produce carbon monoxide
Products: and/or carbon dioxide.
Section 8 — Spill, Leak or Accident Procedures
After Spillage or
Leakage:
Disposal:
Neutralization is not required. The material is very slippery. Spills should
be covered with an inert absorbent and then be placed in a container. Wash
area thoroughly with water. Repeat these steps if slipperiness remains.
Laws and regulations for disposal vary widely by locality. Observe all
applicable regulations and laws. This material may be disposed of in solid
waste. Material is readily degradable and hydrolyses in several hours.
No requirement for a reportable quantity (CERCLA) of a spill is known.
Section 9 — Special Protection or Handling
Should be stored in plastic lined steel, plastic, glass, aluminum, stainless steel, or reinforced fiberglass
containers.
Protective Gloves: Vinyl or Rubber
Eyes: Splash Goggles or Full Face Shield. Area should have approved means of
washing eyes.
Ventilation: General exhaust.
Storage: Store in cool, dry, ventilated area. Protect from incompatible materials.
Regenesis — 3-D Microemulsion MSDS
` vED I DENR I DWQ
aquifer Protection Section
MAY 28 2011
Section 10 — Other Information
This material will degrade in the environment by hydrolysis to lactic acid, glycerol and fatty acids.
Materials containing reactive chemicals should be used only by personnel with appropriate chemical
training.
The information contained in this document is the best available to the supplier as of the time of
writing. Some possible hazards have been determined by analogy to similar classes of material. No
separate tests have been performed on the toxicity of this material. The items in this document are
subject to change and clarification as more information becomes available.