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HomeMy WebLinkAboutWI0600074_Other Correspondence_201105263-D Microemulsion (3DMe)TM MATERIALS SAFETY DATA SHEET Last Revised: March 26, 2007 RECEIVED / DENR / DWQ Aquifer Protection Section MAY 26 2011 Section 1— Material Identification Supplier: c4) REGENESIS 1011 Calle Sombra San Clemente, CA 92673 Phone: Fax: E-mail: 949.366.8000 949.366.8090 info@regenesis.com Chemical Name(s): Chemical Family: Trade Name: Synonyms: Product Use: • Glycerides, di-, mono [2-[2-[2-(2-hydroxy- l -oxopropoxy)-1-oxopropoxyl]-1- oxopropoxy]propanoates] • Propanoic acid, 2-[2-[2-(2-hydroxy-1-oxopropoxy)-1-oxopropoxy]-1- oxopropoxy]-I,2,3-propanetriyl ester • Glycerol Organic Chemical 3-D Microemulsion (3DMe)TM HRC AdvancedTM HRC-PED (Hydrogen Release Compound — Partitioning Electron Donor) Used to remediate contaminated groundwater (environmental applications) Section 2 — Chemical Identification CAS# 823190-10-9 61790-12-3 or 112-80-1 201167-72-8 56-81-5 Chemical HRC-PED Fatty Acids (neutralized) Glycerol Tripolylactate Glycerol Regenesis — 3-D Microemulsion MSDS Section 3 — Physical Data Melting Point: Not Available (NA) Boiling Point: Not determined (ND) Flash Point: > 200 °F using the Closed Cup method Density: 0.9 -1.1 g/cc Solubility: Slightly soluble in acetone. Insoluble in water. Appearance: Amber semi -solid. Odor: Not detectable Vapor Pressure: None Section 4 — Fire and Explosion Hazard Data Extinguishing Media: Use water spray, carbon dioxide, dry chemical powder or appropriate foam to extinguish fires. Water May be used to keep exposed containers cool. For large quantities involved in a fire, one should wear full protective clothing and a NIOSH approved self contained breathing apparatus with full face piece operated in the pressure demand or positive pressure mode as for a situation where lack of oxygen and excess heat are present. Section 5 — Toxicological Information Acute Effects: RTECS# Irritation Data: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. To the best of our knowledge, the chemical, physical, and toxicological properties of the 3-D Microemulsion have not been investigated. Listed below are the toxicological information for glycerol, lactic acid and fatty acid. MA8050000 Glycerol SKN-RBT 500 MG/24H MLD EYE-RBT 126 MG MLD EYE-RBT 500 MG/24H MLD 85JCAE-,207,1986 BIOFX* 9-4/1970 85JCAE-,207,1986 Regenesis — 3-D Microemulsion MSDS c:EIVED / DENR / DWQ Aquifer Protection Section MAY 26 2011 Section 5 — Toxicological Information (cont) Toxicity Data: Target Organ Data: ORL-MUS LD50:4090 MG/KG SCU-RBT LD50:100 MG/KG ORL-RAT LD50:12,600 MG/KG IHL-RAT LC50: >570 MG/M3/1H IPR-RAT LD50: 4,420 MG/KG IVN-RAT LD50:5,566 MG/KG IPR-MUS LD50: 8,700 MG/KG SCU-MUS LD50:91 MG/KG IVN-MUS LD50:4,250 MG/KG ORL-RBT LD50: 27 MG/KG SKN-RBT LD50: >10 MG/KG IVN-RBT LD50: 53 MG/KG ORL-GPG LD50: 7,750 MG/KG FRZKAP (6),56,1977 NIIRDN 6,215,1982 FEPRA7 4,142,1945 BIOFX* 9-4/1970 RCOCB8 56,125,1987 ARZNAD 26,1581,1976 ARZNAD 26,1579,1978 NIIRDN 6,215,1982 JAPMA8 39,583,1950 DMDJAP 31,276,1959 BIOFX* 9-4/1970 NIIRDN 6,215,1982 JIHTAB 23,259,1941 Behavioral (headache), gastrointestinal (nausea or vomiting), Paternal effects (spermatogenesis, testes, epididymis, sperm duct), effects of fertility (male fertility index, post -implantation mortality). Only selected registry of toxic effects of chemical substances (RTECS) data is presented here. See actual entry in RTECS for complete information on lactic acid and glycerol. Fatty Acids Acute oral (rat) LD50 value for fatty acids is 10000 mg/kg. Aspiration of liquid may cause pneumonitis. Repeated dermal contact may cause skin sensitization. Section 6 — Health Hazard Data One should anticipate the potential for eye irritation and skin irritation with large scale exposure or in sensitive individuals. Product is not considered to be combustible. However, after prolonged contact with highly porous materials in the presence of excess heat, this product may spontaneously combust. Handling: Avoid continued contact with skin. Avoid contact with eyes. In any case of any exposure which elicits a response, a physician should be consulted immediately. First Aid Procedures Inhalation: Ingestion: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen. Call a physician. No effects expected. Do not give anything to an unconscious person. Call a Regenesis — 3-D Microemulsion MSDS physician immediately. DO NOT induce vomiting. Section 6 — Health Hazard Data (cont) Skin Contact: Eye Contact: Flush with plenty of water. Contaminated clothing may be washed or dry cleaned normally. Wash eyes with plenty of water for at least 15 minutes lifting both upper and lower lids. Call a physician. Section 7 — Reactivity Data Conditions to Avoid: Strong oxidizing agents, bases and acids Hazardous Will not occur. Polymerization: Further Information: Hydrolyses in water to form lactic acid, glycerol and fatty acids. Hazardous Decomposition Thermal decomposition or combustion may produce carbon monoxide Products: and/or carbon dioxide. Section 8 — Spill, Leak or Accident Procedures After Spillage or Leakage: Disposal: Neutralization is not required. The material is very slippery. Spills should be covered with an inert absorbent and then be placed in a container. Wash area thoroughly with water. Repeat these steps if slipperiness remains. Laws and regulations for disposal vary widely by locality. Observe all applicable regulations and laws. This material may be disposed of in solid waste. Material is readily degradable and hydrolyses in several hours. No requirement for a reportable quantity (CERCLA) of a spill is known. Section 9 — Special Protection or Handling Should be stored in plastic lined steel, plastic, glass, aluminum, stainless steel, or reinforced fiberglass containers. Protective Gloves: Vinyl or Rubber Eyes: Splash Goggles or Full Face Shield. Area should have approved means of washing eyes. Ventilation: General exhaust. Storage: Store in cool, dry, ventilated area. Protect from incompatible materials. Regenesis — 3-D Microemulsion MSDS ` vED I DENR I DWQ aquifer Protection Section MAY 28 2011 Section 10 — Other Information This material will degrade in the environment by hydrolysis to lactic acid, glycerol and fatty acids. Materials containing reactive chemicals should be used only by personnel with appropriate chemical training. The information contained in this document is the best available to the supplier as of the time of writing. Some possible hazards have been determined by analogy to similar classes of material. No separate tests have been performed on the toxicity of this material. The items in this document are subject to change and clarification as more information becomes available.