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WQ0004797_Monitoring - 05-2021_20210628 (2)
Monitoring Report Submittal ............................................................................................................................................ Permit Number #* WQ0004797 Name of Facility:* Month:* May Report Information Clement Pappas NC,LLC Type * NDMR, NDAR-1, NDAR-2, NDMLR GW-59 Confirmation Email Address:* Name of Submitter:* Signature: Date of submittal: Year:* 2021 Upload Document* 5-2021 signed 1.05MB NDAR, NDMR. pdf PDF Only May 2021 Groundwater 3.94MB report signed.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). dale.wolfe@lassonde.com Dale Wolfe 6/28/2021 This will be filled in automatically Initial Review Reviewer: Saunders, Erickson G Is the project number correct?* WQ0004797 Is the monitoring report r Yes r No accepted?* Regional Office* Asheville Accepted Date: 6/29/2021 AnchorQEAof North Carolina, PLLC ANCHOR 231 Haywood Street Asheville, North Carolina 28801 tZ QEA 828.281.3350 June 21, 2021 Billy Watson Lassonde Pappas & Co., Inc. 125 Industrial Park Road Hendersonville, North Carolina 28792 Re: May 2021 Groundwater Sampling Event Clement Pappas NC, LLC Dear Mr. Watson, Anchor QEA of North Carolina, PLLC, is pleased to present the results of the May 2021 water quality monitoring event at the Clement Pappas NC, LLC (Clement Pappas) facility (the Site), located at 485 Brookside Camp Road in Hendersonville, North Carolina. The company that operates the facility rebranded to Lassonde Pappas & Company in 2016. However, for permitting purposes, the Hendersonville facility retains the Clement Pappas NC LLC name that is designated on the property deed. Groundwater Quality Anchor QEA performed the groundwater sampling event at the subject facility (the Site) on May 11, 2021. AS ite location map is included in Figure 1. The groundwater sampling event was performed in accordance with North Carolina Department of Environmental Quality (DEQ wastewater irrigation system permit No. WQ0004797 issued September 3, 2015, and renewed May 15, 2020 (referred to as the permit in this letter; effective September 1, 2020, and expires July 31, 2026). Anchor QEA used low -flow methods to purge and collect groundwater samples from six monitoring wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. Monitoring well MW-9 was installed April 14, 2015, to replace the previously damaged monitoring well MW-2R. The locations of the monitoring wells are shown in Figure 2. Anchor QEA submitted the groundwater samples to Pace Analytical Services, Inc., a North Carolina -certified laboratory, for analysis of the parameters specified in the permit, as follows: • Total organic carbon • Chloride • Fecal coliform • Total ammonia Groundwater Elevation • Total nitrate • Phosphorous • Total dissolved solids Table 1 summarizes current and historical groundwater elevations from November 2018 to May 2021. Except for monitoring well MW-9, all monitoring well concrete pads and top -of -well casing elevations \\athena\ashevile\Prgects\Clanent Pappas\Reports\2021\M3y\Source Files\Text\20210621_May 2021 Groundwater Sampling Event Gement Pappas NC, LLC.docx June21, 2021 Page 2 were surveyed by Wes Cole Land Surveying, PA, on November 21, 2012. Monitoring well MW-9 was surveyed by Wes Cole Land Surveying, PA, on May 29, 2015. The surveyed top -of -casing elevations are indicated in Table 1. Groundwater Analytical Results Table 2 summarizes the current and historical groundwater analytical results from November 2018 to May 2021. During the current sampling event, the parameters analyzed were below or within the groundwater standards provided in the permit,' except for nitrate and pH, which are described as follows: • The pH of the samples collected from MW-4 (5.8 standard units [SU]), MW-5 (5.5 SU), MW-6 (5.5 SU), MW-7R (5.2 SU), and MW-9 (5.4 SU) were below the groundwater standard range of 6.5 to 8.5 SU. The sample collected from the background monitoring well, MW-5, has a pH that is similar to the other groundwater monitoring wells. • The nitrate concentration exceeded the permit groundwater standard of 10 milligrams per liter (mg/L) in the sample collected from one monitoring well, MW-7R (40.4 mg/L). The Title 15A, North Carolina Administrative Code [NCAC], Subchapter 2L, Section .0202 standard (2L standard) for total coliform is 1 colony -forming unit per 100 milliliters (1 CFU/100 mL). There is not a specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal coliform. The following summarizes fecal coliform results from the groundwater monitoring wells: • Fecal coliform concentrations exceeded the 2L standard for total coliform in monitoring well MW-6 (5.0 CFU/100 mL) but was not detected at or above laboratory detection limits in the samples collected from all other monitoring wells. Surface Water Quality Beginning in May 2017, Clement Pappas voluntarily collected surface water samples from Mud Creek, analyzing for the same constituents as those sampled in groundwater. The renewed permit issued in May 2020 and effective September 2020 requires semiannual sampling of the surface water locations. Sampling point SW-1 is located upstream of the Site, and sampling point SW-2 is located downstream of the Site. Sampling locations are shown in Figure 2. Surface Water Analytical Results Table 3 summarizes the historical and current surface water analytical results. For the May 2021 sampling event, no parameters were detected at concentrations above the associated 15A NCAC 2B surface water standards (2B standards). Since collection of surface water samples for all permit constituents began in May 2017, nitrate concentrations have been similar in SW-1 (upstream) and SW-2 (downstream). The spring 2021 sampling showed a similar relationship: upstream sample SW-1 had a nitrate concentration of Most of the groundwater standards are represented by the 2L standards, with the exception of nitrate and total organic carbon, which are set in the Wastewater Irrigation System Permit Number WQ0004797. June21, 2021 Page 3 0.80 mg/L, and downstream sample SW-2 was 0.74 mg/L. The results for total organic carbon, chloride, total dissolved solids (TDS), ammonia, and total phosphorus were also similar for upstream and downstream samples, indicating the unlikelihood that the Site is impacting Mud Creek. Discussion Taking a proactive approach, in 2016 Clement Pappas contracted Nutter and Associates to analyze the overall health and performance of the land application system to determine ways to improve the longevity of the system while reducing the likelihood of impacts on groundwater. Based on this work, Clement Pappas has implemented the following activities: • To avoid introducing additional nitrogen into soils at the subject facility, Clement Pappas has implemented the practice of baling harvested fescue and removing it from the irrigation fields, instead of mowing it and allowing it to decompose. — Removing the harvested fescue should result in improved vegetative growth, which will allow the fescue to uptake additional available nitrogen. — Additionally, it is expected that removing the harvested fescue will result in greater assimilation of nitrogen into facility soils and reduce the potential for nitrogen leaching. All of the samples collected during the May 2021 sampling event were below the permit standard for nitrate except for MW-7R which is consistent with historical results. The results for all analyzed constituents in surface water, including nitrate, were below applicable standards and similar for upstream and downstream samples. On behalf of Clement Pappas, Anchor QEA notified the DEQ of the nitrate results from the May 2021 sampling event on June 15, 2021. Per discussions with the DEQ, Anchor QEA proposes to work with Clement Pappas to evaluate the structural integrity of MW-7R and determine if overland flow from irrigation fields, in combination with heavy rainfall events, may be resulting in the migration of surface water directly into the well. Anchor QEA proposes to inspect the surface seal of MW-7R for settling and cracking and perform a downhole camera inspection of MW-7R, if warranted to determine well casing integrity. Leading up to the November 2021 monitoring event, Anchor QEA proposes to collect the following data to track irrigation, rainfall, and water levels in MW-7R and MW-9 (comparison): — Obtain rainfall data through the National Oceanic and Atmospheric Administration's (NOAA) website for station US1NCHN0060. — Compile spray application volumes for the following locations: • MW-7R: fields 5a, 8, and 9 • MW-9: fields 5b and 6 Acquire water level data from MW-7R and MW-9 using transducers deployed prior to groundwater sampling. The findings will be summarized in the November 2021 Groundwater Sampling Report. June21, 2021 Page 4 In accordance with the spray irrigation permit WQ0004797, Clement Pappas is required to submit the following to the DEQ by June 30, 2021 (on or before the last working day of the month following the sampling month): • Laboratory analytical reports and chain -of -custody forms (Attachment 1) • Well sampling logs and the equipment documentation and instrument calibration data sheet (Attachment 2) • DEQ GW-59A — Compliance Report Form (Attachment 3) • DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Form, for each monitoring well (Attachment 4) Anchor QEA proposes to complete the next scheduled groundwater and surface water sampling event in November 2021. June 21, 2021 Page 5 If you have any questions or would like additional information, please do not hesitate to contact me at (828) 281-3350 orjverde@anchorqea.com. Sincerely, Jennifer Verde Managing Engineer Attachments Table 1 Current and Historical Groundwater Elevation Measurements Table 2 Current and Historical Groundwater Analytical Results Table 3 Current and Historical Surface Water Analytical Results Figure 1 Site Location Map Figure 2 Site Plan Map Attachment 1 Laboratory Analytical Reports and Chain -of -Custody Forms Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet Attachment 3 DEQ GW-59A — Compliance Report Form Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms Tables Table 1 Current and Historical Groundwater Elevation Measurements Well Identification MW-4 MW-5 MW-6 Screened Interval (ft bgs) Date Measured Depth to Groundwater Top -of- Casing Elevation Top -of -Casing Height Above Ground Surface Groundwater Elevation 5.0 - 15.0 11/02/2018 8.00 2063.77 2.43 2055.77 05/21/2019 8.49 2055.28 11/14/2019 8.82 2054.95 05/06/2020 7.98 2055.79 11/06/2020 8.02 2055.75 05/11/2021 8.52 2055.25 9.0 - 19.0 11/02/2018 8.23 2085.60 3.00 3.00 3.00 3.00 2077.37 05/21/2019 8.57 2077.03 11/14/2019 8.90 2076.70 05/06/2020 8.28 2077.32 11/06/2020 8.90 2076.70 05/11 /2021 8.77 2076.83 5.0 - 10.0 11/02/2018 5.03 2061.17 2062.86 2056.14 05/21/2019 5.53 2055.64 11/14/2019 5.59 2055.58 05/06/2020 5.41 2055.76 11/06/2020 5.33 2055.84 05/11 /2021 5.68 2055.49 MW-7R MW-8 5.0 - 15.0 3.0 - 13.0 11/02/2018 10.33 2052.53 05/21/2019 10.88 2051.98 11/14/2019 11.33 2051.53 05/06/2020 10.11 2052.75 11/06/2020 10.05 2052.81 05/11 /2021 10.85 2052.01 11/02/2018 8.85 2060.80 2051.95 05/21/2019 9.38 2051.42 11/14/2019 9.75 2051.05 05/06/2020 8.54 2052.26 11/06/2020 8.37 2052.43 05/11 /2021 9.24 2051.56 MW-9 3.0 - 13.0 11/02/2018 4.55 2060.23 1.44 2055.68 05/21/2019 4.89 2055.34 11/14/2019 5.15 2055.08 05/06/2020 4.30 2055.93 11/06/2020 4.10 2056.13 05/11 /2021 4.75 2055.48 May 2021 Groundwater Sampling Event Pagel of 2 Clement Pappas, Hendersonville, North Carolina June 2021 Table 1 Current and Historical Groundwater Elevation Measurements Notes: Top -of -casing elevations: MW-5 through MW-S top -of -casing elevations are based upon a survey by Hill and Associates Surveyors, dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations are based upon differential level measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of - casing elevations for the monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of - casing elevations for MW-9 were surveyed on May 29, 2015, by Wes Cole Land Surveying. ft bgs: feet below ground surface Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020. May 2021 Groundwater Sampling Event Page 2 of 2 Clement Pappas, Hendersonville, North Carolina June 2021 Table 2 Current and Historical Groundwater Analytical Results Sample Name Sample Date 2 Ol O = p49 N L O R O L V N N Z O F •O O O Q L O• O L O L H C 0 � O F N_ O V O C L V �+ G (SU) (m9/L) (mg/L) (CFUs per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (pg/L) OWL) (pg/L) (pg/L) (pg/L) (pg/L) 2L Groundwater Standards 6.5 - 8.5 70 250 7 NL SOO 7.5 NL 0.7 3 70 700 003 7 Groundwater Standards Provided in Permit No. WQ0004797 - 70 2SO NL 'O 500 7.5 NL 0.7 3 70 700 0.03 7 11/02/2018 5.47' 3.6 9.0 <10.0 0.48 137 <0.10 0.070 < 0.50 '0.50 < 0.50 < 0.50 < 1.0 < 0.50 OS/21/2019 5.81 3.0 11.3 <11_0 33 170 <0.050 0.044J NR 11/14/2019 5.82 3.7 11 <1.0 0.42 190 <0.10 <0.050 < 0.50 z 0-SO 'O.SO < 0.50 < 1.0 < 0.50 MW-4 05/06/2020 5.70 2.3 7.6 <1.0 3.7 172 <0.10 <0.050 NR 11/06/2020 5_30 2.8 6.9 <1.0 0.73 148 <0.10 <O.050 < 0.50 < O.50 < 0.50 < 0.50 < 1.6 < 0.50 05/11/2021 5.8 2.8 6.9 <1.0 1.4 169 0.14 <0.050 NR 11/02/2018 5.53 5.1 23.9 <10.0 <0.020 86 <0.10 0.085 39.1 6.0 6.7 1 < 0.50 < 1.0 < 0.50 05/21/2019 5_68 9.4 26.8 7.0 1 0.1 1 91 <0.050 0.120 NR MW-5 11/14/2019 5.59 6.0 251 7.0 0.055 202 <0.10 0.081 2Z_4 4.4 5.0 < 0.50 < 1.0 < 0.50 05/06/2020 5.90 6.9 7.3 8.0 <0.040 116 <0.10 0.083 NR 11/06/202o 5.65 4.6 6.9 8_0 <0.040 61.0 < _l -0.060 0.86 1_0 < 0.50 < O_SO < 1.0 < 0.50 05/11/2021 5.5 5.5 1T.8 <2.0 <0.040 110 <0.10 0.090 NR 11/02/201a 5.02 2.5 10.1 69.0 0.6 88 <0.10 1 0.057 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/21/2019 5.46 33 113 23.0 0.4 78 <0.050 0.068 N MW-6 11/14/2019 5.30 2.9 9.3 44.0 0.56 342 <0.10 O. S2 < 0.50 < 0.50 < O.SO I < 0.50 1 < 1.0 1 < 0S 05/06/2020 S-38 2.0 9.7 3.0 1.1 96.0 <0.10 <0.050 NR 11/06/2020 5.23 2.6 12.5 3.0 32 139 <0.10 <0.050 < 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50 05/11/2021 5.5 2.2 10.9 5_0 1.4 99.0 <0.10 <0.050 NR 11/02/2018 5.48 53 202 <10.0 75J 243 <0.1 0.17 < 0.50 -0.50 < 0.50 1 < 0.50 < 1.0 < 0.50 05/21/2019 5.58 3.0 29.0 <2.0 20.2 234 <0.050 0.130 NR MW-7R 11/14/2019 6.42 3.0 22.7 <2.0 17.1 73 10.10 0.084 < O.SO < 0.50 < 0.S0 < 0.50 1.0 < 0-SO 05/06/2020 5.20 l.Z ZO.9 <1.0 21.5 219 <0.10 <0.050 NR 11/06/2020 5.54 1.7 T7:8 <1.0 13_0 205 <0.10 <0.050 < 0.50 < 0.50 < 0.50 I < 0.50 < 1.0 < 0.50 05/11/2021 5.2 1.7 342 <1.0 40.4 296 <0.10 0.051 NR 11/02/2018 6.52 9.5 8.0 19.0 6.8 351 <0.10 0.250 < 0.50 < O50 < 0.50 1 < O.SO < 1.0 /21/2OT9 6.89 7T 7.3 <10.0 6.2 249 <0.050 0.290 NR MW 8 11/14/2019 6.71 7.7 7.2 2.0 1.2 51 <0.10 0.10 < 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50 05/06/2020 6.47 2.7 2.8 <1.0 3.6 139 <0.10 <0.050 NR 11/06/2020 634 2.8 2.3 14.0 2.4 12 <0.10 1<0.050 < 5.5 < 0.50 < 0.5 < 0.50 < 1.0 < 0.50 05/11/2021 b.b 3.8 :0 <1.0 1.7 114 .70 1 -0.050 NR 11/02/2018 5.77 8.4 5.8 <10.0 0.6 88 <0.10 0.470 < 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50 05/21/2019 5.64 7.2 4.6 <10.0 02 80 <0.050 0.230 NR MW 9 11/14/2019 5.57 6.1 5.4 <l.0 0.89 56 <0.10 0.076 < 0.50 < 0.50 < OS0 -0.50 < 1.0 < 0- 05/06/2020 5.52 S.9 1.8 <l.0 <0.040 68.0 <0.10 0.099 NR 11/06/2020 4.93 4.5 1 4 76.0 0.043 88.0 <0.10 0.095 < 0.S0 < O.SO < 0.50 1 < 0.50 < 1.0 < 0.50 05/11/2021 5.4 3.6 9.8 <2.0 1.9 <25.0 1 <0.TO 0.089 NR May 2021 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina Table 2 Current and Historical Groundwater Analytical Results Notes: 2L standards are set in North Carolina Administrative Code, Title t 5A Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April t, 2O13) Total organic carbon and nitrate standards are set in Wastewater Irrigation System Permit Number WQOOO4797. There is no defined 2L standard for fecal coliforn; therefore, the standard listed is for "total coliform.' Bolded values indicate a concentration above the respective permit groundwater standard or outside the permit groundwater standard range. pH is analyzed by Anchor QEA of North Carolina, PLLC; NC lab certification number 5445 Monitoring is performed in accordance with Permit No. W0OOO4797 issued to Clement Pappas on May 15, 2020 and effective on September t, 2020. < indicates that the constituent concentration was not detected above the method detection limit. Vg/L microgr-dms per liter CFU: coliforn-forming unit J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate. mg/L milligrams per liter mL: milliliter NL : No 2L standard exists NR: not reported SU: standard unit May 2021 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina Table 3 Current and Historical Surface Water Analytical Results c. C C 0 H O UMU a C O �0 .� v° Z V N N _V o Q o A •O E N O. a (CFUs per Sample Name Sample Date (SU) (mg/L) (mg/L) 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) 28 Standard 6.5 - 8.5 NL 230 200 NL NL NL NL 5/2/2018 6.88 1.5 4.8 53.0 0.74 54.0 <0.10 0.044 J 11/2/2018 6.28 2.9 5.1 780 0.72 54.0 <0.10 0.077 5/21/2019 7.02 1.6 5.0 98.0 0.75 42.0 <0.050 0.067 SW-1 11/14/2019 6.76 1.9 5.3 118 0.83 57.0 <0.10 0.1 (Upstream) 5/6/2020 7.20 1.6 4.6 290 0.76 49.0 <0.10 0.092 11/6/2020 5.83 1.6 4.4 145 0.71 56.0 <0.10 <0.050 5/11/2021 6.8 1.3 5.3 191 0.80 48.0 <0.10 0.068 5/2/2018 6.98 1.4 4.4 118.0 0.72 51.0 0.052 J 0.045 J 11 /2/2018 7.08 2.9 4.6 940.0 0.75 53.0 0.099 J 0.076 5/21/2019 6.99 1.6 4.9 200.0 0.76 47.0 <0.050 0.068 SW-2 11/14/2019 7.01 1.9 5.4 127 0.82 83.0 <0.10 0.089 (Downstream) 5/6/2020 6.67 1.7 4.2 420 0.72 53.0 <0.10 <0.050 11/6/2020 6.19 1.6 4.4 97.0 0.70 1 59.0 <0.10 <0.050 5/11/2021 6.9 1.4 5.0 146 0.74 47.0 <0.10 0.061 Notes: 2B standard: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the U.S. Environmental Protection Agency Nationally Recommended Water Quality Criteria for Aquatic Life and Human Health. Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range. < indicates that the constituent concentration was not detected above the laboratory reporting limit Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020. CFU: coliform-forming unit J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate. mg/L milligrams per liter mL: milliliters NL: No NC 2L standard exists SU: standard unit May 2021 Groundwater Sampling Event Page 1 of 1 Clement Pappas, Hendersonville, North Carolina June 2021 Figures gitogif._a-.� �•.- .-. rltiAk �a ll r/r �Y-7 ,�: •�-�- i :;fit• - �`.''' � ,..:`'R .,—'� ,. �r .�.ryi,. `�•r; V' , �. r•)• �• _. •. .�rh.le•,i411.: 1::;...:tl.'! I:iln;fll �..:, Slu:r:.: :. �°! �• ;iF r ,t I r F1f'!U J �J.-rnACEIBOrQiR�(d L: s I �iEi❑n r;.. �•I :Y9giAigARYA '.w .-..... •b'1L'7-6 L � P i �• _ rll ifl I:::•flo.tl•'..i i11f ilIvi1f/I`1 +` '�!na•c �r�F i LEGEND I;'!4� 3 �raytl yvl: rr+ruar O PIEIOMETER SR 'L4f,4'l: •7 Fj�- ',1L'J•i Lr9syt[•].f ® MONITORING WELL ® OLD OR FORMER MONITORING WELL���� `fir tits,+-•� ® SURFACE WATER SAMPLE LOCATION 4-FOOT CON70UR F 20-FOOT CONTOUR STREAM CENTERUNE �.. '� i• .y'+j1 I� 'l:-r.� F RC. S: • . r r. AAsho! tlEAM Nanh C.reFnA, pl![ ' Y- 1 AOAF•WAS7E TlCWi0C06'7.IUC-(JIWjj MAY{21301 IILaIOA71ON iYA}! i- fMIMSYMW AMWATK LTO FIrOE 3 LAND TREATMTNT WTIEMS. UNEIAIEp 7}t MryAnoJiSveH ANCHOR SITE MAP FIGURE +J HENDEl"ll C0UNIY.GISYNEWC ACCESSEO MAY 5,kill i ALI,e.lpe. N"W C.0ka Owl _ ►20A1OSCHARGE ACAW RENEWAL a AEAIALP$IQIQA PWMITT) 41Ll0EIMPAM EY NC F#I! MAP 12GIi13350 0 [.A c-.._.-L� 1 HC r;w vc— Na C•IIJII$ CLEMENT PAPPAS Ni:. LLC NOTES- US 1NDUSTAIAL PAW. ROAD 1. PROPEMYICUh17ARYUNr`SiROrt nE01gE0.5ON[WNIY GES {PIN4 LLNEsI CAAWN BY�.�FTAViNONA o I }( pEgSpP:YILLF. NOR W CAROLINA ;. AkY{EW 6OUNOARYOkTERH�NEO PER tiAItCAC IIn QSGE iqA LVtiINiS] PROIECF IdGR �i•hlq:[fE171 - - 3. CCMPL3ANCE EClJNl7ARY OE7ERLa{N@II AER 15Y,NCAC 071 ASEA (r�LOW UTLES) EKi_) A DATE TLT PPVDps ,� — 4J£V.tO _ PRO). N: 17914R-01:U LJ Attachment 1 Laboratory Analytical Reports and Chain -of -Custody Forms aoAnalylical www.pacsllbs.com May 19, 2021 Jennifer Verde Anchor QEA 231 Haywood Street Asheville, NC 28801 RE: Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Dear Jennifer Verde: Pace Analytical Services, LLC 2225 Riverside Dr. Asheville. NC 28804 Enclosed are the analytical results for sample(s) received by the laboratory on May 11, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville If you have any questions concerning this report, please feel free to contact me. Sincerely, (34ax,i�- ?_ Lord Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, qeawo o without the written consent of Pace Analytical Services, LLC. (828)254-7176 Pagel of 26 aceAnalyfical www.peslab� can Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01 T01 Pace Project No.: 92538054 , Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 26 2aceAnalyfical` WM.PICNI s.eom SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No. 92538054 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92538054001 MW-4 SM 2540C-2011 ZMC l PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.0 1993 NGP 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A SM 4500-CI-E-2011 MFO 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92538064002 MW-5 SM 254OC-2011 ZMC 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.0 1993 NGP 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A SM 4500-CI-E-2011 MFO 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92538064003 MW-6 SM 2540C-2011 ZMC 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.0 1993 NGP 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A SM 4500-CI-E-2011 MFO 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92538054004 MW-7R SM 254OC-2011 ZMC 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.0 1993 NGP i PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A SM 4500-CI-E-2011 MFO 1 PASI-A SM 531OB-2011 EWS 1 PASI-A 92538054005 MW-8 SM 254OC-2011 ZMC 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.0 1993 NGP 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A SM 4500-CI-E-2011 MFO 1 PASI-A SM 531OB-2011 EWS 1 PASI-A 92538054006 MW-9 SM 254OC-2011 ZMC 1 PASI-A SM 9222D-2006 ECH I PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 26 raceAnalyfical www.paceinbs.csm Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Lab ID Sample ID 92538054007 SW-1 92538064008 SW-2 PASI-A = Pace Analytical Services - Asheville SAMPLE ANALYTE COUNT Method EPA 350.1 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 SM 4500-CI-E-2011 SM 531OB-2011 SM 254OC-2011 SM 9222D-2006 EPA 350.1 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 SM 4500-CI-E-2011 SM 531OB-2011 SM 254OC-2011 SM 9222D-2006 EPA 350.1 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 SM 4500-CI-E-2011 SM 531OB-2011 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Analysts Analytes Reported Laboratory NGP I PASI-A MFO 1 PASI-A KDF1 1 PASI-A MFO 1 PASI-A EWS 1 PASI-A ZMC 1 PASI-A ECH 1 PASI-A NGP 1 PASI-A MFO 1 PASI-A KDF1 1 PASI-A MFO 1 PASI-A EWS 1 PASI-A ZMC 1 PASI-A ECH 1 PASI-A NGP 1 PASI-A MFO 1 PASI-A KDF1 1 PASI-A MFO I PASI-A EWS I PASI-A Page 4 of 26 accAnalyfical www.pacolabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Sample: MW-4 Lab ID: 92538054001 Collected: 05/11/21 13:07 Received: 05/11/21 14:23 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids 169 mg/L 25.0 1 05/15/21 12:20 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 05/11/21 18:40 05/12/21 17:14 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia 0.14 mg/L 0.10 1 05/14/21 11:35 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 1.4 mg/L 0.040 1 05/12/21 04:50 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 05/17/2109:30 05/17/2111:24 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 6.9 mg/L 1.0 1 05/14/2123:18 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Pace Analytical Services - Asheville Total Organic Carbon 2.8 mg/L 1.0 1 05/16/21 23:34 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 26 aceAnalXical www.pscslabs.eom ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Sample: MW-5 Lab ID: 92538064002 Collected: 05/11/21 09:03 Received: 05/11/21 14:23 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Pace Analytical Services -Asheville Total Dissolved Solids 110 mg/L 25.0 1 05/15/21 12:20 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 2.0 2 05/11/21 16:04 05/12/21 15:07 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 05/14/21 11:36 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate ND mg/L 0.040 1 05/12/21 04:40 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 0.090 mg/L 0.050 1 05/17/2109:30 05/17/2111:25 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 11.8 mg/L 1.0 1 05/14/2123:19 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Pace Analytical Services - Asheville Total Organic Carbon 5.5 mg/L 1.0 1 05/16/21 23:59 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 26 (�IacleAnalytical www.p*cW@bs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Sample: MW-6 Lab ID: 92538054003 Collected: 05/11/21 11:46 Received: 05/11/21 14:23 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids 99.0 mg/L 25.0 1 05/15/21 12:20 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services - Asheville Fecal Coliforms 5.0 CFU/100 mL 1.0 1 05/11/21 17:07 05/12/21 15:07 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 05/14/21 11:38 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 1.4 mg/L 0.040 1 05/12/21 04:47 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus ND mg/L 0.050 1 05/17/2109:30 05/17/2111:25 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 10.9 mg/L 1.0 1 05/14/2123:20 16887-00-6 5310E TOC Analytical Method: SM 531OB-2011 Pace Analytical Services - Asheville Total Organic Carbon 2.2 mg/L 1.0 1 05/17/21 00:17 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 26 accAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Sample: MW-7R Lab ID: 92538054004 Collected: 05/11/21 11:04 Received: 05/11/21 14:23 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Pace Analytical Services -Asheville Total Dissolved Solids 296 mg/L 25.0 1 05/15/21 12:20 11,11113110 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services - Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 05/11/21 17:07 05/12/21 15:07 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 05/14/21 11:42 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 40.4 mg/L 0.40 10 05/12/21 05:23 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 0.051 mg/L 0.050 1 05/17/21 09:30 05/17/21 11:26 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 34.2 mg/L 1.0 1 05/14/2123:20 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 1.7 mg/L 1.0 1 05/18/21 21:09 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 26 1)!-7 aceAnalytical www.paalabs.com t ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Sample: MW-8 Lab ID: 92638054005 Collected: 05/11/21 10:09 Received: 05/11/21 14:23 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids 114 mg/L 25.0 1 05/16/21 12:20 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 05/11/21 16:04 05/12/21 15:07 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 05/14/21 11:43 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 1.7 mg/L 0.040 1 05/12/21 04:43 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 05/17/2109:30 05/17/2111:27 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 2.0 mg/L 1.0 1 05/14/2123:21 16887-00-6 5310E TOC Analytical Method: SM 531OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 3.8 mg/L 1.0 1 05/18/21 21:28 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 26 aC,aaryttcai WWW.oecelabstem ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Sample: MW-9 Lab ID: 92638054006 Collected: 05/11/21 12:28 Received: 05/11/21 14:23 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids ND mg/L 25.0 1 05/15/21 12:21 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 2.0 2 05/11/21 18:40 05/12/21 17:14 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 05/14/21 11:45 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 1.9 mg/L 0.040 1 05/12/21 04:48 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.089 mg/L 0.050 1 05/17/21 09:30 05/17/2111:27 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 9.8 mg/L 1.0 1 05114/2123:22 16887-00-6 5310E TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 3.6 mg/L 1.0 1 05/18/21 21:48 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 26 aceAnalytical wnw.P1nl1bs.o0m ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538064 Sample: SW-1 Lab ID: 92538054007 Collected: 05/11/21 13:25 Received: 05/11/21 14:23 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services - Asheville Total Dissolved Solids 48.0 mg/L 25.0 1 05/15/21 12:21 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services -Asheville Fecal Coliforms 191 CFU/100 mL 1.0 1 05/11/21 18:40 05/12/21 17:14 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 05/14/21 11:46 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 0.80 mg/L 0.040 1 05/12/21 04:54 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.068 mg/L 0.050 1 05/17/2109:30 05/17/2111:28 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 5.3 mg/L 1.0 1 05/14/2123:25 16887-00-6 5310B TOC Analytical Method: SM 5310E-2011 Pace Analytical Services -Asheville Total Organic Carbon 1.3 mg/L 1.0 1 05/18/21 23:10 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 26 r P ceAnalytical www.pocelabs.com ANALYTICAL RESULTS Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: SW-2 Lab ID: 92538054008 Collected: 05/11/21 10:30 Received: 05/11/21 14:23 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Total Dissolved Solids MBIO 9222D Fecal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 5310B TOC Total Organic Carbon Date: 05/19/2021 05:10 PM Analytical Method: SM 254OC-2011 Pace Analytical Services - Asheville 47.0 mg/L 25.0 1 05/15/2112:21 Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Pace Analytical Services - Asheville 146 CFU/100 mL 1.0 1 05/11/21 17:07 05/12/21 15:07 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.10 1 05/1412111:48 7664-41-7 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 0.74 mg/L 0.040 1 05/12/2104:45 14797-55-8 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville 0.061 mg/L 0.050 1 05/17/21 09:30 05/17/2111:29 7723-14-0 Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville 5.0 mg/L 1.0 1 05/14/2123:25 16887-00-6 Analytical Method: SM 531OB-2011 Pace Analytical Services -Asheville 1.4 mg/L 1.0 1 05/18/2123:28 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 26 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 QC Batch: 620518 Analysis Method: SM 254OC-2011 QC Batch Method: SM 254OC-2011 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 METHOD BLANK: 3264839 Matrix: Water Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 05/15/21 12:19 LABORATORY CONTROL SAMPLE: 3264840 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 249 244 98 90-110 SAMPLE DUPLICATE: 3264841 92537889013 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 1140 1140 0 SAMPLE DUPLICATE: 3264842 92538054002 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 110 104 6 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 26 ace Analytical www.palabs.com QUALITY CONTROL DATA Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 619989 Analysis Method: SM 9222D-2006 QC Batch Method: SM 9222D-2006 Analysis Description: 9222D Fecal Coliform(MF) -AVL Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 METHOD BLANK: 3261848 Matrix: Water Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 05/12/21 15:07 SAMPLE DUPLICATE: 3261849 Parameter Fecal Coliforms SAMPLE DUPLICATE: 3261850 Parameter Fecal Coliforms 92538192001 Units Result CFU/100 mL� ND Units CFU/100 mL Dup Result RPD Qualifiers ND 92538187002 Dup Result Result ND 1.0 RPD Qualifiers Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 26 aceAnalytical www.p=alabs.com QUALITY CONTROL DATA Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 620334 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 METHOD BLANK: 3263863 Matrix: Water Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 05/14/21 11:07 LABORATORY CONTROL SAMPLE: 3263864 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3263865 3263866 MS MSD 92537426001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.3 5.3 104 104 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3263867 3263868 MS MSD 92537480001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 4.8 4.8 96 96 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 26 aceAnalytical WIIN.pal�lab3.00a1 QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 QC Batch: 619778 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 METHOD BLANK: 3260792 Matrix: Water Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 05/12/21 04:25 LABORATORY CONTROL SAMPLE: 3260793 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.6 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3260796 3260797 MS MSD 92538054002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L ND 1.5 1.5 1.6 1.6 109 108 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3260803 3260804 MS MSD 92537860001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 14.8 15.5 5 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 26 aceAnalytical � wq+w.pacslahs.cam i QUALITY CONTROL DATA Project: Lassonde Pappas 91482-01.01T01 Pace Project No. 92538054 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 620769 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 METHOD BLANK: 3266131 Matrix: Water Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 05/17/2111:16 LABORATORY CONTROL SAMPLE: 3266132 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3266133 MS 92537844001 Spike Parameter Units Result Conc. Phosphorus mg/L 1.8 2.5 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3266135 MS 92537848001 Spike Parameter Units Result Conc. Phosphorus mg/L 1.7 2.5 3266134 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD 2.5 4.4 4.4 103 104 90-110 0 3266136 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD 2.5 4.2 4.2 102 102 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC Qual Qual Page 17 of 26 lceAr�a1ytical www.pacelaba.com QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 QC Batch: 620631 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 METHOD BLANK: 3265503 Matrix: Water Associated Lab Samples: 92538054001, 92538054002, 92538054003, 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 05/14/2123:15 LABORATORY CONTROL SAMPLE: 3265504 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.8 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3265845 3265846 MS MSD 92538789001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 2.2 10 10 12.2 12.0 99 97 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3265847 3265846 MS MSD 92538789002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 2.2 10 10 12.3 12.3 101 101 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 26 1*�P'ceAnalytcal www.plelabs.com QUALITY CONTROL DATA Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 QC Batch: 619968 Analysis Method: SM 531OB-2011 QC Batch Method: SM 531 OB-2011 Analysis Description: 5310B TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92538054001, 92538054002, 92538054003 METHOD BLANK: 3261740 Matrix: Water Associated Lab Samples: 92538054001, 92538054002, 92538054003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 05/14/21 08:41 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 3261741 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.6 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3261742 MS 92534793001 Spike Parameter Units Result Conc. Total Organic Carbon mg/L ND 25 3261743 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD Qual 25 26.1 26.1 103 103 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3261744 3261745 MS MSD 92535193001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 25.5 25.5 100 100 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 26 aciAnalytical www.pacsllbs.com QUALITY CONTROL DATA Project: Lassonde Pappas 91482-01.01T01 Pace Project No.,. 92538054 QC Batch: 619985 Analysis Method: SM 531OB-2011 QC Batch Method: SM 531 OB-2011 Analysis Description: 5310B TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 METHOD BLANK: 3261795 Matrix: Water Associated Lab Samples: 92538054004, 92538054005, 92538054006, 92538054007, 92538054008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 05/18/21 19:41 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 3261796 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 23.7 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3261797 3261798 MS MSD 92535193002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 25.1 25.1 100 100 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3261799 3261800 MS MSD 92537613003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 3.6 25 25 28.7 29.3 100 103 90-110 2 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 26 1ceAnalj6cal W".pacelabs.= QUALIFIERS Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 26 accAnalytical www.pacwabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Lassonde Pappas 91482-01.01T01 Pace Project No.: 92538054 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92538054001 MW-4 SM 2540C-2011 620518 92538064002 MW-5 SM 2540C-2011 620518 92538054003 MW-6 SM 2540C-2011 620518 92538054004 MW-7R SM 2540C-2011 620518 92538054005 MW-8 SM 2540C-2011 620518 92538064006 MW-9 SM 2540C-2011 620518 92538054007 SWA SM 2540C-2011 620518 92538054008 SW-2 SM 2540C-2011 620518 92538054001 MW-4 SM 9222D-2006 619989 SM 9222D-2006 619992 92638054002 MW-5 SM 9222D-2006 619989 SM 9222D-2006 619992 92538054003 MW-6 SM 9222D-2006 619989 SM 9222D-2006 619992 92538054004 MW-7R SM 9222D-2006 619989 SM 9222D-2006 619992 92538054005 MW-8 SM 9222D-2006 619989 SM 9222D-2006 619992 92538054006 MW-9 SM 9222D-2006 619989 SM 9222D-2006 619992 92538064007 SW-1 SM 9222D-2006 619989 SM 9222D-2006 619992 92538054008 SW-2 SM 9222D-2006 619989 SM 9222D-2006 619992 92538054001 MW-4 EPA 350.1 Rev 2.0 1993 620334 92538054002 MW-5 EPA 3§0.1 Rev 2.0 1993 620334 92538054003 MW-6 EPA 350.1 Rev 2.0 1993 620334 92538064004 MW-7R EPA 350.1 Rev 2.0 1993 620334 92538054005 MW-8 EPA 350.1 Rev 2.0 1993 620334 92538054006 MW-9 EPA 350.1 Rev 2.0 1993 620334 92538064007 SW-1 EPA 350.1 Rev 2.0 1993 620334 92538054008 SW-2 EPA 350.1 Rev 2.0 1993 620334 92538064001 MW-4 EPA 353.2 Rev 2.0 1993 619778 92538064002 MW-5 EPA 353.2 Rev 2.0 1993 619778 92538064003 MW-6 EPA 353.2 Rev 2.0 1993 619778 92538054004 MW-7R EPA 353.2 Rev 2.0 1993 619778 92538064005 MW-8 EPA 353.2 Rev 2.0 1993 619778 92538054006 MW-9 EPA 353.2 Rev 2.0 1993 619778 92538054007 SW-1 EPA 353.2 Rev 2.0 1993 619778 92538054008 SW-2 EPA 353.2 Rev 2.0 1993 619778 92538054001 MW-4 EPA 365.1 Rev 2.0 1993 620769 EPA 365.1 Rev 2.0 1993 620816 92538054002 MW-5 EPA 365.1 Rev 2.0 1993 620769 EPA 365.1 Rev 2.0 1993 620816 92538054003 MW-6 EPA 365.1 Rev 2.0 1993 620769 EPA 365.1 Rev 2.0 1993 620816 92538054004 MW-7R EPA 365.1 Rev 2.0 1993 620769 EPA 365.1 Rev 2.0 1993 620816 92538054005 MW-8 EPA 365.1 Rev 2.0 1993 620769 EPA 365.1 Rev 2.0 1993 620816 92538054006 MW-9 EPA 365.1 Rev 2.0 1993 620769 EPA 365.1 Rev 2.0 1993 620816 92538054007 SW-1 EPA 365.1 Rev 2.0 1993 620769 EPA 365.1 Rev 2.0 1993 620816 92538054008 SW-2 EPA 365.1 Rev 2.0 1993 620769 EPA 365.1 Rev 2.0 1993 620816 92538064001 MW-4 SM 4500-CI-E-2011 620631 92538054002 MW-5 SM 4500-CI-E-2011 620631 92538054003 MW-6 SM 4500-CI-E-2011 620631 92538054004 MW-7R SM 4500-CI-E-2011 620631 92538054005 MW-8 SM 4500-CI-E-2011 620631 92538054006 MW-9 SM 4500-CI-E-2011 620631 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2021 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 26 aceAnalyfical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Lassonde Pappas 91482-01.01 T01 Pace Project No.: 92538054 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92538054007 SW-1 SM 4500-CI-E-2011 620631 92538054008 SW-2 SM 4500-CI-E-2011 620631 92538054001 MW-4 SM 5310B-2011 619968 92638054002 MW-5 SM 5310B-2011 619968 92638054003 MW-6 SM 5310B-2011 619968 92538054004 MW-7R SM 5310B-2011 619985 92638054005 MW-8 SM 5310B-2011 619985 92538054006 MW-9 SM 5310B-2011 619985 92538054007 SW-1 SM 5310E-2011 619985 92538064008 SW-2 SM 5310B-2011 619985 Date: 05/19/2021 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 23 of 26 Document Name: Document Revised: October 28, 2020 Sample Condition Upon Recelpt(SCUR) Pa e 1 of 2 acaAnalXical Document No.: Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas CtHaiit Office Laboratory re Iving samples: Asheville❑ EdenGreenwood ❑ Huntersville ❑ Ralelgh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample //Condition Client N me: WO# : 92538054 Upon ReceiptProject #: Courier: ❑Fed fy, OUPS ❑USP5 ❑ Commercial ❑Pace ❑Other: 92636054 Custody Seal Present? Des o Seals Intact? ❑Yes ❑No Dale/Initials Person Examining Contents: Packing Material: ❑Bubble Wrap '�Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer- ,_,/• ❑Yes ❑No ❑N/A I "7 I YIWet []Blue❑None �l iR Gun ID: I 1 Type of Ice; /— Correction Factor: Cooler Temp; `� Add/Subtract (°C) Temp should be above freezing to VC [)Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('C): S� has begun USDA Regulated Soil ( N/A, water sample) Did samples originate i I a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samp'es originate from a foreign source (internationally, ❑Yes LINO inctudingHawail and Puerto 1tIMIF LITes "11V Comments/Discra ant Chain of Custody Present? ]Yes No N/A 1. I Sam les Arrived within tioId Tlrne? 21yes QN0 [IN/A 2. Short Hold Time Analysis (02 hr.)? Yes No NIA 3, ( CS �} ' Rush Turn Around Time Requested? Qves 12No NIA 4. Sufficient Volume? ZrYes []No N/A 5. Correct Containers Used? CJY. []No ❑N/A 6, -Pace Containers Used? Yes No N/A Containers Intact? Yes No MNIA 7. Dissolved analysis: Samples Field Filtered? []Yes ❑No /A 8. Sample Labels Match COC? /"Yes ❑No ❑N/A 9. L -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials 55•15mm ? Yes Duo NJA 30. Trip Blank Present? ❑yes []No N/A 11. Trip Blank Custody Seals Present? ❑Yes 6NIA COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: _ Proetct Manag"r CURT R-eview. Project Manager SRF Review: i Field Data Required? ❑Yes ❑No Lot ID of split containers: Date: ib I Date: Page 24 of 26 Document Name: Document Revised: October 28, 2020 riC6/�I1il�j��lCr7l Sample Condition Upon Recel t(SCUR) Page 2 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles Project tk WO# ; 92538054 PM: LJP Due Dal®: 05/18/21 CLIENT: 83—ALTAMONT w ' t. u Z _ ^.. U v V Q Q _ z Z Z Z _ a m v z Z a m °� f0 To M V v \ ? N ry z rV H a z a N V V V V etl A O Z V V Z Y Q Q O z Z y Z Z Z N W W N N 2 2 2 Q _ a \ ? 0 N V G Z Y Z CJ ii n M U 2 a a V O d \ m \ Z M T Y N N 2 v c c G c Gl n Q z a O ry O d a c O `�� E z O Z a o a m = c o c > > 7 c = 2 N Z 9 c V N 2 Q -' Ll p ui ] a a Z D u v u 7 v = y = U a c rn = « w u d 10 u U v a`—N° n 10 ^ O O ¢o u a aJ aJ aJ E E E > O i a •� J aE E J E E d J E a J ¢ > J J N .2 �, F J J E £ E E w E £ E E v u v a E m E E E E 0 0 E N VO1 O ~ N V1 N �j o Ln _ O� l7 O O O N Q •�1 N Vl ri ,..i N Ov v M M N N at 7 7 7 ,if 2 r- 7 a Y Y F. F Q 7 O1 E Q M N rl a M Q O r•1 rl M1 M1 M Ch Ot M IM a (7 of N MI O (J 0. Ln l7 U 0. a o. a 0. 0. 0. a. 3 U Q W 0 W 0 (D l9 U V' O o> \ > 0. LA 0. m a > ° _ m oo m ao m m co co a a a a a a o > > 3 � � X" ("N\ I I I !NN 6 7 I I 1✓ II j B I I 'f ✓ 10 11 12 PH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot q Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy•gf this form will to sent to the North Carolina uEHNR lennlcation Office (i.e. Out of hold, incorrect preservative, out of temp, Incorrect containers, Page 25 of 26 zw2ekwcal, tf1Y r�ClLLaSIOM Section A Section B CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT_ All relevant fields must be completed accurately. Section C Paae - 1 Of 1 Cornparryr. "„HCHOR ❑EA OF NC. PLLC Report Ta- �,(�,R,t FenittMl Address: 231 Hoy -pod Straw Copy To: ComWy Name: Asheville, NC 28801 Address: R I Email. y f • a [,{np,f ��ii, yri Purchase Order#: Pace Quote: Prxnie; 1828 7C7�827 Fax Project Name: Lassonde Pappas P6yc Prpjeci Manager. lorri-natl paceleos,mm- Stale 1 Location Requcsled Due Da[e r lki, LC� ProjoC {� - t _ •-r Pace Pala Q: sssa Roquested FBbarad !N ^.. a Z cwrauc woe _ — c0i COLLECTED z Preservatives � 2 o D&"g Water DW water wr U O r W w.etewe- ww Product P SAMPLE ID o� _ m D e? START END O _ W a o z oSOiO One Character per box. Wipe WP w w a z_ v o 0 E D (AZ o_s 1. -1 ou.m or Sample Ids must be unique T.- Ts f= <r. z m ?+ C O U m o v3 v T r!�� n a o _ m ai m ✓ W ¢ h DATE 1 TIM& DATE TIME N == O O z z t O Q ri z E EE Q Or m wliltl�'-� tl 13�7 �' o�-- F32 IVY uV / 1l'110w - �- l ►i64 GAG5 Axvu_g I� 67 / CQ7� 3�s ob b 9 iD 11 12 ADOUIONAL COMMEM3 IF0,1NOU011ED BY I AFFILIATION DiTB TIME.-, ACCEPTED BY I AWMTION - . DATE TIME - UMPLECONDfnONS �. SAMPLER NAME AND SIGNATURE c c 0 m m PRINT Name of SAMPLER F m > m m > U r c Y SIGNATURE of SAMPLER: DATE Slgned: rn N O to N N rn m 0_ Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet kzANCHOR IDEA w Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Lag well ID: UCW- Project Name: pm S Date: 113 1��� Project Number. L 1�� �U;Weather. / — Project Location: A1 � ,�' j,l Facility ID or Permits (if applicable): 1 J 0 '1+ Sample Collector(s): � Sample ID (on COC): VVAW -. Well Diameter. in Arrive at Well: Screen Interval: 1 _ ft bgs Start Time: (��,� Well Depth (as comtnlcted): 15 ft bgs Sample Time: 1 ` Depth to Water. I ft Leave Well: _ 13pv Measuring point: Well Type: Tlack Up oFlush Mount Depth of Pump Intake: }V ft Tagged Bottom: ft at (time): Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate: -1 wk/mi Comments: Total Volume Purged: — — — — Pump Speed:_rl_k Time DTw (bat) Tern ire CC) assoMtd Olt W (moll,) Spwmk Cortdttettelty (omw4m) pH (S-W report to al 11L Qxidatbn R.dtat(en Pollift" (MV) Tttrbldlty MM i 0, a i r " _4 I / r•I b . S v Sample Analyst Signature:Alt Semple Analyst Name: d Date: 5 I Notes: 1. Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and furbidiy, +/- 3% Conductivity, +/- 0.1 PH uni4- +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2, Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 PS/CM Abbreviations: Method Reference: 'C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/an: micromhos per centimeter ft, feet Spedi is conductivity: EPA Method 1201, Rev. 1982 mg/L• milligrams per liter In: inches DO: SM 4500 0 G-2011 mV: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 Page 1 of 1 kZANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log well ID: Mkkf Project Name: ((50jq k ( S Date: Q 4 Project Number. (l I Lks 7— 0 ` v } Weather. My� W-s Project Location: ��EWwtff<1)lAvl&1 y 6�L Facility ID or Permit # (If applicable): wl� vv� Li Sample Collector(s): � Sample ID (on COQ: r"- I Well Diameter: in Arrive at Well: M ri Screen Interval: ft bgs Start Time: 093k/ Well Depth (as constructed): 1 ft bgs Sample Time: 0q0b Depth to Water. �. ft Leave Well: V r'. Measuring Point Well Type: dick Up nFlush Mount Depth of Pump intake: l'1 ft Tal Tagged Bottom: A &; ft at (time): 6130 Pump Used (circle): Per)stalt)c Bladder Other (describe): Purge Rate: Comments: Total Volume Purged: Pump Speed: Thne DTW(feet) T—PerotureCC) Dkaolved oxygen (mgM1) Spedfk Condilic" (Pmhoe/au) pH (S.U.) lepoettoo.ftU. Oxidation Redutdon PoaenM(m1) TwbM ty(NTIn r ' z1ryry L {. + J 931 IF o 01 ,bit q r3=k� 7r �� 5 r `� 1 S' v Sample Analyst SigneWre: Sample Analyst Name: Date: l 1< t,Sa vA 6. 611 I � Notes (—Z r 1: Stabllization (3 successive readings, 3 minutes apart): within +/- 1096 0o and turbidity, +/- 396 Conductivity, +/- 0.1 PH unit, +/- 70 mil for ORP from EPA - Low -Flow (Minimal Dmwdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 S. 1 pmho/cm = 1 pS/cm AbbrwAatlons: Method Reference: IC: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter it: feet Specific conductivity: EPA Method 120.1, Rev. 1962 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mV: millivolt bgs: below ground surface pH: SM 4500-H' 3-2011 NTU: nephelometric turbidity units TOC top of casing Turbidity: SM 2130 B-2011 Page 1 of 1 kZANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log Well ID: n Project Name: Last d V as Date: 911 Project Number. ail W � 7 �Di,T Weather. � Q{� �1C� Project Location: uz�U rllAGa N_�L lyC/ Facility ID or Permit * ('d applicable): � Sample Collector(s): � Sample ID (on COQ: j► � [Rr Welt Diameter. in Arrive at Well: Screen Interval: ft bgs Start Time: 1 !� Well Depth (as constructed): ft bgs Sample Time: Depth to Water: ft Leave Well: Measuring Point: Well Type tick Up ❑Flush Mount Depth of Pump Intake: ft Tagged Butttxli: �� at (time): Pump Used (circle): PeristaRic Bladder Other (describe): Purge Rate: Comments: Total Volume Purged: Pump Speed: Time DM (%et) Temperature CC) DbwMed Oxypae (mp/L) Sprc}[ic CovaikKill ({lloh Cm) PH (5-11111 rtlrlWt to R I 111A NO&A tl0a Patine. (MV) Tttrbi ft RMJj d A 9.3 ? •- l;- . - q .� .a IV r .a l i S 5 L ' r 5 5 Sample Analyst Signature:. SampleAnalyst Name: f,Ar}n Date: (t Notes 1: SLabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,' +/- 3% Conductiviiy; +/- 0.7 PH unit +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2 Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed Immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 ps/em Abbreviations.. 'C: degrees Celsius S.U.: standard units pmhos/cm: micromhos per centimeter ft: feet mg/L: milligrams per liter in: inches mv: millivolt bgs: below ground surface NTV: nephelometric turbidity units TOC: top of casing Method Reference: Temperature: SM 2550 B-2010 Specific conductivity. EPA Method 120.1, Rev.1982 DO: SM 4500 O G-2011 PH: SM 4500-H' B-2011 Turbidity. SM 2130 B-2011 Page 1 of 1 kZANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log wrll 1D: -• T Project Name: L a! (1 an�f� Project Number. i� Project Location: o it O Sample Collector(s): 'H Well Diameter, 2)�' 1 Screen Interva): 5—) fy Well Depth (as constructed): 1 15G Depth to Water, O r 9 Measuring Point Depth of Pump Intake:' Pump Used (circle): PeristaRi ' Bladder Comments: — Date: 1}'� f M Weather. G� PO -m Facility ID or Permit N (if applicable): W Sample ID (on COQ: � in Arrive at Well: ft bgs Start Time: — ft bgs Sample Time: 1 ft Leave Well: Well Type: riStick U ❑Flush Mount y ft Tagged Bottom: ft at (time): ! Other (describe): Purge Rate:-10 thgw+ Total Volume Purged: PumpSpeed: Hyb V TMre DTW6WQ TemperswmI4 oblieked Ornm (m9I4 Spedlk SKY (pmhw—) pit (SAM ►/nmtsoQ1IU. Oxidation Redut" Pollnttlsl(Mi TO (NTi) �q r 3' .o a n. .s J06 ti . o a 4. Sample Analyst Signature: Sample Analyst Nema: �/(�� Date: S�f Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% 00 and turbidity, +/- 3% Conductivity +/- 0.1 PH unit +/- 10 mV for OPP from EPA- Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members Initials and date 3 Samples are analyzed immediately upon collection. 4 NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 PS/cm Abbreviations: Method Refervnc . 'C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter It feet Specific conductivity. EPA Method 120.1, Rev. 1902 mg/L: milligrams per liter im inches DO: SM 4500 O G-2071 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity SM 2130 B-2011 Page 1 of 1 kzANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log Well ID: Project Name: Project Number: Project Location: Sample Collector(s): Well Diameter: Screen Interval: Well Depth (as constructed): Depth to Water. Measuring Point: Depth of Pump Intake:� Pump Used (circle): Comments: � QJ � �� Q�S Date: -51 "Pt Weather. 1.1 i L Facility ID or Permit # (if applicable); tL 0 0 i 1�, "", Sample ID (on COQ: in Arrive at Well: tJ L - _�3t; ft bgs Start Time: ft bgs Sample Time: — - — ft Leave Well: Well Type: kup ❑Flush Mount ft Tagged Bottom: ft at (time): Paf(cta ' Bladder Other (describe): Purge flats: Total Volume Purged: Pump Speed: - i r l� J — - - Time DTW (tree) Tempammm ;CC) Dbsolved OvIg- (n119M SpttclrK CavIlluclillft ff111111111WC1111+) pH (S.u.) ne0arf 1m Q.1 s:u osddalba Reductlon Potentld (m1t7 Twbldlb (NT1!) 3. ,0 l , I kil fl, A V .5 7 • 1 , , a a D 6!1a� 2 Sample Analyst Signature: Sample Analyst Name: Date: S� l Notes:- 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% 00 and turbidity; +/- 3% Conductivity; +/- 0.1 pM unlr,, +/- 10 mV /or 0RP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is.lill legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection- 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbre latlonw. Method Reference: °G degrees Celsius S.U: standard units Temperature: SM 2550 B•2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity. EPA Method 120.1, Rev. 1982 mg/L• milligrams per liter in: Inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 0-2011 Page 1 of 1 1ZANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log Well ID: w Project Name: 5 Project Number. (,� �. Project Location: r>j to t �� Sample Collector(s):ft Well Diameter. Screen Interval: Well Depth (as constructed): _ Depth to Water.. � �. Measuring Point "1I L Depth of Pump Intake: r-'r Pump Used (circle): Perisia Bladder Comments: T Date: } k Weather. 1 }} �Of . Facility ID or Permit # (if applicable): _W Q1n[_ G� Sample ID (on COC): W_C in Arrive at Well: I� ft bgs Start Time: { ft bgs Sample Time: �� 7 ft Leave Well: Well Typ . tick Up oFlush Mount ft Tagged Bottom: , O ft at (time): Other (describe): Purge Rate: ' Total Volume Purged: Pump Speed: Time DTW (feat) Temperaturo (Q Dissolved 0j"m (Dom SpecRk CotlduetlrNy (Wahn/an) PH (S.II.) FOWI to 0.1 SIR Otddatlon Reduction PotanBM (mV) TurNWIty (NITM r r S: (1611114161 to 5 5 101b. s . a cam. 3 I al ID si. a 1010 1 Li G -3,o .sI q'D Ott. ' Sample Analyst Signature: Sample Analyst Name. ��/(� Date: + l Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% conductivity, r/ O.T pH unit +/- 10 nil/for ORP from EPA - Low - Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation ertors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection 4. NC Field Laboratory Certificate Number 5445 5 1 pmho/cm = 1 ps/cm Abbreviations: Method Reference: T: degrees Celsius S-U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft feet Specific conductivity: EPA Method 120.1, Rev. 1992 mg/L• milligrams per litter In: Inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometdc turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 am Page 1 of 1 kZANCHOR SEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: W'J.. Project Name:` �}�j Dater Project Number: ����� Weather: Weather: 5 Project Location: fl e)A& kMJAJ LI N Facility ID or Permit # (if applicable): 0"L � Sample Collector(s): , / Sample ID (on COC): Comments: lr t I � (i L to JP Semple Method (cirde — one):rGab Syringe Pump Bailer Disp. Other: Spedfic Oxklation Temperature Dissolved Conductivity pH (S.U.) Reduction Turbidity Time VC) Oxygen (mom) 1 (pmhos/cm) report to 0.11U Potential (roll) (NTU) Comments Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Sample Analyst Signature: Access: S Sample Analyst Name: Date:r�J} Hates: 1. Documentation errors are to be crossed out with a sinale line. so the oriainal text is still leaible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: °C: degrees Celsius Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter Specific conductivity. EPA Method 120.1, Rev.1982 mg/L: milligrams per liter DO: SM 4500 O G-2011 mV. millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units Turbidity. SM 2130 B-2011 S.U.: standard units Page 1 of 1 kzANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: Project Name: Pr*ct Number. �. �Yl tC,(� �I5i Date: Weather. _ Project Location: �.k4JLL t\&cility ID or Permit * (if applicable): W ad Sample Collector(s): _ Sample ID (on COC): tea' Comments: �Q VIlggYE'aq-Vl of �, r r�lk �f ,ia , k iykCk' 5 Sample Method [drr* one): Gra Syringe Pump Bailer-Disp. Other. - — Spadfic i Diddation Temperature Dissolved Conductivity pH (S.U.) Reductlon Turbidity Time CC) Oxygen (nqM (pn*Wcm) report to 0.11 S.U. Poten I (n1V) (MU) Comments tu Al Sampling Container Number of containers Requeded Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass _ 1 L Glass Other Vegetation: Sample Analyst Signature: Sample Analyst Name: Access: Date: Q L I 1. Documentation errors are ru.fpe"crossed out with a sinale line. so the oriainal text is still leaible. followed by the staff members initials and date 2. Samples are analyzed Immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: °C: degrees Celsius Temperature: SM 2550 B-2010 yrmhos/cm: micromhos per centimeter Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter DO: SM 4500 O G-2011 mv: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units Turbiditv: SM 2130 B-2011 S.U.: standard units Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 EgUlDnIent tlsu � ��h tion Data S t Project Name: art wli_r {!I _ Analyst Conducting Calibration: Project Number: }^' 0 _ _ Date of Calibration: _ (J• �� Project Location a Date of Field Measurements: Facility ID or Permit * (if applicable): EQUIPMENT DOCUMENTATION Rental mm ple analysis bqulpmrnI or meters used to take measurements: EqLdpnwM T Rnor d Seril Number Data ad' Use Rental Select lurbldlrrsal Hach 21DOQ (s/n 15101 HF Scientific MicroTPW (s/n 200601045) InsdutMM trlMnttttat it Reading: pled, 21000) (1lF SdentMc WaoTPW) W Still hdt F"d 10 NW 20 NTU 100 NTU 000 NTU 1.000 NTU 10.0 NTU fill NTU Lot / Is Dap• t r Cal (M Cal (N Cal (NTU),7M '' Cal (NTLA Cal (NTU): C u); -y Time: 0.1 O Time• Time: Time: Time: Time: tCat radon •Pro -Analysis Result (NTU): Time: "Pre-Anslysils Retail Jy Time: y Check (14 NiU): "Past-Analysis Result NTU): �.�. Time, V ew Result (NTU): Time: Cho&(10NTU): VS1 hafraiana Plui Mu meter Mew Woe 1g0101B0Z) GI Std Infanrdon Instrimmt ReadhW lets Deb �. Dap Dissolved Oxygan Initially(961+: i 1 1, Cal (%j): , R a �f mmHg: Temperature Cq: Time: (%saturation) 01 `• 10 V l l' (w � J DO (Site 02, In I %)• �, Cal (W mmHg: ,r t� Teat fir Cc): j Time: If a Iinbla s a ` QC," Check; DO Time: I esuit (%): Time: Result (%): Time: Result (%): pH 7 S.U. Initial: ()� �]+ pHmV: Cal .U,): Ll PHMV: reort ro a i S.U. Y[^ '1 e, pH4S.U. Initia pHmV: / Cal(S.Uuj)j jj pHmV: / Time: rQ O�.7V y� report to0.1S.0 6• v PH10S.U. Initial: pHmV:/ Cal IS* : pHmV:' TimP�� rr to �• 1 N� report to 0.1 S.U. /�lr QC" pH 7 S.U. Time: Result (S U.): Time: 11 Result (5 U:: Dme; Result (S.U.): a 1 `�Lryq ✓h r ,ort toaIs.U. l �� Spec. Cond. Initial: Cal N rinhos/f1m): Ti a: toW('0/ji 1,000 nahoocra % R000very_ QC' Spec Cond. Time: I l Result fiurihDss/cm): Time: Result (ymhos/cm): Time: Result (ymhos/cm): 1.000 pmhos/ms % Recovery. ORP30mV InitiQ:� Cale a0 Temperaure(°Cj: Time: N ljjjq ,�?i J Analyst Signature: _ Analyst Name: f� Dap: Notes V V Revision 6, 12/20/20, 1. Instruments shall be eAlbrated in accordance with the manufacturer's operation manual. 2. Specific Conductivity should be calibrated acmrding to values representative of historic range 3. Order of Calibration Is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks 4. 'When performing DO analyses at muldple sample sites Q.e. project/facllity locations), the DO probe must be calibrated at each sample site prior to analysis. 5 QC Acceptable Ranges: PH +/- 0.1 S.U. and Spadfic C cluct'wity 10% of the true value. IFQC readings are out of range, the instrument needs to be recalibrated. 6. "' QC chock must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with ca11bradon standard from a separate lot ha as the initial QC, 7. % Recovery = (Value Obtained, pmiros/cm : True Value, pmhos/cm) x 100 a NC Feld laboratory Certificate Number 5445 9. Documentation errors are to be crossed out with a single line, so the original teat is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppI Salinity. 11- 1 pmho/cm 1 pS/cm Abbreviations: Method Raferonce: pmhos/cm: mlcromhos per centimeter NTU: nephelametric turbidity units Temperature: SM 2550 B-2010 'C degrees Celsius ORR oxidation reduction potential Specific conductivity: EPA Method 120.1, Re, 1902 DO: dissolved oxygen s/m serial number DO: SM 4500 O G-2011 mg/k milligrams per Ilter S.U.: standard units pH: SM 4500.H' 11-2011 mY: millivolt 5pec Cord.; Specific Conductivity Turblellty: SM 2130 B-2011 Page 1 of 1 �aceAm b i rxamcrueswM iectlon A 3egvired Client Information, :;Urnpary ANCHOR QEA OF NC. PLL Address: 231 Haywood Svm-t Asheville, NC 28801 Email: " fi ✓,-iA !}ar Phone: r9Rp 7Gi-SSi7 Fax Reque,'ed P'-w_ Oalc Lu W 1— t z s 4 5 SAMPLE ID One Character per box" (A-Z, 0-9 1, -) Sample Ids must be unique LAJ-1 'r ,W n AA) Section B Required Project Inidrnlation: ?npvrF To CaPY Ta i Puraha- Order#: Pro eCl Name: Lassonds Pappas Proiect#. L t 111 3 - ' k. m MATRIX CODE U Drmlony Water Ow Weev wr m 3 Waste. Watt PwEud P S° C7 sdusdtd rn aL ai START WIPB O he OT U Tea TS X L4 f w DATE T CHAIN -OF -CUSTODY ! Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice hrforrnatlon: P8 @ 1 Of 1 - Attention: i Co Neme' fie late n Address - Pace Quote: t Race prcpg i stale i Location 7 II PeceProfile !r E552 L.e O w J END r N � � o m a m a LL 5 C Y N Cm L U 0 O O r r Q u Z U m m O O @ E w U O O c O rn N Z = S Z 2 i O LL x Z u • Od1� 1 ���l 1 1 I W11 it e L��/I�l�III��II1lt�C9■■�ANN SO MINEEN SEEN 0 12 ADDm0NAL60MMENT5,- - Br I PFMJAVON nwTi:.7 ; .Trut . . PLEB NAME AND SIGNATURE PPJNIT Nance of SAMPLER: SIGNATURE of SAMPLER: 'TLa B'r I OF rtJATSOry DATE Signed: r �' } mi U Ix nMe'='� :�wrEEcauamoNs z Y -2Jr --- U O c Z > n- m z S o f E Z Attachment 3 DEQ GW-59A — Compliance Report Form GW-59A COMPLIANCE REPORT FORM Permit # WQ0004797 (Submit one each moreiforing period with GIV-59 jornm) 1 Enter date monitoring results were due. (12/31/2020) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? Was any required information missing on the GW-59 report forms? YES X NO 2 IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? 1f the answer is "Yes", ", contact the Regional Officefor guidance. X 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below. Nitrate (2L = 10 mg/L): MW-7R® 40.4 mg/L Fecal Coliform (Total Coliform 2L standard = 1.0 CFU/100mL): MW-6® 5.0 CFU/100ML 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) In the same well(s) In the last two years? X If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES'; list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). Nitrate Fecal Coliform MW-7R (mg/L) MW-6 (CFU/100ML) 11/14/19: 17.1 11/14/19: 7.0 05/06/20: 21.5 05/06/20: 8.0 11/06/20: 13.0 11/06/20: 8.0 5/11/21: 40.4 5/11/21: 5.0 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO MW-7R is at or beyond the review boundary. X If the answer /s "YES" a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly located, contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? X If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may bs Leaulred to determine the tMRipct the waste disposal system Is haytgg at fire review and coo II nce boyBdades surrounding this facility, Failure to do so may sub ect the vermittee to a Notice of Violation, fines, andlor nenatties._ Fecal coliform should not be attributable to site operations. Historical monitoring of an on -site tributary of Mud Creek has found high levels of fecal coliform. Nitrate concentrations exceeded the groundwater standard in MW-7R for the first time in May 2016. The high concentrations of nitrate are likely attributable to the frequent flooding of Mud Creek. g The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form. II hereby acknowledge that the above information was evaluated and the Informatiwi submitted in this report (Compliance Report GIN-59A) Is true and complete to the best of my knowled(jo. r Signature of Permlitee (or Authorized Agent) Date G%V-59A 12/8/2003 Attachment DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms SUBMIT FORM ON YELLOW PAPER ONLY ■ • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM • 1617 MAIL SERVICE CENTER, RALEIGH. NC 27699-1a17 FACILITY INFORMATION Pease PHnf Oeaffy or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge W00004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Her dersonville (Street) NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (State) (Ztp) 0 Spray Field El Remediation: Contact Person. Billy Watson Telephone#: 828-388-8682 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: tram Pem r SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-4 Date sample collected: 5/11/2021 FIELD ANALYSES: WAS Well Depth: 18-20 ft. Well Diameter: 2 in. pH 00400: 5.8 units Temp. 000lo: 13-9 °C DRY at Depth to Water Level 82546: 8.52 ft. below measuring point Screened Interval: 5 ft. to 15 — ft. Spec. Cond. 00094: 258.3 µMhos time of sampling, Measuring Point is 2.43 ft. above land surface Relative M.P. Elevation: 2063.77 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 0.83 gallons Appearance here: ❑ Samples for metals were collected unfiltered: B YES ❑ NO and field acidified: AYES ❑ NO LABORATORY INFORMATION Date sample analyzed: 5/11/2021 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 1.4 mg/L Zn - Zinc 01092 mg/L Col'lform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.05 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 169 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 2.8 mg/L Ca - Calcium 00916 mg/L Chloride oo94o 6.9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total o1o34 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron o1o45 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate oo945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? [11 Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 0.14 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Billy Watson, Maintenance Manager Pennittee (or Authorized Agent) Name and Title - Please print or type Signature of Perrnittee (or Authorized Agent) GW-59 Rev 06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY ■ a DEPARTMENT OF ENVIRONMENTAL QUALITY - HIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORHIATEON PROCESSING UNIT COMPLIANCE REPORT FORM , 1617 MAIL SERVICE CENTER. RALiROM. NC 27699.1617 FACILITY INFORMATION PreaseFWntClearly orType PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Stfeef) NC 28792 County Henderson El Lagoon El Remediation: Infiltration Gallery 'cnl �, m, w�. � Spray Field Remediation: Contact Person: Billy Watson Telephone#: 828-388-8682 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: E ❑ Water Source Heat Pump ❑ Other: rmm SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-5 Date sample collected: 5/11/2021 FIELD ANALYSES: WAS Well Depth: 18.50 ft. Well Diameter: 2 in. pH 0040o 5.5 units Temp. 000lo: 13.1 °C DRY at Depth to Water Level 82646: 8.77 ft. below measuring point Screened Interval: 9 ft. to 19 — ft. Spec. Cond. 00094: 73.3 µMhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2085.60 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 1.24 gallons Appearance here.❑ Samples for metals were collected unfiltered: X YES ❑ NO and field acidified: 0 YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 5/11/2021 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N o0615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <2.0 /100mL Nitrate (NO3) as N 00620 <0.040 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 315o4 /100mL Phosphorus: Total as P 00665 0.090 mg/L (Note_ Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 110 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 5.5 mg/L Ca - Calcium 00916 mg/L Chloride 00940 11.8 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? X Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH,asN; Ammonia Nitrogen, Total) Mn - Manganese o1o55 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs mg/L Effluent Total VOCs* mg/L VOC Removal% Billy Watson, Maintenance Manager Permittee (or Authorized Agent) Name and Title - Please mint or type Signature of Permiftee (or Authorized Agent) GW-59 Rev 06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DFV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: • • • • INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1817 MAIL SERVICE CENTER, RALEIGH, NC 276ag-1a17 FACILITY INFORMATION Please Print Clearfy or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge W00004797 UIC Permit Name (if different): NPOES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Street) NC 28792 County Henderson El Lagoon ❑Remediation: Infiltration Gallery rcity) MAW .Z71, N Spray Field Remediation: Contact Person: Billy Watson Telephone#: 828-388-8682 ❑ Rotary Distributor El Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-6 Date sample collected: 5/11/2021 FIELD ANALYSES: WAS Well Depth: 11.58 ft. Well Diameter: 2 in. pH 00000: 5.5 units Temp. 000lo: 14.7 oC DRY at Depth to Water Level 82546: 5.68 ft. below measuring point Screened Interval: 5 ft. to 10 — ft. Spec. Cond. 00094: 189.3 µMhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 0.97 gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 5/11/2021 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 rng/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 5.0 /100mL Nitrate (NO3) as N 00620 1.4 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.05 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units) issolved Solids:Total 70300 99.0 mg/L All -Aluminum o1105 mg/L pH (Lab) 00403 units Ba - Barium o1oo7 ug/L TOC oo68o 2.2 mg/L Ca - Calcium oo916 mg/L Chloride oo94o 10.9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total olo34 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron o1o45 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate oo945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? 0 Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N: Ammonia Nitrogen. Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs mg/L VOC Removal° Billy Watson, Maintenance Manager Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Penmittee (or Authorized Agent) (Qete) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMEHTOF ENVIRONMENTAL QUALITY - DIY. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMA710NPROCESSING UNrr COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH. NC 271599.1517 FACILITY INFORMATION Please Prim Cleady or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge W00004797 UIC Permit Name (if different) NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Street) NC 28792 County Henderson El Lagoon ❑ Remediation: Infiltration Gallery rc4vl st° ' " 0 Spray Field ❑ Remediation: Contact Person: Billy Watson Telephone#: 828-388-8682 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump El Other: ham+'erms SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-7R Date sample collected: 5/11/2021 FIELD ANALYSES: WAS Well Depth: 17.37 ft. Well Diameter: 2 in. pH 00400: 5.2 units Temp. 000lo: 14.1 °C DRY at Depth to Water Level 82546: 10.85 ft. below measuring p g point Screened Interval: 5 ft. to 15 ft. Spec. Cond. 000sa: 382.2 µ Mhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2062.86 ft. Odor 00085 none check Volume of water pumped/bailed before sampling: 1.19 gallons Appearance here. ❑ Samples for metals were collected unfiltered: BE YES ❑ NO and field acidified: 0 YES El NO LABORATORY INFORMATION Date sample analyzed: 5/11/2021 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 40.4 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.051 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): )issolved Solids:Total 703oo 296 mg/L AI -Aluminum o1105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 1.7 mg/L Ca - Calcium 00916 mg/L Chloride oo94o 34.2 mg/L Cd - Cadmium o1o27 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate oo945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑f Yes (1) ❑ No (0) Specific Conductance 0009s µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn -Manganese 01055 ug/L ,method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only • • • I certfy that, to the best of my knowledge and belief, the information subr-ftted art this report is true, accurate, and complete, and that the laboratory analy.cal data was produced us7ng approved methods of analysts by a DWR-certified laboratory I am aware that there are slgndicant penalties for stibmifting false informat,or,, Including the possibility of fines and imprisonment for knowing violations, Billy Watson, Maintenance Manager Penmittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev 06-07-2018 Signature of Permittee (or Authorize[! Agent) (Date) SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENTOF ENVIRONMENTAL QUALITY • Div. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESstNQ UNi7 COMPLIANCE REPORT FORM 1617 WAIL SERVICE CENTER, RALEIGIA. NC 27999-1517 FACILITY INFORMATION Please FIrineC/eafiyorType PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge W00004797 UIC Permit Name (if different). NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (street) NC y Henderson 28792 Count El Lagoon El Remediation: Infiltration Gallery (city) Spray Field El Remediation: Contact Person: Billy Watson Telephone#: 828-388-8682 ❑ Rotary Distributor ❑ Land Application of Sludge Weil Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: hvm Perr*vt SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-8 Date sample collected: 5/11/2021 FIELD ANALYSES: WAS Well Depth 13 93 ft. Well Diameter: 2 in. pH ooaoo: 6.6 units Temp. 000lo: 13.0 °C DRY at Depth to Water Level szsas: 9.24 ft. below measuring point Screened Interval: 3 ft. to 13 ft. Spec. Cond. 000sa: 187.3 µMhos time ofsampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2060.80 ft. Odor o0085: none check Volume of water pumped/bailed before sampling: 1.08 gallons Appearance here: ❑ Samples for metals were collected unfiltered: B YES El NO and field acidified: ON YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 5/11/2021 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00520 1.7 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.05 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 144 mg/L Al -Aluminum oil o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 3.8 mg/L Ca - Calcium 00916 mg/L Chloride oo94o 2.0 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron olo45 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ENS Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N. Ammonia Nitrogen, Total) Mn -Manganese oloss ug/L ,method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Billy Watson, Maintenance Manager (or Authorized Agent) Name and Title - Please print or type c� T /2W Z' Signature of Pennittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLQW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - ENV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: • • INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1517 MAIL SERVICE CENTER. RALEIGH, NC 276994617 FACILITY INFORMATION PfeaseFwnf CreadyorType PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge W00004797 UIC Permit Name (if different) NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery --! DE Spray Field ❑ Remediation: Contact Person. Billy Watson Telephone#: 828-388-8682 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: ham Pam41 SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-9 Date sample collected: 5/11/2021 FIELD ANALYSES: WAS Well Depth: 18.1 ft. Well Diameter: 2 in. pH oo400: 5.4 units Temp. 000lo: 14.0 °C DRY at Depth to Water Level 82546: 4.75 ft. below measuring point Screened Interval: 3 ft. to 13 ft. Spec. Cond. 00094: 104.6 µMhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2060.23 ft. Odor 000m: none check Volume of water pumped/bailed before sampling: 0.83 gallons Appearance dear here: ❑ Samples for metals were collected unfiltered: © YES El NO and field acidified: © YES ❑ NO LABORATORY INFORMATION Date sample analyzed:5/11/2021 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 <2.0 /100mL Nitrate (NO3) as N 00620 1.9 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.089 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 <25.0 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 3.6 mg/L Ca - Calcium 00916 mg/L Chloride 00940 9.8 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron o1045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? l]■ Yes (1) ❑ No (0) Specific Conductance 0009s µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN. Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Billy Watson, Maintenance Manager Pennittee (or Authorized Agent) Name and Tftle - Please print or type GW-59 Rev.06-07-2018 Signature of Permittee rile Authorized Agerd) (Date)