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HomeMy WebLinkAboutWQ0012404_Annual Report_20210219 (2) 2020 Annual Report Land Application Program CF Nitrogen, Inc. Permit No. WQ0012404 PREPARED FOR: CF Industries Holdings, Inc. 4 Parkway North Suite 400 Deerfield, IL 60015-2590 PREPARED BY: S&ME, Inc. 3201 Spring Forest Road Raleigh, NC 27616 February 19, 2021 S&ME, Inc. | 3201 Spring Forest Road | Raleigh, NC 27616 | p 919.872.2660 | www.smeinc.com February 19, 2021 North Carolina Department of Environmental Quality Division of Water Resources – UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Attention: Non-Discharge Permitting Unit Reference: 2020 Annual Report Land Application Program CF Nitrogen, Inc. Permit No. WQ0012404 S&ME Project No. 1040-98-044U Non-Discharge Compliance Unit: S&ME, Inc. (S&ME) is submitting all monitoring and reporting requirements as specified in the above referenced permit for CF Nitrogen, Inc. S&ME compiled this report using data gathered during the compliance year. This data includes: 1) Certification Form, 2) Residual Sampling Summary Form, 3) 2020 Application Summary and Field Loading Rate Reports, 4) Field Application Summaries, 5) Updated Attachment B, 6) Landowner Agreement Attachments & Lessee Agreement Attachments, and 7) Groundwater Report. CF Nitrogen, Inc. conducted land application events on current permitted fields in Hertford and Northampton counties within the year of 2020. A total of 14,484,000 gallons of nitrogen-enriched groundwater were land applied. TCLP, Pathogen and Vector Monitoring, and Soil Analysis are not included in the report as these requirements are not required by Permit based on the permitted operation of a groundwater recovery system only. If there is any further information required or questions regarding this land application program, please do not hesitate to contact us for further assistance. Sincerely, S&ME, Inc. Jason Volker, LSS, ORC Tom Raymond, PE, PMP, RSM Project Manager Principal Environmental Engineer / Vice President 919-880-3137 919-801-5359 jvolker@smeinc.com traymond@smeinc.com cc: Ms. Diane Diks, CHMM, CPEA (CF Nitrogen, Inc.) Mr. Jay Bryant (Granville Farms) 2020 Annual Report Land Application Program CF Nitrogen, Inc. S&ME Project No. Permit No. WQ0012404 February 19, 2021 ii TABLE OF CONTENTS: SECTION NO. TITLE I Annual Land Application Certification Form II Residuals Sampling Summary and Analysis III 2020 Application Summary and Field Loading Rate Reports IV Field Application Summaries V Updated Attachment B VI Landowner Agreement Attachments & Lessee Agreement Attachments VII Groundwater Data 2020 Annual Report Land Application Program CF Nitrogen, Inc. S&ME Project No. Permit No. WQ0012404 February 19, 2021 iii CF Nitrogen, Inc. Ms. Diane Diks 4 Parkway North, Suite 400 Deerfield, IL 60015-2590 847-405-2400 NC PERMIT # WQ0012404 Mr. Jay Bryant Granville Farms, Inc. 100 Farmers Chemical Road Cofield, NC 27922 252-358-2129 LAND APPLIERS: Granville Farms, Inc. 8229 Highway 96 North Oxford, North Carolina 27565 919-690-8000 Attachments Annual Land Application Certification Form ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0012404 County: Facility Name (as shown on permit): Land Application Operator: Hertford Year: CF Nitrogen, Inc. 2020 Granville Farms, Inc. Phone: 919-690-8000 Land application of residuals as allowed by the permit occurred during the past calendar year? ❑� Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the permit: 395 Total number of fields utilized for land application during the year: 27 Total amount of dry tons applied during the year for all application sites: N/A Groundwater Recovery System Total number of acres utilized for land application during the year: 692.9 Part B - Annual Compiance Statement: Facility was compliant during calendar year (including but not limited to items 1-13 below) issued by the Division of Water Quality. 0 Yes ❑ No if no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 2020 with all conditions of the land application permit 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF Nitrogen, Inc. Tunis, NC Facility Permittee Name an Title iv or print) j� vvt 2-- 2 —2o it Signature of Permittee Date Sij i turc of Preparer* Date Signawt o i Land Applier Jason Volker, S&ME, Inc. Jay Bryant, Granville Farms, Inc. * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) Date DENR FORM ACF (12/2006) Residuals Sampling Summary and Analysis WQ Permit Number:1) Facility Name: 2) NPDES # or WQ#:NA 3) Name RESIDUAL ANALYSIS DATA Date Sampled (grab) or Date Composited 1/23/2020 4/27/2020 7/13/2020 10/20/2020 Percent Solids NA N/A N/A N/A PARAMETERS (mg/L dry weight) TKN 217 233 255 235 Ammonia-Nitrogen 239 233 255 234 Nitrate-Nitrogen 273 200 315 225 Total Phosphorus 2.09 1.41 1.78 2.91 Aluminum 0.678 0.323 0.534 1.10 Calcium 57 57 61.3 59.1 Magnesium 17.0 17.0 18.5 18.8 Potassium 31.9 33.0 33.9 33.4 pH 7.0 7.1 2.6*6.9 Sodium 33.4 33.6 35.6 32.5 X Signature of Preparer CF Nitrogen, Inc. ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ0012404 Laboratory:Waypoint Analytical 2/19/2020 Date “I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.” Nitrogen-Enriched Groundwater Recovery System *Apparent Waypoint Analytical lab error- recurring lab errors (reporting of low pH values) were documented by S&ME between April and July 2020. The actual pH of reclaimed water has been well documented as having neutral pH since beginning of the land application program in 1998. 20-023-0001 Account Number 46260 Report Number CF Industries John Foster 100 Farmers Chemical Rd Suite 400 Cofield, NC 27922 Send To: 083004 Analysis Result Quantitation Limit Method Date and Time Test Started Analyst Lab Number: 70243 Sample ID:083004 Project: 01/23/2020Date Sampled: 01/23/2020 B63722Purchase Order: Date Received: REPORT OF ANALYSIS Report Date:01/30/2020 217mg/LTotal Kjeldahl Nitrogen ,10.0 01/29/2020 12:20 JCMSM-4500-NH3C-TKN 2.09mg/LPhosphorus,0.100 01/29/2020 00:25 JTR6010D 31.9mg/LPotassium,0.500 01/29/2020 11:36 KKM6010D 57.4mg/LCalcium,0.500 01/29/2020 00:25 JTR6010D 17.0mg/LMagnesium,0.100 01/29/2020 00:25 JTR6010D 33.4mg/LSodium,0.500 01/29/2020 00:25 JTR6010D 0.678mg/LAluminum,0.100 01/29/2020 00:25 JTR6010D 239mg/LAmmonia Nitrogen ,2.00 01/29/2020 12:20 JCMSM-4500-NH3C 273mg/LNitrate+Nitrite-N ,100 01/30/2020 11:36 BW14500NO3F-2011 7.0s.u.pH ,01/27/2020 14:00 JCM9045D Pauric McGroary Page 3 of 6 , REPORT OF ANALYSISReport Number : Project Information : NC 27922 20-119-9004 46260 Suite 400 CF Industries 100 Farmers Chemical Rd John Foster Cofield Received : 04/28/2020 086531 Revised Report Date: 05/11/2020 Original Report Date : 05/05/2020 Sample ID : Lab No : Sampled:086531 71183 Matrix: 4/27/2020 10:26 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF 233 mg/L 2.00Ammonia Nitrogen 1 04/29/20 10:00 SM-4500-NH3CJCM 200 mg/L 10.0Nitrate+Nitrite-N 100 05/04/20 15:43 4500NO3F-2011ZBD 7.1 s.u.pH 1 05/11/20 12:45 9045DSAJ 233 mg/L 10.0Total Kjeldahl Nitrogen 1 05/01/20 10:00 SM-4500-NH3C-TKNJCM 1.41 mg/L 0.100Phosphorus 1 05/05/20 10:50 6010DKKM 0.323 mg/L 0.100Aluminum 1 05/05/20 10:50 6010DKKM 57.0 mg/L 0.500Calcium 1 05/05/20 10:50 6010DKKM 17.0 mg/L 0.100Magnesium 1 05/05/20 10:50 6010DKKM 33.0 mg/L 1.00Potassium 10 05/05/20 11:19 6010DKKM 33.6 mg/L 0.500Sodium 1 05/05/20 10:50 6010DKKM Qualifiers/ Definitions Limit ExceededLDilution FactorDF Method Quantitation LimitMQL Page 3 of 5 20-198-0007 Account Number 46260 Report Number CF Industries John Foster 100 Farmers Chemical Rd Suite 400 Cofield, NC 27922 Send To: 89479 Analysis Result Quantitation Limit Method Date and Time Test Started Analyst Lab Number: 73100 Sample ID:89479 Project: 07/13/2020Date Sampled: 07/16/2020 B63722Purchase Order: Date Received: REPORT OF ANALYSIS Report Date:07/23/2020 255mg/LTotal Kjeldahl Nitrogen ,10.0 07/20/2020 09:10 JCMSM-4500-NH3C-TKN 1.78mg/LPhosphorus,0.100 07/21/2020 03:09 JTR6010D 33.9mg/LPotassium,1.00 07/21/2020 16:57 TJS6010D 61.3mg/LCalcium,0.500 07/21/2020 03:09 JTR6010D 18.5mg/LMagnesium,0.100 07/21/2020 03:09 JTR6010D 35.6mg/LSodium,0.500 07/21/2020 03:09 JTR6010D 0.534mg/LAluminum,0.100 07/21/2020 03:09 JTR6010D 255mg/LAmmonia Nitrogen ,2.00 07/20/2020 09:10 JCMSM-4500-NH3C 315mg/LNitrate+Nitrite-N ,100 07/17/2020 13:55 BW14500NO3F-2011 2.6s.u.pH ,07/23/2020 04:17 JSL9045D Pauric McGroary Page 3 of 6 20-298-0003 Account Number 46260 Report Number CF Industries Diane Diks 100 Farmers Chemical Rd Suite 400 Cofield, NC 27922 Send To: 94530 Analysis Result Quantitation Limit Method Date and Time Test Started Analyst Lab Number: 73996 Sample ID:94530 Project: 10/20/2020Date Sampled: 10/22/2020 B63722Purchase Order: Date Received: REPORT OF ANALYSIS Report Date:11/02/2020 235mg/LTotal Kjeldahl Nitrogen ,10.0 10/26/2020 09:30 JCMSM-4500-NH3C-TKN 2.91mg/LPhosphorus,0.100 10/28/2020 23:26 TJS6010D 33.4mg/LPotassium,0.500 10/30/2020 21:43 JADS6010D 59.1mg/LCalcium,0.500 10/29/2020 18:43 JADS6010D 18.8mg/LMagnesium,0.100 10/28/2020 23:26 TJS6010D 32.5mg/LSodium,0.500 10/28/2020 23:26 TJS6010D 1.10mg/LAluminum,0.100 10/28/2020 23:26 TJS6010D 234mg/LAmmonia Nitrogen ,2.00 10/26/2020 09:00 JCMSM-4500-NH3C 225mg/LNitrate+Nitrite-N ,100 10/26/2020 11:56 BW14500NO3F-2011 6.9s.u.pH ,10/26/2020 12:00 JCM9045D Pauric Mc Groary Ph.D., CPAg Page 3 of 7 2020 Application Summary and Field Loading Rate Reports FARM FIELD APPL.ACRES TOTAL GAL'S./IN/PAN NAME NO.DATE UTILIZED GALLONS ACRE ACRE (lbs/ac) Q3-20 289,000.00 7,153.47 0.26 26.42 Q4-20 298,000.00 7,376.24 0.27 21.07 2 Q4-20 67.20 820,000.00 12,202.38 0.45 34.86 Q3-20 340,000.00 8,212.56 0.30 21.69 Q4-20 518,000.00 12,512.08 0.46 35.74 42 Q1-20 93.50 2,096,000.00 22,417.11 0.83 79.19 43 Q1-20 17.70 556,000.00 31,412.43 1.16 101.16 44 Q1-20 29.20 347,000.00 11,883.56 0.44 38.27 68 Q4-20 58.00 264,000.00 5,413.79 0.20 15.47 Q1-20 427,000.00 6,909.39 0.25 22.25 Q2-20 1,096,000.00 17,734.63 0.65 57.11 73 Q2-20 74.90 838,000.00 11,188.25 0.41 36.03 1 Q3-20 17.60 622,000.00 35,340.91 1.30 100.69 2 Q3-20 17.50 444,000.00 25,371.43 0.93 67.73 3 Q3-20 25.10 694,000.00 27,649.40 1.02 73.03 8 Q3-20 9.20 221,000.00 24,021.74 0.88 88.71 9 Q3-20 9.90 245,000.00 24,747.47 0.91 91.39 10 Q3-20 1.70 73,200.00 43,058.82 1.59 159.01 11 Q3-20 3.70 122,000.00 32,972.97 1.21 121.76 12 Q3-20 3.60 173,800.00 48,277.78 1.78 178.28 Q3-20 319,000.00 36,666.67 1.35 135.40 Q4-20 127,000.00 14,597.70 0.54 53.91 14 Q3-20 7.00 248,000.00 35,428.57 1.30 130.83 15 Q4-20 17.40 808,000.00 46,436.78 1.71 156.63 16 Q3-20 18.90 799,000.00 42,275.13 1.56 156.11 18 Q3-20 7.40 325,000.00 43,918.92 1.62 162.18 2 Q2-20 11.90 287,000.00 24,117.65 0.89 77.67 3 Q2-20 15.10 320,000.00 21,192.05 0.78 68.25 4 Q2-20 13.60 344,000.00 25,294.12 0.93 81.46 6 Q2-20 14.60 385,000.00 26,369.86 0.97 84.92 7 Q2-20 5.90 38,000.00 6,440.68 0.24 20.74 TOTALS 692.9 14,484,000 3,426,000 3,308,000 4,915,000 2,835,000 Total Gallons Applied 14,484,000 GROUNDWATER RECOVERED 2020 TO HOLDING LAGOON 3,879,300 3,354,600 4,823,800 2,654,600 Total Gallons Recovered 14,712,300 40.40 41.40 61.80 8.70 C.F. NITROGEN Site 11 STEVEN BURGESS Site 27 WALTER PERRY Site 28 WILLIAM WARD, JR. Site 33 1 3 71 13 LAND APPLICATIONS 2020 First Quarter First Quarter Second Quarter Third Quarter Fourth Quarter Second Quarter Third Quarter Fourth Quarter 2020 APPLICATION SUMMARY CF NITROGEN, INC. NITROGEN ENRICHED GROUNDWATER PERMIT No. WQ0012404 NITROGEN ENRICHED GROUNDWATER SUMMARY CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: CF Nitrogen, Inc. OPERATOR: Granville Farms, Inc. RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 40.4 Crop: Fescue Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 1 Q3-20 40.4 289,000 7,153 0.26 26.42 0.11 2.02 Site No. 11 Q4-20 40.4 298,000 7,376 0.27 21.07 0.18 2.06 Annual Totals 587,000 14,530 0.54 47.49 0.29 4.08 1/Z.- (Sig iez a of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information. including the possibility of Imes and imprisonment for knowing violations." 147 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: CF Nitrogen, Inc. OPERATOR: Granville Farms, Inc. RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 67.2 Crop: Fescue Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 2 Q4-20 67.2 820,000 12,202 0.45 34.86 0.30 3.40 Site No. 11 Annual Totals 820,000 12,202 0.45 34.86 0.30 3.40 2- ll 2 1 (Si a of Land Applier) Date 147 RYE Limit (lbs./acre/year) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: CF Nitrogen, Inc. OPERATOR: Granville Farms, Inc. RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 41.4 Crop: Fescue Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 3 Q3-20 41.4 340,000 8,213 0.30 21.69 0.10 2.26 Site No. 11 Q4-20 41.4 518,000 12,512 0.46 35.74 0.30 3.49 Annual Totals 858,000 20,725 0.76 57.43 0.40 5.75 147 RYE Limit (lb s ./acre/y ear) (Sid . iur of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres: 93.5 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 42 Q1-20 93.5 2,096,000 22,417 0.83 79.19 0.42 6.53 Site No. 27 Annual Totals 2,096,000 22,417 0.83 79.19 0.42 6.53 91 RYE Limit (lb s ./acre/y ear) (Si _ of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres: 17.7 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Norfolk - NoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 43 Q1-20 17.7 556,000 31,412 1.16 101.16 0.55 8.36 Site No. 27 Annual Totals 556,000 31,412 1.16 101.16 0.55 8.36 e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 123 RYE Limit (lb s ./acre/y ear) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres: 29.2 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 44 Q1-20 29.2 347,000 11,884 0.44 38.27 0.21 3.16 Site No. 27 Annual Totals 347,000 11,884 0.44 38.27 0.21 3.16 2/0- (. e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 91 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Martha Pearlman OPERATOR: RESIDUAL SOURCE: Permitted Acres: 58 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Goldsboro - GoA FIELD DATE ACRES UTII iZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 68 Q4-20 58 264,000 5,414 0.20 15.47 0.13 1.51 Site No. 27 Annual Totals 264,000 5,414 0.20 15.47 0.13 1.51 136 RYE Limit (lbs./acre/year) (Sig ui of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William E. Davis OPERATOR: RESIDUAL SOURCE: Permitted Acres: 61.8 Nitrogen Enriched Groundwater Crop: Wheat Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 71 Q1-20 61.8 427,000 6,909 0.25 22.25 0.12 1.84 Site No. 27 Q2-20 61.8 1,096,000 17,735 0.65 57.11 0.31 4.72 Annual Totals 1,523,000 24,644 0.91 79.36 0.43 6.56 91 RYE Limit (lb s ./acre/y ear) (Si e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William E. Davis OPERATOR: RESIDUAL SOURCE: Permitted Acres: 74.9 Nitrogen Enriched Groundwater Crop: Soybeans Predominant Soil: Norfolk - NoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 73 Q2-20 74.9 838,000 11,188 0.41 36.03 0.20 2.98 Site No. 27 Annual Totals 838,000 11,188 0.41 36.03 0.20 2.98 l (Sid""' e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 17.6 Crop: Corn Predominant Soil: Norfolk - NoA FIELD DATE ACRFS UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 1 Q3-20 17.6 499,000 28,352 1.04 74.89 0.33 7.81 Site No. 28 Annual Totals! 499,000 28,352 1.04 74.89 0.33 7.81 131 RYE Limit (lbs./acre/year) (Sie of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 17.5 Crop: Corn Predominant Soil: Norfolk - NoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 2 Q3-20 17.5 444,000 25,371 0.93 67.73 0.30 6.99 Site No. 28 Annual Totals 444,000 25,371 I 0.93 67.73 0.30 6.99 t /a I (Side of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 131 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 25.1 Crop: Corn Predominant Soil: Norfolk - NoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 3 Q3-20 25.1 686,125 27,336 1.01 76.35 0.33 7.56 Site No. 28 Annual Totals 686,125 27,336 1.01 76.35 0.33 7.56 2 f ti/Z. t 131 RYE Limit (lb s ./acre/y ear) (due of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 9.2 Crop: Soybeans Predominant Soil: Goldsboro - GoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 8 Q3-20 9.2 221,000 24,022 0.88 88.71 0.36 6.80 Site No. 28 Annual Totals 221,000 24,022 0.88 88.71 0.36 6.80 200 RYE Limit (lbs./acre/year) (Si at it e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 9.9 Crop: Soybeans Predominant Soil: Goldsboro - GoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 9 Q3-20 9.9 245,000 24,747 0.91 91.39 0.37 7.00 Site No. 28 Annual Totals 245,000 24,747 0.91 91.39 0.37 7.00 (Sigoatae of Land Applier) Date 200 RYE Limit (lb s ./acre/year) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fmes and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 1.7 Crop: Soybeans Predominant Soil: Goldsboro - GoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 10 Q3-20 1.7 73,200 43,059 1.59 159.01 0.64 12.18 Site No. 28 Annual Totals 73,200 43,059 1.59 159.01 0.64 12.18 STs- 'L/ 11/2 t 200 RYE Limit (lb s ./acre/y ear) (Sie of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 3.7 Crop: Soybeans Predominant Soil: Craven - CrB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 11 Q3-20 3.7 122,000 32,973 1.21 121.76 0.49 9.33 Site No. 28 - Annual Totals 122,000 32,973 1.21 121.76 0.49 9.33 200 RYE Limit (lbs./acre/year) (Sig e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 3.6 Crop: Soybeans Predominant Soil: Craven - CrB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PERACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 12 Q3-20 3.6 173,800 48,278 1.78 178.28 0.72 13.66 Site No. 28 Annual Totals 173,800 48,278 1.78 178.28 0.72 13.66 21 (Sigre of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: John Lock Mitchell OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 8.7 Crop: Soybeans Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (1bs/ac) PAN P K 13 Q3-20 8.7 319,000 36,667 1.35 135.40 0.54 10.37 Site No. 28 Q4-20 8.7 127,000 14,598 0.54 53.91 0.22 4.13 Annual Totals 446,000 51,264 1.89 189.31 0.76 14.50 L1 e of Land Applier) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Limit (lb s ./acre/y ear) Date CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: John Lock Mitchell OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 7 Crop: Soybeans. Predominant Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 14 Q3-20 7 248,000 35,429 1.30 130.83 0.53 10.02 Site No. 28 Annual Totals 248,000 35,429 1.30 130.83 0.53 10.02 (Sighai rre of Land Applier) Date 200 RYE Limit (Ibs./acre/year) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Berry Perry, John Mitchell, Eleanor Lane, Penny OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 17.4 Crop: Soybeans Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (1bs/ac) PAN P K 15 Q4-20 17.4 808,000 46,437 1.71 156.63 0.86 13.06 Site No. 28 Annual Totals 808,000 46,437 1.71 156.63 0.86 13.06 54A- (Suture of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Limit (lbs./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: John Mitchell, Eleanor Lane, Penny Beasley, Ken OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 18.9 Crop: Soybeans Predominant Soil: Conetoe - CoB FIELD DATE ACRES UTILLZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 16 Q3-20 18.9 799,000 42,275 1.56 156.11 0.63 11.96 Site No. 28 Annual Totals 799,000 42,275 1.56 156.11 0.63 11.96 ZI (Sie of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 200 RYE Limit (lb s ./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: Bettt Everette Perry OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 7.4 Crop: Soybeans Predominant Soil: Craven - CrA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (Ibs/ac) PAN P K 18 Q3-20 7.4 325,000 43,919 1.62 162.18 0.65 12.42 Site No. 28 Annual Totals 325,000 43,919 1.62 162.18 I 0.65 12.42 200 RYE Limit (lb s./acre/year) (Si�ranlJre of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 11.9 Crop: Fescue Predominant Soil: Craven - CrC2 FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 2 Q2-20 11.9 287,000 24,118 0.89 77.67 0.42 6.42 Site No. 33 Annual Totals 287,000 24,118 0.89 77.67 0.42 6.42 Z�II/Z ure of Land Applier) Date 144 RYE Limit (lbs./acre/year) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 15.1 Crop: Fescue Predominant Soil: Norfolk - NoB FIELD DATE ACRFS UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 3 Q2-20 15.1 320,000 21,192 0.78 68.25 0.37 5.64 Site No. 33 Annual Totals 320,000 21,192 0.78 68.25 0.37 5.64 tl e of Land Applier) Date 158 RYE Limit (lbs./acre/year) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 13.6 Crop: Fescue Predominant Soil: Norfolk - NoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (1bs/ac) PAN P K 4 Q2-20 13.6 344,000 25,294 0.93 81.46 0.44 6.73 Site No. 33 Annual Totals 344,000 25,294 0.93 81.46 0.44 6.73 158 RYE Limit (lbs ./acre/y ear) Z/iIZ( (Sip ' e of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 14.6 Crop: Fescue Predominant Soil: Norfolk - NoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 6 Q2-20 14.6 385,000 26,370 0.97 84.92 0.46 7.02 Site No. 33 Annual Totals 385,000 26,370 0.97 84.92 0.46 7.02 Z/I(2( (Sigefure of Land Applier) Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 158 RYE Limit (lb s ./acre/year) CF NITROGEN, INC. - TUNIS, NORTH CAROLINA S&ME, INC. Field Loading Rate Report - Nitrogen Enriched Groundwater PERMIT # WQ0012404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 5.9 Crop: Fescue Predominant Soil: Craven - CrB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre in/ac Nutrients (lbs/ac) PAN P K 7 Q2-20 5.9 38,000 6,441 0.24 20.74 0.11 1.71 Site No. 33 Annual Totals 38,000 6,441 0.24 20.74 0.11 1.71 2-NZ- I (Si of Land Applier) Date 144 RYE Limit (lbs./acre/year) "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Field Application Summaries GRANVILLE FARMS, INC.CLIENT: FIELD APPLICATION SUMMARY PERMIT # WQ0012404 2020 APPLICATION YEAR APPLICATION METHOD: Surface Site:11 FIELD 1 2 3 ACRES 40.4 67.2 41.4 Crop fescue fescue fescue 7/4/2020 - - 45,000 7/5/2020 - - 39,000 7/9/2020 - - 138,000 7/10/2020 - - 118,000 7/13/2020 150,000 - - 7/14/2020 139,000 - - 10/27/2020 - 123,000 - 10/28/2020 - 123,000 - 10/29/2020 - 78,000 - 11/9/2020 155,000 - - 11/10/2020 - - 148,000 11/11/2020 - - 123,000 11/18/2020 143,000 - - 11/19/2020 - 124,000 - 11/20/2020 - - 123,000 11/23/2020 - 124,000 - 11/24/2020 - 124,000 - 11/25/2020 - 124,000 - 12/3/2020 - - 124,000 Totals 587,000 820,000 858,000 Q1-2020 - - - Q2-2020 - - - Q3-2020 289,000 - 340,000 Q4-2020 298,000 820,000 518,000 CF NITROGEN, INC. Granville Farms GRANVILLE FARMS, INC.CLIENT: CF NITROGEN, INC. FIELD APPLICATION SUMMARY PERMIT # WQ0012404 2020 APPLICATION YEAR APPLICATION METHOD: Surface Site:27 FIELD 42 43 44 68 71 73 ACRES 93.5 17.7 29.2 58 61.8 74.9 CROP wheat wheat wheat wheat wheat soybeans 1/2/2020 111,000 1/6/2020 87,000 1/7/2020 74,000 1/9/2020 116,000 1/10/2020 106,000 1/20/2020 55,000 1/21/2020 86,000 1/22/2020 43,000 1/23/2020 88,000 1/24/2020 61,000 1/27/2020 79,000 1/28/2020 80,000 1/29/2020 93,000 1/30/2020 86,000 1/31/2020 78,000 2/3/2020 85,000 2/4/2020 81,000 2/5/2020 71,000 2/10/2020 68,000 2/11/2020 6,000 2/18/2020 62,000 2/26/2020 6,000 3/2/2020 86,000 3/3/2020 86,000 3/4/2020 92,000 3/5/2020 99,000 3/9/2020 111,000 3/10/2020 126,000 3/12/2020 93,000 3/13/2020 88,000 3/14/2020 99,000 3/16/2020 88,000 3/17/2020 62,000 3/18/2020 88,000 3/19/2020 87,000 3/20/2020 88,000 3/24/2020 84,000 3/27/2020 142,000 3/28/2020 74,000 3/30/2020 125,000 3/31/2020 86,000 4/2/2020 118,000 4/3/2020 79,000 4/6/2020 41,000 4/7/2020 84,000 4/9/2020 89,000 4/10/2020 84,000 4/16/2020 76,000 4/17/2020 45,000 4/22/2020 34,000 4/25/2020 43,000 4/27/2020 135,000 4/28/2020 86,000 4/29/2020 123,000 4/30/2020 59,000 5/4/2020 86,000 5/5/2020 85,000 5/7/2020 104,000 5/8/2020 118,000 5/11/2020 80,000 5/12/2020 117,000 5/13/2020 115,000 5/14/2020 97,000 5/15/2020 36,000 12/4/2020 75,000 12/10/2020 75,000 12/11/2020 63,000 12/30/2020 44,000 12/31/2020 7,000 Totals 2,096,000 556,000 347,000 264,000 1,523,000 838,000 Q1-2020 2,096,000 556,000 347,000 - 427,000 - Q2-2020 - - - - 1,096,000 838,000 Q3-2020 - - - - - - Q4-2020 - - - 264,000 - - Steven Burgess GRANVILLE FARMS, INC.CLIENT: CF NITROGEN, INC. FIELD APPLICATION SUMMARY PERMIT # WQ0012404 2020 APPLICATION YEAR APPLICATION METHOD: Surface Site:28 FIELD 1 2 3 8 9 10 11 12 13 14 15 16 18 ACRES 17.6 17.5 25.1 9.2 9.9 1.7 3.7 3.6 8.7 7 17.4 18.9 7.4 CROP corn corn corn soybeans soybeans soybeans soybeans soybeans soybeans soybeans soybeans soybeans soybeans 7/15/2020 139,000 7/16/2020 152,000 7/17/2020 140,000 7/18/2020 68,000 7/19/2020 75,000 7/20/2020 146,000 7/21/2020 126,000 7/22/2020 99,125 7/27/2020 89,000 7/28/2020 151,000 7/29/2020 135,000 7/30/2020 148,000 7/31/2020 149,000 8/3/2020 6,000 8/11/2020 6,000 8/18/2020 12,000 8/19/2020 87,000 8/20/2020 122,000 8/21/2020 122,000 8/25/2020 123,000 8/26/2020 122,000 8/27/2020 73,200 48,800 8/28/2020 125,000 8/31/2020 123,000 9/1/2020 149,000 9/2/2020 117,000 9/3/2020 149,000 9/4/2020 136,000 9/8/2020 125,000 9/14/2020 85,000 9/15/2020 120,000 9/16/2020 120,000 9/21/2020 125,000 9/22/2020 123,000 9/23/2020 122,000 9/24/2020 120,000 9/25/2020 53,000 9/29/2020 24,000 10/6/2020 8,000 10/7/2020 119,000 10/8/2020 123,000 10/9/2020 122,000 10/15/2020 62,000 10/16/2020 99,000 10/19/2020 93,000 10/20/2020 62,000 10/21/2020 63,000 10/22/2020 87,000 10/23/2020 97,000 Totals 499,000 444,000 686,125 221,000 245,000 73,200 122,000 173,800 446,000 248,000 808,000 799,000 325,000 Q1-2020 - - - - - - - - - - - - - Q2-2020 - - - - - - - - - - - - - Q3-2020 499,000 444,000 686,125 221,000 245,000 73,200 122,000 173,800 319,000 248,000 - 799,000 325,000 Q4-2020 - - - - - - - - 127,000 - 808,000 - - Walter Perry GRANVILLE FARMS, INC.CLIENT: CF NITROGEN, INC. FIELD APPLICATION SUMMARY PERMIT # WQ0012404 2020 APPLICATION YEAR APPLICATION METHOD: Surface Site:33 FIELD 2 3 4 6 7 ACRES 11.9 15.1 13.6 14.6 5.9 CROP fescue fescue fescue fescue fescue 5/26/2020 153,000 5/27/2020 134,000 6/2/2020 101,000 6/3/2020 113,000 6/4/2020 106,000 6/5/2020 112,000 6/8/2020 120,000 6/9/2020 112,000 6/10/2020 75,000 6/11/2020 104,000 6/24/2020 113,000 6/25/2020 93,000 6/26/2020 38,000 Totals 287,000 320,000 344,000 385,000 38,000 Q1-2020 - - - - - Q2-2020 287,000 320,000 344,000 385,000 38,000 Q3-2020 - - - - - Q4-2020 - - - - - William Ward, Jr. Attachment B ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 29-1 Ronald Byrd Bertie 36°09'30"-76°57'54"6.7 Leaf—Lf 29-2 Ronald Byrd Bertie 36°09'31"-76°58'02"2.4 Leaf— Lf 29-3 Ronald Byrd Bertie 36°09'31"-76°58'09"6 Exum — ExA 29-4 Ronald Byrd Bertie 36°09'27"-76°58'09"9.8 Exum — ExA 29-5 Ronald Byrd Bertie 36°09'27"-76°58'20"11.1 Exum—ExA 29-6 Ronald Byrd Bertie 36°09'25"-76°58'34"3.1 Leaf— Lf 29-7 Ronald Byrd Bertie 36°09'24"-76°58'10"4.6 Granthum G 29-8 Ronald Byrd Bertie 36°09'21"-76°58'05"10 Granthum Gt 29-9 Ronald Byrd Bertie 36°09'24"-76°58'00"0.5 Exum — ExA 29-10 Ronald Byrd Bertie 36°09'24"-76°57'56"4.0 Exum — ExB 30-1 Kendred C. Williams, Jr.Bertie 36°08'15"-76°57'12"15.4 Exum — ExA 30-2 Kendred C. Williams, Jr.Bertie 36°08'22"-76°57'13"6.1 Exum— ExA 30-3 Kendred C. Williams, Jr.Bertie 36°12'47"-76°56'35"1.3 Craven — CrA 30-4 Kendred C. Williams, Jr.Bertie 36°12'45"-76°56'22"26.3 Norfo k NoB 30-5 Kendred C. Williams, Jr.Bertie 36°12'43"-76°56'07"32.4 Craven — CrB 30-6 Kendred C. Williams, Jr.Bertie 36°12'31"-76°56'09"9.0 Craven CrB 30-7 Kendred C. Williams, Jr.Bertie 36°12'38"-76°56'25"12.9 Craven CrB 30-8 Kendred C. Williams, Jr.Bertie 36°12'40"-76°56'34"6.5 Craven — CrB 30-9 Kendred C. Williams, Jr.Bertie 36°12'41"-76°56'49"16.4 Norfolk — NoA 30-10 Kendred C. Williams, Jr.Bertie 36°12'45"-76°56'47"3.7 Norfolk —NoA 30-11 Kendred C. Williams, Jr.Bertie 36°12'48"-76°56'45"1.4 Norfolk — NoB 30-12 Kendred C. Williams, Jr.Bertie 36°12'48"-76°56'39"1.5 Norfolk — NoA 30-13 Kendred C. Williams, Jr.Bertie 36°12'51"-76°56'41"5.1 Lenoir — Ln WQ0012404 Version: 3.0 Attachment B Page 1 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 30-14 Kendred C. Williams, Jr.Bertie 36°12'56"-76°56'38"0.5 Lenoir—Ln 30-15 Kendred C. Williams, Jr.Bertie 36°13'03"-76°56'36"8.9 Leaf— Lf 30-16 Kendred C. Williams, Jr.Bertie 36°13'09"-76°56'31"4.5 Craven— CrA 30-17 Kendred C. Williams, Jr.Bertie 36°13'06"-76°57'03"28.1 Craven—CrA 30-18 Kendred C. Williams, Jr.Bertie 36°12'55"-76°57'00"20.9 Craven — CrA 30-19 Kendred C. Williams, Jr.Bertie 36°12'54"-76°56'48"9.3 Goldsboro - GoA 30-20 Kendred C. Williams, Jr.Bertie 36°12'13"-76°56'51"10.7 Craven — CrA 30-21 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'23"-76°56'48"7.0 Lenoir — Ln 30-22 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'16"-76°56'53"7.5 Craven — CrA 30-23 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'16"-76°56'59"9.2 Craven — CrA 30-24 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'18"-76°57'02"4 Craven — CrA 30-25 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'19"-76°57'05"1.5 Craven — CrA 30-26 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'26"-76°57'12"4.3 Craven — CrA 30-27 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'16"-76°57'08"4.0 Craven — CrA 30-28 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'13"-76°57'09"5.1 Craven— CrA 30-29 C.S. Hollomon, Jr.Kendred C. Williams, Jr.Bertie 36°12'08"-76°57'07"13.3 Craven — CrA 30-30 Kendred C. Williams, Jr.Bertie 36°10'35"-76°57'25"4.5 Nahunta - Na 30-31 Kendred C. Williams, Jr.Bertie 36°10'28"-76°57'24"20.8 Exum — ExA 30-32 Kendred C. Williams, Jr.Bertie 36°10'24"-76°57'15"7.5 Goldsboro — GoA 30-33 Kendred C. Williams, Jr.Bertie 36°10'18"-76°57'19"17.8 Goldsboro — GoA 30-34 Kendred C. Williams, Jr.Bertie 36°10'18"-76°57'18"24.1 Goldsboro — GoA 30-35 Kendred C. Williams, Jr.Bertie 36°10'20"-76°57'37"0.9 Exum — ExA 30-36 David C. Powell Kendred C. Williams, Jr.Bertie 36°13'13"-76°54'33"19.9 Exum— ExA 30-37 E.M. Powell & Sons, Inc.Kendred C. Williams, Jr.Bertie 36°13'07"-76°54'26"21.2 Exum — ExA 30-38 E.M. Powell & Sons, Inc.Kendred C. Williams, Jr.Bertie 36°12'49"-76°54'30"23.4 Exum — ExA WQ0012404 Version: 3.0 Attachment B Page 2 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 30-39 E.M. Powell & Sons, Inc.Kendred C. Williams, Jr.Bertie 36°12'42"-76°54'24"25.4 Exum — ExA 30-40 T.E. Ruffin Kendred C. Williams, Jr.Bertie 36°09'22"-76°57'24"19.9 Exum — ExA 30-41 T.E. Ruffin Kendred C. Williams, Jr.Bertie 36°09'23"-76°57'37"7.0 Exum — ExA 30-42 T.E. Ruffin Kendred C. Williams, Jr.Bertie 36°09'26"-76°57'43"4.7 Exum — ExA 30-43 T.E. Ruffin Kendred C. Williams, Jr.Bertie 36°09'23"-76°57'46"7.0 Exum — ExA 30-44 James C. Askew Kendred C. Williams. Jr.Bertie 36°11'18"-76°57'21"3 Exum—ExB 30-45 James C. Askew Kendred C. Williams, Jr.Bertie 36°11'18"-76°57'17"6.3 Exum — ExB 30-46 James C. Askew Kendred C. Williams, Jr.Bertie 36°11'17"-76°57'10"12.0 Gritney — Gt 30-47 Oliver B. Balance Kendred C. Williams, Jr.Bertie 36°11'12"-76°57'08"11.6 Exum — ExA 33-17 Leonard L. Godwin William Ward Bertie 36°13'38"-77°00'05"11.2 Norfolk — NoA 33-18 Leonard L. Godwin William Ward Bertie 36°13'31"-76°59'55"11.2 Goldsboro—GoA 33-19 Ola Sanders William Ward Bertie 36°12'15"-76°56'09"16.8 Goldsboro—GoA 33-20 Ruth H. Metcalf William Ward Bertie 36°14'16"-76°54'30"3.3 Exum—ExA 33-21 Ruth H. Metcalf, et al William Ward Bertie 36°14'02"-76°54'24"12.9 Exum — ExA 33-22 Mildred Harris William Ward Bertie 36°13'53"-76°54'12"17.0 Exum — ExA 33-23 Agnes 0. Moore, et al William Ward Bertie 36°13'42"-76°54'09"10 Goldsboro — GoA County Total Bertie 653.6 3-1 Wiley B. Gillam III Hertford 36°19'51"-76°50'39"19.6 Lynchburg - Ly 3-2 Wiley B. Gillam III Hertford 36°19'44"-76°50'43"37.2 Lynchburg - Ly 3-3 Wiley B. Gillam III Hertford 36°19'45"-76°50'28"19.9 Norfolk —NoA 3-4 Wiley B. Gillam III Hertford 36°19'27"-76°48'06"18.6 Wickham — WkB 3-5 Wiley B. Gillam III Hertford 36°19'02"-76°48'02"31.9 Tarboro — TaB 6-1 Stuart Pierce Farms, Inc.Hertford 36°16'06"-76°56'20"17.0 Craven — CrA 6-2 Stuart Pierce Farms, Inc.Hertford 36°16'18"-76°56'20"67.4 Caroline — CaA 6-3 Stuart Pierce Farms, Inc.Hertford 36°16'09"-76°55'58"7.9 Caroline — CaA WQ0012404 Version: 3.0 Attachment B Page 3 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 6-4 Stuart Pierce Farms, Inc.Hertford 36°15'54"-76°56'16"10.9 Caroline — CaA 6-5 Stuart Pierce Farms, Inc.Hertford 36°15'47"-76°56'56"54.0 Caroline — CaA 6-6 Stuart Pierce Farms, Inc.Hertford 36°15'36"-76°56'34"23.3 Craven— CrB 6-7 Stuart Pierce Farms, Inc.Hertford 36°15'27"-76°56'11"42.2 Craven — CrB 6-9 Stuart Pierce Farms, Inc.Hertford 36°16'01"-76°57'17"38.9 Craven — CrA 6-10 Stuart Pierce Farms, Inc.Hertford 36°16'43"-76°55'34"107.0 Caroline — CaA 6-11A Stuart Pierce Farms, Inc.Hertford 36°15'52"-77°00'07"41.0 Craven — CrB 6-11B Stuart Pierce Farms, Inc.Hertford 36°15'41"-76°59'53"72.2 Craven — CrB 6-11C Stuart Pierce Farms, Inc.Hertford 36°15'37"-76°59'40"29.4 Craven — CrB 6-11D Stuart Pierce Farms, Inc.Hertford 36°15'24"-76°59'45"41.2 Craven—CrB 6-11E Stuart Pierce Farms, Inc.Hertford 36°15'36"-76°59'37"47.7 Craven — CrA 6-12 Stuart Pierce Farms, Inc.Hertford 36°18'30"-77°01'47"40.4 Caroline — CaA 6-13 Stuart Pierce Farms, Inc.Hertford 36°18'27"-76°54'52"41.4 Craven — CrA 6-14 Stuart Pierce Farms, Inc.Hertford 36°18'10"-76°54'59"30.9 Craven — CrA 6-15 Stuart Pierce Farms, Inc.Hertford 36°18'14"-76°55'18"48.8 Craven — CrB 6-16 Stuart Pierce Farms, Inc.Hertford 36°16'51"-76°45'06"46.1 Bonneau — BoB 6-17 Stuart Pierce Farms, Inc.Hertford 36°16'44"-76°45'38"41.9 Bonneau — BoB 6-18 Stuart Pierce Farms, Inc.Hertford 36°17'04"-76°45'33"21.0 Bonneau — BoB 6-19 Stuart Pierce Farms, Inc.Hertford 36°16'33"-76 43'56"46.3 Goldsboro — GoA 6-20 Stuart Pierce Farms, Inc.Hertford 36°16'06"-76°44'18"21.4 Goldsboro — GoA 6-21 Stuart Pierce Farms, Inc.Hertford 36°17'50"-76°43'10"70.8 Bonneau — BoB 6-22 Stuart Pierce Farms, Inc.Hertford 36°16'19"-77°02'38"56.4 Craven — CrA 6-23 Stuart Pierce Farms, Inc.Hertford 36°16'32"-77°02'41"94.9 Craven — CrA 6-24 Stuart Pierce Farms, Inc.Hertford 36°16'20"-77°02'23"41.6 Lenoir — Ln WQ0012404 Version: 3.0 Attachment B Page 4 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 9-2 Gray Pierce, et al Hertford 36°18'20"-76°51'10"18.5 Norfolk — NoA 9-3 Gray Pierce Hertford 36°18'14"-76°51'20"8.5 Norfolk — NoA 9-5 Carlyle Archer, et al Gray Pierce Hertford 36°18'13"-76°51'37"22.8 Norfolk — NoA 9-6 Gray Pierce Hertford 36°18'15"-76°51'46"4.5 Goldsboro GoA 9-7 Gray Pierce Hertford 36°18'07"-76°51'28"16.2 Norfolk —NoA 9-8 Gray Pierce Hertford 36°18'03"-76°51'36"11.6 Norfolk — NoA 9-9 Gray Pierce Hertford 36°17'15"-76°51'30"18.1 Craven — CrB 9-10 Gray Pierce Hertford 36°17'59"-76°51'30"5.6 Craven—CrB 9-11 Gray Pierce Hertford 36°17'45"-76°51'19"10.6 Craven — CrB 9-12 Gray Pierce Hertford 36°17'48"-76°51'05"8.6 Conetoe— CoB 9-14 Gray Pierce Hertford 36°17'50"-76°50'58"6.7 Tarboro—TaB 9-15 Gray Pierce Hertford 36°17'58"-76°50'50"7.7 Tarboro —TaB 9-16 Gray Pierce Hertford 36°17'58"-76°51'22"1.5 Craven — CrB 9-17 Gray Pierce Hertford 36°18'01"-76°51'21"3.6 Craven — CrB 9-18 Gray Pierce Hertford 36°17'50"-76°51'25"14.6 Wickham — WkA 9-19 Gray Pierce Hertford 36°17'59"-76°51'10"3.7 Tarboro—TaB 9-20 Gray Pierce Hertford 36°18'06"-76°51'13"3.9 Bonneau — BoB 9-21 Gray Pierce Hertford 36°17'38"-76°51'49"6.0 Craven—CrA 9-22 Gray Pierce Hertford 36°17'45"-76°51'49"9.6 Lenoir — Ln 9-24 Gray Pierce Hertford 36°17'47"-76°51'43"13.5 Craven — CrA 9-26 Gray Pierce Hertford 36°18'34"-76°51'45"27.0 Craven — CrA 9-27 Gray Pierce Hertford 36°19'12"-76°51'48"24.9 Tarboro — TaB 9-28 Gray Pierce Hertford 36°18'51"-76°52'0I"15.0 Wickham — WkA 9-29 Gray Pierce Hertford 36°18'47"-76°51'57"5.7 Wickham — WkA 9-30 Gray Pierce Hertford 36°18'44"-76°51'53"11.9 Wickham — WkA WQ0012404 Version: 3.0 Attachment B Page 5 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 9-31 Gray Pierce, Merle Jones Gray Pierce Hertford 36°17'48"-76°52'45"11.4 Craven — CrA 9-32 Merle Jones Gray Pierce Hertford 36°17'34"-76°52'36"17 6 Lenoir — Ln 9-33 Gray Pierce Hertford 36°17'37"-76°52'10"16.7 Craven — CrA 9-34 Gray Pierce Hertford 36°17'52"-76°53'00"8 Craven — CrA 9-35 Gray Pierce Hertford 36°17'58"-76°52'55"13 Craven — CrA 9-37 R.C. Kennington Gray Pierce Hertford 36°18'33"-76°52'45"16 Craven — CrB 9-38 R.C. Kennington Gray Pierce Hertford 36°18'27"-76°52'32"8 Craven — CrB 9-40 Gray Pierce Hertford 36°19'21"-76°53'33"11.2 Wickham — WkB 9-41 Gray Pierce Hertford 36°19'33"-76°53'28"12.4 Wickham — WkA 9-42 Gray Pierce Hertford 36°19'23"-77°01'20"26.4 Caroline — CaA 9-43 Gray Pierce Hertford 36°19'16"-77°00'38"39.4 Caroline — CaA 9-45 Gray Pierce Hertford 36°19'11"-77°06'56"73.7 Craven — CrA 9-46A Gray Pierce Hertford 36°19'19"-77°07'49"36.7 Craven — CrA 9-46B Gray Pierce Hertford 36°19'15"-77°07'27"42.5 Craven — CrA 9-47 Gray Pierce Hertford 36°19'33"-77°08'09"18.8 Craven — CrA 9-48 Gray Pierce Hertford 36°18 32'-77°06'31"45.1 Craven CrA 9-50 Gray Pierce Hertford 36°18'53"-77°06'43"63.8 Craven CrA 9-52 Gray Pierce Hertford 36°18'57"-77°07'03"27.4 Craven CrA 9-53 Gray Pierce Hertford 36°19'06"-77°07'13"26.7 Craven — CrB 10-1 J.H. Drewry, III Hertford 36°32'36"-77°09'01"7.8 Tarboro — TaB 10-2 J.H. Drewry, III Hertford 36°32'30"-77°08'36"34.1 Wickham — WkA 10-3 J.H. Drewry, III Hertford 36°32'17"-77°08'33"67.7 Autryville — AuB 10-4 J.H. Drewry, III Hertford 36°32'35"-77°08'16"6.9 Lynchburg — Ly 10-5 J.H. Drewry, III Hertford 36°32'58"-77°08'17"20.0 Norfolk — NoA 10-6 J.H. Drewry, III Hertford 36°52'21"-77°07'56"35.0 Craven — CrA WQ0012404 Version: 3.0 Attachment B Page 6 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 10-7 J.H. Drewry, III Hertford 36°32'17"-77°08'07"35.4 Norfolk—NoA 10-8 J.H. Drewry, III Hertford 36°32'15"-77°08'18"42.3 Norfolk—NoA 10-9 J.H. Drewry, III Hertford 36°32'24"-77°07'46"12.3 Autryville — AuB 10-10 J.H. Drewry, III Hertford 36°32'27"-77°07'41"26.3 Bonneau — BoB 10-11 J.H. Drewry, III Hertford 36°32'01"-77°07'07"4.9 Norfolk—NoA 11-1 CF Industries, Inc.Granville Farms, Inc.Hertford 36°22'19"-76°52'10"40.4 Craven CrA 11-2 CF Industries, Inc.Granville Farms, Inc.Hertford 36°22'17"-76°51'47"67.2 Craven—CrA 11-3 CF Industries, Inc.Granville Farms, Inc.Hertford 36°22'01"-76°51'54"41.4 Craven — CrA 12-1 Douglas R. White Tuscarora Greens Hertford 36°23'03"-76°54'59"8.3 Lenoir — Ln 12-2 Douglas R. White Tuscarora Greens Hertford 36°22'57"-76°55'11"8.8 Lenoir — Ln 12-3 Douglas R. White Tuscarora Greens Hertford 36°22'40"-76°54'57"6.3 Craven — CrB 12-4 Douglas R. White Tuscarora Greens Hertford 36°22'43"-76°54'46"30.0 Craven — CrA 12-5 Douglas R. White Tuscarora Greens Hertford 36°22'33"-76°54'51"5.0 Craven — CrA 12-6 Douglas R. White Tuscarora Greens Hertford 36°22'55 -76°54'52"18.0 Craven—CrA 23-1 Johnny Powell Hertford 36°17'01"-76°44'02"24.9 Norfolk —NoA 23-2 Johnny Powell Hertford 36°16'42"-76°45'12"13.1 Norfolk — NoA 23-3 Thaddeus F. Scott Johnny Powell Hertford 36°17'46"-76°45'44"39.1 Norfolk—NoA 23-4 Thaddeus F. Scott Johnny Powell Hertford 36°17'55"-76°45'44"22.0 Norfolk—NoA 23-5 Johnny Powell Hertford 36°18'19"-76°47'17"27.7 Norfolk — NoB 23-6 Johnny Powell Hertford 36°18'02"-76°50'25"19.9 Conetoe— CoB 23-7A Johnny Powell Hertford 36°17'42"-76°49'32"33.5 Craven — CrA 23-7B Johnny Powell Hertford 36°18'03"-76°49'10"13.2 Bonneau — BoB 23-8 Johnny Powell Hertford 36°17'12"-76°53'00"29.8 Caroline — CaA 23-9 Johnny Powell Hertford 36°19'50"-76°51'05"19.8 Craven—CrA 23-10 Johnny Powell Hertford 36°20'26"-76°49'47"15.8 Craven — CrA WQ0012404 Version: 3.0 Attachment B Page 7 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 23-12 Johnny Powell Hertford 36°22'27"-76°54'50"26.3 Craven — CrA 23-13 Johnny Powell Hertford 36°21'38"-76°54'02"20.5 Craven — CrA 23-14 Johnny Powell Hertford 36°21'46"-76°54'23"11.7 Craven — CrA 23-15 Johnny Powell Hertford 36°22'38"-76°56'02"19.0 Norfolk—NoA 23-16 Johnny Powell Hertford 36°18'35"-76°55'42"45.0 Craven — CrB 24-2 Chester Powell Hertford 36°19'15"-76°50'40"14.6 Norfolk — NoA 24-3 Chester Powell Hertford 36°19'28"-76°50'34"11.6 Wickham - WkB 24-4 Chester Powell Hertford 369 8'56"-76°48'52"10.8 Goldsboro — GoA 24-5 Chester Powell Hertford 36°18'43"-76°48'52"13.0 Bonneau — BoB 24-6 Chester Powell Hertford 36°20'24"-76°51'54"13.5 Craven — CrA 24-7 Chester Powell Hertford 36°20'17"-76°51'46"3.6 Craven — CrA 24-8 Chester Powell Hertford 36°15'50"-76°56'33"6.3 Lenoir— Ln 24-9 Chester Powell Hertford 36°15'50"-76°53'54"12.7 Craven — CrA 24-10 Shirley Deramus Chester Powell Hertford 36°18'04"-76°43'20"6.1 Bonneau — BoB 24-11 Shirley Deramus Chester Powell Hertford 36°18'09"-76°43'13"10.5 Goldsboro — GoA 24-13 Chester Powell Hertford 36°15'23"-76°49'06"14.8 Craven — CrA 25-1 Tommy Castelow Hertford 36°21'58"-76°53'54"39.8 Caroline — CaA 25-2 Tommy Castelow Hertford 36°19'46"-76°49'06"9.3 Norfolk — NoA 25-3 Tommy Castelow Hertford 36°20'02"-76°49'03"32.2 Norfolk — NoA 25-4 Tommy Castelow Hertford 36°20'17"-76°49'02"30.2 Craven — CrA 25-5 Tommy Castelow Hertford 36°20'09"-76°48'42"25.6 Craven — CrA 25-6 Tommy Castelow Hertford 36°20'00"-76°47'36"27.2 Craven — CrA 25-7 Tommy Castelow Hertford 36°21'16"-76°47'38"12.3 Craven — CrA 25-8 Tommy Castelow Hertford 36°20'43"-76°54'05"16.6 Craven — CrA 25-9 Tommy Castelow Hertford 36°20'37"-76°54'01"34.7 Craven — CrA WQ0012404 Version: 3.0 Attachment B Page 8 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 25-10 Tommy Castelow Hertford 36°20'26"-76°54'07"11.3 Craven — CrA 25-11 Tommy Castelow Hertford 36°20'25"-76°54'13"4.8 Craven — CrA 25-12 Tommy Castelow Hertford 36°20'01"-76°54'28"32.0 Craven — CrA 26-1 Beechwood Country Club Hertford 36°21'58"-77°00'38"7.9 Caroline — CaA 26-2 Beechwood Country Club Hertford 36°21'53"-77°00'47"10.5 Craven — CrB 26-3 Beechwood Country Club Hertford 36°21'37"-77°00'37"8.3 Craven — CrB 26-4 Beechwood Country Club Hertford 36°21'43"-77°00'01"18.2 Caroline — CaB 27-52 Lori S. Burgess Steven Burgess Hertford 36°25'02"-77°06'01"44.7 Norfolk — NoA 27-53 Lori S. Burgess Steven Burgess Hertford 36°24'42"-77°05'55"10.0 Norfolk—NoA 27-54 Steven Burgess Hertford 36°24'36"-77°06'06"42.7 Norfolk—NoA 27-55 Steven Burgess Hertford 36°21'18"-77°07'40"6.6 Craven — CrA 27-56 Steven Burgess Hertford 36°21'19"-77°07'31"9.8 Craven — CrA 27-57 Steven Burgess Hertford 36°21'22"-77°07'21"12 Craven — CrA 27-58 Steven Burgess Hertford 36°21'11"-77°07'17"4.5 Lenoir — Ln 27-59 Steven Burgess Hertford 36°21'08"-77°07'23"9.0 Lenoir — Ln 27-60 Steven Burgess Hertford 36°21'03"-77°07'07"2 Lenoir — Ln 27-61 Steven Burgess Hertford 36°21'04"-77°06'59"14.9 Craven — CrA 27-62 Steven Burgess Hertford 36°20'55"-77°07'02"3.1 Craven — CrA 27-63 Adam & Wendy Burgess Steven Burgess Hertford 36°21'14"-77°06'55"14.7 Craven — CrA 27-64 Adam & Wendy Burgess Steven Burgess Hertford 36°21'24"-77°06'50"29.5 Craven — CrA 28-1 Judith, Allison, & Walter Perry Hertford 36°19'31"-77°50'15"17.6 Norfolk—NoA 28-2 Judith, Allison, & Walter Perry Hertford 36°19'27"-76°50'05"17.5 Norfolk — NoA 28-3 Judith, Allison, & Walter Perry Hertford 36°19'48"-76°50'10"25.1 Norfolk — NoA 28-4 Judith, Allison, & Walter Perry Hertford 36°19'21"-76°49'51"10.8 Wickham — WkA 28-5 Judith, Allison, & Walter Perry Hertford 36°19'10"-76°49'34"9.4 Conetoe — CoB WQ0012404 Version: 3.0 Attachment B Page 9 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 28-6 Judith, Allison, & Walter Perry Hertford 36°19'24"-76°50'24"20.4 Norfolk—NoA 28-7 Judith, Allison, & Walter Perry Hertford 36°19'50"-76°51'03"16.0 Norfolk — NoA 28-8 Judith, Allison, & Walter Perry Hertford 36°19'42"-76°51'06"9.2 Goldsboro—GoA 28-9 Judith, Allison, & Walter Perry Hertford 36°19'42"-76°51'13"9.9 Goldsboro — GoA 28-10 Judith, Allison, & Walter Perry Hertford 36°19'44"-76°51'18"1.7 Goldsboro — GoA 28-11 Judith, Allison, & Walter Perry Hertford 36°19'48"-76°51'15"3.7 Craven — CrB 28-12 Judith, Allison, & Walter Perry Hertford 36°19'47"-76°51'11"3.6 Craven — CrB 28-13 John Lock Mitchell Walter Perry Hertford 36°17'42"-76°49'37"8.7 Bonneau — BoB 28-14 John Lock Mitchell Walter Perry Hertford 36°17'36"-76°49'45"7.0 Bonneau — BoB 28-15 Betty Perry, John Mitchell, Eleanor Lane, Penny Beasley, & Ken Mitchell Walter Perry Hertford 36°17'19"-76°50'11"17.4 Craven — CrA 28-16 John Mitchell, Eleanor Lane, Penny Beasley, Ken Mitchell, & Wiccacon Properties, LLC Walter Perry Hertford 36°18'02"-76°50'23"18.9 Conetoe — CoB 28-17 Margaret Hall Walter Perry Hertford 36°23'01"-76°56'51"16.9 Craven — CrA 28-18 Betty Everette Perry Walter Perry Hertford 36°17'30"-76°49'53"7.4 Craven — CrA 31-1 Ray & Linda Chamblee Hertford 36°20'42"-76°55'26"8.8 Craven — CrA 31-2 Jackie Chamblee Ray Chamblee Hertford 36°20'40"-76°55'20"9.6 Craven— CrB 31-3 Jackie Chamblee Ray Chamblee Hertford 36°20'47"-76°55'13"15.9 Craven — CrA 31-4 Ray & Linda Chamblee Hertford 36°20'43"-76°55'04"8.8 Craven — CrA 31-5 Ray & Linda Chamblee Hertford 36°17'31"-76°55'16"5.9 Goldsboro—GoA 32-1 Janice Simmons Sessoms William H. Sessoms Hertford 36°17'55"-76°48'53"7.0 Wakulla - WaB 32-2 William H. Sessoms Hertford 36°17'55"-76°48'42"30.6 Lynchburg — Ly 32-3 William H. Sessoms Hertford 36°17'27"-76°48'38"5.0 Craven — CrB 32-4 Joyce Ann Sessoms William H. Sessoms Hertford 36°18'07"-76°48'45"5.0 Bonneau — BoB 32-5 Joyce Ann Sessoms William H. Sessoms Hertford 36°17'43"-76°49'16"5.5 Lynchburg — Ly 32-6 William H. Sessoms Hertford 36°17'42"-76°49'27"2.7 Lynchburg — Ly WQ0012404 Version: 3.0 Attachment B Page 10 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 32-7 William H. & Joyce Ann Sessoms Hertford 36°17'24"-76°47'58"28.9 Goldsboro - Go 32-8 William H. & Delores Sessoms Hertford 36°17'33"-76°47'23"23.2 Norfolk — NoB 32-9 William H. & Delores Sessoms Hertford 36°17'36"-76°47'36"13.3 Norfolk —NoB 32-10 William H. & Delores Sessoms Hertford 36°17'42"-76°47'34"7.3 Norfolk —NoB 32-11 Wiccacon Properties, LLC William H. Sessoms Hertford 36°17'47"-76°49'32"4.3 Craven — CrA 32-12 Ernest Chamblee William H. Sessoms Hertford 36°15'23"-76°49'08"14.0 Craven — CrA 33-1 William W & Nellie Ward William Ward Hertford 36°14'36"-76°56'23"3.0 Caroline — CaB 33-2 William W & Nellie Ward William Ward Hertford 36°14'51"-76°56'23"11.9 Craven — CrC2 33-3 William W & Nellie Ward William Ward Hertford 36°14'47"-76°56'21"15.1 Norfolk —NoB 33-4 William W & Nellie Ward William Ward Hertford 36°14'48"-76°56'12"13.6 Norfolk — NoB 33-5 William W & Nellie Ward William Ward Hertford 36°15'10"-76°56'08"14.2 Tarboro — TaB 33-6 William W & Nellie Ward William Ward Hertford 36°14'43"-76°56'10"14.6 Norfolk — NoB 33-7 William W & Nellie Ward William Ward Hertford 36°14'37"-76°56'08"5.9 Craven — CrB 33-8 William W & Nellie Ward William Ward Hertford 36°14'35"-76°56'14"3.0 Craven—CrB 33-9 Michael A. & Deborah Spalding William Ward Hertford 36°14'23"-76°58'28"14.2 Craven — CrA 33-10 Michael A. & Deborah Spalding William Ward Hertford 36°14'28"-76°58'27"8.0 Craven — CrB 33-11 Michael A. & Deborah Spalding William Ward Hertford 36°14'26"-76°58'17"3.7 Craven - CrB 33-12 Michael A. & Deborah Spalding William Ward Hertford 36°14'21"-76°58'17"2.4 Craven — CrA 33-13 Rosa H. Sessoms William Ward Hertford Hertford 36°15'09"-77°00'47"25.0 Craven — CrA 33-14 Rosa H. Sessoms William Ward Hertford Hertford 36°15'12"-77°00'36"6.3 Leaf — Lf 33-15 Rosa H. Sessoms William Ward Hertford 36°15'15"-77°00'29"2.8 Craven—CrA 33-16 Rosa H. Sessoms William Ward Hertford 36°15'20"-76°00'31"4.2 Craven — CrA County Total Hertford 4,212.3 34-1 Nellie B. Brown Martin 35°59'36"-77°20'10"26.5 Goldsboro — GoA 34-2 Nellie B. Brown Martin 35°59'30"-77°20'17"19.1 Goldsboro — GoA WQ0012404 Version: 3.0 Attachment B Page 11 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 34-3 Nellie B Brown Martin 35°59'26"-77°20'17"3.8 Lynchburg— Ly 34-4 Nellie B Brown Martin 35°59'20"-77°20'16"27.1 Lynchburg— Ly County Total Martin 76.5 15-1 J. Elliot Stephenson Northampton 36°28'42"-77°26'06"19.2 Lynchburg— Ly 15-2 J. Elliot Stephenson Northampton 36°28'31"-77°25'43"27.3 Craven — CrA 15-3 J. Elliot Stephenson Northampton 36°28'19"-77°26'06"38.0 Caroline — CrB 15-4 J. Elliot Stephenson Northampton 36°25'47"-77°25'26"41.3 Norfolk - NoA 15-5 J. Elliot Stephenson Northampton 36°26'06"-77°25'40"71.3 Gritney — GxB 15-6 J. Elliot Stephenson Northampton 36°26'17"-77°25'44"37.1 Gritney — GxB 15-7 J. Elliot Stephenson Northampton 36°26'12"-77°24'48'13.1 Norfolk - NoA 15-8 J. Elliot Stephenson Northampton 36°26'19"-77°28'39"35.6 Goldsboro — GoA 15-9 J. Elliot Stephenson Northampton 36°26'49"-77°26'39"15.1 Gritney — GxB 15-10 J. Bentley Stephenson J. Elliot Stephenson Northampton 36°51'21"-77°26'21"14.2 Gritney — GxB 15-11 J. Bentley Stephenson J. Elliot Stephenson Northampton 36°26'44"-77°26'25"14.5 Gritney — GxB 15-12 J. Elliot Stephenson Northampton 36°26'09"-77°26'36"9.2 Gritney — GxB 15-13 J. Elliot Stephenson Northampton 36°26'03"-77°26'25"17.2 Gritney — GxB 15-14 J. Elliot Stephenson Northampton 36°26'21"-77°26'07"19.9 Gritney — GxB 15-15 J. Elliot Stephenson Northampton 36°28'18"-77°25'54"24.3 Bonneau — BoB 15-16 J. Elliot Stephenson Northampton 36°28'24"-77°25'41"22.8 Bonneau — BoB 15-17 J. Elliot Stephenson Northampton 36°28'09"-77°25'52"33.7 Craven — CrA 18-1 Thomas Williams Northampton 36°29'41"-77°07'55"12.0 Craven — CrB 18-2 Thomas Williams Northampton 36°29'52"-77°08'03"15.0 Craven — CrA 19-1W C.C. Woodard Northampton 36°30'46"-77°20'27"31.7 Norfolk—NoB 19-2W C.C. Woodard Northampton 36°40'47"-77°20'48"21.4 Norfolk —NoB 19-3W C.C. Woodard Northampton 36°30'36"-77°20'56"69.7 Norfolk — NoB WQ0012404 Version: 3.0 Attachment B Page 12 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 19-4W C.C. Woodard Northampton 36°30'27"-77°20'45"76.7 Norfolk — NoB 19-5W Cecil Whitehead C.C. Woodard Northampton 36°30'18"-77°20'50"12.8 Norfolk —NoB 19-6W Amanda Cooke, et al Cecil Whitehead Northampton 36°30'32"-77°20'33"18.6 Norfolk — NoB 19-7W C.C. Woodard Northampton 36°30'18"-77°20'10"85.6 Norfolk —NoA 19-8W C.C. Woodard Northampton 36°30'15"-77°20'29"10.9 Norfolk—NoB 19-9W C.C. Woodard Northampton 36°30'35"-77°20'21"15.7 Norfolk—NoB 19-10W C.C. Woodard Northampton 36°31'25"-77°20'54"3.9 Bonneau - BoB 19-11W C.C. Woodard Northampton 36°31'28"-77°20'44"29.5 Bonneau - BoB 19-12W C.C. Woodard Northampton 36°31'43"-77°20'25"4.6 Bonneau - BoB 19-13W C.C. Woodard Northampton 36°31'12"-77°20'10"7.9 Norfolk NoB 19-14W C.C. Woodard Northampton 36°31'19"-77°20'10"9.3 Norfolk — NoB 19-15W C.C. Woodard Northampton 36°31'26"-77°20'10"11 Norfolk NoB 19-1G C.C. Woodard Northampton 36°32'09"-77°21'07"48.6 Altavista - AtA 19-2G C.C. Woodard Northampton 36°32'17"-77°21'22"13.6 Tarboro - TaB 19-3G C.C. Woodard Northampton 36°32'26"-77°21'03"36.2 Altavista - AtA 19-4G C.C. Woodard Northampton 36°32'43"-77°20'57"42.5 Wickham - WkA 19-5G C.C. Woodard Northampton 36°32'39"-77°21'13"20.7 Roanoke - Ro 21-1 C.G. Perry Northampton 36°25'48"-77°20'07"19.6 Norfolk NoB 21-2 C.G. Perry Northampton 36°25'39"-77°20'45"29.2 Caroline - CaB 21-3 C.G. Perry Northampton 36°25'38"-77°20'17"11.2 Caroline - CaB 21-4 C.G. Perry Northampton 36°25'29"-77°20'34"3.3 Norfolk - NoA 21-5 C.G. Perry Northampton 36°25'31"-77°20'37"9.3 Norfolk—NoB 21-6 C.G. Perry Northampton 36°25'26"-77°20'31"4.0 Norfolk—NoB 21-7 C.G. Perry Northampton 36°25'25"-77°20'25"6.2 Norfolk—NoB 21-8 Robert Jones Robert Jones Northampton 36°25'12"-77°20'28"50.4 Norfolk — NoA WQ0012404 Version: 3.0 Attachment B Page 13 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 21-10 C.G. Perry Northampton 36°23'41"-77°24'16"44.3 Norfolk NoB 21-11 C.G. Perry Northampton 36°27'57"-77°25'57"33.7 Craven - CrA 21-13 C.G. Perry Northampton 36°27'40"-77°25'35"15.4 Norfolk - NoA 21-14A C.G. Perry Northampton 36°27'28"-77°25'40"13.8 Goldsboro - GoA 21-14B C.G. Perry Northampton 36°27'34"-77°25'39"18.0 Goldsboro - GoA 21-15 C.G. Perry Northampton 36°27'34"-77°25'16"17.5 Goldsboro - GoA 21-16 C.G. Perry Northampton 36°27'28"-77°25'16"5.7 Goldsboro - GoA 21-17 C.G. Perry Northampton 36°25'40"-77°21'08"4.5 Norfolk - NoA 21-18 Robert Jones Robert Jones Northampton 36°25'28"-77°21'13"6.7 Norfolk-NoA 21-20 Robert Jones Robert Jones Northampton 36°25'23"-77°21'12"3.7 Norfolk - NoA 21-21 Robert Jones Robert Jones Northampton 36°25'34"-77°21'02"31.4 Norfolk - NoA 21-22 Robert Jones Robert Jones Northampton 36°25'25"-77°21'02"5.7 Goldsboro - GoA 22-1 Charles J. Stephenson Northampton 36°27'24"-77°24'58"23.7 Goldsboro - GoA 22-2 Charles J. Stephenson Northampton 36°27'21"-77°24'49"19.6 Goldsboro - GoA 22-3 Charles J. Stephenson Northampton 36°27'17"-77°24'38"11.4 Goldsboro - GoA 22-4 Charles L Stephenson Northampton 36°26'56"-77°24'31"9.8 Goldsboro - GoA 22-5 Charles J. Stephenson Northampton 36°25'44"-77°23'58"6.9 Goldsboro - GoA 27-1 Neil Burgess Stephen Burgess Northampton 36°20'00"-77°12'50"47.8 Norfolk—NoA 27-2 Neil Burgess Stephen Burgess Northampton 36°26'00"-77°12'36"56.4 Norfolk—NoA 27-3 Neil Burgess Stephen Burgess Northampton 36°25'54"-77°12'27"25.5 Rains — Ra 27-4 Neil Burgess Stephen Burgess Northampton 36°25'41"-77°12'41"27.5 Norfolk—NoA 27-5 Neil Burgess Stephen Burgess Northampton 36°25'18"-77°12'39"16.0 Norfolk-NoA 27-6 Stephen Burgess Stephen Burgess Northampton 36°26'07"-77°11'22"53.4 Bonneau - BoB 27-7 Judi B. Burgess Stephen Burgess Northampton 36°24'20"-77°13'28"13.9 Craven - CrA 27-8 Judi B. Burgess Stephen Burgess Northampton 36°23'59"-77°14'10"17.7 Norfolk —NoB WQ0012404 Version: 3.0 Attachment B Page 14 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 27-9 Lori S. Burgess Northampton 36°23'56"-77°13'57"18.6 Caroline - CaA 27-10 Stephen Burgess Northampton 36°23'52"-77°13'51"20.3 Craven - CrA 27-11 Stephen Burgess Northampton 36°23'42"-77°13'50"23.4 Craven - CrA 27-12 Stephen Burgess Northampton 36°23'39"-77°13'40"16.7 Craven - CrA 27-13 Stephen Burgess Northampton 36°23'34"-77°13'13"5.2 Craven - CrA 27-14 Lori S. Burgess Stephen Burgess Northampton 36°24'34"-77°16'04"14.7 Goldsboro - GoA 27-15 Stephen Burgess Northampton 36°26'31"-77°17'10"6.5 Norfolk—NoB 27-16 Stephen Burgess Northampton 36°26'27"-77°17'02"5.1 Norfolk—NoB 27-17 Stephen Burgess Northampton 36°26'32"-77°16'52"21.9 Norfolk—NoB 27-18 Lori S. Burgess Northampton 36°26'10"-77°14'39"11.1 Goldsboro - GoA 27-19 Lori S. Burgess Northampton 36°26'18"-77°14'24"18.4 Goldsboro - GoA 27-20 Eloise T. Ward Stephen Burgess Northampton 36°26'20"-77°14'17"12.9 Goldsboro - GoA 27-21 Eloise T. Ward Stephen Burgess Northampton 36°26'19"-77°14'13"3.8 Goldsboro - GoA 27-22 Eloise T. Ward Stephen Burgess Northampton 36°26'34"-77°14'15"6.7 Goldsboro - GoA 27-23 Eloise T. Ward Stephen Burgess Northampton 36°27'49"-77°15'27"32.5 Bonneau - BoB 27-24 Eloise T. Ward Stephen Burgess Northampton 36°28'07"-7715'16"21.5 Bonneau - BoB 27-25 Eloise T. Ward Stephen Burgess Northampton 36°28'04"-77°14'45"35.2 Bonneau - BoB 27-26 Eloise T. Ward Stephen Burgess Northampton 36°27'53"-77°14'41"11.5 Norfolk - NoB 27-27 Eloise T. Ward Stephen Burgess Northampton 36°28'02"-77°14'34"14.4 Norfolk — NoB 27-28 Eloise T. Ward Stephen Burgess Northampton 36°27'52"-77°14'25"25.3 Norfolk — NoB 27-29 Eloise T. Ward Stephen Burgess Northampton 36°27'45"-77°14'17"60.5 Norfolk — NoB 27-30 Eloise T. Ward Stephen Burgess Northampton 36°28'11"-77°14'51"5.7 Autryville - AuA 27-31 Eloise T. Ward Stephen Burgess Northampton 36°28'16"-77°14'52"10.5 Norfolk—NoA 27-32 Eloise T. Ward Stephen Burgess Northampton 36°28'21"-77°14'52"26.0 Bonneau — BoB 27-33 Eloise T. Ward Stephen Burgess Northampton 36°28'21"-77°14'42"9.9 Norfolk — NoA WQ0012404 Version: 3.0 Attachment B Page 15 of 16 ATTACHMENT B - Approved Land Application Sites Certification Date: February 19, 2021 CF Nitrogen, Inc. Permit Number: WQ0012404 Version: 3.0 Site/ Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes 27-34 Eloise T. Ward Stephen Burgess Northampton 36°28'26"-77°14'30"17.6 Bonneau — BoB 27-35 Eloise T. Ward Stephen Burgess Northampton 36°28'30"-77°14'18"9.1 Goldsboro — GoA 27-36 Eloise T. Ward Stephen Burgess Northampton 36°28'24"-77°13'57"9.3 Autryville — AuA 27-37 Eloise T. Ward Stephen Burgess Northampton 36°28'23"-77°14'12"17.2 Autryville — AuA 27-38 Eloise T. Ward Stephen Burgess Northampton 36°28'10"-77°14'09"3.0 Norfolk - NoA 27-39 Kevin B. Burgess Stephen Burgess Northampton 36°26'40"-77°12'40"20.6 Norfolk - NoB 27-40 Kevin B. Burgess Stephen Burgess Northampton 36°26'33"-77°12'35"21.0 Norfolk -NoB 27-41 Stephen Burgess Northampton 36°27'33"-77°11'45"9.8 Norfolk - NoB 27-42 Stephen Burgess Northampton 36°27'43"-77°11'32"93.5 Bonneau — BoB 27-43 Stephen Burgess Northampton 36°27'35"-77°11'21"17.7 Norfolk—NoB 27-44 Stephen Burgess Northampton 36°27'43"-77°11'11"29 Bonneau — BoB 27-45 Stephen Burgess Northampton 36°27'49"-77°11'04"18 Norfolk—NoB 27-46 Stephen Burgess Northampton 36°27'27"-77°11'18"13.9 Bonneau — BoB 27-47 Stephen Burgess Northampton 36°27'36"-77°11'06"20.8 Bonneau - BoB 27-48 Kevin B. Burgess Stephen Burgess Northampton 36°27'31"-77°10'15"14.8 State — StA 27-49 Kevin B. Burgess Stephen Burgess Northampton 36°27'27"-77°10'07"6.1 Tarboro — TaB 27-50 Kevin B. Burgess Stephen Burgess Northampton 36°27'38"-77°09'59"17.9 Altavista— AtA 27-51 Kevin B. Burgess Stephen Burgess Northampton 36°27'38"-77°09'40"52.7 Tarboro—TaB 27-65 Bobby Bridges Neil Bridges Northampton 36°25'50"-77°15'01"67.3 Bonneau— BoB 27-66 Neil & Donna B. Burgess Northampton 36°24'50"-77°15'10"18.1 Norfolk - NoB 27-67 Fannie Bryant Stephen Burgess Northampton 36°27'46"77°10'47"33.7 Bonneau - BoB 27-68 Martha Pearlman Northampton 36°30'5"77°11'14"58.0 Goldsboro - GoA 27-69 Ronald Woodard Northampton 36°29'56"77°11'18"42.2 Gritney - GxB 27-70 Ronald Woodard Northampton 36°28'54"77°12'25"85.4 Lynchburg - Ly 27-71 Stephen Burgess Northampton 36°27'29"77°15'27"61.8 Bonneau — BoB 27-72 Stephen Burgess Northampton 36°27'28"77°15'5"39.7 Bonneau — BoB 27-73 Stephen Burgess Northampton 36°27'11" 77°15'14"74.9 Norfolk - NoA County Total Northampton 3,026.2 Permit Total 7,968.6 WQ0012404 Version: 3.0 Attachment B Page 16 of 16 Landowner Agreement Attachments & Lessee Agreement Attachments (NO NEW AGREEMENTS WERE OBTAINED IN 2020) Groundwater Data Annual Groundwater Monitoring Report CF Nitrogen, Inc. Cofield, North Carolina S&ME Project No. 1040-98-044U PREPARED ON BEHALF OF: CF Industries Holdings, Inc. 4 Parkway North Suite 400 Deerfield, IL PREPARED BY: S&ME, Inc. 3201 Spring Forest Road Raleigh, NC 27616 February 18, 2021 S&ME, Inc. | 3201 Spring Forest Road | Raleigh, NC 27616 | p 919.872.2660 | www.smeinc.com February 18, 2021 North Carolina Department of Environmental Quality Division of Water Resources – UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Attention: Non-Discharge Permitting Unit Reference: Groundwater Monitoring Report Permit No. WQ0012404 January 1, 2020 thru December 31, 2020 CF Nitrogen, Inc. Cofield, North Carolina EPA ID No. NCD065288847 S&ME Project No. 1040-98-044U Non-Discharge Permitting Unit: On behalf of CF Nitrogen, Inc. (CFN), a wholly-owned subsidiary of CF Industries Holding, Inc. (CFIH), S&ME, Inc. (S&ME) is submitting the CY 2020 annual groundwater monitoring report for the CFN site located in Cofield, North Carolina (Figure 1) as required by the Land Application Permit (Permit No. WQ0012404 , effective January 1, 2021). S&ME completed this annual report while under contract with CFIH.  Groundwater Recovery and Distribution Volumes Based on weekly flow meter readings recorded from Transfer Pump Station #1 beginning December 26, 2019, and ending December 24, 2020, approximately 14,712,300 gallons of groundwater were removed from the confined shallow aquifer in 2020. Quarterly flow amounts for Transfer Pump Station #1 were as follows: 1st Quarter (January – March 2020): 3,879,300 gallons 2nd Quarter (April – June 2020): 3,354,600 gallons 3rd Quarter (July – September 2020): 4,823,800 gallons 4th Quarter (October – December 2020): 2,654,600 gallons Total Groundwater Recovery for 2020: 14,712,300 gallons Based on flow meter readings from Transfer Pump Station #2, approximately 14,310,000 gallons of water were transferred from the storage basin for land application. Groundwater Monitoring Report Permit No. WQ0012404 January 1, 2020 thru December 31, 2020 CF Nitrogen, Inc. Cofield, North Carolina EPA ID No. NCD065288847 S&ME Project No. 1040-98-044U February 18, 2021 2 The nitrogen-enriched groundwater was applied to a variety of crops throughout the year including corn, wheat, soybeans, and fescue. The following volumes of groundwater may differ slightly to those reported in the land application report, because meter readings were recorded on dates when weekly inspections were conducted, which may have been different than the days readings were recorded by the land application contractor. The flow volumes were recorded during weekly inspections and summed to calculate quarterly volumes of groundwater that were land applied to agricultural fields. Quarterly amounts for 2020 were as follows: 1st Quarter (January – March 2020): 3,377,000 gallons 2nd Quarter (April – June 2020): 3,347,000 gallons 3rd Quarter (July – September 2020): 4,778,000 gallons 4th Quarter (October – December 2020): 2,808,000 gallons Total Groundwater Applied for 2020: 14,310,000 gallons The total annual recorded rainfall at the Ahoskie site was 47.02 inches, compared with the annual average of 46 inches for the area. Land application efforts for 2020, on average, maintained the groundwater elevation within the slurry wall below 30 feet mean sea level (ft-msl). Onsite groundwater elevations were measured monthly from January to October during 2020 and quarterly thereafter. The groundwater elevations recorded from December 26, 2019 through October 27, 2020, and those recorded on January 27, 2021, are presented in Table 1. As required in the permit, potentiometric maps showing quarterly interpretations of general groundwater elevations based on end-of-month measurements for January, April, July, and October 2020 are included as Figures 2, 3, 4 and 5. As required in Attachment C of the Non-Discharge Permit, cross-sectional views of water levels measured in piezometers PI-11 – PO-12 and PI-2 – PO-236 were prepared and are attached as Figures 2A, 3A, 4A and 5A for each corresponding quarterly potentiometric map. Additional cross-sectional views of water levels measured in C- designated wells C-23 – C-22, C-29 – C-28 are included as Figures 2B, 3B, 4B and 5B, and cross-sectional views of C-33-C-32 and monitor wells MWI-4 – MWI-6 are depicted in Figures 2C, 3C, 4C and 5C. The history of water levels for piezometers PI-2, PI-11, PO-12 and PO-236 is graphically shown in Figure 6. The historical water level data from the oldest C-designated wells on site (C-22, C-23, C-28, C-29, C-32 and C-33) are graphically shown in Figure 7. Historical water level elevation data for MWI-3, MWI-4 and MWI-6 are depicted in Figure 8. Precipitation events were recorded by an on-site rain gauge. The amounts of precipitation for CY 2020 are presented in Table 2. Monthly recorded rainfall on-site ranged from 1.83 inches in June 2020 to a season high of 6.97 inches in June 2020. The average monthly rainfall amounts for Cofield, North Carolina (according to precipitation data from the USA.com website, www.USA.com), are presented on Table 2 and depicted on Figure 9. The amount of rainfall in 2020 was approximately one inch greater than the average rainfall for the region. Groundwater Monitoring Report Permit No. WQ0012404 January 1, 2020 thru December 31, 2020 CF Nitrogen, Inc. Cofield, North Carolina EPA ID No. NCD065288847 S&ME Project No. 1040-98-044U February 18, 2021 3 Should you have any questions, please do not hesitate to contact us at (919) 872-2660. Sincerely, S&ME, Inc. Jason Volker, LSS, ORC Tom Raymond, PE, PMP, RSM Project Manager Principal Environmental Engineer / Vice President 919-880-3137 919-801-5359 jvolker@smeinc.com traymond@smeinc.com cc: Ms. Diane Diks, CHMM, CPEA (CF Nitrogen, Inc.) Attachments: Tables Table 1: Groundwater Elevation Data Table 2: Monthly Rainfall 2019 and 2020 Figures Figure 1: Site Location Map Figure 2: Groundwater Potentiometric Map for January 2020 Figure 2A: Cross-sectional View PI-2 – PO-236 & PI-11 – PO-12 for January 2020 Figure 2B: Cross-sectional View C-23 – C-22 & C-29 – C-28 for January 2020 Figure 2C: Cross-Sectional View C-33 – C-32 & MWI-4 – MWI-6 for January 2020 Figure 3: Groundwater Potentiometric Map for April 2020 Figure 3A: Cross-sectional View PI-2 – PO-236 & PI-11 – PO-12 for April 2020 Figure 3B: Cross-sectional View C-23 – C-22 & C-29 – C-28 for April 2020 Figure 3C: Cross-Sectional View C-33 – C-32 & MWI-4 – MWI-6 for April 2020 Figure 4: Groundwater Potentiometric Maps for July 2020 Figure 4A: Cross-sectional View PI-2 – PO-236 & PI-11 – PO-12 for July 2020 Figure 4B: Cross-sectional View C-23 – C-22 & C-29 – C-28 for July 2020 Figure 4C: Cross-Sectional View C-33 – C-32 & MWI-4 – MWI-6 for July 2020 Figure 5: Groundwater Potentiometric Maps for October 2020 Figure 5A: Cross-sectional View PI-2 – PO-236 & PI-11 – PO-12 for October 2020 Figure 5B: Cross-sectional View C-23 – C-22 & C-29 – C-28 for October 2020 Figure 5C: Cross-Sectional View C-33 – C-32 & MWI-4 – MWI-6 for October 2020 Figure 6: Groundwater Elevations for PI-2, PI-11, PO-12, and PO-236 Figure 7: Groundwater Elevations for C-Designated Wells Figure 8: Groundwater Elevations for MWI-3, MWI-4 and MWI-6 Figure 9: Monthly Rainfall 2020 Attachments Attachment I – Tables 12/26/2019 1/29/2020 2/24/2020 3/31/2020 4/30/2020 5/30/2020 6/26/2020 7/27/2020 8/28/2020 9/28/2020 10/27/2020 1/27/2021 MWI-1 29.29 30.62 30.21 29.92 31.05 30.27 29.39 28.81 29.89 29.37 28.71 30.07 MWI-2 28.66 29.54 30.60 30.43 30.96 30.06 29.32 29.36 29.46 29.36 29.14 30.36 MWI-3 28.25 29.51 29.67 29.48 30.01 29.45 29.25 28.59 29.65 29.05 28.71 30.23 MWI-4 30.05 30.88 31.05 30.79 30.69 31.03 30.51 30.13 30.99 30.45 29.75 30.83 MWO-5 24.02 24.62 24.82 25.14 25.12 25.32 24.74 24.34 24.34 24.34 24.14 25.24 MWI-6 29.05 29.21 29.97 30.06 30.79 29.43 29.23 28.99 29.63 29.01 28.97 30.73 MWI-7 26.54 27.34 28.46 28.34 28.66 28.04 27.42 26.96 30.20 27.14 27.04 29.42 MWO-8 25.95 25.73 27.95 28.28 30.45 27.23 27.89 26.51 27.01 27.31 25.93 29.35 PI-1 27.91 29.26 29.69 29.46 29.73 29.37 28.69 27.41 29.01 28.55 28.51 29.07 PI-2 27.60 28.30 30.20 28.85 29.68 28.90 28.02 28.10 28.80 28.60 28.40 29.20 PO-3 19.09 19.50 19.15 19.30 19.07 19.33 19.23 19.23 19.01 19.05 18.87 18.87 PI-4 28.21 28.73 30.51 30.38 30.45 29.61 23.95 28.27 29.09 28.75 28.75 30.43 PI-5 27.47 28.00 30.01 29.50 29.50 29.17 28.29 27.79 28.57 27.41 28.25 29.85 PO-6 23.06 23.28 23.36 24.25 23.86 23.98 23.88 23.48 23.52 23.16 23.14 23.58 PI-7 28.48 29.60 30.02 29.96 30.59 29.78 29.28 28.46 29.66 29.00 28.70 29.92 PI-8 25.98 26.82 27.80 27.71 27.88 27.40 26.64 26.44 27.54 26.56 26.42 28.34 PI-9 28.73 29.51 29.71 30.09 29.79 30.51 29.71 29.15 29.81 29.51 29.29 29.21 PI-10 28.48 29.22 29.74 29.52 29.80 30.02 29.62 28.90 29.54 29.50 29.24 30.52 PI-11 26.21 27.95 28.59 28.47 28.57 27.87 27.19 26.69 27.99 26.89 26.65 28.89 PO-12 15.80 16.93 16.34 16.55 16.60 17.06 16.20 16.20 16.22 16.30 16.04 16.40 PI-13R 28.87 29.45 30.57 30.55 30.77 29.93 29.57 28.75 30.25 29.53 29.07 30.75 PI-14 27.90 28.61 29.86 29.99 29.48 28.86 27.84 27.18 29.18 28.04 27.84 29.28 PO-15 23.88 24.03 24.06 24.52 24.66 24.96 24.42 24.38 24.30 24.24 24.14 24.68 PO-16 26.81 27.51 27.25 28.17 29.43 28.21 27.69 27.47 27.21 27.37 27.11 29.83 PI-17 29.48 30.98 32.02 31.90 31.86 29.50 28.20 27.76 30.56 29.20 28.42 31.72 PI-18 27.89 28.12 29.89 29.52 29.57 28.69 28.39 27.53 28.77 27.89 28.27 29.87 PI-19 26.69 27.01 28.87 28.44 28.81 27.91 27.15 26.89 27.83 23.27 27.21 28.71 PI-20 27.78 27.93 29.66 28.90 29.50 28.98 28.44 28.06 27.70 28.46 27.88 29.68 PI-21 27.75 28.08 29.99 29.36 29.31 28.93 28.31 27.91 28.73 28.29 28.15 29.85 PI-22 28.73 29.23 29.45 29.26 28.63 29.61 29.73 29.15 29.65 29.07 29.09 30.23 PI-23 29.96 30.21 32.56 31.91 32.08 30.34 24.24 28.80 30.72 29.96 30.32 32.62 PI-24 28.33 29.55 29.59 29.37 29.59 29.35 29.07 28.55 29.67 29.17 28.77 30.03 PO-25 24.63 24.85 25.25 25.45 25.97 25.47 25.15 24.89 24.79 24.81 25.07 25.97 PO-26 27.19 27.41 28.31 28.55 29.11 28.31 27.53 27.49 27.71 27.23 26.87 29.17 C-22 15.55 16.00 15.71 16.03 16.85 17.23 14.91 14.77 14.65 14.85 14.75 14.85 C-23 (Replaced 04/05)27.26 28.48 28.96 28.78 29.46 28.68 28.43 27.58 28.90 28.68 26.83 28.94 C-28 (Repaired 08/03)8.73 9.11 9.57 9.84 9.37 9.55 9.41 9.09 9.11 8.93 8.83 9.97 C-29 25.16 25.79 27.02 27.04 27.24 27.24 26.00 24.96 15.14 25.92 25.82 27.74 C-32 10.27 10.75 11.35 12.11 11.77 11.67 11.03 10.67 11.05 21.05 10.97 12.37 C-33 25.22 25.40 27.42 27.60 27.60 26.68 25.96 25.52 27.30 21.22 26.02 28.12 C-4 27.96 28.68 29.16 29.00 28.96 29.14 28.76 28.36 29.10 28.38 27.76 29.46 PO-235 15.93 16.25 15.63 15.99 15.37 15.55 15.55 15.45 15.63 15.37 15.15 15.85 PO-236 12.64 13.37 13.32 13.73 13.32 13.44 13.12 12.92 13.22 13.16 13.04 14.82 PO-237 27.25 27.53 28.45 28.58 29.45 29.01 27.63 27.13 27.65 27.15 26.95 29.35 TABLE 1 GROUNDWATER ELEVATION DATA DECEMBER 2019 THROUGH JANUARY 2021 CF NITROGEN - COFIELD, NORTH CAROLINA S&ME PROJECT NO. 1040-98-044U Date of Water Level Measurement Well ID TABLE 2 MONTHLY RAINFALL 2019 & 2020 CF INDUSTRIES - COFIELD, NORTH CAROLINA S&ME PROJECT NO. 1040-98-044U Month 2020 Recorded Rainfall at CFI-Ahoskie Site (inches) 2019 Recorded Rainfall at CFI-Ahoskie Site (inches) Average Rainfall for Cofield (inches) www.usa.com January 1.90 3.00 3.60 February 4.50 3.20 3.10 March 2.48 2.75 4.10 April 5.12 5.18 3.50 May 3.40 1.02 3.80 June 1.83 3.55 4.10 July 2.05 5.27 4.80 August 6.97 4.39 4.80 September 5.34 0.53 4.60 October 4.63 2.20 3.20 November 6.30 2.09 3.10 December 2.50 1.93 3.30 Annual Total:47.02 35.11 46.00 Monthly Average:3.92 2.93 3.83 Recorded rainfall at site taken from on-site rain gauge Data for average monthly rainfall obtained from the USA.com website for Cofield, NC Attachment II – Figures PROJECT SITE SCALE: DATE: PROJECT NUMBER FIGURE NO.11 " = 4,000 ' 2-15-21 1040-98-044UCF NIT ROGEN INC.COFIELD, NORTH CAROLINA Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\1_sitelocation.mxd plotted by DHomans 02-15-2021 0 4,000 8,000 (FE ET) SITE LOCATION MAP ³ REFERENCE: ESRI STREET MAP USA DATSETTHIS MAP IS FOR INFORMATIONAL PURPOSES ONLY. ALL FEATURELOCATIONS DISPLAYED ARE APPROXIMATED. THEY ARE NOT BASED ONCIVIL SURVEY IN FORMATI ON, U NL ES S S TATED OTHERWIS E. #0#0 #0 #0 #0 #0 #0#0 #0 #0 #0 #0#0#0 #0 #0#0 #0 #0 #0 #0 #0#0 #0 #0 !A$ !A$ !A$!A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G ●○ ●○ ●○ ●○ ●○ ●○ ●○●○●○ ●○●○ ●○ ●○ ●○ ●○ ●○●○ ●○ ●○ ●○ ●○ ●○ ●○ ●○ ●○1211161310181 619 22 26 21 150 1420 20 1319 121621 18 1125 17 1722 2715 231015 241514141424 25 26 27 RW-1 RW-2 RW-3 RW-4 RW-5 RW-6 RW-7 RW-8 RW-9 3029283 029302 9 2 7 26PI-4(28.73)PO-3(19.50) PO-235(16.25)PI-1(29.26) PI-11(27.95)PO-12(16.93) PI-14(28.61)PO-15(24.03) PI-24(29.55) PI-17(30.98)PO-16(27.51) PI-23(30.21) PO-237(27.53)PO-26(27.41) PI-13R(29.45)PO-25(24.85) PI-22(29.23) PI-9(29.51)PI-10(29.22) PO-6(23.28) PI-7(29.60) PO-236(13.37)PI-2(28.30) PI-5(28.00) PI-8(26.82) MWI-7(27.34) MWI-6(29.21) C33(25.40) C32(10.75) C28(9.11) C29(25.79) C22(16.00)C23(28.48) MWI-1(30.62) MWI-2(29.54) MWI-3(29.51) MWO-8(25.73) C4(28.68) MWI-4(30.88) MWO-5(24.62) LEGEND●○Inside Wells Ð!G RECOVERY WELL !A$MONITOR WELL #0 PIEZOMETER )26.03(GROUNDWATER ELEVATION (FEET ABOVE MEAN SEA LEVEL) GROUNDWATER CONTOURS SLURRY WALL SCALE: DATE: PROJECT NUMBER FIGURE NO.2 1 " = 400 ' 2-14-21 1040-98-044UCF NITROGEN INC.COFIELD, NORTH CAROLINADrawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2_pontentioMap_Jan.mxd plotted by DHomans 02-14-20210 400 800 (FEET)GROUNDWATER POTENTIOMETRIC MAPJanuary 29, 2020³ NOTE:PIEZOMETERS PI-18 TO PI-21 ARE G ROUPED NEAR PI-5, WHICH ISWITHIN THE RADIUS OF INFLUENCE; WATER LEVELS OF THESEPIEZOMETERS ARE THUS EXC LUDED FROM THIS MAP. 30 25 35 40 45 20 15 10 5 0 -5 42.60' MSL (T.O.C.) 28.30 FT. MSL SLURRY WALL 43.62' MSL (T.O.C.) ~30' MSL 13.37 FT. MSL 39.20' MSL (T.O.C.) -5 30 5 0 10 20 15 25 35 40 45 ~30' MSL 27.95 FT. MSL WALL SLURRY 42.57' MSL (T.O.C.) 16.93 FT. MSL PI-2 PO-236 PI-11 PO-12 NOTE: GROUNDWATER DATA COLLECTED ON JANUARY 29, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\2A-2C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 2A 1040-98-044U 2-15-2021 1" = 15'CROSS - SECTIONAL VIEW PI-2 - PO-236 & PI-11 - PO-12 30 25 35 40 45 20 15 10 5 0 -5 40.48' MSL (T.O.C.) 28.48 FT. MSL SLURRY WALL 39.65' MSL (T.O.C.) ~30' MSL -5 30 5 0 10 20 15 25 35 40 45 25.79 FT. MSL 43.14' MSL (T.O.C.) C-23 C-22 C-29 C-28 16.00 FT. MSL SLURRY WALL ~30' MSL 39.01' MSL (T.O.C.) 9.11 FT. MSL NOTE: GROUNDWATER DATA COLLECTED ON JANUARY 29, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\2A-2C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 2B 1040-98-044U 2-15-2021 1" = 15'CROSS - SECTIONAL VIEW C-23 - C22 & C-29 - C28 30 25 35 40 45 20 15 10 5 0 -5 39.40' MSL (T.O.C.) 25.40 FT. MSL SLURRY WALL 36.85' MSL (T.O.C.) ~30' MSL 46.31' MSL (T.O.C.) -5 30 5 0 10 20 15 25 35 40 45 29.21 FT. MSL C-33 C-32 MWI-4 MWI-6 10.75 FT. MSL 50 29.51 FT. MSL 44.93' MSL (T.O.C.) 30.88 FT. MSL 42.03' MSL (T.O.C.) MWI-3 NOTE: GROUNDWATER DATA COLLECTED ON JANUARY 29,2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\2A-2C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 2C 1040-98-044U 2-15-2021 1" = 15' CROSS - SECTIONAL VIEW C-33 - C-32 & MWI-4, MWI-3, MWI-6 #0#0 #0 #0 #0 #0 #0#0 #0 #0 #0 #0#0#0 #0 #0#0 #0 #0 #0 #0 #0#0 #0 #0 !A$ !A$ !A$!A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G1213 29 111715 28 1823 1622 1910142112 1527 20 20 1419 1321 18 017 26 22 16 112616231416 24 25151524251410 27302829RW-1 RW-2 RW-3 RW-4 RW-5 RW-6 RW-7 RW-8 RW-9 3 1 3 0293130 29 28 32 PI-4(30.45)PO-3(19.07) PO-235(15.37)PI-1(29.73) PI-11(28.57)PO-12(16.60) PI-14(29.48) PO-15(24.66) PI-24(29.59) PI-17(31.86)PO-16(29.43) PI-23(32.08) PO-237(29.45)PO-26(29.11) PI-13R(30.77)PO-25(25.97) PI-22(28.63) PI-9(29.79)PI-10(29.80) PO-6(23.86) PI-7(30.59) PO-236(13.32)PI-2(29.68) PI-5(29.50) PI-8(27.88) MWI-7(28.66) MWI-6(30.79) C33(27.60) C32(11.77) C28(9.37) C29(27.24) C22(16.85)C23(29.46) MWI-1(31.05) MWI-2(30.96) MWI-3(30.01) MWO-8(30.45) C4(28.96) MWI-4(30.69) MWO-5(25.12) LEGEND Ð!G RECOVERY WELL !A$MONITOR WELL #0 PIEZOMETER SLURRY WALL GROUNDWATER CONTOURS )50.13(GROUNDWATER ELEVATION (FEET ABOVE MEAN SEA LEVEL) SCALE: DATE: PROJECT NUMBER FIGURE NO.3 1 " = 400 ' 2-14-21 1040-98-044UCF NITROGEN INC.COFIELD, NORTH CAROLINADrawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\3_pontentioMap_April.mxd plotted by DHomans 02-14-20210 400 800 (FEET)GROUNDWATER POTENTIOMETRIC MAPApril 30, 2020³ NOTE:PIEZOMETERS PI-18 TO PI-21 ARE G ROUPED NEAR PI-5, WHICH ISWITHIN THE RADIUS OF INFLUENCE; WATER LEVELS OF THESEPIEZOMETERS ARE THUS EXC LUDED FROM THIS MAP. 30 25 35 40 45 20 15 10 5 0 -5 42.60' MSL (T.O.C.) SLURRY WALL 43.62' MSL (T.O.C.) ~30' MSL 13.32 FT. MSL 39.20' MSL (T.O.C.) -5 30 5 0 10 20 15 25 35 40 45 ~30' MSL WALL SLURRY 16.60 FT. MSL PI-2 PO-236 PI-11 PO-12 NOTE : GROUNDWATER DATA COLLECTED ON APRIL 30, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\3A-3C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 3A 1040-98-044U 2-15-2021 1" = 15'CROSS - SECTIONAL VIEW PI-2 - PO-236 & PI-11 - PO-12 30 25 35 40 45 20 15 10 5 0 -5 40.48' MSL (T.O.C.) 29.46 FT. MSL SLURRY WALL 39.65' MSL (T.O.C.) ~30' MSL -5 30 5 0 10 20 15 25 35 40 45 27.24 FT. MSL 43.14' MSL (T.O.C.) C-23 C-22 C-29 C-28 16.85 FT. MSL SLURRY WALL ~30' MSL 39.01' MSL (T.O.C.) 9.37 FT. MSL NOTE: GROUNDWATER DATA COLLECTED ON APRIL 30, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\3A-3C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 3B 1040-98-044U 2-15-2021 1" = 15'CROSS - SECTIONAL VIEW C-23 - C22 & C-29 - C-28 30 25 35 40 45 20 15 10 5 0 -5 39.40' MSL (T.O.C.) 27.60 FT. MSL SLURRY WALL 36.85' MSL (T.O.C.) ~30' MSL 46.31' MSL (T.O.C.) -5 30 5 0 10 20 15 25 35 40 45 30.79 FT. MSL C-33 C-32 MWI-4 MWI-6 11.77 FT. MSL 50 30.01 FT. MSL 44.93' MSL (T.O.C.) 30.69 FT. MSL 42.03' MSL (T.O.C.) MWI-3 NOTE: GROUNDWATER DATA COLLECTED ON APRIL 30, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\3A-3C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 3C 1040-98-044U 2-15-2021 1" = 15' CROSS - SECTIONAL VIEW C-33 - C-32 & MWI-4, MWI-3, MWI-6 #0#0 #0 #0 #0 #0 #0#0 #0 #0 #0 #0#0#0 #0 #0#0 #0 #0 #0 #0 #0#0 #0 #0 !A$ !A$ !A$!A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G10 27 11151712 23 181322 1519 21 26 1420 1320 19 161218 211 117 16 2213 25 231013 2 5 2414141424 2627RW-1 RW-2 RW-3 RW-4 RW-5 RW-6 RW-7 RW-8 RW-9 2 8 2 7 2 6 253 0 292 8 29PI-4(28.27)PO-3(19.23) PO-235(15.45)PI-1(27.41) PI-11(26.69)PO-12(16.20) PI-14(27.18) PO-15(24.38) PI-24(28.55) PI-17(27.76)PO-16(27.47) PI-23(28.80) PO-237(27.13)PO-26(27.49) PI-13R(28.75) PO-25(24.89) PI-22(29.15) PI-9(29.15)PI-10(28.90) PO-6(23.48) PI-7(28.46) PO-236(12.92)PI-2(28.10) PI-5(27.79) PI-8(26.44) MWI-7(26.96) MWI-6(28.99) C33(25.52)C32(10.67) C28(9.09) C29(24.96) C22(14.77)C23(27.58) MWI-1(28.81) MWI-2(29.36) MWI-3(28.59) MWO-8(26.51) C4(28.36) MWI-4(30.13) MWO-5(24.34) LEGEND Ð!G RECOVERY WELL !A$MONITOR WELL #0 PIEZOMETER )18.82(GROUNDWATER ELEVATION (FEET ABOVE MEAN SEA LEVEL) SLURRY WALL GROUNDWATER CONTOURS SCALE: DATE: PROJECT NUMBER FIGURE NO.4 1 " = 400 ' 2-15-21 1040-98-044UCF NITROGEN INC.COFIELD, NORTH CAROLINADrawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\4_pontentioMap_Jul.mxd plotted by DHomans 02-15-20210 400 800 (FEET)GROUNDWATER POTENTIOMETRIC MAPJuly 27,2020³ NOT E:PIEZOMETERS PI-18 TO PI-21 ARE G ROUPED NEAR PI-5, WHICH ISWITHIN THE RADIUS OF INFLUENCE; WATER LEVELS OF THESEPIEZOMETERS ARE THUS EXC LUD ED FROM THIS MAP. 30 25 35 40 45 20 15 10 5 0 -5 42.60' MSL (T.O.C.) 28.10 FT. MSL SLURRY WALL 43.62' MSL (T.O.C.) ~30' MSL 12.92 FT. MSL 39.20' MSL (T.O.C.) -5 30 5 0 10 20 15 25 35 40 45 ~30' MSL 26.69 FT. MSL WALL SLURRY 42.57' MSL (T.O.C.) 16.20 FT. MSL PI-2 PO-236 PI-11 PO-12 NOTE: GROUNDWATER DATA COLLECTED ON JULY 27, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\4A-4C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 4A 1040-98-044U 2-15-2021 1" = 15'CROSS - SECTIONAL VIEW PI-2 - PO-236 & PI-11 - PO-12 30 25 35 40 45 20 15 10 5 0 -5 40.48' MSL (T.O.C.) 27.58 FT. MSL SLURRY WALL 39.65' MSL (T.O.C.) ~30' MSL -5 30 5 0 10 20 15 25 35 40 45 24.96 FT. MSL 43.14' MSL (T.O.C.) C-23 C-22 C-29 C-28 14.77 FT. MSL SLURRY WALL ~30' MSL 39.01' MSL (T.O.C.) 9.09 FT. MSL NOTE: GROUNDWATER DATA COLLECTED ON JULY 27, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\4A-4C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 4B 1040-98-044U 2-15-2021 1" = 15'CROSS - SECTIONAL VIEW C-23 - C22 & C-29 - C-28 30 25 35 40 45 20 15 10 5 0 -5 39.40' MSL (T.O.C.) 25.52 FT. MSL SLURRY WALL 36.85' MSL (T.O.C.) ~30' MSL 46.31' MSL (T.O.C.) -5 30 5 0 10 20 15 25 35 40 45 28.99 FT. MSL C-33 C-32 MWI-4 MWI-6 10.67 FT. MSL 50 28.59 FT. MSL 44.93' MSL (T.O.C.) 30.13 FT. MSL 42.03' MSL (T.O.C.) MWI-3 NOTE: GROUNDWATER DATA COLLECTED ON JULY 27, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\4A-4C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 4C 1040-98-044U 2-15-2021 1" = 15' CROSS - SECTIONAL VIEW C-33 - C-32 & MWI-4, MWI-3, MWI-6 #0#0 #0 #0 #0 #0 #0#0 #0 #0 #0 #0#0#0 #0 #0#0 #0 #0 #0 #0 #0#0 #0 #0 !A$ !A$ !A$!A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ !A$ Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G Ð!G121011 27 17 18 26 22 1521 19 1420 1320 19 918 121117 16211 125 16 22 2310 24914141413232415 272 5 2 6 RW-1 RW-2 RW-3 RW-4 RW-5 RW-6 RW-7 RW-8 RW-9 2 9 28 26 27 28PI-4(28.75)PO-3(18.87) PO-235(15.15)PI-1(28.51) PI-11(26.65)PO-12(16.04) PI-14(27.84)PO-15(24.14) PI-24(28.77) PI-17(28.42)PO-16(27.11) PI-23(30.32) PO-237(26.95)PO-26(26.87) PI-13R(29.07) PO-25(25.07) PI-22(29.09) PI-9(29.29)PI-10(29.24) PO-6(23.14) PI-7(28.70) PO-236(13.04)PI-2(28.40) PI-5(28.25) PI-8(26.42) MWI-7(27.04) MWI-6(28.97) C33(26.02) C32(10.97) C28(8.83) C29(25.82) C22(14.75)C23(26.83) MWI-1(28.71) MWI-2(29.14) MWI-3(28.71) MWO-8(25.93) C4(27.76) MWI-4(29.75) MWO-5(24.14) LEGEND Ð!G RECOVERY WELL !A$MONITOR WELL #0 PIE ZOME TER )17.82(GROUNDWATER ELE VATION (FEET ABOVE MEAN SEA LEVE L) SLURRY WALL GROUNDWATER CONTOURS SCALE: DATE: PROJECT NUMBER FIGURE NO.5 1 " = 400 ' 2-15-21 1040-98-044UCF NITROGEN INC.COFIELD, NORTH CAROLINADrawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\5_pontentioMap_oct.mxd plotted by DHomans 02-15-20210 400 800 (FEET)GROUNDWATER POTENTIOMETRIC MAPOctober 27, 2020³ NOT E:PIE ZOME TERS PI-18 TO PI-21 ARE GROUPED NEAR PI-5, WHIC H ISWITHIN THE RADIUS OF INFLUENCE; WATER LEVELS OF THESEPIEZOMETERS ARE THUS E XCLUDED FROM THIS MAP. 30 25 35 40 45 20 15 10 5 0 -5 39.40' MSL (T.O.C.) 26.02 FT. MSL SLURRY WALL 36.85' MSL (T.O.C.) ~30' MSL 46.31' MSL (T.O.C.) -5 30 5 0 10 20 15 25 35 40 45 28.97 FT. MSL C-33 C-32 MWI-4 MWI-6 10.97 FT. MSL 50 28.71 FT. MSL 44.93' MSL (T.O.C.) 29.75 FT. MSL 42.03' MSL (T.O.C.) MWI-3 NOTE: GROUNDWATER DATA COLLECTED ON OCTOBER 27, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\5A-5C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 5C 1040-98-044U 2-15-2021 1" = 15' CROSS - SECTIONAL VIEW C-33 - C-32 & MWI-4, MWI-3, MWI-6 30 25 35 40 45 20 15 10 5 0 -5 40.48' MSL (T.O.C.) 26.83 FT. MSL SLURRY WALL 39.65' MSL (T.O.C.) ~30' MSL -5 30 5 0 10 20 15 25 35 40 45 25.82 FT. MSL 43.14' MSL (T.O.C.) C-23 C-22 C-29 C-28 14.75 FT. MSL SLURRY WALL ~30' MSL 39.01' MSL (T.O.C.) 8.83 FT. MSL NOTE: GROUNDWATER DATA COLLECTED ON OCTOBER 27, 2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\5A-5C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 5B 1040-98-044U 2-15*-2021 1" = 15'CROSS - SECTIONAL VIEW C-23 - C22 & C-29 - C-28 30 25 35 40 45 20 15 10 5 0 -5 42.60' MSL (T.O.C.) 28.40 FT. MSL SLURRY WALL 43.62' MSL (T.O.C.) ~30' MSL 13.04 FT. MSL 39.20' MSL (T.O.C.) -5 30 5 0 10 20 15 25 35 40 45 ~30' MSL 26.65 FT. MSL WALL SLURRY 42.57' MSL (T.O.C.) 16.04 FT. MSL PI-2 PO-236 PI-11 PO-12 NOTE: GROUNDWATER DATA COLLECTED ON OCTOBER 27,2020 SCALE: DATE: PROJECT NUMBER FIGURE NO.Drawing Path: R:\CADData\Charlotte\1040\CF Industries\1040-98-044U 2020 Results\2020 CAD\5A-5C.dwgCF NITROGEN, INC. COFIELD, NORTH CAROLINA 5A 1040-98-044U 2-15-2021 1" = 15'CROSS - SECTIONAL VIEW PI-2 - PO-236 & PI-11 - PO-12 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 Jan-98Jul-98Jan-99Jul-99Jan-00Jul-00Jan-01Jul-01Jan-02Jul-02Jan-03Jul-03Jan-04Jul-04Jan-05Jul-05Jan-06Jul-06Jan-07Jul-07Jan-08Jul-08Jan-09Jul-09Jan-10Jul-10Jan-11Jul-11Jan-12Jul-12Jan-13Jul-13Jan-14Jul-14Jan-15Jul-15Jan-16Jul-16Jan-17Jul-17Jan-18Jul-18Jan-19Jul-19Jan-20Jul-20Jan-21Groundwater Elevation (ft. MSL)Time FIGURE 6 Groundwater Elevations for PI-2, PI-11, PO-12, PO-236 CF Nitrogen, Inc. Cofield, North Carolina S&ME Project No. 1040-98-044U PI-11 PO-12 PI-2 PO-236 Start Groundwater Recovery Top of Slurry Wall = 30 ft. MSL 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 Jan-98Jul-98Jan-99Jul-99Jan-00Jul-00Jan-01Jul-01Jan-02Jul-02Jan-03Jul-03Jan-04Jul-04Jan-05Jul-05Jan-06Jul-06Jan-07Jul-07Jan-08Jul-08Jan-09Jul-09Jan-10Jul-10Jan-11Jul-11Jan-12Jul-12Jan-13Jul-13Jan-14Jul-14Jan-15Jul-15Jan-16Jul-16Jan-17Jul-17Jan-18Jul-18Jan-19Jul-19Jan-20Jul-20Jan-21C-22 C-23 C-28 C-29 C-32 C-33 FIGURE 7 Groundwater Elevations for C-Designated Wells CF Nitrogen, Inc. Cofield, North Carolina S&ME Project No. 1040-98-044U Groundwater Elevation (ft. MSL)Time Top of Slurry Wall = 30 ft. MSL Start Groundwater Recovery 0 5 10 15 20 25 30 35 40 Feb-98Aug-98Feb-99Aug-99Feb-00Aug-00Feb-01Aug-01Feb-02Aug-02Feb-03Aug-03Feb-04Aug-04Feb-05Aug-05Feb-06Aug-06Feb-07Aug-07Feb-08Aug-08Feb-09Aug-09Feb-10Aug-10Feb-11Aug-11Feb-12Aug-12Feb-13Aug-13Feb-14Aug-14Feb-15Aug-15Feb-16Aug-16Feb-17Aug-17Feb-18Aug-18Feb-19Aug-19Feb-20Aug-20MWI-3 MWI-4 MWI-6 FIGURE 8 Groundwater Elevations for MWI-3, MWI-4 & MWI-6 CF Nitrogen, Inc. Cofield, North Carolina S&ME Project No. 1040-98-044U Groundwater Elevation (ft. MSL)Time Top of Slurry Wall = 30 ft. MSL Start Groundwater Recovery 1.90 4.50 2.48 5.12 3.40 1.83 2.05 6.97 5.34 4.63 6.30 2.50 3.00 3.20 2.75 5.18 1.02 3.55 5.27 4.39 0.53 2.20 2.09 1.93 3.6 3.1 4.1 3.5 3.8 4.1 4.8 4.8 4.6 3.2 3.1 3.3 0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov DecRainfall (Inches)Figure 9 Monthly Rainfall CF Nitrogen, Inc. Cofield, NC S&ME Project 1040-98-044U 2020 Rainfall 2019 Rainfall Average Monthly Rain for Cofield, NC