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HomeMy WebLinkAboutWI0700012_Monitoring (Report) Aug - Oct 2010_20101129PotashCorp' Helping Nature Provide November 29, 2010 Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina, 27699 Attn: Information Management CERTIFIED MAIL Subject: Underground Injection Control Program Quarterly Groundwater Monitoring Report August 2010 — October 2010 Injection Well Permit #W10700012 Tank Farm Remedial Action System Beaufort Co. Dear Qi: TM S DEC 2010 Please find the subject groundwater monitoring report attached. This includes the sampling and reporting requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and monitor well MWTFICR, b) Form GW-59 for each of the fourteen withdrawal wells, c) piezometer level monitoring field sheet, and d) the summary operational and maintenance report. Please do not hesitate to contact me at (252) 322-8283 if you have any questions. Sincerely, ppA,.a rJoi,le-04Er D. Daniel Winstead III Environmental Engineer PCS Phosphate Attachments RECEIVED / DENR / DWQ AQUIFER PRnTFt'.TI(-IN SFCTIoN DEC 21 2010 F fir DEC u 2 2010 Information Processing Unit nWQ/B y 1530 NC HWY 306 S, Aurora, NC US 27806-9245 T 252-322-4111 www.potashcorp.com pc: Will Hart — Aquifer Protection DWQ, WaRO (w/ attachments) R. M. Smith/12-07-02 (w/ attachments) T. S. Ingra - Ardaman & Assoc. (w/attachments) Mike Brom (w/ attachments) Jeremy Pierce (w/ attachments) R. B. Lee (w/ attachments) Total Two Copies Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina, 27699 Attn: Information Management RECEIVED / DENR / DWQ AQUIFER :pRnTFe.TI(w eFCT!ON DEC 21 2010 H:\Reports\2010\Quarterly\TFRAS Report Third Quarter 2010.docx 2 GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CIW-7 Well Depth: 48.00 ft. Well Diamter: 4 inch Screened Interval: Depth to Water Level: Measuring Point is 31.00 ft. to 45.25 ft. N/A ft. below measuring point. N/A ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Systems Check One: Influent (98) Effluent (99) CONTINUOUS Field Analysis: pH 7.0 , Specific Conductance 660 uMhos Temp. 23.3 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01 /31 /13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/26/2010 10/26/2010 to 11/5/2010 PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered Yes COD N/A Coliform: MF Fecal N/A Coliform: MF Total <1.8 MPN` (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N m g/1 /100m1 /100m1 388 mg/1 6.9 units 4.9 mg/1 13.5 mg/I N/A mg/1 N/A mg/1 Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Orthophosphate Al - Aluminum Ba - Barium Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper N/A mg/I Fe - Iron <10.0 mg/I Hg - Mercury N/A uMhos N/A mg/I N/A mg/I K- Potassium Mg - Magnesium Mn - Manganese <0.010 mg/1 0.017 mg/I n/a No and field acidified Yes nig No ) N/A mg/1 Ni - Nickel N/A mg/1 Pb - Lead Zn - Zinc N/A N/A N/A N/A mg/I Ammonia Nitrogen N/A mg/1 N/A mg/1 N/A mg/1 <0.001 mg/1 Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver <0.005 mg/I Se- Selenium N/A mg/1 Sodium 0.49 N/A N/A N/A N/A N/A mg/I Organics: (GC, GC/MS, HPLC) N/A mg/I (Specify test method #. Attach lab report.) N/A mg/I Report attached? Yes (1) No X N/A mg/1 VOC : method# method# method# mg/1 mg/I mg/1 mg/I mg/1 ug/I ug/I ug/l ug/I (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility ui fines and imprisionment for knowing violations. NOTE: *STANDARD METHOD 9221B GW-59 Rev 4/98 Croz- i,,for,»ar,Urr 201g epGS'n9 unit RECEIVED 1 DENR l DWQ AQUIFER PR(1TFCTION SFCTION DEC 212010. Signature of Permittee (or Autho Ross M. Smith - Manager, Environmental Affairs rmi -e (of Authorized Agent) Name and Title - Please type or pint 11za (Date) ized Agent) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): MWTF1-CR Well Depth: 42.00 ft. Well Diamter: 2 inch Screened Interval: 38.70 ft. to 40.70 ft. Depth to Water Level: 21.95 ft. below measuring point. Measuring Point is 3.95 ft above land surface. MILILITERS of water pumped/bailed before sampling: Field Analysis: pH 6.9 , Specific Conductance 669 uMhos For Groundwater Treatment Sys ems Check One: Influent (98) Effluent (99) 2500 Temp. 21.5 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01/31/13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/26/2010 Date sample analyzed: 10/26/2010 to 11/5/2010 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected COD Coliform: MF Fecal Coliform: MF Total N/A mg/1 N/A /100m1 <1.8 MPN' /l00m1 (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total 450 pH (when analyzed) 6.9 TOC Chloride Arsenic Grease and Oils Phenol Sulfate 4.4 18.6 N/A N/A N/A 15.1 Specific Conductance Total Ammonia TKN as N N/A N/A N/A mg/1 units mg/I mg/I mg/I m g/1 mg/1 mg/1 uMhos mg/I mg/I unfiltered Yes n/a No and field acidified Yes n/2 No ) Nitrite (NO2 as N) N/A mg/I Ni - Nickel Nitrate (NO3 as N) N/A mg/I Phosphorus: Total as P 0.860 mg/1 Orthophosphate N/A mg/1 Al - Aluminum N/A mg/I Ba - Barium N/A mgll Ca - Calcium N/A mg/I Cd- Cadmium <0.001 mg/I Ag - Silver Chromium: Total <0.005 mg/1 Cu - Copper N/A mg/I Fe - Iron N/A mg/I Hg - Mercury N/A mg/I N/A mg/I N/A mg/1 K- Potassium Mg - Magnesium Mn - Manganese 0.051 mg/I Pb - Lead Zn - Zinc Ammonia Nitrogen N/A N/A N/A Other (Specify Compounds and Concentration Units) Fluoride MIBK Se- Selenium Sodium 0.17 N/A N/A N/A N/A Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report) Report attached? Yes (1) No VOC : method# method# method# mg/I mg/1 mg/I mg/1 mg/l ug/I ug/I ug/I ug/I (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. false information, including the possibility of fines and imprisionment for knowing violations. accurate, and complete, and that the laboratory analytical data was produced I am aware that there are significant penalties for submitting NOTE: *STANDARD METHOD 9221B GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs /Permittee (of uthorized Agent) Name and Title - Please type or print 4,,J..te-d 4/- 1Zr11S ,i/7?/f Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 fiom ceri Well Identification Number (from Permit): Well Depth: 22.50 ft. Well Diamter: SWW-1 Screened Interval: 18.30 ft. to 21.12 ft. 4 inch Depth to Water Level: 12.88 ft. below measuring point. Measuring Point is 1.52 ft above land surface. For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) GALLONS of water pumped/bailed before sampling: CONTINUOUS Field Analysis: pH 5.7 , Specific Conductance 1352 uMhos Temp. 22.0 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01/31/13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/26/2010 Date sample analyzed: 10/26/2010 to 11/5/2010 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered COD N/A mg/I Nitrite (NO2 as N) Coliform: MF Fecal N/A /100m1 Nitrate (NO3 as N) Yes n/a Coliform: MF Total N/A /100m1 Phosphorus: Total as P (Note: Use MPN method for highly turbid samples) Orthophosphate Dissolved Solids: Total 1064 mg/I Al - Aluminum pH (when analyzed) 5.9 units Ba - Barium TOC 9.5 mg/I Ca - Calcium Chloride 39.2 mg/I Arsenic N/A mg/I Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A mg/I N/A mg/I 184.4 mg/I N/A uMhos N/A mg/I N/A mg/I Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese No and field acidified Yes n/a No ) N/A mg/I Ni - Nickel N/A mg/I Pb - Lead 155.000 mg/I Zn - Zinc N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/l ug/I N/A N/A N/A Ammonia Nitrogen Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver Se- Selenium Sodium 0.57 N/A N/A N/A N/A Organics: (GC, GC/MS (Specify test method # Report attached? Yes VOC • HPLC) Attach lab report.) (1) No X method# method# method# ug/I ug/l ug/I mg/I mg/1 ug/I ug/I ug/I ug/I (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs �P rmitta (of A thorized Agent) Name and Title - Please type or /print .l G�%% �,- R 15 /1/29 0 Signature of Permittee (or Authorized Agent) /// (Dat GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Mom perm° Well Identification Number (from Permit): Well Depth: 23.00 ft. Well Diamter: Screened Interval: 18.80 ft. to 21.63 ft. Depth to Water Level: 3.04 ft. below measuring point. Measuring Point is 3.42 ft above land surface. GALLONS of water pumped/bailed before sampling: CONTINUOUS Field Analysis: pH 5.2 , Specific Conductance 2325 uMhos Temp. 21.5 oC, Odor NONE Appearance: CLEAR SWW-2 4 inch For Groundwater Treatment Sys ems Check One: Influent (98) Effluent (99) X Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01/31/13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/26/2010 10/26/2010 to 11/5/2010 PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered Yes nia COD Coliform: MF Fecal Coliform: MF Total N/A mg/I Nitrite (NO2 as N) N/A /100m1 Nitrate (NO3 as N) N/A /100m1 Phosphorus: Total as P (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total 2680 pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N Orthophosphate mg/I Al - Aluminum 5.4 units Ba - Barium 7.3 mg/I Ca - Calcium 76.9 mg/I Cd- Cadmium N/A mg/I Chromium: Total N/A mg/I Cu - Copper N/A mg/I Fe - Iron 319.3 mg/1 Hg - Mercury N/A uMhos K- Potassium N/A mg/1 Mg - Magnesium N/A mg/I Mn - Manganese No and field acidified Yes n/2 No ) N/A mg/I Ni - Nickel N/A mg/1 Pb - Lead 580.000 mg/I Zn - Zinc N/A mg/I Ammonia Nitrogen N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/1 mg/I Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver N/A ug/I Se- Selenium N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Sodium Organics: (GC, GC/MS, (Specify test method #. Report attached? Yes VOC 0.25 mg/I N/A ug/I N/A ug/I N/A ug/I NIA ug/I HPLC) Attach lab report.) (1) No X (2) method# method# method# certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE. GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs ,Permittee (of Authorized Agent) Name and Title - Please type or print ftl. A.1il%,,.a.. C- m s / t z 9 /,a Signature of Permittee (or Authorized Agent) - (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 om� Well Identification Number (from Permit): Well Depth: 24.50 ft. Well Diamter: SWW-3 4 inch Screened Interval: 20.17 ft. to 23.00 ft. Depth to Water Level: 8.21 ft. below measuring point. For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) Measuring Point is 3.17 ft above land surface. GALLONS of water pumped/bailed before sampling: N/A Field Analysis: pH N/A , Specific Conductance NIA uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge EXPIRATION DATE: UIC X 01/31/13 Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/26/2010 Date sample analyzed: 10/26/2010 to 10/26/2010 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples COD Coliform: MF Fecal Coliform: MF Total for metals N/A N/A N/A were collected mg/I /100m1 /100m1 (Note: Use MPN method for highly turbid samples Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A mg/I N/A mg/1 N/A mg/I N/A mg/I N/A mg/I N/A uMhos N/A mg/I N/A mg/1 unfiltered Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese Yes n/a No and field acidified N/A mg/1 N/A mg/1 N/A mg/I N/ . g/I N/A ug/I N/A ug/1 N/A ug/1 N/A ug/I N/A ug/1 N/A ug/1 N/A ug/1 N/A ug/I Ni - Nickel Pb - Lead Zn - Zinc Ammonia Nitrogen Yes nle No ) Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC method# method# method# N/A ug/1 N/A ug/I N/A ug/I mg/1 N/A ug/1 N/A ug/1 N/A ug/1 N/A ug/1 1 certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs rmi eeI(of uthq[zed Agent) Name and Title - Please type r print 10 D. W�N� -r,� �'� r 1?r)1 s 1 r29 // Signature of Permittee (or Authorized Agent) ate) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 min pegrn Well Identification Number (from Permit): SWW-4 Well Depth: 25.00 ft. Well Diamter: 4 inch Screened Interval: 20.50 ft. to 23.30 ft. Depth to Water Level: 6.29 ft. below measuring point. Measuring Point is 3.42 ft above land surface. For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) GALLONS of water pumped/bailed before sampling: CONTINUOUS Field Analysis: pH 4.6 , Specific Conductance 3932 uMhos Temp. 31.2 oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01/31/13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/26/2010 Date sample analyzed: 10/26/2010 to 11/5/2010 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected COD Coliform: MF Fecal Coliform: MF Total N/A N/A N/A (Note: Use MPN method for highly turbid samples) mg/I /100m1 /100m1 Dissolved Solids: Total 4544 mg/I pH (when analyzed) 4.7 units TOC 7.7 mg/I Chloride 37.0 mg/I Arsenic N/A mg/I Grease and Oils N/A mg/I Phenol Sulfate Specific Conductance Total Ammonia TKN as N unfiltered Yes n/a Nitrite (NO2 as N) Nitrate (NO3 as N) N/A Phosphorus: Total as P 1090.000 Orthophosphate N/A Al - Aluminum Ba - Barium Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper N/A mg/I Fe - Iron 600.8 mg/I Hg - Mercury N/A uMhos N/A mg/I N/A mg/I K- Potassium Mg - Magnesium Mn - Manganese No and field acidified Yes n/z No ) N/A mg/I Ni - Nickel mg/1 mg/I mg/I N/A ug/I N/A ug/l N/A ug/I N/A ug/l Ag - Silver N/A ug/I Se- Selenium N/A ug/I Sodium N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I Pb - Lead Zn - Zinc Ammonia Nitrogen N/A N/A N/A Other (Specify Compounds and Concentration Units) Fluoride MIBK 0.55 N/A N/A N/A N/A Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X VOC : method# method# method# ug/l ug/I ug/I mg/I mg/I ug/I ug/I ug/I ug/l (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs P rmittee (of Authorized Agent) Name/�and Title - Please type or print b. kk lb r }Mg 5 n/Z Q //O Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): SWW-5 Well Depth: 28.21 ft. Well Diamter: 4 inch Screened Interval: 24.83 ft. to 27.21 ft. Depth to Water Level: 5.78 ft. below measuring point. Measuring Point is 2.96 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: W10700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01/31/13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/26/2010 10/26/2010 to 10/26/2010 PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected unfiltered COD Coliform: MF Fecal Coliform: MF Total N/A N/A N/A mg/I Nitrite (NO2 as N) /100m1 /100m1 Nitrate (NO3 as N) Yes n/a Phosphorus: Total as P (Note: Use MPN method for hi.hly turbid sam.les) Ortho•hos hate Dissolved Solids: Tot pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N A N/A mg/1 Cd- Cadmium N/A mg/I Chromium: Total N/A mg/I Cu - Copper N/A mg/I Fe - Iron N/A mg/I Hg - Mercury N/A uMhos K- Potassium N/A mg/I Mg - Magnesium N/A mg/I Mn - Manganese No and field acidified N/A N/A N/A N/A mg/I Ni - Nickel mg/I mg/I ma/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/l N/A ug/l N/A ug/1 N/A ug/I Pb - Lead Zn - Zinc Ammonia Nitrogen Yes n/z No ) N/A N/A N/A er (Spe Fluor Ag - Silver Se- Selenium ntration Units) Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No VOC : method# • method# method# N/A N/A N/A N/A N/A ug/I ug/I ug/I mg/I mg/I ug/I ug/I ug/I ug/I (2) 1 certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs I,PArmii ee// (�off�tut`orized Agent Name and Title - Please typ or print /'�/ ,P.ki z C"Q/'�S f/�2f/`o Signature of Permittee (or Authorized Agent) Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): SWW-6 Well Depth: 26.00 ft. Well Diamter: 4 inch Screened Interval: 22.25 ft. to 24.62 ft. Depth to Water Level: 5.73 ft. below measuring point. Measuring Point is 2.58 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) CONTINUOUS Field Analysis: pH 6.0 , Specific Conductance 2017 uMhos Temp. 26.8 oC, Odor NONE Appearance: LT CLDY YELLOW Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery EXPIRATION DATE: UIC X 01/31 /13 Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/26/2010 Date sample analyzed: 10/26/2010 to 11/5/2010 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered Yes n/a COD N/A mg/I Nitrite (NO2 as N) Coliform: MF Fecal Coliform: MF Total N/A N/A (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total 1226 pH (when analyzed) 6.2 TOC 7.8 Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N 45.8 N/A N/A N/A 436.2 N/A N/A N/A /100m1 Nitrate (NO3 as N) /100m1 Phosphorus: Total as P Orthophosphate mg/I units mg/I mg/I mg/I mg/I mg/I mg/I uMhos mg/I mg/I Al - Aluminum Ba - Barium Ca - Calcium Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury No and field acidified Yes nlz No ) N/A mg/l Ni - Nickel N/A mg/I Pb - Lead 129.500 mg/I Zn - Zinc N/A N/A N/A N/A N/A N/A N/A K- Potassium Mg - Magnesium Mn - Manganese N/A N/A N/A N/A N/A mg/I ug/l ug/I ug/1 ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I Ammonia Nitrogen N/A ug/I N/A ug/1 N/A ug/I Other (Specify Compounds and Concentration Units) Fluoride MIBK Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, (Specify test method #. Report attached? Yes VOC mg/I 0.23 mg/I N/A ug/I N/A ug/1 N/A ug/I N/A ug/I HPLC) Attach lab report.) (1) No X (2) : method# : method# method# I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information. including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs PA)m/iVVe coffA%thorized Agent) Name and Title - Please type or print , , Vfti -iss 112 9 //0 Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): Well Depth: 29.50 ft. Well Diamter: Screened Interval: 25.17 ft. to 27.50 ft. Depth to Water Level: 4.65 ft. below measuring point. Measuring Point is 3.00 ft above land surface. GALLONS of water pumped/bailed before sampling: N/A SWW-7 4 inch For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01/31/13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/26/2010 10/26/2010 to 10/26/2010 PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals COD N/A were collected unfiltered Coliform: MF Fecal Coliform: MF Total N/A N/A (Note. Use MPN method for highly turbid samples) Dissolved Solids: Tota pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A N/A N/A N/A N/A N/A N/A N/A mg/1 Nitrite (NO2 as N) /100m1 Nitrate (NO3 as N) /100m1 mg/I mg/I mg/I mg/I mg/I uMhos mg/1 mg/1 Yes n/a Phosphorus: Total as P Orthophosphate Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese No and field acidified Yes n/E No ) N/A mg/1 Ni - Nickel N/A mg/I Pb - Lead N/A mg/I Zn - Zinc N/A m./I Ammonia Nitrogen N/A N/A N/A N/A N/A N/A N/A N/A ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I Other Concentration Units) Ag - Silver Se- Selenium Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC : method# • method# method# N/A ug/I N/A ug/I N/A ug/I mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs P rmitt ( f Authorized Agent) Name and Title - Please type or pri t � .lJ.W,.tip 01 41• rCi'YIS /�2 q Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 from peoric) Well Identification Number (from Permit): CWW-1 Well Depth: 55.00 ft. Well Diamter: 4 inch Screened Interval: 33.27 ft. to 52.68 ft. Depth to Water Level: N/A ft. below measuring point. Measuring Point is 2.25 ft above land surface. GALLONS of water pumped/bailed before sampling: N/A For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01/31/13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: Certification No(s) 10/26/2010 10/26/2010 to 10/26/2010 PCS PHOSPHATE 330 PARAMETERS: (Samples for metals were collected unfiltered COD Coliform: MF Fecal Coliform: MF Total N/A N/A N/A (Note. Use MPN method for highly turbid samples Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N mg/I /100m1 /100m1 mg/I mgll mg/I N/A mg/I N/A mg/I N/A uMhos N/A mg/I N/A mg/I Yes n/a Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Orthophos.hate Cd- Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K- Potassium Mg - Magnesium Mn - Manganese No and field acidified GNP N/A N/A N/A N/A Nt mg/I mg/I mg/1 m./I N/A ug/I N/A ug/I N/A ug/I Ni - Nickel Pb - Lead Zn - Zinc Yes n/z No ) Ammonia Nitro en thetpecify oride Ag - Silver Se- Selenium Sodium N/A ug/I Organics: (GC, GC/MS, HPLC) N/A ug/I (Specify test method #. Attach lab report.) N/A ug/I Report attached? Yes (1) No X (2) N/A ug/I VOC : method# method# method# tion Units) N/A ug/I N/A ugll N/A ug/I mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs P rm ee (of uthorized Agent) Name and Title - Please type or print -6r QinS it/Z9//.. Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-2 Well Depth: 52.15 ft. Well Diamter: 4 inch Screened Interval: 30.57 ft. to 49.82 ft. Depth to Water Level: N/A ft. below measuring point. Measuring Point is 3.00 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01 /31 /13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: Certification No(s) 10/26/2010 10/26/2010 to 10/26/2010 PCS PHOSPHATE 330 10 PARAMETERS: (Samples for metals were collected unfiltered COD N/A Coliform: MF Fecal N/A Coliform: MF Total N/A (Note: Use MPN method for highly Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N mg/I /100m1 /100m1 PI Yes n/a No and field acidified Yes nl2 No ) Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P 0 •.ph CI h N/A mg/I Cd- Cadmium N/A mg/I Chromium: Total N/A mg/I Cu - Copper N/A mg/I Fe - Iron N/A mg/I Hg - Mercury N/A uMhos K- Potassium N/A mg/I Mg - Magnesium N/A mg/I Mn - Manganese N/A mg/I Ni - Nickel N/A mgll Pb - Lead NA/ mg/I Zn - Zinc .6lmrrwnia Ni pecify N/ Y 1 ■ i F7oride N/A 1./1 N/A ug/I N/A ug/l N/A ug/I N/A ug/I N/A ug/I N/A ug/I Ag - Silver Se- Selenium tion Units) Sodium Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes N/A ug/I VOC N/A ug/l (1) No method# method# method# • • N/A ug/I N/A ug/I N/A ug/I mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I X (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs P rmi ee of uthorizeed Agent Name and Title - Please type or print `--4. D or 12015 /// `1 /a Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-3 Well Depth: 53.00 ft. Well Diamter: 4 inch Screened Interval: 36.42 ft. to 50.67 ft. Depth to Water Level: 1.07 ft. below measuring point. Measuring Point is 3.08 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: _ Influent (98) X Effluent (99) N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01 /31 /13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/26/2010 10/26/2010 to 10/26/2010 PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected unfiltered COD Coliform: MF Fecal Coliform: MF Total N/A N/A N/A (Note: Use MPN method for highly t Dissolved Solids: Total pH (when analyzed) TOC '•id s- . ple Li 1, lar Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N mg/1 1100m1 1100m1 Yes n/a No and field acidified N/A Total as P Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: 0 •..ho N/A mg/I Cd- Cadmium N/A mg/I Chromium: Total N/A mg/I Cu - Copper N/A mg/I Fe - Iron N/A mg/I Hg - Mercury N/A uMhos K- Potassium N/A mg/I Mg - Magnesium N/A mg/1 Mn - Manganese LE N/A N/A mg/1 mg/1 mg/I N/ g/ N/ o N/A N/A .I N/A ug/I Ag - Silver N/A ug/I N/A ug/I N/A ug/1 N/A ug/I N/A ug/I N/A ug/I N/A ug/l Yes n!z No ) Ni - Nickel Pb - Lead Zn - Zinc mania Nitr on Units) Se- Selenium Sodium Organics: (GC, GC/MS. HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC : method# : method# method# N/A ug/I N/A ug/I N/A ug/I mg/I N/A mg/1 N/A ug/I N/A ug/I N/A ug/I N/A ugll I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Signature of Permittee (or Authorize Ross M. Smith - Manager, Environmental Affairs mi e,(of Ijuthorizod f4gent) Name and Title - Please type or pr nt )(Or k/Y15 d Agent) (Date GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-4 Well Depth: 53.00 ft. Well Diamter: 4 inch Screened Interval: 41.67 ft. to 50.92 ft. Depth to Water Level: 0.20 ft. below measuring point. Measuring Point is 2.75 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Systems Check One: Influent (98) X Effluent (99) N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery EXPIRATION DATE: UIC X 01 /31 /13 Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/26/2010 Date sample analyzed: 10/26/2010 to 10/26/2010 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected COD N/A Coliform: MF Fecal N/A Coliform: MF Total N/A (Note: Use MPN method for high) urbid samp Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N mg/I /100m1 /100m1 unfiltered Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P 0 hoph. p a e N/A mg/I Cd- Cadmium N/A mg/I Chromium: Total N/A mg/I Cu - Copper N/A mg/I Fe - Iron N/A mg/I Hg - Mercury N/A uMhos K- Potassium N/A mg/I Mg - Magnesium N/A mg/I Mn - Manganese Yes n/a Pb - Lead Zn - Zinc No and field acidified N/A mg/I Ni - Nickel N/A mg/I N/A mg/I /A m•/I Ammonia Ni Specify Yes n/z No ) N/A N/A N/A N uoride N/ . g/I N/A N/A N/A N/A N/A N/A N/A N/A ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I Ag - Silver Se- Selenium Sodium N/A N/A N/A N/A N/A ug/l ug/I ug/l mg/1 mg/1 ug/I ug/I ug/I ug/I Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC : method# method# method# I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs e of thorized gent) Name and Title - Please type or print e of ermittee (or Authorized Agent) Da Signature g ) ( ) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Mom perm Well Identification Number (from Permit): CWW-5 Well Depth: 53.17 ft. Well Diamter: 4 inch Screened Interval: 41.75 ft. to 51.08 ft. Depth to Water Level: 1.80 ft. below measuring point. Measuring Point is 2.58 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Sys ems Check One: Influent (98) X Effluent (99) N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : EXPIRATION DATE: UIC X 01 /31 /13 Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/26/2010 10/26/2010 to 10/26/2010 PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected unfiltered COD N/A Coliform: MF Fecal N/A Coliform: MF Total N/A (Note: Use MPN method for highly turbid sample Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A N/A N/A N/A N/A N/A N/A N/A mg/I Nitrite (NO2 as N) /100m1 Nitrate (NO3 as N) /100m1 Yes Phosphorus: Total as P Orthophos • hat mg/I Cd- Cadmium mg/I Chromium: Total mg/I Cu - Copper n/a No and field acidified Yes n/s No ) N/A mg/I Ni - Nickel N/A mg/I Pb - Lead N/A mg/I Zn - Zinc N/A m•/I Ammonia Ni allIMIE IF u t Ni /I oride N//I ug/I N/A ug/I N/A ug/I N/A mg/I Fe - Iron N/A ug/I mg/I Hg - Mercury N/A ug/I uMhos K- Potassium N/A ug/I mg/I Mg - Magnesium N/A ug/I mg/I Mn - Manganese N/A ug/I he pecify Ag - Silver Se- Selenium N/A ug/I N/A ug/I N/A ug/I mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I Sodium N/A ug/I Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report attached? Yes (1) No X (2) VOC : method# • method# method# I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs Pp mitt e (of 9uthorized Agent) Name and Title - Please ty or rint Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-6 Well Depth: 53.00 ft. Well Diamter: 4 inch Screened Interval: 36.62 ft. to 50.88 ft. Depth to Water Level: 1.67 ft. below measuring point. Measuring Point is 2.92 ft above land surface. GALLONS of water pumped/bailed before sampling: For Groundwater Treatment Systems Check One: Influent (98) X Effluent (99) N/A Field Analysis: pH N/A , Specific Conductance N/A uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES EXPIRATION DATE: UIC X 01 /31 /13 TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: 10/26/2010 Date sample analyzed: 10/26/2010 to 10/26/2010 Laboratory Name: PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected unfiltered COD Coliform: MF Fecal Coliform: MF Total (Note: Use MPN method for highly Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N N/A mg/I Nitrite (NO2 as N) Yes n/a N/A /100m1 Nitrate (NO3 as N) N/A /100m1 Phosphorus: Total as P d -mpl- 0 ••pho •h N/A mg/1 Cd- Cadmium N/A mg/I Chromium: Total N/A mg/1 Cu - Copper N/A mg/I Fe - Iron N/A mg/1 Hg - Mercury N/A uMhos K- Potassium N/A mg/I Mg - Magnesium N/A mg/1 Mn - Manganese No and field acidified N/A N/A N/A N/ N/A •/I mg/I mg/I mg/I N/A ug/I N/A ug/l N/A ug/I N/A ug/l N/A ug/I N/A ug/l N/A ug/I VOC N/A ug/I Ni - Nickel Pb - Lead Zn - Zinc m nia Ni pecify oride Ag - Silver Yes nla No ) Se- Selenium Sodium Organics: (GC, GC/MS, (Specify test method #. Report attached? Yes tion Units) N/A ug/l N/A ug/I N/A ug/l mg/1 N/A mg/1 N/A ug/I N/A ug/I N/A ug/l N/A ug/I HPLC) Attach lab report.) (1) No X (2) method# method# method# I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs er9Nttee (f Authorized Agent) Name and Title - Please ty a or pjint F✓.UV4:.,t 4I lzms /t/Zq //o Signature of Permittee (or Authorized Agent) (Date) GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORTING FORM FACILITY INFORMATION Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division_ Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Jack H. Taylor, Jr. Telephone: (252)322-8155 Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 18 Well Identification Number (from Permit): CWW-7 Well Depth: 53.00 ft. Well Diamter: 4 inch Screened Interval: Depth to Water Level: Measuring Point is 36.58 ft. to 50.83 ft. 1.66 ft. below measuring point. 1.25 ft above land surface. GALLONS of water pumped/bailed before sampling: Field Analysis: pH N/A , Specific Conductance Temp. N/A oC, Odor NONE For Groundwater Treatment Systems Check One: Influent (98) X Effluent (99) N/A N/A uMhos Appearance: CLEAR Mail Original to: DIVISION OF WATER QUALITY GROUNDWATER SECTION -PERMITS AND COMPLIANCE UNIT P.O. BOX 29578 RALEIGH, NC 27626-0578 Phone: (919)733-3221 PERMIT #: WI0700012 Non -Discharge NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery EXPIRATION DATE: UIC X 01/31/13 Spray Field X Remediation : Rotary Distributor Land Application of Sludge Other Note: Values should reflect dissolved and colloidal concentrations Date sample collected: Date sample analyzed: Laboratory Name: 10/26/2010 10/26/2010 to 10/26/2010 PCS PHOSPHATE Certification No(s) 330 PARAMETERS: (Samples for metals were collected COD N/A Coliform: MF Fecal N/A Coliform: MF Total N/A (Note: Use MPN method for highly turbid samples Dissolved Solids: Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N mg/1 /100m1 /100m1 unfiltered Nitrite (NO2 as N) Nitrate (NO3 as N) Phosphorus: Total as P Orthophos • hate N/A mgll Cd- Cadmium N/A mg/I Chromium: Total N/A mg/I Cu - Copper N/A mg/I Fe - Iron N/A mg/I Hg - Mercury N/A uMhos K- Potassium N/A mg/I Mg - Magnesium N/A mg/I Mn - Manganese Yes n/a No and field acidified N/A mg/I Ni - Nickel N/A mg/I N/A mg/I Pb - Lead Zn - Zinc Yes n/z No ) N/A mg/I Ammonia Nitro en ther :.ecify C ride N N/ N/A .•/I N/A ug/I N/A ug/1 N/A ug/I Ag - Silver Se- Selenium Sodium N/A ug/I Organics: (GC, GC/MS, HPLC) N/A ug/I (Specify test method #. Attach lab report.) N/A ug/I Report attached? Yes (1) No N/A ug/I VOC : method# • method# method# on Units) N/A ug/I N/A ug/I N/A ug/I N/A ug/I mg/I N/A mg/I N/A ug/I N/A ug/I N/A ug/I N/A ug/I X (2) I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisionment for knowing violations. NOTE: GW-59 Rev 4/98 Ross M. Smith - Manager, Environmental Affairs 2eX9entNameeand Title - Please type or grin Signature of Permittee (or Authorized Agent) ' (Date) Date: Time: Tech: PCS Phosphate Co., Inc. - Tank Farm Remediation System Quarterly Monitoring //2/46.40 zeL System Gaup Pressures SWW-1 _ jJlP07'i,- /1a0�i, SWW-7 CWW-1 q./ !l,. CWW-7 e'.4'. File: 12-07-02 pc. TLB Ditch a.r«.nc. Pt MU 12.91 Level ael to xeL 70 Barge Slip - Water Level Control Tank %=MSL 10.59 6T /9i% Sand Layer Pelzometers Level Indicators Well ID ' TOC Elevation MSL' TOC _ Ste Wtr Level' Level Relative To -MSL Ft. Well ID TOC Elevation MSL' TOC Stc Wtr Level' Level Relative To MSL Ft. Spz_',.:._ ' 10A7 S 89 (!/,(O Cpz-1 - 10.51 /l. 79/ -,Sl'a3 Spz-2' , ' r. 1121 F/ . 6 %: S.67 �// J4`T Cpz-2 1025 /9t? '7'u'7 Spz t _ 11.7 0. 1O- 1/J`-7. CPz.3 11.12 /7,66 -6- y Spz-4 11.45 .7 9,R t5.L5.3 CPW .. 9.65 /015 .549g .'��'7%,7 -.7 Spz-5 11A5 9 -iV MWTF-1A• - 14.35. Spa 6°-_.-. 1123 !//, 9/7� OA�/J MWTF-1B• 14.36 oi,010 ,g,, 6a Spz-7`.r 11.59 // 46 -0 07 MWTF-1C • 14.44 a/ 95' - 7.67 Spz-8 '.. . 11.57 -//P�i4 Ot�l� MWTF-2A 14.05 6tfl ,�d 7-9 Spz-9 . 11.01 ,,is* Oi1 •/O,h MWTF-2B 14.02. /04.; /9,.f3 .7•3/ -S/sue .. Spz-10. 12.16 995" a. / MWTF-2C 14.08 SPW-:-- ; - 9.95 Tat Ji87 MWTF.3A 1221 5n 82 MWTF-3B 12.18 �/�� t t .5�9j0/ =Zjfl MWTF-3C 12.19 17, - Sand Layer And Croatan Formation Withdrawal Wells WeIIID,:- TOC Elevation - MSL' Max Ste Wtr Level Ft. Pump Activation Depth ReIMSL Max Level Relative To Control Point MSL' Is Well Pumping? ffl os1 Comments SWW-1 . 10:70 ,'A, B0 6' /MSLaFLL !d ,(l(/ +,'to+7 y - - CWW-1 _. 10.60 00 9' - qa0 -2'to -1' Sww-2 9.99 e.9 .Og 6' ofl 40 +1'to+2' Y, CWW2. 1023 eze 9'.. f '<.v. O -2.to-T /1/.. SWW-3 •. 9.97 - se...Q/ 6' • O/f�I2// +1'to+7 tyi CW= W3 925 /t97 Et •/.79 . -2'to-1' SWW4- 1013 6,19 B 0.l - +1'to+2' ii cww:4` :` 10.73 - g/..sg+e, 9' gg -2'to-1' /,V�1 SWW-6 10.50 .l-!�B 6' .-12.,A +1'to+2' CW-5 W 10.74- 441 9' - /•ig17 _2'ro'1' /,"/ SwW-6 10.66 6. -Q57 / +1'to+2' CWW-6 9.92 /71 /(o% 9' '. _2'tp _, ! /N SWW=7.. 10.70 *?6 7 c '/ - +1'to+2' Cww:t 9.95 /��.... 8' - ZJy -2'to-r ,N/ /�/ Revised 7/29/02 • Riser length added to TOC elevation 124/97 D1Data\Fomis\WeII FonntTenkFann Remed Wells is Spz SPZ-1 .4 CPZ-1 OFFICE CUT—OFF WALL Ewws CPZ-2 �� ASPHALT ROAD CWW-T SWWICWW \ 4 SPZ-7 aO 1 MWTF-E CLUSTER / DRAINAGE DITCH PLANT 5 MWTF4 CLUSTER - SPZ-S SPZ-7 Nt. . SI Z D .io,rts WITHDRAWAL WELL ROW TOTALIZERS AND CONTROL VALVES CPZ-3 X SPZ-9 X PIPERACK SPILL CONTAINMENT PAD CONTROL TANK MWTF-1 CLUSTER cm-dO:O1 SPW CWW4 \ SWW4 T 602 064 1 T' M AI it 11 LV Mr m 4YY�r •hr I 1.(41 N I I GI 011111.111M . /r.Yn WI • Y.nNrr. pH N.,I • ...r«.«r. uw.✓or Nuuumwcl WI I • • n...r.N /..nYu r.W WTNm.WW WI II 0 N•.AIAIII.WN.I.W N«1 I.W WI11' .1 «. r.W Wt r r N14«N 111. n II -AMMO 0I4.1•W Arl *All I.VII .WIN..r IAM LOCATION PLAN FOR TANK f ARM AREA REMEDIAL ACTION SYS I I Si WELLS AND PIEZOMETITIL FIGURE 1 PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN OUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR THE INJECTION AND WITHDRAWAL WATER WELLS August 2010 — October 2010 The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north side of the Tank Farm Area. Iniection Water Well System The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system during the period. Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs Department. The total monthly and quarterly volumes of water injected as well as the month end water level in the Water Level Control Tank are: DPW WATER GALLONS TOTAL GALLONS AVERAGE GPM TANK LEVEL FEET, MSL August 1,186,231 0 1,186,231 26.6 15.0 September 682,569 0 682,569 15.8 15.0 October 706,151 0 706,151 15.8 15.0 TOTALS 2,574,951 0 2,574,951 H:\Reports\2010\Quarterly\TFRAS Report Third Quarter 2010.docx 3 • Withdrawal Well System The withdrawal water well pumps are monitored daily by the area Maintenance Department and preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water volumes for the period are: SAND FORMATION GALLONS CROATAN FORMATION GALLONS TOTAL GALLONS AVERAGE GPM August 104,871 0 104,871 2.3 September 189,440 3,182 192,622 4.5 October 275,642 0 275,642 6.4 TOTALS 569,953 3,182 573,136 Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning, and troubleshooting on individual pumps in the fourteen well systems were experienced. Details of these activities are: The air compressor was serviced on 9/1/2001 and 10/13/2010. Confined Sand Formation Withdrawal Well (SWW) Pumps SWW-1: SWW-2: On 10/11 replaced pump. SWW-3: SWW-4: On 9/1 replaced counter. SWW-5: SWW-6: SWW-7: H:\Reports\2010\Quarterly\TFRAS Report Third Quarter 2010.docx 4 • Croatan Formation Withdrawal Well (CWW) Pumps CWW-1: CWW-2: CWW-3: CWW-4: CWW-5: CWW-6: CWW-7: H:\Reports\2010\Quarterly\TFRAS Report Third Quarter 2010.docx 5