WI0500329_Monitoring (Report)_20140114

f Cape Lookout
Environmental Sciencesw
5TH QUARTERLY
POST INJECTION/EXTRACTION MONITORING REPORT
PEDEN FAMILY LLC
WAKE COUNTY
UIC PERMIT NO. W10500329
NCDENR INCIDENT NO. 21567
CLES PROJECT NO. 13-002
Prepared for:
Peden Family LLC
1859 Capital Boulevard
Raleigh, North Carolina 27629
Prepared by:
Cape Lookout Environmental Sciences, PLLC
8005 Clear Brook Drive
Raleigh, North Carolina 27615
January 14, 2014

Cape Lookout
Environmental Sciences -
January 14, 2014
North Carolina DENR-DWQ
Underground Injection Control Program
Aquifer Protection Section
1636 Mail Service Center
Raleigh, NC 27699-1636
Attention: Mr. David Goodrich
Reference: 5th Quarterly Post Injection/Extraction Monitoring Report
Peden Family, LLC, 1859 Capital Boulevard
Wake County, Raleigh, North Carolina
NCDENR Incident No. 21567
CLES Project Number: 13-002
Dear Mr. Goodrich:
RECEIVED/DENR/DWR
JAN 1 6 2014
Water Quality
Permitting Section
Cape Lookout Environmental Sciences, PLLC (CLES), on behalf of Peden Family, LLC (Peden),
is submitting this 5th Quarterly Post Injection/Extraction Monitoring Report for the remedial
activities at the Peden facility. Peden is located at 1859 (formerly 1815) Capital Boulevard in
Raleigh, North Carolina.
Please find one copy of the enclosed 5th Quarterly Post Injection/Extraction Monitoring Report.
Two copies of this report were also delivered to the Raleigh Regional Office for filing. If you
have any questions concerning the contents of this submittal, please contact me at (919) 880-
6801.
Sincerely,
Cape Lookout Environmental Sciences, PLLC
a:117t_-/Wma
David B. Wells, P.G.
Senior Geologist/Project Manger
Enclosure
One Copy — 5th Quarterly Post Injection/Extraction Monitoring Report
Cape Lookout Environmental Sciences, PLC
8005 Clear Brook Drive, Raleigh, NC 27615 - 919.880.6801

RECEIVED/DENR/DWR
JAN 16 2014
Water Quality
Permitting Section
1
f Cape Lookout
I Environmental Sciences.
5TH QUARTERLY
POST INJECTION/EXTRACTION MONITORING REPORT
PEDEN FAMILY LLC
WAKE COUNTY
UIC PERMIT NO. W10500329
i CDENR INCIDENT NO. 21567
CLES PROJECT NO. 13-002
Prepared for:
Peden Family LLC
1859 Capital Boulevard
Raleigh, North Carolina 27629
Prepared by:
Cape Lookout Environmental Sciences, PLLC
8005 Clear Brook Drive
Raleigh, North Carolina 27615
January 14, 2014
„..to Oei6
David B. Wells, P.G.
Senior Geologist

1
1

Cape Lookout
Environmental Sciences.
January 14, 2014
Peden Family LLC
1859 Capital Boulevard
Raleigh, North Carolina 27629
Attention: Mr. Jim Peden
Reference: 5th Quarterly Post Injection/Extraction Monitoring Report
Peden Family LLC
Wake County
UIC Permit No. WI0500329
NCDENR Incident No. 21567
CLES Project No. 13-002
Dear Mr. Peden:
Cape Lookout Environmental Sciences, PLLC (CLES), is submitting the enclosed 5th
Quarterly Post-Injection/Extraction Monitoring Report for activities performed at the
above referenced site. The activities were performed as part of the ongoing remediation
in response to a petroleum release from underground storage tanks. This report
summarizes the groundwater monitoring activities performed by CLES following the
injection of a surfactant solution and vacuum extraction of emulsified petroleum fuel,
residual surfactant solution and groundwater. Our services were performed under the
terms and conditions outlined in the Agreement between Peden Family LLC (Peden) and
CLES, dated May 30, 2013.
Please find one copy of the enclosed report for your file. Three copies were delivered to
the North Carolina Department of Environment and Natural Resources (NCDENR) on
your behalf. Should you have any questions, please do not hesitate to contact us at
[phone].
Sincerely,
Cape Lookout Environmental Sciences, PLLC
David B. Wells, P.G.
Senior Geologist
L. Yamf-W
Christopher L. Hamblet, CHMM
Senior Consultant
Enclosure: 5th Quarterly Post Injection/Extraction Monitoring Report
C:1Cape Lookout Envinmmtal\Projects 12013102-2013 Peden Family LLC113-002 3rd Quarterly Report13rd Quarterly Post Injection Extraction Monitoring
Report.docx
Cape Lookout Environmental Sciences, PLLC
8005 Clear Brook Drive, Raleigh, NC 27615 - 919.880.6801

I

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC. Raleigh North Carolina January 14, 2014
TABLE OF CONTENTS
1. INTRODUCTION 1
1.1 Site Usage Historical and Present 1
1.2 Origin of Groundwater Contaminants 1
1.3 Previous Remedial Action 1
1.4 Injection/Monitor Well Installation 2
2. SURFACTANT INJECTION/EXTRACTION 3
2.1 Surfactant Injection 3
2.2 Extraction Emulsified LNAPL, Surfactant, Contaminated Groundwater 3
3. POST INJECTION/EXTRACTION GROUNDWATER MONITORING 4
3.1 Pre-5th Quarterly Monitoring 4
3.2 5th Quarterly Monitoring 4
3.2.1 Liquid Levels 4
3.2.2 Groundwater Sampling 5
3.2.3 Groundwater Sample Results 5
4. CONCLUSIONS 7
5. RECOMMENDATIONS 8
LIST OF TABLES
TABLE 1 Monitor Well Construction
TABLE 2
TABLE 3
TABLE 4
TABLE 5
TABLE 6
TABLE 7
Post Injection Liquid Level Monitoring
Surfactant Extraction Liquid Level Monitoring
Groundwater Elevations
Historical Groundwater Analyses
Field Parameters
Groundwater Analytical Results — December 30, 2013
LIST OF FIGURES
FIGURE 1
FIGURE 2
FIGURE 3
FIGURE 4
FIGURE 5
FIGURE 6
FIGURE 7
FIGURE 8
FIGURE 9
APPENDICES
APPENDIX I
APPENDIX II
APPENDIX III
Vicinity Map
Site Map Property Boundaries
Site Excavation Area
Injection/Extraction Well Locations
Injection System Diagram
Groundwater Potentiometric Map
Groundwater Constituent Concentration Map — December 30, 2013
Benzene lsoconcentration Contour Map
Total Xylenes lsoconcentration Contour Map
Calculations
Standard Operating Procedures
Laboratory Analytical Report
ii

i

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC, Raleigh, North Carolina January 14, 2014
1. INTRODUCTION
1.1 Site Usage Historical and Present
The Peden Family, LLC, site is located north of downtown Raleigh, North Carolina, at 1859
Capital Boulevard. Figure 1 is a Vicinity Map that depicts the site location. According to Wake
County Real Estate data and information summarized in a Comprehensive Site Assessment
Report Addendum, prepared by Abacus Consulting Inc. dated September 23, 2002, the subject
property is approximately 18-acres and is identified as Atlantic Center Incorporated. The
property is occupied by a vacant office building, recycling businesses, and offices for Peden
Commercial Realty. A steel fabrication plant previously occupied the property and operated
three underground storage tank (UST) systems that were used for fueling delivery vehicles.
The subject property is currently and has been used historically for commercial and industrial
activities. The property boundaries are shown in Figure 2.
1.2 Origin of Groundwater Contaminants
A petroleum release was reported on April 7, 2000, after receipt of the UST closure assessment
sample results. One -10,000 gallon diesel, one -7,500 gallon gasoline, and one -1,000 gallon
gasoline storage tanks were permanently closed by removal. The approximate locations of the
former USTs are shown in Figure 3. Petroleum constituent concentrations above North Carolina
Department of Environment and Natural Resources (NCDENR) action levels were detected in
soils beneath all three tanks removed. Closure assessment observations and laboratory
analytical results indicated that petroleum constituents were not detected in soils collected from
beneath the pump islands or in soils above the tanks or to the sides of the tanks.
1.3 Previous Remedial Action
The UST's and associated pump islands and piping were removed as part of the initial
abatement measures for this site. Noble Oil Service removed and disposed of approximately 63
gallons of sludge from the tanks. Petroleum -impacted soils below the bottom of the UST's were
not removed during the closure activities.
Gasoline as light non -aqueous phase liquid (LNAPL) was reportedly measured on October 26,
2001, in monitor well MW-1. The LNAPL thickness was reportedly 8 inches (0.67 feet). In
November and December 2001, two aggressive fluid vapor recovery (AFVR) events were
conducted by others on behalf of Peden and reports were submitted to NCDENR. The two
AFVR events reportedly recovered approximately 21 gallons of LNAPL from MW-1. In June
2002, approximately 0.4 feet of LNAPL was measured in MW-1.
A third AFVR event was conducted on February 10, 2006, that reportedly removed
approximately 150 gallons of liquid (groundwater and LNAPL) from monitor well MW-10. Liquid
levels measured on February 15, 2006 documented approximately 0.5 inches of LNAPL on the
groundwater in monitor well MW-10.
Two monitor wells were used for a mobile multiphase extraction (MMPE) event that was
performed between January 2, 2007 and January 6, 2007. The two monitor wells used for the
MMPE events reportedly exhibited dissolved -phase groundwater contamination in excess of the
applicable NCDENR Gross Contaminant Levels (GCLs). The MMPE event was implemented
during a 96-hour time period. Approximately 3,999 gallons of petroleum -impacted groundwater
were recovered from the site during the MMPE event. Based on total emissions calculations
performed by Peden's contractor, approximately 792.6 pounds (or 121.93 gallons) of LNAPL
1

1
i1

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC, Raleigh, North Carolina January 14, 2014
was removed from the site release area during the MMPE event. Groundwater monitoring has
been conducted at the site since 2007. In January 2010, LNAPL in monitor well MW-10 was
documented with a thickness of 0.6 feet, which prompted additional remedial action. Historical
liquid level measurements from before 2010 are not listed in the attached tables.
1.4 Injection/Monitor Well Installation
In September 2011, five 2-inch diameter schedule 40 PVC monitor wells (P-1 through P-5) with
screened intervals of either 20 or 25 feet in length were installed. The site injection/extraction
and monitor well locations are shown on Figure 4. Note that monitor wells MW-2, MW-2D and
MW-6 were not located by previous consultants and are not shown on Figure 4. The monitor
well construction details are summarized in Table 1. Liquid levels were measured before
beginning the surfactant injection event at the subject site by S&ME, Inc., on May 29, 2012. A
measureable layer of LNAPL was detected in monitor wells MW-1 (0.82 feet), MW-10 (0.55 feet)
and P-2 (0.54 feet). The liquid levels previously reported by S&ME, Inc., are summarized in
Table 2.
2

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLCM Raleigh, North Carolina January 14, 2014
2. SURFACTANT INJECTION/EXTRACTION
2.1 Surfactant Injection
Surfactant injection was implemented by S&ME, Inc. between May 29, 2012 and June 1, 2012.
The injection was performed in general accordance with the North Carolina Department of
Natural Resources Division of Water Quality Underground Injection Control (UIC) Permit No.
WI0500329. Injection was performed to emulsify LNAPL present in the vadose zone soils and
on the water table. A solution composed of up to a three percent Aerosol® OT-75 surfactant
mixed with municipal potable water obtained from the City of Raleigh was injected into wells
MW-1, MW-9, MW-10, P-1, P-2, P-3, P-4 and P-5. The detail of the injection system used by
S&ME, Inc. is presented on Figure 5.
A total of approximately 7,600 gallons of municipal water were used during the injection
process. Approximately 6,800 gallons of surfactant solution and approximately 800 gallons of
municipal water were injected into the former source area of the release.
Following the surfactant injection event, the surfactant solution was allowed to permeate
through the aquifer formation for approximately two weeks to allow contact time between
surfactant and LNAPL-impacted vadose zone and aquifer material. S&ME monitored liquid
levels during the surfactant permeation period to observe the time required for liquid levels to
equilibrate in the aquifer. No LNAPL was measured during liquid -level measurement activities
conducted in the source area wells during the two week period following the surfactant injection
event. Liquid levels collected by S&ME, Inc. after the surfactant injection event are summarized
in Table 2.
2.2 Extraction Emulsified LNAPL, Surfactant, Contaminated Groundwater
Post -injection extraction activities recovered emulsified LNAPL, petroleum -impacted
groundwater, and residual surfactant from recovery wells during two events. Event one,
performed between June 19, 2012 and June 23, 2012, used MMPE technology. The second
extraction event, initiated October 29, 2012, used low flow total fluids pumping. Both events
reportedly used wells MW-1R, MW-1, MW-9, MW-10, P-1, P-2, P-3, P-4 and P-5 for recovery.
Shamrock Environmental Corporation performed the MMPE activities during event one and
transported liquids generated during the extraction process for disposal from events one and
two. The two extraction events recovered a cumulative 9,221 gallons of emulsified LNAPL,
petroleum -impacted groundwater, and residual surfactant from nine extraction wells. Disposal
records for the recovered liquids were previously submitted to NCDENR.
Liquid levels in the injection/extraction zone were measured after the first two surfactant
extraction events to observe the aquifer's response to the sustained vacuum and sustained low
flow pumping. The post -extraction liquid level data, summarized from S&ME, Inc.
measurements, is presented in Table 3. Historical groundwater elevation monitoring is
presented in Table 4. LNAPL was not measured during the liquid -level monitoring activities
performed by S&ME, Inc., on June 23, 2012, July 29, 2012, August 22, 2012, October 9, 2012,
October 29, 2012, March 19, 2013, or by CLES on July 4, 2013 or October 2, 2013.
Additional extraction from monitor wells MW-1 R, P-2, P-4, and MW-10 was performed in
December 2013 due to 1,2 dibromomethane (EDB) concentrations that were above the
NCDENR Gross Contaminant Level (GCL). Total fluids pumping removed 330 gallons of
contaminated groundwater. The liquids are temporarily stored in drums on -site. Disposal is
pending based on analytical results of the wastewater.
3

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC, Raleigh, North Carolina January 14, 2014
3. POST INJECTION/EXTRACTION GROUNDWATER MONITORING
3.1 Pre-5th Quarterly Monitoring
Monitoring was performed by S&ME on July 29, 2012, October 9, 2012, October 30, 2012
March 19, 2013, and by CLES on July 4, 2013 and October 3, 2013. The monitoring results
indicated that no measurable thickness of free product has been detected on the water table
based on liquid level measurements since the injection/extraction events.
One constituent, 1,2-dibromoethane (EDB) was reported with concentrations that were above
the GCL of 50 pg/L since the injection/extraction was performed. EDB concentrations in MW-1 R
have decreased from 390 pg/L to 250 pg/L during the first six post -extraction monitoring events.
EDB in groundwater from MW-1 was detected above the GCL (380 pg/L) before the injection,
and since the injection event the EDB concentration was below the detection level of 200 pg/L.
MW-1 has been dry for the past five monitor events. Monitor well MW-9 had an EDB detection
of 160 pg/L in October 2012 and concentrations were below the detection level of 100 pg/L
through July 2013. MW-9 was dry at the time of sampling in October 2013. Groundwater
sampled from MW-10 had one detection of EDB with a concentration of 73 pg/L on March 2013.
EDB on the groundwater sample analyzed from MW-10 was below the detection level (250
pg/L) on July 4, 2013 and was less than 100 pg/L on October 3, 2013. EDB concentrations in
monitor well P-4 since the injection ranged from 81 pg/L to 100 fag/L.
Petroleum constituents: benzene; n-butylbenzene; sec-butylbenzene; bromodichloromethane,
toluene; ethylbenzene; xylenes; isopropylbenzene; methyl tert butyl ether (MTBE); EDB;
naphthalene; n-propylbenzene; 1,2,4-trimethylbenzene; 1,3,5-trimethylbenzene; and/or, lead,
were detected with concentrations that were above the 15A NCAC 2L Groundwater Quality
Standard (2L Standard) in one or more groundwater samples analyzed during one or all three
network monitoring events. In October 2013, petroleum constituent concentrations were
detected above the 2L Standards for groundwater collected from eight monitor wells (P-1, P-2,
P-3, P-4, , MW-1 R, MW-1 D, MW-3, and MW-10). Wells MW-1 and MW-9 were both dry.
Lead concentrations above the 2L Standard were detected in groundwater analyzed from
monitor wells MW-1 R, MW-4, MW-5, MW-10, P-2 and P-4. Tetrachloroethene was detected in
groundwater analyzed from MW-4 and MW-8 with concentrations slightly above the 2L
Standard.
The laboratory analytical data representing groundwater analyses from the baseline
groundwater monitoring event performed September 29, 2011, and the monitoring performed
after extraction are summarized in Table 5.
3.2 5th Quarterly Monitoring
The 5th quarterly monitoring event was performed by CLES on December 30, 2013.
3.2.1 Liquid Levels
On December 30, 2013, the monitor wells were opened to allow site groundwater levels to
equilibrate with atmospheric pressure prior to liquid -level measurement and groundwater
sampling. After approximately one-half hour, the liquid -levels were measured from the top of
the well casings (TOC) with an electronic water level indicator at each monitor well location in
the network. The liquid level measurements were recorded in the field record. Monitor wells
MW-1 and MW-9 were dry. The monitor well TOC elevations, excluding P-1 through P-5, were
measured before September 2011 by Peden's previous consultant relative to an on -site
4

Ii

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC. Raleigh, North Carolina January 14 2014
reference benchmark with an assigned elevation of 100 feet. The TOC elevations for P-1
through P-5 were measured relative to the same site benchmark by CLES on July 12, 2013.
The groundwater level measurements were converted to groundwater elevations relative to the
site benchmark by subtracting the depth -to -water measurements from the measured TOC
elevations. Groundwater levels and LNAPL thicknesses measured since January 22, 2010, by
S&ME, Inc., and CLES are summarized in Table 4.
The groundwater elevations from December 30, 2013, were plotted and a potentiometric
surface of the groundwater contours was drawn using linear interpolation. The groundwater
potentiometric surface map is presented in Figure 6. The horizontal hydraulic gradient was
estimated using groundwater elevation data and three point calculations. On December 30,
2013, the groundwater appeared to flow to the north-northwest based on the three point
calculation using groundwater elevations from monitor wells P-5, MW-8, and MW-5. The
hydraulic gradient was approximately 0.031 ft/ft to the northwest. Calculations for hydraulic
gradient are included in Appendix I.
3.2.2 Groundwater Sampling
On December 30, 2013, CLES personnel visited the site to collect field measurements and to
purge and sample the monitor well network in general accordance with CLES' Standard
Operating Procedures (SOP — Appendix 11). During this site visit, two wells (MW-1 and MW-9)
were dry, and LNAPL was not present in a measurable thickness in the remaining 13 of the 15
network groundwater monitor wells.
After measuring liquid levels, monitor wells in the site monitor well network were sampled in
general accordance with the UIC Permit No. W10500329 and in general accordance with CLES'
SOPs. A new disposable PVC bailer and new section of nylon bailer cord were used to purge
and sample the network monitor wells. Water quality parameters, including temperature, pH,
and specific conductivity (Field Parameters), were measured with a handheld meter (Hanna
Model H198130) during groundwater purging. Groundwater samples were collected after the
field parameter measurements stabilized (+/- 5% change per measurement) for three
consecutive well volumes purged. If monitor wells went dry during purging, they were allowed to
recover before they were sampled. Field parameter measurements are summarized in Table 6.
Groundwater samples were collected from monitor wells MW-1 R, MW-3, MW-4, MW-5, MW-7,
MW-8, MW-10, MW-1 D, P-1, P-2, P-3, P-4 and P-5 by filling laboratory -provided containers with
groundwater poured directly from the bailer. The groundwater samples were labeled, placed
into a cooler with ice, and shipped under standard chain -of -custody procedures to
Environmental Science Corporation (ESC) in Mt. Juliet, Tennessee. The groundwater samples
were analyzed for volatile organic compounds (VOCs) by U.S. EPA Method 6200B and total
lead by Method 6010B.
3.2.3 Groundwater Sample Results
Petroleum constituent concentrations were detected above the 2L Standards in groundwater
collected from nine monitor wells (P-1, P-2, P-3, P-4, MW-1 R, MW-1 D, MW-3, and MW-10).
Petroleum constituent concentrations above the NCDENR GCLs were detected in MW-1, MW-
10 and P-2 before the injection and extraction event. Analyses from the December 30, 2013
monitoring event detected only EDB concentrations in MW-1 R that was above the GCL for this
fifth quarterly sample event. The petroleum constituents detected in groundwater samples
collected from monitor wells at the site are presented on Figure 7. The benzene and total
xylenes isoconcentration contour maps from the December 30, 2013 monitoring event are
5

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC. Raleigh, North Carolina January 14 2014
presented on Figure 8 and Figure 9, respectively. Lead concentrations above the 2L Standard
were detected in groundwater analyzed from monitor wells MW-1 R, MW-4, MW-10, P-1, P-2,
and P-4. Tetrachloroethene was detected in MW-4 with a concentration slightly above the 2L
Standard. The analytical data from the October 3, 2013 groundwater monitoring event is
summarized in Table 7. A copy of the laboratory report with chain -of -custody is attached in
Appendix III.
6

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC, Raleigh. North Carolina January 14 2014
4. CONCLUSIONS
Between May 29, 2012 and June 1, 2012, approximately 6,800 gallons of surfactant solution
and 800 gallons of potable water were injected into eight injection wells at the Peden site.
Extraction performed in two events recovered 9,221 gallons of emulsified free product,
surfactant solution and contaminated groundwater. Approximately 330 gallons of contaminated
groundwater were recovered by pumping in December 2013 from the MW-1 R, MW-10, P-2 and
P-4. On December 30, 2013, two wells were dry and the liquid level measurements did not
detect measurable thickness of LNAPL in the remaining 13 monitor wells gauged.
The fifth quarterly post -extraction groundwater monitoring event was conducted on December
30, 2013. Petroleum constituent concentrations above the 2L Standards were detected in eight
monitor wells. EDB was detected with concentrations above the NCDENR GCL in groundwater
sampled from MW-1 R in this fifth quarterly sample event. Lead concentrations were detected
above the 2L Standard in six of the thirteen groundwater samples analyzed.
7

1

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC. Raleigh, North Carolina January 14, 2014
5. RECOMMENDATIONS
CLES recommends that the post -injection monitoring plan outlined in the UIC Permit Application
and the subsequent permit issuance letter from NCDENR dated March 14, 2011, continue to be
implemented.
Since dissolved petroleum constituent concentrations in groundwater continue to be detected at
levels greater than GCLs in MW-1 R additional extraction from the source area wells is
recommended. If elevated EDB concentrations are detected after additional extraction is
performed, injection of calcium peroxide slurry may be recommended to enhance oxidation and
then aerobic bioremediation in the aquifer. If four consecutive quarters of groundwater
monitoring data indicate that dissolved petroleum constituents at the site are below GCLs,
CLES recommends that a Notice of Residual Petroleum (NORP) be prepared and that a "no
further action notice" for the incident be requested from NCDENR.
8

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC, Raleigh, North Carolina January 14. 2014
LIST OF TABLES
TABLE 1
TABLE 2
TABLE 3
TABLE 4
TABLE 5
TABLE 6
TABLE 7
Monitor Well Construction
Post Injection Liquid Level Monitoring
Surfactant Extraction Liquid Level Monitoring
Groundwater Elevations
Historical Groundwater Analyses
Field Parameters
Groundwater Analytical Results — December 30, 2013

I
I

TABLE 1
MONITOR WELL CONSTRUCTION
PEDEN FAMILY, LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
CLES PROJECT NO.13-002
Pa9e1 oft
Well ID
Date
Installed
(m/dd/yy)
Date
Water
Level
Measured
(nr/dd/yy)
Well
Casing
Depth
(6 BGS)
Screen
Interval
to ft.
Y BGS)
Bottom
of Well
(ft. BGS)
-Top of
Ground
Elevation (ft-
rel)
Top of
Casing
Elevationx
(ft-rep
Depth to
Water
from Top
of Casing
(ft-bloc)
Comments
MW-10
05111/00
05/31/02
46.00
46.0
to 51.0
51.00
99.72
100.84
33.77
Type 111- 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock
MW-2D
05/313/02
05/31/02
70.60
70.6
to 75.6
75.60
100.24
100.04
32,57
Type III - 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock Destroyed
MW-1
04/19/00
05/31/02
15.00
15.0
to 35.0
35.00
100.15
100.00
33.05
Type II- 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Top of Rock
MW-1R
0323/03
03/26I03
15.00
15.0
to 35.0
35.00
100.39
100.29
31.40
Type II- 4" Sch. 40 PVC
casing w/ 0.010 slat screen. Top of Rock
MW-2
05/11/00
05/31/02
12.50
12.5
to 32.5
32.50
99.94
99.79
31.10
Type II - 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Top of Rock Destroyed
MW-3
05/11/00
05/31/02
22.00
22.0
to 42.0
42.00
100.7
100.49
33.80
Type II - 2" Sch. 40 PVC
casing w/ 0.010 slat screen. Rock
MW-4
05/16/00
05/31/02
27.50
27.5
to 47.5
47.50
99.82
99.20
32.02
Type II - 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock
MW-5
07/18/00
05/31432
22.00
22.0
to 42.0
42.00
100.1
98.99
33.132
Type II- 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock
MW-6
05/30/02
05/31/132
18.00
18.0
to 43.0
43.00
99.53
99.33
32.39
Type II - 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Top of Rock Destroyed
MW-7
05/30/02
05/31/02
20.00
20.0
to 65.0
65.00
100.06
99.82
57.89
Typo casing g - w/ 0.01Sc0 40 PVC
0 slot screen. Rock
MW-B
135/30/02
05/31/02
20.00
20.0
10 45.0
45.00
98.68
98.47
31.80
Type II - 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock
MW-9
03/23/03
0326/03
21.70
21.7
to 31.7
31.70
100.04
100.10 I
I
31.40
Type II - 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Top of Rock
MW-10
0323/03
03/26/03
28.00
28.0
to 38.0
38.00
99.97
I
100.35
31.20
Type II- 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock
P-1
09/14/11
09/29/11
19.00
19.0
to 39.0
39.00
NM
100.27
34.59
Type II - 2" Sch. 40 PVC
casing w/ 0.010 slot screen.
P-2
09/14/11
0929/11
19.00
19.0
to 39.0
39.00
NM
I
99.17
33.70
Type II- 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock
P-3
09/13/11
0929/11
15.00
15.0
to 40.0
40.00
NM
100.08
34
Type II- 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock
P-4
09/14/11
09/29/11
15.00
15.0
to 40.0
40.00
NM
I
100.43
34.76
Type II - 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Top of Rock
P-5
09/15/11
09/29/11
19.00
19.0
to 39.0
39.00
NM
100.32
34.42
Type II- 2" Sch. 40 PVC
casing w/ 0.010 slot screen. Rock
"' If Free Product is present in a well, groundwater elevation is calculated by: [Top of Casing Elevation - Depth to Water] + [free product thickness x 0.8581 ].
ft. BGS = feet below ground surface.
11-bloc = feet below top of well casing.
ft-rel = Elevation relative to assumed site benchmark elevation of 100 feet.
Elevations MW-1 D,MW-1 R, MW-1, MW-3, MW-4, MW-5, MW-7, MW-9, MW-10 measured by S&ME, Inc. 3.29-2010 to a benchmark with an assigned elevation of 100'.
Elevations P-1 through P-5 measured by CLES 7-12-2013 to the well network relative to the benchmark used by S&ME, Inc. with an assigned elevation of 100'.
Peden Rawly, LLC
CLES Project No.13-02
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
Ismery 2014

TABLE 2
POST INJECTION LIQUID LEVEL MONITORING
PEDEN FAMILY, LLC, 1859 CAPITAL BOULEVARD
NCDENR INCIDENT NUMBER 21567
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13-002
Pace 1 of 3
Injection Zone Wells
Well ID
Date
Depth to Product (ft. bgs)
Depth to Water (ft. bgs)
Product Thickness (ft.)
MW-1
5/29/2012
33.52
34.34
0.82
6/4/2012
-
16.38
-
6/5/2012
-
18.07
-
6/6/2012
-
19.18
-
6/7/2012
-
20.06
-
6/8/2012
-
20.85
-
6/12/2012
-
23.36
-
6/13/2012
-
23.93
-
6/14/2012
-
24.46
-
6/15/2012
-
24.98
-
6/18/2012
-
26.68
MW-1D
5/29/2012
-
34.9
-
6/1/2012
-
34.27
-
6/4/2012
-
34.43
-
6/5/2012
-
34.47
-
6/6/2012
-
34.49
-
517 12
34.51
-
6/8r2012
-
34.55
-
6/12/2012
-
34.53
-
6/134012
-
34.52
-
6/14/2012
-
34.51
-
6/15/2012
-
34.53
6/18/2012
-
34.53
MW-iR
5/29,2012
-
34.03
-
6/1/2012
-
33.35
-
6/4/2012
-
33.75
-
6/5/2012
-
33.76
-
6/6/2012
-
33.81
-
- 6/7/2012
-
33.82
-
6/8/2012
-
33.85
-
6/12/2012
-
33.86
-
6/13/2012
-
33.84
-
6/14/2012
-
33.86
-
6/15/2012
-
33.86
6/18/2012
-
33.86
MW-9
5/29/2012
-
31.45
-
6/1/2012
-
13.01
-
6/4/2012
-
19.98
-
6/5/2012
-
20.04
-
6/6/2012
-
20.86
-
6/7/2012
-
21.28
-
6/8/2012
-
21.51
-
6/12/2012
-
22.15
-
6/13/2012
-
22.09
-
6/14/2012
-
22.32
-
6/15/2012
-
22.46
6/18/2012
-
22.89
MW-10
5/29/2012
33.90
34.45
0.55
6/1/2012
-
23.90
-
6/4/2012
-
31.36
-
6/5r2012
-
31.6
-
6/612012
-
32.26
-
6/7/2012
-
33.51
-
6/8/2012
-
32.76
-
6/12/2012
-
32.98
-
6/13/2012
-
32.92
-
6/14/2012
-
33.00
-
6/15/2012
-
33.02
-
6/18/2012
-
33.19
Notes
Measurement Data by S&ME, Inc.
Surfactant injection conducted from 5/29/2012 - 6/1/2012
Peden Family, LLC
CUES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

1

TABLE 2
POST INJECTION LIQUID LEVEL MONITORING
PEDEN FAMILY, LLC, 1859 CAPITAL BOULEVARD
NCDENR INCIDENT NUMBER 21567
RALEIGH, NORTH CAROUNA
CLES PROJECT NO.13-002
Pape 2 of 3
Injection Zone Wells
Well ID
Date
Depth to Product (ft. bgs)
Depth to Water (ft. bgs)
Product Thickness (ft.)
P-1
5/29/2012
-
33.92
-
6/1/2012
-
29.94
-
6/4/2012
•
30.38
-
6/5/2012
•
30.51
-
6/6/2012
-
30.57
-
6/7/2012
-
30.55
-
6/8/2012
-
30.70
-
6/12/2012
•
30.81
-
6/13/2012 ,_
-
30.85
-
6/14/2012
-
30.90
-
6/15/2012
-
30.93
-
6/18/2012
-
30.96
P-2
5/29/2012
32.65
33.19
0.54
6/1/2012
-
23.70
-
6/4/2012
-
32.34
-
6/512012
-
32.42
-
6/6/2012
-
32.45
-
6/7/2012
32.39
-
6/8/2012
-
32.53•
6/12/2012
-
32.48
-
6/13/2012
-
32.51
-
6/14/2012
-
32.53
-
6/15/2012
-
32.53
-
6/18/2012
-
32.69
P 3
5/29/2012
-
33.65
-
6/1/2012
-
5.21
-
6/4/2012
-
13.95
-
6/5/2012
-
14.69
-
6/6/2012
-
15.35
-
6/7/2012
-
15.61
6/8/2012
-
16.23
-
6/12/2012
-
18.02
-
6/13/2012
-
18.66
-
6/14/2012
-
19.34
-
6/15/2012
-
19.92
-
6/18/2012
-
21.32
-
P-4
5/29/2012
-
34.10
-
6/1/2012
•
4.12
-
6/4/2012
•14.24
-
6/5/2012
•14.78
-
6/6/2012
•
15.2
-
6/7/2012
-
15.5
-
6/8/2012
-
16.17
-
6/12/2012
-
18.56
-
6/13/2012
-
18.85
-
6/14/2012
-
18.19
-
6/15/2012
-
18.53
-
6/18/2012
19.61
P 5
5/29/2012
-
33.82
-
6/1/2012
-
32.35
-
6/4/2012
-
33.62
-
6/5/2012
-
33.58
-
6/6/2012
-
33.6
-
6/7/2012
-
33.58
-
6/8/2012
-
33.65
-
6/12/2012
-
33.53
-
6/13/2012
-
33.55
-
6/14/2012
-
33.55
-
6/15/2012
-
33.55
-
6/18/2012
-
33.67
-
Notes
Measurement Data by S&ME. Inc.
Surfactant Injection conducted from 5/29/2012 - 6/1/2012
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

ti
I
I 11

TABLE 2
POST INJECTION LIQUID LEVEL MONITORING
PEDEN FAMILY, LLC, 1859 CAPITAL BOULEVARD
NCDENR INCIDENT NUMBER 21687
RALEIGH, NORTH CAROLINA
CLES PROJECT NO.13-002
Pa 3 of 3
Peripheral Wells
Well ID
Date
Depth to Product (ft. bgs)
Depth to Water (ft. bgs)
Product Thickness (ft.)
MW-4
5/29/2012
-
33.02
6/1/2012
-
32.94
6/5/2012
-
32.93
-
6/6/2012
-
32.99
-
6/7/2012
-
32.95
-
6/8/2012
-
32.97
-
6/18/2012
32.95
-
MW-5
5/29/2012
-
34.51
-
6/1/2012
-
34.51
-
MW-7
5/29/2012
-
24.26
-
6/1/2012
-
24.24
-
MW-8
5/29/2012
-
32.89
-
6/1/2012
-
32.88
-
6/8/2012
-
32.91
6/13/2012
-
34.95
6/14/2012
-
32.94
-
6/15/2012
-
32.95
-
6/18/2012
-
32.95
-
Notes
Measurement Data by S&ME, Inc.
Surfactant injection conducted from 5/29/2012 8/1/2012
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January, 2014

•
t
1

TABLE 3
SURFACTANT EXTRACTION LIQUID LEVEL MONITORING
PEDEN FAMILY, LLC,1869 CAPITAL BOULEVARD
NCDENR INCIDENT NUMBER 21667
RALEIGH, NORTH CAROUNA
CLES PROJECT NO. 13-002
Parle 1 of 2
Ityection Zone Wells
Well ID
Date
Depth $ dud (R.
Depth to Water (ft. bgs)
Product Thickness (R.)
MW-1
6/19/2012
-
27.1
-
6/20/2012
-
30.89
-
6/22/2012
-
9.95
-
6/23/2012
-
19.08
-
7292012
-
30.43
-
8/22/2012
NM
DRY
NC
10/9/2012
NM
DRY
NC
10292012
NM
DRY
NC
3/192013
NM
DRY
NC
MW-ID
6/19/2012
-
34.54
-
6202012
-
35.82
-
_
6/23/2012
-
35.82
-
7292012
-
34.68
-
8222012
-
34.51
-
10/92012
-
33.57
10/29/2012
-
34.1
-
31192013
-
34.3
-
MW-1R
6119/7012
-
33 66
-
6/232012
-
35 14
-
6/232012
-
3511
-
726v2012
-
34.04
-
9)22/2012
-
33.86
-
10f512012
-
33.55
-
11292012
-
33.46
-
3f192013
-
33.68
-
MW-9
6/19/2012-
23.03
-
6202012
-
23.58
-
8232012
-
22.1
-
7292012
-
26.71
-
8222012
-
30.11
-
10/9/2012
-
28.75
-
10292012
-
30.21
-
3/192013
-
29.92
-
MW-10
6/19/2012
-
34.42
-
6232012
-
35.24
-
7292012
-
34.04
-
8/22/2012
33.99
-
10/92012
-
33.57
-
10/29/2012
-
33.60
-
3/19/2013
-
33.82
-
P-1
6/19/2012-
30.96
-
6/22/2012
-
24.01
-
6/23/2012
-
26.1
-
7292012
-
33.05
-
8222012
-
33.84
-
10/92012
-
33.36
-
10292012
-
33.34
-
3/192013
-
33.61
-
P-2
6/19/2012-
32.71
6202012
-
31.22
-
6/232012
-
33.33
-
729/2012
-
32.83
-
8122r2012
32.77
10/92012
-
32.34
-
1029/2012
-
32 36
-
3/192013
-
62.60
-
Notes
Meaurement data by S&ME, Inc.
Surfactant extraction conducted from 6/192012 - 6222012
- No free phase product encontered.
NM = Not measured.
NC = Not calculated
Peden Family, LLC
CLES Project No. 13-002
51h Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

1

TABLE 3
SURFACTANT EXTRACTION LIQUID LEVEL MONITORING
PEDEN FAMILY, LLC, 1859 CAPITAL BOULEVARD
NCDENR INCIDENT NUMBER 21587
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13-002
Pace 2 of 2
PriplirYal Weis
Well ID
Date
Depth to Product (k.
1:5P-3
Depth to Water (8. bps)
Product Thickness (fL)
6/19/2012
-
21.66
-
I__
6/20/2012
-
23.62
-
_
_ _ 6232012
_ -
- 35.44
-
7292012
-
33.60
-
822/2012
-
33.52
-
10/92012
-
33.17
-
10292012
-
33.15
-
3/19/2013
-
33.39
-
P-4
8/19/2012
-
19.82
-
E221412
-
13.0
-
8/23/2012
-
22.53
-
7/29/2012
-
33.63
-
8222012
-
34.03
-
10/9/2012
-
33.59
-
1029/2012
-
33 82
-
31492013
-
33.83
-
P-5
8/19/2012
-
35a
-
6202012
-
33.64
-
822/2612
-
33.62
-
623/2012
-
33.68
-
7292012
-
33.52
-
8/222012
-
33,56
-
10/92012
_ -
33.18
-
10292012
-
33.26
-
3/192013
-
33.56
-
M W-4
8/192012
-
32.97
-
7292012
-
33.13
-
8/222012
-
32.95
-
10/92012
-
32.91
-
10292012
-
32.51
-
3/192013
-
32.61
-
MW-7
6232012
-
NM
-
-
7292012
-
24.34
-
8222012
-
24.38
-
10/92012
-
24.65
-
-
10292012
-
24.20
-
3/19/2013
-
24.03
-
MW-8
6/19/2012
-
32.95
-
7292012
-
33.25
-
8222012
-
33.12
-
10/92012
-
32.86
-
10292012
-
32.88
-
3/192013
-
32.97
-
Ngtea
Measurement data by S&ME, Inc.
Surfactant extraction conducted from 6/192012 - 8222012
- No free phase product encontered.
NM = Not measured.
NC = Not calculated.
Peden Family, LLC
CLES Project No. 13-002
51h Quarterly Post Injection/Extraction
Groundwater Monitonng Report
January 2014

I
I

TABLE 4
GROUNDWATER ELEVATIONS
PEDEN FAMILY, LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13.002
Page 1 of 4
Well ID
TOC (Ft-rell
Date
DTP
Product Thickness DTW
GW Elev
MW-1
100.00
1/22/2010
NP
0.0 33.05
66.95
3/28/2010
NP
0.0
32.36
67.64
3/29/2010
NP
0.0
32.34
67.66
5/14/2010
NP
0.0
32.59
67.41
9/22/2010
NP
0.0
33.48
66.52
9/29/2011
34.17
0.69
34.86
65.73
5/29/2012
33.52
0.82
34.34
66.36
6/18/2012
NP
0.00
26.68
73.32
6/23/2012
NP
0.00
19.08
80.92
7/29/2012
NP
0.00
30.43
69.57
8/22/2012
NM
NC
DRY
NC
10/9/2012
NM
NC
DRY
NC
10/29/2012
NM
NC
DRY
NC
3/19/2013
NM
NC
DRY
NC
7/4/2013
NM
NC
DRY
NC
10/2/2013
NM
NG
DRY
NC
12/30/2013
NM
NC
DRY
NC
MW-1R"
100.29
1/22/2010
NM
NC
NM
NC
3/28/2010
NP
0.0
17.86
82.43
3/29/2010
NP
0.0
17.90
82.39
5/14/2010
NP
0.0
22.53
77.76
9/22/2010
NP
0.0
24.70
75.59
9/29/2011
34.65
0.01
34.66
65.64
5/29/2012
NP
0.00
34.03
66.26
6/18/2012
NP
0.00
33.86
66.43
6/23/2012
NP
0.00
35.14
65.15
7/29/2012
NP
0.0
34.04
66.25
8/22/2012
NP
0.0
33.86
33.55-
66.43
66.74
10/9/2012
NP
0.0
1029/2012
NP
0.0
33.46
68.83
3/19/2013
NP
0.0
33.88
66.61
7/4/2013
NP
0.0
33.35
66.94
10/2/2013
NP
0.0
33.50
66.79
12/30/2013
NP
MW-1D
100.84
1/22/2010
NP
0.0
34.02
66.82
3/28/2010
NP
0.0
33.28
67.56
3/29/2010
NP
0.0
33.22
67.62
9/22/2010
NP
0.0
34.36
66.48
9/29/2011
NP
0.0
35.29
65.55
5/29/2012
NP
0.0
34.90
65.94
_
6/18/2012
NP
0.0
34.53
66.31
6/23/2012
NP
0.0
35.82
65.02
7/29/2012
NP
0.0
34.68
86.16
8/22/2012
NP
0.0
34.51
66.33
10/9/2012
NP
0.0
33.57
67.27
10/29/2012
NP
0.0
34.10
66.74
3/19/2013
NP
0.0
34.30
66.54
7/4/2013
NP
0.0
34.00
66.84
10/2/2013
NP
0.0
34.15
66.69
12/30/2013
NP
0.0
34.73
66.11
MW-3
100.49
1/22/2010
NP
0.0
34.10
66.39
3/28/2010
NP
0.0
33.16
67,33
329/2010
NM
NC
NM
NC
9/22/2010
NP
0.0
34.42
66.07
9/29/2011
NP
0.0
35.40
65.09
5/292012
NM
NC
NM
NC
6/18/2012
NM
NC
NM
NC
6/23/2012
NM
NC
NM
NC
7/29/2012
NP
0.0
34.77
65.72
8/222012
NP
0.0
34.60
65.89
10/9/2012
NP
0.0
34.72
65.77
10/292012
NP
0.0
34.23
66.26
3/19/2013
NP
0.0
34.35
66.14
7/42013
NP
0.0
34.05
66.44
10/2/2013
NP
0.0
34.35
66.14
12/30/2013
NP
0.0
34.89
65.60
Notes: Data fom 9-29-2011 to 3-9-13 reported prvlously by S&ME, Inc.
Ft-bgs = Feet below the ground surface.
Ft-rel = Well casing elevations MW-1D,MW-1R, MW-1, MW-3, MW-4, MW-5, MW-7, MW-9, MW-10
measured by S&ME, Inc. 3-29-2010 to a benchmark (MW-1) with an assumed elevation of 100'.
Elevations P-1 through P-5 measured by CLES 7-12-2013 to the well network relative to the benchmark
used by S&ME, Inc. with an assigned elevation of 100'.
NM = Not measured.
NP = No product measured.
NC = Not calculated.
* If Free Product is present In a well, groundwater elevation is calculated by: [fop of Casing Elevation -
Depth to Water] + [free product thickness x 0.85811
Well damaged between 6-20-03 and 1-22-10.
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

r
1

TABLE 4
GROUNDWATER ELEVATIONS
PEDEN FAMILY, LLC
1889 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13-002
Page 2 of 4
Well ID
TOC (Ft-rel)
Date
DTP
Product Thickness
DTW
GW Elev
MW-4
99.20
1/22/2010
NP
0.0
32.37
66.83
3/28/2010
NP
0.0
31.51
67.69
3/29/2010
NP
0.0
31.51
67.69
9/22/2010
NP
0.0
, 32.72
66.48
9/29/2011
NP
0.0
33.77
65.43
5/29/2012
NP
0.0
33.02
66.18
6/18/2012
NP
0.0
32.95
66.25
6/23/2012
NM
NC
NM
NC
7/29/2012
NP
0.0
33.13
66.07
8/22/2012
NP
0.0
32.95
66.25
10/9/2012
NP
0.0
32.91
66.29
10/29/2012
NP
0.0
32.51
66.69
3/19/2013
NP
0.0
32.61
66.59
7/4/2013
NP
0.0
32.31
66.89
10/2/2013
NP
0.0
32.57
66.63
12/30/2013
NP
0.0
33.23
65.97
MW-5
98.99
1/22/2010
NP
0.0
33.61
65.38
3/28/2010
NP
0.0
32.50
66.49
3/29/2010
NM
NC
NM
NC
9/22/2010
NP
0.0
34.31
64.68
9/29/2011
NP
0.0
35.61
63.38
5/29/2012
NP
0.0
34.51
64.48
6/18/2012
NM
NC
NM
NC
6/23/2012
NM
NC
NM
NC
7/29/2012
NP
0.0
34.96
64.03
8/22/2012
NP
0.0
34.61
64.38
1019/2012
NP
0.0
34.04
64.95
14/29/2012
NP
0.0
34.01
64.98
3/19/2013
NP
0.0
33.99
65.00
7/4/2013
NP
0.0
33.45
65.54
10/2/2013
NP
0.0
34.24
64.75
12/30/2013
NP
0.0
35.15
63.84
MW-7
99.82
1/22/2010
NP
0.0
23.96
75.86
3/28/2010
NP
0.0
24.01
75.81
3/29/2010
NM
NC
NM
NC
9/22/2010
NP
0.0
24.41
75.41
9/29/2011
NP
0.0
26.90
72.92
5/29/2012
NP
0.0 1
24.26
75.56
6/18/2012
NM
NC
NM
NC
6/23/2012
NM
NC
NM
NC
7/29/2012
NP
0.0
24.34
75.48
8/22/2012
NP
0.0
24.38
75.44
10/9/2012
NP
0.0
24.65
75.17
10/29/2012
NP
0.0
24.20
75.62
3/19/2013
NP
0.0
24.03
75.79
7/4/2013
NP
0.0
24.15
75.67
10/2/2013
NP
0.0
24.44
75.38
12/30/2013
NP
0.0
25.73
74.09
MW-8
98.47
1/22/2010
NM
NC
NM
NC
3/28/2010
NP
0.0
31.25
67.22
3/29/2010
NM
NC
NM
NC
9/22/2010
NP
0.0
32.41
66.06
9/29/2011
NP
0.0
33.86
64.61
5/29/2012
NP
0.0
32.89
65.58
6/18/2012
NP
0.0
32.95
65.52
6/23/2012
NM
NC
NM
NC
7/29/2012
NP
0.0
33.25
65.22
8/22/2012
NP
0.0
33.12 ,
65.35
10+5)!2012
NP
0.0
32.86
65.61
10/29/2012
NP
0.0
32.86
65.61
3/19/2013
NP
0.0
32.97
65.50
7/4/2013
NP
0.0
32.63
65.84
10/2/2013
NP
0.0
32.97
65.50
12/30/2013
NP
0.0
33.52
64.95
Notes: Data fom 9-29-2011 to 3-9-13 reported prviously by S&M.E, Inc.
Ft-bgs = Feet below the ground surface.
Ft-rel = Well casing elevations MW-1D,MW-1R, MW-1, MW-3, MW-4, MW-5, MW-7, MW-9, MW-10
measured by S&ME, Inc. 3-29-2010 to a benchmark (MW-1) with an assumed elevation of 100'.
Elevations P-1 through P-5 measured by CLES 7-12-2013 to the well network relative to the benchmark
used by S&ME, Inc. with an assigned elevation of 100'.
NM = Not measured.
NP = No product measured.
NC = Not calculated.
* If Free Product is present in a well, groundwater elevation is calculated by: [Top of Casing Elevation -
Depth to Water] + (free product thickness x 0.85811.
" Well damaged between 6-20-03 and 1-22-10.
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
Ianuary 2014

1
(
1

TABLE 4
GROUNDWATER ELEVATIONS
PEDEN FAMILY, LLC
11159 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13.0112
Paae 3 of4
Well ID
TOC (Ft -rep
Date
DTP
Product Thickness
DTW
GW Elev
MW-9
100.10
122/2010
NM
NC
NM
NC
3/28/2010
NP
0.0
31.58
68.52
3/29/2010
NP
0.0
31.59
68.51
5/142010
NP
0.0
31.59
68.51
922/2010
NP
0.0
31.55
68.55
9292011
NP
NC
Dry
NC
5/292012
NP
0.0
31.45
68.65
6/1812012
NP
0.0
22.89
77.21
6/23/2012
NP
0.0
22.10
78.00
7292012
NP
0.0
26.71
73.39
8222012
NP
0.0
30.11
69.99
10/92012
NP
0.0
28.75
71.35
10/29/2012
NP
0.0
30.21
69.89
3/19/2013
NP
0.0
29.92
70.18
7/4/2013
NP
0.0
29.81
70.29
1022013
NP
0.0
30.86
69.24
12/3/32013
NP
0.0
31.39
68.71
MW-10
100.35
1/22/2010
33.36
0.6
33.98
66.90
3/28/2010
32.66
0.02
32.68
67.69
3/292010
32.65
0.02
32.67
67.70
5/142010
32.85
0.26
33.11
67.46
9222010
33.68
0.51
34.19
66.60
9292011
34.49
1.01
35.50
65.72
5292012
33.90
0.55
34.45
66.37
6/18/21]12
NP
0.00
33.19
67.16
6232012
NP
0.00
35.24
65.11
7292012
NP
0 00
34.04
66.31
8222012
NP
0.00
33.99
66.36
10/9/2012
NP
0.00
33.57
66.78
10292012
NP
0.00
33.60
66.75
3/192013
NP
0.00
33.82
66.53
7/421313
NP
0.00
33.37
66.98
1022013
NP
0.00
33.51
66.84
12/30/2013
NP
0.00
34.17
66.18
P-1
100.27
9292011
NP
0.0
34.59
65.68
5/292012
NP
0.0
33.92
66.35
6/182012
NP
0.0
30.96
69.31
6232012
NP
0.0
26.10
74.17
7292012
NP
0.0
33.05
67.22
8222012
NP
0.0
33.84
66.43
10/9/2012
NP
0.00
33.36
66.91
10/29/2012
NP
0.00
33.34
66.93
3/19/2013
NP
0.00
33.61
66.66
7/42013
NP
0.00
33.17
67.10
1022013
NP
0.00
33.35
66.92
12/302013
NP
0.00
34.06
66.21
0.00
P-2
99.17
9292011
33.41
0.29
33.70
65.72
5292012
32.65
0.54
33.19
66.44
6/182012
NP
0.0
32.69
66.48
6232012
NP
0.00
33.33
65.84
7292012
NP
0.00
32.83
66.34
8/222012
NP
0.00
32.77
66.40
10192012
NP
0.00
32.34
66.83
10292012
NP
0.00
32.36
66.81
3/192013
NP
0.00
32.60
66.57
7/4/2013
NP
0.00
32.14
67.03
1022013
NP
0.00
32.27
66.90
12/30/2013
NP
0.00
32.92
66.25
0 00
Notes: Data fom 9-29-201 to 3-9-13 reported prviously by S&ME, Inc.
Ft-bgs = Feet below the ground surface.
Ft-rel = Well casing elevations MW-1 D,MW-1 R, MW-1, MW-3, MW-4, MW-6, MW-7, MW-9, MW-10
measured by S&ME, Inc. 3-29-2010 to a benchmark (MW-1) with an assumed elevation of 100'.
Elevations P-1 through P-5 measured by CLES 7-12-2013 to the well network relative to the benchmark used
by S&ME, Inc. with an assigned elevation of 100'.
NM = Not measured.
NP = No product measured.
NC = Not calculated.
* If Free Product is present in a well, groundwater elevation is calculated by: [Top of Casing Elevation - Depth
to Water] + [free product thickness x 0.8581].
"Well damaged between 6-20-03 and 1-22-10.
Peden Family, LLC
CLFS Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January2014

1
ti

TABLE 4
GROUNDWATER ELEVATIONS
PEDEN FAMILY, LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13-002
Page 4 of 4
Well ID
TOC (Ft-rel)
Date
DTP
Product Thickness
DTW
GW Elev
P-3
100.08
9/29/2011
NP
0.0
34.36
65.72
5/29/2012
NP
0.0
33.65
66.43
6/18/2012
NP
0.0
21.32
78.76
6/23/2012
NP
0.0
35.44
64.64
7/29/2012
NP
0.0
33.60
66.48
8/22/2012
NP
0.0
33.52
66.56
10/9/2012
NP
0.0
33.17
66.91
10/29/2012
NP
0.0
33.15
66.93
3/19/2013
NP
0.0
33.39
66.69
7/442013
NP
0.0
32.98
67,10
10/2/2013
NP
0.0
33.08
67.00
12/30/2013
NP
0.0
33.74
66.34
0.00
P-4
100.43
9/29/2011
NP
0.0
34.76
65.67
5/2912012
NP
0.0
34.10
66.33
6/18/2012
NP
0.0
19.61
80.82
6/23/2012
NP
0.0
22.53
77.90
7/29/2012
NP
0.0
33.63
66.80
8/22/2012
NP
0.0
34.03
66.40
10/9/2012
NP
0.0
33.59
66.84
10/29/2012
NP
0.0
33.62
66.81
3/19/2013
NP
0.0
33.83
66.60
7/4/2013
NP
0.0
33.38
67.05
10/2/2013
NP
0.0
33.51
66.92
12/30/2013
NP
0.0
34.15
_ 66.28
0.00
P-5
100.32
9/29/2011
34.41
0.01
34.42
65.91
5/29/2012
NP
0.00
33.82
66.50
6/18/2012
NP
0.00
33.67
66.65
6/23/2012
NP
0.0
33.68
66.64
7/29/2012
NP
0.0
33.52
66.80
8/22/2012
NP
0.0
33.56
66.76
10/9/2012
NP
0.0
33.18
67.14
10/29/2012
NP
0.0
33.26
67.06
3/19/2013
NP
0.0
33.56
66.76
7/4/2013
NP
0.0
33.05
67.27
10/2/2013
NP
0.0
33.04
67.28
12/30/2013
NP
0.0
33.83
66.49
0.00
Notes: Data fom 9-29-2011 to 3-9-13 reported prviously by S&ME, Inc.
Ft-bgs = Feet below the ground surface.
Ft-rel = Well casing elevations measured by S&ME, Inc. 3-29-2010 to a benchmark (MW-1) with an
NM = Not measured.
NP = No product measured.
NC = Not calculated.
* 11 Free Product is present in a well, groundwater elevation is calculated by: [Top of Casing Elevation -
Well damaged between 6-20-03 and 1-22-10.
* If Free Product is present in a well, groundwater elevation is calculated by: [fop of Casing Elevation -
" Well damaged between 6-20-03 and 1-22-10.
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

i

TABLE 5
7RICAL GROUNDWATER ANALYTICAL RESULTS
N FAMILY, LLC
1a69 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13-002
Pave 1 of 4
Contaminant of
Convem'
/
cocoa
N
1
d
m
2
9
0
m
t
s
m
1 _
oi
cir1,2-Dlchloroethena
B
Mi
g
s
-5g
c
MW-1
9/22/2010
BDL
1,600'
BDL
BDL
BDL
BDl
<250
BDL
BDL
28,000
3,100
23,800
<250
<250
9/30/2011
BDL
BOL
BDL
BDL
BDL
BDL
3211 n0"
1,b-
80L
41,000
7/29/2012
<10,000
310
BDL
<200
<200
BDL
<200
<1 000
BDL
8,200
1.000
: 12,400
<200
<200
10/9/2012
Dry at the time of sampling
10/30/2012.
_ _ _ Dry at the time of sampling
3/19/2013
Dry at the time of sampling
7/4/2013
Dry at the time of sampling
10/3/2013
Dry at the time of sam<lin2 _
1204013
Dry at the time of sampling
MW-1R
12/162005
BDL
840
BOL
BDL
BDL
BDL
<500
BDL
BDL
11,000
1,300
11,000
<500
<500
9/29/2006
BDL
1.400
BDL
BDL
BDL
BDL
<100
BOL
BDL
13.000
1,600
8,500
<100
<100
9/22/2010
BDL
NS'
BDL
BDL
BDL
BDL
NS
BDL
BOL
NS
NS
NS
NS
NS
_
9/30/2011
_ BDL
_ 1.200
BDL
BDL
BDL
BDL
BDL
BDL
BOL
15,900
1,400
11,600
BOL
BDL
7/29/2012
<2500
1600
BDL
<50
<50
BDL
<50
<250
BDL
26,000
2,200
14,700
<50
82
_
IQI0/2012
<5000
_, 1,400
BDL _
<100
<100
BDL _
<100
<500
BDL
22A00
2,400
48,000
<700
110
104012012
880'
1 100
390
13.0
<10
.10
<10
<50
<250
11000
2,400
14 590
<10
110
3/19/2013
<2500
1J000
<500
00
<50
<50
<50
<750
<50
18,000
2,800
16700
<50
120
7/4/2013
<5.000
000
<1 000
<100
<100
<100
<100
<500
<100
20 000
3,709
16 700
<100
110
10/312013
<10,000
496'
<2000
<200
<200
<200
<200
<1000
<200
19,000
2,200
14 790
<200
<200
12/39/2013
Q6,000
490
<500
<60
<50
<50
<50
<250
<50
12,000
1,900
11,600
<50
85
NW
3/2212010
SOL
69.0
BDL
BDL
BDL
BOL
<10
BOL
SOL
520'
26
885
<10
16
9130,2011
74
330
BDL
2.9
2.2
BDL
BDL
BOL
BDL
41D
170
570
BOL
25
_
1030/2012
<250
_ 240
<50
6.7
5.2
<5
<5
<25
<5
316
450
670
<5
55
3/192013
<50
240
<10
8.9
4.4
<1
e1
<5
<1
270
540
740
<1
50
7/432013
<2,500
340
<500
<50
<50
<50
<50
<250
<50
450
490
590
<50
81
10/3/2013
<250
100
<50
16'
10
<5
<5
<25
<5
200
370
470
<5
81
121.0+2013
<Sob
240
<100
11
<10
<10
<10
<50
<10
360
640
730
<10
70
922/2010
BOL
<1.0
BDL
BDL
BDL
BDL
<1.0
BDL
BOL
<5.0
<1.0
<1.0
<1.0
<1.0
9/30/2011
BDL _
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
6.2
2.3
14
BDL
BDL
10//302012
<50
<1
<10
<1
<1
<1
<1
<5
7.9
<5
<1
<1
<1
<1
3/19/2013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<1
<1
<1
7/4/2013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
e1
<1
<1
10/3/2013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<2
<1
<1
12/33/2013
110
<1
12
<1
<1
<1
<1
<5
<1
<5
<1
<2
<1
<1
MW-5
12/16/2005
BDL
<1.0
BDL
BDL
BDL
BDL
<1.0
BDL
BDL
<1.0
<1.0
<1.0
<1.0
<1.0
B>29/2800
BDL
<1,0
BDL
SOL
@0L
BDL
. <1.0
BDL
op_
<1.0
<1.0
<1,0
<1.0
<1.0
9022010
BDL
<1.0
BDL
BDL
BDL
BDL
<1.0
BDL
BDL
<5.0
<1.0
<1.0
<1.0
<1.0
_
9/30/2011
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.0 _
6.7
BDL
8DL
10/30/2012
<50
<1
<10
<1
<1
<1
<1
<5
2.3
<5
<1
<1
<1
<1
3/192013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<1
<1
<1
7/42013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<1
<1
<1
10/3/2013
<50
<1
<10
<7
<1
<1
<1
<5
<1
<5
<1
<2
<1
<1
1&30/2013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<2
<1
<1
MW-6
12/16/2005-
BDL
3.700
BDL
BDL
BDL
BDL
<1000
BDL
BDL
24,000
1.900
13,000
<1000
<1000
4+.12006
Bt1t
2,900
BDL
BDL
BDL
BDL
<100
BDL
BDL
2;000
2.100
1;300
<100
<100
MIN-7
91222010
BDL
<1.0
BDL
SDL
BDL
BDL
<1.0
* BDL
BDL
<5.0
<1.0
<1.0
<1.0
<1.0
9/302011
BDL
BDL
BOX
SQL
BDL
BDL
BDL
BDL
BDL
SOL
1.3
8.1
BDL
BDL
10/302012
<50
<1
<10
<1
<1
<1
<1
<5
1.6
<5
<1
<1
<1
<1
3/192013
<50
<1
<10 T
<1
<1
<1
<1
<5
<1
<5
<1
<1
<1
<1
7/42013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<1
<1
<1
10/32013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<2
<1
<1
126.12013
-72-
<1
<10
<1
<1
<1
<1
<5
<1
e5
<1
<2
<1
<1
MW-5
12+1012005
BOL
<1.0
BDL
BDL
" BDL
BDL
<1.0
SOL
BDL
<1.0
<1.0
<1.0
<10
<10
9292096
BDL
<1,0
BDL
BDL
BDL
BDL
1.7
BDL
BDL
<1.0
<1.0
<1.0
<10
<1.0
922/1010
BDL
< 1 0
BDL
BDL
SQL
BDL
<1.0
BDX
BDL
<5 0
<1.0
<1 0
<1 0
<10
9'3Cb2011
BDL
BDL
BDL
SOL
BDL
BDL
BDL
BDL
BDX
SOL
1.8
BDL
BOL
BDL
10/302012_
<50
<1
<10
<1
<1
<1
<1
<5
1.6
<5
<1
<1
<1
<7
3/19/2013
<50
<1
.10
<1
<1
<1
<1
<5
<7
<5
<1
et
<1
<1
7e412013
150
<1
<10
<1
<1
<1
<1
<5
<1
<5 -
<1
<1
<1
<1
10/3,2013
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<2
<1
<1
12136201S
<50
<1
<10
<1
<1
<1
<1
<5
<1
<5
<1
<2
<1
<1
21 Standard (u111p
8,000
1
4,000
70
70
0.8
4
70
70
800
800
500
NL10
70
NCOENRGCLslu8!1I
6,000,000
5,000
4,000,000
8,900
8,500
NL
4,000
70,000
70,00D
280,000
84,500
85,500
NL
25,000
Note:
1. Analyzed by Method 602MS In 2005. 2006 and 2010. Analyzed by 6200E in 2011. Other contaminants were analyzed by 620013 for listed sample events.
2. Analyzed by EPA Method 3030C/200.7 in 2005 and 2006. Analyzed by 66010E since 2011.
3. Sample analytical concentrations are reported In micrograms per liter (ug/0.
4. Bold depicts constituents detected above the sample practical quantitation limit.
5. SHADED AND BOLD numbers indicate concentrations above NCAC 2L Groundwater Quality Standard.
6. Gross Contaminant Level (GCL)
7. SHADED AND BOLD and RED numbers Indicate concentrations above NCAC 2L Groundwater Quality Standard and NCDENR GCLa.
8. NS = Not Sampled.
'4 = Not Analyzed.
L = Not Usted.
Pedal Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

I

TABLE 5
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
PEDEN FAMILY, LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROUNA
CLES PROJECT NO. 13-002
Contaminant of
Concern'
5
E.
d
o
1.
2}
Methyl -tent -butyl -ether (MTBE)`
Ft
1,2-Dibromcethane (EDB)
1,2,3-Trlehloropropane
1
o
s
S
1,2,4-Trimethyl benzene
m
tit
e5
1,2-Dichloroethane
30ill
��15
MW-1
9/22/2010
BDL
BDL
1 100
<250
BDL
380
<250
1300
540
5,300
1,600
SOL
NA
9/30/2011
8.700
BDL
BDL
BDL
BDL
BDL
BDL
92,000
130,000
720.000
230.000
BM
2,800
7/29/2012-
<200
<2,000
<200
<200
BDL
<200
<500
<1,000
<200
3,200
1 980
<200
20
10/9/2012
_
Dry at the time of sampling
10/30/2012
Drat the lime of sampling
3/19/2013
Dry at the time of sampling
7/4/2013
Dry at the time of sampling
10/3/2013
Dry at the lime of sampling
1210r2013
Dry at the lime of sampling
MW-1R
12/16/2005
BDL
BDL
820
<500
BDL
80
<500
NA'
NA
NA
NA
BDL
30
9/29I2008
BDL
BDL
760
<100
BOL
52
<100
NA
NA
NA
NA
BDL
47
9/22/2010
BDL
BDL
NS
NS
BDL
NS
NS
NS
NS
NS
NS
BDL
NS
9/30/2011
BDL
BOL
920
BDL
BDL
BDL
BDL
BDL
BDL
1.400
970
BDL
250
7/29/2012
<50
<500
200
<50
BDL
390
<120
760
190
1,900
490
<50
66
1592012
<100
<1,000
160
<100
VOL
280
<250
1.200
240
1.590
410
<100
150
10/302012
21
100
100
<10
<250
300
<25
850
250
2,000
540
11
76
3/192013
<50
<500
<50
<50
<50
215C
<120
920
270
2,200
690
<50
100
7/42013
<100
<1,0110
<100
<100
<100
77.:
<250
<500
<100
3,800
3.100
<100
43
101312013
<200
<2900
<200
<200
<200
:Se
<500
<1000
210
1.700
450
<200
100
12/30/2013
<50
<500
<50
<50
<50
<120
610
190
1,700
460
<50
68
1r1W3
9/22/2010
BDL
BDL
10
<10
BDL
<10
.10
150
12
17
32
BDL
NA
9/302011
1.8
17
32
BDL
BDL
BDL
BDL
240
30
22
25
2.6
73
10/30/2012
8.0
<50
7
<5
<5
<5
<12
370
75
36
32
<5
<5
.L1/192013
5.1
<10
4.7
<1
<1
<1
<2.5
410
82
64
38
<1
7.9
7/4/2013
<50
<500
<50
<50
<50
<50
<120
<250
73
<50
<50
<50
<5.0
10/3/2013
8.4
<50
<5
<5
<5
<5
<12
350
110
62
38
<5
13
12/30/2013
11.0
<100
<10
<10
<10
<10
<25
380
110
57
37
<10
6.8
MW-4
922/2010
BDL
BDL
<1.0
<1.0
BDL
<1.0
<1.0
<5.0
<1.0
<1.0
<1.0
BDL
NA
9/30/2011
BDL
BDL
BDL
BOL
BDL
BDL _
BDL
BDL
1.0
5.8
1.7
BDL
43
10/30/2012
<t
<10
<1
1.9
4
<1
<2.5
<5
<1
0
<1
<1
7
3/19/2013
<1
<10
<1
1.8
<1
<1
<2.5
<5
<1
<1 '
<1
<1
18
7/412013
<1
<10
<1
2.0
<1
<1
<2.5
<5
<1
<1
<1
<1
20
10/3/2013
<1
<10
<1
1.8
<1
<1
<2.5
<5
<1
<1
<1
<1
32
1.236/ 013
<1
<10
<1
1.3
<1
<1
<2.6
<5
<1
<1
<1
<1
24
MW-5
12/16/2005
BDL
BDL
1.8
<1.0
BDL
<0.02
<1.0
NA
NA
NA
NA
NA
5.5
9/25/2006
BDL
BOL
<1.0
<1.0
BDL
<0.02
<1.0
NA
NA
NA
NA
NA
40
9222010
BDL
BDL
<1.0
<1.0
BDL
<1.0
<1.0
<5.0
<1.0
<1.0
<1.0
BDL
NA
9/30/2011
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
2.8
BDL
8DL
14
10/30/2012
<1
<10
<1
<1
1.4
<1
<5
<5
<1
<1
<1
<1
19
3119/2013
<1
<10
<1
<1
<1
0
<2.5
<5
<1
<1
<1
<1
<5
7/4/2013
<1
<10
<1
<1
<1
<1
<2.5
<5
<1
<1
<1
<1
<5
10/3/2013
<1
<10
<1
<1
0
<1
<2.5
<5
<1
<1
<1
<1
18
12l3/112015
<1
<10
<1 _
<1
<1
<1
<2.5
<5
<1
<1
0
<i
<5
MW-0
12/16/2005
BDL
BDL
2.200
<1000
BDL
33
<1000
NA
NA
NA
NA
NA
42
9M92006
BDL
BDL
1,000
<100
BOL
300
<100
NA
NA
NA
NA
NA
20
MW-7
922/2010
BDL
BDL
<1.0
<1.0
BDL
<1.0
<1.0
<5.0
<1.0
<1.0
<1.0
BDL
Na
9/30/2011
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
3.6
1.1
_
BDL
7.2
10/302012
<1
<10
<1
<1
<1
<1
<2.5
<5
<1
<1
<1
<1
<5
3/19/2013
<1
<10
<1
<1
<1
<1
<2.5
<5
<1
<1
<1
<1
<5
7/4/2013
<1
<10
<1
<1
<1
<1
<2.5
<5
<1
<1
_
<1
<1
<5
10/3/2013
<1
<10
<t
<1
<1
<1
<2.5
<5
<1
<1
<1
<1
7.7
12/34+2613
<1
<10
<1
<1
<1
<1
<2.5
<8
<1
<1
<1
0
<5
MW-6
12/16;2005
BDL
8DL
1.7
<1.0
SOL
0.064
<10
NA
NA
NA
NA
NA
<5.0
920/2006
BDL
BDL
1.3
1.1
SDL
<0.02
<1.0
NA
NA
NA
NA
NA
<5.0
rie22/2010
8DL
Sal
<1.0
1.1
BDL
<1.0
<1.0
<5.0
<1.0
<1.0
<1.0
6OL
NA
9/30001 i
BDL
BDL
BDL
1.8
BQL
BDL
BDL
BDL
BDL
4A
1A
BDL
7.8
10/30/2012
<1
<10
0
1.8
<1
0
<2.5
<5
<1
<1
<1
<1
<5
3/tt/'013
<1
<10
<1
1.6
<1
<1
<2.5
<5
<1
<1
<1
<1
<5
7/4/2013
<1
<10
<1
1.7
<1
0
<2.5
<5
<1
<1
<1
<1
<5
10/32013
<1
<10
<1
1A
<1
0
<2.5
<5
<1
<1 ''
<1
<1
<5
12/30/2013
<1
<10
<1
<1
<1
<1
<2.5
<5
<1
0 j
<1
<1
<5
2L Seanderd itq„l
NL
NL
20
0.7
3
0.02
0.005
6
70
400
400
0.4
15
NCOENR t3CL2 tu08!
NL
NL
20,000
700
3,000
50
NL
6,000
30,000
28,500
25,000
400
15,000
Note:
1. Analyzed by Method 602MS in 2005, 2006 and 2010 Analyzed by 620013 in 2011. Other contaminants were analyzed by 6200B for listed sample events.
2. Analyzed by EPA Method 3030C200.7 in 2005 and 2006. Analyzed by 8010E in 2011.
3. Sample analytical concentrations are reported In micrograms per Titer (ug/l).
4. Bold depicts constituents detected above the sample practical quantitation limit.
5. SHADED AND BOLD numbers indicate concentrations above NCAC 2L Groundwater Quality Standard.
8. Gross Contaminant Level (GCL)
7. SHADED AND BOLD and RED numbers indicate concentrations above NCAC 2L Groundwater Quality Standard and NCDENR GCLs.
8. NS = Not Sampled.
9. NA = Not Analyzed.
10. NL= Not Listed.
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

I

TABLE 5
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
a.OEN FAMILY, LLC
SAPITALBOULEVARD
JOH, NORTH CAROLINA
CLES PROJECT NO. 13-002
Pace 3 of 4
Contaminant of
Concern'
N
n•Butylbenzene
c
n
/jpS
ffi
ecAi
1
1
coU
s
tl
L
73
10
1
m
F
IsopTopylbenzene
I
MW-9
7/29/2012
39,009
<50
BDL
<50
<50
BDL
<50
<250
BDL
990
T
<50
6,000
<50
<50
10/9/2010
33,000
<100
BDL
<100
<100
BDL
<100
<500
BDL
<500
<100
4,000
<100
<100
10/30/2012
<5000
100
<1000
140
210
<100
<100
<500
<100
2,600
300
33,000
<100
<100
3/19/2013
<5,000
130
<1,000
<100
<100
<100
<100
<500
<100
2,500
200
17,100
<100
<100
7/4/2013
<5,000
110
<1,000
<100
<100
<100
<100
<500
<100
2,300
250
17,100
<100
<100
10/3/2013
Dry al the time of sampling
12/30/2013
Dry at the time of sampling
MW-10
12/16/2005
BDL
2,000
BDL
BDL
BDL
BDL
<100
BDL
60L
33,000
3,100
17,000
<100
<100
9/29/2008
NS
NS
BDL
NS
NS
BDL
NS
SOL
BDL
NS
NS
NS
NS
NS
9/22/2010
BOL
<5,000
BDL
BDL
BDL .
BDL
<5,000
BDL
SOL
30,000
10,000
85,000
<5,000
<5,000
9/30/2011
BDL
BDL
BDL
14,000
7,600
BDL
BDL
BDL
BDL
270,000
`-- -"-
840,000
BDL
19,000
7/29/2012
<25,000
270
BDL
<500
<500
BDL
<500
<2,500
BDL
9,400
2,700
18,500
<500
<500
10/9/2012
6160
330
BDL
<100
<100
BDL
<100
<500
BDL
9,800
1700
11,300
<100
120
10/30/2012
<500
240
<1000
<100
<100
<100
<100
<100
<100
10.000
3,200
14,600
<100
140
34191013
4900
310
<500
89
<50
<50
<50
<250
'50
9,400
1800
12,400
<50
140
7/4/7013
<12,000
260
<2,500
<250
<250
<250
<260
<3,200
.250
11000
2.500
10,800
<250
<250
10112013
<5000
240
<1,000
<100
<100
<100
<100
<500
<100
12,000
1200
15,706
<100
130
11531:/5 13
<'2500
99
<500
<50
<50
<50
<50
<250
<50
5,600
1,200
0,080
<10
69
MW-10
121161005
BDL
1.6
BDL
BDL
BDL
SOL
<1.0
E3D1
801_
<1.0
<1.0
<1.0
<1.0
<1.0
9/291006
BDL
1,7
BDL
BDL
BDL
BDL
<1.0
BDL
BDL
1.3
<1.0
<1.0
<1.0
<1.0
9/22/2010
BDL
27
BOL
DX
BOL
BOX
<10
BDL
BDL
570
86
1 590
<10
27
9/30/2011
110
17
SOL
0,4
5
B1.
SOL
SOL
BDL
430
23
1,340
BDL
30
7/291012
<250
47
BDL
6.5
<5.0
074.
<5.0
29
BDL
730
47
1.160
<5.0
24
10/90012
<250
39
BDL
7.4
<5.0
BDL
<5.0
<25
BDL
850
47
1,450
<5.0
31
10/30/2012
<1000
32
<200
<20
<20
<20
<20
<100
<20
750
49
1,510
<20
38
3/19/2013
<250
35
<50
12
7
<5
<5
<25
<5
520
70
1,200
<5
44
7/4/2013
<500
11
<100
<10
<10
<10
<10
<25
<10
340
14
810
<10
29
10/3/2013
<5000
240
<1 000
<100
<100
<100
<100
<500
<100
12,000
2,200
15,700
<100
130
12/002013
<50
23
<10
6.7
4.9
<1
<1
<5
<1
430
31
620
<1
33
P-1
9/30/2011
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BOL
2.100
1,600
8,000
BDL
BDL
10/3012012
<2500
<50
<500
<50
<50
<50
<50
<250
<50
a
2300 - --
- 1,300
8100 - -
<50
-75
3119/2013
Not Sampled
7/4/2013
<2,500
<50
<500
<50
<50
<50
<50
<250
<50
450
890
590
<50
58
10/3/2013
<1100
<25
<250
<25
<25
<25
<25
<120
<25
1.000
1,000
5.200
<25
95
` 12/302013
<1,200
<25
<250
<25
<25
<25
<25
<120
<25
820
790
3,700
<25
64
P-2
9/30/2011
BDL
5.100
BDL
8.400
BDL
BDL
BDL
BDL
270.0C
_ 110.000
61 _
BDL
13,000
7/2912012
5.400
270
BDL
<100
<100
BDL
<100
<500
BDL
12.000
2,300
12,800
<100
120
10/92012
<5000
170
BDL
<100
<100
BDL
<100
<500
BDL
11000
000
10600
<100
<100
10/30/2012
1,400
1
<10
<1
<1
1.8
<1
<5
<1
85
28
206
<1
2
3/19/2013
<5000
120
<1 000
<100
<100
<100
<100
<500
<100
17000
4,200
23,400
<100
200
7/4/2013
<12,000
<250
<2.500
<250
<250
<250
<250
<1.200
<250
7,700
2,600
14,600
<250
<250
10/3/2013
<2.500
<50
<500
<50
<50
<50
<50
<250
<50
6,400
2,200
13,300
<50
130
121302013
<2500
<50
<500
<50
<50
<50
<50
<250
<50
4.900
1.700
9.800
<25
110
P-3 -
9/30/2011
BDL
91
BDL
BDL
BDL
BDL
BDL
BDL
BDL
820
170
1500
BDL
BOL
10/30/2012
330
9
<10
5.2
3.4 _
<1
<1
<5
<1
130
38 1
1,030
<1
23
3/1912013
Not Sampled
7/4/2013
<1,200
94
<250
<25
<25
<25
<26
<120
<25
390
130
1.670
<25
<25
_
10/3/2013
<250
20
<50
8.9
<5
<5
<5
<25
<5
210
84
1,000
<5
12
12/3212013-
<250
16
<50
<5
<5
<5
<5
<25
<5
110
68
760
<5
11
P-4
, 9/302011
BDL
280
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1,400
230
1,780
BDL
BDL
7/29/2012
11,000
310
BDL
570
260
BDL
<10
<50
ROL
8400
1,800
14,200
<10
360
103012062
3,100
gee
<100
110
<10
<10
<i0
<50
<10
4,300
960
6,100
<10
92
3/19/2013
4,900
270
<500
62
<50
<50
<50
<250
<50
3,800
840
5,600
<50
57
7/4/2013
<2500
170
<500
<50
<50
<50
<50
<250
<50
2.900
560
4,300
<50
<50
10/3/2013
<1,200
220
<250
<25
<25
<25
<25
<120
<25
4,100
560
4,700 ..
<25
30
12,3011313
<1,00
96
<250
,, <25
<25
r25
<26
<120
<25
1,200
240
1.890
<25
<25
P-5
0,30/2011
BDL
BDL
BDL
BDL
5OL
BOL
BOL
BDL
BDL
BDL
BDL
4.2
BOL
BDL
10/30/2012
1,600
320
<200
<20
<20
<20
<20 000
<20
15,000
1400
13,200
<20
110
311a'2013
Mot Sernpwc
7/4/2013
<500
<10
<100
<10
<10
<10 <10
<50
<10
<50 <10_
<10 .
_ <10
<10
10/3/2013
<500
<1
<10
<1
<1
<1 <1
<5
<1
<5 <1
3.6
<1
<1
42,301013
89
<1
<10
<1
<1
<1 <1
<5
<1
<5 <1 _
2.0
<1
<1
IL Standard (ug11)
6,000
1
4,000
70
70
0.6 4
70
70
800 600
500
NL10
70
arCDEIIR O61..' I«L81
6,000,000
5,000
4,000,000
6,900
8,500
NL 4,000
70,000
70,000
260,000 64,500
85,500
NL
25,000
Note:
1. Analyzed by Method 602MS in 2005, 2006 and 2010. Analyzed by 620013 in 2011. Other contaminants were analyzed by 620013 for listed sample events.
2. Analyzed by EPA Method 3030C/200.7 in 2005 and 2006. Analyzed by 601 oB since 2011.
3. Sample analytical concentrations are reported in micrograms per Ilter (ug/).
4. Bold depicts constituents detected above the sample practical quantitation limit.
5. SHADED AND BOLD numbers indicate concentrations above NCAC 2L Groundwater Quality Standard.
6. Gross Contaminant Level (GCL)
' SHADED AND BOLD and RED numbers indicate concentrations above NCAC 2L Groundwater Quality Standard and NCDENR GCLs.
Not Sampled.
= Not Analyzed.
NL = Not Listed.
Peden Family, LLC
CLES Project No. 13.002
5th Quarterly Post Iajection/Extrsction
Groundwater Monitoring Report
January 2014

C

TABLE 5
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
PEDEN FAMILY, LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROUNA
CLES PROJECT NO. 13.002
Paae4of4
Contaminant of
Concern'
1N
d
1,1-
Met yl-tett-butyMther (MTBE)*
l
m
S
Trichloroethene
1
1,2-Dibromaethane (EDB)
f
1,2,3-Trichloropropene
1le
3
gE
a
s
I
EEE
1
2
E
6
m c
c
is
`r'
3
ill
�.-
MW-9
7/29/2012
230
<500
<50
<50
BDL
<50
<120
<250
<50
2,000
2,200
<50
58
10/9/2010
<100
<1,000
<100
<100
BDL
<100
<250
<500
<100
1,100
1,300
<100
28
10/30/2012
160
<1000
<100
<100
<100
160
<250
970
<100
13,000
10,000
<100
<22
3/19/2013
<100
<1,000
<100
<100
<100
<100
<250
<500
<100
4,400
4,000
<100
94
7/4/2013
3130
<1,000
<100
<100
<100
<100
<250
<500
<100
4,400
4,000
<100
22
10/3/2013
Dry at the Ome of sampling
12/30/2013
Dry at the time of sampling
MW-10
12/16/2005
BDL
BDL
1,400
<100
BDL
210
5.0
NA
NA
NA
NA
NA
75
9/292008
NS
NS
NS
NS
BDL
NS
NS
NS
NS
NS
NS
NS
NS
9/22/2010
BDL
BDL
<5,000 _
<5,000
BDL
<5,000
<5,000
<25,000
5,700
45,000
15,000
80L
NA
9/302
8DL
8
BDL
BDL
BDL
BDL
BDL
8DL
BDL
10
86,000
400,000
130,000
BDL 1
1,300
729/2012
<500
<5,000
<500
<500
BDL
<500
<1,200
<25,000
950
7,100
2,400
<500
44
10/9/2012
<100
<1000
<100
<100
BDL
<100
<250
650
270
2,900
190
<100
86
10/30/2012
<100
<1030
<100
<t00
<100
<100
.250
840
360
3,300
950
<100
57
3/19/2013
<50
<500
<50
<55
L <50
<120
650
430
3.200
1.090
<50
74
7/42013
.250
<2.500
<250
<250
<250
<250
<620
<1,200
660
5,700
1,700
<250
54
10/3/2013
<100
<1.000
<100
<100
<100
<100
<250
730
340
3,100
630
<100
45
12/30/2013
<50
<500
<50
<50
<50
<50
<120
830
180
1A00
420
<50
17
MW-ID
12/16/2005
BDL
Bdt.
<1.0
<10
BOL
<002
<1.0
NA
h64
NA
NA
NA
<5
929/2008
BDL
BOL
<1.0
<10
BDL _
<002
<I.0
NA
NA
NA
WA
NA
<5.0
9222010
BDL
BDL
<10
<10
BDL
<10
<10
110
53
450
200
BDL
NA
9/30/2011
2.8
BDL
12
BDL
8DL
BDL
BIM
110
25
350
170
BDL
20
7/29/2012
10
<50
25
<5.0
BDL
<5.0
<12
72
18
240
150
<5.0
<5.0
10/912012
<5.0
<50
26
<5.0
80L
<5.0
<12
110
28
230
180
<5.0
<5.0
10m2012
<20
<200
25
<20
<20
<20
<50
130
34
220
210
<20
<5
3/1942313
<5
<50
16
<5
<5 '
<5
<12
200
46
170
240
<5
<5
7142013
<10
<100
13
<10
<10
<10
<25
100
26
130
180
<10
<5
10/3/2013
<100
<1,000
<100
<100
<100
<100
<250
730
340
3,100
930
<100
<5
12/502013
6.2
<10
17
<1
<1
<1
<2.5
180
28
100
110
<1
<5
'-1
9/302011
BDL
BDL
BDL
BDL
8DL
BDL
BDL
690
280
2,200
750
BDL
3e
10/30/2012
<50
<500
<50
<50
<50
<50
<120
350
160
1.300
400
<50
_ <5
3/19/2013
Not 5amp4e0
7/4/2013
<50
<500
<50
<50
<50
<50
<120
<250
140
1,100
480
<50
20
10/3/2013
59
<250
<25
<26
<25
<25
<62
360
230
1,800
850
<25
10
12302013
34
<250
<25
<25
<25
<25
<62
390
130
1,100
590
<25
22
P-2
9/302011
BDL
BDL
BDL
BDL
BDL
BDL
BDL
58.00
78.000
BDL
98
7/29/2012
<100
<1000
<100
<100
BDL
<100
<250
490
310
2.300
670
<100
22
10/9/2012
<100
<1000
<100
<100
BDL
<100
<250
<500
250
1,700
500
<100
54
10/302012
1.2
<10
<1
<1
<1
<1
<2.5
14
5.8
57
24
<1
14
3/19/2013
<10D
<1.000
<100
<100
<100
<100
<250
1,200
530
4,000
1,100
<100
42
7/4/2013
<250
<2500
<250
<250
<250
<250
<820
<1 200
350
2,600
780
<250
39
10/3/2013
<50
<50
<50
<50
<50
<50
<120
630
340
2.500
760
_ <50 _
38
1223042013
<50
<500
<50
<50
<50
<50
<120
660
270
i, 2,000
590
<50
21
P-3
9/30/2011
BOL
BDL
120
BDL
BDL
BDL
BDL
BDL
58
820
440
BOL
67
10/30/2012,,
9.6
<10
8.3
<1
i <1
2.5
<2.5
180
36
460
160
<1
9.7
3/19/2013
Not Sampled
7/4/2013
26
<120
<25
<25
<25
<25
<82
<120
44
500
420
<25
13
10/3/2013
23
<50
<5
<5
<5
<5
<12
36
32
380
310
<5
10
12/302013
17
<50
<5
<5
<5
<5
<12
80
26
280
230
<5
9.1
P-4
9/30/2011
BDL
BDL
210
BDL
BDL
32
BDL
BDL
35
320
160
BDL
430
7292912
170
<100
84
<10
BDL
<10
<25
1,600
1,300
8.800
3,600
<10
550
19/3012012
110
<100
87
<10
<10
at
<25
620
204)
2,000
940
<10
480
31192013
<50
<500
77
<50
<50
CD
<120
350
190
1,900
840
<50
370
7/4/2013
<50
<500
<50
<50
<50
52
<120
<250
110
1,100
500
<50
240
10/32013
28
<250
35
<25
<25
15.:-
<62
190
74
740
310
<25
380
12202013
<25
<250
<25
<25
<25
<25
<62
130 1
40
390
200
<25
320
P-5
9130i2011
BDL
BDL
BDL
BOL
BOL
BDL
BDL
BDL
BDL
BDL
28
BDL
17
10430 2012
25
t200
<20
<23
<20
37
<50
710
260
2,000
570
<20
20
3001'2013
No1 Sampled
74412013
<10
<100
<10
<10
<10 <10
<25 <50
<10
<10
<10
<10
<5
10212013
<1
<10
<1
<1
<1 <1
<2.5 <5
<1
<1
3
<1
6.8
122912013
<1
<10
<1
<1
<1 <1
<2.5 <5
<1
•1.2
2.1
<1
<5
2L Standard Noll)
NL
NL
20 0.7
3 0.02
0.005 6
70
400
400
0.4
15
NCDENR °CLO (uglll
NL
NL
20,000 . 700
3,000 I 50
NL 6,000
30,000
28,500
25,000
400
15,000
Note:
1. Analyzed by Method 602MS In 2005, 2006 and 2010. Analyzed by 6200E In 2011. Other contaminants were analyzed by 6200B for listed sample events.
2. Analyzed by EPA Method 3030C/200.7 in 2005 and 2006. Analyzed by 6010E In 2011.
3. Sample analytical concentrations are reported in micrograms per liter (ug/1).
4. Bold depicts constituents detected above the sample practical quantitalion limit.
5. SHADED AND BOLD numbers Indicate concentrations above NCAC 2L Groundwater Quality Standard.
6. Gross Contaminant Level (GCL)
7. SHADED AND BOLD and RED numbers indicate concentrations above NCAC 2L Groundwater Quality Standard and NCDENR GCLs.
8. NS = Not Sampled.
9. NA= Not Analyzed.
10. NL = Not Listed.
Paden Family, LLC
CLES Project No. 13-002
51h Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

i
ii

TABLE 6
FIELD PARAMETERS
PEDEN FAMILY, LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13-002
Page 1 of 2
Well ID
Date
pH (SU)
Temperature
(Deg C)
Specific Conductance
(mS)
Comments
MW-1
9/29/2011
6.18
21.4
0.38
Product
7/29/2012
_ 6.43
21.8
0.22
Slightly Cloudy to Turbid
8/22/2012
NM
NM
NM
Dry
10/9/2012
NM
NM
NM
Dry
3/19/2013
NM
NM
NM
DrY
7/4/2013
NM
NM
NM
Dry
10/3/2013
NM
NM
NM
Dry
12/30/2013
NM
imM
NM
❑ry
MW-1 R
9/29/2011
8.16
20.4
0.36
7/29/2012
6.35
20.5
0.30
Slightly Cloudy
8/22/2012
5.77
22.2
0.25
10/9/2012
6.03
18.3
0.38
3/19/2013
6.13
18.5
0.30
Cloudy
7/4/2013
5.61
21.1
Cloudy
10/3/2013
5.89
20.1
_0.26
0.37
Cloudy
12/30/2013
5.88
18.6
-0.39
h•14V-1 i-,
9/29/2011
6 27
20.5
0.25
7/29/2012
6.51
2.4
0.27
Clear
8/2212012
6.07
21.2
0.33
10/9/2012
6.15
18
0.35
3119,2013
6.29
18.4
0.32
Clear
7/4/2013
6.08
20
0.38
Clear
UI/3/2013
6 31
19.5
0.34
12/3072013
8.22
18.2
6;313`--
MW-3
9/29/2011
P 6.67 _
20.4
0.45
7/29/2012
6.54
20.2
0.42
Clear
8/22/2012
6.01
23.9
0.46
10/9/2012
6.34
16
0.39
3/19/2013
6.17
17.1
0.36
Cloudy/Slightly Coudy
7/4/2013
6.11
20.1
0.39
Cloudy/Slightly Coudy
10/3/2013
6.18
19.7
0.35
Cloudy dry after one vol
12/30/2013
6.38
18 2
0.41
MW-4
9/29/2011
6.18
20
0.06
7/29/2012
5.97
21.2
0.07
Clear
8/22/2012
5.77
21.1
0.07
10/9/2012
6.77
17.1
0.08
3/19/2013
6.01
17.3
0.06
Cloudy
7/4/2013
5.86
19.9
0.06
Cloudy
10/3/2013
5.83
19.3
0.06
12/30/2013
5.7 a
16.1
0.10
MW-5
9/29/2011
5.86
18.4
0.03
7/29/2012
6.71
18.9
0.04
Clear
8/22/2012
5.5
20.1
0.08
10/9/2012
5.52
15.6
0.07
3/19/2013
5.5
17.1
0.05
Cloudy
7/4/2013
5.87
18.5
0.05
Cloudy
10/3/2013
5.76
17.9
D.03
Cloudy
12/30/2013
!,.73
16.8
0.04
MW-7
9/20/2011
6.05
19.7
0.05
7/29/2012
6.85
19.2
0.04
Clear
8/22/2012
5.36
21.8
0.05
10/9/2012
5.84
16.7
0.07
3/19/2013
5.87
17.9
0.06
Clear to slightly cloudy
7/4(2013
5.87
19
0.05
Clear to slightly cloudy
10/3/2013
5.64
19.1
0.05
Slightly Cloudy
12/30/2013
5 7
18.4
0.05
SU = Standard Units
Degree Celsius
mS = Milli Siemens
NM = Not Measured
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

1
1

TABLE 6
FIELD PARAMETERS
PEDEN FAMILY, LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
CLES PROJECT NO. 13-002
Pa 2 of 2
Well ID
Date
pH (SU)
Temperature
(Deg C)
Specific Conductance
(mS)
Comments
MW-8
9/29/2011
6.18
20.4
0.16
7/29/2012
7.46
20.4
0.21
Clear
8/22/2012
6.47
23.2
0.22
10/9/2012
6.45
18.5
0.20
3/19/2013
6.26
18.3
0.15
Clear
7/4/2013
6.05
20.1
0.17
Clear
10/3/2013
6.4
20.2
0.15
Clear
12/30/2013
5.35
19
0.17
I'MW-9
9/29/2011
-
-
-
Dry
7/29/2012
6.16
21.6
1.16
Turbid
8/22/2012
6.04
23
1.31
10/9/2012
5.66
17.9
0.54
3/19/2013
_ 6.08
19.1
0.82
Light foam
7/4/2013
5.84
21.6
0.65
Light foam
10/3/2013
6.12
21.2
0.72
Cloudy Dry after one vol
12/30/2013
NM
NM
NM
Dry
MW-10
9/29/2011
6.21
21.8
0.81
Product
7/29/2012
6.67
20.2
0.49
Cloudy Brown
8/22/2012
5.8
21.1
0.42
10/9/2012
6.21
18.6
0.43
3/19/2013
6.14
18.6
0.47
Light foam
7/4/2013
5.89
20.5
0.46
Light foam
10/3/2013
5.98
19.6
0.46
511ghlloam
12/30/2013
5. /
18.1
0.35
/'-1
9/29/2011
6.02
19.9
0.34
7/29/2012
6.65
20.9
0.71
Cloudy
8/22/2012
6.04
21.2
0.82
10/912012
7.05
17.3
0.73
3/19/2013
NM
NM
NM
Slight foam
7/4/2013
6.06
20.1
0.45
Slight foam
10/3/2013
5.54
19.9
0.28
Slight foam
12/30/2013
5.78
1 rT
(09
P-2
9/29/2011
6.22
21.9
0.32
Product
7/29/2012
6.52
19.9
0.31
Clear
8/22/2012
5.91
21
0.31
10/9/2012
6.04
18
0.49
3/19/2013
5.84
18.8
0.56
Slight foam
7/4/2013
5.81
20.9
0.67
Slight foam
10/3/2013
5.83
19.8
0.56
Slight foam
12/30/2013
5.60
18.1
0.53
P-3
9/29/2011
5.92
19.8
0.22
7/29/2012
6.06
21.1
0.19
Clear
8/22/2012
5.54
21.1
0.20
10/9/2012
5.71
18.4
0.20
3/19/2013
NM
NM
NM
Light foam
7/4/2013
5.63
20
0.27
Slight foam
10/3/2013
5.85
20.2
0.22
Slight foam
12/30/2013
5.79
18.1
0.20
P-4
9/29/20/ 1
6.1
19.5
0.31
7/29/2012
6.48
21.1
0.48
Cloudy
6/22/2012
5.9
20.7
0.52
10/9/2012
6.15
18.4
0.45
3/19/2013
6.24
18.6
0.48
Light foam
7/4/2013
6.08
20.9
0.58
Slight foam
10/3r2013
6.07
20.6
0 52
Slight foam
12/30/2013
61
18
9740
P-5
9/2912011
5.91
20.9
0.34
7/29/2012
6.4
21.1
0.45
Slightly Cloudy
8/22/2012
5.98
21.8
0.51
10/9/2012
6.18
18.5
0.43
3/19/2013
NM
NM
NM
Light foam
7/4/2013
5.78
20.2
0.29
Slight foam
10/3/2013
5.83
19.6
0.25
Slight Foam
12/30/2013
5.84
1 /.6
0.29
SU = Standard Units
Degree Celsius
mS = Milli Siemens
NM = Not Measured
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

I 1'

M
N
M
a
peel
NE3V
<1 <1 <1 <1 <5 <1 _ <1 <1 <5
<1 <1 <1 <1 <5 <1 <1 <1 <5
<1 <1 <1 <1 <5 <1 <1 <1 <5
Or at the time of sampling
<50 I <50 I <50 I <5C 1 630 1 160 1 1.400 1 420 I 17
o
h,—
euezueaftewPI-SE' i
§
M V
r W
Yf N
N N C
8
F.
N V
p 8
o T
8°
GGa q
0 NO§ o
M `�
ppN
m
N
6l1BZU8 U�. l{jBW-V Z L
euezuacpAdoid-u
.E r
0
v
A F.
E IS
4 V T°
eueleuludero
E0
mm24�
v
g $21)w
3
(8a3eumeowa9O-ZO
U
v
v '1,4:
8N
V) 17
O
(euegieoioiip zel
v
V ,'•
V v
'v
v o
.(39.1.11) llelAinq-liel-Aleut
(qy�
o V
r (9'8'
v)
M V N
R
euenloilJdOidosl-d
r v
m 3
'cy�'
9 V z
z
euezuaglfda
ppdesl CD
� V
V V V
1
M
M3C
,
O
y Y tiO
!
N
Seuei+�Xi of
SQ
O V
Y V V
oQ
?mA
88oQpp
§n
§N8
,e 41�413
� V
v V v
$
'
� $
-$4
§-
3
(euenlol
0.S8o�
§3W§�
0
Y §ar,N�
euezuegl4ln9-�
N
�-
0
V
�
0
:
�v
V 1§VE
euezue41�8-u
Dry at t
<25.000 1 490 r <500 1 <50 J
� V
<50 I <1 <10 <1
<50 <1 _ <10 _ <1.
<50 <1 <10 <1
Dry at t
<2500 I 99 •1 <500 1 <50
�v'?)NN
rp �
y v
O
y V ti
Sp
Oc
O
8 r,l
V—v
8-Z
V
88
v vNya
08
V
O
v
teUeZU88
V
�a
N
v
01 V—§
(C
i
GUOle j
p
V) r
y-
V v
a Y) NN
v y
00$00
V m
I 6,000,000
n
1
((����jpp,,,,,,
(L'w)
'MOW*�Ilo
9
WO
M M
O
N
r
12/30/2013
12/30/2013
12/30/2013
12/30/2013
12/30/2013
0
aP
12/30/2013 1
:12/30/2013
12/30/2013
12/30/2013
12/30/2013
12J /20l3
ird;u9D
INCDENRGCL° «I
Hem
mi7Yu7rW0,Da
��g��g2
2 2
2daaaaJ
J
Z
w
0
Z
0
0
v
a
2as
0
g
E 7
C O m
bJ
11 U
20
v aZ
c 8

1

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC. Raleigh North Carolina January 14, 2014
LIST OF FIGURES
FIGURE 1
FIGURE 2
FIGURE 3
FIGURE 4
FIGURE 5
FIGURE 6
FIGURE 7
FIGURE 8
FIGURE 9
Vicinity Map
Site Map Property Boundaries
Site Excavation Area
Injection/Extraction Well Locations
Injection System Diagram
Groundwater Potentiometric Map
Groundwater Constituent Concentration Map — December 30, 2013
Benzene Isoconcentration Contour Map
Total Xylenes Isoconcentration Contour Map

2013 9:48am — sthompson — H:\691 — Cope
TOPO SOURCE: NCGS DWG
RALEIGH EAST, DATED 2002
RALEIGH WEST, DATED 2002
CONTOUR INTERVAL 10 FEET
1 "= 2000'
12-30-13
DRAWN BY: D B W
PROJECT NO: 1 3- 002
Lookout ES\002
— Peden
Forn4\891-002—at-10-24-13-daq
454,
0
2000'
4000'
1
SCALE IN FEET
VICINITY MAP
DECEMBER 30, 2013
PEDEN FAMILY LLC
1859 CAPITAL BOULEVARD
RALEIGH NORTH CAROLINA
FIGURE NO.

0 2A 2013 12:27om — sthompson — H: 691 — Cope Lookout ES 002 — Peden Fom11r 691-002—c1-02-24-13.DWG
IMAGE SOURCE: GOGGLE EARTH PRO, 7/5/2010
0
300'
600'
SCALE IN FEET
SCALE:
"=300'
.ATE,
12-30-13
DRAWN BY:
DBW
1
• Cape Lookout
Environmental Sciences
PROJECT
NO: 13-002
SITE MAP_PROPERTY _BOUNDARIES
DECEMBER 30, 2013
PEDEN FAMILY LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
FIGURE NO.

10,28.'2013 12:25J•m - sthomvson - H:.691 - Cope Lookout ES 002 - Peden Fomi11\691-002-p1-02-24-13.0WG
FORMER 10,000 GAL. DIESEL UST-,
SB-2
S-7/B-2
S-1
�n
MW-9.
S-3
/ S-2
APPROXIMATE EXTENT/
OF EXCAVATION
BUILDING
MW-1
SB-4
SB-3
APPROXIMATE TRUCK SCALE LOCATION
FORMER 1,000 GAL. GASOLINE UST
MW-1R
MW-1D
SB-1
FORMER 7,500 GAL. GASOLINE UST
APPROXIMATE MONITOR WELL LOCATION (TYPE II & 111)
APPROXIMATE MONITOR/INJECTION/EXTRACTION WELL LOCATION
0 APPROXIMATE INJECTION/EXTRACTION WELL LOCATION
IMAGE SOURCE: NC ONEMAP, RALEIGH, DATED 2007
0 20' 40'
SCALE IN FEET
gCALE:
1 "-20'
SATE:
12-30-13
DRAWN BY: D B W
PROJECT NO: 13-002
Cape Lookout
Environmental Sciences
SITE EXCAVATION AREA
DECEMBER 30, 2013
PEDEN FAMILY LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
FIGURE NO.
3

}
L

10/28 2013 12:24: m — sthomrson — H: 691 — Co lookout ES\002 — Peden
Fommilr.691-002—e1-02-24-13_DWG
f.\
APPROX. SANITARY
SEWER LOCATION
MW-8
MW-9
P-5
MW-10
P-3
P-2
MW-1
MW-1 R
4.
yr
MW-1D
MW-5
MW-3
APPROXIMATE WATER LINE LOCATION
APPROXIMATE MONITOR WELL LOCATION (TYPE II & III)
APPROXIMATE MONITOR/INJECTION/EXTRACTION WELL LOCATION
APPROXIMATE INJECTION/EXTRACTION WELL LOCATION
SCALE:
1 "= 40'
JE:
12-30-13
DRAWN BY: De w
PROJECT NO: 1-002
•
Cape Lookout.
Environmental Sciences.
MW-4
46,
IMAGE SOURCE: NC ONEMAP, RALEIGH, DATED 2007
0 40'
L___ —
80'
1
SCALE IN FEET
INJECTION/EXTRACTION WELL LOCATIONS
DECEMBER 30, 2013
PEDEN FAMILY LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
FIGURE NO.
4

a'
LI
1

'0 28 2013 12:23om - sthomoson - 11:,691 - Cum Lookout ES'002 - Peden Fomil.\691-002-a1-02-24-13.0WG
TO ADDITHOfAL
INJECTION POINTS
VALVE
GROUND SURFACE -
VARIES
f--
POTABLE WATER I SURFACTANT/ OXIDANT -
1
TOP OF CASING •
WITH EXPANDABLE
LOCKING GAP
VALVE
TEMPORARY
MIXING TANK
PUMP
f WEU. CASING WEER
CONCRETE PAC -
VALE
f-- NEAT CEMENTGROUT 1 .
VARIES
- -- BENTONITESEAL
- 24 DIA. PVC RISER
1i
r DIA. SCHEDULE 40 PVC
SCREEN SLOTTED
(0.010INCHES) S'28
NO. 2 FILTER SAND
TYPICAL
PIEZOMETER INJECTION PORT
Q PRESSURE GAUGE
MANHOLE COVER
GROUND SURFACE
EXPANDABLE LOCKING CAP
NEAT CEMENT GROUT
BENTONITE SEAL
r DIA. SCHEDULE 40
PVC, RISER - SEE NOTE BELOW
r DIR. SCHEDULE 40
PVC SCREEN
SLOTTED (0.010 INCHES)
WELL POINT
(FLUSHIFLATTPOINT)
NO.2 FILTER SAND
TYPICAL
MONITOR WELL INJECTION PORT
NOTE DEPTH TO WATER t LNAPL VARIES FROM 3043 FEET BELOW GROUND SURFACE.
SCALE:
N.T.S.
.ATE:
DRAWN BY:
12-30-13
DBW
PROJECT NO:
13-002
•
$ Cape Lookout
• Environmental Sciences
INJECTION SYSTEM DIAGRAM
DECEMBER 30, 2013
PEDEN FAMILY LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
FIGURE NO.

i
I
■

1' •28/20' 3 1.13am — kho,as — H: io91 — Cape Lockout ES 002 — Peden Farm' 591-002—p1-02-24-1?.0iG
APPROX. SANITARY
SEWER LOCATION
MW-8
(62.95)
/ / o
p f
0
.►[- MW
/�! MW-s'' \ (Dry)
J' sm �� (DRY) $ � MW-1R
(66 8) - P-4 (66.49)�1 C9 MW-1 D
(66.11)*
MW-1O « P-3 $4 - `e A-1
(66.18) (66.34) `8 (66.21)
P-2
(66.25)
MW-5
6�pp (63.84)
MW-3
(65.6)
APPROXIMATE WATRR LINE LOCATION
'0 MW-4
(65.97)
APPROXIMATE MONITOR WELL LOCATION (TYPE II & III)
• APPROXIMATE MONITOR/INJECTION/EXTRACTION WELL LOCATION
e APPROXIMATE INJECTION/EXTRACTION WELL LOCATION
s 63.00 — GROUNDWATER ELEVATION CONTOUR (ft.) 12-30-13
(66.63) GROUNDWATER ELEVATION (ft.) - 12-30-13
GROUNDWATER FLOW DIRECTION AND
HYDRAULIC GRADIENT
MW-7
(75.09)*
IMAGE SOURCE: NC ONEMAP, RALEIGH, DATED 2007
0
40'
80'
If I J
SCALE IN FEET
NOTE:
MEASUREMENTS FROM MW-- i D, MW-7, MW-9
AND MW-1 NOT CONSIDERED IN GROUNDWATER
POTENTIOMETRIC SURFACE CALCULATIONS.
WELL CASING ELEVATIONS MW- 1 D, MW-1 R, MW-1
MW-3, MW-4, MW-5, MW-7, MW-9, AND MW-10
MEASURED BY S&ME, INC. 3/29/2010. P-1
THROUGH P-5 MEASURED BY CLES 7/12/2013.
gCALE:
1"=40'
ATE:
12-30-13
DRAWN BY: DB W
PROJECT NO: 13-002
Cape Lookout
Environmental Sciences
GROUNDWATER POTENi1OMRTRIC MAP
DECEMBER 30, 2013
PEDEN FAMILY LLC
1859 CAPITAL BOULEVARD
RALEIGH. NORTH CAROLINA
FIGURE NO.
6

I
1

aa
oMC mm..pr NCq 'uqQ •py0i7JW ((
mawap5 (mau:u0J+nu3
Inown ade) i
O
m
II
mm
C
m
0
s O
M80 2,03?PRAM
£ t-OE.Z
=„t
=n403
C�NI O Y J n10ON ♦ -1012 V el
aavn3lflos 1VildVD 6G21.
011AlfilVA N303d
£IOZ'OE 838 J 330
NOILMELINO3 ItElftW2d0D ELWANDIS
1
0 o O O CC
0 0 t b
mmC m
N N
E msia_
Id
Mt
N W m a E m m
� Ea m aci 5.n -� E E
0a2mae(4,6:
2r m m !-. W 1- !C W Z C N J
o
CQV r {m') t0 A A s M , iG eA9 m.
E E
m m
N N
m E m c a
m m m 9 =
m m c m a m n ££
. m s.m SX o E. aht-
3 c m o- L m n S am
Em ctwH adz
DECEMBER 30, 2013
a
V
0
U
W
�i
0a
0
O
L
z
0 0
z
0
v
u �
Y-se,
ti
Zus
4-
0
0`
z o
laG
C 0
z<
-G
Q z
viira
Q U
ma
IL1
N Q M m r r N o
N E
0 m m C C
a 2
E m m
N m C m C m N C
m y u a m v m m
0 m a, m E S X on w
3 m'9t�Ei$IOeQ"1
'gym c »}-wF yagz a N_
m
ff
ji
E
m
m
O nl m 4 Q h w N 7 T lu6 a e Q 6 0
7
O
m
0 o W o 0 0 0 0
.'NaQvm"`t aNn
N �mt
Ear
m E2 m
m EX i E=
N m O
P
sa N
b
m 0
m v c
E y E $
1111011
o X Q o t a H~
e Q Yl II
r F Q p 0 R N_ t7 p
dr-wF N0Z c
I
Il
1
l
—T
• N • P O
L
U
000
W A m 0 b O e 00!
r m O b N
O M
m m
C =
m m
N N
m m
c m a
C m C m N L L
e s Q to II
N 5 L O8 m 4 [h m
d H w F Z c a r
O! til N O o a , ?
W Co
m O m, r o m. n
rA m N N N 9
m
c
m C c
m 2 a
C
E m 2 r0 m N rs
m cg ®-$ a m m E E
'? m
g Q N O-o ri e Q Q
$ m
0.m F- W F 3 Z1

it
1

10/28/20i3 1:14crn - leicje_ - CS! - 1.2cpc Lockout ES\002 - Peden Femiij i6Si-171O2 •0-Q2-24-Il g;
APPROX. SANITARY
SEWER LOCATION
1 ug/L
(690)
(SOL)
MW-8
(BDL)
/; MW-1
% / (wry). - f`
_• �r i
MW-9
it
/ •
(Dry)
�!/ P-5 _ MW-1 R
P4 ' (BDL) 9 -((490)
(96) __________ CC s„ __________—
MW-10 —
1
(99)
P-3
p-1
(BDL)
p-2
f16) (BOL)
•
MW-5
(BDL)
MW-3
(240)
APPROXIMATE WATER LINE LOCATION
MW-1 D
(23)
MW-4
(BDL)
,APPROXIMATE MONITOR WELL LOCATION ('TYPE II & nl)
• APPROXIMATE MONITOR/INJECTION/EXTRACTION WELL LOCATION
APPROXIMATE INJECTION/EXTRACTION WELL LOCATION
A GROXIMAOUNE BENZENE ISOCONCENiRATION
BENZENE CONCENTRATION IN GROUNDWATER
ug/L ON 'DECEMBER 30, 2013
LEVEL
BELOW SAMPLE DETECTION
SCALE:
1 „_40,
4TE
12-30-13
-&.AWN BY: DB
t
PROJECT NO: 13-002
• Cape Lookukai
Environmental Sciei t k..3
44
Nert`, =r^Y-,: 2 5
IMAGE SOURCE: NC ONEMAP, RALEIGH, DATED 2007
0
L_ _ 40• 80'
SCALE IN FEET
NOTE:
15A NCAC 2L GROUNDWATER QUALITY STANDARD
FOR BENZENE IS 1 ug/L.
BENZENE LSOCONCENTRAIIO . CONTOUR MAP
DECEMBER 30, 2013
PEDEN FAMILY LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
FIGURE NO.
8
J

L
I

10/29/2.013 t:15 n - . - - - H: 691 Cge Lao.:out ES\002 - Peden Fcma \69t-002-• t-02-24-i3AwG
500 ug/L --
(14,700)
(BOL)
SCALE:
APPROX. SANITARY
SEWER LOCATION
MW-8
(BDL)
MW-1
(Dry)
•
1730)
APPRO Xtt,AATE WATER
5
/ MW-9 �d
/ I (Dry) MW-1 R �r
//� 2ir - o ((11800)
M
(1890)' PW-1D
(620)
MW-1D
(8000) r
` / (3700)
(760)
P-2
(9800)
UNE LOCATION
• MW-4
(80L)
•APPROXIMATE MONITOR WELL LOCATION (TYPE II & i!i)
*APPROXIMATE MONITOR/INJECTION/EXTRACTION WELL LOCATION
APPROXIMATE INJECTION/EXTRACTION WELL LOCATION
ISOCONCEENNTTRRATION INL XYLENES GROUNDWATER
TOTAL XYLENES CONCENYRATJQN_ ift. _GROUND-
WATER ug/L ON DECEMBER 30, 2013 _-
CONCENTRATION BELOW SAMPL DETECTION
LIMIT
Cape Lookout
Environmental Sciences
Ctesc 9r Raleigh. North Carolina 27515
(91g):3C-:.c0: C==eLea!:autErn;irchmenta:.w..
Mw-7
(BDL)
IMAGE SOURCE NC ONE MAP, RALEIGH, DATED 2007
0 40' 80'
L--Ili I
SCALE IN FEET
NOTE:
15A NCAC 2L GROUNDWATER QUALITY STANDARD
FOR TOTAL XYLENES IS 500 ug/L.
VAL XVNES BOCCAMIRKilai MOIR MAP
—DECEMBER 30, 2013
PEDEN FAMILY LLC
1859 CAPITAL BOULEVARD
RALEIGH, NORTH CAROLINA
FIGURE NO.

ti
f •1

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC. Raleigh. North Carolina January 14, 2014
APPENDICES
APPENDIX I Calculations
APPENDIX II Standard Operating Procedures
APPENDIX III Laboratory Analytical Report

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC, Raleigh, North Carolina January 14, 2014
APPENDIX I
(CALCULATIONS)

1

HYDRAULIC GRADIENT CALCULATIONS - December 30, 2013
Peden Family LLC
1859 Capital Boulevard
CLES Project No. 13-002
Purpose: To determine the hydraulic gradient
GIVEN:
GRADIENT 1S DEFINED: i = h, — h,
distance
Calculated from three point solution using the head of groundwater from
groundwater elevations measured at monitor wells P-5, MIN-8 and MW-5.
WHERE: Distance between hi and h2 is parallel to flow determined from the
three point problem using projection.
12 = P-5 — MW-8 = 66.49 - 62.95
distance
128
Calculate Distance for point with Elevation = MW-5 between P-5 and MW-8
P-5 - MW-5 = 66.49 - 63.84 =
0.0277 0.0277
0.0277
95.82
Place point on line 95.82 feet from P-5 toward MW-8, Draw line from point to MW-5.
Draw line perpendicular to Line drawn between MW-8 and Point 95.82 feet from P-5.
Project P-5 and MW-8 locations onto perpendicular line and measure new distance
between projected well locations.
Divide change in head between P-5 to MW-8 and divide by new distance to predict gradient.
P-5 - MW-8 =
New Distance
66.49 62.95 =
114
0.031 northwest flow
Peden Family, LLC
CLES Project No. 13-002
5th Quarterly Post Injection/Extraction
Groundwater Monitoring Report
January 2014

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC, Raleigh, North Carolina Janua 14 2014
APPENDIX II
(STANDARD OPERATING PROCEDURES)

)
_
I:

Cape Lookout
Environmental Sciences..
STANDARD OPERATING PROCEDURES
Soil Sampling, Soil Boring and Monitor Well Installation, Well Development
Soil borings are completed with a stainless steel hand auger, direct -push hydraulic drill or
auger rotary drill using either a macro core sampler, 3-1/4, 4-1/4, or 6-1/4-inch inside
diameter hollow stem augers. Soil borings are typically sampled at discrete intervals from
the bucket of a clean stainless steel hand auger, direct push stainless steel sampler with
acetate sleeve, or a split barrel sampler.
Monitor wells are completed in selected soil borings using one, two, or four -inch inside
diameter PVC casing and machine slotted screen intervals in accordance with 15A NCAC
2C Rules and North Carolina Department of Environment and Natural Resources guidelines.
Clean quartz sand is typically used to fill the boring annulus around the well screen to
approximately one foot above the screened interval, approximately one foot of hydrated
bentonite is placed over the sand pack and neat cement grout or bentonite is placed above
the well seal. Concrete is placed to secure the wellhead in the top three feet of boring
annulus. Wellheads may be completed with either flush mounted traffic -bearing protectors
with bolt down covers or steel above -ground protectors set in a concrete pad. Temporary
wells or piezometers may be completed with the PVC riser cut at or above grade. The
wellheads are secured with locking caps.
Wells may be developed using a bailer, electric submersible pump, pneumatic pump, or
peristaltic pump. When wells are developed by the driller, they may be developed with air
injection, water injection, pumping or bailing. Soil boring Togs and well construction details
are typically prepared for presentation in a report appendix. Borings completed in bedrock
may be drilled using air rotary, coring, or sonic drilling methods.
Liquid Levels
Groundwater Measurements
Groundwater level measurements are typically obtained using an electronic
soundinglinterface detection device which registers a tone or illuminated light when a probe
makes contact with the groundwater. Depth to groundwater measurements are obtained by
lowering a probe attached to a cable marked in 0.01 feet intervals into the well until the
probe of the meter intersects the product or water surface. The measurement from the top of
the riser pipe or top of casing (T.O.C.) to the liquid level is recorded. The measurement is
recorded to the nearest 0.01 foot. The electronic interface probe is decontaminated between
measurement locations.
LNAPL Measurements
Light Non -Aqueous Phase Liquid (LNAPL) present on the water table is measured using an
oilwater interface probe. The electronic meter has both an audible and illuminating light that
indicate when a liquid level is encountered. The oil/water interface probe registers a solid

'I

tone/light when LNAPL petroleum product is encountered and a beeping tone/light when
groundwater is encountered. Depth to LNAPL measurements are obtained by lowering a
probe attached to a cable marked in 0.01 feet intervals into the well until the probe of the
meter intersects the product or groundwater. The measurements from the top of the riser
pipe or top of casing (T.O.C.) to the liquid level is recorded. The measurement is recorded
to the nearest 0.01 foot. The thickness of LNAPL is calculated by subtracting the depth to
LNAPL measurement from the depth to groundwater measurement. The electronic interface
probe is decontaminated between measurement locations.
Soil Sampling
Soil sampling is performed in general accordance with ASTM: 1586-84 where applicable.
Sampling procedures are followed to protect the chemical integrity of the soil samples and
minimize the potential for cross contamination. This includes discarding of the exterior of
the sample which contacts the auger bucket, acetate sleeve, or split barrel sampler,
collecting the interior soil for screening with the PID or FID, and either pressure washing,
steam cleaning, or washing with non -phosphate detergent and/or rinsing sampling
equipment with clean water between sampling intervals. The samples are placed in glass
jars, sealed, and placed in an ice filled cooler. An aliquot of the sample is typically placed in
a clean sealable bag and allowed to reach ambient air temperature. The PID or FID is used
to measure total organic vapors (TOV) in the head space in each sample bag.
Excavation soil samples may also be collected from the bucket of excavation equipment.
Care to collect soil samples from excavation equipment includes retrieving native soil from
material that has not made contact with the excavating equipment. Samples are collected in
sealable bags or by directly filling sample containers using new gloves, laboratory provided
sampling utensils, or decontaminated stainless steel sampling equipment.
Field personnel don new, unused, disposable nitrile gloves at soil boring and sampling
locations. Gloves are changed between each sample interval. Sampling equipment such
as hand auger extensions and buckets, direct push samplers, split spoons and/or drilling
augers, are decontaminated before collecting samples.
Groundwater Sampling
Bailer or Dedicated Pump
Groundwater samples are collected using new dedicated polyethylene bailers or dedicated
pump with polyethylene tubing (or equal) at each monitor well. Before obtaining a sample, a
minimum of three well volumes of groundwater is typically evacuated from the well to ensure
collection of a sample representative of the in -situ groundwater conditions. Field
parameters (not limited to pH, specific conductance and temperature) are measured on
purged groundwater after each volume approximately equal to one water column in the well
is evacuated to monitor the changes of the field parameters in the groundwater as the
monitor wells are purged. Once the fluctuation of field parameters stabilizes to within ten
percent over three consecutive purge parameter measurements, or after the well is purged
dry and allowed to recover, the record sample is collected. The groundwater samples are
collected by directly filling laboratory -supplied containers with groundwater poured directly
from the dedicated disposable bailer or polyethylene tubing attached to the dedicated well
pump. Samples will be then transferred to insulated containers with ice for transport to the
laboratory. Field personnel don clean chemical resistant/non-reactive gloves at each well
during purging and don a new pair of gloves before filing sample containers.
2

i
1

Peristaltic Pump (Low Flow Method)
Groundwater is purged from the monitor wells using a peristaltic pump with either dedicated
Teflon -lined or PVC tubing inserted into the well, or using a clean section of disposable
silicon and a clean section of PVC tubing inserted into the well by the following low flow
sampling methods. The silicon tubing is inserted into the peristaltic pump. The silicon is
attached to the PVC or Teflon -lined tubing that is inserted into the monitor well to the bottom
of the well screen. The tubing is pulled back off of the bottom of the well with the end
located within the screened interval of the well and the peristaltic pump is started. The initial
flow from the well that passes through the peristaltic pump tubing is discharged into a bucket
or container. Once the initial turbid liquid effluent becomes relatively clear (lower turbidity)
the effluent may be passed through a flow cell for parameter measurements or captured in a
container so that a multi meter can be used to monitor field parameters. This minimizes
potential fowling of the flow cell and meters used to monitor field parameters. Field
parameters will be measured on groundwater purged from each well to monitor the changes
of the field parameters in the groundwater as the monitor wells will be purged. Field
parameters will be recorded after approximately each consecutive two minutes of pumping
from the peristaltic pump. Once the fluctuation of field parameters stabilizes at each well to
within ten percent over three consecutive measurements, the record sample is collected. If
the well is purged dry, it is allowed to recharge sufficiently for a sample to have be collected.
Samples will then be transferred directly from the section of silicon tubing into containers
supplied by the laboratory. Field personnel don clean chemical resitantlnon-reactive gloves
at each well during purging and before sampling activities.
Decontamination Procedures
The potential for cross -contamination between sample locations is minimized by thoroughly
cleaning the sampling equipment, both prior to the initiation of sampling and between uses.
Glass and Teflon® sampling equipment, in -situ hydraulic conductivity measurement
equipment, bucket augers and split -spoon samplers used for soil sampling, and other tools
and equipment will be decontaminated between each use according to the following
procedures:
• Remove excess soillsludge as necessary.
• Wash and scrub the equipment with a phosphate -free detergent in a hot tap water (prior
to field use) or ambient tap water solution. Use a brush to remove particulate matter and
surface films. Repeat as necessary.
• Rinse thoroughly with tap water.
• Rinse thoroughly with analyte-free water (deionized water).
• Allow the equipment to air dry.
• Prevent inadvertent contamination during storage and transport.
All personnel engaged in equipment decontamination wear clean, disposable chemical
resistant non -reactive gloves.
3

I

Aquifer Testing Procedures
Aquifer hydraulic conductivity testing is performed at selected wells to evaluate the relative
hydraulic conductivity at targeted locations. Rising head slug tests will be performed at
target monitor well/piezometer locations. Prior to performing the tests, the monitor
wells/piezometers will be opened and allowed to equilibrate. The water level in each
well/piezometer is measured to the nearest 0.01 feet using a decontaminated water level
probe. This reading is used as the initial reading for the tests. Slug tests will be performed
in the monitor wells/piezometers by installing into the monitor well a pressure transducer
equipped with a data recorder or that is attached to a data recorder. After obtaining an initial
water level reading, a clean polyethylene bailer of known volume is submerged in the water
in the well/piezometer. The filled bailer is removed and the water level in the
well/piezometer is monitored with the pressure transducer as the water level in the
well/piezometer returned to static conditions. The volume of water removed by the bailer is
noted. Tests may be repeated on or more times in each test welVpiezometer.
The transducer data is graphically evaluated in the field using Win -Situ (or equal) computer
software. The Win -Situ data is imported into an MS Excel® Workbook for analysis by
Bouwer-Rice techniques for partially or fully penetrating well screens using Aqtesolv®
computer software. The Bouwer-Rice techniques make a variety of simplifying assumptions
in the evaluation of slug test data. These include the assumptions that the aquifer in
question is homogenous, isotropic, and extends infinitely in the horizontal direction (Bouwer-
Rice, 1976).
4

1 j

5th Quarterly Post Injection/Extraction Monitoring Report CLES Project No. 13-002
Peden Family LLC_ Raleicti North Carolina _ _ January 14, 2014
APPENDIX III
(LABORATORY ANALYTICAL REPORT)

I

OESC
L. S•C•€•e.ai•C•=•S
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Report Summary
Wednesday January 08, 2014
Report Number: L676247
Samples Received: 12/31/13
Client Project: 13-002
Description: Peden Family LLC
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have any
questions regarding this data package, please do not hesitate to call.
Entire Report Reviewed By:
Laboratory Certification Numbers
A2LA - 14
FL - E874
NC - ENV3
SC - 8400
MN - 047-
TX - T104
61-01, AIHA - 100
87, GA - 923, IN
75/DW21704/BI0041
4, TN - 2006, VA
999-395, NY - 117
704245-11-3, OK -
Terrie Fudg
789, AL - 40660,
- C-TN-01, KY - 9
, ND - R-140. NJ
- 460132, WV - 23
42 WI - 99809391
9915, PA - 68-02
ESC / resentative
CA - 01157CA, CT - PH-0197,
0010, KYUST - 0016,
- TN002, NJ NELAP - TN002,
3, AZ - 0612,
0, NV - TN000032011-1,
979, IA Lab #364, EPA - TN002
Accreditation is only applicable to the test methods specified on each scope of accreditation held
by ESC Lab Sciences.
Note: The use of the preparatory EPA Method 3511 is not approved or endorsed by the CA ELAP.
This report may not be reproduced, except in full, without written approval. from ESC Lab Sciences.
Where applicable, sampling conducted by ESC is performed per guidance provided
in laboratory standard operating procedures: 060302, 060303, and 060304.
Page 1 of 49

J
4 I

OESC
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID MW-1R
Collected By DW / CH
Collection Date : 12/30/13 15:00
Parameter
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TA 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-01
Site ID : RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
Lead
58. 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone BDL 2500 ug/1 6200B-1997 01/08/14 50
Acrolein BDL 2500 ug/1 6200B-1997 01/08/14 50
Acrylonitrile BDL 500 ug/1 6200E-1997 01/08/14 50
Benzene 490 50. ug/1 6200B-1997 01/08/14 50
Bromobenzene BDL 50. ug/1 6200B-1997 01/08/14 50
Bromodichloromethane BDL 50. ug/1 6200B-1997 01/08/14 50
Bromoform BDL 50. ug/1 6200B-1997 01/08/14 50
Bromomethane BDL 250 ug/1 6200E-1997 01/08/14 50
n-Butylbenzene BDL 50. ug/1 6200B-1997 01/08/14 50
sec-Butylbenzene BDL 50. ug/1 6200B-1997 01/08/14 50
tert-Butylbenzene BDL 50. ug/1 6200B-1997 01/08/14 50
Carbon tetrachloride BDL 50. ug/1 6200B-1997 01/08/14 50
Chlorobenzene BDL 50. ug/1 6200B-1997 01/08/14 50
Chlorodibromomethane BDL 50. ug/1 6200B-1997 01/08/14 50
Chloroethane BDL 250 ug/1 6200B-1997 01/08/14 50
Chloroform BDL 250 ug/1 6200B-1997 01/08/14 50
Chloromethane BDL 120 ug/1 6200B-1997 01/08/14 50
2-Chlorotoluene BDL 50. ug/1 6200B-1997 01/08/14 50
4-Chlorotoluene BDL 50. ug/1 6200B-1997 01/08/14 50
1,2-Dibromo-3-Chloropropane BDL 250 ug/1 6200E-1997 01/08/14 50
1,2-Dibromoethane 200 50. ug/1 6200B-1997 01/08/14 50
Dibromomethane BDL 50. ug/1 6200B-1997 01/08/14 50
1,2-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/08/14 50
1,3-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/08/14 50
1,4-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/08/14 50
Dichlorodifluoromethane BDL 250 ug/1 6200B-1997 01/08/14 50
1,1-Dichloroethane BDL 50. ug/1 6200B-1997 01/08/14 50
1,2-Dichloroethane BDL 50. ug/1 6200B-1997 01/08/14 50
1,1-Dichloroethene BDL 50. ug/1 62008-1997 01/08/14 50
cis-1,2-Dichloroethene BDL 50. ug/1 6200B-1997 01/08/14 50
trans-1,2-Dichloroethene BDL 50. ug/1 6200B-1997 01/08/14 50
1,2-Dichloropropane BDL 50. ug/1 6200B-1997 01/08/14 50
1,1-Dichloropropene BDL 50. ug/1 62008-1997 01/08/14 50
1,3-Dichloropropane BDL 50. ug/1 6200B-1997 01/08/14 50
2,2-Dichloropropane BDL 50. ug/1 62008-1997 01/08/14 50
Di -isopropyl ether BDL 50. ug/1 6200B-1997 01/08/14 50
Ethylbenzene 1900 50. ug/1 6200B-1997 01/08/14 50
Hexachloro-1,3-butadiene BDL 50. ug/1 6200B-1997 01/08/14 50
Isopropylbenzene 85. 50. ug/1 6200B-1997 01/08/14 50
p-Isopropyltoluene BDL 50. ug/1 6200B-1997 01/08/14 50
2-Butanone (MEK) BDL 500 ug/1 6200B-1997 01/08/14 50
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 2 of 49

OESC
L•A•9 8•G•€•E•14,u.z.S
Y❑u rt LA 3:1
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
12065 Lebanon Rd.
Mt. Juliet, TE 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-01
Site ID : RALEIGH, NC
Sample ID M0-1R
Project # : 13-002
Collected By D8 / CH
Collection Date : 12/30/13 15:00
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 250 ug/1 6200B-1997 01/08/14 50
4-Methyl-2-pentanone (MIBK) BDL 500 ug/1 6200B-1997 01/08/14 50
Methyl tert-butyl ether BDL 50. ug/1 62008-1997 01/08/14 50
Naphthalene 610 250 ug/1 6200B-1997 01/08/14 50
n-Propylbenzene 190 50. ug/1 6200B-1997 01/08/14 50
Styrene BDL 50. ug/1 6200B-1997 01/08/14 50
1, 1, 1, 2-Tetrachloroethane BDL 50. ug/1 6200B-1997 01/08/14 50
1,1,2,2-Tetrachloroethane BDL 50. ug/1 6200B-1997 01/08/14 50
Tetrachloroethene BDL 50. ug/1 6200B-1997 01/08/14 50
Toluene 12000 2500 ug/1 62008-1997 01/08/14 500
1,2,3-Trichlorobenzene BDL 50. ug/1 6200B-1997 01/08/14 50
1,2,4-Trichlorobenzene BDL 50. ug/1 6200B-1997 01/08/14 50
1,1,1-Trichloroethane BDL 50. ug/1 6200B-1997 01/08/14 50
1,1,2-Trichloroethane BDL 50. ug/1 6200B-1997 01/08/14 50
Trichloroethene BDL 50. ug/1 6200B-1997 01/08/14 50
Trichlorofluoromethane BDL 250 ug/1 6200B-1997 01/08/14 50
1,2,3-Trichloropropane BDL 120 ug/1 6200B-1997 01/06/14 50
1,2,4-Trimethylbenzene 1700 50. ug/1 6200B-1997 01/08/14 50
1,3,5-Trimethylbenzene 480 50. ug/1 6200B-1997 01/08/14 50
Vinyl chloride BDL 50. ug/1 6200B-1997 01/08/14 50
o-Xylene 4100 50. ug/1 62008-1997 01/08/14 50
m&p-Xylenes 7900 100 ug/1 6200E-1997 01/08/14 50
Surrogate Recovery
Toluene-d8 104. % Rec. 6200E-1997 01/08/14 50
Dibromo£luoromethane 104. 8 Rec. 62008-1997 01/08/14 50
a,a,a-Trifluorotoluene 90.1 % Rec. 6200E-1997 01/08/14 50
4-Bromofluorobenzene 101. 8 Rec. 6200B-1997 01/08/14 50
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 3 of 49

r

ilESC
L•A•€•£•Ai• 1 8
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID MN-3
Collected By DW / CH
Collection Date : 12/30/13 13:20
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-02
Site ID : RALEIGH, NC
Project # : 13-002
Parameter Result Det. Limit Units Method Date Dil.
Lead 6.8 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone BDL 500 ug/1 6200B-1997 01/08/14 10
Acrolein BDL 500 ug/1 6200B-1997 01/08/14 10
Acrylonitrile BDL 100 ug/1 6200B-1997 01/08/14 10
Benzene 240 10. ug/1 62008-1997 01/08/14 10
Bromobenzene BDL 10. ug/1 6200B-1997 01/08/14 10
Bromodichloromethane BDL 10. ug/1 6200B-1997 01/08/14 10
Bromoform BDL 10. ug/1 6200B-1997 01/08/14 10
Bromomethane BDL 50. ug/1 62008-1997 01/08/14 10
n-Butylbenzene 11. 10. ug/1 6200B-1997 01/08/14 10
sec-Butylbenzene BDL 10. ug/1 6200B-1997 01/08/14 10
tert-Butylbenzene BDL 10. ug/1 6200B-1997 01/08/14 10
Carbon tetrachloride BDL 10. ug/1 6200B-1997 01/08/14 10
Chlorobenzene BDL 10. ug/1 6200B-1997 01/08/14 10
Chlorodibromomethane BDL 10. ug/1 6200B-1997 01/08/14 10
Chloroethane BDL 50. ug/1 6200B-1997 01/08/14 10
Chloroform BDL 50. ug/1 6200B-1997 01/08/14 10
Chloromethane BDL 25. ug/1 6200B-1997 01/06/14 10
2-Chlorotoluene BDL 10. ug/1 6200B-1997 01/08/14 10
4-Chlorotoluene BDL 10. ug/1 6200B-1997 01/08/14 10
1,2-Dibromo-3-Chloropropane BDL 50. ug/1 6200B-1997 01/08/14 10
1,2-Dibromoethane . BDL 10. ug/1 6200B-1997 01/08/14 10
Dibromomethane BDL 10. ug/1 6200B-1997 01/08/14 10
1,2-Dichlorobenzene BDL 10. ug/1 62008-1997 01/08/14 10
1,3-Dichlorobenzene BDL 10. ug/1 6200B-1997 01/08/14 10
1,4-Dichlorobenzene BDL 10. ug/1 6200B-1997 01/08/14 10
Dichlorodifluoromethane BDL 50. ug/1 6200B-1997 01/08/14 10
1,1-Dichloroethane BDL 10. ug/1 6200B-1997 01/08/14 10
1,2-Dichloroethane BDL 10. ug/1 6200B-1997 01/08/14 10
1,1-Dichloroethene BDL 10. ug/1 6200B-1997 01/08/14 10
cis-1,2-Dichloroethene BDL 10. ug/1 6200B-1997 01/08/14 10
trans-1,2-Dichloroethene BDL 10. ug/1 6200B-1997 01/08/14 10
1,2-Dichloropropane BDL 10. ug/1 6200B-1997 01/08/14 10
1,1-Dichloropropene BDL 10. ug/1 6200B-1997 01/08/14 10
1,3-Dichloropropane BDL 10. ug/1 6200B-1997 01/08/14 10
2,2-Dichloropropane BDL 10. ug/1 6200B-1997 01/08/14 10
Di -isopropyl ether BDL 10. ug/1 62008-1997 01/08/14 10
Ethylbenzene 640 10. ug/1 6200B-1997 01/08/14 10
Hexachloro-1,3-butadiene BDL 10. ug/1 6200B-1997 01/08/14 10
Isopropylbenzene 70. 10. ug/1 6200B-1997 01/08/14 10
p-Isopropyltoluene 11. 10. ug/1 6200B-1997 01/08/14 10
2-Butanone (MEK) BDL 100 ug/1 6200B-1997 01/08/14 10
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 4 of 49

1
1
1
1

OESC
L.A=9 S •G.i . ESN• LI• z•E
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received •December 31, 2013
Description •Peden Family LLC
Sample ID MW-3
Collected By DW / CH
Collection Date : 12/30/13 13:20
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-02
Site ID : RALEIGH, NC
Project # : 13-002
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 50. ug/1 6200B-1997 01/08/14 10
4-Methyl-2-pentanone (MIBK) BDL 100 ug/1 6200B-1997 01/08/14 10
Methyl tert-butyl ether BDL 10. ug/1 6200B-1997 01/08/14 10
Naphthalene 360 50. ug/1 62008-1997 01/08/14 10
n-Propylbenzene 110 10. ug/1 6200B-1997 01/08/14 10
Styrene BDL 10. ug/1 6200B-1997 01/08/14 10
1,1,1,2-Tetrachloroethane BDL 10. ug/1 62008-1997 01/08/14 10
1,1,2,2-Tetrachloroethane BDL 10. ug/1 6200B-1997 01/08/14 10
Tetrachloroethene BDL 10. ug/1 6200B-1997 01/08/14 10
Toluene 360 50. ug/1 6200B-1997 01/08/14 10
1,2,3-Trichlorobenzene BDL 10. ug/1 6200B-1997 01/08/14 10
1,2,4-Trichlorobenzene BDL 10. ug/1 6200B-1997 01/08/14 10
1,1,1-Trichloroethane BDL 10. ug/1 6200B-1997 01/08/14 10
1,1,2-Trichloroethane BDL 10. ug/1 6200B-1997 01/08/14 10
Trichloroethene BDL 10. ug/1 62008-1997 01/08/14 10
Trichlorofluoromethane BDL 50. ug/1 6200B-1997 01/08/14 10
1,2,3-Trichloropropane BDL 25. ug/1 6200B-1997 01/08/14 10
1,2,4-Trimethylbenzene 57. 10. ug/1 6200E-1997 01/08/14 10
1,3,5-Trimethylbenzene 37. 10. ug/1 6200B-1997 01/08/14 10
Vinyl chloride BDL 10. ug/1 6200B-1997 01/08/14 10
o-Xylene 480 10. ug/1 62008-1997 01/08/14 10
m6p-Xylenes 250 20. ug/1 6200B-1997 01/08/14 10
Surrogate Recovery
Toluene-d8 105. % Rec. 6200B-1997 01/08/14 10
Dibromofluoromethane 106. % Rec. 6200E-1997 01/08/14 10
a,a,a-Trifluorotoluene 92.3 % Rec. 6200E-1997 01/08/14 10
4-Bromofluorobenzene 103. 6 Rec. 6200B-1997 01/08/14 10
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 5 of 49

I 1'
ti

ESC
L,AG• ,e-FM F•5
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received
Description
••
December 31, 2013
Peden Family LLC
Sample ID MW-4
Collected By DW / CH
Collection Date : 12/30/13 12:45
Parameter
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-03
Site ID : RALEIGH, NC
Project # : 13-002
Result bet. Limit Units Method Date Dil.
Lead
24. 5.0 ug/1 60108 01/02/14 1
Volatile organics
Acetone 110 50. ug/1 62009-1997 01/07/14 1
Acrolein BDL 50. ug/1 62008-1997 01/07/14 1
Acrylonitrile HDL 10. ug/1 6200B-1997 01/07/14 1
Benzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromodichloromethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromoform BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromomethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
sec-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
tert-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Carbon tetrachloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorodibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloroform BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloromethane BDL 2.5 ug/1 6200E-1997 01/07/14 1
2-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
4-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromo-3-chloropropane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromoethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,4-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dichlorodifluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
cis-1,2-Dichloroethene BDL 1.0 ug/1 62008-1997 01/07/14 1
trans-1,2-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloropropene BDL 1.0 ug/1 62008-1997 01/07/14 1
1,3-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
2,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Di -isopropyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Ethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Hexachloro-1,3-butadiene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Isopropylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
p-Isopropyltoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
2-Butanone (HER) 12. 10. ug/1 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 6 of 49

1
I

ESC
L•A.G 5-• .€.£=A1.s.'.-�•S
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID MW-4
Collected By DM / CH
Collection Date : 12/30/13 12:45
12065 Lebanon Rd.
Mt. Juliet, TR 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-03
site ID : RALEIGH, NC
Project # : 13-002
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride ODL 5.0 ug/1 6200B-1997 01/07/14 1
4-Methyl-2-pentanone (MIBK) BDL 10. ug/1 6200B-1997 01/07/14 1
Methyl tert-butyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Naphthalene BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Propylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Styrene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Tetrachloroethene 1.3 1.0 ug/1 6200B-1997 01/07/14 1
Toluene BDL 5.0 ug/1 6200E-1997 01/07/14 1
1,2,3-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2,4-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,1-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichlorofluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2,3-Trichloropropane BDL 2.5 ug/1 6200B-1997 01/07/14 1
1,2,4-Trimethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3,5-Trimethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Vinyl chloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
o-Xylene BDL 1.0 ug/1 6200B-1997 01/07/14 1
m&p-Xylenes BDL 2.0 ug/1 6200B-1997 01/07/14 1
Surrogate Recovery
Toluene-d8 99.2 % Rec. 6200E-1997 01/07/14 1
Dibromofluoromethane 100. % Rec. 6200E-1997 01/07/14 1
a,a,a-Trifluorotoluene 94.7 % Rec. 6200B-1997 01/07/14 1
4-Bromofluorobenzene 87.8 % Rec. 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 7 of 49

i'

ESC
L•A,S S•C•€•E.eJ.L•�.&
Mr. David wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received
Description
••
December 31, 2013
Peden Family LLC
Sample ID Mw-5
Collected By •DW / CH
Collection Date : 12/30/13 12:15
Parameter
Lead
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Mallet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-04
Site ID : RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
BDL 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone BDL 50. ug/1 6200B-1997 01/07/14 1
Acrolein BDL 50. ug/1 62008-1997 01/07/14 1
Acrylonitrile BDL 10. ug/1 6200B-1997 01/07/14 1
Benzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromodichloromethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromoform BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromomethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
sec-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
tert-Butylbenzene BDL 1.0 ug/1 62008-1997 01/07/14 1
Carbon tetrachloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorodibromomethane BDL 1.0 ug/1 62008-1997 01/07/14 1
Chloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloroform BDL 5.0 ug/1 62008-1997 01/07/14 1
Chloromethane BDL 2.5 ug/1 6200B-1997 01/07/14 1
2-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
4-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromo-3-Chloropropane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromoethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichlorobenzene . BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,4-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dichlorodifluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
cis-1,2-Dichloroethene BDL 1.0 ug/1 62008-1997 01/07/14 1
trans-1,2-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloropropene BDL 1.0 ug/1 62008-1997 01/07/14 1
1,3-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
2,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Di -isopropyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Ethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Hexachloro-1,3-butadiene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Isopropylbenzene BDL 1.0 ug/1 62008-1997 01/07/14 1
p-Isopropyltoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
2-Butanone (MEK) HDL 10. ug/1 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 8 of 49

1
ti
'1

ESC
liZEREIZIEMESSIEUI
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-04
Site ID : RALEIGH, NC
Sample ID MW-5
Project # : 13-002
Collected By DW / CH
Collection Date : 12/30/13 12:15
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 5.0 ug/1 6200B-1997 01/07/14 1
4-Methyl-2-pentanone (MIBK) BDL 10. ug/1 62008-1997 01/07/14 1
Methyl tent -butyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Naphthalene BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Propylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Styrene BDL 1.0 ug/1 62008-1997 01/07/14 1
1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Tetrachloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Toluene BDL 5.0 ug/1 62008-1997 01/07/14 1
1,2,3-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2,4-Trichlorobenzene BDL 1.0 ug/1 6200E-1997 01/07/14 1
1,1,1-Trichloroethane BDL 1.0 ug/1 62008-1997 01/07/14 1
1,1,2-Trichloroethane BDL 1.0 ug/1 62008-1997 01/07/14 1
Trichloroethene BDL 1.0 ug/1 6200E-1997 01/07/14 1
Trichlorofluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2,3-Trichloropropane BDL 2.5 ug/1 6200B-1997 01/07/14 1
1,2,4-Trimethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3,5-Trimethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Vinyl chloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
o-Xylene BDL 1.0 ug/1 62008-1997 01/07/14 1
m&p-Xylenes BDL 2.0 ug/1 62008-1997 01/07/14 1
Surrogate Recovery
Toluene-d8 99.4 % Rec. 6200B-1997 01/07/14 1
Dibromofluoromethane 104. % Rec. 6200B-1997 01/07/14 1
a,a,a-Trifluorotoluene 97.3 % Rec. 6200B-1997 01/07/14 1
4-Bromofluorobenzene 90.2 % Rec. 6200E-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 9 of 49

OESC
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received
Description
••
December 31, 2013
Peden Family LLC
Sample ID MW-7
Collected By DW / CH
Collection Date : 12/30/13 12:30
Parameter
Lead
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-05
Site ID : RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
BDL 5.0 ug/1 60108 01/02/14 1
Volatile Organics
Acetone BDL 50. ug/1 6200B-1997 01/07/14 1
Acrolein BDL 50. ug/1 6200B-1997 01/07/14 1
Acrylonitrile BDL 10. ug/1 62008-1997 01/07/14 1
Benzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromodichloromethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromoform BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromomethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
sec-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
tert-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Carbon tetrachloride BDL 1.0 ug/1 62008-1997 01/07/14 1
Chlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorodibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloroform BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloromethane BDL 2.5 ug/1 6200B-1997 01/07/14 1
2-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
4-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromo-3-Chloropropane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromoethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,4-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dichlorodifluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
cis-1,2-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
trans-1,2-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloropropene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
2,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Di -isopropyl ether 'BDL 1.0 ug/1 6200B-1997 01/07/14 1
Ethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Hexachloro-1,3-butadiene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Isopropylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
p-Isopropyltoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
2-Butanone (MEK) BDL 10. ug/1 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 10 of 49

OESC
LAB li-��i>E•aE>G-�•S
.y Q i.% :2 L A 2 4 F- �_ �• G E
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received •December 31, 2013
Description •Peden Family LLC
12065 Lebanon Rd.
Nt. Juliet, TO 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0614299
Est. 1970
January 08,2014
ESC Sample # : L676247-05
Site ID : RALEIGH, NC
Sample ID MW-7
Project # : 13-002
Collected By DW / CH
Collection Date : 12/30/13 12:30
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 5.0 ug/1 6200B-1997 01/07/14 1
4-Methyl-2-pentanone (MIRK) BDL 10. ug/1 6200B-1997 01/07/14 1
Methyl tert-butyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Naphthalene BDL 5.0 ug/1 6200E-1997 01/07/14 1
n-Propylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Styrene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Tetrachloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Toluene BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2,3-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2,4-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,1-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichlorofluoromethane BDL 5.0 ug/1 62008-1997 01/07/14 1
1,2,3-Trichloropropane BDL 2.5 ug/1 6200B-1997 01/07/14 1
1,2,4-Trimethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3,5-Trimethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Vinyl chloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
o-Xylene BDL 1.0 ug/1 6200E-1997 01/07/14 1
m&p-Xylenes BDL 2.0 ug/1 6200B-1997 01/07/14 1
Surrogate Recovery
Toluene-d8 99.9 % Rec. 6200B-1997 01/07/14 1
Dibromofluoromethane 101. % Rec. 6200E-1997 01/07/14 1
a,a,a-Trifluorotoluene 96.4 Rec. 6200B-1997 01/07/14 1
4-Bromofluorobenzene 91.0 % Rec. 6200E-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 11 of 49

I

ESC
L•A•8 S.C.€•E •Af. L-�•S
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID MW-8
Collected By DW / CH
Collection Date : 12/30/13 12:00
Parameter
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, Tii 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-06
Site ID : RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
Lead
BDL 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone BDL 50. ug/1 6200B-1997 01/07/14 1
Acrolein BDL 50. ug/1 6200B-1997 01/07/14 1
Acrylonitrile BDL 10. ug/1 6200B-1997 01/07/14 1
Benzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromodichloromethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromoform BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromomethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
sec-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
tert-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Carbon tetrachloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorodibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloroform BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloromethane BDL 2.5 ug/1 6200B-1997 01/07/14 1
2-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
4-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromo-3-Chloropropane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromoethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,4-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dichlorodifluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
cis-1,2-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
trans-1,2-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloropropene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
2,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Di -isopropyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Ethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Hexachloro-1,3-butadiene BDL 1.0 ug/1 62008-1997 01/07/14 1
Isopropylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
p-Isopropyltoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
2-Butanone (MEK) BDL 10. ug/1 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 12 of 49

i

ESC
L>A=a 5•,C•i•a •N>G-�•S
Mr. David Neils
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received
Description
Sample ID
Collected By
Collection Date :
December 31, 2013
Peden Family LLC
MN-8
DM / CH
12/30/13 12:00
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TA 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0E1429D
Est. 1970
January 08,2014
ESC Sample # : L676247-06
Site ID : RALEIGH, NC
Project # : 13-002
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 5.0 ug/1 6200B-1997 01/07/14 1
4-Methyl-2-pentanone (MIRK) BDL 10. ug/1 6200B-1997 01/07/14 1
Methyl tert-butyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Naphthalene BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Propylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Styrene BDL 1.0 ug/1 62008-1997 01/07/14 1
1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Tetrachloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Toluene BDL 5.0 ug/1 62008-1997 01/07/14 1
1,2,3-Trichlorobenzene BDL 1.0 ug/1 62008-1997 01/07/14 1
1,2,4-Trichlorobenzene BDL 1.0 ug/1 62008-1997 01/07/14 1
1, 1, 1-Trichloroethane BDL 1.0 ug/1 62008-1997 01/07/14 1
1,1,2-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichlorofluoromethane BDL 5.0 ug/1 62008-1997 01/07/14 1
1,2,3-Trichloropropane BDL 2.5 ug/1 6200B-1997 01/07/14 1
1,2,4-Trimethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3,5-Trimethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Vinyl chloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
o-Xylene BDL 1.0 ug/1 6200B-1997 01/07/14 1
m&p-Xylenes BDL 2.0 ug/1 6200B-1997 01/07/14 1
Surrogate Recovery
Toluene -de 98.9 % Rec. 6200B-1997 01/07/14 1
Dibromofluoromethane 99.2 % Rec. 6200E-1997 01/07/14 1
a,a,a-Trifluorotoluene 96.2 % Rec. 6200E-1997 01/07/14 1
4-Bromofluorobenzene 88.1 % Rec. 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 13 of 49

ZAESC
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID MW-1D
Collected By DW / CH
Collection Date : 12/30/13 13:30
Parameter
Lead
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-07
Bite ID : RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
BDL 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone BDL 50. ug/1 6200B-1997 01/07/14 1
Acrolein BDL 50. ug/1 6200B-1997 01/07/14 1
Acrylonitrile BDL 10. ug/1 6200B-1997 01/07/14 1
Benzene 23. 1.0 ug/1 6200B-1997 01/07/14 1
Bromobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromodichloromethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromoform BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromomethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Butylbenzene 6.7 1.0 ug/1 6200B-1997 01/07/14 1
sec-Butylbenzene 4.9 1.0 ug/1 6200B-1997 01/07/14 1
tert-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Carbon tetrachloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorodibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloroform BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloromethane BDL 2.5 ug/1 6200B-1997 01/07/14 1
2-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
4-Chlorotoluene BDL 1.0 ug/1 6200E-1997 01/07/14 1
1,2-Dibromo-3-Chloropropane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromoethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dibromomethana BDL 1.0 ug/1 62008-1997 01/07/14 1
1,2-Dichlorobenzene BDL 1.0 u_/1 6200B-1997 01/07/14 1
1,3-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,4-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dichlorodifluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
I,1-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
cis-1,2-Dichloroethene BDL 1.0 ug/1 62008-1997 01/07/14 1
trans-1,2-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloropropene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
2,2-Dichloropropane BDL 1.0 ug/1 62008-1997 01/07/14 1
Di -isopropyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Ethylbenzene 31. 1.0 ug/1 6200B-1997 01/07/14 1
Hexachloro-1,3-butadiene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Isopropylbenzene 33. 1.0 ug/1 6200B-1997 01/07/14 1
p-Isopropyltoluene 6.2 1.0 ug/1 6200B-1997 01/07/14 1
2-Butanone (MEK) BDL 10. ug/1 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 14 of 49

1
1
k

ESC
L+A�9 S+G•i•E-N•t .E•S
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received •December 31, 2013
Description Peden Family LLC
Sample ID MW-1D
Collected By DIN / CH
Collection Date : 12/30/13 13:30
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-07
Site ID : RALEIGH, NC
Project # : 13-002
Parameter Result Det. Limit Units Method Date Dil,
Methylene Chloride BDL 5.0 ug/1 6200B-1997 01/07/14 1
4-Methyl-2-pentanone (MIRK) BDL 10. ug/1 6200B-1997 01/07/14 1
Methyl tert-butyl ether 17. 1.0 ug/1 6200B-1997 01/07/14 1
Naphthalene 180 5.0 ug/1 6200B-1997 01/07/14 1
n-Propylbenzene 28. 1.0 ug/1 6200B-1997 01/07/14 1
Styrene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Tetrachloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Toluene 430 5.0 ug/1 62008-1997 01/07/14 1
1,2,3-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2,4-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,1-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichlorofluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2,3-Trichloropropane BDL 2.5 ug/1 62008-1997 01/07/14 1
1,2,4-Trimethylbenzene 100 1.0 ug/1 6200B-1997 01/07/14 1
1,3,5-Trimethylbenzene 110 1.0 ug/1 6200B-1997 01/07/14 1
Vinyl chloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
o-Xylene 400 1.0 ug/1 62008-1997 01/07/14 1
m&p-Xylenes 220 2.0 ug/1 6200B-1997 01/07/14 1
Surrogate Recovery
Toluene-d8 102. % Rec. 6200B-1997 01/07/14 1
Dibromofluoromethane 100. % Rec. 6200E-1997 01/07/14 1
a,a,a-Trifluorotoluene 96.5 % Rec. 6200B-1997 01/07/14 1
4-Bromofluorobenzene 86.1 % Rec. 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 15 of 49

1

RAESC
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID MW-10
Collected By •DW / CH
Collection Date : 12/30/13 14:55
Parameter
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, IN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax S.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-08
Site ID : RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
Lead
17. 5.0 ug/1 6010E 01/02/14 1
Volatile Organics
Acetone BDL 2500 ug/1 6200B-1997 01/07/14 50
Acrolein BDL 2500 ug/1 6200B-1997 01/07/14 50
Acrylonitrile BDL 500 ug/1 6200B-1997 01/07/14 50
Benzene 99. 50. ug/1 6200B-1997 01/07/14 50
Bromobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
Bromodichloromethane BDL 50. ug/1 6200B-1997 01/07/14 50
Bromoform BDL 50. ug/1 6200B-1997 01/07/14 50
Bromomethane BDL 250 ug/1 6200B-1997 01/07/14 50
n-Butylbenzene BDL 50. ug/1 6200B-1997 01/07/14 50
sec-Butylbenzene BDL 50. ug/1 6200B-1997 01/07/14 50
tert-Butylbenzene BDL 50. ug/1 6200B-1997 01/07/14 50
Carbon tetrachloride BDL 50. ug/1 6200B-1997 01/07/14 50
Chlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
Chlorodibromomethane BDL 50. ug/1 6200B-1997 01/07/14 50
Chloroethane BDL 250 ug/1 6200B-1997 01/07/14 50
Chloroform BDL 250 ug/1 6200B-1997 01/07/14 50
Chloromethane BDL 120 ug/1 62008-1997 01/07/14 50
2-Chlorotoluene BDL. 50. ug/1 6200B-1997 01/07/14 50
4-Chlorotoluene BDL 50. ug/1 6200B-1997 01/07/14 50
1,2-Dibromo-3-Chloropropane BDL 250 ug/1 6200B-1997 01/07/14 50
1,2-Dibromoethane BDL 50. ug/1 6200B-1997 01/07/14 50
Dibromomethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,2-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
1,3-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
1,4-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
Dichlorodifluoromethane BDL 250 ug/1 6200B-1997 01/07/14 50
1,1-Dichloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,2-Dichloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,1-Dichloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
cis-1,2-Dichloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
trans-1,2-Dichloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
1,2-Dichloropropane BDL 50. ug/1 6200B-1997 01/07/14 50
1,1-Dichloropropene BDL 50. ug/1 6200B-1997 01/07/14 50
1,3-Dichloropropane BDL 50. ug/1 6200B-1997 01/07/14 50
2,2-Dichloropropane BDL 50. ug/1 6200B-1997 01/07/14 50
Di -isopropyl ether BDL 50. ug/1 6200B-1997 01/07/14 50
Ethylbenzene 1200 50. ug/1 6200B-1997 01/07/14 50
Hexachloro-1,3-butadiene BDL 50. ug/1 6200B-1997 01/07/14 50
Isopropylbenzene 69. 50. ug/1 6200B-1997 01/07/14 50
p-Isopropyltoluene BDL 50. ug/1 6200B-1997 01/07/14 50
2-Butanone (MEK) BDL 500 ug/1 6200B-1997 01/07/14 50
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 16 of 49

I
I

ESC
L.A S.C.i.g.$4.c.g.E
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID MW-10
Collected By •DW / CH
Collection Date : 12/30/13 14:55
12065 Lebanon Rd.
Mt. Juliet, TA 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-08
Site ID : RALEIGH, NC
Project # : 13-002
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 250 ug/1 62008-1997 01/07/14 50
4-Methyl-2-pentanone (MIBA) BDL 500 ug/1 6200B-1997 01/07/14 50
Methyl tert-butyl ether BDL 50. ug/1 6200B-1997 01/07/14 50
Naphthalene 630 250 ug/1 62008-1997 01/07/14 50
n-Propylbenzene 160 50. ug/1 6200B-1997 01/07/14 50
Styrene BDL 50. ug/1 6200B-1997 01/07/14 50
1,1,1,2-Tetrachloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,1,2,2-Tetrachloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
Tetrachloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
Toluene 5600 250 ug/1 62008-1997 01/07/14 50
1,2,3-Trichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
1,2,4-Trichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
1, 1, 1-Trichloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,1,2-Trichloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
Trichloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
Trichlorofluoromethane BDL 250 ug/1 6200B-1997 01/07/14 50
1,2,3-Trichloropropane BDL 120 ug/1 6200B-1997 01/07/14 50
1,2,4-Trimethylbenzene 1400 50. ug/1 6200B-1997 01/07/14 50
1,3,5-Trimethylbenzene 420 50. ug/1 6200B-1997 01/07/14 50
Vinyl chloride BDL 50. ug/1 6200B-1997 01/07/14 50
o-Xylene 3000 50. ug/1 62008-1997 01/07/14 50
m&p-Xylenes 5000 100 ug/1 6200E-1997 01/07/14 50
Surrogate Recovery
Toluene-d8 101. % Rec. 6200B-1997 01/07/14 50
Dibromofluoromethane 94.9 % Rec. 6200E-1997 01/07/14 50
a,a,a-Trifluorotoluene 96.0 % Rec. 6200E-1997 01/07/14 50
4-Bromofluorobenzene 90.0 % Rec. 6200B-1997 01/07/14 50
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 17 of 49

L

OESC
L>A•$ S.G•i• •AI -c=S
v 4 ++ H r_i }» 6 r L E.
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received •December 31, 2013
Description •Peden Family LLC
Sample ID P-1
Collected By DW / CH
Collection Date : 12/30/13 13:45
Parameter
Lead
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-081428N
Est. 1970
January 08,2014
ESC Sample # : L676247-09
Site ID ; RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
22. 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone BDL 1200 ug/1 6200B-1997 01/07/14 25
Acrolein BDL 1200 ug/1 6200B-1997 01/07/14 25
Acrylonitrile BDL 250 ug/1 6200B-1997 01/07/14 25
Benzene BDL 25. ug/1 6200B-1997 01/07/14 25
Bromobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
Bromodichloromethane BDL 25. ug/1 6200B-1997 01/07/14 25
Bromoform BDL 25. ug/1 6200B-1997 01/07/14 25
Bromomethane BDL 120 ug/1 6200B-1997 01/07/14 25
n-Butylbenzene BDL 25. ug/1 6200B-1997 01/07/14 25
sec-Butylbenzene BDL 25. ug/1 62008-1997 01/07/14 25
tert-Butylbenzene BDL 25. ug/1 6200B-1997 01/07/14 25
Carbon tetrachloride BDL 25. ug/1 6200B-1997 01/07/14 25
Chlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
Chlorodibromomethane BDL 25. ug/1 6200B-1997 01/07/14 25
Chloroethane BDL 120 ug/1 6200B-1997 01/07/14 25
Chloroform BDL 120 ug/1 62008-1997 01/07/14 25
Chloromethane BOL 62. ug/1 6200B-1997 01/07/14 25
2-Chlorotoluene BDL 25. ug/1 6200B-1997 01/07/14 25
4-Chlorotoluene BDL 25. ug/1 6200B-1997 01/07/14 25
1,2-Dibromo-3-Chloropropane BDL 120 ug/1 6200E-1997 01/07/14 25
1,2-Dibromoethane BDL 25. ug/1 6200B-1997 01/07/14 25
Dibromomethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,2-Dichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
1,3-Dichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
1,4-Dichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
Dichlorodifluoromethane BDL 120 ug/1 6200B-1997 01/07/14 25
1,1-Dichloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,2-Dichloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,1-Dichloroethene BDL 25. ug/1 6200B-1997 01/07/14 25
cis-1,2-Dichloroethene BDL 25. ug/1 6200B-1997 01/07/14 25
trans-1,2-Dichloroethene BDL 25. ug/1 6200B-1997 01/07/14 25
1,2-Dichloropropane BDL 25. ug/1 6200B-1997 01/07/14 25
1,1-Dichloropropane BDL 25. ug/1 62008-1997 01/07/14 25
1,3-Dichloropropane BDL 25. ug/1 6200B-1997 01/07/14 25
2,2-Dichloropropane BDL 25. ug/1 6200B-1997 01/07/14 25
Di -isopropyl ether BDL 25. ug/1 6200B-1997 01/07/14 25
Ethylbenzene 790 25. ug/1 6200B-1997 01/07/14 25
Hexachloro-1,3-butadiene BDL 25. ug/1 6200B-1997 01/07/14 25
Isopropylbenzene 64. 25. ug/1 6200B-1997 01/07/14 25
p-Isopropyltoluene 34. 25. ug/1 6200B-1997 01/07/14 25
2-Butanone (MEK) BDL 250 ug/1 6200E-1997 01/07/14 25
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 18 of 49

I
1

ESC
t•A•E •ai, G-^c•s
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-09
Date Received December 31, 2013
Description Peden Family LLC
Site ID : RALEIGH, NC
Sample ID P-1
Project # : 13-002
Collected By DW / CH
Collection Date : 12/30/13 13:45
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 120 ug/1 6200B-1997 01/07/14 25
4-Methyl-2-pentanone (MIBA) BDL 250 ug/1 6200B-1997 01/07/14 25
Methyl tert-butyl ether BDL 25. ug/1 6200B-1997 01/07/14 25
Naphthalene 390 120 ug/1 6200B-1997 01/07/14 25
n-Propylbenzene 130 25. ug/1 6200B-1997 01/07/14 25
Styrene BDL 25. ug/1 6200B-1997 01/07/14 25
1,1,1,2-Tetrachloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,1,2,2-Tetrachloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
Tetrachloroethene BDL 25. ug/1 6200B-1997 01/07/14 25
Toluene 820 120 ug/1 6200B-1997 01/07/14 25
1,2,3-Trichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
1,2,4-Trichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
1,1,1-Trichloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,1,2-Trichloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
Trichloroethene BDL 25. ug/1 6200B-1997 01/07/14 25
Trichlorofluoromethane BDL 120 ug/1 6200B-1997 01/07/14 25
1,2,3-Trichloropropane BDL 62. ug/1 6200B-1997 01/07/14 25
1,2,4-Trimethylbenzene 1100 25. ug/1 6200B-1997 01/07/14 25
1,3,5-Trimethylbenzene 590 25. ug/1 6200B-1997 01/07/14 25
Vinyl chloride BDL 25. ug/1 6200B-1997 01/07/14 25
o-Xylene 1700 25. ug/1 62008-1997 01/07/14 25
m&p-Xylenes 2000 50. ug/1 6200B-1997 01/07/14 25
Surrogate Recovery
Toluene-d8 99.1 % Rec. 6200B-1997 01/07/14 25
Dibromofluoromethane 97.2 % Rec. 6200B-1997 01/07/14 25
a,a,a-Trifluorotoluene 98.0 % Rec. 6200B-1997 01/07/14 25
4-Bromofluorobenzene 93.8 % Rec. 6200B-1997 01/07/14 25
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 19 of 49

OESC
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
12065 Lebanon Rd.
Mt. Juliet, TA 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142E9
Est. 1970
January 08,2014
ESC Sample # : L676247-10
Site ID : RALEIGH, NC
Sample ID P-2
Project # : 13-002
Collected By DW / CH
Collection Date : 12/30/13 14:45
Parameter Result Det. Limit Units Method Date Dil,
Lead 21. 5.0 ug/1 60108 01/02/14 1
Volatile Organics
Acetone BDL 2500 ug/1 6200B-1997 01/07/14 50
Acrolein BDL 2500 ug/1 6200B-1997 01/07/14 50
Acrylonitrile BDL 500 ug/1 62008-1997 01/07/14 50
Benzene BDL 50. ug/1 6200B-1997 01/07/14 50
Bromobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
Bromodichloromethane BDL 50. ug/1 6200B-1997 01/07/14 50
Bromoform BDL 50. ug/1 6200E-1997 01/07/14 50
Bromomethane BDL 250 ug/1 6200B-1997 01/07/14 50
n-Butylbenzene BDL 50. ug/1 6200B-1997 01/07/14 50
sec-Butylbenzene BDL 50. ug/1 6200B-1997 01/07/14 50
tert-Butylbenzene BDL 50. ug/1 6200B-1997 01/07/14 50
Carbon tetrachloride BDL 50. ug/1 6200B-1997 01/07/14 50
Chlorobenzene BDL 50. ug/1 62008-1997 01/07/14 50
Chlorodibromomethane BDL 50. ug/1 6200B-1997 01/07/14 50
Chloroethane BDL 250 ug/1 62008-1997 01/07/14 50
Chloroform BDL 250 ug/1 6200B-1997 01/07/14 50
Chloromethane BDL 120 ug/1 6200B-1997 01/07/14 50
2-Chlorotoluene BDL 50. ug/1 6200B-1997 01/07/14 50
4-Chlorotoluene BDL 50. ug/1 6200B-1997 01/07/14 50
1,2-Dibromo-3-Chloropropane BDL 250 ug/1 6200B-1997 01/07/14 50
1,2-Dibromoethane BDL 50. ug/1 6200B-1997 01/07/14 50
Dibromomethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,2-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
1,3-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
1,4-Dichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
Dichlorodifluoromethane BDL 250 ug/1 6200B-1997 01/07/14 50
1,1-Dichloroethane BDL 50. ug/1 62008-1997 01/07/14 50
1,2-Dichloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,1-Dichloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
cis-1,2-Dichloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
trans-1,2-Dichloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
1,2-Dichloropropane BDL 50. ug/1 6200B-1997 01/07/14 50
1,1-Dichloropropene BDL 50. ug/1 6200B-1997 01/07/14 50
1,3-Dichloropropane BDL 50. ug/1 6200B-1997 01/07/14 50
2,2-Dichloropropane BDL 50. ug/1 6200B-1997 01/07/14 50
Di -isopropyl ether BDL 50. ug/1 6200B-1997 01/07/14 50
Ethylbenzene 1700 50. ug/1 6200B-1997 01/07/14 50
Hexachloro-1,3-butadiene BDL 50. ug/1 6200B-1997 01/07/14 50
Isopropylbenzene 110 50. ug/1 6200B-1997 01/07/14 50
p-Isopropyltoluene BDL 50. ug/1 6200B-1997 01/07/14 50
2-Butanone (MEK) BDL 500 ug/1 6200B-1997 01/07/14 50
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 20 of 49

1
1'

RAESC
L•A•fi,.i•E•N.5.2•S
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID P-2
Project # : 13-002
Collected By DW / CH
Collection Date : 12/30/13 14:45
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride. BDL 250 ug/1 6200B-1997 01/07/14 50
4-Methyl-2-pentanone (MIBK) BDL 500 ug/1 6200B-1997 01/07/14 50
Methyl tert-butyl ether BDL 50. ug/1 6200B-1997 01/07/14 50
Naphthalene 660 250 ug/1 6200B-1997 01/07/14 50
n-Propylbenzene 270 50. ug/1 6200B-1997 01/07/14 50
Styrene BDL 50. ug/1 6200B-1997 01/07/14 50
1,1,1,2-Tetrachloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,1,2,2-Tetrachloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
Tetrachloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
Toluene 4900 250 ug/1 6200B-1997 01/07/14 50
1,2,3-Trichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
1,2,4-Trichlorobenzene BDL 50. ug/1 6200B-1997 01/07/14 50
1,1,1-Trichloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
1,1,2-Trichloroethane BDL 50. ug/1 6200B-1997 01/07/14 50
Trichloroethene BDL 50. ug/1 6200B-1997 01/07/14 50
Trichlorofluoromethane BDL 250 ug/1 6200B-1997 01/07/14 50
1,2,3-Trichloropropane BDL 120 ug/1 6200B-1997 01/07/14 50
1,2,4-Trimethylbenzene 2000 50. ug/1 6200B-1997 01/07/14 50
1,3,5-Trimethylbenzene 590 50. ug/1 6200B-1997 01/07/14 50
Vinyl chloride BDL 50. ug/1 6200B-1997 01/07/14 50
o-Xylene 3700 50. ug/1 6200B-1997 01/07/14 50
m&p-Xylenes 6100 100 ug/1 6200E-1997 01/07/14 50
Surrogate Recovery
Toluene-d8 101. % Rec. 6200E-1997 01/07/14 50
Dibromofluoromethane 98.0 % Rec. 6200E-1997 01/07/14 50
a,a,a-Trifluorotoluene 95.1 % Rec. 6200B-1997 01/07/14 50
4-Bromofluorobenzene 92.7 % Rec. 6200E-1997 01/07/14 50
12065 Lebanon Rd.
Mt. Juliet, TA 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-10
Site ID : RALEIGH, NC
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 21 of 49
1

I.

ESC
L•A,$ $•C•i•E.N'G•E•S
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received •December 31, 2013
Description •Peden Family LLC
Sample ID P-3
Collected By DW / CH
Collection Date : 12/30/13 14:25
12065 Lebanon Rd.
Mt. Juliet, TR 37122
[phone]
1-800-767-5859
Fax [phone]
Tax Z.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-11
Site ID : RALEIGH, NC
Project # : 13-002
Parameter Result Det. Limit Units Method Date Dil.
Lead 9.1 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone BDL 250 ug/1 6200B-1997 01/07/14 5
Acrolein BDL 250 ug/1 6200B-1997 01/07/14 5
Acrylonitrile BDL 50. ug/1 6200B-1997 01/07/14 5
Benzene 16. 5.0 ug/1 6200E-1997 01/07/14 5
Bromobenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
Bromodichloromethane BDL 5.0 ug/1 6200E-1997 01/07/14 5
Bromoform BDL 5.0 ug/1 6200B-1997 01/07/14 5
Bromomethane BDL 25. ug/1 6200B-1997 01/07/14 5
n-Butylbenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
sec-Butylbenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
tert-Butylbenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
Carbon tetrachloride BDL 5.0 ug/1 6200B-1997 01/07/14 5
Chlorobenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
Chlorodibromomethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
Chloroethane BDL 25. ug/1 6200B-1997 01/07/14 5
Chloroform BDL 25. ug/1 6200B-1997 01/07/14 5
Chloromethane BDL 12. ug/1 6200B-1997 01/07/14 5
2-Chlorotoluene BDL 5.0 ug/1 6200B-1997 01/07/14 5
4-Chlorotoluene BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,2-Dibromo-3-Chloropropane BDL 25. ug/1 6200B-1997 01/07/14 5
1,2-Dibromoethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
Dibromomethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,2-Dichlorobenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,3-Dichlorobenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,4-Dichlorobenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
Dichlorodifluoromethane BDL 25. ug/1 6200B-1997 01/07/14 5
1,1-Dichloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,2-Dichloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,1-Dichloroethene BDL 5.0 ug/1 6200B-1997 01/07/14 5
cis-1,2-Dichloroethene BDL 5.0 ug/1 6200B-1997 01/07/14 5
trans-1,2-Dichloroethene BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,2-Dichloropropane BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,1-Dichloropropene BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,3-Dichloropropane BDL 5.0 ug/1 6200B-1997 01/07/14 5
2,2-Dichloropropane BDL 5.0 ug/l 6200B-1997 01/07/14 5
Di -isopropyl ether BDL 5.0 ug/1 6200B-1997 01/07/14 5
Ethylbenzene 68. 5.0 ug/1 6200B-1997 01/07/14 5
Hexachloro-1,3-butadiene BDL 5.0 ug/1 6200B-1997 01/07/14 5
Isopropylbenzene 11. 5.0 ug/1 6200B-1997 01/07/14 5
p-Isopropyltoluene 17. 5.0 ug/1 6200E-1997 01/07/14 5
2-Butanone (MEK) BDL 50. ug/1 62008-1997 01/07/14 5
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 22 of 49

r
i

OESC
L„A•6 .sLc. I•E•A(•G-E•S
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received
Description
Sample ID
Collected By
Collection Date :
Parameter
December 31, 2013
Peden Family LLC
P-3
DW / CH
12/30/13 14:25
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814209
Est. 1970
January 08,2014
ESC Sample # : L676247-11
Site ID : RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 25. ug/1 62008-1997 01/07/14 5
4-Methyl-2-pentanone (MIBK) BDL 50. ug/1 6200B-1997 01/07/14 5
Methyl tert-butyl ether BDL 5.0 ug/1 6200B-1997 01/07/14 5
Naphthalene 80. 25. ug/1 6200E-1997 01/07/14 5
n-Propylbenzene 26. 5.0 ug/1 6200E-1997 01/07/14 5
styrene BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,1,1,2-Tetrachloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,1,2,2-Tetrachloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
Tetrachloroethene BDL 5.0 ug/1 6200B-1997 01/07/14 5
Toluene 110 25. ug/1 6200B-1997 01/07/14 5
1,2,3-Trichlorobenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,2,4-Trichlorobenzene BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,1,1-Trichloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
1,1,2-Trichloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 5
Trichloroethene BDL 5.0 ug/1 6200B-1997 01/07/14 5
Trichlorofluoromethane BDL 25. ug/1 62000-1997 01/07/14 5
1,2,3-Trichloropropane BDL 12. ug/1 62008-1997 01/07/14 5
1,2,4-Trimethylbenzene 280 5.0 ug/1 6200B-1997 01/07/14 5
1,3,5-Trimethylbenzene 230 5.0 ug/1 6200B-1997 01/07/14 5
Vinyl chloride BDL 5.0 ug/1 6200B-1997 01/07/14 5
o-Xylene 380 5.0 ug/1 6200B-1997 01/07/14 5
map-Xylenes 380 10. ug/1 6200B-1997 01/07/14 5
Surrogate Recovery
Toluene-d8 105. % Rec. 6200B-1997 01/07/14 5
Dibromofluoromethane 105. % Rec. 6200B-1997 01/07/14 5
a,a,a-Trifluorotoluene 92.4 % Rec. 6200E-1997 01/07/14 5
4-Bromofluorobenzene 101. % Rec. 62008-1997 01/07/14 5
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 23 of 49

IlESC
L-A=$ b•C•i•E•l+f•."..-c•S
vQV LA9 F cNL7�.`"
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received •December 31, 2013
Description •Peden Family LLC
Sample ID P-4
Project # : 13-002
Collected By DW / CH
Collection Date : 12/30/13 13:50
Parameter Result Det. Limit Units Method Date Dil.
Lead 320 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone BDL 1200 ug/1 6200E-1997 01/07/14 25
Acrolein BDL 1200 ug/1 6200B-1997 01/07/14 25
Acrylonitrile BDL 250 ug/1 62O0B-1997 01/07/14 25
Benzene 96. 25. ug/1 6200B-1997 01/07/14 25
Bromobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
Bromodichloromethane BDL 25. ug/1 6200B-1997 01/07/14 25
Bromoform BDL 25. ug/1 62008-1997 01/07/14 25
Bromomethane BDL 120 ug/1 6200B-1997 01/07/14 25
n-Butylbenzene BDL 25. ug/1 6200B-1997 01/07/14 25
sec-Butylbenzene BDL 25. ug/1 6200B-1997 01/07/14 25
tert-Butylbenzene BDL 25. ug/1 6200B-1997 01/07/14 25
Carbon tetrachloride BDL 25. ug/1 62008-1997 01/07/14 25
Chlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
Chlorodibromomethane BDL 25. ug/1 6200B-1997 01/07/14 25
Chloroethane BDL 120 ug/1 6200E-1997 01/07/14 25
Chloroform BDL 120 ug/1 6200B-1997 01/07/14 25
Chloromethane BDL 62. ug/1 6200B-1997 01/07/14 25
2-Chlorotoluene BDL 25. ug/1 6200B-1997 01/07/14 25
4-Chlorotoluene BDL 25. ug/1 6200B-1997 01/07/14 25
1,2-Dibromo-3-Chloropropane BDL 120 ug/1 6200B-1997 01/07/14 25
1,2-Dibromoethane BDL 25. ug/1 6200B-1997 01/07/14 25
Dibromomethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,2-Dichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
1,3-Dichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
1,4-Dichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
Dichlorodifluoromethane BDL 120 ug/1 6200B-1997 01/07/14 25
1,1-Dichloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,2-Dichloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,1-Dichloroethene BDL 25. ug/1 62008-1997 01/07/14 25
cis-1,2-Dichloroethene BDL 25. ug/1 6200B-1997 01/07/14 25
trans-1,2-Dichloroethene BDL 25. ug/1 62008-1997 01/07/14 25
1,2-Dichloropropane BDL 25. ug/1 6200B-1997 01/07/14 25
1,1-Dichloropropene BDL 25. ug/1 6200B-1997 01/07/14 25
1,3-Dichloropropane BDL 25. ug/1 6200E-1997 01/07/14 25
2,2-Dichloropropane BDL 25. ug/1 6200B-1997 01/07/14 25
Di -isopropyl ether BDL 25. ug/1 6200B-1997 01/07/14 25
Ethylbenzene 240 25. ug/1 6200B-1997 01/07/14 25
Hexachloro-1,3-butadiene BDL 25. ug/1 6200B-1997 01/07/14 25
Isopropylbenzene BDL 25. ug/1 6200B-1997 01/07/14 25
p-Isopropyltoluene BDL 25. ug/1 62008-1997 01/07/14 25
2-Butanone (MEK) BDL 250 ug/1 62008-1997 01/07/14 25
12065 Lebanon Rd.
Mt. Juliet, TO 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-12
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Site ID : RALEIGH, NC
Page 24 of 49

1
i

OESC
L•A=$ $-C. i•E •S4•5t-E-S
REPORT OF ANALYSIS
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
12065 Lebanon Rd.
Mt. Juliet, FM 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0614289
Est. 1970
January 08,2014
ESC Sample # : L676247-12
Date Received December 31, 2013
Description Peden Family LLC
site ID : RALEIGH, NC
Sample ID P-4
Project # : 13-002
Collected By DM / CH
Collection Date : 12/30/13 13:50
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 120 ug/1 6200B-1997 01/07/14 25
4-Methyl-2-pentanone (MIBK) BDL 250 ug/1 62008-1997 01/07/14 25
Methyl tert-butyl ether BDL 25. ug/1 6200B-1997 01/07/14 25
Naphthalene 130 120 ug/1 6200B-1997 01/07/14 25
n-Propylbenzene 40. 25. ug/1 6200E-1997 01/07/14 25
Styrene BDL 25. ug/1 6200E-1997 01/07/14 25
1,1,1,2-Tetrachloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,1,2,2-Tetrachloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
Tetrachloroethene BDL 25. ug/1 6200B-1997 01/07/14 25
Toluene 1200 120 ug/1 62009-1997 01/07/14 25
1,2,3-Trichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
1,2,4-Trichlorobenzene BDL 25. ug/1 6200B-1997 01/07/14 25
1,1,1-Trichloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
1,1,2-Trichloroethane BDL 25. ug/1 6200B-1997 01/07/14 25
Trichloroethene BDL 25. ug/1 6200B-1997 01/07/14 25
Trichlorofluoromethane BDL 120 ug/1 6200B-1997 01/07/14 25
1,2,3-Trichloropropane BDL 62. ug/1 6200B-1997 01/07/14 25
1,2,4-Trimethylbenzene 390 25. ug/1 6200B-1997 01/07/14 25
1,3,5-Trimethylbenzene 200 25. ug/1 6200B-1997 01/07/14 25
Vinyl chloride BDL 25. ug/1 6200B-1997 01/07/14 25
o-Xylene 790 25. ug/1 62008-1997 01/07/14 25
map-Xylenes 1100 50. ug/1 6200B-1997 01/07/14 25
Surrogate Recovery
Toluene-d8 104. % Rec. 6200B-1997 01/07/14 25
Dibromofluoromethane 103. % Rec. 6200B-1997 01/07/14 25
a,a,a-Trifluorotoluene 92.2 % Rec. 6200B-1997 01/07/14 25
4-Bromofluorobenzene 102. % Rec. 6200B-1997 01/07/14 25
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 25 of 49

i

ESC
L•A=$ fi-C. i•E•14.C.E.,S
Mr. David Wells
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID P-5
Collected By DM / CH
Collection Date : 12/30/13 14:30
Parameter
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-13
Site ID : RALEIGH, NC
Project # : 13-002
Result Det. Limit Units Method Date Dil.
Lead
BDL 5.0 ug/1 6010B 01/02/14 1
Volatile Organics
Acetone 89. 50. ug/1 6200B-1997 01/07/14 1
Acrolein BDL 50. ug/1 6200B-1997 01/07/14 1
Acrylonitrile BDL 10. ug/1 6200B-1997 01/07/14 1
Benzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromodichloromethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromoform BDL 1.0 ug/1 6200B-1997 01/07/14 1
Bromomethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
sec-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
tert-Butylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Carbon tetrachloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
Chlorobenzene BDL 1.0 ug/1 62009-1997 01/07/14 1
Chlorodibromomethane BDL 1.0 ug/1 6200E-1997 01/07/14 1
Chloroethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloroform BDL 5.0 ug/1 6200B-1997 01/07/14 1
Chloromethane BDL 2.5 ug/1 6200B-1997 01/07/14 1
2-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
4-Chlorotoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromo-3-Chloropropane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2-Dibromoethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Dibromomethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,4-Dichlorobenzene BDL 1.0 ug/1 62008-1997 01/07/14 1
Dichlorodifluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
cis-1,2-Dichloroethene BDL 1.0 ug/1 62008-1997 01/07/14 1
trans-1,2-Dichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1-Dichloropropene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,3-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
2,2-Dichloropropane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Di -isopropyl ether BDL 1.0 ug/1 6200E-1997 01/07/14 1
Ethylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Hexachloro-1,3-butadiene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Isopropylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
p-Isopropyltoluene BDL 1.0 ug/1 6200B-1997 01/07/14 1
2-Butanone (MEK) BDL 10. ug/1 62008-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Page 26 of 49

OESC
L A,EI 5• •i•E•pJ,u.c•M,
REPORT OF ANALYSIS
Mr. David Neils
Cape Lookout Environmental Services
8005 Clear Brook Drive
Raleigh, NC 27615
Date Received December 31, 2013
Description Peden Family LLC
Sample ID P-5
Collected By DA / CH
Collection Date : 12/30/13 14:30
12065 Lebanon Rd.
Mt. Juliet, TH 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08,2014
ESC Sample # : L676247-13
Site ID : RALEIGH, NC
Project # : 13-002
Parameter Result Det. Limit Units Method Date Dil.
Methylene Chloride BDL 5.0 ug/1 6200B-1997 01/07/14 1
4-Methyl-2-pentanone MBA) BDL 10. ug/1 6200B-1997 01/07/14 1
Methyl tert-butyl ether BDL 1.0 ug/1 6200B-1997 01/07/14 1
Naphthalene BDL 5.0 ug/1 6200B-1997 01/07/14 1
n-Propylbenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Styrene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Tetrachloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Toluene BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2,3-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,2,4-Trichlorobenzene BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,1-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
1,1,2-Trichloroethane BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichloroethene BDL 1.0 ug/1 6200B-1997 01/07/14 1
Trichlorofluoromethane BDL 5.0 ug/1 6200B-1997 01/07/14 1
1,2,3-Trichloropropane BDL 2.5 ug/1 6200B-1997 01/07/14 1
1,2,4-Trimethylbenzene 1.2 1.0 ug/1 6200B-1997 01/07/14 1
1,3,5-Trimethylbenzene 2.1 1.0 ug/1 6200B-1997 01/07/14 1
Vinyl chloride BDL 1.0 ug/1 6200B-1997 01/07/14 1
o-Xylene 2.0 1.0 ug/1 6200B-1997 01/07/14 1
m&p-Xylenes BDL 2.0 ug/1 6200B-1997 01/07/14 1
Surrogate Recovery
Toluene-d8 105. % Rec. 62008-1997 01/07/14 1
Dibromofluoromethane 107. % Rec. 6200B-1997 01/07/14 1
a,a,a-Trifluorotoluene 93.4 % Rec. 6200B-1997 01/07/14 1
4-Bromofluorobenzene 103. % Rec. 6200B-1997 01/07/14 1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/08/14 15:43 Printed: 01/08/14 15:44
Page 27 of 49

Attachment A
List of Analytes with QC Qualifiers
Sample Work
Number Group
Sample
Type Analyte
Run
ID
Qualifier
L676247-01 WG700132 SAMP Bromodichloromethane R2874865 J4
L676247-02 WG700132 SAMP Bromodichloromethane R2874865 J4
L676247-07 WG700059 SAMP Benzene R2874464 V3
WG700059 SAMP Methyl tert-butyl ether R2874464 V3
WG700059 SAMP Toluene R2874464 E
WG700059 SAMP o-Xylene R2874464 E
Page 28 of 49

1
i

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
E GTL (EPA) - Greater than upper calibration limit: Actual value is known to
be greater than the upper calibration range.
J4 The associated batch QC was outside the established quality control range
for accuracy.
v3
(ESC) - Additional QC Info: The internal standard exhibited poor recovery
due to sample matrix interference. The analytical results will be biased
high. BDL results will be unaffected.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
"unless qualified as TR' (Rejected)."
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 29 of 49

1

Summary of Remarks For Samples Printed
01/08/14 at 15:44:29
TSR Signing Reports: 064
R5 - Desired TAT
CL 7500
Sample: L676247-01 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-02 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
sample: L676247-03 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-04 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-05 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-06 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-07 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-08 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-09 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-10 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-11 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-12 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43
Sample: L676247-13 Account: CAPLOOKRNC Received: 12/31/13 15:15 Due Date: 01/08/14 00:00 RPT Date: 01/08/14 15:43

k

OESC
L•A=$ S•C•':•E•N•G S
4$R 03, 0E
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Raleigh, NC 27615
Quality Assurance Report
Level II
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08, 2014
Laboratory Blank
Analyte Result Units 8 Rec Limit Batch Date Analyzed
Lead < .005 mg/1 WG699922 01/02/14 02:37
1,1,1,2-Tetracbloroethane < .001 mg/1 WG700059 01/07/14 12:59
1,1,1-Trichloroethane < .001 mg/1 WG700059 01/07/14 12:59
1,1,2,2-Tetrachioroethane < .001 mg/1 WG700059 01/07/14 12:59
1,1,2-Trichloroethane < .001 mg/1 WG700059 01/07/14 12:59
1,1-Dichloroethane < .001 mg/1 WG700059 01/07/14 12:59
1,1-Dichloroethene < .001 mg/1 8Je700059 01/07/14 12:59
1,1-Dichloropropene < .001 mg/1 WG700059 01/07/14 12:59
1,2,3-Trichlorobenzene < .001 mg/1 WG700059 01/07/14 12:59
1,2,3-Trichloropropane < .001 mg/1 WG700059 01/07/14 12:59
1,2,4-Trichlorobenzene < .001 mg/1 WG700059 01/07/14 12:59
1,2,4-Trimethylbenzene < .001 mg/1 WG700059 01/07/14 12:59
1,2-Dibromo-3-Chloropropane < .005 mg/1 WG700059 01/07/14 12:59
1,2-Dibromoethane < .001 mg/1 WG700059 01/07/14 12:59
1,2-Dichlorobenzene < .001 mg/1 WG700059 01/07/14 12:59
1,2-Dichloroethane < .001 mg/1 WG700059 01/07/14 12:59
1,2-Dichloropropane < .001 mg/1 WG700059 01/07/14 12:59
1,3,5-Tri.methylbenzene < .001 mg/1 WG700059 01/07/14 12:59
1,3-Dichlorobenzene < .001 mg/1 WG700059 01/07/14 12:59
1,3-Dichloropropane < .001 mg/1 WG700059 01/07/14 12:59
1,4-Dichlorobenzene < .001 mg/1 WG700059 01/07/14 12:59
2,2-Dichloropropane < .001 mg/1 WG700059 01/07/14 12:59
2-Butanone (MEK( < .01 mg/1 W0700059 01/07/14 12:59
2-Chlorotoluene < .001 mg/1 WG700059 01/07/14 12:59
4-Chlorotoluene < .001 mg/1 WG700059 01/07/14 12:59
4-Methy1-2-pentanone (MIBK( < .01 mg/1 WG700059 01/07/14 12:59
Acetone < .05 mg/1 WG700059 01/07/14 12:59
Acrolein < .025 mg/1 WG700059 01/07/14 12:59
Acrylnnitrile < .01 mg/1 WG700059 01/07/14 12:59
Benzene < .001 mg/1 WG700059 01/07/14 12:59
Bromobenzene < .001 mg/1 WG700059 01/07/14 12:59
Bromodichloromethane < .001 mg/1 WG700059 01/07/14 12:59
Bromoform < .001 mg/1 WG700059 01/07/14 12:59
Bromomethane < .005 mg/1 WG700059 01/07/14 12:59
Carbon tetrachloride < .001 mg/1 WG700059 01/07/14 12:59
Chlorobenzene < .001 mg/1 WG700059 01/07/14 12:59
Chlorodibromomethane < .001 mg/1 WG700059 01/07/14 12:59
Chloroethane < .005 mg/1 WG700059 01/07/14 12:59
Chloroform < .005 mg/1 WG700059 01/07/14 12:59
Chloromethane < .0025 mg/1 1G700059 01/07/14 12:59
cis-1,2-Dichloroethene < .001 mg/1 WG700059 01/07/14 12:59
Di -isopropyl ether < .001 mg/1 WG700059 01/07/14 12:59
Dibromomethane < .001 mg/1 WG700059 01/07/14 12:59
Dichlorodifluoromethane < .005 mg/1 WG700059 01/07/14 12:59
Ethylbenzene < .001 mg/1 WG700059 01/07/14 12:59
Hexachloro-1,3-butadiene < .001 mg/1 WG700059 01/07/14 12:59
Isopropylbenzene < .001 mg/1 WG700059 01/07/14 12:59
msp-Xylenes < .002 mg/1 WG700059 01/07/14 12:59
Methyl tert-butyl ether < .001 mg/1 WG700059 01/07/14 12:59
Methylene Chloride < .005 mg/1 WG700059 01/07/14 12:59
n-Butylbenzene < .001 mg/1 WG700059 01/07/14 12:59
n-Propylbenzene < .001 mg/1 WG700059 01/07/14 12:59
Naphthalene < .005 mg/1 WG700059 01/07/14 12:59
o-Xylene < .001 mg/1 r4G700059 01/07/14 12:59
p-Isapropyltoluene < .001 mg/1 WG700059 01/07/14 12:59
sec-Butylbenzene < .001 mg/1 WG700059 01/07/14 12:59
Styrene < .001 mg/1 WG700059 01/07/14 12:59
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 30 of 49

1

ESC
L.A=8 6•C•1•E•W•C.-.-E•S
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L 67 6247
12065 Lebanon Rd.
Mt. Juliet, TA 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Laboratory Blank
Analyte Result Units 8 Rec Limit Batch Date Analyzed
tert-Butylbenzene < .001 mg/1 WG700059 01/07/14 12:59
Tetrachloroethene < .001 mg/1 WG700059 01/07/14 12:59
Toluene < .005 mg/1 WG700059 01/07/14 12:59
trans-1,2-Dichloroethene < .001 mg/1 WG700059 01/07/14 12.59
Trichlorcethene < .001 mg/1 WG700059 01/07/14 12:59
Trichlorofluoromethane < .005 mg/1 WG700059 01/07/14 12:59
Vinyl chloride < .001 mg/1 WG700059 01/07/14 12:59
4-Bromofluorobenzene 8 Rec. 89.80 71-126 WG700059 01/07/14 12:59
Dibromofluoromethane 8 Rec. 97.10 78.3-121 WG700059 01/07/14 12:59
Toluene-d8 8 Rec. 101.0 88.5-111 WG700059 01/07/14 12:59
a,a,a-Trifluorotoluene 4 Rec. 94.90 85-114 WG700059 01/07/14 12:59
1,1,1,2-Tetrachloroethane < .001 mg/1 WG700493 01/07/14 14:05
1,1,1-Trichloroethane < .001 mg/1 WG700493 01/07/14 14:05
1,1,2,2-Tetrachloroethane < .001 mg/1 WG700493 01/07/14 14:05
1,1,2-Trichloroethane < .001 mg/1 WG700493 01/07/14 14:05
1,1-Dichloroethane < .001 mg/1 WG700493 01/07/14 14:05
1,1-Dichlaroethene < .001 mg/1 WG700493 01/07/14 14:05
1,1-Dichloropropene < .001 mg/1 WG700493 01/07/14 14:05
1,2,3-Trichlorobenzene < .001 mg/1 WG700493 01/07/14 14:05
1,2,3-Trichloropropane < .001 mg/1 WG700493 01/07/14 14:05
1,2,4-Trichlorobenzene < .001 mg/1 WG700493 01/07/14 14:05
1,2,4-Trimethylbenzene < .001 mg/1 WG700493 01/07/14 14:05
1,2-Dibromo-3-Chloropropane < .005 mg/1 WG700493 01/07/14 14:05
1,2-Dibromoethane < .001 mg/1 WG700493 01/07/14 14:05
1,2-Dichlorobenzene < .001 mg/1 WG700493 01/07/14 14:05
1,2-Dichloroethane < .001 mg/1 WG700493 01/07/14 14:05
1,2-Dichloropropane < .001 mg/1 WG700493 01/07/14 14:05
1,3,5-Trimethylbenzene < .001 mg/1 WG700493 01/07/14 14:05
1,3-Dichlorobenzene < .001 mg/1 WG700493 01/07/14 14:05
1,3-Dichloropropane < .001 mg/1 WG700493 01/07/14 14:05
1,4-Dichlorobenzene < .001 mg/1 WG700493 01/07/14 14:05
2,2-Dichloropropane < .001 mg/1 WG700493 01/07/14 14:05
2-Butanone (MEK) < .01 mg/1 WG700493 01/07/14 14:05
2-Chlorotoluene < .001 mg/1 WG700493 01/07/14 14:05
4-Chlorotoluene < .001 mg/1 WG700493 01/07/14 14:05
4-Methyl-2-pentanone (MIBK) < .01 mg/1 WG700493 01/07/14 14:05
Acetone < .05 mg/1 WG700493 01/07/14 14:05
Acrolein < .025 mg/1 WG700493 01/07/14 14:05
Acrylonitrile < .01 mg/1 WG700493 01/07/14 14:05
Benzene < .001 mg/1 WG700493 01/07/14 14:05
Bromobenzene < .001 mg/1 WG700493 01/07/14 14:05
Bromodichloromethane < .001 mg/1 WG700493 01/07/14 14:05
Bromoform < .001 mg/1 WG700493 01/07/14 14:05
Bromomethane < .005 mg/1 WG700493 01/07/14 14:05
Carbon tetrachloride < .001 mg/1 WG700493 01/07/14 14:05
Chlorobenzene < .001 mg/1 WG700493 01/07/14 14:05
Chlorodibromomethane < .001 mg/1 WG700493 01/07/14 14:05
Chloroethane < .005 mg/1 WG700493 01/07/14 14:05
Chloroform < .005 mg/1 WG700493 01/07/14 14:05
Chloromethane < .0025 mg/1 WG700493 01/07/14 14:05
cis-1,2-Dichloroethene < .001 mg/1 WG700493 01/07/14 14:05
Di -isopropyl ether < .001 mg/1 WG700493 01/07/14 14:05
Dibromamethane < .001 mg/1 WG700493 01/07/14 14:05
Dichlorodifluoromethane < .005 mg/1 WG700493 01/07/14 14:05
Ethylbenzene < .001 mg/1 WG700493 01/07/14 14:05
Hexachloro-1,3-butadiene < .001 mg/1 WG700493 01/07/14 14:05
Isopropylbenzene < .001 mg/1 WG700493 01/07/14 14:05
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 31 of 49

OESC
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Laboratory Blank
Analyte Result Units 8 Rec Limit Batch Date Analyzed
msp-Xylenes < .002 mg/1 WG700493 01/07/14 14:05
Methyl tert-butyl ether < .001 mg/1 WG700493 01/07/14 14:05
Methylene Chloride < .005 mg/1 WG700493 01/07/14 14:05
n Butylbenzene < .001 mg/1 WG700493 01/07/14 14:05
n-Propylbenzene < .001 mg/1 WG700493 01/07/14 14:05
Naphthalene € .005 mg/1 WG700493 01/07/14 14:05
o-Xylene < .001 mg/1 WG700493 01/07/14 14:05
p-Isopropyltoluene < .001 mg/1 WG700493 01/07/14 14:05
sec-Butyibenzene < .001 mg/1 WG700493 01/07/14 14:05
Styrene < .001 mg/1 WG700493 01/07/14 14:05
tert-Butylbenzene < .001 mg/1 WG700493 01/07/14 14:05
Tetrachloroethene < .001 mg/1 WG700493 01/07/14 14:05
Toluene < .005 mg/1 WG700493 01/07/14 14:05
trans-1,2-Dichloroethene < .001 mg/1 WG700493 01/07/14 14:05
Trichloroethene < .001 mg/1 1G700493 01/07/14 14:05
Trichlorofluoromethane < .005 mg/1 WG700493 01/07/14 14:05
Vinyl chloride < .001 mg/1 WG700493 01/07/14 14:05
4-Bromofluorobeazene 8 Rec. 101.0 71-126 WG700493 01/07/14 14:05
Dibromofluoromethane 8 Rec. 103.0 78.3-121 WG700493 01/07/14 14:05
Toluene -dB 8 Rec. 104.0 88,5-111 WG700493 01/07/14 14:05
a,a,a-Trifluorotoluene 8 Rec. 93.20 85-114 WG700493 01/07/14 14:05
1,1,1,2-Tetrachloroethane < .001 mg/1 WG700132 01/08/14 12:28
1,1,1-Trichloroethane < .001 mg/1 WG700132 01/08/14 12:28
1,1,2,2-Tetrachloroethane < .001 mg/1 WG700132 01/08/14 12:28
1,1,2-Trichloroethane < .001 mg/1 WG700132 01/08/14 12:28
1,1-Dichloroethane < .001 mg/1 WG700132 01/08/14 12:28
1,1-Dichloroethene < .001 mg/1 WG700132 01/08/14 12:28
1,1-Dichloropropene < .001 mg/1 WG700132 01/08/14 12:28
1,2,3-Tricblorobenzene < .001 mg/1 WG700132 01/08/14 12:28
1,2,3-Trichloropropane < .001 mg/1 WG700132 01/08/14 12:28
1,2,4-Trichlorobenzene < .001 mg/1 WG700132 01/08/14 12:28
1,2,4-Trimethyibenzene < .001 mg/1 WG700132 01/08/14 12:28
1,2-Dibromo-3-Chloropropane < .005 mg/1 1G700132 01/08/14 12:28
1,2-Dibromoethane < .001 mg/1 WG700132 01/08/14 12:28
1,2-Dichlorobenzene < .001 mg/1 WG700132 01/08/14 12:28
1,2-Dichloroethane < .001 mg/1 WG700132 01/08/14 12:28
1,2-Dichloropropane < .001 mg/1 1G700132 01/08/14 12:28
1,3,5-Trimethylbenzene < .001 mg/1 WG700132 01/08/14 12:28
1,3-Dichlorobenzene < .001 mg/1 WG700132 01/08/14 12:28
1,3-Dichloropropane < .001 mg/1 WG700132 01/08/14 12:28
1,4-Dichlorobenzene < .001 mg/1 WG700132 01/08/14 12:28
2,2-Dichloropropane < .001 mg/1 WG700132 01/08/14 12:28
2-Butanone (MEK) < .01 mg/1 WG700132 01/08/14 12:28
2-Chlorotoluene < .001 mg/1 WG700132 01/08/14 12:28
4-Chiorotoluene < .001 mg/1 WG700132 01/08/14 12:28
4-Methy1-2-pentanone (MIBK) < .01 mg/1 WG700132 01/08/14 12:28
Acetone < .05 mg/1 WG700132 01/08/14 12:28
Acrolein < .025 mg/1 WG700132 01/08/14 12:28
Acrylonitrile < .01 mg/1 WG700132 01/08/14 12:28
Benzene < .001 mg/1 WG700132 01/08/14 12:28
Bromobenzene < .001 mg/1 WG700132 01/08/14 12:28
Bromodichloromethane < .001 mg/1 WG700132 01/08/14 12:28
Bromoform < .001 mg/1 WG700132 01/08/14 12:28
Bromomethane < .005 mg/1 WG700132 01/08/14 12:28
Carbon tetrachloride < .001 mg/1 WG700132 01/08/14 12:28
Chlorobenzene < .001 mg/1 wG700132 01/08/14 12:28
Chlorodibromometbane < .001 mg/1 WG700132 01/08/14 12:28
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 32 of 49

r

OESC
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Raleigh, NC 27615
Quality Assurance Report
Level II
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08, 2014
Analyte
Result
Laboratory Blank
Units 8 Rec
Limit
Batch Date Analyzed
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
Di -isopropyl ether
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Nexachloro-1,3-butadiene
Isopropylbenzene
msp-%ylenes
Methyl tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-lylene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-d8
a,a,a-Trifluorotoluene
.005
.005
.0025
.001
.001
.001
.005
.001
.001
.001
.002
.001
.005
.001
.001
.005
.001
.001
.001
.001
.001
.001
.005
.001
.001
.005
.001
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/ 1
mg/ 1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/ 1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
8 Rec.
% Rec.
6 Rec.
8 Rec.
101.0
108.0
104.0
91.60
71-126
78.3-121
88.5-111
85-114
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/06/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
01/08/14
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
12:28
Analyte
Units
Duplicate
Result Duplicate RPD
Limit
Ref Samp Hatch
Lead
mg/1 0.0600
0.0585 2.00 20 L676247-01 WG699922
Analyte
Lead
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
* Performance of this Analyte
For additional information,
Units
mg/1
Laboratory Control Sample
Known Val Result
1
0.990
8 Rec
99.0
mg/1 .025 0.0216 86.6
mg/1 .025 0.0226 90.4
mg/1 .025 0.0216 86.2
mg/1 .025 0.0238 95.3
mg/1 .025 0.0230 92.0
mg/1 .025 0.0262 105.
mg/1 .025 0.0236 94.3
mg/1 .025 0.0237 94.8
mg/1 .025 0.0219 87.7
mg/1 .025 0.0252 101.
mg/1 .025 0.0209 83.5
mg/1 .025 0.0244 97.8
mg/1 .025 0.0232 92.9
mg/1 .025 0.0237 94.7
mg/1 .025 0.0241 96.3
mg/1 .025 0.0227 90.7
is outside of established criteria.
please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 33 of 49
Limit
85-115
74.2-124
73.2-123
70.7-122
77.7-118
70.7-126
67.8-129
73.1-125
64.9-135
71.8-121
69.7-136
75-123
65.4-128
76.6-121
78.4-117
68.8-124
76.5-119
Batch
WG699922
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059
WG700059

OESC
L•A -B K•C•i•e•Ai•.".•Z•S
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Laboratory Control Sample
Anal•y+e Units Known Val Result
8 Rec
Limit Batch
1,3,5-Tri.methylbenzene mg/1 .025 0.0218 87.2 75.6-124 WG700059
1,3-Dichlorobenzene mg/1 .025 0.0222 88.7 70.8-128 WG700059
1,3-Dichloropropane mg/1 .025 0.0237 94.9 77.4-117 WG700059
1,4-Dichlorobenzene mg/1 .025 0.0228 91.4 78.8-115 MG100059
2,2-Dichloropropane mg/1 .025 0.0233 93.1 62.4-133 WG700059
2-Butanone (MEK} mg/1 .125 0.131 105. 55-149 WG700059
2-Chlorotoluene mg/1 .025 0.0203 81.2 74.7-122 WG700059
4-Chlorotoluene mg/1 .025 0.0213 85.3 77.5-120 WG700059
4-Methy1-2-pentanone (MIBK) mg/1 .125 0.130 104. 70.5-133 WG700059
Acetone mg/1 .125 0.119 95.3 35.6-163 WG700059
Acrolein mg/1 .125 0.142 114. 10-190 WG700059
Acrylonitrile mg/1 .125 0.125 99.9 55.2-130 WG700059
Benzene mg/1 .025 0.0231 92.3 74.8-121 WG700059
Bromobenzene mg/1 .025 0.0218 87.2 77.5-116 WG700059
Bromodichloromethane mg/1 .025 0.0215 86.0 75.1-116 WG700059
Bromoform mg/1 .025 0.0227 90.8 67.5-130 WG700059
Bromomethane mg/1 .025 0.0251 100. 49.9-162 WG700059
Carbon tetrachloride mg/1 .025 0.0228 91.3 70.2-123 WG700059
Chlorobenzene mg/1 .025 0.0229 91.6 78.1-119 WG700059
Chlorodibromomethane mg/1 .025 0.0222 88.9 74-121 WG700059
Chloroethane mg/1 .025 0.0255 102. 61.7-135 WG700059
Chloroform mg/1 .025 0.0232 92.8 76-121 WG700059
Chloromethane mg/1 .025 0.0231 92.3 61.5-129 WG700059
cis-1,2-Dichloroethene mg/1 .025 0.0223 89.3 76-119 WG700059
Di -isopropyl ether mg/1 .025 0.0228 91.2 65.6-132 WG700059
Dibromomethane mg/1 .025 0.0237 94.7 79.5-118 WG700059
Dichlorodifluoromethane mg/1 .025 0.0230 91.8 54.8-135 WG700059
Ethylbenzene mg/1 .025 0.0227 90.7 78.8-122 WG700059
liexachloro-1,3-butadiene mg/1 .025 0.0224 89.4 64.7-129 WG700059
Isopropylbenzene mg/1 .025 0.0238 95.4 78.6-132 WG700059
m6.p-Xylenes mg/1 .05 0.0428 85.6 78.8-121 WG700059
Methyl tent -butyl ether mg/1 .025 0.0215 86.1 71.2-126 WG700059
Methylene Chloride mg/1 .025 0.0205 81.8 70.3-120 WG700059
n-Butylbenzene mg/1 .025 0.0249 99.4 76.2-126 WG700059
n-Propylbenzene mg/1 .025 0.0225 90.2 78.2-122 WG700059
Naphthalene mg/1 .025 0.0238 95.2 68.4-128 WG700059
o-Xylene mg/1 .025 0.0219 87.6 77.6-122 WG700059
p-Isopropyltoluene mg/1 .025 0.0220 87.9 74-131 WG700059
sec-Butylbeneene mg/1 .025 0.0217 86.7 74.4-127 WG700059
Styrene mg/1 .025 0.0239 95.5 80.4-126 WG700059
text-Butylbenzene mg/1 .025 0.0215 86.1 75.3-126 WG700059
Tetrachloroethene mg/1 .025 0.0235 93.8 72.6-126 WG700059
Toluene mg/1 .025 0.0228 91.2 79.7-116 WG700059
trans-1,2-Dichloroethene mg/1 .025 0.0222 88.9 72.6-121 WG700059
Trichloroethene mg/1 .025 0.0226 90.4 77.7-118 WG700059
Trichlorofluoromethane mg/1 .025 0.0250 99.8 63.5-135 WG700059
Vinyl chloride mg/1 .025 0.0244 97.5 65.9-128 WG700059
4-Bromofluorobenzene 91.10 71-126 WG700059
Dibromofluoromethane 98.80 78.3-121 WG700059
Toluene-d8 100.0 88.5-111 WG700059
a,a,a-Trifluorotoluene 95.40 85-114 WG700059
1,1,1,2-Tetrachloroethane mg/1 .025 0.0221 88.5 74.2-124 WG700493
1,1,1-Trichloroethane mg/1 .025 0.0219 87.4 73.2-123 WG700493
1,1,2,2-Tetrachloroethane mg/1 .025 0.0212 84.9 70.7-122 WG700493
1,1,2-Trichloroethane mg/1 .025 0.0230 91.8 77.7-118 WG700493
1,1-Dichloroethane mg/1 .025 0.0217 86.6 70.7-126 WG700493
1,1-Dichloroethene mg/1 .025 0.0252 101. 67.8-129 WG700493
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 34 of 49

1

OESC
L•JL•El 4-C•'•E•Af•L'..-E•S
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L 67 6247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Analyte
Laboratory Control Sample
Units Known Val Result 8 Rec Limit Batch
1,1-Dichloroprapene mg/1 .025 0.0216 86.2 73.1-125 WG700493
1,2,3-Trichlorobenzene mg/1 .025 0.0246 98.2 64.9-135 WG700493
1,2,3-Trichloropropane mg/1 .025 0.0222 89.0 71.8-121 WG700493
1,2,4-Trichlorobenzene mg/1 .025 0.0248 99.4 69.7-136 WG700493
1,2,4-Trimethylbenzene mg/1 .025 0.0233 93.1 75-123 WG700493
1,2-Dibromo-3-Chloropropane mg/1 .025 0.0208 83.1 65.4-128 WG700493
1,2-Dibromoethane mg/1 .025 0.0215 85.9 76.6-121 WG700493
1,2-Dichlorobenzene mg/1 .025 0.0214 85.8 78.4-117 WG700493
1,2-Dichloroethane mg/1 .025 0.0210 83.8 68.8-124 WG700493
1,2-Dichloropropane mg/1 .025 0.0199 79.5 76.5-119 WG700493
1,3,5-Trimethylbenzene mg/1 .025 0.0240 95.9 75.6-124 WG700493
1,3-Dichlorobenzene mg/1 .025 0.0242 96.9 70.8-128 WG700493
1,3-Dichloropropane mg/1 .025 0.0216 86.2 77.4-117 WG700493
1,4-Dichlorobenzene mg/1 .025 0.0220 87.8 78.8-115 WG700493
2,2-Dichloropropane mg/1 .025 0.0223 89.3 62.4-133 WG700493
2-Butanone (MEK) mg/1 .125 0.105 83.9 55-149 WG700493
2-Chlorotoluene mg/1 .025 0.0236 94.4 74.7-122 WG700493
4-Chlorotoluene mg/1 .025 0.0232 92.9 77.5-120 WG700493
4-Methyl-2-pentanone (MIBK) mg/1 .125 0.102 81.6 70.5-133 WG700493
Acetone mg/1 .125 0.123 98.3 35.6-163 WG700493
Acrolein mg/1 .125 0.101 81.1 10-190 WG700493
Acrylonitrile mg/1 .125 0.112 89.9 55.2-130 WG700493
Benzene mg/1 .025 0.0219 87.6 74.8-121 WG700493
Bromobenzene mg/1 .025 0.0215 86.0 77.5-116 WG700493
Bromodichloromethane mg/1 .025 0.0192 76.9 75.1-116 WG700493
Bromoform mg/1 .025 0.0224 89.4 67.5-130 WG700493
Bromomethane mg/1 .025 0.0247 98.8 49.9-162 WG700493
Carbon tetrachloride mg/1 .025 0.0215 86.1 70.2-123 WG700493
Chlorobenzene mg/1 .025 0.0223 89.2 76.1-119 WG700493
Chlorodibromomethane mg/1 .025 0.0216 86.3 74-121 WG700493
Chloroethane mg/1 .025 0.0257 103. 61.7-135 WG700493
Chloroform mg/1 .025 0.0218 87.2 76-121 WG700493
Chloromethane mg/1 .025 0.0203 81.3 61.5-129 WG700493
cis-1,2-Dichloroethene mg/1 .025 0.0219 87.6 76-119 WG700493
Di -isopropyl ether mg/1 .025 0.0207 83.0 65.6-132 WG700493
Dibromomethane mg/1 .025 0.0211 84.3 79.5-118 WG700493
Dichlorodifluoromethane mg/1 .025 0.0211 84.4 54.8-135 WG700493
Euhylbenzene mgll .025 0.0230 91.9 78.8-122 WG700493
Hexachloro-1,3-butadiene mg/1 .025 0.0231 92.5 64.7-129 WG700493
Isopropylbenzene mg/1 .025 0.0247 98.9 78.6-132 WG700493
map-xylenes mg/1 .05 0.0459 91.7 78.8-121 WG700493
Methyl tert-butyl ether mg/1 .025 0.0208 83.2 71.2-126 WG700493
Methylene Chloride mg/1 .025 0.0218 87.2 70.3-120 WG700493
n-Butylbenzene mg/1 .025 0.0225 89.9 76.2-126 WG700493
n-Propylbenzene mg/1 .025 0.0228 91.2 78.2-122 WG700493
Naphthalene mg/1 .025 0.0227 90.8 68.4-128 WG700493
o-xylene mg/1 .025 0.0229 91.4 77.6-122 WG700493
p-Isopropyltoluene mg/1 .025 0.0253 101. 74-131 WG700493
sec-Butylbenzene mg/1 .025 0.0246 98.6 74.4-127 WG700493
Styrene mg/1 .025 0.0235 94.2 80.4-126 WG700493
text-Butylbenzene mg/1 .025 0.0242 96.9 75.3-126 WG700493
Tetrachloroethene mg/1 .025 0.0228 91.3 72.6-126 WG700493
Toluene mgll .025 0.0209 83.6 79.7-116 WG700493
trans-1,2-Dichloroethene mg/1 .025 0.0226 90.4 72.6-121 1G700493
Trichlaroethene mgll .025 0.0208 83.2 77.7-118 WG700493
Trichlorofluoromethane mgll .025 0.0266 106. 63.5-135 WG700493
Vinyl chloride mg/1 .025 0.0225 90.0 65.9-128 WG700493
4-Bromofluorobenzene 104.0 71-126 1G700493
Dibromofluoromethane 104.0 78.3-121 WG700493
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 35 of 49

1 1'
L
11
I

ESC
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, AC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Laboratory Control Sample
Analyte Units Known Val Result 8 Rec Limit Batch
Toluene-d8 104.0 88.5-111
a,a,a-Trifluorotoluene 93.00 85-114
1,1,1,2-Tetrachloroethane mg/1 .025 0.0222 88.7 74.2-124 WG700132
1,1,1-Trichluroethane mg/1 .025 0.0235 94.1 73.2-123 WG700132
1,1,2,2-Tetrachloroethane mg/1 .025 0.0211 84.2 70.7-122 WG700132
1,1,2-Trichloroethane mg/1 .025 0.0231 92.4 77.7-118 WG700132
1,1-Dichloroethane mg/1 .025 0.0232 92.9 70.7-126 WG700132
1,1-Dichloroethene mg/1 .025 0.0263 105. 67.8-129 WG700132
1,1-Dichloropropene mg/1 .025 0.0232 92.8 73.1-125 WG700132
1,2,3-Trichlorobenzene mg/1 .025 0.0235 94.1 64.9-135 WG700132
1,2,3-Trichloropropane mg/1 .025 0.0221 88.4 71.8-121 WG700132
1,2,4-Trichlorobenzene mg/1 .025 0.0249 99.4 69.7-136 WG700132
1,2,4-Trimethylbenzene mg/1 .025 0.0230 91.9 75-123 WG700132
1,2-Dibromo-3-Chloropropane mg/1 .025 0.0205 81.9 65.4-128 WG700132
1,2-Dibromoethane mg/1 .025 0.0215 86.0 76.6-121 WG700132
1,2-Dichlorobenzene mg/1 .025 0.0225 89.9 78.4-117 WG700132
1,2-Dichloroethane mg/1 .025 0.0226 90.2 68.8-124 WG700132
1,2-Dichloropropane mg/1 .025 0.0212 85.0 76.5-119 WG700132
1,3,5-Trimethylbenzene mg/1 .025 0.0238 95.4 75.6-124 WG700132
1,3-Dichlorabenzene mg/1 .025 0.0235 94.1 70.8-128 WG700132
1,3-Dichloropropane mg/1 .025 0.0216 86.5 77.4-117 WG700132
1,4-Dichlorobenzene mg/1 .025 0.0230 92.1 78.8-115 WG700132
2,2-Dichloropropane mg/1 .025 0.0239 95.8 62.4-133 WG700132
2-Butanone (MEK) mg/1 .125 0.111 88.5 55-149 WG700132
2-Chlorotoluene mg/1 .025 0.0238 95.2 74.7-122 WG700132
4-Chlorotoluene mg/1 .025 0.0231 92.3 77.5-120 WG700132
4-Methy1-2-pentanone (MIRK) mg/1 .125 0.108 86.4 70.5-133 WG700132
Acetone mg/1 .125 0.126 100. 35.6-163 WG700132
Acrolein mg/1 .125 0.102 81.8 10-190 WG700132
Acrylonitrile mg/1 .125 0.117 93.5 55.2-130 WG700132
Benzene mg/1 .025 0.0231 92.5 74.8-121 WG700132
Bromobenzene mg/1 .025 0.0215 86.1 77.5-116 WG700132
Bromodichloromethane mg/1 .025 0.0199 79.5 75.1-116 WG700132
Bromoform mg/1 .025 0.0219 87.7 67.5-130 WG700132
Bromomethane mg/1 .025 0.0289 116. 49.9-162 WG700132
Carbon tetrachloride mg/1 .025 0.0213 85.1 70.2-123 WG700132
Chlorobenzene mg/1 .025 0.0221 88.3 78.1-119 WG700132
Chlorodibromomethane mg/1 .025 0.0214 85.8 74-121 WG700132
Chloroethane mg/1 .025 0.0278 111. 61.7-135 WG700132
Chloroform mg/1 .025 0.0236 94.5 76-121 WG700132
Chloromethane mg/1 .025 0.0214 85.6 61.5-129 WG700132
cis-1,2-Dichloroethene mg/1 .025 0.0236 94.6 76-119 WG700132
Di -isopropyl ether mg/1 .025 0.0220 88.1 65.6-132 WG700132
Dibromomethane mg/1 .025 0.0220 88.2 79.5-118 WG700132
Dichlorodifluoromethane mg/1 .025 0.0232 92.9 54.8-135 WG700132
Ethylbenzene mg/1 .025 0.0228 91.2 78.8-122 WG700132
Hexachloro-1,3-butadiene mg/1 .025 0.0222 88.9 64.7-129 WG700132
Isopropylbenzene mg/1 .025 0.0245 98.1 78.6-132 WG700132
ms.p-Xylenes mg/1 .05 0.0459 91.8 78.8-121 WG700132
Methyl tert-butyl ether mg/1 .025 0.0222 88.7 71.2-126 WG700132
Methylene Chloride mg/1 .025 0.0234 93.4 70.3-120 WG700132
n-Butylbenzene mg/1 .025 0.0233 93.2 76.2-126 WG700132
n-Propylbenzene mg/1 .025 0.0229 91.4 78.2-122 WG700132
Naphthalene mg/1 .025 0.0228 91.1 68.4-128 WG700132
o-Kylene mg/1 .025 0.0227 90.6 77.6-122 WG700132
p-Isopropyltoluene mg/1 .025 0.0247 98.8 74-131 WG700132
sec-Butylbenzene mg/1 .025 0.0240 96.0 74.4-127 WG700132
Styrene mg/1 .025 0.0236 94.3 80.4-126 WG700132
tert-Butylbenzene mg/1 .025 0.0239 95.6 75.3-126 WG700132
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 36 of 49

I
ti

ESC
L•A,B b'C-i- N ice,,. �.g
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Raleigh, NC 27615
Quality Assurance Report
Level II
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08, 2014
Analyte
Units
Laboratory Control Sample
Known Val Result
8 Rec
Limit
Batch
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromafluorobenzene
Dibramofluoromethane
Toluene-d8
a,a,a-Trifluorotoluene
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
.025
.025
.025
.025
.025
.025
0.0231
0.0221
0.0238
0.0210
0.0277
0.0240
92.5
88.3
95.2
84.1
111.
95.9
99.20
106.0
104.0
92.40
72.6-126 14G700132
79.7-116 WG700132
72.6-121 WG700132
77.7-118 WG700132
63.5-135 WG700132
65.9-128 WG700132
71-126 WG700132
78.3-121 WG700132
88.5-111 WG700132
85-114 WG700132
Analyte
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
4-Chlorotoluene
4-Methy1-2-pentanone (MIBK)
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloraethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
Di -isopropyl ether
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Eexachloro-1,3-butadiene
' Performance of this Analyte
For additional information,
Laboratory Control Sample Duplicate
Units Result Ref %Rec
Limit
mg/1 0.0223 0.0216 89.0 74.2-124
mg/1 0.0219 0.0226 88.0 73.2-123
mg/1 0.0219 0.0216 87.0 70.7-122
mg/1 0.0239 0.0238 96.0 77.7-118
mg/1 0.0225 0.0230 90.0 70.7-126
mg/1 0.0248 0.0262 99.0 67.8-129
mg/1 0.0236 0.0236 94.0 73.1-125
mg/1 0.0243 0.0237 97.0 64.9-135
mg/1 0.0218 0.0219 87.0 71.8-121
mg/1 0.0260 0.0252 104. 69.7-136
mg/1 0.0213 0.0209 85.0 75-123
mg/1 0.0269 0.0244 108. 65.4-128
mg/1 0.0255 0.0232 102. 76.6-121
mg/1 0.0244 0.0237 98.0 78.4-117
1.19/1 0.0245 0.0241 98.0 68.8-124
mg/1 0.0225 0.0227 90.0 76.5-119
mg/1 0.0219 0.0218 88.0 75.6-124
mg/1 0.0221 0.0222 88.0 70.8-128
mg/1 0.0249 0.0237 100. 77.4-117
mg/1 0.0230 0.0228 92.0 78.8-115
mg/1 0.0222 0.0233 89.0 62.4-133
1.19/1 0.137 0.131 110. 55-149
1.19/1 0.0206 0.0203 82.0 74.7-122
m9/1 0.0215 0.0213 86.0 77.5-120
mg/1 0.125 0.130 100. 70.5-133
mg/1 0.121 0.119 97.0 35.6-163
mg/1 0.153 0.142 123. 10-190
mg/1 0.125 0.125 100. 55.2-130
mg/1 0.0232 0.0231 93.0 74.8-121
mg/1 0.0216 0.0218 86.0 77.5-116
mg/1 0.0212 0.0215 85.0 75.1-116
mg/1 0.0234 0.0227 93.0 67.5-130
mg/1 0.0251 0.0251 100. 49.9-162
mg/1 0.0222 0.0228 89.0 70.2-123
1.19/1 0.0232 0.0229 93.0 78.1-119
mg/1 0.0229 0.0222 92.0 74-121
mg/1 0.0245 0.0255 98.0 61.7-135
mg/1 0.0227 0.0232 91.0 76-121
mg/1 0.0220 0.0231 88.0 61.5-129
mg/1 0.0224 0.0223 89.0 76-119
mg/1 0.0225 0.0228 90.0 65.6-132
mg/1 0.0238 0.0237 95.0 79.5-118
mg/1 0.0228 0.0230 91.0 54.8-135
mg/1 0.0231 0.0227 92.0 78.8-122
mg/1 0.0226 0.0224 90.0 64.7-129
is outside of established criteria.
please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 37 of 49
RPD Limit Batch
3.03 20 WG700059
2.93 20 WG700059
1.37 20 WG700059
0.200 20 WG700059
2.35 20 WG700059
5.49 20 WG700059
0.120 20 WG700059
2.42 20 WG700059
0.560 20 WG700059
2.99 20 WG700059
1.80 20 WG700059
9.58 20 WG700059
9.27 20 WG700059
3.14 20 WG700059
1.69 20 WG700059
0.750 20 WG700059
0.660 20 WG700059
0.360 20 WG700059
4.89 20 WG700059
0.840 20 WG700059
4.79 20 WG700059
4.61 20 WG700059
1.33 20 WG700059
0.700 20 WG700059
4.57 20 WG700059
1.81 23.9 WG700059
7.72 28.1 WG700059
0.330 20 WG700059
0.520 20 WG700059
0.940 20 WG700059
1.37 20 WG700059
2.89 20 WG700059
0.0400 20 WG700059
2.93 20 WG700059
1.32 20 WG700059
3.06 20 WG700059
4.08 20 WG700059
1.99 20 WG700059
4.77 20 WG700059
0.220 20 WG700059
1.28 20 WG700059
0.690 20 WG700059
0.580 20 WG700059
1.65 20 WG700059
0.850 20 WG700059

ilESC
e..G.s•E•Al•v•E•S
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L 67 6247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Analyte
Laboratory Control Sample Duplicate
Units Result Ref %Rec
Limit
RPD Limit Batch
Isopropylbenzene mg/1 0.0236 0.0238 94.0 78.6-132 0.960 20 WG700059
msp %glenes mg/1 0.0440 0.0428 88.0 78.8-121 2.65 20 WG700059
Methyl tert-butyl ether mg/1 0.0212 0.0215 85.0 71.2-126 1.61 20 w9700059
Methylene Chloride mg/1 0.0200 0.0205 80.0 70.3-120 2.11 20 WG700059
n-Butylbenzene mg/1 0.0252 0.0249 101. 76.2-126 1.49 20 WG700059
n-Propylbenzene mg/1 0.0222 0.0225 89.0 78.2-122 1.68 20 WG700059
Naphthalene m9/1 0.0248 0.0238 99.0 68.4-128 3.98 20 16700059
o-%ylene mg/1 0.0220 0.0219 88.0 77.6-122 0.620 20 WG700059
p-Isopropyltoluene mg/1 0.0220 0.0220 88.0 74-131 0.0700 20 WG700059
sec-Butylbenzene mg/1 0.0216 0.0217 86.0 74.4-127 0.360 20 WG700059
Styrene mg/1 0.0239 0.0239 96.0 80.4-126 0.130 20 WG700059
tert-Butylbenzene mg/1 0.0218 0.0215 87.0 75.3-126 1.44 20 WG700059
Tetrachloroethene mg/1 0.0234 0.0235 94.0 72.6-126 0.230 20 1G700059
Toluene mg/1 0.0224 0.0228 90.0 79.7-116 1.83 20 WG700059
trans-1,2-Dichloroethene mg/1 0.0216 0.0222 86.0 72.6-121 2.86 20 WG700059
Trichloroethene mg/1 0.0224 0.0226 90.0 77.7-118 0.900 20 16700059
Trichlarofluoromethane mg/1 0.0232 0.0250 93.0 63.5-135 7.51 20 WG700059
Vinyl chloride mg/1 0.0235 0.0244 94.0 65.9-128 3.88 20 WG700059
4-Bromofluorobenzene 90.40 71-126 WG700059
Dibromofluoromethane 95.00 78.3-121 WG700059
Toluene -dB 97.20 88.5-111 16700059
a,a,a-Trifluorotoluene 90.80 85-114 WG700059
1,1,1,2-Tetrachloroethane mg/1 0.0214 0.0221 86.0 74.2-124 3.19 20 WG700493
1,1,1-Trichloroethane mg/1 0.0222 0.0219 89.0 73.2-123 1.36 20 WG700493
1,1,2, 2 -Tetrachloroethane mg/1 0.0195 0.0212 78.0 70.7-122 8.46 20 WG700493
1,1,2-Trichloroethane mg/1 0.0221 0.0230 88.0 77.7-118 3.84 20 WG700493
1,1-Dichloroethane mg/1 0.0214 0.0217 85.0 70.7-126 1.40 20 WG700493
1,1-Dichloroethene mg/1 0.0248 0.0252 99.0 67.8-129 1.62 20 WG700493
1,1-Dichloropropene mg/1 0.0216 0.0216 86.0 73.1-125 0.270 20 WG700493
1,2,3-Trichlorobenzene mg/1 0.0221 0.0246 88.0 64.9-135 10.3 20 WG700493
1,2,3-Trichloropropane mg/1 0.0213 0.0222 85.0 71.8-121 4.40 20 WG700493
1,2,4-Trichlorobenzene mg/1 0.0225 0.0248 90.0 69.7-136 9.83 20 WG700493
1,2,4-Trimethylbenzene mg/1 0.0215 0.0233 86.0 75-123 7.92 20 WG700493
1,2-Dibromo-3-Chloropropane mg/1 0.0197 0.0208 79.0 65.4-128 5.40 20 WG700493
1,2-Dibromoethane mg/1 0.0210 0.0215 84.0 76.6-121 2.19 20 WG700493
1,2-Dichlorobenzene mg/1 0.0208 0.0214 83.0 78.4-117 3.17 20 WG700493
1,2-Dichloroethane mg/1 0.0208 0.0210 83.0 68.8-124 0.840 20 WG700493
1,2-Dichloropropane mg/1 0.0202 0.0199 81.0 76.5-119 1.74 20 WG700493
1,3,5-Trimethylbenzene mg/1 0.0223 0.0240 89.0 75.6-124 7.40 20 WG700493
1,3-Dichlorobenzene mg/1 0.0221 0.0242 88.0 70.8-128 9.31 20 WG700493
1,3-Dichloropropane mg/1 0.0207 0.0216 83.0 77.4-117 4.17 20 WG700493
1,4-Dichlorobenzene mg/1 0.0213 0.0220 85.0 78.8-115 3.09 20 WG700493
2,2-Dichloropropane mg/1 0.0225 0.0223 90.0 62.4-133 0.760 20 WG700493
2-Butanone (MEK) mg/1 0.0958 0.105 77.0 55-149 8.98 20 WG700493
2-Chlorotoluene mg/1 0.0220 0.0236 88.0 74.7-122 7.06 20 WG700493
4-Chlorotoluene mg/1 0.0219 0.0232 88.0 77.5-120 5.98 20 WG700493
4-Methyl-2-pentanone (MIBK) mg/1 0.0948 0.102 76.0 70.5-133 7.28 20 WG700493
Acetone mg/1 0.108 0.123 86.0 35.6-163 12.8 23.9 WG700493
Acrolein mg/1 0.0937 0.101 75.0 10-190 7.85 28.1 WG700493
Acrylonitrile mg/1 0.100 0.112 80.0 55.2-130 11.6 20 wG700493
Benzene mg/1 0.0217 0.0219 87.0 74.8-121 0.840 20 wG700493
Bromobenzene 149/1 0.0205 0.0215 82.0 77.5-116 4.97 20 WG700493
Bromodichloromethane mg/1 0.0189 0.0192 76.0 75.1-116 1.51 20 WG700493
Bromoform mg/1 0.0209 0.0224 84.0 67.5-130 6.58 20 WG700493
Bromomethane mg/1 0.0269 0.0247 107. 49.9-162 8.36 20 WG700493
Carbon tetrachloride mg/1 0.0202 0.0215 81.0 70.2-123 6.17 20 WG700493
Chlarobenzene mg/1 0.0216 0.0223 86.0 78.1-119 3.28 20 WG700493
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifies.'
Page 38 of 49

451ESC
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Analyte
Laboratory Control Sample Duplicate
Units Result Ref %Rec
Limit
RPD Limit Batch
Chlorodibromomethane mg/1 0.0208 0.0216 83.0 74-121 3.66 20 WG700493
Chloroethane mg/1 0.0258 0.0257 103. 61.7-135 0.290 20 WG700493
Chloroform mg/1 0.0219 0.0216 88.0 76-121 0.520 20 WG700493
Chloromethane mg/1 0.0203 0.0203 81.0 61.5-129 0.240 20 WG700493
cis-1,2-Dichloroethene mg/1 0.0220 0.0219 88.0 76-119 0.270 20 WG700493
Di -isopropyl ether mg/1 0.0203 0.0207 81.0 65.6-132 2.07 20 WG700493
Dibromomethane mg/1 0.0204 0.0211 82.0 79.5-118 3.27 20 WG700493
Dichlorodifluoromethane mg/1 0.0205 0.0211 82.0 54.8-135 2.90 20 WG700493
Euhylbenzene mg/1 0.0224 0.0230 89.0 78.8-122 2.77 20 WG700493
Hexachloro-1,3-butadiene mg/1 0.0199 0.0231 80.0 64.7-129 15.0 20 WG700493
Isopropylbenzene mg/1 0.0235 0.0247 94.0 78.6-132 4.98 20 WG700493
map-Xylenes mg/1 0.0439 0.0459 88.0 78.8-121 4.37 20 WG700493
Methyl tert-butyl ether mg/1 0.0197 0.0208 79.0 71.2-126 5.28 20 WG700493
Methylene Chloride mg/1 0.0219 0.0218 88.0 70.3-120 0.480 20 WG700493
n-Butylbenzene mg/1 0.0207 0.0225 83.0 76.2-126 8.44 20 WG700493
n-Propylbenzene mg/1 0.0215 0.0228 86.0 78.2-122 5.71 20 WG700493
Naphthalene mg/1 0.0206 0.0227 82.0 68.4-128 9.63 20 WG700493
o-Xylene mg/1 0.0216 0.0229 86.0 77.6-122 5.80 20 WG700493
p-Isopropyltoluene mg/1 0.0229 0.0253 92.0 74-131 9.68 20 WG700493
sec-Butylbenzene mg/1 0.0222 0.0246 89.0 74.4-127 10.3 20 WG700493
Styrene mg/1 0.0226 0.0235 90.0 80.4-126 4.16 20 WG700493
tert-Butylbenzene mg/1 0.0227 0.0242 91.0 75.3-126 6.71 20 WG700493
Tetrachloroethene mg/1 0.0220 0.0228 88.0 72.6-126 3.54 20 WG700493
Toluene mg/1 0.0204 0.0209 82.0 79.7-116 2.51 20 WG700493
trans-1,2-Dichloroethene mg/1 0.0219 0.0226 88.0 72.6-121 3.08 20 WG700493
Trichloroethene mg/1 0.0205 0.0208 82.0 77.7-118 1.43 20 WG700493
Trichlorofluoromethane mg/1 0.0262 0.0266 105. 63.5-135 1.39 20 WG700493
Vinyl chloride mg/1 0.0224 0.0225 89.0 65.9-128 0.590 20 WG700493
4-Bromofluorobenzene 102.0 71-126 WG700493
Dibromofluoromethane 105.0 78.3-121 WG700493
Toluene -dB 104.0 88.5-111 WG700493
a,a,a-Trifluorotoluene 92.60 85-114 WG700493
1,1,1,2-Tetrachloroethane mg/1 0.0213 0.0222 85.0 74.2-124 4.18 20 WG700132
1,1,1-Trichloroethane mg/1 0.0231 0.0235 92.0 73.2-123 1.88 20 WG700132
1,1,2,2-Tetrachloroethane mg/1 0.0203 0.0211 81.0 70.7-122 3.65 20 WG700132
1,1,2-Trichloroethane mg/1 0.0226 0.0231 90.0 77.7-118 2.22 20 WG700132
1,1-Dichloroethene mg/1 0.0222 0.0232 89.0 70.7-126 4.38 20 WG700132
1,1-Dichloroethene mg/1 0.0250 0.0263 100. 67.8-129 5.32 20 WG700132
1,1-Dichloropropene mg/1 0.0227 0.0232 91.0 73.1-125 2.23 20 WG700132
1,2,3-Trichlorobenzene mg/1 0.0221 0.0235 88.0 64.9-135 6.24 20 WG700132
1,2,3-Trichloropropane mg/1 0.0221 0.0221 88.0 71.8-121 0.270 20 WG700132
1,2,4-Trichlorobenzene mg/1 0.0228 0.0249 91.0 69.7-136 8.77 20 WG700132
1,2,4-Trimethylbenzene mg/1 0.0218 0.0230 87.0 75-123 5.13 20 WG700132
1,2-Dibroma-3-Chloropropane mg/1 0.0199 0.0205 80.0 65.4-128 2.76 20 WG700132
1,2-Dibromoethane mg/1 0.0212 0.0215 85.0 76.6-121 1.54 20 WG700132
1,2-Dichlorobenzene mg/1 0.0213 0.0225 85.0 78.4-117 5.23 20 WG700132
1,2-Dichloroethane mg/1 0.0216 0.0226 86.0 68.8-124 4.16 20 WG700132
1,2-Dichloropropane mg/1 0.0202 0.0212 81.0 76.5-119 5.08 20 WG700132
1,3,5-Trimethylbenzene mg/1 0.0227 0.0238 91.0 75.6-124 4.75 20 WG700132
1,3-Dichlorobenzene mg/1 0.0226 0.0235 90.0 70.8-128 3.96 20 WG700132
1,3-Dichloropropane mg/1 0.0211 0.0216 84.0 77.4-117 2.42 20 WG700132
1,4-Dichlorobenzene mg/1 0.0220 0.0230 88.0 78.8-115 4.52 20 WG700132
2,2-Dichloropropane mg/1 0.0240 0.0239 96.0 62.4-133 0.450 20 WG700132
2-Butanone (MEK) mg/1 0.105 0.111 84.0 55-149 4.80 20 WG700132
2-Chlorotoluene mg/1 0.0225 0.0238 90.0 74.7-122 5.63 20 WG700132
4-Chlorotoluene mg/1 0.0223 0.0231 89.0 77.5-120 3.31 20 WG700132
4-Methyl-2-pentanone (MIBK) mg/1 0.100 0.108 80.0 70.5-133 7.62 20 WG700132
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 39 of 49

OESC
L•fi,•B b+C>i•E•EV>�-'c•S
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Analyte
Laboratory Control Sample Duplicate
Units Result Ref $Rec Limit RPD Limit Batch
Acetone mg/1 0.114 0.126 91.0 35.6-163 9.44 23.9 WG700132
Acrolein mg/1 0.0981 0.102 78.0 10-190 4.09 28.1 6G700132
Acrylonitrile mg/1 0.111 0.117 88.0 55.2-130 5.54 20 WG700132
Benzene mg/1 0.0225 0.0231 90.0 74.8-121 2.92 20 WG700132
Bromobenzene mg/1 0.0209 0.0215 84.0 77.5-116 3.00 20 WG700132
Bromodichloromethane mg/1 0.0187 0.0199 75. 75.1-116 6.34 20 WG700132
Bromoform mg/1 0.0210 0.0219 84.0 67.5-130 4.37 20 WG700132
Bromomethane mg/1 0.0279 0.0289 112. 49.9-162 3.45 20 WG700132
Carbon tetrachloride mg/1 0.0225 0.0213 90.0 70.2-123 5.76 20 WG700132
Chlorobenzene mg/1 0.0221 0.0221 88.0 78.1-119 0.0600 20 WG700132
Chlorodibromomethane mg/1 0.0212 0.0214 85.0 74-121 1.30 20 WG700132
Chloroethane mg/1 0.0271 0.0278 108. 61.7-135 2.34 20 WG700132
Chloroform mg/1 0.0227 0.0236 91.0 76-121 3.89 20 WG700132
Chloromethane mg/1 0.0210 0.0214 84.0 61.5-129 1.92 20 WG700132
cis-1,2-Dichloroethene mg/1 0.0229 0.0236 92.0 76-119 3.04 20 WG700132
Di -isopropyl ether mg/1 0.0211 0.0220 84.0 65.6-132 4.38 20 WG700132
Dibromomethane mg/1 0.0208 0.0220 83.0 79.5-118 6.02 20 WG700132
Dichlorodifluoromethane mg/1 0.0226 0.0232 90.0 54.8-135 2.77 20 WG700132
Ethylbenzene mg/1 0.0228 0.0228 91.0 78.8-122 0.130 20 WG700132
i8exachloro-1,3-butadiene mg/1 0.0206 0.0222 82.0 64.7-129 7.75 20 WG700132
Isopropylbenzene mg/1 0.0240 0.0245 96.0 78.6-132 2.39 20 w6700132
mip-Xylenes mg/1 0.0446 0.0459 89.0 78.8-121 2.87 20 WG700132
Methyl tert-butyl ether mg/1 0.0217 0.0222 87.0 71.2-126 2.05 20 8G700132
Methylene Chloride mg/1 0.0225 0.0234 90.0 70.3-120 3.71 20 WG700132
n-Butylbenzene mg/1 0.0220 0.0233 88.0 76.2-126 5.65 20 WG700132
n-Propylbenzene mg/1 0.0220 0.0229 88.0 78.2-122 3.92 20 WG700132
Naphthalene mg/1 0.0214 0.0228 86.0 68.4-128 6.21 20 WG700132
o-Xylene mg/1 0.0221 0.0227 88.0 77.6-122 2.35 20 WG700132
p-Isopropyltoluene mg/1 0.0236 0.0247 94.0 74-131 4.68 20 WG700132
sec-Butylbenzene mg/1 0.0229 0.0240 92.0 74.4-127 4.62 20 WG700132
Styrene mg/1 0.0226 0.0236 90.0 80.4-126 4.41 20 WG700132
tert-Butylbenzene mg/1 0.0231 0.0239 92.0 75.3-126 3.52 20 WG700132
Tetrachloroethene mg/1 0.0220 0.0231 88.0 72.6-126 4.77 20 WG700132
Toluene mg/1 0.0209 0.0221 84.0 79.7-116 5.52 20 WG700132
trans-1,2-Dichloroethene mg/1 0.0234 0.0238 94.0 72.6-121 1.57 20 WG700132
Trichloroethene mg/1 0.0205 0.0210 82.0 77.7-118 2.60 20 WG700132
Trichlorofluoromethane mg/1 0.0282 0.0277 113. 63.5-135 1.83 20 WG700132
Vinyl chloride mg/1 0.0234 0.0240 94.0 65.9-128 2.43 20 WG700132
4-Bromofluorobenzene 99.80 71-126 6G700132
Dibromofluoromethane 107.0 78.3-121 6G700132
Toluene-d8 105.0 88.5-111 WG700132
a,a,a-Trifluorotoluene 90.40 85-114 WG700132
Analyte
Lead
Matrix Spike
Units MS Res Ref Res TV 6 Rec Limit Ref Samp Batch
mg/1 1.05 0.0585 1 99.0 75-125 1.676247-01 WG699922
1,1,1,2-Tetrachloroethane mg/1 0.0223 0.0 .025 89.0 64-128 L676220-01 WG700059
1,1,1-Trichloroethane mg/1 0.0245 0.0 .025 98.0 58.7-134 L676220-01 WG700059
1,1,2,2-Tetrachloroethane mg/1 0.0217 0.0 .025 87.0 56-132 L676220-01 WG700059
1,1,2-Trichloroethane mg/1 0.0240 0.0 .025 96.0 66.3-125 L676220-01 WG700059
1,1-Dichloroethane mg/1 0.0241 0.0 .025 96.0 58.5-132 L676220-01 WG700059
1,1-Dichloroethene mg/1 0.0282 0.0 .025 110. 51.1-140 L676220-01 WG700059
1,1-Dichloropropene mg/1 0.0261 0.0 .025 100. 57.3-136 L676220-01 WG700059
1,2,3-Trichlorobenzene mg/1 0.0249 0.0 .025 99.0 59.1-138 L676220-01 WG700059
1,2,3-Trichloropropane mg/1 0.0214 0.0 .025 86.0 61.4-128 L676220-01 WG700059
1,2,4-Trichlorobenzene mg/1 0.0266 0.0 .025 110. 63.6-143 L676220-01 WG700059
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 40 of 49

OESC
L•A.a S.C.€•£•al : -E•S
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Analyte
Matrix Spike
Units MS Res Ref Res TV 8 Rec Limit Ref Samp Batch
1,2,4-Trimethylbenzene mg/1 0.0217 0.0 .025 87.0 57.4-137 1676220-01 WG700059
1,2-Dibromo-3-Chloropropane mg/1 0.0267 0.0 .025 110. 57.3-136 1676220-01 WG700059
1,2-Dibromoethane mg/1 0.0244 0.0 .025 98.0 67.1-125 1676220-01 WG700059
1,2-Dichlorobenzene mg/1 0.0244 0.0 .025 98.0 68.2-123 1676220-01 WG700059
1,2-Dichloroethane mg/1 0.0247 0.0 .025 99.0 60-126 1676220-01 W6700059
1,2-Dichloropropane mg/i 0.0234 0.0 .025 94.0 64.2-123 1676220-01 WG700059
1,3,5-Trimethylhenzene mg/1 0.0226 0.0 .025 90.0 63.6-132 L676220-01 WG700059
1,3-Dichlorabenzene mg/1 0.0227 0.0 .025 91.0 63.1-131 L676220-01 WG700059
1,3-Dichloropropane mg/1 0.0244 0.0 .025 98.0 67.9-121 L676220-01 WG700059
1,4-Dichlorobenzene mg/1 0.0239 0.0 .025 96.0 68.6-123 L676220-01 WG700059
2,2-Dichloropropane mg/1 0.0249 0.0 .025 99.0 50.5-144 L676220-01 WG700059
2-Butanone (MEK) mg/1 0.0973 0.0 .125 78.0 22.4-138 L676220-01 WG700059
2-Chlorotoluene mg/1 0.0215 0.0 .025 86.0 63.6-128 1676220-01 WG700059
4-Chlorotoluene mg/1 0.0222 0.0 .025 89.0 65.7-127 1676220-01 WG700059
4-Methy1-2-pentanone (MIBK) mg/1 0.127 0.0 .125 100. 60.8-140 L676220-01 W0700059
Acetone mg/1 0.0620 0.00117 .125 49.0 10-130 1676220-01 WG700059
Acrolein mg/1 0.218 0.0 .125 170. 10-200 1676220-01 WG700059
Acrylonitrile mg/1 0.129 0.0 .125 100. 49.4-133 L676220-01 WG700059
Benzene mg/1 0.0242 0.0 .025 97.0 54.3-133 1676220-01 WG700059
Bromobenzene mg/1 0.0224 0.0 .025 90.0 63.9-124 1676220-01 WG700059
Bromodichloromethane mg/1 0.0223 0.0 .025 89.0 63.9-121 L676220-01 WG700059
Bromoform mg/1 0.0231 0.0 .025 92.0 59.5-134 1676220-01 WG700059
Bromomethane mg/1 0.0269 0.0 .025 110. 41.7-155 1676220-01 WG700059
Carbon tetrachloride mg/1 0.0250 0.0 .025 100. 55.7-134 1676220-01 WG700059
Chlorobenzene mg/1 0.0235 0.0 .025 94.0 67-125 1676220-01 WG700059
Chlorodibromomethane mg/1 0.0229 0.0 .025 92.0 64.3-125 L676220-01 WG700059
Chloroethane mg/1 0.0274 0.0 .025 110. 51.5-136 1676220-01 WG700059
Chloroform mg/1 0.0240 0.0 .025 96.0 63-129 1676220-01 WG700059
Chloromethane mg/1 0.0247 0.0 .025 99.0 42.4-135 1676220-01 W0700059
cis-1,2-Dichloroethene mg/1 0.0237 0.0 .025 95.0 59.2-129 L676220-01 1G700059
Di -isopropyl ether mg/1 0.0236 0.0 .025 94.0 56.9-136 1676220-01 WG700059
Dibromomethane mg/1 0.0242 0.0 .025 97.0 68.2-124 1676220-01 WG700059
Dichlorodifluoromethane mg/1 0.0276 0.0 .025 110. 40.6-144 L676220-01 WG700059
Ethylbenzene mg/1 0.0238 0.0 .025 95.0 61.4-133 1676220-01 WG700059
Eexachloro-1,3-butadiene mg/1 0.0236 0.0 .025 94.0 55.1-136 L676220-01 WG700059
Isopropylbenzene mg/1 0.0253 0.0 .025 100. 66.8-141 L676220-01 WG700059
m&p-Xylenes mg/1 0.0463 0.00 .05 92.6 61.7-133 1676220-01 WG700059
Methyl tert-butyl ether mg/1 0.0219 0.0 .025 88.0 57.7-134 L676220-01 WG700059
Methylene Chloride mg/1 0.0212 0.0 .025 85.0 58.1-122 L676220-01 WG700059
n-Butylbenzene mg/1 0.0270 0.0 .025 110. 62.7-140 L676220-01 WG700059
n-Propylbenzene mg/1 0.0236 0.0 .025 94.0 65.9-131 1676220-01 WG700059
Naphthalene mg/1 0.0254 0.0 .025 100. 58-135 1676220-01 WG700059
o-Xylene mg/1 0.0225 0.00 .025 90.2 63.3-130 1676220-01 WG700059
p-Isopropyltoluene mg/1 0.0230 0.0 .025 92.0 63.2-139 L676220-01 WG700059
sec-Butylbenzene mg/1 0.0228 0.0 .025 91.0 62.2-136 1676220-01 WG700059
Styrene mg/1 0.0246 0.0 .025 99.0 66.8-133 L676220-01 WG700059
tert-Butylbenzene mg/1 0.0224 0.0 .025 90.0 63.3-134 L676220-01 WG700059
Tetrachloroethene mg/1 0.0253 0.0 .025 100. 53-139 L676220-01 WG700059
Toluene mg/1 0.0239 0.0 .025 96.0 61.4-130 1676220-01 WG700059
trans-1,2-Dichloroethene mg/1 0.0236 0.0 .025 95.0 56.5-129 L676220-01 WG700059
Trichloroethene mg/1 0.0244 0.0 .025 98.0 44.1-149 L676220-01 WG700059
Trichlorofluoromethane mg/1 0.0279 0.0 .025 110. 49.6-145 L676220-01 WG700059
Vinyl chloride mg/1 0.0275 0.0 .025 110. 47.8-137 L676220-01 WG700059
4-Bromofluorobenzene 90.70 71-126 WG700059
Dibromofluoromethane 96.60 78.3-121 WG700059
Toluene-d8 99.10 88.5-111 WG700059
a,a,a-Trifluorotoluene 94.30 85-114 WG700059
" Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 41 of 49

II I

ESC
L-ALB 6-C.€•E •AI,:1-E•S
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Raleigh, NC 27615
Quality Assurance Report
Level II
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08, 2014
Analyte
Matrix Spike
Units MS Res Ref Res TV 8 Rec
Limit
Ref Swop Batch
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-Chloropropane
1,2-Dihromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEKf
2-Chlorotoluene
4-Chlorotoluene
4-Methy1-2-pentanone (MIRK)
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
Di -isopropyl ether
Dihromomethane
Dichlorodifluoromethane
Ethylbenzene
Eexachloro-1,3-butadiene
Isopropylbenzene
m&p-xylenes
Methyl tent -butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
p-Isopropyitoluene
sec-Butylbenzene
Styrene
tent-Butylbenzene
Tetrachloroethene
Toluene
* Performance of this Analyte
For additional information,
mg/1 0.0207 0.0 .025
mg/1 0.0225 0.0 .025
mg/1 0.0195 0.0 .025
mg/1 0.0219 0.0 .025
mg/1 0.0219 0.0 .025
mg/1 0.0255 0.0 .025
mg/1 0.0221 0.0 .025
mg/1 0.0259 0.0 .025
mg/1 0.0209 0.0 .025
mg/1 0.0260 0.0 .025
mg/1 0.0255 0.00476 .025
mg/1 0.0202 0.0 .025
mg/1 0.0201 0.0 .025
mg/1 0.0208 0.0 .025
mg/1 0.0208 0.0 .025
mg/1 0.0195 0.0 .025
mg/1 0.0217 0.0 .025
mg/1 0.0218 0.0 .025
mg/1 0.0199 0.0 .025
mg/1 0.0213 0.0 .025
mg/1 0.0239 0.0 .025
mg/1 0.0722 0.0 .125
mg/1 0.0216 0.0 .025
mg/1 0.0211 0.0 .025
mg/1 0.0937 0.0 .125
mg/1 0.0558 0.00159 .125
mg/1 0.0959 0.0 .125
mg/1 0.104 0.0 .125
mg/1 0.0241 0.00242 .025
mg/1 0.0197 0.0 .025
mg/1 0.0187 0.0 .025
mg/1 0.0195 0.0 .025
mg/1 0.0269 0.0 .025
mg/1 0.0203 0.0 .025
mg/1 0.0211 0.0 .025
mg/1 0.0199 0.0 .025
mg/1 0.0266 0.0 .025
mg/1 0.0219 0.0 .025
mg/1 0.0194 0.0 .025
mg/1 0.0223 0.0 .025
mg/1 0.0205 0.0 .025
mg/1 0.0200 0.0 .025
mg/1 0.0208 0.0 .025
mg/1 0.0218 0.0 .025
mg/1 0.0223 0.0 .025
mg/1 0.0306 0.00750 .025
mg/1 0.0431 0.00 .05
mg/1 0.0218 0.00110 .025
mg/1 0.0216 0.0 .025
mg/1 0.0233 0.00212 .025
mg/1 0.0209 0.0 .025
mg/1 0.0598 0.0344 .025
mg/1 0.0228 0.00118 .025
mg/1 0.0223 0.0 .025
mg/1 0.0278 0.00638 .025
mg/1 0.0219 0.0 .025
mg/1 0.0218 0.0 .025
mg/1 0.0229 0.000987 .025
mg/1 0.0200 0.0 .025
is outside of established criteria.
please see Attachment A 'List of Analytes
Page 42 of 49
83.0
90.0
78.0
88.0
88.0
100.
88.0
100.
84.0
100.
83.0
81.0
80.0
83.0
83.0
78.0
87.0
87.0
80.0
85.0
96.0
58.0
86.0
84.0
75.0
43.0
77.0
84.0
87.0
79.0
75.0
78.0
110.
81.0
84.0
80.0
110.
88.0
78.0
89.0
82.0
80.0
83.0
87.0
89.0
92.0
86.2
83.0
86.0
85.0
84.0
100.
86.3
89.0
86.0
87.0
87.0
88.0
80.0
64-128
58.7-134
56-132
66.3-125
58 . 5-132
51.1-140
57.3-136
59. 1-13 8
61.4-128
63 . 6-143
57.4-137
57.3-136
67 . 1-125
68.2-123
60-126
64.2-123
63 . 6-132
63 . 1-131
67.9-121
68 . 6-123
50.5-144
22.4-138
63 . 6-128
65.7-127
60.8-140
10-130
10-200
49.4-133
54.3-133
63.9-124
63.9-121
59.5-134
41.7-155
55.7-134
67-125
64.3-125
51.5-136
63-129
42.4-135
59.2-129
56.9-136
68.2-124
40.6-144
61.4-133
55.1-136
66.8-141
61.7-133
57.7-134
58 . 1-122
62.7-140
65.9-131
58-135
63.3-130
63.2-139
62.2-136
66.8-133
63.3-134
53-139
61.4-130
with QC Qualifiers.'
1676786-04
L676786-04
167 678 6-04
L 67 6 78 6-0 4
1 67 678 6-04
L676786-04
L 67 6 78 6-0 4
1676786-04
1676786-04
1 67 678 6-04
L676786-04
1 67 678 6-04
L676786-04
1 67 678 6-04
1676786-04
L 67 678 6-04
1676786-04
1676786-04
1676786-04
1676786-04
1676786-04
1 67 678 6-04
1676786-04
167 678 6-04
1676786-04
1 67 678 6-04
1 67 678 6-04
1676786-04
L676786-04
L676786-04
1676786-04
1676786-04
1 67678 6-04
1676786-04
1 67678 6-04
1 67678 6-04
1 67678 6-04
1 67678 6-04
1676786-04
1676786-04
1 67678 6-04
1 67678 6-04
1 67678 6-04
1676786-04
L676786-04
1676786-04
1676786-04
1 67 678 6-04
1676786-04
1 67 678 6-04
1 67 678 6-04
1 67 678 6-04
1 67 678 6-04
1 67 678 6-04
1676786-04
1676786-04
1676786-04
1 67 678 6-04
1676786-04
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
1G700493
WG700493
WG700493
WG700493
1G700493
WG700493
WG700493
WG700493
WG700493
WG700493
9G700493
1c700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
w4700493
wG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
WG700493
W G700493
WG700493
WG700493

1 '1

OESC
L-A,S•T.i.E•N.Et-E•S
EMEREEEICIMINES
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Raleigh, NC 27615
Quality Assurance Report
Level II
L676247
12065 Lebanon Rd.
Mt. Juliet, TA 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 08, 2014
Analyte
Matrix Spike
Units MS Res Ref Res TV S Rec
Limit
Ref Samp Batch
trans-1,2-Dichloroethene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromo£luorobenzene
Dibromofluoromethane
Toluene-d8
a, a, a-Trifluorotoluene
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-Chlorapropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEKM
2-Chlorotoluene
4-Chlorotoluene
4-Methy1-2-pentanone (MIRK)
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
8romodicbloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
Di -isopropyl ether
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Bexachloro-1,3-butadiene
Isopropylbenzene
map-Xylenes
Methyl tert-butyl ether
Methylene Chloride
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
0.0228
0.0203
0.0275
0.0227
0.0219
0.0233
0.0219
0.0228
0.0222
0.0253
0.0225
0.0254
0.0232
0.0267
0.0238
0.0221
0.0219
0.0224
0.0216
0.0204
0.0246
0.0243
0.0218
0.0231
0.0237
0.0861
0.0238
0.0235
0.104
0.0688
0.112
0.123
0.0224
0.0217
0.0191
0.0217
0.0260
0.0226
0.0228
0.0216
0.0245
0.0224
0.0195
0.0224
0.0206
0.0214
0.0221
0.0236
0.0240
0.0254
0.0468
0.0216
0.0226
0.0
0.0
0.0
0.0
0.0
0.0
0.000355
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.00142
0.0
0.0
0.0
0.0
0.0
0.000427
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.00
0.0
0.0
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.125
.025
.025
.125
.125
.125
.125
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.025
.05
.025
.025
91.0
81.0
110.
91.0
99.90
107.0
104.0
94.00
88.0
93.0
86.0
91.0
89.0
100.
90.0
100.
93.0
110.
95.0
88.0
88.0
90.0
86.0
76.0
98.0
97.0
67.0
92.0
95.0
69.0
95.0
94.0
83.0
55.0
89.0
98.0
90.0
87.0
77.0
87.0
100.
90.0
91.0
86.0
98.0
90.0
78.0
90.0
82.0
86.0
68.0
95.0
96.0
100.
93.5
86.0
90.0
56.5-129
44.1-149
49. 6-145
47.8-137
71-126
78.3-121
88.5-111
85-114
64-128
58.7-134
56-132
66.3-125
58.5-132
51.1-140
57.3-136
59. 1-138
61.4-128
63 . 6-143
57.4-137
57.3-136
67.1-125
68 . 2-123
60-126
64.2-123
63.6-132
63.1-131
67.9-121
68 . 6-123
50.5-144
22.4-138
63 . 6-128
65.7-127
60.8-140
10-130
10-200
49.4-133
54.3-133
63 . 9-124
63.9-121
59.5-134
41.7-155
55.7-134
67-125
64.3-125
51.5-136
63-129
42.4-135
59.2-129
56.9-136
68.2-124
40.6-144
61.4-133
55.1-136
66.8-141
61.7-133
57.7-134
58 . 1-122
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 43 of 49
L 67 678 6-04
L 67 678 6-04
L 67 678 6-04
L676786-04
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
L676330-01
8G700493
8G700493
8G700493
8G700493
1G700493
WG700493
8G700493
8G700493
WG700132
8G700132
8G700132
WG700132
WG700132
WG700132
WG700132
8G700132
WG700132
WG700132
WG700132
WG700132
8G700132
WG700132
8G700132
8G700132
8G700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
WG700132
8G700132
WG700132
wG700132
WG700132
WG700132
8G700132
WG700132
8G700132
8G700132
1G700132
WG700132
1G700132
1G700132
1G700132
8G700132
1G700132
8G700132
WG700132
1G700132
wG700132
8G700132
1G700132
8G700132

I
i

OESC
L•A.4•€•E•AE•G S
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859 '
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Analyte
Matrix Spike
Units MS Res Ref Res TV 6 Rec Limit Ref Sam.• Batch
n-Butylbenzene mg/1 0.0244 0.0 .025 98.0 62.7-140 L676330-01 WG700132
n-Propylbenzene mg/1 0.0235 0.0 .025 94.0 65.9-131 L676330-01 WG700132
Naphthalene mg/1 0.0235 0.0 .025 94.0 58-135 5676330-01 WG700132
o-Xylene mg/1 0.0228 0.00 .025 91.2 63.3-130 5676330-01 WG700132
p-Isopropyltoluene mg/1 0.0261 0.0 .025 100. 63.2-139 L676330-01 WG700132
sec-Butylbenzene mg/1 0.0254 0.0 .025 100. 62.2-136 L676330-01 WG700132
Styrene mg/1 0.0238 0.0 .025 95.0 66.8-133 5676330-01 WG700132
tert-Butylbenzene mg/1 0.0247 0.0 .025 99.0 63.3-134 L676330-01 WG700132
Tetrachloroethene mg/1 0.0235 0.0 .025 94.0 53-139 L676330-01 WG700132
Toluene mg/1 0.0211 0.0 .025 84.0 61.4-130 5676330-01 WG700132
trans-1,2-Dichloroethene mg/1 0.0236 0.0 .025 94.0 56.5-129 L676330-01 WG700132
Trichloroethene mg/1 0.0211 0.0 .025 84.0 44.1-149 L676330-01 WG700132
Trichlorofluoromethane mg/1 0.0279 0.0 .025 110. 49.6-145 L676330-01 WG700132
Vinyl chloride mg/1 0.0223 0.0 .025 89.0 47.8-137 L676330-01 WG700132
4-Bromafluorobenzene 102.0 71-126 WG700132
Dibramofluoromethane 105.0 78.3-121 WG700132
Toluene-d8 105.0 88.5-111 WG700132
a,a,a-Trifluorotoluene 91.80 85-114 WG700132
Analyte
Matrix Spike Duplicate
Units MSD Ref $Rec
Limit
RPD Limit Ref Scamp Batch
Lead
mg/1 1.04 1.05 98.1 75-125 1.00 20 5676247-01 WG699922
1,1,1,2-Tetrachloroethane mg/1 0.0216 0.0223 86.2 64-128 3.61 20 5676220-01 WG700059
1,1,1-Trichloroethane mg/1 0.0237 0.0245 95.0 58.7-134 3.07 20 5676220-01 WG700059
1,1,2,2-Tetrachloroethane mg/1 0.0223 0.0217 89.4 56-132 2.73 22.2 L676220-01 WG700059
1,1,2-Trichloroethane mg/1 0.0234 0.0240 93.8 66.3-125 2.52 20 1.676220-01 WG700059
1,1-Dichloroethane mg/1 0.0229 0.0241 91.7 58.5-132 4.82 20 5676220-01 WG700059
1,1-Dichloroetbene mg/1 0.0265 0.0282 106. 51.1-140 6.21 20.2 5676220-01 WG700059
1,1-Dichloropropene mg/1 0.0247 0.0261 99.0 57.3-136 5.32 20 5676220-01 WG700059
1,2,3-Trichlorobenzene mg/1 0.0247 0.0249 98.9 59.1-138 0.530 23.7 5676220-01 WG700059
1,2,3-Trichloropropane mg/1 0.0226 0.0214 90.5 61.4-128 5.59 22.4 5676220-01 WG700059
1,2,4-Trich1orobenzene mg/1 0.0264 0.0266 106. 63.6-143 0.910 21.9 5676220-01 WG700059
1,2,4-Trimethylbenzene mg/1 0.0208 0.0217 83.3 57.4-137 4.29 20 5676220-01 WG700059
1,2-Dibromo-3-Chloropropane mg/1 0.0283 0.0267 113. 57.3-136 5.70 27 L676220-01 WG700059
1,2-Dibromaethane mg/1 0.0243 0.0244 97.1 67.1-125 0.540 20 5676220-01 WG700059
1,2-Dichlorobenzene mg/1 0.0242 0.0244 96.8 68.2-123 0.890 20 5676220-01 WG700059
1,2-Dichloroethane mg/1 0.0249 0.0247 99.5 60-126 0.490 20 5676220-01 WG700059
1,2-Dichloropropane mg/1 0.0224 0.0234 89.6 64.2-123 4.36 20 5676220-01 WG700059
1,3,5-Trimethylbenzene mg/1 0.0219 0.0226 87.6 63.6-132 3.14 20.5 5676220-01 WG700059
1,3-Dichlorobenzene mg/1 0.0225 0.0227 89.9 63.1-131 1.05 20 5676220-01 WG700059
1,3-Dichloropropane mg/1 0.0239 0.0244 95.6 67.9-121 1.90 20 5676220-01 WG700059
1,4-Dichlorobenzene mg/1 0.0230 0.0239 91.8 68.6-123 4.11 20 5676220-01 WG700059
2,2-Dichloropropane mg/1 0.0243 0.0249 97.2 50.5-144 2.25 21.9 5676220-01 WG700059
2-Butanone (84EK} mg/1 0.111 0.0973 88.6 22.4-138 12.9 27 L676220-01 WG700059
2-Chlorotoluene mg/1 0.0208 0.0215 83.3 63.6-128 3.28 20 5676220-01 WG700059
4-Chlorotoluene mg/1 0.0218 0.0222 87.2 65.7-127 1.95 20 5676220-01 WG700059
4-Methy1-2-pentanone (MIBK) mg/1 0.138 0.127 110. 60.8-140 8.42 25.1 L676220-01 WG700059
Acetone mg/1 0.0664 0.0620 52.2 10-130 6.89 27.9 5676220-01 WG700059
Acrolein mg/1 0.232 0.218 185. 10-200 6.27 27.7 5676220-01 WG700059
Acrylonitrile mg/1 0.134 0.129 107. 49.4-133 3.75 25.3 5676220-01 WG700059
Benzene mg/1 0.0236 0.0242 94.4 54.3-133 2.27 20 5676220-01 WG700059
Bromobenzene mg/1 0.0215 0.0224 85.8 63.9-124 4.47 20 5676220-01 WG700059
Bromodichloromethane mg/1 0.0219 0.0223 87.5 63.9-121 1.91 20 L676220-01 WG700059
Bromoform mg/1 0.0236 9.0231 94.6 59.5-134 2.25 20.5 L676220-01 WG700059
Bromomethane mg/1 0.0264 0.0269 105. 41.7-155 2.16 21.9 5676220-01 99700059
Carbon tetrachloride mg/1 0.0242 0.0250 96.6 55.7-134 3.32 20 L676220-01 WG700059
t Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 44 of 49

1

ilESC
L•A flk +Ca•Tr• •E•A(•G',,•c•8
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
IMECEIEMITEMEEI Est. 1970
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive Quality Assurance Report
Raleigh, BC 27615
Level II
L676247
January 08, 2014
Analyte
Matrix Spike Duplicate
Units MSD Ref %Rec
Limit
RPD Limit Ref Swop Batch
Chlorobenzene mg/1 0.0225 0.0235 90.0 67-125 4.41 20 1676220-01 WG700059
Chlorodibromomethane mg/1 0.0227 0.0229 90.6 64.3-125 1.10 20.8 1676220-01 WG700059
Chloroethane mg/1 0.0256 0.0274 102. 51.5-136 6.78 40 1676220-01 WG700059
Chloroform mg/1 0.0231 0.0240 92.5 63-129 3.68 20 1676220-•01 WG700059
Chloromethane mg/1 0.0234 0.0247 93.6 42.4-135 5.38 20 1676220-01 WG700059
cis-1,2-Dichloroethene mg/1 0.0232 0.0237 92.8 59.2-129 2.06 20 1676220-01 WG700059
Di -isopropyl ether mg/I 0.0231 0.0236 92.6 56.9-136 2.02 20 1676220-01 WG700059
Dibromomethane mg/1 0.0248 0.0242 99.4 68.2-124 2.68 20 1676220-01 WG700059
Dichlorodifluoromethane mg/1 0.0252 0.0276 101. 40.6-144 9.22 20.2 1676220-01 WG700059
Ethylbenzene mg/1 0.0228 0.0238 91.1 61.4-133 4.43 20 2676220-01 WG700059
Hexaehloro-1,3-butadiene mg/1 0.0234 0.0236 93.5 55.1-136 0.900 23.6 1676220-01 WG700059
Isopropylbenzene mg/1 0.0239 0.0253 95.7 66.8-141 5.55 20 1676220-01 WG700059
o6p-Xy1enes mg/1 0.0434 0.0463 86.8 61.7-133 6.39 20 1676220-01 WG700059
Methyl tert-butyl ether mg/1 0.0225 0.0219 89.9 57.7-134 2.67 20 L676220-01 WG700059
Methylene Chloride mg/1 0.0205 0.0212 82.2 58.1-122 2.94 20 L676220-01 WG700059
n-Buty1be6zene mg/1 0.0258 0.0270 103. 62.7-140 4.30 20.3 1676220-01 WG700059
n-Propylbenzene mg/1 0.0226 0.0236 90.5 65.9-131 4.09 20 1676220-01 WG700059
Naphthalene mg/1 0.0258 0.0254 103. 58-135 1.48 25.5 1676220-01 WG700059
o-Xylene mg/1 0.0216 0.0225 86.2 63.3-130 4.46 20 1676220-01 WG700059
p-Isopropyltoluene mg/1 0.0228 0.0230 91.2 63.2-139 0.790 20.4 1676220-01 WG700059
sec-Butylbenzene mg/1 0.0223 0.0228 89.4 62.2-136 1.89 20.3 1676220-01 WG700059
Styrene mg/1 0.0233 0.0246 93.1 66.8-133 5.71 20 1676220-01 WG700059
tert-Butylbenzene mg/1 0.0219 0.0224 87.5 63.3-134 2.23 21 1676220-01 WG700059
Tetrachloroethene mg/1 0.0234 0.0253 93.4 53-139 7.86 20 1676220-01 WG700059
Toluene mg/1 0.0230 0.0239 92.1 61.4-130 3.75 20 1676220-01 WG700059
trans-1,2-Dichloroethene mg/1 0.0228 0.0236 91.2 56.5-129 3.67 20 1676220-01 WG700059
Trichloroethene mg/1 0.0232 0.0244 93.0 44.1-149 4.80 20 1676220-01 WG700059
Trichlorofluoromethane mg/1 0.0256 0.0279 102. 49.6-145 8.67 21.2 1676220-01 WG700059
vinyl chloride mg/1 0.0255 0.0275 102. 47.8-137 7.45 20 1676220-01 WG700059
4-Bromofluorobenzene 90.10 71-126 WG700059
Dibromofluoromethane 100.0 78.3-121 WG700059
Toluene-d8 99.60 88.5-111 WG700059
a,a,a-Trifluorotoluene 93.30 85-114 WG700059
1,1,1,2-Tetrachloroethane mg/1 0.0215 0.0207 85.9 64-128 3.82 20 1676786-04 WG700493
1,1,1-Trichloroethane mg/1 0.0238 0.0225 95.2 58.7-134 5.81 20 1676786-04 WG700493
1,1,2,2-Tetrachloroethane 1119/1 0.0217 0.0195 86.7 56-132 10.8 22.2 1676786-04 WG700493
1,1,2-Trichloroethane mg/1 0.0229 0.0219 91.4 66.3-125 4.36 20 1676786-04 WG700493
1,1-Dichloroethene mg/1 0.0227 0.0219 90.9 58.5-132 3.61 20 1676786-04 WG700493
1,1-Dichloroethene mg/1 0.0259 0.0255 103. 51.1-140 1.47 20.2 1676786-04 WG700493
1,1-Dichloropropene mg/1 0.0231 0.0221 92.3 57.3-136 4.28 20 1676786-04 WG700493
1,2,3-Trichlorobenzene mg/1 0.0237 0.0259 94.9 59.1-138 8.73 23.7 1676786-04 WG700493
1,2,3-Trichlaropropane mg/1 0.0230 0.0209 91.8 61.4-128 9.41 22.4 1676786-04 WG700493
1,2,4-Trich1orobenzene mg/1 0.0242 0.0260 97.0 63.6-143 6.84 21.9 1676786-04 WG700493
1,2,4-Trimethylbenzene mg/1 0.0278 0.0255 92.0 57.4-137 8.37 20 1676786-04 WG700493
1,2-Dibromo-3-Chloropropane mg/1 0.0220 0.0202 88.2 57.3-136 8.60 27 1676786-04 WG700493
1,2-Dibromoethane mg/1' 0.0211 0.0201 84.4 67.1-125 4.76 20 1676786-04 WG700493
1,2-Dichlorobenzene mg/1 0.0215 0.0208 85.9 68.2-123 3.33 20 1676786-04 WG700493
1,2-Dichloroethane 1119/1 0.0220 0.0208 87.9 60-126 5.36 20 1676786-04 WG700493
1,2-Dichloropropane mg/1 0.0206 0.0195 82.2 64.2-123 5.12 20 1676786-04 WG700493
1,3,5-Trimethylbenzene mg/1 0.0238 0.0217 95.2 63.6-132 9.19 20.5 1676786-04 WG700493
1,3-Dichlorobenzene mg/1 0.0232 0.0218 92.9 63.1-131 6.22 20 1676786-04 WG700493
1,3-Dichloropropane mg/1 0.0209 0.0199 83.6 67.9-121 4.85 20 1676786-04 WG700493
1,4-Dichlorobenzene mg/1 0.0223 0.0213 89.3 68.6-123 4.77 20 1676786-04 WG700493
2,2-Dichloroprapane mg/1 0.0249 0.0239 99.7 50.5-144 4.15 21.9 1676786-04 WG700493
2-Butanone (MEI() mg/1 0.0889 0.0722 71.1 22.4-138 20.7 27 1676786-04 816700493
2-Chlorotoluene mg/1 0.0230 0.0216 92.0 63.6-128 6.33 20 1676786-04 WG700493
4-Chlorotoluene mg/1 0.0227 0.0211 90.8 65.7-127 7.27 20 1676786-04 816700493
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 45 of 49

i
1
ti

ESC
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615( 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Analyte
Matrix Spike Duplicate
Units MSD Ref 4Rec
Limit
RPD Limit Ref Samp Batch
4-Methyl-2-pentanone (MIBK) mg/1 0.107 0.0937 85.5 60.8-140 13.1 25.1 L676786-04 WG700493
Acetone mg/1 0.0722 0.0558 56.5 10-130 25.6 27.9 1676786-04 WG700493
Acrolein mg/1 0.126 0.0959 101. 10-200 27.4 27.7 1676786-04 WG700493
Acrylonitrile mg/1 0.128 0.104 103. 49.4-133 20.6 25.3 1676786-04 WG700493
Benzene mg/1 0.0254 0.0241 91.8 54.3-133 5.10 20 1676786-04 WG700493
Bromobenzene mg/1 0.0210 0.0197 83.8 63.9-124 6.39 20 1676786-04 WG700493
Bromodichloromethane mg/1 0.0196 0.0187 78.2 63.9-121 4.73 20 L676786-04 WG700493
Bromoform mg/1 0.0226 0.0195 90.4 59.5-134 14.8 20.5 1.676786-04 WG700493
Bromomethane mg/1 0.0273 0.0269 109. 41.7-155 1.64 21.9 1.676786-04 WG700493
Carbon tetrachloride mg/1 0.0230 0.0203 92.0 55.7-134 12.5 20 L676786-04 WG700493
Chlorobenzene mg/1 0.0218 0.0211 87.1 67-125 3.21 20 1.676786-04 WG700493
Chlorodibromomethane mg/1 0.0208 0.0199 83.2 64.3-125 4.27 20.8 L676786-04 WG700493
Chloroethane mg/1 0.0261 0.0266 104. 51.5-136 1.99 40 1676786-04 WG700493
Chloroform mg/1 0.0232 0.0219 92.8 63-129 5.68 20 1.676786-04 WG700493
Chloromethane mg/1 0.0198 0.0194 79.2 42.4-135 2.26 20 1676786-04 WG700493
cis-1,2-Dichloroethene mg/1 0.0234 0.0223 93.5 59.2-129 4.68 20 L676786-04 WG700493
Di -isopropyl ether mg/1 0.0219 0.0205 87.5 56.9-136 6.76 20 L676786-04 WG700493
Dibromomethane mg/1 0.0217 0.0200 86.9 68.2-124 8.13 20 1676786-04 WG700493
Dichlorodifluoromethane mg/1 0.0217 0.0208 86.9 40.6-144 4.53 20.2 L676786-04 WG700493
Ethylbenzene mg/1 0.0225 0.0218 90.1 61.4-133 3.25 20 1676786-04 WG700493
Hexachloro-1,3-butadiene mg/1 0.0211 0.0223 84.4 55.1-136 5.60 23.6 L676786-04 WG700493
Isopropylbenzene mg/1 0.0321 0.0306 98.5 66.8-141 5.00 20 1676786-04 WG700493
map-Xylenes mg/1 0.0446 0.0431 89.1 61.7-133 3.33 20 1676786-04 WG700493
Methyl tert-butyl ether mg/1 0.0240 0.0218 91.5 57.7-134 9.53 20 1676786-04 WG700493
Methylene Chloride mg/1 0.0228 0.0216 91.0 58.1-122 5.24 20 L676786-04 WG700493
n-Butylbenzene mg/1 0.0255 0.0233 93.6 62.7-140 8.90 20.3 1676786-04 WG700493
n-Propylbenzene mg/1 0.0225 0.0209 89.8 65.9-131 7.27 20 1676786-04 WG700493
Naphthalene mg/1 0.0576 0.0598 92.6 58-135 3.79 25.5 1676786-04 WG700493
o-Xylene mg/1 0.0228 0.0228 86.6 63.3-130 0.370 20 1676786-04 WG700493
p-Isopropyltoluene mg/1 0.0250 0.0223 100. 63.2-139 11.6 20.4 L676786-04 WG700493
sec-Butylbenzene m9/1 0.0311 0.0278 98.7 62.2-136 11.1 20.3 1676786-04 WG700493
Styrene mg/1 0.0227 0.0219 90.7 66.8-133 3.72 20 1676786-04 WG700493
tert-Butylbenzene mg/1 0.0240 0.0218 96.0 63.3-134 9.72 21 1676786-04 WG700493
Tetrachloroethene mg/1 0:0228 0.0229 87.2 53-139 0.690 20 1676786-04 WG700493
Toluene mg/1 0.0213 0.0200 85.2 61.4-130 6.16 20 1676786-04 WG700493
trans-1,2-Dichloroethene mg/1 0.0235 0.0228 94.0 56.5-129 2.97 20 L676786-04 WG700493
Trichloroethene mg/1 0.0210 0.0203 83.8 44.1-149 2.98 20 1676786-04 WG700493
Trichlorofluoromethane mg/1 0.0276 0.0275 110. 49.6-145 0.230 21.2 1676786-04 WG700493
Vinyl chloride m9/1 0.0228 0.0227 91.0 47.0-137 0.340 20 1676786-04 WG700493
4-Bromofluorobenzene 101.0 71-126 WG700493
Dibromofluoromethane 108.0 78.3-121 WG700493
Toluene-d8 106.0 88.5-111 WG700493
a,a,a-Trifluorotoluene 93.00 85-114 WG700493
1,1,1,2-Tetrachloroethane mg/1 0.0197 0.0219 78.8 64-128 10.7 20 1676330-01 WG700132
1,1,1-Trichloroethane mg/1 0.0220 0.0233 87.9 58.7-134 5.91 20 1676330-01 WG700132
1,1,2,2-Tetrachloroethane mg/1 0.0196 0.0219 77.0 56-132 11.2 22.2 1676330-01 WG700132
1,1,2-Trichloroethane mg/1 0.0211 0.0228 84.6 66.3-125 7.72 20 1676330-01 WG700132
1,1-Dichloroethane mg/1 0.0210 0.0222 83.8 58.5-132 5.62 20 1676330-01 WG700132
1,1-Dichloroethene mg/1 0.0244 0.0253 97.7 51.1-140 3.58 20.2 1676330-01 WG700132
1,1-Dichloropropene mg/1 0.0220 0.0225 87.8 57.3-136 2.38 20 1676330-01 WG700132
1,2,3-Trichlorobenzene mg/1 0.0221 0.0254 88.6 59.1-138 13.7 23.7 1676330-01 WG700132
1,2,3-Trichloropropane mg/1 0.0207 0.0232 82.9 61.4-128 11.3 22.4 1676330-01 WG700132
1,2,4-Trichlorobenzene mg/1 0.0228 0.0267 91.2 63.6-143 15.6 21.9 L676330-01 WG700132
1,2,4-Trimethylbenzene mg/1 0.0205 0.0238 81.8 57.4-137 15.1 20 1676330-01 WG700132
1,2-Dibromo-3-Chloropropane mg/1 0.0202 0.0221 80.9 57.3-136 8.66 27 L676330-01 WG700132
1,2-Dibromoethane mg/1 0.0203 0.0219 81.2 67.1-125 7.84 20 1676330-01 WG700132
1,2-Dichlorobenzene mg/1 0.0206 0.0224 82.4 68.2-123 8.29 20 1676330-01 WG700132
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 46 of 49

I

40ESC
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Analyte
Matrix Spike Duplicate
Units MSD Ref %Rec Limit RFD Limit Ref Samp Batch
1,2-Dichloroethane mg/1 0.0209 0.0216 83.7 60-126 3.16 20 1676330-01 WG700132
1,2-Dichloropropane mg/1 0.0184 0.0204 67.9 64.2-123 10.2 20 1676330-01 WG700132
1,3,5-Trimethylbenzene mg/1 0.0211 0.0246 84.4 63.6-132 15.4 20.5 1676330-01 WG700132
1,3-Dichlorobenzeue mg/1 0.0212 0.0243 84.8 63.1-131 13.5 20 1676330 01 WG700132
1,3-Dichloropropane mg/1 0.0203 0.0218 81.0 67.9-121 7.34 20 1676330-01 WG700132
1,4-Dichlorobenzene mg/1 0.0213 0.0231 85.1 68.6-123 8.14 20 1676330-01 WG700132
2,2-Dichloropropene mg/1 0.0231 0.0237 92.4 50.5-144 2.52 21.9 1676330-01 WG700132
2-Butanone (MEK) mg/1 0.0756 0.0861 60.1 22.4-138 13.1 27 1676330-01 WG700132
2-Chlorotoluene mg/1 0.0207 0.0236 62.9 63.6-128 14.0 20 1676330-01 WG700132
4-Chlorotoluene mg/1 0.0211 0.0235 84.4 65.7-127 10.7 20 1676330-01 WG700132
4-Methy1-2-pentanone (MIRK) mg/1 0.0942 0.104 75.3 60.8-140 9.93 25.1 L676330-01 WG700132
Acetone mg/1 0.0566 0.0688 45.2 10-130 19.6 27.9 1676330-01 WG700132
Acrolein mg/1 0.0992 0.112 79.4 10-200 11.8 27.7 1676330-01 WG700132
Acrylonitrile mg/1 0.106 0.123 84.9 49.4-133 14.7 25.3 1676330-01 WG700132
Benzene mg/1 0.0212 0.0224 84.9 54.3-133 5.35 20 1676330-01 WG700132
Bromobenzene mg/1 0.0194 0.0217 77.8 63.9-124 10.8 20 1676330-01 WG700132
Bromodichloromethane mg/1 0.0180 0.0191 71.9 63.9-121 6.33 20 1676330-01 WG700132
Bromoform mg/1 0.0195 0.0217 77.9 59.5-134 11.0 20.5 1676330-01 WG700132
Bromomethane mg/1 0.0267 0.0260 107. 41.7-155 2.42 21.9 1676330-01 WG700132
Carbon tetrachloride mg/1 0.0204 0.0226 81.4 55.7-134 10.5 20 L676330-01 WG700132
Chlorobenzene mg/1 0.0205 0.0228 82.1 67-125 10.6 20 1676330-01 WG700132
Chlorodibromomethane mg/1 0.0194 0.0216 77.6 64.3-125 10.6 20.8 L676330-01 WG700132
Chloroethane mg/1 0.0257 0.0245 103. 51.5-136 4.79 40 1676330-01 066700132
Chloroform mg/1 0.0214 0.0224 85.8 63-129 4.29 20 1676330-01 WG700132
Chloromethane mg/1 0.0196 0.0195 78.3 42.4-135 0.250 20 1676330-01 WG700132
cis-1,2-Dichloroethene mg/1 0.0216 0.0224 86.5 59.2-129 3.73 20 L676330-01 WG700132
Di -isopropyl ether mg/1 0.0197 0.0206 79.0 56.9-136 4.04 20 1676330-01 WG700132
Dibromomethane mg/1 0.0205 0.0214 81.8 68.2-124 4.40 20 L676330-01 WG700132
Dichlorodifluoromethane mg/1 0.0213 0.0221 85.4 40.6-144 3.53 20.2 L676330-01 WG700132
Ethylbenzene mg/1 0.0212 0.0236 84.9 61.4-133 10.8 20 L676330-01 066700132
Bexachloro-1,3-butadiene mg/1 0.0199 0.0240 79.6 55.1-136 18.8 23.6 L676330-01 WG700132
Isopropylbenzene mg/1 0.0226 0.0254 90.4 66.8-141 11.7 20 L676330-01 WG700132
m&p-Xylenes mg/1 0.0415 0.0468 82.9 61.7-133 12.0 20 1676330-01 WG700132
Methyl tert-butyl ether mg/1 0.0206 0.0216 82.6 57.7-134 4.67 20 L676330-01 WG700132
Methylene Chloride mg/1 0.0214 0.0226 85.4 58.1-122 5.50 20 L676330-01 WG700132
n-Butylbenzene mg/1 0.0212 0.0244 84.8 62.7-140 14.2 20.3 1676330-01 WG700132
n-Propylbenzene mg/1 0.0207 0.0235 83.0 65.9-131 12.5 20 1676330-01 WG700132
Naphthalene 18g/1 0.0214 0.0235 85.6 58-135 9.33 25.5 1676330-01 WG700132
o-Xylene mg/1 0.0206 0.0228 82.6 63.3-130 9.92 20 1676330-01 WG700132
p-Isopropyltoluene mg/1 0.0219 0.0261 87.6 63.2-139 17.6 20.4 1676330-01 WG700132
sec-8utylbenzene mg/1 0.0215 0.0254 85.8 62.2-136 16.9 20.3 1676330-01 WG700132
Styrene mg/1 0.0212 0.0238 84.8 66.8-133 11.5 20 1676330-01 WG700132
tert-Butylbenzene mg/1 0.0215 0.0247 85.8 63.3-134 14.2 21 1676330-01 WG700132
Tetrachloroethene 119/1 0.0208 0.0235 83.2 53-139 12.4 20 1676330-01 WG700132
Toluene mg/1 0.0196 0.0211 78.5 61.4-130 7.18 20 1676330-01 WG700132
trans-1,2-Dichloroethene mg/1 0.0224 0.0236 89.7 56.5-129 5.01 20 L676330-01 WG700132
Trichloroethene 119/1 0.0195 0.0211 78.0 44.1-149 7.76 20 1676330-01 WG700132
Trichlorofluoromethane mg/1 0.0262 0.0279 105. 49.6-145 6.28 21.2 L676330-01 WG700132
Vinyl chloride mg/1 0.0224 0.0223 89.4 47.8-137 0.120 20 1676330-01 WG700132
4-Bromofluorobenzene 98.00 71-126 WG700132
Dibromofluoromethane 108.0 78.3-121 WG700132
Toluene-d8 104.0 88.5-111 WG700132
a,a,a-Trifluorotoluene 90.00 85-114 1G700132
Post Spike
* Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 47 of 49

1

OESC
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
level II
Raleigh, NC 27615 January 08, 2014
L 67 6247
12065 Lebanon Rd.
Mt. Juliet, TV 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Serial Dilution
Batch number /Run number / Sample number cross reference
WG699922: R2873126: L676247-01 02 03 04 05 06 07 08 09 10 11 12 13
WG700059: R2874464: L676247-03 04 05 06 07 08 09 10
WG700493: R2874565: L676247-11 12 13
WG700132: R2874865: 0676247-01 02
* Calculations are performed prior to rounding of reported values.
Performance of this Analyte is outside of established criteria.
For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.'
Page 48 of 49

I
1

OESC
L•A= B•Q,=•E•AI•G.r,.s
Cape Lookout Environmental Services
Mr. David Wells
8005 Clear Brook Drive
Quality Assurance Report
Level II
Raleigh, NC 27615 January 08, 2014
L676247
12065 Lebanon Rd.
Mt. Juliet, TA 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "J5" or a "J6". The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 49 of 49

11

•
f1

•
z