Loading...
HomeMy WebLinkAboutWI0700012_Monitoring (Report) Aug - Oct 2009_20091118PotashCorp Helping Nature Provide 1-MS O 3 20(19 November 11, 2009 Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina, 27699 Attn: Information Management CERTIFIED MAIL Subject: Underground Injection Control Program Quarterly Groundwater Monitoring Report August 2009 — October 2009 Injection Well Permit #WI0700012 Tank Farm Remedial Action System Beaufort Co. Dear Qi: Please find the subject groundwater monitoring report attached. This includes the sampling and reporting requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and monitor well MWTF1 CR, b) Form GW-59 for each of the fourteen withdrawal wells, c) piezometer level monitoring field sheet, and d) the summary operational and maintenance report. Please do not hesitate to contact me at (252) 322-8283 if you have any questions regarding this information. Sincerely, D. Daniel Winstead III Environmental Engineer PCS Phosphate Attachments RECEIVED / DENR / DWQ Aquifer r�� ,��, t, S?rtion C 1530 NC Hwy 306 South, Aurora, NC USA 27806 T (252) 322-4111 PCS Phosphate I www.potashcorp.com pc: Will Hart — Aquifer Protection DWQ, WaRO (w/ attachments) R. M. Smith/12-07-02 (w/ attachments) T. S. Ingra - Ardaman & Assoc. (w/attachments) R. A. Allen (w/ attachments) Mike Brom (w/ attachments) Anthony Shrewsbury (w/ attachments) R. B. Lee (w/ attachments) Total Two Copies Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina, 27699 Attn: Information Management H:\Reports\2009\Quarterly\TFRAS Report Third Quarter 2009.doc 2 GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CIW-7 Well Depth: 48.00 ft. Well Diamter: 4 inch Screened Interval: 31.00 ft. to 45.25 ft. Depth to Water Level: N/A ft. below measuring point. Measuring Point is N/A ft above land surface. GALLONS of water pumped/bailed before sampling: N/A For Groundwater Treatment Sys ems Check One: Influent (98) Effluent (99) Field Analysis: pH 7.1 , Specific Conductance 644 uMhos Temp. 22.1 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01 /31 /13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/20/2009 Date sample analyzed: 10/20/2009 to 10/30/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered COD N/A mg/I Coliform: MF Fecal N/A /100m1 Nitrite (NO2 as N) Nitrate (NO3 as N) Coliform: MF Total <1.0 /100m1 Phosphorus: Total as P (Note: Use MPN method for highly turbid samples) Orthophosphate Dissolved Solids: Total 420 mg/I Al - Aluminum pH (when analyzed) 7.1 units Ba - Barium TOC 4.4 mg/1 Ca - Calcium Chloride 17.2 mg/I Cd- Cadmium Arsenic N/A mg/I Chromium: Total Grease and Oils N/A mg/I Cu - Copper Phenol N/A mg/1 Fe - Iron Sulfate Specific Conductance Total Ammonia TKN as N <10.0 mg/I Hg - Mercury N/A uMhos K- Potassium N/A mg/I Mg - Magnesium N/A mg/I Mn - Manganese Yes n/a No and field acidified Yes n/z No ) N/A mg/I Ni - Nickel N/A mg/I Pb - Lead 0.022 mg/1 Zn - Zinc N/A mg/I Ammonia Nitrogen N/A ug/I N/A ug/I N/A ug/I <0.001 ug/I Ag - Silver N/A N/A N/A Other (Specify Compounds and Concentration Units) Fluoride MIBK 0.008 ug/I Se- Selenium N/A ug/I Sodium N/A ug/I N/A ug/I N/A ug/I N/A ug/I 0.012 ug/I 0.54 N/A N/A N/A N/A Organics: (GC, GC/MS, (Specify test method #. Report attached? Yes VOC HPLC) Attach lab report.) (1) No : method# : method# method# ug/I ug/I ug/I mg/I mg/I ug/I ug/I ug/I ug/I (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 t.� 1 MS D t'� lD 3 200`�, ivu v 1 8 2009 ,J:c.c ssefg Unit DWQ/BOG Ross M. Smith - Manager, Environmental Affairs P rmi ee (of A thorized Agent) Name and Title - Please type or print Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 (from perrn0 Well Identification Number (from Permit): MWTF1-CR Well Depth: 42.00 ft. Well Diamter: 2 inch Screened Interval: 38.70 ft. to 40.70 ft. Depth to Water Level: 15.65 ft. below measuring point. Measuring Point is 3.95 ft above land surface. MILILITERS of water pumped/bailed before sampling: 3100 for Groundwater Treatment Sys ems Check One: Influent (98) Effluent (99) Field Analysis: pH 7.1 , Specific Conductance 669 uMhos Temp. 20.6 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH. NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge EXPIRATION DATE: UIC X 01/31/13 Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/20/2009 Date sample analyzed: 10/20/2009 to 10/30/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples COD Coliform: MF Fecal Coliform: MF Total (Note: Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N for metals were collected N/A N/A <1.0 Use MPN method for highly turbid samples) 460 7.2 4.5 16.7 N/A N/A N/A <10.0 N/A N/A N/A mg/l /100m1 /100m1 mg/I units mg/I mg/I mg/l mg/I mg/1 mg/1 uMhos mg/I mg/I unfiltered Yes n/a Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Orthophosphate Al - Aluminum Ba - Barium Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese No and field acidified N/A mg/I N/A mg/I 0.525 mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I <0.001 ug/l 0.010 ug/I N/A ug/I N/A ug/I N/A ug/l N/A ug/I N/A ug/I 0.079 ug/I Yes n/a No ) Ni - Nickel Pb - Lead Zn - Zinc Ammonia Nitrogen N/A ug/I N/A ug/I N/A ug/I mg/I Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No VOC : method# method# method# 0.46 mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I X (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 TMS Ross M. Smith - Manager, Environmental Affairs Permittee (of Authorized Agent) Name and Title - Please type or print Signature o ermittee or uthorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 cm , Well Identification Number (from Permit): SWW-1 Well Depth: 22.50 ft. Well Diamter: 4 inch Screened Interval: 18.30 ft. to 21.12 ft. Depth to Water Level: 7.22 ft. below measuring point. For Groundwater Treatment Sys ems Check One: _ Influent (98) X Effluent (99) Measuring Point is 1.52 ft above land surface. GALLONS of water pumped/bailed before sampling: CONTINUOUS Field Analysis: pH 5.6 , Specific Conductance 1438 uMhos Temp. 18.7 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01 /31 /13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/27/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered COD N/A mg/I Coliform: MF Fecal N/A /100m1 Coliform: MF Total N/A /100m1 (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total 1436 pH (when analyzed) 5.8 TOC 5.1 Chloride 85.5 mg/I Arsenic N/A mg/I Grease and Oils N/A mg/I Phenol N/A mg/I Sulfate Specific Conductance Total Ammonia TKN as N 158.0 N/A N/A N/A mg/1 uMhos mg/1 mg/1 Yes n/a Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Orthophosphate mg/I Al - Aluminum units Ba - Barium mg/I Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese No and field acidified Yes n/a No ) N/A mg/I Ni - Nickel N/A mg/l 312.000 mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Pb - Lead Zn - Zinc Ammonia Nitrogen Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver N/A ug/I Se- Selenium N/A ug/I Sodium N/A N/A N/A 0.54 N/A N/A N/A N/A N/A ug/I Organics: (GC, GC/MS, HPLC) N/A ug/I (Specify test method #. Attach lab report.) N/A ug/I Report attached? Yes (1) No X N/A ug/I VOC : method# method# method# N/A ug/I ug/I ug/I ug/I mg/I mg/I ug/I ug/I ug/I ug/I (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 TMS Ross M. Smith - Manager, Environmental Affairs A yre (of uthorized Agent) Name and Title - Please type or print A.v1.ai�`� r PillS 1 / t 3%o 9 u a Signature of Permittee (or Authorized Agent) (t GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): SWW-2 Well Depth: 23.00 ft. Well Diamter: 4 inch Screened Interval: 18.80 ft. to 21.63 ft. Depth to Water Level: 13.62 ft. below measuring point. Measuring Point is 3.42 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) CONTINUOUS Field Analysis: pH 4.9 , Specific Conductance 2865 uMhos Temp. 20.0 oC, Odor NONE Appearance: MILKY WHITE Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01/31/13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/27/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected COD N/A mg/I Coliform: MF Fecal N/A /100m1 Coliform: MF Total N/A /100m1 (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total 4552 mg/1 pH (when analyzed) 4.9 units TOC 8.1 mg/I Chloride 56.1 mg/I Arsenic N/A mg/I Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A mg/I N/A mg/I 431.3 mg/I N/A uMhos N/A mg/I N/A mg/I unfiltered Yes n/a No and field acidified Yes n/z No ) Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Orthophosphate Al - Aluminum Ba - Barium Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese 1090.000 mg/I N/A mg/I Ni - Nickel N/A mg/I Pb - Lead Zn - Zinc N/A mg/I Ammonia Nitrogen N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Se- Selenium N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Sodium Organics: (GC, GC/MS, (Specify test method #. Report attached? Yes VOC N/A ug/1 N/A ug/I N/A ug/I Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver mg/I 2.00 mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I HPLC) Attach lab report.) (1) No X (2) method# method# method# I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: TMS GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs it tn ee (of uthorized Agent) ame and Title - Please type or print -Cr )2rY15 itht/o 9 Signature of ermittee (or Authorized Agent) (Da ) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): SWW-3 Well Depth: 24.50 ft. Well Diamter: 4 inch Screened Interval: 20.17 ft. to 23.00 ft. Depth to Water Level: 7.48 ft. below measuring point. Measuring Point is 3.17 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: _ Influent (98) X Effluent (99) CONTINUOUS Field Analysis: pH 4.3 , Specific Conductance 4397 uMhos Temp. 21.4 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH. NC 27626-0578 Phone: (919)733-3221 PERMIT #: W10700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01/31/13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/27/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected COD Coliform: MF Fecal Coliform: MF Total N/A N/A N/A (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N mg/I /100m1 /100m1 7844 mg/I 4.4 units 9.5 mg/1 41.6 mg/I N/A mg/1 N/A mg/1 N/A mg/I 594.2 mg/I N/A uMhos N/A mg/1 N/A mg/I unfiltered Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Orthophosphate Al - Aluminum Ba - Barium Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese Yes nla No and field acidified N/A mg/I N/A mg/1 1865.000 mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/l N/A ug/I Yes nlg No ) Ni - Nickel Pb - Lead Zn - Zinc Ammonia Nitrogen N/A ug/I N/A ug/I N/A ugll mg/I Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC : method# • method# method# 0.18 mg/I N/A ug/I N/A ug/I N/A ug/l N/A ug/I I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 TMS Ross M. Smith - Manager, Environmental Affairs ittee (of Authorized Agent) Name and Title - Please type or print P l,/ 12s 11 Signature of Permittee (or Aut orized Agent) i39 (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): Well Depth: 25.00 ft. Well Diamter: SWW-4 4 inch Screened Interval: 20.50 ft. to 23.30 ft. Depth to Water Level: 7.29 ft. below measuring point. For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) Measuring Point is 3.42 ft above land surface. GALLONS of water pumped/bailed before sampling: CONTINUOUS Field Analysis: pH 5.1 , Specific Conductance 3868 uMhos Temp. 30.8 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01/31/13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/27/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered Yes n/a COD Coliform: MF Fecal Coliform: MF Total N/A N/A N/A (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total 4408 pH (when analyzed) 5.3 TOC 8.1 Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N 45.6 N/A N/A N/A 618.9 N/A N/A N/A mg/I Nitrite (NO2 as N) /100m1 Nitrate (NO3 as N) /100m1 Phosphorus: Total as P Orthophosphate mg/I Al - Aluminum units Ba - Barium mg/I Ca - Calcium mgll Cd- Cadmium mg/I Chromium: Total mg/I Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury uMhos K- Potassium mg/1 Mg - Magnesium mg/1 Mn - Manganese 930.000 mg/I No and field acidified Yes n/z No ) N/A mg/I Ni - Nickel N/A mg/l Pb - Lead Zn - Zinc N/A mg/1 Ammonia Nitrogen N/A ug/I N/A ug/I N/A ug/l N/A ug/I N/A ug/l N/A ug/I N/A ug/l N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, (Specify test method #. Report attached? Yes VOC mg/1 0.06 mg/I N/A ug/I N/A ug/I N/A ug/l N/A ug/I HPLC) Attach lab report.) (1) No X (2) : method# method# method# I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: TMS GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs P rmittee (of Authorized Agent) Name and Title - Please type or print TZ/111 l 1 /i3 i Signature of Permittee (or Authorized Agent) / (Date} GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 ( Well Identification Number (from Permit): Well Depth: 28.21 ft. Well Diamter: SWW-5 4 inch Screened Interval: 24.83 ft. to 27.21 ft. Depth to Water Level: 7.04 ft. below measuring point. For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) Measuring Point is 2.96 ft above land surface. GALLONS of water pumped/bailed before sampling: CONTINUOUS Field Analysis: pH 6.9 , Specific Conductance 1035 uMhos Temp. 23.3 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge EXPIRATION DATE: UIC X 01/31/13 Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/27/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered COD N/A mg/1 Nitrite (NO2 as N) Coliform: MF Fecal Coliform: MF Total N/A /100m1 Nitrate (NO3 as N) Yes n/a N/A /100m1 Phosphorus: Total as P (Note: Use MPN method for highly turbid samples) Orthophosphate Dissolved Solids: Total 616 mg/I Al - Aluminum pH (when analyzed) 6.9 units Ba - Barium TOC 2.9 mg/I Ca - Calcium Chloride 127.5 mg/1 Cd- Cadmium Arsenic N/A mg/I Chromium: Total Grease and Oils N/A mg/I Cu - Copper Phenol N/A mg/I Sulfate <10.0 mg/I Specific Conductance N/A uMhos Total Ammonia TKN as N N/A mg/I N/A mg/I Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese No and field acidified Yes n/e No ) N/A mg/I Ni - Nickel N/A mg/I Pb - Lead 141.000 mg/I Zn - Zinc N/A mg/I Ammonia Nitrogen N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Se- Selenium N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X VOC : method# N/A N/A N/A Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver 0.03 N/A N/A N/A N/A method# method# ug/l ug/I ug/I mg/I mg/I ug/I ug/I ug/I ug/I (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information; including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 TMS DEC 0 3 2009 Ross M. Smith - Manager, Environmental Affairs Permittee (o Authorized Agent) Name and Title - Please type or rint / R,»$ 3 /0 9 Signature of Permittee (or Authorized Agent) (Daffe) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. -Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 (from, Well Identification Number (from Permit): SWW-6 Well Depth: 26.00 ft. Well Diamter: 4 inch Screened Interval: 22.25 ft. to 24.62 ft. Depth to Water Level: 7.49 ft. below measuring point. Measuring Point is 2.58 ft above land surface. GALLONS of water pumped/bailed before sampling: Field Analysis: pH 7.0 , Specific Conductance Temp. 23.2 oC, Odor NONE For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) CONTINUOUS 2134 uMhos Appearance: LIGHT RUST Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01 /31 /13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/19/2009 10/19/2009 to 10/27/2009 PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected u COD Coliform: MF Fecal Coliform: MF Total (Note: Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A N/A N/A Use MPN method for highly turbid samples) 1716 7.1 14.3 48.3 N/A N/A N/A 669.9 N/A N/A N/A mg/I /100m1 /100m1 mg/I units mg/I mg/I mg/I mg/I mg/I mg/I uMhos mg/I mg/I nfiltered Yes n/a Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Orthophosphate Al - Aluminum Ba - Barium Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese No and field acidified Yes n/g No ) N/A N/A 164.500 mg/I mg/1 mg/I N/A mg/1 N/A ug/I N/A ug/1 N/A ug/I N/A ug/I N/A ug/l N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Ni - Nickel Pb - Lead Zn - Zinc Ammonia Nitrogen N/A ug/I N/A ug/I N/A ug/l mg/1 Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No VOC : method# method# method# 0.17 mg/I N/A ug/I N/A ug/I N/A ug/1 N/A ug/I X (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. false information, including the possibility of fines and imprisonment for knowing violations. accurate, and complete, and that the laboratory analytical data was produced I am aware that there are significant penalties for submitting NOTE: GW-59 Rev 4/98 TMS Ross M. Smith - Manager, Environmental Affairs (of 4uthorized ALJri�rv5 ame and Title - Please type or print 4,,"t ! /i3�O? Signature of Permittee (or Authorized Agent) (date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): SWW-7 Well Depth: 29.50 ft. Well Diamter: 4 inch Screened Interval: 25.17 ft. to 27.50 ft. Depth to Water Level: 6.91 ft. below measuring point. Measuring Point is 3.00 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) CONTINUOUS Field Analysis: pH 5.9 , Specific Conductance 555 uMhos Temp. 20.5 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01/31/13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/27/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered COD Coliform: MF Fecal Coliform: MF Total (Note: Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A N/A N/A Use MPN method for highly turbid samples) 408 6.0 5.2 23.7 N/A N/A N/A 57.6 N/A N/A N/A mg/I /100m1 /100m1 mg/1 units mg/l mg/I mg/1 mg/I mg/I mg/I uMhos mg/I mg/I Nitrite (NO2 as N) Nitrate (NO3 as N) Yes Phosphorus: Total as P Orthophosphate Al - Aluminum Ba - Barium Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese nla No and field acidified Yes n/a No ) N/A mg/1 Ni - Nickel N/A mg/I Pb - Lead 32.500 mg/I Zn - Zinc N/A mg/I Ammonia Nitrogen N/A ug/I Other (Specify Compounds and Concentration Units) N/A ug/l Fluoride N/A ug/I MIBK N/A ug/I Ag - Silver N/A ug/I Se- Selenium N/A ug/I N/A ug/l N/A ug/1 N/A ug/I N/A ug/I N/A ug/1 N/A N/A N/A Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes VOC (1) No : method# method# method# 0.11 N/A N/A N/A N/A ug/I ug/I ug/I mg/I mg/I ug/I ug/I ug/I ug/I (2) 1 certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 TMS Ross M. Smith - Manager, Environmental Affairs Peittt e (of Authorized Agent) Name and Title - Please type or print .arJzw,s ,(43/! Signature of Permitt a (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-1 Well Depth: 55.00 ft. Well Diamter: 4 inch Screened Interval: 33.27 ft. to 52.68 ft. Depth to Water Level: 2.81 ft. below measuring point. Measuring Point is 2.25 ft above land surface. MILILITERS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01/31/13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/19/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: COD Coliform: MF Fecal N/A Coliform: MF Total N/A (Note: Use MPN method for highly turbid samples) N/A Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol (Samples for metals were collected unfiltered N/A mg/1 Nitrite (NO2 as N) /100m1 Nitrate (NO3 as N) /100m1 Phosphorus: Total as P Sulfate Specific Conductance Total Ammonia TKN as N mg/I nit g N g/I N mg/I N/A mg/I N/A uMhos N/A mg/I N/A mg/I Orthophosphate Al - Aluminum - Barium Calcium Cadmium omium: Tota u - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese Yes n/a No and field acidified N/A mg/1 Ni - Nickel N/A mg/I b - -d Vn ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Yes n/a No ) Nitrog or (fy Compo Flu MIBK Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, (Specify test method #. Report attached? Yes VOC centration Units) HPLC) Attach lab report.) (1) No : method# • method# method# N/A ug/I N/A ug/I N/A ug/I mg/I N/A mg/1 N/A ug/I N/A ug/l N/A ug/I N/A ug/I X (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 TMS Ross M. Smith - Manager, Environmental Affairs Permitteq, (of AuthorizegAgent) Name and Title - Please type or print Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Mail Original to: Well Identification Number (from Permit): CWW-2 Well Depth: 52.15 ft. Well Diamter: 4 inch Screened Interval: 30.57 ft. to 49.82 ft. Depth to Water Level: Measuring Point is 2.21 ft. below measuring point. 3.00 ft above land surface. MILILITERS of water pumped/bailed before sampling: N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH. NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 EXPIRATION DATE: 01 /31 /13 Non -Discharge UIC X NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/19/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected COD N/A Coliform: MF Fecal N/A Coliform: MF Total N/A (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total N/A pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A mg/I /100m1 /100 mg mg/I mg/I mg/I mg/I uMhos mg/I mg/I unfiltered Nitrite (NO2 as N) Nitrate (NO3 as N) horus: Total sphate num um cium Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese Yes n/a No and field acidified N/A mg/I Ni - Nickel N/A ' g/I N ug/I N/A ug/l N/A ug/I N/A ug/l N/A ugll N/A ug/I N/A ug/I N/A ug/I N/A ug/l a er (Specify Fluoride MIBK Ag - Silver Yes n/e No ) Se- Selenium Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC method# method# method# ion Units) ug/I ug/I ug/I mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/l N/A ug/I 1 certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment f:ir ;i . h:^(.1 violations. NOTE: - ' Ross M. Smith - Manager, Environmental Affairs GW-59 Rev 4/98 ttee (�f A thorized A ent) Name and Title - Please type or print /17S i/ Signature of Permittee (or Authorize Agent) (Date) 3— 9 GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 (from oar,. Well Identification Number (from Permit): CWW-3 Well Depth: 53.00 ft. Well Diamter: 4 inch Screened Interval: 36.42 ft. to 50.67 ft. Depth to Water Level: 3.03 ft. below measuring point. Measuring Point is 3.08 ft above land surface. MILILITERS of water pumped/bailed before sampling: Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) N/A CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01/31/13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/19/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected COD Coliform: MF Fecal Coliform: MF Total (Note: Use MPN method for highly Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A mg/I N/A /100m1 N/A _ /100 N/A N/A N/A mg N/A mg/I N/A mg/I N/A mg/I N/A mg/I N/A uMhos N/A mg/I N/A mg/I unfiltered Nitrite (NO2 as N) Nitrate (NO3 as N) horus: Total osphate inum um cium Yes n!a No and field acidified N/A mg/l Ni - Nickel N/A g/I N/A - Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese N/A N/A N/A N/A N/A N/A N/A N/A ug ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/l er (Spec' Fluorid MIBK Yes n/k No ) ation Units) Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No VOC : method# method# method# N/A ug/I N/A ug/1 N/A ug/l mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/1 X (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 TMS Ross M. Smith - Manager, Environmental Affairs PRrmitteg (of,Authorized Agent) Name and Title - Please type or print 24 4S i( Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Mail Original to: Well Identification Number (from Permit): CWW-4 Well Depth: 53.00 ft. Well Diamter: 4 inch Screened Interval: 41.67 ft. to 50.92 ft. Depth to Water Level: 2.33 ft. below measuring point. Measuring Point is 2.75 ft above land surface. MILILITERS of water pumped/bailed before sampling: Field Analysis: pH N/A , Specific Conductance Temp. N/A oC, Odor NONE For Groundwater Treatment Systems Check One: Influent (98) X Effluent (99) N/A N/A uMhos Appearance: CLEAR DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 EXPIRATION DATE: 01/31/13 Non -Discharge UIC X NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/19/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected unfiltered COD N/A mg/I Nitrite (NO2 as N) Coliform: MF Fecal N/A /100m1 Nitrate (NO3 as N) Coliform: MF Total N/A /100mL •horus: Total (Note. Use MPN method for highly turbid samples) Dissolved Solids: Total N/A pH (when analyzed) N/A TOC N/A Chloride N/A Arsenic N/A Grease and Oils N/A Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A N/A N/A N/A NIA sphate inum um cium mg .- Cadmium mg/I Chromium: Total mg/I Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury uMhos K- Potassium mg/I Mg - Magnesium mg/I Mn - Manganese Yes n/a No and field acidified N/A mg/I Ni - Nickel N/A • g/I N ug/I N/A ug/l N/A ug/l a er (Specify Fluoride MIBK Ag - Silver Yes n/z No ) Se- Selenium N/A ug/I Sodium N/A ug/I Organics: (GC, GC/MS, HPLC) N/A ug/I (Specify test method #. Attach lab report.) N/A ug/I Report attached? Yes (1) No X (2) N/A ug/I VOC method# method# method# N/A ug/l N/A ug/I N/A ug/l mg/I N/A mg/I N/A ug/I N/A ug/l N/A ug/I N/A ug/I N/A ug/I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: TMS GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs Per itte (qf Authorized Agent) Name and Title - Please type or print Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-5 Well Depth: 53.17 ft. Well Diamter: 4 inch Screened Interval: 41.75 ft. to 51.08 ft. Depth to Water Level: 4.93 ft. below measuring point. Measuring Point is 2.58 ft above land surface. MILILITERS of water pumped/bailed before sampling: For Groundwater Treatment Systems Check One: Influent (98) Effluent (99) X N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery EXPIRATION DATE: UIC X 01 /31 /13 Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/19/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected unfiltered COD N/A mg/I Nitrite (NO2 as N) Coliform: MF Fecal N/A /100m1 Nitrate (NO3 as N) Coliform: MF Total N/A /100 •horus: Total (Note: Use MPN method for highly turbid samples) .;y: osphate Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A AI - A'''` inum N/A Ba um N/A - . cium N/A W mg .- Cadmium N/A mg/I Chromium: Total N/A mg/I Cu - Copper N/A mg/I Fe - Iron N/A mg/l Hg - Mercury N/A uMhos K- Potassium N/A mgll Mg - Magnesium N/A mg/I Mn - Manganese Yes n/a No and field acidified N/A mg/I N/A g/I /A N/A N/A N/A N/A N/A N/A N/A N/A u ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/l N/A N/A N/A a er (Specify action Units) Fluoride MIBK Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC method# method# method# ug/I ug/I ug/I mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs Signature of Permittee (or ent) Name and Title - Please type or print PA- 3/ Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-6 Well Depth: 53.00 ft. Well Diamter: 4 inch Screened Interval: 36.62 ft. to 50.88 ft. Depth to Water Level: 5.32 ft. below measuring point. Measuring Point is 2.92 ft above land surface. MILILITERS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) NIA Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge EXPIRATION DATE: UIC X 01 /31113 NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/19/2009 10/19/2009 to 10/19/2009 PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected unfiltered COD Coliform: Coliform: N/A N/A N/A (Note: Use MPN method for highly turbid steles) Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic MF Fecal MF Total Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A mg/I N/A mg/I N/A mg/I N/A uMhos N/A mg/I N/A mg/I mg/I /100m1 /100m1 Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: rthophosp - Aluminu - Barium a - Calcium Cd- Cadmium /A mg/I Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese No and field acidified N/A mg/I Ni - Nickel N/A N/A N/A N/A N/A N/A N/A N/A ug/I ug/l ug/I ug/I ug/l ug/I ug/I ug/I ug/I MIBK Ag - Silver Se- Selenium oncentration Units) N/A N/A N/A N/A N/A N/A N/A Sodium N/A Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC : method# ug/I ug/I ug/I mg/I method# method# mg/I ug/I ug/I ug/I ug/l I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs ee (of orized Agent) Name and Title - Plea a type or print /.//3 v9 Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: P.O. Box 48 Aurora, NC 27806 County: Beaufort Contact Person: Jimmy Hardy Telephone: (252)322-8154 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-7 Well Depth: 53.00 ft. Well Diamter: 4 inch Screened Interval: 36.58 ft. to 50.83 ft. Depth to Water Level: 2.24 ft. below measuring point. Measuring Point is 1.25 ft above land surface. MILILITERS of water pumped/bailed before sampling: N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR For Groundwater Treatment Systems Check One: Influent (98) X Effluent (99) Mad Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: W10700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01/31/13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/19/2009 Date sample analyzed: 10/19/2009 to 10/19/2009 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected unfiltered COD Coliform: MF Fecal Coliform: MF Total N/A N/A N/A (Note: Use MPN method for highly turbid s Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N les) mg/I Nitrite (NO2 as N) /100m1 Nitrate (NO3 as N) /100m1 Phosphorus: Qhophosp Aluminu - Barium - Calcium - Cadmium /A mg/I Chromium: Total N/A N/A N/A N/A N/A N/A mg/I Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury uMhos K- Potassium mg/I Mg - Magnesium mg/I Mn - Manganese Yes n/a No and field acidified N/A mg/I Ni - Nickel A q/1 b - ad c is Nitro /A N/A N/A N/A N/A N/A N/A N/A N/A ug/I ug/I ug/I ug/I ug/I ug/I ug/l ug/I ug/I MIBK Ag - Silver Se- Selenium Yes n/k No ) oncentration Units) Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No VOC method# method# method# N/A ug/I N/A ug/l N/A ug/I m g/1 N/A mg/l N/A ug/I N/A ug/l N/A ug/1 N/A ug/l X (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs P _rmi ee (ofAhorized Agent) Name and Title - Please type or print Signature of Permittee (or Authorized Ag (Date) /r Date: Time: Tech: PCS Phosphate Co., Inc. - Tank Farm Remediation System Quarterly Monitoring /a/i9/o9 System Gaj SWW-1 a Pressures _.LiJoP, SWW-7 CWW-1 ...n4"..04% �r14r CWW-7 �aP File: 12-07-02 pc: TLB Reference Point MSL Love? Rel to MSL Ditch 12.91 // Barge Slip 10.59 Water Level Control Tank %= MSL Sand Layer Pelzometers Level Indicators Well ID TOC Elevation MSL' TOC Ste Wtr Level' Level Relative To MSL Ft. Well ID TOC Elevation MSL' TOC Stc Wtr Level' Level Relative To Ft. Spz-1 10.47 �/n. '7O d, 7 7 Cpz-1 10.51 p /S 9p ?MSL 'V• y7 Spz-2 11.21 Agat a. 93 Cpz-2 10.25 /a./J -/, 498 Spz-3 11.87 a 20 /j. 67 Cpz-3 11.12 /S. 9' -07.85 Spz-4 11.45 % 45 .`J./O CPW 9.65 fi Spz-5 11.45 9 EU a s/a MWTF-1A • 14.35 ' . 0 9 ,,95 1 Spz-6 11.23 /40-33 ©. 90 MWTF-1B• 14.36 67 S8 ©,°%(/ Spz-7 11.59 990s / ,749 MWTF-1C• 14.44 /S aa/% -�/c9/ Spz-8 11.57 4 MWTF-2A 14.05 t .c /,8/ Spz-9 11.01 799%/ '/ MWTF-2B 14.02 /A /g 7 SI S' Spz-10 12.16 7 9V ../DDj41 7,c s� MWTF-2C 14.08 /7a9 -,3.a/ SPW 9.95 7 al. %`' MWTF-3A 12.21 (-'g0 49 V/ W MTF-3B 12.18 9.7 a/,D 4/ - 7, 04, MWTF-3C 12.19 /G-a,� • Sand Layer And Croatan Formation Withdrawal Wells Well ID TOC Elevation MSL' Max Stc Wtr Level Ft. Pump Activation Depth Rel MSL Max Level Relative To MSL Ft. Control Point MSL' Is Well Pumping? (Y)es/(N)o Comments SWW-1 10.70 Le �•.2-g 6' /•ou +1' to+2' p CWW-1 10.60 a• 8/ 9' 7 7/9 -2'to-1' Ai� W SW-2 9.99 /�. /o.%l 6' .14.5 +1 ' to+2' CWW-2 10.23 /9.42/ 9' 6 0,Z -2 'to-1' " SWW 9.97 2-3 94" 6' O/ . •7 ! +1'to+2' ri CWW-3 9.95 c50 - 9' W•9/=1 -2'to-1' N SWW-4 10.73 7,-9 9' 6' eigO-- 4 +1' to+2' CW-4 W 10.73 CPS 9' 90 -2 ' to-1' �1, /r" SWW-5 10.80 7o 6' 1 '76 +1' to+2' CWW-5 10.74 9'. 99J' 9' . . B,R -2 ' to-1' N SWW-6 10.66 7«9 6' .fie 7 +1' to +2' " CWW-6 9.92 6:.�ol 9' '//// Y• tp0 -2'to-1' /�"/ SWW-7 10.70 t/r• 9/ 6' 9 79 71 'to+2' j , CWW-7 9.95 a• g 4 9' 77/ -2' to-1' N Revised 7/29/02 • Riser length added to TOC elevation 1/24/97 ,'zvr ors oovtre� /,r,,ii/c d.77! D:\Data\Forms\Well Ferm\Tank Farm Remed Wells.xls • PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR THE INJECTION AND WITHDRAWAL WATER WELLS August 2009 — October 2009 The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north side of the Tank Farm Area. Injection Water Well System The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system during the period. Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs Department. The total monthly and quarterly volumes of water injected as well as the month end water - level in the Water Level Control Tank are: DPW WATER GALLONS TOTAL GALLONS AVERAGE GPM TANK LEVEL FEET, MSL August 923,699 0 923,699 20.7 15.0 September 860,468 0 860,468 19.3 15.0 October 894,077 0 894,077 20.0 15.0 TOTALS 2,678,244 0 2,678,244 H:\Reports\2009\Quarterly\TFRAS Report Third Quarter 2009.doc 3 • Withdrawal Well System The withdrawal water well pumps are monitored daily by the area Maintenance Department and preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water volumes for the period are: SAND FORMATION GALLONS CROATAN FORMATION GALLONS TOTAL GALLONS AVERAGE GPM August 1,067,377 0 1,067,377 26.5 September 1,351,209 16 1,351,225 31.3 October 1,535,127 505 1,535,632 35.5 TOTALS 3,953,713 520 3,954,233 Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning, and troubleshooting on individual pumps in the fourteen well systems were experienced. Details of these activities are: Confined Sand Formation Withdrawal Well (SWW) Pumps SWW-1: On 8/10 air blasted well. On 8/12 replaced pump. On 8/28 replaced pump. On 9/8 replaced counter. SWW-2: On 9/9 replaced pump. SWW-3: On 10/14 replaced pump. On 10/27 replaced pump. SWW-4: On 8/11 replaced pump. On 8/27 replaced pump. On 9/22 replaced pump. On 9/29 repaired pump. On 10/8 replaced pump. On 10/30 replaced pump. SWW-5: On 8/10 air blasted well. SWW-6: SWW-7: H:\Reports\2009\Quarterly\TFRAS Report Third Quarter 2009.doc 4 Croatan Formation Withdrawal Well (CWW) Pumps CWW-1: CWW-2: CWW-3: CWW-4: CWW-5: CWW-6: CWW-7: On 8/17 switched to plant air due to solenoid failure associated with the dryer. On 8/18 replaced solenoid and switched back to air compressor. On 10/12 switched to plant air due to sheave problem. On 10/22 main discharge header plugged. On 10/27 switched back to air compressor. H:\Reports\2009\Quarterly\TFRAS Report Third Quarter 2009.doc 5