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HomeMy WebLinkAboutNCG030390_DMR_20210222 (2)PEERLESS B L O W E R S P.O. Box 187 172 South Andrews Ave. Hot Springs, NC 28743 828-622-7500 3C73`�b Division of Water Quality O Attn: DWQ Central Files RCt. FIN/FD 1617 Mail Service Center MAR 15 2021 Raleigh, N.C. 27699-1617 CENT RAL FILF_3 DWF� SECTION Sir or Madam: Enclosed is analysis for a recent storm water event. We have two outfalls, one flows to the French Broad River and the other to Spring Creek. The event took place on 2/22/21, samples were collected after 1 hour and 30 minutes of rain that produced .3 inches of rain in that period of time. Both outfalls are from roof and parking lot drains and there are no manufacturing or storage activity outside of the building. k, r 1, � �4 eel �;" j Don Wallin Materials/Maintenance Director Pace Analytical Services, LLC 2225e acema1yt1Ca1' Asheville, NC 28804 a .pacelebs.cum (828)254-7176 March 03, 2021 Mr. Donald Wallin MMC, Peerless Blowers 172 South Andrews Avenue Hot Springs, NC 28743 RECEIVED MAR 15 2021 `.rlVt IQVL F!I.E5 RE: Project: PeerlessStonnwater DWRSECTION Pace Project No.: 92523505 Dear Mr. Wallin Enclosed are the analytical results for sample(s) received by the laboratory on February 23, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me Sincerely, pro..,.. 7:-We:, Lord Patton lord.pafton@pacelabs.com 1(828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 aceAinalytical. �ew.paal�b>ti.�acn CERTIFICATIONS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification M E87627 North Carolina Drinking Water Certification M 37706 Kentucky UST Certification M 84 North Carolina Field Services Certification #: 5342 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification M 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification M 40 Florida/NELAP Certification M E87648 South Carolina Certification #: 99030001 North Carolina Drinking Water Certification M 37712 virginia/VELAP Certification M 460222 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 23 ceMalytical' SAMPLE ANALYTE COUNT Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92523505001 OUTFALL #1 EPA 1664E TEG 1 PASI-C EPA 200.7 Rev 4.4 1994 KQ 3 PASI-A EPA 625.1 PKS 59 PASI-C EPA 624.1 PM 1 37 PASI-C SM 254OD-2011 RED 1 PASI-A 92523505002 OUTFALL #2 EPA 1664B TEG 1 PASI-C EPA 200.7 Rev 4.4 1994 KQ 3 PASI-A EPA 625.1 PKS 59 PASI-C EPA 624.1 PM 1 37 PASI-C SM 254OD-2011 RED 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 23 ceAnalytical ( re RKM ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #1 Parameters Lab ID: 92523605001 Collected: 02/22/21 11:30 Results Units Report Limit DF Received: 02/23/21 12:00 Matrix: Water Prepared Analyzed CAS No. Qual 1664 SGT HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 03/03/21 09:40 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.41994 Pace Analytical Services -Asheville Copper 6.8 ug/L 5.0 1 02/26/21 02:07 02/28/21 20:28 7440-50-8 Lead ND ug/L 5.0 1 02/2612102:07 02/28/2120:28 7439-92-1 Zinc 16.4 ug/L 10.0 1 02/26/21 02:07 02/28/21 20:28 7440-66-6 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 83-32-9 Acenaphthylene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 208-96-8 Anthracene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 120-12-7 Benzidine ND ug/L 50.0 1 02/26/2107:54 02/26/2121:43 92-87-5 IL Benzo(a)anthracene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/26/2107:54 02/26/2121:43 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 02/26/2107:54 02/26/21 21:43 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 91-58-7 2-Chlorophenol ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 7005-72-3 Chrysene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43_.53-7.0_3 - 3,3'-Dichlorobenzidine ND ug/L 10.0 1 02/26/2107:54 02/26/2121:43 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 120-83-2 Diethylphthalate ND ug/L 5.0 1 02/26/2107:54 02/2612121:43 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 02126/2107:54 02/26/2121:43 105-67-9 Dimethylphthalate ND ug/L 5.0 1 0212612107:54 02/26/2121:43 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 02/26/21 07:54 02/2612121:43 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 02/2612107:54 02/26/2121:43 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 0212612107:54 02/2612121:43 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 122-66-7 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 117-81-7 Fluoranthene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 206-44-0 Fluorene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 87-68-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 23 'o aceftykal Me�n�e.�actitbtcam ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #1 Parameters Lab ID: 92623606001 Collected: 02/22/21 11:30 Results Units Report Limit DF Received: 02/23/21 12:00 Matrix: Water Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Hexachlorobenzene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 02/26/2107:54 02/26/2121:43 77-47-4 Hexachloroethane ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 193-39-5 Isophorone ND ug/L 10.0 1 02/26/2107:54 02/26/2121:43 78-59-1 Naphthalene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 91-20-3 Nitrobenzene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 98-95-3 2-Nitrophenol ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 88-75-5 4-Nitrophenol ND ug/L 10.0 1 02/26/2107:54 02/26/2121:43 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 02/26/21 07:54 02/26/2121:43 86-30-6 Pentachlorophenol ND ug/L 10.0 1 02126/2107:54 02/26/2121:43 87-86-5 Phenanthrene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 85-01-8 Phenol ND ug/L 5.0 1 02/26/21 07:54 02/26/2121:43 108-95-2 Pyrene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 129-00-0 1,2,4-Tdchlorobenzene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 120-82-1 2,4,6-Tdchlorophenol ND ug/L 10.0 1 02126/2107:54 02/26/2121:43 88-06-2 Surrogates Nitrobenzene-d5 (S) 76 % 10-120 1 02126/2107:54 02/26/2121:43 4165-60-0 2-Fluorobiphenyl (S) 58 % 15-120 1 02/26/21 07:54 02/26/2121:43 321-60-8 Terphenyl-dl4 (S) 111 % 11-131 1 02/26/21 07:54 02/26/2121:43 1718-51-0 Phenol-d6 (S) 39 % 10-120 1 02126/2107:54 02/26/2121:43 13127-88-3 2-Fluorophenol (S) 51 % 10-120 1 02/26/2107:54 02/26/2121:43 367-12-4 2,4,6-Tribromophenol (S) 85 % 10-137 1 02/26/2107:54 02/26/2121:43 118-79-6 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Acrolein ND ug/L 5.0 1 02/2412120:23 107-02-8 Acrylonitrile ND ug/L 5.0 1 02/2412120:23 107-13-1 Benzene ND ug/L 1.0 1 02/24/2120:23 71-43-2 Bromodichloromethane ND ug/L 2.0 1 02/24/2120:23 75-27-4 Bromoform ND ug/L 2.0 1 02/2412120:23 75-25-2 Bromomethane ND ug/L 2.0 1 02124/2120:23 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 02/24/21 20:23 56-23-5 Chlorobenzene ND ug/L 2.0 1 02/24/2120:23 108-90-7 Chloroethane ND ug/L 2.0 1 02/24/2120:23 75-00-3 2-Chloroethyivinyl ether ND ug/L 5.0 1 02/24/2120:23 110-75-8 Chloroform ND ug/L 2.0 1 02/24/2120:23 67-66-3 Chloromethane ND ug/L 2.0 1 02/24/2120:23 74-87-3 R1 Dibromochloromethane ND ug/L 2.0 1 02/24/2120:23 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:23 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:23 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:23 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 02/24/2120:23 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 02/2412120:23 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 23 aceAnalytical ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #1 Lab ID: 92623505001 Collected: 02/22/21 11:30 Received: 02/23/21 12:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte 1,1-Dichloroethene ND ug/L 2.0 1 02124/2120:23 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 02124/2120:23 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 02/24/2120:23 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 02/24/2120:23 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 02/24/2120:23 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 02/24/2120:23 10061-02-6 Ethylbenzene ND ug/L 1.0 1 02/24/2120:23 100-41-4 Methylene Chloride ND ug/L 2.0 1 02/24/2120:23 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 02/24/2120:23 79-34-5 Tetrachloroethene ND ug/L 2.0 1 02/24/2120:23 127-18-4 Toluene ND ug/L 1.0 1 02/24/2120:23 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 02124/2120:23 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 02124/2120:23 79-00-5 Trichloroethene ND ug/L 2.0 1 02/24/2120:23 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 02/24/2120:23 75-69-4 Vinyl chloride ND ug/L 2.0 1 02/24/2120:23 75-01-4 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 02/24/2120:23 460-00-4 Toluene-d8 (S) 98 % 70-130 1 02/24/2120:23 2037-26-5 1,2-Dichloroethane-d4 (S) 92 % 70-130 1 02/24/2120:23 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 2540D-2011 Pace Analytical Services - Asheville Total Suspended Solids ND mg/L 2.5 1 02/25/21 19:27 Sample: OUTFALL #2 Lab ID: 92523605002 Collected: 02/22/21 11:20 Received: 02/23/21 12:00 Matrix: Water Parameters 1664 SGT HEM, TPH Total Petroleum Hydrocarbons 200.7 MET ICP Copper Lead Zinc 625 RVE Acenaphthene Acenaphthylene Anthracene Date: 03/03/2021 03:40 PM Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 1664B Pace Analytical Services - Charlotte ND mg/L 5.0 1 03/03/2109:39 Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville 5.1 ug/L 5.0 1 02/26/2102:07 02/28/2120:31 7440-50-8 ND ug/L 5.0 1 02126/2102:07 02/28/2120:31 7439-92-1 67.3 ug/L 10.0 1 02126/2102:07 02/28/2120:31 7440-66-6 Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte ND ug/L 5.0 1 02/26/21 07:54 02/26/2122:11 83-32-9 ND ug/L 5.0 1 02/26/2107:54 02/2612122:11 208-96-8 ND ug/L 5.0 1 02/26/21 07:54 02/26/21 22:11 120-12-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, I.I.C. Page 6 of 23 ILe�rcal teu�rpaalstrs.carn ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #2 Parameters Lab ID: 92623606002 Collected: 02/22/21 11:20 Results Units Report Limit DF Received: 02/23/21 12:00 Matrix: Water Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Benzidine ND ug/L 50.0 1 02/26/2107:54 02/26/2122:11 92-87-5 IL Benzo(a)anthracene ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 02/26/2107:54 0212612122:11 205-99-2 Benzo(g,hJ)perylene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 02/26/2107:54 02/2612122:11 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 02126/2107:54 02/26/2122:11 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 02/26/21 07:54 02/26/2122:11 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 02/26/2107:54 02/2612122:11 91-58-7 2-Chlorophenol ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 7005-72-3 Chrysene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 120-83-2 Diethylphthalate ND ug/L 5.0 1 02/26/2107:54 02/2612122:11 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 105-67-9 Dimethylphthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 02/26/2107:54 02/26/2122:11 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 02/2612107:54 02/26/2122:11 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 02126/2107:54 02/26/2122:11 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 02126/2107:54 02/26/2122:11 122-66-7 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 117-81-7 Fluoranthene ND ug/L 5.0 1 02/2612107:54 02/26/2122:11 206-44-0 Fluorene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 02126/2107:54 02/26/2122:11 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 77-47-4 Hexachloroethane ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 193-39-5 Isophorone ND ug/L 10.0 1 02/26/2107:54 02126/2122:11 78-59-1 Naphthalene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 91-20-3 Nitrobenzene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 98-95-3 2-Nitrophenol ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 88-75-5 4-Nitrophenol ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 86-30-6 Pentachlorophenol ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 87-86-5 Phenanthrene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 85-01-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 23 aceARalytical WW1r pacdrh = ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Servlces, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #2 Lab ID: 92523505002 Collected: 02/22/21 11:20 Received: 02/23/21 12:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenol ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 108-95-2 Pyrene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 88-06-2 Surrogates Nitrobenzene-d5 (S) 68 % 10-120 1 02/26/2107:54 02/26/2122:11 4165-60-0 2-Fluorobiphenyl (S) 52 % 15-120 1 02/26/21 07:54 02/26/2122:11 321-60-8 Terphenyl-d14 (S) 98 % 11-131 1 02/26/2107:54 02/26/2122:11 1718-51-0 Phenol-d6 (S) 29 % 10-120 1 02/26/21 07:54 02/26/2122:11 13127-88-3 2-Fiuorophenol (S) 34 % 10-120 1 02/26/21 07:54 02/26/2122:11 367-12-4 2,4,6-Tribromophenol (S) 54 % 10-137 1 02/26/2107:54 02/26/2122:11 118-79-6 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Acrolein ND ug/L 5.0 1 02/24/2120:41 107-02-8 Acrylonitrile ND ug/L 5.0 1 02/24/2120:41 107-13-1 Benzene ND ug/L 1.0 1 02/24/2120:41 71-43-2 Bromodichloromethane ND ug/L 2.0 1 02/24/2120:41 75-27-4 Bromoform ND ug/L 2.0 1 02/24/2120:41 75-25-2 Bromomethane ND ug/L 2.0 1 02/24/2120:41 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 02/24/2120:41 56-23-5 Chlorobenzene ND ug/L 2.0 1 02/24/2120:41 108-90-7 Chloroethane ND ug/L 2.0 1 02/24/2120:41 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 02/24/2120:41 110-75-8 Chloroform ND ug/L 2.0 1 02/24/2120:41 67-66-3 Chloromethane ND ug/L 2.0 1 02/24/2120:41 74-87-3 Dibromochloromethane ND ug/L 2.0 1 02/24/2120:41 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:41 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 02124/2120:41 541-73-1 - �- 1,4-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:41 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 02/24/2120:41 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 02/24/2120:41 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 02/24/2120:41 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 02/24/2120:41 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 02/24/2120:41 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 02/24/2120:41 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 02/24/2120:41 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 02/24/2120:41 10061-02-6 Ethylbenzene ND ug/L 1.0 1 02/24/2120:41 100-41-4 Methylene Chloride ND ug/L 2.0 1 02/24/2120:41 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 02/24/2120:41 79-34-5 Tetrachloroethene ND ug/L 2.0 1 02/24/2120:41 127-18-4 Toluene ND ug/L 1.0 1 02/24/2120:41 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 02/24/2120:41 71-55-6 1,1,2-Trichioroethane ND ug/L 2.0 1 02/24/2120:41 79-00-5 Trichloroethene ND ug/L 2.0 1 02/24/2120:41 79-01-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, I-I-C. Page 8 of 23 aceAt'cal meat p plod an ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #2 Parameters Lab ID: 92523605002 Collected: 02/22/21 11:20 Results Units Report Limit DF Received: 02/23/21 12:00 Matrix: Water Prepared Analyzed CAS No. Qual 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Trichlorofluoromethane ND ug/L 2.0 1 02/24/2120:41 75-69-4 Vinyl chloride ND ug/L 2.0 1 02/24/21 20:41 75-01-4 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 02/24/21 20:41 460-00-4 Toluene-d8 (S) 97 % 70-130 1 02/24/21 20:41 2037-26-5 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 02/24/21 20:41 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 32.6 mg/L 5.0 1 02/25/21 19:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in fall, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, L.L.C. Page 9 of 23 aCeAnalytica! t�rlr.�pl=tecatll QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 603708 Analysis Method: EPA 1664B QC Batch Method: EPA 1664E Analysis Description: 1664 SGT=HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92523505001, 92523505002 METHOD BLANK: 3180620 Matrix: Water Associated Lab Samples: 92523505001, 92523505002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L ND 5.0 03/03/21 09:34 LABORATORY CONTROL SAMPLE: 3180621 Spike LCS LCS e% Rec Parameter Units Conc. Result °% Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 20 17.3 86 64-132 MATRIX SPIKE SAMPLE: 3180622 35613802002 Spike MS MS °% Rec Parameter Units Result Conc. Result °% Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 5.OU 20 ND 4 64-132 M1 Results presented on this page are to the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 23 aceAr�alydr"calWWKPWaks QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 602773 QC Batch Method: EPA 200.7 Rev 4.41994 Associated Lab Samples: 92523505001, 92523505002 Analysis Method: Analysis Description: Laboratory: EPA 200.7 Rev 4.4 1994 200.7 MET Pace Analytical Services -Asheville METHOD BLANK: 3176232 Matrix: Water Associated Lab Samples: 92523505001, 92523505002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper ug/L ND 5.0 02/28/2119:06 Lead ug/L ND 5.0 02/28/2119:06 Zinc ug/L ND 10.0 02128/2119:06 LABORATORY CONTROL SAMPLE: 3176233 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper ug/L 500 522 104 85-115 Lead ug/L 500 500 100 85-115 Zinc ug/L 500 497 99 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3176234 3176235 MS MSD 92523050001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual Copper ug/L 14.8 500 500 539 532 105 104 70-130 1 Lead ug/L ND 500 500 492 491 98 98 70-130 0 Zinc ug/L 0.049 500 500 555 553 101 101 70-130 0 mg/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3176236 3176237 MS MSD 92523693001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual Copper ug/L 607 500 500 1140 1120 107 103 70-130 2 Lead ug/L ND 500 500 506 500 101 100 70-130 1 Zinc ug/L 27.1 500 500 531 526 101 100 70-130 1 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23 aceAnalytical r�ew.�plstr�.�cta QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 QC Batch: 602248 Analysis Method: EPA 624.1 QC Batch Method: EPA 624.1 Analysis Description: 624 MSV with Acrolein Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92523505001, 92523505002 METHOD BLANK: 3173190 Matrix: Water Associated Lab Samples: 92523505001, 92523505002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1-Tdchloroethane ug/L ND 2.0 02124/2110:36 1,1,2,2-Tetrachlorcethane ug/L ND 2.0 02/24/21 10:36 1,1,2-Tdchloroethane ug/L ND 2.0 02/24/21 10:36 1,1-Dichloroethane ug/L ND 2.0 02124/2110:36 1,1-Dichloroethene ug/L ND 2.0 02/24/21 10:36 1,2-Dichlorobenzene ug/L ND 2.0 02/24/21 10:36 1,2-Dichloroethane ug/L ND 2.0 02/24/21 10:36 1,2-Dichloropropane ug/L ND 2.0 02/24/21 10:36 1,3-Dichlorobenzene ug/L ND 2.0 02/24/21 10:36 1,4-Dichlorobenzene ug/L ND 2.0 02/24/21 10:36 2-Chloroethylvinyl ether ug/L ND 5.0 02/24/21 10:36 Acrolein ug/L ND 5.0 02/24/21 10:36 Acrylonitrile ug/L ND 5.0 02/24/21 10:36 Benzene ug/L ND 1.0 02/24/21 10:36 Bromodichloromethane ug/L ND 2.0 02/24/21 10:36 Bromoform ug/L ND 2.0 02/24/21 10:36 Bromomethane ug/L ND 2.0 02/24/21 10:36 Carbon tetrachloride ug/L ND 2.0 02/24/21 10:36 Chlorobenzene ug/L ND 2.0 02/24/21 10:36 Chloroethane ug/L ND 2.0 02/24/21 10:36 Chloroform ug/L ND 2.0 02/24/21 10:36 Chloromethane ug/L ND 2.0 02124/2110:36 cis-1,2-Dichloroethene ug/L ND 2.0 02/24/21 10:36 cis-1,3-Dichloropropene ug/L ND 2.0 02/24/21 10:36 Dibromochloromethane ug/L ND 2.0 02124/2110:36 Ethylbenzene ug/L ND 1.0 02/24/21 10:36 Methylene Chloride ug/L ND 2.0 02/24/21 10:36 Tetrachloroethene ug/L ND 2.0 02/24/21 10:36 Toluene ug/L ND 1.0 02/2412110:36 trans-1,2-Dichloroethene ug/L ND 2.0 02/24/21 10:36 trans-1,3-Dichloropropene ug/L ND 2.0 02/24/21 10:36 Tdchloroethene ug/L ND 2.0 02/24/21 10:36 Trichlorofluoromethane ug/L ND 2.0 02/24/21 10:36 Vinyl chloride ug/L ND 2.0 02/24/21 10:36 1,2-Dichloroethane-d4 (S) °% 91 70-130 02/24/21 10:36 4-Bromofluorobenzene (S) % 98 70-130 02/24/21 10:36 Toluene-d8 (S) °% 98 70-130 02/24/21 10:36 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the reautL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 23 ® aceAnaiyrcal ttillilR�6dtf13.COt0 Project: Peerless Stormwater Pace Project No.: 92523505 QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 3173191 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1, 1, 1 -Trichloroethane ug/L 20 18.3 92 70-130 1,1,2,2-Tetrachloroethane ug/L 20 20.6 103 70-130 1,1,2-Trichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethane ug/L 20 18.9 94 70-130 1,1-Dichloroethene ug/L 20 19.9 100 70-132 1,2-Dichlorobenzene ug/L 20 22.9 115 70-130 1,2-Dichloroethane ug/L 20 16.8 84 70-130 1,2-Dichloropropane ug/L 20 19.9 99 70-130 1,3-Dichlorobenzene ug/L 20 22.0 110 70-130 1,4-Dichlorobenzene ug/L 20 23.1 115 70-130 2-Chloroethylvinyl ether ug/L 40 30.3 76 67-130 Acrolein ug/L 100 103 103 60-140 Acrylonitrile ug/L 100 98.1 98 70-130 Benzene ug/L 20 19.5 98 70-130 Bromodichloromethane ug/L 20 17.4 87 70-130 Bromoform ug/L 20 18.7 94 70-130 Bromomethane ug/L 20 26.1 130 30-177 Carbon tetrachloride ug/L 20 18.4 92 70-130 Chlorobenzene ug/L 20 20.8 104 70-130 Chlorcethane ug/L 20 23.8 119 46-131 Chloroform ug/L 20 18.3 91 70-130 Chloromethane ug/L 20 17.9 89 49-130 cis-1,2-Dichloroethene ug/L 20 18.8 94 70-130 cis- 1, 3-Dichloropropene ug/L 20 20.4 102 70-130 Dibromochlorcmethane ug/L 20 19.5 98 70-130 Ethylbenzene ug/L 20 20.4 102 70-130 Methylene Chloride ug/L 20 18.3 92 68-130 Tetrachloroethene ug/L 20 19.8 99 70-130 Toluene ug/L 20 19.5 97 70-130 trans-1,2-Dichloroethene ug/L 20 19.7 98 70-130 trans-1,3-Dichloropropene ug/L 20 19.2 96 70-130 Trichloroethene ug/L 20 19.8 99 70-130 Trichlorofluoromethane ug/L 20 20.4 102 61-130 Vinyl chloride ug/L 20 17.6 88 59-142 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromoftuorobenzene (S) % 96 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3173192 Parameter 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane MS 92523505001 Spike Units Result Conc. ug/L ND 20 ug/L ND 20 ug/L ND 20 3173193 MSD Spike MS MSD MS Conc. Result Result % Rec 20 20.7 20.4 104 20 18.2 18.9 91 20 20.5 19.6 103 MSD % Rec % Rec Limits RPD Qual 102 70-148 2 94 70-131 4 98 70-136 5 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resulL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 23 CUAnalytical �rtnrpactltbsaaia QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3173192 3173193 MS MSD 92523505001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1-Dichloroethane ug/L ND 20 20 20.4 19.2 102 96 71-143 6 1,1-Dichloroethene ug/L ND 20 20 22.0 21.1 110 105 70-158 4 1,2-Dichlorobenzene ug/L ND 20 20 20.7 20.3 104 101 70-133 2 1,2-Dichloroethane ug/L ND 20 20 18.4 17.5 92 88 72-137 5 1,2-Dichloropropane ug/L ND 20 20 20.4 19.9 102 99 70-138 3 1,3-Dichlorobenzene ug/L ND 20 20 20.6 20.0 103 100 75-133 3 1,4-Dichlorobenzene ug/L ND 20 20 20.8 20.1 104 100 70-133 4 2-Chloroethyivinyl ether ug/L ND 40 40 36.6 39.2 92 98 10-200 7 Acrolein ug/L ND 100 100 91.3 89.4 91 89 50-150 2 Acrylonitrile ug/L ND 100 100 89.6 89.8 90 90 68-140 0 Benzene ug/L ND 20 20 20.3 19.0 102 95 75-125 7 Bromodichloromethane ug/L ND 20 20 19.0 18.8 95 94 70-138 1 Bromoform ug/L ND 20 20 20.4 21.2 102 106 57-138 4 Bromomethane ug/L ND 20 20 15.0 14.6 75 73 10-200 3 Carbon tetrachloride ug/L ND 20 20 21.7 21.7 108 108 70-125 0 Chlorobenzene ug/L ND 20 20 20.5 21.2 102 106 82-137 4 Chloroethane ug/L ND 20 20 17.4 15.6 87 78 51-166 11 Chloroform ug/L ND 20 20 19.3 19.1 97 95 70-121 1 Chloromethane ug/L ND 20 20 10.6 17.7 53 89 24-161 51 R1 cis-1,2-Dichloroethene ug/L ND 20 20 19.4 18.3 97 91 67-148 6 cis-1,3-Dichloropropene ug/L ND 20 20 19.8 20.1 99 100 70-142 1 Dibromochloromethane ug/L ND 20 20 21.4 21.5 107 107 69-133 1 Ethylbenzene ug/L ND 20 20 20.7 20.8 104 104 75-134 0 Methylene Chloride ug/L ND 20 20 18.8 17.7 94 88 64-148 6 Tetrachloroethene ug/L ND 20 20 23.4 23.7 117 118 70-133 1 Toluene ug/L ND 20 20 20.4 19.8 102 99 75-134 3 trans-1,2-Dichloroethene ug/L ND 20 20 20.5 19.6 103 98 70-143 4 trans-1,3-Dichloropropene ug/L ND 20 20 20.3 19.0 102 95 70-138 7 Trichloroethene ug/L ND 20 20 21.9 21.7 110 108 75-138 1 Tdchlorofluoromethane ug/L ND 20 20 18.9 19.9 95 100 61-154 5 Vinyl chloride ug/L ND 20 20 18.9 18.5 94 92 55-172 2 1,2-Dichloroethane-d4 (S) % 93 98 70-130 4-Bromofluorobenzene (S) % 91 97 70-130 Toluene-d8 (S) % 96 97 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shalt not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 23 IaceAffloical mimpowth"tult QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 QC Batch: 602808 Analysis Method: EPA 625.1 QC Batch Method: EPA 625.1 Analysis Description: 625 MSS Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92523505001, 92523505002 METHOD BLANK: 3176312 Associated Lab Samples: 92523505001, 92523505002 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed 1,2,4-Trichlorobenzene ug/L ND 5.0 02/26/21 11:10 1,2-Diphenylhydrazine ug/L ND 5.0 02/26/21 11:10 2,4,6-Trichlorophenol ug/L ND 10.0 02/26/21 11:10 2,4-Dichlorophenol ug/L ND 5.0 02/26/21 11:10 2,4-Dimethylphenol ug/L ND 10.0 02/26/21 11:10 2,4-Dinitrophenol ug/L ND 50.0 02/26/21 11:10 2,4-Dinitrotoluene ug/L ND 5.0 02/26/21 11:10 2,6-Dinitrotoluene ug/L ND 5.0 02/26/21 11:10 2-Chloronaphthalene ug/L ND 5.0 02/26/21 11:10 2-Chlorophenol ug/L ND 5.0 02/26/21 11:10 2-Nitrophenol ug/L ND 5.0 02/26/21 11:10 3,3'-Dichlorobenzidine ug/L ND 10.0 02/26/21 11:10 4,6-Dinitro-2-methylphenol ug/L ND 10.0 02/2612111:10 4-Bromophenylphenyl ether ug/L ND 5.0 02/26/21 11:10 4-Chloro-3-methylphenol ug/L ND 5.0 02/26/21 11:10 4-Chlorophenylphenyl ether ug/L ND 5.0 02/26/21 11:10 4-Nitrophenol ug/L ND 10.0 02/2612111:10 Acenaphthene ug/L ND 5.0 02/26/21 11:10 Acenaphthylene ug/L ND 5.0 02/2612111:10 Anthracene ug/L ND 5.0 02/26/21 11:10 Benzidine ug/L ND 50.0 0212612111:10 IL Benzo(a)anthracene ug/L ND 5.0 02126/2111:10 Benzo(a)pyrene ug/L ND 5.0 02/26/21 11:10 Benzo(b)fluoranthene ug/L ND 5.0 02126/2111:10 Benzo(g,h,i)perylene ug/L ND 5.0 02/26/21 11:10 Benzo(k)fluoranthene ug/L ND 5.0 02/26/21 11:10 bis(2-Chloroethoxy)methane ug/L ND 10.0 02/26/21 11:10 bis(2-Chloroethyl) ether ug/L ND 5.0 02/26/21 11:10 bis(2-Ethylhexyl)phthalate ug/L ND 5.0 02/26/21 11:10 Butylbenzylphthalate ug/L ND 5.0 02/26/21 11:10 Chrysene ug/L ND 5.0 02/26/21 11:10 Di-n-butylphthalate ug/L ND 5.0 02/26/21 11:10 Di-n-octylphthalate ug/L ND 5.0 02/26/21 11:10 Dibenz(a,h)anthracene ug/L ND 5.0 02/2612111:10 Diethylphthalate ug/L ND 5.0 02/2612111:10 Dimethylphthalate ug/L ND 5.0 02/26/21 11:10 Fluoranthene ug/L ND 5.0 02/26/21 11:10 Fluorene ug/L ND 5.0 02/26/21 11:10 Hexachloro-1,3-butadiene ug/L ND 5.0 02/2612111:10 Hexachlorobenzene ug/L ND 5.0 02/26/21 11:10 Qualifiers Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, IBC 28804 (828)254-7176 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23 m aceftlytrcal Project: Peerless Stormwater Pace Project No.: 92523505 QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside 04 Asheville, NC 28804 (828)254-7176 METHOD BLANK: 3176312 Matrix: Water Associated Lab Samples: 92523505001, 92523505002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Hexachlorocyclopentadiene ug/L ND 10.0 02/26/21 11:10 Hexachloroethane ug/L ND 5.0 02/26/21 11:10 Indeno(1,2,3-cd)pyrene ug/L ND 5.0 02/26/21 11:10 Isophorone ug/L ND 10.0 02/26/21 11:10 N-Nitroso-di-n-propylamine ug/L ND 5.0 02/26/21 11:10 N-Nitrosodimethylamine ug/L ND 5.0 02/26/21 11:10 N-Nitrosodiphenylamine ug/L ND 10.0 02/26/21 11:10 Naphthalene ug/L ND 5.0 02/26/21 11:10 Nitrobenzene ug/L ND 5.0 02/26/21 11:10 Pentachlorophenol ug/L ND 10.0 02126/2111:10 Phenanthrene ug/L ND 5.0 02/26/21 11:10 Phenol ug/L ND 5.0 02/26/21 11:10 Pyrene ug/L ND 5.0 02/26/21 11:10 2,4,6-Tribromophenol (S) °% 95 10-137 02/26/21 11:10 2-Fluorobiphenyl (S) % 77 15-120 02/26/21 11:10 2-Fluorophenol (S) °% 61 10-120 02/26/21 11:10 Nitrobenzene-d5 (S) °% 94 10-120 02/26/21 11:10 Phenol-d6 (S) % 46 10-120 02/26/21 11:10 Terphenyl-d14 (S) °% 138 11-131 02/26/21 11:10 S3 LABORATORY CONTROL SAMPLE: 3176313 Spike LCS LCS °% Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/L 50 30.9 62 44-142 1,2-Diphenylhydrazine ug/L 50 49.9 100 25-150 2,4,6-Trichlorophenol ug/L 50 52.1 104 37-144 2,4-Dichlorophenol ug/L 50 49.8 100 1-191 2,4-Dimethylphenol ug/L 50 51.9 104 32-119 2,4-Dinitrophenol ug/L 250 320 128 1-181 2,4-Dinitrotoluene ug/L 50 46.1 92 39-139 2,6-Dinitrotoluene ug/L 50 60.3 121 50-158 2-Chloronaphthalene ug/L 50 35.4 71 60-118 2-Chlorophenol ug/L 50 47.7 95 23-134 2-Nitrophenol ug/L 50 57.4 115 29-182 3,3'-Dichlorobenzidine ug/L 100 115 115 1-262 4,6-Dinitro-2-methylphenol ug/L 100 138 138 1-181 4-Bromophenylphenyl ether ug/L 50 50.4 101 53-127 4-Chloro-3-methylphenol ug/L 100 103 103 22-147 4-Chlorophenylphenyl ether ug/L 50 42.2 84 25-158 4-Nitrophenol ug/L 250 151 60 1-132 Acenaphthene ug/L 50 39.5 79 47-145 Acenaphthylene ug/L 50 42.9 86 33-145 Anthracene ug/L 50 55.3 111 1-166 Benzidine ug/L 100 ND 11 10-130 IL Results presented on this page are to the units indicated by the "Units" column except where an alternate unit is presented to the right of the resulL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 23 aceftlytical WWdLPWd8h= QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 LABORATORY CONTROL SAMPLE: 3176313 Spike Parameter Units Conc. Benzo(a)anthracene ug/L 50 Benzo(a)pyrene ug/L 50 Benzo(b)fiuoranthene ug/L 50 Benzo(g,h,i)perylene ug/L 50 Benzo(k)fluoranthene ug/L 50 bis(2-Chloroethoxy)methane ug/L 50 bis(2-Chloroethyl) ether ug/L 50 bis(2-Ethylhexyl)phthalate ug/L 50 Butylbenzylphthalate ug/L 50 Chrysene ug/L 50 Di-n-butylphthalate ug/L 50 Di-n-octylphthalate ug/L 50 Dibenz(a,h)anthracene ug/L 50 Diethylphthalate ug/L 50 Dimethylphthalate ug/L 50 Fluoranthene ug/L 50 Fluorene ug/L 50 Hexachloro-1,3-butadiene ug/L 50 Hexachlorobenzene ug/L 50 Hexachlorocyclopentadiene ug/L 50 Hexachloroethane ug/L 50 Indeno(1,2,3-cd)pyrene ug/L 50 Isophorone ug/L 50 N-Nitroso-di-n-propylamine ug/L 50 N-Nitrosodimethylamine ug/L 50 N-Nitrosodiphenylamine ug/L 50 Naphthalene ug/L 50 Nitrobenzene ug/L 50 Pentachlorophenol ug/L 100 Phenanthrene ug/L 50 Phenol ug/L 50 Pyrene ug/L 50 2,4,6-Tdbromophenol (S) % 2-Fiuorobiphenyl (S) % 2-Fluorophenol (S) °% Nitrobenzene-d5 (S) % Phenol-d6 (S) % Terphenyl-dl4 (S) % LCS Result 59.2 60.2 59.9 57.7 57.9 50.6 53.0 65.1 64.8 56.5 58.2 71.0 59.6 52.6 50.8 56.7 46.1 27.7 48.4 28.3 31.2 60.2 52.1 53.9 39.9 51.3 36.8 51.9 113 52.8 30.2 55.7 LCS % Rec % Rec Limits 118 33-143 120 17-163 120 24-159 115 1-219 116 11-162 101 33-184 106 12-158 130 8-158 130 1-152 113 17-168 116 1-118 142 4-146 119 1-227 105 1-114 102 1-112 113 26-137 92 59-121 55 24-116 97 1-152 57 25-150 62 40-113 120 1-171 104 21-196 108 1-230 80 25-150 103 25-150 74 21-133 104 35-180 113 14-176 106 54-120 60 5-112 111 52-115 109 10-137 81 15-120 65 10-120 100 10-120 48 10-120 119 11-131 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resulL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 23 aceft yticai wwPueltbs.m QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Or. Asheville, NC 28804 (828)254-7176 QC Batch: 602714 Analysis Method: SM 254OD-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92523505001, 92523505002 METHOD BLANK: 3175982 Matrix: Water Associated Lab Samples: 92523505001, 92523505002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 02/25/21 19:22 LABORATORY CONTROL SAMPLE: 3175983 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 240 96 90-110 SAMPLE DUPLICATE: 3176179 92523421004 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 1530 1400 8 SAMPLE DUPLICATE: 3176180 92524022001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 5900 6000 2 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23 Pace Analytical Services, LLC 2225 Riverside Dr. CG�•""" Asheville, NC 28804 tr.els6scatn (828)254-7176 QUALIFIERS Project: Peerless Stormwater Pace Project No.: 92523505 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services. LLC. Page 19 of 23 2UuAnalyiicallku= QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92623606001 OUTFALL #1 EPA 1664E 603708 92623506002 OUTFALL #2 EPA 1664B 603708 92523505001 OUTFALL #1 EPA 200.7 Rev 4.41994 602773 EPA 200.7 Rev 4.41994 92523505002 OUTFALL #2 EPA 200.7 Rev 4.41994 602773 EPA 200.7 Rev 4.41994 92523505001 OUTFALL #1 EPA 625.1 602808 EPA 625.1 92623605002 OUTFALL #2 EPA 625.1 602808 EPA 625.1 92523505001 OUTFALL #1 EPA 624.1 602248 92623506002 OUTFALL #2 EPA 624.1 602248 92623605001 OUTFALL #1 SM 2540D-2011 602714 92523SC5002 OUTFALL #2 SM 2540D-2011 602714 Date: 03/03/2021 03:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 602805 602805 602884 602884 Page 20 of 23 Document Name: Document Revised: October 28, 2020 n��,s,�6�,,��,, CB^„esJrrCalo r Sample Condition Upon Recelpt(SCUR Page 1 of 2 Document No.: F-CAR-CS-033-Rev 07 Issuing Authority: Pace Carolinas Quality Office Laboratoryrec ing samples: Asheville Eden[] Greenwood ❑ Huntersvllle ❑ Raleigh❑ Mechanicsville[] Atlanta❑ Kernersville❑ Client Name: WO# : 92523505 11p1C • _ Pezr�a 3f CJ�"�itr-1 Project Courier: ❑Fed IN UOPS ❑USPS ❑Client 11111 II I II Till III ❑ Commercial []Pace []Other:— 5 Custody Seal Present? ❑Yes �No Seals Intact? ❑Yes E3(do Packing Material: []Bubble Wrap 8 bbie Bags ❑None ❑ Other Thermometer �T� Gun to: / V wet ❑Blue FIRGunof Ica: Correction Factor: Cooler Temp: Add/Subtract('C) lJ Cooler Temp Corrected('C" USDA Regulated Soil( /A, water sample) Did samoles originate in a auarantine zone within the United States: CA. NY. or SC (check maps)? 9252350 Dace/Initials Person Examining Contents:QT) _JJ--a., Biological Tissue Pozen? ❑Yes []Nos(�N/A ❑None Temp should be above freezing to 6'C ❑sanples out of temp criteria. Samples on Ice, cooling process has begun Did samdes originate from a foreign source (Intem thmally, Yes CgKo includmgilawail and Puerto Rlcop Ures ipno Comments Olscrepancy: Chain of Custody Present? es nN. N/A 1. Samples Arrived within Hold lime? Mfe, EJNq ❑N/A 2. Short Hold Time Analysis 1<72 hr.? Yes N/A 3. Rush Turn Around Time Requested? vas No N A 4. Suff Went Volume? 0NO N/A S. Correct Containers used? -Pace Containers Used? es [IN. []NIA No N A 6. Containers intact? Er 171NO ❑N/A 7. Dissolved analysis: Samples Field Filtered? vas No /A a. Sample Labels Match COC? -Includes Date/Time/ID/Anal sls Matrix: vas —r []NO ❑N/A 9. Heads ace in VOA Vials (>S-6mm 7 es N, 5k1a v S 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes ❑Yes w COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Field Data Required? ❑Yes []No Person contacted: Date/Time: Project Manager SCURF Review: Date: AI; a� Project Manager SRF Review: Date: Page 21 of 23 a aceAnalyticai Document Name: Sample Condition Upon Recet t SCUR) Document Revised: October 28, 2020 page 2 of 2 Document No.: F-CAR-CS-033-Rev.07 Issuing Authority: Pace Carolinas Quality Office *Check mark top half of box If pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, UMS **Bottom half of box is to list number of bottles Project # tine: Q- 2-ru3sds PH: UP Due Date: 03/03/21 CLIENT: 93-PEERLESS a 0 U N a Z Z a °1 .. m f -- 'p t7 v ^� N dj '� zp tea► ^ Ci .. 2 �1 V V a. N � j V N z a to u uu b�uss cam, _u t A E = Z a _ 1 a � , � -i , � ..� � .. .. E ¢ -J .�. , � � ,� � � E E E E E E t►E� E QE E E E E -o V 5 o E E E E E 'G a 0 g o Qq iSQ ^� r, "1 Sri fl�y1 `4 1q- q g =Q .M•. F�. A tJl Z N {,� N R=f e1 f�rf M Cf Of GM1 01 a iA qq f7 0. 0. d CL C6 OI. O¢. m m m m m m m m S ¢ ¢ Q Q Q ¢ O > > 1 1 131 L L L I NNX 2 1 iNi I N N N I I I n I I Na 3 4 5 6 7 8 9 10 31 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added lot R -4f61.1. L.........111 k. ram -..I,.. +kn Nnrfk rnrnnna nFHNR Certification Office (i.e. RUIC: YYRCnCVef LRCre IS a U13VFCPdI{{.r OItCl.11tlg 6w.a.. w.v...... ��•••r - ^--- r --• out of hold, Incorrect preservative, out of temp. Incorrect containers. Page 22 of 23 a � �� z � � �` m ao; � o►.� a a. w IV ITEM N *t � bN MATRUt CODE (fa vttBd codef to (� &WMTYPE (G•GRM C*COMP) r m o i ��IYYY y -i. SAMPIETE!<RPATCOLLECTION ,M i OF CONTAINERS A Unpressivocl { H2804 :• I 7x HNO3 HCI 4 NsOH N828203 Methanol other a n AIl*M Test . YINmin Pb, Zn M.7 VOCby624 h 8V0AU5 At M O T88 °s TPH SGT-HEM IM F. • • -• TEMP in C. Reeidu®I Chlodne (YIN) Received an ice (Y" Sealed CooMr samples = • • 7 Page 23 of 23