WI0600047_Other Correspondence_20090813

1 •
Vednesday. July 12, 2006
(PHYS) Physical Properties:
SECTION III - PHYSICAL DATA
s=_=
BOILING POINT: N/A
MELTING POINT: 550 C (1022 F)
(AT 760 MM HG)
SPECIFIC GRAVITY: 1.20 (H2O=1)
SOLUBILITY(H20): COMPLETE (100%)
PH: N/A ODOR THRESHOLD (P.P.M.): N/A
COEFFICIENT-WATER/OIL DISTRIBUTION: N/A
APPEARANCE & ODOR: WHITE GRANULES. ODORLESS.
(FHAZ) Fire Hazards:
VAPOR PRESSURE (MMHG): N/A
VAPOR DENSITY (AIR=1): N/A
EVAPORATION RATE: N/A
% VOLATILES BY VOLUME: 0 (21C)
PHYSICAL STATE: SOLID
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (CLOSED CUP): N/A
AUTOIGNITION TEMPERATURE: N/A
FLAMMABLE LIMITS: UPPER - N/A
FIRE EXTINQUISHING MEDIA
LOWER - N/A
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
SPECIAL FIRE -FIGHTING PROCEDURES
==
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
UNUSUAL FIRE & EXPLOSION HAZARDS
NONE IDENTIFIED.
TOXIC GASES PRODUCED
OXIDES OF PHOSPHORUS
EXPLOSION DATA -SENSITIVITY TO MECHANICAL IMPACT
NONE IDENTIFIED.
EXPLOSION DATA -SENSITIVITY TO STATIC DISCHARGE
NONE IDENTIFIED.
(HA2H) Health Hazards:
SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE (TLV/TWA): NOT ESTABLISHED
SHORT-TERM EXPOSURE LIMIT (STEL): NOT ESTABLISHED
PERMISSIBLE EXPOSURE LIMIT (PEL): NOT ESTABLISHED
TOXICITY OF COMPONENTS
ORAL MOUSE LD50 FOR SODIUM HEXAMETAPHOSPHATE 7250 MG/KG
INTRAPERITONEAL MOUSE LD50 FOR SODIUM HEXAMETAPHOSPHATE 870 MG/KG
SUBCUTANEOUS MOUSE LD50 FOR SODIUM HEXAMETAPHOSPHATE 1300 MG/KG
INTRAVENOUS MOUSE LD5O'FOR SODIUM HEXAMETAPHOSPHATE 62 MG/KG
CARCINOGENICITY: NTP: NO IARC: NO 2 LIST: NO OSHA REG: NO
CARCINOGENICITY
NONE IDENTIFIED.
REPRODUCTIVE EFFECTS
NONE IDENTIFIED.
2

1
ve6aaaday, July 12, 2006
EFFECTS OF OVEREXPOSURE
INHALATION:
SKIN CONTACT:
BYE CONTACT:
SKIN ABSORPTION:
INGESTION:
CHRONIC EFFECTS:
IRRITATION OF UPPER RESPIRATORY TRACT
IRRITATION
IRRITATION
NONE IDENTIFIED
HEADACHE, NAUSEA, VOMITING, DIZZINESS, GASTROINTESTINAL
IRRITATION
NONE IDENTIFIED
TARGET ORGANS : NONE IDENTIFIED
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
NONE IDENTIFIED
PRIMARY ROUTES OF ENTRY
INHALATION, INGESTION, SKIN CONTACT, EYE CONTACT
(AID) First Aid:
EMERGENCY AND FIRST AID PROCEDURES
INGESTION:
INHALATION:
SKIN CONTACT:
EYE CONTACT:
IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
PERSON TO FRESH AIR.
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH PLENTY OF
SOAP AND WATER FOR AT LEAST 15 MINUTES.
IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF
WATER, FOR AT LEAST 15 MINUTES.
(REGS) Regulations:
SARA/TITLE III HAZARD CATEGORIES AND LISTS
ACUTE: NO CHRONIC: NO FLAMMABILITY: NO PRESSURE: NO REACTIVITY: NO
EXTREMELY HAZARDOUS SUBSTANCE: NO
CERCLA HAZARDOUS SUBSTANCE: NO
SARA 313 TOXIC CHEMICALS: NO
TSCA INVENTORY: YES
(HAIR) Hazardous, Reactions:
STABILITY: STABLE
CONDITIONS TO AVOID:
INCOMPATIBLES:
SECTION VI - REACTIVITY DATA
v ==
HAZARDOUS POLYMERIZATION: WILL NOT
MOISTURE, AIR
NONE IDENTIFIED
DECOMPOSITION PRODUCTS: OXIDES OF PHOSPHORUS
(SPIL) Spillage Disposal:
==
OCCUR
SECTION VII - SPILL & DISPOSAL PROCEDURES
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
DISPOSAL PROCEDURE
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL
REGULATIONS.
3

1
Wednesday, July 12, 2006
(EQP) Protective Equipment:
=== =_
SECTION VIII - INDUSTRIAL PROTECTIVE EQUIPMENT
_
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO
KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION. CONDITIONS
EXIST. IF AIRBORNE CONCENTRATION IS HIGH, USE AN
APPROPRIATE RESPIRATOR OR DUST MASK.
EYE/SKIN PROTECTION: SAFETY GOGGLES, RUBBER GLOVES ARE RECOMMENDED.
(STOR) Storage Procedures:
_
SECTION IX - STORAGE AND HANDLING PRECAUTIONS
STORAGE CODE: (GENERAL STORAGE)
STORAGE REQUIREMENTS
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA.
STORE IN A DRY AREA.
(TRAM) Transportation Information:
SECTION X - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
DOMESTIC (D.O. T. )
PROPER SHIPPING NAME: CHEMICALS, N.O.S. (NON -REGULATED)
INTERNATIONAL (I.M.0.)
PROPER SHIPPING NAME: CHEMICALS, N.O.S. (NON -REGULATED)
MARINE POLLUTANTS: NO
AIR (I.C.A.O.)
PROPER SHIPPING NAME: CHEMICALS, N.0.8. (NON -REGULATED)
U.S. CUSTOMS HARMONIZATION NUMBER: 28353900002
N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED
DRCLAMM=
WE BELIEVE TIE TRANSPORTATION DATA AND REPPAEI(ES CONTAINED HEREIN TO RE PACTUAL AND THE OPINION OP QUAVERED EXPERTS. THE DATA P MEANT AS A
GUIDE TO TM OVERALL CASEPICATION OP TM IRODUC1 AND IS NOT PACKAGE SCE SPECIFIC. NOR SHARD IT BE TAKEN AS A WARRANTY OR BITAESPNTATION
FOR WINCE TR COMPANY ARTUMBS LEGAL RPSPONSIBDDY. TOM INFORMATION D OFITIRPD SOLELY FOR YOUR CONSIDERATION, INVPSTIOATION. AND
VERPIC TIoN. ANY USE OP THE DEFORMATION WUST BB DETERMENT() BYTE USER TO BE IN ACCORDANCE WIIN APPLICABLE INTERNATIONAL, FEDERAL. SPATE
AND LOCAL LAWS AND REOUTATONS. PEI SHIPPER RBQUR!MENIS UNDER DSO. LATA, ATID 49CFR 1721 AND EMPLOYER IRAININGA9CPR 1731. Tim WFOR1MT10N IN
TNL7 MAMMAL SAFETY DATA MST WAS PREPARED FROM INFORMATION ESTEEMED ON THE CImMGL OPORMATNON SYSTEM AS PROVIDED BY OS. INC. AND
MEETS 18E REQUREMENT3 OF THB UHTRD STALES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS PROMULGATED THEREUNDER. (19 C+R 19R0.1100 ET.
SEQ.)AND THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. TES DOCUMENT IB DV1@DIBD ONLY AS A GUAR TO THE APPROPRIATE
PRECAUTIONARY HANDLING OF THE MATERIAL RV A PERSON TRAINED IN, OR SUPERVISED BYA PERSON TRAINED IN, CHEMICAL HANDLING. THE USER IS
RESPONSIBLE FOR MERMEID10TIE PRECAUTIONS Ate DANGERS TIP TES COMICAL FOR EMS OR MR PARTICULAR APA.1CATON. DEPEIDINO ON USA®.
PROTECTIVE O.ODENG INCLUDING BYE AND PARE GUARDS AND MEDIATORS MUST RE USED 10 AVOID CONTACT WTM MATERIEL OR !DIADEM OIFJIICAL
VAPORS/FUMES. EXFOIDEE7D Das PRoDUCP MAY HAVE SERIOUS ADVERSE MALTS BPPECTS. TIES CHEMICAL MAY INTERACT Wan OT st suisANCES SE'N1MTR
PO'SENILA. vas APE SO VARPD, SUPPLIER CANNOT WARN OF ALL OP THE P01EV11A1. DANGERS OP USE at INTIRACTON WTH OILER =COALS OR MATE MI.3.
SUPPLER DISMAPES ANY WARRANTERS, E7RESPD OR DOLED WITH REGARD TO TM PRODUCT SUPPLED HEREUNDER. ITS MEtCH*NTAIL1IY OR ITS EMNE55 FORA
PARTCRAR PURPOSE. ME USER SHOULD RENm2= TEAT TES PRODUCT CAN CAUSE SEVERE INJURY AND EVES DEA11L ESPECIALLY IF IMPROPERLY HANDLE) OR
THE KNOWN DANGERS OP DID ABE NOT MIMED. READ ALL PRECAUTIONARY INFORMATION. AS NEW DONSffiGID GENERAL SAFETY DPOLYA11ON BECOMES
AVAILABLE. SUPP = WILL PEIDDIGILY REVISE TENT MATERIAL 141E1Y0ATA MET. NOTE: 1]®MTREC CAMTBC, AND NATIONAL RESPONSE MITER
EMERGENCY TELEPHONE NUMBERS AM TO BE USED OE.YIN TICE EVER OP CP®9CAI. EMPAGE CEPS MOLVINOA WELL. LEAK. PRE, EXPOSURE. OR ACCIDENT
INVOLVING C9!EWPAY S. ALL NON.EME1C8MCY QUESTIONS SHOED BE DIRECTED TO LOSIOMER SERVICE.
4

1
•ednesday, July 12, 2006
Effective Date:6/1/93
Rev. No.: A
Title: Material Safety Data Sheet
SODIUM HEXAMETAPHOSPHATE
Page(s):4
Doc. No.: COC-MSD37
Prepared by: Clare Welker
Approved by: Clare Welker
(MID) Material Identification:
MATERIAL SAFETY DATA SHEET
SODIUM HEXAMETAPHOSPHATE
=======.======================O=CC9a=======... -J pas=============YID====
SECTION I - PRODUCT IDENTIFICATION
acs_OCpaLYYCCaamY®C O=MONCCI____ YYYCtlGOelaa==== OCaa QYYYYYY====
EMERGENCY CONTACT: CHEMTREC 1-800-424-9300 NOTE: EMERGENCY TELEPHONE NUMBERS ARE TO
BE USED ONLY IN THE EVENT OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE,
EXPOSURE, OR ACCIDENT INVOLVING CHEMICALS. ALL NON -EMERGENCY QUESTIONS SHOULD HE
DIRECTED TO CUSTOMER SERVICE.
PRODUCT NAME:
COMMON SYNONYMS:
CHEMICAL FAMILY:
FORMULA:
FORMULA WT.:
CAS NO.:
NIOSH/RTECS NO.:
PRODUCT USE:
SODIUM HEXAMETAPHOSPHATE
METAPHOSPHORIC ACID, HEXASODIUM SALT; GLASSY SODIUM
METAPHOSPHATE; SHMP
INORGANIC SODIUM COMPOUNDS
(NAP03)D
611.77
10124-56-8
OY3675000
Cammercial Use
(PHA2) Primary Hazards:
PRECAUTIONARY LABELING
HEALTH
FLAMMABILITY
REACTIVITY
CONTACT
- 1 SLIGHT'
- 0 NONE
- 0 NONE
- 1 SLIGHT
LABORATORY PROTECTIVE EQUIPMENT: GOGGLES; LAB COAT
U.S. PRECAUTIONARY LABELING
CAUTION
CAUSES IRRITATION.. MAYBE HARMFUL IF SWALLOWED OR INHALED. AVOID CONTACT WITH EYES.
SKIN, CLOTHING. DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
INTERNATIONAL LABELING
AVOID CONTACT WITH EYES. AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH
PLENTY OF WATER. KEEP CONTAINER TIGHTLY CLOSED.
(COMP) Components:
SECTION II - COMPONENTS
COMPONENT
CAS NO. WEIGHT% OSHA/PEL ACGIH/TLV
SODIUM HEXAMETAPHOSPHATE
10124-56-8 90-100 N/E N/E
1

CLF SERVICES Friday, July 07, 2006
SodiumBicarbonate (144-55-8) Date: 08/01/2005
Changes in information are as follows:
Section 7 (Handling and Storage)
Section 16 (Other Information)
FMC Logo - FMC Corporation Trademark
® 2005 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. It is a violation of Federal law to
use this product in a manner inconsistent with its labeling. Further, since the conditionsand methods of use
are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as
to any results obtained or arising from any use of the product or reliance on such information
Page 9 of 9

CLP SERVICES Friday, July 07, 2000
Sodium Bicarbonate (144-55-8) Date: 08/012005
Product Identification Number: None
Hazard Classification / Division: None
Ingredient Disclosure List: Not listed
COMMENTS:
CLEAN WATER ACT (CWA) - SECTION 307 / 311
Not listed as a hazardous pollutant (40 CFR 116), nor as a toxic pollutant (40 CFR 401.15)
CLEAN AIR ACT (CAA) - SECTION 112
Not regulated under the chemical accident prevention provisoins (40 CFR 68)
16.OTHER INFORMATION
HMIS
Health
0
Flammability
0
Physical Hazard
0
Personal Protection (PPE)
B
Protection = B (Safety glasses and gloves)
HMIS = Hazardous Materials Identification System
Degree of Hazard Code:
4 = Severe
3 = Serious
2 = Moderate
1= Slight
0 = Minimal
NFPA
Health
0
Flammability
0
Reactivity
0
Special
None
No special requirements
NFPA = National Fire Protection Association
Degree of Hazard Code:
4 = Extreme
3 = High
2 = Moderate
1= Slight
0 = Insignificant
REVISION SUMMARY:
This MSDS replaces Revision #3, dated January 26, 2004.
Page 8 of 9

Q.P SERVICES Friday, July 07, 2006
SodiumBicarbonate (144-55-8) Date: 08/012005
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
ADDITIONAL INFORMATION:
Not regulated
•
ADR - EUROPEAN AGREEMENT CONCERNING THE
INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
ADDITIONAL INFORMATION: Not regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Not listed
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
No TPQ for this product
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
Not listed
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABHJTY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Not applicable
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA INVENTORY STATUS (40 CFR 710):
Listed
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA)
RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261):
Waste Number. Refer to Section 13 "Disposal Considerations" for RCRA status.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
Page 7 of 9

CLF SERVICES Friday, July 07, 200b'
Sodium Bicarbonate (144-55-8) Date: 08/012005
CARCINOGENICITY:
NTP: Not listed
IARC: Not listed
OSHA: Not listed
OTHER: (ACGIH) Not listed
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: 48 hr LCso = 2000 mg/L (Culex sp. larvae
or mosquito)
• CHEMICAL FATE INFORMATION: No data available for the product.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: When this product is discarded or disposed of, as purchased, it is
neither a characteristic nora listed hazardous waste according to US Federal RCRA regulations (40 CFR
261). As a non -hazardous waste the material may be disposed of in a landfill in accordance with '
government regulations; check local or state regulations for applicable requirements prior to disposal. Any
processing, usage, alteration, chemical additions to, or contamination of, the product may alter the disposal
requirements. Under Federal regulations, it is the generator's responsibility to determine if a waste is a
hazardous waste.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
PROPER SHIPPING NAME: Not regulated
PRIMARY HAZARD CLASS / DIVISION: Not applicable
UN/NA NUMBER: None
LABEL(S): Not applicable
PLACARD(S): Not applicable
MARKING(S): Not applicable
ADDITIONAL INFORMATION: Hazardous Substance/RQ: Not applicable
49 STCC Number: Not applicable
Page 6 of 9

Q.P SERVICES Friday, July 07, 2006
Sodium Bicarbonate (144-55-8) Date: 08/01/2005
VAPOR PRESSURE: Not available
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Contact with acids except under controlled
conditions.
STABILITY: Stable
POLYMERIZATION: Will not occur
INCOMPATIBLE MATERIALS: Reacts with acids to release carbon dioxide gas and
heat.
HAZARDOUS DECOMPOSITION PRODUCTS: None
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Non -irritating (rabbit) J. Amer. Coll. ToxicoL 1987
SHIN EFFECTS: Non-iaitating (rabbit) J. Amer. Coll. ToxicoL 1987
DERMAL LDso: No data available for the product.
ORAL LDso: 20% sluny: 4,300 mg/kg (rat)
50 % slurry: 6,000 mg/kg (rat)
Gosselin, Smith & Hodge, Clinical Tox. of Comm. Products, 1984
INHALATION LCsa: No data available for the product.
TARGET ORGANS: None
ACUTE EFFECTS FROM OVEREXPOSURE: This product, when dry, is generally
non -irritating to intact skin. However, when moisture is present, it can be irritating to damaged skin and
can create irritation after long exposures. This product is approved for use as a food ingredient and is
Generally Recognized As Safe (GRAS). No significant acute toxicological effects expected
CHRONIC EFFECTS FROM OVEREXPOSURE: Administration of large doses of
sodium bicarbonate to patients with renal insufficiency can produce systemic alkalosis.
Page 5 of 9

CI& SERVICES Friday, July 07, 2000 -
SodiumBicarbonate (144-55-8) Date: 08/012005
after long exposures when moisture is present. Under such conditions, gloves and long-sleeved
clothing are recommended to minimize skin contact.
COMMENTS:
ADDITIONAL EXPOSURE GUIDELINES:
Federal guidelines teat the ingredients) in this product as a nuisance dustas no product -specific
guidelines have been Issued for exposure. As with all nuisance dusts, worker breating zone concentrations
should be measured by validated sampling and analytical methods. The following limits (OSHA and
MSHA) apply to this material:
Particulates Not Otherwise Regulated:
OSHA (PEL / TWA): 15 mg/m3 (total dust); 5'mg/m' (resp fraction)
MSHA (PEL /TWA): 10 mg/m3 (total dust)
The information noted above provides general guidance for handling this product. Specific work
environments and material handling practices will dictate the selection and use of personal protection
equipment (PPE).
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR:
APPEARANCE:
AUTOIGNTTION TEMPERATL1REi
BOILING POINT:
COEFFICIENT OF OIL / WATER:
DENSITY / WEIGHT PER VOLUME:
EVAPORATION RATE:
FLASH POINT:
MELTING POINT:
ODOR THRESHOLD:
OXIDIZING PROPERTIES:
PERCENT VOLATILE:
PH:
SOLUBILITY IN WATER
SPECIFIC GRAVITY:
VAPOR DENSITY:
Odorless
White, granular solid.
Not applicable
Not applicable
Not available
0.88 g/mL
Not applicable Butyl Acetate = 1)
Non-combustible
Decomposes
Not applicable
Not applicable
Not available
8.3 (1% solution)
% by wt. @ 20°C (68°F): 9.0
(li=O = 1) 2.20
Not applicable (Air = 1)
Page 4 of 9

CBP sznVxCss Ssiday, July 07, 2006
Sodium Bicarbonate (143-55-8) Date: 08/01/2005
6. ACCIDENTAL RELEASE MEASURES
COMMENTS: PERSONAL PRECAUTIONS: Refer to Section 8 "Exposure Controls / Personal
Protection".
CLEAN-UP: This product, if spilled, can be recovered and re -used if contamination does not present a
problem. Vacuum or sweep up the material. If the spilled product is unusable due to contamination,
consult state or federal environmental agencies for acceptable disposal procedures and locations. See
Section 13 "Disposal Considerations".
NOTIFICATION REQUIREMENTS: Federal regulations do not require notification for spills of this
product. State and local regulations may contain different requirements; consult local authorities.
7. HANDLING AND STORAGE
HANDLING: Use air conveying/mechanical systems for bullc transfer to storage. For manual
handling of bulk transfer use mechanical ventilation to remove airborne dust from railcar, ship or truck
Use approved respiratory protection when ventilation systems are not available. Selection of respirators is
based on the dust cloud generated.
STORAGE: Protect from excessive heat and moisture. Store away from acids.
COMMENTS: Use general room dilution or local exhaust ventilation when excessive dust is
expected in the work environment.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Where possible, provide general mechanical and/or Local
exhaust ventilation to prevent release of airborne dust into the work environment.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Appropriate eye and face protection equipment (ANSI Z87
approved) should be selected for the particular use intended for this material. Safety glasses with
side shields are recommended.
RESPIRATORY: Whenever dust in the worker's breathing zone cannot be controlled with
ventilation or other engineering means, workers should wear respirators or dust masks approved by
NIOSH/MSHA, EU CEN or comparable certification organization to protect them against airborne
dust.
PROTECTIVE CLOTHING: Dry product is generally non -irritating to intact skin.
However. this product can be irritating where skin has been damaged and can create skin irritation
Page 3 of 9

CLP SERVICES Friday, July 07, 2D0I1'
SodiumBicarbonate (144-55-8)
Date: 08/012005
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
CAS#
WL%
EC No.
EC Class
Sodium Bicarbonate
14-55-8
100
205-633-8
Not classified
4. FIRST AID MEASURES
EYES: Flush with plenty of water. Get medical attention if irritation occurs and persists.
SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists.
INGESTION: Drink plenty of water. Never give anything by mouth to an unconscious person. If any
discomfort persists, obtain medical attention.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, obtain
medical attention.
NOTES TO MEDICAL DOCTOR: Internal toxicity is low. Treatment is symptomatic and
supportive.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water, water fog, carbon dioxide (CO2), dry chemical
FIRE I EXPLOSION HAZARDS: None
FIRE FIGHTING PROCEDURES: None
FLAMMABLE LIMITS: Not applicable
HAZARDOUS COMBUSTION PRODUCTS: None
SENSITIVITY TO IMPACT: None
SENSITIVITY TO STATIC DISCHARGE: None
Page 2 of 9

CL4 SERVICES Friday, July 07, 2006
MATERIAL SAFETY DATA SHEET
Sodium Bicarbonate
MSDS Ref. No.: 144-55-8
Date Approved: 08/012005
Revlslon No.: 4
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the Canada's Workplace Hazardous Materials Information System (WHMIS)
and, the EC Directive, 2001/58/EC.
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
SYNONYMS:
GENERAL USE:
MANUFACTURER
FMC Wyoming Corporation
Alkali Chemicals Division
1735 Market Street
Philadelphia, PA 19103
[phone] (General Information)
Sodium Bicarbonate
Baking Soda, Bicarbonate of Soda
Leavening agent; cleaner ingredient, bath salt ingredient, water
softener, diaper rinse ingredient, feed additive.
This chemical is certified to ANSI/NSF Standard 60, Drinking Water
Chemicals -Health Effects (as packaged in the original, unopened
container). The maximum dosage level for this chemical is 100 mg/L
EMERGENCY TELEPHONE NUMBERS
[phone] (CHEMTREC - U.S.)
[phone] (Medical - Call Collect)
[phone] (Plant - Green River, WY)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
• White, odorless, granular solid.
• Product is non-combustible.
• Reacts with acids to release carbon dioxide gas and heat.
POTENTIAL HEALTH EFFECTS: No significant health effects anticipated.
Page 1 of 9

1
WILCLEAR
MSDS REPORT (1)
Emergency and First Aid Procedures:
SKIN: In case of contact with skin, immediately wash with soap and water while removing
contaminated clothing.
EYE: In case of contact with eyes, immediately flush eyes with water for at least 15 minutes, lifting
eyelids during flushing to facilitate irrigation. Get medical attention if necessary.
INHALATION: If inhaled, remove person from contaminated atmosphere to fresh air
INGESTION: If swallowed, get medical attention.
ttttfIttttltii irk* ktktittthkttttkiN4HMtltkMitikttfittlktititlikfHHtittttittitftkfiiiitliMftifittittttttttttftittki
PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to Be Taken in Case Material is Released or Spilled: Contain spill and place material in drum for
disposal. Dispose of according to all local, state and federal regulations at an approved waste treatment
facility.
Precautions to Be Taken in Handling and Storing: Store in cool, dry area to preserve product quality.
Other Precautions: NA
tetttkltttlttttfattmtttttttttmtttttttt************t1tfaftf+tt«wttttkt*****************************
CONTROL MEASURES/PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection (Specify Type): None.
Ventilation: General Ventilation: Is recommended.
Local Exhaust: Is recommended.
Other: NA
Protective Gloves:, Are recommended.
Eye Protection: Is recommended.
Other Protective Clothing or Equipment: NA
Work/Hygienic Practices: NA
END OF REPORT.
Page 3

WILCLEAR
MSDS REPORT (1)
COMPOSITION/INFORMATION ON INGREDIENTS
tent **rtat***ata wti*w_+*`+*K*ta*»**+`a
Component Name: SODIUM LACTATE
Product: Yes Percent: 60
CAS No.: 72-17-3
Exposure Limits
Limit Note: OSHA PPM: NA \ ACGIH PPM: NA \ OSHA STEL PPM: NA
Component Name: WATER
Percent: 40
CAS No.: 7732-18-5
Exposure Limits
Limit Note: OSHA PPM: NA \ ACGIH PPM: NA \ OSHA STEL PPM: NA
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HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Hazardous Components
(optional) Specific Chemical
Identity: Common Name(s)
None
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OSHA PEL ACGIH TLV Other Limits % Recommended
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FIRE AND EXPLOSION HAZARD DATA
Flash Point: NA Flammable Limits: NA LEL: NA
Extinguishing Media: Water, Carbon Dioxide or Dry chemical.
Special Fire Fighting procedures: Wear self-contained breathing apparatus.
Unusual Fire and Explosion Hazards: Fire may produce irritating or toxic fumes.
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REACTIVITY DATA
Stability: Stable. Conditions to Avoid: NA
Incompatibility (Materials to Avoid): NA
Hazardous Decomposition or Byproducts; NA
Hazardous Polymerization: Will not occur.
UEL: NA
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HEALTH HAZARD DATA
Route(s) of Entry: Inhalation? Yes Skin? NA Ingestion? Yes
Health Hazards (Acute and chronic): No specific data. Low order of toxicity. The chemical, physical, and
toxicological properties have not been thoroughly investigated.
Carcinogenicity: NTP? NA IARC Monographs? NA OSHA Regulated? NA
Signs and symptoms of Exposure: NA
Medical Conditions Generally Aggravated by Exposure: NA
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TSCA Registered? Yes

/i•
WILCLEAR
MSDS REPORT (1)
Status: Current
Status Date; 08/08/2003
Product Name: WILCLEAR® SODIUM LACTATE 60% SOLUTION, U.S.P.
Current Company Information:
JRW Bioremediation, LLC
14321 W. 96TH TERRACE
LENEXA, KS 66215.
Fax: [phone]
MSDS Prepared: 12/07/1994
MSDS Revised: 08/08/2003
Emergency: 913-438-5544
Formula: CH3-CHOH-COONa
Keyword: ORGANIC ACID SALT
Stock Item(s): S-110-2
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Physical/Chemical Characteristics
Boiling Point: 105 iC
Specific Gravity: 1.323 H20=1 @ 20`C
Vapor Density: Air=1 NA
Evaporation Rate: NA
Melt/Freeze Point: NA
pH: 6.5-7.5
% Volatile: NA
Vapor Pressure: NA
Pour Point: NA
Viscosity: 100cP @ 20'C
Molecular weight: 112.07
Solubility In Water: SOLUBLE
Appearance/Odor: CLEAR AND COLORLESS LIQUID, ODORLESS
Physical State: Liquid
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FIRE AND EXPLOSION DATA:
Closed Cup Flash Pt.: NA
Open cup Flash Point: NA
Auto Ignition: NA
Fire Point: NA
LEL/LFL: NA
UEL/UFL: NA
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DOT INFORMATION:
DOT hazard class: NA
Label: NA
Proper shipping Name: WilClear®SODIUM LACTATE 60%
Page 1