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HomeMy WebLinkAboutWQ0012404_Annual Report_202102192020 Annual Report Land Application Program CF Nitrogen, Inc. Permit No. WQ0012404 PREPARED FOR CF Industries Holdings, Inc. 4 Parkway North Suite 400 Deerfield, IL 60015-2590 S&ME, Inc. 3201 Spring Forest Road Raleigh, NC 27616 February 19, 2021 February 19, 2021 North Carolina Department of Environmental Quality Division of Water Resources — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Attention: Non -Discharge Permitting Unit Reference: 2020 Annual Report Land Application Program CF Nitrogen, Inc. Permit No. WQ0012404 S&ME Project No. 1040-98-044U Non -Discharge Compliance Unit: S&ME, Inc. (S&ME) is submitting all monitoring and reporting requirements as specified in the above referenced permit for CF Nitrogen, Inc. S&ME compiled this report using data gathered during the compliance year. This data includes: 1) Certification Form, 2) Residual Sampling Summary Form, 3) 2020 Application Summary and Field Loading Rate Reports, 4) Field Application Summaries, 5) Updated Attachment B, 6) Landowner Agreement Attachments & Lessee Agreement Attachments, and 7) Groundwater Report. CF Nitrogen, Inc. conducted land application events on current permitted fields in Hertford and Northampton counties within the year of 2020. A total of 14,484,000 gallons of nitrogen -enriched groundwater were land applied. TCLP, Pathogen and Vector Monitoring, and Soil Analysis are not included in the report as these requirements are not required by Permit based on the permitted operation of a groundwater recovery system only. If there is any further information required or questions regarding this land application program, please do not hesitate to contact us for further assistance. Sincerely, S&ME, Inc. Jason Volker, LSS, ORC Project Manager 919-880-3137 ivolker@smeinc.com cc: Ms. Diane Diks, CHMM, CPEA (CF Nitrogen, Inc.) Mr. Jay Bryant (Granville Farms) Tom Raymond, PE, PMP, RSM Principal Environmental Engineer / Vice President 919-801-5359 traymond@smeinc.com S&ME, Inc. 1 3201 Spring Forest Road 1 Raleigh, NC 27616 1 p 919.872.2660 1 www.smeinc.com 2020 Annual Report Land Application Program CF Nitrogen, Inc. S&ME Project No. Permit No. WQ0012404 TABLE OF CONTENTS: III SECTION NO. TITLE I Annual Land Application Certification Form II Residuals Sampling Summary and Analysis III 2020 Application Summary and Field Loading Rate Reports IV Field Application Summaries V Updated Attachment B VI Landowner Agreement Attachments & Lessee Agreement Attachments VII Groundwater Data February 19, 2021 ii 2020 Annual Report Land Application Program CF Nitrogen, Inc. S&ME Project No. Permit No. WQ0012404 CF Nitrogen, Inc. Ms. Diane Diks 4 Parkway North, Suite 400 Deerfield, IL 60015-2590 847-405-2400 NC PERMIT # WQ0012404 Mr. Jay Bryant Granville Farms, Inc. 100 Farmers Chemical Road Cofield, NC 27922 252-358-2129 LAND APPLIERS: Granville Farms, Inc. 8229 Highway 96 North Oxford, North Carolina 27565 919-690-8000 III February 19, 2021 iii Attachments Annual Land Application Certification Form ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0012404 County: Facility Name (as shown on permit): Land Application Operator: Hertford Year: CF Nitrogen, Inc. 2020 Granville Farms, Inc. Phone: 919-690-8000 Land application of residuals as allowed by the permit occurred during the past calendar year? ❑� Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the permit: 395 Total number of fields utilized for land application during the year: 27 Total amount of dry tons applied during the year for all application sites: N/A Groundwater Recovery System Total number of acres utilized for land application during the year: 692.9 Part t3 - Annual Compiance Statement: Facility was compliant during calendar year (including but not limited to items 1-13 below) issued by the Division of Water Quality. 0 Yes ❑ No if no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 2020 with all conditions of the land application permit 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF Nitrogen, Inc. Tunis, NC Facility Permittee Name anTitle iv or print) Signature of Permittee Date Shy, i turc of Preparer* Date SignawLand Applier Date Jason Volker, S&ME, Inc. Jay Bryant, Granville Farms, Inc. * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) Residuals Sampling Summary and Analysis ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0012404 Facility Name: CF Nitrogen, Inc. NPDES # or WQ#: NA Name RESIDUAL ANALYSIS DATA Nitrogen -Enriched Groundwater Recovery System Laboratory: 1) Waypoint Analytical 2) 3) Date Sampled (grab) or Date Composited 1/23/2020 4/27/2020 7/13/2020 10/20/2020 Percent Solids NA N/A N/A N/A PARAMETERS (mg/L dry weight) TKN 217 233 255 235 Ammonia -Nitrogen 239 233 255 234 Nitrate -Nitrogen 273 200 315 225 Total Phosphorus 2.09 1.41 1.78 2.91 Aluminum 0.678 0.323 0.534 1.10 Calcium 57 57 61.3 59.1 Magnesium 17.0 17.0 18.5 18.8 Potassium 31.9 33.0 33.9 33.4 pH 7.0 7.1 2.6* 6.9 Sodium 33.4 33.6 35.6 32.5 *Apparent Waypoint Analytical lab error- recurring lab errors (reporting of low pH values were documented by S&ME between April and July 2020. The actual pH of reclaimed water has been well documented as having neutral pH since beginning of the land application program in 1998. X Signature of Preparer "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/19/2020 Date Report Number 20-023-0001 Account Number 46260 Waypoint Send To: CF Industries John Foster 100 Farmers Chemical Rd Suite 400 Cofield, NC 27922 Project: 083004 Lab Number: 70243 Sample ID: 083004 Analysis ANALYTICAL Total Kjeldahl Nitrogen , mg/L Phosphorus , mg/L Potassium , mg/L Calcium , mg/L Magnesium , mg/L Sodium , mg/L Aluminum , mg/L Ammonia Nitrogen , mg/L Nitrate+Nitrite-N , mg/L pH, s.u. 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointa nalytical.com REPORT OF ANALYSIS Result 217 2.09 31.9 57.4 17.0 33.4 0.678 239 273 7.0 Quantitation Limit 10.0 0.100 0.500 0.500 0.100 0.500 0.100 2.00 100 Purchase Order: B63722 Report Date: 01/30/2020 Date Received: 01/23/2020 Date Sampled: 01/23/2020 Method SM-4500-NH3C-TKN 6010D 6010D 6010D 6010D 6010D 6010D SM-4500-NH3C 4500NO3F-2011 9045D Date and Time Test Started Gator 01/29/2020 12:20 01/29/2020 00:25 01/29/2020 11:36 01/29/2020 00:25 01/29/2020 00:25 01/29/2020 00:25 01/29/2020 00:25 01/29/2020 12:20 01/30/2020 11:36 01/27/2020 14:00 Analyst JCM JTR KKM JTR JTR JTR JTR JCM BW1 JCM Page 3 of 6 Pauric McGroary Waypoint, ANALYTICAL 46260 CF Industries John Foster 100 Farmers Chemical Rd Suite 400 Cofield , NC 27922 Report Number : 20-119-9004 Lab No : 71183 Sample ID : 086531 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 o Fax 804-271-6446 www.waypointa nalytical. com Project 086531 Information : REPORT OF ANALYSIS Original Report Date : 05/05/2020 Revised Report Date: 05/11/2020 Received : 04/28/2020 Matrix: Aqueous Sampled: 4/ 27/ 2020 10:26 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 233 mg/L 2.00 1 04/29/20 10:00 JCM SM-4500-NH3C Nitrate+Nitrite-N 200 mg/L 10.0 100 05/04/20 15:43 ZBD 4500NO3F-2011 pH 7.1 s.u. 1 05/11/20 12:45 SAJ 9045D Total Kjeldahl Nitrogen 233 mg/L 10.0 1 05/01/20 10:00 JCM ;M-4500-NH3C-TKI` Phosphorus 1.41 mg/L 0.100 1 05/05/20 10:50 KKM 6010D Aluminum 0.323 mg/L 0.100 1 05/05/20 10:50 KKM 6010D Calcium 57.0 mg/L 0.500 1 05/05/20 10:50 KKM 6010D Magnesium 17.0 mg/L 0.100 1 05/05/20 10:50 KKM 6010D Potassium 33.0 mg/L 1.00 10 05/05/20 11:19 KKM 6010D Sodium 33.6 mg/L 0.500 1 05/05/20 10:50 KKM 6010D Qualifiers/ Definitions DF Dilution Factor MQL Method Quantitation Limit L Limit Exceeded Page 3 of 5 Report Number 20 198 0007 Waypoint r VAccount Number -"7621 Whitepine Road, Richmond, VA 23237 Main 804-743 94D1 ° Fax 804-271-6446 46260 ANALYTICAL www.waypointanalytical.com Send To: CF Industries John Foster 100 Farmers Chemical Rd Suite 400 Cofield, NC 27922 Project: 89479 REPORT OF ANALYSIS Lab Number: 73100 Sample ID: 89479 Purchase Order: B63722 Report Date: 07/23/2020 Date Received: 07/16/2020 Date Sampled: 07/13/2020 Quantitation Date and Time Analysis Result Limit Method Test Started Analyst Total Kjeldahl Nitrogen , mg/L 255 10.0 SM-4500-NH3C-TKN 07/20/2020 09:10 JCM Phosphorus , mg/L 1.78 0.100 6010D 07/21/2020 03:09 JTR Potassium , mg/L 33.9 1.00 6010D 07/21/2020 16:57 TJS Calcium , mg/L 61.3 0.500 6010D 07/21/2020 03:09 JTR Magnesium , mg/L 18.5 0.100 6010D 07/21/2020 03:09 JTR Sodium , mg/L 35.6 0.500 6010D 07/21/2020 03:09 JTR Aluminum , mg/L 0.534 0.100 6010D 07/21/2020 03:09 JTR Ammonia Nitrogen , mg/L 255 2.00 SM-4500-NH3C 07/20/2020 09:10 JCM Nitrate+Nitrite-N , mg/L 315 100 4500NO3F-2011 07/17/2020 13:55 BW1 pH , s.u. 2.6 9045D 07/23/2020 04:17 JSL Pauric McGroary Page 3 of 6 Report Number 20-298-0003 Account Number 46260 Send To: CF Industries Diane Diks 100 Farmers Chemical Rd Suite 400 Cofield, NC 27922 Project: 94530 Lab Number: 73996 Sample ID: 94530 Analysis Waypoint ANALYTICAL Total Kjeldahl Nitrogen , mg/L Phosphorus , mg/L Potassium , mg/L Calcium , mg/L Magnesium , mg/L Sodium , mg/L Aluminum , mg/L Ammonia Nitrogen , mg/L Nitrate+Nitrite-N , mg/L pH, s.u. 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointa nalytical.com REPORT OF ANALYSIS Result 235 2.91 33.4 59.1 18.8 32.5 1.10 234 225 6.9 Quantitation Limit 10.0 0.100 0.500 0.500 0.100 0.500 0.100 2.00 100 Purchase Order: B63722 Report Date: 11/02/2020 Date Received: 10/22/2020 Date Sampled: 10/20/2020 Method SM-4500-NH3C-TKN 6010D 6010D 6010D 6010D 6010D 6010D SM-4500-NH3C 4500NO3F-2011 9045D Date and Time Test Started 10/26/2020 09:30 10/28/2020 23:26 10/30/2020 21:43 10/29/2020 18:43 10/28/2020 23:26 10/28/2020 23:26 10/28/2020 23:26 10/26/2020 09:00 10/26/2020 11:56 10/26/2020 12:00 Pi kocriy Analyst JCM TJS JADS JADS TJS TJS TJS JCM BW1 JCM Page 3 of 7 Pauric Mc Groary Ph.D., CPAg 2020 Application Summary and Field Loading Rate Reports 2020 APPLICATION SUMMARY CF NITROGEN, INC. NITROGEN ENRICHED GROUNDWATER PERMIT No. WQ0012404 NITROGEN ENRICHED GROUNDWATER SUMMARY FARM NAME FIELD NO. APPL. DATE ACRES UTILIZED TOTAL GALLONS GAL'S./ ACRE IN/ ACRE PAN (lbs/ac) C.F. NITROGEN Site 11 1 03 20 40.40 289,000.00 7,153.47 0.26 26.42 04-20 298,000.00 7,376.24 0.27 21.07 2 04-20 67.20 820,000.00 12,202.38 0.45 34.86 3 Q3-20 41.40 340,000.00 8,212.56 0.30 21.69 Q4-20 518,000.00 12,512.08 0.46 35.74 STEVEN BURGESS Site 27 42 Q1-20 93.50 2,096,000.00 22,417.11 0.83 79.19 43 Q1-20 17.70 556,000.00 31,412.43 1.16 101.16 44 Q1-20 29.20 347,000.00 11,883.56 0.44 38.27 68 Q4-20 58.00 264,000.00 5,413.79 0.20 15.47 71 Q120 61.80 427,000.00 6,909.39 0.25 22.25 Q2-20 1,096,000.00 17,734.63 0.65 57.11 73 Q2-20 74.90 838,000.00 11,188.25 0.41 36.03 WALTER PERRY Site 28 1 Q3-20 17.60 622,000.00 35,340.91 1.30 100.69 2 Q3-20 17.50 444,000.00 25,371.43 0.93 67.73 3 Q3-20 25.10 694,000.00 27,649.40 1.02 73.03 8 Q3-20 9.20 221,000.00 24,021.74 0.88 88.71 9 Q3-20 9.90 245,000.00 24,747.47 0.91 91.39 10 Q3-20 1.70 73,200.00 43,058.82 1.59 159.01 11 Q3-20 3.70 122,000.00 32,972.97 1.21 121.76 12 Q3-20 3.60 173,800.00 48,277.78 1.78 178.28 13 Q3-20 8.70 319,000.00 36,666.67 1.35 135.40 Q4-20 127,000.00 14,597.70 0.54 53.91 14 Q3-20 7.00 248,000.00 35,428.57 1.30 130.83 15 Q4-20 17.40 808,000.00 46,436.78 1.71 156.63 16 Q3-20 18.90 799,000.00 42,275.13 1.56 156.11 18 Q3-20 7.40 325,000.00 43,918.92 1.62 162.18 WILLIAM WARD,JR. Site 33 2 Q2-20 11.90 287,000.00 24,117.65 0.89 77.67 3 Q2-20 15.10 320,000.00 21,192.05 0.78 68.25 4 Q2-20 13.60 344,000.00 25,294.12 0.93 81.46 6 Q2-20 14.60 385,000.00 26,369.86 0.97 84.92 7 Q2-20 5.90 38,000.00 6,440.68 0.24 20.74 TOTALS I1 692.9 11 14,484,000 LAND APPLICATIONS 2020 First Quarter 3,426,000 Second Quarter 3,308,000 Third Quarter 4,915,000 Fourth Quarter 2,835,000 Total Gallons Applied 14,484,000 GROUNDWATER RECOVERED 2020 TO HOLDING LAGOON First Quarter 3,879,300 Second Quarter 3,354,600 Third Quarter 4,823,800 Fourth Quarter 2,654,600 Total Gallons Recovered 14,712,300 CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: CF Nitrogen, Inc. OPERATOR: Granville Farms, Inc. RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 40.4 Crop: Fescue Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (I bs/ac) PAN P K 1 Q3-20 40.4 289,000 7,153 0.26 26.42 0.11 2.02 Site No. 11 Q4-20 40.4 298,000 7,376 0.27 21.07 0.18 2.06 - Annual Totals 587,000 14,530 0.54 47.49 0.29 4.08 147 RYE Limit (lbs./acre/year) is (Signi,at.u\e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: CF Nitrogen, Inc. OPERATOR: Granville Farms, Inc. RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 67.2 Crop: Fescue Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 2 Q4-20 67.2 820,000 12,202 0.45 34.86 0.30 3.40 Site No. 11 Annual Totals 820,000 12,202 0.45 34.86 0.30 3.40 147 RYE Limit (Ibs ./acre/year) ? it Z1 Sire of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: CF Nitrogen, Inc. OPERATOR: Granville Farms, Inc. RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 41.4 Crop: Fescue Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 3 Q3-20 41.4 340,000 8,213 0.30 21.69 0.10 2.26 Site No. 11 Q4-20 41.4 518,000 12,512 0.46 35.74 0.30 3.49 Annual Totals 858,000 20,725 0.76 57.43 0.40 5.75 147 RYE Limit (lb s./acre/year ; (Si tur of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres: 93.5 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Bonneau - BoB �D DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 42 Q1-20 93.5 2,096,000 22,417 0.83 79.19 0.42 6.53 Site No. 27 Annual Totals 2,096,000 22,417 0.83 79.19 0.42 6.53 91 RYE Limit (lbs./acre/year) (Siauia of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres: 17.7 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Norfolk - NoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 43 Q1-20 17.7 556,000 31,412 1.16 101.16 0.55 8.36 Site No. 27 Annual Totals 556,000 31,412 1.16 101.16 0.55 8.36 e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 123 RYE Limit (Ibs ./acre/y ear) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres: 29.2 Nitrogen Enriched Groundwater Croix Wheat Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 44 Q1-20 29.2 347,000 11,884 0.44 38.27 0.21 3.16 Site No. 27 Annual Totals 347,000 11,884 0.44 38.27 0.21 3.16 /L I (944=^ e of Land Applier) Date 91 RYE Limit (lbs ./acre/year) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Martha Pearlman OPERATOR: RESIDUAL SOURCE: Permitted Acres: 58 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Goldsboro - GoA FIELD DATE ACRES UTIT IZFD TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 68 Q4-20 58 264,000 5,414 0.20 15.47 0.13 1.51 Site No. 27 Annual Totals 264,000 5,414 0.20 15.47 0.13 1.51 136 RYE Li mi t (Ibs ./acre/y ear (Si r of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF Nl1ROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William E. Davis OPERATOR: RESIDUAL SOURCE: Permitted Acres: 61.8 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 71 Q1-20 61.8 427,000 6,909 0.25 22.25 0.12 1.84 Site No. 27 Q2-20 61.8 1,096,000 17,735 0.65 57.11 0.31 4.72 Annual Totals 1,523,000 24,644 0.91 79.36 0.43 6.56 91 RYE Limit (lbs ./acre/y ear) Z/1/Z( (Sic a of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William E. Davis OPERATOR: RESIDUAL SOURCE: Permitted Acres: 74.9 Nitrogen Enriched Groundwater Crop: Soybeans Predominant Soil: Norfolk - NoA FIELD DATE ACRES UTILIZED TOTAL GALLO NS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 73 Q2-20 74.9 838,000 11,188 0.41 36.03 0.20 2.98 Site No. 27 Annual Totals 838,000 11,188 0.41 36.03 0.20 2.98 and Applier) Date 200 RYE Limit (lb s ./acre/y ear) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 17.6 Crop: Corn Predominant Soil: Norfolk - NoA �ll DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 1 Q3-20 17.6 499,000 28,352 1.04 74.89 0.33 7.81 Site No. 28 Annual Totals) 499,000 28,352 1.04 74.89 0.33 7.81 Z/I►/21 Sira<".r e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 131 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Pe rn itte d Acres: 17.5 Crop: Corn Predominant Soil: Norfolk - NoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 2 Q3-20 17.5 444,000 25,371 0.93 67.73 0.30 6.99 Site No. 28 Annual Totals] 444,000 25,371 0.93 67.73 0.30 6.99 L/I1/2 I (Si e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 131 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 25.1 Crop: Corn Predominant Soil: Norfolk - NoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 3 Q3-20 25.1 686,125 27,336 1.01 76.35 0.33 7.56 Site No. 28 Annual Totals 686,125 27,336 1.01 76.35 0.33 7.56 131 RYE Limit (lb s ./acre/year) (Slgnat'ure of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 9.2 Crop: Soybeans Predominant Soil: Goldsboro - GoA FI>+.T,D DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 8 Q3-20 9.2 221,000 24,022 0.88 88.71 0.36 6.80 Site No. 28 Annual Totals 221,000 24,022 0.88 88.71 0.36 6.80 200 RYE Limit (lbs ./acre/year) (Siriat Ga of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 9.9 Crop: Soybeans Predominant Soil: Goldsboro - GoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 9 Q3-20 9.9 245,000 24,747 0.91 91.39 0.37 7.00 Site No. 28 Annual Totals 245,000 24,747 0.91 91.39 0.37 7.00 200 RYE Limit (lbs ./acre/yea (Si e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 1.7 Crop: Soybeans Predominant Soil: Goldsboro - GoA FTIF:TD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (1bs/ac) PAN P K 10 Q3-20 1.7 73,200 43,059 1.59 159.01 0.64 12.18 Site No. 28 Annual Totals 73,200 43,059 1.59 159.01 0.64 12.18 2.. 200 RYE Limit (Ib s ./acre/year) (Side of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 3.7 Crop: Soybeans Predominant Soil: Craven - CrB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 11 Q3-20 3.7 122,000 32,973 1.21 121.76 0.49 9.33 Site No. 28 Annual Totals 122,000 32,973 1.21 121.76 0.49 9.33 200 RYE Limit (lbs./acre/year Z�i12 I (Sig Sirtt a of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 3.6 Crop: Soybeans Predominant Soil: Craven - CrB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre i n/ac Nutrients (tbs/ac) PAN P K 12 Q3-20 3.6 173,800 48,278 1.78 178.28 0.72 13.66 Site No. 28 Annual Totals 173,800 48,278 1.78 178.28 0.72 13.66 7_,/f�2 I re of Land Applier) Date "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Limit (Ibs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: John Lock Mitchell OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 8.7 Crop: Soybeans Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 13 Q3-20 8.7 319,000 36,667 1.35 135.40 0.54 10.37 Site No. 28 Q4-20 8.7 127,000 14,598 0.54 53.91 0.22 4.13 Annual Totals 446,000 51,264 1.89 189.31 0.76 14.50 2.1 e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: John Lock Mitchell OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 7 Crop: Soybeans. Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 14 Q3-20 7 248,000 35,429 1.30 130.83 0.53 10.02 Site No. 28 Annual Totals 248,000 35,429 1.30 130.83 0.53 10.02 Z-1 1 V?. i '1.--- (SigT of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Limit (Ibs ./acre/y ear CF Nl'1ROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Berry Perry, John Mitchell, Eleanor Lane, Penny OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 17.4 Crop: Soybeans Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 15 Q4-20 17.4 808,000 46,437 1.71 156.63 0.86 13.06 Site No. 28 Annual Totals 808,000 46,437 1.71 156.63 0.86 13.06 (Siure of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Li mit (lbs ./acre/y ear) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: John Mitchell, Eleanor Lane, Penny Beasley, Ken OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 18.9 Crop: Soybeans Predominant Soil: Conetoe - CoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 16 Q3-20 18.9 799,000 42,275 1.56 156.11 0.63 11.96 Site No. 28 Annual Totals 799,000 42,275 1.56 156.11 0.63 11.96 200 RYE Limit (lbs./acre/year) Z_/1 2 I (Sim e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Bettt Everette Perry OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 7.4 Crop: Soybeans Predominant Soil: C ven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 18 Q3-20 7.4 325,000 43,919 1.62 162.18 0.65 12.42 Site No. 28 Annual Totals 325,000 43,919 I 1.62 162.18, 0.65 12.42 200 RYE Limit (Ib s ./acre/y ear) (SizirrrtT of Land Applier) Date "I certify, under penalty of Law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 11.9 Crop: Fescue Predominant Soil: Craven - CrC2 FIELD DATE ACRES UTLUZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 2 Q2-20 11.9 287,000 24,118 0.89 77.67 0.42 6.42 Site No. 33 Annual Totals 287,000 24,118 0.89 77.67 0.42 6.42 ure of Land Applier) Date 144 RYE Limit (lb s ./acre/year) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 15.1 Crop: Fescue Predominant Soil: Norfolk - NoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 3 Q2-20 15.1 320,000 21,192 0.78 68.25 0.37 5.64 Site No. 33 Annual Totals 320,000 21,192 0.78 68.25 0.37 5.64 and Applier) Date "I certify, render penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 158 RYE Limit (Ibs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S& ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 13.6 Crop: Fescue Predominant Soil: Norfolk - NoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 4 Q2-20 13.6 344,000 25,294 0.93 81.46 0.44 6.73 Site No. 33 Annual Totals 344,000 25,294 0.93 81.46 0.44 6.73 158 RYE Limit (lbs./acre/year) it/L (Si a of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 14.6 Crop: Fescue Predominant Soil: Norfolk - NoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 6 Q2-20 14.6 385,000 26,370 0.97 84.92 0.46 7.02 Site No. 33 Annual Totals 385,000 26,370 0.97 84.92 0.46 7.02 158 RYE Limit (lb s ./acre/y ear) Z/I(A.I e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 5.9 Crop: Fescue Predominant Soil: Craven - CrB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 7 Q2-20 5.9 38,000 6,441 0.24 20.74 0.11 1.71 Site No. 33 Annual Totals 38,000 6,441 0.24 20.74 0.11 1.71 -.SS4±S- .2111/Z— {Si of Land Applier) Date "I certify, under penalty of law, that this document was prepared wider my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 144 RYE Limit (lbs ./acre/year) Field Application Summaries GRANVILLE FARMS, INC. FIELD APPLICATION SUMMARY 2020 APPLICATION YEAR Granville Farms Site: I I FIELD ACRES Crop 1 2 3 40.4 67.2 41.4 fescue fescue fescue 7/4/2020 - - 45,000 7/5/2020 - - 39,000 7/9/2020 - - 138,000 7/10/2020 - - 118,000 7/ 13/2020 150,000 - - 7/ 14/2020 139,000 - - 10/27/2020 - 123,000 - 10/28/2020 - 123,000 - 10/29/2020 - 78,000 - 1 1 /9/2020 155,000 - - I 1 / 10/2020 - - 148,000 1 / 1 1 /2020 - - 123,000 I 1 / 18/2020 143,000 - - 1 / 19/2020 - 124,000 - 1 /20/2020 - - 123,000 1 /23/2020 - 124,000 - 1 /24/2020 - 124,000 - 1 /25/2020 - 124,000 - 12/3/2020 - - 124,000 Totals 587,000 820,000 858,000 Q I -2020 - - - Q2-2020 - - - Q3-2020 289,000 - 340,000 Q4-2020 298,000 820,000 518,000 CLIENT: CF NITROGEN, INC. PERMIT # WQ0012404 APPLICATION METHOD: Surface GRANVILLE FARMS, INC. FIELD APPLICATION SUMMARY 2020 APPLICATION YEAR Steven Burgess Site: 27 CLIENT: CF NITROGEN, INC. PERMIT # WQ0012404 APPLICATION METHOD: Surface FIELD ACRES CROP 42 93.5 wheat 43 17.7 wheat 44 29.2 wheat 68 58 wheat 71 61.8 wheat 73 74.9 soybeans 1/2/2020 1 1 1,000 1/6/2020 87,000 1/7/2020 74,000 1/9/2020 116,000 1 / 10/2020 106,000 1/20/2020 55,000 1 /21 /2020 86,000 1/22/2020 43,000 1/23/2020 88,000 1/24/2020 61,000 1/27/2020 79,000 1/28/2020 80,000 1/29/2020 93,000 1/30/2020 86,000 1 /31 /2020 78,000 2/3/2020 85,000 2/4/2020 81,000 2/5/2020 71,000 2/10/2020 68,000 2/ 1 1 /2020 6,000 2/18/2020 62,000 2/26/2020 6,000 3/2/2020 86,000 3/3/2020 86,000 3/4/2020 92,000 3/5/2020 99,000 3/9/2020 1 1 1,000 3/10/2020 126,000 3/12/2020 93,000 3/13/2020 88,000 3/14/2020 99,000 3/16/2020 88,000 3/17/2020 62,000 3/18/2020 88,000 3/19/2020 87,000 3/20/2020 88,000 3/24/2020 84,000 3/27/2020 142,000 3/28/2020 74,000 3/30/2020 125,000 3/31 /2020 86,000 4/2/2020 1 18,000 4/3/2020 79,000 4/6/2020 41,000 4/7/2020 84,000 4/9/2020 89,000 4/10/2020 84,000 4/16/2020 76,000 4/17/2020 45,000 4/22/2020 34,000 4/25/2020 43,000 4/27/2020 135,000 4/28/2020 86,000 4/29/2020 123,000 4/30/2020 59,000 5/4/2020 86,000 5/5/2020 85,000 5/7/2020 104,000 5/8/2020 1 18,000 5/1 1 /2020 80,000 5/12/2020 117,000 5/13/2020 115,000 5/14/2020 97,000 5/15/2020 36,000 2/4/2020 75,000 2/ 10/2020 75,000 12/ 1 1 /2020 63,000 2/30/2020 44,000 2/31 /2020 7,000 Totals 2,096,000 556,000 347,000 264,000 1,523,000 838,000 Q I -2020 2,096,000 556,000 347,000 - 427,000 - Q2-2020 - - - - 1,096,000 838,000 Q3-2020 - - - - - - Q4-2020 - - - 264,000 - - GRANVILLE FARMS, INC. FIELD APPLICATION SUMMARY 2020 APPLICATION YEAR Walter Perry Site: 28 CLIENT: CF NITROGEN, INC. PERMIT # W000I2404 APPLICATION METHOD: Surface FIELD ACRES CROP 1 17.6 corn 2 17.5 corn 3 25.1 corn 8 9.2 soybeans 9 9.9 soybeans 10 1.7 soybeans II 3.7 soybeans 12 3.6 soybeans 13 8.7 soybeans 14 7 soybeans 15 17.4 soybeans 16 18.9 soybeans 18 7.4 soybeans 7/ 15/2020 139,000 7/16/2020 152,000 7/ 17/2020 140,000 7/18/2020 68,000 7/19/2020 75,000 7/20/2020 146,000 7/21/2020 126,000 7/22/2020 99,125 7/27/2020 89,000 7/28/2020 151,000 7/29/2020 135,000 7/30/2020 148,000 7/31/2020 149,000 8/3/2020 6,000 8/ 1 1 /2020 6,000 8/18/2020 12,000 8/19/2020 87,000 8/20/2020 122,000 8/21/2020 122,000 8/25/2020 123,000 8/26/2020 122,000 8/27/2020 73,200 48,800 8/28/2020 125,000 8/31/2020 123,000 9/1/2020 149,000 9/2/2020 1 17,000 9/3/2020 149,000 9/4/2020 136,000 9/8/2020 125,000 9/14/2020 85,000 9/ 15/2020 120,000 9/16/2020 120,000 9/21/2020 125,000 9/22/2020 123,000 9/23/2020 122,000 9/24/2020 120,000 9/25/2020 53,000 9/29/2020 24,000 10/6/2020 8,000 10/7/2020 119,000 10/8/2020 123,000 10/9/2020 122,000 10/15/2020 62,000 10/16/2020 99,000 10/19/2020 93,000 10/20/2020 62,000 10/21/2020 63,000 10/22/2020 87,000 10/23/2020 97,000 Totals 499,000 444,000 686,125 221,000 245,000 73,200 122,000 173,800 446,000 248,000 808,000 799,000 325,000 QI-2020 - - - - - - - - - - - - - Q2-2020 - - - - - - - - - - - - - Q3-2020 499,000 444,000 686,125 221,000 245,000 73,200 122,000 173,800 319,000 248,000 - 799,000 325,000 Q4-2020 - - - - - - - - 127,000 - 808,000 - - GRANVILLE FARMS, INC. FIELD APPLICATION SUMMARY 2020 APPLICATION YEAR William Ward, Jr. Site: 33 CLIENT: CF NITROGEN, INC. PERMIT # WQ0012404 APPLICATION METHOD: Surface FIELD ACRES CROP 2 11.9 fescue 3 15.1 fescue 4 13.6 fescue 6 14.6 fescue 7 5.9 fescue 5/26/2020 153,000 5/27/2020 134,000 6/2/2020 101,000 6/3/2020 1 13,000 6/4/2020 106,000 6/5/2020 1 12,000 6/8/2020 120,000 6/9/2020 1 12,000 6/10/2020 75,000 6/ 1 1 /2020 104,000 6/24/2020 1 13,000 6/25/2020 93,000 6/26/2020 38,000 Totals 287,000 320,000 344,000 385,000 38,000 Q I -2020 - - - - - Q2-2020 287,000 320,000 344,000 385,000 38,000 Q3-2020 - - - - - Q4-2020 - - - - - Attachment B ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 29-1 Ronald Byrd Bertie 36°09'30" -76°57'54" 6.7 Leaf Lf 29-2 Ronald Byrd Bertie 36°09'31" -76°58'02" 2.4 Leaf— Lf 29-3 Ronald Byrd Bertie 36°09'31" -76°58'09" 6 Exum ExA 29-4 Ronald Byrd Bertie 36°09'27" -76°58'09" 9.8 Exum ExA 29-5 Ronald Byrd Bertie 36°09'27" -76°58'20" 11.1 Exum ExA 29-6 Ronald Byrd Bertie 36°09'25" -76°58'34" 3.1 Leaf— Lf 29-7 Ronald Byrd Bertie 36°09'24" -76°58'10" 4.6 Granthum G 29-8 Ronald Byrd Bertie 36°09'21" -76°58'05" 10 Granthum Gt 29-9 Ronald Byrd Bertie 36°09'24" -76°58'00" 0.5 Exum ExA 29-10 Ronald Byrd Bertie 36°09'24" -76°57'56" 4.0 Exum ExB 30-1 Kendred C. Williams, Jr. Bertie 36°08'15" -76°57'12" 15.4 Exum ExA 30-2 Kendred C. Williams, Jr. Bertie 36°08'22" -76°5713" 6.1 Exum— ExA 30-3 Kendred C. Williams, Jr. Bertie 36°12'47" -76°56'35" 1.3 Craven CrA 30-4 Kendred C. Williams, Jr. Bertie 36°12'45" -76°56'22" 26.3 Norfo kNoB 30-5 Kendred C. Williams, Jr. Bertie 36°12'43" -76°56'07" 32.4 Craven CrB 30-6 Kendred C. Williams, Jr. Bertie 36°12'31" -76°56'09" 9.0 Craven CrB 30-7 Kendred C. Williams, Jr. Bertie 36°12'38" -76°56'25" 12.9 Craven CrB 30-8 Kendred C. Williams, Jr. Bertie 36°12'40" -76°56'34" 6.5 Craven CrB 30-9 Kendred C. Williams, Jr. Bertie 36°12'41" -76°56'49" 16.4 Norfolk NoA 30-10 Kendred C. Williams, Jr. Bertie 36°12'45" -76°56'47" 3.7 Norfolk —NoA 30-11 Kendred C. Williams, Jr. Bertie 36°12'48" -76°56'45" 1.4 Norfolk NoB 30-12 Kendred C. Williams, Jr. Bertie 36°12'48" -76°56'39" 1.5 Norfolk NoA 30-13 Kendred C. Williams, Jr. Bertie 36°12'51" -76°56'41" 5.1 Lenoir Ln WQ0012404 Version: 3.0 Attachment B Page 1 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 30-14 Kendred C. Williams, Jr. Bertie 36°12'56" -76°56'38" 0.5 Lenoir Ln 30-15 Kendred C. Williams, Jr. Bertie 36°13'03" -76°56'36" 8.9 Leaf— Lf 30-16 Kendred C. Williams, Jr. Bertie 36°13'09" -76°56'31" 4.5 Craven— CrA 30-17 Kendred C. Williams, Jr. Bertie 36°13'06" -76°57'03" 28.1 Craven CrA 30-18 Kendred C. Williams, Jr. Bertie 36°12'55" -76°57'00" 20.9 Craven CrA 30-19 Kendred C. Williams, Jr. Bertie 36°12'54" -76°56'48" 9.3 Goldsboro - GoA 30-20 Kendred C. Williams, Jr. Bertie 36°12'13" -76°56'51" 10.7 Craven CrA 30-21 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'23" -76°56'48" 7.0 Lenoir Ln 30-22 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'16" -76°56'53" 7.5 Craven CrA 30-23 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'16" -76°56'59" 9.2 Craven CrA 30-24 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'18" -76°57'02" 4 Craven CrA 30-25 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'19" -76°57'05" 1.5 Craven CrA 30-26 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'26" -76°57'12" 4.3 Craven CrA 30-27 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'16" -76°57'08" 4.0 Craven CrA 30-28 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'13" -76°57'09" 5.1 Craven— CrA 30-29 C.S. Hollomon, Jr. Kendred C. Williams, Jr. Bertie 36°12'08" -76°57'07" 13.3 Craven CrA 30-30 Kendred C. Williams, Jr. Bertie 36°10'35" -76°57'25" 4.5 Nahunta - Na 30-31 Kendred C. Williams, Jr. Bertie 36°10'28" -76°57'24" 20.8 Exum ExA 30-32 Kendred C. Williams, Jr. Bertie 36°10'24" -76°57'15" 7.5 Goldsboro GoA 30-33 Kendred C. Williams, Jr. Bertie 36°10'18" -76°57'19" 17.8 Goldsboro GoA 30-34 Kendred C. Williams, Jr. Bertie 36°10'18" -76°57'18" 24.1 Goldsboro GoA 30-35 Kendred C. Williams, Jr. Bertie 36°10'20" -76°57'37" 0.9 Exum ExA 30-36 David C. Powell Kendred C. Williams, Jr. Bertie 36°13'13" -76°54'33" 19.9 Exum ExA 30-37 E.M. Powell & Sons, Inc. Kendred C. Williams, Jr. Bertie 36°13'07" -76°54'26" 21.2 Exum ExA 30-38 E.M. Powell & Sons, Inc. Kendred C. Williams, Jr. Bertie 36°12'49" -76°54'30" 23.4 Exum ExA WQ0012404 Version: 3.0 Attachment B Page 2 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 30-39 E.M. Powell & Sons, Inc. Kendred C. Williams, Jr. Bertie 36°12'42" -76°54'24" 25.4 Exum ExA 30-40 T.E. Ruffm Kendred C. Williams, Jr. Bertie 36°09'22" -76°57'24" 19.9 Exum ExA 30-41 T.E. Ruffm Kendred C. Williams, Jr. Bertie 36°09'23" -76°57'37" 7.0 Exum ExA 30-42 T.E. Ruffm Kendred C. Williams, Jr. Bertie 36°09'26" -76°57'43" 4.7 Exum ExA 30-43 T.E. Ruffm Kendred C. Williams, Jr. Bertie 36°09'23" -76°57'46" 7.0 Exum ExA 30-44 James C. Askew Kendred C. Williams. Jr. Bertie 36°11'18" -76°57'21" 3 Exum ExB 30-45 James C. Askew Kendred C. Williams, Jr. Bertie 36°11'18" -76°57'17" 6.3 Exum ExB 30-46 James C. Askew Kendred C. Williams, Jr. Bertie 36°11'17" -76°57'10" 12.0 Gritney Gt 30-47 Oliver B. Balance Kendred C. Williams, Jr. Bertie 36°11'12" -76°57'08" 11.6 Exum ExA 33-17 Leonard L. Godwin William Ward Bertie 36°13'38" -77°00'05" 11.2 Norfolk NoA 33-18 Leonard L. Godwin William Ward Bertie 36°13'31" -76°59'55" 11.2 Goldsboro—GoA 33-19 Ola Sanders William Ward Bertie 36°12'15" -76°56'09" 16.8 Goldsboro—GoA 33-20 Ruth H. Metcalf William Ward Bertie 36°14'16" -76°54'30" 3.3 Exum—ExA 33-21 Ruth H. Metcalf, et al William Ward Bertie 36°14'02" -76°54'24" 12.9 Exum ExA 33-22 Mildred Harris William Ward Bertie 36°13'53" -76°54'12" 17.0 Exum ExA 33-23 Agnes 0. Moore, et al William Ward Bertie 36°13'42" -76°54'09" 10 Goldsboro GoA County Total Bertie 653.6 3-1 Wiley B. Gillam III Hertford 36°19'51" -76°50'39" 19.6 Lynchburg - Ly 3-2 Wiley B. Gillam III Hertford 36°19'44" -76°50'43" 37.2 Lynchburg - Ly 3-3 Wiley B. Gillam III Hertford 36°19'45" -76°50'28" 19.9 Norfolk NoA 3-4 Wiley B. Gillam III Hertford 36°19'27" -76°48'06" 18.6 Wickham WkB 3-5 Wiley B. Gillam III Hertford 36°19'02" -76°48'02" 31.9 Tarboro TaB 6-1 Stuart Pierce Farms, Inc. Hertford 36°16'06" -76°56'20" 17.0 Craven CrA 6-2 Stuart Pierce Farms, Inc. Hertford 36°16'18" -76°56'20" 67.4 Caroline CaA 6-3 Stuart Pierce Farms, Inc. Hertford 36°16'09" -76°55'58" 7.9 Caroline CaA WQ0012404 Version: 3.0 Attachment B Page 3 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 6-4 Stuart Pierce Farms, Inc. Hertford 36°15'54" -76°56'16" 10.9 Caroline CaA 6-5 Stuart Pierce Farms, Inc. Hertford 36° 15'47" -76°56'56" 54.0 Caroline CaA 6-6 Stuart Pierce Farms, Inc. Hertford 36° 15'36" -76°56'34" 23.3 Craven— CrB 6-7 Stuart Pierce Farms, Inc. Hertford 36°15'27" -76°56'11" 42.2 Craven CrB 6-9 Stuart Pierce Farms, Inc. Hertford 36°16'O1" -76°57'17" 38.9 Craven CrA 6-10 Stuart Pierce Farms, Inc. Hertford 36°16'43" -76°55'34" 107.0 Caroline CaA 6-11A Stuart Pierce Farms, Inc. Hertford 36°15'52" -77°00'07" 41.0 Craven CrB 6-11B Stuart Pierce Farms, Inc. Hertford 36°15'41" -76°59'53" 72.2 Craven CrB 6-11C Stuart Pierce Farms, Inc. Hertford 36°15'37" -76°59'40" 29.4 Craven CrB 6-11D Stuart Pierce Farms, Inc. Hertford 36°15'24" -76°59'45" 41.2 Craven CrB 6-11E Stuart Pierce Farms, Inc. Hertford 36°15'36" -76°59'37" 47.7 Craven CrA 6-12 Stuart Pierce Farms, Inc. Hertford 36°18'30" -77°01'47" 40.4 Caroline CaA 6-13 Stuart Pierce Farms, Inc. Hertford 36°18'27" -76°54'52" 41.4 Craven CrA 6-14 Stuart Pierce Farms, Inc. Hertford 36°18'10" -76°54'59" 30.9 Craven CrA 6-15 Stuart Pierce Farms, Inc. Hertford 36°18'14" -76°55'18" 48.8 Craven CrB 6-16 Stuart Pierce Farms, Inc. Hertford 36°16'51" -76°45'06" 46.1 Bonneau BoB 6-17 Stuart Pierce Farms, Inc. Hertford 36°16'44" -76°45'38" 41.9 Bonneau BoB 6-18 Stuart Pierce Farms, Inc. Hertford 36°17'04" -76°45'33" 21.0 Bonneau BoB 6-19 Stuart Pierce Farms, Inc. Hertford 36° 16'33" -76 43'56" 46.3 Goldsboro GoA 6-20 Stuart Pierce Farms, Inc. Hertford 36°16'06" -76°44'18" 21.4 Goldsboro GoA 6-21 Stuart Pierce Farms, Inc. Hertford 36°17'50" -76°43'10" 70.8 Bonneau BoB 6-22 Stuart Pierce Farms, Inc. Hertford 36°16'19" -77°02'38" 56.4 Craven CrA 6-23 Stuart Pierce Farms, Inc. Hertford 36° 16'32" -77°02'41" 94.9 Craven CrA 6-24 Stuart Pierce Farms, Inc. Hertford 36° 16'20" -77°02'23" 41.6 Lenoir Ln WQ0012404 Version: 3.0 Attachment B Page 4 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 9-2 Gray Pierce, et al Hertford 36°18'20" -76°51'10" 18.5 Norfolk NoA 9-3 Gray Pierce Hertford 36°18'14" -76°51'20" 8.5 Norfolk NoA 9-5 Carlyle Archer, et al Gray Pierce Hertford 36°18'13" -76°51'37" 22.8 Norfolk NoA 9-6 Gray Pierce Hertford 36°18'15" -76°51'46" 4.5 Goldsboro GoA 9-7 Gray Pierce Hertford 36°18'07" -76°51'28" 16.2 Norfolk NoA 9-8 Gray Pierce Hertford 36°18'03" -76°51'36" 11.6 Norfolk NoA 9-9 GrayPierce Hertford 36°17'15" -76°51'30" 18.1 Craven CrB 9-10 GrayPierce Hertford 36°17'59" -76°51'30" 5.6 Craven CrB 9-11 GrayPierce Hertford 36°17'45" -76°51'19" 10.6 Craven CrB 9-12 Gray Pierce Hertford 36°17'48" -76°51'05" 8.6 Conetoe— CoB 9-14 Gray Pierce Hertford 36°17'50" -76°50'58" 6.7 Tarboro—TaB 9-15 Gray Pierce Hertford 36°17'58" -76°50'50" 7.7 Tarboro TaB 9-16 Gray Pierce Hertford 36°17'58" -76°51'22" 1.5 Craven CrB 9-17 GrayPierce Hertford 36°18'Ol" -76°51'21" 3.6 Craven CrB 9-18 Gray Pierce Hertford 36°17'50" -76°51'25" 14.6 Wickham WkA 9-19 GrayPierce Hertford 36°17'59" -76°51'10" 3.7 Tarboro—TaB 9-20 Gray Pierce Hertford 36°18'06" -76°51'13" 3.9 Bonneau BoB 9-21 Gray Pierce Hertford 36°17'38" -76°51'49" 6.0 Craven CrA 9-22 Gray Pierce Hertford 36°17'45" -76°51'49" 9.6 Lenoir Ln 9-24 Gray Pierce Hertford 36°17'47" -76°51'43" 13.5 Craven CrA 9-26 Gray Pierce Hertford 36°18'34" -76°51'45" 27.0 Craven CrA 9-27 Gray Pierce Hertford 36°19'12" -76°51'48" 24.9 Tarboro TaB 9-28 Gray Pierce Hertford 36°18'51" -76°52'0I" 15.0 Wickham WkA 9-29 Gray Pierce Hertford 36°18'47" -76°51'57" 5.7 Wickham WkA 9-30 Gray Pierce Hertford 36°18'44" -76°51'53" 11.9 Wickham WkA WQ0012404 Version: 3.0 Attachment B Page 5 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 9-31 Gray Pierce, Merle Jones Gray Pierce Hertford 36°17'48" -76°52'45" 11.4 Craven CrA 9-32 Merle Jones Gray Pierce Hertford 36°17'34" -76°52'36" 17 6 Lenoir Ln 9-33 Gray Pierce Hertford 36°17'37" -76°52'10" 16.7 Craven CrA 9-34 Gray Pierce Hertford 36°17'52" -76°53'00" 8 Craven CrA 9-35 Gray Pierce Hertford 36°17'58" -76°52'55" 13 Craven CrA 9-37 R.C. Kennington Gray Pierce Hertford 36°18'33" -76°52'45" 16 Craven CrB 9-38 R.C. Kennington Gray Pierce Hertford 36°18'27" -76°52'32" 8 Craven CrB 9-40 Gray Pierce Hertford 36°19'21" -76°53'33" 11.2 Wickham WkB 9-41 Gray Pierce Hertford 36°19'33" -76°53'28" 12.4 Wickham WkA 9-42 Gray Pierce Hertford 36°19'23" -77°01'20" 26.4 Caroline CaA 9-43 Gray Pierce Hertford 36°19'16" -77°00'38" 39.4 Caroline CaA 9-45 Gray Pierce Hertford 36°19'11" -77°06'56" 73.7 Craven CrA 9-46A Gray Pierce Hertford 36°19'19" -77°07'49" 36.7 Craven CrA 9-46B Gray Pierce Hertford 36°19'15" -77°07'27" 42.5 Craven CrA 9-47 Gray Pierce Hertford 36°19'33" -77°08'09" 18.8 Craven CrA 9-48 Gray Pierce Hertford 36°18 32' -77°06'31" 45.1 Craven CrA 9-50 Gray Pierce Hertford 36°18'53" -77°06'43" 63.8 Craven CrA 9-52 Gray Pierce Hertford 36°18'57" -77°07'03" 27.4 Craven CrA 9-53 Gray Pierce Hertford 36°19'06" -77°07'13" 26.7 Craven CrB 10-1 J.H. Drewry, III Hertford 36°32'36" -77°09'O1" 7.8 Tarboro TaB 10-2 J.H. Drewry, III Hertford 36°32'30" -77°08'36" 34.1 Wickham WkA 10-3 J.H. Drewry, III Hertford 36°32'17" -77°08'33" 67.7 Autryville AuB 10-4 J.H. Drewry, III Hertford 36°32'35" -77°08'16" 6.9 Lynchburg Ly 10-5 J.H. Drewry, III Hertford 36°32'58" -77°08'17" 20.0 Norfolk NoA 10-6 J.H. Drewry, III Hertford 36°52'21" -77°07'56" 35.0 Craven CrA WQ0012404 Version: 3.0 Attachment B Page 6 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 10-7 J.H. Drewry, III Hertford 36°32'17" -77°08'07" 35.4 Norfolk NoA 10-8 J.H. Drewry, III Hertford 36°32'15" -77°08'18" 42.3 Norfolk NoA 10-9 J.H. Drewry, III Hertford 36°32'24" -77°07'46" 12.3 Autryville AuB 10-10 J.H. Drewry, III Hertford 36°32'27" -77°07'41" 26.3 Bonneau BoB 10-11 J.H. Drewry, III Hertford 36°32'O1" -77°07'07" 4.9 Norfolk NoA 11-1 CF Industries, Inc. Granville Farms, Inc. Hertford 36°22'19" -76°52'10" 40.4 Craven CrA 11-2 CF Industries, Inc. Granville Farms, Inc. Hertford 36°22'17" -76°51'47" 67.2 Craven CrA 11-3 CF Industries, Inc. Granville Farms, Inc. Hertford 36°22'O1" -76°51'54" 41.4 Craven CrA 12-1 Douglas R. White Tuscarora Greens Hertford 36°23'03" -76°54'59" 8.3 Lenoir Ln 12-2 Douglas R. White Tuscarora Greens Hertford 36°22'57" -76°55'11" 8.8 Lenoir Ln 12-3 Douglas R. White Tuscarora Greens Hertford 36°22'40" -76°54'57" 6.3 Craven CrB 12-4 Douglas R. White Tuscarora Greens Hertford 36°22'43" -76°54'46" 30.0 Craven CrA 12-5 Douglas R. White Tuscarora Greens Hertford 36°22'33" -76°54'51" 5.0 Craven CrA 12-6 Douglas R. White Tuscarora Greens Hertford 36°22'55 -76°54'52" 18.0 Craven CrA 23-1 Johnny Powell Hertford 36°17'O1" -76°44'02" 24.9 Norfolk —NoA 23-2 Johnny Powell Hertford 36°16'42" -76°45'12" 13.1 Norfolk NoA 23-3 Thaddeus F. Scott Johnny Powell Hertford 36°17'46" -76°45'44" 39.1 Norfolk NoA 23-4 Thaddeus F. Scott Johnny Powell Hertford 36°17'55" -76°45'44" 22.0 Norfolk NoA 23-5 Johnny Powell Hertford 36°18'19" -76°47'17" 27.7 Norfolk NoB 23-6 Johnny Powell Hertford 36°18'02" -76°50'25" 19.9 Conetoe— CoB 23-7A Johnny Powell Hertford 36°17'42" -76°49'32" 33.5 Craven CrA 23-7B Johnny Powell Hertford 36°18'03" -76°49'10" 13.2 Bonneau BoB 23-8 Johnny Powell Hertford 36°17'12" -76°53'00" 29.8 Caroline CaA 23-9 Johnny Powell Hertford 36°19'50" -76°51'05" 19.8 Craven CrA 23-10 Johnny Powell Hertford 36°20'26" -76°49'47" 15.8 Craven CrA WQ0012404 Version: 3.0 Attachment B Page 7 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 23-12 Johnny Powell Hertford 36°22'27" -76°54'50" 26.3 Craven CrA 23-13 Johnny Powell Hertford 36°21'38" -76°54'02" 20.5 Craven CrA 23-14 Johnny Powell Hertford 36°21'46" -76°54'23" 11.7 Craven CrA 23-15 Johnny Powell Hertford 36°22'38" -76°56'02" 19.0 Norfolk NoA 23-16 Johnny Powell Hertford 36°18'35" -76°55'42" 45.0 Craven CrB 24-2 Chester Powell Hertford 36°19'15" -76°50'40" 14.6 Norfolk NoA 24-3 Chester Powell Hertford 36°19'28" -76°50'34" 11.6 Wickham - WkB 24-4 Chester Powell Hertford 369 8'56" -76°48'52" 10.8 Goldsboro GoA 24-5 Chester Powell Hertford 36°18'43" -76°48'52" 13.0 Bonneau BoB 24-6 Chester Powell Hertford 36°20'24" -76°51'54" 13.5 Craven CrA 24-7 Chester Powell Hertford 36°20'17" -76°51'46" 3.6 Craven CrA 24-8 Chester Powell Hertford 36°15'50" -76°56'33" 6.3 Lenoir Ln 24-9 Chester Powell Hertford 36°15'50" -76°53'54" 12.7 Craven CrA 24-10 Shirley Deramus Chester Powell Hertford 36°18'04" -76°43'20" 6.1 Bonneau BoB 24-11 Shirley Deramus Chester Powell Hertford 36°18'09" -76°43'13" 10.5 Goldsboro GoA 24-13 Chester Powell Hertford 36°15'23" -76°49'06" 14.8 Craven CrA 25-1 Tommy Castelow Hertford 36°21'58" -76°53'54" 39.8 Caroline CaA 25-2 Tommy Castelow Hertford 36°19'46" -76°49'06" 9.3 Norfolk NoA 25-3 Tommy Castelow Hertford 36°20'02" -76°49'03" 32.2 Norfolk NoA 25-4 Tommy Castelow Hertford 36°20'17" -76°49'02" 30.2 Craven CrA 25-5 Tommy Castelow Hertford 36°20'09" -76°48'42" 25.6 Craven CrA 25-6 Tommy Castelow Hertford 36°20'00" -76°47'36" 27.2 Craven CrA 25-7 Tommy Castelow Hertford 36°21'16" -76°47'38" 12.3 Craven CrA 25-8 Tommy Castelow Hertford 36°20'43" -76°54'05" 16.6 Craven CrA 25-9 Tommy Castelow Hertford 36°20'37" -76°54'Ol" 34.7 Craven CrA WQ0012404 Version: 3.0 Attachment B Page 8 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 25-10 Tommy Castelow Hertford 36°20'26" -76°54'07" 11.3 Craven CrA 25-11 Tommy Castelow Hertford 36°20'25" -76°54'13" 4.8 Craven CrA 25-12 Tommy Castelow Hertford 36°20'O1" -76°54'28" 32.0 Craven CrA 26-1 Beechwood Country Club Hertford 36°21'58" -77°00'38" 7.9 Caroline CaA 26-2 Beechwood Country Club Hertford 36°21'53" -77°00'47" 10.5 Craven CrB 26-3 Beechwood Country Club Hertford 36°21'37" -77°00'37" 8.3 Craven CrB 26-4 Beechwood Country Club Hertford 36°21'43" -77°00'O1" 18.2 Caroline CaB 27-52 Lori S. Burgess Steven Burgess Hertford 36°25'02" -77°06'O1" 44.7 Norfolk NoA 27-53 Lori S. Burgess Steven Burgess Hertford 36°24'42" -77°05'55" 10.0 Norfolk NoA 27-54 Steven Burgess Hertford 36°24'36" -77°06'06" 42.7 Norfolk NoA 27-55 Steven Burgess Hertford 36°21'18" -77°07'40" 6.6 Craven CrA 27-56 Steven Burgess Hertford 36°21'19" -77°07'31" 9.8 Craven CrA 27-57 Steven Burgess Hertford 36°21'22" -77°07'21" 12 Craven CrA 27-58 Steven Burgess Hertford 36°21'11" -77°07'17" 4.5 Lenoir Ln 27-59 Steven Burgess Hertford 36°21'08" -77°07'23" 9.0 Lenoir Ln 27-60 Steven Burgess Hertford 36°21'03" -77°07'07" 2 Lenoir Ln 27-61 Steven Burgess Hertford 36°21'04" -77°06'59" 14.9 Craven CrA 27-62 Steven Burgess Hertford 36°20'55" -77°07'02" 3.1 Craven CrA 27-63 Adam & Wendy Burgess Steven Burgess Hertford 36°21'14" -77°06'55" 14.7 Craven CrA 27-64 Adam & Wendy Burgess Steven Burgess Hertford 36°21'24" -77°06'50" 29.5 Craven CrA 28-1 Judith, Allison, & Walter Perry Hertford 36°19'31" -77°50'15" 17.6 Norfolk NoA 28-2 Judith, Allison, & Walter Perry Hertford 36°19'27" -76°50'05" 17.5 Norfolk NoA 28-3 Judith, Allison, & Walter Perry Hertford 36°19'48" -76°50'10" 25.1 Norfolk NoA 28-4 Judith, Allison, & Walter Perry Hertford 36°19'21" -76°49'51" 10.8 Wickham WkA 28-5 Judith, Allison, & Walter Perry Hertford 36°19'10" -76°49'34" 9.4 Conetoe CoB WQ0012404 Version: 3.0 Attachment B Page 9 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 28-6 Judith, Allison, & Walter Perry Hertford 36°19'24" -76°50'24" 20.4 Norfolk NoA 28-7 Judith, Allison, & Walter Perry Hertford 36°19'50" -76°51'03" 16.0 Norfolk NoA 28-8 Judith, Allison, & Walter Perry Hertford 36°19'42" -76°51'06" 9.2 Goldsboro GoA 28-9 Judith, Allison, & Walter Perry Hertford 36° 19'42" -76°51'13" 9.9 Goldsboro GoA 28-10 Judith, Allison, & Walter Perry Hertford 36°19'44" -76°51'18" 1.7 Goldsboro GoA 28-11 Judith, Allison, & Walter Perry Hertford 36°19'48" -76°51'15" 3.7 Craven CrB 28-12 Judith, Allison, & Walter Perry Hertford 36°19'47" -76°51'11" 3.6 Craven CrB 28-13 John Lock Mitchell Walter Perry Hertford 36°17'42" -76°49'37" 8.7 Bonneau BoB 28-14 John Lock Mitchell Walter Perry Hertford 36°17'36" -76°49'45" 7.0 Bonneau BoB 28-15 Betty Perry, John Mitchell, Eleanor Lane, Penny Beasley, & Ken Mitchell Walter Perry Hertford 36° 17'19" -76°50'11" 17.4 Craven CrA 28-16 John Mitchell, Eleanor Lane, Penny Beasley, Ken Mitchell, & Wiccacon Properties, LLC Walter Perry Hertford 36° 18'02" -76°50'23" 18.9 Conetoe CoB 28-17 Margaret Hall Walter Perry Hertford 36°23'O1" -76°56'51" 16.9 Craven CrA 28-18 Betty Everette Perry Walter Perry Hertford 36° 17'30" -76°49'53" 7.4 Craven CrA 31-1 Ray & Linda Chamblee Hertford 36°20'42" -76°55'26" 8.8 Craven CrA 31-2 Jackie Chamblee Ray Chamblee Hertford 36°20'40" -76°55'20" 9.6 Craven— CrB 31-3 Jackie Chamblee Ray Chamblee Hertford 36°20'47" -76°55'13" 15.9 Craven CrA 31-4 Ray & Linda Chamblee Hertford 36°20'43" -76°55'04" 8.8 Craven CrA 31-5 Ray & Linda Chamblee Hertford 36°17'31" -76°55'16" 5.9 Goldsboro GoA 32-1 Janice Simmons Sessoms William H. Sessoms Hertford 36°17'55" -76°48'53" 7.0 Wakulla - WaB 32-2 William H. Sessoms Hertford 36°17'55" -76°48'42" 30.6 Lynchburg Ly 32-3 William H. Sessoms Hertford 36°17'27" -76°48'38" 5.0 Craven CrB 32-4 Joyce Ann Sessoms William H. Sessoms Hertford 36°18'07" -76°48'45" 5.0 Bonneau BoB 32-5 Joyce Ann Sessoms William H. Sessoms Hertford 36°17'43" -76°49'16" 5.5 Lynchburg Ly 32-6 William H. Sessoms Hertford 36°17'42" -76°49'27" 2.7 Lynchburg Ly WQ0012404 Version: 3.0 Attachment B Page 10 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 32-7 William H. & Joyce Ann Sessoms Hertford 36°17'24" -76°47'58" 28.9 Goldsboro - Go 32-8 William H. & Delores Sessoms Hertford 36°17'33" -76°47'23" 23.2 Norfolk NoB 32-9 William H. & Delores Sessoms Hertford 36°17'36" -76°47'36" 13.3 Norfolk —NoB 32-10 William H. & Delores Sessoms Hertford 36°17'42" -76°47'34" 7.3 Norfolk NoB 32-11 Wiccacon Properties, LLC William H. Sessoms Hertford 36°17'47" -76°49'32" 4.3 Craven CrA 32-12 Ernest Chamblee William H. Sessoms Hertford 36°15'23" -76°49'08" 14.0 Craven CrA 33-1 William W & Nellie Ward William Ward Hertford 36°14'36" -76°56'23" 3.0 Caroline CaB 33-2 William W & Nellie Ward William Ward Hertford 36°14'51" -76°56'23" 11.9 Craven CrC2 33-3 William W & Nellie Ward William Ward Hertford 36°14'47" -76°56'21" 15.1 Norfolk NoB 33-4 William W & Nellie Ward William Ward Hertford 36°14'48" -76°56'12" 13.6 Norfolk NoB 33-5 William W & Nellie Ward William Ward Hertford 36°15'10" -76°56'08" 14.2 Tarboro TaB 33-6 William W & Nellie Ward William Ward Hertford 36°14'43" -76°56'10" 14.6 Norfolk NoB 33-7 William W & Nellie Ward William Ward Hertford 36°14'37" -76°56'08" 5.9 Craven CrB 33-8 William W & Nellie Ward William Ward Hertford 36°14'35" -76°56'14" 3.0 Craven CrB 33-9 Michael A. & Deborah Spalding William Ward Hertford 36°14'23" -76°58'28" 14.2 Craven CrA 33-10 Michael A. & Deborah Spalding William Ward Hertford 36°14'28" -76°58'27" 8.0 Craven CrB 33-11 Michael A. & Deborah Spalding William Ward Hertford 36°14'26" -76°58'17" 3.7 Craven - CrB 33-12 Michael A. & Deborah Spalding William Ward Hertford 36°14'21" -76°58'17" 2.4 Craven CrA 33-13 Rosa H. Sessoms William Ward Hertford Hertford 36°15'09" -77°00'47" 25.0 Craven CrA 33-14 Rosa H. Sessoms William Ward Hertford Hertford 36°15'12" -77°00'36" 6.3 Leaf Lf 33-15 Rosa H. Sessoms William Ward Hertford 36°15'15" -77°00'29" 2.8 Craven CrA 33-16 Rosa H. Sessoms William Ward Hertford 36°15'20" -76°00'31" 4.2 Craven CrA County Total Hertford 4,212.3 34-1 Nellie B. Brown Martin 35°59'36" -77°20'10" 26.5 Goldsboro GoA 34-2 Nellie B. Brown Martin 35°59'30" -77°20'17" 19.1 Goldsboro GoA WQ0012404 Version: 3.0 Attachment B Page 11 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 34-3 Nellie B Brown Martin 35°59'26" -77°20'17" 3.8 Lynchburg— Ly 34-4 Nellie B Brown Martin 35°59'20" -77°20'16" 27.1 Lynchburg— Ly County Total Martin 76.5 15-1 J. Elliot Stephenson Northampton 36°28'42" -77°26'06" 19.2 Lynchburg— Ly 15-2 J. Elliot Stephenson Northampton 36°28'31" -77°25'43" 27.3 Craven CrA 15-3 J. Elliot Stephenson Northampton 36°28'19" -77°26'06" 38.0 Caroline CrB 15-4 J. Elliot Stephenson Northampton 36°25'47" -77°25'26" 41.3 Norfolk - NoA 15-5 J. Elliot Stephenson Northampton 36°26'06" -77°25'40" 71.3 Gritney GxB 15-6 J. Elliot Stephenson Northampton 36°26'17" -77°25'44" 37.1 Gritney GxB 15-7 J. Elliot Stephenson Northampton 36°26'12" -77°24'48' 13.1 Norfolk - NoA 15-8 J. Elliot Stephenson Northampton 36°26'19" -77°28'39" 35.6 Goldsboro GoA 15-9 J. Elliot Stephenson Northampton 36°26'49" -77°26'39" 15.1 Gritney GxB 15-10 J. Bentley Stephenson J. Elliot Stephenson Northampton 36°51'21" -77°26'21" 14.2 Gritney GxB 15-11 J. Bentley Stephenson J. Elliot Stephenson Northampton 36°26'44" -77°26'25" 14.5 Gritney GxB 15-12 J. Elliot Stephenson Northampton 36°26'09" -77°26'36" 9.2 Gritney GxB 15-13 J. Elliot Stephenson Northampton 36°26'03" -77°26'25" 17.2 Gritney GxB 15-14 J. Elliot Stephenson Northampton 36°26'21" -77°26'07" 19.9 Gritney GxB 15-15 J. Elliot Stephenson Northampton 36°28'18" -77°25'54" 24.3 Bonneau BoB 15-16 J. Elliot Stephenson Northampton 36°28'24" -77°25'41" 22.8 Bonneau BoB 15-17 J. Elliot Stephenson Northampton 36°28'09" -77°25'52" 33.7 Craven CrA 18-1 Thomas Williams Northampton 36°29'41" -77°07'55" 12.0 Craven CrB 18-2 Thomas Williams Northampton 36°29'52" -77°08'03" 15.0 Craven CrA 19-1W C.C. Woodard Northampton 36°30'46" -77°20'27" 31.7 Norfolk NoB 19-2W C.C. Woodard Northampton 36°40'47" -77°20'48" 21.4 Norfolk —NoB 19-3W C.C. Woodard Northampton 36°30'36" -77°20'56" 69.7 Norfolk NoB WQ0012404 Version: 3.0 Attachment B Page 12 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 19-4W C.C. Woodard Northampton 36°30'27" -77°20'45" 76.7 Norfolk NoB 19-5W Cecil Whitehead C.C. Woodard Northampton 36°30'18" -77°20'50" 12.8 Norfolk —NoB 19-6W Amanda Cooke, et al Cecil Whitehead Northampton 36°30'32" -77°20'33" 18.6 Norfolk NoB 19-7W C.C. Woodard Northampton 36°30'18" -77°20'10" 85.6 Norfolk NoA 19-8W C.C. Woodard Northampton 36°30'15" -77°20'29" 10.9 Norfolk NoB 19-9W C.C. Woodard Northampton 36°30'35" -77°20'21" 15.7 Norfolk NoB 19-10W C.C. Woodard Northampton 36°31'25" -77°20'54" 3.9 Bonneau - BoB 19-11W C.C. Woodard Northampton 36°31'28" -77°20'44" 29.5 Bonneau - BoB 19-12W C.C. Woodard Northampton 36°31'43" -77°20'25" 4.6 Bonneau - BoB 19-13W C.C. Woodard Northampton 36°31'12" -77°20'10" 7.9 Norfolk NoB 19-14W C.C. Woodard Northampton 36°31'19" -77°20'10" 9.3 Norfolk NoB 19-15W C.C. Woodard Northampton 36°31'26" -77°20'10" 11 Norfolk NoB 19-1G C.C. Woodard Northampton 36°32'09" -77°21'07" 48.6 Altavista - AtA 19-2G C.C. Woodard Northampton 36°32'17" -77°21'22" 13.6 Tarboro - TaB 19-3G C.C. Woodard Northampton 36°32'26" -77°21'03" 36.2 Altavista - AtA 19-4G C.C. Woodard Northampton 36°32'43" -77°20'57" 42.5 Wickham - WkA 19-5G C.C. Woodard Northampton 36°32'39" -77°21'13" 20.7 Roanoke - Ro 21-1 C.G. Perry Northampton 36°25'48" -77°20'07" 19.6 Norfolk NoB 21-2 C.G. Perry Northampton 36°25'39" -77°20'45" 29.2 Caroline - CaB 21-3 C.G. Perry Northampton 36°25'38" -77°20'17" 11.2 Caroline - CaB 21-4 C.G. Perry Northampton 36°25'29" -77°20'34" 3.3 Norfolk - NoA 21-5 C.G. Perry Northampton 36°25'31" -77°20'37" 9.3 Norfolk NoB 21-6 C.G. Perry Northampton 36°25'26" -77°20'31" 4.0 Norfolk NoB 21-7 C.G. Perry Northampton 36°25'25" -77°20'25" 6.2 Norfolk NoB 21-8 Robert Jones Robert Jones Northampton 36°25'12" -77°20'28" 50.4 Norfolk NoA WQ0012404 Version: 3.0 Attachment B Page 13 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 21-10 C.G. Perry Northampton 36°23'41" -77°24'16" 44.3 Norfolk NoB 21-11 C.G. Perry Northampton 36°27'57" -77°25'57" 33.7 Craven - CrA 21-13 C.G. Perry Northampton 36°27'40" -77°25'35" 15.4 Norfolk - NoA 21-14A C.G. Perry Northampton 36°27'28" -77°25'40" 13.8 Goldsboro - GoA 21-14B C.G. Perry Northampton 36°27'34" -77°25'39" 18.0 Goldsboro - GoA 21-15 C.G. Perry Northampton 36°27'34" -77°25'16" 17.5 Goldsboro - GoA 21-16 C.G. Perry Northampton 36°27'28" -77°25'16" 5.7 Goldsboro - GoA 21-17 C.G. Perry Northampton 36°25'40" -77°21'08" 4.5 Norfolk - NoA 21-18 Robert Jones Robert Jones Northampton 36°25'28" -77°21'13" 6.7 Norfolk-NoA 21-20 Robert Jones Robert Jones Northampton 36°25'23" -77°21'12" 3.7 Norfolk - NoA 21-21 Robert Jones Robert Jones Northampton 36°25'34" -77°21'02" 31.4 Norfolk - NoA 21-22 Robert Jones Robert Jones Northampton 36°25'25" -77°21'02" 5.7 Goldsboro - GoA 22-1 Charles J. Stephenson Northampton 36°27'24" -77°24'58" 23.7 Goldsboro - GoA 22-2 Charles J. Stephenson Northampton 36°27'21" -77°24'49" 19.6 Goldsboro - GoA 22-3 Charles J. Stephenson Northampton 36°27'17" -77°24'38" 11.4 Goldsboro - GoA 22-4 Charles L Stephenson Northampton 36°26'56" -77°24'31" 9.8 Goldsboro - GoA 22-5 Charles J. Stephenson Northampton 36°25'44" -77°23'58" 6.9 Goldsboro - GoA 27-1 Neil Burgess Stephen Burgess Northampton 36°20'00" -77°12'50" 47.8 Norfolk NoA 27-2 Neil Burgess Stephen Burgess Northampton 36°26'00" -77°12'36" 56.4 Norfolk NoA 27-3 Neil Burgess Stephen Burgess Northampton 36°25'54" -77°12'27" 25.5 Rains Ra 27-4 Neil Burgess Stephen Burgess Northampton 36°25'41" -77°12'41" 27.5 Norfolk NoA 27-5 Neil Burgess Stephen Burgess Northampton 36°25'18" -77°12'39" 16.0 Norfolk-NoA 27-6 Stephen Burgess Stephen Burgess Northampton 36°26'07" -77°11'22" 53.4 Bonneau - BoB 27-7 Judi B. Burgess Stephen Burgess Northampton 36°24'20" -77°13'28" 13.9 Craven - CrA 27-8 Judi B. Burgess Stephen Burgess Northampton 36°23'59" -77°14'10" 17.7 Norfolk —NoB WQ0012404 Version: 3.0 Attachment B Page 14 of 16 ATTACHMENT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 27-9 Lori S. Burgess Northampton 36°23'56" -77°13'57" 18.6 Caroline - CaA 27-10 Stephen Burgess Northampton 36°23'52" -77°13'51" 20.3 Craven - CrA 27-11 Stephen Burgess Northampton 36°23'42" -77°13'50" 23.4 Craven - CrA 27-12 Stephen Burgess Northampton 36°23'39" -77°13'40" 16.7 Craven - CrA 27-13 Stephen Burgess Northampton 36°23'34" -77°13'13" 5.2 Craven - CrA 27-14 Lori S. Burgess Stephen Burgess Northampton 36°24'34" -77°16'04" 14.7 Goldsboro - GoA 27-15 Stephen Burgess Northampton 36°26'31" -77°17'10" 6.5 Norfolk NoB 27-16 Stephen Burgess Northampton 36°26'27" -77°17'02" 5.1 Norfolk NoB 27-17 Stephen Burgess Northampton 36°26'32" -77°16'52" 21.9 Norfolk NoB 27-18 Lori S. Burgess Northampton 36°26'10" -77°14'39" 11.1 Goldsboro - GoA 27-19 Lori S. Burgess Northampton 36°26'18" -77°14'24" 18.4 Goldsboro - GoA 27-20 Eloise T. Ward Stephen Burgess Northampton 36°26'20" -77°14'17" 12.9 Goldsboro - GoA 27-21 Eloise T. Ward Stephen Burgess Northampton 36°26'19" -77°14'13" 3.8 Goldsboro - GoA 27-22 Eloise T. Ward Stephen Burgess Northampton 36°26'34" -77°14'15" 6.7 Goldsboro - GoA 27-23 Eloise T. Ward Stephen Burgess Northampton 36°27'49" -77°15'27" 32.5 Bonneau - BoB 27-24 Eloise T. Ward Stephen Burgess Northampton 36°28'07" -7715'16" 21.5 Bonneau - BoB 27-25 Eloise T. Ward Stephen Burgess Northampton 36°28'04" -77°14'45" 35.2 Bonneau - BoB 27-26 Eloise T. Ward Stephen Burgess Northampton 36°27'53" -77°14'41" 11.5 Norfolk - NoB 27-27 Eloise T. Ward Stephen Burgess Northampton 36°28'02" -77°14'34" 14.4 Norfolk NoB 27-28 Eloise T. Ward Stephen Burgess Northampton 36°27'52" -77°14'25" 25.3 Norfolk NoB 27-29 Eloise T. Ward Stephen Burgess Northampton 36°27'45" -77°14'17" 60.5 Norfolk NoB 27-30 Eloise T. Ward Stephen Burgess Northampton 36°28'11" -77°14'51" 5.7 Autryville - AuA 27-31 Eloise T. Ward Stephen Burgess Northampton 36°28'16" -77°14'52" 10.5 Norfolk NoA 27-32 Eloise T. Ward Stephen Burgess Northampton 36°28'21" -77°14'52" 26.0 Bonneau BoB 27-33 Eloise T. Ward Stephen Burgess Northampton 36°28'21" -77°14'42" 9.9 Norfolk NoA WQ0012404 Version: 3.0 Attachment B Page 15 of 16 ATTACIIIVICNT B - Approved Land Application Sites CF Nitrogen, Inc. Certification Date: February 19, 2021 Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 27-34 Eloise T. Ward Stephen Burgess Northampton 36°28'26" -77° 14'30" 17.6 Bonneau BoB 27-35 Eloise T. Ward Stephen Burgess Northampton 36°28'30" -77° 14'18" 9.1 Goldsboro GoA 27-36 Eloise T. Ward Stephen Burgess Northampton 36°28'24" -77° 13'57" 9.3 Autryville AuA 27-37 Eloise T. Ward Stephen Burgess Northampton 36°28'23" -77° 14' 12" 17.2 Autryville AuA 27-38 Eloise T. Ward Stephen Burgess Northampton 36°28'10" -77° 14'09" 3.0 Norfolk - NoA 27-39 Kevin B. Burgess Stephen Burgess Northampton 36°26'40" -77° 12'40" 20.6 Norfolk - NoB 27-40 Kevin B. Burgess Stephen Burgess Northampton 36°26'33" -77° 12'35" 21.0 Norfolk -NoB 27-41 Stephen Burgess Northampton 36°27'33" -77° 11'45" 9.8 Norfolk - NoB 27-42 Stephen Burgess Northampton 36°27'43" -77° 11'32" 93.5 Bonneau BoB 27-43 Stephen Burgess Northampton 36°27'35" -77°11'21" 17.7 Norfolk—NoB 27-44 Stephen Burgess Northampton 36°27'43" -77° 11' 11" 29 Bonneau BoB 27-45 Stephen Burgess Northampton 36°27'49" -77° 11'04" 18 Norfolk—NoB 27-46 Stephen Burgess Northampton 36°27'27" -77° 11' 18" 13.9 Bonneau BoB 27-47 Stephen Burgess Northampton 36°27'36" -77° 11'06" 20.8 Bonneau - BoB 27-48 Kevin B. Burgess Stephen Burgess Northampton 36°27'31" -77° 10' 15" 14.8 State StA 27-49 Kevin B. Burgess Stephen Burgess Northampton 36°27'27" -77°10'07" 6.1 Tarboro TaB 27-50 Kevin B. Burgess Stephen Burgess Northampton 36°27'38" -77°09'59" 17.9 Altavista— AtA 27-51 Kevin B. Burgess Stephen Burgess Northampton 36°27'38" -77°09'40" 52.7 Tarboro—TaB 27-65 Bobby Bridges Neil Bridges Northampton 36°25'50" -77° 15'01" 67.3 Bonneau— BoB 27-66 Neil & Donna B. Burgess Northampton 36°24'50" -77° 15' 10" 18.1 Norfolk - NoB 27-67 Fannie Bryant Stephen Burgess Northampton 36°27'46" 77°10'47" 33.7 Bonneau - BoB 27-68 Martha Pearlman Northampton 36°30'5" 77° 11'14" 58.0 Goldsboro - GoA 27-69 Ronald Woodard Northampton 36°29'56" 77° 11'18" 42.2 Gritney - GxB 27-70 Ronald Woodard Northampton 36°28'54" 77° 12'25" 85.4 Lynchburg - Ly 27-71 Stephen Burgess Northampton 36°27'29" 77°15'27" 61.8 Bonneau BoB 27-72 Stephen Burgess Northampton 36°27'28" 77° 15'5" 39.7 Bonneau BoB 27-73 Stephen Burgess Northampton 36°27'11" 77° 15'14" 74.9 Norfolk - NoA County Total Northampton 3,026.2 Permit Total 7,968.6 WQ0012404 Version: 3.0 Attachment B Page 16 of 16 Landowner Agreement Attachments & Lessee Agreement Attachments (NO NEW AGREEMENTS WERE OBTAINED IN 2020) Groundwater Data Annual Groundwater Monitoring Report CF Nitrogen, Inc. Cofield, North Carolina S&ME Project No. 1040-98-044U PREPARED ON BEHALF OF: CF Industries Holdings, Inc. 4 Parkway North Suite 400 Deerfield, IL PREPARED BY: S&ME, Inc. 3201 Spring Forest Road Raleigh, NC 27616 February 18, 2021 February 18, 2021 North Carolina Department of Environmental Quality Division of Water Resources — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Attention: Non -Discharge Permitting Unit Reference: Groundwater Monitoring Report Permit No. WQ0012404 January 1, 2020 thru December 31, 2020 CF Nitrogen, Inc. Cofield, North Carolina EPA ID No. NCD065288847 S&ME Project No. 1040-98-044U Non -Discharge Permitting Unit: On behalf of CF Nitrogen, Inc. (CFN), a wholly -owned subsidiary of CF Industries Holding, Inc. (CFIH), S&ME, Inc. (S&ME) is submitting the CY 2020 annual groundwater monitoring report for the CFN site located in Cofield, North Carolina (Figure 1) as required by the Land Application Permit (Permit No. WQ0012404, effective January 1, 2021). S&ME completed this annual report while under contract with CFIH. Groundwater Recovery and Distribution Volumes Based on weekly flow meter readings recorded from Transfer Pump Station #1 beginning December 26, 2019, and ending December 24, 2020, approximately 14,712,300 gallons of groundwater were removed from the confined shallow aquifer in 2020. Quarterly flow amounts for Transfer Pump Station #1 were as follows: 1st Quarter (January — March 2020): 2nd Quarter (April — June 2020): 3rd Quarter (July — September 2020): 4th Quarter (October — December 2020): Total Groundwater Recovery for 2020: 3,879,300 gallons 3,354,600 gallons 4,823,800 gallons 2,654,600 gallons 14,712,300 gallons Based on flow meter readings from Transfer Pump Station #2, approximately 14,310,000 gallons of water were transferred from the storage basin for land application. S&ME, Inc. 1 3201 Spring Forest Road 1 Raleigh, NC 27616 1 p 919.872.2660 1 www.smeinc.com Groundwater Monitoring Report Permit No. WQ0012404 January 1, 2020 thru December 31, 2020 CF Nitrogen, Inc. Cofield, North Carolina EPA ID No. NCD065288847 S&ME Project No. 1040-98-044U The nitrogen -enriched groundwater was applied to a variety of crops throughout the year including corn, wheat, soybeans, and fescue. The following volumes of groundwater may differ slightly to those reported in the land application report, because meter readings were recorded on dates when weekly inspections were conducted, which may have been different than the days readings were recorded by the land application contractor. The flow volumes were recorded during weekly inspections and summed to calculate quarterly volumes of groundwater that were land applied to agricultural fields. Quarterly amounts for 2020 were as follows: 1st Quarter (January — March 2020): 2nd Quarter (April — June 2020): 3rd Quarter (July — September 2020): 4th Quarter (October — December 2020): Total Groundwater Applied for 2020: 3,377,000 gallons 3,347,000 gallons 4,778,000 gallons 2,808,000 gallons 14,310,000 gallons The total annual recorded rainfall at the Ahoskie site was 47.02 inches, compared with the annual average of 46 inches for the area. Land application efforts for 2020, on average, maintained the groundwater elevation within the slurry wall below 30 feet mean sea level (ft-msl). Onsite groundwater elevations were measured monthly from January to October during 2020 and quarterly thereafter. The groundwater elevations recorded from December 26, 2019 through October 27, 2020, and those recorded on January 27, 2021, are presented in Table 1. As required in the permit, potentiometric maps showing quarterly interpretations of general groundwater elevations based on end -of -month measurements for January, April, July, and October 2020 are included as Figures 2, 3, 4 and 5. As required in Attachment C of the Non -Discharge Permit, cross -sectional views of water levels measured in piezometers PI-11 — PO-12 and PI-2 — PO-236 were prepared and are attached as Figures 2A, 3A, 4A and 5A for each corresponding quarterly potentiometric map. Additional cross -sectional views of water levels measured in C- designated wells C-23 — C-22, C-29 — C-28 are included as Figures 2B, 3B, 4B and 5B, and cross -sectional views of C-33-C-32 and monitor wells MWI-4 — MWI-6 are depicted in Figures 2C, 3C, 4C and 5C. The history of water levels for piezometers PI-2, PI-11, PO-12 and PO-236 is graphically shown in Figure 6. The historical water level data from the oldest C-designated wells on site (C-22, C-23, C-28, C-29, C-32 and C-33) are graphically shown in Figure 7. Historical water level elevation data for MWI-3, MWI-4 and MWI-6 are depicted in Figure 8. Precipitation events were recorded by an on -site rain gauge. The amounts of precipitation for CY 2020 are presented in Table 2. Monthly recorded rainfall on -site ranged from 1.83 inches in June 2020 to a season high of 6.97 inches in June 2020. The average monthly rainfall amounts for Cofield, North Carolina (according to precipitation data from the USA.com website, www.USA.com), are presented on Table 2 and depicted on Figure 9. The amount of rainfall in 2020 was approximately one inch greater than the average rainfall for the region. February 18, 2021 2 Groundwater Monitoring Report Permit No. WQ0012404 January 1, 2020 thru December 31, 2020 CF Nitrogen, Inc. Cofield, North Carolina EPA ID No. NCD065288847 S&ME Project No. 1040-98-044U Should you have any questions, please do not hesitate to contact us at (919) 872-2660. Sincerely, S&ME, Inc. Jason Volker, LSS, ORC Project Manager 919-880-3137 jvolker@smeinc.com cc: Ms. Diane Diks, CHMM, CPEA (CF Nitrogen, Inc.) Attachments: Tables Table 1: Table 2: Figures Figure 1: Figure 2: Figure 2A: Figure 2B: Figure 2C: Figure 3: Figure 3A: Figure 3B: Figure 3C: Figure 4: Figure 4A: Figure 4B: Figure 4C: Figure 5: Figure 5A: Figure 5B: Figure 5C: Figure 6: Figure 7: Figure 8: Figure 9: Groundwater Elevation Data Monthly Rainfall 2019 and 2020 Tom Raymond, PE, PMP, RSM Principal Environmental Engineer / Vice President 919-801-5359 traymond@smeinc.com Site Location Map Groundwater Potentiometric Map for January 2020 Cross -sectional View PI-2 — PO-236 & PI-11 — PO-12 for January 2020 Cross -sectional View C-23 — C-22 & C-29 — C-28 for January 2020 Cross -Sectional View C-33 — C-32 & MWI-4 — MWI-6 for January 2020 Groundwater Potentiometric Map for April 2020 Cross -sectional View PI-2 — PO-236 & PI-11 — PO-12 for April 2020 Cross -sectional View C-23 — C-22 & C-29 — C-28 for April 2020 Cross -Sectional View C-33 — C-32 & MWI-4 — MWI-6 for April 2020 Groundwater Potentiometric Maps for July 2020 Cross -sectional View PI-2 — PO-236 & PI-11 — PO-12 for July 2020 Cross -sectional View C-23 — C-22 & C-29 — C-28 for July 2020 Cross -Sectional View C-33 — C-32 & MWI-4 — MWI-6 for July 2020 Groundwater Potentiometric Maps for October 2020 Cross -sectional View PI-2 — PO-236 & PI-11 — PO-12 for October 2020 Cross -sectional View C-23 — C-22 & C-29 — C-28 for October 2020 Cross -Sectional View C-33 — C-32 & MWI-4 — MWI-6 for October 2020 Groundwater Elevations for PI-2, PI-11, PO-12, and PO-236 Groundwater Elevations for C-Designated Wells Groundwater Elevations for MWI-3, MWI-4 and MWI-6 Monthly Rainfall 2020 February 18, 2021 3 Attachments Attachment I — Tables TABLE 1 GROUNDWATER ELEVATION DATA DECEMBER 2019 THROUGH JANUARY 2021 CF NITROGEN - COFIELD, NORTH CAROLINA S&ME PROJECT NO. 1040-98-044U Well ID 12/26/2019 2/24/2020 Date r4/30/2020 of Water Level 5/30/2020 Measurement 6/26/2020 i i v v MWI-1 29.29 30.62 30.21 29.92 31.05 30.27 29.39 28.81 29.89 29.37 28.71 30.07 MWI-2 28.66 29.54 30.60 30.43 30.96 30.06 29.32 29.36 29.46 29.36 29.14 30.36 MWI-3 28.25 29.51 29.67 29.48 30.01 29.45 29.25 28.59 29.65 29.05 28.71 30.23 MWI-4 30.05 30.88 31.05 30.79 30.69 31.03 30.51 30.13 30.99 30.45 29.75 30.83 MWO-5 24.02 24.62 24.82 25.14 25.12 25.32 24.74 24.34 24.34 24.34 24.14 25.24 MWI-6 29.05 29.21 29.97 30.06 30.79 29.43 29.23 28.99 29.63 29.01 28.97 30.73 MWI-7 26.54 27.34 28.46 28.34 28.66 28.04 27.42 26.96 30.20 27.14 27.04 29.42 MWO-8 25.95 25.73 27.95 28.28 30.45 27.23 27.89 26.51 27.01 27.31 25.93 29.35 PI-1 27.91 29.26 29.69 29.46 29.73 29.37 28.69 27.41 29.01 28.55 28.51 29.07 PI-2 27.60 28.30 30.20 28.85 29.68 28.90 28.02 28.10 28.80 28.60 28.40 29.20 PO-3 19.09 19.50 19.15 19.30 19.07 19.33 19.23 19.23 19.01 19.05 18.87 18.87 PI-4 28.21 28.73 30.51 30.38 30.45 29.61 23.95 28.27 29.09 28.75 28.75 30.43 PI-5 27.47 28.00 30.01 29.50 29.50 29.17 28.29 27.79 28.57 27.41 28.25 29.85 PO-6 23.06 23.28 23.36 24.25 23.86 23.98 23.88 23.48 23.52 23.16 23.14 23.58 PI-7 28.48 29.60 30.02 29.96 30.59 29.78 29.28 28.46 29.66 29.00 28.70 29.92 PI-8 25.98 26.82 27.80 27.71 27.88 27.40 26.64 26.44 27.54 26.56 26.42 28.34 PI-9 28.73 29.51 29.71 30.09 29.79 30.51 29.71 29.15 29.81 29.51 29.29 29.21 PI-10 28.48 29.22 29.74 29.52 29.80 30.02 29.62 28.90 29.54 29.50 29.24 30.52 PI-11 26.21 27.95 28.59 28.47 28.57 27.87 27.19 26.69 27.99 26.89 26.65 28.89 PO-12 15.80 16.93 16.34 16.55 16.60 17.06 16.20 16.20 16.22 16.30 16.04 16.40 PI-13R 28.87 29.45 30.57 30.55 30.77 29.93 29.57 28.75 30.25 29.53 29.07 30.75 PI-14 27.90 28.61 29.86 29.99 29.48 28.86 27.84 27.18 29.18 28.04 27.84 29.28 PO-15 23.88 24.03 24.06 24.52 24.66 24.96 24.42 24.38 24.30 24.24 24.14 24.68 PO-16 26.81 27.51 27.25 28.17 29.43 28.21 27.69 27.47 27.21 27.37 27.11 29.83 PI-17 29.48 30.98 32.02 31.90 31.86 29.50 28.20 27.76 30.56 29.20 28.42 31.72 PI-18 27.89 28.12 29.89 29.52 29.57 28.69 28.39 27.53 28.77 27.89 28.27 29.87 PI-19 26.69 27.01 28.87 28.44 28.81 27.91 27.15 26.89 27.83 23.27 27.21 28.71 PI-20 27.78 27.93 29.66 28.90 29.50 28.98 28.44 28.06 27.70 28.46 27.88 29.68 PI-21 27.75 28.08 29.99 29.36 29.31 28.93 28.31 27.91 28.73 28.29 28.15 29.85 PI-22 28.73 29.23 29.45 29.26 28.63 29.61 29.73 29.15 29.65 29.07 29.09 30.23 PI-23 29.96 30.21 32.56 31.91 32.08 30.34 24.24 28.80 30.72 29.96 30.32 32.62 PI-24 28.33 29.55 29.59 29.37 29.59 29.35 29.07 28.55 29.67 29.17 28.77 30.03 PO-25 24.63 24.85 25.25 25.45 25.97 25.47 25.15 24.89 24.79 24.81 25.07 25.97 PO-26 27.19 27.41 28.31 28.55 29.11 28.31 27.53 27.49 27.71 27.23 26.87 29.17 C-22 15.55 16.00 15.71 16.03 16.85 17.23 14.91 14.77 14.65 14.85 14.75 14.85 C-23 (Replaced 04/05) 27.26 28.48 28.96 28.78 29.46 28.68 28.43 27.58 28.90 28.68 26.83 28.94 C-28 (Repaired 08/03) 8.73 9.11 9.57 9.84 9.37 9.55 9.41 9.09 9.11 8.93 8.83 9.97 C-29 25.16 25.79 27.02 27.04 27.24 27.24 26.00 24.96 15.14 25.92 25.82 27.74 C-32 10.27 10.75 11.35 12.11 11.77 11.67 11.03 10.67 11.05 21.05 10.97 12.37 C-33 25.22 25.40 27.42 27.60 27.60 26.68 25.96 25.52 27.30 21.22 26.02 28.12 C-4 27.96 28.68 29.16 29.00 28.96 29.14 28.76 28.36 29.10 28.38 27.76 29.46 PO-235 15.93 16.25 15.63 15.99 15.37 15.55 15.55 15.45 15.63 15.37 15.15 15.85 PO-236 12.64 13.37 13.32 13.73 13.32 13.44 13.12 12.92 13.22 13.16 13.04 14.82 PO-237 27.25 27.53 28.45 28.58 29.45 29.01 27.63 27.13 27.65 27.15 26.95 29.35 TABLE 2 MONTHLY RAINFALL 2019 & 2020 CF INDUSTRIES - COFIELD, NORTH CAROLINA S&ME PROJECT NO. 1040-98-044U Month 2020 Recorded Rainfall at CFI-Ahoskie Site (inches) 2019 Recorded Rainfall at CFI-Ahoskie Site (inches) Average Rainfall for Cofield (inches) www.usa.com January 1.90 3.00 3.60 February 4.50 3.20 3.10 March 2.48 2.75 4.10 April 5.12 5.18 3.50 May 3.40 1.02 3.80 June 1.83 3.55 4.10 July 2.05 5.27 4.80 August 6.97 4.39 4.80 September 5.34 0.53 4.60 October 4.63 2.20 3.20 November 6.30 2.09 3.10 December 2.50 1.93 3.30 Annual Total: 47.02 35.11 46.00 Monthly Average: 3.92 2.93 3.83 Recorded rainfall at site taken from on -site rain gauge Data for average monthly rainfall obtained from the USA.com website for Cofield, NC Attachment II — Figures Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\1_sitelocation.mxd plotted by DHomans 02-15-2021 na Nclue N peel Cy � 1 9k 8,000 (FEET) n REFERENCE: ESRI STREETMAP USA DATSET THIS MAP IS FOR INFORMATIONAL PURPOSES ONLY. ALL FEATURE LOCATIONS DISPLAYED ARE APPROXIMATED. THEY ARE NOT BASED ON CIVIL SURVEY INFORMATION, UNLESS STATED OTHERWISE. a A Rover Rtl M°te " Ps° 6 • Baxema,e G PROJECT SITE SITE LOCATION MAP CF NITROGEN INC. COFIELD, NORTH CAROLINA SCALE: 1"=4,000' DATE: 2-15-21 PROJECT NUMBER 1040-98-044U FIGURE NO. 1 r 0 400 800 PO-235 (16.25) 17 18 19 PO-3 (19.50) 20 21 22 0 (FEET) 1' 6, PO-236 O PI-1 (29.26) O PI-4 (28.73) PI-7 (29.60) PO,-6 A (23728) w 0 IO (30.6MWI2)'-'I (13.37) O MWI-2 (29.54) MWO-5 (24.62) PI-9 (29.51) 25P0=25 (24.85) 26 MWU_8 27 (25.73) PO-26 0 PO-237 (27.41) (27.53) PI-2 (2,T300) C23 (28.48) RW-2 RW-1 O MWI-3 (29.51) PI-22 PI-5 O (28.00) RW-3 O PI-10 (29.22) C4 .68) 29 (29.23) PI-13R (29.45) 30 PI-23 (30.21) C22 16.00) 4 PO-16 (27.51) OMWI-6 (29:211) PI-24 O (29.55) PI-17 (30.98N ^o �0 C29 (25.79) (26.82) C28 (9.11) (10.75) C33 O (25.40) MWI-7 O (27.34) PI-14 (28.61) PO-15 (24.03) • C32 �N (27.95) c'O '9 N LEGEND O InsideWells RECOVERY WELL ® MONITOR WELL O PIEZOMETER (30.62) GROUNDWATER ELEVATION (FEET ABOVE MEAN SEA LEVEL) GROUNDWATER CONTOURS SLURRY WALL NOTE: PIEZOMETERS PI-18 TO PI-21 ARE GROUPED NEAR PI-5, WHICH IS WITHIN THE RADIUS OF INFLUENCE; WATER LEVELS OF THESE PIEZOMETERS ARE THUS EXCLUDED FROM THIS MAP. GROUNDWATER POTENTIOMETRIC MAP January 29, 2020 CF NITROGEN INC. COFIELD, NORTH CAROLINA SCALE: 1"=400' DATE: 2-14-21 PROJECT NUMBER 1040-98-044U FIGURE NO. 2 Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\2A-2C.dwg 45 40 35 30 25 20 15 10 5 0 -5 45 40 35 30 25 20 15 10 5 0 -5 PI-11 42.57' MSL (T.O.C.) -4 27.95 FT. MSL PI-2 42.60' MSL (T.O.C.) SLURRY WALL -4 28.30 FT. MSL -30' MSL PO-236 SECTION PI-2 - PO-236 SECTION PI-11 - PO-12 NOTE: GROUNDWATER DATA COLLECTED ON JANUARY 29, 2020 43.62' MSL (T.O.C.) -4 13.37 FT. MSL SLURRY WALL -30' MSL PO- 2 39.20' MSL (T.O.C.) -4 16.93 FT. MSL CROSS - SECTIONAL VIEW PI-2 - PO-236 & PI-11 - PO-12 SCALE: FIGURE NO. 1"=15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 2A J Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\2A-2C.dwg 45 40 35 30 25 20 15 10 5 0 -5 45 40 35 30 25 20 15 10 5 0 -5 C-29 43.14' MSL (T.O.C.) -4 25.79 FT. MSL C-23 40.48' MSL (T.O.C.) 2 28.48 FT. MSL C-22 39.65' MSL (T.O.C.) SLURRY WALL -30' MSL 16.00 FT. MSL 2- SECTION C-23 - C-22 SECTION C-29 - C-28 NOTE: GROUNDWATER DATA COLLECTED ON JANUARY 29, 2020 SLURRY WALL -30' MSL C-28 39.01' MSL (T.O.C.) 4 9.11 FT. MSL CROSS - SECTIONAL VIEW C-23 - C22 & C-29 - C28 SCALE: FIGURE NO. 1"=15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 2B J Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\2A-2C.dwg 45 40 35 30 25 20 15 10 5 0 -5 50 45 40 35 30 25 20 15 10 5 0 -5 C-33 39.40' MSL (T.O.C.) -2 25.40 FT. MSL 42.03' MSL (T.O.C.) 30.88 FT. MSL Q- MWI-4 36.85' MSL (T.O.C.) SLURRY WALL -30' MSL 10.75 FT. MSL SECTION C-33 - C-32 MWI-3 46.31' MSL (T.O.C.) 44.93' MSL (T.O.C.) -2 29.51 FT. MSL 29.21 FT. MSL 2- SECTION MWI-4, MWI-3, MWI-6 NOTE: GROUNDWATER DATA COLLECTED ON JANUARY 29,2020 MWI-6 C-32 CROSS - SECTIONAL VIEW C-33 - C-32 & MWI-4, MWI-3, MWI-6 SCALE: FIGURE NO. = 15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 2C r E a 0 400 800 16 17 18 19 20 21 22 23 PI-4 A (30.45) PO 1.3 (19.07) PI-7 (30.59) A PO-6 (23,86) (FEET) MWI-1 (31.05) MWI-2 ® (30.96) by MWO-5(25.12) PI-9 RW-1 (29.79) PI-22 (28.63) PO-25 (25.97) P 0 (29I-5.50) RW-3 PI9.8-10 0 (20) PI-13R 30.77) RW-4 29 30 C23 (29.46) (6285) '• RW-5 RW-6 MWI-4 ® (30.69) C4 (28.96) '° MWO-8 ' I' PI-23 4(30.45) (32108) ti ) P0-237 `c PO-26 (29.45) (29t11) ticb PO-16 (29.43) , MWI-6 (30.79) A PI-24 (29.59) RW-7 RW-8 0 (130 C29 (27.24) RW-9 PI-8 (27.88) 2j 28 C28 (9.37) C33 (27.60) MWI-7 ® (28.66) PI-14 (29.48) 26 P0-15 (248 6) c'S 131 C32 (11.77) <2' No• PI-11 (28.57) '9 20 PO-12 (16.60) LEGEND RECOVERY WELL @ MONITOR WELL O PIEZOMETER SLURRY WALL GROUNDWATER CONTOURS (31.05) GROUNDWATER ELEVATION (FEET ABOVE MEAN SEA LEVEL) N NOTE: PIEZOMETERS PI-18 TO PI-21 ARE GROUPED NEAR PI-5, WHICH IS WITHIN THE RADIUS OF INFLUENCE; WATER LEVELS OF THESE PIEZOMETERS ARE THUS EXCLUDED FROM THIS MAP. GROUNDWATER POTENTIOMETRIC MAP April 30, 2020 CF NITROGEN INC. COFIELD, NORTH CAROLINA SCALE: 1"=400' DATE: 2-14-21 PROJECT NUMBER 1040-98-044U FIGURE NO. 3 s\1040-98-044U 2020 Results\2020 CAD\3A-3C.dwg Drawing Path: R:\CADData\Charl 45 40 35 30 25 20 15 10 5 0 -5 45 40 35 30 25 20 15 10 5 0 -5 PI-11 42.57' MSL (T.O.C.) 2 28.57 FT. MSL PI-2 42.60' MSL (T.O.C.) SLURRY WALL 4 29.68 FT. MSL -30' MSL PO-236 SECTION PI-2 - PO-236 SECTION PI-11 - PO-12 NOTE: GROUNDWATER DATA COLLECTED ON APRIL 30, 2020 SLURRY WALL 43.62' MSL (T.O.C.) 2 13.32 FT. MSL -30' MSL PO- 2 39.20' MSL (T.O.C.) -4 16.60 FT. MSL CROSS - SECTIONAL VIEW PI-2 - PO-236 & PI-11 - PO-12 SCALE: FIGURE NO. 1"=15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 3A Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\3A-3C.dwg 45 40 35 30 25 20 15 10 5 0 -5 45 40 35 30 25 20 15 10 5 0 -5 C-29 43.14' MSL (T.O.C.) -4 27.24 FT. MSL C-23 40.48' MSL (T.O.C.) 2 29.46 FT. MSL C-22 39.65' MSL (T.O.C.) SLURRY WALL -30' MSL 16.85 FT. MSL 4 SECTION C-23 - C-22 SECTION C-29 - C-28 NOTE: GROUNDWATER DATA COLLECTED ON APRIL 30, 2020 SLURRY WALL -30' MSL C-28 39.01' MSL (T.O.C.) 4 9.37 FT. MSL CROSS - SECTIONAL VIEW C-23 - C22 & C-29 - C-28 SCALE: FIGURE NO. = 15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 3B Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\3A-3C.dwg 45 40 35 30 25 20 15 10 5 0 -5 50 45 40 35 30 25 20 15 10 5 0 -5 C-33 39.40' MSL (T.O.C.) 27.60 FT. MSL 42.03' MSL (T.O.C.) 30.69 FT. MSL 4- MWI-4 SECTION C-33 - C-32 MWI-3 44.93' MSL (T.O.C.) 2 30.01 FT. MSL SLURRY WALL 36.85' MSL (T.O.C.) 30' MSL 11.77 FT. MSL 46.31' MSL (T.O.C.) 30.79 FT. MSL Q SECTION MWI-4, MWI-3, MWI-6 NOTE: GROUNDWATER DATA COLLECTED ON APRIL 30, 2020 MWI-6 C-32 CROSS - SECTIONAL VIEW C-33 - C-32 & MWI-4, MWI-3, MWI-6 SCALE: FIGURE NO. 1"=15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 3C J N Len E r 0 400 800 20 21 22 23 PI-4 A (28.27) PO ,3 (19.23) PI-7 (28.46) PO 6 0 (23748) (FEET) P0-236 PI,�2 �$ ( ) (28.1 ,gyp, ®(28.81) MWI-1 MWI-2 ® (29.36) MWO-5 (24.34) PI-9 (29.15) PO-25 (24.89) 25 RW-2 RW-1 ® (28.59) (29.15) MW.O-8 0(26.51) - PI-23 26 (28.80) 0 PO-237 PO-26 (27.13) (27.49) C23 (27.58) C22 / (14.7'7) #3' A PI;5 RW-5 (27.79) RW-3 PI-10 0 (28.90) PI-13R RW-6 C28 (9.09) C29 RW; 4 (24.96) O 1(30.13 RW-9 C33 C32 (25.52) ® (10.67)) �3 (28.75) C4 ® (28.36) MWI-6 (28.99) PI-24 A (28.55) PO-16 �� (27 6c'> (27.47) cab PO-15 (24.38) 2Q 2J 22 c'O '9 PO-12 (16.20) N LEGEND RECOVERY WELL ® MONITOR WELL O PIEZOMETER (28.81) GROUNDWATER ELEVATION (FEET ABOVE MEAN SEA LEVEL) SLURRY WALL GROUNDWATER CONTOURS NOTE: PIEZOMETERS PI-18 TO PI-21 ARE GROUPED NEAR PI-5, WHICH IS WITHIN THE RADIUS OF INFLUENCE; WATER LEVELS OF THESE PIEZOMETERS ARE THUS EXCLUDED FROM THIS MAP. GROUNDWATER POTENTIOMETRIC MAP CF NITROGEN INC. COFIELD, NORTH CAROLINA SCALE: 1"=400' DATE: 2-15-21 PROJECT NUMBER 1040-98-044U FIGURE NO. 4 • Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\4A-4C.dwg 45 40 35 30 25 20 15 10 5 0 -5 45 40 35 30 25 20 15 10 5 0 -5 PI-11 42.57' MSL (T.O.C.) -Q 26.69 FT. MSL PI-2 42.60' MSL (T.O.C.) SLURRY WALL 2 28.10 FT. MSL -30' MSL PO-236 SECTION PI-2 - PO-236 SECTION PI-11 - PO-12 NOTE: GROUNDWATER DATA COLLECTED ON JULY 27, 2020 43.62' MSL (T.O.C.) -4 12.92 FT. MSL SLURRY WALL -30' MSL PO- 2 39.20' MSL (T.O.C.) -Q 16.20 FT. MSL CROSS - SECTIONAL VIEW PI-2 - PO-236 & PI-11 - PO-12 SCALE: FIGURE NO. = 15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 4A Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\4A-4C.dwg 45 40 35 30 25 20 15 10 5 0 -5 45 40 35 30 25 20 15 10 5 0 -5 C-29 43.14' MSL (T.O.C.) 2 24.96 FT. MSL C-23 40.48' MSL (T.O.C.) 2 27.58 FT. MSL NOTE: GROUNDWATER DATA COLLECTED ON JULY 27, 2020 C-22 39.65' MSL (T.O.C.) SLURRY WALL -30' MSL 14.77 FT. MSL 4 SECTION C-23 - C-22 SECTION C-29 - C-28 SLURRY WALL -30' MSL C-28 39.01' MSL (T.O.C.) 4 9.09 FT. MSL CROSS - SECTIONAL VIEW C-23 - C22 & C-29 - C-28 SCALE: FIGURE NO. = 15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 4B Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\4A-4C.dwg 45 40 35 30 25 20 15 10 5 0 -5 50 45 40 35 30 25 20 15 10 5 0 -5 C-33 39.40' MSL (T.O.C.) 4 25.52 FT. MSL 42.03' MSL (T.O.C.) 30.13 FT. MSL 4 MWI-4 SECTION C-33 - C-32 MWI-3 44.93' MSL (T.O.C.) -4 28.59 FT. MSL SLURRY WALL 36.85' MSL (T.O.C.) 30' MSL 10.67 FT. MSL 46.31' MSL (T.O.C.) 28.99 FT. MSL 7 SECTION MWI-4, MWI-3, MWI-6 NOTE: GROUNDWATER DATA COLLECTED ON JULY 27, 2020 MWI-6 4 C-32 CROSS - SECTIONAL VIEW C-33 - C-32 & MWI-4, MWI-3, MWI-6 SCALE: FIGURE NO. 1"=15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 4C J E 0 Lin a r 0 400 800 20 21 22 23 PI-4 A (28.75) PO,3 (18.87) PI-7, (28.70) PO-6 A (23�14) (FEET) MWI-2 ® (29.14) MWO-5 (24.14) PI-9 (29.29) 25 PO-25 •••••'(25:07) 26 (28.71)MWI-3 ® PI-22 (29.09) MWO-8 (25193) PI-10 A (29`.24) (PI13R PO-26 (26.87) 0 (29.07) a ` C22/ (26.83)\14.75) 2� 26, ,moo RW-6 RW,7 `)d' RW'8 C29 RW-4 ` (25.82) MWI-4 ® (29.75) so,C4 ^\� (27.76) (30B2) PO-237 (26.95) 2l PO-16 (27.11) MWI-6 (28.97) 0 PI-24 (28.77) PI17 0 (28.42) RW-9 (2PI-8 0 6.42) C28 (8.83) RI-14 (27.84) C32 (10.97)' C33 (26.02) MWI-7 (27.04) 22 PO-15 2,, (24..14) PI 0 (16.04) (26.65) 65 2J 20 '9 PO-12 ./j N LEGEND RECOVERY WELL ® MONITOR WELL O PIEZOMETER (28.71) GROUNDWATER ELEVATION (FEET ABOVE MEAN SEA LEVEL) SLURRY WALL GROUNDWATER CONTOURS NOTE: PIEZOMETERS PI-18 TO PI-21 ARE GROUPED NEAR PI-5, WHICH IS WITHIN THE RADIUS OF INFLUENCE; WATER LEVELS OF THESE PIEZOMETERS ARE THUS EXCLUDED FROM THIS MAP. GROUNDWATER POTENTIOMETRIC MAP October 27, 2020 CF NITROGEN INC. COFIELD, NORTH CAROLINA SCALE: 1"=400' DATE: 2-15-21 PROJECT NUMBER 1040-98-044U FIGURE NO. 5 Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\5A-5C.dwg 45 40 35 30 25 20 15 10 5 0 -5 50 45 40 35 30 25 20 15 10 5 0 -5 C-33 39.40' MSL (T.O.C.) 26.02 FT. MSL 42.03' MSL (T.O.C.) 29.75 FT. MSL 4 MWI-4 SECTION C-33 - C-32 MWI-3 44.93' MSL (T.O.C.) -4 28.71 FT. MSL SLURRY WALL 36.85' MSL (T.O.C.) 30' MSL 10.97 FT. MSL 46.31' MSL (T.O.C.) 28.97 FT. MSL 8 SECTION MWI-4, MWI-3, MWI-6 NOTE: GROUNDWATER DATA COLLECTED ON OCTOBER 27, 2020 MWI-6 C-32 CROSS - SECTIONAL VIEW C-33 - C-32 & MWI-4, MWI-3, MWI-6 SCALE: FIGURE NO. 1"=15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 5C J Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\5A-5C.dwg 45 40 35 30 25 20 15 10 5 0 -5 45 40 35 30 25 20 15 10 5 0 -5 C-29 43.14' MSL (T.O.C.) 2 25.82 FT. MSL C-23 40.48' MSL (T.O.C.) C-22 39.65' MSL (T.O.C.) 2 26.83 FT. MSL SLURRY WALL -30' MSL 14.75 FT. MSL 4 SECTION C-23 - C-22 SECTION C-29 - C-28 NOTE: GROUNDWATER DATA COLLECTED ON OCTOBER 27, 2020 SLURRY WALL -30' MSL C-28 39.01' MSL (T.O.C.) 4 8.83 FT. MSL IINit CROSS - SECTIONAL VIEW C-23 - C22 & C-29 - C-28 SCALE: FIGURE NO. = 15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15*-2021 PROJECT NUMBER 1040-98-044U 5B • Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\5A-5C.dwg 45 40 35 30 25 20 15 10 5 0 -5 45 40 35 30 25 20 15 10 5 0 -5 PI-11 42.57' MSL (T.O.C.) 2 26.65 FT. MSL PI-2 42.60' MSL (T.O.C.) SLURRY WALL 2 28.40 FT. MSL -30' MSL PO-236 SECTION PI-2 - PO-236 SECTION PI-11 - PO-12 NOTE: GROUNDWATER DATA COLLECTED ON OCTOBER 27,2020 SLURRY WALL 43.62' MSL (T.O.C.) 4 13.04 FT. MSL -30' MSL PO- 2 39.20' MSL (T.O.C.) 16.04 FT. MSL CROSS - SECTIONAL VIEW PI-2 - PO-236 & PI-11 - PO-12 SCALE: FIGURE NO. = 15' DATE: CF NITROGEN, INC. COFIELD, NORTH CAROLINA 2-15-2021 PROJECT NUMBER 1040-98-044U 5A Groundwater Elevation (ft. MSL) 40.00 35.00 30.00 25.00 20.00 15.00 10.00 5.00 0.00 III FIGURE 6 Groundwater Elevations for PI-2, PI-11, PO-12, PO-236 CF Nitrogen, Inc. Cofield, North Carolina S&ME Project No. 1040-98-044U Top of Slurry Wall = 30 ft. MSL y ‘Id 111/4A iNf4111\r/V Start Groundwater Recovery 00 ct 00 o, o, 0 0 O1 OS O 0 O 0 ct N 0 0 0 0 i i 1 o N N 00 00 0, o, O 0 O O O O O O O O 0 T--1 '--� j N j N Cr) M T--1 T--1 .--1 ct ▪ tIn N 00 00 C 0 T--1 T--1 T--1 T--1 T--1 T--1 T--1 T--1 T--1 T--1 T--1 N Ct Time 40.00 35.00 j) 30.00 25.00 v 20.00 v z 15.00 C7 10.00 5.00 0.00 III FIGURE 7 Groundwater Elevations for C- Designated Wells CF Nitrogen, Inc. Cofield, North Carolina S&ME Project No. 1040-98-044U L Start Groundwater Recovery Top of Slurry Wall = 30 ft. MSL 00 00 0\ O\ O O -- - N N M M ▪ in in N N 00 00 01 O1 O O - N N M M in in N N 00 00 01 01 O O -� CI) CI) CI) CI) CI) O O O ▪ O CI) CI) O O O O CI) CI) CI) Time Groundwater Elevation (ft. MSL) 40 35 30 25 20 15 10 5 0 IMMir III FIGURE 8 Groundwater Elevations for MWI-3, MWI-4 & MWI-6 CF Nitrogen, Inc. Cofield, North Carolina S&ME Project No. 1040-98-044U Top of Slurry Wall = 30 ft. MSL Start Groundwater Recovery bo bo bA bo bo bo bA bo bo bo bo bA , bo bo bo bo bA bA bo bo - w- w- w- w- w- w- w- w- w- w- w- w- w- w- w- w- w- w- w- w- w- w- Time I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 00 01 01 O O - N N M M ▪ in in \O \O N N 00 00 On On O O - N N M M ▪ in in \O \O N N 00 00 On O\ O O 01 01 01 O O O - O O O O O O ▪ O O O O O O O O O O O N N bA OW OW Rainfall (Inches) III 8.00 7.00 6.00 5.15.18 Figure 9 Monthly Rainfall CF Nitrogen, Inc. Cofield, NC S&ME Project 1040-98-044U 5.27 5.00 ■ 4.8 4.00 3.00 2.00 1.00 0.00 3.6 3.00 4.50 iil 2.7 4.1 4.1 3.8 3.55 3.5 Jan Feb Mar Apr ■ 2020 Rainfall 3.40 i .02 i May 111 2.0 i Jun Jul 6.97 4.8 Aug 5.34 ■ 2019 Rainfall Average Monthly Rain for Cofield, NC Sep Oct 6.30 Nov Dec