WI0700012_Monitoring (Report)_20030528 (2)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
County: Beaufort
Contact Person: Jimmy Hardy Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Well Identification Number (from Permit):
Well Depth: 42.00 ft. Well Diamter:
Screened Interval: 38.70 ft. to 40.70 ft.
Depth to Water Level: 10.21 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
MILILITERS of water pumped/bailed before sampling:
MWTF1-CR
2 inch
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
2100
Field Analysis: pH 7.3 , Specific Conductance 626 uMhos
Temp. 21 oC, Odor NONE Appearance: CLDY LT YELLOW
Mail Original
to:
DIVISION OF WATER QUALITY
GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT
P.O. BOX 29578
RALEIGH, NC 27626-0578 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Ca
Lagoon Remediation: Infiltration GalAdy
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor
Other
Land Application of Sludge ill
(A)
Note: Values should reflect dissolved and 'v
colloidal concentrations
Date sample collected: 4/22/03
Date sample analyzed: 4/22/03 to 5/21/03
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered X Yes
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
<1.0
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
472
7.2
7.9
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
14.0
N/A
N/A
N/A
24.9
N/A
N/A
N/A
mg/I
/100m1
/100m1
mg/1
units
mg/I
mg/I
mg/I
mg/I
mg/I
mg/I
uMhos
mg/I
mg/I
Nitrite (NO2 as N)
Nitrate (NO3 as N)
No and field
N/A mg/I
N/A mg/I
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
0.354 mg/I
acidified X Yes No )
Ni - Nickel
Pb - Lead
Zn - Zinc
N/A mg/I Ammonia Nitrogen
N/A mg/I
N/A mg/I
N/A mg/I
<0.001 mg/I
<0.005 mg/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
N/A� ug/I
N/A ug/I
l/A � 51/1
cog/I
0.131
11171
Se- Selenium N/P mi l:
N/A mg/I Sodium N/A. u
N/A mg/I Organics: (GC, GC/MS, HPLC) N
N/A mg/I (Specify test method #. Attach lab report.)
N/A mg/1 Report attached? Yes (1) No X (2)
N/A mg/I VOC
0.063 mg/I
method#
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisionment for knowing violations.
NOTE:
GW-59 Rev 4/98
Terry L. Baker - Manager, Environmental Affairs
Permittee (of Authorized Agpgt) I'me and Title - Please type or prin
ignatur ermittee (or Authorized Agent)
D?te)

CS 1 2 3 0Et

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
County: Beaufort
Contact Person: Jimmy Hardy Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18
Well Identification Number (from Permit): CIW-7
Well Depth: 48.00 ft. Well Diamter:
4 inch
Screened Interval: 31.00 ft. to 45.25 ft.
Depth to Water Level: N/A ft. below measuring point.
Measuring Point is N/A ft above land surface.
MILILITERS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
N/A
Field Analysis: pH 7.3 , Specific Conductance 589 uMhos
Temp. 19.2 oC, Odor NONE
Appearance: CLEAR
Mail Original
to:
DIVISION OF WATER QUALITY
GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT
P.O. BOX 29578
RALEIGH, NC 27626-0578 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
EXPIRATION DATE:
UIC X
01/15/08
Lagoon
Spray Field
Rotary Distributor
Other
Remediation: Infiltration Galle
X Remediation :
Land Application of Sludge
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 4/22/03
Date sample analyzed: 4/22/03 to 5/21/03
Laboratory Name:
Certification No(s) 330 10
PCS PHOSPHATE and ENVIRONMENT 1
PARAMETERS: (Samples for metals were collected unfiltered X Yes
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
<1.0
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 436
pH (when analyzed) 7.1
TOC 7.8
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
15.0
N/A
N/A
N/A
<10.0
N/A
N/A
N/A
mg/l Nitrite (NO2 as N)
/100m1 Nitrate (NO3 as N)
/100m1
mg/I
units
mg/I Ca - Calcium
mg/I
mg/I
mg/I
mg/I
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
mg/I Hg - Mercury
uMhos
mg/I
mg/I
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified
N/A mg/I
N/A mg/I
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
0.057 mg/I
<0.001 mg/I
<0.005 mg/I
X Yes No )
Ni - Nickel
Pb - Lead
Zn - Zinc
N/A mg/I Ammonia Nitrogen
N/A mg/I Other (Specify Compounds and Concentration Units)
N/A mg/I Fluoride
N/A mg/I MIBK
Ag - Silver
Se- Selenium
N/A mg/I Sodium
N/A mg/I Organics: (GC, GC/MS, HPLC)
N/A mg/I (Specify test method #. Attach lab report.)
N/A mg/1 Report attached? Yes (1) No X (2)
N/A ug/I
N/A mg/I VOC
<0.010 mg/I
method#
method#
method#
I certify that. to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisionment for knowing violations.
NOTE:
GW-59 Rev 4/98
Terry L. Baker - Manager, Environmental Affairs
Permittee(of Authorized Agen). f' ante and Title - Please type or print
//attire
gnature
ermittee (or Authorized Agent)
U ;

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jimmy Hardy Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Well Identification Number (from Permit): WLCT
Well Depth:
Screened Interval:
N/A ft. Well Diamter: N/A
N/A ft. to N/A ft.
Depth to Water Level: N/A ft. below measuring point.
Measuring Point is N/A ft above land surface.
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
GALLONS of water pumped/bailed before sampling: CONTINUOUS
Field Analysis: pH 7.2 , Specific Conductance 591 uMhos
Temp. 19.5 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DIVISION OF WATER QUALITY
GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT
P.O. BOX 29578
RALEIGH, NC 27626-0578 Phone: [phone]
PERMIT #: WI0700012 EXPIRATION DATE:
01/15/08
Non -Discharge UIC X
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED w
Lagoon Remediation: Infiltration Gamy
Spray Field X Remediation : U7
Rotary Distributor Land Application of Sludge (4
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
Certification No(s)
4/22/03
4/22/03 to 5/21/03
PCS PHOSPHATE and ENVIRONMENT 1
330 10
PARAMETERS: (Samples for metals were collected unfiltered X Yes
COD
Coliform: MF Fecal
Coliform: MF Total
(Note.
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
<1.0
Use MPN method for highly turbid samples)
436
7.2
8.2
12.8
N/A
N/A
N/A
<10.0
N/A
N/A
N/A
mg/I Nitrite (NO2 as N)
/100m1 Nitrate (NO3 as N)
/100m1 Phosphorus: Total as P
mg/I
units
mg/I Ca - Calcium
mg/I
mg/I
mg/I
mg/I
mg/I
uMhos
mg/I
mg/I
Orthophosphate
Al - Aluminum
Ba - Barium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
No and field acidified X Yes No )
N/A mg/I Ni - Nickel N/ ug/I
N/A mg/I Pb - Lead c ,N/A , j g/I
0.034 mg/I Zn - Zinc t,�N/A /1
N/A mg/I Ammonia Nitrogen G— �=f /I
N/A mg/1 Other (Specify Compounds and Concentration Units) 1 a rn
N/A mg/I Fluoride e49 41,ag,!I
N/A mg/I MIBK1-r191
_
<0.001 mg/I Ag - Silver r(al l
<0.005 mg/I Se- Selenium N) rreil
N/A mg/I Sodium N/,j ugh
N/A mg/I Organics: (GC, GC/MS, HPLC)
N/A mg/I (Specify test method #. Attach lab report.)
K- Potassium
Mg - Magnesium
Mn - Manganese
N/A mg/I Report attached? Yes (1) No X (2)
N/A mg/I VOC : method#
<0.010 mg/I : method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisionment for knowing violations.
NOTE:
GW-59 Rev 4/98
Terry L. Baker - Manager, Environmental Affairs
(of Author n Name and Title - Please type or print ,
ermittee or Authorized Agent) (Da el
Signatur {

PCS Phosphate Co., Inc. - Tank Farm Remediation System Quarterly Monitoring
Date: 0V-03
Time:
Tech:
14/(3.G PG
System Gauge Pressures
sww-1
O-/V
SWW-7
,a);
0-/RP.s;
0-/%1As'
CWW-1
CWW-7
C.- 9vsi
File: 12-07-02
pc: TLB
Referents
Point MSL
Level Rel
to MSL
Ditch
Barge Slip
Water Level
Control Tank
%= MSL
12.91
10.59
8o%
7• 4/7
97
/393
Sand Layer Peizometers Level Indicators
Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
Level'
Level
Relative To
MSL Ft.
Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
Level'
Level
Relative To
MSL Ft.
Spz-1
10.47
35 0
6. 6 7
Cpz-1
10.51
9 /4/
AP/
Spz-2
11.21
7 By
3 37
Cpz-2
10.25
/12.6o
-C.3✓C
Spz-3
11.87
aJ 7a
.O. /.J
Cpz-3
11.12
9, 92-
/&o
Spz-4
11.45
G. 40
505
CPW
9.65
/0.a7
- O. (pp5
Spz-5
11.45
8 90
a5S
MWTF-1A•
14.35
440E
9,95"
Spz-6
11.23
8 9/
a.3?
MWTF-1B •
14.36
y3 0
9`
Spz-7
11.59
/0.05
/5y
W MTF-1C•
14.44
/0. ?/
/Bl
'7•/7,
Spz 8
11:57-
-?-4j--5:d01
}'
MWTF 2A-
14.05
. '. (pL
%-i//
Spz-9
11.01
797
5 0V
MWTF-28
14.02
/0• 76
5-a6,
Spz-10
12.16
vJ 53
Lam. 63
W MTF-2C
14.08
/I/ 30
-,po7a
SPW
9.95
7VS/
dZ,57
MWTF-3A
12.21
5 9'7
gale
MWTF-38
12.18
9.86
Se
MWTF-3C
12.19
/ 8 , oa
-.0 83
Sand Layer And Croatan Formation Withdrawal Wells
Well ID
TOC
Elevation
MSL'
Max Stc
Wtr
Level Ft.
Pump
Activation Depth
Rel MSL
Max Level
Relative To
MSL Ft.
Control
Point
MSL'
Is Well
Pumping?
(Y)es/(N)o
Comments
swW-1
10.70
723
6'
/O23
+1'to+2'
yL'f
CVVW-1
10.60
6..85
9'
-a. /S
-2'to-1'
ys
SWW-2
9.99
76 /
6'
/ 6'7
+1'to+2'
re
CWW-2
10.23
73Z
9'
/48
-2 ' to-1'
SWW-3
9.97
.1 .52
6'
ta 5-a
+1 ' to+2'
/Pei
ylS
CWW-3
9.95
7./y
9'
-/ Be,
-2 ' to-1'
yes
SWW-4
10.73
7, GB
6'
/ 68
+1'to+2'
CWW-4
10.73
7027
9'
_/ '73
-2'to-1'
/
SwW-5
10.80
7, 60
6'
/6C
+1'to+2'
yes
y43
CWW-5
10.74
7 07
9'
-/, Cf3
-2'to-1'
free
SWW-6
10.66
7 93
6'
/ 9/_ '
+1. to +2'
yes
W CW-6
9.92
7, 35
9'
- y.6
-2' to-1'
743
SWW-7
10.70
7a/
6'
/.=2l
+1' to+2'
yes
CWW-7
9.95
6.48
9'
- . 9'Z
-2'to-I'
yea
Revised 7/29/02
' Riser length added to TOC elevation 1/24/97
DAD talFormslWell FormlTank Farm Remed Wells.xis

PCS
Phosphate AURORA
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27808
May 20, 2003
EVAN O. KANE
GROUND WATER
DENR
1636 MAIL SERVICE CENTER
RALEIGH, NC 27626-1636
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
February 2003 — April 2003
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Evan:
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTF1CR, b) Form GW-59 for each of the fourteen withdrawal wells, c) Form GW-59 for
monitor wells MWTF1A and MWTF1B, d) Form GW-59 for the WLCT, e) piezometer level monitoring
field sheet, and f) the summary operational and maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
D. Daniel Winstead III
Environmental Engineer
PCS Phosphate
Attachments
pc: Willie Hardison — DWQ- GWS, WaRO (w/ attachments)
T. L. Baker/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
W. A. Schimming

E-Mail: S. A. Beckel
J. A. Hardy / R. B. Lee
C:\MyData\Reports\2003\Quarterly\TFRAS Report First Quarter 2003.doc
2

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
February 2003 — April 2003
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Injection Water Well System
The injection water well system operated with the DPW Water - Anthracite Sand Filter / Ultraviolet Light
(ASF/UV) disinfection system throughout the period.
Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs
Department. The total monthly and quarterly volumes of water injected as well as the month end water
level in the Water Level Control Tank are:
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
LEVEL
FEET, MSL
Feb
576,210
0
576,210
14.3
12.9
March
585,580
0
585,580
13.1
13.1
April
521,290
0
521,290
12.1
14.3
TOTALS
1,683,080
0
1,683,080
C:\MyData\Reports\2003\Quarterly\TFRAS Report First Quarter 2003.doc
3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
Feb
398,021
126,900
524,921
13.5
March
456,527
160,772
617,299
15.3
April
411,287
155,230
566,517
13.1
TOTALS
1,265,836
442,902
1,708,738
Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWW) Pumps
SWW-1: On 2/5 shook pump to start. On 4/1 shook pump to start. On 4/14 changed pump.
SWW-2:
SWW-3:
SWW-4: On 3/12 shook pump to start. On 3/17 changed pump. On 4/4 shook pump to start.
SWW-5: On 4/4 shook pump to start. On 4/14 changed pump.
SWW-6: On 4/3 shook pump.
SWW-7: On 2/10 shook pump. On 2/18 pulled pump and cleaned well. On 3/10 changed pump. On 3/19
acid washed well.
C:\MyData\Reports\2003\Quarterly\TFRAS Report First Quarter 2003.doc
4

Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1: On 2/12 changed pump and cleaned well. On 3/10 changed pump.
CWW-2: On 2/4 cleared well with air. On 2/5 changed counter.
CWW-3:
CWW-4:
CWW-5:
CWW-6:
CWW-7: On 4/22 acid washed well. On 4/24 changed pump.
C:\MyData\Reports\2003\Quarterly\TFRAS Report First Quarter 2003.doc
5