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HomeMy WebLinkAboutWI0700035_Application_19990730NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Class 5I Wells In Accordance with the provisions of NCAC Title 15A: 02C.0200 Complete application and mail to address on the back page. t0 U Sm N 0 TO: DIRECTOR, NORTH CAROLINA DIVISION OF WATER QUALITY DATE: July 30 , 1999 A. PERMIT APPLICANT 4- c.n Name: Hamilton Beach/Proctor-Silex, Inc. Attn: Mario Kuhar Address: 4421 Waterfront Drive City: Glen Allen State: VA Zip Code: 23060 County: Henrico Telephone: (804) 527-7222 B. PROPERTY OWNER (if different from applicant) Name: City of Washington, Attn: -City Manager Address: 201 East Second Street City: Washington State: NC Zip Code: 27889 County: Beautort Telephone: (252) 975=9319 C. STATUS OF APPLICANT Private: Commercial: x County: Municipal: Federal: State: Native American Lands: D. FACILITY (SITE) DATA (Fill out ONLY if the Status is Federal, State, County, Municipal or Commercial). Name of Business or Facility: Hamilton Beach/Proctor-Silex, Inc. Address: 234 Springs Road City: Washington Zip Code: 27889 County: Beaufort Telephone: (804) 527-7222 Contact Person: Mario Kuhar E. INJECTION PROCEDURE Provide a detailed description of all planned activities relating to the proposed injection facility including but not limited to: (1) construction plans and materials; See Attachment E (2) operation procedures; and (3) a planned injection schedule. GW-57 REM (May 1998) Page 1 of 5 0 0 7.0rn O n am, 0< D 0 rn0 R1 <nz m73 H O F. DESCRIPTION OF SITE See Attachment F Provide a brief description of the contamination incident and the incident number assigned by the Division of Water Quality staff in the Department's Regional Office: G. HYDROGEOLOGIC DESCRIPTION See Attachment G Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that included the known or projected depth of contamination. The number of borings shall be sufficient to determine the following: (1) the regional geologic setting; (2) (3) (4) (5) significant changes in lithology; the hydraulic conductivity of the saturated zone; the depth to the mean seasonal high water table; and a determination of transmissivity and specific yield of the aquifer to be used for injection (showing calculations). H. MONITORING PROCEDURE See Attachment H Provide plans for proposed location and construction details of groundwater monitoring well network, including a schedule for sampling and analytical methods. Include any modeling/testing performed to investigate injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. I. WELL USE Will the injection well(s) also be used as the supply well(s) for the following? (1) The injection operation? (2) Personal consumption? J. CONSTRUCTION DATA (check one) YES YES NO X NO X EXISTING WELL being proposed for use as an injection well. Provide the data in (1) through (7) below to the best of your knowledge. Attach a copy of Form GW-1 (Well Construction Record) if available. X PROPOSED WELL to be constructed for use as an injection well. Provide the data in (1) through (7) below as PROPOSED construction )rary Injection Points specifications. Submit Form GW-1 after construction. (1) Well Drilling Contractor's Name: Radian Mobile Field Services NC Driller Registration number: TBD (2) Date to be constructed: TBD Approximate depth of each boring (feet): Number of borings: 3, 6 10, 35 GW-57 REM (May 1998) Page 2 of 5 (3) NA Well casing: Type: Galvanized steel_ Black steel_ Plastic Other (specify) Casing depth: From to ft. (reference to land surface) Casing extends above ground inches (4) Grout: NA Grout type: Cement Bentonite _ Other (specify) Grouted surface and grout depth (reference to land surface): around closed loop piping; from to (feet). around well casing; from to (feet). (5) NA (6) NA (7) NA Screens Depth: From to feet below ground surface. N.C. State Regulations (Title 15A NCAC 2C .0200) require the permittee to make provisions for monitoring wellhead processes. A faucet on both influent (recovered groundwater) and effluent (fluid being injected into the well) lines is generally required. Will there be a faucet on the influent line? yes no Will there be a faucet on the effluent line? yes no SOURCE WELL CONSTRUCTION INFORMATION (if different from injection well). Attach a copy of Form GW-1 (Well Construction Record). If Form GW-1 is not available, provide the data in part G of this application form to the best of your knowledge. NOTE: THE WELL DRILLING CONTRACT`ORCAN SUPPLY int DA lA FOREITHER With TING-OR PROPOSED WELLS IF THIS INFORMATION IS UNAVAILABLE BY OTHER MEANS K. OTHER WELL DATA See Attachment.. K Provide a tabulation of data on all wells within ''A mile of the injection well(s), excepting water supply wells serving a single-family residence, which penetrate the proposed injection zone. Such data shall include a description of each well's type, depth, record of abandonment or completion, and additional information the Director may require. L. PROPOSED OPERATING DATA (1) Injection rate: Average (daily) 15-50gallons per minute (gpm) (2) Injection volume: Average (daily)16 , 000 gallons per day (gpd) (3) Injection pressure: Average (daily)100-80Qlounds/square inch (psi) (4) Injection temperature:Average (January) ° F, Average (July) ° F Ambient (5) Hydraulic capacity of the well: NA (6) Expected lifetime of the injection facility: 5 years days (7) Give a description of how the above data will be measured and controlled: Pressure gauges and a control valve. GW-57 REM (May 1998) Page 3 of 5 M. INJECTION -RELATED EQUIPMENT See Attachment M Attach a diagram showing the detailed plans and specifications of the surface and subsurface construction details of the system. N. LOCATION OF WELL(S) See Attachment N Attach a scaled, site -specific map(s) showing the location(s) of the following: (1) the proposed injection well(s); (2) all property boundaries; (3) contour intervals not exceeding two feet; (4) the direction and distance from the injection well or well system to two nearby, permanent reference points (such as roads, streams, and highway intersections); (5) all buildings within the property boundary; (6) any other existing or abandoned wells, including water supply and monitoring wells, within the area of review of the injection well or wells system; (7) potentiometric surface showing direction of groundwater movement; (8) the horizontal and vertical extent of the contaminant plume (including isoconcentration lines and plume cross sections); (9) any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within the area of review of the injection well or well system; and (10) all surface water bodies within 1000 feet of the injection well or well system.. O. INJECTION FLUID DATA (1) Fluid source, if underground, from what depth, formation and type of rock/sedtment unit will the fluid be drawn (e.g., granite, limestone, sand, etc.). NA Depth: Formation: Rock/sediment unit: (2) Provide the chemical, physical, biological and radiological characteristics of the fluid to be injected. See Attachment 0 P. PERMIT LIST Attach a list of all permits or construction approvals that are related to the site, including but not limited to: (1) Hazardous Waste Management program permits under RCRA (2) NC Division of Water Quality Non -Discharge permits (3) Sewage Treatment and Disposal Permits (4) Other environmental permits required by state or federal law. NPDES Permit No. NC0086151 GW-57 REM (May 1998) Page 4 of 5 Q. CERTIFICATION "I hereby certify, under penalty of law, that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the approved specifications and conditions of the Permit." (Signature of Well Owner or Authorized Agent) If authorized agent is acting on behalf of the well owner, please supply a letter signed by the owner authorizing the above agent. R. CONSENT OF PROPERTY OWNER (Owner means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land rests ownership in the landowner in the absence of contrary agreement in writing.) If the property is owned by someone other than the applicant, the property owner hereby consents to allow the applicant to construct each injection well as outlined in this application and that it shall be the responsibility of the applicant to ensure that the injection well(s) conforms to the Well Construction Standards (Title 15A NCAC 2C .0200) L (Signature Of roi wner If Different From Applicant) Please return two copies of the completed Application package to: UIC Program Groundwater Section North Carolina DENR-DWQ P.O. Box 29578 Raleigh, NC 27626-0578 Telephone (919) 715-6165 GW-57 REM (May 1998) Page 5 of 5 Attachment F Description of Site The Abbott Laboratories Laurinburg facility is located on approximately 51 acres of land at the intersection of U.S. Highway 15-501 and U.S. Highway 401 By -Pass in Laurinburg, North Carolina. The facility was constructed by Abbott Laboratories in 1969 and produces medical devices including sets for intravenous administration of drugs and health maintenance solutions. Products are manufactured using polyvinyl chloride and other plastics. The operation of a former solvent disposal pit between 1970 and 1976 resulted in groundwater contamination at this site. Several phases of remediation have been conducted. Property line groundwater intercept wells have been in operation since November 1993. Source area remediation was first conducted in the Fall of 1995 using in situ volatilization (MecTool). Subsequently, a groundwater remediation system consisting of 2-Phase Vacuum Extraction and deep groundwater pumping was constructed to extract dissolved contaminants from the shallow source area (zero to 20 feet below land surface) and the underlying sand and gravel aquifer (20 to 80 feet below land surface). The groundwater remediation system began operation in August 1996. As of February 2000, approximately 835 pounds of contaminant mass had been removed by this remediation system. Throughout this period, remedial performance has been monitored and a number of remedial optimization measures have been implemented. These measures have included: • Upsizing groundwater pumps to maximize contaminant extraction rates; • Rehabilitating extraction wells to maintain well efficiency; • Groundwater modeling to reduce the number of wells required to achieve plume containment at the southern property line; • Pulsing the 2-Phase Vacuum Extraction system to increase the cost effectiveness of shallow contaminant mass removal; • Discontinuing 2-Phase Vacuum Extraction when mass removal from the shallow zone reached asymptotic levels; • Modifying the post closure sampling program to reduce the number of wells sampled, and • Evaluating the potential of monitored natural attenuation (MNA) as an alternative remedial strategy for this site. Remedial action at this site has been effective at reducing the mass, concentration, and mobility of contaminants. The groundwater contaminant plume is shrinking. Yet, groundwater contaminant concentrations in the source area remain more than two orders of magnitude greater than clean up levels. The current pump and treat system continues to extract more than 10 pounds of contaminants per month, but progress toward achieving clean up levels is slow. It F-1 Attachment K Other Well Data Well Id Date Installed Date Abandoned Total Depth Screened Interval Casing Diameter 2P-1 1/17/1996 NA 20 5-20 4 2P-2 1/17/1996 NA 20 5-20 4 2P-3 1/10/1996 NA 20 5-20 4 2P-4 1/10/1996. NA 20 5-20 4 2P-5 1/10/1996 NA 20 5.20 4 2P-6 I/10/1996 NA 20 5.20 4. 2P-7 I/10/1996 NA 20 5.20 4 EW-I 6/9/1994 Sept -Nov 1995' 19.3 8.9 - 18.9 4 EW-2 1/9/1995 NA 15 9.9 - 14.9 4 MW-la 3/7/1990 Sept -Nov 1995' 14.1 4.1 - 14.1 2 MW-lb 3/7/1990 7/23/1990 18.6 15.6 - 18.6 2 MW-2 3/8/1990 NA 14.6 4.6. 14.6 2 MW-2b 7/26/1990 NA 23:7 18.7 - 23.7 2 MW-3 3/8/1990 Sept -Nov 1995' 14 4-14 2 MW-4 3/7/1990 Sept -Nov 1995' 14.1 4.1 - 14.1 2 MW-5 3/6/1990 NA 33 23.33 2 MW-6a 7/23/1990 NA 10 5-10 2 MW-6b 7/25/1990 NA 19 14-19 2 MW-7a 7/27/1990 NA 10.4 5.4 - 10.4 2 MW-76 7/26/1990 NA 21 16-21 2 MW-7d 7/19/1991 NA 43 34-43 2 MW-8a 7/26/1990 NA 8.8 3.8 - 8.8 2 MW-8b 7/26/1990 NA 16 13.0 - 16.0 2 MW.8d 2/3/1992 NA 57.2 48.2.57.2 2 MW-9a 7/24/1990 NA 10.6 5.6. 10.6 2 MW-9b 7/23/1990 NA 20 15-20 2 MW-l0a 7/26/1990 NA 10.8 5.8 - 10.8 2 MW-10b 7/24/1990 NA 26.5 16.5.26.5 2 MW-I0d 1/17/1996 NA 40 30-40 2 MW-II 7/27/1990 NA 33 28.0 - 33.0 2 MW-lld 7/25/1990 NA 80.1 65.1 - 80.1 2 MW-12b 7/19/1991 NA 14.6 5.6 - 14.6 2 MW-13b 7/18/1991 NA 18.3 9.3 - 18.3 2 MW-14b 7/19/1991 Oct-95 16 7.0 - 16.0 2 MW-15b 7/17/1991 NA 38.6 29.6.38.6 2 MW-I5d 7/16/1991 NA 77.5 68.5 -77.5 2 MW-I6b 7/17/1991 NA 24.25 15.25-24.5 2 MW-I6d 7/18/1991 NA 71.5 62.5 - 71.5 2 MW-17b 7/18/1991 NA 34.5 25.5 - 34.5 2 MW-18b 2/5/1992 NA 14.5 5.5 - 14.5 2 MW-18d 2/7/1992 NA 57.1 48.1 -57.1 2 MW-19b 4/24/1992 NA 25 - 15-25 2 MW-19d 4/27/1992 NA _ 73.8 63.8 - 73.8 2 MW-20b 4/28/1992 NA 27 17.27 2 MW-20d 4/27/1992 NA 78 68 - 78 2 MW-21b Oct-95 NA 25 7.0- 16.0 2 MW-23b 1/17/1996 NA 20 8.20 2 MW-23d 1/17/1996' NA 40 30-40 2 MW-24b 1/11/1996 NA 20 10-20 2 MW-25b 1/11/1996 NA 20 10-20 2 MW-26b 1/11/1996 NA 20 10-20 2 MW-27d 1/11/1996 NA 40 30-40 2 OW-1 6/4/1994 • Sept -Nov 1995' 19.35 14.3 - 19.0 2 OW-2 6/8/1994 Sept -Nov 1995' _ 19.2 14- 18.7 2 OW-3 6/8/1994 Sept -Nov 1995' . 19.2 14- 18.7 2 OW-I0 1/9/1995 NA 15 10-15 2 OW-15 1/10/1995 NA 15 10-15 2 OW-30 1/10/1995 NA 15 10-15 2 OW-50 1/10/1995 NA 15 '10-15 2 RW-1 7/24/1990 Sept -Nov 19951 18.2 15.7 - 18.2 2 RW-2 Oct-93 NA 71 31-71 4 RW-3 Oct-93 NA 71 31.71 4 RW-4 1/17/1996 NA 75 35 .75 4 RW-5 1/16/1996 NA 75 35-75 4 RW-6 1/17/1996 NA 75 35-75 4 RW-7 1/17/1996 NA 75 33-75 4 Well destroyed during in -place volatilization remediation effort. 2P = 2-Phase extraction well. EW = Extraction well. M W = Monitoring well. OW =Observation well. RW = Recovery well. Attachment N Potentiometric Surface Maps See attachment G for maps depicting the potentiometric surface showing the direction of groundwater movement. These maps are from 1990 through 1992 prior to initiation of remediation efforts on the site. They reflect the natural groundwater flow conditions at the site that are not altered by the current remediation system. The remediation system will be shut off during the pilot -scale test. Therefore, these potentiometric surface maps depict the flow conditions as they will be during the pilot -scale test. Attachment 0 Injection Fluid Data The technology chosen to cleanup chlorinated solvent contamination in the groundwater depends on reductive dechlorination and utilizes activated iron powder (Zero Valent Iron) as an electron donor. The iron powder is mixed with water, molasses, and a thixotropic agent is added in order to control slurry viscosity. In general, slurry properties and composition will remain fairly constant, containing: - 1. Water 2. Thixotropic Agent 3. Iron Powder 4. Molasses 69%to 91.8% 0.2%to1% 3 % to 20 % 5% to 10% Note: Fluid viscosity is expected to range from 1500 cp to approximately 5000 cp. The above composition is expressed as weight percent. Thixotropic agents typically employed include Guar Gum or a high molecular weight water-soluble acrylamide polymer. These materials are non -toxic biodegradable products that are widely used throughout industry from foods to mining and waste water treatment. Attachment P Permit List 1. Permit to Discharge Remediated Groundwater as Wastewater under the Pretreatment Program - Pretreatment Permit No. NC0020656-0002 2. Stormwater Discharge General Permit — Permit No. NCG030000 3. Air Permit — Permit No. 3921R6 is appropriate at this time to evaluate alternative remedial action technologies that have the potential to achieve site closure, while minimizing the life cycle cost of remedial action. This site is regulated by the Division of Waste Management, Superfund Section, Inactive Sites Branch under case # NO NCD 000 0040. F-2 Excerpt from : Pre -Construction Report, October 1995 (Radian Engineering) 2.0 FIELD ACTIVITIES Radian performed field activities for the pumping test between January 9 and January 27, 1995. These activities included well installation, water level measurement, and a three-day pumping test. This section describes the procedures used to perform the test. 2.1 . Well Installation Radian installed an extraction well (EW-2) and four observation wells (OW-10, OW-15, OW-30, and OW-50) prior to conducting the pumping test. The wells were installed by Carolina Drilling under the supervision of an on -site geologist on January 9 and 10, 1995. Well EW-2 was drilled to a depth of 15 feet and screened from 9.9 to 14.9 feet below ground level within a predominantly clayey sand interval. Well EW-2 was constructed with five feet of 4-inch diameter 0.010-inch slot wire -wound stainless steel screen and ten feet of 4-inch diameter PVC casing. Each observation well was drilled to a depth of 15 'feet and screened from 10 to 15 feet below ground level. The wells were constructed with 5 feet of 2-inch diameter, 0.010-inch machine -slotted PVC screen and 10 feet of 2-inch diameter PVC casing. All of the observation wells were screened within the same clayey sand interval as the extraction well. The well network was configured as shown in Figure 1. Three observation wells were installed north of the extraction well at radii of 10, 30, and 50 feet. The fourth observation well was installed 15 feet west of the extraction well to measure the degree of isotropy associated with the uppermost aquifer unit. Attachment G.doc 2-1 MW-1 LEGEND O Monitoring Well A Aquifer Test Extraction Well o Aquifer Test Observation Well MW-3 0 O OW-50 O OW-30 O 0W-10 d A EW-2 OW-1.5 MW-8B eMW-8D MW-8A SCALE IN FEET 3 0 so 0 Figure 1. Aquifer Test Extraction Well and Observation Well Locations Abbott Laboratories, Laurinburg, NC AC-1097 2-2 2.2 Pumping Test On Monday, January 23, 1995, Radian mobilized to the site to conduct the pumping test. The 2-PHASE Extraction system and a mobile air stripper (provided by Four Seasons Environmental) were set up and wired. Static water levels were measured in the extraction well, observation wells, and nearby monitoring wells and recorded. Pressure transducers were installed in wells OW-10 and OW-50 and connected to a data logger to continuously record water level data. The test was started at 12:52 PM on Tuesday, January 24. Water levels were measured and recorded at two minute intervals in observation wells OW-10 and OW-50 using the pressure transducers and data logger. Water levels in OW-15, OW-30, and MW-3 were measured periodically using an electric water -level probe and recorded manually on data sheets. Flow measurements and other operating parameters for the 2-PHASE system were also routinely recorded. The 2-PHASE system was stopped briefly for a period of approximately one minute during the afternoons of January 25 and January 26 to check the vacuum pump oil level. The test was terminated at 9:10 AM on January 27 after 68.28 hours. The 2-PHASE system was set up to achieve 10.5 feet of drawdown in the extraction well. The initial flow rate out of the well was 0.54 gallons per minute (gpm) and the flow rate at the end of the pumping test was 0.27 gpm. A total of 1,469 gallons of water was removed during the pumping test; therefore, the average flow rate over the entire test was 0.36 gpm Well construction records and schematics are provided in Appendix A. 2.2 Pumping Test On Monday, January 23, 1995, Radian mobilized to the site to conduct the pumping test. The 2-PHASE Extraction system and a mobile air stripper (provided by Four Seasons Environmental) were set up and wired. Static water levels were measured in the Attachment G.doc 2-3 extraction well, observation wells, and nearby monitoring wells and recorded. Pressure transducers were installed in wells OW-10 and OW-50 and connected to a data logger to continuously record water level data. The test was started at 12:52 PM on Tuesday, January 24. Water levels were measured and recorded at two minute intervals in observation wells OW-10 and OW-50 using the pressure transducers and data logger. Water levels in OW-15, OW-30, and MW-3 were measured periodically using an electric water -level probe and recorded manually on data sheets. Flow measurements and other operating parameters for the 2-PHASE system were also routinely recorded. The 2-PHASE system was stopped briefly for a period of approximately one minute during the afternoons of January 25 and January 26 to check the vacuum pump oil level. The test was terminated at 9:10 AM on January 27 after 68.28 hours. The 2-PHASE system was set up to achieve 10.5 feet of drawdown in the extraction well. The initial flow rate out of the well was 0.54 gallons per minute (gpm) and the flow rate at the end of the pumping test was 0.27 gpm. A total of 1,469 gallons of water was removed during the pumping test; therefore, the average flow rate over the entire test was 0.36 gpm Attachment G.doc 2-4 4.0 PUMPING TEST RESULTS Water levels from the four observation wells and monitoring well MW-3 were measured at regular intervals. These water level data were plotted to prepare a hydrograph for each well as shown in Figures 2 through 6. The hydrographs show that some degree of hydraulic influence was evident in each well. Approximately one foot of drawdown was achieved in the nearest wells, decreasing to approximately 0.1 feet at well MW-3 located more than 100 feet upgradient of the extraction well. During the first 18 to 24 hours of the test, a consistent drawdown was noted in each well. After 24 hours, water levels in the wells began to fluctuate. These fluctuations are attributed to a decrease in the pumping rate and, possibly, to groundwater recharge from rainfall and melting snow cover. 4.1 Analytical Procedures The principal model used to analyze the pumping test data is that of a semi - confined (leaky confined) aquifer with no storage in the confining layer. Time-drawdown data were analyzed for observation wells OW-10, OW-15, and OW-50. Governing equations and type curves are those presented by Hantush and Jacob (1955). Type curves were fit to measured drawdown data by nonlinear least -squares parameter estimation using AQTESOLV software developed by Geraghty and Miller Modeling Group. AQTESOLV provides solutions for the analysis of pumping test data in a user-friendly, menu -driven format. The analysis was tested by also modeling the data from the same three observation wells as an unconfined aquifer having an initial elastic response with the potential for delayed yield. Governing equations and type curves for this case are those presented by Neuman (1975). As in the semi -confined case, type curves were, fit to the measured drawdown by the least -squares method using AQTESOLV software. Input to the two aquifer models, in addition to the measured drawdown, is summarized in Table 1. Attachment G.doc - 4-1 -3.6 -3.7 -3.8 a -3.9 a> i 4- -4 -4 1 -4.2 o -4.3 -4.4 -4.5 -4.6 Figure 2 Hydrograph - OW-10 0 6 12 18 24 30 36 42 48 54 60 66 72 Cumulative Time (Hours) 4-2 i -3.8 -4 Figure 3 Hydrograph - OW-15 'W -4.2 -4.4 n o, -4.6 to 1.0 0 -4.8 -5 - 0 6 12 18 ' 24 30 36 -42 48 - - Cumulative Time (Hours) — Interpolated Depth IN Measured Depth 54 60 66 4-3 -3 -3 -3 -3 Figure 4 Hydrograph - OW-30 .0 -4.3 .6 . .7 , .8 ^ 9 .1 .2 8 18 Cumulative Time (Hours) — Interpolated Depth • Measured Depth 4-4 -2.9 —3 —3.1 m i —3.2 CT) Y es —3.3 0 — 3.4 a o 3.5 —3.6 Figure 5 Hydrograph-.OW-50 —3.7 0 \ThiVall""44"*"\ \1/4 6 12 18 24 30 36 42 48 54 60 66 72 Cumulative Time (Hours) Recorded Depth 4-5 -4. -4 Figure 6 Hydrograph - MW-3 oo 58 1..6 62 66 .68 4.7- - - — .- — — as ... .0 e. CI. CC Cumulative Time (Hours) — Interpolated Depth ■ Measured Depth 4-6 TABLE 1 MODEL INPUT USED TO CALCULATE AQUIFER CONSTANTS Abbott Laboratories, Laurinburg, North Carolina January 24-27, 1995 Model Input Data Used Analysis as a Semi -Confined Aquifer Q Average flow rate for the test used (Total flow/test duration). r Distance from extraction well to observation well as measured in the field. rc Casing radius equal to 1 inch (2 inch diameter). rw Borehole radius equal 4 inches (8 inch diameter). Analysis as an Unconfined Aquifer Q Average flow rate for the test used (Total flow/test duration). r Distance from extraction well -to observation well as measured in the field. b Aquifer thickness estimated as depth to confining layer minus depth to water (approximately 11 feet). 4.2 Results The results of analyses are summarized in Table 2. Graphs showing the relationship -between -measured -data -and -type -curves ate provided-inAppendix-A—Hydraulic conductivity values for the semi -confined model range from 4.6 x 104 cm/sec to 8.8 x 10-4 cm/sec with a harmonic mean of 6.4 x 104 cm/sec. The hydraulic conductivity values for the unconfined aquifer model range from 7.4 x 104 cm/sec to 9.7 x 104 cm/sec with a harmonic mean of 8.2 x 104 cm/sec. Relationships between measured drawdown data and type curves for the individual wells are -discussed -below. 4.2.1 Well OW-10 Well OW-10 is located 10 feet north of the extraction well. The response to pumping is indicated as a log -log plot of time versus drawdown (Appendix A). The data was analyzed using a type curve with a r/B ratio of 0.40. The best fit to the type curve as determined by the least squares method gave a hydraulic conductivity value of 4.6 x 10-4 cm/sec. Attachment G.doc 4-7 TABLE 2 AQUIFER CONSTANTS CALCULATED FROM PUMPING TEST DATA Abbott Laboratories, Laurinburg, North Carolina January 24-27,1995 Aquifer Parameter Observation Well Harmonic Mean OW-10 I OW-15 OW-50 Analysis as a Semi -Confined Aquifer Transmissivity (T) (ft2/min) 9.9x10-3 1.9x10"2 , 1.6x10-2 1.4x10-2 Storativity (S) 7.8x10'3 1.2x10"3 2.0x10"3 2.1x10"3 r/B 0.40 0.12 0.24 -- Hydraulic Conductivity (K) (cm/sec) 4.6x104 " 8.8x10-4' 7.4x104 6.4x104 Analysis as an Unconfined Aquifer Transmissivity (T) (f/min) 1.6x10"2 2.1x10.2 1.7x10'2 1.8x10-2 Storativity (S) 7.5x10-3 1.3x10"3 2.0x10"3 2.1x10"3 Specific Yield (Sy) 4.3x10"2 8.8x10"3 6.9x10d -- P 1.0x10"3 1.0x104 1.0x10'3 -- Hydraulic Conductivity (K) (cm/sec) 7.4x10- 9.7x104 7.9x10"4 8.2x10-0 For comparison purposes, the data was also analyzed as an unconfined aquifer with delayed yield using a type curve with a (i value of 0.001. The best fit to the type curve gave &hydraulic conductivity_xalue of 7.4 x 104 cm/sec. 4.2.2 Well OW-15 Well OW-15 is located 15 feet west of the extraction well. The response to pumping is indicated as.a log -log plot of time versus drawdown (Appendix A). The data was analyzed using a type curve with a rB ratio of 0.12. The best fit to the type curve as determined by the least squares method gave a hydraulic conductivity value of 8.8 x 104 cm/sec. This value is associated with a well that is located perpendicular to a line formed by wells OW-10 and OW-50, suggesting that only a slight degree of anistropy (about 0.1 orders -of -magnitude) is inherent in the aquifer tested. For comparison purposes, the data for well OW-15 was also analyzed as an unconfined aquifer with delayed yield using a type curve with a R value of 0.001. The best fit to the type curve gave a -hydraulic conductivity value of 9.7 x 104 cm/sec. Attachment G.doc 4-8 4.2.3 Well OW-50 Well OW-50 is located 50 feet north of the extraction well. The response to pumping is indicated as a log -log plot of time versus drawdown (Appendix A). The data was analyzed using a type curve with a r/B ratio of 0.24. The best fit to the type curve as determined by the least squares method gave a hydraulic conductivity value of 7.4 x 104 cm/sec. For comparison purposes, the data was also analyzed as an unconfined aquifer with delayed yield using a type curve with a R value of 0.001. The best fit to the type curve gave a hydraulic conductivity value of 7.9 x 104 cm/sec. 4.3 Discussion Although the amount of drawdown in the observation wells was small, the results of the pumping test appear to be reasonably representative. Hydraulic conductivity values obtained for the three observation wells show good agreement. Also, the harmonic mean of the pumping test -derived hydraulic conductivity values show acceptable agreement with the harmonic mean of hydraulic conductivity values obtained from slug tests conducted in comparably screened monitoring wells during the remedial investigation. As expected, the hydraulic conductivity value from the slug tests (1.7 x 10-4 cm/sec) is lower than the value calculated for pumping test (6.4 x 104). Nevertheless, the results are within 0.4 orders of magnitude. Although the pumping test provided internally consistent hydraulic conductivity values, the fit between the type curves and measured data was not perfect. Differences between the measured drawdown and the type curves may be attributed to a number of factors including differences between assumed and actual aquifer conditions; changes in the pumping rate during the test; and precipitation effects. Attachment G.doc 4-9 APPENDIX A PUMPING TEST SOLUTIONS Abbott Laboratories Project No.: Client: Abbott Laboratories 654-045-11-01 Location: Laurinburg, North Carolina OW-10 Confined/Leaky Aquifer Drawdowh (ft) 10. 0.1 0.01 I I 1 Hfl1 I I I 1 11111 I I I I 1 1III I I I I I II 0.001 1. 10. 100. 1000. Time (min) 10000. DATA SET: owlocon.Olt 03/0B/91 AQUIFER TYPE: Leaky SOLUTION METHOD: wntufl TEST DATE: January 24-27. 1995 TEST HELL: EV-2 OBS. WELL: OW -10 ESTIMATED PARAMETERS: T - 0.009t ft2hln s - 0.007a_'a r/9- 0.400 TEST DATA: 0 - 0.040 ft3/w1n r - 10.2 ft re - 0.167 ft rw - 0.333 It Radian Corporation Project No.: 654-045-11-01 Client: Location: Abbott Laboratories Laurinburg, North Carolina OW-15 Confined/Leaky Aquifer Drawdowh (ft) 100. 10. 1. 0.1 1 I 1 1 1 1 1 1 I 1 1 1 11IIII 1 1 1 1 111 1 I I I I11± 0.01 el, I l I I I_i_L 1 1 1 1 1 111 1_1 1 1 1 111 1 1 1 1 1 111 1. 10. 100. 1000. 10000. Time (min) DATA SET: 0k15con.eat 03/09/95 AQUIFER TYPE: Leaky SOLUTION METHOD: H.ntue0 TEST DATE: J.nu.ry 24-27. 1995 TEST NELL: EV-2 OBS. WELL: 0.-15 ESTIMATED PARAMETERS: T - 0.01888 ft2/.18 5 - 0.00123 rifts 0.s27A TEST DATA 0 - 0.040 ft3/.tn r - 13.4 ft re-.0.167 It rw - 0.333 It i�. :1Z d k. a 4 =L ;,•9r 1, t. 1f 2•i r " xl Y -04 �ryll1�• • t. • • 4 •.tr .44 ri • •I_p. • 4- 1' '(r,f' t MA 4IP--.ti • t" _ kk I'•• _ �;>t :• 71 Radian Corporation Project No.: Client: Abbott Laboratories 654-045-11-01 Location: Laurinburg, North Carolina OW-50 Confined Leaking Aquifer 10. 0.01 10. • 1 1 1 1 1 1 11 1 1 1 1 1 1 14-- I ,1, 1 1 1 1 1I; I I 1 I Intl I 1 1 1 1 1 I I 100. 1000. 10000. Time (min) DATA SET: ok50con.0at 03/09/95 AQUIFER TYPE: Leaky SOLUTION METHOD: Mantuan TEST DATE: January 24-27. 1995 TEST WELL: Ell-2 OBS. WELL: ON-50 ESTIMATED PARAMETERS: T - 0.01894 ft2/.In 9 - 0.001997 rill- 0.2335 TEST DATA: 0 - 0.048 ft3/.In r - AAA ft rc - 0.167 It rw - 0.333 It Cl Sent: Abbott Laboratories Radian Co. )oratio-n Project No.: 654-045-11-01 Lace font Laurinburg, North Carolina OW=10 Unconfined Aquifer Drawhown (ft) 10. 0.1 0.01 0.001 1. 1 1 1 11111 10. 1 1 1 11111 I 1 1 I ITTll 1 1 1 I I I1± 1 1 1 11111 1 I 1 ll1U 100. 1000. Time (min) 1 I 111111 10000. DATA SET: 02/21/95 AQUIFER TYPE: Unroof tne0 SOLUTION METHOC: Neufn ESTIMATED PARAMETERS: i - 0.01576 ft2/etn S - 0.007476 Sy - 0.04277 e - 0.001 TEST DATA: O - 0.04E ft'/n1n ✓ - 10.2 ft e -11. ft Radian Cc poration Client: Abbott Laboratories Project No.: 654-045-11-01 Location: Laurinburg, North Carolina OW-15 Unconfined Aquifer 100. _ 1 1 1-1 11111 1 1 1 111111 1 1 1 111 10. 0.1 0.01 1. 11 'mil 1 1 1 lilil 100. 1000. Time (min) 1 1 1 1111 10000. DATA SET: 0e15un.aat 02/20/95 AQUIFER TYPE: Unconnnea SOLUT ION METHOD: Nauman TEST DATE: January 24-27. 1995 TEST WELL: EM-2 OBS: WELL: 0M-15 ESTIMATED PARAMETERS: T - 0.0211 tt2/aln 5 - 0.001266 Sy - 0.006812 r- 0.001 TEST DATA: 0 - 0.046 eta/aln r - 13.4 et b - 11.1 et Radian ( 9rporatiori client: Abbott Laboratories Project No.: 654-045-11-01 Location: Laurinburg, North Carolina OW-50 Unconfined Aquifer 10. tct c1 0.1 0.01 I I I I I I11 I I .I I I I I4-- I I 11111 I I I I I I I 10. 100. 1000. Time (min) 10000. DATA SET: 0w5Oun.out 02/27/95 AQUIFER TYPE: Unconf lned SOLUTION METHOD: Neuman TEST DATE: January 24-27. 1995 TEST WELL: EW-2 OSS. WELL: ON-50 ESTIMATED PARAMETERS: T-.0.01671 ft2/N1n S - 0.001971 Sy - 0.0006899 - 0.001 TEST DATA: O - 0.01e ft3/m2n ✓ - AS.9 ft 9 - 11. ft APPENDIX A SCHEMATIC SHOWING GENERALIZED GEOLOGIC PROFILE WEST Fine to Coarse Sand :JQV HORIZONTAL 0 mM 0 • 200 SCALE IN FEET OM OW Q V OM NN NN as as 0.37 LOCI OLO 1000 OM OLO nNN Inn NN NM =NN NN as as aaa as yr 'V ri 0.32 0.46 = = - 0.50 0.57= 0.95 Clay 0.7: 11.64 0.33 0.59 EAST GRADE Silty to Clayey Sand and Clay Clay with Sand Lenses Value opposite well screen represents maximum drawdown measured in feet. Schematic Showing Generalized Geologic Profile and Maximum Drawdown Measured in Observation Wells X-SECT ea HYDRAULIC TESTING PROCEDURES AND CALCULATIONS (PRINCIPAL AQUIFER) Excerpt from: Pumping Test Results, Well RW-7, July 1996 (Radian Engineering) 4.0 PUMPING TEST RESULTS This section presents the results of the step-drawdown and constant -rate pumping tests. The step-drawdown test, which took place on March 8, 1996, was conducted to select a pumping rate for the constant -rate test. It is discussed in Section 4.1. The constant -rate test, which took place from March 11 to 14, was conducted to determine the hydraulic characteristics of the sand aquifer. It is discussed in Section 4.2. 4.1 Step-Drawdown Pumping Test The results of the step-drawdown test are illustrated in Figure 4-1 and are summarized in Tables 4-1 and 4-2. Hydraulic response to groundwater extraction is manifested as changes in water level corresponding to the rate of pumping over the period during which pumping occurs. Figure 4-1 shows the water -level changes (drawdown) measured in the pumping well, RW-7, for five different pumping rates (steps). The pumping rate was increased during each successive step and maintained at that rate for 60 minutes before commencing to the next step. The graph illustrates the increase in drawdown resulting with each successive step. Each step is characterized initially by a relatively rapid increase in drawdown followed by a relatively stable pumping water -level. The fluctuation in drawdown note in the third step was due to a valve adjustment required to maintain the pumping rate (Q) at 5 gallons per minute (gpm). The final step was performed at a pumping rate of 9 gpm and resulted in a drawdown of 19.60 feet compared to the available drawdown of 20.3 feet based on the pump's depth in the well. Consequently, a pumping rate of approximately 9 gpm represents the well's maximum sustainable yield under the test conditions. Table 4-1 summarizes the hydraulic response measured in RW-7 during each of the five -one -hour steps. The table also includes the specific capacity calculated for each step. Attachment G.doc 4-1 Z-b a Drawdown (ft below static level) O 01 J O bl O 0 g S TABLE 4-1 SUMMARY TABLE OF STEP-DRAWDOWN PUMPING TEST RESULTS Abbott Laboratories Laurinburg, North Carolina Step Total Time (minutes) Discharge (gpm) Drawdown Specific Capacity (gpm/ft-dd) 1 60 1.0 2.15 0.47 2 120 2.0 4.82 0.42 3 180 5.0 - 11.24 0.45. 4 240 7.5 16.71 0.45 5 300 9.0 19.60 0.46 gpm/ft-dd = Gallons per minute per foot of drawdown TABLE 4-2 HYDRAULIC RESPONSE OF SELECTED OBSERVATION WELLS TO THE STEP-DRAWDOWN PUMPING TEST Abbott Laboratories Laurinburg, North Carolina Observation Well Distance from Pumping Well (ft) Screen Interval (ft above msl) Hydraulic Response PZ-2B 10 213 - 203 No response measured. PZ-2D 11 179 - 169 Response measured 1.2 minutes after pumping commenced. Drawdown after 300 minutes was 0.34 feet. PZ-3B 76 213 -.203 No response measured. PZ-3D 77 176 -166 No response measured. MW-10A 98 224 - 219 No response measured. I MW-10B 95 213 - 203 No response measured. Attachment G.doc 4-3 Changes in water level were also monitored in six observation wells to assess the rate at which the hydraulic response propagated through the sand aquifer and to provide a preliminary assessment of the radius of influence associated with a short period of pumping. The observation wells monitored during the step-drawdown test included PZ-2B, PZ-2D, PZ-3B, PZ-3D, MW-10A, and MW-10B. The, results of the water -level monitoring are summarized in Table 4-2. The hydraulic response in PZ-2D was measured nearly immediately within 1.2 minutes of test initiation. The rapidity of the response supports the assumption that the sand aquifer is semi -confined. The absence of hydraulic response in all wells but PZ-2D is attributed to the fact that the step-drawdown test was initiated shortly after the intercept well system had been shut off. Consequently, water levels in the area were still recovering and masked any response associated with the pumping of well RW-7. This conclusion is supported by the measurement of hydraulic response in these wells shortly after pumping was initiated during the subsequent constant -rate test. Other factors contributing to the absence of a hydraulic response in some of the observation wells may include the presence of the discontinuous clay layer and possible recharge associated with rainfall occurring on the day of the step-drawdown test. 4.2 Constant -Rate Pumping Test The constant -rate pumping test was conducted for approximately 70 hours at an average pumping rate of 7.7 gpm with a maximum drawdown of 16.32 feet. The greatest responses to pumping well RW-7 were recorded in observation wells PZ-2D and -3D. Therefore, time-drawdown data from these two wells were selected to analyze the hydraulic characteristics of the sand aquifer. Hydraulic responses to pumping were also recorded in the other observation wells; however, the effects appear to have been dampened by the clay layer located between the intake of the pumping well and the observation well screens. Section 4.2.1 discusses the'analytical procedures used to calculate the hydraulic characteristics of the sand aquifer and Section 4.2.2 discusses the results of the test. Attachment G.doc 4-4 4.2.1 Analytical Procedures The principal model used to analyze the pumping test data for observation wells PZ-2D and -3D is that of a semi -confined (leaky) aquifer with no storage effects in the confining layer. Governing equations and type curves are those presented by Hantush and Jacobs (1955) with a correction applied for partial penetration of the observation wells (Hantush, 1961). Type curves were fit to measured drawdown data by nonlinear least -squares parameter estimation using AQTESOLV software developed by Geraghty and Miller Modeling Group (Duffield, 1991). Input to the aquifer model, in addition to the measured drawdown, is summarized in Table 4-3. Results are discussed in the next section. TABLE 4-3 MODEL INPUT USED TO CALCULATE HYDRAULIC CHARACTERISTICS CONSTANT -RATE PUMPING TEST Abbott Laboratories Laurinburg, North Carolina Model Input Data Used Analysis as -Confined -Aquifer Q -a -Semi Average pumping rate for the test used(Total flow/test duration). r Distance from pumping well to observation well. ra Casing radius. r,,. Borehole radius. b Aquifer thickness. Time-drawdown data measured in the other observation wells were analyzed qualitatively to estimate the radius of influence developed by pumping well RW-7. These results are also discussed in -the .next -section.- - 4.2.2 Results The results of analyses are summarized in Table 4-4. The harmonic mean of transmissivity and storativity are 1.05 ft2/min and 3.7 x 104, respectively. The mean transmissivity equates to a hydraulic value of 8.9 x iOE3 cm/sec. These values are consistent with a semi -confined aquifer comprised of fine to medium sand. Attachment G.doc 4-5 TABLE 4-4 HYDRAULIC CHARACTERISTICS CALCULATED FROM PUMPING TEST DATA Abbott Laboratories Laurinburg, North Carolina March 11-14,1996 Aquifer Parameter Observation Well Harmonic Mean PZ-2D PZ-3D Analysis as a Semi -Confined Aquifer Transmissivity (T) (fP/min) 0.94 1.18 1.05 Storativity (S) 1.7x104 2.4x10' 3.7x104 rB 0.022 0.017 -- Hydraulic Conductivity (K) (cm/sec) 8.0x104 1.0x10-2 8.9x10-3 Hydrographs showing drawdown plotted versus time since pumping began are included at Figures 4-2 and 4-4, and graphs showing the relationship between recorded time- drawdown data and the Hantush leaky aquifer type curves are provided as Figures 4-3 and 4-5. Relationships between measured drawdown data and type curves for the two observation wells are discussed below. Well PZ-2D a Well PZ-2D is located 10 feet east of the pumping well. Figure 4-2 is a hydrograph illustrating drawdown in PZ-2D plotted versus time. The hydrograph shows that the effect of pumping well RW-7 was evident almost immediately in PZ-2D. The rate of drawdown was most rapid in the initial 360 minutes but continued at a lesser rate throughout the test, attaining a final -level of 0.-76-feet below static conditions. The hydrograph also illustrates the recovery toward static conditions after pumping was terminated. The response to pumping is indicated as a log -log plot of time versus drawdown (Figure 4-3). The data was analyzed using a type curve with a r/B ratio of 0.022. The best fit to the,type curve as determined by the least squares method gave a transmissivity of 0.94, ft2/min and a storativity of 1.7 x 10-3. From the transmissivity, the hydraulic conductivity of the aquifer at PZ-2D was calculated to be 8.0 x 10-3 cm/sec. Attachment G.doc 4-6 L-b Figure 4-2. Time - Drawdown Graph for PZ-2D O pW 8A Drawdown (ft below static) 6 b b b b b b to GO to th to A b O • \Abbott Laboratori: Laurinburg, 1\r‘ 0 co 0 co 0 In 0 DATA SET: a: \ PI-20 08/21/9S CA ign ex. a I I I ut-111111 I I 1111111ilTil •5 0 ( ) u mopm:gaa 0 a• 0 0 -0.1 -0.2 -0.3 0 -0.5 -0.7 -0.8 -0.9 -1 0 1000 2000 ?RXi$?.R6T£`.Va• �. Time (min) 3000 Figure 4-4. Time - Drawdown Graph for PZ-3D \ Abbott Laboratc. \ Laurinburg, 705-016-03-00 cd I I I I I I JO DATA SET: K \oz-30.0at 06/21/96 ADUIFER TVI \ 0 �h ¢ c I d .4 ri ry e 1 1 1111 1 1 1 1 1 I II\ 1 1 1 hhTl1`f -1-1-1 ,21 (uu) A/wpm-eau 41 O m. L Well PZ-3D Well PZ-3D is located 77 feet east of the pumping well. Figure 4-4 is a hydrograph illustrating drawdown in PZ-3D plotted versus time. As in Figure 4-2, the hydrograph illustrates a rapid rate of water -level decline initially, followed by a lesser rate of decline throughout the remainder of the pumping period. A maximum drawdown of 0.59 feet below static conditions was achieved by the end of the test. As in the preceding hydrograph, the recovery of the water level toward static conditions is evident after pumping ceases. The response to pumping is also indicated as a log -log plot of time versus drawdown (Figure 4-5) The data was analyzed using a type curve with a r/B ratio of 0.017. The best fit to the type curve as determined by the least squares method gave a transmissivity of 1.18 ft2/min and a storativity of 2.4 x 104. From the transmissivity, the hydraulic conductivity of the aquifer was calculated to be 1.0 x 1.0-2 cm/sec. Deep Observation Wells Drawdown was measured manually in deep observation wells PZ-1D, PZ-4D, PZ-5D, PZ-10D, PZ-16D, and PZ-16E. The measurements indicate that some degree of hydraulic response to pumping was evident in all deep wells. The maximum drawdown measured in each well is summarized in Table 4-5. In general, drawdown was greatest in wells nearest to the pumping well and decreased with increasing distance from the pumping well. This trend was apparent when water levels were compared in the five observation wells that were screened at comparable depths: PZ-1D, PZ-2D, PZ-3D, PZ-4D, and PZ-5D. Relative drawdown departed from this trend in wells MW-10D, MW-16D, and MW-16E. The drawdown in MW-10D, which is screened above the other deep wells, was less than the general trend. Conversely, the drawdown in MW-16D, which is screened below the other deep wells in the sand aquifer, was greater than the general trend. These departures from the general trend suggest that the hydraulic response to pumping is not evenly distributed throughout the sand aquifer. Rather, the response is greater near the bottom of the aquifer and less near the top. Attachment G.doc 4-11 TABLE 4-5 SUMMARY TABLE OF MAXIMUM DRAWDOWN IN DEEP WELLS PUMPING TEST WELL NETWORK Abbott Laboratories Laurinburg, North Carolina Observation Well Distance from Pumping Well (ft) Screen Interval Elevation (ft. above msl) Maximum Drawdown (ft. below static) PZ-1D 106 ' 178 - 168 0.57 PZ-2D 11 179- 169 0.75 PZ-3D 77 176 - 166 0.59 PZ-4D 287 179 - 169 0.46 PZ-5D 221 178 - 168 0.50 MW-10D 92 199 - 189 0.53 MW-16D 54 167 - 157 0.85 MW-16E 54 136 - 131 0.20 The drawdown in well MW-16E was less than that measured in all other deep wells. However, this result was expected as MW-I6E is screened beneath the lower confining layer in a liydrogeologic unit separate from the sand aquifer which was pumped. The drawdown measured in MW-16E was most likely an elastic response to pumping and did not represent the actual movement of water through the lower confining layer. Shallow Observation Wells Drawdown was measured by pressure transducers and recorded by data logger in observation wells PZ-2B, PZ-3B, MW-10A, and MW-10B. Manual measurements were made in wells PZ-1B, PZ-4B, and PZ-5B. Figures 4-6 through 4-9 illustrate hydrographs for the four shallow wells in which drawdown was measured by transducer and Table 4-6 summarizes the maximum drawdown recorded in each of the shallow wells. As in the deeper observation wells, a hydraulic response was evident in each shallow observation well. Although the magnitude of the drawdown was less than that measured in the deep observation wells, the rate of drawdown was again greatest during the initial minutes of the test and continued throughout the test at a lower rate. AttaclunentG.doc 4-12 fib 0 -0.1 -0.2 -0.3 -0.8 -0.9 _1 0 1000 2000 Time (min) 3000 Figure 4-6. Time - Drawdown Graph for PZ-2B 4000 5000 Drawdown (ft below static) 6 6 6 6 b b ;:r• ;J1 :11. b tie Drawdown (ft below static) 0 1000 2000 Time (min) 3000 Figure 4-8. Time - Drawdown Graph for MW-10A 4000 5000 rn Draw down (ft below static) 0 -0.1 -0.2 -0.3 -0.4 -0.5 -0.6 -0.7 -0.8 -0.9 1000 2000 Time (mbm) 3000 Figure 4-9. T me - Drawdown Graph for MW-10B 4000 5000 TABLE 4-6 SUMMARY TABLE OF MAXIMUM DRAWDOWN IN SHALLOW WELLS PUMPING TEST WELL NETWORK Abbott Laboratories Laurinburg, North Carolina Observation Well Distance from Pumping Well (ft) Screen Interval Elevation (ft. above ms1) Maximum Drawdown (ft. below static) PZ-IB 106 212 - 202 0.32 PZ-2B 10 213 - 203 0.27 PZ-3B 76 213 - 203 0.33 PZ=4B 287 213 - 203 0.37 PZ-5B 220 212 - 202 0.35 MW-10A 98 224 - 219 0.16 MW-10B 95 213 - 203 0.23 However, unlike drawdown in the deep observation wells, which was greatest nearer the pumping well, drawdown in the shallow wells exhibited an opposite trend. This uncharacteristic response is attributed to the discontinuous clay layer present between the pumping well intake and the screened intervals of the overlying shallow wells. The clay layer acts as a barrier that dampens the hydraulic response dueto_pumping. Consequently, the magnitude of the hydraulic response is greatest in shallow wells located nearer the outer limits of the clay layer where the dampening effect is less, even though these wells are located farther from the pumping well. A schematic illustrating this concept is included as Appendix A. In summary, Well RW-7 attained a maximum drawdown of 16.32 feet after approximately 70 hours of pumping at an average rate of 7.7 gallons per minute. -The hydraulic response to the pumping was evident in all 15 wells comprising the observation well network and the radius of influence exceeded a distance of 300 feet. The magnitude of the response increased with depth within the sand aquifer and was diminished in the upper portion of the aquifer by the presence of a discontinuous clay layer located above the intake of the pumping well. An elastic response was measured in a separate hydrogeologic unit underlying the lower confining layer. Analysis of time-drawdown data for wells PZ-2D and PZ-3D showed good agreement. The harmonic means for the transmissivity, storativity, and hydraulic conductivity Attachment G.doc 4-17 are 1.05 ft2/min, 3.7 x 104, and 8.9 x 10'3 cm/sec, respectively. These values are consistent with a leaky confined aquifer comprised of fine to coarse sand. Attachment G.doc 4-18 ATTACHMENT H MONITORING PROCEDURE Pilot -Scale Testing The pilot -scale test will consist of injecting an iron slurry through three injection points in Unit A and placing a permeable iron wall perpendicular to the plume flow direction in Unit B. A slurry of powdered zero-valent iron and a carbon source carrier will be placed into the subsurface. In Unit A, the slurry will be injected from approximately 5 feet to 10 feet bgs at the locations shown in Figure 5-5 (see Attachment N). In Unit B, this slurry will be placed beginning at approximately 15 feet to 35 feet bgs vertically across Unit B at the locations shown in Figure 5-6 (see Attachment N). Radian's in house designed Bio-Pumping system will be the vehicle used to apply the slurry. This pumping system will produce 3,300 psi at 55 gpm peak efficiency. The system is controlled by an operator that matches volume and pressure to the formation to most effectively place the slurry. A direct push technology (DPT) rig pushing a 2.125-inch drill rod will be utilized to inject the slurry. The rig will push the rod to the top of the hydrogeologic units as the slurry is being mixed. When the rod is located at the top of a unit the injec ton head wiIl-be fitted to the top ofthe dnll rod and connected -to the slurry pump. Injection will begin through the injection nozzle placed above the drive point on the down -hole end of the drill rod. Th&nozzle is configured with three slots on 120 degree centers that inject slurry in a "Y" pattern into the formation. The slurry will be continually injected at the rod is driven through the unit until the rod reaches the confining layer below. The DPT rod will be pulled out of the formation, and the rig will be offset to the next injection location where the injection process will be repeated. Each leg of the "Y" will be pressured approximately 5 to 10 feet into the formation. In Unit B, six injection points on 8 feet centers will be placed as seen in Figure 5-6. Newly constructed 1-inch diameter monitoring wells will be utilized to measure the effectiveness of the treatment during the pilot application. Nine monitoring wells will be used in both hydrogeologic units. Three wells will be placed upgradient of the injection points, three downgradient of the injection points, and three adjacent to the injection points in both Units A and B. These wells will be sampled before, during, and after the pilot test. Samples will be analyzed for VOCs, SVOCs, CO2, Ethane, and Methane. In addition, parameters such as dissolved oxygen, pH, conductivity, temperature, and oxidation-reduction potential (ORP) will be recorded during the application process to gauge the progress of reactions in the treatment area. The on -site activities associated with the pilot -scale test will be conducted for a period of approximately eight weeks. A technical report will be prepared that describes the results of the bench and pilot -scale test. It will include the observations recorded during the pilot application, and the conclusions and recommendations from review of the analytical results from the monitoring program: Information regarding the radius of influence from the application wells and the reactivity of site media to the reagents will be presented. The post- , treatment results will also be compared with the baseline monitoring results to illustrate the effectiveness of the technology in reducing VOC concentrations in saturated soil and groundwater within the treatment area. Lastly, the report will include the recommendations and estimated cost for implementing full-scale application of the process. ' ATTACHMENT F Attachment F Description of Site The Hamilton Beach Proctor-Silex (HB PS) facility is located at 234 Springs Road, north of the City of Washington, in Beaufort County, North Carolina. The facility and surrounding land parcel are owned by the City of Washington and have been leased by HB PS since 1990 and previously leased by predecessor companies. The facility is involved in the final assembly, packaging, and warehousing of small electric household appliances. Since 1992, when chemicals were initially detected in groundwater, several phases of environmental investigation have been performed at the site. Soil and water at the site contain fuel, chlorinated and non -chlorinated volatile organic compounds, and semivolatile organic compounds that are consistent with the storage and use of petroleum products and degreasing solvents. The principal chemicals detected at the site are certain volatile organics. Certain semivolatile organics are detected less. frequently, at lower concentrations, and over a smaller area. These principal chemicals are no longer in use at the facility. Based on the site's description and operating history and on the results of the investigations, it is apparent that the chemicals_detectedin_soiLand_groundwater.originated from multiple sources. There are no known, on -going, primary sources of trichloroethene or 1,1,1-trichloroethane at the site. A, possible source of the solvents is the former above -ground storage tank (AST) that contained trichloroethene and, later, 1,1,1-trichloroethane. The specific source of the petroleum constituents is unknown. The specific nature, volume, and time period of any releases associated with these sources is also unknown. Regardless, they have created a "secondary source" within the soil located near the southeast corner of the plant building. In 1995, an unknown quantity of oil was accidentally released into a drainage ditch along the south property line when a North Carolina Department of Transportation work crew ruptured a former roof drain pipe that transects the source area. HB PS reported the incident to the appropriate state agency and responded to the release by excavating all visibly affected soil from the drainage ditch. With the concurrence of the North Carolina Department of Environment, Health, and Natural Resources and the City of Washington, the excavated soil was subsequently land farmed in an area east of the employee parking lot. Oil was later measured in la c:\hamilton\CAP.doc\Attach F F-1 650138.0701 a monitoring well and free product recovery was initiated. After the volume of product recovered from the well by periodic manual bailing had diminished, HB PS, with the concurrence of the North Carolina Department of Environment and Natural Resources, implemented free product recovery using Aggressive Fluid -Vapor Recovery technology on both the well and the former drain pipe. Recovery efforts have removed approximately 50 gallons of product, but results have shown steadily diminishing returns. The facility's site priority ranking score is 70/B, and the incident has been assigned No. 14338. la c:\hamilton\CAP.doc\Attach_F F-2 650138.0701 ATTACHMENT G Attachment G (Excerpted from Comprehensive Site Assessment Report) 4.2 Regional Geology Beaufort County, North Carolina is located in the east -central part of the Coastal Plain Physiographic Province. The region is characterized by relatively flat, low, topography with many wetland features. Surrounding areas are drained by the Pamlico and Pungo Rivers and their tributaries, which are estuarine in the lower reaches. Surface elevation in the county ranges from approximately 70 feet above sea level in the southwestern part of the county to less than five feet above sea level in the eastern part. The region is underlain by a wedge of sedimentary deposits consisting of sand, silt, clay, limestone, and various combinations of these lithologies. The sediments thicken in a southeasterly direction attaining a maximum thickness of approximately 3,000 feet in the eastern part of the county (Robison, 1977) and a thickness of about 1,000 feet near Washington (Sumsion, 1970). The sediments lie on crystalline metamorphic and igneous bedrock consisting of schist, gneiss, gram e't , and slate (rB own, 1959)-The sedimtniswhich range in age from Cretaceous to Recent, can be classified into a number of stratigraphic units or formations. From oldest to youngest, these stratigraphic units are known to include the Middendorf (formerly Tuscaloosa) Formation; Black Creek Formation; Peedee Formation; Beaufort Formation; Castle Hayne Formation; Yorktown Formation; and, undifferentiated surficial deposits. A wedge of sediments consisting of basal deposits of Early Cretaceous Age may underlie the Middendorf Formation beneath parts of the region; however, as cited by Brown (1959), the extent of these Early Cretaceous deposits is uncertain. Also, the Pungo River Formation, important for its phosphorite beds, underlies parts of the region east of Washington (DeWiest et al., 1967). Brown (1959) reports that Early Cretaceousdeposits and sediments of the Late Cretaceous Middendorf Formation, unconformably overlie bedrock in the region. The early Cretaceous deposits were identified in cuttings from a well drilled in Greenville. Although their extent is unknown, the deposits comprising this unnamed unit are presumed to be widespread Ia c:\hamilton\CAP.doc\App-G (07/13/99) G-1 650138.0701 r throughout the region. Swain and Brown (1964) report that the formation consists primarily of sand and silt interbedded with green and brown silty clay. The formation is estimated to be between 150 and 200 feet thick near Washington and to dip toward the southeast at about 20 feet per mile. Where the Early Cretaceous deposits are absent, the bedrock is unconformably overlain by the Middendorf Formation of Late Cretaceous Age. The lithology of the formation is highly variable but, in general, is characterized by interbedded lenses of pinkish to drab -gray micaceous sand and clay (Brown, 1959). The upper 150 feet of the deposits consists principally of lenticular clay. Coarse- to medium -grained sand and gravel occur throughout the formation but are more common below the upper 150 feet of the deposits. Sumsion (1970) describes the formation as grading upward from fine sand and silt to coarser sand interbedded with silt and clay. Brown (1972) estimates that the top of the formation is about 650 feet below sea level near Washington. The strike of the Middendorf Formation is northeast and the dip is estimated at more than 20 feet per mile toward the southeast (Brown, 1959). Approximately 300 feet of the Late Cretaceous Black Creek Formation unconformably overlies the Middendorf Formation near Washington (Brown, 1972). The formation, which includes the upper Snow Hill member and a lower unnamed member, varies in composition, but generally consists of gray lenticular sand interbedded with dark gray. to black micaceous clay. The unnamed member commonly contains lignitized wood fragments and some glauconite, and the Snow Hill member contains thin shell beds and glauconite. In its upper part, the Black Creek Formation is lithologically similar to, and difficult to distinguish from, the overlying Peedee Formation described below. The top of the formation is about 300 to 350 feet below sea level near Washington (Brown, 1972 and Sumsion, 1970). The strike of the Black Creek Formation is reported to be toward the east-northeast in the subsurface (Brown, 1972). The dip of the formation is difficult to determine due to the nature of the beds but has been estimated to vary from 11 feet per mile (Sumsion, 1970) to 15 feet per mile (Brown, 1959) in adjoining Pitt County. la c:\hamilton\CAP.doc\App-G (07/13/99) G-2 650138.0701 Approximately 120 feet of the Cretaceous Peedee Formation lies conformably on the Black Creek Formation near Washington (Brown, 1972). The Peedee Formation consists of lenticular beds of dark green or gray, medium- to coarse -grained quartz sand interbedded with thinner layers of clay, dark gray silt, and indurated shell. The top of the formation is about 230 feet below sea level near Washington (Brown, 1972). The strike of the Peedee Formation is toward the northeast and the dip is southeast at about 10 feet per mile (Sumsion, 1970) to 15 feet per mile (Brown, 1959) in adjoining Pitt County. The Beaufort Formation of Paleocene age unconformably overlies the Peedee Formation. The Beaufort Formation, which is about 35 to 60 feet thick near Washington (Brown, 1959 and 1972), consists primarily of fine glauconitic sand interbedded with thin layers of clay, silt, and marl. Near Washington, the top of the formation is about 125 feet (Sumsion, 1970) to 170 feet (Brown, 1972) below sea level. The dip of the Beaufort Formation is toward the east at about 14 feet per mile in adjoining Pitt County (Sumsion, 1970). The Castle Hayne Limestone of Eocene age unconformably overlies the Beaufort Formation. The thickness of the Castle Hayne Limestone increases from about 60 feet thick in the western portion of Beaufort County to about 250 feet near its eastern border (Brown, 1959). Near Washington, the formation is between 75 feet (Sumsion, 1970) and 130 feet thick (Brown, 1972). The Castle Hayne Limestone varies in lit,hology and consolidation. It consists of interlayered gray to white shell limestone, marl, fine- to medium -grained calcareous sand, and clay. The top of the formation is about 35 feet (Brown, 1972) to 50 feet.(Sumsion, 1970) below sea level in the vicinity of Washington. The regional strike of the formation is east-northeast and the dip is toward the southeast at 10 to 30 feet per mile (Brown, 1959). The Yorktown Formation of Miocene age unconformably overlies the Castle Hayne Limestone. The thickness of the Yorktown Formation is about 30 feet near Washington, but may reach a thickness of 200 feet in eastern parts of Beaufort County (Brown, 1959 and 1972). Brown (1959) describes the lower part of the Yorktown Formation as massive interbedded marine clays. In the upper part, it is composed of light-colored sandy shell beds and marls. Similarity of the upper part of the formation with the overlying younger deposits makes la c:\hamilton\CAP.doc\App-G (07/13/99) G-3 650138.0701 distinguishing between them difficult (Sumsion, 1970). The top of the formation is about 35 feet below sea level in the vicinity of Washington (Brown, 1972). The formation strikes northeastward and dips toward the southeast at less than 25 feet per mile (Brown, 1959). Undifferentiated surficial deposits of varying origin and age (Pleistocene to Recent) generally blanket the region and unconformably overlie the Yorktown Formation. The surficial deposits consist of sand, sandy clay, clay, and gravel. The unit ranges from a few feet to about 60 feet in aggregate thickness throughout the region (Brown, 1959). Near Washington, the unit is about 35 feet thick (Brown, 1972). The deposits exhibit little stratification other than localized cross -bedding. 4.3 Site Soils and Geology This section describes the soils and geology at the facility. Interpretation of subsurface• conditions at the site is based on boring and drilling logs developed during the CSA and on observations noted and recorded during previous subsurface investigations. Consequently, the discussion is limited to the upper 75 feet of sediments penetrated at the site. 4.3.1 Soils Soil at the site has been mapped as Urban land (Kirby, 1995). This classification describes areas where the original soil has been altered by cutting, filling, and grading such that a soil series is not recognized. However, soil observed during the subsurface investigations appears characteristic of the Craven fine sandy loam, Leaf silt loam, and Lenoir loam series, which occur over large areas surrounding the site. The soil at the site consists primarily of complexly interbedded silty, to clayey sand, sandy to clayey silt, sandy to silty clay, and clay. The color of the soil is also variable ranging from light- to dark -gray to dusky brown with frequent orange mottling in the subsoil. la c:\hamilton\CAP.doc\App-G (07/13/99) G-4 650138.0701 4.3.2 Geology The subsurface geology of the upper 75 feet of sediments underlying the site is characterized by three stratigraphic units. These units, from lower to upper, are the Castle Hayne Limestone, the Yorktown Formation, and the overlying undifferentiated surficial deposits. This sequence of stratigraphy is consistent with regional subsurface conditions described in Section 4.2. Well MW-226 was the only well at the site that was drilled deep enough to reach the Castle Hayne Limestone. In this well, the limestone formation was encountered immediately below the Yorktown formation at a depth of 69 feet below land surface. The Castle Hayne formation underlying the site, based on drill cuttings from the upper six feet of the unit, is greenish gray to white shell limestone. The top of the Yorktown Formation occurs approximately 30 to 40 feet below land surface and is characterized by a transition zone of silty sand interbedded with clay, grading downward to predominantly clay. The transition zone is, itself, up to 10 feet thick as shown on cross -sections prepared for the site. The locations of cross -sections A -A' to C-C' are depicted on Figure 4-3 and the cross -sections are illustrated on Figures 4-4 to 4-6. Below the transition zone, the formation consists of dark greenish gray clay and silty clay containing gastropod shells and shell fragments. The formation is continuous across the site having been encountered in all of the deeper CPT borings advanced during the CSA and also having been noted in a deeper boring drilled during a previous investigation (MW-201D). Based on drill cuttings from well MW-226, the bottom of the unit is at 69 feet below land surface. The thickness of the Yorktown formation is approximately 33 feet at this location as illustrated on cross -sections B-B (Figure 4-5). Undifferentiated surficial deposits form the uppermost stratigraphic unit at the site. The deposits, which extend from land surface to the top of the Yorktown Formation, are about 30 to 40 feet thick as illustrated in cross -sections A -A' (Figure 4-4) to C-C' (Figure 4-6). From land surface to a depth of approximately 15 feet, the surficial deposits consist of complexly interbedded sediments that range in texture from fine sand to clay. Between a depth la c:\hamilton\CAP.doe\App-G (07/13/99) G-5 650138.0701 H'r of approximately 5 and 15 feet below land surface, the finer -grained sediments form a layer, ranging from 3 to 12 feet thick, that appears to be continuous beneath the site. Below this layer, the surficial deposits are characterized by light gray to green, predominantly silty sand interbedded with light to medium gray, fine- to medium -grained sand, and some clay lenses. Below a depth of approximately 22 feet the deposits contain shells and shell fragments. The shell -bearing deposits could represent sediments of Late Miocene age, which are difficult to distinguish from the younger, overlying deposits; consequently, regardless of age, they are included with the surficial deposits in this report. 5.2 Regional Hydrogeolo2y The stratigraphic unitsdescribed in Section 4.0 can be grouped into several distinct hydrogeologic units on the basis of their hydrologic properties. The region's principal hydrogeologic units include, from deepest to shallowest, the Cretaceous aquifer system, the Beaufort aquifer, the Tertiary limestone aquifer, the Yorktown confining layer, and the surficial aquifer. This section briefly describes these hydrogeologic units and Table 5-4 correlates the units with the stratigraphic units that comprise them. The Cretaceous aquifer system includes interbedded sand, silt, and clay deposits in the unnamed Early Cretaceous unit and in the Middendorf, Black Creek, and Peedee Formations of Late Cretaceous age. Sumsion (1970) identified four individual aquifers in the system, each separated by extensive beds of clay. Groundwater in the aquifers is confined and recharge occurs as leakage from overlying units. The aquifer system is more than 700 feet thick near Washington; however, the depth to brackish water is about 200 feet (Robison, 1977). Therefore, near Washington, only the upper aquifer in the system, which occurs in the Peedee Formation, is capable of supplying potable water. Because of the thinness and moderate permeability'of the fresh -water zone, individual wells are not anticipated to yield above 100 gallons per minute (Robison, 1977). Groundwater obtained from depths greater than 150 feet is soft and of good quality (Brown, 1959). la c:\hamilton\CAP.doc\App-G (07/13/99) G-6 650138.0701 The Beaufort aquifer is comprised of glauconitic and argillaceous sands, indurated shell, and impure limestone with the glauconitic sand beds being the most productive deposits (Brown, 1959). Groundwater in the aquifer is confined and recharge occurs as leakage from overlying units. the yield of individual wells completed in the Beaufort aquifer ranges from 15 to 150 gallons per minute. The quality of groundwater in the Beaufort aquifer is soft (Sumsion, 1970). The Tertiary limestone aquifer is comprised of the Castle Hayne Limestone and associated calcareous sand deposits. Groundwater in the aquifer is confined and recharge occurs as leakage from overlying and underlying units (Brown, 1959). The aquifer ranges from about 50 to 100 feet thick near Washington to about 400 feet thick in eastern part of Beaufort County. The aquifer is highly productive throughout much of the region where it occurs in sufficient thickness. Small diameter wells yield from 5 to 150 gallons per minute; where the aquifer is thickest, large diameter gravel -packed wells yield up to 1000 gallons per minute (Brown, 1959). Groundwater in the aquifer is very hard, exhibits moderate to high levels of dissolved solids, and moderately high pH. The water commonly contains hydrogen sulfide gas and excessive iron (Robison, 1977). Although thin sand lenses and sand beds associated with the Yorktown Formation can provide water to wells, thick marine clay deposits that predominate the unit form a confining bed underlying the surficial aquifer. The surficial aquifer is the uppermost hydrogeologic unit in the region. It consists of interbedded sand and clay deposits. Groundwater in the aquifer is unconfined and recharge to the surficial aquifer occurs over broad interfluvial areas throughout the region. The yield of wells completed in the surficial aquifer is between two and ten gallons per minute (Brown, 1959). Groundwater in the surficial aquifer is typically corrosive and contains excessive iron. 1a c:\hamilton\CAP.doc\App-G (07/13/99) G-7 650138.0701 fl 5.3 Site Hydrogeology The hydrogeologic units discussed in the preceding section are all represented at the facility. Locally, five hydrogeologic units have been penetrated at the site. These units include, from upper to lower: a shallow groundwater reservoir, a shallow confining bed, a semi - confined sandy aquifer, the Yorktown confining bed, and the Tertiary limestone aquifer. Because the scope of the site assessment focused primarily on the surficial deposits, only one boring (MW-226) was advanced below a depth of 52 feet. Nevertheless, a brief description of the Tertiary limestone aquifer underlying the facility is included following more detailed treatment of the hydrogeologic units within the surficial and Yorktown deposits. The uppermost hydrogeologic unit coincides with the complexly interbedded fine sand to clay deposits that comprise the upper five to ten feet of sediments underlying the site. The unit, which is identified as Unit A in this report, is not considered to be an aquifer due to the' variable permeability, discontinuous nature, and thin saturated thickness of its component deposits. Rather, the unit's function at the site can be viewed as a groundwater reservoir that supplies base flow to surface water and, potentially, recharge to underlying aquifers. The hydraulic conductivity of deposits comprising Unit A was measured as ranging from 3.6 x 10-2 ft/day to 7.4 x 10-2 ft/day. These measurements represent average values because the intervals tested include interlayered beds of both low permeability clay and more permeable sand. Measurement of hydraulic conductivity at 5.7 x 10- ft/day in one location may represent an interval of lower permeability clay deposits comprising Unit A or may represent a section of the confining bed underlying the unit. Based on a textural description of the deposits, the hydraulic conductivity of the more permeable sand layers is in the order of 10° ft/day and the effective porosity is estimated to range from approximately 3 percent for the clay deposits to approximately 20 percent for the sand deposits (Brassington, 1988). Groundwater within Unit A is expected to occur under water table conditions; although, water within an individual sand layer or lens may be confined. The top of Unit A occurs at the water table which is typically about three to five feet below land surface at the site. The base of Unit A is approximately four to seven feet below land surface and coincides with the top of a surficial confining bed that is described below. Therefore, the thickness of Unit A at the site is typically four feet or less. la c:\hamilton\CAP.doc\App-G (07/13/99) G-8 650138.0701 Fine-grained deposits, consisting of sandy silt to clay, form a shallow confining bed immediately below Unit A. Due to its composition of primarily fine-grained deposits, the confining bed separates Unit A from the underlying semi -confined aquifer described below. Based on a textural description of the deposits, the hydraulic conductivity of the shallow confining bed is estimated to be low to very low, on the order of 10-2 ft/day to 10-3 ft/day or less (Brassington, 1988). As described above, a hydraulic conductivity value, that is likely to be representative of the confining bed, was measured at 5.7 x 104 ft/day. The top of the shallow confining bed ranges from about four feet to seven feet below land surface. As a result, the water table may occur within the confining bed at some locations where the top of the bed is most shallow. The bottom of the confining bed is as shallow as seven feet below land surface at some locations and as deep as 16 feet at others. As illustrated in cross -sections A -A (Figure 4-4) to C-C (Figure 4-6), the shallow confining bed appears to be continuous across the site but it varies in thickness from about three to ten feet depending on location. Where present within the shallow confining bed, layers and lenses of more permeable deposits decrease its effective thickness as a barrier to vertical groundwater flow. Silty to fine sand deposits form a semi -confined aquifer between the overlying shallow confining bed and the underlying Yorktown confining bed. The aquifer is identified as Unit B in this report to distinguish it from the shallow groundwater reservoir that also occurs within the surficial deposits at the site. Groundwater within Unit B occurs under semi -confined conditions; recharge to the aquifer is derived through leakage from the overlying units. Based on a textural description of the deposits, the hydraulic conductivity of the Unit B is estimated to be moderate, in the range of 1 to 6 ft/day, and the effective porosity is estimated to be approximately 20 percent (Brassington, 1988). Pumping test results confirm the hydraulic characteristics estimated from textural analysis. The transmissivity of Unit B was calculated to range from 63.4 ft2/day to 64.9 ft2/day. These values equate to hydraulic conductivity values between 3.0 ft/day and 3.1 ft/day. The coefficient of storage calculated from the pumping test ranged from 0.0003 to 0.0006. As illustrated in cross -sections A -A (Figure 4-4) to C-C (Figure 4-6), the top of Unit B typically occurs about 12 to 16 feet below land surface at the site, but may be as shallow as seven feet below land surface where the overlying shallow confining bed is thin. The base of Unit B is approximately 30 to 40 feet below land surface and coincides la c:\hamilton\CAP.doc\App-G (07/13/99) G-9 650138.0701 with the top of the Yorktown confining bed. The thickness of Unit B averages about 25 feet, but varies considerably across the site ranging from about 15 feet to 35 feet. The clay deposits of the Yorktown Formation described in Section 4.3.2 comprise a confining bed overlying the Tertiary limestone aquifer. Due to its high content of clay and silt, the Yorktown confining bed exhibits a lower hydraulic conductivity than either an overlying semi -confined aquifer within the surficial deposits or the underlying Tertiary limestone aquifer. Based on a textural description of the deposits, the hydraulic conductivity of the confining bed is estimated to be low to very low, on the order of 10-3 ft/day, or less (Brassington, 1988). Consequently, the confining bed retards the flow of groundwater through it and essentially isolates the two aquifers from each other. As illustrated in cross -sections A -A' (Figure 4-4) to C-C' (Figure 4-6), the confining bed is continuous beneath the site with the top of the bed occurring approximately 40 feet below land surface. The clay deposits were completely penetrated only at well MW-226 where the bottom of the clay was encountered at a depth of 69 feet below land surface. The thickness of the confining bed at MW-226 is approximately 33 feet as illustrated in cross-section B-B' (Figure 4-5). The Tertiary aquifer underlies the Yorktown confining bed at a depth of approximately 69 feet below land surface. The upper six feet of the aquifer is comprised of shell limestone. Water levels measured in the aquifer are lower than those measured in the overlying hydrogeologic units indicating that the aquifer is recharged, in part, through leakage from above. During the CSA, the water table at the site occurred about three feet below land surface. Tables 5-5 and 5-6 summarize the depth to water and the corresponding water -level elevations measured on May 13, 1998 and November 16, 1998, respectively, in selected monitoring wells located throughout the site. Figure 5-3 depicts the potentiometric surface in Unit A on May 13, 1998 and incorporates water levels measured in the drainage ditch (Table 5-5). Although localized variations occur, the horizontal hydraulic gradient at the site and, therefore, groundwater flow are generally toward the ditch, located east and south of the facility. Beneath and southwest of the plant building, the hydraulic gradient ranges from 0.002 to 0.004 ft/ft. South and east of the plant building, the gradient increases to about 0.008 ft/ft and, la c:\hamilton\CAP.doc\App-G (07/13/99) G-10 650138.0701 approaching the ditch, steepens to more than 0.02 ft/ft. Using the previously noted values for horizontal hydraulic conductivity, and effective porosity, the average linear groundwater flow velocity in the more permeable beds in Unit A ranges from 0.01 to 0.04 feet/day. Figure 5-4 depicts the potentiometric surface in Unit B on May 13, 1998. In general, the horizontal hydraulic gradient and groundwater flow are to the northwest, nearly opposite the direction measured in Unit A. The horizontal hydraulic gradient in Unit B averages 0.003 ft/ft at the site. Using the previously noted values for horizontal hydraulic conductivity, and effective porosity, the linear groundwater flow velocity in Unit B is estimated to average 0.05 feet/day; however, flow within more permeable deposits comprising Unit B may approach 0.1 ft/day. The range of velocity values presented is considered representative for the site, but does not take into account inherent small-scale differences in gradient, porosity, and hydraulic conductivity that occur within the units. Figures 5-5 and 5-6 depict the potentiometric surface in Units A and B, respectively, based on water levels measured in November 1998. In Unit A, the configuration of the potentiometric surface in November is similar to that measured in May. Within Unit B, the hydraulic gradient in November has shifted to a more northerly direction than was measured in May. Water -level elevations measured in four well pairs in May 1998, each comprised of a well screened in Unit A and a well screened near the bottom of Unit B, indicate the presence of vertical hydraulic gradients between the two units. Measurements at well pair MW-216 and MW-217, and well pair MW-222 and MW-223 indicate downward hydraulic gradients of 0.015 and 0.172 ft/ft, respectively. Conversely, measurements at well pair MW-218 and.MW-219, and well pair MW-220 and MW-221 indicate upward hydraulic gradients of 0.026 and 0.035 ft/ft, respectively. These measurements, when evaluated in conjunction with the potentiometric surface maps (Figures 5-3 and 5-4) suggest that much of the site overlies a recharge area for the underlying hydrogeologic units. However, narrow areas immediately adjacent to the drainage ditch are, at certain times, discharge areas for groundwater within Unit B; as well as Unit A. This conclusion is consistent with the concept that groundwater recharge in the region occurs over the broad areas located between streams. In general, vertical gradients measured in November 1998 were similar to those measured in May with the exception that gradients in all well pairs, but one (MW-210/MW-211) were downward. la c:\hamilton\CAP.doc\App-G (07/13/99) G-11 650138.0701 FIGURES m G2 1 `:•G1 \ \ T PLANT BUILDING 1 / s B / 1 C16 O CII3 C15/ i .CI4 0 C7 Ce C10 226 (onset C12 C11 J Y 1 200 C13 0 200 SCALE 1N FEET e' rW IOIMI : 1511• • 1-]. 1.0I Cross Section Laces.... Fso•nzr-sr. 1. �L. ss '. 4301300001 I.-ssO o ▪ ani n SOUTHWEST A 30 - 25 - 20 - 15 - 10 - 5 - 0 - IC-15I /-29.A - 10 - - 15 - - 20 - ID - 25 - 52.0 A 8 IC-I6I //-28.3 � c-a 29.5 NORTHEAST A' 28.1 To 52.0 TD 52.0 100 TD 52.0 0 100 HORIZONTAL SCALE to 0 to VERTICAL SCALE m 52.0 LEGEND Location Number Ground Surface Elevation Total Depth of Boring Higher permeability deposits including Sand. Fine Sand. and Silly Sond Lower permeability deposits including Clayey Sond. Sandy Silt. Silt, and Cloy As sra+m Iv. INTERNA ecc nu..sis a u _ . gaussme. PStOI"s... rti wo.aaw. I rAd-e.l 0 D • KIPS \OCD DD•ISDEC.0 WEST B 30 — 25 — 20 — 15- 10 — 5- 0- - 10 — - 15 — - 20 —1 -25 — 52.0 IC-IBI 28.4 C-17 28.3 28.3 r (offset 30' to south) 11W-226 IG-IBI 26.6 EAST C-11 8' 28.9 - 35 — -40 — -45 — - 50 — . TB 52.0 1 1IIT S 7514 .0 m 52.0 28.1 100 ID 52.0 LEGEND Location Number Ground Surface Elevation Total Depth of Boring Higher permeability deposits including Sand, Fine Sand. and Silty Sand Lower permeability deposits including Clayey Sand, Sandy Sill, Silt, and Clay Shell Limestone deposits 0 100 HORIZONTAL SCALE 10 0 10 VERTICAL SCALE I" AS snow % IW(CYe—� ry,.. 4-e. �. awa4e cro..-s.1uo� a-e' eMRW IMFaNATON?O. iw[�=�e.ro. smer,«r.-e... w. __.-_ Holyatol cA o co- 9 NORTHWEST C 30 — 25 — 20 — 15 — 10 — 5 - 10 — - 15 — - 20 — -25 — I G-2 I I C-5 I 31.4 31.8 SOUTHEAST C• IC-18I IC-12I 28.3 i 28.8 TD 52.0 28.1 TD 52.0 LEGFND Location Number v_. Ground Surface Elevation • TO Total Depth of Boring 52.0 Higher permeability deposits including Sond, Fine Sond, and Silty Sand Loner permeability deposits including Clayey Sand, Sandy Silt, Silt, and Clay TO 52.0 100 100 HORIZONTAL SCALE 10 0 10 VERTICAL SCALE TD 52.0 AS SnervaN .II iSM INTERNATIONALr ef=` 22WT96 _ np4. 1-6 2e1asbaGet c °or -Sect C-Cm: =wa 6.a6•vmru.• r -ywarov,.'a eo �. .]Olb o'PI Ua-e-c 0 a 10 W-201 (27.37 MW-223 0 (27.25) MW-217 7(24 2 (22.35) • W113 (23.45) 200 4 3.51) 200 SCALE IN FEET LEGEND Monitoring Well with Groundwater Elevation (M5L) • Surface Water Measuring Point with Water Elevation Potentiomelnc Surface Contour (dashed where inferred) Groundwater Flo. Direction AS SWAIN Al '!]wvsa_ frog. 5-3 Pel.nrcnrlh Sins. Mop. 1S1 Tlhe3�9PB�aAw.�R.ab�Sw� rr BfY9lr INTERNATIONAL= — 630115 030l I vwuaw I 0 J • MW-22/22.5 (22.34) i li • 23.5 24 24.5 1 MW-216 o (24.39) w 3 6 200 25 MW-216 0 (25.16) 0 200 SCALE IN FEET LEEENO Monitoring Well with Groundwater Elevation (MSL) Polenliomeldc Surface Contour (dashed where interred) Groundwater Flow Direction AS Snead JI nwree .t • tJ Ywwwu. sew. wo. ISn few I.M & w / IY9e BFa• r �c �Noow' IK INTERNATIONAL — o-wnYaw� I ow' Io ��wew 200 LEGEND Monitoring Well with Groundwater Elevation (MSL) • Surlace Water Measuring Point with Water Elevation Potentiometric Surface Contour (dashed where inferred) Groundwater Flow Direction AS SHWA .n iho€csa nw!. !-! Pa.nlwm.4c Satan aos. NRADIAM NIFRN710tW _an w� ' � 6501360401 l SaML0 I D.\HDPS\DEEP\16DEC96 YW99-222 19. L. I - 20.5 ° YW-2k0 20.551 200 SCALE IN FEET d o Monitoring�riWell with Groundwater Elevation (Ma) Potentiomelric Surface Contour (dashed where interred) Groundwater Flow Direction MIS _�.�. . votWit B. 14.3.mber .nuo s s'.icr. 7aurleroIFIACWIINTERPallOINAL •rI OUP 10 AS SHOW. i.occae TABLES _ A_ Table 5-4 Relationship Between Stratigraphic Units and Hydrogeologic Units Hamilton BeachOProctor Sitex, Washington, North Carolina Period Epoch Stratigraphic Unit Hydrogeologic Unit General Description Quaternary Holocene Undifferentiated Surficial Deposits Surficial Aquifer Deposits consisting of sand, clay, and marl form the uppermost aquifer in the region. Groundwater occurs under water -table conditions. Pleistocene Tertiary Miocene Yorktown Formation Yorktown Confining Bed Massive clay deposits overlying sand lenses and shell beds form a confining bed that separates the surficial aquifer from the underlying limestone aquifer. Eocene Castle Hayne Limestone Tertiary Limestone Aquifer Shell limestone and calcareous sand deposits constitute the principal aquifer in Beaufort County. Groundwater occurs under confined conditions. Paleocene Beaufort Formation Beaufort Aquifer Glauconitic sands, argillaceous sands, and impure limestones constitute a fresh -water aquifer in Beaufort County. Groundwater occurs under confined conditions. Cretaceous Late Cretaceous Peedee Formation Cretaceous Aquifer System Deposits of complexly interbedded sand, silt, and clay constitute an aquifer system. Individual aquifers typically are separated by extensive beds of clay. Groundwater occurs under confined conditions. Only the Peedee Formation contains fresh water in westem Beaufort County. Black Creek Formation Middendorf Formation Early Cretaceous Unnamed Cretaceous Deposits lu c:\hamillon\washington\csa-rpt (1/20/99) Table 5-5 Groundwater Elevations: May 13, 1998 Hamilton BeachQProctor-Silex, Washington, North Carolina Well Measuring Point Elevation (ft. above MSL) Depth to Water (ft. below MP) Water -Level Elevation (ft. above MSL) MW-2018 29.74 2:37 27.37 MW-206 28.79 3.35 25.44 MW-207 33.78 , 3.70 30.08 MW-208 32.11 _ 5.49 26.62 MW-209 32.93 t 7.82 25.11 MW-210 32.49 7.39 25.10 MW-211 31.75 6.84 24.91 MW-212 28.45 2.80 25.65 MW-213 28.44 2.90 25.54 MW-214 27.93 2.98 24.95 MW-215 28.06 3.09 24.97 MW-216 . 32.82 8.43 24.39 MW-217 32.75 8.00 24.75 MW-218 31.55 6.37 25.18 MW-219 31.83 •7.33 24.50 MW,220_ 31.50 6.37 25.13 MW-221 31.39 7.04 24.35 MW-222 35.11 12.77 22.34 MW-223 35.15 7.90 27.25 Surface Water Elevations Hamilton BeachOProctor-Silex, Washington, North Carolina Measuring Point Measuring Point Elevation (ft. above MSL) Depth to Water (ft. below MP) Water -Level Elevation (ft. above MSL) W81 22.73 0.79 21.94 W82 23.16 0.81 22.35 W83 23.99 0.54 23.45 W84 23.99 0.48 23.51 W85 24.25 0.85 23.40 MSL = Mean Sea Level MP = Measuring Point la c:\hamilton\washington\csa-tpt (1/20/99) Table 5-6 Groundwater Elevations: November 16,1998 Hamilton BeachOProctor-Silex, Washington, North Carolina Well Measuring Point Elevation (ft. above MSL) Depth to Water (ft. below MP) . Water -Level Elevation (ft. above MSL) MW-201S 29.74 3.59 26.15 MW-208 32.11 . 7.25 24.86 • MW-209 32.93 11.25 21.68 MW-210 32.49 9.30 23.19 MW-211 31.75 • 8.97 22.78'__ MW-212 28.45 5.95 22.50 MW-213 28.44 - 4.23 24.21 MW-214 27.93 5.75 22.18 MW-215 28.06 3.87 24.19 MW-216 32.82 10.45 22.37 MW-217 32.75 8.77 23.98 MW-218 31.55 9.40 22.15 MW-219 31.83 8.83 23.00 MW-220 31.5 10.95 20.55 MW-221 31.39 10.52 20.87 MW-222 35.11 15.12 19.99 MW-223 35.15 7.56 27.59 MW-224 33.43 9.79 23.64 MW-225 33.43 9.07 24.36 MW-226 28.46 20:03 8:43 - MW-227 28.47 6.09 22.38 MW-228 28.71 5.70 23.01 MW-229 30.44 8.67 21.77 MW-230 33.47 12.33 21.14 MW-231 31.94 9.58 22.36 Surface Water Elevations Hamilton BeachOProctor-Silex, Washington, North Carolina Measuring Point- Measuring Point Elevation (ft. above MSL). Depth to Water (ft. below MP) Water -Level Elevation (ft. above MSL) W81 22.73 0.68 22.05 W82 23.16 '0.71 22.45 W83 23.99 0.65 • 23.34 W84 23.99 0.60 23.39 W85 24.25 0.96 23.29 la c:\hamilton\washington\csa-rpt(120/99) HYDRAULIC TESTING PROCEDURES AND CALCULATIONS HYDRAULIC TESTING PROCEDURES AND CALCULATIONS This appendix describes procedures used to conduct a pumping test and four "bail -down" tests at the facility. The appendix includes the recorded field measurements and the calculations performed in analyzing the data. I.1 Pumping Test I.1.1 Introduction A constant -rate pumping test was conducted at well PW-1 located in the area east of the employee parking lot. The objective of the tests was to determine hydraulic characteristics of hydrogeologic unit B. The test site was selected based on its location outside any chemical plume, which allowed the water generated by the test to be discharged without treatment. _ PW-1 was pumped-using-an-electric-powered-submersible-pumpWell-yield-was monitored using a calibrated bucket and stop watch and regulated, as necessary, by adjusting the pump's impeller speed. The discharge was diverted from the pumping well through a water hose and released to a drainage ditch. Drawdown in the pumping and observation wells was measured using an electric water -level indicator and recorded manually. I.1.2 - _Pumping Test Description The well network for the pumping test included wells PW-1, OW-10, OW-20, and MW-220. Well PW-1 served as the pumping well and wells OW-10, OW-20, and MW-220, served as the observations wells. Wells OW-10 and OW-20 are located 10 feet and 20 feet west of PW-1, respectively. Well MW-220 is located 48.5 feet south of PW-1. All wells are screened in hydrogeologic unit B. A constant -rate test was started at 7:34 a.m. on November 5, 1998. PW-1was pumped at an average rate of 1.6 gallons per minute (0.214 ft/min) and drawdown la e:ThamiltorAwashingtonkesa-rpt (17/16198) I-1 was measured in all wells in the test network. Pumping continued uninterrupted until terminated after 480 minutes. Results of the test are discussed in Section I.1.3.2. I.1.3 Pumping Test Analysis This section describes the analytical procedure used to evaluate the data from the pumping test and presents the results. Tables and graphs of water -level drawdown measurements utilized in the analyzing the test are included at the end of the discussion. I.1.3.1 Analytical Procedure The conceptual model used to analyze the pumping test is that of a semi -confined (leaky) aquifer with no storage effects in the confining layer. Governing equations and type curves are those presented by Hantush and Jacobs (1955) with a correctionapplied for partial penetration of the observation wells (Hantush, 1961). Type curves were initially fit to measured drawdown data by nonlinear least -squares parameter estimation and, subsequently, matched visually usingAQTESOLV software developed by Geraghty and Miller Modeling Group (Duffield, 1991). Input to the aquifer model, in addition to the measured drawdown, included discharge rate (Q); distance from the pumping well to the observation well (r); well casing radius (re); borehole radius (rw); and, aquifer thickness (b). Specific input values for these parameters are listed under "Test Data" on the accompanying graphs. 1.1.3.2 Pumping Test Results Transmissivity calculated for hydrogeologic unit B ranges from 0.044 fl /min (63.4 ft/day) to 0.045 ft2/min (64.9 it/day). These values equate to hydraulic conductivity values between 3.0 ft/day and 3.1 ft/day. The range of hydraulic conductivity values is consistent with an aquifer comprised of fine-grained silty sand. The coefficient of storage ranges from 0.0003 to 0.0006, which is typical of semi -confined aquifers. la c:\hamiltotwashingtonksa•rpt (12/ I6/98) I-2 Radian International client Hamilton Beach<>Proctor-Silex Protect Ho.: 650138.0601 Lout ton: Washington, NC Pumping Test OW 10 Drawdown (ft) 100. 10. I I I I I I1II 1 11 I I I I Hit I I it 10. Time (m I I I I I I I I I II14-- 1111I 100. n) I I I I 1 I I1 1000. AQUIFER TYPE: SOLUTION NE THUD: sn...0 TEST DATE: ll/N- 1E51 BELL: DDS. WELL: Os-10 EMANATED PAMIIEIERS T - ...l.w u2/nn TEST DATA. • - o L. T[lhm ♦[ 0.0a I. .- O.Dn . - as. I. TEST .ELL'' °..alit • 0 • - le. II AQTESOLV A Program for Automatic Estimation of Aquifer Coefficients From Aquifer Test Data By: Glenn M. Duffield and James 0. Rumbaugh, III Geraghty &Miller Modeling Group 1895 Preston White Drive, Suite 301 Reston, VA 22091 (703) 476 -.0335 AQTESOLV is a user-friendly program designed to. analyze data from aquifer tests automatically. Aquifer. coefficients for a variety of aquifer teat conditions can be estimated by A Q T E S 0 L V, including the following: o confined aquifers, unconfined aquifers, and leaky aquifers o pum ny testa, iujectiun—testsecovery tests, and slug tests Features: o Interactive, menu -driven program design o Nonlinear least -squares estimation of aquifer coefficients o Statistical analysis of results o Complete graphical display of results «c «««««««««««c «««««««>»»»»»>?»»»»»»»»»»»» AQTESOLV RESULTS Version 1.10 12/15/98 14:10:4( ========________________________________====aa==a=====_________________________: TEST DESCRIPTION Data set ow10.dat Data set title Pumping Test OW-10 Company Radian International Project 650138.0601 Client Hamilton Beach<>Proctor-Silex Location Washington, NC Test date 11/5/98 Test wel'1 PW-1 Obs. well OW-10 Knowns and Constants: No. of data points 47 Pumping rate 0.214 Radius (distance) to obs. well 10 Radius of pumped well casing 0.083 Radius of pumped wellbore 0.25 Partial Penetration Data: Depth of top of well screen 1 Depth of bottom of well screen 21 Depth of top of obs. well screen 1 Depth of bottom of obs. well screen21 Hyd. conductivity ratio (Kz/Kr) 1 ______=====a=a aaa====a=aa==a=========aaa=aaaa========a================___====== ANALYTICAL METHOD Hantush (Leaky Aquifer) ===aaa== ' RESULTS FROM STATISTICAL CURVE MATCHING STATISTICAL MATCH PARAMETER ESTIMATES T = S = r/B= ANALYSIS residual weighted Estimate Std. Error 4.4017E-002 +/- 1.2682E-003 6.4284E-004 +/- 4.3263E-005 1.0000E-005 +/- 2.4364E+001 OF MODEL RESIDUALS = calculated - observed residual = residual * weight weighted Residual Statistics: Number of residuals 47 Number of estimated parameters3 Degrees of freedom 44 Residual mean 0.002898 Residual standard deviation 0.05422 Residual variance 0.00294 Model Residuals: Time Observed Calculated Residual Weight 1 0.4 0.29583 0.10417 1 1.5 0.54 0.4121 0.1279 1 2 0.62 0.50219 0.11781 1 2.5 0.68 0.5755 0.1045 1 '-- 3 0.72 0.63722 0.082776 1 4 0.79 0.73736 ' 0.052641 1 5 0.85 0.81691 0.033089 1 6 0.91 0.88289 0.027105 1 7 0.94 0.93926 0.000736 1 _ 8 0.98 0.98846 -0.0084643 1 9 1.01 1.0321 -0.022113 1 10 1.02 1.0713 -0.051336 1 11 1.07 1.1069 -0.036949 1- 12 .1.09 1.1396 -0.04956 1 13 1.12 1.1696 -0.049635 1 14 1.15 1.1975 -0.047541 1 15 1.18 1.2236 -0.043569 1 16 1.2 1.248 -0.047957 1 18 1.24 1.2926 -0.052556 1 20 1.26 1.3325 -0.072542 1 22 1.31 1.3688-0.05878 1 24 1.35 1.4019 -0.051913 1 26 1.38 1.4324-0.052431 1 28 1.41 1.4607 -0.050717 1 30 1.44 1.4871 -0.047076 1 35 1.49 1.546 -0.056046 1 40 1.54 1:5972 -0.057206 1 50 1.64 1.6828 -0.042835 1 60 1.72 1.7529 -0.032904 1 70 1.8 1.8122 -0.012209 1 80 1.86 1.8636 -0.003619 1 90 1.91 1.909 0.0010076 1 1 1 100 1.95 1.9496 0.00040124 1 r 120 2.02 2.0199 9.7744E-005 1 140 2.09 2.0794 0.010626 1 160 2.14 2.1309 0.0090901 1 180 2.2 2.1764 0.023619 1 200 2.24 2.2171 0.022934 1 220 2.28 2.2539 0.026124 1 240 2.31 2.2875 0.022513 1 260 2.34 2.3184 0.021591 1 280 2.38 2.347 0.032958 1 300 2.41 2.3737 0.036299 1 330 ' 2.45 2:4105 0.039467 1 360 2.5 2.4442 0.055839 1 420 2.56 2.5037 0.056255 1 480 2.63 2.5554 0.074635 1 =======__======_=====================================a=====__=====a: RESULTS FROM VISUAL CURVE MATCHING VISUAL MATCH PARAMETER ESTIMATES T = S = r/B= Estimate 4.4017E-002 6.4284E-004 1.0000E-005 TYPE CURVE DATA • T = 4.40165E-002 S = 6.42844E-004 r/B= 1.00000E-005 Time 1.000E+000 1.413E+000 1.995E+000 2.818E+000 3.981E+000 5.623E+000 7.943E+000 1.122E+001 1.585E+001 2.239E+001 3.162E+0-01 4.467E+001 6.310E+001 8.933E+001 1.259E+002 1.778E+002 2.512E+002' 3.548E+002 5.012E+002 7.079E+002 1.000E+003 Drawdown 2.958E-001 3.940E-001 5.014E-001 6.159E-001 7.357E-001 8.593E-001 9.858E-001 1.114E+000 1.244E+000 1.375E+000 1.507E+000 1.640E+000 1.772E+000 1.905E+000 2.038E+000 2.172E+000 2.305E+000 2.439E+000 2.572E+000 2.706E+000 2.839E+000 Time 1.122E+000 1.585E+000 2;239E+000 3.162E+000 4.467E+000 6.310E+000 8.913E+000 1.259E+001 1.778E+001 Drawdown 3.274E-001 4.289E-001 5.389E-001 6.553E-001 7.765E-001 9.012E-001 1.028E+000 1.158E+000 1.288E+000 2.512E+001 1.419E+000 -3.548E+001--1:551E+000 5.012E+001 1.684E+000 7.079E+001 1.817E+000 1.000E+002 1.950E+000 1.413E+002 2.083E+000 1.995E+002 2.216E+000 2.818E+002 2.350E+000 3.981E+002 2.483E+000 5.623E+002 2.617E+000 7.943E+002 2..750E+000 Time Drawdown 1.259E+000 3.601E-001 1.778E+000 4.647E-001 2.512E+000 5.771E-001 3.548E+000 6.953E-001 5.012E+000 8.178E-001 7.079E+000 9.434E-001 1.000E+001 1.071E+000 1.413E+001 1.201E+000 1.995E+001 1.332E+000 2.818E+001 1.463E+000 3-.A 81 E+ 0 01-1-.-5 95 E+0 0 0 5.623E+001 1.728E+000 7.943E+001 1.861E+000 1.122E+002 1.994E+000 1.585E+002 2.127E+000 2.239E+002 2.261E+000 3.162E+002 2.394E+000 4.467E+002 2.528E+000 6.310E+002 2.661E+000 8.913E+002 2.795E+000 Radian International Meat: Hamilton Beach<>Proctor-Silex Project Ho.: 650138.0601 Loceuon: Washington, NC Pumping' Test OW-20 Drawdown (ft) 100. 10. 1. 0.1 I I 111111 1 I I I I 1 1 111111 I 1 1 I II11I 10. 100. Time (min) I I I 1114- 1 1 1 1 1 1 I 1 1000. DATA SET: a.aa.a.t intern •OUTFEN TYPE. L.r. SOLUTION .ETHOO: 11•ntMIn TEST DAIE: ulvr ZEST NELL: OSS. NELL: a -A ESIIMATE0 PAR/METERS: . - ..o«n n°nm • - 0.1003131 ▪ f L•<• TEST DMA: 1.1. MILL: COS. Vial: o .... • I•. u AQTESOLV A Program for Automatic Estimation of Aquifer Coefficients From Aquifer Test Data By: Glenn M. Duffield and James 0. Rumbaugh, III Geraghty & Miller Modeling Group 1895 Preston White Drive, Suite 301 Reston, VA 22091 (703) 476 - 0335 AQTESOLV is a user-friendly program designed to analyze data from aquifer tests automatically. Aquifer-. coefficients for a variety of aquifer test conditions can' be estimated by A Q T E S O L V, including the following: o confined aquifers, unconfined aquifers, and leaky aquifers _ o pumping_testsTinjection tests,—reC2ery tests, and slug tests Features: o Interactive, menu -driven program design o Nonlinear least-squares,estimation of aquifer coefficients o Statistical analysis of -results _.o -Complete graphical display of results 12/15/98 AQTESOLV RESULTS Version 1.10 14:11:5: =====================================_________________________. TEST DESCRIPTION Data set ow20.dat Data set title Pumping Test OW-20 Company Radian International Project 650138.0601 Client Hamilton Beach<>Proctor-Silex Location Washington, NC Test date 11/5/98 Test well PW-1 Obs. well OW-20 Knowns and Constants: No. of data points 47 Pumping rate 0.214 Radius (distance) to obs. well 20 Radius of pumped well casing 0.083 Radius of pumped wellbore 0.25 Partial Penetration Data: Depth of top of well screen 1 Depth of bottom of well screen 21 Depth of top of obs. well screen 1 Depth of bottom of obs. well screen21 Hyd. conductivity ratio (Kz/Kr) 1 ANALYTICAL METHOD Hantush (Leaky Aquifer) _______: __________=====a==========a==a=====_=======a a==== a==a======= =____________ RESULTS FROM STATISTICAL CURVE MATCHING STATISTICAL MATCH PARAMETER ESTIMATES T = S = r/B= ANALYSIS residual weighted Estimate 4.4765E-002 +/- 3.1534E-004 +/- 1.0000E-005 +/- Std. Error 1.4800E-003 1.9386E-005 5.0262E+001 OF MODEL RESIDUALS = calculated - observed residual = residual * weight Weighted Residual Statistics: Number of residuals 47 Number of estimated parameters3 Degreesoffreedom 44 Residual mean 0.0106 Residual standard deviation 0.05344 Residual variance 0.002856 Model Residuals: Time Observed Calculated Residual Weight 1 0.24 0.141 0.098999 1 1.5 0.33 0.22764 0.10236 1 2 0.39 0.30045 0.089551 1 2.5 0.45 0.36237 0.087629 1 . 3 0.49 0.41599 0.074015 1 4 0.56 0.50524 • 0.054762 1 5 0.62 0.57774 0.042264 1 6 0.66 0.63872 0.021284 1 7 0.71 0.69131 0.018687 1 8 0.75 0.73755 0.012455 1 9 0.78 0.77878 0.0012185 1 10 0.82 0.81599 0.0040063 1 11 0.85 0.8499 0.00010403 1 12 0.87 0.88103 -0.011028 1 13 0.87 0.90981 -0.039808 1 14 0.92 0.93657 -0.016566 . 1 15 0.94 0.96157 -0.021567 1 16 0.97 0.98503 -0.015027 1 18 0.99 1.028 -0.038012 1 20 1 1.0666 -0.066633 1 22 1.03 1.1017 -0.071693 1 24 1.07 1.1338 -0.063795 1 26 1.1 171634 -0.063398 1 28 1.12 1.1909 -0.070864 1 30 1.15 1.2165 -0.06648 1 35 1.21 1.2739 -0.063861 1 40 1.27 1.3237-0.053711 1 50 1.37 1.4073 -0.037271 1 60 1.43 1.4757 -0.045743 1 70 1.52 1.5338 -0.013751 1 80 1.57 1.5841 -0.014074 1 90 1.63 1:6285 0.0014893 1 100 1.68 1.6683 0.011704 1 12a 1.75 1.7372 . 0.01279 1 140 1.82 1.7955 0.024465 1 160 1.87 1.8461 0.023905 1 180 1.92 1.8907 0.029283 1 200 1.96 1.9306 0.02935 1 220 2.01 1.9668 0.043213 1 240 2.04 1.9998 0.040213 1 260 2.08 2.0302 0.049849 1 280 2.12 2.0583 0.06173 1 300 2.14 2.0845 0.055547 1. 330 2.18 2.1206 0.05937 1 360 2.21 2.1537 0.056336 1 420 2.29 2.2122 0.0778 1 480 2.35 2.2629 0.087081 1 ========ova====================================================_====== ,RESULTS FROM VISUAL CURVE MATCHING VISUAL MATCH PARAMETER ESTIMATES T = S = r/B= Estimate 4.4765E-002 3.1534E-004 1.0000E-005 «c <cc«<c«««««cc ccccc<c<ccc<cccc<c»»»>»»>»»»»»»»»»»»»»> TYPE CURVE DATA T = 4.47646E-002 S = 3.15337E-004 r/B= 1.00000E-005 Time 1.000E+000 1.413E+000 1.995E+000 2.818E+000 3.981E+000 5.623E+000 7.943E+000 1.122E+001 1.585E+001 Drawdown 1.410E-001 2..136E-001 2.998E-001 1. 973E-001 5.037E-001 6.169E-001 7.351E-001 8.570E-001 9.816E-001 Time 1.122E+000 1.585E+000 2:239E+000 3.162E+000 4.467E+000 6.310E+000 8.913E+000 1.259E+001 1.778E+001 2.239E+001 1.108E+000 2.512E+001 3.162E+0011.236E+000 3.548E+001 4.467E+001 1.365E+000 5.012E+001 6.310E+001 1.495E+000 7.079E+001 8.913E+001 1.625E+000 1.000E+002 1.413E+002 1.995E+002 2.818E+002 3.981E+002 5.623E+002 7.943E+002 1.259E+002 1.778E+002 2.512E+002 3:548E+002 5.012E+002 7.079E+002 1.000E+003 1.755E+000 1.886E+000 2.017E+000 2.148E+000 2.279E+000 2.411E+000 2.542E+000 Drawdown 1.635E-001 2.409E-001 3.312E-001 4319E-001 5.408E-001 6.558E-001 7.753E-001 8.982E-001 1.024E+000 1.151E+000 1.279E+000 1.408E+000 1.538E+000 1.668E+000 1.799E+000 1.930E+000 2.061E+000 2.192E+000 2.323E+000 2.454E+000 Time 1.259E+000 1.778E+000 2.512E+000 3.548E+000 5.012E+000 7.079E+000 1.000E+001 1.413E+001 1.995E+001 2.818E+001 3-98tE+001 5.623E+001 7.943E+001 3.122E+002 1.585E+002 2.239E+002 3.162E+002 4.467E+002 6.310E+002 8.913E+002 Drawdown 1.877E-001 2.697E-001 3.637E-001 4.674E-001 5.785E-001 6.952E-001 8.160E-001 9.398E-001 1.066E+000 1.193E+000 1-: 322E+000 1.451E+000 1.581E+000 1.712E+000 1.843E+000 1.973E+000 2.104E+000 2.236E+000 2.367E+000 2.498E+000 Radian International CI mnt: Hamilton Beach<>Proctor-Silex ProIecl No.: 650138.0601 Locet Ion: Washington, NC Pumping Test MW-220 10. 0.01 1. 1 1 1 1 I 1 1 I 1 1 I I III 1 1 1111-1k- I I IIIIII I I I 11 1 1 1 I 1 1 1 1 1 1 1 1 10. Time 100. 1000. min) DATA SET: Eli Oda EDIT IF EN TYPE: Lvov SOLUI ION ME MOO. Nwl..n ZEST DATE: M/Vle TEST HELL: OBS. NELL: EST !MATE° PEMME TENS: I - 0.4E5A raeLln • - 1.O0011.50 NI- I.EW TEST PAL: 0- 0 as. I.I/.m . .COI. • [ - 0:0II It 0-]I I. tics tall: MOS. MOIL .... -]I. I. ««< c «< c ««c «««««««««««c <c»»»»»»»»»» >o»»»»»»»>>>: AQTESOLV A Program for Automatic Estimation of Aquifer Coefficients From Aquifer Test Data By: Glenn M. Duffield and James 0. Rumbaugh, III Geraghty & Miller Modeling Group 1895 Preston White Drive, Suite 301 Reston, VA 22091 (703) 476 - 0335 AQTESOLV is a user-friendly program designed to. analyze data from aquifer tests automatically. Aquifer. coefficients for a variety of aquifer test conditions can be estimated by A Q T E S 0 L V, including the following: • o confined aquifers, unconfined aquifers, and leaky aquifers o pumping tests, injection tests, recovery testa, and slug tests Features: o Interactive, menu -driven program design." o Nonlinear least -squares estimation of aquifer coefficients o Statistical analysis of results o Complete graphical display of results « « « « « « « « « c<cc« ce« « « « « cc « » » » » » » » » » » » » » » » » » »»» AQTESOLV R E S U L T S Version 1.10 12/15/98 TEST DESCRIPTION Data set mw220.dat Data Set title Pumping Test MW-220 Company Radian International Project 650138.0601 Client Hamilton Beach<>Proctor-Silex Location Washington, NC Test date 11/5/98 • Test well. PW-1 Obs. well MW-220 Knowns and Constants: No. of data points 40 Pumping rate 0.214 Radius (distance) to obs. well 48.5 Radius of pumped well casing 0.083 Radius of pumped wellbore 0.25 Partial Penetration Data: Depth of top of well screen 1 Depth of bottom of well screen...,21 Depth of -top of obs. well screen 1 Depth of bottom of obs. well screen.. 21 Hy_d. conductivity ratio (Kz/Kr)...... 1 ANALYTICAL METHOD Hantush (Leaky Aquifer) 14:13:22 === ==== ======__===========va====aaaaaassaas=samaaa=aa==sa====s==========___=====_====_ RESULTS FROM STATISTICAL CURVE MATCHING STATISTICAL. MATCH PARAMETER ESTIMATES Estimate Std. Error T = 4.5056E-002 +/- 1.7333E-003 S = 3.2553E-004 +/- 1.1315E-005 r/B= 1.0000E-005 +/- 2.5352E+002 ANALYSIS OF MODEL RESIDUALS residual = calculated.- observed weighted residual = residual * weight Weighted Residual Statistics: Number of residuals 40 Number of estimated parameters3 Degrees of freedom 37 Residual mean 0.006571 Residual standard deviation 0.03199 Residual variance 0.001023 Model Residuals: Time Observed Calculated Residual Weight 1 0.05 0.0010582 0.048942 1 2 0.08 0.015579 0.064421 1 2.5 0.08 0.028237 0.051763 1 3 0.1 0.04286 0.05714 1 5.5 0.18 0.12342 0.056582 1 6 0.18 0.13911 0.040886 1 7 0.2 0.16935 0.030646 1 8 0.22 0.19796 0.022045 1 10.5 0.28 0.26256 0.017442 1 11 0.29 0.2744 0.015601 1 12 0.31 0.29712 0.012881 1 13 0.32 0.31865 0.0013528 1 14 0.33 0.33909 -0.0090891 1.. 15 0.35 0.35854 -0.0085386 1 16 0.36 0.37708 -0.01708 1 18 0.39 0.41173 -0.021735 1 20 0.42 0.44357 -0.023565 1 30 0.56 0.57229-0.012287 1 35.5 0.63 0.62814 0.0018627 1 40 0.67 0.66843 0.0015658 1 50 0.72 0.74512 -0.025117 1 60 0.77 0.80888 -0.038879 1 70 0.83 0.86344 -0.033442 1 80 0.88 0.91113 -0.031125 1 90 0.93 0.95347 -0.023468 1 100 0.98 0.99155 -0.011546 1 120 1 1.0578 -0.057832 1 140 1.14 1.1142 0.025784 1 160 1.17 1.1633 0.0067275 1 1801 1.22 1.2067 0.013311 1 200 1.28 1.2456 0.03437 1 220 1.28 1.2809 -0.00093139 1 240 1.28 1.3132 -0.033216 1 260 1.31 1.343 -0.032959 1 280 1.38 1.3705 0.0094681 1 300 1.41 1.3962 0.013771 1 330 1.45 1.4318 0.01823 1 363 1.51 1.4674 0.042645 1 420 1.56 1.5219 0.038115 1 480 1.59 1.5719 0.018121 1 ___=___=============aa=aaaa===============================a=============_: as==. RESULTS FROM VISUAL CURVE MATCHING VISUAL MATCH PARAMETER ESTIMATES = S = r/B= Estimate 4.5056E-002 3.2553E-004 1.0000E-005 TYPE CURVE DATA 1 T = 4.50557E-002 S = 3.25529E-004 r/B= 1.00000E-005 Time 1.000E+000' 1.413E+000 1.995E+000 2.818E+000 3.981E+000 5.623E+000 7.943E+000 1.122E+001 1.585E+001 2.239E+001 3.162E+001 4.467E+001 6.310E+001 8.913E+001 1.259E+002 1.778E+002 2.512E+002 3.548E+002 5.012E+002 7.079E+002 1.000E+003 Drawdown 1.058E-003 4.883E-003 1.547E-002 3.738E'-002 7.417E-002 1.273E-001 1.964E-001 2.795E-001 3.743E-001 4.784E-001_ 5.896E-001 7.062E-001 8.266E-001 9.499E-001 1.075E+000 1.202E+000 1.330E+000 1.459E+000 1.588E+000 1.718E+000 1.848E+000 Time 1.122E+000 1.585E+000 2.239E+000 3.162E+000 4.467E+000 6.310E+000 8.913E+000 1.259E+001 1.778E+001 2:512E+001 3.548E+001 5.012E+001 7.079E+001 1.000E+002 1.413E+002 1.995E+002 2.818E+002 3-981E+002 5.623E+002 7.943E+002 Drawdown 1.852E-003 7.433E-003 2.131E-002 4.787E-002 9.005E-002 1.486E-001 2.226E-001 3.099E-001 4.081E-001 5.148E-001 6:280E-001 7.459E-001 8.675E-001 9.915E-001 1.117E+000 1.245E+000 Time 1.259E+000 1.778E+000 2.512E+000 3.548E+000 5.012E+000 7.079E+000 1.000E+001 1.413E+001 1.995E+001 2.818E+001 3.981E+001 5.623E+001 7.943E+001 1.122E+002 1.585E+002 2.239E+002 1.373E+000 3.162E+002 1: 5 0 2 E+0 0 0--- 4.-16 7-E+0 0 2 1.631E+000 6.310E+002 1.761E+000 8.913E+002 Drawdown 3.077E-003 1.090E-002 2.857E-002 6.011E-002 1.078E-001 1.717g-001 2.504E-001 3.416E-001 4.428E-001 5.519E-001 6.668E-001 7.861E-001 9.086E-001 1.033E+000 1.160E+000 1.287E+000 1.416E+000 1 545E+000 1.674E+000 1.804E+000 I.2 Rail -down Tests I.2.1- Introduction Bail -down tests were conducted at wells MW-217, MW-219, MW-223, and MW- 231. The objective of the tests was to determine the hydraulic conductivity of the hydrogeologic unit A at the facility. The test sites were selected based on their locations in different parts of the facility. A "secondary consideration was each well's location outside any chemical plume, which allowed water generated during the test to be disposed without treatment. I.2.2 Bail -down Test Description All wells tested are screened in hydrogeologic unit A. Instantaneous removal of water to effect the initial drawdown was performed using an electric -powered peristaltic pump. Immediately after withdrawal, water -level recovery in each well was measured using an electric water -level indicator and recorded manually. Measurement continued at regular intervals until the -water level_recovered.to_withit at east95_percentoequilibriUm. Results of the tests are discussed in Section I.1.3.2: I.2.3 Bail -down Test Analysis This section describes the analytical procedure used to evaluate the data from each bail -down test and presents the results. Tables and graphs of water -level recovery measurements utilized in the analysis of each test are included at the end of the discussion. I.2.3.1 Analytical Procedure The conceptual model used to analyze each bail -down test is that of an unconfined aquifer with completely or partially penetrating wells . Governing equations and type curves are those presented by Bouwer and Rice (1976). Type curves were initially fit to measured drawdown data by nonlinear least -squares parameter estimation and, subsequently, matched visually using AQTESOLV software developed by Geraghty and Miller Modeling la c:\hamilton\washington\csa.rpt (1 V 16198) 1-3 Group (Duffield, 1991). Input to the aquifer model, in addition to the measured water levels, included initial drawdown (H,); well casing radius (r.); borehole radius (rw); saturated length of well screen (L); aquifer thickness (b); and height of water in the well. Specific input values for these parameters ate listed under "Test Data" on the accompanying graphs. I.2.3.2 Bail -down Test Results Hydraulic conductivity values calculated for hydrogeologic unit A range from 3.9 x 10'' ft/min (5.7 x 104 ft/day) to 5.1 x 104 ft/min (7.4 x 10'2 ft/day). The range of hydraulic conductivity values are representative of clay, sandy silt, and clayey sand. la ehamilton\washington\cu-tpt (12/16/98) I-4 Radian International Client: Hamilton Beach<>Proctor—Silex Molect No.: 650138.0601 Location: Washington, NC MW-217 Ba it —down Test Displacement (ft) 10. 0.1 a11111111111IIIIIII 1' 11111'111 11111111111111111I1- 0 0 0 0 0 0 0. 01 1 1 1 1 1 1 1 1 1 1 1 1 i 1. 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1-1 1 1 1 1 1 1 1 1 1 0. 6.4 12.8 19.2 .25..6 32. Time (min) DATA SEA: Sale,.. AQUIFER TYPE: L,cai me SOLUTION METHOD. asera.s. TEST DATE: Ie,YVf 1ESI WELL: le-a0 OILS. SELL: ESTIMATED PARAMETERS: a • I.51a1L0' /Uem 0-O.wM IESI DATA: W-00A/I t - 0.03 II O.GI It AQTESOLV A Program for Automatic Estimation of Aquifer Coefficients From Aquifer Test Data By: Glenn M. Duffield and James 0. Rumbaugh, III Geraghty & Miller Modeling Group 1895 Preston White Drive, Suite 301 Reston, VA 22091 (703) 476 - 0335 AQTESOLV is a user-friendly program designed to. analyze data from aquifer tests automatically. Aquifer coefficients for a variety of aquifer test conditions can be estimated by A Q T E S 0 L V, including the following: o confined aquifers, unconfined aquifers, and leaky aquifers o—ptmptng-tests, ction tests recovery tests, and slug tests Features: o Interactive, menu -driven program design o Nonlinear least -squares estimation of aquifer coefficients o Statistical analysis of results -o Complete graphical display of results <C«<<c« « « « « « «« « « « « « «c« « » » »» » » » » » » » » » » » » » » » 12/15/98 A Q T E S O L V RESULTS Version 1.10 TEST DESCRIPTION Data set mw217.dat Data set title MW-217 Bail -down Test Company Radian International Project 650138.0601 Client Hamilton Beach<>Proctor-Silex Location Washington, NC Test date • 10/04/98 Test well MW-217 Knowns and Constants: No. of data points 28 Radius of' well casing 0.02 Radius of well 0.083 Aquifer saturated thickness 4.42 Well screen length 4.42 Static height of water• in well 4.42 Log(Re/Rw) 3.045 A, B, C 0.000, 0.000, 2.754 __________ ANALYTICAL METHOD Bouwer-Rice (Unconfined-Aquifer-Siug-Test) 13:50:2 _________________________________________=====as=====_________________________ RESULTS FROM STATISTICAL CURVE MATCHING STATISTICAL MATCH PARAMETER ESTIMATES Estimate Std. Error. K = 1.5276E-005 +/- 8.6034E-007 y0 = 4.3333E+000 +/- 1.2807E-001 ANALYSIS OF MODEL RESIDUALS residual = calculated - observed weighted residual.= residual * weight Weighted Residual Statistics: Number of residuals 28 Number of estimated parameters2 Degrees of freedom 26 Residual mean -0.05019 Residual standard deviation 0.2284 Radian International C,tant: Hamilton Beach<>Proctor—Silex Project No.: 650138.0601 Luca ton: Washington, NC MW-219 B -down Test Displacement (ft) 10. 1. 0.1 111111IIIIIIIIIIIIIIIIIIII111 IIIIIIIIIIIIIIIIIII- 0 0 0 0 0.01 IIIIIIIIII111111111I11111111 IIIIIIII11I111 11111a 0. 6.4 12.8 19.2 25.6 32. Time (min) DATA SET: ultvu AQUIFER TYPE: untie t/i d SOLUTION METHOD: mer-lift. TEST DATE: IOIWY TEST WELL: r-au OBS. WELL: ESTIMATED PARAMETERS a - 3..)]I- S nn.a Io- Lis so ZEST DATA: .W • t Y It re - 0.02 It re .• 0.00.1 It - 3.- It • • Of It a• )O[I1 Residual variance 0.05216 Model Residuals: Time Observed Calculated - Residual Weight 0.5 3.84 4.0996 -0.25959 1 1 - 3.64 3.8785 -0.23849 1 1.5 3.49 3.6693 -0.17931 1 2 3.36 3.4714 -0.11142 1 2.5 3.25 3.2842 -0.034197 1 3 3.13 3.1071 0.022927 1 3.5 3.01 2.9395 0.070498 1 4 2.93 2.781 0.14903 '1 4.5 2.8 2.631 0.16902 1 5 2.69 2.4891 0.20091 1 5.5 2.61 2.3548 0.25515 1 6 2.5 2.2278 0.27215 1 7 2.26 1.994 0.26598 1 8 2.04 1.7847 0.25526 1 9 1.8 1.5974 0.20258 1 10 1.57 1.4298 0.14024 1 11 1.32 1.2797 0.0403 1 12 1.08 1.1454 -0.065388 1 14 0.7 0.91758 -0.21758 1 16 0.38 0.73507 -0.35507 1 18 0.19 0.58887 -0.39887 1 20 0.1 0.47175 -0.37175 1 22 0.06 0.37792 -0.31792 1 24 0.04 .0.30275 -0.26275 1 26 0.03 0.24254 -0.21254 - 1 28 0.02 0.1943 -0.1743 1 30 0.02 0.15565 -0.13565 1 32 0.01 0.12469 -0.11469 1 _________ RESULTS FROM VISUAL CURVE MATCHING VISUAL MATCH PARAMETER ESTIMATES Estimate K = 1.5276E-005 y0 = 4.3333E+000 TYPE CURVE DATA K = 1.52764E-005 y0 = 4.33329E+000 Time Drawdown Time Drawdown Time Drawdown 0.000E+000 4.333E+000 3.200E+001 1.247E-001 r-� AQTESOLV A Program for Automatic Estimation of Aquifer Coefficients From Aquifer Test Data By: Glenn M. Duffield and James 0. Rumbaugh, III Geraghty & Miller Modeling Group 1895 Preston White Drive, Suite 301 Reston, VA 22091 (703) 476 - 0335 AQTESOLV is a user-friendly program designed to. analyze data from aquifer tests automatically. Aquifer coefficients for a variety of aquifer test conditions can be estimated by A Q T E S O L V, including the following:. o confined aquifers, unconfined aquifers, and leaky aquifers o pumping tests, injection tests, recovery tests, and slug tests Features: o Interactive, menu -driven program design o Nonlinear least -squares estimation of aquifer coefficients o Statistical analysis of results o Complete graphical display of results AQTESOLV RESULTS Version 1.10 12/15/98 14:02:1 ____________________________=__===========a===========a=====___________________ TEST DESCRIPTION Data set mw219.dat Data set title MW-219 Bail -down Test Company Radian International Project 650138.0601 Client Hamilton Beach<>Proctor-Silex Location Washington, NC Test date 10/04/98 Test well MW-219 Knowns and Constants: No. of data points' 28 Radius of well casing 0.02 Radius of well 0.083 Aquifer saturated thickness 3.86 Well screen length 3.86 Static height of water in well 3.86 Log(Re/Rw) 2.936 A, B, C 0.000, 0.000, 2.519 _________ ______ __= ====== ANALYTICAL METHOD Bouwer-Rice (Unconfi g—Test-) ____________________=========a=====a======a=a=====__===========_ RESULTS FROM STATISTICAL CURVE MATCHING STATISTICAL MATCH PARAMETER ESTIMATES Estimate Std. Error. K = 3.1333E-005 +/- 8.3575E-007 y0 = 3.7101E+000 +/- 6.2539E-002 ANALYSIS OF MODEL RESIDUALS residual = calculated - observed weighted residual = residual * weight Weighted Residual Statistics: Number of residuals 28- Number of estimated parameters2 Degrees of freedom 26 Residual mean 0.00792 Residual standard deviation 0.08102 Residual variance 0.006564 Model Residuals: Time Observed Calculated Residual Weight 0.5 3.22 3.3469 -0.12694 1 1 3.01 3.0194 -0.0093585 1 1.5 2.79 2.7238 0.066159 1 2 2.47 2.4572 0.012753 1 2.5 2.3 2.2167 0.083254 1 3 2.08 1.9998 0.080216 1 3.5 2.04 1.8041 0.23594 1 4 1.47 1.6275 -0.15749 1. 4.5 1.46 1.4682 -0.008197 1 5 1.37 1.3245 0.045502 1 5.5 1.06 1.1949 -0.13486 1 6 1.04 1.0779 -0.037918 1 7 0.81 0.87724 -0.067243 1 8 0.63 0.71393 -0.083927 1 9 0.52 0.58102 -0.061016 1 10 0.45 0.47285 -0.022849 1 11 0.39 0.38482 0.005181 1 12 0.35 0.31318 0.036822 1 14 0.27 0.20742 0.062576 1 16 0.2 0.13738 0.062619 1 18 0.15 0.09099 0.05901 1 20 0.1 0.060265 0.039735 1 22 0.08 0.039915 0.040085 1 24 0.06 0.026436 0.033564 1 26 0.04 0.017509 0.022491 1 28 0.04 0.011597 0.028403 1 30 0.02 0.0076808 0.012319 1 32 0.01 0.0050871 0.0049129 1 RESULTS FROM VISUAL CURVE MATCHING VISUAL MATCH PARAMETER ESTIMATES Estimate K = 3.1333E-005 y0 = 3.7101E+000 TYPE CURVE DATA K = 3.13328E-005 y0 = 3.71006E+000 Time Drawdown Time Drawdown Time Drawdown 0.000E+000 3.710E+000 3.200E+001 5.087E-003 Radian International Client: Hamilton Beach<>Proctor-Silex PEEL" NEL: 650138.0.601 Location: Washington, NC • MW-223 Bail —down Test Displacement (ft) p r DATA SEC motet a.I 12T15/91 • J11111111111111111111111111111111111111111111111L IIIII — 1OUIFEN TYPE: Nconr wa SOLUTION MEIMOO: s.rrrlc. LEST DATE: a0/Wi TEST WELL: OBS. WELL: to -no Di ' • •-uI • • • $ • Q — III 1111II III' IIIII I I I III 1111 _ -- _ _ 0 O O O II-I1111IIIII ESTIMATED PAMAMETEMS: I(- a.ImtWin .Ea n re- 6u]rt \. TEST DATA: N - .. YY It rc-a.OZII - 0.OYI rI b.a) II e - a.an • 2.4 4.8 i.2 Time (min) 9..6 12. AQTESOLV A Program for Automatic Estimation of Aquifer Coefficients .From Aquifer Test Data By: Glenn M. Duffield and James 0. Rumbaugh, III Geraghty & Miller Modeling Group 1895 Preston White Drive, Suite 301 Reston, VA 22091 (703) 476 -'0335 AQTESOLV is a user-friendly program designed to analyze data from aquifer tests automatically. Aquifer coefficients for a variety of aquifer test conditions can be estimated by A Q,T E S 0 L V , including the following: o confined aquifers, unconfined aquifers, and leaky aquifers o putivisly teats, i-nj-ect-ion—tests,—recovery tests, and slug tests Features: o Interactive, menu -driven program design o Nonlinear least -squares estimation of. aquifer coefficients o Statistical analysis of results --o Complete graphical display of results 12/15/98 ==__== AQTESOLV RESULTS Version 1.10 14:03:45 ===========================_=_____==__=___===================_____=_: TEST DESCRIPTION Data set mw223.dat Data set title MW-223 Bail -down Test Company Radian International Project 650138.0601 Client Hamilton Beach<>Proctor-Silex Location Washington, NC Test date 10/04/98 Test well MW-223 Knowns and Constants: No. of data points 18 Radius of well casing 0.02 Radius of well 0.083 Aquifer saturated thickness 5.47 Well screen length 5.47 Static height of water in well 5.47 Log(Re/Rw) 3.214 A, B, C 0.000, 0.000, 3.195 ==__======== =_=_=_==__ ANALYTICAL METHOD ___'____====_= Bouwer-Rice (Unconfined Aquifers ug Teat RESULTS FROM STATISTICAL CURVE MATCHING STATISTICAL MATCH PARAMETER ESTIMATES Estimate Std. Error K = 5.1014E-005 +/- 1.6398E-006 y0 = _4.7431E+000 +/- 1.1671E-001 ANALYSIS OF MODEL RESIDUALS residual = calculrated - observed weighted residual = residual • weight Weighted Residual Statistics: Number of residuals 18 Number of estimated parameters2 Degrees of freedom 16 Residual mean 0.04066 Residual standard deviation 0.09684 =_=___==_=____=_ Residual variance 0.009377 Model Residuals: Time Observed Calculated Residual Weight 0.5 3.87 3.8177 . 0.05229 1 1 - 3.08 3.0729 0.0071428 1 1.5 2.53 2.4733 0.056671 1 2 1.91 1.9908 -0.080771 1 2.5 1.5 1.6024 -0.10236 1 3 1.22 1.2897 -0.069734 1 3.5 0.97 1.0381 -0.068101 1 4 0.81 0.83556 -0.025563 1 4.5 0.68 0.67254 0.007459 1 5 0.58 0.54133 0.038675 1 5.5 0.49 0.43571 0.05429 1 6 0.43 0.3507 0.079299 1 7 0.32 0.2272 0.092796 1 8 0.26 0.1472 0.1128 1 9 0.21 0.095362 0.11464 1 10 0.2 0.061781 0.13822 1 11 0.2 0.040025 0.15997 1 12 0.19 0.025931 0.16407 . 1 ==aa=========aasaaaa======aa=====a======a=====a==a========a=========a==a====a== RESULTS FROM VISUAL CURVE MATCHING VISUAL MATCH PARAMETER ESTIMATES Estimate K = 5.1014E-005 y0 = 4.7431E+000 c c c c c c ««c c c c c c «c «c <c ««c c c c c c««c c»»»»»»»»»»»> i»»»»»»»> TYPE CURVE DATA K = 5.10138E-005 y0 = 4.74311E+000 Time Drawdown Time Drawdown Time • Drawdown 0.000E+000 4.743E+000 1.200E+001 2.593E-002 Radian International CI tent: Hamilton Beach<>Proctor-Si1ex Protect no.: 650138.0601 Local Ton: Washington, NC MW-231 B ii1—down Test . Displacement (ft) 1. Iflllllllllllllllllllllllllll IIIIIIIIIIIIIIIIIIII 0.1 IIIIIIIIIIIIIILIIIIIIIIIIIII IIIIIIIIIIIIIIIIIIII 0. 12. 24. 36. 48. 60. Time (min) DATA SET: .i)1.Y1 32/1.0JOS £OuIfER TYPE: Lan./ IMI Saul DST RETn00:. TEST DATE: Waves LEST WELL: y-61, o5. WELL: ESTIW TEO P*RIWE IERS: 14 - 3.6322E-0I II/.to p - 6.I611 11 IESI DATA: oti It - 0.01It - 1.67 It .- let It n-167 It AQTESOLV A Program for Automatic Estimation of Aquifer Coefficients From Aquifer Test Data By: Glenn M. Duffield and James 0. Rumbaugh, III Geraghty & Miller Modeling Group 1895 Preston White Drive, Suite 301 Reston, VA 22091 (703) 476 - 0335 AQTESOLV is a user-friendly program designed to analyze data from aquifer tests automatically. Aquifer.. coefficients for a variety of aquifer test conditions can be estimated by A Q T E S 0 L V, including the following: o confined aquifers, unconfined aquifers, , and leaky aquifers o—pullyiatg-test9,—indection-tests .-ecovery-tests, and slug tests Features: o Interactive, menu -driven program design o Nonlinear least -squares estimation of aquifer coefficients o Statistical analysis of results -o Complete graphical display of results 12/15/98 AQTESOLV RESULTS Version 1.10 14:07:5 _====__==============================s=========-=----a====== TEST DESCRIPTION Data set mw231.dat Data set title MW-231 Bail -down Test Company Radian International Project 650138.0601 Client Hamilton Beach<>Proctor-Silex Location Washington, NC Test date 10/04/98 Test well MW-231 Knowns and Constants: No. of data points 41 Radius of well casing 0.02 Radius of well 0.083 Aquifer saturated thickness 3.67 Well screen length 3.67 Static height of water in well 3.67 Log(Re/Rw) 2.894 A, B, C 0.000, 0.000, 2.440 ===s======a========s== ANALYTICAL METHOD Bouwer-Rice (Unconfrned Agntfer-SlugTest) ==___=_==_ ====ass======================a========s=saes===sass========a=====_______===___: RESULTS FROM STATISTICAL CURVE MATCHING • STATISTICAL MATCH PARAMETER ESTIMATES. Estimate Std. Error K = 3.9322E-007 +/- 3.5856E-008 y0 = 7.9715E-001 +/- 5.2288E-003 ANALYSIS OF MODEL RESIDUALS residual = calculated - observed weighted residual a residual * weight Weighted Residual Statistics: Number of residuals_ 41 Number of estimated parameters2 Degrees of freedom 39 Residual mean 1.024E-005 Residual standard deviation 6.02034 Residual variance 0.0004135 Model Residuals: Time Observed Calculated Residual = Weight 0.5 0.88 0.79616 0.083845 1 1 0.85 0.79516 0.054837 1 1.5 0.82 0.79417 0.025827 1 2 0.82 0.79318 0.026816 1 2.5 0.79 0.7922 -0.0021955 1 3 0.79 0.79121 -0.0012086 1 3.5 0.79 0.79022 -0.00022301 1 4 0.78 0.78924 -0.0092386 1 4.5 0.78 0.78826 -0.0082555 1 5 0.77 0.78727 -0.017274 1 6 0.77 0.78531. -0.015313 1 7 0.77 0.78336 .-0.013358 1 8 0.77 0.78141 -0.011408 1 9 0.77 0.77946 -0.009462 1 10 0.77 0.77752 -0.0075213 1 11 0.76 0.77559 -0.015585 1 12 0.76 0.77365 -0.013654 1 14 0.75 0.76981 -0.019807 1 16 0.75 0.76598 -0.015978 1 18 Q.74 0.76217 -0.022168 1 20 0.74 0.75838 -0.018378 1 22 0.74 0.75461 -0.014606 1 24 0.74 0.75085 -0.010853 1 26 0.74 0.74712 -0.0071185 1 28 0.73 0.7434 -0.013403 1 30 0.73 0.73971 -0.0097054 1 32 0.73 0.73603 -0.0060265 1 34 0.73 0.73237-0.0023658 1 36 0.73 0.72812 0.OU r2766 1 38 0.72 0.7251 -0.0050991 .1 40 0.72 0.72149 -0.0014928 1 42 0.72 0.7179 0.0020955 1 44 0.72 0.71433 0.005666 1 46 0.71 0.71078 -0.00078128 1 48 0.71 0.70725 0.0027538 1 50 0.71 0.70373 0.0062713 1 52 0.71 0.70023 0.0097713 1 54 0.71 0.69675 0.013254 1 56 0.71 0.69328 0.016719 1 58- 0.7 0.68983 0.010167 - 1 60 0.7 0.6864 0.013598 1 RESULTS FROM VISUAL CURVE MATCHING. VISUAL MATCH PARAMETER ESTIMATES Estimate K = 3.9322E-007 y0 = 7.9715E-001 «««<- ««««««««««««««.<.:<. »»»»»»»»»»»»»»»-» TYPE CORVE DTa K = 3.93232E-007 y0 = 7.977.48E-001 Time Drawdown ,Time Drawduwn Time Drawdown 0 000E+00^ 7 971E-001 6.000E+001 6.864E-001 ATTACHMENT H 4 Pilot -Scale Test Monitoring Newly constructed 1-inch diameter monitoring wells will be�uti ized to measure to effectiveness of the treatment during the pilot applicatio i1Q ne monitoring wells will be ib ed in both hydrogeologic units. Three wells be placed upgradient of the injection point , ee downgradient of the injje 3 n points, and three adjacent to the injection points in both b its A and B. T -swells will be sampled before, during, and after the pilot test. Samples wi b- . alyzed for VOCs, SVOCs, CO2, Ethane, and Methane. Iri addition, par. .• - e dissolved oxygen, pH, conductivity,. temperature, and oxi.: ion -reduction potent.. ORP) will be recorded during the application pr. • - ss to gauge the progress of reaction n�the treatment area. The on -site activiti- .. sociated with the pilot -scale test will be conductZ;d,for a period of a roximately eight weeks. rs suc ATTACHMENT K Table 5-3 Monitoring Well Construction Data Hamilton BeachOProctor-Silex, Washington, North Carolina Well No. installation Date Top of Casing Elevation (ft. above MSL) Total Depth (ft. bks) Screen Interval (ft. bg) Filler Pack (ft. bgs) Bentonite Seal (ft. bgs) Grout Seal (ft. bgs) MW-2015 9/10/92 29.74 9.9 7.9-9.9 5-9.9 2.9-5 0-2.9 MW-201D 9/10/92 29.71 45' 43-45 14-45 2.9-14 0-2.9 MW-202 9/10/92 34.98 1t 4-14 3.5-14 2-3.5 0-2 MW-203 9/11/92 32.16 I 5-15 • 4-15 2-4 0-2 MW-204 9/11/92 32.65 ISJJI 5-15 4-15 2-4 0-2 MW-205 9/11/92 • 31.75 l5 5-15 4-15 1.3-4 0-1.3 MW-206 9/11/92 28.79 13.5 3.6-13.6 3.1-13.6 0.7-3.1 0-0.7 MW-207 11/4/92 33.78 10.4 5.4-10.4 4.2-10.4 1.2-4.2 0-1.2 MW-208 11/4/92 32.11 9.i 4.7-9.7 4-9.7 1.2-4 0- 1.2 MW-209 1/14/98 32.93 26 16.4-26.4 14-26.4 13- 14 0- 13 MW-210 1/14/98 32.49 2 12-20 11-20 9.3-11 0-9.3 MW-211 1/14/98 31.75 7.5 3-7.5 2.5-7.5 1.5-2.5 0-1.5 MW-212 1/14/98 28.45 20 12-20 11-20 10-11 0-10 MW-213 1/14/98 28.44 74 3-7.5 2.5-7.5 1.5-2.5 0-1.5 MW-214 1/16/98 27.93 2I 14.5-21 13.5-21 12.5-115 0-12.5 MW-215 1/16/98 28.06 14 8.5-10 8-10 7-8 0-7 MW-216 5/5/98 32.82 1 35 26 - 35 25 - 35 24 - 25 0 - 24 MW-217 5/5/98 32.75 1 10 • 4-10 3-10 2-3 0-2 la c:lhamiltim\washPngluWcsa-ryl (1/20/99) Table 5-3 (Continued) Well No. Installation Date Top of Casing Elevation (ft. above MSL) TotalDepth (MI bgs) Screen Interval (ft. bgs) Filter Pack (ft. bgs) Bentonite Seal (ft. bgs) Grout Seal (It. bgs) M W-218 5/6/98 31.55 B7 28 - 37 27 - 37 • 26 - 27 0 - 26 MW-2I9 1 5/5/98 .31.83 0 4 - 10 3 - 10 2 - 3 0 - 2 MW-220 5/5/98 31.50 34 25 - 34 24 - 34 23 - 24 0 — 23 MW2221 5/5/98 31.39 , 10 4-10 3-10 2-3 0-2 MW-222 5/6/98 35.11 40 31 -40 30 - 40 29 - 30 0 - 29 MW-223 5/6/98, 35.15 10 4- 10 3- 10 2- 3 0- 2 MW-224 11/13/98 33.43 134 25 - 34 24 - 34 23 - 24 0 - 23 MW-225 11/13/98 ,'33.43 10 4-10 3-10 2-3 0-2 MW-226 9/30/98 28.46 75 70 - 75 69 - 75 67 - 69 0 - 67 MW-227 10/1/98 28.47 25.5 20.5 - 25.5 19.5 - 25 5 17.5 - 19.5 0 - 17.5 MW-228 9/23/98 28.71 10 3 - 10 2 - 10 1 - 2 0 - 1 MW-229 10/26/98 30.44 10 4- 10 3- 10 2- 3 0- 2 MW-230 10/26/98 33.47 14 8 - 14 _ 7 - 14 5 - 7 0 - 5 M W-231 10/26/98 31.94 10 4- 10 3- 10 2- 3 0- 2 PW-I 9/24/98 31.97 35 15-35 13.5-35 11-13.5 0-11 OW-10 10/26/98 31.27 30 18 - 30 16 - 30 14 - 16 0 - 14 OW-20 10/26/98 31.71 30 18 - 30 17 - 30 15 - 17 0 - 15 Monitoring wells 201 through 208 installed by Engineering Tec onics, .A. Monitoring well 206 was closed by grouting on 9/23/98. Monitoring wells 209 through 215 installed by Groundwater Managem nt Associates, Inc. Monitoring wells 216 through 223 installed by Radian Mobile Feld Services. Monitoring wells 226 through 228 and pumping well PW-1 installed by Parratt Wolff, Incl. Monitoring wells 224, 225, and 229 through 231, and observation wells OW-10 and OW-20 installed by Probe Technology, Inc. la c \hamilton\washingtonksa-spl (I/20/99) __I 4 1 DPT Rig : 7: '1 PSI Guage Q Control Valve Pump Trailer Fe/Guar Slurry Infiltrate U Injection Ports Injedtion Schematic Zero—Valent Iron and a Carbon Source C:\Injection ATTACHMENT N SITE LOCATION Figure r 2-1. Topographic Map Hamilton Beach $ Proctor—Silex, Inc. C \NHVSNSSTC-GBJUN9B-1115 se PLANT BUILDING Parking Cua d House Former Fuel AS (removed) Former Solvent AST (removed), Petroleum ASTs (diked) Shed Hazardous Materials Storage Shed Former IPA/ Noptho AST Employee Parking Pump House Hazardous Wosle Storage Shed LPG AST Landlarming Area D rBuilding fl_ Rood and/or Parking Area ZT — • — Property Line - Fenceline t Ditch O Water Tank Cooling Tower m Translormers AST Aboveground Storoge Tank UST Underground Storage lank 200 200 SCALE IN FEET As srawn momma RADIAN iinniAT101ML r rse .evc mouseFp✓•jeap 2-3 irrc 11Nivmse some waaw-sr. c. 6501340001 I SOL T0 A / (MW-201S °MW-201D C • —2 1> / •/Mw-222 ' A W 223 2 i'I :Jl1 liu0 I iINI. YW-207 MW-206 • MW-215 `;I 15.16 MW-21 { • I 'FPA I YW-203,1 it l YW+221. MW-2 .MW-209 w-208 1/111-226 60V72 2♦ lW-213 l ' • MW-217 1•W-204 MW-216l •MW-219 1 MW_a .MW-210 YW-218 -> W-228 YW 227 —220 MW-225 YW-224 200 0 YW-230 —231 SCALE IN FEET LE. ND o Monitoring Web Nolo: Well YW-206 was properly closed in October 1998. AS vlwn ,x Ixccee `r s-2. Iscdrn d 200'P" wr err.. 1511 IIR^'s' - Ando a sr S.Y.. Y. S]e1Y 0401 I Lana RADIAN MYliW 70tMll"vc Io D\ HBPS \ UNITA- AREA \ 17 JUN99 • • .. • 200 .. 0 200 SCALE IN FEET LEUND + Monitoring Well Location • Groundwater Screening Location [74 Remediation with Chemical Oxidization flRemedialion with Zero—Volence Iron and a Carbon Source X Zero —Valence Iron and a Carbon Source Pilot —Scale Testing Injection Location A Chemical Oxidation Pilot —Scale Testing Injection Location (Groundwater) * Chemical Oxidation Pilot —Scale Testing Injection Location (Unsaturated Soil) AS SHOWN IIRADIAN INTEAMIONAL I7JUN99 Incurs 5-5. Und A Grocaloccor R•mcoalcan &wary hanulon Babe Proctor Sen. lac. 650738.0'701 1.187-51.11Th HBPS\UNITB-AREA\17JUN99 ..7 ' I L • 'AN —21 7 200 0 200 SCALE IN FEET EiEND ± Monitoring Well Locotion • Groundwater Screening Location flRemediation with Zero —Valence Iron and a Carbon Source vegg Zero —Valence Iron and a Carbon Source Pilot —Scale Testing Injection Location — 6 Points on 8 Centers AS SH RADIAN ••••idasia.. TSH MUM FlUre 5-6. UM B Groundwater Rensdiaton Scermno Hamilton Barb6 Prtctor Slag. Inc. m..= 650138.0701 1.I B-S00.1 0 i • D\NIPS\DE-SC CT 23DEC9Y ei W-222/22 200 NW-216/219 0 200 SCALE IN FEET LEGEND .YW-209 Monitoring Well oC0 Groundwater Screening Location �A s�rq ..r .N "... rSn .. s->. iw[cce Don SSecoc. t«mo.s i�occse�„w a„ce. l+ww-5..... mJMO9L. ..... `' aoneaoel I Of -SECT I 0 D.\ HOPS \UNIT A\1SDCC•Q9 j / ND `/ _ ND• / ..- .. C • 'ND • NO I'LANI R frii.iMc; 1-1 303,000-\ MW- 228 173,000-, \ Mw 2 I5-' (,I • Y 1. ND ND 7 *NO MW ND c8 -ND w- 208 NO `G5 20.700 ILj.T.09 M'8-:•19 Mw-21 53-----'/'CI4 ±0.1¢7 J ND 125 200 0 200 SCALE IN FEET LEGEND j Monitoring well Location and Reported Concentration in ug/L (Nov. 1998) • Groundwater Screening Location and Reported Concentration in ug/L (Various Dotes) i— Contour Line Indicates 2L Standard of 200 ug/L AS SHOWN I RANI N161HAllO AL Naar - 1 lsn MIMES •at••. •NA o•uu.a rein a-e aa0ta•0•ot awe 0 5DCC91398 itt •• •- -• -.• .... • °ND 'CV "" 41.1W ND 1 AN I Hi III.INNt; • _ •'• WIN -214 NO - - . tfijl • -. / /4 I ND I a. +LIN 212 140 LON • 21tf t I ") ND *ND I c No to : 4 ND LEGEND 4- Monitoring Well Location and Reported Concentration in ug/L (Nov. 1998) Groundwater Screening Location and Reported Concentration in ug/L (Various Doles) t- Contour Line Indicates 2L Standard of 200 ugil. 11.ree 5-0 200 290 AS sown ' 20C/EC9 *imamate Otebtution nli laDIC964.14i:n leice•Peoctort. IIRACW4ItalAnOtIAL nik ram„. SCALE IN FEET 00130 0•01 0 SOUTHWEST 0 30 25 - 20 - 15 - 10 - 5 - 0- HIPS ‘vSMIIGTDA1CA-DD V 1aO! IMW-217 MW-216 (offset 20' to NW) MW-215 MW-214 (Offset 40' NORTHEAST to SE) D' IMW,2091 (Offset to SE)5 I C-6 I MW-221 -21 1 MW-220 10.0. (Offset 60' to SW) MW-22 MW-227 MW-226 3.0 35.0 11111111 1 I 1 .rr T. 1t11 1I(Lq,1 1 I 1 1 1 aril 75.01 1 ' 26.0 100 n 25.0 0 100 10 HORIZONTAL SCALE 0 10 VERTICAL SCALE (ND) J FGEND 1 I Location Number Ground Surface 3.0 Top of Screen Depth 7.0 Do11om of Screen Depth — Water Level Elevation Contour Line Indicates 2L Standard of 200 ug/L •,960) Reported concentration in ug/L (ND) Nol Detected Higher permeability deposits including Sand, Fine Sand, and Silty Sond Loner permeability deposits including Clayey Sand, Sandy Sill, Silt, and Clay Shell Limestone Deposits ...., nr+. 5-10 n.ltuto A''aNATIONAL Tam-im•• "�oi�,1r-Inc1�heo.ow. 0-0' ■ °='""°° 00120001 J 1 m � 0 NORTHWEST 30 — 25 — 20 — 15 — 10 — 5 — 0 — — 10 — — 20 — — 25 3.0 7.0 LIW-223 LIW-2 2 4.0 (NO) 10.0 31.0 (ND) 34,9, Location Number Ground Surface Elevation Top of Screen Depth Bottom of Screen Depth _IC— Water Level Elevation 10.0 15.0 4941 28.9 ND 32.0 (960) (ND) LEGEND Contour Line Indicates 21 Standard of 200 ug/L Reported concentration M ug/L Not Detected Higher permeability deposits including Sand. Fine Sand. and Silty Sand Lower permeability deposits including Clayey Sand. Sandy Silt. Silt. and Clay • Shell Limestone Deposits (Offset 70' to NE (011set 50' to NE) lAW-219 lAW —218 SOUTHEAST HORIZONTAL SCALE 10 VERTICAL. SCALE . riga 5-11 300( Approx.:me. Distrabsuon iMM eM 1150135 0401 la -a °ND --1/111.4 do' • z I tANI Lit/II 27,000 L, 24.100 • • • 1.4W • '2 Er.•••• 4.3Q ND .11 87 • • jir MW NO 32.1 c.•:" + IflJ vi 1 50 • 11.600 •iL‘ t , tin I 5.17 ma 108 • :1 ND ND 200 0 200 SCALE IN FEET LEGEND f Monitoring Well Location end Reported Concentration in ug/L (Nov. 1998) • Groundwater Screening Locolion and Reported Concentration in ug/L (Various Dates) 4*Th Contour Line Indicoles 2L Standard ol 700 ug/L _J IIIRCZ1:Cc r4a5-s12 AS NC osnas Itrp"Ctk 26frU S MANMESAOALnG Moanr:I74_011110601 1 it _swan D \MBPS . LIN}T A\13DCC999B / / C .ND / NO - .- / ilih _ ND tau t ND • 1.620 . NO ILIA I :<n. 1 •N01 1• ( 1 ... l'ww :in ti. ti ,a . ,.1 ND 2.56 200 :r .1 EGFNQ } 'Monitoring Well Location and Reported Concentration in ug/L (Nov. 1998) Groundwater Screening Location and Reported Concentration in ug/L (Various Dates) r\ Contour Line Indicates 2L Standard of 700 ug/L 0 200 .r •S�Iro�wll� • Y !so[cse�W or.4s�r• 5-.10bAow, 151 %NM ...-dubaou. w una • RADIAN MFAW101W 8'•g •—tr•' t. .. SCALE 1N FEET uim+irainier ...... G501380001 •_po. 1 0 SOUTHWEST 30 — 25 — 20- - 15 — 10 — 5 — 0 — — 10 — —15 — —20 — — 25 — tr, Trna 25.0 35.0 (Offset 20' FEH 414 to NW) (108) (bout so' to SW Offset 40' to SE) MW— 09 (Offset 45 to SE NI 12 Vas 24.1100 ) (.71D) 9,7 !CI0 20.5 (4.620) 25.5 lAW-221 25.0 •340 100 0 ' 100 HORIZONTAL SCALE 10 -1 0 • VERTICAL SCALE NORTHEAST 0' (ND) LEGEND - Location Number 3.0 7.0 Ground Surface Top of Screen Depth Bottom of Screen Depth Water Level Elevation Contour Line Indicates 2L Standard of 700 ug/L (960) Reported concentration in ug/L (ND) Not Detected • Higher permeability deposits including Sand. Fine Sand. and Silty Sand Lower permeability deposits ifICILICIalg Clayey Sand. Sondy Silt. Silt. and Cloy FMShell Limestone Deposits aupwarffERNAnotia AricH Sot_ csesztf.1 war" D:Or Sae AS 2111[Clair Appewriant"rla 50.3-11:adien 450138 0601 0CA-00 0 NORTHWEST E 30 — 25 — 20 — 15 — 10 — -10 — -15 — -20 - -25 — MW-223 MW-222 EMI 4.0 (ND) 10.01- 10.0 15.0 (ND) (Offset 70' to NE) LIW-2 8 MW-227 MW-226 3.0 (24,100T 209 31.0 - 3.0 7.0 (NO) Location Number Ground Surface Elevation lop o1 Screen Depth Bottom of Screen Depth Water Level Elevation 32.0 (960) (ND) isseatp Contour Line indicates 2L Standard of 700 ug/L Reported concentration in ug/L Not Detected • 10.0. (011sel 50' to NE) uW-214 MW-212 3.0 219 MW-218 3.0 100 Higher permeability deposits including Sand, Fine Sand, and Silty Sand Lower permeability deposits including Clayey Sand, Sondy Silt, Silt, and Cloy. Shell Limestone Deposits 20.5 (4,620)O 25.5 (2.56 20.0 ND) 100 SOUTHEAST 0 ioo HORIZONTAL SCALE 10 0 10 VERTICAL SCALE I 1 t7b.� r1 it .5 Isn .RAONN INTERKal10fdAL BVG )e0FC9e nq,u. a ppw+rol. O.aeu-IO N Ceq 1.1-4W,,.Mnm.. I-C actress of mn�fjwne I301I00.U1 f1L9-Lr 0 I eND 0 u a 11 i a i a a 1 a y °ND e 1.. ..-..�i �_. _.. NO ('t ANI F1 ill (IINI 2.700 • 2 ,808'0Y 2 2,0 ND 1.1Y1 ND I .t415I r' I . :,i 1' M'N- 111 / , ND ND I- I @J 1 l:.1 : .' ND C7 °ND M 1 Mv: ND 200 0 200 SCALE IN FEET IF. ND + Monitoring Well Location and Reported Concenlrolion in ug/L (Nov. 1998) • Groundwater Screening Location and Reported Concentration in ug/L (Various Dates) Contour Line Indicoles Estimated Duanlitotion Limit of 5 ug/L I 1 rpm s-u AS SHOWN it xeo[cse y/�pypwv.MY�Y!s �b ,e,.,., e tLl ]NI[C'YI�r�t.tsn e M ail •Fe9u. F[ RiwN11141 tNMMML MWi9L 7� !'.al]00WI guile-;CII0 A r a 0 W n 4 a 2 a / •ND / / .ND ./ NO ND ND • NN -ill I ND 111 •ND 1Y-idJ ND 810 •• Ia ND ND 1 .21 { • t ..1)'(. 4n._. It •' ND •N IIP ND 200 0 SCALE IN FEET 200 Monitoring Well ellLocation and Reported Concentration in ug/L (Nov. 1998) Groundwater Screening Location and Reported Concentration in ug/L (Various Dates) T Trace Concentration r\ Contour Line Indicates Estimated Ouanlitation Limit of 5 ug/L J As TSH IIIRADII • pINQY11I04.4 " g %otcaa -"' rya s-O. aboAson ;WCw• �LSI • Nkra99u •..▪ a..hsry Si. 06MM99 •]91!•0Ea1 e-IU1-O SOUTHWEST D 30 — 25 — 20 — 15 — 10 — 5- 0— —5 — — 10 — — 15 - - 20 — — 25 — uw-217 NW-216 (Offset 6)0' (Offset 20' IYto SYW8 to NW) NW-227 uW-226 FSiti (Offset 40' to SE) JIW-2091 (Oto SE)et 5 I c-e HAY —20{I uW-221 1IW-220 NORTHEAST D' 3.0 25.0 (ND) 75.0 (ND) 21.0- 20.5 (e10) 25.5 (140) 6.4 26.0 1 11 �liri r �1 ill l OIQ 75.0 100 25.0 1 (ND) 0 100 HORIZONTAL SCALE a VERTICAL SCALE LEGEND —1 I Location Number 3.0 I- 7.0 Ground Surface Top of Screen Depth Bottom of Screen Depth Water Level Elevation Contour Line Indicates Estimated Ouantitalion Limit of 5 ug/L Doshed Line Indicates that Plume is 011set from Section Shown 060) Reported concentration in ug/L (ND) Not Detected Higher permeability deposits including Sand. Fine Sond, and Silly Sond Loser permeability deposits including Clayey Sand. Sandy Silt. Sill, and Gay Shell Limestone Deposits AS SNOW 10 Appl..p Ail NOCae9tDOCCN ,.rtl..InichbareMM.. 11-b .-�•eWlq yypl� IQ -OD • a n Y NORTHWEST 30 — 25 20 15 — 10 — 5- - 10 - - 15 — - 20 — - 25 — MW-223 MW-22 0 (NO) 10.0 31.0 - (ND) 2 32 C- 3.0 7.0 Location Number Ground Surface Elevation Top of Screen Depth Bottom of Screen Depth Water Level Elevation (Offset 70' to NE) MW-2 8 MW-227 MW-226 3.0 LEGEND Contour Line Indicotes Estimated Ouantilotion Limit o1 5 ug/L (960) Reported concentration in ug/L (ND) Not Detected Higher permeability deposits including Sond, Fine Sond, and Silty Sand Lower permeability deposits including Clayey Sond. Sandy Sill, Silt, and Cloy Shell Limestone Deposits 1 I J' T I 176 (O11set 50' to NE) �'IF7 3.0 W-219 MW-218 3.0 28.0 - 37.0 (ND) 100 SOUTHEAST • 0 100 HORIZONTAL SCALE 10 0 10 VERTICAL SCALE As 5110wn Tooccsen rqur. 0-19 AP1140 .not. a.aa.uon Ism ]cacao d b t o.i ..L-C .R11WVa INDLRHATICIPML epc OS„, - • -- U013e 0601 12-111 0 co L. ,• NO °NO • ND —11; in e•I 10.000 i) 3.330 ND • NO ND • 1 ND 200 0 LEGEND Monitoring WeH Location ond Reported Concentration in ug/L (Nov. 1998) I I Contour Line Indicates 2L Standard of 70 ug/L 200 SCALE IN FEET Groundwater Screening Locabon ond Reported Concentration in ug/L (Various Doles) T Troce Concentration AS • ERA01,4,11/11EPtallOttAL •s's rilOCC90 %DEC 0814199 -.Didliate""r•Cinathil•A-20 DUnita".5 ill Ufa A Beach Prtclat S.S InA 670601 113117-;15 I 0 50..• • <: ;NO NMBPS UNI T A \ 15D C C98 98 200 200 SCALE IN FEET J FUND it Monitoring Well Location and Repotted Concentration in ug/L (Nov. 1998) . Groundwater Screening Location and Reported Concentration in ug/L (Various Doles) rs• Contour Line Indicates 2L Standard of 70 ug/L AS SHOWN so *WWI NIEMADONAL "pc risac,a M:ps Goa 5-21 state Datnitsals• el lis 36.092gptcpai 01.7.1.273...0alblo1ootbinsma .7.61.1..., LI 450130 0601 I 8-CIS 0 sis• ••••• D,Ml5 W*SMICT SOUTHWEST 0 30 - 25 - 20 - 15 - 10 - 5 - 0 - —10 — IMW-217I uW-216 (Of Ise 20' to NW) (Offset 80' to SW IMW-22 MW-227 MW-226 (offset 40' to SE) JLIW-2091 (Offset 45 I C-8 to SE) IMW-2081 MW-221 Mw-220 NORTHEAST D' 3.0 (NO) 25.0 (ND) 35.0 8.5 IO.OaND 43- 21.0 (3.330) 0 LEGEND 11 Location Number • f7Ti- Ground Surface 3.0 - lop of Screen Depth 6.86) j20.5 (228) 25.5 -16A 47.7 6.4 r io.If I 11 1 .fi4)1111111 75.0r I 26.0 100 25.0 34.0 r 1 (ND) 0 100 110RIZDNTAL SCALE 10 0 VERTICAL SCALE 7.0 Bottom of Screen Depth �— Water Level Elevation ,/Th. Contour Line Indicates 2L Standard of 70 ug/L Dashed Line Indicates that Plume is Offset from Section Shown t9b0) Reported concentration in ug/L ND) Not Detected Higher permeobility deposits including Sand, Fine Sand. and Silty Sand Lover permeability deposits including Clayey Sand. Sandy Silt. Sill. and Cloy Shell Limestone Deposits J10 AS 5 tioim— JIr 2 0fC90 rQs. 0-22 [ . o.mD,w 1. P.un 15n 29X 2-U.w.a.rnur. D OM-D' .WAM 1MWWgN.L eTc aewna, n iithealimas 650rx Dear as-m D NORTHWEST E MIMW-223I W-222 30 — 25 — 20 — 15 — 10 — 5- 0 — -15 -20 25 4.0 10.0 31.0 �QQ (ND) (ND) C- C- 3.0 7.0 - Location Number Ground Surface Elevation Top of Screen Depth Bottom of Screen Depth Water level Elevation. ND r` Contour Line Indicates 2L Standard of 70 ug/L (960) Reported concentration in ug/L (ND) Not Detected (Offset 70' to NE) MW-2 8 MW-227 MW-226 Higher permeability deposits including Sand, Fine Sand, and Silty Sand' Lower permeability deposits including Clayey Sand, Sandy VERTICAL SCALE Silt, Silt, and Clay lAS s .M 30c aa•-n. nvve 5-23 Shell Limestone deposits • C Y �sn iorcc 1.2-u`w°"uws'ws-r 1 �6.b 1-�MO/wlrmNullgHu .eca�,� a egata �. r awlxaol rant' (Offset 50' to NE) MW-219 MW-212 MW-218 3.0 28.0 37.0 (ND) 100 SOUTHEAST E' p 100 • HORIZONTAL SCALE 10 0 10 •ND 1 le ND / / // I �_ . -.__J l_ ..: I`1 AN I Hill IlING 15C:i .600,.•\ MW-i29 96,500 -• • NO • ND 3.85 IAA'- 21 ND r MA ND IA' ' 1' 0.866 200 7 •' ND 0 200 SCALE IN FEET LEGEND } Monitoring Well Location and Reported Concentration in ug/L (Nov. 1998) . Groundwater Screening locolion and Reported Concentration in ug/L (Various Dotes) it". Contour .Line Indicates 2L Standard of 7 ug/L AS 10aECDe vlawrl rya+ a-2* I na*awa uro.Alw- nal 2aptc a •.l-a JJ_ .D.w • WAw °Olairm Damn* Iwaw Sin. Inc MOW* MHRNTIONN.1 BYG *DDNDp 6501300601 IIMu-afLI o / D \HDPS\ UNITA\1DDCC9999 C eND - 1< •/ 4i.ia ." — ND 200 • 0 200 SCALE IN FEET +. Monitoring Welll Location and Reported Concentration in ug/L (Nov. 1998) • Groundwater Screening Locotion and Reported Concentration in ug/L (Various Doles) /\ Contour Line Indicates 2L Standard of 7 ug/L ▪ AS &CNN Isn ieo[cse..... ry.n s-:•. w..�a. truwa yp▪ piLy a i.r-pnbwti. w ar 4ra... ma r �sr. rum esoiaonr I s-rrorl 0 4 SOUTHWEST -D 30 — 25 — 20 — 15 — 10 — 5 0 — —5 — — 10 — — 15 — — 20 — — 25 — W-217 25.0 35.0 (ND) (Offset 80' (Olisel 20' toy to NW) 8.16) 2 0 3.0 20.5 (705) 25.5 1 1 1 I I 1 1 J 1 I,I (offset 40' to SE) 1Mw-2091 (Offset 45 to SE C-8 I 111111 1011111 I I 75.0' ' ' 1 50 .4 8.0 1 0 MW-221 25.0 3f 100 HORIZONTAL SCALE ' 10 0 10 VERTICAL SCALE NORTHEAST D' (ND) LEGFND —1 I Location Number 3.0 7.0 (960) (ND) f1 Ground. Surface Top of Screen Depth Bottom of Screen Depth Water Level Elevation Contour Line Indicates 2L Standard of 7 ug/L" Reported concentration in ug/L Not Detected . Higher permeability deposits including Sond, Fine Sond, and Silty Sond Lower permeaDilAy deposits including Clayey Sand, Sondy S01, Silt, and Clay • Shell Limestone Deposits • r :.eoccad"' o .,„r', e''or.`re.� lln lefl[f1M d 1,1-Orl Chsvit. D-D' RWIMNlINFSMANOIOL ate— -iG Oy6lali0 e]Orb Ot01 Ocr-0a e ) NORTHWEST 30 — 25 — 20 — 15 — 10 — 5 — 0- - 10 — - 15 — -20 — - 25 MW-223 MVO -222 4.0 10.0 1(NO) 31.0 (NO) -5 3.0 7.0 Location Number Ground Surface Elevation Top of Screen Depth Bottom of Screen Depth Water Level Elevation IEGEND Contour Line Indicates 2L Standord of 7 ug/L (960) Reported concentration in ug/L (ND) Not Detected Higher permeability deposits including Sond. Ana Sand. and Silty Sond Lower permeability deposits Silt. Silt and Cloy including Clayey Said, Sandy Shell Lineslone Deposits (Offset 70' to NE) MW-228 1AV-227 LIW-226, (011sel 50' to NE) MW-213 MW-212 MW-219 MW-218 3.0 28.0 37.0- (0.1266) tlb SD? 100 SOUTHEAST 0 100 HORIZONTAL SEALE 10 8 10 M SHOWN VERTICAL SCALE . 'IL roo co ((cc 9a9 a —.4 p 7.1. .. c . .. iiman 0 u J. so. it. i . .0 5- b a i a27 it co r t19.4ADIM7...114finezioNAL. . . Jo awn, mociroorriti.. ism ,,,, 1. 6.501340•01 ax-ot 8 / 0 BPS\UNITA / / - • • ..- • • • . • • • . i•. •ND / 'tin C7 •ND 1. - ND f AN I c2:620 OM [MG MW-22S ND Mei ND . _ . 66.! N;)' irw L7.02 1,1NND .- rf ND • M4 I I Y 4 ND I u 94 4 .2 m4 ' No • NO NO ao o- 200 SCALE IN FEET ULM? Monitoring Well Locationone Reported Concentrobi on n ug/L (Nov. 1998) Groundwater Screening Location and Repotted Concentration 10 ug/L (Various Dotes) , C tour tine Indicates Estulated Contour Limit of 5 ug/ --• IIRADON IIMONATI:o44/ warrassean al non 2 ea Dylet,41.. ....71KC94m:LL 2frrcaikb:"..-2,„ch • enxIo"....:.51.1- m 00.1199 m13110501 au I inu_fica / n 2 a a < •ND / • / 441,5, i ND J.- I'1 ANI I4111I I itl' • NO ND • MA - ND Al* ••21,; I NO •21 inv -11G 4.1119 .1 nv - .11 0.698 • • i oh 200 0 200 SCALE IN FEET LEGEND 4 Monitoring Well Locution and •Reported Concentration in ug/L (Nov. 1998) • Groundwater Screening Locution and Reported Concentration in ug/L (Various Doles) , % Contour Line indicates Estimated Duanlilotion Limit of 5 ug/L AS NRADIANIMIENIMIONAL BPG 200(C9s �••� Nwe +,i1• &NM,lm N b 200(C90-00.. e]WO O0001 I 0-120CA I 0 SOUTHWEST D MW-217 MW-216 30 — 25 — 20 — 15 — 10 — 5 — 25.0 0 — (ND) —10 — — 15 — — 20 - - 25 — qY a 35.0 (Offset 60' (Offset 20' to S to NW) i11W-215I NW-214 21.0 3.0 P4 (Offset 40' to SE) JMW-209( (Offset 4 I C-B to SE) how —20? 0 100 HORIZONTAL SCALE • 10 is VERTICAL SCALE 'NORTHEAST MW-221 MW-220 25.0 tiaff• (ND) LEGEND 1 I Location Number Ground Surface 3.0 Top of Screen Depth 7!0 Bottom o1 Screen Depth Z Water Level Elevation �� Contour Line Indicates Estimated Ouantitotion Limit of 5 ug/L (960) Reported concentration in ug/L (ND) Not 'Detected Higher permeability deposits including Sand, Fina Sand, and Silly Sand Lover permeability deposits including Clayey Sand, Sandy Silt, Silt, and Clay 1 Shell Limestone Deposits *5 snoex sass icrccse — rw+• 0-]0 r��..r•. 15n zioccO tl 1.2-aitHcreMNw,. Dietr"tD-D' . epa erns esorseaal Inca 0 L G a -20 — -25 — 3.0 7.0 (ND) (ND) Location Number Ground Surface Devotion Top of Screen Depth Bottom of Screen Depth Water Level Elevation 10.0 15.0 (960) (ND) Contour Line Indicates Estimated Ouantitotion Limit of 5 ug/L Reported concentration in ug/L Not Detected Higher permeability deposits including Sand, Fine Sand, and Silly Sand Lower permeability deposits including Clayey Sand, Sandy Silt, Set. and Cloy Shell Limestone Deposits (ousel 50' to NE (0.698) UW-219 NW-218 37.0 (0.966) (ND) 100 SOUTHEAST E' 0 100 HORIZONTAL SCALE l0 0 10 VERTICAL SCALE IOpecpf`— rqu. 5-31 1 (i1 1 eA,.,.. "Ashyore l.x-ornwe . [-r Sbp .b T I 'a°"""'r�� y"'"'"° 450130 We npM'Q 0 Jet $pr,..nol. Ontriberbon .-i L - AS Sax 1 j / trl \ •ND i / -2/ {♦ it.IW - 221 ' NO G3 'ND PLAN I BUILDING 273- MW-228 314 -\ i Id' _.0 17' ND -- i MW-230 =t .2 j MW-217 ND C14 •_19 Si_31 i kW }�L 7<,. NIW- 315 ND 200 200 SCALE IN FEET JFCFNQ + Monitoring Well Location and Reported Concentration in ug/L (Nov. 1998) • Groundwater Screening Location and Reported Concentration in ug/L (Various Dates) /\ Contour Line Indicates Estimated QuantitoUon Limit of 5 ug/L AS SHOWN IIIRADMLSIN1FwWgIWL aniNfir at 191 lR reoccsa 1VrR1` rya sw oube+lm {vl• nods Sr.K 16e13110001 iIM4'K I a A L a n a z z i a n z ( L / " eND ,7 GS ND ND 5e ND PLANE BUILDING 'ND 1.tie MW- let I N MW-212 +ND CD e NMDIW- 209 T1.69 5.7 it) ND +Mw .!I2 4.48 ,r MW NSW 218 No lw CIi +ND 200 200 SCALE IN FEET } Monitoring Well Location and Reported Concentration in ug/L (Nov. 1996) Groundwater Screening Location and Reported Concentration in ug/L (Various Dates) r\ Contour Line Indicates Estimated Duanlitalion Limit of 5 ug/L AS �s ,4 :ei xerccsa ilea saW., ,,, Mt 10�COq J Or�W b ai s 1R110W1RRFJals110NM �.eS Lve•wo Ma MI k iliMilallailililer... innnwrw1 �a aw,xoso, I n-SC 1 o ATTACHMENT 0 JUL 15 1999 08:33 FR 01`M TOi 94611415 P.11/12 Peerless Metal Powders & Abrasives 124 South Military Dcfmit. Michigan 48209 313-841-5400 MATERIAL SAFETY DATA SHEET SECTION I IDENTIFICATION Product Name ; j :AST IRON ACMREGATE Common Name CAS No : 65997-191 Chemical Family' Metals Formula : NLA Date : hum 13,1998 SECTION II -INGREDIENTS AND RECOMMENDED OCCUPATIONAL EXPOSURE LIMITS Material CAS No. Weight % ACGIH TLV Mg/cu m Iron Carbon Manganese Silicon Chromium 1309-37-1 7440-44-0 13094114 7440-21-3 7440-47-3 90+ 1.50 - 3.50 0.60 2.00 0,20 5 3.5 10 5 0.5 c means ceiling limit. 'These arc limits which shall be exceeded. SECTION III PHYSICAL DATA Melting Point Specific Density Appearance and Odor base metal - 2750 degrees F 6.7 gm / cc grey particles - no odor HSECTIONIV FIRE AND EXPLOSION-HAZARD-DA-TA Airborne finely dispersed dust will ignite. -. Extinguishing Media Dry chemical, dry sand, graphite to smother fire Special Fue Fighting Procedures : Use water only in mist / fog Dry application to avoid spreading powder or accumulated dust. Use self-contained breathing apparatus and protective clothing. SECTION V REACTIVITY DATA Stable under normal conditions of storage and transport. Will react with strong oxidizers. SECTION VI HEALTH HAZARD DATA No potential health hazards other than those listed are known Major Exposure Hazard X Inhalation Skin Contact X Eye Contact Indigestion Effects of Overexposure Inhalation - bronchitis, sidemsis Eye Contact - mechanical irritation Emergency and First Aid Procedures _ inhalation - remove to fresh air Eye Contact - irrigate eyes to remove dust particles JUL 15 1999 08:33 FR 01 TO( ,94611415 P.12/12 SECTION VIL SPILL OR LEAK PROCEDURES avoid generation of airborne dust during clean-up process Dispose of in accordance with local, state and federal' regulations • SECTION VM SPECIAL PROTECTION INFORMATION As needed, use approved dust respirator and eye protection ( OSHA 29 CFR t910.94). Do not use contact lenses. Veatiladon recommended. 1/4 SECTION IX SPECIAL PRECAUTIONS Keep in closed containers. Do not store near strong oxidizers. Use good housekeeping procedures to avoid creating dust. The information contained herein bas been compiled from sources considered reliable and accurate to the best of our lmowledge. and belle$ but is not guaranteed to be so. It relates only to the product listed and does not relate to use of the product in combination with any other material or materials or in a particular processes. Since the use of the MSDS information, the conditions of use of ow product and the environment in which that product is placed are not within the control of Peerless Metal , Powders & Abrasive, it is the users obligation and duty to determine the conditions of safe use of the products used as well as the manner in which these products may be affected by the environment in which they may be used. We urge you to review each MSDS to ensure that year uses of the product take into account the current information available on its potential hazards. It is your responsibility to convey this information to your employees, customers or anyone who may be exposed to this product Please check your files and discard any previous versions as may be applicable. If you have any questions or require additional copies. pleasccontact our Sales Department. , • ' 1 1 : Vapor Pressure: Solid, n/a Vapor Density: Solid. Na -4 Evaporation RateSolic1,-n/a Solubility In Water: Complete Appearance and Odor: Creamy white povaller withbean-like odor Specific Gravity: Density -40 to 45 lidcf Melting Point Deo3rnposes • " G150 MATERIAL SAFEIY DATA.HE " • . . bane-al:Y.: • ••• • • MANUFACTURER'S NAME: • RANTEC CORPORATION , PO SOX 729 • • RANCHESTER, VYY 82139 • • • EMERGENCY PHONE: 1-307-655-956.5 Product name: Rantec G150 Blopolymei Chemical name: Guar gum, Galadomannan Chemical family: Carbohydrate/Polysaccharide • Formula: Approximately (C61-1,00)n DOT hazard class: None DOT proper shipping nante: Naitaeourated ••••••;;; .t* •••-) • DA1EPREPARED:13 Derieihber;19,97:•i• .• • • PREPARED By: • • • Lloyd Marsden, Plant Managei:le44.4r:.: • • . r•-sc.CfaT4.,, .• • •• ...•••••••:;e1.4•:••• ••• • .• • • • •••1,14.•icit. • .. • SECTION Hazardous Ingredients Rantec G150 Blopotymer contains no hazardous ingredients. SECTION III - PnySICal Data Boiling Point: Solid, n/a Flash Point Flammable or Explosion Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: N/A UEL Not Determined LEL Approx. 0.04 oz/ci. Similar to Flour and grain Dusts. CO2, dry chemical, foam, water fog. Wearself-contained breathing apparatus to avoid smoke. Powder has the potential to form explosive mixture with air. Avoid creating dust. Keep away from heat, open flame and sparks. Use spark -proof motors, ventilate to control dust and use other preventive measures as with all dusty materials. Powder becomes very slippery when wet. Application of waterto material may produce slipping hazards. JUL 15 1999 013: 31 FR 01E'^,c_ . . . e,77'PAM 11% oc, ' TO 714611415 1: ?;;;•sr t. •ov • :• y : : • SECTION'rgiiiiviti Data; " : • ••;1:•:•• ; s ••• • :, Stability' • • s : •:•:•', • • i• •ThSlable:(2.44::.)ici;',-Ait.•. Conditions to Avoid: rs. :•••- 1.• Ignition sourest, air suspended diretvraier contacC P.08/12 Incompatibi lity: Hazardous Oitcompositieri Products: • Hazardous Polynierization: SEC-tic/00710th rate@ Petit OSHA Pemdssible Exposure tlmth ACGIH Signs and Symptoms of Overexpestae: Medical Conditions Generally Aggravated by Exposure: Caminogenicity: Primary Route(s) of Exposure_ and Emergency/first Aid Procedures: ..:• • ' None'j..s • 7::::'1:;;;;;)••• ; ••••• " : ;•:••• •L WO reit•••• • • "i • . .• :*.•• • ..• •; ; • .• • 41.14:1(041 • NoneostaUished . • Acute: None established airenia None established • ' • • None established. However, like any drat. G150 may produce respiratory irritation andlor allergic - • • Not established as a dirdnogert' . . Eyes: May be irritating. 'RemoveeXcesi material from • ." • • . around eyes: Irrigate eyes with water. Consult physiciatt if irritation persists, Inhalation: May produce respiratory irrit- • atIon and/or allergic response in some individuals. Move to fresh at Gonad physlSn if irritation or allergic reaction. occurs. Skin: May causedrynes$. Wash skin with soap and water. Use a suitable skin lotion. . • • f!N:Cli.:FAVil • 4 CJ:.' Yir SECTION VII - Special Precatitionsand Spill Prcicedurei Handling and Storage: Store in a dry, cool place G150 is stable in the dry form. Parted iron moisture, excessive heat and damage by rodents. Keep containers dosed to avoid moisture pickup. Propedy cover Material Spills: WasteDisposal: and retest after maendedstorage to assure -quality -retort° use. Please note.that 0150 becomes very slippery whenwet Sweep up dry and Containerize. Rouse W suitable or dispose. Mop area with hot water to remove final traces. Test area and repeat if necessary. G150 is not hazardous waste. Dispose in an approved landfill in accordance with local regulations. Do not dump downtewers or drains as this may cause blockage. SECTION:VII- Special Firoteotittiti Ilifortnationfor Respiratory Protection: ProvIdelnaviduals with approved dust masks or respirators that are _,. capable of removing aerosol dust Ventilation: Provide du St control measures to remove or recover airborne dust • Use spark -proof equipment Protective Gloves: Rubber, plastic, leather. .. Eye Protection: Safety glasses. Notice.••';' -:•••••••••;:. • • : :N;;;•::.Inforrnehon contained in this literature. is given in.good faithiand ••"-• • •••••••V' Vairrahk.exprester. Implied;rernadercontadmanufacthrerllstedr : for more information. P.09/12 PRODUCT NASIVMEt.L CHEMICAL NAME: Proprietary '.:.; '`° . ;; CHEMICAL FAMILY: Propylene Glycol Solution%Enzyme.Protein FORMULA: Proprietary: ::; .;•::;:,.04.,t .• DOT HAZARD CLASS: None ' DOT PROPER SHIPPING NAME; Non -Regulated SECTION 1 MANUFACTURER'S NAME:. RANTEC CORPORATION PO BOX 729 RANCHESTER, WY 82839 EMERGENCY PHONE: 1-307-055-9585 SECTION I1 Hazardous Ingredients, Information LEB contains no hazardous ingredients. DATE PREPARED: 28 May 1993 PREPARED BY:. Lloyd Marsden, Plant Manager SECTION I11 Physical Characteristics BOILING POINT: 220° F ' SPECIFIC GRAVITY:(H30-11:1.02 VAPOR PRESSURE: Unknown VAPOR DENSITY: Unknown EVAPORATION RATE: Unknown MELTING POINT: Less than 32° F SOLUBILITY IN WATER: Complete. APPEARANCE AND ODOR: Dark brown liquid with glircol and fermentation odor. SECTION IV Fire and Explosion Hazard Data Non -Flammable SECTION V Reactivity. Data STABILITY: Stable CONDITIONS TO AVOID: High temperatures INCOMPATIBILITY: Strong adds, bases, oxidaing agents. HAZARDOUS DECOMPOSITON PRODUCTS: None HAZARDOUS POLYMERIZATION: Will Not Occur, JUL 15 1999 08:32 FR 01'' TOrm',94611415 P.10/12 w amtreepntinwe ••Yi+!Jwi:'ay.4ANA'4-4�a.a,(•.�y�.'..y !voks • 1/,.1f •• .. :. �i+�i•1�nS '�:.i • .. ..:i;i.•j•,•� ':. SECTIOIH`1/jti 1:"Hea•yth'h zaTdrData '''. `..•. ROUTES OF ENTRY: $kin; ingestion • }.:. • '.. : j�.i.:*d 4. %'4: .Ta 'btu ,•::�'=5�':.-,t�.•' ::'•'% :'L•' '•'�'.�'•� ��L�+'I'l: `G �: '::HEEyes May cabs !.. : ;.;._; •' , :>: indlyidual sensitivity./ Remove.' material: eves' . .2A3fil Eyes upon �rect�goatabt • depedirig.on.. .. r :•,.... . '•May cause eye.. • �.:::�-;;,....'::;..;. y flushing fresh water. Cc if irritation "'i:: Consult physician t7etsists::;' .' ; S b flush .with •�i:._,,:a;.. 2. `Skm•' Essentially: en -toxic: May produce a • n .• 'drying effect; • � '_ , repeated .can cause irritati:'on on;pralonged•. or' • exposure:.Waeh skin with; soap and water:. Use a sortable skin khtion. 3. Ingestion: Ingestion of this material may produce toxic effects. If ingested, consult a physician. CHRONIC OVEREXPOSURE: None known to occur..,, Individuals with a history of respiratory allergic responses may have respiratory conditions such as asthma intensified by exposure to dust from this product if allowed to dry. _ • . . CARCINOGENICITY: None of the ingredients are known to be carcinogenic.. • • • SECTION VII Precautions for Safe Handling. And lase• STEPS TO BE TAKEN IN CASE OF SPILL: Stop flow of material, surround spill to prevent spread. Do not allow material to dry on floor or other surfaces as dust may be irritating. SPILL HANDLING: Use pumps and containers as necessary to recover material. Salvage uncontaminated material, flush balance to drain. Completely flush spill area to avoid drying and dustiness. SECTION VIII Control Measures RESPIRATORY PROTECTION: Not required. VENTILATION: N/A. PROTECTIVE GLOVES: Rubber, plastic, leather. EYE PROTECTION: Safety glasses. WORK/HYGIENICPRACTICES: Avoid contact and central spills. Remove material that may come in personal contact. Keep work area clear of spilled material and avoid contact. Personnel should be tested for protein enzyme sensitivity prior to work assignment in handling material. JUL 15 1999 09 : 45 FR I,-•, T1' •-1194611415 P.02/06 MATERIAL SAFETY DATA SHEET Last Revised: January 27, 1998 Supplier: Section 1 - Material Identification Applied Power Concepts, Inc. 1738 N. Neville Street Orange, CA 92865 ' Telephone: (714) 282-6140 Facsimile: (714) 282-6139 Chemical Name: Propanoic acid, 2-[242-(2-hydroxy-l-oxopropoxy)-1-oxopropoxy] -1-oxopropoxy]-1,2,3-propanetriyl ester Chemical Family: Organic Chemical Trade Name: Glycerol tripolylactate Section 2-.=-Harardous Ingredients CAS #: 201167-72-8 One should anticipate the potential for eye irritation and skin irritation with large scale exposure or in sensitive individuals. ***************************************************************** Section 3 - Physical Data Melting Point: . NA Boiling Point: ND Flash Point: ND Density: 1.347 Solubility: Acetone and DMSO Appearance: Pale white liquid Odor: Not detectable Vapor Pressure: None MSDSGLYCEROL TRIPOLYLACTATE.DOC JUL 15 1999 09:46 FR 1M T -'494611415 P.03/06 Section 4 - Fire and Explosion Hazard Data Extinguishing Media: Carbon Dioxide, Dry Chemical Powder or Appropriate Foam. Water may be used to keep exposed containers cool. For large quantities involved in a fire, one should wear full protective clothing and a NIOSH approved self contained breathing apparatus with full face piece operated in the pressure demand or positive pressure mode as for a situation where lack of oxygen and excess heat are present. Section 5 - Toxicological Information ***************************************************************** Acute Effects: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. To the best of our knowledge. the chemical. physical. and toxicological properties of the glycerol tripolylactate have not been investigated. Listed below are the toxicological information for glycerol and lactic acid. RTECS#: MA8050000 Glycerol Irritation data SKN-RBT-500 MG/24H MLD EYE-RBT 126 MG MLD EYE-RBT 500 MG/24H MLD Toxicity data: ORL-MUS LD50:4090 MG/KG SCU-RBT LD50:100 MG/KG ORL-RAT LD50:12600 MG/KG IHL-RAT LC50: >570 MG/M3/1H IPR-RAT LD50: 4420 MG/KG IVN-RAT LD50:5566 MG/KG IPR-MUS LD50: 8700 MG/KG SCU-MUS LD50:91 MG/1CG IVN-MUS LD50: 4250 MG/KG ORL-RBT LD50: 27 GM/KG SKN-RBT LD50:> 10GM/KG IVN-RBT LD50: 53 GM/KG ORL-GPG LD50: 7750 MG/KG 85JCAE-7207,1-986 BIOFX* 9-4/1970 85JCAE-,207.1986 FRZKAP (6),56,1977 NIIRDN 6,215,1982 FEPRA7 4,142,1945 BIOFX* 9-4/1970 RCOCBB 56,125,1987 ARZNAD 26,1581,1976 ARZNAD 26,1579,1978 NIIRDN 6,215,1982 JAPMAB 39,583,1950 DMDJAP 31,276.1959 BIOFX* 9-4/1970 NIIRDN 6,215,1982 JIHTAB 23,259,1941 Target Organ data: Behavioral (headache), gastrointestinal (nausea or vomiting), Paternal effects (spermatogenesis, testes, epididynils, sperm duct), effects of fertility (male fertility index, post - implantation mortality). MSDSGLYCEROLTRIPOLYLACTATE.DOC 2 JUL 15 1999 09:46 FR (' TV '194611415 F.04/06 • RTECS#: OD2800000 Lactic acid Irritation data: SKN-RBT 5MG24H SEV 85JCAE -,656,86 EYE-RBT 750 UG SEV AJOPAA 29,1363,46 Toxicity data: ORL-RAT LDS0:3543 MG/KG FMCHA2-,C252,9 1 SKN-RBT LD50:>2 GM/KG FMCHA2-,C252,91 ORL-MUS LD50: 4875 MO/KG FAONAU 40,144,67 ORL-GPG LD50: 1810 MG/KG, JIHTAB 23,259,41 ORL-QAL LD50: >2250 MG/KG FMCHA2-,C252,91 Only selected registry of toxic effects of chemical substances (RTECS) data is presented here. See actual entry in RTECS for complete information on lactic acid and glycerol. Section 6 - Health Hazard Data Handling: Avoid continued contact with skin. Avoid contact with eyes. In any-case-of-any-exposure-which-elicits-a-response,ra-physician-should-be-consulted immediately. First Aid Procedures: Inhalation: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen. Call a physician. Ingestion: No effects expected. Do not give•anything to an unconscious person. Call a physician immediately. Skin Contact: Flush with plenty of water. Contaminated clothing may be washed or dry cleaned normally. Eye contact: Wash eyes with plenty of water for at least 15 minutes lifting both upper and lower lids. ,Call a physician. MSDSGLYCEROL TRIPOLYLACTATE.DOC 3 JUL 15 1999 09:46 FR T^ a1194611415 P.05/06 Section 7 - Reactivity Data Conditions to Avoid: -Strong oxidizing agents, bases and acids Hazardous Polymerization: None known Further Information: Hydrolyses in water to form Lactic Acid and Glycerol. ******s4***is*********i*********ittis**#sus********************** Section 8 - Spill, Leak or Accident Procedures ***************************************************************** After Spillage or Leakage: Neutralization is not required. This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Disposal: Laws and regulations for disposal vary widely by locality. Observe all applicable regulations and laws. This material, may be disposed of in solid waste. Material is readily degradable and hydrolyses in several hours. No requirement for a reportable quantity (CERCLA) of a spill is known. ***************************************************************** Section 9 - Special Protection or Handling Should be stored in plastic lined steel, plastic, glass, aluminum, stainless steel, or reinforced fiberglass containers. Protective Gloves: Vinyl or Rubber Eyes: Splash Goggles or Full Face Shield Area should have approved means of washing eyes. - Ventilation: General exhaust. Storage: Store in cool, dry, ventilated area. Protect from imcompatible materials. ***************************************sass*ss***s*************** Section 10 - Other Information This material will degrade in the environment by hydrolysis to lactic acid and glycerol. Materials containing reactive chemicals should be used only by personnel with appropriate chemical training. The information contained in this document is the best available to the supplier as of the time of' MSDSGLYCEROL TRIPOLYLACTATE.DOC 4 JUL 15 1999 09:46 FR Q:' 1 TG H194611415 . P.06,06 writing. Some possible hazards have been determined by analogy to similar classes of material. No separate tests have been performed on the toxicity of this material. The items in this document are subject to change and clarification as more information becomes available. MSDSGLYCEROL TRIPOLYLACTATE.DOC 5