WI0700012_Monitoring (Report)_20080821

PCS
Phosphate
AURORA
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27806
August 21, 2008
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
May 2008 — July 2008
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Qi:
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTF1CR, b) piezometer level monitoring field sheet, and c) the summary operational and
maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
/O. iDevvIAJ
D. Daniel Winstead III
Environmental Engineer
PCS Phosphate
Attachments

pc: Will Hart —Aquifer Protection DWQ, WaRO (w/ attachments)
R. M: Smith/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
Mike Brom (w/ attachments)
Anthony Shrewsbury (w/ attachments)
R. B. Lee (w/ attachments)
Total Two Copies
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
\\aurdata2\users\AURIDDW\Reports\2008\Quarterly\TFRAS Report Second Quarter 2008.doc
2

COD
Coliform: MF Fecal
Coliform: MF Total <1.0
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
pH (when analyzed) N/A
TOC N/A
Chloride N/A
Arsenic N/A
Grease and Oils N/A
Phenol N/A
N/A
Specific Conductance N/A
Total Ammonia N/A
TKN as N N/A
Sulfate
GROUNDWATER CUALITY MONITORING'
COMPL''IANGE REPbRTING Fi
•
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. -Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled 3
Well Identification Number (from Permit): MWTF1-CR
Well Depth: 42.00 ft Well Diamter: 2 inch
Screened Interval: 38.70 ft. to 40.70 ft
Depth to Water Level: 14.50 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
MILILITERS of water pumped/bailed before sampling:
Field Analysis: pH 7.1 , Specific Conductance 700 uMhos
Temp. 23.6 oC, Odor NONE Appearance:
For Groundwater Treatment
System Check One:
RInfluent (98)
Effluent (99)
2100
CLEA
P,ARTMENT41;ivat6HMglall ikrth AL REaoI]RCES''-
ATERQUALITY Olt/IS!ON.GROUNDWATER SECT(bN
PERMIT #: WI0700012 EXPIRATION DATE: 01/31/13
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
UIC X
Rotary Distributor Land Application of Sludge
Other
r
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 7/10/2008
Date sample analyzed: 7/10/2008 to 7/11/2008
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes
N/A mgA Nitrite (NO2 as N) 1
N/A /100m1 Nitrate (NO3 as N)
/100ml Phosphorus: Total as P
Orthophosphate
N/A Al - Aluminum
mg/I
units Ba - Barium
mgA Ca - Calcium
mg/I
mg/I
mgA
mgA
mg/I
uMhos
mg/I
mgA
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
n/a No
NIA
NIA
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
and field acidified Yes nla No )
mg/l Ni - Nickel
mgA Pb - Lead
Zn - Zinc
Ammonia Nitrogen
Other (Specify Compounds and Concentration Units)
mgll
mg/I
ug/I
ug/I
ug/1
ug/1
ug/1
ugA
ug/I
ug/1
ug/I
ug/I
ug/I
Fluoride
MIBK
Ag - Silver
Se- Selenium
Sodium
N/A
N/A
N/A
N/A
N/A
N/A
WA
N/A
ugA
ug/I
ug/I
mg/I
mg/l
ugA
ug/1
ugA
ug/I
Organics: (GC, GC/MS, HPLC)
(Specify test method it Attach lab report.)
Report attached? Yes (1) No X (2)
VOC method#
method#
method#
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate,
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am awa
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
and complete, and that the laboratory analytical data was produced
re that there are significant penalties for submitting
Ross M. Smith - Manager, Environmental Affairs
Permittee (of Authorizer S ent) Neme and Title - Please type or print
i r 2,0s V t /0 g
Signature of Permittee (or Authorized Agent) (D e)

Gf2OLINDVNATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC.- Aurora .Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806 County: Beaufort
Contact Person: Jack H. Taylor, Jr. Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sambled
-c
Well Identification Number (from Permit): CIW-7
Well Depth: 48.00 ft. Well Diamter: 4 inch
Screened Interval: 31.00 ft. to 45.25 ft
Depth to Water Level: N/A ft below measuring point
Measuring Point is N/A ft above land surface.
GALLONS of water pumped/bailed before sampling:
Field Analysis: pH 7.0 , Specific Conductance 690 uMhos
Temp. 24.6 oC, Odor NONE Appearance:
For Gro ndwaterTreatment
Sys ems Cheek One:
Influent (96)
Effluent (99)
0
CLEAR
TMENTOF ENVIRONIJIEHwpNA ,osfiL'RESOURCES'^
mat to-
WATE t QUALITY DIVISIONS GROUNDWATER SECTION
1'i s3�s I�an;setuicm te��`"iy,a :1'rf ,
-,fSLEIGI-r, C7,2769
hone (919)7*3221
PERMIT#: WI0700012 EXPIRATION DATE: 01/31/13
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
Inc X
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 7/22/2008
Date sample analyzed: 7/22/2008 to 7/23/2008
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples
COD
Coliform: MF Fecal
Coliform: MF Total
for metals were collected unfiltered
N/A
N/A
<1.0
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total N/A
pH (when analyzed)
TOC
mg/I
/100ml
/100m1
mg/1
N/A units
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
Yes
Nitrite (NO2 as N) 1
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
N/A mg/I Ca - Calcium
N/A mg/I Cd- Cadmium
N/A mg/I Chromium: Total
N/A mg/I Cu - Copper
N/A mgA Fe - Iron
N/A mg/I Hg - Mercury
N/A uMhos K- Potassium
N/A mgA Mg - Magnesium
N/A mgA Mn - Manganese
n/a
No and field acidified Yes n/a No )
N/A mg/I Ni - Nickel N/A
N/A mgll Pb - Lead N/A
N/A mgA Zn - Zinc N/A
ug/I
ug/I
ugll
N/A mg/I Ammonia Nitrogen mg/I
N/A ug/I Other (Specify Compounds and Concentration Units)
N/A ug/I Fluoride N/A mgA
N/A ug/I MIBK N/A ugll
N/A ug/I Ag - Silver N/A ug/I
N/A ug/I Se- Selenium N/A ug/I
N/A ugA Sodium N/A ug/I -
N/A ugA Organics: (GC, GC/MS, HPLC)
N/A ugll (Specify test method #. Attach lab report.)
N/A ug/I Report attached? Yes (1) No X (2)
N/A ug/I VOC method#
N/A ugA
. method#
. method#
I certify that, to the best of my knowledge and belief, the information submitted in this repor is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 3/2000
Ross M. Smith - Manager, Environmental Affairs
Permittee (of Authorized Agent) Name and Title - Please type or nn
DA 4.1, --772 ,� r , rr'7$ `/2. ( /O r
Signature of Permittee (orAut orized Agent) (Date)

PCS Phosphate Co., In " - Tank Farm Remediation S,'" 'am Quarterly Monitoring
Date:
Time:
Tech:
System Gaulle Pressures
SW W-1
CwW-1
CWW-7
File: 12-07-02
pc: TLa
Reference
Point MSL
Level Rol
to MSL
Ditch
12.91
Boy
Barge Sllp
10.59
0.9�
Water Level
Control Tank
e/ = MSL
Sand Layer Peizometers Level Indicators
Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
'
Level
Relative To
MSL Ft.
Well ID
TOC
Elevation
MSL'
TOC
Stc Wtr
Level '
Level
Relative To
MSL Fi.
Spz-1
10.47
'
y , 6 /
CJIO :
Cpz-1
10.51
/4',,D
-A 99
Spz-2
11.21
B/.l
.. S� C7O,,
Cpz-2
10.25
/✓�•73'
- 01. 20
Spz-3
11.87
0 /0
/Leevel
//i /
Cpz-3
11.12
41•3 7
-7`//
Spz-4
11.45
67. 73,
`/7'/73
CPW
9.65
/it y%
o?• C9g
Spz-5
11.45
960
/46
MWTF-IA•
14.35
..9-7 f
/9�.aS.?
a•doI
Spz-6
11.23
/D•67I0
/l3�
MWTF-1B•
14.36
377.i
Spz-7
11.59
/O...T /
/ 3!/
MWTF-1C•
14.44
/3/457
-00�°
77/
/-7
£. (09
Spz-8
11.57
l.O/
b-;a
MWTF-2A
14.05
6.3/
// S3
Spz-9
11.01
85/a5c?
MWTF-2B
14.02
Spz-10
12.16
63
7 5-
,7/• Wv
MWTF-2C
14.08
/6..S/S/
-agso
SPW
9.95
t�O/
494/
MWTF-3A
12.21
3.,47
e
MWTF-3B
12.18
/0O. 98
/q
MWTF-3C
12.19
/5, /0
/7d
i7� . //
Sand Layer And Croatan Formation Withdrawal Wells
Well ID
TOC
Elevation
MSL'
Max Stc
Wtr
Level Ft.
Pump
Activation Depth
Rel MSL
Max Level
Relative To
MSL Ft.
Control
Point
MSL'
Is Well
Pumping?
(Y)es/(N)o
Comments
SWW-1
10.70
70.&
6'
/
+1. to +2'
S
.VI -
.
CM-1
10.60
eV,
9'
, /66.
-/«1 9,
-2 ' to -1'
yC3
SW
9.99
/0.t
e./at
,/a-
6'
L/'/, /s2-
+1'to+2'
c/fi•.
CWW-2
10.23
1/•79
9'
- 7•. /
-2'to-1'
yPS
SWW-3
9.97
/76R
6'
-/ «B
+1' to+2'
r1-5
C1NW-3
9.95
/0.e/7
till
J.• ..3
-2 'to-1'
yeS
SWW-4
10.73
ji08
6'
- a. 9:Z.
+1' to+2'
r
..
CWW-4
10.73
35,1
9'
-S. bee,
-2 ' to-1'
y<5
SWW-5
10.80
7:8
6'
428
+1. to +2'
ei
CWW-5
10.74
6,/eZ
9'
-/i
arias
-2'to-1'
y'S
SWW-6
10.66
,$ '75-
6'
- 0' A-S
+1 ' to+2'
yes
CWW-6
9.92
l,./3
9'
2.8'
-2 'to-1'
/Ci
SWW-7
10.70
5 /OD
6'
-0.. 'VO
+1' to+2'
yfi
CWW-7
9.95
i/.%7
9'
-7, A6
-2'to-1'
yei
Revised 7/29/02
• Riser length added to TOC elevation 1/24/97
D:\DataWmms\WeII Fonn\Tank Farm Remed Wellsxls

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
May 2008 — July 2008
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Injection Water Well System
The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system
during the period.
Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs
Department. The total monthly and quarterly volumes of water injected as well as the month end water
level in the Water Level Control Tank are:
i1i
646.i`t+'fl�
S,k .�Yx n.+42 r �,lqc.
Yoh ��'ti v:' e Y L i Yk
lc -
$.rd, i Y Y ,: f %s, i f4i
�.3-1-ti .V?a,,.`1W,.� . �. , � �+-ti3�� ><w r _%
{+{ 1 {y '}
... ,s �Y,'"r, :.
. _ .rM
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
TANK
LEVEL
FEET, MSL
May
1,102,806.
0
1,102,806
24.7
15.0
June
1,028,944
0
1,028,944
23.8
15.0
July
976,650
0
976,650
22.6
15.0
TOTALS
3,108,400
0
3,108,400
\\aurdata2\users\AUR1DDW\Reports\2008\Quarterly\TFRAS Report Second Quarter 2008. doc
3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
r
S Y L Y ; 1 Zli C
�G N,??.. �. �wr� ....a< .,.<�I ir1M1._.
(t
1 1ne�i
f"�f
J1
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
May
127,039
12,626
139,665
3.2
June
234,024
0
234,024
5.4
July
90,998
0
90,998
2.1
TOTALS
452,060
12,626
464,687
Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWW) Pumps
On 6/19 replaced drive belts on compressor.
SWW-1: On 5/15 changed pump.
SWW-2: On 5/21 changed pump. On 5/26 replaced counter. On 7/9 changed pump.
SWW-3: On 5/21 reset counter.
SWW-4: On 5/12 changed counter. On 7/25 replaced pump.
SWW-5: On 5/15 replaced pump. On 7/22 reset head. On 7/31 replaced pump.
SWW-6:
SWW-7: On 5/28 flushed well.
\\aurdata2\users\AUR1DDW\Reports\2008\Quarterly\TFRAS Report Second Quarter 2008.doc
4

LI
Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1:
CW W-2:
CWW-3: On 5/28 flushed well.
CWW-4:
CWW-5:
CWW-6:
CWW-7: On 5/28 flushed pump.
\\aurdata2\users\AUR1DDW\Reports\2008\Quarterly\TFRAS Report Second Quarter 2008.doc
5