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HomeMy WebLinkAboutWI0600047_Application_20181106North Carolina Department of Environmental Quality — Division of Water Resources APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION In Situ Groundwater Remediation (15A NCAC 02C .0225) / Tracer Injection (15A NCAC 02C .0229) Do not use this form for the following: • In -situ remediation, tracer, or aquifer test injection wells permitted by rule (ref. 15A NCAC 02C .0217) • remediation systems that reinject treated contaminated groundwater (Non -discharge) (ref. 15A NCAC 02T .1600) OPermit Number (to be completed by DWR): WI 06 63 L L11- I. APPLICATION INFORMATION 1. Project is: [ ] New [ ] Modification [] Renewal without modification [X ] Renewal with modification 2. If this application is being submitted for Renewal and/or Modification to an existing permit, provide: (a.) Existing permit number WI060047 Issued Date: 12/18/2009 & Expiration Date: 11/30/2011 For all Renewals, submit a status report including monitoring results of all injection activities to date. For Renewal without modification only, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner). II. WELL OWNER(S)/PERMIT APPLICANT (generally the responsible party) 1. Name(s): The North Carolina Department of Transportation 2. Signing Official's Name*: Jason Prosser Title: Environmental Operations Engineer * Signing Official must be in accordance with instructions in Part X on page 5. 3. Mailing address of Permittee/Applicant: 1577 Mail Service Center City: Raleigh State: NC Zip: 27601 4. Telephone number: 919-707-2927 Email: jfprosser@ncdot.com 5. Status (choose one): Individual Business/Org. Federal X State County Municipality III. PROPERTY OWNER(S) (if different than well owners) 1. Name(s): Johnson Brother's Utility & Paving Company, Inc. 2. Mailing address: 1924 North Main Street City: Lillington State: NC Zip: 27546 3. Telephone number: 910-893-8378 Email: IV. PROJECT CONTACT — (generally the environmental/engineering consultant). 1. Name: Katie Hackney, PG 2. Company: Groundwater Management Associates, Inc. 3. Address: 4300 Sapphire Court, Suite 100 4. City: Greenville State: NC Zip: 27834 5. Telephone number: 252-758-3310 Email: katie@gma-nc.com EECEIVF %.!.CDEQ)\t NOV06201� In -Situ Groundwater Remediation Application Rev. 8-28-2017 kec ior1�! Water ( a Y . Opemtiu;is Section Title: Senior Hydrogeologist Page l of 12 jl V. FACILITY INFORMATION 1. Facility name: NCDOT Priority Site #32/Johnson Brothers Utility & Paving Company 2. Phone No. if available: 910-893-8378 3. Physical address: 1924 Main Street City: Lillington County: Harnett Zip: 27546 3. Geographic Coordinates: Latitude: 35.4223744 Longitude: -78.7973889 (32-MW17) Reference Datum: NAD83 Accuracy: Method of Collection (i.e., Google Earth, GPS, etc.): Surveyed by RLS (James L. Haines & Assoc. Land Surveying L-2860 4. Brief description of business: Asphalt Plant VI. INCIDENT DESCRIPTION 1. Source and date of contamination: From at least the early 1970's, Johnson Brothers Utility and Paving Company operated on the property and maintained an asphalt materials testing laboratory for use by its staff and various customers including NCDOT inspectors. NCDOT inspectors and unrelated private testing firms used chlorinated aliphatic compound solvents to dissolve asphaltic cement in the testing processes. On site release of the solvent(s) resulted in contamination of the underlying groundwater. A.plume of trichloroethene, 1,1,1- trichloroethane, 1,1-dichloroethene, and 1,1-dichloroethane now underlies the site. 2.. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): Trichloroethene, 1 1,1-dichloroethane 1,1-dichloroethene, 1,1-dichloroethane, benzene, ethvlbenzene, xylenes naphthalene, isopropylbenzene, n-propylbenzene, 1,3,5-trimethylbenzene, 1,2,4-trimethylbenzene, n- butvlbenzene, sec-butylbenzene, and tert-butylbenzene, bromoform, dibromochloromethane, and chloroform. LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? [ ] Yes If yes, list maximum measured separate phase thickness: feet [X] No If no, list maximum concentration of total VOCs observed at site:•32-MW22 on 3/28/18, 483 ppb 3. Agency managing the contamination incident: [ ] UST Section [ ] Superfund Section (including REC Program and DSCA sites) [x] DWR Aquifer Protection Section [ ] Solid Waste Section [ ] Hazardous Waste Section [x] Other: NCDOT - Division of H%hways is Principal Agency managing the site 4. Incident manager's name: Jason Prosser, PG (NCDOT); Stephanie Grubbs (NCDEO) Phone No.: 919- 707-2927 (Prosser) and 919-707-8372 (Grubbs). 5. Incident number or other incident mgmt. agency tracking number: NCDOT Priority Site #32 In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 2 of 12 VII. PERMITS List all applicable permits or construction approvals issued for the facility or incident: 1. Previous or other UIC permits issued by DWR (e.g., NOIs) N/A 2. Other Non -Discharge or NPDES permit issued by DWR: N/A 3. County or DEH subsurface wastewater disposal permits: N/A 4. Hazardous waste management or other environmental permits required by state or federal law: N/A VIII. INJECTION SUMMARY i.List all proposed injectants/additives. NOTE: Only injectants approved by the epidemiology section of the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at http://deq.nc.gov/about/divisions/water-resources/water-resources-perm its/wastewater-branch/ground-water- protection/ground-water-approved-injectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919-807-6496) if you wish to get approval for a different additive. However, please note it may take 3 months or longer. lnjectant: Beverage Remediation Product (BRP) Total Amt. to be injected (gal)/event 2500 gals/event Injectant: Sodium polymetaphosphate (phosphorous) Total Amt. to be injected (gal)/event 200 lbs/event Injectant: Sodium Bicarbonate Total Amt. to be injected (gal)/event 1500 lbs/event NOTE: North Carolina Dept. of Transportation requests that NCDEQ write the permit to allow the injection of any product on the NCDEQ list of "Additives or Tracers Approved by NC DHHS to Inject into Groundwater". This will enable NCDOT through its consultant to continue with remediation efforts even if there is a suspension of supply of BRP. i i. Number of separate injection events: 16 - 20 Duration of Event: 5 days iii. Estimated Injection rate per well: - 0.25 to 2 gallons per minute (GPM) iv. Estimated Injection pressure: 6 to 10 if by gravity up to 50 max if pumped pounds/square inch (PSI) v. Temperature at point of injection: 67.1 °F vi. Injection will be via: ( Existing well(s); Total b.: 5 ✓• Well Type (DPI, Permanent, etc.): Permanent: 32-MW1, 32-MW8., 32-MW 10.32-MW 17, & 32-MW 18 ( Proposed well(s); Total No.: NA : Well Type (DPT, Permanent, etc.): vii. NC Certified Well Drilling Contractor's Name (if known): Carolina Soil Investigations, LLC NC Well Contractor Certification No.: 2579-A viii. Date to be constructed if proposed: NA (attach GW-ls for existing injection wells) ix. Screened interval/Injection interval of injection wells: Depth from 10 to 61 feet below land surface (BLSXif multiple intervals, indicate shallowest to deepest depth) In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 3 of 12 x. Well casing (leave blank if Geoprobes®): Type: ( PVC ( Stainless steel( Other: Casing depth: 0 to 41 ft. BLS (deepest well) Type: ( PVC ( Stainless steel( Other: Casing depth: 0 to 15 ft. BLS (most shallow well) xi. Grout (leave blank if Geoprobes): Type: ( Cement ( Bentonite Grout depth: 0 to 34 Type: ( Cement ( Bentonite Grout depth: 0 to 10 ( Other: ft. BLS (deepest well) ( Other: ft. BLS (most shallow well) IX. ATTACHMENTS — provide the following information in separate attachments. The attachments should be clearly identified and presented in the order below to expedite review of the permit application package. 1. INJECTION ZONE — Per 15A NCAC 02C .0225(e)(2). sped the horizontal and vertical portion of the subsurface within which the proposed injection activity will take place and beyond which no violations of groundwater quality standards shall result from the injection as determined by an approved monitoring plan. The determination shall be based on the hydraulic properties of the specified zone. Provide any supporting documentation in a separate attachment. See the attached original UIC permit application (PDF on CD) for NCDOT Site #32 that contains details concerning the injection zone. Also see the attached Figures 6 and 17 for a depiction of the horizontal and vertical zones selected for injection. Attachment 1 contains Well Construction Records not previously submitted in the original UIC permit application. As stated in VIII.6 above, we will inject in the following wells (see attached Table 1 for well data): 32-MW1 — screened from 15-25 feet below land surface. 32-MW8 — screened from 40-50 feet below land surface. 32-MW 10 — screened from 40-50 feet below land surface. 32-MW17 — screened from 15-30 feet below land surface. 32-MW18 — screened from 41-61 feet below land surface. 2. HYDROGEOLOGIC EVALUATION — Per 15A NCAC 02C .0225(e)(3). provide a hydrogeologic evaluation of the injection zone that includes all of the following: See the attached original UIC permit application that contains details concerning items 2.A — 2.G. (A) (B) (C) (D) (E) (F) (G) Regional and local geology and hydrology; Changes in lithology underlying the facility; Depth to bedrock; Depth to the mean seasonal high water table; Hydraulic conductivity, transmissivity, and storativity, of the injection zone based on tests of site -specific material, including a description of the test(s) used to determine these parameters; Rate and direction of groundwater flow as determined by predictive calculations or computer modeling; and Lithostratigraphic and hydrostratigraphic logs of any existing test and injection wells. 3. INJECTANT INFORMATION— Per 15A NCAC 02C.0225(e)(5). provide information on each injectant as indicated below: See the attached original UIC permit application for details concerning items in Section 3 for NCDOT Site #32. Pepsi Bottling Venture's (PBV) Beverage Remediation Product (BRP) will In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 4 of 12 replace the function and use of sodium lactate as described in the original UIC permit application. North Carolina Dept. of Transportation requests that NCDEQ write the permit to allow the injection of any product on the NCDEQ list of "Additives or Tracers Approved by NC DHHS to Inject into Groundwater". This will allow NCDOT through its consultant to continue with remediation efforts even if there is a suspension of supply of BRP. (A) MSDS, concentration at the point of injection, and percentage if present in a mixture with other injectants; There is no Material Safety Data Sheet (MSDS) available for BRP. Code of Federal Regulations 29CFR1910.1200(b)(5)(iii) exempts food, food additives, color additives, etc. from MSDS requirements. BRP consists of water, high fructose corn syrup (HFCS) and a small quantity (less than 0.5%) of other food grade ingredients approved for human consumption by the US FDA (various flavorings, food colorants, compounds to preserve product freshness, and other substances). HFCS consists of 55% fructose (C6H12O6) and 42% glucose (C6H14O7). BRP is included on the NC DWQ-UIC's List of Approved Injectants. BRP is typically delivered to the injection site in 2,500-gal batches. At another NCDOT injection project (Former ATL Site 003), a laboratory assessment of total organic carbon (TOC) and solution density in 2,500 gallon batches of BRP found the following: i. The minimum TOC concentration was 21.1 g/L or 52.7 g/L as HFCS. This is equivalent to 5.22 wt % or 4.06 % vol/vol and translates into 1,101 lbs of HFCS in the 2,500-gallon batch. ii. The maximum TOC concentration was 89.2 g/L or 223 g/L as HFCS. This is equivalent to 20.7 wt % or 17.2 % vol/vol and translates into 4,653 lbs of HFCS in the 2,500-gallon batch. iii. The mean TOC concentration was 42.1 g/L or 105.2 g/L as HFCS. This is equivalent to 10.2 wt % or 8.10 % vol/vol and translates into 2,196 lbs of HFCS in the 2,500-gallon batch. iv. The median TOC concentration was 38.0 g/L or 95.0 g/L as HFCS. This is equivalent to 9.24 wt % or 7.31 % vol/vol and translates into 1982 lbs of HFCS in the 2,500-gallon batch. We will add sodium bicarbonate and sodium phosphate as necessary to buffer the aquifer and to provide for microbial production of adenosine triphosphate (ATP). ATP is linked to the energy required for respiration, synthesis, growth, and reproduction of microbial mass. MSDS information for Sodium Bicarbonate and Sodium Polymetaphosphate (phosphorous) is included in Attachment 2. (B) The source of fluids used to dilute, early, or otherwise distribute the injectant throughout the injection zone. If any well within the area of review of the injection facility is to be used as the fluid source, then the following information shall be submitted: location/ID number, depth of source, formation, rock/sediment type, and a chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site; We will use the municipal water supply system as the source of water to carry, dilute and distribute the injectant. (C) A description of the rationale for selecting the injectants and concentrations proposed for injection, including an explanation or calculations of how the proposed injectant volumes and concentrations were determined; We have defined the rough dimensions of the aquifer study area to be approximately 1-acre as shown in Figure 17. The static water table is roughly 15 ft bls (below land surface) and the deepest on -site monitor well (32-DW-1) is approximately 65 feet bls (not including deep well In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 5 of 12 32-MW25). Therefore, the thickness of the aquifer study area is 50 ft. Assuming an effective porosity of 45% for the aquifer, the volume of groundwater within the aquifer study area is the following: 43,560 ft2 x 50 ft x 0.45 = 980,100 ft3 980,100 ft3 x 7.481 gal/ft3 = 7,332,128 gal 7,332,128 gal x 3.78 L/gal = 277715.44 L Based on sampling results from the last monitoring event held in March 2018, the average pH (excluding 32-DW-1 because of likely grout contamination) is 5.25 (Table 2). To adjust the pH introduced to neutralize the pH of groundwater alone is as follows: 5.25 x 10-6 moles/L x 84.01 g/mole = 0.000472 g/L 0.000472 g/L x 27,715,444 L = 13,093 g 13,093 grams (13.09 kilograms) of 27,715,444 liters of groundwater from a pH of 5.25 to a pH of 7, it follows: H++ HCO3- H2CO3 Thus, it will require one mole of bicarbonate to neutralize each mole of hydrogen ion. PH is the -log of the hydrogen ion's activity. Therefore, it follows: pH = 5.25 all, _> 10-5.25 = 5.62x 10-6 moles/L It will take 5.62 x 10-6 moles/L of bicarbonate to raise the pH of the groundwater to 7. The molecular weight of sodium bicarbonate is 84.01 grams/mole. Therefore, the mass of sodium bicarbonate that must be introduced to neutralize the pH of groundwater alone is as follows: 5.25 x 10-6 moles/L x 84.01 g/mole = 0.000472 g/L 0.000472 g/L x 27,715,444 L = 13,093 g 13,093 grams (13.09 kilograms) is 29 lbs. We expect that the injection rate at the site will be low, and up to one week could elapse before the 2,500 gallons of BRP enters the aquifer. During that period, aerobic metabolism will convert the HFCS to acetic acid at a ratio of 1:3 (i.e., for each mole of HFCS that is consumed, three moles of acetic acid will be produced). Buffering of the acetic acid will require the following: 0.75ga1 of HFCS x 2,500 gal = 1,875 lbs of HFCS (1,875 lbs of HFCS) x (2Ob) x(1,000g)x f imole)4,720 moles s kg 180.16E 25% of the 4,720 moles of HFCS converted to acetic acid = 1,180 moles of acetic acid, which when dissociated could produce 1,180 moles of hydrogen ions (i.e. 1,180 moles of H+ or H3O+). Neutralization the 1,180 moles of H3O+ will require the following mass of sodium bicarbonate: 1,180m Iles x 84.01 9 = 99,132E mole In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 6 of 12 .205 99,1321 x \i,000yl x (2 lkgbsl = 219 lbs Once in the aquifer, initial metabolic utilization of HFCS by indigenous microbial populations creates various carboxylic acids. These include, from most to least abundant, acetic, propionic, butyric, valeric/pentanoic, and caproic/hexanoic acids. As conditions become more reducing, microbial populations may produce comparable alcohols rather than acids (i.e. ethanol, propanol, butanol, pentanol, etc.), which react with existing organic acids to form carboxylates/esters (e.g., ethyl-, propyl-, or butyl- acetate, propionate, or butyrate, etc.). Sufficient sodium bicarbonate should be added to buffer in situ formation of organic acids from HFCS. The mass of sodium bicarbonate should be sufficient to offset conversion of all the HFCS to acetic acid (i.e., an additional 657 lbs of sodium bicarbonate). The silicate minerals comprising the aquifer matrix may also release hydrogen ions through ion exchange. The magnitude of the phenomenon is empirical and site -specific. In the absence of empirical data, we propose to increase the sodium bicarbonate concentrations in the BRP by an additional 50% to a total of' 1,350 lbs ((29+219+657) x 1.5 - 1,350 Ibs). Commercial suppliers provide food grade sodium bicarbonate (baking soda) in 50-1b bags. Therefore, it will require approximately twenty-seven 50-1b bags of sodium bicarbonate to raise the pH of groundwater from 5.25 to 7.00, maintain the pH of the BRP as the indigenous microbial populations converts the HFCS to organic acids, and to account for ion exchange effects with the silicate mineral phases in the aquifer matrix. If, during subsequent monitoring work we determine that we have still not sufficiently buffered the aquifer, we will increase the loading of the sodium bicarbonate up to its solubility in BRP (approximately 1,500 lbs). Based on sampling results from the last monitoring event held in March 2018, the average total phosphorus concentration 2.86 mg/L and the average orthophosphate concentration is 2.45 mg/L (Table 2). We propose to add sufficient bioavailable phosphorous to the aquifer to bring the phosphate concentration to 2.9 mg/L. The molecular weight of sodium polymetaphosphate is 611.77 g/mole of which sodium accounts for 22.98977 g/mole. Therefore, the total mass of sodium polymetaphosphate that must be introduced in the initial injection to attain an average aquifer concentration of 2.9 mg/L is as follows: (2.9-2.45) mg/L x 27,715,444 L x 10-6 Kg/mg x 2.205 Ibs/Kg = 27.5 Ibs Commercial suppliers provide food grade sodium polymetaphosphate in 50-1b bags. Therefore, it will require approximately half of a 50-1b bag of sodium polymetaphosphate to provide a concentration of 2.9 mg/L during the initial injection. We will closely monitor phosphorus concentrations in the aquifer prior to and subsequent to the initial injection and adjust quantities accordingly. (D) A description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; See the attached original UIC permit application. BRP will replace the function and use of sodium lactate as described in the original UIC permit application. The original UIC permit application contains details concerning reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection. Tables 2, 3 and 4 contain sampling results from the last monitoring event held in March 2018. The laboratory report is included as Attachment 3. In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 7 of 12 (E) A summary of results if modeling or testing was performed to investigate the injectant's potential or susceptibility for biological, chemical, or physical change in the subsurface; See the attached original UIC permit application. (F) An evaluation concerning the development of byproducts of the injection process, including increases in the concentrations of naturally occurring substances. Such an evaluation shall include the identification of the specific byproducts of the injection process, projected concentrations of byproducts, and areas of migration as determined through modeling or other predictive calculations. See the attached original UIC permit application. 4. INJECTION PROCEDURE — Per 15A NCAC 02C .0225(e)(6), submit a table with a detailed description of the proposed injection procedure that includes the following: (A) The proposed average and maximum daily rate and quantity of injectant; (B) The average maximum injection pressure expressed in units of pounds per square inch (psi); and (C) The total or estimated total volume to be injected. Depending on how BRP is prepared for transport at the PBV plant, a tanker or flatbed truck will transport BRP to the site. We will transfer the BRP to a 3,210-gallon drainable HDPE horizontal leg tank equipped with a 2-inch stainless steel ventral drain. Eductors (1.5-inch size) will be mounted on both ends of the tank approximately 24 inches above the bottom. We will collect BRP samples from the tank for laboratory QA/QC analyses of density and total organic carbon. We will then circulate the BRP through the tank using the eductors with 2 centrifugal pumps. The intake for one pump will be connected to the ventral drain and the intake of the second pump will be a suction line lowered through the dorsal fill port. The total flow rate will be between 350 gpm and 400 gpm. As the solution circulates, our staff will slowly add twenty-seven to thirty 50-1b bags of sodium bicarbonate (1,350 to 1,500 lbs total) and one half of a 50-1b bag of sodium polymetaphosphate (25 lbs total). We will adjust the amount of phosphate in subsequent events as needed to maintain a concentration of 2.9 mg/L in the aquifer. It will require 1 to 2 hours to add the bicarbonate and phosphate. The solution will continue to circulate for a minimum of 2 hours after all components are added to insure dissolution of the granular products and thorough mixing. The site is an active asphalt plant and construction traffic may affect how we deliver the solution to the five injection wells. If site conditions warrant, the solution will gravity feed into wells 32- MW1, 32-MW8, 32-MW10, 32-MW17, and 32-MW18 from the mixing tank. The depth to the static water table is approximately 15 ft bls. The height of the solution in the tank when it is full is approximately 7 feet above ground surface. Therefore, the maximum injection pressure will be approximately 10 PSI by gravity. If a pump is needed for injection, the pressure may be as high as 50 PSI. If construction traffic precludes the use of a central tank, then smaller individual tanks will be placed at each well and solution transferred to them from the mixing tank. Each injection event will consist of one 2,500-gallon aliquot of BRP distributed between the five injection wells. The estimated total volume to be injected will be that volume required to develop and maintain a microcosm that effectively dehalogenates groundwater contamination. Following the initial injection(s), there is typically an acclimation period where microorganisms capable of halo - respiration through hydrogenolysis become established and dominant. This typically takes 3 to 18 months. During that period, microbes will aggressively utilize the BRP and additional injections will be required to maintain the system. The target concentration for TOC is >100 mg/L in the treatment area. We anticipate quarterly to semiannual injections during the first year In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 8 of 12 of operation and injections on an as needed basis thereafter. The maximum total number of injections in a five year period will be 20 for a total volume of 50,000 gallons. 5. FRACTURING PLAN (if applicable) — NOT APPLICABLE Per 15A NCAC 02C .0225(e)(7). submit a detailed description of the fracturing plan that includes the following: (A) Material Safety Data Sheets offracturing media including information on any proppants used; (B) a map offracturing well locations relative to the known extent of groundwater contamination plus all buildings, wells, septic systems, underground storage tanks, and underground utilities located within the Area of Review; (C) a demonstration that buildings, wells, septic systems, underground storage tanks, and underground utilities will not be adversely affected by the fracturing process; (D) injection rate and volume; (E) orientation of bedding planes, joints, and fracture sets of the fracture zone; (F) performance monitoring plan for determining the fracture well radius of influence; and (G) if conducted, the results of geophysical testing or pilot test of fracture behavior conducted in an uncontaminated area of the site. 6. WELL CONSTRUCTION DETAILS — Per 15A NCAC 02C .0225(e)(8). submit the following information in tabular or schematic form as appropriate for each item: See the attached original UIC permit application for details concerning items 6.A — 6.H. The original UIC permit covered injection into permanent wells 32-MW1, 32-MW17 and 32-MW18. We have added permanent wells 32-MW8 and 32-MW10 as injection wells. All injection wells are existing. Well construction records are included in Attachment 1 for wells installed at the site subsequent to the date of the original permit application. The attached Table 1 updates the information found in Section F of the original application. (A) number and depth of injection wells; (B) number and depth of borings if using multi -level or "nested" well systems; (C) indication whether the injection wells are existing or proposed; (D) depth and type of casing; (E) depth and type of screen material; (F) depth and type of grout; (G) indication whether the injection wells are permanent or temporary "direct push" points; and (H) plans and specifications of the surface and subsurface construction details. 7. MONITORING PLAN — Per 15A NCAC 02C .0225(e)(9), submit a monitoring plan that includes the following: See the attached original UIC permit application for details concerning items 7.A — 7.B. (A) target contaminants plus secondary or intermediate contaminants that may result from the injection; See the attached original UIC permit application. We will continue to monitor for parameters listed in the attached Tables 2 and 3. (B) other parameters that may serve to indicate the progress of the intended reactions; See the attached original UIC permit application. We will continue to monitor for parameters listed in the attached Tables 2 and 3. (C) a list of existing and proposed monitoring wells to be used; and We will use monitoring wells 32-MW 1 through 32-MW25 and 32-DW1. See the attached Table 1 and Figure 3. (D) a sampling schedule to monitor the proposed injection. In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 9 of 12 Monitoring wells shall be of sufficient quantity and location to detect any movement of injection fluids, injection process byproducts, or formation fluids outside the injection zone. The monitoring schedule shall be consistent with the proposed injection schedule, pace of the anticipated reactions, and rate of transport of the injectants and contaminants. Tables 1 and 2 present a list of all existing monitor wells. We will perform water level gauging, field analyses and laboratory analyses for all wells. Groundwater sampling will occur as follows: • a sampling event immediately prior to injection. • quarterly during periods of active injection. • semiannually for two years after the final injections occur. See the attached original UIC permit application for details concerning sampling methods and data analyses. 8. WELL DATA TABULATION — Per 1 SA NCAC 02C .0225(e)(10), provide a tabulation of data on all existing or abandoned wells within the area of review of the injection well(s) that penetrate the proposed injection zone, including monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's type, depth, and record of construction or abandonment. See the attached original UIC permit application for a tabulation of well data within the area of review. The attached Table 1 updates the information found in Section F of the original application. 9. MAPS AND CROSS -SECTIONS — Per 15A NCAC 02C . 0225(e) (11), provide scaled, site -specific site plans or maps depicting the location, orientation, and relationship of facility components including the following: (A) area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site; See attached Figure 1. (B) topographic contour intervals showing all facility related structures, property boundaries, streams, springs, lakes, ponds, and other surface drainage features; See attached Figures 1, 2 & 4. (C) all existing or abandoned wells within the area of review of the wells listed in the well data tabulation that penetrate the proposed injection zone; See attached Figures 2, 3 & 17. (D) potentiometric surface map(s) that show the direction of groundwater movement, existing and proposed wells; See attached Figures 5 & 6. (E) contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, and existing and proposed wells; See attached Figures 7 through 16. (F) cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, major changes in lithology, and existing and proposed wells; See attached Figures 7 through 16. In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 10 of 12 (G) any existing sources of potential or known groundwater contamination, including waste storage, treatment, or disposal systems within the area of review of the injection well or well system. See attached Figure 3 for the location of former and current asphalt testing labs (ATL) and above ground fuel storage tanks (AST). The former asphalt testing laboratory has been gone for over 30 years. Past investigations found no soil contamination consistent with an ongoing source of contamination. Residual groundwater contamination is the only known continuing source at the site to feed the plume. X. CERTIFICATION (to be signed as required below or by that person's authorized agent*) NCAC 15A 02C .0211(e) requires that all permit applications shall be signed as follows: 1. for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor, respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. *If an authorized agent is signing on behalf of the applicant, then supply a letter signed by the applicant that names and authorizes their agent. "1 hereby cert fy under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate, and complete. 1 am aware that there are penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit." Printed Name and Title: Jason F. Prosser Environmental Operations Engineer Signature: -?/ Date: G 0 `Z'2 / zrn XI. CONSENT OF PROPERTY OWNER (if the property is not owned by the permit applicant) "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C .0200). " Printed Name and Title: See Attachment 4 for Property Access Agreement Signature: See Attachment 4 for Property Access Agreement Date: In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 11 of 12 Submit TWO hard copies of the completed application package with an electronic version in CD or USB Flash Drive to: Division of Water Resources — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 807-6464 In -Situ Groundwater Remediation Application Rev. 8-28-2017 Page 12 of 12 Tables TABLE l: UPDATED WELL DATA (ORIGINAL UIC PERMIT APPLICATION SECTION F) Well I.D. Well Type NC Planar Coordinate - NAD 83 Northing (ft) NC Planar Coordinate - NAD 83 Easting (ft) Well Diameter and Material Total Depth (ft-bsg) Screened Interval (ft-bsg) Location Shown on Figure: Remarks Municipal Water Connection 32-MW 1 Injection/ Monitoring 608753.3 2060358.3 2" PVC 25.5 15-25 3 On site - Well Construction Log Previously Submitted Yes 32-DW1 Monitoring 608756.2 2060362.2 2" PVC 65.5 53-63 3 On site - Well Construction Log Previously Submitted Yes 32-MW2 Monitoring 608883.9 2060356.0 2" PVC 25.5 15-25 3 On site - Well Construction Log Previously Submitted Yes 32-MW7 Monitoring 608661.3 2060364.1 2" PVC 25.5 10-25 3 On site - Well Construction Log Previously Submitted Yes 32-MW8 Injection/ Monitoring 608667.8 2060369.3 2" PVC 50.5 40-50 3 On site - Well Construction Log Previously Submitted Yes 32-MW9R Monitoring 608537.0 2060318.0 2" PVC 25.5 10-25 3 On site - Well Construction Log Attached Yes 32-MW10 Injection/ Monitoring 608545.9 2060303.6 2" PVC 50.5 40-50 3 On site - Well Construction Log Previously Submitted Yes 32-MW11 Monitoring 608332.5 2060201.5 2" PVC 25.5 10-25 3 On site - Well Construction Log Previously Submitted Yes 32-M W 12 Monitoring 608338.1 2060182.3 2" PVC 50.5 40-50 3 On site - Well Construction Log Previously Submitted Yes 1 Table 1 (continued) Well I.D. Well Type NC Planar Coordinate - NAD 83 Northing (ft) NC Planar Coordinate - NAD 83 Easting (ft) Well Diameter and Material Total Depth (ft-bsg) Screened Interval (ft-bsg) Location Shown on Figure: Remarks Municipal Water Connection 32-MW13R Monitoring 608,543.2504 2,060,524.7049 2" PVC 25.5 15-25 3 On site - Well Construction Log Attached Yes 32-MW 14 Monitoring 608791.7 2060090.0 2" PVC 30.5 15-30 3 On site - Well Construction Log Previously Submitted Yes 32-MW 15R Monitoring 608,448.6157 2,060,398.5989 2" PVC 26.5 15-25 3 On site - Well Construction Log Attached Yes 32-MW16R Monitoring 608,384.8814 2,060,398.9793 2" PVC 50.5 40-50 3 On site - Well Construction Log Lost Yes 32-MW 17 Injection/ Monitoring 608,712.7969 2,060,365.4810 42" PVC 30.5 15-30 3 On site - Well Construction Log Attached Yes 32-MW 18 Injection/ Monitoring 608,699.3826 2,060,362.1447 4" PVC 61.5 41-61 3 On site - Well Construction Log Attached Yes 32-MW19 Monitoring 608,882.4745 2,060,378.5448 2" PVC 36 20-35 3 On site - Well Construction Log Attached Yes 32-MW20 Monitoring 608,749.I869 2,060,364.2935 2" PVC 35 20-35 3 On site - Well Construction Log Attached Yes 32-MW21 Monitoring 608,658.9322 2,060,372.2034 2" PVC 35 20-35 3 On site - We11 Construction Log Attached Yes 32-MW22 Monitoring 608,544.9137 2,060,310.0600 2" PVC 35 20-35 3 On site - Well Construction Log Attached Yes 32-MW23 Monitoring 608,722.7402 2,060,333.3787 2" PVC 35 20-35 3 On site - Well Construction Log Attached Yes 32-MW24 Monitoring 608,713.5976 2,060,326.3050 2" PVC 65 50-60 3 On site - Well Construction Log Attached Yes 2 fable s tcuntinueu; Well I.D. Well Type NC Planar Coordinate - NAD 83 Northing (ft) NC Planar Coordinate - NAD 83 Easting (ft) Well Diameter and Material Total Depth (ft-bsg) Screened Interval (ft-bsg) Location Shown on Figure: Remarks Municipal Water Connection 32-MW25 Monitoring 608,575.8374 2,060,323.5444 2" PVC 85 75-85 3 On site - Well Construction Log Attached Yes Tucker_] Private Well 609714 2061962 Unknown Unknown Unknown Original A 17 PP 381 Old Coats Road; Exposed well head. Yes Tucker_2 Private Well 609754 2061988 Unknown Unknown Unlmown Original App 381 Old Coats Road; Pump house building. Yes Sellers Private Well 609595 2062281 Unknown Unknown Unknown OrriAgppal 416RO10 oats Yesad. LL Jemigan_1 Private Well 609244 2061453 Unknown Unknown Unknown Original App 416 Old Coats Road. Yes Jemigan_2 Private Well 609574 2061292 Unknown Unknown Unknown Original App 35 Sarah Green Lane. Yes Lee (Davis Rental Prop.) Private Well 609574 2061232 Unknown Unlmown Unknown Original App 233 Old Coats Road. Yes Owens Private Well 609603 2061029 Unknown Unknown Unknown original App Old 201 Road.oats Yes Herring Private Well 609592 2060973 Unknown Unknown Unknown Original App 150 Old Coats Road. USTs? Basement? Other Wells? Yes Schmitt Private Well 609562 2060752 Unknown Unknown Unknown original PotableWater ce Yes Butts Private Well 609191 2060893 Unknown Unknown Unlmown Original App 150 Old Coats Road. USTs? Basement? Other Wells? Yes Long_] Private Well 609121 2060446 Unknown Unknown Unknown Original App 58 Old Coats Road. Basement. Yes Long_2 Private Well 609136 2060408 Unknown Unknown Unknown Original App 58 Old Coats Road. Hand pump well on porch. Yes Long_3 Private Well 609493 2060612 Unknown Unknown Unknown Original App Multiple outbuildings; antique equipment; USTs and Multiple ASTs. Yes 3 fabic a (Cant uucu, Well I.D. Well Type NC Planar Coordinate - NAD 83 Northing (ft) NC Planar Coordinate - NAD 83 Fasting (ft) Well Diameter and Material Total Depth (ft-bsg) Screened Interval (ft-bsg) Location Shown on Figure: Remarks Municipal Water Connection Trailer Lot 13 Private Well 610351 2060352 Unknown Unknown Unknown Original A PP 225 Hwy 2]0 North; Trailer on Lot 13. Yes Wilburn Private Well 609244 2059838 Unknown Unknown Unknown Original App Well is 10 feet NW of Coordinate. Yes TriTronics Private Well 608334 2059718 Unknown Unknown Unknown Original App Yes Johnson Paving Private Well 608655 2060254 Unknown Unknown Unknown Original App Yes 4 a mmaryof:Groundwater-GeochemicatParamete_rs DOT Priority Site #32, Johnson Brothers Paving & Utir" Lillington, Hamett County, NC GMA Project #160502 4 -J re 1-1: Fietrameters - n. .. ::,y 'l.. ti <::_ .� Laboratory Parameiers a - - , -: Well Numbers [ [ , Sample Date .,- DD m n ' OBP v Temper afore.`, ; " (--, pN Speafi4, Condor trvity , +TOC a (m9,114 -Ethane ° (u9/1 y `rEthene N9/L) Methane (u9/L) Chloride (m9/L) "' Total c Phos 9/ ) us Phosphate '. as P _ Total Iron , (mg/L) Dissolved ,.� ( 99/L) - Manganese I: ( 9/L- '. Dissolved nganeie , M (m9/L) 1/12/2017 0.03 19.7 22.3 7.28 816.00 10.3 <0.110 <0.150 2460 8.2 24 20 28 0.21 0.28 0.047 32-MW1 3/28/2018 0.09 19.2 21.1 7.11 697.00 5.43 <0.110 <0.150 511 7.1 17 2.9 33 5.3 1.2 0.36 1/12/2017 4.55 102.2 19.3 5.80 189.80 3.1 3 <0.110 <0.150 <0.435 7.3 0.35 <50 17 <100 0.32 0.062 32-MW2 3/28/2018 3.47 126.1 17.6 5.00 2.00 <1.5 <0.110 <0.150 <0.435 7.5 0.76 <0.050 16 0.45 0.45 0.066 1/12/2017 4.27 110.2 20.1 3.96 41.20 0.983 <0.110 <0.150 <0.435 7.0 0.31 <50 11 <100 0.081 0.045 32-MW7 3/28/2018 4.76 111.7 19.1 4.63 42.60 <1.5 <0.110 <0.150 <0.435 7.3 0.42 <0.050 2.6 <0.10 0.077 <0.010 32-MW8 1/12/2017 5.23 124.9 18.8 3.73 65.10 <1.5 <0.110 <0.150 <0.435 5.8 2.4 <50 550 <100 4.90 0.042 3/28/2018 5.68 132.8 18.8 4.75 68.70 <1.5 <0.110 <0.150 <0.435 5.8 1.8 <0.050 52 <0.10 0.71 0.11 32-MW9R 1/12/2017 0.09 55.7 20.9 4.69 45.40 10.5 <0.110 <0.150 6.73 5.8 0.06 <50 0.77 <100 0.00 0.66 3/28/2018 0.18 102.6 19.8 4.73 43.40 10.9 <0.110 <0.150 30 5.7 <0.050 <0.050 1.90 0.30 0.80 0.72 32-MW10 1/12/2017 3.67 78.0 19.4 5.10 142.70 <1.5 <0.110 <0.150 <0.435 10 3.3 <50 220 <100 2.90 0.022 3/28/2018 4.44 116.5 19.4 4.96 68.50 <1.5 <0.110 <0.150 <0.435 8.4 2.00 <0.050 9.5 <0.10 0.39 0.053 32-MW11 1/12/2017 2.08 77.6 17.3 4.91 44.40 0.63 <0.110 <0.150 <0.435 2.0 0.4 <50 60 <100 0.74 0.04 3/28/2018 0.75 107.8 16.0 4.81 55.90 <1.5 <0.110 <0.150 <0.435 2.4 0.26 <0.050 85 0.18 1.4 0.15 32-MW12 1/12/2017 4.57 77.1 17.1 5.33 47.10 1.6 3 <0.110 <0.150 <0.435 3.3. 8.9 <50 54 E <100 7 0.016 3/28/2018 - 5.12 71.2 17.0 5.62 50.80 <1.5 <0.110 <0.150 <0.435 3.2 1.9 <0.050 680 1.1 9.6 0.29 32-MW13R 1/12/2017 3.07 83.6 19.5 4.41 124.80 1.83 <0.110 <0.150 1.563 7.4 0.8 <50 64 <100 0.43 0.16 3/28/2018 3.69 106.6 17.6 4.69 157.90 <1.5 <0.110 <0.150 1.423 6.3 0.93 <0.050 320 <0.10 1.5 0.26 32-MW14 1/12/2017 2.88 79.3 21.9 4.32 117.00 1.93 <0.110 <0.150 <0.435 10 1.4 <50 19 <100 0.88 0.40 3/28/2018 3.79 108.9 20.5 4.39 116.40 <1.5 <0.110 <0.150 <0.435 12 0.9 <0.050 68 <0.10 0.56 0.30 32-MW16R 3/28/2018 NA NA NA NA NA NA NA NA NA 5.7 11 <0.050 1,400 4.6 42 4.3 32-MW17 1/12/2017 0.03 17.1 30.4 7.22 1557.00 11.4 <0.110 <0.150 2780 23 11 6.3 16 0.14 0.83 0.21 3/28/2018 0.08 -10.5 18.9 6.50 564.10 3.73 <0.110 <0.150 1100 8.9 2.4 <0.050 39 8.4 20 20 32-MW18 1/12/2017 0.04 7.6 19.2 6.42 549.10 <3.0 <0.110 <0.150 3140 24 2.4 0.15 21 0.12 10 0.21 3/28/2018 0.08 -33.8 19.8 7.16 1555.00 4.93 <0.110 <0.150 1470 26 6.6 2.0 14 2.80 0.64 0.57 32-MW19 1/12/2017 4.60 114.1 18.3 4.73 102.00 2.83 <0.110 <0.150 <0.435 7.4 0.19 <50 12 <100 0.21 0.093 3/28/2018 5.21 103.3 17.9 4.47 118.00 <1.5 <0.110 <0.150 <0.435 8.1 1.3 <0.050 58 <0.10 0.68 0.11 32-MW20 1/12/2017 3.69 72.8 21.0 5.37 84.40 1.93 <0.110 <0.150 1.573 6.5 4.2 <50 440 <100 4.80 0.02 3/28/2018 3.89 33.7 21.0 5.18 87.90 <1.5 <0.110 <0.150 1.933 8.6 1.6 <0.050 460 <0.10 13 0.37 32-MW21 1/12/2017 5.23 107.0 19.2 3.96 37.50 <1.5 <0.110 <0.150 <0.435 5.4 2.6 <50 540 <100 6 <10 3/28/2018 5.37 105.2 18.9 4.59 39.10 <1.5 <0.110 <0.150 <0.435 5.1 0.74 <0.050 310 <100 2.7 0.073 32-MW22 1/12/2017 0.18 60.1 19.9 4.80 62.30 7.0 <0.110 <0.150 235 0.6 0.3 <50 29 <100 0.29 0.039 3/28/2018 0.26 109.9 19.9 4.90 63.60 6.33 <0.110 <0.150 189 5.8 0.82 <0.050 390 <100 3.4 1.0 32-MW23 1/12/2017 3.09 84.4 20.7 6.17 109.50 1.23 <0.110 <0.150 <0.435 3.5 2.7 <50 180 <100 2.70 0.025 3/28/2018 2.98 30.8 20.6 6.11 105.80 <1.5 <0.110 <0.150 <0.435 3.5 1.7 <0.050 250 <100 2.9 . 0.083 32-MW24 1/12/2017 5.92 98.0 19.7 4.90 37.70 1.63 <0.110 <0.150 <0.435 4.2 4.7 <50 420 <100 5.7 E 0.041 3/28/2018 6.11 78.8 19.5 4.95 39.90 <1.5 <0.110 <0.150 <0.435 4.2 0.99 <0.050 630 <100 9.7 0.11 32-MW25 1/12/2017 5.81 69.2 18.6 5.17 37.70 <1.5 <0.110 <0.150 <0.435 3.1 6.8 <50 690 0.30 7.70 0.99 3/28/2018 _ 6.96 103.4 18.3 5.20 37.20 <1.5 <0.110 <0.150 <0.435 3.2 1.8 <0.050 830 <100 11 0.081 32-DW1 1/12/2017 5.05 66.5 19.4 6.73 116.10 <3.0 <0.110 <0.150 <0.435 5.5 8.9 <50 760 <100 11 E <10 3/28/2018 4.85 70.9 19.2 6.83 112.20 <1.5 <0.110 <0.150 <0.435 5.5 2.3 <0.050 720 0.56 11 0.13 NA = Not analyzed TOC = Total Organic Carbon J = the analyte was detected, but value is below the Reporting Limit; therfore, the result is an estimated concentration 2018 average pH ==> 5.25 2018 average Total Phoshorus =_> 2.86 mg/L 2018 average Orthophosphate as P ==> 2.45 mg/L Table 3. Summary of Monitoring Well Groundwater Analytical Results (ug/L) NCDOT Mod ty Site #32, !Jilin On, Harnett Co , NC GMA Project #160502 ,PAMeNlods62t Me6/5-6010DT(u9/L ISSIIIIIIII (ug/7 "Ma/ylto%Merhodll=MI �La7�,y +� _ u t3.'fi i � f u ai D. S u W' i~ S. rYm� A§C..�y�g7#f�7�� �iF�g ��] N. /Yu� '21 a Cj '�:J]J �Y L1 ` r T � g-`'� 1E`WeIIID �' I,FI� � C y o - - O a LLLp S �5 CS eto NO 3.i .4 i w`'_�c P I uF .4i ° - °ed $j/�� T�O grtrJ '. .�', u U� <0.50 <1.5 <1.0 NA <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 27 : 92 - 84 Q Eigiitiol 210 fl . 280 47 1/12/2017 <0.50 0.54 0.86 <0.50 CO - <0.50 <0.50 11 - < <0.50 7.7 1.5 2.0 <0.50 32-MW1 3/28/2018 <0.50 <0.50 0.50 <0.50 p <0.50 <0.50 <030 <0.50 <0.50 24 <0.50 1.4 <0.50 c0.50 <1.5 <0.50 1.4 <1.0 <0.50 <0.50 <3.0 <0.50 <0.50 <0.50 12 52 Ilia 5,300 1,200. 360 1/12/2017 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.5 <1.0 NA <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <10 <10 <10 8.7 132;000 , <100 <5 _' 320 ; 62 32-MW2 3/28/2018 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <1.5 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <5.0 <20 <20 8.4 t16;000 450 7.9 - 450 -' 666 1/12/2017 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 3.2 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.5 <1.0 NA <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <10 <10 <10 7.7 11,000 <100 5.3 ' 45 <0.50 <1.5 <0.50 <0.50 <1.0 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <5.0 <20 <20 <5.0 2, 11 <100 5.3 m , 32 32-MW7 3/28/2018 <0.50 <0.50 <0.50 <0.50 2A <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <1.5 <1.0 NA <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <10 I 1 <10 z,7o0 550,000. <100 11;900 . 42 1/12/2017 <0.50 2.0 1.4 <0.50 I m ! <0.50 <0.50 fl <0.50 <0.50 2.7 <2.0 <0.50 32•MW8 3/28/2018 <0.50 1.7 1.4 <0.50 E(] <0.50 <0.50 <0.50 fl <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <1.5 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <5.0 ems. - 45 E 52,000 <100 ;� '.� 1,100 1/12/2017 <0.50 <0.50 <0.50 <0.50 5.5 <0.50 <0.50 <0.50 2.6 <0.50 <0.50 <0.50 <2.0 0.70 21 <1.0 NA m.'.I 9.1 11 <0.50 <0.50 <0.50 0.79 <10 <10 <10 _m' �.' <100 <5 660 32•MW9R 3/28/2018 <0.50 <0.50 <0.50 <0.50 3.0 <0.50 <0.50 <0.50 2.5 <0.50 <0.50 <0.50 <1.0 0.57 30 <1.0 <0.50 � , 20 11 <030 0.76 <0.50 1.5 12 <20 <20 <5.0 1,900 300 <5.0 -: 720 1/12/2017 <0.50 0.62 <0.50 <0.50 m-. <0.50 <0.50 <0.50 0.50 <0.50 1.3 <2.0 0.73 <0.50 <1.5 <1.0 NA <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <10 }' <10 - . 220000 <100 m 2,900 22 <0.50 <l.5 <1.0 <0.50 <1.0 <0.50 <0.50 c0.50 <0.50 <0.50 <0.50 <5.0 <20 <20 '[�] `all <100 .;. ] 390 - 53 32-MW10 3/28/2018 <0.50 0.52 <0.50 <0.50 <0.50 <0.50 <0.50 'LEA' ; <0.50 <0.50 <0.50 <1.0 <0.50 1/12/2017 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <1.0 NA <1.0 <0.50. <0.50 <0.50 <0.50 <0.50 <0.50 <10 -fl ' <10 m 60,000 <100 12 40 <0.50 <1.5 32-MW11 3/28/2018 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50- <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <1.5 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <5.0 <20 <20 : m I}1' 180 <5.0 150 1/12/2017 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.5 <1.0 NA <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <10 330 <10 330 '-54;000E <100 1 3E61 L1,400E 16 <0.50 <1.5 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <5.0 350 ) <20 1.552,0001 1,100 ' 130 19;6001 <10 32-MW12 3/28/2018 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 c0.50 <0.50 <0.50 <1.0 <0.50 1/12/2017 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.5 <1.0 NA <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <10 .. <10 m 64,000 <100.r 160 <0.50 <1.5 <0.50 <0.50 <3.0 <0.50 <0.50 <3.0 <0.50 <0.50 <0.50 <5.0 <20 32g008� coo 260 32-MW13R 3/28/2018 <0.50 <0.50 <0.50 <0.50 <0.50 c0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <3.0 <0.50 1/12/2017 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.5 <1.0 NA <1.0 <0.50 - <0.50 <0.50 <0.50 <0.50 <0.50 <10 - <10 Q 19,000 <100`, / ''{{ 400 <0.50 <1.5 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <5.0 <20 <20 '-:}�'.. 68,0007 <100 '.Ym i'_560 ' 300 32•MW14 3/28/2018 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 32-MW16R 3/28/2018 <0.50 <0.50 <0.50 <0.50 2.2 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <1.5 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <5.0 5,400 94 &2D 4,600 12;000 '42,0004,300 1/12/2017 <0.50 1.2 2.2 <0 50 .(Fj 1 ' - : <0.50 <0.50 t ;I 14 1.2 2.0 <0.50 NA <1.0 3.7 <0.50 <0.50 <0.50 <0.50 <0.50 8.43 x 1 46 5.9 [1,400,000 l 16,000::1 140 <5 . 830 � 210 <0.50 <1.5 <1.0 <0.50 <1.5 <0.50' <0.50 0.743 3:5 <0.50 <1.0 <0.50 <0.50 <0.50 <5.0 Q"- <20 8.2 t390001 .8,400 <5.0 ,000 20,000 32-MW37 3/28/2018 <0.50 1.7 24 <0.50 -. g.78 <0.50 <0.50 ° , s' <0.50 <0.50 1.3 <0.50 1/12/2017 <0.50 2.1 2.7 <0.50 <0.50 0:60 :V _.. .,: 2.7 1.0 1.53 <0.50 <0.50 <1.5 <1.0 NA <1.0 29 <0.50 <0.50 <0.50 <0.50 <0.50 <10 32 46 <5 11220001 120 <5 10000, 210 32-MW18 3/28/2018 <0.50 0.74 2.2 <0.50 `m- ,,. • -, <0.50 <0.50 _ ; 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GCL = gross contaminant levels Gold = Concentrations above Detectable Limits Shaded = Concentrabons above 2L Groundwater Standards NSE = No Standard Established 11,1-Dichloroethylene (vinylidene chloride, or 1,1 DCE ) was adopted by the Environmental Management Commision in accordance with 15A NCAC 02L .0202 (f) at 350 ug/L and is above the federal MCI.. Where a private drinking water well or public water system is Impacted by 1,1 DCE, the applicable standard is 7 ug/L, in accordance with 15A NCAC 02L .0202. E = Estimated concentration above the calibration range 3 = Detected but below the Reporing Limit, therefore, the result is an estimated concentration Table 4. Summary of Targeted Monitoring Well Groundwater Analytical Results (pmole/L) NCDOT Priority Site #32, Lillington, Hamett Co., NC GMA Project #160502 Analytical Method EPA Methods 6200E (micromoles/liter) Well ID Date Collected Tetrachloro- ethene Trichloro- ethene cis-1,2- dichloro ethene Trans-1,2- dichioro- ethene 1,1-Dichioro ethene' Vinyl Chloride 1, 1, 1- Tethtoro- ethane 1, 1, 2- Teth{ora ethane 1,1 dichloro ethane 1,2-Dichloro ethane Chloro-Methylene ethane Chloride Chloroform 1/12/2017 0.001508 0.004110 0.008871 0.002579 0.825253 0.013280 0.001874 0.001874 0.111156 0.002526 0.119343 0.023549 0.012565 32-MW1 3/28/2018 0.001508 0.001903 0.005158 0.002579 0.557046 0.004000 0.001874 0.001874 0.002526 0.002526 0.037198 0.016484 0.002094 1/12/2017 0,001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-M W 2 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.032336 0.002526 0.003875 0.002944 0.002094 32-M W 7 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.024758 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-MW8 1/12/2017 0.001508 0.015222 0.014442 0.002579 0.004000 0.001874 0.006573 0.131366. 0.002526 0.003875 0.002944 0.022617 3/28/2018 0.001508 0.012939 0.014442 0.002579 0.>>f0f62 0.004000 0.001874 0.001874 0.131366- 0.002526 0.003875 0.002944 0.002094 32-MW9R 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.056736 0.004000 0.001874 0.001874 0.026273 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.030947 0.004000 0.001874 0.001874 0.025263 0.002526 0.003875 0.002944 0.002094 32-M W 10 1/12/2017 0.001508 0.004719 0.002579 0.002579 0.526099 0.004000 0.001874 0.001874 0.073767 0.002526 0.003875 0.002944 0.010890 3/28/2018 0.001508 0.003958 0.002579 0.002579 0.422942 0.004000 0.001874 0.001874 0.074778 0.002526 0.003875 0.002944 0.002094 32-M W 11 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0,003875 0.002944 0.002094 32-M W 12 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002914 0.002094 32-M W 13R 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-MW14 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-MW16 3/28/2017 0.001508 0.001903 0.002579 0.002579 0.022694 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-M W 17 1/12/2017 0.001508 0.009133 0.022694 0.002579 0.876831 0.017600 0.001874 0.001874 0.565885 0.006265 0.216987 0.002944 0.010052 3/28/2018 0.001508 0.012939 0.024758 0.002579 0.835568 0.012480 0.001874 0.001874 0.788197 0.008286 0.003875 0.015307 0.002094 32-MW18 1/12/2017 0.001508 0.015983 0.027852 0.002579 1.134723 0.010240 0.001874 0.004498 0.909458 0.010105 0.041847 0.002944 0.008377 3/28/2018 0.001508 0.005632 0.022694 0.002579 0.330101 0.035200 0.001874 0.001874 0.252627 0.002526 0.418475 0.010597 0.002094 32-M W 19 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.034000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 3/28/2018 ; 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-MW20 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.618940 ', 0.004000 0.001874 0.001874 0.151576 0.002526 0.003875 0.002944 0.020942 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.536414 " 0.004000 , 0.001874 0.001874 0.222312 0.002526 0.003875 0.002944 0.009214 32-M W 21 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.005261 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-M W 22 1/12/2017 , 0.001508 0.001903 0.002579 0.002579 0.154735 ' 0.004000 0.001874 0.001874 0.032336 0.012126 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.088715 0.064000 0.001874 0.001874 0.002526 0.009802 0.003875 0.002944 0.002094 32-MW23 1/12/2017 0.001508 0.005937 0.002579 0.002579 0.814937 0.004000 0.001874 0.001874 0.062652 0.002526 0.003875 0.002944 0.026805 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.701465 0.004000 0.001874 0,001874 0.084883 0.002526 0.003875 0.002944 0.017591 32-M W 24 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-M W 25 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.007074 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.005880 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 32-DW1 1/12/2017 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 3/28/2018 0.001508 0.001903 0.002579 0.002579 0.002579 0.004000 0.001874 0.001874 0.002526 0.002526 0.003875 0.002944 0.002094 2013 2L Standard (Nmole/L) 0.004221 0,022833 0.722096 1.031566 0.072210 0.000480 1.499250 0.004498 0.060631 0.004042 4.649721 0.058872 0.586363 All concentrations shown are expressed in micromoles per liter (pmol/L) GCL = gross contaminant levels Shaded = Concentrations above 2L Groundwater standards Bold = Concentrations above Detectable Limits NSE = No Standard Established 11,1-Dichloroethylene (vinylidene chloride, or 1,1 DCE ) was adopted by the Environmental Management Commision in accordance with 15A NCAC 02L .0202 (f) at 350 ug/L and is above the federal MCL. Where a private drinking water well or public water system is impacted by 1,1 DCE, the applicable standard is 7 ug/L, in accordance with 15A NCAC 02L .0202. E = Estimated concentration above the calibration range J = Detected but below the Reporing Limit, therefore, the result is an estimated concentration fro sjiji5 Table 5. Anticipated Schedule of Injection Related Activities - Year One NCDOT Priority Site #32, Johnson Brothers Paving & Utility Co., Llllington, Flamed County, NC GMA Project #160502 Activity Anticipated Start Date -( subject to future ..modification) Monitoring Well Installation 3/12-14/2019 Develop New monitoring Wells 3/14/2019 Antecedent (Pre -Injection) Sampling Event 3/26-27/2019 Initial Injection Event 4/10/2019 1st Quarterly Sampling Event between 5/17/19 & 6/17/19 Second Injection Event 7/16/2019 2nd Quarterly Sampling Event between 8/22/19 & 10/21/19 Third Injection Event 11/19/2019 3rd Quarterly Sampling Event between 1/6/20 & 2/24/20 Report of Findings and Schedule of Additional Activities 5/11/2020 Table 5. Anticipated Schedule of Injection Related Activities - Year One NCDOT Priority Site #32, Johnson Brothers Paving & Utility Co., Lillington, Harnett County, NC GMA Project #160502 Activity Anticipated Start Date ( subject to future modification) Monitoring Well Installation 2/15/2019 Develop New monitoring Wells 3/4/2019 Antecedent (Pre -Injection) Sampling Event 3/6/2019 Initial Injection Event 4/3/2019 1st Quarterly Sampling Event betlnegn5/17/19 & 6/17/19 Second Injection Event n5 7716/2019 2nd Quarterly Sampling Event between 8/22/19 0/21/19 Third Injection Event 11/19/2019 3rd Quarterly Sampling Event between 1/6/20 & 2/24/20� Report of Findings and Schedule of Additional Activities 5/11/2020 -�, Attachment 1 Updated/Additional Well Construction Logs for NC DOT Priority Site No. 32