NC0037508_EPA Requirements_20040407

Department of Public Utilities
Wastewater Treatment Plant
1094 Addor Road
Aberdeen, NC 28315
aanty a/ aaxe
April 7, 2004
Re: Results for EPA Expanded Requirements for Permit Renewal
NPDES Permit No. NC0037508
Mrs. Valery Stephens
NCDENR/D WQ/NPDES
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Mrs. Stephens:
Telephone: [phone] t)
Facsimile: [phone]
COPY"
DEN
Ai4Z - 8 2304
l�f O
PIease find included a copy of the Priority Pollutant Analysis and the Fat Head Minnow
Toxicity test results for March 2004. This is the second set of test for plant. renewal. The
next set of test will be done in June. I will send you those results as I receive them.
If additional information is needed, please do not hesitate to call me at 910-281-3146.
Sincerely,
t:
James D. Frye, System Superintendent
JDF/sab
Cc: Mr. Paul Rawls, Fayetteville Regional Office, DEM
Mr. Charles Weaver, NPDES Unit
Mr. Kevin Bowden, Aquatic Toxicology Unit
Mr. Steve Wyatt, County Manager
Mr. Phillip Boles, Director of Public Utilities
0

ENVIRONMENTAL OPy
SCIENCE CORP .
REPORT OF ANALYSIS
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Date Received March 12, 2004
Description 13874-Moore County WWTP
Sample ID 0310088
Collected By Operator
Collection Date : 03/10/04 07:54
March 19, 2004
12065 Lebanon.Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
ESC Sample # : L147403-01
Site ID .
Project # : TBL-13874
Parameter Result Det. Limit Units Method Date Dil.
Cyanide BDL 0.0050 mg/1 335.3 03/17/04 1
Hardness,calcium 120 1.3 mg/1 Calc. 03/15/04 1
Total Phenol by 4AAP BDL 0.040 mg/1 420.2 03/18/04 1
Thallium BDL 0.0010 mg/1 200.8 03/19/04 1
Mercury BDL 0.00020 mg/1 245.1 03/15/04 1
Antimony BDL 0.0050 mg/1 200.7 03/13/04 1
Arsenic BDL 0.010 mg/1 200.7 03/15/04 1
Beryllium BDL 0.0020 mg/1 200.7 03/13/04 1
Cadmium BDL 0.0050 mg/1 200.7 03/13/04 1
Calcium 48. 0.50 mg/1 200.7 03/13/04 1
Chromium BDL 0.010 mg/1 200.7 03/13/04 1
Copper 0.016 0.010 mg/1 200.7 03/13/04 1
Lead BDL 0.0050 mg/1 200.7 03/15/04 1
Nickel BDL 0.010 mg/1 200.7 03/13/04 1
Selenium BDL 0.010 mg/1 200.7 03/15/04 1
Silver BDL 0.0050 mg/1 200.7 03/13/04 1
Zinc 0.037 0.030 mg/1 200.7 03/15/04 1
PP Volatile Organics
Benzene BDL 0.0010 mg/1 624 03/14/04 1
Bromodichloromethane BDL 0.0010 mg/1 624 03/14/04 1
Bromoform BDL 0.0010 mg/1 624 03/14/04 1
Bromomethane BDL 0.0010 mg/1 624 03/14/04 1
Carbon tetrachloride BDL 0.0010 mg/1 624 03/14/04 1
Chlorobenzene BDL 0.0010 mg/1 624 03/14/04 1
Chlorodibromomethane BDL 0.0010 mg/1 624 03/14/04 1
Chloroethane BDL 0.0010 mg/1 624 03/14/04 1
2-Chloroethyl vinyl ether BDL 0.050 mg/1 624 03/14/04 1
Chloroform BDL 0.0050 mg/1 624 03/14/04 1
Chloromethane BDL 0.0010 mg/1 624 03/14/04 1
1,2-Dichlorobenzene BDL 0.0010 mg/1 624 03/14/04 1
1,3-Dichlorobenzene BDL 0.0010 mg/1 624 03/14/04 1
1,4-Dichlorobenzene BDL 0.0010 mg/1 624 03/14/04 1
1,1-Dichloroethane BDL 0.0010 mg/1 624 03/14/04 1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
Page 1 of 6
DENR FRO
APR - 8 2004
DWQ

ENVIRONMENTAL
S C I ENCE CORP .
REPORT OF ANALYSIS
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Date Received March 12, 2004
Description 13874-Moore County WWTP
Sample ID 0310088
Collected By Operator
Collection Date : 03/10/04 07:54
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
March 19, 2004
ESC Sample # : L147403-01
Site ID .
Project # : TBL-13874
Parameter Result Det. Limit Units Method Date Dil.
1,2-Dichloroethane BDL 0.0010 mg/1 624 03/14/04 1
1,1-Dichloroethene BDL 0.0010 mg/1 624 03/14/04 1
trans-1,2-Dichloroethene BDL 0.0010 mg/1 624 03/14/04 1
1,2-Dichloropropane BDL 0.0010 mg/1 624 03/14/04 1
cis-1,3-Dichloropropene BDL 0.0010 mg/1 624 03/14/04 1
trans-1,3-Dichloropropene BDL 0.0010 mg/1 624 03/14/04 1
Ethylbenzene BDL 0.0010 mg/1 624 03/14/04 1
Methylene Chloride BDL 0.0050 mg/1 624 03/14/04 1
1,1,2,2-Tetrachloroethane BDL 0.0010 mg/1 624 03/14/04 1
Tetrachloroethene BDL 0.0010 mg/1 624 03/14/04 1
Toluene BDL 0.0050 mg/1 624 03/14/04 1
1,1,1-Trichloroethane BDL 0.0010 mg/1 624 03/14/04 1
1,1,2-Trichloroethane BDL 0.0010 mg/1 624 03/14/04 1
Trichloroethene BDL 0.0010 mg/1 624 03/14/04 1
Vinyl chloride BDL 0.0010 mg/1 624 03/14/04 1
Surrogate Recovery
Toluene-d8 100 % Rec. 624 03/14/04 1
Dibromofluoromethane 110 % Rec. 624 03/14/04 1
4-Bromofluorobenzene 91. % Rec. 624 03/14/04 1
Pesticide/PCBs
Aldrin BDL 0.00050 mg/1 608 03/18/04 1
Alpha BHC BDL 0.00050 mg/1 608 03/18/04 1
Beta BHC BDL 0.00050 mg/1 608 03/18/04 1
Delta BHC BDL 0.00050 mg/1 608 03/18/04 1
Gamma BHC BDL 0.00050 mg/1 608 03/18/04 1
Chlordane BDL 0.0050 mg/1 608 03/18/04 1
4,4-DDD BDL 0.00050 mg/1 608 03/18/04 1
4,4-DDE BDL 0.00050 mg/1 608 03/18/04 1
4,4-DDT BDL 0.00050 mg/1 608 03/18/04 1
Dieldrin BDL 0.00050 mg/1 608 03/18/04 1
Endosulfan I BDL 0.00050 mg/1 608 03/18/04 1
Endosulfan II BDL 0.00050 mg/1 608 03/18/04 1
Endosulfan sulfate BDL 0.00050 mg/1 608 03/18/04 1
Endrin BDL 0.00050 mg/1 608 03/18/04 1
Endrin aldehyde BDL 0.00050 mg/1 608 03/18/04 1
Heptachlor BDL 0.00050 mg/1 608 03/18/04 1
Heptachlor epoxide BDL 0.00050 mg/1 608 03/18/04 1
Hexachlorobenzene BDL 0.00050 mg/1 608 03/18/04 1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
Page 2 of 6

ENVIRONMENTAL
SCIENCE CORP .
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Date Received March 12, 2004
Description 13874-Moore County WWTP
Sample ID 0310088
Collected By Operator
Collection Date : 03/10/04 07:54
Parameter
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
March 19, 2004
ESC Sample # : L147403-01
Site ID .
Project # : TBL-13874
Result Det. Limit Units Method Date Dil.
Methoxychlor BDL 0.00050 mg/1 608 03/18/04 1
Toxaphene BDL 0.010 mg/1 608 03/18/04 1
PCB 1016 BDL 0.00050 mg/1 608 03/18/04 1
PCB 1221 BDL 0.00050 mg/1 608 03/18/04 1
PCB 1232 BDL 0.00050 mg/1 608 03/18/04 1
PCB 1242 BDL 0.00050 mg/1 608 03/18/04 1
PCB 1248 BDL 0.00050 mg/1 608 03/18/04 1
PCB 1254 BDL 0.00050 mg/1 608 03/18/04 1
PCB 1260 BDL 0.00050 mg/1 608 03/18/04 1
Pest/PCBs Surrogates
Decachlorobiphenyl 110 0.00050 % Rec. 608 03/18/04 1
Tetrachloro-m-xylene 77. 0.00050 % Rec. 608 03/18/04 1
PP Base/Neutral Extractables
Acenaphthene BDL 0.010 mg/1 625 03/17/04 1
Acenaphthylene BDL 0.010 mg/1 625 03/17/04 1
Anthracene BDL 0.010 mg/1 625 03/17/04 1
Benzidine BDL 0.050 mg/1 625 03/17/04 1
Benzo(a)anthracene BDL 0.010 mg/1 625 03/17/04 1
Benzo(b)fluoranthene BDL 0.010 mg/1 625 03/17/04 1
Benzo(k)fluoranthene BDL 0.010 mg/1 625 03/17/04 1
Benzo(g,h,i)perylene BDL 0.010 mg/1 625 03/17/04 1
Benzo(a)pyrene BDL 0.010 mg/1 625 03/17/04 1
Bis(2-chlorethoxy)methane BDL 0.010 mg/1 625 03/17/04 1
Bis(2-chloroethyl)ether BDL 0.010 mg/1 625 03/17/04 1
Bis(2-chloroisopropyl)ether BDL 0.010 mg/1 625 03/17/04 1
4-Bromophenyl-phenylether BDL 0.010 mg/1 625 03/17/04 1
2-Chloronaphthalene BDL 0.010 mg/1 625 03/17/04 1
4-Chlorophenyl-phenylether BDL 0.010 mg/1 625 03/17/04 1
Chrysene BDL 0.010 mg/1 625 03/17/04 1
Dibenz(a,h)anthracene BDL 0.010 mg/1 625 03/17/04 1
3,3-Dichlorobenzidine BDL 0.010 mg/1 625 03/17/04 1
2,4-Dinitrotoluene BDL 0.010 mg/1 625 03/17/04 1
2,6-Dinitrotoluene BDL 0.010 mg/1 625 03/17/04 1
Fluoranthene BDL 0.010 mg/1 625 03/17/04 1
Fluorene BDL 0.010 mg/1 625 03/17/04 1
Hexachlorobenzene BDL 0.010 mg/1 625 03/17/04 1
Hexachloro-1,3-butadiene BDL 0.010 mg/1 625 03/17/04 1
Hexachlorocyclopentadiene BDL 0.010 mg/1 625 03/17/04 1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
Page 3 of 6

ENVIRONMENTAL
SCIENCE CORP .
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Date Received March 12, 2004
Description 13874-Moore County WWTP
Sample ID 0310088
Collected By Operator
Collection Date : 03/10/04 07:54
Parameter
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
March 19, 2004
ESC Sample # : L147403-01
Site ID .
Project # : TBL-13874
Result Det. Limit Units Method Date Dil.
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
n-Nitrosodimethylamine
n-Nitrosodiphenylamine
n-Nitrosodi-n-propylamine
Phenanthrene
Benzylbutyl phthalate
Bis(2-ethylhexyl)phthalate
Di-n-butyl phthalate
Diethyl phthalate
Dimethyl phthalate
Di-n-octyl phthalate
Pyrene
1,2,4-Trichlorobenzene
PP Acid Extractables
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Surrogate Recovery
Nitrobenzene-d5
2-Fluorobiphenyl
p-Terphenyl-d14
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1. 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
BDL 0.010 mg/1 625 03/17/04 1
36. % Rec. 625 03/17/04 1
39. % Rec. 625 03/17/04 1
73. % Rec. 625 03/17/04 1
22. % Rec. 625 03/17/04 1
32. % Rec. 625 03/17/04 1
73. % Rec. 625 03/17/04 1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA -
KY - 90010, KYUST - 0016, NC - ENV375,DW21704,
Note:
The reported analytical results relate only to
This report shall not be reproduced, except in
CILL Qic �
Cheli Boucher, ESC Representative
Certification Numbers:
I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
the sample submitted.
full, without the written approval from ESC.
Reported: 03/19/04 13:20 Printed: 03/19/04 13:21
Page 4 of 6

Attachment A
List of Analytes with QC Qualifiers
Sample #
L147403-01
Analyte Qualifier
2-Chloroethyl vinyl ether J4
Vinyl chloride J4
Benzo(b)fluoranthene J4
Nitrobenzene-d5 J2
2-Fluorobiphenyl J2
Page ,5 of 6

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
J2 Surrogate recovery limits have been exceeded; values are outside lower
control limits
J4
The associated batch QC was outside the established quality control range
for accuracy.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits
2-Fluorophenol 31-119 Nitrobenzene-d5 43-118 Dibromfluoromethane 79-126 83-119
Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 81-114 82-116
2,4,6-Tribromophenol 51-141 Terphenyl-d14 43-137 4-Bromofluorobenzene 65-129 72-126
TIC
- Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 6 of 6

TBL Laboratory
2401 West 5th Street
Lumberton,NC 28359
Alternate billing information:
Report:
Do C-041/,
Project
7)/
wine:
Loo re n TPA
Phone[phone]
FAX: [phone]
Client Project fl:
ESC Key:
Collected by:
(print): 0 Q..reAtIr
Site/FID acility ff:
ROA 61 3 g
Collected by (signa(ure):
•
[Rush? ( Lab MUST Be Notified )
Dale Results Nee(Ir4:
Same Day 200%
Next Day. 100%
3 -D-----0.--(
Two Day.. 50%
FAX? No?.?;
Sample ID
Comp/Grab
Matrix
Depth
Date
Time
0 M CYZ
el
)(
3110104
oq
___Wj_13 _
. ..
•
'Matrix: SS - Soil/Solid G VV - Groundwater VVW - WasteWa ter DW - Drinking Water
Remarks:
elinguished by: (Signature)
t(.,c11(•43(W b ki,-At aLk03
Date:
i ( oq
Time:
olDo
fl ve by: (Signature
•sh
?Ain by: (Signature)
•1
Dale:
3-11-04
.
Time:
tOT.3.c.
_ _
Recei b : nat e
elin ish by: 1L ;,
Date:
Time:
Received for lab by:
Analysis/Container/Preservative
• -9 . " .Y71
— I 2
--fr. ;
co.
F 2: _9
ill X X Y )0( )icY./\i/
L
Chain of Custody
Page of
Prepared by:
ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Road
Mt. Juliet. TN 37122
Plione [phone]
Phone [phone]
FAX [phone]
CoCode: TBLLAB (lab use only)
Template/Prelogin
Cooler #:
Shipped Via:
Remarks/Contaminant
e.41_4-740-2
Sample fi (tab only)
V
—tall -Va
ICC
:11 ii;13 Et,
• t,
1. 2
T —›
pl I •_ Temp
()tirer
Samples returned vi5: u UPS
u FedEx Courier u
Temp:
2 ,-7
Bottles Received:
I
Condition: (lab
Date:
•'2
Time:
C.)
NCF:
pH Checked:

Alternate billing information:
TBL Laboratory
2401 West 5th Street
Lumberton,NC 28359
Report:
-DQ.kriko ccuiR,
Project r me: TPA
00 re n
Phone[phone]
FAX: [phone]
Client Project #:
7AL — C3 S 1 Li
ESC Key:
Collected by:
(print): 09Qf CAt1(
Site/Facility ID#:
P.0.#: 61 3 sy
Collected by (signature):
Rush?
( Lab MUST Be Notified )
Date Results Ncericd:
Same Day 200%
Next Day. 100%
3 _,Da---0 (7(
Two Day..50%
FAX? No Y.:',;
Sample ID
Comp/Grab
Matrix*
Depth
Date
Timt.r!
0 n CIZQ
k)303
X.
3110i0-1
01.5'-k
. ...
Matrix: SS - Soil/Solid GW - Groundwater VW - Was teWa ter DW - Drinking Water OT 1;;19r
Remarks:
Relinquished by: (Signature)
Relin ish by: (Signature)
Relin
Date:
CO
Time:
cl c.,,
R ve by: (Signature':
N.,
----
Date:
3-11-04
Tinier
t01,35-
I.
Recei by: inat4 e'
111
Date:
Time:
Received for lab by:
(Signature)
tin.
Ct!
(Mfrs
!it
Analysis/Container/Preservative
Chain of Custody
Page of
Prepared by:
ENVIRONMENTAL
SCIENCE CORI'.
12065 Lebanon Road
Mt. Juliet. TN 37122
Phone [phone]
Phone [phone]
FAX [phone]
CoCode: rriBLLAB (lab use only)
Template/Prelogin
Cooler #:
Shipped Via:
Remarks/Contaminant
aajlo-Var\-k-
Sample # (lab only)
pl I leinp
Flow Other
j— UPS
[) FedEx Cou ier
Temp:
Bottles Received:
Condition:
(lab use only)
Date:
Time:
pH Checked: I NCF:

'Effluent Toxicity Report Form -Chronic Fathead Minnow Multi -Concentration Test
Date:3/22/2004'-y!
Facility: Moore County WWTP NPDES # NC0037508
ipe #: 001 County: Moore
Laboratory: Meritech, Inc.
x
Signature f Operator in ResponsibleCharte
; _
Signature of Laboratory Supervisor
Comments '
MAIL ORIGINAL TO:
Environmental Sciences Branch
Division of Water Quality
NC DENR
1621 Mail Service Center
Raleigh, NC 27699-1621
OPY
Test Initiation Date/Time 3/9/2004
% Eff.
Control
Repl.
Surviving #
Original #
Wt/original (mg)
Surviving #
Original #
Wt/original (mg)
10.25
20.5
Surviving #
Original #
Wt/original (mg)
41
Surviving #
Original #
Wt/original (mg)
61.5
Surviving #
Original #
Wt/original (mg)
82
Surviving #
Original #
Wt/original (mg)
Water Quality Data
Control
pH (SU) Init/Fin
DO (mg/L) Init/Fin
Temp (C) Init/Fin
High Concentration
pH (SU) Init/Fin
DO (mg/L) Init/Fin
Temp (C) Init/Fin
Sample
Collection Start Date
Grab
Composite (Duration)
Hardness (mg/L)
Alkalinity (mg/L)
Conductivity (umhos/cm)
Chlorine(mg/L)
Terrp. at Receipt (°C)
Dilution H2O
Hardness (mg/L)
Alkalinity (mg/L)
Conductivity (umhos/cm)
1
/ 12:00 PM
2
3
10
10
10
10
10
10
10
10
0.453
0.622
0.429
0.551
10
10
10
10
10
10
10
10
0.481
0.557
0.397
0.446
10
10
10
10
10
10
10
10
0.501
0.493
0.460
0.484
10
10
10
10
10
10
10
10
0.545
0.566
0.503
0.577
10
10
10
10
10
10
10
10
0.606
0.610
0.677
0.587
10
10
10
10
10
10
10
10
0.492
0.488
0.532
0.500
Day
Avg Wt/Surv. Control
% Survival
Avg Wt (mg)
% Survival
Avg Wt (mg)
% Survival
Avg Wt (mg)
% Survival
Avg Wt (mg)
% Survival
Avg Wt (mg)
% Survival
Avg Wt (mg)
0.514
100.0
0.514
100.0
0.470
100.0
0.485
100.0
0.548
100.0
0.620
100.0
0.503
0
1
2
3
8.25
/
8.15
8.24
/
8.16
8.25
/
8.14
8.27
/
8.16
8.26
/
8.13
8.25
/
8.18
8.24
/
8.20
7.83
/
7.15
7.84
/
7.18
7.79
/
7.09
7.81
/
7.10
7.80
/
7.13
7.79
/
7.14
7.81
/
7.12
25.0
/
24.8
25.0
/
24.8
25.0
/
24.7
25.0
/
24.6
25.0
/
24.7
25.0
/
24.8
25.0
/
24.8
0
1
2
3
7.79
/
8.10
7.77
/
8.15
8.13
/
8.27
8.10
/
8.25
8.11
/
8.06
8.09
/
8.13
8.10
/
8.18
7.89
/
7.06
7.92
/
7.10
7.95
/
7.05
7.96
/
7.07
7.94
/
7.05
7.95
/
7.10
7.93
/
7.07
25.0
/
24.9
25.0
/
24.8
25.0
/
24.8
25.0
/
24.7
25.0
/
24.7
25.0
/
24.8
25.0
/
24.8
1
2
3
3/7/2004
3/8/2004
3/11/2004
24.30
24.27
24.00
100.00
140.00
128.00
87.00
120.00
105.00
419
469
457
<0.1
<0.1
<0.1
1.4
0.1
0.9
42.00
66.00
228
Normal
Horn. Var.
NOEC
LOEC
Survival
ii I<;
ii
82
Growth
lip l
82
>82 >82
ChV >82 >82
Method Steel's
Dunnett's
Test Organisms
t:, Cultured In -House
7 Outside Supplier
Hatch Date: 3/8/04
Hatch Time: 1:00 PM
Overall Result
ChV
>82
Stats Survival Growth
Conc. Critical Calculated Critical Calculated
10.25 10 18 2.41 1.197
20.5
41
10 18 2.41 0.8048
10 18 2.41-0.9356
61.5 10 18 2.41 -2.9236
82
10 18 2.41 0.2958
DENR-FRO
- 8 2004
w
DWQ Form AT-5 (1/04)

MERITECH
Chronic Fathead Minnow Benchsheet
Transfer and Feeding Dates and Times
Tost_initiation Data:
Start Dale: •
Start Time:- i
Initials/Signature: ‘,.1.1' r•-•
Date/Time Fed ,?•,.q.r.-)ti ' (i4:DA-----
Date/Tirne
‘, ek 11,57
(I 7 7°--
Transfer
Date Time
Day 1 i•
Day 2
Day 3 3
Day 4 ?••• /0 riv-- AA
Day 5 • • Aric,
Day 6 .;••• .14:•:-0 • ; t•rt. L
Test Termination Data:
Initials/Signature:
End Date:
End Time:.
Initials
•
tt of Organisms per Chamber: IQ
Test Vessel Size:
Test Solution Volume:
Temp. of Stock:
i/ of Reps: Li
Date Time 1
Day 0
Day 1
Day 2 3 -- Li 61
Day-3
Day 4 3- / Ain
Day 5 3 •-
Day 6
Facility CO
NPDES // i\)( f)
Dilution Water:.'7„:4,01,„
Randomization: (..'E) NO
Incubator it:
Feeding
Initials Time 2 Initials Time 3 Initials
c •
i Qv •
ire) 11,-
•
3'1
e- -
L.

.1-1,
r-a e
‘:1 p
-.-
Faci
lity NP DES t Dates: Start:3. ri Erld
Test Organism: Analystr, Test Time: Start
c I 2
Temp. Initial
Final I
U.U.
4xs
pH ini T. 1 a I
Final
Al a I i n1 ty I (,-.:(„ I
Ha rdne s's .. I LI •?4, I
Conduct. Tniti al 1,11 • I 1,1A-"-,:,
• Fin a 1 I.)f-;'D
U y
JI4151bi I
\;:•-• • .D I :;5:•:- 17-1S) 0 I „2,5. ri! I
I I -c!,7 I I
I 2-1D 17..7 -al1
I 7.1, CD 1'4 r • I 7. I
Ir..?..:::;"•)- I''- I -1,
I 3,•.1 I I
I
1173,•,:
1;3
Res Chlorine Lo. iLo frii 140c11
Remarks
Finalr
iri . 0 . i n i ti a .1 I :-ii?---.,-. 1•:?,...:',;% 14,3c- 1';f-i L, I 7:1.\'‘ I.7:e2k c-- I 74.7; I
I:41V) I -.; I .-4-..--)- I T;C:. 1'7 . i 0 I 7. b"7- I
pH initial I':'+4__,q. I---,-;.-:,; I S.i?: Ilt-:., I 5.11 I S:Cli: I 8.:ic I
- n a:I I kic• I •f?.,Irs: I P., "A-4,- 1 '-,-.•,)‹ I (.----17..)1,c! I "i i '. I '•;>, C:,,,.. I.
A ik a I i n 1 ty irrif,- h- I I fAn. I I ti.Dc I I I
,Llardness ico-f. I ibri I I r'i r.:. .1 I i',-,,c-,.... I I I
1 nal
• Day
Conc.
Tem? • Tni ti I:;. -I :IS%1s .b 1 Tc ()
I a I . I : Ik. .:•i; I
Conduct. Ial 1..:3•`-c: 1E4 Vz.--? IL 4 I
7'; nal • I ii-42,.ri I4.3 1 : I I
Res- Chlorine- 1,f: • I I :•,:".0 ; ILi1"-fs I I
'kemarks
Conc.
Temp. Initiall
Final I
D.O. initial I
DH
Final
flarnes;
Conauct.jnitjall
.Fin-1
Res. Chlorjne 1
IJ =I-
I I
I I
I I
I 1I
I I I
Day
I I I
I I I
erna rks

MERITECH,
FACILITY
NPDES #:
FISH LARVAL SURVIVAL/GROVVTH DATA SHEET
CHRONIC FATHEAD MINNOW
. •7
?",
Rs—% •
DATE OFTEST:
DATE WEIGHED:
ORGANISM:
CONC
REP.
c
0
11
L.,
A
B
A
B
A
B
D
11 S V
PAGE OF a
OUTFALL:
INITIALS:
FOIL WT.
(mg)
FOIL WT. +
ORG. (mg)
WT. OF
ORG, (mg)
# ORG.
•
t L-1
to,—; 7.)
r
LT;
•
Li • ,s.;
•-•;
• ac
,
I
I u
13
MEAN WT/
ORG. (mg)
(f)
•Th
01 1
S URV
7/ , • •
c,--
Cr;
a( 5 f
1
g7./
-`
1.,
0:•••,./ L'
• 1 7—
o
0 ,Li
czY-77-
t.." t
.ZCf
01
C77- .-)/J
• /-*
.••_}
I
c
C7C

MERITECH, INC.
FACILITY:
FISH LARVAL SURVIVAL/GROVVTH DATA SHEET
CHRONIC FATHEAD MINNOW
NPDES #: :\)C,
DATE OF TEST:
r".7
DATE WEIGHED: so-1
ORGANISM:
PAGE OF
OUTFALL:.
INITIALS: Aqe__
CONC
REP.
FOIL WT.
(mg)
FOIL WT. +
ORG. (mg)
W.T. OF
ORG. (mg)
# ORG.
MEAN WT/
ORG. (mg)
SURV °A
//',. C:5?
CC\ .1. c I.: \_) !_71)
-5,f-15- .
. •r--,
, •1/4_,
B
, • -
, :2) c)
,-",',..
; (..,,.
.. ,
,
._,
1 )
0 , ;5-6
C-
C7 i c.17 -;-7
C-, 1 L— —
.
—
.
i) ..---- ,1 ••••
1--r-7.3-0.
,...
D
'
re7 57.( -31-
, . , ..... ..,..,,:.f,
(7(... ,
c--- -.-7 7
) . i e•
f .)
,,, C-- -7 ,71
0 c ,.,:-' 1 —
(AZ ,
A
,.• t ..1.-
s.- I .." i ....—., /
Cyl--.., .
(r-';',-) R. ...." '
c .
'1/4S.) •1/4 C, (1"
_
t. \ s--/
0 : (C' 0 (2'
1 4C7C„.3
B
.
-
C
:----1., 3 .c-
'?.-.5- :.,77:,-5,1 n,. •
.
6 ;77
.-.,--„.,
t ,..._,
t.) ,-;7-7,--.
D
( Z)
0 ,.—_ c3-7___
\.-,.--),...„
/, )(71
n..,:.,, P ,, D.6..
o
--i i_.. i • 1,--
.i ..„...„..,
0 ,---
B
7" , .), , -
1 .,,L,',- Li
o '','(•,"?,
. i .----'
.;-, i 4 c..,:.-+
C
c?-
f_l. < /
•1?„0 , ) )
D .
.-c7,-)
' r-J --`-
— , ,-
)'-..,13C
c • ,.-.
Ut,..)
i-i---,
' s,..—?
,
,,,:t '.• —,t_f

Concentration
Rep #1
MERITECH
Mortality Data: Chronic Fathead Test
Start Date/Time End Date/Time 3 hi, 1 4T
Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Day 7
D
Rep #2 (,)
Rep #3
Rep #4 C)
Concentration
C)
Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Day 7
Rep #1 "'CD
C7)
Rep #2 oC)
Rep #3 C-)
'Cf_2=1
Rep #4 C.7)
Concentration ..),tp• C
Rep #1
Rep #2
Rep #3
Rep #4
Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Day 7
C.)
(
L)
rTh

MERITECH
Mortality Data: Chronic Fathead Test
Start Date/Time End Date/Time dn,k,i 11.
Concentration 141
Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Day 7
Rep #1
• /(.7.)
Rep #2 C.5 1.=
Rep #3 0(Th
Rep #4 0C.))
Concentration (,1..c
Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Day 7
Rep #1 0 ---..._rc-) •
"C:',
Rep #2 CD C.) C.) TT) - OM
‘..„/
Rep #3 ezTh
-QT.)
n')
Rep #4 (-3 )
Concentration F-01
Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Day 7
Rep #1 c,---- 0 C) --,
\-..) 1.--)
„.._.; ---\
t-
s..._.,
Rep #2 v--,----, 1,
Cm c_,•-,
C) --k::::, F")
Rep #3 0 00 0(7)
Rep #4 „c3 cf) 1,7:)

Meritech, Inc.
Bioassay Sample Chain of Custody
642 Tamco Rd
Reidsville, NC 27320
[phone]
Client Information
Client: \ \C L
TBL
PO Box 589
Lumberton, NC 28359
910-738-6190
-Jr-
J
:1
N C. Zip:
PO
NPDES #: N Q. 00 3 `15 C.
Phone: ek.l`: -, `; - 3 iq
Pipe Number:
Sample Information ,.
Sampling Site: r C=�;:`tti�"
Sample Type: Grab ✓- • Composite
Sampling Time: START Date: '3 ! ck. ( ,q Time:
END Date: 3 l 104 Time:
Sample Chilled (Covered with Ice): Yes ✓ No
Collector's Name Print } ' rz - { U' a
Collector's Signature: 4�f,.-.,€_ 7: 1''
of Containers
0 (0: 1 , s1 PM
- 7 1 PM
Toxicity Test Information
-sk Test Required: Chronic:
Acute:
►� Test Organism: Ceriodaphnia Dubia:
Pimephales promelas -
Mysidopsis bahia:
FIATC1.
Toxicity Test Concentration(s):
*List Any Special Requirements: Ms `;
FO:Vh VIA in iclt,10L.,3
Shipping Information I
Relinquished By;
Received By:
Relinquished B
Received By:
Sample Temperature C°):
Date: 3 0 Time:©$ D , ( lPM
Date: 3 s\ a Time: o'FO, PM
Date: Time: U Si b MPM
Date: Time: AM PM
Method of Shipment: WTC(p/u) UPS Fed -Ex
Circle One • Other:
Sample Receiving (Laboratory Use Only)
Received From: p t-(
Received By: ,k‘, �e �:: Date:
Sample Temperature (C°): 1, / 1 / /
' Sample Condition:
Time: ` C' (AM PM

Meritech, Inc.
Bioassay Sample Chain of Custody
642 Tamco Rd
Reidsville, NC 27320
[phone]
�7 CT)
I �L"
Client Information
Client: ' \ P
Contact: ''.-i �e L;,-\.c, 1 C L\ t
Address: kc;UIL-{ {-\C{C�.C; �
City: Nb_ CAQQ,r\
County: INA_C:y -Q- State:
-ca\-lame RO 5938
PO # C9.Cio* Poi �j`l33
NPDES #: cle5CR
Phone: ciri.0-2si-3i`I(4.
Pipe Number:
Zip:
Type of Facility Generating Effluent: we_S VeirLYZk
Sample lnformatior},
Sampling Site:
Sample Type: Grab :-------
Sampling Time: START Date: 31E'101,
END Date: 319.1 c)�1 Time:
Sample Chilled (Covered with Ice): Yes ,ter No
Collector's Name (Print): 14,Sii,}n:r;,11- l'1/44,c 10-e- i
Collector's Signature: r Zr`,.lA,,, rAt— . k 1, ` l t,,..
Composite # of Containers �?
Time: 0 7 ; t'l ',PM
Ivy PM
Toxicity Test Information
-Test Required: Chronic: Test Organism: Ceriodaphnia Dubia: ✓ /
Acute: . Pimephales promelas: &/
Mysidopsis bahia:
IWC:
Toxicity Test Concentration(s):
List Any Special Requirements: n\c,c: A -Ls I � j� � , C I\ •;�0�;k.
Shipping Enformation
Relinquished By :1o>.. i f
Received By: r.
Relinquished By'"
Received By:.
Sample Temperature
Date: 3 I q I Oy Time: t';>> nap PM
Date: •ti c) 's. Time: 0;,4'•:` .\ : u -PM
Date: ` / 01,i Time: AMto,
Date: :i
Method of Shipment: WTC(p/u) UPS Fed -Ex
Circle One Other:
Sample Receiving (Laboratory Use Only)
Received From: �:,�. _��
Received By: : `} ; k 01 Date: 3 / cr 'i) / Time: L/
Sample Temperature (C°): 0,, • / / Sample Condition: { _ c/

Meritech, Inc.
Bioassay Sample C'hain of Custody
642 Tamco Rd
Reidsville, NC 27320
[phone]
CIient Information
Client: iliC' f !.A ', � .P
Contact: -; F(;, X�
Address: 't i d ,o:`'-(,
t; Z.�
City:
County:
State:
�3 �E3
13��
PO #i «'.c�u�;FK�._ �, {t 3 3
NPDES
Phone:9') -,,— =;i4°
Pipe Number:
Zip: C2R
Type of Facility Generating Effluent: L. •.rt`►-e;
Sample Information
Sampling Site: ,
Sample Type: Grab Composite
Sampling Time: START Date: 3tjk:_f Time:
END Date: 1,1y4 y Time:
Sample Chilled (Covered with Ice): Yes No
Collector's Name (Print): L. A a'ckt.}
Collector's Signature: C
Toxicity Test Information
# of Containers
0-7 , -' ; PM
M\ PM
,-Test Required: Chronic: Test Organism: Ceriodaphnia Dubia: 1-�
Acute: Pimephales promelas:
Mysidopsis bahia:
IWC:
Toxicity Test Concentration(s):
List Any Special Requirements:
i S 1 I` 2f-h.e.cld
Shipping Information
Relinquished By:
Received By:
Relinquished By:
Received By:
Sample Temperature
Date: 031 a0 Time:Qcio� A��? PM
Date: '.> - I z -,, Time: .w pM
Date: 3_}2- u •• Time: `.r. ` AM 4)
Date:.? /,c 4?U'i = Time:, ._r XX AM PIyI`
Method of Shipment: WTC(p/u) UPS Fed -Ex
Circle One ' Other:
Sample Receiving (Laboratory Use Only)
Received From: ) ,ramL.
Received By: �.:01,-- -(r•,j
Date: 5 i oJ Time: >: i > AM�PM
Sample Temperature C° : ,, r`
( ) � � • /1' c-;% Sample Condition: r`c eo

Title: Moore
File: Moore Transform: NO TRANSFORMATION
Shapiro'- Wilk's Test for Normality
D=
W
0.0475
0.9719
Critical W = 0.8840 (alpha = 0.01 , N = 24)
W = 0.9160 (alpha = 0.05 , N = 24)
Data PASS normality test (alpha = 0.01). Continue analysis.

Title: Moore
File: Moore Transform: NO TRANSFORMATION
Bartlett's Test for Homogeneity of Variance
Calculated Bl statistic = 10.1299 (p-value = 0.0716)
Data PASS B1 homogeneity test at 0.01 level. Continue analysis.
Critical B = 15.0863 (alpha = 0.01, df = 5)
= 11.0705 (alpha = 0.05, df = 5)

Title: Moore
File: Moore Transform: NO TRANSFORMATION
ANOVA Table
SOURCE
DF SS MS F
Between
5 0.0591 0.0118 4.4737
Within (Error) 18 0.0475 0.0026
Total
23 0.1066
(p-value = 0.0080)
Critical F = 4.2479 (alpha = 0.01, df = 5,18)
= 2.7729 (alpha = 0.05, df = 5,18)
Since F > Critical F REJECT Ho: All equal (alpha = 0.05)

Title: Moore
File: Moore Transform: NO TRANSFORMATION
Summary Statistics on Data TABLE 1 of 2
GRP IDENTIFICATION N MIN MAX MEAN
1 control 4 0.4290 0.6220 0.5138
2 10.25% 4 0.3970 0.5570 0.4703
3 20.5% 4 0.4600 0.5010 0.4845
4 41% 4 0.5030 0.5770 0.5478
5 61.5% 4 0.5870 0.6770 0.6200
6 82% 4 0.4880 0.5320 0.5030
Title: Moore
File: Moore Transform: NO TRANSFORMATION
Summary Statistics on Data TABLE 2 of 2
GRP IDENTIFICATION VARIANCE SD SEM C.V. %
1 control 0.0080 0.0894 0.0447 17.4021
2 10.25% 0.0045 0.0673 0.0337 14.3152.
3 20.5% 0.0003 0.0177 0.0089 3.6632
4 41% 0.0011 0.0327 0.0163 5.9614
5 61.5% 0.0015 0.0393 0.0197 6.3391
6 82% 0.0004 0.0200 0.0100 3.9695

Title: Moore
File: Moore Transform: NO TRANSFORMATION
Dunnett's Test.
TABLE 1 OF 2
Ho:Control<Treatment
GROUP IDENTIFICATION
TRANSFORMED MEAN CALCULATED IN . SIG
MEAN ORIGINAL UNITS T STAT 0.05
1 control 0.5138 0.5138
2 10.25% 0.4703
3 0.4703 1.1970
20.5% 0.4845 0.4845 0.8048
4 41% 0.5478 0.5478-0.9356
5 61.5% 0.6200
0.6200-2.9236
6 , 82% 0.5030 0.5030 0.2958
Dunnett critical value = 2.4100 (1 Tailed, alpha = 0.05, df = 5,18)
Title: Moore .
File: Moore Transform: NO TRANSFORMATION
Dunnett's Test
TABLE 2 OF 2
Ho:Control<Treatment
NUM OF MIN SIG DIFF % OF DIFFERENCE
GROUP IDENTIFICATION REPS (IN ORIG: UNITS) CONTROL FROM CONTROL
1 control 4
2 10.25% 4 0.08766 17.0 0.0435
3 20.5% 4 0.0876 17.0 0.0292
4 41% 4 0.0876 17.0-0.0340
5 61.5% 4 0.0876 17.0-0.1062
6 82% 4 0.0876 17.0 0.0107

Alternate billing information:
Analysis/Container/Preservative
TBL Laboratory
P.O. Box 589
Lumberton,NC 28359
Pe;�art: r
(- f' , 6.k
Phone[phone]
FAX: [phone]
Collected by:
(print): (.;)-k_' ('\ . ',-
Collected by (signbture):
Project name:
Client Project #:
`"I (), 2:3 I = / `T/(,-
Site/FacilityID#
1Rush71
ESC Key:
r :-L t►�;.;.�J �� i 5 `l 3 (
P.O.#:
0,Af irk., L\ a F C O tt 5 r13 3
( Lab MUST Be Notified )
_ Same Day 200%
Next Day. 100%
Two Day .. 50%
Date Results Needed:
FAX? No Yes
Sample ID
Comp/Grab
Matrix'
Depth
Date
Time
No.
of
Cntrs
O31 V L
31 NO
-15
31Xi
Chan of Custody
Page cf
Prepared 5y:
ElNVIRONMEN'T.-\L
SCIENCE CORP.
12065 Lebanon Road
Mt. Julic;TN 37 1,2
Phone.[phone]
Phone (S00) 767-5859
FAX [phone]
CoCode: TBLLAB
Template/Prelogin
Cooler #:
Shipped Via:
(lab use only)
RemarksiCenlaminanl Sample # (lab only)
'Matrix: SS - SoWSolid GW_ Groundwater WW-WasteWater DW - Drinking Water OT - Other
Remarks:
Relinquished by: (Signature)
btoai
Relinquished by: (Signature)
Relin d by: (Sig ):ture)
Date:
Date:
Time:
OcDo
Time:
Time:
e iv by: (Signature)
R ceived y: (Sign ture)
Received for lab by:
(Signature)
pi!
Flow
amp es returne vla: ❑ UPS
0 FedEx ❑ Courier ❑
Temp
Other
Temp:
Bottles Received:
Condition: (lab use only)
Date:
Time:
pH Checked:
NCF: