WI0700012_Monitoring (Report) Aug - Oct 2006_20061130

PCS
PhosphateW. AURORA
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27806
November 30, 2006
Evan O. Kane
1636 Mail Service Center
Raleigh, North Carolina, 27626-1636
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
August 2006 — October 2006
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Evan:
RECEIVED ( DENR / DWG
AQUIFFP PRfTF('TION SFGTion
NOV 3 0 2006
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTF1CR, b) Form GW-59 for each of the fourteen withdrawal wells, c) piezometer level
monitoring field sheet, and d) the summary operational and maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
1.0 Laivu,a1,1,,,,,,.„„„{
D. Daniel Winstead III
Environmental Engineer
PCS Phosphate
Attachments

pc: Will Hart — Aquifer Protection DWQ, WaRO (w/ attachments)
R. M. Smith/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
W. A. Schimming (w/ attachments)
Total Two Copies Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
E-Mail: M. D. Johnson
R. B. Lee
H:\Reports\2006\Quarterly\TFRAS Report Third Quarter 2006.doc
2

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
August 2006 — October 2006
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Infection Water Well System
The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system
during the period.
Daily operational data are collected by the SPA/Fertilizer Department and reported to the Environmental
Affairs Department. The total monthly and quarterly volumes of water injected as well as the month end
water level in the Water Level Control Tank are:
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
LEVEL
FEET, MSL
August
1,091,423
0
1,091,423
24..4
15.0
September
838,555
0
838,555
19.4
15.0
October
799,015
0
799,015
17.9
15.0
TOTALS
2,728,993
0
2,728,993
H:\Reports\2006\Quarterly\TFRAS Report Third Quarter 2006.doc
3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
Aug
347, 620
25,763
373,383
8.4
Sept
294,838
43,577
338,416
8.1
Oct
469,094
17,202
486,296
10.9
TOTALS
1,111,553
86,542
1,198,095
Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWW) Pumps
On 8/3, 8/8, 8/16, 8/25, 8/29, 9/7, 9/13, 9/22, 9/29, 10/4, 10/10, 10/17 and 10/26 flushed out pumps and
lines on each of the Confined Sand Formation Withdrawal Well (SSW) and the Croatan Formation
Withdrawal Well (CWW) Pumps.
SWW-1: On 10/3 replaced pump.
SWW-2:
SWW-3: On 9/11 changed counter.
SWW-4: On 9/5 replaced pump. On 10/5 changed counter.
SWW-5:
SWW-6:
SWW-7: On 10/24 changed pump.
H:\Reports\2006\Quarterly\TFRAS Report Third Quarter 2006.doc
4

Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1:
CWW-2:
CWW-3: On 10/9 changed counter.
CWW-4: On 10/23 repaired air line.
CWW-5:
CWW-6: On 10/19 air blasted well.
CWW-7: On 10/19 air blasted well.
H:\Reports\2006\Quarterly\TFRAS Report Third Quarter 2006.doc
5

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Mail Original
to:
Well Identification Number (from Permit): CIW-7
Well Depth: 48.00 ft. Well Diamter: 4 inch
Screened Interval: 31.00 ft. to 45.25 ft.
Depth to Water Level:
Measuring Point is
N/A ft. below measuring point.
N/A ft above land surface.
GALLONS of water pumped/bailed before sampling:
0
For Groundwater Treatment
Sys ems Check One:
Influent (98)
Effluent (99)
X
Field Analysis: pH 7.2 , Specific Conductance 621 uMhos
Temp. 21.0 oC, Odor NONE Appearance:
CLEAR
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
EXPIRATION DATE: 01/15/08
Non -Discharge UIC X
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
Certification No(s)
10/30/2006
10/30/2006 to 11/28/2006
PCS PHOSPHATE and ENVIRONMENT 1
330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
<1.0
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
434
7.2
5.7
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
14.2
N/A
N/A
N/A
<10.0
Specific Conductance N/A
Total Ammonia N/A
TKN as N N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/I
mg/I
mg/I Fe - Iron
mg/I Hg - Mercury
uMhos
mg/I
mg/I
X Yes
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified X Yes No )
N/A mg/I Ni - Nickel N/A mg/I
N/A mg/I Pb - Lead N/A mg/I
0.046 mg/I Zn - Zinc N/A mg/1
N/A mg/I Ammonia Nitrogen mg/I
N/A mg/I Other (Specify Compounds and Concentration Units)
N/A mg/1
N/A mg/I
<0.001 mg/I
<0.005 mg/I
Fluoride
MIRK
Ag - Silver
0.59 mg/1
N/A ug/I
N/A ug/I
Se- Selenium N/A ug/I
N/A mg/I Sodium N/A ug/I
N/A mg/I Organics: (GC, GC/MS, HPLC)
N/A mg/I (Specify test method #. Attach lab report.)
N/A mg/I Report attached? Yes (1) No X (2)
N/A mg/I VOC : method#
<0.010 mg/I
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
FArmitee (of Authorized Agent) Name and Title - Please type or print
�� 1 P /
/�/ 7'aa� kA?S '//29`0 do
Signature of Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Well Identification Number (from Permit): MWTF1-CR
Well Depth: 42.00 ft. Well Diamter: 2 inch
Screened Interval: 38.70 ft. to 40.70 ft.
Depth to Water Level: 13.04 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
MILILITERS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
2100
Field Analysis: pH 6.9 , Specific Conductance 668 uMhos
Temp. 22.8 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone' [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
EXPIRATION DATE:
UIC
01/15/08
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 10/30/2006
Date sample analyzed: 10/30/2006 to 11/28/2006
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A mg/I
Coliform: MF Fecal N/A /100m1
Coliform: MF Total <1.0 /100m1
(Note: Use MPN method for highly turbid samples)
X Yes
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Dissolved Solids: Total 456 mg/I Al - Aluminum
pH (when analyzed) 6.9 units Ba - Barium
TOC 5.9 mg/1 Ca - Calcium
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate 12.4 mg/I Hg - Mercury
19.4 mg/I Cd- Cadmium
N/A mg/I Chromium: Total
N/A mg/I Cu - Copper
Specific Conductance
Total Ammonia
TKN as N
N/A mg/I Fe - Iron
N/A uMhos K- Potassium
N/A mg/I Mg - Magnesium
N/A mg/I Mn - Manganese
No and field acidified X Yes No )
N/A mg/I Ni - Nickel
N/A mg/I
0.735 mg/I Zn - Zinc N/A
N/A mg/I
N/A mg/1
N/A mg/I
N/A mg/I
N/A mg/I
Pb - Lead N/A mg/I
mg/I
Ammonia Nitrogen mg/I
Other (Specify Compounds and Concentration Units)
Fluoride 0.46 mg/I
MIBK N/A ug/I
<0.001 mg/I Ag - Silver
0.022 mg/i Se- Selenium
N/A mg/I Sodium
N/A ug/I
N/A ug/I
N/A ug/I
N/A mg/1 Organics: (GC, GC/MS, HPLC)
N/A mg/I (Specify test method #. Attach lab report.)
N/A mg/I Report attached? Yes (1) No X (2)
N/A mg/I VOC •method#
0.126 mg/I
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. 1 am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
Pe ittee 1of Authorized Agent) Name and Title - Please type or print
N/ �j -4( I2M5 1 1129 l 6.
Signature of Permittee (or Authonzed Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled
18
Mail Original
to:
Well Identification Number (from Permit): CWW-1
Well Depth: 55.00 ft. Well Diamter: 4 inch
Screened Interval: 33.27 ft. to 52.68 ft.
Depth to Water Level: ft. below measuring point.
Measuring Point is 2.25 ft above land surface.
GALLONS of water pumped/bailed before sampling:
Field Analysis: pH , Specific Conductance
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
uMhos
Temp. oC, Odor Appearance:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012 EXPIRATION DATE: 01/15/08
Non -Discharge UIC X
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/29/2006
to
PCS PHOSPHATE
Certification No(s) 330
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A mg/I
Coliform: MF Fecal N/A /100m1
Coliform: MF Total N/ /100m1
(Note: UsIfN method i t
Dissoly
pH (wh
TOC
Chlorid
Arsenic
Grease and Oils
Phenol
Sulfate
N/A
N/A
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
N/A
mg/I
mg/I
mg/l
mg/I
mg/I
mg/I
mg/I
uMhos
mg/I
mg/I
Nitrite (NO2 as N)
Nitrate (NO3_.s N)
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
Yes n/a
No and field acidified
Yes n/a No )
N/A mg/1 Ni - Nickel
mg/I
N/A ug/I
N/A ug/I
Ag - Silver
Se- Selenium
N/A ug/I Sodium
N/A ug/I Organics: (GC, GC/MS,
N/A ug/I (Specify test method #.
N/A ug/I Report attached? Yes
N/A ug/I VOC
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
mg/I
mg/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
HPLC)
Attach lab report.)
(1) No X (2)
method#
method#
method#
I certify that. to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE: No Sample - Static Water Level Below Pump.
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
(of Authorized Agent) Name an. Title - Please type . print
//
Signature of Permittee (or thorized Agent)
(Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled 18
Well Identification Number (from Permit):
Well Depth: 52.15 ft. Well Diamter:
CWW-2
Screened Interval: 30.57 ft. to 49.82 ft.
Depth to Water Level:
Measuring Point is
4 inch
5.47 ft. below measuring point.
3.00 ft above land surface.
GALLONS of water pumped/bailed before sampling:
For Groundwater Treatment
Sys ems Check One:
Influent (98)
X Effluent (99)
CONTINUOUS
Field Analysis: pH 6.4 , Specific Conductance 2862 uMhos
Temp. 21.8 oC, Odor NONE Appearance: LT RUST
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
EXPIRATION DATE:
UIC X
01/15/08
Lagoon
Spray Field
Rotary Distributor
Other
Remediation: Infiltration Gallery
Remediation :
Land Application of Sludge
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/19/2006
10/19/2006 to 11/28/2006
PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD
N/A mg/I Nitrite (NO2 as N)
Coliform: MF Fecal N/A
Coliform: MF Total N/A
(Note:
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Use MPN method for highly turbid samples)
2140
6.5
10.0
63.0
N/A
N/A
N/A
Specific Conductance
Total Ammonia
TKN as N
/100m1 Nitrate (NO3 as N)
/100m1 Phosphorus: Total
Orthophosphate
mg/I Al - Aluminum
units Ba - Barium
mg/I Ca - Calcium
mg/I Cd- Cadmium
mg/I Chromium: Total
mg/I Cu - Copper
mg/I Fe - Iron
905.7 mg/1 Hg - Mercury
N/A uMhos K- Potassium
N/A mg/I Mg - Magnesium
N/A mg/I Mn - Manganese
Yes n/a No and field acidified Yes nla No )
N/A mg/I Ni - Nickel N/A ug/I
N/A mg/I Pb - Lead N/A ug/I
as P 77.750 mg/I Zn - Zinc N/A ug/I
N/A mg/I Ammonia Nitrogen mg/I
N/A ug/I Other (Specify Compounds and Concentration Units)
N/A ug/I Fluoride 0.19 mg/I
N/A ug/I MIBK N/A ug/I
N/A ug/I Ag - Silver N/A ug/I
N/A ug/l Se- Selenium N/A ug/I
N/A ug/I Sodium N/A ug/I
N/A ug/I
Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A ug/I VOC : method#
method#
method#
N/A ug/I
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
mite (of Authorized Agent) Name and Title - Please type or print
40.r RM S 1//2 9 /e)‘:6
Signature of Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18
Well Identification Number (from Permit):
Well Depth: 53.00 ft. Well Diamter:
CWW-3
Screened Interval: 36.42 ft. to 50.67 ft.
4 inch
Depth to Water Level: 5.25 ft. below measuring point.
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
Measuring Point is 3.08 ft above land surface.
GALLONS of water pumped/bailed before sampling: CONTINUOUS
Field Analysis: pH 6.4 , Specific Conductance 2486 uMhos
Temp. 23.8 oC, Odor NONE Appearance: LT RUST
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
EXPIRATION DATE:
UIC X
01/15/08
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 10/19/2006
Date sample analyzed: 10/19/2006 to 11/28/2006
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A mg/I
Coliform: MF Fecal N/A /100m1
Coliform: MF Total N/A /100m1
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 2076 mg/I
pH (when analyzed) 6.5 units
TOC 11.4 mg/I
Chloride 64.6 mg/I
Arsenic N/A mg/I
Grease and Oils N/A mg/1
Phenol N/A mg/I
Sulfate 793.4 mg/1
Specific Conductance N/A uMhos
Total Ammonia N/A mg/I
TKN as N N/A mg/I
Nitrite (NO2 as N)
Yes n/a
No and field acidified Yes n/a No )
N/A mg/I Ni - Nickel
Nitrate (NO3 as N) N/A mg/1 Pb - Lead
Phosphorus: Total as P 26.300 mg/I Zn - Zinc
Orthophosphate N/A mg/I
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
ug/I
ug/I
ug/I
Ammonia Nitrogen mg/I
N/A ug/I Other (Specify Compounds and Concentration Units)
N/A ug/I Fluoride 0.13 mg/I
N/A ug/1 MIBK N/A ug/1
N/A ug/I
N/A ug/1 Se- Selenium N/A ug/I
N/A ug/I Sodium N/A ug/I
N/A ug/I Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A ug/l
Ag - Silver
N/A
N/A
N/A
N/A ug/I VOC : method#
• method#
method#
N/A ug/I
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
P mittee (of Autholized Agent) Name and Title - Please type or print
41,1J fj• ,2 ns .�/z9 46
Signature of Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18
Well Identification Number (from Permit): CWW-4
Well Depth: 53.00 ft. Well Diamter: 4 inch
Screened Interval: 41.67 ft. to 50.92 ft.
Depth to Water Level:
Measuring Point is
5.89 ft. below measuring point.
2.75 ft above land surface.
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
GALLONS of water pumped/bailed before sampling: CONTINUOUS
Field Analysis: pH 6.9 , Specific Conductance 1306 uMhos
Temp. 26.4 oC.Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH. NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/19/2006
10/19/2006 to 11/28/2006
PCS PHOSPHATE and ENVIRONMENT 1
•
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
N/A
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 740
pH (when analyzed) 6.8
TOC 6.5
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
137.0
N/A
N/A
N/A
58.4
N/A
N/A
N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/I
mg/I
mg/I
mg/I
uMhos
mg/l
mg/I
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified
N/A
N/A
8.500
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mg/I
mg/I
mg/I
mg/I
ug/I
ug/I
ugll
ug/l
ug/I
ug/I
ug/I
ug/I
ug/I
ug/I
ug/I
Ni - Nickel
Pb - Lead
Zn - Zinc
Yes n/a No )
Ammonia Nitrogen
N/A ug/I
N/A ug/I
N/A ug/l
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
Se- Selenium
Sodium
mg/I
0.35 mg/I
N/A ug/I
N/A ug/l
N/A ug/I
N/A ug/I
Organics: (GC, GC/MS. HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC : method#
method#
method#
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
Pe itt: e,(of authorized Agent) Name and Title - Please type or print
Signature of Permittee (or Authors ed Agent)
(Date)
O

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Well Identification Number (from Permit):
Well Depth: 53.17 ft. Well Diamter:
CWW-5
Screened Interval: 41.75 ft. to 51.08 ft.
Depth to Water Level:
Measuring Point is
4 inch
5.71 ft. below measuring point.
2.58 ft above land surface.
GALLONS of water pumped/bailed before sampling:
For Groundwater Treatment
Sys ems Check One:
Influent (98)
X Effluent (99)
CONTINUOUS
Field Analysis: pH 6.4 , Specific Conductance 2749 uMhos
Temp. 26.1 oC, Odor NONE Appearance: LT CLOUDY
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH. NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/19/2006
10/19/2006 to 11/27/2006
PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD N/A Nitrite (NO2 as N)
Coliform: MF Fecal N/A Nitrate (NO3 as N)
Coliform: MF Total N/A Phosphorus: Total as P
(Note. Use MPN method for highly turbid samples) Orthophosphate
Dissolved Solids: Total 1972 mg/I Al - Aluminum
pH (when analyzed) 6.6 units Ba - Barium
TOC 9.0 mg/I Ca - Calcium
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
mg/I
/100m1
/100m1
52.3 mg/I
N/A mg/I
N/A mg/I
Cd- Cadmium
Chromium: Total
Cu - Copper
N/A mg/I Fe - Iron
981.7 mg/I Hg - Mercury
N/A uMhos K- Potassium
N/A mg/I Mg - Magnesium
Mn - Manganese
N/A mg/I
No and field
acidified Yes n/a No )
N/A mg/I Ni - Nickel N/A ug/I
N/A mg/I Pb - Lead N/A ug/I
30.900 mg/I Zn - Zinc N/A ug/I
N/A mg/I Ammonia Nitrogen mg/I
N/A ug/I Other (Specify Compounds and Concentration Units)
N/A ug/I Fluoride 0.10 mg/I
N/A ug/I MIBK N/A ug/I
N/A ug/I Ag - Silver N/A ug/I
N/A ug/l Se- Selenium N/A ug/I
N/A ug/I Sodium N/A ug/I
N/A ug/I Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A ug/I VOC method#
N/A ug/I : method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
4 ignature of Permittee (or Authorized Agent) (Date)
Permittee (o Authorized Agent) Name and Title - Please type or print
.�.�.�. �-•C f� � 2M S ///z q /t

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Itp
Well Identification Number (from Permit): CWW-6
Well Depth: 53.00 ft. Well Diamter: 4 inch
Screened Interval: 36.62 ft. to 50.88 ft.
Depth to Water Level:
Measuring Point is
7.21 ft. below measuring point.
2.92 ft above land surface.
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
GALLONS of water pumped/bailed before sampling: CONTINUOUS
Field Analysis: pH 6.4 , Specific Conductance 3386 uMhos
Temp. 30.8 oC, Odor NONE
Appearance: LT RUST
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH. NC 27699-1636 Phone: [phone]
PERMIT #: W10700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/19/2006
10/19/2006 to 11/28/2006
PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
N/A
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 2280
pH (when analyzed) 6.6
TOC 11.9
Chloride 77.9
Arsenic N/A
Grease and Oils N/A
Phenol N/A
Sulfate
Specific Conductance
Total Ammonia
TKN as N
1073.4
N/A
N/A
N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/I
mg/I
mg/I
mg/I
uMhos
mg/1
mg/I
unfiltered Yes n/a
Nitrite (NO2 as N) N/A mg/I
Nitrate (NO3 as N) N/A mg/I
Phosphorus: Total as P 45.250 mg/I
Orthophosphate N/A mg/I
Al - Aluminum N/A ug/I
Ba - Barium N/A ug/I
Ca - Calcium N/A ug/I
Cd- Cadmium N/A ug/I
Chromium: Total N/A ug/I
Cu - Copper N/A ug/I
Fe - Iron N/A ug/I
Hg - Mercury N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified
Yes nla No )
Ni - Nickel N/A
Pb - Lead N/A
Zn - Zinc N/A
ug/I
ug/I
ug/I
Ammonia Nitrogen mg/I
Other (Specify Compounds and Concentration Units)
Fluoride 0.08 mg/I
N/A ug/l
N/A ug/I
Se- Selenium N/A ug/I
Sodium N/A ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC : method#
MIBK
Ag - Silver
method#
method#
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
Permittee (of Authgized Agent) Name and Title - Please type or print
12IYI 5 l /
Signature of Permittee (or Aut orized Agent)
(Date)
0

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled
18
rnk
Well Identification Number (from Permit): CWW-7
Well Depth: 53.00 ft. Well Diamter:
Screened Interval: 36.58 ft. to 50.83 ft.
Depth to Water Level:
Measuring Point is 1.25 ft above land surface.
GALLONS of water pumped/bailed before sampling:
Field Analysis: pH 7.4 , Specific Conductance
Temp. 23.5 oC, Odor NONE
4 inch
5.32 ft. below measuring point.
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
CONTINUOUS
1095 uMhos
Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
EXPIRATION DATE:
UIC X
01 /15/08
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon
Spray Field X Remediation :
Remediation: Infiltration Gallery
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 10/19/2006
Date sample analyzed: 10/19/2006 to 11/28/2006
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A mg/I
Coliform: MF Fecal N/A
Nitrite (NO2 as N)
/100m1 Nitrate (NO3 as N)
Coliform: MF Total N/A /100m1
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
708
7.0
9.2
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
135.0
N/A
N/A
N/A
307.7
N/A
N/A
N/A
mg/l
units
mg/I
mg/I
mg/I
mg/I
mg/I
mg/I
uMhos
mg/I
mg/I
Yes n/a
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified Yes n/a No )
N/A mg/I Ni - Nickel N/A ug/I
N/A mg/I Pb - Lead N/A ug/I
10.325 mg/I Zn - Zinc N/A ug/I
N/A mg/I Ammonia Nitrogen mg/I
N/A ug/I Other (Specify Compounds and Concentration Units)
N/A ug/I Fluoride 0.52 mg/I
N/A ug/I MIBK N/A ug/I
N/A ug/I Ag - Silver N/A ug/I
N/A ug/I Se- Selenium N/A ug/I
N/A ug/I Sodium N/A ug/l
N/A ug/I Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A ug/I VOC : method#
method#
method#
N/A ug/I
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
/P�Rrmittee of Authorized Agent) Name and Title - Please type or print
N� 4..m. ta-O-ca r k!'✓I S /!/Z 9 �D G
Signature of Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18
Well Identification Number (from Permit):
Well Depth: 22.50 ft. Well Diamter:
SWW-1
4 inch
Screened Interval: 18.30 ft. to 21.12 ft.
Depth to Water Level: 7.52 ft. below measuring point.
Measuring Point is 1.52 ft above land surface.
GALLONS of water pumped/bailed before sampling:
For Groundwater Treatment
Sys ems Check One:
Influent (98)
X Effluent (99)
CONTINUOUS
Field Analysis: pH 6.0 , Specific Conductance 1517 uMhos
Temp. 21.8 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT.#: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 10/19/2006
Date sample analyzed: 10/19/2006 to 11/28/2006
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered
COD N/A mg/I Nitrite (NO2 as N)
Coliform: MF Fecal N/A /100m1 Nitrate (NO3 as N)
Coliform: MF Total N/A /100m1 Phosphorus: Total as P
(Note: Use MPN method for highly turbid samples)
Orthophosphate
Dissolved Solids: Total 1208 mg/I Al - Aluminum
pH (when analyzed) 6.2 units Ba - Barium
TOC 5.5 mg/I Ca - Calcium
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
89.0 mg/I Cd- Cadmium
N/A mg/I Chromium: Total
N/A mg/I Cu - Copper
N/A mg/I Fe - Iron
209.5 mg/I Hg - Mercury
N/A uMhos K- Potassium
N/A mg/I Mg - Magnesium
N/A mg/I Mn - Manganese
Yes n/a No and field acidified
N/A mg/I
N/A mg/I
132.500 mg/I
N/A mg/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/l
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
Yes n/a No )
Ni - Nickel N/A ug/I
Pb - Lead N/A ug/I
Zn - Zinc N/A ug/I
Ammonia Nitrogen mg/I
Other (Specify Compounds and Concentration Units)
Fluoride
M I BK
Ag - Silver
0.57 mg/l
N/A ug/I
N/A ug/I
Se- Selenium N/A ug/I
Sodium N/A ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC : method#
method#
method#
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
Permittee of AutbLorized Agent) Name and Title - Please type or prin
/KS 11/29 /oc
Signature of Permittee (or Au orized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: _ Tank Farm No. of Wells to be Sampled
18
Well Identification Number (from Permit):
Well Depth: 23.00 ft. Well Diamter:
SWW-2
Screened Interval: 18.80 ft. to 21.63 ft.
Depth to Water Level:
Measuring Point is
4 inch
5.88 ft. below measuring point.
3.42 ft above land surface.
GALLONS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
CONTINUOUS
Field Analysis: pH 6.3 , Specific Conductance 2164 uMhos
Temp. 21.5 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION. GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/19/2006
10/19/2006 to 11/28/2006
PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD N/A mg/I
Coliform: MF Fecal
Coliform: MF Total
NIA /100m1
N/A /100m1
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed)
TOC
1616
6.3
8.0
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
54.3
N/A
N/A
N/A
469.0
N/A
N/A
N/A
mg/I
units
mg/I
mg/1
mg/I
mg/I
mgll
mg/I
uMhos
mg/I
mg/I
No and field acidified
Nitrite (NO2 as N) N/A mg/1
Nitrate (NO3 as N) N/A mg/I
Phosphorus: Total as P 94.000 mg/I
Orthophosphate N/A mg/I
Al - Aluminum N/A ug/I
Ba - Barium N/A ug/I
Ca - Calcium N/A ug/I
Cd- Cadmium N/A ug/I
Chromium: Total N/A ug/I
Cu - Copper N/A ug/I
N/A ug/I
N/A ug/I
K- Potassium N/A ug/I
Mg - Magnesium N/A ug/I
Mn - Manganese N/A ug/I
Fe - Iron
Hg - Mercury
Yes n/a No )
Ni - Nickel N/A ug/I
Pb - Lead N/A ug/I
Zn - Zinc N/A ug/I
Ammonia Nitrogen mg/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
Se- Selenium
Sodium
0.20
N/A
N/A
N/A
N/A
mg/I
ug/I
ug/I
ug/I
ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC : method#
method#
method#
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
4P rm tee (of Authorized Agent) Name and Title - Please type or print
a h4 {:r QMS .' /V1 /oo
Signature of Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled 18
Well Identification Number (from Permit): SWW-3
Well Depth: 24.50 ft. Well Diamter: 4 inch
Screened Interval: 20.17 ft. to 23.00 ft.
Depth to Water Level: 7.86 ft. below measuring point.
Measuring Point is 3.17 ft above land surface.
GALLONS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
CONTINUOUS
Field Analysis: pH 6.2 , Specific Conductance 1425 uMhos
Temp. 22.7 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
EXPIRATION DATE:
UIC X
01/15/08
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 10/19/2006
Date sample analyzed: 10/19/2006 to 11/28/2006
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples
COD
Coliform: MF Fecal
Coliform: MF Total
(Note: Use MPN method for highly
Dissolved Solids: Total
pH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
for metals were collected
N/A mg/1
N/A /100m1
N/A /100m1
turbid samples)
1024 mg/I
6.4 units
5.9 mg/I
40.9 mg/I
N/A mg/I
N/A mg/I
N/A mg/I
322.1 mg/I
N/A uMhos
N/A mg/I
N/A mg/I
unfiltered Yes n/a
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified Yes n/a No )
N/A mg/I Ni - Nickel N/A ug/I
N/A mg/I Pb - Lead _N/A ug/I
54.500 mg/I Zn - Zinc N/A ug/I
N/A mg/1 Ammonia Nitrogen mg/I
N/A ug/I Other (Specify Compounds and Concentration Units)
N/A ug/I Fluoride 0.07 mg/1
N/A ug/I MIBK N/A ug/I
N/A ug/I Ag - Silver N/A ug/I
N/A ug/I Se- Selenium N/A ug/I
N/A ug/I Sodium N/A ug/l
N/A ug/I Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A ug/I VOC : method#
N/A ug/I
: method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
PPrmittee f Authorized Agent) Name and Title - Please type or print
Q 4r 12M5 tt/24/o to
Signature of Permittee (or Authorized Agent) ( ate)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled
18
hom
Well Identification Number (from Permit): SWW-4
Well Depth: 25.00 ft. Well Diamter:
4 inch
Screened Interval: 20.50 ft. to 23.30 ft.
Depth to Water Level: 8.11 ft. below measuring point.
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
Measuring Point is 3.42 ft above land surface.
GALLONS of water pumped/bailed before sampling: CONTINUOUS
Field Analysis: pH 6.2 , Specific Conductance 2321 uMhos
Temp. 30.8 oC, Odor NONE Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH. NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
EXPIRATION DATE:
UIC X
01/15/08
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/19/2006
10/19/2006 to 11/28/2006
PCS PHOSPHATE and ENVIRONMENT 1
MIL
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
N/A
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 1820
pH (when analyzed) 6.1
TOC 6.4
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
37.8
N/A
N/A
N/A
596.1
N/A
N/A
N/A
mg/I Nitrite (NO2 as N)
/100m1
/100m1
mg/1
units
mg/I
mg/I
mg/l
mg/l
mg/l
mg/I
uMhos
mg/I
mg/I
Nitrate (NO3 as N)
Phosphorus: Total as
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field acidified
N/A mg/1 Ni - Nickel
N/A mg/I Pb - Lead
Yes n/a No )
P 215.000 mg/I Zn - Zinc
N/A mg/I Ammonia Nitrogen
N/A ug/I
N/A ug/I
N/A ug/l
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
mg/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
N/A ug/I Se- Selenium
N/A ug/I
N/A ug/l
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
Sodium
Organics: (GC, GC/MS, HPLC)
(Specify test method #.
Report attached? Yes
VOC
Attach lab report.)
(1) No
method#
method#
method#
0.14 mg/l
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
X (2)
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
P�rn]i(te.e (9f Authorized Agent) Name and Title - Please type or print
r 32M3 /I / i /06.
Signature of Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled
18
Mail Original
to:
Well Identification Number (from Permit): SWW-5
Well Depth: 28.21 ft. Well Diamter: 4 inch
Screened Interval: 24.83 ft. to 27.21 ft,
Depth to Water Level:
Measuring Point is
7.33 ft. below measuring point.
2.96 ft above land surface.
For Groundwater Treatment
Systems Check One:
nfluent (98)
X Effluent (99)
GALLONS of water pumped/bailed before sampling: CONTINUOUS
Field Analysis: pH 6.5 , Specific Conductance 2403 uMhos
Temp. 27.5 oC, Odor NONE Appearance: CLEAR
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012 EXPIRATION DATE: 01/15/08
Non -Discharge UIC X
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Remediation: Infiltration Gallery
X Remediation :
Lagoon
Spray Field
Rotary Distributor
Other
Land Application of Sludge
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/19/2006
10/19/2006 to 11/28/2006
PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes
COD
Coliform: MF Fecal
Coliform: MF Total
N/A
N/A
N/A
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 1556
pH (when analyzed) 6.5
TOC 8.6
Chloride 48.3
Arsenic N/A
Grease and Oils N/A
Phenol N/A
Sulfate
672.4
Specific Conductance N/A
Total Ammonia N/A
TKN as N N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/I
mg/1
mg/I
mg/I
uMhos
mg/I
mg/l
Nitrite (NO2 as N)
n/a No and field acidified
Yes n/a No )
N/A mg/I Ni - Nickel N/A
Nitrate (NO3 as N) N/A mg/I Pb - Lead N/A
Phosphorus: Total as P 65.750 mg/I
Orthophosphate
Al - Aluminum N/A ug/I
Ba - Barium N/A ug/I
Ca - Calcium N/A ug/I
Cd- Cadmium N/A ug/I
Chromium: Total N/A ug/I
Cu - Copper N/A ug/I
N/A ug/l
Hg - Mercury N/A ug/I
K- Potassium N/A ug/I
Mg - Magnesium N/A ug/I
Mn - Manganese N/A ug/I
Fe - Iron
Zn - Zinc N/A
N/A mg/I Ammonia Nitrogen
ug/I
ug/I
ug/I
mg/I
Other (Specify Compounds and Concentration Units)
Fluoride 0.34 mg/I
MIBK N/A ug/I
Ag - Silver N/A ug/I
Se- Selenium N/A ug/I
Sodium N/A ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC : method#
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
;Mee tee (of uthorLed Agent) Name and Title - Please type or print
Cat DMS 11/294G
Signature of Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
Telephone: [phone]
No. of Wells to be Sampled
18
Well Identification Number (from Permit):
Well Depth: 26.00 ft. Well Diamter:
SWW-6
4 inch
Screened Interval: 22.25 ft. to 24.62 ft.
Depth to Water Level: 6.57 ft. below measuring point.
Measuring Point is 2.58 ft above land surface.
GALLONS of water pumped/bailed before sampling:
Field Analysis: pH 6.1 , Specific Conductance
Temp. 29.0 oC, Odor NONE
For Groundwater Treatment
Systems Check One:
Influent (98)
X Effluent (99)
CONTINUOUS
3445 uMhos
Appearance: CLEAR
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH. NC 27699-1636 Phone [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
EXPIRATION DATE:
UIC X
01/15/08
Lagoon
Spray Field
Rotary Distributor
Other
Remediation: Infiltration Gallery
Remediation :
Land Application of Sludge
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected:
Date sample analyzed:
Laboratory Name:
10/19/2006
10/19/2006 to 11/28/2006
PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD N/A
Coliform: MF Fecal N/A
Coliform: MF Total N/A
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 2412
pH (when analyzed) 6.4
TOC 14.6
Chloride 82.8
Arsenic N/A
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A
N/A
1145.2
N/A
N/A
N/A
mg/I
/100m1
/100m1
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
mg/I Al - Aluminum
units Ba - Barium
mg/I Ca - Calcium
mg/I Cd- Cadmium
mg/I Chromium: Total
mg/I Cu - Copper
mg/I Fe - Iron
mg/I Hg - Mercury
uMhos
mg/I
mg/1
K- Potassium
Mg - Magnesium
Mn - Manganese
No and field
N/A mg/I
N/A mg/I
35.000 mg/I
N/A mg/I
N/A ug/l
N/A ug/I
N/A ug/l
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
acidified Yes n/a No )
Ni - Nickel
Pb - Lead
Zn - Zinc
Ammonia Nitrogen
N/A ug/I
N/A ug/I
N/A ug/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
Se- Selenium
mg/l
0.05 mg/I
N/A ug/I
N/A ug/l
N/A ug/I
Sodium N/A ug/I
Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A ug/I VOC method#
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. 1 am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
P
ee (of Authorized Agent) Name and Title - Please type or print
/W_/ (41r / 04/5 /129la6
Signature of Permittee (or Authorized Agent) (Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm
No. of Wells to be Sampled
18
Well Identification Number (from Permit): SWW-7
Well Depth: 29.50 ft. Well Diamter: 4 inch
Screened Interval: 25.17 ft. to 27.50 ft.
Depth to Water Level: 7.96 ft. below measuring point.
Measuring Point is 3.00 ft above land surface.
GALLONS of water pumped/bailed before sampling:
For Groundwater Treatment
Systems Check One:
Influent (98)
Effluent (99)
X
CONTINUOUS
Field Analysis: pH 6.7 , Specific Conductance 919 uMhos
Temp. 25.0 oC, Odor NONE
Appearance: LT CLOUDY
Mail Original
to:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 Mail Service Center
RALEIGH, NC 27699-1636 Phone: [phone]
PERMIT #: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation
EXPIRATION DATE:
UIC X
01/15/08
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 10/19/2006
Date sample analyzed: 10/19/2006 to 11/28/2006
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples
COD
Coliform: MF Fecal
Coliform: MF Total
for metals were collected
N/A
N/A
N/A
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 532
pH (when analyzed) 6.7
TOC 4.5
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
115.0
N/A
N/A
N/A
62.6
N/A
N/A
N/A
mg/I
/100m1
/100m1
mg/I
units
mg/I
mg/I
mg/l
mg/I
mg/I
mg/l
uMhos
mg/I
mg/l
unfiltered Yes
Nitrite (NO2 as N)
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
15.000 mg/I
N/A mg/I
N/A ug/I
N/A ug/1
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
N/A ug/I
n/a No and field acidified Yes n/a No )
N/A mg/I Ni - Nickel N/A ug/I
N/A mg/I Pb - Lead N/A ug/I
Zn - Zinc N/A ug/I
Ammonia Nitrogen mg/I
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
Se- Selenium
Sodium
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X (2)
VOC
0.38 mg/I
N/A ug/1
N/A ug/I
N/A ug/1
method#
method#
method#
N/A ug/1
1 certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
P ttee (o Authorized Agent) Name and Title - Please type or print
Cr kens /I/i 9 / / o (0
Signature of Permittee (or Authorized Agent) (Date)