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HomeMy WebLinkAboutWI0700012_Corrective Action Plan_198911061 • Supplemental Remedial Action Plan Tank Farm Area Texasgulf Inc. Phosphate Operations Aurora, North Carolina Ardaman & Associates, Inc. OF=:C7=S WgSH NGTON OFF/CF /NOS 61989 a E M. Xio c m N : Orlando. 8008 S. Orange Avenue, P.O. Box 593003. Orlando. Florida 32859-3003, Phone (407) 855-3860 Bartow, 1987 S. Holland Parkway, P.O. Box 812. Bartow. Florida 33830. Phone (813) 533-0858 Bradenton, 209 A 6th Avenue East. P.O. Box 1335, Bradenton. Florida 33508. Phone (813) 748-3971 Cocoa, 1300 N. C,nc 3tvr+ ° D Sox 1E57 Cocca ="cr da .'_2924. Phone 632-2503 Fort Myers, 2508 Rockiiil Road. Fort Myers, Florida 33916, Phone (813) 337-1288 Miami, 2608 'N. 84th Street, Hialeah. Florida 33016, Phone i305) 825-2683 Port St. Lucie, 1017 S.E. Holbrook Ct., P.O. Box 8687, Port St. Lucie. Florida 34985. Phone r407) 337-1200 Sarasota, 2500 Bee Ridge Road. P.O. Box 15008. Sarasota. Fonda 34277 Phone (813) 922-3526 Tallahassee, 3175 West Tharpe Street, Tallahassee. Florida 32303, Phone (904) 576-6131 Tampa. 105 N. Faulkenburg Road, Suite D. P.O. Box 1506. Brandon, Florida 34299-1506. Phone (813) 654-2336 West Palm Beach, 2511 Westgate Avenue, Suite 10, West Palm Beach. Florida 33409, Phone (407) 687-8200 MEMBERS: American Concrete 'ns:lute American Society for Testing and Materials American Consulting Engineers Council Association of Soil and Foundation Engineers Florida Institute of Consulting Engineers Professional Engineers in Private Practice 1 1 1 1 =Ai Ardaman & Associates, Inc. Consultants in Soils, Hydrogeology, Foundations and Materials Testing Texasgulf Inc. Post Office Box 48 Aurora, North Carolina 27806 Attention: Mr. William A. Schimming, Manager Environmental Affairs October 31, 1989 File Number 88-089 Subject: Supplemental Remedial Action Plan, Tank Farm Area, Texasgulf Phosphate Operations, Aurora, North Carolina Gentlemen: As requested, we have completed a supplemental remedial action plan for the tank farm area in accordance with the requirements of the notice of violation issued by the Division of Environmental Management on September 1, 1989 in response to the underground drain line leak incident. The document presents: (i) an overview of reported leak incidents at the tank farm and status of the previously submitted remedial action plan; (ii) a description of the hydrogeology of the tank farm area and implications on containment migration; (iii) a characterization of groundwater quality in the tank farm based upon three quarterly sampling events and (iv) a supplemental remedial action plan to contain and clean-up the existing groundwater contamination. If you have any questions or require additional information, please contact us. Very truly yours, ARDAMAN & ASSOCIATES, INC. CC.. Thomas S. Ingra, P.E. Senior Project Engineer hn E. Garlanger, h.D., P.E. Principal North Carolina Registration No. 9046 TSI:sc Encls. BOOB 5. Orange Avenue, P.O. Box 593003. Orlando. Florida 32859-3003 (407) 855-3860 - FAX I, 407 855-219 Offices in. Rarinw Rradnnrn, rnrn. 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File Number 88-089 1-1 Section 1 OVERVIEW OF TANK FARM LEAK INCIDENTS AND REMEDIAL ACTION PLAN 1.1 Tank Leak Incident at Tank 008 On May 31, 1988 during repair and maintenance of an above ground phosphoric acid storage tank, designated Tank 008 (Figure 1-1), it wasdiscoveredthat the rubber liner within the tank was damaged at two locations allowing the loss of an undetermined amount of 54 percent ;phosphoric acid over an unknown length of time. Shallow excavations beneath .the tank floor revealed the accumulation of phosphoric acid within soils underlying the tank. The phosphoric acid stored within the tank is characterized by the following chemical constituents: Constituent Concentration • Inorganic Constituents (%) Phosphorus, P205 Sulfate, SO, Magnesium, MgO Iron, Fe203 Aluminum, A1203 Fluoride, F Calcium, CaO Chloride, CI Silica, SiO2 • Trace Metals (mg/1) 52.8 2.6 1.3 1.3 0.6 0.5 0.05 0.005 0.07 Arsenic, As 1.3 Cadmium, Cd 30 Chromium, Cr 271 Copper, Cu 1.5 Manganese, Mn 74 Nickel, Ni 30 Vanadium, V 46 • Organic Constituents (mg/I) Total Organic Carbon, C 29 Followirig`the'discove"ry`of the7inerdamage;'the"fank'was'tepaired by neutralizing the 6- to 8-inch thick soil pad at the base of the tank with soda ash, adding 6 inches of clean Texasgulf Inc. File Number 88-089 1-2 silica sand above the existing soil pad, installing a new steel tank bottom, and installing a new rubber liner within the tank. The existing 6- to 8-inch thick soil pad is underlain by a PVC liner which was maintained in -place as part of the repair. Since implementing these repairs, Tank 008 has been re -activated and is presently in use. In response to the tank leak incident, the Diyision of Environmental Management (DEM) issued -a -halide -of noncompliance-on-AugUSt 8; 1988 and requested the submission of: (i) an assessment report characterizing the groundwater conditions in the tank farm area and identifying the extent of the contaminants, and; (ii) a remedial action plan outlining the proposed corrective actions to remediate the groundwater impacts. In accordance with these requests, a preliminary contamination assessment and remedial action plan were issued on September 7,'1988-and October 10, -1988; respectively. 12 Objectives and Status of Tank Leak Incident Remedial Action Plan The objectives of the remedial action plan as submitted to the DEM were to: (i) remove the source of contamination (Tank 008) addressed in the notice of noncompliance; (ii) minimize and contain future spills from tanks and associated pumps and pipelines in the tank farm (source control); (iii) pump existing contaminated groundwater from the surficial aquifer underlying the tank farm; and (iv) protect the adjacent Pamlico River barge slip from significant impacts from existing contaminants in the surficial aquifer. To achieve these objectives, the following four element remedial action system was undertaken. • Repair Tank 008 to remove the source of contamination addressed in the notice of noncompliance. • Provide new containment facilities for the existing tank farm main east -to - west piperack and phosphoric acid and super phosphoric acid tanks to minimize and contain future spills. • Pump existing contaminated groundwater from the surficial aquifer underlying / - — the tank farm area in conjunction with the installation of the new containment facilities. • Monitor the quality of groundwater flowing northward from the tank farm towards the Pamlico River barge slip within the surficial aquifer to determine if additional remedial measures are needed in the future to protect the Pamlico River from significant impacts. 1.2.1 Repair of Tank 008 and Installation of New Containment Facilities Tank: 008 -has ',teen repaired, as described above, and accordingly the source of contamination identified in the August 8, 1988 notice of noncompliance has been removed. The'new.,•main east-to-,westjpiperack,spilli containment'.system isfargelyainstalled,''and is, schedulediforscompletiothby:;December 1.989.9 The long-term program to minimize and contain leaks/spills around the phosphoric and super phosphoric acid tanks in the tank farm area is also underway. The relocation and reconstruction of Tank 044 is already !! 11 1.1 3 11 11 4 Texasgulf Inc. File Number 88-089 1-3 complete, and Tank 016 has been relocated with reconstruction scheduled for completion by December 1989 (Figure 2-1)*. 1.2.2 Pumping of Existing Contaminated Groundwater • A shallow::well=p'ointidewateringsystem':was.installed to. allow excavation .of the existing piperack'-foundatioris' :as'^part >of • construction of ,/the :main east -to -west -piperack spill containment --system. Permit No. 06-0071-WS-0150 was issued by the Division of Environmental Management for the installation of the well -point system. The <f rst/stage of..the"-well=point system(Figure 4=1)(was =operated,?from July.12;through Septemberl1, 1988Eat '•flow 2iates-43f =7- to =37ii-. gal/min.•and -yielded an estimated .1.1x10* gallons of contaminated groundwater from the surficial aquifer with a pH of 2.8 to 4.5 and specific conductance of 4,000 to 16,000 µmhos/cm (Figure 1-2). Groundwater removed by the well - point system was pumped to Cooling Pond No. 2. • The Stage 1 _dewatering system was subsequently removed, and re -installed at the Stage 3 location (Figure 1-1). The Stage 3 dewatering system was operated from September 13, 1988 through November 1, 1988 and removed on November 3, 1988.. The Stage 3 well - point system was operated at the rates of 21 to 33 gal/min and yielded an estimated 610,000 gallons of contaminated groundwater from the surficial aquifer with a pH of 2.0 to 3.7 and a specific conductance of 2,700 to 20,500 µmhos/cm (Figure 1-2). Groundwater removed by the well -point system was pumped to Cooling Pond No. 2. The remedial action plan originally anticipated operating the Stage 3 well -point system for a period of up to one year. The Stage 3 well -point system, however, was removed on November 3, 1988 upon completion of construction of the piperack spill containment system foundations. The well -point system was designed by the contractor to be a temporary construction dewatering system. It was subsequently discovered after submission of the remedial action plan in October 1988 that the temporary dewatering system could not be effectively operated for an extended period of time, such as one year, due to the excessive monitoring and maintenance requirements of the system. 1.2.3 Groundwater Monitoring Three monitor well clusters, designated MWTF-1, MWTF-2 and MWTF-3, were installed in the tank farm in accordance with the remedial action plan to monitor the quality of groundwater flowing northward toward the Pamlico River barge slip (Figure 1-1). These monitor wells were installed in October 1988 and have been sampled three times to -date (in January, April and July 1989). An evaluation of the quality of groundwater at the monitor wells is presented in Section 3. * Presently, construction plans are to relocate and rebuild Tanks 007, 008, 009 and 013 in 1990, Tanks. 015, 017, 019, 021 and 023 in 1991, and Tank 006 in 1992. Note that the tank locations depicted in Figures 1-1 and 2-1 are the existing tank locations. The reconstructed locations were depicted in Figure 4 (East Group Drawing DOG-071-047) of the remedial action plan submitted October 10, 1988. ':J J ih , A4y44. Texasgulf Inc. File Number 88-089 1-4 13 Leak at Underground Drain Line On.'June:5, 1989,, ih DEM was infoi id'by,Texasgulf Inc. that a leak :of in excess of 5,000pounds :of4hosph'oiic.acid had :been-diseovefed.in`an underground drain line in the tank farm :area.AFigure.-..1-1).:7_ Water, -leaking ;from the drain line was reportedly' characterized by..a.;pH..of<2.2,' and iflubride and. phosphorus concentrations of 1,660 and 4,900 mg/1, respectively.. -;The' drain line is a gravity -flow pipeline connecting two sumps, and the leak occurred ahrough'a"damaged-section'•of the.pipelines:'In response to the leak incident, the DEM issued -a notice of violation on September 1, 1989 and requested the submission of an active remedial action plan to abate groundwater contamination from both the Tank 008 and drain line leak incidents. Accordingly, in response to the DEM request, this document outlines supplemental remedial action efforts, to be undertaken in conjunction with the on -going program of source'control (i.e., the new containment facilities for.. the piperack and phosphoric acid tanks), to abate groundwater contamination in the tank farm area. The damaged section of pipeline has since been replaced and the sump and drain liner are again.iri`use. A11 3 Ail MONITOR WELL ' ,• MONITOR WELL I • STAGE 1 WELL -POINT DEWATERING SYSTEM I I • I -I, i , I (OPERATED FROM 3 ; 07/12/68 THROUGH • TANK 008 ' I (LEAK INCIDENT .. ". •L — REPORTED 05/31/88) ! I t •') • (4.;5"" f Of • OW„ 5 • ± r; I.A!4 T LOCATION OF UNDERGROUND DRAIN LINE LEAK INCIDENT (LEAK INCIDENT REPORTED 06/05/89 • I I ei'' 100 200 WS-CjT51 SCALE 1"-150' • I • O • ) 621 STAGE 3 WELL -POINT DEWATERING SYSTEM (OPERATED FROM 09/13/88 THROUGH 11/01/88) t 09/01/88) - ..'MONITOR WELL .• I CLUSTER MWTF-1 • ; ! I ' ; •"; H (-) ! i!•;) TANK FARM SITE PLAN cry Ardarnan & Associates, Inc. 01,1A1 Consulting Engineers in Soil Pile:hanks. foundations, end Materials Testing ge SUPPLEMENTAL REMEDIAL ACTION PLAN TANK FARM AREA TEXASGULF INC. PHOSPHATE OPERATIONS AURORA. NORTH CAROUNA 011Aelo• RBE &Melt ii•: ' •9/22/89 Inv 11tere. FILE NO ;vp 1111-09 . N74568 FIGURE 1-1 4� FLOW RATE, 0 (gpm) 40 30 20 10 i 2.0 0 1.5 3 a 0 u IS 1.0 W > o F w 3 0.5 0.0 2 n 1 20,000 of U Z 15,000 U E 1 ❑ 9' 0 10,000 U � U LL U 5,000 U w 1 um�.nn JUL 1 1988 AUG 1988 r in SEP 198E OCT 1988 111111111131 NOV 198a PUMPING RECORD AND GROUNDWATER QUALITY AT WELL -POINT DEWATERING SYSTEM Ardaman & Associates, Inc. Consulting Engineers In Soil Mechanics. Foundations. and Materials Testing SUPPLEMENTAL EMEFARIAAL L ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA O ROE I<Mtc rpe NO i L»epv, asses o sr:''` pare 9/Z2/89 Texasgulf Inc. File Number 88-089 2-1 Section 2 GENERALIZED HYDROGEOLOGIC SETTING IN TANK FARM AREA 2.1 Monitor Well Locations The locations of the three tank farm monitor well clusters, designated MWTF-1, MWTF-2 and MWTF-3, are depicted in Figure 2-1. As shown, monitor well cluster MWTF-1 is located about 180 feet south of phosphoric acid Tank 016 near the fertilizer blend storage area. Monitor well clusters MWTF-2 and MWTF-3 are located about 230 feet north of the phosphoric acid tanks. Three monitor wells were installed at each cluster (designated A, B and C), providing a total of nine monitor wells in the tank farm area. 2.2 Monitor Well Installation and Construction The monitor wells were installed by Ardaman & Associates, Inc. (North Carolina Driller Registration No. 1019) in accordance with well construction permit No. 06-0071-WM-0156. The monitor wells were installed between October 21 and October 27, 1988. A Standard Penetration Test (SPT) boring was performed at the location of each monitor well cluster to the top of the Yorktown formation. The subsurface profile determined at each location was then used to establish the depths for installation of the monitor wells The Standard Penetration Test borings were conducted in accordance with ASTM D 1586 with split -spoon samples obtained at 5-foot intervals. The boreholes were sealed with cement-bentonite grout to land surface upon completion of sampling. The monitor wells were installed in accordance with NCAC Subchapter 2C.0100 "Well Construction Standard?. A schematic detail of the monitor wells is presented in Figure 2-2*. The wells were installed by: (i) advancing a 6-inch diameter hollow -stem auger to the final well depth using a wooden plug at the bottom of the auger to maintain the inside of the auger clear of soils; (ii) filling the auger with clean water and knocking out the wooden plug; (iii) inserting a 2-foot length of slotted PVC well screen (0.010-inch wide slots) with a stainless steel centralizer connected to a 2-inch diameter Schedule 40 solid threaded flush joint PVC casing inside the auger; (iv) backfilling the annular space between the 10-inch diameter borehole created by the auger flights and well screen with 8/16 silica sand; (v) installing a 12-inch minimum thick tamped bentonite seal above the collection zone; and (vi) removing the hollow -stem auger and sealing the remaining annular space between the well casing and inside of borehole with neat cement grout to land surface. Each of the monitor wells was provided with a vented locking cap and labelled with the designation and related information as required by NCAC Subchapter 2C.0100. * Monitor well clusters MWTF-1 and MWTF-3 were installed with the at -grade leak - resistant steel manhole covers depicted in Figure 2-2. Monitor well cluster MWTF-2 was installed with conventional PVC well casings extending about 2.5 feet above grade. • • i 11 Texasgulf Inc. File Number 88-089 2-2 After installation, each well was flushed with clean water, developed and the water level recorded. Construction records (Form GW-1) for each monitor well were previously submitted to the DEM on December 29, 1988 and are also included in Appendix A identifying: • Date of Installation • Total Depth of Well • Casing Length • Grout Seal Interval • Well Screen Length • Thickness and Depth of Collection Zone (Gravel Pack) • Thickness and Depth of Bentonite Seal 23 Generalized Subsurface Stratigraphy The results of the Standard Penetration Test borings conducted at each monitor well cluster are presented on the soil boring logs in Appendix B. The stratification lines indicated on the boring logs -represent our interpretation of the contents of the field logs, and the results of laboratory observations and index tests on the recovered split -spoon samples. Laboratory index tests used to classify the soils are shown on the boring Togs, and the soils were classified in accordance with ASTM D 2487 standard test method for classification of soils for engineering purposes. The stratification lines represent the approximate boundary between soil types and the transition may be more gradual than implied. The locations of the monitor well collection zones within the soil profile are also depicted on the soil boring logs. The soil borings were completed to a depth of 60 feet in order to penetrate the undifferentiated surficial deposits and Pleistocene Croatan formation, and encounter the top of the Pliocene Yorktown formation. The subsurface conditions encountered at the soil borings consisted of the following generalized stratigraphy. Figure 2-3 depicts the generalized subsurface stratigraphy across the tank farm area. Undifferentiated Surficial Deposits • A surficial layer of interbedded fine sand to clayey fine sand (generally believed to be comprised of fill materials) extended from ground surface to depths of 5 to 14 feet. Standard Penetration Test resistance values in these soils varied widely from 9 to 43 blows per foot, representative of loose to dense sands, with an overall average of 29±12 blows/foot from 13 determinations. The upper monitor well at each well cluster (i.e., wells designated 1A, 2A and 3A) tapped the base of this surficial sandy stratum. • The surfic• ial sandy stratum was underlain by a 4.5- to 9.0-foot thick brown to dark brown clayey fine sand to plastic clay layer. Standard Penetration Test resistance values in this layer ranged from 0 blows/foot in the plastic clay (boring TF-3) to about 10 blows/foot in the clayey sands, characteristic 1 Texasgulf Inc. File Number 88-089 2-3 of very soft to stiff clayey soils. Two fines content* determinations on soil samples from this layer yielded values of 35% in a clayey sand and 59% in a sandy clay. • A gray to brown fine sand to silty fine sand layer ranging in thickness from 1.5 to 4.5 feet, with an average thickness at the three borings of about 3 feet was encountered below and confined by the overlying clayey sand to plastic clay layer. Standard Penetration Test resistances ranged from 10 to 31 blows/foot, characteristic of a medium dense sand. The intermediate taeppth h monitor well at each cluster (i.e., wells designated 1B, this confined sand layer. • A 10.5- to 20.8-foot thick stratum of typically gray to greenish -gray clayey fine sand to sandy clay often with some shell fragments was encountered within the base of the undifferentiated surficial deposits. Standard Penetration Test resistance values within this stratum were characteristic of soft to medium stiff clayey soils with blow counts of 2 to 7 blows/foot and an average of 5±2 blows/foot. Four fines content determinations onhsoail samples from this stratum yielded values of 47, 25, 31 and 31 To average of 34±9%. Croatan Formation • The Croatan formation, generally consisting of clayey to silty fine sand and shell fragments occasionally with cemented sand, was encountered at depths of 32 to 38 feet and extended for thicknesses of 15 to 20 feet. This formation is confined by the overlying clayey sand to plastic clay layer in the base of the undifferentiated surficial deposits, and below by the Yorktown formation. The standard Penetration Test resistance varied -widely from 7 to 69 blows/foot (when cemented sands were present) with a representative value of about 13 blows/foot, characteristic of a medium dense sand. The deepest monitor well at each cluster (i.e., wells designated 1C, 2C and 3C) tapped the Croatan formation. Yorktown Formation • The Yorktown formation underlies and confines the Croatan formation, and was generally found to consist of clayey fine sand to sandy plastic clay. The Yorktown formation was encountered at depths of 47 to 43 feet and extended below the 60-foot completion depth of the borings. Standard Penetration Test resistances varied from 6 to 12 blows/foot with an average of 9 blows/foot, characteristic of stiff clayey soils. Where the fines content is the soil fraction by dry weight finer than the U.S. Standard No. 200 sieve. 1 1 Texasgulf Inc. File Number 88-089 2-4 24 In Situ Permeability Tests An in situ permeability test was performed in each monitor well by raising the water level in the well and measuring the rate of decline with time using an electric pressure transducer and data acquisition system. The test results were analyzed to provide an estimate of the in situ horizontal coefficient of permeability of the formation containing the well collection zone for the case of a homogeneous, isotropic aquifer. The calculated horizontal coefficients of permeability are summarized below: Horizontal Coefficient Monitor Screen Depth of Permeability Fines Well (Feet) (cm/sec) Content(%)` MWTF-1A 3.4 - 5.4 4.0 x 104 13 MWTF-1B 10.6 - 12.6 3.9 x 104 20 MWTF-1C 38.7 - 40.7 9.7 x 10' 16 MWTF-2A 10.2 - 12.2 3.8 x 104 21 MWTF-2B 18.8 - 20.8 1.1 x 10.2 6 MWTF-2C 39.7 - 41.7 1.4 x 10'4 24 MWTF-3A 10.9 - 12.9 3.2 x 10-' 22 MWTF-3B 24.2 - 26.2 1.1 x 10'Z 3 MWTF-3C 44.7 - 46.7 3.1 x 10' 16 The in situ horizontal coefficients of permeability ranged from 1.1x10-1 to 3.8x104 cm/sec, with the confined sand layer displaying the greatest coefficients of permeability. The in situ horizontal coefficients of permeability judged representative for the various stratigraphic units are presented below: Fines content (soil fraction by dry weight finer than the U.S. Standard No. 200 sieve) determined on split -spoon soil samples from Standard Penetration Test borings completed at each monitor well cluster location. misigmanaiansireapiitainalitl4'd/R"Q"WifRur SY.c 4.'E 4 _ Texasgulf Inc. File Number 88-089 Horizontal Coefficient Stratigraphic Unit of Permeability (cm/sec) Surficial Sand Layer* Confined Sand Layer** Croatan formation 1.3 x 104 1.1 x 10'Z 4.7 x 104 2-5 25 Groundwater Levels, Aquifer Flow Directions and Seepage Velocities Groundwater levels were measured in the monitor wells at the time of each sampling event in January, April and July, 1989. The measured water level elevations are summarized below.*** Water Level Elevation, Feet (MSL) Monitor Well 01 89 04/89 07/89 MWTF-1A 8.47 9.44 9.14 MWTF-1B 8.06 8.66 8.66 MWTF-1C -3.96 -0.74 -2.19 MWTF-2A 6.82 6.94 5.25 MWTF-2B 4.14 4.66 4.30 MWTF-2C -1.85 -0.45 -1.06 MWTP-3A 7.45 7.57 7.15 MWTF-3B 3.13 3.67 3.37 MWTF-3C -2.61 -0.49 -1.32 Based upon the measured water level elevations, the direction of groundwater flow in the various layers tapped by the monitor wells are presented in Figures 2-4, 2-5 and 2-6. As shown, the direction of groundwater flow in the surficial sand layer (Figure 2-4) is generally north -northwestward at a gradient of about 0.005 feet/foot. For the selected in situ horizontal coefficient of permeability of 1.3x10'' cm/sec (135 feet/year) the resulting Based upon the reported pumping rates from the well -point dewatering system (Figure 1-2), a coefficient of permeability of up to 1x103 cm/sec may also be appropriate for portions of the surficial sand layer. ** Based upon the more pervious soils at monitor wells MWTF-2B and MWTF-3B, disregarding the 3.9x10' cm/sec value measured at monitor well MWTF-1B. ***Surface water level elevations of 0.6 feet (MSL) for the barge slip and 6.1 to 6.7 feet (MSL) for the drainage ditch near monitor well clusters MWTF-2 and MWTF-3 were also measured in January 1989. 11 1 1 1 1 As shown in Figure 2-7, the water level elevations generally decline with depth, indicative of downward vertical seepage. The verticalgradient across the clayey fine sand to plastic clay layer separating the confined sand layer and Croatan formation (i.e., between monitor wells designated B and C) varies from 0.49 to 0.54 feet/foot with an average of 0.51 feet/foot. Vertical gradients across the clayey fine sand to plastic clay layer separating the ` surficial and confined sand layers (i.e., between monitor wells designated A and B) equalled 0.44 and 0.48 feet/foot at clusters MWTF-2 and MWTF-3, and 0.13 feet/foot at cluster MWTF-1. For an overall representative vertical gradient of 0.50 feet/foot, estimated in situ vertical coefficient of permeability on the order of 1x10d cm/sec for the clayey sands to plastic clays and a porosity of 0.50, the resulting estimated vertical seepage rate is on the order of 1 foot/year. a Texasgulf Inc. File Number 88-089 2-6 horizontal seepage velocity is a relatively slow 2 feet/year (based upon a porosity of 0.35). The direction of groundwater flow in the confined sand layer (Figure 2-5) is also generally northward, but slightly to the north-northeast, at a slightly larger gradient of about 0.01 feet/foot. For the selected in situ horizontal coefficient of permeability of 1.1x104 cm/sec (11,400 feet/year), the resulting horizontal seepage velocity is about 300 feet/year. ' This seepage velocity is 150 times greater than occurs in the surficial sand layer, and results largely due to the greater coefficient of permeability and to a lesser extent from the larger gradient. The direction of groundwater flow in the Croatan formation (Figure 2-6) is opposite the direction of flow in the overlying undifferentiated surficial deposits, and is generally south - southeastward at a gradient of about 0.0023 feet/foot. For the selected in situ horizontal coefficient of permeability of 4.7x10 ° cm/sec (490 feet/year) the horizontal seepage velocity is a relatively slow 3 feet/year. 1 1 1 1 :« ..i 7."_Ori L� -lam.•o • •.P• 'DEPTH VARIES 8' 3: 8' 12' 24' -,LEAK—PROOF LOCKING CAP 6.25—INCH I.D. LEAK RESISTANCE STEEL MANHOLE 3'x3'x4' THICK CONCRETE PAD GROUND SURFACE .8/18 SILICA SAND;.;;•;: 10 INCH DIAMETER BOREHOLE ADVANCED WITH HOLLOW STEM AUGER NEAT CEMENT GROUT: • 6 GALLONS OF CLEAN WATER • 1 SACK OF CEMENT (94 Ibs) • 4.0 — 4.5 Ibs OF BENTONITE 2 INCH DIAMETER SCHEDULE 40 THREADED FLUSH JOINT PVC WELL CASING FINE SILICA SAND TAMPED BENTONITE SEAL 8/18 SILICA SAND COLLECTION ZONE STAINLESS STEEL CENTRALIZER 2 INCH DIAMETER SCHEDULE 40 PVC WELL SCREEN (0.010 INCH WIDE SLOTS) END CAP SCHEMATIC OF MONITOR WELL INSTALLATION ®' Ardaman & Associates, Inc. Consulting Entanwn in Soil Mechanics, Foundations. and Materials Tinting SUPPLEMENTAL REMEDIAL ACTION PLAN TANK FARM AREA TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA N2436a FIGURE 2-2 MWTF-2A EL 6,94' j 100 200 SCALE 1'-150' &, MWTF-3A EL 7.57' -/ ".MWTF-1A EL 9.44' WATER TABLE ELEVATION IN FEET (MSL) AS MEASURED IN APRIL 1989' WATER TABLE ELEVATION IN SURFICIAL SAND LAYER Ardaman & Associates, Inc. Consulting Engineers in Sal M Wrriia, Foundations, nd Martinis Testing SUPPLEMENTAL REMEDIAL ACTION PLAN TANK FARM AREA TEXASOULF.INC. PHOSPHATE OPERATIONS .. ... AURORA;.NORTHp,�CAROUNA MAIM a• RSE IaaWD rt: WI ern: 9/22/89 te-SWAren.'711 N2456 FIGURE 2-4 MWTF-28 EL 4.66' CO 100 200 SCALE 1"-150' EL 3.67' @.0• MWTF-1 B ® EL 8.66' POTENTIOMETRIC SURFACE MAP FOR CONFINED SAND LAYER PIEZOMETRIC WATER ELEVATION IN FEET (MSL) IN APRIL 1989 • ®® Ardaman 8 Associates, Inc. fanzAi Coruultinl Engineers In Soil Lbd,w a. Foundations, and Materials Testing SUPPLEMENTAL REMEDIAL ACTION PLAN TANK FARM AREA - TEXASOULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA wewN. E 1040.101T: ottl DATE 9/22/69 N24568 FIGURE 2-6 qla M;. ee-069 ' PIEZOMETRIC WATER ELEVATION IN FEET (MSL) IN JULY 1989 2p 100 200 C. MWTF-3 C''' MWTF-1C EL. -2.19' `t.,,,,! POTENTIOMETRIC SURFACE MAP FOR CROATAN FORMATION ®a Ardaman & Assocktes, Inc. wisilits Consulting Endn"n In Soil MMunks, Foundation. and M.t,SI. Tonne SUPPLEMENTAAL REMEDIALEAACTION PLAN TEXASOULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA SCALE 1"-150' anwm. ROE 'srmacno :'N o•n: 9/22I99 MI W. Pe*? FIGURE-2-6 Texasgulf Inc. File Number 88-089 3-1 Section 3 CHARACTERIZATION OF GROUNDWATER QUALITY AT TANK FARM MONITOR WELL AND WELL -POINT SAMPLING LOCATIONS Groundwater samples have been obtained three times to -date at each of the nine monitor wells and a nearby Castle Hayne aquifer water supply well between January and July 1989, and once at a well -point sampling location in March 1989. Additionally, a surface water sample was obtained from the adjacent Pamlico River barge slip in January 1989. 3.1 Groundwater Sampling Methodology Groundwater sampling of the monitor wells was undertaken by Texasgulf Inc. personnel in accordance with the sampling procedures outlined in the Tank Farm Remedial Action Plan.* Groundwater sampling of the well -points was undertaken by Ardaman & Associates, Inc. personnel in accordance with the procedure outlined below in Section 3.1.2. 3.1.1 Water Quality Parameters and Test Procedures Groundwater from each monitor well, water supply well and the well -points was analyzed , for the following parameters: • Field Specific Conductance • Field and Laboratory pH • Total Phosphorus, P • fluoride, F • Chloride, CI • Sulfate, SO. • Total Dissolved Solids, IDS • Total Organic Carbon, TOC All laboratory chemical analyses were performed by Texasgulf Inc. Specific analytical procedures used to determine the water quality parameters are summarized below. * Ardaman & Associates, Inc. (1988). "Remedial Action Plan for Tank Farm Ar Texasgulf Inc., Phosphate Operations, Aurora, North Carolina. 1 1 1 1 Texasgulf Inc. File Number 88-089 Parameter Specific Conductance pH Total Phosphorus Fluoride Chloride Sulfate Total Dissolved Solids Total Organic Carbon Method Conductivity Cell Electrometric Chlorimetric, Ascorbic Acid, Single Reagent Potentiometric, Ion Selective Electrode Potentiometric, Ion Selective Electrode Gravimetric (without silica removal) Gravimetric @ 180°C Persulfate-Ultraviolet Oxidation Method Reference 120.1 * 150.1 * 365.2* 340.2* 407.C** 375.3* 160.1* 505.B** 3-2 3.1.2 Well -Point Installation and Sampling To determine the quality of groundwater nearer potential sources of phosphoric acid leaks/spills, groundwater was sampled with a well -point sampling device at a location (designated WPTF-1) just north of the piperack near phosphoric acid Tank 009 (Figure 2-1). The well -point sampler consists of a 1.34-inch outside diameter by 9.0-inch long No. 8 slotted stainless steel well screen with an 18° cone tip. The sampler is attached to conventional AW drill rod for inserting into the ground. A 0.375-inch outside diameter (0.250-inch inside diameter) polypropylene tube is attached to the sampler and carried to the surface through the inside of the AW drill rod. During sampling of groundwater, a vacuum is applied to the polypropylene tube and groundwater is withdrawn from the sampling zone through the well screen to the surface. The well -point sampling was completed by: (i) advancing a 6.5-inch outside diameter (3.25-inch inside diameter) hollow -stem auger to just above the desired sampling depth; (ii) removing soil from within the hollow -stem auger (generally a 6- to 12-inch thick plug of soil forms at the base of the auger) by rotary washing with clean water; (iii) driving a split -spoon sampler 18-inches below the bottom of the auger and extracting a soil sample to verify the nature of the soil from which the groundwater will be withdrawn; (iv) inserting the well -point sampler down the borehole and driving the sampler until the 9-inch long well screen is below the interval sampled by the split -spoon sampler; (v) applying a vacuum to the polypropylene tube and extracting groundwater and collecting a sample afte�Ih�_p.E and sttecific conductance achjgve_constant.xalues; (vii) removing the well -point sampler and * "Methods for Chemical Analysis of Water and Wastes", Environmental Monitoring and Support Laboratory, Office of Research and Development, USEPA, Report EPA-600/4- 79-020, March 1983. "Standard Methods for the Examination of Water and Wastewater", 16th Edition, 1985. ** Texasgulf Inc. File Number 88-089 hollow -stem auger after extraction of the borehole with a neat cement grout to land s Four groundwater samples were extracted at The sampling intervals were 3.0 to 3.75 feet, to 47. 3.2 ,Surface Water Quality 3-3 groundwater sample; and (viii) sealing the urface. location WPTF-1 with the well -point sampler. 11.25 to 12.0 feet, 25.25 to 26.0 feet and 46.25 The tank farm area is adjacent to a barge slip and the Pamlico River which contain brackish water. Because the quality of groundwater in the surficial and Croatan aquifers in the tank farm area can potentially be affected by the brackish water (depending on the direction of groundwater flow), a surface water sample was obtained from the barge slip to characterize constituents within the brackish water.* The results of these chemical analyses are presented below. • FIELD MEASUREMENTS Sampling Date Specific Conductance (µmhos/cm) Temperature (°C) Field pH Odor Appearance • LABORATORY ANALYSES Lab pH Total Phosphorus, P (mg/t) Fluoride, F (mg/l) Chloride, Cl (mg/1) Sulfate, SO, (mg/1) Total Dissolved Solids, TDS (mg/1) Total Organic Carbon, TOC (mg/1) 01/27/89 28,820 20 7.8 None Brown 7.8 0.20 0.72 10,900 1499 19,248 7 As expected, the brackish water is high in total dissolved solids with elevated concentrations of sulfate and chloride. The concentration of sodium, although not measured, would also be relatively high (on the order of 6000 mg/1). Fluoride and total phosphorus concentrations are relatively low and on the same order -of -magnitude as naturally occurring in groundwater at the site. The measured fluoride and total phosphorus concentrations are also in generally good agreement with typical values reported by Hem (1970)** for sea water of 1.3 and 0.07 mg/1, respectively. * The sample was obtained from near the mid -point of the barge slip. ** Hem, J.D. (1970). "Study and Interpretation of the Chemical Characteristics of Natural Water". Geological Survey Water Supply Paper 1473. 9 1 1 a 1 Texasgulf Inc. File Number 88-089 3-4 33 Groundwater Quality Summaries of groundwater quality at the nine monitor wells and at the well -point sampling location are presented in Tables 3-1 through 3-4. The maximum contaminant levels specified in NCAC Subchapter 2L.0202 are also presented for comparison. 3.3.1 Surficial Aquifer Groundwater Quality The surficial aquifer at the tank farm is comprised of the undifferentiated surficial deposits (Section 2.3), and generally extends to a depth of about 50 feet. Within the aquifer, two layers were tapped by monitor wells: (i) the surficial sand layer; and (ii) a relatively thin confined sand layer occurring at a depth of 10 to 20 feet and extending for a thickness of about 4 feet. 3.3.1.1 Surficial Sand Laver The average* constituent concentrations measured in the surficial sand layer are summarized below and presented in Figure 3-1. Well Monitor Well Point Parameter MWTF-1A MWTF-2A MWTF-3A WPTF-1A Field pH 6.8 6.4 5.7 6.2 Specific Conductance (µmhos/cm) 452 1790 1383 3100 Total Phosphorus, P (mg/l) 0.40 0.15 0.22 87.0 Fluoride, F (mg/i) 0.71 0.18 0.14 0.23 Chloride, CI (mg/I) 16 66 310 69 Sulfate, SO, (mg/1) 74 308** 98 1862 Total Dissolved Solids, TDS (mgf) 325 973** 794 3508 Total Organic Carbon, TOC (mg/l) 5.7 11 8.3 12 As shown, at monitor well MWTF-1A upgradient of the phosphoric acid facilities, the phosphorus, fluoride and sulfate concentrations (major contaminants in phosphoric acid - see Section 1.1) were relatively low indicating that groundwater impacts do not exist in the surficial sand layer at this location. The measured constituents are also in compliance with Subchapter 2L.0202 maximum contaminant levels. * Average constituent concentrations from three groundwater samples obtained in January, April and July 1989. ** Disregarding apparently high concentrations of 1,090 mg/1 of sulfate and 2,339 mg/I of bJh -/ total dissolved solids reported for April 1989. Texasgulf Inc. File Number 88-089 3-5 At 'downgtadientwell-point sampling flocation",WPTF4At the • phosphorus, 'sulfate, 'total organic:.'carbon:_and rtotalytiissolved csoh. dsconcentrations • are • elevated, --indicative .of contamination: from phosph6riccadidleakage/spills.ti At further downgradient monitor wells MWTF-2A and MWTF-3A, however, total phosphorus concentrations are low (only 0.15 and 0.22 mg/1) and sulfate is only slightly elevated (308 mg/1) at MWTF-2A. Accordingly, impacts from phosphoric acid leakage/spills have not occurred at monitor wells MWTF-2A and MWTF-3A, which would be expected given the relatively slow horizontal seepage velocity in this layer (Section 2.5), as well as vertical seepage causing contaminants in this layer to migrate downward into the underlying confined sand layer. Further, although slightly elevated sulfate and total dissolved solids concentrations occur at monitor well MWTF-2A in comparison to MWTF-1A, the seepage of this groundwater into the adjacent barge slip will not result in surface water impacts because the brackish water sulfate and total dissolved solids concentrations are higher (Section 3.2) than occur in the groundwater. 3.3.1.2 Confined Sand Layer The average constituent concentrations measured in the confined sand layer are summarized below and presented in Figure 3-2. Parameter Well Monitor Well Point MWTF-1B MWTF-2B MWTF-3B WPTF-1C Field pH 5.6 6.4 6.0 6.4 Specific Conductance (gmhos/cm) 920 2300 2143 2100 Total Phosphorus, P (mg/I) 0.19 65.6 94.9 34.5 Fluoride, F (mg/1) 0.27 1.61 0.18 0.43 Chloride, CI (mg/I) 213 328 104 115 Sulfate, SO. (mg/l) 17 355 512 587 Total Dissolved Solids, TDS (mg/1) 538 1497 1348 770 Total Organic Carbon, TOC (mg/I) 3 9.7 7.7 11 As shown, at monitor well MWTF-1B upgradient of the phosphoric acid facilities, the phosphorus, fluoride and sulfate concentrations are relatively low indicating that impacts do not exist in the confined sand layer at this location. The fluoride, chloride and sulfate constituent concentrations are in compliance with Subchapter 2L.0202 maximum contaminant levels at this location, although pH and the total dissolved solids concentration are somewhat beyond the maximum contaminant levels. •Well -point WPTF4B;3sampled•fi6ihiaidepth;pf41:25Jo110 ifeet in the clayey sand layer=tiiiderlyingzhe tirfieialIandtisplayeci higher coutatninaiit4evels (Table 34). The"phosphorus'; sulfate►ndrtotaltdis§olved%tilids'cb`n'centratioii 'were':veryhighin'this well -point '(P-.� 5,27_5.Ong/1;4SOj=i2,555M1 /!,'mad:'tIDS:ir 20,076:ing/I). 'The'specific conductance: of;11,000FµmliblicanwasialsTa'�lti ggreemenf vuhthe values 'reported forgrouudwateripumped+fromxheVellivintAleWatbting!atem Figured )• Texasgulf Inc. File Number 88-089 3-6 At downgradient well -point sampling location WPTF-1C, the phosphorus, sulfate and total dissolved solids concentrations are elevated, indicative of contamination from phosphoric acid leakage/spills. At further downgradient monitor wells MWTF-2B and MWTF-3B contamination also exists as evidenced by elevated phosphorus (65.6 to 94.9 mg/1), sulfate (355 to 512 mg/1), and total dissolved solids (1348 to 1497 mg/1) concentrations. Contamination at monitor wells clusters MWTF-2 and MWTF-3 in the confined sand layer (Figure 3-2) without contamination in the overlying surficial sand layer (Figure 3-1) is explainable due to the differences in horizontal seepage velocity, and downward seepage gradient observed at each well cluster location (Section 2.5). Leakage/spills of phosphoric acid from the tanks and piperack enters the surficial sand layer and migrates both horizontally (north -northwestward) within the layer and downward across the underlying clayey sand to plastic clay layer into the confined sand (Figure 2-3). Once contaminants enter the confined sand layer, which can have a seepage velocity on the order of 300 feet/year (Section 2.5), the contaminants can migrate horizontally at a much greater rate than in the surficial sand layer. 3.3.2 Croatan Aquifer Groundwater Quality The Croatan aquifer is generally comprised of relatively pervious coarse to fine sands and shell within the Croatan formation. At the tank farm, the Croatan formation soils were gegerally'3omewhatiilty to clayey, and not as pervious as found elsewhere at the phosphate opettatioe-Whe Croatan formation soils were encountered at depths of 32 to 38 feet, and extended for thicknesses of 15 to 20 feet. The average constituent concentrations measured in the Croatan formation monitor wells are summarized below and presented in Figure 3-3. At'boring TF-1, a pervious zone was encountered in the Croatan formation at a depth ofc42{eefas'indicatedby a:loss of drilling fluid circulation (see boring log in Appendix B):`1'The :horizontal coefficient of permeability •determined 'in 4he monitor. well; just; tappingithis.zone {MWTF-1C) ,was ;Also ,the ;highest ,of ":the :thr'"ee"•tatik�fer n'Ci6atan formation -monitor wells., r o r .t . ,H t.4, _ I.. 1 1 1 1 1 1 4 Texasgulf Inc. File Number 88-089 3-7 G TaNi PA. ; Parameter Field pH Specific Conductance (gmhos/cm) Total Phosphorus, P (mg/1) Fluoride, F (mg/1) Chloride, CI (mg/l) Sulfate, SO, (mg/I) Total Dissolved Solids, TDS (mg/l) Total Organic Carbon, TOC (mg/1) Well Point WPTF-1D 6.5 2800 34.3 0.37 195 727 1084 13 Monitor Wells MWTF-1C MWTF-2C MWTF-3C 6.9 6.3 6.1 808 2317 2530 0.15 0.38 54 59** 536 4.3 15.6 0.17* 77 874 2337 12 24.7 0.12 94 647 2053 10.3 At monitor well MWTF-1C downgradient from the phosphoric acid facilities, the phosphorus. fluoride and sulfate concentrations are relatively low indicating that groundwater impacts do not exist in the Croatan formation at this location. The measured constituent concentrations are also in compliance with Subchapter 2L.0202 maximum contaminant levels with the exception of a slightly elevated average total dissolved solids concentration of 536 mg/1. At upgradient monitor wells MWTF-2C and MWTF-3C and well -point WPTF-1D, the phosphorus, sulfate, and total dissolved solids concentrations are elevated, indicative of phosphoric acid contaminants. At these locations, the phosphorus concentrations are generally lower (except at WPTF-1D) than occur in the overlying confined sand layer, but the sulfate and total dissolved solids concentrations are somewhat greater. Because the direction of groundwater flow in the Croatan formation is south -southeastward (Figure 2-6), these contaminants cannot have entered the formation at the location of the phosphoric acid tanks and piperack. Instead, it is expected that these contaminants entered the Croatan formation by downward seepage from the overlying confined sand layer after the contaminants had already migrated northward from the source in this overlying layer. 3.3.3 Castle Hayne Aquifer Groundwater Quality Groundwater quality at the Castle Hayne aquifer water supply well FERT-1 located within the tank farm near phosphoric acid Tank 007 (Figure 2-1) is summarized below. * Disregarding apparently high fluoride concentration of 1.17 mg/1 reported in July 1989. ** Disregarding apparently high sulfate concentration of 292 mg/1 reported in January 1989. ANY Texasgulf Inc. File Number 88-089 3-8 Parameter • FIELD MEASUREMENTS Sampling Date 01/89 04/89 07/89 Specific Conductance (p.mhos/cm) 1320 1380 1500 Temperature (°C) 20 20 25 Field pH 7.0 7.2 7.4 Odor None None None Appearance Clear Clear Clear • LABORATORY ANALYSES Lab pH 7.1 7.3 7.6 Total Phosphorus, P (mg/I) 0.030 0.10 0.043 Fluoride, F (mg/1) 0.66 0.59 0.63 Chloride, CI (mg/1) 290 290 303 Sulfate, SO4 (mg/1) 9 10 5 Total Dissolved Solids, TDS (mg/I) 888 796 760 Total Organic Carbon, TOC (mg/1) 5 5 5 As shown, groundwater quality in the Castle Hayne aquifer at well FERT-1 displays background level phosphorus, fluoride and sulfate concentrations, the major contaminants within phosphoric acid. Accordingly, as expected, due to the approximately 100-foot thick Yorktown-Pungo River aquitard separating the Castle Hayne aquifer from the Croatan. aquifer, contaminants from phosphoric acid leakage/spills have not impacted the Castle Hayne aquifer. 1 ISM tiMJ COW ti=id 1 1 1232= ea area ets r+caszaer. a rev ; Table 3-1 GROUNDWATER QUALITY AT MONITOR WELL CLUSTER MWTF-1 Parameter • FIELD MEASUREMENTS Surficial Aquifer Croatan Aquifer Subchapter MWTF-IA MWTF-1B MWTF-IC 2L.0202 MCL 01/89 04/89 07/89 01/89 04/89 07/89 01/89 04/89 07/89 Water Elevation, feet (MSL) x 8.47 9.44 9.14 8.06 8.66 8.66 -3.96 -0.74 -2.19 Specific Conductance, (µmhos/cm) ns 590 380 385 900 910 950 800 800 850 Temperature (°C) x 18 17 27 19 18 25 19.5 19 21 Field pH 6.5-8.5 6.8 6.8 6.7 5 6:>i 5 & , 5.4 6.8 7.2 6.9 Odor x None None None Norte None None None None None Appearance x Rusty Rusty Milky Clear Clear Clear Clear Turbid Gray • LABORATORY ANALYSES Lab pH x 6.8 6.8 6.9 5.7 5.8 5.7 5.7 6.8 7.6 Total Phosphorus, P(mg/1) ns 0.46 0.67 0.064 0.12 0.23 0.23 0.30 0.13 0.025 Fluoride, F(mg/1) 2.0 0.64 0.60 0.90 0.18 0.17 0.45 0.61 0.26 0.28 Chloride, Cl(mg/l) 250 29 8 10 218 218 204 56 52 53 Sulfate, SO4(mg/1) 250 88 92 43 12 22 18 Z ') 59 58 Total Dissolved Solids, TDS(mg/1) 500 372 336 268 593! 5621 460 5541 5Z6 S.2fii Total Organic Carbon, TOC(mg/1) ns 7 5 5 3 3 3 6 3 4 ns: Not Specified : Exceeds Subchapter 15 NCAC 2L.0202 Maximum Contaminant Lcvel (MCL) w1aGi➢ 1® WS- / won ANSI ::9e9 .Ltd wawa ea.+ew *some 'fable 3-2 GROUNDWATER QUALITY AT MONITOR WELL CLUSTER MWTF-2 Parameter • FIELD MEASUREMENTS Surficial Aquifer Croatan Aquifer Subchapter MWTF-2A MWTF-2B MWTF-2C 2L.0202 MCL 01/89 04/89 07/89 01/89 04/89 07/89 01/89 04/89 07/89 Water Elevation, feet (MSL) x 6.82 6.94 5.25 4.14 4.66 4.30 -1.85 -0.45 -1.06 Specific Conductance, (pmhos/cm) ns 1370 2650 1350 2200 2300 2410 2300 2300 2350 Temperature (°C) x 16.5 17 24.5 18.5 18 21.5 19 19 20.5 Field pH 6.5-8.5 64 6.9 60 64. 6.6 6.2 al 6.5 60' Odor x None None None None None None None None None Appearance x Clear Milky Clear Clear Rusty Milky Clear Clear Clear • LABORATORY ANALYSES Lab pH x 6.3 6.9 6.3 6.3 6.6 Total Phosphorus, P(mg/1) ns 0.090 0.16 0.20 92.0 : 47.3 Fluoride, F(mg/1) 2.0 0.15 0.26 0.14 1.96 1.81 Chloride, Cl(mg/I) 250 71 .62 66 9;76: 321< Sulfate, SO4(mg/1) 250 135Z C 1091) 259 270;; 444 Total Dissolved Solids, TDS(mg/1) 501 1.14,6: ?339. 840 1212 25$0 Total Organic Carbon, TOC(mg/1) ns 12 12 9 12 8 ns: Not Specified : Exceeds Subchapter 15 NCAC 2L.0202 Maximum Contaminant Level (MCL) 6.7 6.3 6.5 57.6 12.8 16.6 1.07 0.17 0.16 1287; 78 75 51 .:, :$44 17Q0, ;2308 2272 < 430 9 13 11 12 6.5 17.4 (1.1 72. 78 Parameter "]'able 3-3 GROUNDWATER QUALITY AT MONITOR WELL CLUSTER MW 1'F-3 • FIELD MEASUREMENTS Surficial Aquifer - Croatan Aquifer Subchapter MWTF-3A MWTF-3B MWTF-3C 2L.0202 MCL 01/89 04/89 07/89 01/89 04/89 07/89 01/89 04/89 07/89 Water Elevation, feet (MSL) x 7.45 7.57 7.15 3.13 3.67 3.37 -2.61 -0.49 -1.32 Specific Conductance, (µmhos/cm) ns 1250 1400 1500 2080 2100 2250 2510 2500 2580 Temperature (°C) x 20 20 26.5 29 29.5 30.5 27 28.5 29.5 Field pH 6.5-8.5 ic.5,7; 5.7< 5.7: Lea 6,0 5.9. „6.3 :i.6250., Odor x None None None None None None None None Sulfur Appearance x Clear Turbid Clear Clear Turbid Clear Rusty Clear Milky • LABORATORY ANALYSES Lab pH x 5.8 6.1 6.2 6.0 6.2 5.8 6.3 6.4 6.3 Total Phosphorus, P(mg/t) ns 0.24 0.17 0.26 97.5 100.3 86.8 20.2 28.2 25.7 Fluoride, F(mg/1) 2.0 0.14 0.14 0.15 0.18 1.19 0.18 0.14 0.12 0.10 Chloride, Cl(mg/1) 250 283322 324 91 108 112 87 98 98 Sulfate, SO4(mg/1) 250 92 107 94 50¢ $15a 517# 659; 67 A?!. Total Dissolved Solids, TDS(mg/1) 500 7845 896a 700': 1146 1533; 1365 2018: 2002, r2140. Total Organic Carbon, TOC(mg/1) ns 11 8 6 7 8 8 11 10 10 ns: Not Specified : Exceeds Subchapter 15 NCAC 2L.0202 Maximum Contaminant Level (MCL) dam:# ass ma _ uins mxva jimagasii Table 3-4 Parameter GROUNDWATER QUALITY AT WELL -POINT SAMPLING LOCATION WPTF-1 Subchapter Undifferentiated Surficial Deposits Croatan Formation 2L.0202 MCL WPTF-1A WPTF-1B WPTF-IC WPTF-ID • FIELD MEASUREMENTS Sampling Date' x 03/14/89 03/14/89 03/15/89 03/15/89 Sampling Depth (feet) x 3.00 - 3.75 11.25 - 12.00 25.25 - 26.00 46.25 - 47.00 Specific Conductance, (µmhos/cm) ns 3,100 11,000 2,100 2,800 Temperature (°C) x 13 17 22 • 27.5 Field pH 6.5-8.5 1643 i.:4*.!:!1! 6.4 6.5 Appearance x SI. Cloudy Yellowish Clear SI. Cloudy • LABORATORY ANALYSES Lab pH x 6.1 Total Phosphorus, P(mg/1) ns 87.0 Fluoride, F(mg/1) 2.0 0.23 Chloride, CI(mg/1) 250 69 Sulfate, SO4(mg/1) 250 1,S62 Sodium, Na (mg/1) ns 280 Total Dissolved Solids, TDS(mg/1) 500 Total Organic Carbon, TOC(mg/1) ns 4.3 6.1 6.2 5,275 34.5 34.3 0.12 0.43 0.37 104 115 195 2,555< S87€ 727 712 256 308 3iS08 20,076 77Qi 11)g1 12 52 11 13 ns: Not Specified 13: Exceeds Subchapter 15 NCAC 2L.0202 Maximum Contaminant Level (MCI.) PAWIT-2A.S pH 2" 6.4 P = 0.15- F -= 0.18 SO4 = 308 TDS et 973 TOC = 11 WPTF-1A 5 pH = 6.2 P = 87.0 F = 0.23 SO4 = 1862 'TDS =•3508 TOO MWTF-3A F zr- 0.14- 904 = 99 TDS = 794 TOC r 8.3 -5 MWTF-1A pH 6.8- P = 0.40 F = 0.71 SO4 74 TDS = 325-, ; TOC = 5.7• GROUNDWATER QUALITY IN SURFICIAL SAND LAYER 100 200 SCALE - 1" 150' CONCENTRATIONS IN mg/1 N2Mii fl Ardaman & Associates, Inc. rcAsConsulting Engineers In Son Methinks, Foundations, end Marble Twins SUPPLEMENTAL REMEDIAL ACTION PLAN TANK FAFIM AREA 7E/IASI:Mir INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA • loss,: 9M21159 04, Al" Or ARE •101100DIY; F,LI. IAM • 1 MWTF-2B S,. pH q 6.4 — P =. 65.6/50 F - 1.61 SO4 - 355/636 TDS =•1497/101 .. TOC=9.7 WPTF-1C pH=6.1 P=34.5453 ...._.... F = 0.43 SO = 567/P-2-5. = 77 0/26(20:. = 11 s MWTF-B--' H6.0 __..... .-.:, p v'=94.9/A.-r......... SO4 m 512-- /" ,.,TDS = 13 a/^•ig JD,;•� TOC = 7.7 r:nl S MWTF•1B pH = 5.6 p = 0.19/%.3 F = 0.27 SO4 = 17/10 • TDS = 536 $ GROUNDWATER QUALITY IN CONFINED SAND LAYER 0 • 100 200 larr 121 Ardaman 6 Associates, Inc. usaltbe FoyEngineers SoilunI=• Foundations, NmtYo Twin SUPPLEMENTAL REMEDIAL ACTION PLAN TANK FARM A TEEXASOU FAINC. PHOSPHATE OPERATIONS AURORA, NORTH CAROIJNA r eSCALE 1•1150' ycbNOENTRATIONS IN.mg& WAt^ n nu w: 9 • MWTF-2C s pH = 6.3 P = 15.6 F = 0.17 SO4 = 874fro fey 1DS..= 2337/4..wo TOC = 12 WPTF-1D 6) pH = 0.5 P = 34.2 F = 0.37 r 4 = 727431$ = 084,ip •• pH 6.1 SO4 = 6474.6a— ' 36 = ,:3„TOC 10.3 MWTF-1C pH = 6.9- P = 0.15 F 0.38 SO4 = 59/0 TOS = 538A4b. TOC 4.3 . GROUNDWATER QUALITY IN CROATAN FORMATION 'taNCENTHATithiSIN mg/l Mr Ardaman & Associates, Inc. rageNConsulting Enginws In Soil Machanta, Foundations, and Mantis's Tasting SUPPLEMENTAL REMEDIAL ACTION PLAN TANK FARM AREA . TEXASOULF INC. PHOSPHATE OPERATIONS • AURORA; NORTH CAFIOUNA oft. sy, ABE 01000 or. a/22M_ ,`4, • 57:„Irgni,t;V47f:a. .d. • , T ;;;:r1S:At'it kAer 1 Texasgulf Inc. File Number 88-089 Section 4 SUPPLEMENTAL REMEDIAL ACTION PLAN 4.1 Introduction 4-1 This section presents a proposed remedial action system to supplement the remedial actions already undertaken in the tank farm area. The objectives of and a preliminary design for the supplemental remedial action system is presented, a time schedule for implementation is discuss/ill, and a continuing groundwater monitoring plan for evaluation of the effects of the system on abating groundwater contamination are outlined. 42 Objectives of Supplemental Remedial Action Plan The objectives of the supplemental remedial action plan are to: (i) minimize and contain future spills from tanks and associated pumps and pipelines in the tank farm (source control); (ii) containment of contaminants in the surficial aquifer to protect the adjacent Pamlico River barge slip from impacts from existing groundwater contamination; and (iii) removal of contaminated groundwater in the surficial aquifer. To achieve these objectives, the following three element remedial action system will be undertaken. • Continue the on -going program of installation of new containment facilities to contain leaks/spills around the piperack, and phosphoric acid and super phosphoric acid tanks. • Install a cut-off wall along the north wall of the tank farm to contain the contaminants in the surficial aquifer and protect the adjacent Pamlico River barge slip. • Install dewatering wells along the inside of the cut-off wall tapping the confined sand layer to remove existing contaminants. 4.2.1 Installation of New Containment Facilities Tank 008 has been repaired, as described in Section 1.1, and accordingly the source of contamination as identified in the August 8, 1988 notice of noncompliance has been removed. The underground drain line identified in the September 1, 1989 notice of violation has been repaired, and accordingly this source of contamination has also been removed. The new main east -to -west piperack spill containment system is largely installed, and is scheduled for completion by December 1989. Previously, spills from the piperack could occur onto the ground with the potential for groundwater contamination. The new spill containment slab will minimize the potential for spills from the piperack from entering the groundwater, and therefore to a large degree removes the main east -to -west piperack as a source of groundwater contamination. j i Texasgulf Inc. File Number 88-089 4-2 The long-term program to minimize and contain leaks/spills around the phosphoric and super phosphoric acid tanks is also underway. The relocation and reconstruction of Tank 044 is already complete, and Tank 016 has been relocated with reconstruction scheduled for completion by December 1989. Presently, construction plans are to relocate and rebuild Tanks 007, 008, 009 and 013 in 1990, Tanks 015, 017, 019, 021 and 023 in 1991, and Tank 006 in 1992. These tanks are being relocated and rebuilt on new foundations with concrete spill containment pads and lined drainage ditches. The rebuilding program will both greatly improve the tank farm spill containment capabilities and minimize the potential for spills from the tanks. The installation of the new containment facilities on the piperack and tanks, although a passive feature of the remedial action system, is an important step in abating groundwater contamination in the tank farm area. Without source control, future spills and leaks would continue to introduce new contaminants into the surficial soils Accordingly, the long-term maintenance of improved groundwater. quality in the tank farm area requires, as much as practical, the prevention of contaminants from entering the surficial soils. 4.2.2 Installation of Cut -Off Wall As presented in Section 2.5, the direction of groundwater flow in the surficial sand layer and confined sand layer is generally northward. At downgradient monitor well clusters MWTF-2 and MWTF-3, impacts have been detected in the confined sand layer (Section 3.3.1.2). Groundwater quality in the surficial sand layer at the downgradient monitor wells, however, remains largely unaffected (Section 3.3.1.1). To contain the existing contaminants in the confined sand layer and any potential future contamination in the surficial sand layer, an approximately 800-foot long vertical soil- bentonite backfilled cut-off wall constructed using the slurry trench method will be installed on the north side of the tank farm (Figure 4-1).* The cut-off wall will be excavated through the surficial and confined sand layers and keyed into the top of the clayey sand to plastic clay layer underlying the confined sand layer (Figure 4-2). The cut-off wall will be designed and constructed to provide an average soil-bentonite backfill thickness of 2.5 feet and coefficient of permeability of equal to or less than 1x107 cm/sec, or an equivalent ratio of permeability to thickness (i.e., and therefore the same effectiveness). Installation of the cut-off wall will prevent the existing northward flow of groundwater within the surficial aquifer across the tank farm area. Accordingly, to collect the groundwater flow that would naturally occur across the area and prevent flow around the ends of the cut-off wall, the existing drainage ditch along the north_ side of the. tank farm will be used.. to_ collect seepage in the surficial sand layer. Seepage in the confined sand layer will be collected by the dewatering wells (see Section 4.2.3). • The alignment of the cut-off wall depicted in Figure 4-1 is conceptual and will be finalized during design of the containment system to accommodate existing facilities in the area. The length of the return on the west end of the cut-off wall will also be , selected during final design to accommodate field conditions. c'v4 ( .diaa r,rOO. "`A • r 1 1 1 1 11 1 Texasgulf Inc. File Number 88-089 4-3 4.2.3 Installation of Dewatering Wells A series of five dewatering wells on about 150-foot centers tapping the confined sand layer will be installed on the inside (south side) of the cut-off wall to remove contaminants from the surficial aquifer. The wells will be operated such that a maximum piezometric water level of 2 feet (MSL) is achieved in the confined sand layer between the wells, creating a "low point" in the confined ,sand piezometric water level to prevent flow around the ends of the slurry wall. It is expected that about 5 to 10 gal/min of groundwater will be removed by the dewatering system. Because of downward_seepage..from the_surficial_sand layer (Section 2.5), dewatering of the confined sand layer will also-resultin the_removal-of contaminants from the,surficial sand layer as they migrate downward into the confined sand lamer. Groundwater removed by the dewaten cvstem will be_ptuum.1 either_eaosting_�� Cooling Pond No. 1 or No.2. (tiez� ometers will be installed at the locations depicted in Figure 4-1 to verify that the dewatering system is lowering the piezometric water levels in the confined sand layer as projected. • The dewatering wells will be operated as long as needed to lower the groundwater total phosphorus concentration in the confined sand layer to a t get clean-up value of 5 mg/1.* Clean-up concentrations are not proposed for other groundwater quality parameters. Fluoride concentrations in the confined sand layer are presently below the Subchapter 2L.0202 maximum contaminant level (Section 3.3.1.2). Sulfate and total dissolved solids concentrations are elevated in the confined sand layer, but the brackish water is high in these constituents and therefore is not impacted by these groundwater contaminants. Attainment and maintenance of the proposed total phosphorus target clean-up concentration of 5 mg/1 in the confined sand layer, however, will require the control of future spills and leaks from the piperack and tanks within the new containment facilities. Abatement of groundwater contamination in the surficial aquifer will result in the eventual abatement of groundwater contamination in the underlying Croatan formation as the source of contaminants in the Croatan aquifer (i.e., contaminants seeping downward from the surficial aquifer) are removed. Accordingly, measures to directly lower the total phosphorus concentration in the Croatan formation are not proposed. 43 Time Schedule for Implementation of Supplemental Remedial Action System The following time schedule is proposed for implementation of the supplemental remedial action system. • The detailed design, construction drawings and specifications for the cut-off wall and dewatering well remedial action system will be submitted to the DEM 120 days after DEM approval of the supplemental remedial action plan. • The total phosphorus target clean-up concentration of 5 mg/l is the existing total phosphorus daily average discharge limit for stormwater outfalls 005, 006, 007 and 009 ' into the Pamlico River on the north side of the,phosphate operations. itusk. l&oZi,, .�... &crwyt. 5 4n "AIC%. ZV .w v 1 1 1 1 4 I Texasgulf Inc. File Number 88-089 4-4 • 'The remedial action system will be completed and in operation by January 1, o 1991. • Installation of the new piperack and tank containment facilities will continue as presently planned, with completion scheduled for the end of 1992. 4.4 Groundwater Monitoring for Evaluation of Remedial Action System Groundwater monitoring will continue in the existing nine monitor wells and FERT-1 Castle Hayne aquifer water supply well on a quarterly basis. After installation of the cut-off wall and dewatering wells, quarterly monitoring will continue at the MWTF-1 well cluster and the FERT-1 well, and quarterly water quality measurements will be obtained on groundwater withdrawn from the dewatering wells. Piezometers installed to monitor water level elevations in the confined sand layer .will also be read quarterly. Quarterly determinations of water quality at the dewatering wells will consist of the parameters listed in Section 3.1.1 as presently undertaken as part of the quarterly monitor well sampling program. After the target clean-up concentration of total phosphorus is attained, pumping of the confined sand layer will be stopped. Quarterly groundwater monitoring for a period of 1 year after the termination of pumping, and thereafter annually, will be implemented at two of the wells to allow continuing evaluation of the effectiveness of the remedial action system. 1 1 1 1 1 4 •, .! • CUT-OFF WALL DEWATERING WELL ' PIEZOMETERS • rt • _ -2 .• Q • - A.7, • • 5- , • CUT-OFF WALL AND DEWATERING WELL CONTAINMENT SYSTEM CONCEPTUAL SITE PLAN 200 SCALE le 150' Ardaman & Associates, Inc. estAiConsulting Engiren In Soil MoctunIcs. Foundation', and Materials Toting SUPPLEMENTAL REMEDIAL ACTION PLAN TANK FARM AREA TEXASOULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CATIOLJNA cti,PrAtt FIGURE 4-1 ELEVATION 0 -10 -20 -30 -40 -50 SOIL-BENTONITE CUT-OFF WALL PAMLICO RIVER BARGE SLIP 0 100 HORIZONTAL DISTANCE 200 DEWATERING WELLS DRAINAGE DITCH SULFUR TANKS PHOSPHORIC ACID TANKS FINE SAND TO CLAYEY FINE SAND CLAYEY FINE SAND TO PLASTIC CLAY CLAYEY FINE SAND WITH SOME SHHEELLLFF CLAYEY TO SILTY FINE SAND • AND SHELL FRAGMENTS (CROATAN Fm) 300 \CLAYEY FINE SAND TO SANDY PLASTIC CLAY (YORKTOWN Fm) I 400 500 60 SCHEMATIC CROSS SECTION OF CUT-OFF WAL AND DEWATERING WELL CONTAINMENT SYSTE Appendix A MONITOR WELL INSTALLATION RECORDS is 11 1 FOR OFFICE USE ONLY 1 NORTH CAROLitA D9ART EKr OF NA11.MAL IL ES ANO COASUNITY DEVELOPMENT ' DIV12110NOF B/IARON.ENTAL MANAGE]N: . ' GROUNDWATER SECTION •- P.O. SOX 27E57 - RAWE &N. « 27611. PHONE (919) 733-5083 WELL CONSTRUCTION RECORD •WELL NUMBER MNTF1-A 1 DRILLING CONTRACTOR Ardaman 8 Associates, Inc. 1019 STATE WELL CONSTRUCTION DRILLER REGISTRATION NUMBER PERMIT NUMBER- 06-0071-WM-0156 Quad. No. Serial No. Lat. Long. Pc Minor Basin Basin Code Header Ent GW-1 Ent. 11. WELL LOCATION: (Show sketch of the location below) Nearest Town. Aurora, North Carolina County: Beaufort 1 (Road. Community. or Subdivision and Lot No.) Depth DRILLING LOG From To Formation Description 2. OWNER Texasgulf Inc. P.O. Box 48 • SEE ATTACHED BORING LOG IADDRESS Aurora, Nort(aitruatrol ina No.) 27806 City or Town State Zip Code 13. DATE DRILLED 10-27-88 USE OF WELL Monitoring 4. TOTAL DEPTH 6.4' CUTTINGS COLLECTED 0 Yes ■ No 5. DOES WELL REPLACE EXISTING WELL? ❑ Yes II No 13. STATIC WATER LEVEL: 1.86* FT p above TOP OF CASING. TOP OF CASING IS O** 0 belowFT ABOVE LAND SURFACE. 17. YIELD (gum): X METHOD OF TEST X B. WATER ZONES (depth): X 9. CHLORINATION: Type None Amount X 0. CASING: Wall Thickness Depth Diameter or Weight/Ft. Material PVC 2" Sch 40 LOCATION SKETCH From O• D To 3.4 Ft(Show direction and distance from at least two State Roads. From To Ft or other map reference points) It From To Ft. SEE ATTACHED MONITOR WELL LOCATION PLAN 1. GROUT: If additional space is needed use back of form. Depth Material Method From 0.0 To 1.7 Ft. Neat Cement Trermie *Static water level on 12-07-88 From To Ft. **Monitor well in leak resistant steel manhole 12. SCREEN: Depth Diameter Slot Size Material From 3.4 To 6.4 Ft. 2 in. 0.01 in. PVC Fram To Ft. ;n. in. NOTE: Total depth of well, and the casing, From To Ft in. in. grout, screen, gravel pack and bentonite seal depths are referenced from the top of 13. GRAVEL PACK: the PVC well casing in the steel manhole. Depth Size From 2.9 To 6.4 F1. 8/16 Material Silica Sand From To F t. .•'REItARKs: '.Bentonite seal from 1.9 to 2.9 feet t - TDO HEREBV'CERTIFY THAT THIS WELL WAS CON&RUU T D IN CCOR ANCE WITH 15 NCAC 2C. WELL CONSTRUCTION SD TA ARDS. AND THAT A COPY OF THIS RECOR t AMEN O ED TO E WELL OWNER. • 12-27-88 SIGNATURE OF CONTRACTOR OF$ AGENT DATE Submit onninal to Division of Environm.n,,i M.n.n..n.nt mewl nnnv ,n wall n.mnr. l�t'k1?`'ku _ .e.r'[.r, �. ...,. r..,• ...e �..L�Y44r .i ��.e!.3f.�u§3?r ..U,'.:,.... ,,: Lit%::i;;. z FOR OFFICE USE ONLY NORTH CAROU$1.4 boPARTLENn OF NATURAL RE ES APO cowman. DEVELOPMENT DIVISION OF E)IVIRpN1..ENTAL MN4M LE_.- DROIRDWATEH SECTION P.O. BOX 275e7 - RAIEIO/LrLC. 27811. PHONE (a 19) 733-5083 WELL CONSTRUCTION RECORD WELL NUMBER MWTF1-B DRILLING CONTRACTOR Ardaman & Associates, Inc. DRILLER REGISTRATION NUMBER 1019 Quad. No. Serial No. Lat Long. Pc Minor Basin Basin Code Header Ent GW-1 Ent._. STATE WELL CONSTRUCTION PERMIT NUMBER- 06-0071-WM-0156 WELL LOCATION: (Show sketch of the location below) Nearest Town: Aurora; North Carolina (Road. Community. or Subdivision and Lot No.) 2. OWNER ti ADDRESS Texasgulf Inc. P.O. Box 48 tr etarolTor Rouna te No.) Aurora, Nort( �i L27806 City or Town State "Zip Code 10-26-88 USE OF WELL Monitoring 13.5' CUTTINGS COLLECTED' ❑ Yes al No . DATE DRILLED 4. TOTAL DEPTH County: Beaufort Depth DRILLING LOG From To Formation Description SEE ATTACHED BORING LOG DOES WELL REPLACE EXISTING WELL? . STATIC WATER LEVEL: 2.35* FT TOP OF CASING IS 0** FT ❑ Yes 11 No ❑ above TOP OF CASING m below ABOVE LAND SURFACE. • YIELD WPM):X METHOD OF TEST X . WATER ZONES (depth): X . CHLORINATION: 0. CASING: Typo none Depth From 0.0. To 10.6 From To To From GROUT: Amount X Wall Thickness Diameter or Weight/Ft. Material FI 2" Sch 40 PVC FI FI Depth Material Method From 0.0 To 8.0 Ft. Neat Cement Tremmie From To FI. SCREEN: Ft: Depth From 10.6 To 12.6 "From To FI. ..'From To Ft '3. GRAVEL PACK: Diameter If additional space is needed use back of form. LOCATION SKETCH (Show direction and distance from at least two State Roaos. or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN *Static water level on 12-07-88 **Monitor well in leak resistant steel manhole Slot Size Material Ft. 2 in. 0.01 in. PVC Depth Size earn 10.0 to 13.5 F1. 8/16 From To Ft— pKs;: "Bentonite seal from O HEREBY 'CERTIFY TAT THIS WELL WAS CONST STANDARDS. AND THAT A COPY OF THIS RECORD in. in. in. in. Material Silica Sand 8.3 to 10.0 feet NOTE: Total depth of well, and the casing, grout, screen, gravel pack and bentonite seal depths are referenced from the top of the PVC well casing in the steel manhole. ORI3ANCE WITH 15 NCAC 2C. WELL CONSTRUCTION TO iE WELL OWNER. a 12-27-88 SIGNATURE OF CONTRACTOR OR i4GENT DATE Submit onainal to Division of Envirnnmonmt ,.dn...o.,..ar 'n.. rants On wall ..Wnst I12. SCREEN. Depth Diameter Slot Size Idatenal From 38.7 To 40.7 Ft. 2 in. 0.01 m. PVC { From To FI. in. in. From To Ft in in. 13. GRAVEL PACK: _ Depth Size Material • From 36.3 To 42.0 F1. 8/16 Silica Sand • From 4. REMARKS: To Ft. Bentonite seal from 34.3 to 36.3 feet NCRTH CAROLI4A MP. ARTLIENT OF NATURAL RES ES AND COMMUNITY DEVELOPMENT DNISION OF EHVAIONIENTAL IA4AOELOII - GROUNDWATER SECT)ON P.O. RO2 270e7 - RAUDONPLC. 27611. PHONE (070) 733-5083 WELL .CONSTRUCTION RECORD WELLNUMBER MWTF1-C IDRILLING CONTRACTOR Ardaman & Associates, Inc. DRILLER REGISTRATION NUMBER 1019 11. WELL LOCATION: (Show sketch of the location below) Nearest Town: Aurora, North Carolina County: Beaufort Depth DRILLING LOG FOR OFFICE USE ONLY Quad. No. Serial No. Lat Long. Pc Minor Basin Basin Code Header Ent GW-1 Ent. STATE WELL CONSTRUCTION PERMIT NUMBER. 06-0071-WM-0156 ((Ioad. Community, Or Subdivision and Lot NO.) 2. OWNER IADDRESS Texasgulf Inc. From To Formation Description P.O. Box 48 SEE ATTACHED BORING LOCH Aurora, NoratruarolinaeNoJ 27806 City or Town State Zip Code 13. DATE DRILLED 10-26-88 USE OF WELL Monitoring 4. TOTAL DEPTH 42.0' CUTTINGS COLLECTED ❑ Yes • l No DOES WELL REPLACE EXISTING WELL? ❑ Yes la No 1i. STATIC WATER LEVEL: 14. 65* FT 0 above TOP OF CASING. TOP OF CASING IS O** M below FT ABOVE LAND SURFACE. 17. YIELD (gpm): X METHOD OF TEST X 1 a. WATER ZONES (depth): X 13. CHLORINATION: Type None 0. CASING: Amount X Wall Thickness ` From 0.0 Depth Diameter or Weight/Ft. Material To 38.7 Ft 2" Sch 40 PVC From To Ft I From To Ft. 1 1. GROUT: Depth Material Method If additional space i5 needed use back of form. LOCATION SKETCH (Show direction and distance from al least two State Roads. or Other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN From 0.0 To 34.1 FL Neat Cement Tremmie *Static water level on 12-07-88 } From To Ft. **Monitor well in leak resistant steel manhole NOTE: Total depth of well, and the,casing, grout, screen, gravel pack and bentonite seal depths are referenced from the top of the PVC well casing in the steel manhole. „TDO HEREBY CERTIFY TRAT THIS WELL WAS CONST CTED IN AC RDAWCE WITH 15 NCAC 2C. WELL CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS RECORD N EN PROVIDE9JTO TFi WELL OWNER. fl 12-27-88 SIGNATURE OF CONTRACTOR OR AGENT DATE Submit orloinal to Division of Envirnmman,,i ,r..... ....... ,.-.. r..n.. In wall nwn•r 1 NORnh •c/u,011lA OOARrie4T CF NATURAL R ; ICES AIO COMMUNITY DEVELOPLFNT DIVISION OF BNIRON EE71i<AL►WNAO Se4t - GROUNDWATER SECTION P.O.'DOX 27tta7-RMDGULC. 27611. PHONE (919) 733-Sofia WELL CONSTRUCTION RECORD WELL NUMBER MWTF2—A IDRILLING CONTRACTOR Ardaman & Associates, Inc. DRILLER REGISTRATION NUMBER 1019 FOR OFFICE USE ONLY Quad No Serial No. Lat Long Pc Minor Basin Basin Code Header Ent GW-1 Ent. STATE WELL CONSTRUCTION PERMIT NUMBER. 06-0071-WM-0156 1. WELL LOCATION: (Show sketch of the location below) Aurora, North Carolina County: iNearest Town: Beaufort (Road. Community. or Subdivision and Lot No.) Depth DRILLING LOG 2. OWNER Texasgulf Inc. From To Formation Description ADDRESS P.O. Box 48 SEE ATTACHED BORING LOG Aurora, NoratrLarolina No') 27806 i3. DATE DRILLED 10-21-88 USE OF WELL Moni tori rig City or Town State Zip Code 4. TOTAL DEPTH 13.0' CUTTINGS COLLECTED ❑ Yes ■ No 115. DOES WELL REPLACE EXISTING WELL? 0 Yes v No 5. STATIC WATER LEVEL: 7.36* FT 0 above TOP OF CASING, ■ below TOP OF CASING IS FT ABOVE LAND SURFACE. 13.25 7. YIELD (gpm): X METHOD OF TEST X -. 8. WATER ZONES (depth): X , 1 9. CHLORINATION: Type None Amount 10. CASING: X Wall Thickness Depth Diameter or Weight/Ft. Material From 0.0 To 10.2 Ft 2" Sch 40 PVC From To Ft From To Ft. 1. GROUT: 9 Depth Material Method 4 From 0.0 To 7.0 Ft. Neat Cement Tremmie From To FI. 112. SCREEN: Depth Diameter Slot Size Material From 10.2 To 12.2 Et. 2 in. 0.01 in. PVC From To Ft. in. in. From To Ft. in. in. 113. GRAVEL PACK: Depth Size From 8.9 To 13.0 FL 8/16 From To Ft._ Material Silica Sand {&REruR((s: .Bentonite seal from 7.3 to 8.9 feet If additional space is needed use back of form. LOCATION SKETCH (Show direction and distance from at least two State Roaos. or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN *Static water level on 11-30-88 731)0HEREBY'CERTIFY TRAT THIS WELL WAS CON ' RUCTED IN A OR ANCE WITH 15 NCAC 2C. WELL CONSTRUCTION - STANDARDS, 'AND THAT A COPY OF THIS RECORD EN PROMTO ( ' WELL OWNER. \^ 4l vV1/0 ' �'_ 12-27-88 SIGNATURE OF CONTRACTOR OR GENT DATE Submit onoinal to Division of Envirnnmen.m b .ntn.men. +nw ..nnv .n. Well n.rri r, NORTH CACAROUNA p9ARTLIENT OF NATURAL I SCEs Atc CO1.ed)a)Y Dcvaopwla �.' OIVti10N Of nwmONme(7AL►ANAGE„ - GRCEINDWATOT SECTION ;<1,A.`81:)( heel RAWGULC. 27611. PHONE (DID) 733-5083 ELL°CONSTRUCTION RECORD WEtL HUfaBER . STF2-8 bRILLWOCONTRACTOR Ardaman & Associates, Inc. 'DRILLER'RECi1STRATION NUMBER 1019 FOR OFFICE USEONLY c. . Quad. No. Serial No. Lat Long. Minor Basin Basin Code Header Ent GW-1 Ent. Pc STATE WELL CONSTRUCTION PERMIT NUMBER- 06-0071-WM-0156 1 1.' WELL LOCATION: (Show sketch of the location below) 'Neareit Tovrn• Aurora, North Carolina (Road. Community. or Subdivision and Lot No.) 2. OWNER IADDRESS Texasqul f .Inc. P.O. Box 48 Aurora, NorairLatrolRnae No.) 27806 City or Town State Zip Code 3. DATE DRILLED 10-21-88 USE OF WELL Monitoring County: Beaufort Depth DRILLING LOG From To Formation Description SEE ATTACHED BORING LOG 4. TOTAL DEPTH 21.5' CUTTINGS COLLECTED ❑ Yes ® No 5. 6. DOES WELL REPLACE EXISTING WELL? STATIC WATER LEVEL: 9.80* FT. TOP OF CASING IS 3.15 FT 7. YIELD (gpm): • X ❑ Yes 0 No ❑ above TOP OF CASING ■ below ABOVE LAND SURFACE. METHOD OF TEST X 8. WATER ZONES`(depth)• • X 19. CHLORINATION: Type None 10. CASING: Depth From 0.0 To 18.8 Ft From 131 From ! 1.'GROUT: To Ft Amount X Wall Thickness Diameter or Weight/Ft. Material 2" Sch 40 PVC To Ft. Depth Material From 0.0 To 15.0 Ft. Neat Cement From To Ft. 12. SCREEN_ Method Tremmie Depth Diameter Slot Size From 18.8 To 20.8 Ft. 2 in. 0.01 in. Fran) To Ft. in. _ in. From To Ft in. in. 13.GRAVEL PACK: Depth Size 17.0 To 21.5 FL 8%16 To Ft. - From• ' From, `4 'REMARKS:' Bentonite seal from 15.4 TDO HEREBY CERTIFY TAT THIS WELL -11 STANDARDS. AND THAT A COPY OF THIS rv1, _Rov(tiodl, V84 Material PVC Material Silica Sand to 17.0 feet It additional space is needed use back of form. LOCATION SKETCH (Show direction and distance from at least two State Rcacs. or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN *Static water level on 11-30-88 • WAS CONSTRqL)CTED IN ACCODANCE� WITH 15 NCAC 2C, WELL CONSTRUCTION RECORD HATS EEN PROVIDED THE 'NW. OWNER. tabir yifL 12-27-88 SIGNATURE OF CONTRACTOR OR AGENTj DATE Submit oriainal to Division of Envirnnman,ei a ,..anano. ,,.wall rumor NORM Ci1R011ihtbErARItmory ,W17tmAL ltEsotl nro = aTY pEvEloPserr DeAn Orr c .DM Kyµ.Caearf _-OtRCWATEB SECTION _ is w.�tna Rusoew a lye t 1. PHONE rote) Tao-soea "-K 1k: K :ice WELL; CONSTRUCTION RECORD rrESNUMBERJ I44TF2=L':;. '' "�` ' '° ''Ardaman 8 Associates, Inc. Rtl.l. W a'CONTR ALTO R 1019 )KILLER_ REG S_TRATION NUMBER FOR OFFICE USE ONLY Quad. No. Serial No Lat. Long. Pc Minor Basin Basin Code Header Ent. GW-1 Ent. STATE WELL CONSTRUCTION PERMIT NUMBER. 06-0071-WM-0156 WELL LOCATION: (Show sketch of the location below) Nearelet Town: Aurora, North Carolina county: Beaufort Depth DRILLING LOG (Road. Community. or Subdivision and Lot No.) OWNER Texasgulf Inc. ADDRESS P.O. Box 48 ( it el caror Route No.] Aurora, Nortrtoltna 27806 City or Town State Zip Code DATE GRILLED 10-22-88 USE OF WELL Monitoring TOTAL DEPTH 42.5' CUTTINGS COLLECTED ❑ Yes II No DOES WELL REPLACE EXISTING WELL? ❑ Yes II NO STATIC WATER LEVEL: 16.03* FT 0 above TOP OF CASING. 323 ■ below . TOP OF CASING IS FT ABOVE LAND SURFACE. . YIELD (gpm): X METHOD OF TEST X . WATER ZONES (depth): X .CHLORINATION: Type None Amount X J. CASING: Wall Thickness Depth Diameter or Weignt/Ft. Material From 0.0 To 39.7 Ft 2" Sch 40 PVC From To Ft From To Ft. t. GROUT: From To Formation Description SEE ATTACHED BORING LOG If,additional space is needed use back of form. LOCATION SKETCH (Show.direction and distance from at least two State Roacs. or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN Depth Material Method From 0.0 To 36.0 FI. Neat Cement Tremmie *Static water level on 11-30-88 From To Ft. 12. SCREEN: Depth Diameter - Slot Size Material From 39.7 To 41.7 Ft 2 in. 0.01 in. PVC From To Ft. in. in. '( From To Ft in. in. 13. GRAVEL PACK: Depth Size Material From 36.0 To 42.5 Ft. 8/16 Silica Sand From To Ft. '.REMARKS: Bentonite seal from 36.3 to 38.0 feet TDO HEREBY'CERTIFY THAT THIS WELL WAS CONST CTED IN ACC ROANCE WITH 15 NCAC 2C, WELL CONSTRUCTION L .', ..STANDARDS; AND THAT A COPY OF THIS RECORD N PROVIDED O WELL OWNER. ,O . !n- 12-27-88 DATE SIGNATURE OF CONTRACTOR OR A gihmil onninal to flivieinn of Pnvirnn...n.,..., .• • FOR OFFICE USE ONLY 1 NORTH CNVJi11f1 DEPARTMENT,OF NATURAL. I IRCES AND COLA/1ATY DEVELOPIANT DMSION OF 9iWiON.®(TAL ANHAGE.:.=.;. GROl10WATER SECTION ;P.O. BOX 276S7 - RALEIGH.tLC. 27611. PHONE (910) 723-6083 WELL CONSTRUCTION RECORD -WELL-NUMBER MWTF3-A DRILLING CONTRACTOR Ardaman & Associates, Inc. DRILLER REGISTRATION NUMBER 1019 i1. WELL LOCATION: (Show sketch of the location below) Nearest Town- Aurora, North Carolina County: Beaufort (Road. Community. or Subdivision and Lot No.) Depth DRILLING LOG From To Formation Description 2. OWNER Texasgul f Inc. Quad. No. Serial No. Lat Long. Pc Minor Basin Basin Code Header Ent GW-1 Ent. STATE WELL CONSTRUCTION PERMIT NUMBER: 06-0071-WM-0156 ADDRESS P.O. Box 48 SEE ATTACHED BORING LOG Aurora, NoratrLatrolinaeNO') 27806 City or Town State Zip Code 3. DATE DRILLED 10-24-88 USE OF WELL Monitoring 4. TOTAL DEPTH 13. 91 CUTTINGS COLLECTED ❑ Yes ® No 5. DOES WELL REPLACE EXISTING WELL? ❑ Yes I■ No 6. STATIC WATER LEVEL: 4.62* FT 0 above TOP OF CASING. TOP OF CASING IS 0** FT A■VBOVEow E LAND SURFACE. 7. YIELD (gpm)- X METHOD OF TEST X B. WATER ZONES (depth): - X 9. CHLORINATION: Type None 10. CASING: Amount X Wall Thickness Depth Diameter or Weight/Ft. Material From 0.0 To 10.9 Ft 2" Sch 40 PVC From From 11. GROUT: Depth Material Method To -Ft To Ft. From From j. 2. SCREEN: II additional space is needed use back of form. LOCATION SKETCH (Show direction and distance from at least two State Roads. or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN 0.0 To 7.8 FI. Neat Cement Tremmie *Static water level on 12-07-88 To Ft. **Monitor well in leak resistant steel manhole Depth Diameter Slot Size Material From 10.9 To 12.9 Ft 2 in. 0.01 m. PVC "Frgm To F1. in. in. NOTE: Total depth of well, and the casing, From To Ft. in ;n. grout, screen, gravel pack and bentonite ti2GR4EL seal depths are referenced from the top of a s{„ Depth the PVC well casing in the steel manhole. ' Size Material torn ""9.6 in 13.9 Ft 8/16 Silica Sand rom c. 1.:: ... To Ft.- RKs:- Bentonite seal from 8 1 to 9 6 feet DO HEREBYCERTIFY TAT THIS WELL WAS CON-FUCTED IN A COA NCE WITH 15 NCAC 2C. WELL CONSTRUCTION TAAO3.`AND THAT A COPY OF THIS RECORD EN PROM TO WELL OWNER a 12-27-88 • SIGNATURE OF CONTRACTOR OR AGENT DATE Submit original to Division of Envlrrininnn,,, I .wn..• wA en..., ,n who al lwu.w"r o'tt 1 • FOR OFFICE USE ONLY NORTH CaROUNEUa PAFITI R OF NATURAL RESOUR rto COt.188s+7r DEVELOPMENT DIVISION OF ENVIROMc(7AL, LMIAGE ENT - SECTION P.O.W OOX 27ee7- RAIi70LC. 27e11. PHOIE (010) 733-50e3 WELL CONSTRUCTION RECORD +ELL NUMBER Mb1TF3=B RILLING CONTRACTOR Ardaman & Associates, Inc. RILLER REGISTRATION NUMBER 1019 Quad. No. Serial No Lat. Long. Pc Minor Basin Basin Code Header Ent GW-1 Ent. STATE WELL CONSTRUCTION PERMIT NUMBER: 06-0071-WM-0156 WELL LOCATION: (Show sketch o1 the location below) Aurora, North Carolina Nearest Town: OWNER ADDRESS (Road. Community. or Subdivision and Lot No.) Texasqulf Inc. P.O. Box 48 (Street or Route No ) Aurora, Nortn arollna • 27806 DATE DRILLED TOTAL DEPTH City or Town ' State Zip Code 10-24-88 USE OF WELL Monitoring 27.2' CUTTINGS COLLECTED' ElYes IINo DOES WELL REPLACE EXISTING WELL? STATIC WATER LEVEL: 9•12* FT TOP OF CASING IS 0** FT YIELD (gem): ElYes II No 'IDabove TOP OF CASING. El below ABOVE LAND SURFACE. X METHOD OF TEST X WATER ZONES (depth): X CHLORINATION: Type None CASING: From From From .. GROUT: Amount X Wall Thickness Depth Diameter or Weight/Ft. 0.0 To 24.2 Fl To Ft To Ft Material 2" Sch 40 PVC Depth Material Method From 0.0 From 1. SCREEN: i To 22.3 Ft. Neat Cement Tremmie To Ft. Depth From 24.2 To Diameter 26.2 FL 2 ram To Fl. From I..GRAVEL PACK: To Ft Depth Size tOm 23.7 To 27.2 FI. 8/16 roii'•r• To Ft. se REmA(_y r4<Bentonite seal from 22.6 to 23.7 feet =-TDO HEREBYCERTIFY THAT THIS WELL WAS CONS - STANDAppS, ANO THAT A COPY OF THIS RECORD HQS Slot Size Material in. 0.01 in. PVC in. in. in in. Material Silica Sand County: Beaufort Depth DRILLING LOG From To Formation Description SEE ATTACHED BORING LOG If additional space is needed use back of form. LOCATION SKETCH (Show direction and distance from at least two State Roads. or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN *Static water level on 12-07-88 **Monitor well in leak resistant steel manhole NOTE: Total depth of well, and the casing, grout, screen, gravel pack and bentonite seal depths are referenced from the top of the PVC well casing in the steel manhole. 3CTED IN ACC RDAN E WITH 15 NCAC 2C. WELL CONSTRUCTION E N PROVIDED O THE; ELL QWNER. �tfl%1,t' Yrfll( 12-27-88 SIGNATURE OF CONTRACTOR OR AGE DATE Cnhmn nnninal In fliviainn of Fnvirnnmen,.• a ..... _ ••• ...•• ^^-•• ••• .pee n•en or Frain ,r '.t:• From li�i NORTH rC ,Itiz >1A�.p3t 1iuf .%f " P r I '.: .. /uarrt tr oF/IA IFJ .'ES Alto'eo&ware oevaopmerr :.ayµ•'/' .IT* tlIW6ln4 OF BNiWIW4T&L IWM0F/A GROUOWATER SECTION i I.O-DOi27a87-(INFSIYi 27e11. PIfOIE (919) 733-S053 WELL'CONSTRUCTION RECORD WEU. NUtdSEq 4-MtJTF3-C g::, i DRILLING CONTRACTOR fArdaman r . DRILLER '' REGISTRATION NUMBER & Associates, 1019 Inc. FOR OFFICE USE ONLY Quad. No. Serial No. Lat Long. Pc_ Minor Basin Basin Code Header Ent GW-1 Ent. STATE WELL CONSTRUCTION PERMIT NUMBER: 06-0071-WM-0156 i.•WELL LOCATIONleShow'Sketch of the location below) NearestTown: - Aurora; - North Carolina (Road. Community. or Subdivision and Lot No.) 2. OWNER ADDRESS Texasgulf Inc. P.O. Box 48 Aurora, Nort(nit`�arolinae No.) 27806 City or Town State Zip Code .. DATE DRILLED 10-24-88 USE OF WELL Monitoring 4. TOTAL DEPTH 47.7' CUTTINGS COLLECTED' 0 Yes M No DOES WELL REPLACE EXISTING WELL? ❑ Yes ® No . STATIC WATER LEVEL: 14.58* County: Beaufort Depth DRILLING LOG From To Formation Description SEE ATTACHED BORING LOG FT ❑ above TOP OF CASING. below TOP OF CASING IS O** FT ABOVE LAND SURFACE. YIELD (gpm): X METHOD OF TEST X WATER ZONES (depth) X . CHLORINATION: Type None Amount X 10. CASING: 1 From From From 1. GROUT: Depth 0.0 To44.7 To To Wall Thickness Diameter or Weight/Ft. Material Ft 2" Sch 40 PVC Ft Ft Depth Material From 0.0 To 41.8 Ft. Neat Cement From '.SCREEN: Depth From 44.7 To 46.7 To To :?;GRAVEL PACK: Diameter Ft. 2 Ft. F1. Depth Size From +'.43.5 To 47.7 Ft. 8/16 ',From ' - To - Ft.- aA�ucs:'-'Bentonite seal from 42.1 to 43.5 feet HEREBY CERTIFY TRAT THIS WELL WAS CO ,STA IDARDS, AND THAT A COPY OF THIS RECORH ,f,) w Method Tremmie 11 additional space is needed use back of form. LOCATION SKETCH (Show direction and distance from al least two State Roads. or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN *Static water level on 12-07-88 **Monitor well in leak resistant steel manhole Slot Size Material in. 0.01 in. PVC in. in. in in. Material Silica Sand NOTE: Total depth of well grout, screen, gravel pack seal depths are referenced the PVC well casing in the UCTED IN A , and the casing, and bentonite from the top of steel manhole. CORD NCE WITH 15 NCAC 2C. WELL CONSTRUCTION I TO r, E WELL OWNER. SIGNATURE OF CONTRACTOR OR AGENT Submit orioinal to Division of Envirnmm�nrei u 12-27-88 DATE ...n..• _-......... la ...all a ••••. Appendix B STANDARD PENETRATION TEST BORING LOGS 1 1 l 1 1 1 �.'.... ` . BORING LOG ARDAMAN & ASSOCIATES, INC. BORING NO. TF-1 TOTAL DEPTH 60.0 ft SHEET 1 of 2 PROJECT Remedial Action Plan - Tank Farm Area FILE NO. 88-089 CLIENT TexasguIf Inc BORING LOCATION Phosphate Qperations COUNTY Beaufort STATE North Carolina . ELEVATION 10.5'- feet (MSL) DATE STARTED 10-25-88 DATE COMPLETED 10-25-88 BORING TYPE Rotary wash with mud DRILLER/RIG Shanawav do Prather/CME-55 LENGTH/TYPE CASING 45 ft/6" dia hollow stem auger WATER TABLE DEPTH: 1st x DATE x TIME x 2nd x DATE x TIME x _ REMARKS Borehole grouted with cement-bentonite grout; Field Inspector: Ellingsworth Depth Standard Penetration Tat T nSTN 0-1sas Lab Data Soil Description rag Remarks (Unified Cls sification) tU Unduwed samcw L. CI u as u w Blows/6" N Value Sample No. NSt (%) -200 (%) LL (%) pI (%) - 3-6-6 12 1 - Light brown fine sand (SP) 2.0' - 1 -17-11-11 22 2 22 13 /. / / Light gray fi.te sand with small balls of clayey fine sand (SP) 5 0' _ __ _ 8-6-3 9 5-4-6 10 3 5.5' Dark brown clayey fine sand with roots (SC) 2 - - 4 24 59 / _ Gray and yellowish -brown sandy clay (CL) 8.0' _ Dark brown plastic clay (CH) 9.5' _ - 2-4-10 14 5 3 10 6 23 20 / / � 11.0' Brown silty fine sand (SM) q _ - _ Brown clayey fine sand with seams of fine sand (SC) - 15 2-1-5 6 7 31 47 /1/ 5.- - - 18.0' - Dark gray sandy clay with seams of fine sand (CH) _ 6 - 20 5-4-2 6 8 7 - 2"0' - Greenish -gray plastic clay with shell (CH) - - - 25 2-3-3 6 9 8 _28.5' - 9 0 3-3-4 7 10 34 25 //,-/ Greenish -gray clayey fine sand with shell (SC) 31.3't - - 10 - - - Greenish -gray clayey fine sand and shell = (SC and shell) — I 35_, 4-5-5 10 11 _ if - 38.5' T. -..:;'. FM i0 t ta-� ..:,/ 7 12 25 16 / / Greenish -gray silty ime sand with traces - of clayey fine sand and ahaU CM • ij BORING LOG ARDAMAN & ASSOCIATES, INC. BORING NO. TF-1 TOTAL DEPTH 60.0 ft SHEET 2 OF 2 PR0SECT4 Reaiadlel Adtlaii Plat -Tank Farm Area Cun1T K'. Teawacult lne FILE NO. 88-089 _Oiplh i .'v- r Mnd iwntpa Test Lab Data ' 13 IS Sample No. NM (%) -200 (%) LL (%) Soil Description and Remarks Undttu.e,me (Unified Classification) Greenish -gray silty fine sand with traces of - 42.0' clayey fine sand and shell (SM) 17-3615 69 13 Ji 15 16 17 16 19 20 SO Clio al loss of drilling fluid circulatio0.g.1 42' Gray slightly silty medium to fine sand with some shell fragments and thin layers of cemented sand (SM) 47.0' 4-3-5 7 14 Greenish -gray clayey fine sand (SC) - 52.5' 8 15 Greenish -gray clayey fine sand with thin layers of greenish gray sandy clay (SC) - 56.5' - 8 16 Greenish -gray sandy clay (CL) 65 2) Boring terminated at 60.0 feet Samples . 11 3 1 a _, BORING LOG ARDAMAN & ASSOCIATES, INC. BORING NO. TF-2 TOTAL DEPTH 60.0 ft SHEET 1 OF 2 PROJECT Remedial Action Plan - Tank Farm Area FILE NO. 88-089 -,l CLIENT Texasgutf Inc. BORING LOCATION Phosphate Operations COUNTY -Beaufort STATE North Carolina ELEVATION 10.9= feet (]ISL) DATE STARTED 10-20-88 DATE COMPLETED 10-20-88 BORING TYPE Rotary wash with mud DRILLER/RIG Shanaway . Prather/CME-55 LENGTH/TYPE CASING None WATER TABLE DEPTH: 1st x DATE x TIME x , 2nd x DATE x TIME x REMARKS Borehole grouted with cement-bentonite grout; Field Inspector: Ellingsworth . Depth Standard STSI Penetration T� . Lab Data >: e E -N 4. Blows/6" Value Sample No. NM (%) -200 (%) LL (%) PI (%) p Soil Description and Remarks (Unified Classification) Undisturbed Samples 1 - 4-12-18 30 1 - Brown fine sand with traces of shell (SP), fill fix *1 k Th5-21-22 2.0' , 43 2 Grayish -brown tine sand with traces of shell 5 }9-29-14 43 3 (SP), till 4.0' 13-13-21 34 4 - — Gray slightly silty fine sand with traces of 6 0, shell and wood (SP-SM), fill 2 3 - - 30 _ Gray aria yellowish -brown silty fine sand -7.5' (SM), till - Gray and yellowish -brown clayey fine sand (SC), fill 4-14-19 33 6 22 21 // 9.5' 11.0' Gray silty fine sand (SM), fill 4, _ - - 15 - Gray clayey fine sand with thin layers of =: 13.0' sand (SC), fill 3-2-5 7 7 36 35 / % / Dark brown clayey tine sand with thin lenses of - gray fine sand (SC) 5 5 - - 20 _ -17.5' - - Gray slightly silty fine sand 2-11-20 31 8 20 6 // _ (SP-SM) 7 - - 25 21.0' _ Dark gray clayey fine sand with thin lenses of gray fine sand and traces of shell fragments (SC) 1-1-1 2 9 35 31 / /- / / 8 9 _ _ - 30 26.5' Gray clayey fine sand with shell fragments - and cemented sand (SC) 4-2-2 4 10 - ' 10 Y". - '35 -31.5'1 - Gray clayey fine sand with cemented sand and - shell fragments (SC and shell) 5-4-4 8 11 - 13 �f• ii 4 i. ;- ' rl -37.5' .. 12-f-8, � -prit -, 15' 12 24 24 /f_ Gray slightly clayey (Inc sand with shell (SC) } 1: e. s f5111 0 AswelelN, Inc. . _. `,� x)r'r"�'p rpoiwat VYlYa*,, . _.• .. .. .. S'. .1.%ii9�� BORING LOG .ARDAMAN & ASSOCIATES, INC. BORING NO. TOTAL DEPTH SHEET 2 TF-2 60.0 ft OF O PROJECT CLIENT • Remedied Action Plan -Tank Farm Area FILE NO. 88-089 •, Tee ,Depth . Maori :... ...:.:/04_ 'Vat um Test . tilt, Lab Data Soil Description and Remarks (Unified Classification) undisturbed samples rr 'S �' ;;; i P, =. • ;: BloWfa/6• N Value Sample No. NM (%) -200 (%) LL (%) PI (%) . j - -42.5' Gray slightly clayey fine sand with shell (SC) .• - }t" 4 _ 4S Gray clayey fine se id with shell and thin layers of grer.nish-gray clay (SC) _ 44 -11 17 13 - -46.8't 1 - - - _ Gray clayey fine sand with shell (SC) _ - _ .5-7-8 15 14 - 18 17 50 ' - 55 - 51.5' - Greenish -gray clayey fine sand with shell (SC)- - - _ - •3-3-6 9 15 : .• 60 - 56.5' 18 - Greenish -gray sandy clay (CL) - - 5-6-6 12 16 9 65 ' 1 b1r.M�1 ... - - - — - - - _ -- — Boring terminated at 60.0 feet - 1' 22 :.a 0' _ ri • 24 4i5y} rt F e r BORING LOG ARDAMAN & ASSOCIATES, INC. BORING NO. TF-3 TOTAL DEPTH 60.0 ft SHEET 1 OF 2 PROJECT Remedial Action Plan -Tank Farm Area FILE NO. 88-089 CLIENT Texa tf lnr BORING LOCATION Phosphate Operations COUNTY Reanirrt STATE North Carolina ELEVATION 12.0`- feet (MSL) DATE STARTED 10-20-RR DATE COMPLETED 10-21-88 BORING TYPE Rotary wash with mud DRILLER/RIG Shanaway & Prather/C6IE-55 LENGTH/TYPE CASING None WATER TABLE DEPTH: 1st x DATE x TIME x 2nd x DATE r TIME x REMARKS Rnrehole muted with cement-bentonite Prout• Field InSDertor: F]]invsworth_ Depth P Standard ASTN Penetration D-15! Test Lab Data - u 0 m Blows/6^ N Value - Sample No. NM (%) -200 (%) LL (%) PI (%) Soil Description and Remarks ' .. (Unified Classification) Undbturoea s°'"P�' 1.0' Brown fine sand (SP), fill - 4-16-8 24 1 Light brown to yellowish -brown slightly 40 2' - 2.5' silty fine sand (SP-SM), fill - 1 13-18-22 fine - 18-24-16 40 Yellowish -brown slightly clayey • 4,0' snnd (SC). fill , _ 5 Gray clayey fine sand (SC), fill _ 11-15-19 34 3 — 2 - 8.0' 3 - 6-5-4 9 4 - Gray clayey fine sand with traces of gray 10 - fine sand (SC) "•777- = '{. -• 11.0'`- • _ Brown silty fine sand (SM) _- `.r.., 2-1-1-1- Dark brown sandy(CH) �— clay 17.0't - - Brown plastic clay (CH) - .Hammer 7 —23.0' - 1`a ZS^ `pEs-S. 10 g 20 3 Gray medium to fine sand (SP) - '1., if.?'''' e - 27.5' y.- r� - 1 r,akc;'�ti1,:. 9 Dark gray clayey fine sand (SC) — - Y ' f?t - _ - 9 ++�� s 10 40 31 �././ - - ii n �i dt5 <r p y _ 38.0' - .. r�J S ,.� ^." aT. Q rll _ Gray clayey fine sand and shell (SC and shell) _ - 4^ �iR- '� )Tgf�Y!tai•r�'„ ..Me.. i� 1. ♦,� MRL ., tit" i l'1' ytkV.ay p z a 4.. �4Y y ♦�- S Boring terminated at 60.0 feet Soil Description and Remarks Undisturbed Samples fiaLS PROJECT CLIENT Depth 0 w 13 45 14 15 50 BORING LOG ARDAMAN & ASSOCIATES, INC. BORING NO. TF-3 TOTAL DEPTH 60.0 ft SHEET 2 OF 2 Remedial Action Plan -Tank Farm Area FILE NO. 88-089 Texasgulf Inc Vanden, Penetnuan Test 7fl4 D-1}Id Blows/6" N Value Sample No. NM (%) Lab Data -200 (%) LL (%) PI (%) 41.8'r (Unified Classification) Gray clayey fine sand and shell (SC and shell) 5-7-7 14 12 34 16 // ^ 7-11-19 30 13 Shell fragments and gray silty fine sand (shell and SM) 47.0' _ Gray silty fine sand and shell with thin lenses of cemented sand (SM and shell) 16 53.0' 55� 3-3-3 6 14 Greenish -gray clayey fine sand with shell (SC) 17 18 60 - 56.5' 4-5-6 11 15 Light greenish -gray clayey fine sand (SC) t 19 65. 70 3