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HomeMy WebLinkAboutWI0600071_Other Correspondence_20110224ADV£NTUS 1 Proven Soil, Sediment, and Groundwater �I Remediation Technologies Safet, Data MATERIAL SAFETY DATA SHEET: EHC® Page: 1 of 3 1. PRODUCT IDENTIFICATION: PRODUCT USE: EHC® Bioremediation product for the remediation of contaminated soil and groundwater only. Not for use in potable drinking water. MANUFACTURER: EMERGENCY PHONE: Adventus Americas Inc. Office Hours: 815-235-3503 2871 W. Forest Rd, Suite 2 After Hours: 630-309-1175 Freeport, IL 61032 TRANSPORTATION OF DANGEROUS GOOD CLASSIFICATION: Not Regulated WHMIS CLASSIFICATION: Not Regulated CONTAINMENT HAZARD: Any vessel that contains wet EHC or EHC and water must be vented due to potential pressure build up from fermentation gasses. 2. INGREDIENTS CHEMICAL NAME: CAS# TLV (mg/m3) LD low (mg/Kg) % in Product Organic Amendment N/D N/E N/E 52 - 82 Iron 7439-89-6 5 (as iron oxide fume) N/E 18 - 48 3. PHYSICAL DATA Physical state Solid Melting point 1371-1480°F Odour threshold N/A Boiling point 3000°C Density, 0.80 Kg/L Vapour pressure (nun Hg) 1 @ 1787°C pH 5.6 Vapour density (air=1) N/A Solubility in water Insoluble Evaporation rate N/A Coeff. of water/oil N/A Appearance & odour Tan/Grey Powder, Odourless 4. FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Deg. C PMCC): N/A FLAMMABLE LIMITS IN AIR % BY VOLUME: AUTO IGNITION TEMP (Deg. C): LOWER UPPER N/A N/A N/A rrAADVENTUS 1116N` Proven Soil, Sediment, and Groundwater Remediation Technologies MATERIAL SAFETY DATA SHEET: EHC® Page: 2 of 3 EXTINGUISHING MEDIA: Dry chemicals or sand or universal type foam. SPECIAL PROCEDURES: Firefighters should wear SCBA and protective clothing. UNUSUAL FIRE AND EXPLOSION HAZARDS: Dust can present fire and explosion hazards when exposed to fire, chemical reaction, or contact with powerful oxidizers. 5. REACTIVITY DATA STABILITY (NORMAL COND.): Stable: X Unstable: CONDITIONS TO AVOID: INCOMPATIBILITY (Materials to Avoid): HAZARDOUS DECOMPOSITION PRODUCTS: 6. TOXICOLOGICAL PROPERTIES ROUTE OF ENTRY: Inhalation Ingestion (not likely) HEALTH HAZARDS: Contact with powerful oxidizers such as strong acids. Powerful oxidizers such as strong acids. Hydrogen, Carbon monoxide, Carbon dioxide. Acute overexposure may cause eye, nose, mouth and skin irritation. Carcinogenicity: No Information Available Signs and Symptoms of Exposure: No Information Available Medical Conditions Generally Aggravated by Exposure: No Information Available 7. PREVENTIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Eye Protection: X Gloves: X Clothing: RESPIRATORY PROTECTION: Use dust mask in severe conditions. rAN ADVENTUS `sole Proven Soil, Sediment, and Groundwater Remediation Technologies Safet Data MATERIAL SAFETY DATA SHEET: EHC° Page: 3 of 3 Use good housekeeping practices to keep dust to a minimum. VENTILATION REQUIREMENTS: Not normally required. SPILL AND LEAK PROCEDURES: Sweep up and return to container. WASTE DISPOSAL: Sanitary landfill. Follow Federal, State and Local guidelines. HANDLING PROCEDURES: Wear safety glasses for normal use. Avoid generating excessive dust, wear dust mask in severe conditions. STORAGE REQUIREMENTS: Do not store near powerful oxidizers such as strong acids. Keep dry. Any vessel that contains wet EHC or EHC and water must be vented due to potential pressure build up from fermentation gasses. SPECIAL HANDLING INFORMATION: Treat as a nuisance dust 8. FIRST AID MEASURES INHALATION: Remove to fresh air. Seek medical attention. INGESTION: Seek medical attention. SKIN CONTACT: Brush off excess. Wash with soap and water. EYE CONTACT: Flush with running water. Seek medical attention. 9. OTHER INFORMATION None 10. PREPARATION INFORMATION Prepared By: Adventus Remediation Technologies Date PrepJRev.: 12/4/09 1345 Fewster Drive Print Date: 12/4/09 Mississauga, Ontario Phone: 905-273-5374 L4W 2A5 Fax: 905-273-4367 Definitions: N/D - No Data N/A - Not Applicable N/E - Not Established EHC' is a registered trademark of Adventus Intellectual Property Inc. Product Name, ATOMET 414 -�ormt (i/ X P ( rade Name Supplier Synonym QUEBEC METAL POWDERS Ltd. 450-746-5050 MaterL .1 Safety Data Sheet K rotTJ irircaIrtftrc&,dr Code QMP-2-2933 CAS# 7439-Fst6 DSL Not applicable. Reduced Iron Powder. CI# Not available. EINECS# Not applicable. Chemiral Name NA Chemical Family Metals. rChcmnlcal Formula Fe amavvs>.••.•. 450-748-5050 hlanufacturer Quebec Metal Powders Ltd. 1655 Marie-Viclorin, Sorel -Tracy, Quebec, Canada. J3R 4R4 Tel: 450-746-5050 Material Uses Powdered memilurgy. 'Si `tturrP:Ik'CODJirGSS Op cei)Lt109Y/lfrdt/p ,t 40 ,,Y,3 Exposure Limits Name CAS# TWA STEL C.r'.11, % by Weight 'Iron 7439-89-6 15 mg/m3 NA --{ NA 1100 pToxicological Data .. on Ingredients This product has not been tested as a whole for ail potential health effects. ,-, Sectigt Jib: Haag. ag. Pote❑tial Acute Health Effects -Inhalation: over -exposure by inhalation may cause respiratory irritation. -This product may irritate eyes (conjunctivitis, retinae) and skin upon contact. -Ingestion: not a normal exposure route, but could induce gastric problem. Potential Chronic Health Repeated inhalation of dust can produce varying degrees of respiratory irritation. Effects LLL� ,`.' Secfrolr tV 'F0 Eye Contact Skin Contact Wash gently and thoroughly the contaminated skin with running water and non-abrasive soap. Get medical attention if irritation persists. € assures,, Check for and remove any contact lenses. IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention. v' Hazardous Skin Contact Seek medical attention. ' ff7nhalatimr � Hazardooa Inhalation Allow the victim to rest in a well ventilated area. Seek medical attention if breathing difficulties persist. Seek medical attention. tit Ingestion Haz: wdoas 1 ag stion Flave conscious person drink several glasses of water or milk. DO NOT INDUCE VOMITING. Seek medical t attention. Seek medical attention. Tetnianeys ATOMET 414 uz H Engineering Controls V.SF.CtfOR gFff£` /d R",yf�PO4¢0gP,d, '' 1. Asa ,_ W T Pr- ,,. ::.' - s'• The Product is: Non-flammable. SEE SPECIAL REMARKS ON FIRE HAZARDS. lute -Ignition Temperature Not applicable. ,Flash Points This material does not burn or give a flash point by conventional test methods. Flammable Limits No data. Products of Combustion Some metallic oxides. Fire Hazards in Presence of No data. Various Substances Explosion Hazards in Presence Non explosive under normal conditions. of Various Substances Fire Fighting Media Do not use Foam or carbon dioxide. USE A FOG NOZZLE to spray water. and Instructions Special Remarks on As with any finely granulated product (i.e flour) a risk of fire is present should the msterial be dispersed in air , Fire Hazards and exposed to a source of ignition. Fine powder forms flammable and explosive mixtures in air. Special Remarks on Explosion No additional remarks. Hazards - ?S Zfert: Small Spill Large Spill Per O e��� , No special procedures are required for clean-up of spills or leaks of this material. Avoid methods that result in water pollution. No additional information in case of a spill and/or a leak of the product. Use a shove; to put the material into a convenient waste disposal container. SadtiOp Precautions slot, Avoid contact with skin and eyes. Do not breathe dust. Do not ingest. Storage Do not store in unlabelled containers. Empty containers may contain product residue. Do not reuse without i adequate precautions. 17 eelrl i(F3: Expos igeH0 JJarrrfs Persona. f fec(ior Use process enclosures, local exhaust ventilation, or other engineering controis to keep airborne level recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure of airborne contaminants below the permissible limits. Personal Protection Wear safety glasses or chemical goggles. Wear protective clothing. Use approved respiratory protection when airbome exposure limits are exceeded. Protective Clothing Personal Protection in Case of No more data. a Large Spill Exposure Limits TWA (1997): 15 mg/m3 - OSHA, for total dust base on Particulates Not Otherwise Regulated (PNOR). ' ATONET 414 # 3 j saZ• Q. to !sf t ,ti `.-v '^Y`itYn ^5='i7.n"Y,"".+... k r lk Lk 04 Noet t�#� " Y ��t)t Physical State and )ppearance Granular powder. Odor Odorless. Taste Not available. Molecular Weight Not applicable. Color Gray. pH (I%sole/water) Not applicable. Boiling Point 2750.0 C (4982F) for Iron. Melting Point 1535 C (2795 F) for Iron. Critical Temperature Not applicable. Specific Gravity 7.8 (Water = 1) for Iron. Vapor Pressure Not available. Vapor Density Not available. Volatility Not available. Odor Threshold Not applicable. Water/Oil Dist. Coeff. Not available. tonicity (in Water) Not available. Dispersion Properties Not available. Solubility Insoluble in cold or hot water. . dif t 401 i{�/� kf):4111 d[3` y' ?� i.`7b"M�z:r; Y` 5'°t , 4 s( e,"', � %4s r�t12 r " � �1 Stability Instability Temperature \ !onditions of Instability The product is stable. Not applicable. Stable. • Incompatibility with various substances Avoid contact with oxidizers and reducing agents. Corrosivity No data. Special Remarks on Reactivity Special Remarks on Corrosivity No additional remarks. No additional remarks. eia,MIT �R Ric 1 IZ ° . ;. ., r t} i t� � � , � � .. ���i , y1i}� 4`,� i.�'..-. ,..?S n:3ek' .�,1,. P Routes of Entry Ingestion, Inhalation. 11 Toxicity to Animals LD50: 30 gm/kg. Oral -Rat for iron powder -325 mesh. Chronic Effects on Humans I Other Toxic Effects bon Humans Repeated inhalation of dust can produce varying degrees of respiratory irritation. -Inhalation: over -exposure by inhalation may cause respiratory irritation. -This product may irritate eyes (conjunctivitis, retinae) and skin upon contact. -Ingestion: not a normal exposure route, but could induce gastric problem. f, Special Remarks on Toxicity to Animals Special Remarks on )hronic Effects on Humans Special Remarks on ; Other Toxic Effects on Humans Iron: LDLo (lowest published lethal dose) = 20 mglkg , intraperitoneal - rabbit. No additional remarks. No additional remarks. ;;a1W. E14�4 tf4 / I ^ (� (�1'QN�0 () Y �`r-KT'rL� L £ZSf '.a���5rv.*A. 3S, — ... F ,rcY4' RZd �}' i{" 4 IA,av'"1.:'Ps -� 11��- V u cL -�' k . P —c «r, y ,@� ,¢-. ""+�+MF i � N '{I � ylt,x... ri: � i .. ii, -.iG�l T f 1 : 'R' {N'{ � -i9, {SKY E:: �� L P ...r Icotoxicity Not available. —, BODS and COD No data. Products of Biodegradation No data. Toxicity of the Products No data. of Biodegradation l'Special Remarks on the No additional remarks. Products of Biodegradation #po Waste Disposal Consult your local or regional authorities. rU+ti' ,+. ar tc r £ zu.r TaiP"' :r -ev4 !+, rut+4y'iJf✓.yxKY'vu;''rR Yam. i,'hfan 1 �r�§ec�f�r?��;�1�a1n�.�t�ii� a;°?`+,r� �e..��+'rs:�,!`�_� , r ti � TDG Classification Not controlled under TDG (Canada). Not applicable. DOT Classification Not a DOT controlled material (United States). Not applicable. )DR Classification Not controlled under ADR of the EEC. None. Environmentally hazardous substance n.o.s. PG: Special Provisions for Transport in Canada No additional remarks. ' Special Provisions for Transport in the States No additional remarks. ' Special Provisions for Transport in Europe No additional remarks. +✓ ti sc, 1'.n T "r•'. h E ^Kx'? �lpith".'u"'x:^k^. y'p ii .srs"r' c. +� .. _ V �. t. r ¢5I pvi ilY 0-74. !_ O he , CC�j w1E1IIf€eP. Af�r!I 110it'keib Am.. it'.r+>�lFt P`"""=4' r. ,'"P. ki .: 6p ir.�; :..,r,� WHMIS (Canada) Not WHMIS (Canada) (Pictograms) controlled under WHMIS(Canada). NFPA (U.S.A.) FIRE HAZARD q HEALTH I `I`f-1d" REACTIVITY SPECIFIC HAZARD it DSCL (EEC) Not controlled underl(DSCL �xC i ip; �yy,{k ie M { j,\,C(44 iv Si "'4q R ,�gO�IfIIiUCI�R�Xt�'i✓�s.�`$.F�,.�' `�..�,+!`vl ATOMET 414 #5 �DSCL (EEC) (Pictograms) �'-+' :T. Mkt s i'u Rkr ,tmotttnickonstsa, „.., it-, w € '""' " t'C 2 :r" References SAX, N.I. Dangerous Properties of Industrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. ' Guide to Occupationnal Exposure Values, ACGIH 1997. ACGIH, threshold limit values for chemical substances and physical agents and biological exposure Indices, 1997. Chemical hazard communication guidebook, OSHA, EPA and DOT requirements, second edition, 1993. SARA TITLE III: Hazardous Chemicals and The Right to Know, 1993. Official Journal of the European Communities L180. PEL-OSHA, Table Z-1 & Z-3, limits of air contaminants 08/1997. !Other Special Rev. 0 Considerations Validated by Service d'hygiene industrielle on 22-06-05. by Service d'hygI ne Industrielle. (Verified Printed 22-06-05. Information Contact QUEBEC METAL POWDERS Ltd. 450-746-5050 Notice to Reader Mr any of its subdmurie any llabfU wbowane;for Ou accuracy emplelenerafthe in/nation rovaL,m hazards and aboard be used wit raObn Ahbn.gh ealaln hazenfruo- f,xnihed hen in mgonowee 6m To the beg Gloat knowledge, the IN n,mon eunoted herein it accurate. Hawvvn. neither the above named supplier �e benht blaal danmfnotkVV stiffly along mmend la theaf ,e on,ibitgo of eke wen All manle& mwypre,ent unknown 1 lbmeareIkeenly haurG that aba