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HomeMy WebLinkAboutWI0600060_Other Correspondence_20100617amec9 ATTACHMENT C INJECTION FLUID COMPOSITION AMEC plans to utilize a solution of emulsified vegetable oil with 4% sodium lactate. A copy of the Material Safety Data Sheet is attached. The material will be diluted with potable water and injected as a solution consisting of 99% water and 1 % injectant. AMEC Earth & Environmental, Inc. 2200 Gateway Centre Blvd, Suite 205 Morrisville, NC 27560 www.amec.com Tel — (919) 447-2750 Fax — (919) 447-2751 MATERIAL SAFETY DATA SHEET EMULSIFIED EDIBLE OIL SUBSTRATE (EOS®450) D.O.T. HAZARD CLASSIFICATION: NONE MANUFACTURER'S NAME EOS Remediation, LLC 1101 Nowell Road Raleigh,NC 27607 www.E0SRemediation.com DATE OF PREPARATION 01/24/03, Rev. 5/4/2009 HEALTH FLAMMABILITY REACTIVITY PERSONAL PROTECTION --HMIS--- 1 0 0 B INFORMATION TELEPHONE NO. 919-873-2204 SECTION I - PRODUCT IDENTIFICATION PRODUCT NAME EOSe450 PRODUCT CLASS VEGETABLE OIL BASED EMULSION CAS NUMBER MIXTURE SECTION II - HAZARDOUS INGREDIENTS THIS PRODUCT IS A MIXTURE OF EDIBLE FOOD GRADE ADDITIVES AND CONTAINS NO HAZARDOUS INGREDIENTS. COMPONENT(S) SOYBEAN OIL SODIUM LACTATE FOOD ADDITIVES / EMULSIFIERS / PRESERVATIVES (PROPRIETARY) WATER % BY CAS NO. WEIGHT 45 — 50 8001-22-7 4 867-56-1 6-10 BALANCE EXPOSURE LIMIT OSHA PEL ACGIH TLV - TWA 15 mg/m3 NA EMULSIFIED EDIBLE OIL SUBSTRATE (EOS® 450) SECTION III - PHYSICAL DATA BOILING POINT: SPECIFIC GRAVITY (H20 = 1): VAPOR PRESSURE: PERCENT VOLATILE BY VOLUME (%): VAPOR DENSITY: EVAPORATION RATE: SOLUBILITY IN WATER: APPEARANCE AND ODOR: 212°F 0.97 NOT ESTABLISHED 24 (AS WATER) HEAVIER THAN AIR NOT ESTABLISHED SOLUBLE OFF WHITE LIQUID WITH VEGETABLE OIL ODOR SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: FLAMMABLE LIMITS: EXTINGUISHING MEDIA: UNUSUAL FIRE AND EXPLOSION HAZARDS: SPECIAL FIRE FIGHTING PROCEDURES: >300°F NOT ESTABLISHED CO2, FOAM, DRY CHEMICAL NOTE: WATER, FOG, AND FOAM MAY CAUSE FROTHING AND SPATTERING. BURNING WILL CAUSE OXIDES OF CARBON. WEAR SELF CONTAINED BREATHING APPARATUS AND CHEMICAL RESISTANT CLOTHING. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. SECTION V - PHYSICAL HAZARDS STABILITY: STABLE CONDITIONS TO AVOID: NONE INCOMPATIBILITY: STRONG ACIDS AND OXIDIZERS. HAZARDOUS DECOMPOSITION THERMAL DECOMPOSITION MAY PRODUCT OXIDES PRODUCTS: OF CARBON. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR SECTION VI - HEALTH HAZARDS SIGNS AND SYMPTOMS OF EXPOSURE: 1. Acute Overexposure - NONE 2. Chronic Overexposure - NONE MEDICAL CONDITIONS GENERALLY NONE KNOWN AGGRAVATED BY EXPOSURE: CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: N.T.P. - NO I.A.R.C. - NO OSHA - NO 2 EMULSIFIED EDIBLE OIL SUBSTRATE (EOS® 450) EMERGENCY 1.) Inhalation- 2.) Eyes- 3.) Skin- 4.) Ingestion - AND FIRST AID PROCEDURES: REMOVE TO FRESH AIR. FLUSH WITH WATER FOR 15 MINUTES, IF IRRITATION PERSISTS SEE PHYSICIAN. WASH WITH MILD SOAP AND WATER. PRODUCT IS NON -TOXIC. IF NAUSEA OCCURS, INDUCE VOMITING AND SEEK MEDICAL ATTENTION. SECTION VII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: VENTILATION: PROTECTIVE GLOVES: EYE PROTECTION: OTHER PROTECTIVE CLOTHING OR EQUIPMENT: NOT NORMALLY REQUIRED LOCAL EXHAUST NOT NORMALLY REQUIRED NOT NORMALLY REQUIRED NONE SECTION VIII - SPECIAL PRECAUTIONS AND SPILULEAK PROCEDURES PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: OTHER PRECAUTIONS: STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED: WASTE DISPOSAL METHODS: DO NOT STORE NEAR EXCESSIVE HEAT OR OXIDIZERS. NONE SOAK UP WITH DRY ABSORBENT AND FLUSH AREA WITH LARGE AMOUNTS OF WATER. DISPOSE OF ACCORDING TO FEDERAL, STATE, AND LOCAL REGULATIONS. SECTION IX - ADDITIONAL REGULATORY INFORMATION SARA TITLE III UNDER THE PROVISIONS OF TITLE 111, SECTION 311/312 OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATIONS ACT, THIS PRODUCT IS CLASSIFIED INTO THE FOLLOWING HAZARD CATEGORIES: NONE THIS PRODUCT DOES NOT CONTAIN SECTION 313 REPORTABLE INGREDIENTS. THE INFORMATION CONTAINED HEREIN IS BASED ON AVAILABLE DATA AND IS BELIEVED TO BE CORRECT. HOWEVER, EOS REMEDIATION, INC. MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED THEREOF. THIS INFORMATION AND PRODUCT ARE FURNISHED ON THE CONDITION THAT THE PERSON RECEIVING THEM SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE PRODUCT FOR HIS/HER PARTICULAR PURPOSE. 3 EMULSIFIED EDIBLE OIL SUBSTRATE (EOS® 450) T:\EOS Remediation\Products\EOS\MSDS\MSDS EOS 450.doc 4 Description & Use: Chemical Physical Properties: Packaging: Product Information Sheet EOS® 450 EOS® 450 is an economical food -grade oil/water emulsion manufactured with a tightly controlled droplet size that is used for groundwater remediation of chlorinated solvents, perchlorate, energetics, acid rock drainage, oxidized metals and other recalcitrant chemicals that can be degraded under anaerobic conditions. EOS® 450 is formulated with both rapidly -biodegradable substrates to "jump start" bacterial growth and slow -release biodegradable substrates that promote growth of halorespiring and other Indigenous bacteria. EOS® 450 has been proven to be active in the subsurface for longer than three years and is non -toxic to the environment. Due to the small oil droplet size and negative surface charge, EOS° 450 can be distributed across a large aquifer volume. EOS® 450 is shipped as a concentrate that is easily diluted with water in the field. Because the droplet size is "built in" during the manufacturing process, it is not necessary to use a complicated field mixing process. Simple mixing with water is all that is required to prepare a high quality emulsion. EOS® 450 has a viscosity low enough that it can be mixed and pumped with most commonly available pumps or metered with diluter (DosatronTm). EOS® 450 is most commonly injected after being diluted be- tween a range of 4:1 to 20:1 (water:EOS® 450). However, actual dilution rates may depend on site condi- tions. All injections should utilize a water flush cycle to push the remaining substrate out of the well into the formation. Oil Emulsion Concentrate Typical Soybean Oil (refined and bleached) (% by wt) 49.9 Rapidly Biodegradable Soluble Substrate (% by wt) 4.0 Food Additives (% by wt) 10 Specific Gravity (H20 = 1) 0.98 pH (Standard units) 5.0 Median Oil Droplet Size (pM) 1.4 Organic Carbon (% by wt) 63 Viscosity (cP) 100-140 Electron Equivalents per Kg EOS® 450 240 Shipped in 55-gallon drums (420 Ibs net contents), 275-gallon IBC totes (2,100 Ibs net contents) or bulk tankers (40,000 Ibs min.) Storage & Handling: Store indoors and protect from exposure to temperature extremes (<32°F or > 120° F). EOS® 450 should be diluted with water prior to use. Workers should use eye protection and prevent skin contact. Consult the MSDS for addi- tional information before using EOS® 450. Clean up spilled product promptly and dispose of in accordance with all regulations. For best performance, use within 30 days of delivery. NOTICE The information contained herein is, to the best of our knowledge and belief, accurate. Any recommendations or suggestions made are without warranty or guarantee of results since conditions of handling and of use are beyond our control. We, therefore, assume no liability for loss or damage incurred by following these suggestions. EOS Remediation warrants only that this product will meet the specifications set forth, any other representation or warranty, either expressed or implied, is specifically disclaimed including warranties of fitness for a particular purpose and of merchantability. EOS Remediation's only obligation shall be to replace such quantity of the product proved to be defective before using. User shall deter- mine the suitability of the product for user's intended application and user assumes all risk and liability whatsoever in connection therewith. EOS Remediation shall not be liable In tort, contract or under any theory for any loss or damage, incidental or consequentia, arising out of the use of or the inability to use the product. EOS Remediation, LLC • EOS Remediation, LLC • 1101 Nowell Road • Raleigh, NC 27607 • 888.873.2204 • • www.eosremediation.com • info@eosremediation.com •