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HomeMy WebLinkAboutWI0700012_Report_19900802Design Report Remedial Action System Tank Farm Area Texasgulf Phosphate Operations Aurora, North Carolina Nair MI Ardaman & Associates, Inc. OFFICES Orlando, 8008 S. Orange Avenue, Orlando, Florida 32859-3003, Phone (407) 855-3860 Bartow, 1987 S. Holland Parkway, Bartow, Florida 33830, Phone (813) 533-0858 Bradenton, 209 A 6th Avenue East, Bradenton, Florida 33508, Phone (813) 748-3971 Cocoa, 1300 N. Cocoa Blvd., Cocoa, Florida 32924, Phone (407) 632-2503 Fort Myers, 2508 Rockfill Road, Fort Myers, Florida 33916, Phone (813) 337-1288 Miami, 2608 W. 84th Street, Hialeah, Florida 33016, Phone (305) 825-2683 Port St. Lucie, 1017 S.E. Holbrook Ct., Port St. Lucie, Florida 34985, Phone (407) 337-1200 Sarasota, 2500 Bee Ridge Road, Sarasota, Florida 34277, Phone (813) 922-3526 Tallahassee, 3175 West Tharpe Street, Tallahassee, Florida 32303, Phone (904) 576-6131 Tampa, 105 N. Faulkenburg Road, Suite D, Brandon, Florida 34299-1506, Phone (813) 654-2336 West Palm Beach, 2511 Westgate Avenue, Suite 10, West Palm Beach, Florida 33409, Phone (407) 687-8200 MEMBERS: American Concrete Institute American Society for Testing and Materials American Consulting Engineers Council Association of Soil and Foundation Engineers Florida Institute of Consulting Engineers American Council of Independent Laboratories ® ? Ardaman & Associates, Inc. MAI Consultants in Soils, Hydrogeology, Foundations and Materials Testing Texasgulf Inc. Post Office Box 48 Aurora, North Carolina 27806 Attention: Mr. William A. Schimming, Manager Environmental Affairs July 31, 1990 File Number 88-089 Subject: Design Report, Remedial Action System, Tank Farm Area, Texasgulf Phosphate Operations, Aurora, North Carolina Gentlemen: As requested, we have completed the final design of the tank farm remedial action system. This design implements the remedial action plan conceptually approved by the North Carolina Division of Environmental Management on March 19, 1990. This document presents: (i) an overview of the reported leak incidents at the tank farm and the remedial activities to date; (ii) the results of the field exploration and laboratory testing program conducted in support of the remedial design; (iii) a review of the quarterly water quality data obtained from the tank farm monitor wells through April 1990; (iv) a detailed discussion of the design and expected performance of the remedial action system; and (v) recommended technical specifications for installation of a soil- bentonite cut-off wall and withdrawal/injection well system. If you have any questions or require additional information, please contact us. Very truly yours, ARDAMAN & ASSOCIATES, INC. Senior Project Engineer hn E. Garlanger, Ph.D., P.E. 'rincipal North Carolina Registration No. 9046 TSI:ed Encls. 4-88089.TEX 8008 S. Orange Avenue. P O. Box 593003. Orlando. Florida 32859-3003 (407) 855-3860 FAX (407) 859-8121 Offices in Avon Park. Bartow, Bradenton, Cocoa, Fort Myers, Miami. Orlando, Port Charlotte. Pod St Lucie, Sarasota. Tallahassee, Tampa W Pain; Bea:' TABLE OF CONTENTS Section Title Page 1 PROJECT BACKGROUND 1-1 2 HYDROGEOLOGIC SETTING IN TANK FARM AREA 2-1 2.1 Previous Field Exploration Programs 2-1 2.2 Additional Field Exploration Program 2-1 2.2.1 Standard Penetration Test Borings 2-2 2.2.2 Undisturbed Shelby Tube Sampling 2-3 2.3 Generalized Subsurface Stratigraphy 2-3 2.3.1 Yorktown Formation 2-4 2.3.2 Croatan Formation 2-4 2.3.3 Undifferentiated Surficial Deposits 2-4 2.3.3.1 Lower Confining Unit 2-5 2.3.3.2 Confined Sand Layer 2-5 2.3.3.3 Upper Confining Unit 2-6 2.3.3.4 Surficial Soils 2-6 2.4 Groundwater Levels and Flow Directions 2-6 2.5 Pumping Tests and Evaluation of In Situ Aquifer Properties 2-7 2.5.1 Croatan Formation Pumping Tests 2-8 2.5.1.1 North Pumping Test 2-8 2.5.1.2 South Pumping Test 2-9 2.5.2 Confined Sand Layer Pumping Test 2-11 2.6 Water Quality in Tank Farm Monitor Wells 2-12 2.6.1 Groundwater Quality in Undifferentiated Surficial Deposits 2-12 2.6.1.1 Surficial Sand Layer 2-12 2.6.1.2 Confined Sand Layer 2-13 2.6.2 Groundwater Quality in Croatan Formation 2-14 2.6.3 Castle Hayne Aquifer Groundwater Quality 2-14 3 ENGINEERING PROPERTIES OF IN SITU SOILS AND 3-1 SOIL-BENTONITE BACKFILL MIXES 3.1 Engineering Properties of Undifferentiated Surficial Deposits 3-1 3.1.1 Lower Confining Unit 3-1 3.1.1.1 Classification and Index Properties 3-1 3.1.1.2 Coefficient of Permeability 3-1 TABLE OF CONTENTS (continued) Section Title Page 3 ENGINEERING PROPERTIES OF IN SITU SOILS AND 3-1 SOIL-BENTONITE BACKFILL MIXES (continued) 3.1.1.3 Consolidation Characteristics 3.1.1.4 Undrained Shear Strength 3.1.2 Confined Sand Layer 3.1.3 Upper Confining Unit 3.1.3.1 Consolidation Characteristics 3.1.3.2 Undrained Shear Strength 3.1.4 Surficial Soils 3.2 Engineering Properties of Croatan Formation 3.3 Soil-Bentonite Backfill Mixes 3-2 3-2 3-2 3-2 3-2 3-3 3-3 3-3 3-3 3.3.1 Soil Backfill Characteristics 3-3 3.3.2 Characteristics of Bentonite Product 3-4 3.3.3 Coefficient of Permeability of Soil-Bentonite Backfill Mixes 3-5 4 DESIGN CONSIDERATIONS FOR REMEDIAL ACTION SYSTEM 4-1 4.1 Elements of Remedial Action System 4-1 4.2 Installation of New Containment Facilities 4-1 4.3 Installation of Cut -Off Wall 4-2 4.4 Installation of Confined Sand Layer Withdrawal Well System 4-3 4.4.1 Design Features of Withdrawal Well System 4-3 4.4.2 Modeling of Performance of Withdrawal Well System 4-3 4.5 Installation of Croatan Formation Injection/Withdrawal Well System 4-4 4.5.1 Design Features of Injection Well System 4-4 4.5.2 Design Features of Withdrawal Well System 4-4 4.5.3 Modeling of Performance of Injection/Withdrawal Well 4-4 Systems 4.6 Surface Settlements Induced from Groundwater Withdrawals 4.7 Performance Monitoring of Remedial Action System 4-5 4-6 4.7.1 Water Volumes 4-6 4.7.2 Water Quality Monitoring 4-6 4.7.3 Water Level Monitoring 4-6 TABLE OF CONTENTS (continued) Section Title Page 5 GENERAL CUT-OFF WALL AND WITHDRAWAL/INJECTION 5-1 WELL TECHNICAL SPECIFICATIONS 5.1 Intent 5-1 5.2 List of Drawings 5-1 5.3 Contractor's Understanding 5-2 5.4 Work by Contractor 5-2 5.4.1 Layout of Work 5.4.2 Soil-Bentonite Cut -Off Wall 5-2 5-2 5.4.2.1 Cut -Off Wall Geometric Requirements 5-2 5.4.2.2 Depth of Cut -Off Wall 5-2 5.4.2.3 Cut -Off Wall Materials 5-3 5.4.2.4 Disposal of Unsuitable Soils Excavated from 5-4 Slurry Trench 5.4.2.5 Excavation of Slurry Trench 5-4 5.4.2.6 Soil-Bentonite Backfill Mixture Placement 5-5 5.4.2.7 Containment of Bentonite Slurry 5-5 5.4.2.8 Daily and Final Clean -Up 5-5 5.4.2.9 Temporary Relocation of Existing Facilities 5-5 and Work Around Existing Facilities 5.4.3 Withdrawal and Injection Wells 5-6 5.4.3.1 Well Drilling Procedures 5-6 5.4.3.2 Well Casings 5-6 5.4.3.3 Well Screens and Centralizers 5-6 5.4.3.4 Silica Gravel Filter 5-6 5.4.3.5 Bentonite Seal and Grout 5-6 5.4.3.6 Injection Well Clean -Outs and Riser Pipes 5-7 5.4.3.7 Withdrawal Well Discharge Pipes, Air Line 5-7 Conduits and Injection Well Header Pipe 5.4.3.8 Withdrawal Well Service Box 5-7 5.4.3.9 Pumps, Pulse Senders and Associated Fittings 5-7 5.4.3.10 Air Compressor, Coalescing Filter, Air Dryer 5-7 and Associated Controls 5.4.3.11 Injection Well Water Level Control Tank 5-8 5.4.3.12 Control Building 5-8 5.4.4 Earthwork 5-8 5.4.4.1 Trench Excavation and Pipe Bedding 5-8 5.4.4.2 Allowable Pipe Trench Backfill Materials 5-8 5.4.4.3 Backfill Above Cut -Off Wall and Around Pipe 5-9 Crossings 5.4.5 Replacement of Asphalt Pavement 5-9 TABLE OF CONTENTS (continued) Section Title Page 5 GENERAL CUT-OFF WALL AND WITHDRAWAL/INJECTION 5-1 WELL TECHNICAL SPECIFICATIONS (continued) 5.5 General Provisions 5-9 5.5.1 General 5-9 5.5.2 Drawings and Specifications 5-9 5.5.3 Right to Change Location and Drawings 5-9 5.5.4 As -Built Drawings 5-9 5.5.5 Safety Regulations 5-10 5.5.6 Environmental Compliance 5-10 5.5.7 Protection of Existing Facilities 5-10 5.6 Engineering Data 5.7 Quality Control Testing and Inspection 5-10 5-11 5.7.1 Cut -Off Wall 5-11 5.7.2 Earthwork 5-12 5.7.3 Injection/Withdrawal Well System Installation 5-13 5.8 Construction Schedule 5-13 5.9 Method of Measurement and Payment 5-13 5.10 Final Inspection, Testing, and Acceptance 5-13 5.11 Supplemental General Conditions 5-13 Appendix A Soil Boring Logs B Test Well Construction Records Attachment I Drawings Table Title 2-1 2-2 2-3 2-4 2-5 2-6 2-7 2-8 2-9 2-10 Groundwater Groundwater Groundwater Groundwater Groundwater Groundwater Groundwater Groundwater Groundwater Groundwater LIST OF TABLES Quality in Tank Farm Area at Monitor Well MWTF-1A Quality in Tank Farm Area at Monitor Well MWTF-1B Quality in Tank Farm Area at Monitor Well MWTF-1C Quality in Tank Farm Area at Monitor Well MWTF-2A Quality in Tank Farm Area at Monitor Well MWTF-2B Quality in Tank Farm Area at Monitor Well MWTF-2C Quality in Tank Farm Area at Monitor Well MWTF-3A Quality in Tank Farm Area at Monitor Well MWTF-3B Quality in Tank Farm Area at Monitor Well MWTF-3C Quality in Castle Hayne Aquifer at Utility Well FERT-1 3-1 Index Properties of Lower Confining Unit 3-2 Permeability Test Results on Lower Confining Unit 3-3 Permeability Test Results on Soil-Bentonite Backfill Mixes LIST OF FIGURES Figure Title 1-1 Locations of Tank Farm Leak Incidents 2-1 Tank Farm Soil Boring, Monitor Well, and Test Well Location Plan 2-2 Generalized Stratigraphic Cross Sections 2-3 Isopach Map of Croatan Formation 2-4 Isopach Map of Confined Sand Layer 2-5 Aquifer Water Levels Vs. Time 2-6 Aquifer Water Levels Vs. Depth 2-7 Layout of Croatan Formation Pumping Tests 2-8 Drawdown Vs. Time at Test Well CPW for Pumping Rate of 2 Gal/Min 2-9 Drawdown Vs. Time at Observation Wells COW and MWTF-1C for Pumping Rate of 2 Gal/Min at Test Well CPW 2-10 Drawdown Vs. Log Time at Observation Wells COW and MWTF-3C for Pumping Rate of 2 Gal/Min at Test Well CPW 2-11 Drawdown Vs. Time at Test Well MWTF-1D and Observation Well MWTF-1C for Pumping Rate of 3.4 Gal/Min 2-12 Drawdown Vs. Log Time for Observation Well MWTF-1C for Pumping Rate of 3.4 Gal/Min at Test Well MWTF-1D 2-13 Layout of Confined Sand Layer Pumping Test 2-14 Drawdown Vs. Time at Test Well SPW and Observation Wells SPW and MWTF-3B for Pumping Rate of 4.3 Gal/Min 3-1 Particle Size Distribution of Lower Confining Unit Along Cut -Off Wall Alignment 3-2 Atterberg Limits of Lower Confining Unit Along Cut -Off Wall Alignment 3-3 Consolidation Test Results for Clayey Fine Sand with Shell Fragments from Lower Confining Unit 3-4 Consolidation Test Results for Clayey Fine Sand with Seams of Plastic Clay from Lower Confining Unit 3-5 Consolidation Test Results for Clayey Fine Sand from Lower Confining Unit 3-6 Particle Size Distribution of Confined Sand Layer 3-7 Consolidation Test Results for Lean Sandy Clay with Seams of Silty Sand from Upper Confining Layer 3-8 Consolidation Test Results for Plastic Clay from Upper Confining Unit 3-9 Summary of Particle Size Distribution of Croatan Formation Soils 3-10 Particle Size Distribution of Croatan Formation Soils 3-11 Particle Size Distribution of Croatan Formation Soils 3-12 Particle Size Distribution of Croatan Formation Soils 3-13 Particle Size Distribution of Croatan Formation Soils 3-14 Particle Size Distribution of Croatan Formation Soils 3-15 Atterberg Limits of Wyo-Ben Hydrogel Bentonite 3-16 Bentonite Content Vs. Coefficient of Permeability of Soil-Bentonite Backfill Mixes 3-17 Particle Size Distribution of Soil-Bentonite Backfill Mixes LIST OF FIGURES (continued) Figure Title 4-1 Layout of Tank Farm Remedial Action System 4-2 Generalized Hydrogeologic Cross Section and Formation Properties for Tank Farm Area 4-3 Projected Potentiometric Surface Map of Confined Sand Layer During Operation of Remedial Action System 4-4 Water Levels and Flow Rates for Confined Sand Layer Withdrawal Wells 4-5 Projected Potentiometric Surface Map of Croatan Formation During Operation of Remedial Action System 4-6 Water Levels and Flow Rates for Croatan Formation Injection/Withdrawal Well System 4-7 Monitor Well and Piezometer Location Plan for Performance Monitoring of Remedial Action System Texasgulf Inc. File Number 88-089 1-1 Section 1 PROJECT BACKGROUND On May 31, 1988 during repair and maintenance of an above ground phosphoric acid storage tank, designated Tank 008 (Figure 1-1), it was discovered that the rubber liner within the tank was damaged at two locations allowing the loss of an undetermined amount of 54 percent P205 - phosphoric acid. In response to the tank leak incident, the North Carolina Department of Environment, Health and Natural Resources/Division of Environmental Management (DEM) issued a notice of noncompliance on August 8, 1988 and requested the submission of: (i) an assessment report characterizing the groundwater conditions in the tank farm area and identifying the extent of the contaminants; and (ii) a remedial action plan outlining the proposed corrective actions to remediate the groundwater impacts. In accordance with these requests, a preliminary contamination assessment and a remedial action plan were issued on September 7, 1988 and October 10, 1988, respectively. On June 5, 1989, the DEM was informed by Texasgulf Inc. that a leak of in excess of 5,000 pounds of phosphoric acid was discovered in an underground drain line in the tank farm (Figure 1-1). Water leaking from the drain line was reportedly characterized by a pH of 2.2, and fluoride and phosphorus concentrations of 1,660 and 4,900 mg/1, respectively. The drain line was a gravity -flow pipeline connecting two sumps, and the leak occurred through a damaged section of pipeline. In response to the leak incident, the DEM issued a notice of violation on September 1, 1989 and requested the submission of an active remedial action plan to abate groundwater contamination from both the Tank 008 and drain line leak incidents. In response to this request, a supplemental remedial action plan was submitted to the DEM on October 31, 1989. Upon review of this document, the DEM in their letter of December 8, 1989 requested some modifications to the proposed supplemental remedial action plan. Responses to these concerns were addressed at a meeting in their Washington, North Carolina regional office on January 18, 1990 and documented in our letter of March 6, 1990 titled "Response to Deficiencies Noted by the DEM Concerning the Tank Farm Supplemental Remedial Action Plan and Proposed Revised Remedial Action Plan", which conceptually proposed the following five element remedial action system: • Continue the on -going program of installation of new containment facilities to contain leaks/spills around the piperack, and phosphoric and superphosphoric acid storage tanks. • Install a soil-bentonite cut-off wall along the north side of the tank farm to contain contaminants in the surficial deposits and protect surface waters in the adjacent barge slip. • Install a system of withdrawal wells along the inside of the cut-off wall tapping the confined sand layer to remove existing contaminants from the confined sand layer and overlying deposits. Texasgulf Inc. File Number 88-089 1-2 • Install a system of fresh water injection wells on the north and south sides of the tank farm and a system of withdrawal wells in the center of the tank farm tapping the Croatan formation to remove existing contaminants from this formation. • Institute a revised groundwater monitoring program in the tank farm area to measure the effectiveness of the above actions. The DEM conceptually approved the revised remedial action plan on March 19,1990. Additional engineering evaluations and field explorations were initiated by Ardaman & Associates, Inc. shortly thereafter to complete the final design of the remedial action system for submission to the DEM for final approval prior to construction. This document presents the results of the engineering evaluations, laboratory testing and field explorations undertaken to complete the design of the tank farm remedial action system. Section 2 presents the results of the additional field exploration undertaken by Ardaman & Associates, Inc. in the tank farm area comprised of test borings and pump tests, as well as an overview of the hydrogeology of the site relevant to the design and performance of the remedial action system. A review of the quarterly water quality data obtained from the tank farm monitor wells through April 1990 is also included in Section 2. Engineering properties of the in situ soils relevant to the design of the various elements of the remedial action system are presented in Section 3, as are the results of laboratory tests on soil-bentonite backfill mixes. The design and performance of the remedial action system is addressed in Section 4. Technical specifications for installation of the soil-bentonite cut-off wall and withdrawal/injection well systems are presented in Section 5. TANK 008 LEAK INCIDENT REPORTED 5/31/88 1 s,_ V ti 0 VA L� L 1 MONITOR WELLS (TYPICAL) PP M= Mll CONTAINMENT MO 0 J 3B 3C UNDERGROUND DRAIN LINE LEAK INCIDENT f---- REPORTED 6/5/89 I SPA I PLAN 0 LOCATIONS OF TANK FARM LEAK INCIDENTS .4 H 0 75 150 SCALE — 1"=150' v 7 T war Ardaman & Associates, Inc. Consulting Engineers in Soil Mechanics, FoundatNms, and Materials Testing • TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA N3%95 FIGURE 1-1 DRAWN8v KJS ICHECKED SY L'` GATE: 7.18-90 FILE 8- TAPIR 88-089 Texasgulf Inc. File Number 88-089 2-1 Section 2 HYDROGEOLOGIC SETTING IN TANK FARM AREA 2.1 Previous Field Exploration Programs An initial field exploration program, consisting of three standard penetration borings designated _ B-1, B-2 and B-3, was completed in June 1988 in response to the May 1988 tank leak incident at Tank 008. The locations of these borings are depicted on the soil boring, monitor well and test well location plan (Figure 2-1). As shown, the borings were located on the north side of the tank farm, and were drilled to a depth of 40 feet to obtain soil samples for chemical analyses to ascertain if impacts for the Tank 008 leak incident had migrated northward. The results of this initial field exploration program were presented in our report titled "Preliminary Contamination Assessment in Tank Farm Area in Response to Tank 008 Leakage", dated September 7, 1988. In response to an underground drain line leak incident in the tank farm, reported by Texasgulf Inc. to the DEM on June 5, 1989, a subsequent field exploration was undertaken in October 1989. This program consisted of the installation of three tank farm monitor well clusters, designated MWTF-1, MWTF-2 and MWTF-3 at the locations depicted in Figure 2-1. Monitor well cluster MWTF-1 was located on the south side of the tank farm near the fertilizer blend storage area, some 190 feet south of the row of phosphoric acid storage tanks (i.e., tanks 006 through 009, 017, 019 and 021) and about 100 feet southeast of the reported drain line leak. Monitor well clusters MWTF-2 and MWTF-3 were located about 230 feet north of the phosphoric acid storage tanks. Three monitor wells were installed at each cluster (designated A, B and C), providing a total of nine monitor wells in the tank farm area. The results of this subsurface exploration and groundwater monitor program were presented in our report titled "Supplemental Remedial Action Plan for Tank Farm Area", dated October 31, 1989. 2.2 Additional Field Exploration Program As part of the design of the tank farm remedial action system presented in our letter of March 6, 1990, titled "Response to Deficiencies Noted by the DEM Concerning the Tank Farm Supplemental Remedial Action Plan and Proposed Revised Remedial Action Plan", an additional field exploration program was undertaken in May and June 1990 consisting of the following elements: • Eleven Standard Penetration Test borings, designated TF-100 through TF-110, performed at the locations depicted in Figure 2-1 to supplement the field exploration results previously obtained in the tank farm area. • Two pumping tests in the Croatan formation, one near monitor well cluster MWTF-1 and another near monitor well cluster MWTF-3, to determine aquifer properties for design of the Croatan formation injection/withdrawal well system. • A pumping test in the confined sand layer in the surficial deposits near monitor well cluster MWTF-3 to determine aquifer properties for design of the confined sand layer withdrawal well system. Texasgulf Inc. File Number 88-089 2-2 The objective of the additional field exploration program was to assess the subsurface soil conditions at the tank farm relevant to: (i) determining the required depth of installation of the cut-off wall and nature and consistency of the soils through which the cut-off wall will be excavated; (ii) the nature, thickness, extent and transmissivity of the confined sand layer to be tapped by a withdrawal well system; (iii) the nature, thickness, extent and transmissivity of the Croatan formation to be tapped by an injection/withdrawal well system; and (iv) the nature, thickness, extent and leakance of the clayey confining layers interbedded above the confined sand layer and Croatan formation. 2.2.1 Standard Penetration Test Borings The results of the eleven Standard Penetration Test borings conducted as part of the field exploration program (i.e., borings TF-100 through TF-110) are presented on the soil boring logs in Appendix A. The logs from previous test borings performed at the tank farm (i.e., borings B-1, B-2, B-3, MWTF-1, MWTF-2 and MWTF-3) are also included in Appendix A. The stratification lines indicated on the boring logs represent our interpretation of the contents of the field logs, and the results of laboratory observations and index tests on the recovered split -spoon samples. Laboratory index tests* used to classify the soils are shown on the boring logs, and the soils were classified in accordance with ASTM D 2487 standard test method for classification of soils for engineering purposes. The stratification lines represent the approximate boundary between soil types and the transition may be more gradual than implied. The Standard Penetration Test borings were completed in general accordance with ASTM Standard D 1586. The Standard Penetration Test is a widely accepted method of in situ testing of soils.. A 2-foot long, 2-inch O.D. split -barrel sampler attached to the end of a string of drilling rods is driven 18 inches into the ground by successive blows of a 140-pound hammer freely dropping 30 inches. The number of blows needed for each 6 inches of penetration is recorded. The sum of the blows required for penetration of the second and third 6-inch increments of penetration constitutes the penetration resistance or N-value.** After the test, the sampler is extracted from the ground and opened to allow visual examination and classification of the retained soil sample. The N-value has been empirically correlated with various soil properties allowing estimates of the behavior of soils under load. For this project, the N-value also allows an estimate of the effort required to drill a well or excavate the slurry trench. The N-value has been correlated with the relative density of cohesionless soils (sands) and consistency of cohesive soils (clays) as outlined in the Terzaghi & Peck (1967) classification system presented below. * Refer to Section 3 for the results of the laboratory testing program. * * The split -barrel sampler was sometimes driven the fourth 6 inches (Le., the full 24-inch length of the sampler) particularly when sampling continuously. Texasgulf Inc. File Number 88-089 2-3 Relative Density of Sand Based on Standard Penetration Test Consistency of Clay Based on Standard Penetration Test N-Value (blows/foot) Relative Density N-Value (blows/foot) Consistency 0-4 4-10 10-30 30-50 >50 Very Loose Loose Medium Dense Very Dense <2 2-4 4-8 8-15 15-30 >30 Very Soft Soft Medium Stiff Very Stiff Hard A representative portion of the soil recovered in each split -barrel sample was saved within a sealed glass jar for laboratory classification and testing. A total of 150 split -barrel soil samples were recovered from borings TF-100 through TF-110. The soil borings were generally completed to a depth of 61.5 feet to completely penetrate the undifferentiated surficial deposits and Pleistocene Croatan formation and encounter the top of the Pliocene Yorktown formation (i.e., borings TF-100 through TF-106). Borings TF-107, TF-108, TF-109 and TF-110 were completed to shallower depths of 27 to 42 feet to better define the nature and extent of the undifferentiated surficial deposits and Pleistocene Croatan formation at selected locations in the tank farm area. 2.2.2 Undisturbed Shelby Tube Sampling In addition to split -barrel samples, undisturbed Shelby tube samples were obtained from each representative soil formation to provide samples for permeability, strength and consolidation testing. A total of nine 3-inch diameter undisturbed samples were recovered at borings TF-102 through TF-106 at the depths shown on the soil boring logs (see Appendix A). The undisturbed samples were obtained in general accordance with ASTM D 1587 using a 2.875-inch inside diameter 30-inch long thin walled seamless steel Shelby tube. 2.3 Generalized Subsurface Stratigraphy The subsurface stratigraphy in the tank farm area within the depth of interest relative to the design of the remedial action system consists of in ascending order: (i) the Pliocene Yorktown formation; (ii) the Pleistocene Croatan formation; and (iii) the undifferentiated surficial deposits. Generalized cross sections depicting the subsurface stratigraphy in the tank farm are presented in Figure 2-2.* * Test borings previously performed in the tank farm area by other Texasgulf Inc. consultants were also used in developing the generalized subsurface stratigraphy at each cross section (i.e., Law Engineering Testing Co., Orofino and Company, Tippetts-Abbett-McCarthy-Stratton, and Thor Engineers). The locations of these previously drilled borings are shown on Figure 2-1. Texasgulf Inc. File Number 88-089 2-4 2.3.1 Yorktown Formation The upper portion of the Yorktown formation penetrated by the test borings generally consisted of calcareous clayey fine sand to sandy clay. The top of the formation was encountered at depths of about 47 to 56 feet below land surface, corresponding to elevations of -36 to -44 feet (MSL), with an overall average depth of 51.5 feet. Standard Penetration Test resistances vary in the Yorktown formation from 6 to 12 blows/foot with an average of 9 blows/foot, characteristic of medium stiff to stiff clayey soils. The Yorktown formation and underlying Pungo River formation comprise the Yorktown-Pungo River aquitard which confines the Castle Hayne aquifer. The Yorktown-Pungo River aquitard is expected to be about 100 feet thick extending from the base of the Croatan formation to the top of the Castle Hayne limestone at about Elevation -140 feet (MSL). 2.3.2 Croatan Formation The Croatan formation generally consists of clayey fine sand to fine sand and shell fragments, occasionally with cemented sand. The formation was encountered at depths of 26 to 38 feet below land surface, corresponding to elevations of -15 to -25 feet (MSL), with an overall average depth of about 31 feet. The thickness of the formation ranges from 14 to 29 feet, with an average of about 21 feet. As shown by the isopach map in Figure 2-3, the thickness is variable but is generally somewhat thinner in the central portion of the tank farm area. The Standard Penetration Test resistance in the Croatan formation varied widely from 1 to 69 blows/foot with an overall representative value of about 16 blows/foot, which is characteristic of a medium dense sand. Along the south side of the tank farm where the injection wells will be installed the penetration resistance varied from 6 to 69 blows/foot, with an average of 20 blows/foot (i.e., at borings TF-100, TF-101, MWTF-1, B-10 and B-16). Penetration resistances as high as 59 and 69 blows per foot were encountered in borings MWTF-1 and TF-100 at depths of 45 feet. Along the north side of the tank farm where the withdrawal wells will be installed, the penetration resistance is generally lower, ranging from 24 inches of penetration under the weight of the drill rods and hammer to 30 blows/foot, with an average of about 12 blows/foot (i.e., at borings B-1, B-2, B-3, MWTF-2, MWTF-3, and TF-104 through TF-108). Complete drilling fluid circulation losses were observed along the south side of the tank farm in the Croatan formation at borings MWTF-1, TF-100 and TF-101 at depths of 39 to 42 feet. The circulation losses indicate the presence of a relatively continuous permeable zone between the depths of 39 and 42 feet on the south side of the tank farm which was not encountered elsewhere. At each circulation loss the formation was comprised of fine sand to slightly silty fine sand and shell fragments, rather than the less pervious slightly clayey to clayey fine sand and shell fragments which occurred at most other borings and above the water loss zone in these three borings. The presence of this permeable zone will affect the installation of the injection wells by requiring the use of casing or hollow -stem auger. As noted in Section 2.5.1.2, the permeable zone also resulted in a greater formation transmissivity on the south side of the tank farm than observed on the north side of the tank farm. 2.3.3 Undifferentiated Surficial Deposits The undifferentiated surficial deposits consist of a layered sequence in ascending order of a lower confining unit, confined sand layer, upper confining unit, and a surficial layer of generally sandy Texasgulf Inc. File Number 88-089 2-5 soils. The following conditions are considered representative for each of these layers based upon the field exploration programs. 2.3.3.1 Lower Confining Unit. The base of the undifferentiated surficial deposits is typically comprised of a gray to greenish -gray clayey fine sand to sandy clay often with some shell fragments. This stratum overlies and confines the underlying Croatan formation. The stratum ranges from 3.5 to 14.5 feet in thickness, with an overall average of about 7.5 feet based upon thicknesses observed at 26 soil borings in the tank farm area. The top of the stratum occurs at _ depths ranging from 17 to 28 feet, corresponding to elevations of -8 to -17 feet (MSL), with an average depth of about 23 feet. Standard Penetration Test resistance values were characteristic of very soft to stiff clayey soils with blow counts varying from 24 inches of penetration under the weight of the drill rods to 12 blows per foot. The average penetration resistance was about 5 blows/foot, characteristic of a medium stiff clayey soil. Along the north side of the tank farm where the cut-off wall will be keyed into this lower confining unit, a portion of the layer was found to be very soft between borings TF-105 and TF-107. Along this approximately 100-foot long reach the soils were often penetrated by the weight of the drill rods, and were always less than 2 blows/foot, characteristic of very soft clayey soils. 2.3.3.2 Confined Sand Layer. A gray to brown medium to fine sand to silty fine sand layer ranging in thickness from 2 to 5.5 feet, with an average thickness of about 4 feet, was encountered above the lower confining unit over portions of the tank farm area. As shown by the lsopach map in Figure 2-4, the following trends in thickness are apparent from 33 test borings completed in the tank farm area: • Along the north side of the tank farm where the confined sand layer dewatering wells will be installed, the sand layer varies from a minimum of 2 feet in thickness at borings TF-105 and TF-108 to a maximum of 4.8 feet at boring MWTF-3 (also see Section A -A on Figure 2-2). • The confined sand layer extends southward into the tank farm for a distance of about 250 feet south of the asphalt road (i.e., the asphalt road along the north side of the tank farm - see Figure 2-1). At this point the confined sand layer tapers -out below a portion of the area, and was not encountered at several borings on both the east and west sides of the tank farm (i.e., borings TF-101, TF-109, TF-110, MWTF-1*, B-10, B-16, B-17, T-25 and FB-1). • Further south of the tank farm area the confined sand layer occurs at borings T-20, T-21 and T-22, and is continuous across the east side of the tank farm through an approximately 200-foot wide area near borings TF-100, E-10, B-14 and B-15. * The sand layer at a depth of 9.5 to 11.0 feet in this boring was previously included as part of the confined sand layer. Based upon the results of the additional borings and review of other borings in the tank farm, this sand layer potentially may not be hydraulically connected to the confined sand layer underlying the north side of the tank farm. Accordingly, the isopach map (Figure 2-4) has been prepared without the confined sand layer at boring MWTF-1. Texasgulf Inc. File Number 88-089 2-6 Standard Penetration Test resistance values in the confined sand layer range from 2 to 33 blows/foot, characteristic of very loose to medium dense sand, with an average of about 17 blows/foot, characteristic of a medium dense sand. 2.3.3.3 Upper Confining Unit. The confined sand layer is generally overlain by (and confined by) brown to gray clayey fine sands to plastic clays ranging in thickness from 2 to 15 feet with an overall average of about 5.5 feet. The upper confining unit is present above the sand layer except at borings B-1, TF-100 and TF-104. At locations where the confined sand layer does not exist, the clayey fine sands to plastic clays directly overlie the basal clayey fine sand to sandy clay lower confining unit (Section 2.3.3.1). The Standard Penetration Test resistance varies widely in this unit from 24 inches of penetration under the weight of the drill rods and hammer to 16 blows/foot, characteristic of very soft to stiff clayey soils, although a resistance of less than 4 blows/foot, characteristic of soft clayey soils appears representative. Along the north side of the tank farm where the cut-off wall will be installed, the upper confining unit generally consists of very soft gray plastic clays with blow counts typically less than 2 blows/foot along an approximately 400-foot long reach between borings B-2 and TF-107. Along this reach the cut-off wall will be excavated through 4 to 9 feet of the very soft plastic clays at depths of 14 to 23 feet below land surface. 2.3.3.4 Surficial Soils. The surficial soils consist of interbedded fine sands to clayey fine sands (comprised partly of fill materials) extending from ground surface to depths of 5 to 19 feet, with an overall average thickness of about 12 feet. Standard Penetration Test resistance values vary widely from 5 to 64 blows/foot, representative of loose to dense sands, with an overall average of 23 blows per foot, characteristic of medium dense sands. 2.4 Groundwater Levels and Flow Directions Groundwater levels were measured in the monitor wells at the time of each quarterly sampling event in January, April, July and November 1989, and in January and April 1990. The measured water level elevations are summarized below. Monitor Well Water Level Elevation, feet (MSL) 01/89 04/89 07/89 11/89 01/90 04/90 MWTF-1A 8.47 9.44 9.14 9.21 10.2 9.9 MWTF-1B 8.06 8.66 8.66 8.45 7.25 9.3 MWTF-1C -3.96 -0.74 -2.19 -0.28 +0.46 -0.84 MWTF-2A 6.82 6.94 5.25 7.00 7.41 6.35 MWTF-2B 4.14 4.66 4.30 4.99 5.18 3.84 MWTF-2C -1.85 -0.45 -1.06 +0.18 +0.20 -0.40 MWTF-3A 7.45 7.57 7.15 7.24 7.67 6.38 MWTF-3B 3.13 3.67 3.37 4.12 3.91 3.24 MWTF-3C -2.61 -0.49 -1.32 +0.13 +0.12 -0.53 Texasgulf Inc. File Number 88-089 2-7 As previously documented in Section 2.5 of the Supplemental Remedial Action Plan, the direction of groundwater flow is generally: (i) north -northwestward in the surficial soils as measured in the 1A, 2A and 3A monitor wells*; (ii) north -northwestward in the confined sand layer as measured in the 1B**, 2B and 3B monitor wells; and (iii) south -southwestward in the Croatan formation as measured in the 1C, 2C and 3C monitor wells. As shown in Figure 2-5, over the 15-month monitoring period from January 1989 through April 1990, the water levels in the various formations have varied somewhat, but the direction of flow has remained the same as initially reported (as indicated by the same relative elevation of water levels between wells in each layer). As shown in Figure 2-6, the water level elevations decline with depth indicative of downward vertical seepage. The decline in water level with depth has remained relatively consistent over the 15-month monitoring period from January 1989 through April 1990, equalling about 11, 7 and 8 feet between the surficial soils and Croatan formation at monitor well clusters MWTF-1, MWTF-2 and MWTF-3, respectively. During this period, the overall average water levels in the surficial soils and Croatan formation were about +8 and -1 feet (MSL), respectively. 2.5 Pumping Tests and Evaluation of In Situ Aquifer Properties Two pumping tests were performed in the Croatan formation and one pumping test was performed in the confined sand layer to provide aquifer properties for design of the injection/withdrawal well systems. The construction records for the test wells installed to perform the pumping tests are included in Appendix B, and the locations of the test wells are shown on Figure 2-1. Figures 2-7 and 2-13 present more detailed layouts of the wells at each pumping test. The five test wells installed for the pumping tests were given the following designations: • North Pumping Test in Croatan Formation CPW (Pumping Well) COW (Observation Well) • South Pumping Test in Croatan Formation MWTF-1D (Pumping Well) • Confined Sand Layer Pumping Test SPW (Pumping Well) SOW (Observation Well) * Refer to Figure 2-1 for the locations of the monitor wells within the tank farm. ** As addressed in Section 2.3.3.2, the sand layer tapped by monitor well MWTF-1B potentially may not be hydraulically connected to the confined sand layer underlying the north side of the tank farm. Texasgulf Inc. File Number 88-089 2-8 2.5.1 Croatan Formation Pumping Tests One Croatan formation pumping test was performed on the north side of the tank farm near monitor well cluster MWTF-3, and the other was performed on the south side of the tank farm near monitor well cluster MWTF-1. The layout of the pumping test wells is depicted in Figure 2-7. 2.5.1.1 North Pumping Test. The north pumping test was performed by pumping test well CPW for a period of 2547 minutes at an average rate of 1.98 gal/min. As shown in Figures 2-8, 2-9 and 2-10, the pumping test well was drawn down about 11.5 feet for this rate of flow, and the observation wells displayed steady-state drawdowns of 2.8 and 4.5 feet at radial distances from the pumping well of 35.5 and 10.0 feet, respectively. Using a steady-state leaky artesian aquifer analysis of distance-drawdown field data from the test well and two observation wells, the following properties were calculated for the Croatan formation and overlying confining layer: Transmissivity, T Confining Layer Leakance, k„/B Confining Layer Coefficient of Permeability, k„ 305 gal/day/ft 0.0066 gal/day/ft3 3.3x10-6 cm/sec For a Croatan formation thickness of 15 feet at the test location (see log for boring MWTF-3) the measured transmissivity corresponds to a horizontal coefficient of permeability of 2.7 feet/day.* The in situ permeability test previously performed at monitor well MWTF-3C via a slug test yielded a somewhat lower value of 0.9 feet/day. The coefficient of permeability calculated from the pumping test is considered more representative of the formation than the value calculated from the slug test. The pumping test stresses a larger portion of the aquifer than the slug test, and accordingly measures the hydraulic properties of a larger and therefore more representative portion of the formation. For the measured confining layer leakance of 0.0066 gal/day/ft3 and a confining layer thickness of 10.5 feet at the test location, the corresponding confining layer vertical coefficient of permeability equals 3.3x10-6 cm/sec. This value is reasonable for the clayey fine sands comprising the confining layer overlying the Croatan formation at the test location. Alternatively, using a leaky artesian aquifer analysis of the time-drawdown field data from each observation well, somewhat lower transmissivities of 230 and 180 gal/day/ft were backfigured for the MWTF-3C and COW observation wells, respectively. These values are still somewhat greater than obtained from the slug test performed on monitor well MWTF-3C. Two groundwater samples were obtained from the pumping well near the end of the test to characterize the quality of groundwater withdrawn from the Croatan formation. The results of the chemical analyses are presented below, and compared with water quality data from nearby monitor well MWTF-3C. * Transmissivity, T, equals the product of the horizontal coefficient of permeability, kb, and the aquifer thickness, t (i.e., T = ke t). Texasgulf Inc. File Number 88-089 2-9 Parameter Test Well CPW Monitor Well MWTF-3C at t = 1300 minutes at t = 2547 minutes Sampling Date 06/07/90 06/09/90 04/17/90 Field pH 6.74 6.72 6.0 Field Temperature, °C 34.5 33.8 29.0 Field Specific Conductance, °C 2970 2920 2450 Laboratory pH (@ 19°C) 7.0 7.0 6.6 Total Dissolved Solids, TDS (mg/1) 2111 2106 1830 Sulfate, SO4 (mg/1) 691 662 589 Chloride, Cl (mg/1) 98 97 98 Sodium, Na (mg/1) 162 156 x Total Phosphorus, P (mg/1) 0.67 0.69 28.8 Fluoride, F (mg/1) 0.31 0.29 0.13 Total Organic Carbon, TOC (mg/1) 8 9 4 Groundwater pumped from test well CPW is generally similar to somewhat higher in dissolved solids than groundwater at monitor well MWTF-3C. The total dissolved solids, sulfate, fluoride, and total organic carbon concentrations are slightly higher at test well CPW than at MWTF-3C, the chloride concentrations are essentially identical, and the total phosphorus concentration is notably lower at well CPW. The lower total phosphorus concentration is unexpected, because a similar to somewhat higher total phosphorus concentration as observed at MWTF-3C was expected for the groundwater at test well CPW. 2.5.1.2 South Pumping Test. The south pumping test was performed by pumping test well MWTF-1D for a period of 1684 minutes at an average rate of 3.40 gal/min. As shown in Figure 2-11, the pumping well was drawn down 4.5 feet over this period, and the MWTF-1C monitor well was drawn down 1.7 feet. For this test period the wells had not reached steady-state conditions, and the water levels were still declining at the time the test was terminated. Analysis of the time-drawdown behavior of monitor well MWTF-1C (Figure 2-12) by both the Theis and Cooper -Jacob methods of solution yielded the following typical properties for the Croatan formation and overlying confining layer: Transmissivity, T Confining Layer Leakance, k./B Confining Layer Coefficient of Permeability, k„ 2400 gal/day/ft <0.00056 gal/day/ft3 <5x101 cm/sec For a formation thickness of about 15 feet at the test location (see log for boring MWTF-1), the calculated transmissivity corresponds to a horizontal coefficient of permeability of about 21 feet/day. As expected, because of the circulation loss zone encountered on the south side of the tank farm, this transmissivity is greater than found on the north side of the tank farm (Section 2.5.1.1). The in situ permeability (slug) test previously performed at monitor well MWTF-1C yielded a horizontal coefficient of permeability of 2.7 feet/day. Accordingly, the pumping test yielded a horizontal coefficient of permeability 7.8 times greater than the slug test. Texasgulf Inc. File Number 88-089 2-10 The difference between the test results occurs because the pumping test well fully penetrated the pervious water loss zone encountered in the Croatan formation along the south side of the tank farm, whereas the monitor well collection zone did not penetrate the water loss zone. The horizontal coefficient of permeability determined from the pumping test is considered more representative of the formation because: (i) the test well fully penetrated the permeable water loss zone; and (ii) the pumping test stresses are a larger portion of the aquifer thereby measuring the hydraulic properties of a larger more representative portion of the formation. - Although steady-state conditions were not reached during the pumping test, it was possible to determine an upper bound confining layer leakance from the time-drawdown behavior at well MWTF-1C. As tabulated above, a confining layer leakance of less than 0.00056 gai/day/ft3 is projected for the plastic clays and clayey sands overlying the Croatan formation at the test location, corresponding to a vertical coefficient of permeability of less than 5x10 7 cm/sec for the approximately 20-foot thick confining layer. The quality of groundwater withdrawn from the pumping well near the end of the test is presented below. The results of groundwater quality analyses performed on nearby monitor well MWTF-1C are also tabulated for comparison. Parameter Test Well Monitor Well MWTF-1C MWTF-1D Sampling Date 06/17/90 04/18/90 Field pH 6.95 6.8 Field Specific Conductance, µmhos/cm 850 775 Field Temperature, °C 19.7 19 Laboratory pH 7.3 7.4 Total Dissolved Solids, TDS (mg/1)* 1190 560 Sulfate, SO4 (mg/I) 80 77 Sodium, Na (mg/1) 38 x Calcium, Ca (mg/1) 119 x Magnesium, Mg (mg/1) 8 x Iron, Fe (mg/1) 15 x Chloride, Cl (mg/1) 60 55 Total Phosphorus, P (mg/1) 0.19 0.30 Fluoride, F (mg/1) 0.33 0.60 Total Organic Carbon, TOC (mg/1) 3 4 As shown, the groundwater quality at the test well is similar to that at the adjacent monitor well. Based upon a correlation between total dissolved solids and specific conductance for groundwater in the tank farm area, a total dissolved solids concentration of 500 to 600 mg/1 is expected for a specific conductance of 800 to 850 µmhos/cm. Accordingly, the reported total dissolved solids concentration of 1190 mg/1 is suspect. Texasgulf Inc. File Number 88-089 2-11 2.5.2 Confined Sand Layer Pumping Test One pumping test was performed in the confined sand layer on the north side of the tank farm near monitor well cluster MWTF-3. The layout of the pumping test is depicted in Figure 2-13. The test was performed by pumping test well SPW for a period of about 1400 minutes at an average rate of 4.28 gal/rain. As shown in Figure 2-14, the pumping well was drawn down 4.2 feet over this period, and monitor well MWTF-3B was drawn down 1.32 feet. Observation well SOW was drawn down 1.3 feet after about 500 minutes. Beyond this time an instrumentation malfunction resulted in erroneous water level measurements in observation well SOW. During the test period the wells did not reach steady-state conditions, and the water levels were still declining at the time the test was terminated. Analysis of the time-drawdown behavior of the SOW observation well and MWTF-3B monitor well by both the Theis and Cooper -Jacob methods of analyses yielded the following typical properties for the confined sand layer and overlying confining layer: Transmissivity, T Confining Layer Leakance, k.JB Confining Layer Coefficient of Permeability, k„ 2,170 gal/day/ft <0.0049 gal/day/ft3 <2x10-6 cm/sec For a confined sand layer thickness of 4.5 feet at the test location (see log for boring MWTF-3) the measured transmissivity corresponds to a horizontal coefficient of permeability of 64 feet/day. The in situ coefficient of permeability previously determined at monitor well MWTF-3B via a slug test equalled 31 feet/day. Accordingly, the coefficient of permeability determined by the pumping test is somewhat greater than determined by the monitor well slug test. As discussed above for the Croatan formation pumping tests, the permeability determined from a pumping test is generally considered more representative of the formation than the permeability obtained from a slug test. Although steady-state conditions were not reached during the pumping test, it was possible to determine an upper bound confining layer leakance from the time-drawdown behavior at monitor well MWTF-3C. As tabulated above, a confining layer leakance of less than 0.0049 gal/day/ft3 is projected for the plastic clay overlying the confined sand layer at the test location, corresponding to a vertical coefficient of permeability of less than 2x10-6 cm/sec for the approximately 9-foot thickness of clay at the test location. Two groundwater samples were obtained from pumping well SPW near the end of the test to characterize the quality of groundwater withdrawn from the confined sand layer. The results of the chemical analyses are presented below, and compared with water quality data from monitor well MWTF-3B. Texasgulf Inc. File Number 88-089 2-12 Parameter Test Well SPW Monitor Well at t = 370 minutes at t = 1215 minutes MWTF-3B Sampling Date 06/04/90 06/05/90 04/17/90 Field pH 5.82 5.88 5.8 Field Temperature, °C 38.9 38.2 30 Field Specific Conductance, µmhos/cm 2850 2790 2525 Laboratory pH @ 23°C 6.0 6.1 6.3 Total Dissolved Solids, TDS (mg/1) 1639 1745 1800 Sulfate, SO4 (mg/1) 621 622 613 Chloride, Cl (mg/1) 130 131 129 Sodium, Na (mg/1) 118 115 x Total Phosphorus, P (mg/1) 80 105 145 Fluoride, F (mg/I) 0.33 0.30 0.23 Total Organic Carbon, TOC (mg/1) 9 x 12 As shown, the groundwater quality at test well SPW is similar to the quality of groundwater at monitor well MWTF-3B, displaying elevated phosphorus, sulfate and total dissolved solids concentrations. 2.6 Water Quality in Tank Farm Monitor Wells Groundwater samples have been obtained six times to -date on a quarterly basis at each of the nine monitor wells and a nearby Castle Hayne aquifer water supply well between January 1989 and April 1990. The results of chemical analyses on the groundwater samples are summarized in Tables 2-1 through 2-10. 2.6.1 Groundwater Quality in Undifferentiated Surficial Deposits Groundwater quality in the undifferentiated surficial deposits is monitored in the surficial sand layer (wells 1A, 2A and 3A) and in the confined sand layer (wells 1B, 2B and 3B). 2.6.1.1 Surficial Sand Layer. At monitor well MWTF-1A (Table 2-1) upgradient of the phosphoric acid facilities, the phosphorus, fluoride and sulfate concentrations were relatively low through July 1989. Since that time, total phosphorus and fluoride concentrations have increased somewhat to 4.5 and 7.6 mg/1, respectively. The sulfate, chloride and total dissolved solids concentrations, specific conductance and pH have not changed. The measured total dissolved solids, sulfate and chloride concentrations and pH are in compliance with Title 15 NCAC Subchapter 2L.0202 Class GA water quality standards of 500, 250 and 250 mg/1 and range of 6.5 to 8.5, respectively, but the fluoride concentration is greater than the Class GA standard of 2.0 mg/l. At downgradient monitor wells MWTF-2A and MWTF-3A (Tables 2-4 and 2-7) the quality of groundwater has not changed significantly over the 15-month monitoring period except for an Texasgulf Inc. File Number 88-089 2-13 increase in the sulfate concentration at MWTF-3A from 92 to 226 mg/1. Groundwater at these two wells is characterized by the following average constituent concentrations. Parameter Monitor Well MWTF-2A MWTF-3A Field pH 6.4 5.5 Specific Conductance (µmhos/cm) 1530* 1380 Total Phosphorus, P (mg/1) 0.13 0.23 Fluoride, F (mg/1) 0.19 0.15 Chloride, Cl (mg/I) 61 315 Sulfate, SO4 (mg/1) 411* 138 Total Dissolved Solids, TDS (mg/1) 1180* 808 Total Organic Carbon, TOC (mg/1) 15 7.3 Groundwater at monitor well MWTF-3A is in compliance with Class GA water quality standards for fluoride, chloride and sulfate, but displays a total dissolved solids concentration greater than 500 mg/1 and a pH less than the standard lower bound of 6.5. Groundwater at monitor well MWTF-2A is in compliance with Class GA water quality standards for fluoride and chloride, but displays total dissolved solids and sulfate concentrations greater than the standards and a pH less than the standard lower bound of 6.5. 2.6.1.2 Confined Sand Layer. At monitor well MWTF-1B** upgradient of the phosphoric acid facilities (Table 2-2), the phosphorus, fluoride and sulfate concentrations are relatively low and have remained essentially unchanged over the 15-month monitoring period, indicating that impacts do not exist at this location. The fluoride, chloride and sulfate constituent concentrations are in compliance with Class GA water quality standards. The measured pH and total dissolved solids concentrations, however, indicate that the background pH and total dissolved solids concentration may naturally exceed Class GA water quality standards. Total dissolved solids concentrations exceeding the standard by 4 to 93 mg/1 have been measured on four of the six sampling events. The pH has been less than the standard on each sampling event to -date. At downgradient monitor wells MWTF-2B and MWTF-3B (Tables 2-5 and 2-8) groundwater impacts are evident by the elevated phosphorus concentrations. Groundwater quality at these two wells displayed some changes over the 15-month monitoring period, namely: (i) a general increase in total phosphorus concentrations at both wells; and (ii) an increase in sulfate and total dissolved solids concentrations at MWTF-3B. Fluoride and chloride concentrations are in compliance with Class GA water quality standards at both downgradient monitor wells. The sulfate and total * Disregarding inconsistent high values reported in April 1989. ** As addressed in Section 2.3.3.2, the sand layer tapped by monitor well MWTF-1B potentially may not be hydraulically connected to the confined sand layer underlying the north side of the tank farm. Texasgulf Inc. File Number 88-089 2-14 dissolved solids concentrations, however, exceed the Class GA standards, and the groundwater pH is below the standard lower bound of 6.5. 2.6.2 Groundwater Quality in Croatan Formation The average constituent concentrations measured in the Croatan formation over the 15-month monitoring period are summarized below: Parameter Monitor Wells MWTF-1C Field pH Specific Conductance (µmhos/cm) Total Phosphorus, P (mg/1) Fluoride, F (mg/1) Chloride, CI (mg/1) Sulfate, SO4 (mg/I) Total Dissolved Solids TDS (mg/1) Total Organic Carbon, TOC (mg/1) 6.9 794 0.26 0.48 54 54* 541 4.2 MWTF-2C 6.2 2293 17.6 0.17 77 862 2290 12 MWTF-3C 6.1 2508 24.4 0.11 96 622 1973 8.8 *Disregarding inconsistent high sulfate concentration of 292 mg/I reported in January 1989. At monitor well MWTF-1C (Table 2-3), the phosphorus, fluoride and sulfate concentrations are relatively low indicating that groundwater impacts do not exist in the Croatan formation at this location. The measured constituent concentrations are in compliance with Class GA water quality standards with the exception of the total dissolved solids concentration. The total dissolved solids concentration has typically exceeded the standard by 26 to 96 mg/1 (only one of six samples displayed a concentration less than the standard) indicating that the background total dissolved solids concentration may naturally exceed the Class GA water quality standard. At monitor wells MWTF-2C and MWTF-3C (Tables 2-6 and 2-9) the phosphorus, sulfate, and total dissolved solids concentrations are elevated. These parameters, however, have remained essentially unchanged over the 15-month monitoring period. Fluoride and chloride concentrations are within the Class GA water quality standards, but sulfate and total dissolved solids concentrations exceed the standards and the pH is less than the standard lower bound of 6.5. 2.6.3 Castle Hayne Aquifer Groundwater Quality Groundwater quality in the Castle Hayne aquifer at water supply well FERT-1 (Figure 2-1) has remained unchanged over the 15-month monitoring period (Table 2-10). Groundwater in the Castle Hayne aquifer at well FERT-1 displays background levels of phosphorus, fluoride and sulfate. Accordingly, as expected, due to the approximately 100-foot thick Yorktown-Pungo River aquitard separating the Castle Hayne aquifer from the Croatan aquifer, phosphoric acid leakage/spills have not impacted the Castle Hayne aquifer. Table 2-1 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MWTF-IA Sampling Date Parameter 1/89 4/89 7/89 11/89 1/90 4/90 • FIELD DATA Specific Conductance (µmhos/cm) at Field Temperature 590 380 385 430 370 365 Corrected to 25°C 673 441 370 456 451 - pH 6.8 6.8 6.7 6.6 7.2 6.8 Water Temperature (°C) 18 17 27 22 14 17.5 Water Level, feet (MSL) 8.47 9.44 9.14 9.21 10.2 9.9 Gallons Purged Before Sampling 3.7 3.6 5.5 3.3 4.4 2.8 • PHYSICAL APPEARANCE Odor none none none none none none Apparent Color rusty light milky clear clear clear rusty (light) • LABORATORY DATA Lab pH 6.8 6.8 6.9 6.5 7.8 7.6 Total Phosphorus, P (mg/1) 0.464 0.672 0.064 2.56 2.53 4.5 Fluoride, F (mg/1) 0.64 0.60 0.9 11.30 9.59 7.60 Chloride, CI (mg/1) 29 8 10 7 5 8 Sulfate, SO4 (mg/1) 88 92 43 52 149 44 Total Dissolved Solids, TDS (mg/1) 372 336 268 256 276 252 Total Organic Carbon, TOC (mg/I) 7 5 5 4 3 12 Table 2-2 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MWTF-1B Parameter Sampling Date 1/89 4/89 7/89 11/89 1/90 4/90 • FIELD DATA Specific Conductance (pathos/cm) at Field Temperature 900 910 950 925 790 775 Corrected to 25°C 1008 1037 950 944 809 pH 5.6 5.8 5.4 5.2 5.4 5.2 Water Temperature (°C) 19 18 25 24 20 18.5 Water Level, feet (MSL) 8.06 8.66 8.66 8.45 7.25 9.3 Gallons Purged Before Sampling 6.2 6.0 6.0 6.5 7.25 8.5 • PHYSICAL APPEARANCE Odor none none none eggs none none Apparent Color clear clear clear clear clear clear • LABORATORY DATA Lab pH 5.7 5.8 5.7 5.2 6.4 6.0 Total Phosphorus, P (mg/1) 0.122 0.228 0.234 5.08 0.775 0.45 Fluoride, F (mg/1) 0.18 0.165 0.45 2.17 1.83 0.295 Chloride, Cl (mg/1) 218 218 204 191 166 199 Sulfate, SO4 (mg/1) 12 22 18 15 32 28 Total Dissolved Solids, TDS (mg/1) 593 562 460 504 408 524 Total Organic Carbon, TOC (mg/1) 3 3 3 3 3 4 Table 2-3 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MWTF-1C Parameter Sampling Date 1/89 4/89 7/89 10/89 1/90 4/90 • FIELD DATA Specific Conductance (µmhos/cm) at Field Temperature 800 800 850 790 750 775 Corrected to 25°C 888 896 918 809 833 pH 6.8 7.2 6.9 7.0 6.8 6.8 Water Temperature (°C) 19.5 19 21 20 19.5 19 Water Level, feet (MSL) -3.96 -0.74 -2.19 -0.28 +0.46 -0.84 Gallons Purged Before Sampling 15.0 17.5 16.5 16.0 19.0 20.0 • PHYSICAL APPEARANCE Odor none none none none none none Apparent Color clear turbid gray milky gray clear • LABORATORY DATA Lab pH Total Phosphorus, P (mg/t) Fluoride, F (mg/1) Chloride, CI (mg/1) Sulfate, SO4 (mg/1) 5.7 6.8 7.6 7.1 7.5 7.4 0.299 0.131 0.025 0.614 0.208 0.298 0.61 0.26 0.28 0.31 0.785 0.604 56 52 53 54 52 55 292 59 58 57 70 77 Total Dissolved Solids, TDS (mg/I) 554 526 528 596 484 560 Total Organic Carbon, TOC (mg/1) 6 3 4 4 4 4 Table 2-4 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MWTF-2A Parameter Sampling Date 1/89 4/89 7/89 10/89 1/90 4/90 • HELD DATA Specific Conductance (µmhos/cm) at Field Temperature 1370 2650 1350 1475 1800 1650 Corrected to 25°C 1603 3074 1364 1534 2142 pH 6.4 6.9 6.0 6.2 6.5 6.1 Water Temperature (°C) 16.5 17 24.5 23 15.5 20 Water Level, feet (MSL) 6.82 6.94 5.25 7.0 7.41 6.35 Gallons Purged Before Sampling 5.5 6.5 5.0 5.0 5.75 4.30 • PHYSICAL APPEARANCE Odor none none none none none none Apparent Color clear milky clear clear clear clear • LABORATORY DATA Lab pH 6.3 6.9 6.3 6.4 7.0 6.7 Total Phosphorus, P (mg/1) 0.090 0.156 0.204 0.241 0.048 0.038 Fluoride, F (mg/1) 0.15 0.259 0.14 0.15 0.181 0.237 Chloride, CI (mg/1) 71 62 66 64 50 54 Sulfate, SO4 (mg/l) 357 1091 259 282 638 520 Total Dissolved Solids, TDS (mg/I) 1106 2339 840 1130 1528 1300 Total Organic Carbon, TOC (mg/1) 12 12 9 16 9 30 1 Table 2-5 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MWTF-2B Sampling Date Parameter 1/89 4/89 7/89 10/89 1/90 4/90 • FIELD DATA Specific Conductance (µmhos/cm) at Field Temperature 2200 2300 2410 2410 2490 2220 Corrected to 25°C 2486 2622 2579 2627 2789 pH 6.4 6.6 6.2 6.2 6.3 6.0 Water Temperature (°C) 18.5 18 21.5 20.5 19 18.5 Water Level, feet (MSL) 4.95 4.66 4.30 4.99 5.18 3.84 Gallons Purged Before Sampling 8.5 9.5 8.0 8.8 9.0 9.5 • PHYSICAL APPEARANCE Odor none none none none none none Apparent Color clear light milky clear clear clear rusty • LABORATORY DATA Lab pH Total Phosphorus, P (mg/1) Fluoride, F (mg/1) Chloride, CI (mg/1) Sulfate, SO4 (mg/1) 6.3 6.6 6.7 6.3 6.8 6.7 92.0 47.2 57.6 93.2 95.0 131.5 1.96 1.81 1.07 1.41 1.41 1.43 376 321 287 254 222 209 270 444 351 490 528 418 Total Dissolved Solids, TDS (mg/l) 1212 1580 1700 1590 1520 1590 Total Organic Carbon, TOC (mg/1) 12 8 9 10 12 10 Table 2-6 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MW TF-2C Sampling Date Parameter 1/89 4/89 7/89 10/89 1/90 4/90 • FIELD DATA Specific Conductance (µmhos/cm) at Field Temperature 2300 2300 2350 2200 2300 2310 Corrected to 25°C 2576 2576 2562 2442 2576 - pH 6.3 6.5 6.0 6.2 6.2 6.0 Water Temperature (°C) 19 19 20.5 19.5 19 20 Water Level, feet (MSL) -1.85 -0.45 -1.06 +0.18 +0.20 -0.40 Gallons Purged Before Sampling 16.0 16.0 16.0 16.5 16.75 19.0 • PHYSICAL APPEARANCE Odor none none none none none none Apparent Color clear clear clear clear clear clear • LABORATORY DATA Lab pH 6.3 6.5 6.5 6.4 6.7 6.5 Total Phosphorus, P (mg/1) 12.80 16.55 17.35 20.55 19.25 18.9 Fluoride, F (mg/1) 0.17 0.16 0.17 0.15 0.17 0.225 Chloride, Cl (mg/1) 78 75 78 76 75 78 Sulfate, SO4 (mg/1) 882 884 857 811 851 888 Total Dissolved Solids, TDS (mg/1) 2308 2272 2430 2300 2200 2230 Total Organic Carbon, TOC (mg/1) 13 11 12 11 12 12 Table 2-7 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MWTF-3A Sampling Date Parameter 1/89 4/89 7/89 10/89 1/90 4/90 • FIELD DATA Specific Conductance (µmhos/cm) at Field Temperature 1250 1400 1500 1400 1325 1400 Corrected to 25°C 1375 1540 1455 1316 1458 pH 5.7 5.7 5.7 5.5 5.3 5.2 Water Temperature (°C) 20 20 26.5 28 20 21.5 Water Level, feet (MSL) 7.45 7.57 7.15 7.24 7.67 6.38 Gallons Purged Before Sampling 5.2 8.0 6.0 5.0 6.0 6.5 • PHYSICAL APPEARANCE Odor none none sulfur none none none Apparent Color clear particles clear clear clear clear • LABORATORY DATA Lab pH 5.8 6.1 6.2 5.8 6.1 6.0 Total Phosphorus, P (mg/1) 0.240 0.172 0.257 0.395 0.15 0.146 Fluoride, F (mg/1) 0.145 0.135 0.15 0.14 0.130 0.197 Chloride, Cl (mg/1) 283 322 324 324 321 313 Sulfate, SO4 (mg/1) 92 107 94 132 174 226 Total Dissolved Solids, TDS (mg/l) 786 896 700 800 812 856 Total Organic Carbon, TOC (mg/1) 11 8 6 5 5 9 1 Table 2-8 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MWTF-3B Sampling Date Parameter 1/89 4/89 7/89 10189 1/90 4/90 • FIELD DATA Specific Conductance (jimhos/cm) at Field Temperature 2080 2100 2250 2100 2450 2525 Corrected to 25°C 1914 1911 2003 1785 2205 pH 6.0 6.0 5.9 5.9 5.7 5.8 Water Temperature (°C) 29 29.5 30.5 32.5 30 30 Water Level, feet (MSL) 3.13 3.67 3.37 4.12 3.91 3.24 Gallons Purged Before Sampling 11.0 13.5 10.0 10.5 10.5 12.5 • PHYSICAL APPEARANCE Odor none none none none none none Apparent Color clear particles clear clear clear It. yellow • LABORATORY DATA Lab pH 6.0 6.2 5.8 6.1 6.5 6.3 Total Phosphorus, P (mg/1) 97.5 100.3 86.8 123.5 143.5 145.3 Fluoride, F (mg/I) 0.18 0.186 0.18 0.15 0.151 0.231 Chloride, CI (mg/1) 91 108 112 111 124 129 Sulfate, SO4 (mg/1) 504 515 517 588 574 613 Total Dissolved Solids, TDS (mg/1) 1146 1533 1365 1480 1776 1800 Total Organic Carbon, TOC (mg/1) 7 8 8 8 8 12 1 Table 2-9 GROUNDWATER QUALITY IN TANK FARM AREA AT MONITOR WELL MWTF-3C Sampling Date Parameter 1/89 4/89 7/89 10/89 1/90 4/90 • FIELD DATA Specific Conductance (µmhos/cm) at Field Temperature 2510 2500 2580 2510 2500 2450 Corrected to 25°C 2410 2325 2348 2359 2350 pH 6.3 6.2 5.9 6.2 6.0 6.0 Water Temperature (°C) 27 28.5 29.5 28 28 29 Water Level, feet (MSL) -2.61 -0.22 -1.32 +0.13 +0.12 -0.53 Gallons Purged Before Sampling 17.5 18.5 18.0 18.5 20.5 21.0 • PHYSICAL APPEARANCE Odor none none sulfur none none none Apparent Color rusty clear milky clear clear clear • LABORATORY DATA Lab pH 6.3 6.4 6.3 6.4 6.7 6.6 Total Phosphorus, P (mg/1) 20.20 28.20 25.70 14.10 29.40 28.8 Fluoride, F (mg/1) 0.14 0.119 0.10 0.08 0.086 0.128 Chloride, CI (mg/1) 87 98 98 97 99 98 Sulfate, SO4 (mg/I) 659 671 612 612 587 589 Total Dissolved Solids, TDS (mg/l) 2018 2002 2140 1870 1980 1830 Total Organic Carbon, TOC (mg/1) 11 10 10 9 9 4 i Table 2-10 GROUNDWATER QUALITY IN CASTLE HAYNE AQUIFER AT UTILITY WELL FERT-1 Sampling Date Parameter 1/89 4/89 7/89 10/89 1/90 4/90 • FIELD DATA Specific Conductance (µmhos/cm) at Field Temperature 1320 1380 1500 1400 1400 1425 Corrected to 25°C 1452 1518 1500 1526 1540 pH 7.0 7.2 7.4 7.0 7.1 6.9 Water Temperature (°C) 20 20 25 20.5 20 20 Water Level, feet (MSL) x x x x x x Gallons Purged Before Sampling * * * * 15.0 * • PHYSICAL APPEARANCE Odor none none none none none none Apparent Color clear clear clear clear clear clear • LABORATORY DATA Lab pH Total Phosphorus, P (mg/1) Fluoride, F (mg/1) Chloride, CI (mg/1) Sulfate, SO4 (mg/1) 7.1 7.3 7.6 7.3 7.7 7.5 0.030 0.100 0.043 0.160 0.094 0.012 0.66 0.59 0.63 0.61 0.60 0.671 290 290 303 299 297 308 9 10 5 8 6 10 Total Dissolved Solids, TDS (mg/1) 888 796 760 848 950 844 Total Organic Carbon, TOC (mg/1) 5 5 5 5 5 4 *Pump on well was running at time of sampling. � 11 2 w 10 9 8 7 6 5 to r o 3A i O? 111111■111u11111111Nu■I• M■■■ 1989 1990 SURFICIAL SOILS 10 co i u 9 8 7 6 5 0 w 3 — 1 B 2B / r Al. A /' �.l' •' Q,: J7.. Or 1 .D— 3B 11111111111 11111111111 1990 1989 CONFINED SAND LAYER -.! w 0 -1 -2 -3 z -4 5 o o• 'o /. /'o /' �2C a o1C 0 111111111 11111111111 1990 1989 CROATAN FORMATION AQUIFER WATER LEVELS VS. TIME I♦'* Ardaman & Associates, Inc. Comsatiq ENmors M iris. NYkMsNy. ForrYtirrs. red Mrlwws Tot* TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA DRANK SY• KJS (CRICKED BY ' ,11\ !DATE 7-118840 FILE NO. APPROVE SY crnrrn c n r WATER LEVEL ELEVATION (FEET, MSL) 0 10 20 -10 -20 Z 0 Q -30 W J W -40 _-----, I 41$ //ZA\\\ //c\\\ FINE SAND TO CLAYEY FINE SAND ) A / 0257,-"Ac" , B FINE SAND i / / - \ CLAYEY\\\\ CLAYEY TO SILTY , C FINE SAND AND SHELL FRAGMENTS (CROATAN Fm) Cal�q i 1 ali MONITOR WELL CLUSTER MWTF-3 WATER LEVEL ELEVATION (FEET, MSL) -10 0 10 20 20 10 0 -10 -20 -30 -40 `— — _, I FINE SAND TO CLAYEY FINE SAND FINE SANDlif / IB/CLAYEY SLIGHTLY SILTY/ FINE SAND / / / NN,`\\\\\\ CLAYEY FINE \SAND WITH SHELL FRAGMENTS \ \\\\\\\ I i i I 1 SLIGHTLY CLAYEY TO A„.. C CLAYEY FINE SAND AND SHELL FRAGMENTS (CROATAN Fm) MONITOR WELL CLUSTER MWTF-2 WATER LEVEL ELEVATION (FEET, MSL) 20 10 0 -10 -20 -30 -40 -10 0 10 20 A FINE SAND I CL YEl(FINE SANDZ To PLASTIC cuv B SILTY FINE SAND f / / / \\\\\\\\ CLAYEY FINE SAND. TO PLASTIC CLAY \ \ WITH SHELL FRAGMENTS \W\\\\\\\\, II _ IT`�z' CLAYEY TO SLIGHTLY ' C SILTY FINE SAND AND SHELL FRAGMENTS (CROATAN Fm) //(YORKTOWN F ►N// MONITOR WELL CLUSTER MWTF-1 SYMBOL DATE OF MEASUREMENT O • 0 ■ ♦ JANUARY 1989 APRIL 1989 JULY 1989 SEPTEMBER 1989 JANUARY 1990 APRIL 1990 AQUIFER WATER LEVELS VS. DEPTH 111111,1111 Ardaman i Associates, Inc. c Eie/Mas is Seib, NYMMesiMN. Fsw.Mlisss, sad Alston: s Testis, TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA DRAW BY FILE NO ss-099 KJS �CI+ECKEO By �I ifl 1 DATE 7-1s-90 N24568 rim 113C o_i; N 88+00 EDGE OF ASPHALT , CROATAN FORMATION PAVEMENT MONITOR WELL MWTF-3C DRAINAGE DITCH 8 M w 1 CROATAN FORMATION PUMPING WELL CPW 8 co w FLASH TANKS 3.8' 0'1 CROATAN FORMATION OBSERVATION WELL COW 10' N 87+00 8 w NORTH PUMPING TEST CROATAN FORMATION PUMPING WELL MWTF-1 D CROATAN FORMATION MONITOR WELL MWTF-1 C SOUTH PUMPING TEST 8 w -i-- N 83+00 LAYOUT OF CROATAN FORMATION PUMPING TESTS I♦ Ardaman & Associates, Inc. Cowolbq En*nows ni Soik, MYhegeMoly, Foonirtau, Noi Mean* Test* TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA DRAWN ev ,LE N4 88-089 ROE ICNECKEO •Y IDAT 7-18-90 Nis FIGURE 2-7 z 8 8-Z 3df1OId 0-0 2 10 12 0 2 4 W 6 U. ( 8 10 • • • 1 2 - • 0 5 10 t (minutes) 15 000 0 0 0 0 0 0 0 0 00 0 O T 1 1 1 I I i f r 0 z w 0 0 0 00 0 0 0 1000 2000 3000 TIME SINCE START OF PUMPING, t (minutes) DRAWDOWN VS. TIME AT TEST WELL CPW FOR PUMPING RATE OF 2 GAL/MIN czc� 6-3 31:111OId 0- 1 Elk 2 —L LL Cri 3 Z O 0 4- Cbt - 0 0 0 0 �CO 0 0 ° s • • • • • • • • • 5 6 7 r 0 OBSERVATION WELL MWrF3C RADIUS = 35.5' • •• • • > 0 0 00 o0 OBSERVATION WELL COW RADIUS = 10.0' 1000 00 x 2 ri0 D a LL O 0 2 1 1 1 1 2000 3000 TIME SINCE START OF PUMPING, t (minutes) DRAWDOWN VS. TIME AT OBSERVATION WELLS COW AND MWTF-1C FOR PUMPING RATE OF 2 GAL/MIN AT TEST WELL CPW o I-z 3811Oid 8 6 W LL u) 4 0 0 0 2- 0 O Fyi 1 1 1 1 1 1 1 1 1 I 11 1 1 1 1 1 I 1 1 1 1 1 1 10 100 1000 3000 TIME SINCE START OF PUMPING, t (minutes) 0 0 0 000 0 0 OBSERVATION WELL COW RADIUS = 10.0' o 0 0. 000 OBSERVATION WELL MWTF-3C RADIUS=35.5' DRAWDOWN VS. LOG TIME AT OBSERVATION WELLS COW AND MWTF-3C FOR PUMPING RATE OF 2 GAL/MIN AT TEST WELL CPW < <-z 37:111OIJ 0 6 7 - OBSERVATION - WELL MWTF•IC RADIUS = 10.5' • • • • • • 0 • • j • 0 0 0 • • • • 0 0 TEST WELL MWTF-1 D • 1` 1000 I I I I 1 1 2000 3000 TIME SINCE START OF PUMPING, t (minutes) DRAWDOWN VS. TIME AT TEST WELL MWTF-1 D AND OBSERVATION WELL MWTF-1C FOR PUMPING RATE OF 3.4 GAL/MIN z l-z 3dfS1J DRAWDOWN, S (FEET) "nD 1 s» a o=3 m 7, 7 'Q, pe fit s co 1 a� 0 0.5 -. 1.5 OBSERVATION WELL MWTF-1C RADIUS = 10.5' J 0 O 0 0 O p 0 00O Op 0 QcboO 1 1 1 1 1 1 1 1 1 1 1 1 1111 1 1 11111 1 10 100 TIME SINCE START OF PUMPING , t (minutes) 1000 3000 DRAWDOWN VS. LOG TIME FOR OBSERVATION WELL MWTF-1 C FOR PUMPING RATE OF 3.4 GAL/MIN AT TEST WELL MWTF-1 D 8 W N 88+00 -I- DRAINAGE DITCH EDGE OF ASPHALT PAVEMENT CONFINED SAND LAYER / MONITOR WELL. MWTF3B a } A v a 1 CONFINED SAND LAYER OBSERVATION WELL SOW 9.r N 87+00 �-- CONFINED SAND LAYER PUMPING WELL SPW LAYOUT OF CONFINED SAND LAYER PUMPING TEST atiorls Ardaman & Associates, Inc. Committing Engineers in Ss* Hvereneelerf, Foundations, sal Mnsrisk Tasting TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA OBAWN BY. RBE 1 CHECKED BY. ¶ IDATE. 7-18-90 FILEpHOB� ! APPP VEO Y 8PV89 I Z• N3%95 FIGURE 2-13 tit-3 31:111OIJ 0 1 2 3 4 5 6 7 T' i i - igii > if Pidh 6 m w c RI Ps‘ .4° q bm ti gir, p gi ijj OBSERVATION WELL M4YTFB RADIUS = 34.6' O 0 8 g O p ,.D 8 8 0 0 • \IkO O OBSERVATION WELL SOW 00 O RADIUS = 9.7' O O 0 0 TEST WELL SPW S 0 0 o MN(3 ca _ AT t=14 1 I I I I T I I I I 1 I 0 1000 2000 TIME SINCE START OF PUMPING, t (minutes) DRAWDOWN VS. TIME AT TEST WELL SPW AND OBSERVATION WELLS SPW AND MWTF-3B FOR PUMPING RATE OF 4.3 GAL/MIN 3000 Texasgulf Inc. File Number 88-089 3-1 Section 3 ENGINEERING PROPERTIES OF IN SITU SOILS AND SOIL-BENTONITE BACKFLLL MIXES This section addresses the engineering properties of in situ soils within the undifferentiated surficial deposits and Croatan formation of interest relative to the design and performance of the _ remedial action system, and of the soil-bentonite backfill mix that will be used to construct the cut-off wall. 3.1 Engineering Properties of Undifferentiated Surficial Deposits The undifferential surficial deposits consist of a layered sequence in ascending order of a lower confining unit, confined sand layer, upper confining unit, and a surficial layer of generally sandy soils. 3.1.1 Lower Confining Unit The soil-bentonite cut-off wall will be keyed a minimum of 3 feet into a relatively impervious clayey fine sand to sandy clay layer at the base of the undifferentiated surficial deposits. The properties of this layer of interest relative to the cut-off wall construction are presented below. 3.1.1.1 Classification and Index Properties. The lower confining unit along the cut-off wall is generally a dark brown to dark gray or greenish -gray clayey fine sand occasionally with some shell fragments, thin lenses of fine sand or thin lenses of plastic clay. Index properties measured on ten undisturbed Shelby tube or split -spoon samples recovered from the lower confining unit are presented in Table 3-1. As shown, the natural moisture content varies from 28 to 49% with an average of 40±6%, and the fines content (i.e., soil fraction by dry weight finer than the U.S. Standard No. 200 sieve) varies from 18 to 47% with an average of 30.4±9.2%. Typical particle size distribution curves from six samples of the clayey sand, representing a range in fines content from 18 to 45%, are presented in Figure 3-1. The in situ dry density measured on six undisturbed samples recovered from the lower confining unit ranged from 76.0 to 82.2 lb/ft3 with an average of 79.3 lb/ft3. The Atterberg limits determined on seven samples of clayey sand are presented in Table 3-1 and graphically summarized in Figure 3-2. As shown, the Atterberg limits are characteristic of CL- to CH -type lean to plastic clays, which considered with the fines contents of 18 to 47% indicate the soils are classified as SC -type clayey sands in accordance with ASTM D 2487 "Classification of Soils for Engineering Purposes". 3.1.1.2 Coefficient of Permeability. The results of four constant -head permeability tests performed on undisturbed samples of clayey sand from the lower confining unit are presented in Table 3-2. As shown, the vertical coefficient of permeability is relatively low for all four test specimens, ranging from 6.8x10-8 to 2.2x10-7 cm/sec with an average of 1.4x10-7 cm/sec. The vertical coefficient of permeability backfigured from one-dimensional consolidation tests over the load increment near the in situ effective vertical consolidation stress are also presented in Texasgulf Inc. File Number 88-089 3-2 Table 3-2 (see Figures 3-3, 3-4 and 3-5). The backfigured vertical coefficients of permeability are in good agreement with the measured coefficients of permeability, indicating a representative value of 1.4x101 cm/sec from the three test specimens. 3.1.1.3 Consolidation Characteristics. The results of three one-dimensional incremental consolidation tests on samples of clayey sand from the lower confining unit obtained from soils with penetration resistances of 0 to 10 blows/foot are presented in Figures 3-3, 3-4 and 3-5.* As shown, the soils were characterized by compression ratios (corrected by the Schmertmann (1955) procedure) of 0.18 to 0.28 and recompression ratios of 0.009 to 0.020 both of which increased, as expected, with increasing plasticity index. The lower confining unit is slightly overconsolidated, with overconsolidation ratios ranging from 1.9 to 3.7. 3.1.1.4 Undrained Shear Strength. The lower confining unit is very soft along a portion of the cut-off wall alignment between borings TF-105 and TF-107 with Standard Penetration Test resistance values of less than 2 blows/foot. One unconfined compression test performed on a sample recovered from boring TF-103 in clayey sand with a penetration resistance of about 2 blows/foot yielded an undrained shear strength of 350 lb/ft2. Undrained shear strengths measured with a hand-held laboratory vane on other undisturbed samples of clayey sand from the lower confining unit ranged from 200 to 750 lb/ft2 for samples in soils with penetration resistances of 0 to 2 blows/foot. For a representative effective vertical consolidation stress in the lower confining unit of about 1600 lb/ft2, a minimum undrained shear strength of about 400 lb/ft2 is expected, which agrees with the measured values. 3.1.2 Confined Sand Layer The confined sand layer along the north wall of the tank farm where the withdrawal wells will be installed consists of a gray to brown medium to fine sand to silty fine sand. The natural moisture content ranges from 17 to 32% with an average of 21%, and the fines content varies from 3 to 16% with an average of 7% from eight determinations. As shown in Figure 3-6, the soils in the confined sand layer are poorly graded, and based on the fines content of 3 to 16% classify as poorly graded sand, poorly graded sand with silt (slightly silty sand), and silty sand in accordance with ASTM D 2487 "Classification of Soils for Engineering Purposes". 3.1.3 Upper Confining Unit The upper confining unit is comprised of brown to gray clayey fine sands to plastic clays. The clayey fine sands display natural moisture contents ranging from 29 to 53% with an average of 35%, and fines contents of 22 to 47% with an average of 31% from five determinations. The natural moisture content of the clays varied from 43 to 80% with an average of 68%, and fines content varied from 50 to 98% with an average of 79%. The liquid limit and plasticity index of the clays typically varied from 88 to 102% and 52 to 75%, respectively, characteristic of CH -type fat (plastic) clays to sandy fat clays when classified in accordance with ASTM D 2487. 3.1.3.1 Consolidation Characteristics. The results of two one-dimensional incremental consolidation tests on samples of a lean sandy clay and fat (plastic) clay from the upper confining * Consolidation tests were performed to estimate surface settlements in the tank farm due to groundwater withdrawals from the confined sand layer. Texasgulf Inc. File Number 88-089 3-3 unit are presented in Figures 3-7 and 3-8. As shown, the soils were characterized by compression ratios of 0.13 for the lean sandy clay to 0.34 for the plastic clay, and corresponding recompression ratios of 0.012 to 0.031. The samples were slightly overconsolidated, both with overconsolidation ratios of 2.3. 3.1.3.2 Undrained Shear Strength. The upper confining unit is very soft along portions of the cut-off wall alignment with Standard Penetration Test resistance values of less than 2 blows/foot, for which an undrained shear strength of less than 250 Ib/ft2 is expected. One unconfined compression test performed on an undisturbed sample recovered from boring TF-103 in a clay with a somewhat higher penetration resistance of 3 blows/foot yielded an undrained shear strength of 510 lb/ft2. This value is in general agreement with the expected undrained shear strength for the sample based on the in situ effective vertical consolidation stress of 1180 lb/ft2 and overconsolidation ratio of 2.3 determined on the consolidation test sample (Figure 3-8). 3.1.4 Surficial Soils The surficial soils are variable, and consist of fine sands to clayey fine sands classifying as SP, SP-SM, SM, SP-SC and SC -type soils in accordance with ASTM standard D 2487. The natural moisture content of the surficial soils below the water table varied from 20 to 36% with an average of 23%. The fines content varied from 8 to 28% with an average from 19 samples of 18%. This average fines content is characteristic of SM-type silty to SC -type clayey fine sands. 3.2 Engineering Properties of Croatan Formation The Croatan formation generally consists of clayey fine sand to fine sand and shell fragments occasionally with cemented sand. The proportion of shell fragments in the samples was variable, but was estimated to be as high as 55% by dry weight. The natural moisture content varied from 17 to 37% with an average of 28%, and the fines content from 29 samples varied from 6 to 39% with an average of 17%. A summary of the particle size distribution of the Croatan formation soils from twelve samples is presented in Figure 3-9, and the individual particle size distribution curves are presented in Figures 3-10 through 3-14. As shown, the formation is typically comprised of fine gravel to fine sand size shell fragments and clayey to silty fine sands with particle sizes ranging from 25 mm to less than 0.074 mm (the U.S. Standard No. 200 sieve). The formation, however, can also contain lenses of slightly silty fine sand with traces of shell fragments. 3.3 Soil-Bentonite Backfill Mixes Soil-bentonite backfill mixes were prepared from soil samples recovered from borings B-1 and MWTF-2 to evaluate the bentonite content required to achieve the design backfill coefficient of permeability of less than 1x104 cm/sec. 3.3.1 Soil Backfill Characteristics Soils along the alignment and within the depth of penetration of the cut-off wall will vary widely from fine sands to plastic clays with fines contents varying from 4% to 93%. At each boring location the following overall average fines contents are expected for the soil backfill after thoroughly mixing the soils within the depth of penetration of the cut-off wall. Texasgulf Inc. File Number 88-089 3-4 Boring Approximate Penetration Depth of Cut -Off Wall (feet) Expected Backfill Fines Content (%) B-1 27 17 MWTF-2 24 22 B-2 27 23 MWTF-3 31 37 TF-105 29 22 B-3 32 27 TF-106 25 20 As shown, the overall average fines contents vary from 17% at boring B-1 where the soils consist largely of fine sands to silty fine sands, to 37% at boring MWTF-3 where a 9-foot thick plastic clay layer with fmes contents of 53 to 93% is encountered within the depth of penetration of the cut-off wall. The average backfill fines content projected for the six boring locations equals 24%. Based upon the expected backfill fines contents, borings B-1 and MWTF-2 were selected as representative of the minimum and average fines content likely to occur in soil available for backfill, respectively. Backfill samples for testing were prepared by combining the upper eight split -spoon jar samples in proportion by dry weight of each soil type within the depth to be penetrated by the cut-off wall at each boring (i.e., about 27 feet at boring B-1 and 24 feet at boring MWTF-2), and then thoroughly mixing the soils into a homogeneous soil backfill. After mixing, the soil backfill samples were visually classified and the fines contents determined as follows: Boring Soil Backfill Description Fines Content (%) B-1 Brown silty medium to fine sand with trace fine shell fragments (SM) 15 MWTF-2 Brown clayey fine sand with trace fine shell fragments (SC) 25 3.3.2 Characteristics of Bentonite Product Wyo-Ben Hydrogej bentonite, a sodium montmorillonitic clay manufactured by Wyo-Ben, Inc. for slurry trench applications, was used in preparing the soil-bentonite backfill mixes. The Wyo-Ben Hydrogel bentonite had an as -received moisture content of 8.5%, and Atterberg limits consisting of a plastic limit of 36%, liquid limit of 495% and plasticity index of 459%. These Atterberg limits, as expected, are characteristic of a highly plastic clay, and as shown on Figure 3-15 are consistent with the Atterberg limits typically found for bentonites used in slurry trench applications. Texasgulf Inc. File Number 88-089 3-5 3.3.3 Coefficient of Permeability of Soil-Bentonite Backfill Mixes The coefficient of permeability of each soil backfill with varying quantities of Wyo-Ben Hydrogel bentonite are summarized in Table 3-3 and in Figure 3-16. As shown, the addition of bentonite decreases the soil backfill coefficient of permeability by 3 to 4 orders of magnitude from an estimated initial value (without bentonite) on the order of 1x104 cm/sec to about 4x104 cm/sec with 5 to 6% bentonite (dry weight basis). To achieve the design soil-bentonite backfill coefficient of permeability of less than 1x104 cm/sec, a bentonite content of about 3.5 to 4.5% will be _ required for the soil backfill. The particle size distribution of three of the permeability test specimens are presented in Figure 3-17. Texasgulf Inc. File Number 88-089 3-6 Table 3-1 INDEX PROPERTIES OF LOWER CONFINING UNIT Boring Approximate Depth to Top of Key -In Stratum (feet) Index Properties NM (%) 200 (%) LL (%) PL (%) PI (%) B-1 24 28 37 32 15 17 MWTF-2 21 35 28,31 x x x B-2 24 43 35 53 14 39 MWTF-3 28 40 19,28 x x x TF-105 26 37,43 22,24 42 20 22 TF-106 22 37 45 45 18 27 TF-102• 24 44 37,38 67 15 52 TF-103• 28 40 18,21,35 51 15 36 TF-104• 22 49 21 x x x PS-2•• 25 43 47 53 20 33 Where: NM = natural moisture content; -200 = fines content; LL = liquid limit; PL = plastic limit and PI = plasticity index. • Borings TF-102, TF-103 and TF-104 are nearby, but not actually on the cut-off wall alignment (see Figure 2-1). **Boring PS-2 is not on the cut-off wall alignment, but is located at the east end of the drainage ditch at coordinates N8762-E13,700. This boring was drilled for Badger Design & Constructors, Inc. for the design of a pumping station as part of the water management system. Texasgulf Inc. File Number 88-089 3-7 Table 3-2 PERMEABILITY TEST RESULTS ON LOWER CONFINING UNIT Boring Sample Depth (feet) Initial Conditions Final Conditions a (i'f) 200 (%) (��) wi (%) Yd (pcf) wf (%) Yd (Per) • k,, Measured from Permeability Tests TF-102 US-2 27.0-29.0 54.0 69.3 54.3 69.3 1008 37.5 2.2x10"7 TF-103 US-2 30.0-32.0 44.2 79.5 42.8 78.7 1008 34.8 1.5x10"7 TF-104 US-1 24.5-26.5 37.9 87.0 33.8 90.4 1008 21.1 6.8x10-8 TF-106 US-1 25.0-27.0 36.3 83.8 35.9 84.5 1008 45.3 1.2x10-7 • k,, Backfigured from Consolidation Tests' TF-102 US-2 27.0-29.0 53.5 68.3 x 68.9t 16121* 38.4 1.1x10-7 TF-103 US-2 30.0-32.0 40.6 72.1 x 73.0t 1612•• 21.0 1.7x10-7 TF-105 US-1 27.5-29.5 35.2 84.9 x 85.9t 1612" 22.2 1.5x10-7 Where: wi = initial moisture content; wf = final moisture content; yd = dry density; o, = isotropic effective consolidation stress; -200 = fines content; k,, = vertical coefficient of permeability.. * Vertical coefficient of permeability backfigured from relationship k„ = c„m<yR„ where c„ and m„ are the coefficient of consolidation and coefficient of volume change determined from the consolidation test for the load increment of interest and yW is the unit weight of water. * • Vertical coefficient of permeability calculated for load increment of 806 to 1612 psf. The estimated to 1780 in situ effective vertical stress for the test specimens was in the range of 1580 psf. t Dry density of test specimen at end of 1612 psf load increment. Texasgulf Inc. File Number 88-089 Table 3-3 PERMEABILITY TEST RESULTS ON SOIL-BENTONITE BACKFILL MIXES Sample Bentonite Content (%) Initial Conditions Final Conditions °c (Pst -200 (%) kv (cm/sec) wi (%) Yd (pci) wt. (%) Yd (pcl) B-1 2 23.1 99.8 17.3 110.3 360 - 7.8x10.7 B-1 4 25.4 97.9 23.1 102.7 0' 16.7 1.5x1(17 B-1 6 24.5 97.3 22.0 104.2 360 17.6 3.9x10-8 MWTF-2 2 27.5 94.4 19.4 110.5 360 - 4.4x10'7 MWTF-2 5 26.4 94.6 23.4 100.9 360 333 2.8x104 Where: wi = initial moisture content; wr = final moisture content; yd = dry density; v, = isotropic effective consolidation stress; -200 = fines content; and 1t1, = vertical coefficient of permeability. `Coefficient of permeability determined on sample in rigid wall permeameter without isotropic effective consolidation stress. All other coefficients of permeability determined on samples in flexible wall permeameters with indicated isotropic effective consolidation stress. 3-8 U.S. STANDARD SIEVE SIZE WI N — i..1 & 2 9 2 2 2 222 ) t . , 1 90 1 4 4 4 1 .., 80 44 1 I 4 1 l• 4:11 di 1 la A It* •- x 70 4 r i i -+ a 1 f + 1 CD La so • t . 4 t 0 ... r 0 ..4 # o to cr 5O i 4 4 4 1 V i cy 4 It a .4 W i7. 40 i t .4 I t 4. $ 4.) 4 44 I 1— lyl 30 1 it 4 1 .4. 1 ti t 4 * A 0 CC tal 20 4 1 1 t 1 .., E 0 Q. 10 I I- rt 1 I t t I* 180 10 1.0 GRAIN 0 SIZE IN MILLIMETERS I 0.01 0.00 I GRAVEL SAND COARSE j FINE COARSE 1 MEDIUM i F INE SILT CLAY TEST HOLE NQ SAMPLE NO. DEPTH SYMBOL SAMPLE DESCRIPTION UNIFIED CLASS. TF-102 US-2 27.0'-29.0' • DARK GRAY CLAYEY FINE SAND SC TF-103 US-2 30.0.-32.0' 0 DARK GRAY CLAYEY FINE SAND (3 TEST SAMPLES) SC TF-104 US-1 24.5.-26.5 • DARK GREENISH -GRAY CLAYEY FINE SAND WITH SC CLAY LENSES TF-106 US-1 25.0.-27.0' A DARK GREENISH -GRAY CLAYEY FINE SAND SC B-2 S-11 34.0%36.0' CI DARK GRAY CLAYEY MEDIUM TO FINE SAND SC TF-3 S-10 33.5'-35.0' • DARK GRAY CLAYEY FINE SAND SC PARTICLE SIZE DISTRIBUTION OF LOWER CONFINING UNIT ALONG CUT-OFF WALL ALIGNMENT Now li Ardaman & Associates, Inc. ...• ... eirmsenrig Emnivers ea Saki Hydropelegy. e TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA. NORTH CAROUNA CHECKED By ' ,i } DATE 7.1840 DRAVA. ," RBE , c' G t LE MO 88-089 .00110 4 / N3%95 FIGURE 3-1 PLASTICITY 70 10 SYMBOL BORING DEPTH (FEET) SAMPLE O B-1 24'-26S-8 O B-2 24'-26' S-9 p TF-105 27.5'-29.5' US-1 • TF-106 25'-27' US-1 • TF-102 27'-29' US-2 • TF-103 30'-32' US-2 7 PS-2 23.5'-25' S-8 f FINES CONTENT -200(%) 0 0 10 20 30 40 50 60 70 80 LIQUID LIMIT, LL(%) ATTERBERG LIMITS OF LOWER CONFINING UNIT ALONG CUT-OFF WALL ALIGNMENT 111111111r Ardaman & Associates, Inc. Consulting Engineers in Sods, Hydrogeoiogy, Foundations, and Materials Testing TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA N3%93 FIGURE 3-2 PRAWN R� RBE 'CHECKED BY T"i !DATE 7. 8_90 E'LE NO IAPv(COVED BY 88-089 Uvo UVM (SCHMERTMANhg VERTICAL STRAIN, E„ (%) 0.0 5.0 10.0 15.0 20.0 25.0 30.0 0.01 Z 2x10-2 O 1.5x10-2 0 in U Z Uc' 1x102 u_ U 0 0> 0.5x1 d-2 - W U LL 00 U L 1 1 1 INDla PROPERTIES -200=38% 1 LL=67% 1 PL=15% 1 1 Pi=52% 1 1 1 1 1 1 1 1 1 \31 1 1 1 1 0.1 10 100 BORING SAMPLE DEPTH (feet) NM (%I yt (PO e ° a„° (tifl iv"' (0) OCR CR CRe RR TF-102 US-2 27'-29' 44 110 1.457 0.77 2.8 3.5 0.27 0.28 0.020 Cv 001 01 10 100 EFFECTIVE VERTICAL CONSOLIDATION STRESS, &ye (T.S.F.) CONSOLIDATION TEST RESULTS FOR CLAYEY FINE SAND WITH SHELL FRAGMENTS FROM LOWER CONFINING UNIT 1x1041 1xio-10 Mir * Ardaman & Associates, Inc. Cnnialtini Envenoms in Sit. HYdrclinnsrl. ..;: Feelldxtw®1, gad MetRd! Testing TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA. NORTH CAROUNA N39695 FIGURE 3-3 DRAWN 9, RBE �Br IDATE 7_113..90 E..0 ro9 DYED wO89 l Uyo Q (SCHMERTMANN) VERTICAL STRAIN, E,, (%) 0.0 5.0 10.0 15.0 20.0 25.0 • 2x10-2 0 1.5x10 Z O H O E 1x10'2 IZ U 0.5x10-2 0 LL W O 0 0 e e� o�� e \ o INDEX PROPERTIES -200=21% LL=51% PL=15% P1=36% O 11 1 1 1 1 _ 1 1 1 1 0.01 01 10 100 BORING SAMPLEDEPTH NM ) (YPt e° OCR CR CR0 RR TF-103 US-2 30'-32' 40 114 1.09 0.83 1.6 1.9 0.19 0.22 0.015 001 txlo-t0 01 1 10 100 EFFECTIVE VERTICAL CONSOLIDATION STRESS, cT (T.S.F.) CONSOLIDATION TEST RESULTS FOR towArdarnan Associates, Inc. afgAreCoawloM Eupwwn wE $iil. ►MMMe1Nf�, CLAYEY FINE SAND WITH SEAMS OF `°tl�"""`""�"'AC1O°"' PLASTIC CLAY FROM LOWER CONFINING UNIT TE(ASTANK FARM GULF INC. E ACTION PLAN PHOSPHATE OPERATIONS AURORA. NORTH CAROUNA 1439695 OR. r RBE �8e 4 0p9 CHECKED !v , 1 FIGURE 3-4 Qv. Qvrw (SCHMERTMANN) VERTICAL STRAIN, E„ (%) 0.0 2.5 5.0 7.5 10.0 12.5 15.0 0.01 Z 4x10-2 0 0 0 3x10-2 Z OU N 2x10.2 0 cv U 1x10"2 LU 0 U tL 0 U o r' '0 01�� o e \ o ‘ INDEX PROPERTIES -200=22% - _ 1 1 0 1 LL=42% PL=19% PI=22% 1 1 11 t 01 1 0 1 1 1 0 0 o 0 01 10 100 BORING SAMPLE DEPTH (1�) NM (%) yt (Pci)(taf) so a� o�,l ( ) OCR CR CRc RR TF-105 US-1 27.5'-29.5' 37 111 0.963 0.87 3.2 3.7 0.14 0.18 0.009 0.01 kv 01 10 100 EFFECTIVE VERTICAL CONSOUDAT)ON STRESS, a (T.S.F.) CONSOLIDATION TEST RESULTS FOR CLAYEY FINE SAND FROM LOWER CONFINING UNIT Ix1o8 1x10 10 Row Ardaman & Associates. Inc. giawAti Committal Esposito to Sells, Mylrogeolo,y, Farmhouses, sad Algiers* Tram, TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA ORAWN R. RBE HF[KEDaV NJ%% FIGURE 3-5 88-089 U.S. 2 2= Z = a r, N ' h RI 0 100 J , i J STANDARD SIEVE SIZE o o 8 o o 0 a N 2 O 0 O 0 0 O Z 2 Z Z 2 Z it I , 90 a E t I 4 80 • • . E 4 0 1 E r t- = 70 4 4 / 1 1 N 4 I $ r W b0 . .. t$ 4 ♦ 4 E 1 m Cr 50 E E• 4 1 4 4 r' I I I. W Z 1-1.40 • • 0-- • 1 -� ♦ 1 s ‘1t- 1 Z W 30 I I N I. .1 r E e J U CC d 20 • •. I i 4 I 4 .E ., 10 • • • F : 1 4 0 � 4 '00 i0 i.0 0. GRAIN SIZE IN MILLIMETERS 0.01 0.001 GRAVEL SAND COARSE FINE COARSE i MEDIUM FINE SILT SILT TEST HOLE NQ SAMPLE NO. DEPTH SYMBOL SAMPLE DESCRIPTION UNIFIED CLASS. B-1 S-7 20.0'-21.0' 0 LIGHT BROWN FINE SAND SP B-2 S-8 20.0'-21.0' • DARK GRAY SLIGHTLY SILTY MEDIUM TO FINE SAND SP-SM TF-106 S-8 20.0'-22.0' o GRAY MEDIUM TO FINE SAND SP PARTICLE SIZE DISTRIBUTION OF CONFINED SAND LAYER ow is Ardaman & Associates, Inc. Consulting Engineers In Sods, Hydrogaotogy, Foundations, and Materials Testing TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORT�H�CAROUNA "A"" RBE ICNECKED KY f' y/1 !DATE 7-18..I90 FILE NO i niMAO AOOBYi N3%95 FIGURE 3-6 tivm (SCHMERTMANN) VERTICAL STRAIN, E„ (%) 0.0 5.0 10.0 15.0 20.0 4x102 0 O • 3x10 (n U Z O n U E 2x102— Li. O > U W 1x10-2 0 LL W 0 0 0 0.01 0.1 10 100 BORING SAMPLDEPTH E} NM (yP� ea OCR CR CR RR TF-102 US-1 18'-20' 31 119 0.986 0.54 1.25 2.3 0.10 0.13 0.012 0.01 01 10 100 EFFECTIVE VERTICAL CONSOLIDATION STRESS, U„c (T.S.F.) = 7 & Associates, Inc. CONSOLIDATION TEST RESULTS FOR I. Ardaman n. M ., ates,«ac. Fouwart ns, and Matsu& Team, LEAN SANDY CLAY WITH SEAMS OF SILTY SAND TANK FARM REMEDIAL ACTION PLAN FROM UPPER CONFINING LAYER TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA DRAWN ON ABE 1,kuko sr s IowTE 7.18_ 0 88-089 N39693 FIGURE 3-7 0.0 Qv0 -4 Uvwt (SCHMERTMANN) VERTICAL STRAIN, P„ (%) 5.0 10.0 15.0 20.0 25.0 30.0 35.0 - 40.0 - 1 x10-2 0 7.5x10-3 Z • to O -..1„, 5x10 u. O U LU 2.5x10-3 0 u. W 0 O 0 0.01 0.1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 10 INDEX PROPERTIES -200=96% LL=9696 PL=28% P1=68% 100 BORING SAMPLE DEPTH (feet) NM (%) yt (Pcf) a a1O OA om, OA OCR CR CRc RR TF-103 US-1 20'-22' 61 95.5 2.298 0.59 1.35 2.3 0.33 0.34 0.031 0.01 01 1 10 100 EFFECTIVE VERTICAL CONSOUDATION STRESS, cY (T.S.F.) CONSOLIDATION TEST RESULTS FOR PLASTIC CLAY FROM UPPER CONFINING UNIT w Ardaman & Associates, Inc. oneNCSfIWI1mi Ew art rvi SWs, Hydf°paotagy, Fevivi4trevis, avid Mnin h Tatting TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA oa.., .• RBE ICNECr<EOIV { 1°.rt 7-18-90 Gi8F8n�i089 ✓v N39695 FIGURE 3-8 PERCENT FINER BY WEIGHT 100 90 80 70 6 5 40 3 20 10 zz N/ N z In 0 U.S. STANDARD SIEVE SIZE 8 O 0 7 N 0 0 i z z z z 0 9 / 1 v1 � `N ... 4 1 , C a 1 , 1 — SLIGHTLY SILTY FINE TRACE SHELL FRAGMENTS SAND WITH 1 / t r + w r 1 .r r\ , (BORING TF-100, SAMPLE S-12) _ II r r 1 ri r F /`J\V1 41 4 I 44 1 11 1 1 1 1 r b - ii r r RANGE N PARTICLE S ZE • � • r _1 j i, 1 01 it1 • DISTRIBUTION FROM 11 SAMPLES WITH SHELL r e + • 1 r 41 FRAGMENTS COMPRISING ABOUT 30% TO 55% OF N 4 il0 11/ SAMPLE BY DRY WEIGHT r IN 11 I lr 1.0 GRAIN SIZE IN MILLIMETERS GRAVEL SAND C'OARSE FINE COARSE 44E01011 =IEEE 0.01 SILT 0.001 CLAY SUMMARY OF PARTICLE SIZE DISTRIBUTION OF CROATAN FORMATION SOILS 1111111, 112 Ardaman & Associates, Inc. K'w Cannibal Engineers in Sods, Hydroiaoiony, Mer .41 Foundations, and 'Arenas Trains TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA DRAWN et RBE CHECKED av 1 ,DATE 7-18-90 EILE NO 88-089 A0 V N 3%95 FIGURE 3-9 U.S. z = ♦ as N — en n 2 STANDARD SIEVE SIZE o o 8 0 N p;.; 8 O C N 2 2 2 2 2 2 2 90 r « G ' BO o r 1$ 4 ..Ft. M 4 E F— 4 0 r W 60 ► f l w 1 a r CO Cr 50 r 1 4 h 1 4 4 i 1 1 ? 11 40 ► ► 1 4 w 1 W �+:. e _ 1 0 4 ♦ 1 .+ H Z W 30 r 4 4 is 1 i Q 4 4 4 4 U Er d 20 .` Y a 1 ll 4 a a-•- a 1 .li 100 10 1.0 GRAIN 0 0.01 0.001 SIZE IN MILLIMETERS GRAVEL SAND CCAISE FINE COARSE MEDIUM riNE SILT CLAY TEST HOLE NQ SAMPLE NO. DEPTH SYMBOL SAMPLE DESCRIPTION UNIFIED CLASS. B-2 S-12 38.5'-40.0' 0 GRAY CLAYEY MEDIUM TO FINE SAND WITH SHELL SC FRAGMENTS AND CEMENTED SAND B-3 S-12 38.0'-40.0' • GRAY CLAYEY COARSE TO FINE SAND AND SHELL SC FRAGMENTS TF-2 S-11 33.5'35.0' O SHELL FRAGMENTS AND GRAY SLIGHTLY CLAYEY FINE — SAND WITH CEMENTED SAND (SHELL FRAGMENTS COMPRISE ABOUT 55% OF SAMPLE BY DRY WEIGHT AND RANGE FROM ABOUT 1 mm TO 25mm IN SIZE) PARTICLE SIZE DISTRIBUTION OF CROATAN FORMATION SOILS fisiff..-11 Ardaman & Associates, Inc. Consoling Engineers la Sods, Hydroa1ogy• 'p ' ' Foundations. and Maters is Tasting TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA GRAW. ROE ICNECKED 4Y. I OwIF 7-18-90 FOIE Yi: a AO DIl 88-089 I Z N39895 FIGURE 3-10 U.S. STANDARD SIEVE SIZE z Z f 0 0 0 0 0 p 8 N .4., N Z N1 N Z ,1 Ni 2 p Z 0 0 0 0 0 Z Z Z Z Z 00i. •1 1 90 •• + 80 4 • 1 1 S. • • M t $ 0 4— I TO • 4 t» • t fa -. 4 i 4 ll 60 4- , t i 4 4 C • 1• 1 1 M r co Q' 50 / n $ l I 4 t • t 4 4 t W Z _ CZ 40 la 4 4 4 1 �y "1 4 R 4 4 4 4 • 4— z W 30 •t:• 4 •4 •• t 4 4 4 14 cr laeL 20e t • ,. 1 4 N P 4 • $ F M Q A 0 10 + e 4 ,M 1 111 4 4— _j k • El 9 1 3 o-..+- — , 4 4 1 r - 1oo io L '0 0. 0.01 GRAIN SIZE IN MILLIMETERS 0.001 GRAVEL 1 SAND COARSE �,NE ECOARSE MEDRJH E,NE SILT CLAY TEST HOLE NO. SAMPLE N DEPTH SYMBOL SAMPLE DESCRIPTION UNIFIED CLASS. TF-3 S-11 38.5'-40.0' 0 GRAY CLAYEY COARSE TO FINE SAND AND SHELL SC FRAGMENTS TF-3 S-13 48.5'-50.0' • GRAY SIGHTLY SILTY COARSE TO FINE SAND AND SP-SM SHELL FRAGMENTS (SHELL FRAGMENTS COMPRISE ABOUT 38% OF SAMPLE BY DRY WEIGHT, RANGING FROM ABOUT 1 TO 20mm IN SIZE) TF-100 S-11 35.0'-36.5' 2, SHELL FRAGMENTS AND GRAY CLAYEY FINE SAND (SHELL FRAGMENTS COMPRISE ABOUT 53% OF SAMPLE BY DRY WEIGHT, RANGING FROM ABOUT 0.2 TO 25mm IN SIZE) PARTICLE SIZE DISTRIBUTION OF CROATAN FORMATION SOILS irarle Ardaman & Associates, Inc. . . .. .. Cl'Orni n� En*neen Io Seds, HydroWology, Foundations, and A4lrdt Testin1 TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA DRAWN , RB CHECKED BDATE 7-1 a.9Q E NC 88.089 1 4. By '1 N39695 FIGURE 3-11 U.S. STANDARD SIEVE SIZE b 4. o 0 0 0 0 a g oor ,„ N M pQ N 2 IA 2 Z 2 i 2 2 2 2 00 1 ♦ l J I. II1 1 1...90 N 4 • ♦ d lr ` 80 • 41 1 1 1- y I I. 1-4 ` r �` E 1 I 1- 70 M 1 • 4 k N Q 4 1 N • oz al• 60 I+ 1 .I I 144 r 1 11 ,1 1 / • o: 50 I I 1 M 1. 1 k 1 • 1 1 W Z u. 40 1 I 4 44 1 4 1 :.:., 1 _:.. 1 ` 1‘ $ 4 h Z 30 '• I •• 1 I 1 l 11 • 0 CIC a. 20 1 1 1 1 I 1 4 M 1 1 I • !0 1 1 1 rt Anr j z - y jb ♦ 4 f 14 00 10 1.0 GRAIN 0. SIZE IN MILLIMETERS 0.01 0.001 GRAVEL SAND COARSE FINE COARSE I MEDIUM FINE SILT CLAY TEST HOLE NQ SAMPLE NO. DEPTH SYMBOL SAMPLE DESCRIPTION UNIFIED CLASS. TF-100 S-12 40.0'-41.5' 0 GRAY SLIGHTLY SILTY FINE SAND WITH TRACE SHELL SP-SM FRAGMENTS TF-102 S-15 45.0'-46.5' • SHELL FRAGMENTS AND GRAY SUGHTLY CLAYEY FINE — SAND WITH CEMENTED SAND (SHELL COMPRISES ABOUT 54% OF SAMPLE BY DRY WEIGHT, RANGING FROM 0.2 TO 25mm IN SIZE) TF-103 S-12 40.0'-41.5' 0 GRAY CLAYEY COARSE TO FINE SAND AND SHELL SC FRAGMENTS (SHELL COMPRISES ABOUT 42% OF f SAMPLE BY DRY WEIGHT, RANGING FROM ABOUT 0.2 TO 19mm IN SIZE) PARTICLE SIZE DISTRIBUTION OF CROATAN FORMATION SOILS witarlo Ardaman & Associates, Inc. :'i; Consulting En*nien 1• Sods, Hydrogology, Foundations. and Materials Testing TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA DRAWN 8v KJS [HECKE08v !DATE 7-18-90 fI88./Ip� W-Voa R vE08 j . l N39695 FIGURE 3-12 U.S. z i a . E = Y N .- of Z 00 _:: I; d STANDARD SIEVE SIZE 0 0 $ o N r$ 0 p N p Q i 2 2 2 2 2 2 1 ( 1 90 1 1 1 1 1 1 0 �••• 80 4 4 1 4 1/ 0 CI 'J '6% 1 ), 1 1— 70 $ 4 4 1. .44. 1 11 1 - (.9 W 3 s0 ♦ 14 • 4 A 1 1 1 1 I CO ft 50 ♦I I w I 4 1 it 1 Ill 1 W 2 11 40 14 1 M 1 i i 4 g 4 I Y I- Z LAJ I • - H ♦ 4 / a f 030 cr a20 • 1 14 N 4 I.1 1 FI o 1 Y I + / I_ \II 0 L 1 I -` r 1 100 iL 10 1.0 0. GRAIN SIZE IN MILLIMETERS 0.01 0.001 GRAVEL SAND _OARSE ,,ME COARSE 1 U(DW 11 FINE SILT CLAY TEST HOLE NG SAMPLE NO. DEPTH SYMBOL SAMPLE DESCRIPTION UNIFIED CLASS. TF-104 S-13 45.0'-46.5' 0 GRAY CLAYEY MEDIUM TO FINE SAND AND SHELL SC FRAGMENTS WITH CEMENTED SAND ISHELL COMPRISES ABOUT 32% OF SAMPLE BY DRY WEIGHT, RANGING FROM 0.2 TO 10mm IN SIZE) TF-105 S-13 45.0'-46.5' • GRAY SLIGHTLY CLAYEY FINE SAND WITH TRACE SC SHELL FRAGMENTS TF-105 US-3 32.5'-34.5' GRAY CLAYEY COARSE TO FINE SAND WITH SHELL SC FRAGMENTS PARTICLE SIZE DISTRIBUTION OF CROATAN FORMATION SOILS amr.111 Andaman & Associates, Inc. ::`.' Ceinult'n* Enlneen 1R Soib. Hydro�edo�y, Foundatlom end Aletanh Tenin� TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA DRAWN tl, KJs 1 CHECKED e. _13iO*TE 7-18-90 .J — v eV v�8c - 1 N39695 FIGURE 3-13 U.S. STANDARD SIEVE SIZE z v o 0 0 0 o a g oo Ni o, ,0 N N - RI Ai Z T Z Z Z Z Z Z i00 ' 1 1 J J 1 1 1 l 1. i 9 BO 1• I 1 1 • '.. N 70 I r I 1 ,4 I 6 ... g I 1 1 44 1 C.9 W 60 ►• 1 1 ** .4 44 / 4 I I CO Cr 50 s e 4 4 4 1 j ^11 V a 1 1 A I W 2 CI 40 1• 1 1 I.. 1 1 4 Ii 1 g I 0 4 Z LiJ 30 ► 4 1 e I -i I 1 4 1 V Q d20 l e 14 AI I ! I 1 Q 1 13 ;ID1 • 1 r1 .4 4 N i 1 M • . iii Y i 1 , 1 100 10 1.0 GRAIN 0. SIZE IN MILLIMETERS 0.01 I 0.001 GRAVEL SAND COARSE .IRE COARSE 81E0108 FINE SILT CLAY TEST HOLE NO. SAMPLE NO. DEPTH SYMBOL SAMPLE DESCRIPTION UNIFIED CLASS. TF-106 S-11 30.0-31.5' 0 SHELL FRAGMENTS AND GRAY CLAYEY FINE SAND — (SHELL COMPRISES ABOUT 50% OF SAMPLE BY DRY WEIGHT, RANGING IN SIZE FROM 0.1 TO 19mm) TF-106 S-14 45.0-46.5' • SHELL FRAGMENTS AND GRAY SLIGHTLY CLAYEY FINE SAND — (SHELL COMPRISES ABOUT 55% OF SAMPLE BY DRY WEIGHT, RANGING FROM 0.1 TO 19mm IN SIZE) PARTICLE SIZE DISTRIBUTION OF CROATAN FORMATION SOILS SW * Ardaman & Associates, Inc. !1.�.�,,. Consulting Engineers In Seib. Hydrogeology, .... foundations. mil Materiels Testing TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA ORAWN or KJS !CHECK EDeT DATE 7-1&gp +-i/T1 Cil 88-089 APR E ev `- { ,"_` N3%95 FIGURE 3-14 PLASTICITY INDEX, PI(%) 800 700 600 500 400 300 200 100 0 — 0 ' 1 TYPICAL RANGE FOR SLURRY TRENCH BENTONITES 100 200 300 400 500 600 700 UQUID LIMIT, LL(%) ATTERBERG LIMITS OF WYO-BEN HYDROGEL BENTONITE 800 Ardaman & Associates, Inc. Cossetting Eagleson it Sock, HyMMslotiy. Forr/rtiens, mid MotwiMt Testing TANK FARM REMEDIAL ACTION PLAN TDCASGULF INC, PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA N3%95 FIGURE 3-15 DRAWN BY E LLpE�NO��� WW8O KJS ICNECREO BY I4 1 DAT 7-18-90 10 COEFFICIENT OF PERMEABILITY, cm/sec 105 10$ 10' SYMBOL SAMPLE -200 (%) B-1 15 MWTF-2 25 RANGE IN kh FOR SURFICIAL SOILS FROM IN -SITU PERMEABILITY TESTS FOR FINES CONTENTS OF 13 TO 22% A...--- INITIAL MOISTURE W, =23.1 CONTENT, % Yd =99.8 INITIAL DRY DENSITY, pcf W1 =27.5 Yd =94.4 Wi =25.4 Yd =97.9 Wt ar24.5 Yd =97.3 W; =26.4 Yd=94.6 0 1 2 3 4 5 6 7 BENTONITE CONTENT, % BENTONITE CONTENT VS. COEFFICIENT OF PERMEABILITY OF SOIL-BENTONITE BACKFILL MIXES Niar'U Andaman & Associates, Inc. ` t Commits*, Ewomen in Sods. Hydrogeology, f onndatient. and Materraa% Testing TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA. NORTH CAROLINA N3%9 FIGURE 3-16 PAWN 9, ,,LE �( ��N 8&)0QQ9 S CHECKED SY A/rN04E0 :5 PERCENT FINER BY WEIGHT 100 90 80 70 60 50 40 30 20 10 i z FO N 1 z z .- ern 1 1 o rn 2 U.S. STANDARD SIEVE SIZE o 0 0 o a Z 2 2 z 2 2 1 1 1 I w 4 0 1-- 1 t � n M E. ae� 4 h a- 1* 4 b` ` 100 10 1.0 0. GRAIN SIZE IN MILLIMETERS 0.01 0.001 GRAVEL SAND COARSE FINE COARSE I MEDIUM FINE SILT CLAY SYMBOL - SAMPLE DESCRIPTION MWTF-2 BROWN CLAYEY FINE SAND WITH TRACE FINE SHELL FRAGMENTS (SC) WITH 5% WYO-BEN HYDROGEL • O B-1 BROWN SILTY MEDIUM TO FINE SAND WITH TRACE FINE SHELL FRAGMENTS (SM) WITH 4% AND 6% WYO-BEN HYDROGEL PARTICLE SIZE DISTRIBUTION OF SOIL-BENTONITE BACKFILL MIXES Ardaman & Associates, Inc. Consulting En*neen in Soils, Mydrogeology, Foundations, and Matetals Testing TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA. NORTH CAROUNA DRAWN SV KJS 1CMECKEOev 1,1 JOATE 7-18-90 FILE NO 88-089 N39695 FIGURE 3-17 Texasgulf Inc. File Number 88-089 4-1 Section 4 DESIGN CONSIDERATIONS FOR REMEDIAL ACTION SYSTEM 4.1 Elements of Remedial Action System The tank farm remedial action system consists of the following five elements: • Continue the on -going program of installation of new containment facilities to contain leaks/spills around the piperack, and phosphoric and superphosphoric acid storage tanks. • Install an approximately 750-foot long soil-bentonite cut-off wall along the north side of the tank farm to contain contaminants in the surficial deposits and protect surface waters in the adjacent barge slip. • Install a system of withdrawal wells along the inside of the cut-off wall tapping the confined sand layer to reduce the levels of contaminants in the confined sand layer and overlying deposits. • Install a system of fresh water injection wells on the south side of the tank farm and a system of withdrawal wells on the north side of the tank farm tapping the Croatan formation to reduce the levels of contaminants in this formation.* • Institute a revised groundwater monitoring program in the tank farm area to measure the effectiveness of the above actions. The layout of the remedial action system is depicted in Figure 4-1. 4.2 Installation of New Containment Facilities Installation of new containment facilities to minimize and contain leaks/spills from the main east - to -west piperack (see Figure 4-1) have been completed. This system includes a concrete containment pad with a lined drainage ditch and sump to collect leaks/spills from the pipelines, and therefore to a large degree removes the east -to -west piperack as a source of groundwater contamination. * The conceptual layout of the remedial action system, as presented in our letter of March 6, 1990 titled "Response to Deficiencies Noted by the DEM Concerning the Tank Farm Supplemental Remedial Action Plan and Proposed Revised Remedial Action Plan", originally included a system of injection wells on both the north and south sides of the tank farm and withdrawal wells in the center of the tank farm. This conceptual layout was modified during final design to a system with one line of injection wells on the south side of the tank farm and one line of withdrawal wells on the north side of the tank farm. The modification was made to simplify the system, and eliminate the need to install wells in the congested center portion of the tank farm near the east -to -west piperack. The two lines of wells achieve the objective of the remedial action plan to reduce the levels of contaminants in the Croatan formation. Texasgulf Inc. File Number 88-089 4-2 The long-term program to minimize and contain leaks/spills around the phosphoric and superphosphoric acid storage tanks is also underway. The relocation and reconstruction of Tanks 016 and 044 (see Figure 4-1) have been completed. The rebuilt tanks are constructed on new foundations with a concrete spill containment pad and lined drainage ditch and sump. Installation of new containment facilities around the remaining phosphoric and superphosphoric acid storage tanks will be implemented as outlined in Section 4.2.1 of the original Remedial Action Plan dated October 31, 1989. 4.3 Installation of Cut -Off Wall As discussed in Section 2.4, the direction of groundwater flow in the surficial sand layer and confined sand layer is generally northward. At downgradient monitor well clusters MWTF-2 and MWTF-3, elevated levels of some constituents have been detected in the confined sand layer (Section 2.6.1.2), while groundwater quality in the surficial sand layer remains largely unaffected (Section 2.6.1.1). To contain the existing contaminants in the confined sand layer, a 750-foot long vertical soil-bentonite backfilled cut-off wall constructed using the slurry trench method will be installed on the north side of the tank farm (Figure 4-1). The cut-off wall will be excavated through the surficial and confined sand layers and keyed 3 feet into the top of the relatively impervious lower confining unit in the surficial deposits, resulting in a cut-off wall ranging from 25 to 32 feet deep (Drawing 5).* As discussed in Section 2.3.3.1, this confining unit is typically comprised of gray to greenish -gray clayey fine sand to sandy clay often with shell fragments. The cut-off wall will have a top elevation of 8.0 feet (MSL), a thickness of 2.5 feet, and a backfill coefficient of permeability equal to or less than 1x10-7 cm/sec, or an equivalent ratio of permeability to thickness. As addressed in Section 3.3, soils excavated from the slurry trench will be used as backfill for the cut-off wall with sufficient bentonite added to provide a backfill coefficient of permeability of less than 1x10-7 cm/sec. The end points of the cut-off wall were selected such that the cut-off wall extends sufficiently in an east -west direction to intercept contaminants within the surficial sand and confined sand layers. The potential extent of contaminants was estimated from the direction of groundwater flow obtained from the water table and potentiometric surface maps of the surficial sand and confined sand layers presented in Figures 2-4 and 2-5 of the Supplemental Remedial Action Plan. Using these maps, flow lines** were drawn for these two layers along the west side of the tank farm from phosphoric acid tank 006 and along the east side from the east end of the pipe rack. Previous leakage from these two locations should represent the western- and eastern -most potential sources of leaks/spills, respectively, and accordingly flow lines from these sources should delineate the likely western and eastern extent of groundwater contamination. As outlined below in Section 4.4, a series of seven withdrawal wells on 100-foot centers tapping the confined sand layer will be installed on the inside (south side) of the cut-off wall to reduce the levels of contaminants in the confined sand layer and overlying soils. The withdrawal wells will lower the piezometric water level in the confined sand layer on the inside of the cut-off wall, * Drawings 1 through 11 are contained in Attachment I. ** Flow lines are drawn perpendicular to the water table or piezometric water elevation lines shown on these figures. Texasgulf Inc. File Number 88-089 4-3 creating a "low point" in the confined sand layer piezometric water level, and thereby preventing the flow of contaminants around the ends of the cut-off wall. 4.4 Installation of Confined Sand Layer Withdrawal Well System A series of seven withdrawal wells on 100-foot centers tapping the confined sand layer will be installed on the inside (south side) of the cut-off wall to reduce the level of contaminants in the confined sand layer. The locations of the withdrawal wells, designated SWW-1 through SWW-7, are depicted on Figure 4-1. The wells will be operated such that a maximum piezometric water level of about 2 feet (MSL) is achieved in the confined sand layer between the wells, creating a "low point" in the confined sand piezometric water level to prevent flow around the ends of the slurry wall. An elevation of 2 feet (MSL) was selected because this level is about 1-foot lower than the lowest natural piezometric water level measured to -date at monitor wells MWTF-2B and MWTF-3B (Section 2.4). Because of downward seepage from the surficial sand layer, groundwater withdrawal from the confined sand layer will also result in the reduction of the level of contaminants in the surficial soils as they migrate downward into the confined sand layer. 4.4.1 Design Features of Withdrawal Well System As shown on Drawing 6, the withdrawal wells will be constructed of 4-inch diameter PVC pipe with a 4-foot long slotted well screen in a 12-inch diameter borehole sealed into the confined sand layer. Pneumatic pulse pumps will be installed in each well connected to a common 2-inch diameter HDPE discharge pipe. A ball valve will be installed at the top of each well to allow isolating each pump/well for service, and a pet cock valve will be installed to allow sampling of groundwater from each well. The two discharge pipes from the wells (one servicing wells SWW-1 through SWW-3 and one servicing wells SWW-4 through SWW-7) will be routed to the control building (Figure 4-1), connected together, and then connected to a totalizing meter (Drawing 7). Groundwater from the withdrawal wells will be pumped to the existing pond water return system in the SPA plant. Four pulse senders will be used to control the pumping rates from the wells: (i) one servicing well SWW-1; (ii) one servicing well SWW-7; (iii) one servicing wells SWW-2 and SWW-3; and (iv) one servicing wells SWW-4, SWW-5 and SWW-6. 4.4.2 Modeling of Performance of Withdrawal Well System Based upon the results of the field exploration (Section 2), the generalized hydrogeologic cross section and formation properties depicted in Figure 4-2 were used to model the stratigraphy of the tank farm area. The three dimensional finite -difference groundwater flow model MODFLOW by McDonald & Harbaugh (1984) was used with this generalized stratigraphy to predict the effect of the withdrawal wells on water levels and the flow into each well. The projected potentiometric surface map of the confined sand layer based upon maintaining a maximum piezometric water level between wells of about 2 feet (MSL) is presented in Figure 4-3. As shown, the withdrawal wells create a "low -point" in the potentiometric surface of the confined sand layer resulting in groundwater from beyond both the east and west ends of the cut-off wall flowing radially towards the wells. Accordingly, groundwater in the confined sand layer below the tank farm area cannot flow around the ends of the cut-off wall. As shown in Figure 4-4, the projected flow into the withdrawal wells ranges from 2.7 gal/min for the two end wells (SWW-1 and SWW-7) to 1.2 gal/min at the center well (SWW-4), resulting in a total projected flow of 12.8 Texasgulf Inc. File Number 88-089 4-4 gal/min. The piezometric water levels in the wells will vary from about 1-foot (MSL) in the two end wells to 1.2 feet (MSL) in the center well (Figure 4-4). 4.5 Installation of Croatan Formation Injection/Withdrawal Well System A series of seven fresh water injection wells on 100-foot centers tapping the Croatan formation on the south side of the tank farm, and a series of seven withdrawal wells on 100-foot centers tapping the Croatan formation on the north side of the tank farm will be installed as part of the remedial action system to remove contaminants from the Croatan formation. The locations of the injection wells, designed CIW-1 through CIW-7, and the withdrawal wells, designated CWW-1 through CWW-7, are presented on Figure 4-1. 4.5.1 Design Features of Injection Well System As shown on Drawing 8, the injection wells will be constructed of 4-inch diameter PVC pipe with a 15-foot long slotted well screen in a 12-inch diameter borehole sealed into the Croatan formation. The injection wells will be connected to a common 4-inch diameter PVC header pipe at Elevation 5.0 feet (MSL). The header pipe will be connected to a water level control tank. The water level within the tank will be adjustable within the range of 5 to 15 feet (MSL) via an adjustable drop pipe. Once the drop pipe is set at a selected water level, the flow of water into the tank to maintain the selected water level will be controlled by a float valve. A totalizing meter will be provided for the water level control tank to monitor the quantity of fresh water injected into the Croatan formation. Clean -outs are provided at three locations on the header pipe (Figure 4-1), and access is provided to each injection well by a riser pipe to ground surface (Drawing 8). 4.5.2 Design Features of Withdrawal Well System As shown on Drawing 6, the withdrawal wells will be constructed of 4-inch diameter PVC pipe with a 15-foot long slotted well screen in a 12-inch diameter borehole sealed into the Croatan formation. Pneumatic pulse pumps will be installed in each well connected to a common 2-inch diameter HDPE discharge pipe. A ball valve will be installed at the top of each well to allow isolating each pump/well for service, and a pet cock valve will be installed to allow sampling of groundwater from each well. The two discharge pipes from the wells (one servicing wells CWW-1 through CWW-3 and one servicing wells CWW-4 through CWW-7) will be routed to the control building (Figure 4-1), connected together, and then connected to a totalizing meter (Drawing 7). Groundwater from the withdrawal wells will be pumped to the existing pond water return system in the SPA plant. Four pulse senders will be used to control the pumping rates from the wells: (i) one servicing well CWW-1; (ii) one servicing well CWW-7; (iii) one servicing wells CWW-2 and CWW-3; and (iv) one servicing wells CWW-4, CWW-5 and CWW-6. 4.5.3 Modeling of Performance of Injection/Withdrawal Well Systems The projected potentiometric surface map of the Croatan formation for the operating condition of maintaining a piezometric water level of 10 feet (MSL) in the injection wells and about -2 feet (MSL) in the withdrawal wells is presented in Figure 4-5. As shown, the injection wells will create a "mound" in the Croatan formation along the line of wells with flow occurring both northward and southward away from the wells. The withdrawal wells will create low points in the Texasgulf Inc. File Number 88-089 4-5 potentiometric surface with flow into the withdrawal wells coming largely from the injection well induced flow, and a small component from the formation to the north of the withdrawal wells. As shown by the potentiometric surface map, flow from the injection wells will also occur radially around both the east and west ends of the tank farm. Accordingly, groundwater within the Croatan formation somewhat beyond the east and west ends of the lines of wells will also be recovered by the withdrawal wells. As shown in Figure 4-6, the projected flow into the injection wells ranges from 3.9 gal/min for the two end wells (CIW-1 and CIW-7) to 1.7 gal/min for the center well (CIW-4). The total projected flow into the injection well system is 19.3 gal/min. The projected flow from the withdrawal wells to maintain a piezometric water level in the withdrawal wells of about -2 feet (MSL) varies from 1 gal/min for the two end wells (CWW-1 and CWW-7) to 0.7 gal/min for the center well (CWW-4). The projected total flow into the withdrawal well system is about 6 gal/min. 4.6 Surface Settlements Induced from Groundwater Withdrawals The surface settlement expected at various locations in the tank farm was estimated based upon the projected changes in piezometric water levels in the confined sand layer and Croatan formation due to the injection and withdrawal well systems. The surface settlements were estimated for the following locations: (i) at the line of withdrawal wells on the north side of the tank farm; (ii) between and below the sulfur tanks (i.e., Tanks 003, 005 and 050); (iii) between and below the phosphoric acid tanks (i.e., Tanks 006, 007, 008, 009, 017, 019 and 021); and (iv) at the south end of the tank farm below the fertilizer blend tanks. The estimated settlements for each of these locations are presented below: Location Surface Settlement (inches) • At Withdrawal Wells • Sulfur Tanks Between Tanks At Center of Tanks • Phosphoric Acid Tanks Between Tanks At Center of Tanks • Fertilizer Blend Tanks Between Tanks At Center of Tanks 0.2 0.2 0.5 0.15 0.2 0.1 0.1 As shown, the estimated surface settlements from projected piezometric water level changes are relatively small, ranging from 0.1 to 0.5 inches. At the sulfur tanks, where surface settlement will be the largest, a differential settlement across the tanks in the north -south direction of about 0.25 inches is expected (i.e., the north side of the tanks will settle 0.25 inches more than the south side Texasgulf Inc. File Number 88-089 4-6 of the tanks). This differential settlement will result in an angular distortion of 0.0002 feet/foot, which is very small. 4.7 Performance Monitoring of Remedial Action System Monitoring of injected and withdrawn water volumes, formation water levels, and groundwater quality will be undertaken as generally requested by the DEM in their letter of December 8, 1989 concerning the tank farm Supplemental Remedial Action Plan. 4.7.1 Water Volumes The volume of water withdrawn from the seven confined sand layer withdrawal wells, the volume of water withdrawn from the seven Croatan formation withdrawal wells, and the volume of fresh water injected into the seven Croatan formation injection wells will be determined monthly via three totalizing meters incorporated into the system (see Drawings 7 and 8). The cumulative total and monthly total volumes of groundwater withdrawn from the wells in the confined sand layer and Croatan formation, and cumulative total and monthly total volumes of fresh water injected into the Croatan formation will be provided quarterly to the DEM within 30 days after the end of each quarter. 4.7.2 Water Quality Monitoring After installation of the remedial action system, water quality monitoring will be undertaken quarterly at: (i) the MWTF-1 well cluster; (ii) the FERT-1 utility well; (iii) the seven confined sand layer withdrawal wells; (iv) the seven Croatan formation withdrawal wells; and (v) at the water level control tank used to supply fresh water to the Croatan formation injection wells.* Water quality monitoring will include determination of the field pH, water temperature and specific conductance, laboratory pH, total dissolved solids, total organic carbon, chloride, sulfate, total phosphorus, and fluoride as presently undertaken in conjunction with the quarterly groundwater monitoring program. The results of the water quality monitoring will be reported to the DEM within 30 days after the end of each quarter. 4.7.3 Water Level Monitoring Water levels will be measured monthly in each of the existing nine monitor wells, two of the existing test wells, and 13 proposed piezometers (three in the Croatan formation designated CPZ-1, CPZ-2 and CPZ-3, and ten in the confined sand layer designated SPZ-1 through SPZ-10). As shown in Figure 4-7: (i) three monitor wells (1C, 2C and 3C), one test well (CPW) and three piezometers will tap the Croatan formation; (ii) three monitor wells (1B, 2B and 3B), one test well (SPW), and ten piezometers will tap the confined sand layer; and (iii) three monitor wells (1A, 2A and 3A) will tap the surficial sand layer. The results of the water level monitoring will be submitted quarterly to the DEM within 30 days after the end of each quarter. In conjunction with water level monitoring, the water level in the barge slip and drainage ditch at the time of the * Quarterly sampling of the MWTF-2C and MWTF-3C monitor wells as originally presented in our letter of March 6, 1990 is not needed with the Croatan formation withdrawal wells relocated to the north side of the tank farm. The groundwater quality in the Croatan formation will be determined at each withdrawal well. Texasgulf Inc. File Number 88-089 4-7 well/piezometer readings will also be determined. Water level monitoring will continue on a monthly basis for the first 12 months of operation of the remedial action system. If consistent and expected water level behavior is observed, water level monitoring will be changed to a quarterly basis thereafter. z-b 31:1f19IA Z 0 20 0 -10 -20 -30 -40 -50 -60 STRATIQRAPHIC UNIT SURFICIAL SOILS UPPER CONFINING UNIT CONFINED SAND LAYER LOWER CONFINING UNIT TYPICAL COEFFICIENT THICKNESS OF PERMEABILITY SOIL DESCRIPTION FINE SAND TO 12' CLAYEY FINE SAND 6' kv=0.0038 ft/day CLAYEY FINE SAND TO PLASTIC CLAY 4' khft/day 10' kv=0.0012 ft/day MEDIUM TO FINE SAND TO SILTY FINE SAND CLAYEY FINE SAND TO SANDY CLAY CROATAN FORMATION 20' kh=4.5 ft/day CLAYEY TO SILTY FINE SAND WITH SHELL FRAGMENTS YORKTOWN FORMATION 100' kv 0.0016 ft/day GENERALIZED HYDROGEOLOGIC CROSS SECTION AND FORMATION PROPERTIES FOR TANK FARM AREA CALCAREOUS CLAYEY FINE SAND TO SANDY CLAY 4 0 C WELL 1 2 3 4 5 6 7 WELL NUMBER 4 3 2- 2 1 0 FLOW FROM WELL, a WATER LEVELS AND FLOW RATES FOR CONFINED SAND LAYER WITHDRAWAL WELLS W il Ardaman & Associates, Inc. '• Consulting Engineers in Soil Mechanics, Foundation, and Materials Tasting TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROLINA DRAWNBT KJS ICHECKEDBV: 1DATE7.18.90 FILE8 NO. AVPR Y' 8-069 N 36488 FIGURE 4-4 WATER LEVEL IN WELL, h (FEET, MSL) 16 14 12 10 8 6 4 2 0 -2 -4 h INJECTION WELLS ♦ 0 0— ..i ♦ • 0 0 0 0 INJECTION WELLS 0 0 WITHDRAWAL WELLS o � 4— h WITHDRAWAL WELLS 1 2 3 4 5 WELL NUMBER 6 7 5 4 3 2 0 WATER LEVELS AND FLOW RATES FOR CROATAN FORMATION INJECTION/WITHDRAWAL WELL SYSTEM FLOW, Q (GAL/MIN) I1Ardaman & Associates, Inc. Conseil p Engineers in Seik. Hyhogeology, Founretiens, 7e1 Materiels Testing TANK FARM REMEDIAL ACTION PLAN TEXASGULF INC. PHOSPHATE OPERATIONS AURORA, NORTH CAROUNA DRAWN KV KJS 'CHECKED 6, P/1 "DATE 7-18-90 FILE NO. APP OVE •V L. 'f�f 88- 89 1 `• N3%95 FIGURE 4-6 Texasgulf Inc. File Number 88-089 5-1 Section 5 GENERAL CUT-OFF WALL AND WITIIDRAWAI.ANJECTION WELL TECHNICAL SPECIFICATIONS The following technical specifications address the construction methodologies, construction materials, and quality control testing requirements of the soil-bentonite cut-off wall and portions of the injection/withdrawal well systems. The specifications may be revised during preparation of the Bid Documents to include additional information or to reflect changes made in some features of the design. Texasgulf Inc. will also provide the general terms and conditions portion of the specification as part of the Bid Documents. 5.1 Intent The intent of this specification is for the Contractor to install a groundwater remedial action system comprised of a soil-bentonite cut-off wall, and a system of fresh water injection and groundwater withdrawal wells in the tank farm area at Texasgulf Phosphate Operations in Aurora, North Carolina. The cut-off wall will consist of 750 linear feet of a soil-bentonite backfill wall a minimum of 2.5-foot thick extending to depths of about 26 to 31 feet (about 21,300 ft2) and having a coefficient of permeability of equal to or less than 1x10-7 cm/sec, or an equivalent permeability to thickness ratio. The withdrawal/injection well system will consist of: (i) seven 4-inch diameter PVC withdrawal wells tapping the confined sand layer generally 22 to 28 feet deep; (ii) seven 4-inch diameter PVC withdrawal wells tapping the Croatan formation generally 53 feet deep; (iv) seven 4-inch diameter PVC injection wells tapping the Croatan formation generally 50 feet deep; and (v) the associated connecting header and discharge pipes, injection well water level control tank, withdrawal well pneumatic pumps and pulse senders, air compressor, coalescing filter, air dryer and associated controls, and control building. 5.2 List of Drawings The eleven drawings listed below illustrating the general layout and typical details of the soil- bentonite cut-off wall and withdrawal/injection well systems are included in Attachment I. The drawings may be revised during preparation of Bid Documents to include additional information or changes in some features of the design, and during construction as required by the Contractor for installation of the cut-off wall and injection/withdrawal well systems. Drawing Revision Description 1 P1 Tank Farm Aerial Photograph and Boring, Monitor Well and Test Well 1 Mation Plan 2 P1 Layout of Tank Farm Remedial Action System 3 P1 Site Plan for Soil-Bentonite Cut -Off Wall and Confined Sand and Croatan Formation Withdrawal Well Systems 4 P1 Site Plan for Soil-Bentonite Cut -Off Wall and Confined Sand and Croatan Formation Withdrawal Well Systems 5 P1 Profile Along Soil-Bentonite Cut -Off Wall and Typical Sections and Details 6 P1 Typical Details for Confined Sand and Croatan Formation Withdrawal Well Systems Texasgulf Inc. File Number 88-089 5-2 Drawing Revision Description 7 P1 Typical Cross Section and Details for Confined Sand and Croatan Formation Withdrawal Well System 8 P1 Typical Details for Croatan Formation Injection Well System 9 P1 Soil Borings Along Soil-Bentonite Cut -Off Wall and Confined Sand and Croatan Formation Withdrawal Well System Alignment 10 P1 Soil Borings Along Soil-Bentonite Cut -Off Wall and Confined Sand and Croatan Formation Withdrawal Well System Alignment 11 P1 Soil Borings Along Croatan Formation Injection Well System Alignment 5.3 Contractor's Understanding It is understood and agreed that the Contractor has, by careful examination and inspection, fully satisfied himself as to the: nature and location of the work; conformation and character of ground; site accessibility and nature of adjacent tank farm facilities; groundwater conditions; character and quality of materials; kind of equipment and facilities needed for the performance of this work; and general and local conditions which can affect the work covered here -under. 5.4 Work by Contractor The work consists of furnishing all tools, labor, materials, plant, equipment, supervisory personnel and Contractor's facilities to construct: (i) 750 linear feet of soil-bentonite backfill cut-off wall having a minimum thickness of 2.5 feet and a coefficient of permeability equal to or less than to 1x10-7 cm/sec, or equivalent coefficient of permeability to thickness ratio; and (ii) 14 groundwater withdrawal wells and 7 fresh water injection wells with all associated connecting header and discharge pipes, injection well water level control tank, withdrawal well pneumatic pumps and pulse senders, air compressor, coalescing filter and air dryer, and control building. 5.4.1 Layout of Work The Owner will establish reference points for horizontal and vertical control near the construction area. From these reference points, the Contractor will provide all horizontal and vertical control necessary to complete the work to the location, lines and grades shown on the Drawings. The exact locations of the injection and withdrawal wells, injection well water level control tank and control building has not been specified, but will be in general accordance with the locations shown on Drawing 2 field adjusted as approved by the Owner. 5.4.2 Soil-Bentonite Cut -Off Wall 5.4.2.1 Cut -Off Wall Geometric Requirements. The width of the soil-bentonite cut-off wall shall be equal to or greater than 2.5 feet, or the equivalent thickness provided the required ratio of coefficient of permeability to thickness is maintained (i.e., (10-7 cm/sec)/2.5'). 5.4.2.2 Depth of Cut -Off Wall. The cut-off wall shall extend a minimum of 3 feet into the clayey sands of the lower confining unit in the surficial deposits. The expected depth of the cut-off wall along the 750-foot long alignment is shown on the cut-off wall profile on Drawing 5. The Texasgulf Inc. File Number 88-089 5-3 elevation of the base of the trench shall be determined by the Inspector representing the Owner to confirm the 3-foot minimum depth of penetration into the approved clayey stratum. Material excavated from the base of the trench shall be examined by the Inspector to confirm penetration into the lower confining unit. 5.4.2.3 Cut -Off Wall Materials (a) Bentonite. The bentonite shall consist of a premium grade high -swelling natural sodium montmorillonite based product. The material shall have been formulated to function in the presence of water soluble inorganic contaminants without loss of its filtrate control properties. The Contractor shall submit a 10 pound sample of the bentonite proposed for use for evaluation by the Owner, and shall indicate the manufacturer, trade name, and properties of the proposed bentonite (mineralogic information and Atterberg limits (ASTM D 423 and D 424)) for approval by the Owner prior to construction. The Contractor shall not change bentonite during the work without the approval of the Owner. (b) Water. Clean, fresh water shall be used to produce the bentonite slurry. The Owner will make available a water source in the tank farm area. The Contractor shall be responsible for securing water from the source designated by the Owner. (c) Bentonite Slurry. The bentonite slurry used for supporting the sides of the trench and for mixing with backfill material shall consist of a stable colloidal suspension of bentonite in clean, fresh water. The bentonite slurry viscosity, prior to mixing with the backfill, shall be no less than 40 seconds -Marsh as determined by a Marsh Funnel in accordance with API RP 13B "Standard Procedure for Field Testing Drilling Fluids" (Section 2). The density of the bentonite slurry shall not be less than 64 lb/ft3 as determined by API RP 13B (Section 1). The bentonite slurry everywhere in the trench must be maintained fluid enough to pass through a Marsh Funnel and its total unit weight must be at least 15 lb/ft3 lighter than the soil-bentonite backfill mixture. From Station 3+00 to Station 7+50, where soft clays are present, the bentonite slurry shall be maintained at a total unit weight greater than 88 lb/ft3. (d) Soil Backfill. Soil used as backfill shall consist of soil excavated from the slurry trench provided it has no deleterious debris (i.e., trash, wood, organic material, etc.), has no particles larger than 2 inches in diameter, is thoroughly homogenized prior to mixing with bentonite slurry, and is approved for use as backfill by the Owner. Borrow soils, if needed for use as backfill, shall be approved by the Owner. Locations of areas to stockpile borrow soils at the construction site, if needed, also shall be approved by the Owner. (e) Soil-Bentonite Backfill Mixture. Sufficient bentonite slurry and dry bentonite shall be added and mixed uniformly and homogeneously with the soil backfill such that the soil- bentonite backfill mixture has the following properties: • a minimum bentonite content of 3.5 percent by dry weight of soil, where the bentonite content is defined as the ratio of the dry weight of bentonite product to the dry weight of soil; Texasgulf Inc. File Number 88-089 5-4 • a minimum of 18 percent material (bentonite and soil) by dry weight finer than the U.S. Standard No. 200 sieve determined in accordance with ASTM D 421 and D 422; • a coefficient of permeability equal to or less than 1x10 7 cm/sec at the in -situ density determined in accordance with Section 5.7.1(e); • a saturated paste placement consistency and water content corresponding to a slump cone value of 4 to 6 inches determined in accordance with ASTM C 143; • a placement saturated unit weight at least 15 lb/ft3 greater than the bentonite slurry determined in accordance with API RP 13B. For determining compliance with the permeability specification, a soil-bentonite backfill mixture coefficient of permeability up to 2x10-7 cm/sec will be allowed, provided the average coefficient of permeability of all test samples is equal to or less than 1x10-7 cm/sec. The soil-bentonite backfill mixture must not shrink, consolidate or otherwise settle more than 2 inches beneath the desired final top of soil-bentonite backfill elevation of 8.0 feet (MSL) prior to placing backfill above the top of the cut-off wall. The Contractor shall schedule the work to allow the soil-bentonite backfill to settle and consolidate as much as possible prior to placement of compacted granular backfill above the cut-off wall. If settlements in excess of these specifications occur, the Contractor shall refill the trench with approved soil-bentonite backfill mixture to Elevation 8.0 feet (MSL). 5.4.2.4 Disposal of Unsuitable Soils Excavated from Slurry Trench. Soils unsuitable for use as soil backfill excavated from the slurry trench shall be disposed of on Texasgulf Inc. property at a location selected by the Owner. 5.4.2.5 Excavation of Slurry Trench. The slurry trench shall be excavated by the slurry method, i.e., under bentonite mud. The toe of the slope of the trench excavation shall precede the toe slope of the soil-bentonite backfill mixture by a minimum of 50 feet and a maximum of 150 feet to permit proper cleaning of the trench bottom, inspection of the material at the base of the trench, and measurement of the depth of the trench. The Contractor shall maintain the stability of the excavated trench at all times, with particular attention given to trench stability where soft clays are penetrated between Station 3+00 and Station 7+50. The elevation of the surface of the bentonite slurry and total unit weight of the bentonite slurry shall be maintained as high as required to prevent cave-in, with the elevation of the surface of the bentonite slurry maintained at least 2 feet above the surrounding water table during construction. The excavated trench above the bentonite slurry level shall not be allowed to cave into the bentonite slurry -filled trench. The Contractor shall provide all personnel, equipment and material, as needed, to maintain the bentonite slurry level at all times during the trench construction, after hours, weekends and holidays included. After excavation of the trench is complete, the bottom of the excavation shall be cleaned of sediments, as needed, prior to the placement of soil-bentonite backfill mixture to meet the coefficient of permeability and the requirements of uniform homogeneous backfill. Texasgulf Inc. File Number 88-089 5-5 5.4.2.6 Soil-Bentonite Backfill Mixture Placement. Care shall be exercised during backfilling to ensure that the soil-bentonite backfill mixture flows and displaces the bentonite slurry in the trench, and to ensure that a uniform and homogeneous soil-bentonite backfill cut-off wall is constructed. Initially, the backfill mixture shall be placed in the trench by dropping it at the beginning of the excavation from one location only until the material forms its angle of repose and emerges above the bentonite slurry surface. The Contractor shall then backfill from the location of the initial backfill to the opposite end of the trench. Backfilling operations shall proceed in such a manner that the slope of the initial soil-bentonite backfill is maintained, which shall be no steeper than 5 horizontal to 1 vertical (5H:1V) nor flatter than 10H:1V. The soil-bentonite backfill material shall be placed such that it slides down the slope of the previously placed backfill, and in such a manner that pockets of bentonite slurry are not trapped within the backfill. Free dropping of backfill through the bentonite slurry shall not be permitted after the initial backfill operation is concluded. The soil-bentonite backfill may be placed by the use of a bulldozer or other Owner approved equipment, and in such a manner that the backfill below the bentonite slurry surface will be pushed along the trench. 5.4.2.7 Containment of Bentonite Slurry. During construction of the slurry trench, the Contractor shall provide earth berms on both sides of the work area to prevent the release of bentonite slurry or soil-bentonite backfill into the drainage ditch on the south side of the road or into the barge slip. Particular care shall be taken to prevent the release of any materials into the barge slip. 5.4.2.8 Daily and Final Clean -Up. The Contractor shall clean-up the work site and install all barricades as needed at the end of each work day to maintain the site in a clean and safe condition as required by Texasgulf Inc. safety regulations. Upon completion of the work, the Contractor shall remove and dispose of all trash, debris, bentonite slurry, unused soil, etc., resulting from operations and excavations during construction of the cut-off wall. Remaining unused soil and bentonite slurry shall be removed and disposed of in areas designated by the Owner. The surfaces of the asphalt road disturbed by the cut-off wall installation shall be replaced as outlined in Section 5.4.5. Soil surfaces disturbed by the cut-off wall installation shall be cleaned of bentonite slurry and/or soil-bentonite backfill and refilled and/or regraded to their existing condition as directed by the Owner. All slurry ponds shall be pumped dry and backfilled. All trash and debris shall be removed from the premises by the Contractor. 5.4.2.9 Temporary Relocation of Existing Facilities and Work Around Existing Facilities. Telephone cables are located in the south shoulder of the asphalt road and may cross the road along the cut-off wall alignment. The Contractor shall arrange to have the locations of the telephone cables flagged. The Contractor shall execute his work without disturbing the cables or shall arrange to have the cables temporarily relocated as approved by the Owner. The cut-off wall will pass beneath two piperacks at about Station 3+50 and Station 6+80. The Contractor shall not disturb or damage the piperacks, and is responsible for the timely repair or replacement of any portions of the piperacks damaged by the Contractor's operations and/or personnel during construction. Texasgulf Inc. File Number 88-089 5-6 The cut-off wall will traverse: (i) five existing 15- to 24-inch diameter HDPE pipe culverts below the asphalt road at about Stations 0+43, 4+47, 5+20, 6+07, and 6+93; (ii) two 12-inch diameter PVC pipe firelines at about Station 5+53 and Station 7+15; and (iii) a concrete fire trench at about Station 5+83. The Contractor shall install the cut-off without disturbing these existing facilities, and is responsible for the timely repair and replacement of any pipelines damaged by his operations and/or personnel during construction. 5.4.3 Withdrawal and Injection Wells 5.4.3.1 Well Drilling Procedures. The withdrawal and injection wells shall be installed in 12-inch minimum diameter boreholes drilled with hollow stem auger or rotary washed with Vari Flo drilling fluid or other Owner -approved biodegradable drilling fluid. After installation, the wells shall be developed by pumping until clear water is obtained from each well. Groundwater pumped from the wells during development shall be discharged to a location approved by the Owner. A permeability test shall also be performed on each well after development in general accoardance with NAVFAC DM 7.1 (1982) Chapter 2, Section 9.4. and as directed by the Owner to allow calculation of the coefficient of permeability of the zone tapped by the well screen. 5.4.3.2 Well Casings. All well casings and associated fittings shall be Schedule 40 polyvinyl chloride (PVC) pipe satisfying the material, workmanship, dimension, pressure rating and marking requirements of ASTM standards D 1785 and D 2466. Pipe and fittings shall be manufactured from a PVC compound meeting the requirements of cell classification 12454-B as outlined in ASTM Standard D 1784, and shall be white in color. Joints shall be socket -type, glued with solvent cement satisfying the requirements of ASTM standard D 2564 and made using standard practices as outlined in ASTM practice D 2855. 5.4.3.3 Well Screens and Centralizers. Well screens shall be Schedule 40 PVC pipe satisfying the requirements of Section 5.4.3.2 with 0.050-inch wide slots and a minimum inlet area of 10 square inches per foot of well screen. Centralizers on the well screens shall be stainless steel and capable of adjusting to the 12-inch diameter borehole to center the well screen in the borehole. 5.4.3.4 Silica Gravel Filter. Gravel used around the well screens shall contain at least 98% silica, be free of any deleterious materials, classify as an SP-type poorly graded coarse sand to GP -type poorly graded fine gravel with coarse to fine sand in accordance with ASTM standard D 2487, and exhibit the following gradation requirements determined by ASTM standard D 421 and 422: U.S. Standard Sieve Size Percent Passing (Dry Weight Basis) 3/4-inch 3/8-inch No. 4 No. 10 No. 20 No. 40 100 80-100 50-100 20-50 0-15 0 5.4.3.5 Bentonite Seal and Grout. The well screen shall be sealed with a minimum 2-foot thick tamped bentonite seal made with 1/2 inch diameter bentonite pellets. A 1-foot thick layer of silica Texasgulf Inc. File Number 88-089 5-7 sand (20/30 size) shall be placed between the bentonite seal and silica gravel collection zone. Neat cement grout shall be tremmie placed from the bentonite seal to ground surface. The neat cement grout shall consist of a mixture of 6 gallons of clean water per 94 pound bag of Type II Portland cement (ASTM C 150) with 4 to 4.5 pounds (dry weight basis) of bentonite drilling mud. 5.4.3.6 Injection Well Clean -Outs and Riser Pipes. Three clean -outs shall be constructed on the injection well header pipe at the locations shown on Drawing 2 and in accordance with the detail shown on Drawing 8. A riser pipe shall also extend to ground surface at each injection well in accordance with the detail shown on Drawing 8. Concrete pads around the clean -outs and riser pipes shall be constructed to the dimensions shown in the details on Drawing 8. The concrete shall consist of Type II Portland cement (ASTM C 150) and shall develop a 28-day compressive strength of not less than 4,0001b/in2 (ASTM C 31 and C 39). A Brooks Products, Inc. 8.75 inch diameter concrete traffic box with cast iron cover, or Owner -approved equivalent, shall be provided at each clean -out and riser pipe. 5.4.3.7 Withdrawal Well Discharge Pipes, Air Line Conduits and Injection Well Header Pipe. Polyethylene pipe and fittings used for the discharge pipes from the withdrawal wells shall be DRISCOPIPE 1000 series 2-inch diameter SDR 17 high density polyethylene pipe, or an Owner - approved equivalent, meeting the material, workmanship, dimension, pressure test, and marking requirements of ASTM standard F 714. The pipe and fittings shall be manufactured of high density polyethylene having a cell classification of PE 345434C in accordance with ASTM Standard D 3350. The pipe sections shall be joined by flanged connections or by butt fusion in accordance with the manufacturer's recommendations. The withdrawal well air line conduit, piping from the well to the discharge pipe, and injection well header pipe and associated fittings shall be Schedule 40 PVC pipe satisfying the requirements of ASTM standards D 1785 and D 2466. Joints shall be socket -type, glued with solvent cement satisfying the requirements of ASTM standard D 2564 and made using standard practices as outlined in ASTM practice D 2855. Threaded PVC fittings in the service box shall be in accordance with ASTM standard D 2464. 5.4.3.8 Withdrawal Well Service Box. The Contractor shall provide shop drawings to the Owner for approval illustrating and specifying the components of the service box and associated piping and fittings at each withdrawal well. The piping at each service box shall include as a minimum the features shown on the details on Drawing 6. 5.4.3.9 Pumps, Pulse Senders and Associated Fittings. The pneumatic pumps, pulse senders, exhaust valves, nylon and polyethylene lines and associated fittings, and well caps shall be manufactured by QED Environmental Systems, Inc. or an Owner -approved equivalent and shall be installed in accordance with the manufacturer's recommendations. QED Model LP1001 PVC pulse pumps with a maximum capacity of 2.7 gal/min shall be installed in the Croatan formation withdrawal wells, and QED Model LP 4600 PVC pulse pumps with a maximum capacity of 7.2 gal/min shall be installed in the confined sand layer dewatering wells. All pumps shall have inlet screens. 5.4.3.10 Air Compressor, Coalescing Filter, Air Dryer and Associated Controls. The Contractor shall provide shop drawings to the Owner for approval illustrating and specifying the proposed air compressor, coalescing filter, air dryer and associated controls to provide 35 to 42 SCFM at 100 Texasgulf Inc. File Number 88-089 5-8 PSIG (i.e., 2.5 to 3.0 SCFM at 100 PSIG at each well) of clean dry air as specified by the pump manufacturer for the proposed installation. The equipment shall be designed for a service life of 20 years. 5.4.3.11 Injection Well Water Level Control Tank. The Contractor shall provide shop drawings to the Owner for approval illustrating and specifying the components of an injection well water level control tank capable of supplying a nominal flow rate of 20 gal/min at water surface elevations of 5 to 15 feet (MSL). The tank shall include as a minimum the features shown on Drawing 8, and shall be designed for a service life of 20 years. 5.4.3.12 Control Building. The air compressor, pulse senders and totalizing meters for the withdrawal wells shall be housed in a control building (see Drawings 2 and 7). The Contractor shall provide shop drawings of his proposed construction of the control building to the Owner for approval. These shop drawings shall also include a piping plan and details for installing a pipeline from the control building to the pond water return system in the SPA plant. 5.4.4 Earthwork Earthwork shall consist of: • Placing compacted granular backfill above the top of the soil-bentonite backfill in the cut-off wall from Elevation 8.0 feet (MSL) to the base of existing asphalt or gravel road surfaces (see Drawing 5). • Placing compacted granular backfill around each pipe crossing through the cut-off wall (see Drawing 5). • Excavating and backfilling of a 11 • Excavating and backfilling of all trenches for installation of the injection well header pipe, riser pipe and clean -outs. 5.4.4.1 Trench Excavation and Pipe Bedding. Excavation of all trenches and installation of pipes shall be undertaken in general accordance with ASTM standard D 2321 using Class II bedding materials. The Class II bedding material shall consist of sand tailings obtained from on -site borrow areas, shall extend 6 inches above the crown, 4 inches below the invert of the pipe, and across the full width of the trench, and shall be compacted to a density equal to or greater than 95% of the standard Proctor maximum dry density (ASTM D 698). 5.4.4.2 Allowable Pipe Trench Backfill Materials. Fill material used to backfill the trenches above the bedding shall consist of Owner -approved slightly silty, silty, slightly clayey or clayey sands free of deleterious materials (organics, wood, trash, debris, etc.), originally obtained from the excavation of the trenches, and classifying as SP-SM, SM, SP-SC, or SC type soils in accordance with ASTM standard D 2487. The backfill should be placed in 12-inch loose lifts and compacted to a minimum of 95% of the standard Proctor maximum dry density (ASTM D 698). After backfilling, the surface of the trench shall be regraded to the existing condition as approved by the Owner. Texasgulf Inc. File Number 88-089 5-9 5.4.4.3 Backfill Above Cut -Off Wall and Around Pipe Crossings. Fill material above the cut-off wall soil-bentonite backfill shall consist of slightly silty, silty, slightly clayey or clayey sands free of deleterious material (organics, wood, trash, debris, etc.), originally obtained from the slurry trench excavation or from a borrow source, and classifying as SP-SM, SM, SP-SC or SC type soils in accordance with ASTM standard D 2487. Prior to placing backfill in the trench, the side walls shall be excavated to a slope of 1.0 vertical to 0.6 horizontal (see Drawing 5). The backfill shall be placed in level loose lifts not exceeding 12 inches in thickness and compacted to a minimum of 95% of the standard Proctor maximum dry density (ASTM D 698). The Contractor shall schedule the backfilling to allow the soil-bentonite backfill to settle and consolidate as much as possible prior to placement of compacted granular backfill above the cut-off wall. Care shall be taken around the pipe crossings during compaction to prevent displacement or damage of the pipes. 5.4.5 Replacement of Asphalt Pavement Where asphalt pavement is removed or damaged by the Contractor's cut-off wall or well installation operations, the pavement shall be replaced in accordance with the following: • a 2-inch thick bituminous concrete surface course, Type I-2, at an average rate of 105 pounds per square yard in each of two layers. • a 1.5-inch thick bituminous concrete binder course, Type H, at an average rate of 165 pounds per square yard. • a 6-inch thick compacted aggregate base course. All materials, equipment, tools, labor, and incidentals necessary to complete the work shall be in accordance with the North Carolina Department of Transportation STANDARD SPECIFICATIONS FOR ROADS AND STRUCTURES, including the latest "Standard Special Provisions", and "Roadway Standard Drawings" dated July 1, 1978, and the latest revision thereof. 5.5 General Provisions 5.5.1 General To be provided as part of the Bid Documents by Texasgulf Inc. 5.5.2 Drawings and Specifications To be provided as part of the Bid Documents by Texasgulf Inc. 5.5.3 Right to Change Location and Drawings To be provided as part of the Bid Documents by Texasgulf Inc. 5.5.4 As -Built Drawings To be provided as part of the Bid Documents by Texasgulf Inc. Texasgulf Inc. File Number 88-089 5-10 5.5.5 Safety Regulations To be provided as part of the Bid Documents by Texasgulf Inc. 5.5.6 Environmental Compliance To be provided as part of the Bid Documents by Texasgulf Inc. 5.5.7 Protection of Existing Facilities The Contractor is responsible, at no additional cost to the Owner, for timely repair or replacement of structures, equipment, pipelines, powerlines, monitor wells, or any Texasgulf Inc. facilities damaged by the Contractor's operations and/or personnel during construction. In particular, the Contractor shall exercise care when working near the following existing facilities: • The five 15- to 24-inch diameter HDPE pipe culverts, two 12-inch diameter PVC pipe firelines and concrete fire trench traversing the cut-off wall alignment. • The underground telephone cables along the south side of the asphalt road where the withdrawal wells will be installed. • The piperacks traversing the cut-off wall alignment at about Station 3 +50 and Station 6+80. • The fireline along the south side of the asphalt road near withdrawal wells SSW-6, CWW-6, SWW-7 and CWW-7. • The underground telephone cable along the north side of the tank farm office near injection well CIW-1. • The three piperacks along the injection well header pipe alignment. • The five drainage pipes traversing the injection well header pipe. 5.6 Engineering Data Soil samples from test holes drilled along the cut-off wall and well system alignments and at other Locations in the tank farm are available for inspection at the office of ARDAMAN & ASSOCIATES, INC., 8008 South Orange Avenue, Orlando, Florida. Bidders are urged to examine these samples. Geologic profiles interpreted from the test holes are included on Drawings 9, 10 and 11, and the boring logs are provided in Appendix A. The geologic profiles are provided for informational purposes only, and the actual soil conditions may vary between soil borings. The groundwater at some locations and at some depths along the cut-off wall alignment and within the depth of penetration of the wells has been impacted by spills/leaks of phosphoric acid from the tank farm. The quality of the groundwater as measured in monitor wells at three locations in the tank farm is shown on Drawings 9 and 11. The elevation of the groundwater level in the various formations to be penetrated by the cut-off wall and wells is shown for each monitor well Texasgulf Inc. File Number 88-089 5-11 on Drawings 9 and 11. Fluctuations in the water table and piezometric levels in deeper confined layers should be anticipated throughout the year. The soils have been classified in accordance with ASTM Standard D 2487 "Classification of Soils for Engineering Purposes". The transitions between soil types was often more gradual than implied by the boring logs. The Contractor must form his own opinion of the character of the work and of the materials to be excavated, and must satisfy himself, through examination of available samples, or with his own investigations, explorations, tests or studies, of the conditions affecting the work to be done. The Contractor must assume all responsibility for deductions and conclusions as to the nature or condition of earth, and other materials to be excavated, the difficulties of making and maintaining the required slurry trench excavation and well boreholes, and of doing other work affected by the geology of the site. 5.7 Quality Control Testing and Inspection 5.7.1 Cut -Off Wall The Owner or Owner's Representative (Inspector) will undertake observations and perform quality control testing to confirm compliance of the soil-bentonite backfill cut-off wall construction with these specifications. The Contractor shall also perform some quality control tests specifically referred to below. Quality control testing performed by the Owner will include: monitoring the depth of penetration of the cut-off wall; performing laboratory permeability tests to confirm compliance with the soil-bentonite backfill permeability criteria; and grain size analyses to confirm compliance with the soil-bentonite backfill gradation requirements. (a) Uniformity and Depth. The Inspector shall continuously monitor construction to confirm that the cut-off wall is uniformly and homogeneously constructed of approved soil- bentonite backfill, and that the depth of penetration of the cut-off wall is a minimum of 3 feet into an approved clayey stratum. Material from the trench bottom will be examined to document the nature of the material at the base of the trench. The depth of the slurry trench shall be measured by the Contractor, in the presence of the Inspector, a minimum of once every 20-foot of slurry wall trench. (b) Bentonite Slurry Viscosity and Weight. The Contractor, in the presence of the Inspector, shall measure the bentonite slurry viscosity and weight prior to mixing with soil backfill. The bentonite slurry viscosity and weight shall be determined each time the batch plant begins operation and a minimum of once every 2 hours during the installation of the soil- bentonite backfill mixture. The bentonite slurry viscosity shall be determined with a Marsh Funnel and the bentonite slurry weight with a mud balance in accordance with API RP 13B. (c) Soil-Bentonite Backfill Slump and Weight. The slump and weight of the soil-bentonite backfill shall be determined by the Contractor, in the presence of the Inspector, after mixing with the bentonite slurry at the initiation of each day's backfill placement, and a minimum of once every 2 hours during placement of the soil-bentonite backfill. The backfill slump shall be determined in accordance with procedures given in ASTM C 143 "Slump of Portland Cement Concrete", and the weight shall be determined with a mud balance in accordance with API RP 13B. Texasgulf Inc. File Number 88-089 5-12 (d) Soil-Bentonite Backfill Grain Size Distribution. Grain size distribution analyses will be performed by the Inspector on the soil-bentonite backfill. A minimum of one sample of backfill per day or one sample for each 50 feet of installed cut-off wall shall be obtained for grain size testing in accordance with the procedures in ASTM standards D 421 and D 422. (e) Soil-Bentonite Backfill Coefficient of Permeability. Laboratory permeability tests will be performed by the Inspector on the soil-bentonite backfill. A minimum of one sample per day or one sample for each 100 feet of installed cut-off wall shall be obtained for laboratory permeability testing. The tests shall be constant head type permeability tests performed under backpressure on specimens molded at the placement moisture content to the in situ dry density. For specimens tested in rigid -wall permeameters, the imposed hydraulic gradient shall be less than 12 to minimize consolidation of the sample during testing. For specimens tested in flexible -wall permeameters, the average effective isotropic consolidation stress shall not be greater than 3 lb/in2 and the imposed hydraulic gradient shall be less than 12. The average coefficient of permeability of the soil-bentonite backfill mixture shall be less than or equal to 1 x 10 cm/sec. The average coefficient of permeability shall be determined based on the results from a minimum of eight permeability tests for the 750-foot long cut-off wall. For determining compliance with this specification, a soil- bentonite backfill coefficient of permeability up to 2x10-7 cm/sec will be allowed provided the average of all test samples is less than 1x10"7 cm/sec. 5.7.2 Earthwork The Owner or Owner's Representative (Inspector) will undertake observations and perform quality control testing to confirm compliance of the earthwork construction with these specifications. Quality control testing shall include monitoring the excavation and backfilling of the trenches around and between wells, monitoring the backfilling above the soil-bentonite cutoff wall, and performing in situ density tests to confirm compliance with compaction requirements. (a) Fill and Pipe Bedding Characteristics. The Inspector shall monitor fill placement to confirm that allowable fill and pipe bedding materials are used in the pipe trenches and that allowable fill materials are used to backfill above the soil-bentonite cut-off wall. Standard Proctor compaction tests (ASTM D 698) will be performed on the borrow soils. One -point standard Proctor compaction tests may be performed to complement the standard Proctor compaction tests in establishing the applicable maximum dry density for different fill materials. (b) In situ Density Tests. The Inspector shall perform in situ density tests after compaction and compare the results to the standard Proctor compaction tests for the given borrow soil before allowing the placement of another layer. Testing will be performed by either the drive cylinder method (ASTM D 2937) or nuclear method (ASTM D 2922). Penetration test probes will also be performed as needed to verify the uniformity of compaction. Field in situ density tests shall be performed a minimum of once per lift for each 150 feet of trench length. Texasgulf Inc. File Number 88-089 5-13 5.7.3 Injection/Withdrawal Well System Installation. The Owner or Owner's Representative (Inspector) will undertake observations and perform quality control tests to confirm compliance of the injection/withdrawal well system installations with these specifications and the approved shop drawings. Quality control testing will include: performing grain size analyses on the silica gravel filter to verify compliance with gradation requirements; monitoring the installation of the wells, well development and permeability tests; inspection of the well screens for proper slot size; inspection of all pipes and fittings for proper size, location and installations; inspection of the pump installations; and inspection of the installation and construction of the control building, air compressor and associated equipment and controls, and injection well water level control tank. 5.8 Construction Schedule To be provided as part of the Bid Documents by Texasgulf Inc. 5.9 Method of Measurement and Payment To be provided as part of the Bid Documents by Texasgulf Inc. 5.10 Final Inspection, Testing, and Acceptance To be provided as part of the Bid Documents by Texasgulf Inc. 5.11 Supplemental General Conditions To be provided as part of the Bid Documents by Texasgulf Inc. Appendix A SOIL BORING LOGS BORING & ASSOCIATES, LOG INC. BORING NO: B-1 SSHEEET iDOF 1 40.Oft. LARDAMAN PROJECT Preliminary Contamination Assessment in Tank Farm Area FILE NO 88-089 CLIENT Texasgulf Inc. ELEVATION 11.03'(MSL) BORING LOCATION N.M.Corner of Tank Farr Latitude:35°22'52' Longitude:75°46'35' BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 6-11-88 COMPLETED 6-11-88 DRILLER/RIG Dan Groover / CME-45 MATER TABLE: ist depth 7•0' DATE 6-11-88 TIME 12:00 P.M. MATER TABLE 2nd depth -- DATE -- TIME -- REMARKS Borehole grouted with cement-bentonite grout. Field Inspector: o.Bioomberg % —'1 43 W Depth (ft1 Standard Pen. Test ASTN D-1586 Lab 08t8 Sails Description and Remarks Depth (ft) 1 0+ J A C- GO oA. xx 0 m Sample Number NM (X) -200 (x) LL (x) PI (X) Dry Den (pcf) 6.03 - 22-22-53 31-25 1 Brown medium to fine sand with trace shell fragments (SP) - • 22-27- 37-40 64 2 Brown slightly silty medium to fine sand with shell - fragments (SP-SM) - 5 25-31- 32-32 63 3 1.03 Brown medium to fine sand with shell fragments (SP) - z1-24- Mil; 51 4 14 16 _Q_ _ Grayish -brown silty medium to fine sand with shell fragments (SM) 10 17-21- 22-23 43 5 - Gray slightly silty medium to fine sand with shell _ fragments (SP-SM) - - -3.97 - _ 15 10 7-4-5 11 6 -A Gray clayey fine sand with cemented sand (SC) C -8.97 Gray silty fine sand with shell fragments (SM) _ _ a.I J a. _ 20 1l-13- 20-22 33 7 21 4 Grayish -brown slightly silty fine sand (SP-SM) 13.97 25 Light brown fine sand (SP) 2-2-3-3 5 8 28 37 32 17 - Brownish -gray clayey fine sand with shell - fragments (SC) - Slight drilling fluid circulation loss at 30.0 feet - ___,. : :1;21 ~43, 18.97 30 3-3 3-4 6 9 23.97 — 35 — Gray clayey medium to fine sand with abundant shell fragments and cemented sand (SC) - Boring terminated at 40.0 feet — /'''!Y - 0 4; 5-5-6-8 11 10 27 17 88.97 - 40 839 12 11 22 17 ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: 8-2 TOTAL DEPTH: 40.0ft. SHEET i OF i PROJECT Preliminary Contamination Assessment in Tank Fars Area FILE NO 88-0B9 CLIENT Texasqulf Inc. ELEVATION 10.90'(MSL) BORING LOCATION Road North of Tank Fars; Latitude:35°22'51'; Longitude 76°46'30' BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 6-11-8B COMPLETED 6-11-88 DRILLER/RIG 0an Groover / CME-45 MATER TABLE: ist depth 5.75' DATE 6-11-B8 TINE 4:00 P.M. MATER TABLE 2nd depth -- DATE -- TIME -- REMARKS Borehole grouted with cement-bentonite grout. Field Inspector: 0.Bloomberg w Depth ift) Standard Pen. Test ASTN 0-1586m Lab Date Soils Description and Remarks Depth (ft) J ,� CO2 Sample Number NM (z) -200 (%) LL (z) PI (%) Dry ,Den Ipcfl 5.9 - 5 5-7- 19-21 26 1 ` Brown fine sand with shell fragments(SP) - _ Q - - - - Gray slightly silty fine sand with shell - fragments (SP-SM) 18-22- 26-27 48 2 - - Gray silty fine sand with trace shell fragments (SM) - 20-17- 17-t4 34 3 12 16 .&9 - - 10 6-6-7-7 13 4 21 26 5-6-5-6 11 5 20 25 4.1 15 J 2 2-1-2 3 6 53 23 9.1 201 - 25 Dark gray clay (CH) / / 3 14 15 17 7 63 93 98 72 e i7 12 14.1 - Dark gray slightly silty medium to fine sand (SP-SM) - ! / 2-2-2-2 4 9 43 35 53 39 - - Dark gray clayey fine sand (SC) - -/ - -19.1 30 4-3-3-3 6 10 41 17 4. 2 1 35 3-3-1-2 4 11 33 13 29 i 40 Gray clayey medium to fine sand with abundant shell fragments and cemented sand (SC) - .,° 6-7-3 10 12 27 24 ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: B-3 TOTAL DEPTH: 40.0ft. SHEET i OF 1 PROJECT Preliminary Contamination Assessment in Tank Farm Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 11.77'(MSL) BORING LOCATION N.E.Corner of Tank Farm; Latitude:35°22'51'; Longitude:76°46'27" BORING TYPE Standard Penetration Test COMITY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 6-11-88 COMPLETED 6-11-88 DRILLER/RIG 0an Groover / CME-45 WATER TABLE: 1st depth 6.5' DATE 6-11-88 TIME 6:30 P.M. WATER TABLE: 2nd depth -- DATE -- TIME -- REMARKS Borehole grouted with cement-bentonite grout. Field Inspector: D.Bloomberg Depth (ft) Standard Pen. Test ASTM 0-15B6 Lab Data Soils Description and Remarks Depth (tt) 0 J M `e` (0 co a 0 0 Sample Number NM (%) -200 (%) LL (%) PI (%) Dry Den (pc f l 6.77 - 5 8-12- 22-28fragments 34 1 - Light and dark brown fine sand with shell- (SP) _ 17-21- z2-21 43 2 - Brown slightly silty fine sand with trace shell - fragments (SP-SM) - - — 14-16- 20-17 36 3 1.77 14 10 6-5 16 4 15 13 Brownish -gray silty medium to fine sand (SM) - Q - _ —. _ - 10 3-5-6-7 11 5 A_ - - Grayish -brown slightly silty medium to fine sand with shell fragments (SP-SM) - -3.23 15 10652 11 7 26 22 -8.22 _ Grayish -brown silty fine sand (SM) _ 20 3 2 2 1 4 8 43 75 91 52 - - Dark gray silty clay (CH) r " 13.23 25 1-1-2-9 3 9 10 - Gray silty medium to fine sand (SM) 18.23 30 NOH 11 - Dark gray clayey fine sand (SC) - Slow loss of drilling fluid circulation when rods fell _ from 31.0 to 38.0 feet :--32( _ 23.23 35 liCIR 28.23 _ - 40 2-2-2-3 4 12 37 17 .://` , -' ' 4 27/:. /4,:c ., _ Gray clayey coarse to fine sand with abundant shell fragments (SC) - AROAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-1 TOTAL DEPTH: 60.0ft. SHEET 1 OF 2 PROJECT Remedial Action Plan - Tank Farm Area FILE NO 88-089 CLIENT Texasgulf Inc. ELEVATION 10.5'4SL) BORING LOCATION Tank Farm; N 82+95 : E 131+20 BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE 45 ft / 6' dia. hollow stem auger DATE STARTED 10-25-88 COMPLETED 10-25-88 DRILLER/RIG D.Shanaway / CME-55 MATER TABLE 1st depth -- DATE -- TIME -- MATER TABLE 2nd depth - DATE -- TIME -- REMARKS Borehole grouted with cement-bentonite grout. Field Inspector: H.Ellingsworth 2 ICI -, W Depth (ftl Standard Pen. Test ASTN 0-1586 Lab Bata Soils Description and Remarks Depth (ft) Graphic Log co c COiu Sample Number NM (z) -200 (%) LL (%) PI (z) ›...`a' o V O 5.5 - 5 3-6-6 12 1 Light brown fine sand (SP) 17 ii 11 22 2 22 13 Light gray fine sand with small balls of - clayey fine sand (SP) - _ - B-6-3 9 5-4-6 10 3 . 5 10 1 Dark brown clayey fine sand with roots (SC) - -� 4 24 59 Gray and yellowish -brown sandy clay (CL) - Dark brown plastic clay (CH) _ —. - _ - " " 2-4-10 14 5 6 23 20 - Brown silty fine sand (SM) -4.5 - ' 15 _ - Brown clayey fine sand with seams of fine - sand (SC) _ /7. 2-1-5 6 7 31 47 -9.5 20 Dark gray clayey sand with seams of fine sand (SC) - 5-4-2 5 8 29 30 -14.5 25 Greenish -gray clay with shell fragments (CHI - - - L - - r - /0 // 2-3-3 6 9 55 69 -19.5 30 3-3-4 7 10 34 25 - Greenish -gray clayey fine sand with shell fragments (SC) 24.5 - 35 - Greenish -gray slightly clayey fine sand and shell fragments (SC and shell) _ $:///, . •v2 4-5-5 10 11 28 12 --29.5 - 40 - Greenish -gray silty fine sand with traces of clayey sand and she 11 (SM) 3-4-3 7 12 25 16 AROAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-1 TOTAL SHEET 22 OF 2 60.Oft. PROJECT Remedial Action Plan - Tank Farm Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 10.5'(MSL) BORING LOCATION Tank Farm; N 82+95 ; E 131+20 BORING TYPE Standard Penetration Test o q, W c a o standard Pen. Test ASTM 0-1586 Lab Data Soils Description and Remarks Depth (ft) Graphic Log .. _ o .D ma co d i ig �_ NM (t) -200 (s) LL (t) PI (%) a o LI — = 0 34.5 45 - _ Greenish -gray silty fine sand with traces of clayey sand and shell (SMI _ . c a Total loss of drilling fluid circulation at 42 feet - - Gray slightly silty medium to fine sand with some shell6 _ fragments and thin layers of cemented sand (SM) - -l.G. -I- - __ - 17-34-35 69 13 9 7 -39.5 50 - Greenish -gray clayey fine sand (SCI /// 4-3-3 7 14 -44.5 55 _ Greenish -gray clayey fine sand with thin layers - of sandy clay (SC) 3-4-4 8 15 -49.5 = 60 - Greenish -gray clayey fine sand (SC) 3-4-4 8 16 22 43 -54.5 65 Boring terminated at 60.0 feet _ -59.5 70 -64.5 75 -69.5 80 ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-2 TOTAL DEPTH 60.0ft. SHEET 1 OF 2 PROJECT Remedial Action Plan - Tank Fars Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 10.9'(MSL) BORING LOCATION Tank Farm; N 87+83 ; E 128+80 BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 10-20-88 COMPLETED 10-20-88 DRILLER/RIG 0.Shanaway / CME-55 MATER TABLE ist depth -- DATE -- TIME -- MATER TABLE 2nd depth -- DATE -- TIME -- REMARKS Borehole grouted with cement-bentonite grout. Field Inspector: H.Ellingsworth m W Depth (ft) Standard Pen. Test ASTM 0--1586 Lab Data Soils Description and Remarks L a ii a, c J c q 0 m� y Sample Number NM (%) -200 (XI LL (X1 PI (%( Dry Den (pcf) 5.9 - 4-12-18 30 1 8 - Grayish -brown slightly silty fine sand with trace - shell fragments (SP-SM) - - - - - -/. - 25-21-22 43 2 5 19-29-14 43 3 _ Gray slightly silty fine sand with traces of shell and wood (SP-SM) 36 13 13 21 34 4 .89 Gray and yellowish -brown clayey fine sand (SC) _ - i0 s 4 14 19 33 6 22 21 - Gray silty fine sand (SM) -4.1 - 15 - Gray to dark brown clayey fine sand with thin - lenses of gray fine sand (SC) - 3-2-5 7 36 35 9 1 - 20 - Gray slightly silty fine sand (SP SM) 2-11-20 31 8 20 6 -14.1 J - -, - 25 Dark gray clayey fine sand with thin lenses of gray fine - sand and traces of shell fragments (SC) - - - - _ - _ _ i-i-1 2 9 35 31 -19.1 _ 30 J� 4 - Gray clayey fine sand with shell and cemented sand (SC) (shell fragments comprise about 34 % of sample by dry _ - weight, ranging in size from about i to 10 mm) 28 4-2-2 4 10 -24.1 _ _ - 35 - _ Shell fragments and gray slightly clayey fine sand with cemented fine sand (Shell fragments and SP-SC) - (shell fragments comprise about 55 % of sample by dry _ weight, ranging in size from about 1 to 25 mm) 12 5-4-4 8 11 -29.1 - 40 A _ Gray slightly clayey fine sand with shell fragments (SC) 1276 15 12 24 24 BORING ARDAMAN & ASSOCIATES. LOG INC . BORING NO: TF-2 TOTAL DEPTft 60.Oft. SHEET 2 OF 2 PROJECT CLIENT BORING Remedial Texasgulf Action Plan - Tank Farm Area FILE NO 88-089 Inc. ELEVATION 10.9'(MSL) LOCATION Tank Farm; N 87+63 ; E 128+80 BORING TYPE Standard Penetration Test N. 21 W a Standard Pen. Test ASTM D-1586 Lab Data Soils Description and Remarks Depth (ft) Graphic Log o� m `. r Sample Number NM (z) 200 (z) LL (%) PI (%) ra o_ 0) 0 -34.1 - _ - 45 - _ Gray slightly clayey fine sand with shell fragments (SC) - - - _ Gray clayey fine sand with shell fragments and thin,- layers of greenish -gray clay (SC) �¢{ 0 4-6-11 17 13 17 -39.1 - 50 - - Greenish -gray to gray slightly clayey fine sand - with shell fragments (SP-SC) - / . Q% 5-7-8 15 14 9 -44.1 _ - 55 - ` _ —_� - Greenish -gray clayey fine sand with trace shell- fragments (SC) 3-3-6 9 15 -49. t _ - 60 _, _ _ Greenish -gray clayey fine sand (SC) - 566 12 16 47 -54.1 - 65 Boring terminated at 60.0 feet -59.1 70 -64.1 75 -69.1 80 BORING ARDAMAN & ASSOCIATES, LOG INC . BORING NO: TF-3 TOTAL DEPTH: 60.0ft. SHEET 1 OF 2 PROJECT Remedial Action Plan - Tank Farm Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 12.0'(MSL) BORING LOCATION Tank Fars; N 87+65 ; E 131+50 BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 10-20-88 COMPLETED 10-20-88 DRILLER/RIG D.Shanaway / CME-55 MATER TABLE: 1st depth -- DATE -- TIME -- MATER TABLE: 2nd depth _- DATE -- TIME -- REMARKS Borehole grouted with cement-bentonite grout. Field Inspector H.Ellingsworth 2 43 W - Standard Pen. Test ASTN 0-1586 Lab Data Soils Description and Remarks Depth (ft) l Ja c J A c� _ = m z Sample Number NM (%) -200 (t) LL (%) PI (%) r o o_.. w 0 7 5 4-16-8 24 1 15 Brown fine sand (SP) - Tri Light brown to yellowish -brown silty fine sand (SM) 13-18-22 40 2_ - Yellowish -brown slightly clayey fine sand (SC) t8 24 i6 40/7-. _ Gray clayey fine sand (SC) / 11-15-19 34 3 29 2 - 10 Gray clayey fine sand with traces of gray fine - sand lenses (SC) 6-5-4 9 4 -j 15 Brown silty fine sand (SM) - j 5 26 22 2-1-1-1 2 6 53 _ Dark brawn sandy clay (CH) - f -8 20 - Dark gray clay (CH) - - - _ - 4 MOH 7 64 93 88 54 13 - 25 Gray medium to fine sand (SP) i 6-5-5 10 8 20 3 -18 - 30 _ - Dark gray clayey fine sand (SC) .7/ / 3-3-3 6 9 28 23 3 5 3-3-2 5 10 40 19 -28 40 Gray clayey coarse to fine sand and shell fragments (SC) - i 2-9-7 16 11 23 ARDAMAN BORING C ASSOCIATES, LOG INC . BORING NO: TF-3 TOTALT 2EOFF so.oft. PROJECT Remedial Action Plan - Tank Farm Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 12.0'(MSL) BORING LOCATION Tank Farm; N 87+65 ; E 131+50 BORING TYPE Standard Penetration Test Elevation _ c CI. 8 stsndsrd Pen. Test 0-1586 Lab Oats Soils Description and Remarks Depth (ft) en 0 -J 10 `�i ~ -. (D CO z Sample Number NN (%) -200 (%) LL (%) PI (%) Dry Den (pcf) -33 - 45 clayey coarse to fine sand and shell fragments (SC) L - - _Mi. _ - - "5/Gray _ - Shell fragments and gray silty fine sand (shell and SM) 5-7-7 14 12 34 16 38 - 50 C - Gray slightly silty coarse to fine sand and shell fragments - with thin layers of cemented sand (SP-SM and shell) _ - (shell fragments comprise about 38 % of sample by dry weight, ranging in size from about 1 to 20 nm) g 7-11-19 30 13 -43 - 55 Greenish -gray clayey fine sand with trace shell - fragments (SC) 17 3-3-3 6 14 -48 - 60 ? - _ Light greenish gray sandy clay (CL) - 50 4-5-6 11 15 -53 65 Baring terminated at 60.0 feet - - _ -58 70 -63 75 -68 80 ARDAMAN BORING & ASSOCIATES, LOG INC. BORING NO: TF-100 TOTAL SHEET 1 OF 2 6i.5ft. _ PROJECT Remedial Action System - Tank Farm Area FILE NO 88-089 CLIENT Texasguif Inc. ELEVATION 12.7'(MSL BORING LOCATION Tank Farm; N B3+32.36 ; E 133+84.81 BORI% TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE 451 3' dim. steel DATE STARTED 5 11 90 CD1PLE1t0 5 12 90 DRILLER/RI6 S.McCluskey / CME - 55 MATER TABLE: ist depth 1.5' DATE 5-11-90 TIME 16:15 MATER TABLE 2nd depth -- DATE -- THE -- RENAq(S Borehole grouted with cement-bentonite grout. Field Inspector: H.Ellingsworth C 6 d w _ •r a Standard Pen. iest ASTN 0-1596 LHO Bata Soils Description and Remarks _ L 1 0, J t la m`� Y z Sample Number NM (%) -200 (z) LL (x) PI (x) Dry Den (pc f l 7.7 6-8-8-10 16 1 Brown fine sand (SP) Q _ - - - - _ _ _ _ - _ - _ - ._2,,,2X - - Gray fine sand with thin layers (1"-2") of gray clayey - fine sand with traces of shell fragments (SP) - - 7 11 18-19 29 2 5 15-18- 23-16 41 3 2.7 10 - Brown silty fine sand (SM► - -2.3 - - _ 15 8-9-6-4 15 4 36 28 . - Gray to brown slightly silty fine sand with some thin _ clayey sand layers (SP-SM) -7.3 20 3-15-16 31 5 21 5 Gray slightly silty medium to fine sand (SP-SM) 11 14 5 5 19 6 22 6 -12.3 - _ 25 7-1-2-3 3 7 • .. - _ Dark gray sandy clay with trace shell fragments (CH) / _ Greenish -gray clay with trace shell fragments (CH) - 9 Y Y 9 17.3 - - 30 2-3-4-4 7 8 84 87 112 82 3-4-4-6 8 9 0 )2 6i 6/Y - Shell fragments and gray clayey fine sand (shell and SC) -- - (shell fragments comprise about 53 % of sample by dry weight, ranging in size from about 0.2 to 25 mm) _ - Complete loss of drilling fluid circulation at 39.5 feet -22.3 - _ 35 3-4-6-6 10 10 -27.3 - 40 4-7-9 16 11 31 14 .o ^ a Gray slightly silty fine sand with trace shell fragments BORING ARDAMAN g ASSOCIATES, LOG INC. BORING NO: TF-100 TOTAL DEPTit 61.5ft. SHEET 2 OF 2 PROJECT CLIENT BORING Texasgulf Remedial Action System - Tank Farr Area FILE NO 88-089 Inc. ELEVATION 12.7.(MSL) LOCATION Tank Farm; N 83+32.36 ; E 133+84.81 BORING TYPE Standard Penetration Test a m cm Depth (ft) 1 Standard Pen. Test ASTN 0-1586 L80 Data Soils Description and Remarks Depth (ft) Graphic Loge _ = m = Z Sample Number NM (x) -200 (z) LL (%) PI (z) Dry Den (pcfl -32.3 45 5-13-14 27 12 19 6 _ Gray slightly silty fine sand with trace shell - fragments (SP-SMI - .� ' .c7..t o • 4 .- - Gray slightly silty fine sand with trace shell fragments ._ and some thin layers of clayey sand (SP-SM) - . 52 13 -37.3 _ _ 50 10-20-39 59 13 17 9 - - - - - Gray clayey fine sand with trace shell fragments (SC) _ - -42.3 _ _ 55 6-5-5 10 14 28 20 _ -47.3 - 60 3-4-5 9 15 -�// Greenish -gray clayey fine sand (SC) _ -52.3 _ 3-3-4 7 16 _ _ 65 _ Boring terminated at 61.5 feet _ _ -57.3 70 -62.3 75 -67.3 80 ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-101 TOTAL DEPTH: 61.5ft. SHEET 1 OF 2 PROJECT Remedial Action System - Tank Farm Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 11.5'(MSL) BORING LOCATION Tank Farr N 83+04.10 ; E 127+75.89 80R1N6 TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE 457 3. dia. steel DATE STARTED 5-12-90 COMPLETED 5-13-90 DRILLER/RI6 S.McCluskey / CME - 55 MATEH TABLE: lot depth 2.2' DATE 5-12-90 TIME -- MATER TABLE 2nd depth -- DATE -- TIME -- REMARKS Borehole grouted with ce.ent-bentonite grout. Field Inspector: H.Ellingsworth 1 Elevation Depth (ft) standard Pen. Test ASTI 0-158fi Lab haste Soils Description and Remarks I Depth (ftl 0, 0 J o co co c zo.� '43(x) m = Sample Number NM -200 (%) LL (Z) PI (X) Dry Den (pcfI 6.5 - 5 - Post hole dig to 3.0 feet to check for telphone line - and then rotary washed to 5.0 feet - _Q _ Brown slightly silty fine sand with trace shell fragments (SP-SM) ` - - _ - 1.5 - 5-5-4-3 9 1 . - Brown slightly silty fine sand with trace shell - fragments and thin layers of clayey fine sand (SP-SM) - 10 4-2-3-4 5 2 -3.5 _ _ _ 15 6-12-13 25 3 - _ Gray slightly clayey to clayey sand with roots (SC) 7: _ Dark brown clay with layers of fine sand (CH) 8 .5 _ 20 5-2-1-2 3 4-5 ///////, _ Dark brown clay (CH) - - - - - 0-0-1-1 1 6 82 102 75 -13.5 - _- 25 0-0-t-2 1 7 , - Greenish -gray claywith shell fragments (CH) g Y g 1-1-2-3 3 6 9 -18.5 30 2-3-3 6 10 80 95 119 87 2-2-3-4 5 11 _ _ Gray clayey sand and shell fragments (SC and shell) - _ _ Complete loss of drilling fluid circulation at 39' _ _ - - r:'6v -23.5 _ _ 35 3-2-4 6 12 -28.5 - 40 11-6-3-4 9 13 34 35 o Gray fine sand and shell fragments (SP and shell) BORING ARDAMAN 6 ASSOCIATES, LOG INC . BORING NO: TF-101 TOTAL 2 OTF 2 61.5ft. PROJECT CLIENT BORING Texasgulf Remedial Action System - Tank Fare Area FILE NO 88-089 Inc. ELEVATION 11.5'(MSL) LOCATION Tank Farm N 83+04.10 ; E 127+75.89 BORING TYPE Standard Penetration Test _ m k1 . ya O stanear1Pen. Test ASTM 0-1586 Lao Data Soils Description and Remarks Depth (ft) I Graphic Log — o c0 ? Z a" a E Vi Z NM (t) -200 (X) LL (XI PI (X) n L C N O -33.5 _ 45 Gray fine sand and shell fragments (SP and shell) 1.: Gray slightly clayey sand and shell fragments with thin - layers of cemented sand and shell fragments (SC and shell) - - - -38.5 - - 50 6-8-10 18 14 24 8 - _ Greenish -gray clayey fine sand with trace shell _ fragments (SC) _ -43.5 - 55 5-5-5 10 15 _ -48.5 - 60 3-4-6 10 16 ^� - Greenish-gray- clayey fine sand (SC) - -53.5 3-3-4 7 17 - 65 _ Boring terminated at 61.5 feet _ -58.5 70 -63.5 75 -68.5 80 - ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-102 SHEOEEET 1 OF 2 61.5ft. PROJECT Remedial Action System - Tank Fars Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 11.3'(NSL) BORING LOCATION Tank Fars; N 85+05.87 ; E 127+80.11 BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 5-11-90 COMPLEit0 5-11-90 DRILLER/RIG S.McCluskey / CIE - 55 WATER TABLE 1st depth 2.0' DATE 5-11-90 TIME -- WATER TABLE: 2nd depth -- DATE -- TIME -- REARICS Borehole grouted with cement-bentonite grout. Field Inspector: H.El1ingsworth 4..m Depth (ft) Standard Pen. test ASTN 0-1586m Lab Bata Soils Description and Remarks Depth (ft) Sample Number NM MI -200 (z) LL (x) PI MIp Dry Den Oct) 6.3 - 5 5" of asphalt over 2" of "reject" material over 17" of gray to brown fine sand and shell _ 9 - ~ - _ - So 11 is 27 1 Gray slightly silty fine sand (SP-SM) - 17-11-14 25 2 14-14-3 17 3 _ Gray slightly silty fine sand with trace shell fragments (SP-SM) - 1.3 - _ 10 4-7-10 17 4 _ Dark brown clay (CH) A - Light gray to light brown silty fine sand (SM) -3.7 15 14 16 13 29 5 24 is - Dark brown clay (CH) /�� // -8.7 _ - 20Su 1-6-6 14 6 Brown silty fine sand (SM) - - - - 5-2-1 3 7-8 US-1 31 75,61 36 20 90.5 - Dark brown clay (CL) with seams of silty sand (PP) -250 psf f�%%/L �/' -13.7 - 25 1-2-6-16 8 9 - Gray medium to fine sand (SP) - Dark brown to clayey fine sand (SC) - - —i X -18.7 - - 30 3-4-4-2 8 10 US-2 44 38.37 67 52 76.5 gray - 2-1-1-2 2 11 Laboratory Permeability Test; ke o-7 cm/sec- Su (TV) -740 to 860 psf -23.7 - 35 NOH 12 Dark brown to gray clayey fine sand to sandy clay and shell fragments (SC and shell) -• - - _ -28.7 - - 40 1-1-2-2 3 13 - Shell fragments and gray slightly clayey fine sand with cemented sand (shell and SP-SC) i;i BORING ARDAMAN & ASSOCIATES, LOG INC . BORING NO: TF-102 TOTAL DEPTH: 61_5ft. SHEET 2 OF 2 PROJECT CLIENT BORING Texasqulf Remedial Action System - Tank Farr Area FILE NO 8B-089 Inc. ELEVATION 11.3'(MSL) LOCATION Tank Farr; N 85+05.87 ; E 127+80.11 BORING TypE Standard Penetration Test Elevation 3 c g Standard Pen. Test ASTM 0-1596 Lab Data Soils Description and Remarks .-3 L S Graphic log I N� .- LD N Value Sample Number NM (%) -200 (%) LL (z) PI (z) Dry Den (pcf) -33.7 - 45 B-6-B 14 14 - Shell fragments and gray slightly clayey fine sand with cemented sand (Shell and SP-SC) - (shell fragments comprise about 54 % of sample by dry _ weight, ranging in size from about 0.2 to 25 mm) - /. -38.7 - 50 B 10 10 20 15 32 7 - _ - Gray clayey fine sand with cemented sand and _ shell fragments (SC and shell) -43.7 - - 55 12 7 l0 17 16 - - Gray clayey fine sand (SC) - -48.7 60 3-4-7 11 17 - Grayish -green sandy clay (CLI _ -53.7 _ 4-4-6 10 iB _ 65 _ Boring terminated at 6i.5 feet - ~ -58.7 70 -63.7 75 -68.7 B0 ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-103 TOTAL 1 DF 2 6i.5ft. PROJECT Remedial Action System - Tank Farm Area FILE NO 88-089 CLIENT Texasgulf Inc. ELEVATION 11.3'(MSL) BORING LOCATION Tank Farm: N 86+06.58 : E 130+66.30 BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 5-08-90 COMPLETED 5-08-90 DRILLER/RIG S.McCluskey / CME - 55 MATER TABLE ist depth 2-0' DATE 5-08-90 TIME -- MATER TABLE: 2nd depth -- DATE -- TIME -- REMARKS Borehole grouted with cement-bentonite grout. Field Inspector: H.Ellingsworth m 4, Depth (ft) standard Pen. Test ASTN 0-1586 Lab Data Soils Description and Remarks Depth (ft) I c " o C- CD a " CO A LO 2 NM (zl -200 (z) LL (z) PI (z) Dr y Oen (pcf) 6.3 - 5 7-11- 11-11 22 t 2 Reject material - . _ Gray to brown slightly silty fine sand with trace she11(SP-SIty 10-11- 12-12 23 3 - Gray medium to fine sand (SP) 5 5 5 4 10 4 - Gray slightly silty fine sand (SP-SM) 1.3 10 Dark brown clay (CH) _ ____,/ _ -` - _ _ Gray clayey fine sand with thin layers of gray fine _ sand (SC) _ /%. -3.7 _ - 15 5-7-8 15 5 = 20 6-9-7 16 6 2B 22 r gr Dark g ay clay (CH) ay - - - - !A -13.7 - _ 25 US 1 80 96,95 96 68 53.2 - Unconfined Compression Test: Su (UC)-510 psf- Su (TV)-500 to 600 4-1-2 3 7-8 psf 1 Su(PP)-500 to 600 psf - Gray silty medium to fine sand (SM) 4-1-1-1 2 9 32 16 -18.7 30 Gray clayey fine sand with seams of gray plastic clay (SC) -23.7 - 35 US-2 40 35,21 18 51 36 82.0 - Laboratory Perneability Test: 1.5x104 cm/sec 1-1-1 2 10 Unconfined Compression Test: Su (UC) -350 psf = Gray clayey coarse to fine sand and and shell _ fragmennts (SC ans shell) - - - J -28.7 40 1-4-3 7 11 BORING ARDAMAN & ASSOCIATES, LOG INC . BORING NO: TF-103 PT TAT 2EOF 2 61.5ft. PROJECT CLIENT BORING Texasqulf Remedial Action System - Tank Faro Area FILE NO 88-089 Inc. ELEVATION 11.3'(MSL) LOCATION Tank Faro; N 85+06.58 ; E 130+66.30 BORING TypE Standard Penetration Test Q w I Depth (ftl Standard Pen.lest 0-1586 Lab Bata Soils Description and Remarks — „ o o, o J co m _ Sample Number NM (XI -200 (X) LL (XI PI (X) Dry Den (pcf1 -33.7 = 45 10-8-9 17 12 36 18 - Gray clayey coarse to fine sand and shell - fragments (SC and shell) _ - (shell fragments comprise about 42 X of sample by dry _ weight, ranging in size from about 0.2 to 19 mn) - - I- J ../i., Y -38.7 - 50 4-5 7 12 13 - - - Gray clayey fine sand with shell fragments and - cemented sand and shell fragments (SC and shell) -43.7 _ 55 6-6-9 15 la 19 18 - - Gray clayey fine sand (SC) - -48.7 _ 60 3-3-6 9 15 - Gray sandy clay (CL) _ ...A -53.7 4-5-6 11 16 _ _ 65 - Boring terminated at 61.5 feet - - - -58.7 70 _ -63.7 75 -68.7 80 - ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-104 TOTAL DEPTFt 61.5ft. SHEET 1 OF — PROJECT Remedial Action System - Tank Farm Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 11.2'(MSL) BORING LOCATION Tank Farm; N 88+05.68 ; E 127+76.52 BORING TYPE Standard Penetration Test COMITY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 5-14-90 COMI 1u u) 5-14-90 DRILLER/RIG S.McCluskey / DIE - 55 MATER TABLE 1st depth 2.3' DATE 5-14-90 TIME -- WATER TABLE: 2nd depth -- DATE -- TIME -- RENARI(S Borehole grouted with cement-bentonite grout. Field Inspector: H.Ellingsworth al "�i 4Y Cl G Standard Pen. rest ASTM 0-1586 Lab Data So119 Description and Remarks = gyyp O Graphic Log I _ = OlD OD >. = Sample Number NM (%) -200 (�) LL`` (%) PI (1•) .-. y,o CS` d 0 6.2 - - 5 Cut through 2' of asphalt pavement and then rotary rotary washed to 5.0 feet - 15-15- 13-12 28 1 Gray slightly clayey fine sand with trace shell fragments (SP-SC) 10 Gray to brown silty fine sand with trace shell fragments (A1.2 11 11 I.4 5-6-10-12 16 2 -3.8 - 4-8-8-6 16 3 - 15 Wood (logs) 10-12-10 22 4 Gray to brown silty fine sand (SM) -8.8 - 9-12-13 25 5 25 18 Soft layer (clay ?) Ad 10-13-12 25 6 Gray medium to fine sand (SP) 20 -13.8 - 25 9-9-9 18 7 Dark greenish -gray clayey fine sand (SC) Laboratory Permeability Test' irv.tecto4 cm/sec Su (TV) -200 to 500 psf MOH 8 54 30 US-1 41 21 76,:. -18.8 - Shell fragments and gray clayey fine sand (shell and SC) `- i 01"A!! ` ie •' 2-2-3 5 9 30 -23.8 35 2-2-4 6 10 30 39 -28.8 r 40 4-7-9 16 11 ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-104 TOTAL DEPTft 51.5ft. SHEET 2 OF 2 PROJECT CLIENT BORING Remedial Action System - Tank Farm Area FILE NO 88-089 Texasqulf Inc. ELEVATION 11.2'(MSL) LOCATION Tank Farm; N 88+05.68 ; E 127+76.52 BORING TYPE Standard Penetration Test a w Depth (ft) I simian Pen. rest ASTM 0-1586 Lab Data Soils Description and Remarks Depth (ft) Graphic Lop a L. m Sample Number NM (x) -200 (xl LL (x) PI (E Dry Den (pcfl -33.8 _ 45 8-15-4 19 12 - Gray clayey medium to fine sand and shell fragments with cemented sand layers (SC and shell) - (shell fragments comprise about 32 % of sample by dry weight, ranging in size from about 0.2 to 10 mil)�/ H. J / -38.8 - _ 50 4-4-13 17 13 32 13 18 _,f� -43.8 _ 55 40 9 it 20 !4 _J Gray clayey fine sand and shell fragments with _ YY 9 cemented sand (SC and shell) - i1/1 /" -48.8 - 60 4-3-5 8 15 - Greenish -gray clayey sand with trace shell fragments (SC) Greenish -gray sandy clay (CL) - - _ -53.8 - 4-4-4 8 16 - 65 - Boring terminated at 61.5 feet - _ -58.8 70 ^ -63.8 75 -68.8 80 ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-105 TOTAL DEPTH: 61.5ft. SHEET I OF 2 PROJECT Remedial Action System - Tank Farm Area FILE NO 88-089 CLIENT Texasqulf Inc. ELEVATION 11.6'(MSL) BORING LOCATION Tank Farm; N 87+66.23 ; E 133+03.55 BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 5-14-90 COMPLETED 5-15-90 DRILLER/RIG S.McCluskey / CME - 55 MATER TABLE 1st depth -- DATE -- TIME -- MATER TABLE 2nd depth -- DATE -- TIME -- REMAAKS Borehole grouted with cement-bentonite grout. Field InspectorH.Ellingsworth W Standard Pen. Test ASTN 6-1586 Lab Data Soils Description and Remarks Depth (ft) l 0 q c�3 m. z Sample Number NM (%) -200 3) LL 3) PI (%) Dry Den (pcfl 6.6 5 Gray fine sand with shell (SP) - - - - _ - Brown silty fine sand with trace shell fragments (SM) - - 1.6 - 5-5-4-4 9 1 22 19 10 -3.4 - 5-5-5-4 10 2 20 12 151 -8.39 20 3-6-8 14 3 25 14 _ Gray to brown silty fine sand (SM) - Dark gray sandy clay with organics (CH) _ _ ij -13.4 - 25 MOM 4 49 Gray to brown medium to fine sand (SPI -18.4 - 30 5-5-2 7 5-6 21 5 - Greenish -gray clayey fine sand (SC) - Su (TVI -760 psf -_ _ _ - MOH US-1 37 22 42 22 61.1 -23.4 35 woH 8 US-2 43 36 77.7 Greenish -gray clayey fine sand with soft shell - fragments (SC) Su (TV) -340 psf wOH 9 US-3 32 34 87.6 ,/. a, � G - - Gray clayey coarse to fine sand with shell fragments (SC) - -28.4 - 40 1/24' 10 36 27 2-5-6 11 11 Gray slightly clayey fine sand with shell fragments (SC) - /,�( BORING AROAMAN & ASSOCIATES, LOG INC . BORING NO: TF-105 TOTAL DEPTH 61.5ft. SHEET 2 OF 2 PROJECT CLIENT BORING Texasqulf Remedial Action System - Tank Farm Area FILE NO 8B-089 Inc. ELEVATION 11.6'(MSL) LOCATION Tank Farm; N 87+66.23 ; E 133+03.55 BORING TYPE Standard Penetration Test •� . 4, y c. Standard Pen. Test ASTN 0-1586 Lab Data Soils Description and Remarks Depth (ft) I Graphic Lop 01 Z ..r 52.. a, 7-4 Sample Number NM (%1 -200 (%) II (X) PI (%) Dr y Den (pcf) -33.4 - - 45 8-7-5 12 12 _ Gray slightly clayey fine sand with shell fragments (SC) Gray slightly clayey fine sand with trace shell = fragments (SC) - -38.4 _ 50 10-14-14 28 13 29 13 - - _ - Gray slightly clayey fine sand with shell fragments and thin cemented layers (SC) - ;27 l ; -43.4 _ - 55 8-11-17 28 14 - - Greenish -gray clayey fine sand with trace shell fragments (SC) j -48.4 60 2-3-3 6 15 _ Greenish -gray sandy clay (CL) - -53.4 _ 3-3-5 8 16 _ 65 _ Boring terminated at 61.5 feet - -58.4 70 -63.4 75 - -68.4 B0 BORING & ASSOCIATES, LOG INC . BARING NO: TF-106 TOTAROAMAN SET 1 OF 2 61.5ft. PRO..ECT Remedial Action System - Tank Farm Area FILE NO 88-0B9 CLIENT Texasqulf Inc. ELEVATION 10.1'(MSL) BORING LOCATION Tank Farm; N 87+65.64 ; E 135+11.29 BORING TYPE Standard Penetration Test COUNTY Beaufort STATE North Carolina CASING TYPE None DATE STARTED 5-15-90 COMPLtfhD 5-15-90 DRILLER/RIG S.McCluskey / CME - 55 MATER TABLE: ist depth 4.0' DATE 5-15-90 TIME -- MATER TABLE 2nd depth -- DATE -- TIME -- REMARKS Borehole grouted with cement-bentonite grout. Field Inspector: H.Ellingsworth C O ^ m w v Standard -PTest 586 Lab Data Soils Description and Remarks Depth (ft) 1 CO o J 2 A -. : ti NM (%) -200 (%) LL (z) PI (z) Dry Den (pcf) 5.1 - 5 Brown fine sand with shell fragments (SP) r - - Brown slightly silty fine sand with trace shell - fragments (SP-SM) 1 10 3-3-4 7 1 21 23 Brown slightly clayey fine sand (SC) - - < - Gray silty clay with trace shell fragments (CH) 1-2-6-7 8 2-3 22 17 _ Dark gray silty fine sand (SM) 4.9 - - 15 4-5-7-8 12 4 25 19 Gray medium to fine sand (SP) 4-3-2-2 5 5-6 - Brown silty clay with organics (CH) �,f%�,� %%�{/// -9.89 - _ 20 5-3-3-4 6 7 Brown silty fine sand with thin layers of silty clay (SM) _ - _ - -/ - _ - _ Gray medium to fine sand (SP) -14.9 - - 25 12-11 8-10 19 8 18 3 3-2-2-2 4 9 _ - Dark greenish -gray clayey fine sand with lenses of gray clay (SC) -19.9 30 uS-1 37 45 45 27 82.2 - Laboratory Permeability Test k=i.acio4 cm/sec Su (TV) =B00 to 1060 1-2-4 6 10 psf _ Shell fragments and gray clayey fine sand (shell and SCI _ _ (shell fragments comprise about 50 X of sample by dry weight, ranging in size from about 0.1 to i9 inn) J -24.9 35 5-6-4 10 11 29 20 -29 9 1-1 2 69 25 - SOH 12 _ Dark gray clayey fine sand with trace shell fragments (SC) 40 _ Gray slightly clayey fine sand and shell fragments (SC and shell) _ BORING AROAMAN g ASSOCIATES, LOG INC . BORING NO: TF-106 SOTA HEEET 2 OF 2 61.5ft. PROJECT CLIENT BORING Texasqulf Remedial Action System - Tank Farm Area FILE N0. 88 089 Inc. ELEVATION 10.1'(MSL) IOYATION Tank Farr, N 87+65.64 ; E 135+11.29 BORING TYPE Standard Penetration Test a 44 I Depth (ft) Standard Pen. Test ASTM 0-1586 Lab Data Soils Description and Remarks Depth (ftl 1 Graphic Lop . C o co — > c m m VI 2 NH (X) -200 (X) LL (%) PI (z) Dry Den (pcf) -34.9 _ 45 6-8-8 16 13 Gray slightly clayey fine sand and shell fragments - (SC and shell) - �/ - Shell fragments and gray clayey fine sand with thin (1" to 2") cemented sand layers (shell and SC) (shell fragments comprise about 55 % of sample by dry weight, ranging in size from about 0.1 to 19 mm) - T. i -39.9 - _ 50 10-11-11 22 14 20 12 ^ -44.9 _ 55 5-3-3 6 15 _ _ Greenish -gray clayey fine sand with trace shell fragments (SC) / -49.9 - 60 4-4-8 12 15 - _ _ Greenish -gray sandy clay (CL) -54.9 2-3-6 9 17 65 _ Boring terminated at 61.5 feet ~ - - -59.9 70 - -64.9 75 - -69.9 B0 BORING ARDAMAN & ASSOCIATES, LOG INC. BORING NO: TF-107 TOTAL 1 of 42.Oft. PROJECT CLIENT BORING COUNTY DATE MATER MATER RE)4mm Texasqulf Remedial Action System - Tank Farm Area FILE NO 88-089 Inc. ELEVATION i0.8'(MSL) LOCATION Beaufort Tank Farm; N 87+65.65 ; E 134+05.95 BORING TYPE Standard Penetration Test STATE COVETED DATE DATE North Carolina CASING TYPE None STARTED TABLE: TABLE 5-30-90 -- 5-30-90 DRILLER/RIG S.McCluskey / CME - 55 1st depth 2nd depth Borehole grouted -- TIME -: -- -.- TIME -- with cement-bentonite grout. Field Inspector: H.Ellingsworth 2 ft 1 Depth (ftl Standard Pen. Lest £STM 0-1586 LaG Date Soils Description and Remarks Depth (ft) I om " A o d 0 ) ` - .4 NM (z) -200 (z) LL (z) PI (z) Dry Den (pcfl 5.8 - Rotary washed to 15.0 feet - - . .8 10 -4.2 15 -9.2 11 12 9 3 21 1 Gray to brown fine sand (SP) _ 20 _ Gray slightly sandy clay (CH) - ii� //'i� -14.2 - OM / M 18'- 3 2 1 25 - Gray fine sand [SP) 2-3-5-6 8 3 -19.2 2-1-1-1 2 4 Gray sandy clay (CH) S ht tcirculation _ lig lasso drilling fluid at 29 5 _ _ 30 NOH/12' z z 2 g -242 - 1-1-2-2 3 6 - - Gray clayey fine sand and shell (SC and shell) - - /¢./^ - _ 35 :z::::: -29.2 �/ 40 BORING AROAMAN & ASSOCIATES, LOG INC . BORING NO: TF-107 TOTAL DEPTtt 42.0ft. SHEET 2 OF 2 PROJECT CLIENT BORING Tex Remedial Action System - Tank Farm Area FILE NO 88-089 asqulf Inc. ELEVATION 10.8'(MSL) LOCATION Tank Fare; N 87+65.65 ; E 134+05.95 BORING TYPE Standard Penetration Test so W m- y cS Standard Pan. Test ASTN D-1586_ Lab Gate Soils Description and Remarks --* CaO 0 J p = = coro Sample Number NM (X) -200 (X) LL (X) PI (%) o o 0 -34.2 - 8-6-6-7 12 9 - Gray clayey fine sand and shell (SC and shell) - '/;' 45 Boring terminated at 42.0 feet - - -39.2 50 - -44.2 55 - -49.2 60 -54.2 65 70 - -59.2 -64.2 75 -69.2 BO ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-10B t SET 11 OF 2 42.Oft. PROJECT CLIENT BORING COUNTY DATE MATER MATER REMARKS Remedial Texasgulf Action System - Tank Fars Area FILE ND BB-089 Inc. ELEVATION 11.4'(MSL) LOCATION Beaufort Tank Farm; N 87+66.20 E 132+50.00 BORING TYPE Standard Penetration Test STATE COMPLETED DATE DATE North Carolina CASING TYPE None STARTED TABLE TABLE: Borehole 5-29-go -- 5-29-90 DRILLER/RIG S.McCluskey / CME - 55 ist depth 2nd depth grouted -- TIME -- -- -- TIME -- with cement-bentonite grout. Field Inspector: H.Ellingsworth W Depth (ft) I Standar0 Pen. Test ASTN 0-15060 Lab Data S0119 Description and Remarks Depth (ft) J L cob m N Value Sample Number (NM -((200 LL PrI Dry Den (pcfl 6.4 5 Rotary washed to 15.0 feet 1.4 10 -3.6 15 -8.6 - 9-9-6-3 15 1 Gray fine sand (SP) 20 - Dark gray clay (CH) - j -13.6 - woH/12' 1 1 2 77 - - 25 9-16- 124 28 3 - Gray medium to fine sand (SP) 18.6 - 2-2-2-3 4 4 - Gray clayey fine sand with trace shell fragments (SC) 30 Gray clayey fine sand with shell fragments (SC) - 3-3-3-4 6 5 -23.6 - 3-3-5-6 8 6 - 35 Gray clayey fine sand and shell fragments (SC and shell) = - , -28.6 14 1 10 10o 20 7 = - - 40 BORING & ASSOCIATES, LOG INC . BORING NO: TF-10B SOTHEET 2EOF 2 42.0ft. ALARDAMAN PROJECT CLIENT BORING Texasgulf Remedial Action System - Tank Farm Area FILE NO 88-089 Inc. ELEVATION 11.4'(MSL) LOCATION Tank Farm,_ N 87+66.20 ; E 132+50.00 BORING TYPE Standard Penetration Test _. 4.4 V N. 47 k1 L y ydy O Standard Pen. Test ASTM o-15a Lab Data Soils Description and Remarks L 0 Graphic Log I _ tn G = . i O— up m m } _ Sample Number NM (X) -200 (%) LL (X) PI (X) Dry Den (pcfl -33.6 - 10-i1- 11-11 22 a Gray clayey fine sand and shell fragments (SC and shell) -OCi; 45 Boring terminated at 42.0 feet - - - -38.6 50 - -43.6 55 - -48.6 60 -53.6 65 -58.6 70 -63.6 75 68.6 B0 BORING ARDAMAN & ASSOCIATES, LOG INC . BORING NO: TF-109 TOTAL DEPTH: 47.0ft. SHEET 1 OF 2 PROJECT CLIENT BORING COUNTY DATE MATER MATER REMARKS Remedial Texasgulf Action System - Tank Farm Area FILE NO 88-089 Inc. ELEVATION 12.2'(MSL) LOCATION Beaufort Tank Farm; N 85+37.02 ; E 133+88.03 BORING TYPE Standard Penetration Test STATE COMPLETED DATE DATE North Carolina CASING TYPE None STARTED TABLE: TABLE: 5-30-90 -- 5-30-90 DRILLER/RIG S.McCluskey / CME - 55 1st depth 2nd depth Borehole grouted -- TIME -- -- __ -- TIME -- with cement-bentonite grout. Field Inspector: H.Ellingsworth a ox a',8 - . ca.3 Standard Pen. Test ASTM o-i58fi Lab Data Soils Description and Remarks Depth (ft) 1 m o J L 4 m`o Z Sample Number NM (t) -200 (%) LL (z) PI (%) Dry Den (pcfl 7.2 5 Rotary washed to 5.0 feet 2.2 - 4-3-3-4 6 1 _ Gray to brown sandy clay (CH) _ i� 10 - - Brown slightly clayey fine sand (SC) _ -2.8 - 3-2-5-10 7 2 - r _ _ 15 - Dark gray to gray slightly sandy clay (CH) _ �� -7.8 t t t 5 2 3 -• _ _ 20 5-5-2-2 7 4 -12.8 - 6-5-4-6 9 5 - Gray slightly clayey medium to fine sand (SP-SC) - - - _ 25 3-2-1-1 3 6 _ Gray clayey fine sand with trace shell fragments (SC) - - -17.8 - NOH 7 - - J 30 t-t-2-3 3 8 - Gray clayey fine sand and shell fragments (SC and shell) E _ _ ,/� ,-/9 /5? -22.8 - 3-3-4-5 7 9 - - - 35 -27.8 - 7-7-5-9 12 10 _ - 40 BORING AROAMAN & ASSOCIATES, LOG INC . BORING NO: TF-109 TOTAL SHEET 22OOFF 2 47.Ott. PROJECT CLIENT BORING Texasgulf Remedial Action System - Tank Farm Area FILE NO 88-089 Inc. ELEVATION 12.2'(MSL) LOCATION Tank Fara; N 85+37.02 ; E 133+68.03 BORING TYPE Standard Penetration Test Elevation Depth (ft) I Standard Pen. Test ASTN 0-1586 Lab Data Sails Description and Remarks Depth (ft) Graphic Lop Inc o ID m — Sample Number NM (%) -200 (%) LL (%) PI (%) Dry Den (pcf) -32.8 - 8-6-6-7 12 11 - - _ Gray clayey fine sand and shell fragments (SC and shell) _ - - - - r Y / _ 45 -37.8 - 15 56 12-14 28 12 ^ 50 Boring terminated at 47.0 feet - -42.8 55 -47.8 60 -52.8 65 - -57.8 70 -62.8 75 -67.8 B0 ARDAMAN BORING & ASSOCIATES, LOG INC . BORING NO: TF-110 TOTAL DEPTH: 27.0ft. SHEET 1 OF 1 PROJECT CLIENT BORING COUNTY DATE WATER WATER REMAAKS Remedial Action System - Tank Farm Area FILE NO 88-089 Texasqulf Inc. ELEVATION 11.6'(MSL) LOCATION Beaufort Tank Farr; N 83+43.38 ; E 129+82.54 BORING TYPE Standard Penetration Test STATE COIPLtfEU DATE DATE North Carolina CASING TYPE None STARTED TABLE: TABLE Borehole 6-14-90 -- 6-14-90 ORILLER/RIG D.Shanaway / CME - 55 ist depth 2nd depth grouted -- TIME -- -- -- TIME -- with cement-bentonite grout. Field Inspector: H.Ellingsworth c c 43 (13 W Depth (ft) I Standard ion. Tut ASTM 0-1586 Lab Oats Sails Description and marks Depth (ft) 1 Graphic Log _.0 o —co s Z Sample Number NM (z) -200 (z) LL (z) PI (z1 Dry Den (pcfl 6.6 5 ` Rotary washed to 15.0 feet ~ 1.6 10 -3.4 15 8.39 - 1-2-i-i 3 1 - -- Dark brown clay (CH) _ - 4 /%/ 20 1-1-1-i 2 2 13.4 - 1-1-1-1 2 3 - - _ _ - Dark brown clay with thin lenses of gray fine sand and with trace of shell fragments (CH) �,//// - 25 2-2-2-2 4 4 // Greenish -gray clay with trace shell fragments (CH) - -18.4 - 2-3-3-4 6 5 - - 30 Boring terminated at 27.0 feet -23.4 35 -28.4 40 Appendix B TEST WELL CONSTRUCTION RECORDS FOR OFFICE USE ONLY GROUT: Wall Thickness Depth Diameter or Weight/Ft. Material Depth Material Method From 0.0 To 19.17 Ft. Neat Cement Tremmie From To Ft. z. SCREEN: Depth Diameter Slot Size Material From 22.47 To 27.47 R. 2 in. 0.02 in. PVC From To Ft. in. in. From To Ft in. in. .3. GRAVEL PACK: OWNER ADDRESS NORTH CAROLNA DEPARMENT OF NATLRAL RE110UgCt 8 AIM COMMUNITY DEVELOPMENT MOWN OF EINIRONMBITAL MANAGEMENT - GROUM3W T6i SECTION P.o. BOX 27687 - RALEIGH.N.C. 27611. PHONE Cal SO 733-6083 WELL_ CONSTRUCTION RECORD NELL NO SOW DRILLING CONTRACTOR Ardaman & Associates, Inc. DRILLER REGISTRATION NUMBER 1019 Quad_ No. Serial No. Lat Long. Pc Minor Basin Basin Code Header Ent GW-1 Ent STATE WELL CONSTRUCTION PERMIT NUMBER: 06-0071-WG-0194 WELL LOCATION: (Show sketch of the location below) Nearest Town: Aurora, North Carolina County: Beaufort Depth DRILLING LOG (Road, Community, or Subdivision and Lot No.) Texasgulf Inc. From To Formation Description P.O. Box 48 SEE ATTACHED BORING LOG (Street or Route No.) Aurora, North Carolina 27806 City or Town State Zip Code 3. DATE DRILLED 05-25-90 USE OF WELL Test Well TOTAL DEPTH 30.0' CUTTINGS COLLECTED ❑ Yes II No DOES WELL REPLACE EXISTING WELL? ❑ Yes II No o. STATIC WATER LEVEL: 8.83 FT. 0 above TOP OF CASING, ■ below TOP OF CASING IS 2.83 FT. ABOVE LAND SURFACE. r. YIELD (gpm): X METHOD OF TEST X WATER ZONES (depth): X 9. CHLORINATION: Type None Amount . CASING: If additional space is needed use back of form. LOCATION SKETCH From 0.0 To 22.47 Ft 2" Sch 40 PVC (Show direction and distance from at least two State Roads, From 27.47 To 29.47 Ft 2" Sch 40 PVC* or other map reference points) From To Ft. SEE ATTACHED MONITOR WELL LOCATION PLAN *2'-long sump below screen section Depth Size Material From 21.47 To 30.0 Ft. 4/20 Silica Sand From To Ft. ,REMARKS: Sand from 19.17' to 19.47' and bentonite seal from 19.47' to 21.47'; 1 stainless steel centralizer on well screen. DO HEREBY CERTIFY THAT THIS WELL WAS CONS UCTED IN ACE WITH 15 NCAC 2C. WELL CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS RECORD . - • r�i TO TI WELL OWNER. 7/16/90 DATE GW-1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner. FOR OFFICE USE ONLY NORTH CAROLP A DEFART1113fT OF NATUFIAL RESOURCES AND cOIWITY DEvaOPINENr DIVISION OF ENVIRONINENTAL MANAGEMENT - r3ROIJCWATER !SECTION P.O. BOX 276e7 - RALEit3101C. 27e11, PHONE WO 73 -5083 WELL CONSTRUCTION RECORD FELL NO SPW _RILLING CONTRACTOR Ardaman & Associates, Inc. ')BILLER REGISTRATION NUMBER 1019 Quad. No. Serial No. Lat. Long. Pc Minor Basil Basin Code Header Ent. GW-1 Ent STATE WELL CONSTRUCTION PERMIT NUMBER. 06-0071-WG-0194 1. WELL LOCATION: (Show sketch of the location below) Nearest Town: Aurora, North Carolina Cosh: Beaufort (Road. Community, or Subdivision and Lot No.) OWNER Texasgulf Inc. Depth DRILLING LOG From To Formation Description ADDRESS P.O. Box 48 SEE ATTACHED BORING LOG (Street or Route No.) Aurora, North Carolina 27806 City or Town State Zip Code DATE DRILLED 05-24-90 USE OF WELL Test Well TOTAL DEPTH 30.01 CUTTINGS COLLECTED 0 Yes II No DOES WELL REPLACE EXISTING WELL? ❑ Yes . No 3. STATIC WATER LEVEL: 8.75 FT. 0 above TOP OF CASING, TOP OF CASING IS 3.17 II below FT. ABOVE LAND SURFACE. . YIELD (gpm): X METHOD OF TEST X WATER ZONES (depth). X 3. CHLORINATION: Type None CASING: Amount Wall Thickness Depth Diameter or Weight/Ft. Matenai From 0.0 To 22.83 Ft 2" Sch 40 PVC (Show direction and distance from at least two State Roads, From 27.83 To 29.83 Ft 2" Sch 40 PVC* or other map reference points) From To Ft. SEE ATTACHED MONITOR WELL LOCATION PLAN GROUT: If additional space is needed use back of form. Depth Material Method From 0.0 To 19.63 Ft. Neat Cement Tremmie From To Ft. ▪ SCREEN: Depth Diameter Slot Size Material From 22.83 To 27.83 Ft. 2 iR 0.02 in. PVC From To Ft. in. in. From To Ft in in_ • GRAVEL PACK: Depth Size Material From 22.0 To 30.0 Ft. 4/20 Silica Sand From To Ft. REMARKS. Sand from 19.63' to 19.93' and bentonite centralizer on well screen. I DO HEREBY CERTIFY THAT THIS WELL WAS C9 TRUCTED IN 1CCOR ANCE WITH 15 NCAC 2C, WELL CONSTRUCTION STANDARDS, AM) THAT A COPY OF THIS REC BEEN PRO ► :IN TO WELL OWNER 41, 7/16/90 LOCATION SKETCH *2'-long sump below screen section seal from 19.93' to 22'; 1 stainless steel SIGNATURE OF CONTRACTOR OR AGENT DATE GW-1 Reviaai 1 IIPa Submit onainal to Division of Environmental Manaoement and coov to well owner. FOR OFFICE USE ONLY NORTH CAROL1 A OEPARTIAENT OF NATURAL RESOURCES AND COMa*ITY DEVB_OPRBiT DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION P.O. BOX 27687 - RALEIGKIL.C. 27611. PHONE (g19) 733-4083 WELL CONSTRUCTION RECORD VELL NO COW DRILLING CONTRACTOR Ardaman & Associates, Inc. 'DRILLER REGISTRATION NUMBER 1019 Quad. No. Serial No. Lat. Long. Pc Minor Basin Basin Code Header Ent GW-1 Ent STATE WELL CONSTRUCTION PERMIT NUMBER: 06-0071-WG-0194 WELL LOCATION: (Show sketch of the location below) Nearest Town: Aurora, North Carolina (Road. Community, or Subdivision and Lot No.) OWNER Texasgulf Inc, ADDRESS P.O. Box 48 (Street or Route No.) Aurora, North Carolina 27806 City or Town State Zip Code DATE DRILLED 05-24-90 USE OF WELL Test Well TOTAL DEPTH 55.0' CUTTINGS COLLECTED ❑ Yes DOES WELL REPLACE EXISTING WELL? ❑ Yes No STATIC WATER LEVEL: TOP OF CASING IS . YIELD (gpm): X METHOD OF TEST X WATER ZONES (depth): X ■ No 13.04 FT. O above TOP OF CASING. 3.25 ■ below FT. ABOVE LAND SURFACE. 3. CHLORINATION: Type None CASING: From From 52.55 From GROUT: Depth 0.0 To 37.55 To 54.55 To Amount Wail Thickness Diameter or Weight/Ft. Material Ft. 2" Sch 40 PVC Ft 2" Sch 40 PVC* Ft. Depth Material From 0.0 To 34.25 Ft. Neat Cement From To Ft. SCREEN: Method Tremmie Depth Diameter Slot Size Material From 37.55 To 52.55 Ft. 2 in. 0.02 in, PVC From To Ft. in in. From To Ft in. in. _. GRAVEL PACK: Depth From 36.5 To 55.0 Size Material Ft. 4/20 Silica Sand County: Beaufort Depth DRILLING LOG From To Formation Description SEE ATTACHED BORING LOG If additional space is needed use back of form. From To Ft. REMARKS. Sand from 34.25' to 34.5' and bentonite seal centralizer on well screen. I DO HEREBY CERTIFY THAT THIS WELL WAS CO UCTED IN A STANDARDS, AND THAT A COPY OF THIS RE PRO LOCATION SKETCH (Show direction and distance from at least two State Roads, or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN *2'-long sump below screen section from 34.5' to 36.5'; 1 stainless steel CORD NCE WITH 15 NCAC 2C. WELL CONSTRUCTION TO 'li WELL OWNER. GW-1 Revised 11/84 7/16/90 SIGNATURE OF CONTRACTOR OR Aca DATE Submit original to Division of Environmental Management and copy to well owner_ FOR OFFICE USE ONLY GROUT: Depth Material Method From 0.0 To 34.24 Ft. Neat Cement Tremmie From To Ft. _. SCREEN: Depth Diameter Slot Size Material From 36.95 To 51.95 Ft. 2 in. 0.02 in. PVC From To Ft. in. in. From To Ft in in. GRAVEL PACK: Depth Size From 36.5 To 55.0 Ft. 4/20 From To Ft. REMARKS. Material Silica Sand LOCATION SKETCH NORTH CAROLR4A DEPARTMENT OF NATURAL RESOURCES AND COl.WITY DEVELOPMENT DIVISION OF ENVIR01Nl6IML MANAGEMENT - GROUNDWATER SECTION P.O. BOX 27687 - RALB(iFLN.C. 27611, PHONE (91e) 733-5083 WELL CONSTRUCTION RECORD FELL NO CPW KILLING CONTRACTOR Ardaman & Associates, Inc. ^RILLER REGISTRATION NUMBER 1019 Quad. No. Serial No. Lat. Long. Pc Minor Basin Basin Code Header Ent. GW-1 Ent. STATE WELL CONSTRUCTION PERMIT NUMBER: 06-0071-WG-0194 WELL LOCATION: (Show sketch of the location below) Nearest Town- Aurora, North Carolina County: Beaufort Depth DRILLING LOG (Road-. Community, or Subdivision and Lot No.) OWNER ADDRESS Texasgulf Inc. From To Formation Description P.O. Box 48 SEE ATTACHED BORING LOG (Street or RouteNo.)) Aurora, North Carolina 27806 City or Town State Zip Code DATE DRILLED 05-24-90 USE OF WELL Test Wel 1 TOTAL DEPTH 55.01 CUTTINGS COLLECTED ❑ Yes 111 No DOES WELL REPLACE EXISTING WELL? ❑ Yes III No STATIC WATER LEVEL: 13.21 FT. O above TOP OF CASING. 3.46 ■ below TOP OF CASING IS FT.BOVE ALAND SURFACE. . YIELD (gpm): X METHOD OF TEST X 'NATER ZONES (depth): X CHLORINATION: Type None CASING: Amount Wall Thickness If additional space is needed use back of form. Depth Diameter or Weight/Ft. Material From 0.0 To 36.95 Ft 2" Sch 40 PVC (Show direction and distance from at least two State Roads, From 51.95 To 53.95 Ft 2" Sch 40 PVC* or other map reference points) From To Ft. SEE ATTACHED MONITOR WELL LOCATION PLAN *2'-long sump below screen section Sand from 34.24' to 35.54' and bentonite seal from 35.54' to 36.5'; 1 stainless steel centralizer on well screen. I DO HEREBY CERTIFY THAT THIS WELL WAS CO STANDARDS, AND THAT A COPY OF THIS REC 3W-1 Revised 11/84 NCE WITH 15 NCAC 2C. WELL CONSTRUCTION WELL OWNER. 7/16/90 SIGNATURE OF CONTRACTOR OR AGENT DATE Submit anginal to Division of Environmental Management and copy to well owner. FOR OFFICE USE ONLY NORTH CAROLINA DttPARTIa=J4T OF NATURAL FIE8OURCE3 AND COOWaTY cEvaOPMENT DIVISION OF ENvIRON tf NTAL MANAGESIENT - GROUNDWATER SECTION P.O. BOX 27687 - RAL.Eirs•i.N.C. 27811, PHONE (910) 733-60e3 WELL CONSTRUCTION RECORD NELL NO MWTF-1D DRILLING CONTRACTOR Ardaman & Associates, Inc. DRILLER REGISTRATION NUMBER 1019 Quad. No. Serial No. Lat Long. Pc Minor Basin Basks Code Header Ent GW-1 Ent STATE WELL CONS RU T N-WG-0199 PERMIT NUMBER: WELL LOCATION: (Show sketch of the location below) Nearest Town: Aurora, North Carolina County: Beaufort Depth DRILLING LOG (Road, Community, or Subdivision and Lot No.) . OWNER Texasgulf Inc. ADDRESS From To Formation Descnption P.O. Box 48 SEE ATTACHED BORING LOG (Street or Route No.) Aurora, North Carolina 27806 City or Town State Zip Code DATE DRILLED 06-12-90 USE OF WELL Test Well TOTAL DEPTH 49.0' CUTTINGS COLLECTED ❑ Yes 111 No DOES WELL REPLACE EXISTING WELL? ❑ Yes II No 6. STATIC WATER LEVEL- 14.2± FT. 0 above TOP OF CASING, TOP OF CASING IS 2.67 ■ below FT. ABOVE LAND SURFACE. YIELD (gpm): X METHOD OF TEST X - WATER ZONES (depth): Water Loss Zone at 37.5' 9. CHLORINATION: Type None Amount . CASING: Wall Thickness Depth Diameter or Weight/Ft. Material From 0.0 To 32.0 Ft 2" Sch 40 PVC From 47.0 To 49.0 Ft 2" Sch 40 PVC* From To Ft . GROUT: Depth Material Method From 0.0 To 28.33 Ft. Neat Cement Tremmie From To Ft. ,c. SCREEN: Depth Diameter Slot Size Material From 32.0 To 47.0 Ft. 2 in. 0.010 in. PVC From To Ft. in in. From To Ft in n. GRAVEL PACK: If additional space is needed use back of form. LOCATION SKETCH (Show direction and distance from at least two State Roads, or other map reference points) SEE ATTACHED MONITOR WELL LOCATION PLAN *2'-long sump below screen section Depth Size Material From 30.33 To 49.0 Ft. 4/20 Silica Sand From To Ft. REMARKS Bentonite seal from 28.33' to 30.33', 1 stainless steel centralizer on well screen. I DO HEREBY CERTIFY THAT THIS WELL WAS C STANDARDS, AND THAT A COPY OF THIS RE RUCTED IN CORD NCE WITH 15 NCAC 2C, WELL CONSTRUCTION BEEN PRO .►l�s TO TE WELL OWNER. CAMOKL SIGNATURE OF CONTRACTOR OR /iGENT 7/16/90. DATE GW-1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner.