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HomeMy WebLinkAboutNC0025542_Fact Sheet_20210526Fact Sheet NPDES Permit No. NC0025542 Permit Writer / Email Contact: Diana Yitbarek / diana.yitbarek@ncdenr.gov Date: 5/26/2021 Division/Unit: NC DEQ Division of Water Resources / NPDES Municipal Permitting Unit Fact Sheet Template: Version 1/9/2017 Permitting Action: ❑X Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, three effluent pollutant scans, four 2nd species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA 1. Basic Facility Information Table 1. Facility Information Facility Information Applicant/Facility Name: City of Hickory/ Hickory - Catawba Wastewater Treatment Plant (WWTP) Applicant Address: PO Box 398, Hickory, N.C. 28603 Facility Address: 104 6th Avenue NE, Catawba, NC 28609 Permitted Discharge Flow: 1.5/3 0 million gallons per day (MGD) Facility Type/Waste: Major Municipal/ Domestic Facility Class: Class III (1.5 MGD)/ Class IV (3.0 MGD) Biological - 15A NCAC 08G .0302 Treatment Units: Mechanical bar screening and grit removal structures, two oxidation ditches, two secondary clarifiers, four tertiary filters, chlorine contact basin, dechlorination, cascade aerator, sludge pump station, and two sludge holding tanks Pretreatment Program (Y/N/Inactive) Inactive County: Catawba Region: Mooresville Regional Office (MRO) Permitting Action: The City of Hickory (City) applied for NPDES permit renewal for Hickory -Catawba WWTP in January 2020. The WWTP has a design capacity of 1.5 MGD and is currently authorized to discharge 1.5 MGD (up to 3.0 MGD upon obtaining authorizations) into Lyle Creek, a class WS-IV, critical area (CA) waters. The Page 1 of 16 class WS-IV denotes use as a source of water supply for drinking, culinary, or food processing purposes. The Hickory -Catawba Creek WWTP (Facility) serves about 3500 customers within the Town of Catawba and in the Southeast area of the Catawba County. The pretreatment program is inactive. Per February 22, 2021, City's email, there are no significant industrial users (SIUs) in the Facility's service area. October 30, 2019, City's cover letter for renewal application requests reducing monitoring for this Facility per 2012 DWQ Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities. February 22, 2021, City's email, clarifies the requested parameters to reduce monitoring; BOD, TSS, NH3/N, and Fecal Coliform. These requests are addressed below in this fact sheet. Facility Background: When the City purchased the Facility in 2003, the capacity of the plant was 0.225 MGD. In 2010, the City requested modification and expansion of the plant to 1.5 MGD (phase I) and 3.0 MGD (phase II). The old facility was demolished, and phase I expansion was completed in August 2015. At the present time, this fact sheet assessment is based on a wastewater plant flow of 1.5 MGD. 2. Receiving Waterbody Information: Table 2. Receivin Waterbodv Information Outfalls/Receiving Stream(s): Outfall 001 [35°42'55.3"N 81°04'25.8"W]/Lyle Creek Stream Segment/Assessment Unit (AU): 11-76-(4.5) Stream Classification: WS-IV, CA Drainage Area (mi2): 72.8* Summer 7Q10 (cfs) 13* Winter 7Q10 (cfs): 19* 30Q2 (cfs): 27.62* Average Flow (cfs): 80* Instream Waste Concentration (IWC) (% effluent): 15 % at 1.5 MGD (7Q10S) 26 % at 3.0 MGD (7Q10S) 303(d) listed/parameter: No Subject to TMDL/parameter: Yes/Mercury Statewide TMDL implemented in 2012 Basin/Sub-basin/ Hydrologic unit code (HUC): Catawba River Basin/03-08-32/03050101 USGS Topo Quad/State Grid: Catawba/E14NE *Statistical data taken from the previous fact sheet per Division's guideline. Lyle Creek is a little over 20 miles in total length and is split into three segments. The creek begins in the City of Hickory, flows east through the City of Conover and into Lake Norman at the Town of Catawba. Between the municipalities, the creek drains agricultural land. Since 1992, the biological community has been stable but of moderate quality. The benthic site had the highest specific conductivity level (122 µS/cm) of any other site in this and surrounding watersheds in 2007. For more information, see the 2010 Catawba River Basinwide Water Quality Plan. Page 2 of 16 3. Effluent Data Summary Effluent data for Outfall 001 is summarized below from June 2016 through December 2020. Table 3. Effluent Data Summary with permit limits Outfall 001. Parameters listed as in the last permit. Parameter Units Average Max. Min. Permit Limit Flow MGD 0.08 0.87 0.02 MA 1.5 MGD BOD5 mg/1 2.5 14 2.0 MA 10.0 mg/I WA 15.0 mg/I NH3N mg/1 0.70 10.3 0.01 MA 2.0 mg/I WA 6.0 mg/I Total Suspended Solids (TSS) mg/1 3.7 30.0 2.5 MA 30.0 mg/I 45.0 mg/I Dissolved Oxygen (DO) mg/17.9 15.10 5.10 DA >_ 5.0 mg/I Fecal Coliform #/100 ml 2.06 (Geomean) 3600.00 1.00 MA 200/100m1 WA 400/100m1 pH SU 6.9 9.0 6.0 6.0 < pH < 9.0 Total Residual Chlorine (TRC) µg/1 20 20 20 DM 28.00 pg/I Temperature °C 18.5 29 3.7 Total Zinc µg/1 70.1 430.0 27.8 Bis (2-Ethylhexyl) Phthalate µg/l 5.25 9.20 4.90 Total Hardness [as CaCO3] m n g 47.5 66.3 37.2 Total Nitrogen (TN) mg/1 4.9 14.0 0.73 Total Phosphorus (TP) mg/11.72 5.20 0.12 *MA -Monthly Average, WA -Weekly Average, DM -Daily Maximum, DA=Daily Average. Table 4 Summary of Conductivity values from May 2016 to October 2016 at Outfall 001 Parameter Units Average Max Min. Conductivity µmho/cm 541.6 1209.0 55.0 Table 5. Effluent Data Summary from expanded effluent pollutant scan at Outfall 001 Parameter Units Average Max. Chloroform µg/1 37.9 78.5 Copper µg/1 17.5 24 Dichlorobromomethane 1.1g/1 7.5 17.8 Lead µg/1 0.15 0.15 Methyl Bromide µg/1 4.4 11.7 Mercury* ng/1 2.9 5.5 *See section 6.6 Mercury Statewide Total Maximum Daily Load (TMDL) Evaluation Page 3 of 16 Sample results for the sampled metals not included above, such as antimony, arsenic, beryllium, cadmium, chromium, cyanide, nickel, selenium, silver, and thallium, were less than the method detection limit. The compounds in the above table were analyzed in the reasonable potential analysis (RPA) and discussed below in the RPA section of this fact sheet. Given the former conductivity results (>1000 µmho/cm) and the results from the expanded effluent pollutant scan, the reissued permit will include a condition to conduct an industrial waste survey (IWS) to identity and control potential pollutant sources. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example, 1) to verify model predictions when model results for instream DO are within 1 mg/1 of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future total maximum daily load (TMDL); 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). Instream data summary and instream monitoring proposed for this permit action: 1. The current permit requires instream [upstream (U) and downstream (D)] monitoring for dissolved oxygen (DO), temperature, total nitrogen, total phosphorous, and chlorophyll A. Monitoring of upstream hardness is required as well. The U sampling location is at Highway 10, about 1000 feet from the outfall. The D sampling location is at Marina off Canvasback Ln, about 4000 feet from the outfall. Instream monitoring requirements for total nitrogen, total phosphorous, and chlorophyll A were added per the recommendation of the Modeling and Assessment Branch. Catawba River Nutrient Management Strategy requires limiting nutrients from any expanding discharger to avoid potential over -allocation in Lake Norman. The facility started conducting instream sampling for total nitrogen, total phosphorous and chlorophyll A after expansion to 1.5 MGD. The figures below summarizes instream and effluent (Eff) data from the analyzed period, September 2016 - September 2020. Figure 1. Average, maximum, and minimum instream and effluent data summary for T, DO, TN, and TP 35.0 30.0 25.0 20.0 15.0 10.0 5.0 0.0 Temperature, C Upstream Effluent Downstream ■ Average 17.9 18.5 19.6 • Max 27.0 29.0 28.0 • Min 0.0 3.7 2.8 18.0 16.0 14.0 12.0 10.0 8.0 6.0 4.0 2.0 0.0 DO, mg/I Upstream Effluent Downstream ■ Average 7.4 8.0 6.8 • Max 15.4 15.1 15.9 • Min 1.4 5.1 1.4 Page 4 of 16 35.0 30.0 25.0 20.0 15.0 10.0 5.0 0.0 Total Nitrogen, mg/I Total Phosphorus, mg/I Upstream Effluent Downstream ■ Average 1.3 7.3 1.0 • Max 4.6 30.0 7.3 • Min 0.3 0.9 0.2 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 Upstream Effluent AL Downstream ■ Average 0.3 2.8 0.3 • Max 0.7 6.4 1.4 • Min 0.3 0.3 0.3 T-tests were run to analyze relationships between instream sample results. A statistically significant difference is determined when the t-test p-value result is < 0.05. Temperature: The maximum downstream temperature was 28 degrees Celsius, and the maximum temperature differential between the upstream and downstream samples was seven degrees Celsius. It was concluded that there is a statistically significant difference between the upstream and downstream temperatures. DO: The minimum downstream DO detected was 1.4 mg/1 on 9/21/2016, and the maximum DO differential between the upstream and downstream samples was 10.7 mg/1. The downstream and upstream DO were detected below 5.0 mg/1 57 and 19 times, respectively. It was concluded that there is a statistically significant difference between upstream and downstream DO. Total Nitrogen (TN): The maximum downstream TN detected was 7.3 mg/1. It was concluded that there is a statistically significant difference between upstream and downstream TN. Total Phosphorous (TP): The maximum downstream TP detected was 1.4 mg/1. It was concluded that there is no statistically significant difference between upstream and downstream TP. Figure 2. Average, maximum, and minimum upstream and downstream data summary for Chlorophyll A 16.0 14.0 12.0 10.0 8.0 6.0 4.0 2.0 0.0 Chlorophyll A, µg/I 1 Upstream Downstream ■ Average 8.5 9.3 • Max 14.4 14.9 • Min 2.0 2.0 Chlorophyll A: The maximum downstream chlorophyll A detected was 1.4 mg/l. It was concluded that there is a statistically significant difference between upstream and downstream chlorophyll A. The nutrient and chlorophyll A data collected provide useful information for nutrient criteria development. Page 5 of 16 Figure 3. Average, maximum, and minimum instream and effluent data summary for Fecal Coliform 7000.0 6000.0 5000.0 4000.0 3000.0 2000.0 1000.0 0.0 Fecal Coliform, #/100 ml Upstream Effluent Downstream • GeoMean 442.5 2.1 452.6 • Max 6000.0 3600.0 6000.0 • Min 88.0 1.0 11.0 Instream monitoring for fecal coliform was removed in the previous permit cycle, 2016, as the receiving body is not listed as impaired for fecal coliform. The Permittee has voluntarily collected instream fecal coliform samples. Fecal Coliform: The maximum upstream and downstream fecal coliform detected was 6000/100 ml. The maximum effluent fecal coliform detected was 3600/100 ml. After running the T-test, it was concluded that there is no statistically significant difference between upstream and downstream fecal coliform. Hardness: Effluent hardness and instream hardness sampling, upstream of the discharge are being sampled at a monitoring frequency of quarterly. Is this facility a member of a Monitoring Coalition with waived instream monitoring (Y/N): N Name of Monitoring Coalition: NA 5. Compliance Summary From January 2016 to January 2021, the Facility received a total of five notices of violation (NOVs) for exceeding monthly average (MA) and weekly average (WA) limits for ammonia and not reaching the daily minimum (Dmin) for DO. The Facility also received six Enforcement Cases for exceeding MA and WA limits for ammonia. The MRO representative, Wes Bell, is working with the Facility to monitor the Facility's compliance performance. The report on limit violations that proceeded to NOV or Enforcement Case were as follows: • Ammonia - 6 MA limit exceedances and 4 WA limit exceedances. The maximum MA limit exceedance was 5.2 mg/1 and the maximum WA limit exceedance was 8.9 mg/1, both in 2020. • DO - 1 Dmin not reached in 2017. Summary of the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The Facility passed seventeen of eighteen quarterly chronic toxicity tests from February 2016 to May 2020. February 2017 test failed, therefore multiple -concentration testing were performed in each of the two following months (March and April 2017) as described in North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure. The results of these follow-up tests were acceptable. The Facility complied with all 2nd species WET tests. The four 2nd species tests were performed in November 2018, February 2019, May 2019, and August 2019. Page 6 of 16 Summary of the results from the most recent compliance inspection: The last facility inspection conducted in January 2021 by Wes Bell rated the facility as very reliable and reported one compliance issue regarding the influent sampling. The ORC and staff are aware and are looking for a new influent sampling location above all side streams. 6. Water Quality -Based Effluent Limitations (WQBELs) 6.1 Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following stream flows are used for dilution considerations for development of WQBELs: 1Q10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). Stream flow values were extracted from the previous fact sheets (2010 and 2015). In 2010, the 7Q10 and average annual flow were updated. If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with 15A NCAC 2B. 0204(b): NA 6.2 Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/1 for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: The current permit limits for BOD are based on a Water Quality Analysis Simulation Program (WASP) model run for the proposed wasteflow of 3.0 MGD in 2007. The model and its documentation were reviewed by DWQ's Modeling and TMDL Unit (MTU), and a technical memorandum were submitted in May 2008. It was determined that based on the model results for a 3.0 MGD flow that limits consistent with tertiary treatment and effluent aeration is the most viable option for consideration of an expansion of discharge into Lyle Creek. With the issuance of speculative limits, it was recommended that frequent monitoring be required downstream of the discharge to ensure that DO levels do not fall below 5.0 mg/1. No changes for DO nor BOD are proposed for this permit cycle. 6.3 Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/1 (summer) and 1.8 mg/1 (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/1) and capped at 28 ug/1 (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/1 are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: Ammonia: There are no proposed changes for ammonia. The current permit sets MA (2.0 mg/1) and WA (6.0 mg/1) limits for ammonia for the 1.5 MGD flow tier, and sets summer and winter MA and WA limits for ammonia for the 3.0 MGD flow tier [summer, MA (1.0 mg/1) and WA (3.0 mg/1) and winter MA (2.0 mg/1) and WA (6.0 mg/1)]. In previous permit cycles a WASP model indicated that BOD5 and NH3 had been over allocated in Lyle Creek under prior wasteload allocation (WLA) procedures. The modeling was done to Page 7 of 16 establish NPDES permit limits for the Town of Conover WWTP (discharging upstream of Catawba) to protect the DO standard and was used to guide recommendation for future expansions and new facilities in the Lyle Creek watershed. Expanding facilities in the Lyle Creek watershed received and will receive BOD and NH3 limits that will hold their load of oxygen consuming waste constant. WASP model results predicted that at 3.0 MGD limits of BOD5 = 5 mg/1 and NH3 = 2 mg/1 would protect dissolved oxygen in Lyle Creek. The limits at 1.5 MGD would be year round limits with no differentiation during the summer and winter months. The ammonia limits will be the same as the previous permit cycle. With this permit renewal, the City requested monitoring frequency reduction for ammonia. Upon performing the monitoring reduction in frequency evaluation from a period of three years (12/2017 to 12/2020), this facility has received four non -monthly average limit violations in the past year for ammonia; therefore, this facility does not meet the approval criteria for monitoring reduction for ammonia TRC: The facility uses chlorination as its primary disinfection. The current permit limits TRC at 28 ug/L as a daily maximum for 1.5 and 3.0 MGD. The facility is considered compliant with its permit since all reported values were 20 ug/L. The Division recommends verifying equipment calibration protocols. No changes are proposed for TRC 6.4 Reasonable Potential Analysis (RPA) for Toxicants The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of Y2 detection limit for "less than" values; and 4) stream flows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation oflnstream Dissolved Metals Standards, dated June 10, 2016. The RPAs were conducted for permitted flows of 1.5 MGD and 3.0 MGD with a 7Q10S of 13 cubic feet per second (cfs) and site -specific hardness values on the effluent toxicant data collected in the Permittee's 2016 to 2020 effluent pollutant scans and DMRs. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. The data set was limited for arsenic, beryllium, cadmium, chromium, cyanide, lead, nickel, selenium, silver, chloroform, methyl bromide, and dichlorobromomethane. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: For the 3.0 MGD flow tier: Bis(2-ethylhexyl) phthalate • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: For 1.5 MGD: Zinc, copper , bis(2-ethylhexyl) phthalate, and dichlorobromomethane (based on a limited dataset. No value exceeded the Allowable discharge concentration) For 3.0 MGD: Zinc, copper • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, molybdenum, nickel, silver, selenium, tin, titanium, vanadium, and total phenolic compounds. Page 8 of 16 • POTW Effluent Pollutant Scan Review: Five effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: For 1.5 MGD: Methyl bromide For 3.0 MGD: Methyl bromide and dichlorobromomethane o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: NA • Additional notes: o Silver: The City of Hickory reported total silver at less than detection, with detection levels of < 5.0 µg/L and < 0.5 µg/L, in the Effluent Pollutant Scans. Based on the RPA, the City's total silver allowable discharge concentrations are 0.395 µg/L for 1.5 MGD and 0.228 µg/L for 3.0 MGD. 15A NCAC 2B .0505 (e) (4) requires that all test procedures must produce detection and reporting levels that are below the permit discharge requirements, and all data generated must be reported to the approved detection level or lower reporting level of the procedure. If no approved methods can achieve a detection level below the permit discharge requirement (or allowable discharge concentration) the method with the lowest detection level must be used. The City should use sufficiently sensitive test methods for all pollutants, including when performing Effluent Pollutant Scans. Failure to use the lowest silver detection value may result in the inclusion of effluent monitoring for silver at the next permit renewal. 6.5 Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This is a Major Publicly Owned Treatment Work (POTW), and a chronic WET limit will continue on a quarterly frequency at Outfall 001 at 15% at 1.5 MGD using Ceriodaphnia dubia. For the 3.0 MGD flow tier, a quarterly chronic WET limit would apply at 26% effluent concentration, using Ceriodaphnia dubia, as well. 6.6 Mercury Statewide Total Maximum Daily Load (TMDL) Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year) and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging multiple quantifiable levels of mercury (>1 ng/1) received an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/1. A mercury evaluation was conducted in accordance with the Permitting Guidance developed for the implementation of the statewide Mercury TMDL to determine the need for a limit. Below find summaries of Page 9 of 16 compliance mercury data from 2016 to 2020. Based on the dataset, the water quality -based effluent limitation (WQBEL) for mercury is 79.1 and 45.5 ng/1 for 1.5 MGD and 3.0 MGD. Table 6. Mercury Effluent Data Summary - 1.5 MGD 2016 2017 2018 2019 2020 # of Samples 1 1 2 2 Mercury Annual Average (ng/1) 2.3 3.4 3.0 1.29 1.77 Mercury Annual Max (ng/1) 2.29 3.37 3.18 1.695 1.77 TBEL (ng/1) 47 WQBEL (ng/1) 79.1 Table 7. Mercury Effluent Data Summary - 3.0 MGD 2016 2017 2018 2019 2020 # of Samples 1 1 2 2 1 Mercury Annual Average (ng/1) 2.3 3.4 3.0 1.29 1.77 Mercury Annual Max (ng/1) 2.29 3.37 3.18 1.695 1.77 TBEL (ng/1) 47 WQBEL (ng/1) 45.5 Describe proposed permit actions based on mercury evaluation: Mercury evaluation results used EPA Method 1631E. No annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL. The maximum value reported in this period was 3.37 ng/1. No mercury limit is required. The mercury minimization plan (MMVIP) will continue to be required under the 3.0 MGD flow tier because multiple quantifiable levels (> 1 ng/L) of mercury were reported, and this flow tier is > 2 MGD. 6.7 Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: Effluent and instream monitoring for total nitrogen (TN) and total phosphorous (TP) have been included in the permit per 15A NCAC 02B .0508 for Effluent and recommendation of Basin Planning Section for instream monitoring. The permit reflects the monthly nutrient (TP and TN; TKN + NO3-N + NO2-N) monitoring for 1.5 MGD and 3.0 MGD flows. Annual nutrient TN and TP loads: The TN and TP annual loads were calculated with the monthly monitoring reported during Jan 2017 to Dec 2020. The Facility is currently operating at a flow limit of 1.5 MGD and there is a proposal to increase it to 3.0 MGD. Page 10 of 16 Table 8. Nutrients Effluent Data Summary Parameter 2017 2018 2019 2020 Annual TN load, lb/yr 1,137 1,355 1,219 2,067 Annual TP load, lb/yr 507 603 711 569 6.8 Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107(c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: Based on the RPA predicting a maximum effluent methyl bromide concentration that is greater than the allowable discharge concentration based on state water quality standards, monthly monitoring for methyl bromide has been added to the permit [See A. (1) and A. (2)]. To provide an opportunity for the City to develop a plan to assess sources of methyl bromide in order to come in compliance with the limits in Section A. (1.), a 3-year schedule of compliance has been added to the permit. Since the methyl bromide limit is below its current PQL (< 2 µg/L), to show compliance with the limit, the Division expects non -detects at the PQL (unless the PQL changes before May 25, 2024, and the Permiee can show compliance with the limit). If applicable, describe any water quality standards variances proposed in accordance with NCGS 143-215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/1 BOD5/TSS for Monthly Average, and 45 mg/1 for BOD5/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BOD5/TSS included in the permit? YES If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge) The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105( c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA Page 11 of 16 9. Antibacksliding Review Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: NA 10.Monitoring Frequency Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. The facility met the approval criteria for monitoring reduction for BOD, TSS, and Fecal Coliform; therefore, the monitoring frequency for these parameters was changed from 3/Week to 2/Week for both effluent and influent where applicable. As mentioned in Section 6.3 of this fact sheet, with this permit renewal, the City requested monitoring frequency reduction for ammonia. Upon performing the monitoring reduction frequency evaluation from a period of three years (12/2017 to 12/2020), this facility has received four non -monthly average limit violations in the past year for ammonia; therefore, this facility does not meet the approval criteria for monitoring reduction for ammonia For instream monitoring, refer to Section 4. 11.Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. While NPDES regulated facilities would initially be required to submit additional NPDES reports electronically effective December 21, 2020, EPA extended this deadline from December 21, 2020, to December 21, 2025. The current compliance date, effective January 4, 2021, was extended as a final regulation change published in the November 2, 2020 Federal Register This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12.Summary of Proposed Permitting Actions Table 9. Current Permit Conditions and Proposed Changes for 1.5 MGD and 3.0 MGD Parameter Current Permit Limits and Monitoring Frequency Proposed Change Basis for Condition/Change Flow MA 1.5 MGD and 3.0 MGD Continuous monitoring No changes 15A NCAC 2B .0505 The average flow for the past five years was less than 1.15 MGD Page 12 of 16 BOD5 For 1.5 MGD MA 10.0 mg/I WA 15.0 mg/I For 3.0 MGD Summer: MA 5.0 mg/1 WA7.5mg/1 Winter: MA 10.0 mg/I WA 15.0 mg/I 3/week for 1.5 MGD Daily for 3.0 MGD Monitoring frequency decreased to 2/week for 1.5 MGD Waste load allocation for plant expansion based on WASP Model Monitoring according to 15A 02B. 0508 2012 DWQ Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities TSS For 1.5 MGD and 3.0 MGD MA 30 mg/1 WA 45 mg/1 3/week for 1.5 MGD Daily for 3.0 MGD Monitoring frequency decreased to 2/week for 1.5 MGD TBEL. Secondary treatment standards/40 CFR 133 / 15A NCAC 2B .0406. 2012 DWQ Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities NH3-N For 1.5 MGD MA 2.0 mg/I WA 6.0 mg/1 For 3.0 MGD Summer: MA 1.0 mg/1 WA 3.0 mg/1 Winter: MA 2.0 mg/1 WA 6.0 mg/I 3/week for 1.5 MGD Daily for 3.0 MGD No changes Waste load allocation for plant expansion based on WASP Model Monitoring according to 15A 02B .0508 DO For 1.5 MGD and 3.0 MGD DO shall not be less than 6 mg/1 Monitor and report effluent 3/week for 1.5 MGD Daily for 3.0 MGD Monitor and report instream for 1.5 MGD and 3.0 MGD at a variable** frequency No changes Based on a water quality model to protect DO levels in Lyle Creek Monitoring according to 15A 02B. 0508 Page 13 of 16 Fecal coliform (Geometric Mean) MA 200 /100m1 WA 400 /100m1 for 1.5 MGD and 3.0 MGD 3/week for 1.5 MGD Daily for 3.0 MGD Monitoring frequency decreased to 2/week for 1.5 MGD WQBEL. State WQ standard, 15A NCAC 2B .0200. 2012 DWQ Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities pH 6 - 9 S.U. for 1.5 and 3.0 MGD 3/week for 1.5 MGD Daily for 3.0 MGD No changes WQBEL. State W.Q. standard, 15A NCAC 2B .0200 TRC DM 28.0 µg/I for 1.5 MGD and 3.0 MGD 3/week for 1.5 MGD Daily for 3.0 MGD No changes WQBEL. State WQ standard, 15A NCAC 2B .0200. The Division considers all effluent TRC values reported below 50 ug/1 to be in compliance with the permit. Temperature Monitor and report effluent daily for for 1.5 MGD and 3.0 MGD Monitor and report instream for 1.5 MGD and 3.0 MGD at a variable** frequency No changes 15A NCAC 2B.0200 and 15A NCAC 2B.0500 Total Copper Quarterly monitoring for 3.0 MGD Added quarterly monitoring for 1.5 MGD and keeping quarterly monitoring for 3.0 MGD Based on RPA. Predicted Max >_ 50% of Allowable Cw Total Zinc Quarterly monitoring for 1.5 MGD and 3.0 MGD No changes Based on RPA. Predicted Max > 50% of Allowable Cw Total Lead Quarterly monitoring for 3.0 MGD Removed quarterly monitoring for 3.0 MGD Based on RPA. Predicted Max < 50% of Allowable Cw Bis(2-ethylhexyl) Phthalate Quarterly monitoring for 1.5 MGD Monthly monitoring for 3.0 MGD MA: 6.1 µg/I Updated MA limit for 3.0 MGD as 5.8 µg/I Based on RPA. Predicted Max > 50% of Allowable Cw EPA National Recommended Water Quality Criteria for Human Health Page 14 of 16 Methyl Bromide None Added monthly monitoring for 1.5 MGD and MA limit: 0.26 µg/I Added monthly monitoring for 3.0 MGD and MA limit: 0.15 µg/I 3-year schedule of compliance has been added to the permit for 1.5 MGD Based on RPA. RP exists. Predicted Max > Allowable Cw. 5 values > Allowable Cw North Carolina In -Stream Target Values for Surface Waters Dichlorobromomethane None Added quarterly monitoring for 1.5 MGD Added monthly monitoring for 3.0 MGD and MA limit: 17.3 µg/I Based on RPA. RP exists. Predicted Max > Allowable Cw North Carolina In -Stream Target Values for Surface Waters Total Hardness Quarterly monitoring upstream and in effluent for 1.5 MGD and 3.0 MGD No changes Hardness -dependent dissolved metals water quality standards approved in 2016 Total Nitrogen (TN) Monitor and report effluent monthly for for 1.5 MGD and 3.0 MGD Monitor and report instream for 1.5 MGD and 3.0 MGD at a variable** frequency No changes 15A NCAC 02B .0508 for Effluent and recommendation of Basin Planning Section for instream monitoring Total Phosphorus (TP) Monitor and report effluent monthly for for 1.5 MGD and 3.0 MGD Monitor and report instream for 1.5 MGD and 3.0 MGD at a variable** frequency No changes 15A NCAC 02B .0508 for Effluent and recommendation of Basin Planning Section for instream monitoring Page 15 of 16 Chlorophyll A For 1.5 MGD and 3.0 MGD monitor and report instream at a variable** frequency No changes Per recommendation of Basin Planning Section for instream monitoring Chronic Toxicity Test Chronic limit, 15% at 1.5 MGD or 26% at 3.0 MGD No changes WQBEL. No toxics in toxic amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 Effluent Pollutant Scan Three times per permit cycle for 1.5 MGD and 3.0 MGD Next scans must be performed in each of the following years: 2023, 2024, and 2025. 40 CFR parts 423 and 122 Mercury Minimization Plan (MMP) MMP required for 3.0 MGD No changes Consistent with EPA approved 2012 Statewide Mercury TMDL Electronic Reporting Electronic reporting special condition for 1.5 MGD and 3.0 MGD Added language for new electronic reporting deadline December 21, 2025 In accordance with EPA Electronic Reporting Rule 2015 and Rule -Phase 2 Extension *MA - Monthly Average, WA - Weekly Average, DM - Daily Max. * * Variable monitoring frequency for total nitrogen, total phosphorous, and chlorophyll a is defined as follows: twice per month during June 1 through September 30 and monthly from October 1 through May 31. Variable monitoring frequency for dissolved oxygen and temperature is defined as follows: Samples collected three times per week during June 1 through September 30 and once per week October 1 through May 31. 13.Public Notice Schedule Permit to Public Notice: April 7, 2021 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14.Fact Sheet Addendum (if applicable) Were there any changes made since the Draft Permit was public noticed (Yes/No): No If Yes, list changes and their basis below: NA 15.Fact Sheet Attachments (upon request) 1. RPA Sheets Summary for 1.5 and 3.0 MGD. Each sheet contains: input information tab, data analyzed tab, and results summary tab. 2. BOD and TSS Removal Rate calculations 3. Data Summary for Reduced NPDES Permit Monitoring Reduction Frequency Assessment 4. NH3/TRC/Fecal Waste Load Allocation (WLA) Spreadsheet for 1.5 and 3.0 MGD 5. Mercury TMDL Calculations for 1.5 and 3.0 MGD 6. Toxicity Summary/WET testing 7. Instream data summary and ttest 8. Monitoring Report Violations summary 9. Compliance Evaluation Inspection 10. Renewal Application Addendums - Addendum Form 2A 11. Correspondence 12. NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards 13. Signed effluent pollutant scans 14. Public Water Supply memo 15. Affidavit Page 16 of 16 Metal Translator /95% Confidence Usi 95% Probabili Q a Freshwate MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 2. Parameters of Concern 0 E L 0 c) w .O a w a) O U ❑ CHECK IF HQW OR ORW WQS J O) 7 J O) 7 J O) 7 J O) 7 —I 0) E J O) 7 J O) 7 J O) 7 J_ O) 1 J_ O) 1 J O) 7 J O) 7 J O) 7 J O) 7 J_ 0) C J O) 7 J O) 1 J O) 1 J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J_ O) 1 0 N— (n 0 O COCOZ N/A 4.2005 1154.8102 N O CO ODN L0 V 0 O 431.1483 Z 0.4944 161.7457 LL = 2 LLLL LL > Q Q LL LL LL LL LL LL LL LL > LL > LL LL LL 5j 1 u 0 CO 0 0 300 148.6191 Z O 0 In 1,800 4.0489 CO 47.3612 25.0000 In CO O O 161.2745 cv Mo 0.04 0 0 0 z 0 z 0 z 0 z 0 z 0 z 0 z 0 z 0 z 0 z 0 z 0 z 0 z 0 z 0 z O z 0 z 0 z 0 z O z 0 O z Aquactic Life Human Health Water Supply Aquatic Life Aquatic Life Water Supply Water Supply Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Water Supply Aquatic Life Water Supply Aquatic Life Aquatic Life Aquatic Life Water Supply Human Health Aquatic Life Arsenic Arsenic Beryllium Cadmium Chlorides Chlorinated Phenolic Compounds Total Phenolic Compounds Chromium III Chromium VI Chromium, Total Copper Cyanide Fluoride Lead Mercury Molybdenum Nickel Nickel E .c T.) N > u U c Chloroform Bis(2--ethylhexyl) phthalate Methyl Bromide T N M l() f0 W W 0 N M l() f0 fs W O • N M O O O 0 0 0 0 0 NNNNN a • a • a • a • a • a • a • a • a a a a a a a • a • a • a • a • a • a • a • a • a WWI Hickory -Catawba VWVTP NC0025542 0 O 0 a) a) 0 a) > J O O 0 O 0 Facility Name WWTPIWTP Class NPDES Permit 0 Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ❑✓ Apply WS Hardness WQC O 0 () 0 CO N 0 0 co 0 N w N • w u w 45 co)O O N V� O 55005 47.49 mg/L (Avg) 30.68 mg/L (Avg) J 0) E co Effluent Hardness Upstream Hardness Combined Hardness Chronic Combined Hardness Acute N a) L 0 co R w 0 0 a 0 0 w 0 Outfall 001 a Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators 2 Z MAXIMUM DATA POINTS = 58 COMBINED HARDNESS WWTP/WTP Class: III 17.76843714 z Ill U K 1- a a w a CO zw 0I Ill 4 = 7 ce Ill 1- N 7.76423443 Effluent Hard: 0 value > 100 mg/L Effluent Hard Avg = 47.49 mg/L 1- oa ✓ Q csi U N ▪ N oa c4 rj` N O O 10 O CO O 0 2 RECOMMENDED ACTION Limited dataset. No RP, Predicted Max < 50 % of Allowable Cw - No Monitoring required, other than pollutant scan (PS) A- ll values in limited dataset reported non -detect < 1 ug/L - No Monitoring required, other than PS. No - RP, Predicted Max < 50 % of Allowable Cw - No Monitoring required, other than PS. N- o RP, Predicted Max < 50 % of Allowable Cw - No Monitoring required, other than PS. h See Chromium, Total See Chromium, Total a: No monitoring required other than PS if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. Pr- edicted Max > 50% Allowable Cw. No value > Allowable Cw. Apply Quarterly Monitoring REASONABLE POTENTIAL RESULTS ri # Det. Max Pred Cw Allowable Cw Acute (FW): 1,913.5 Chronic (FW) 988.7 Max MDL = 10 Ch_ _ ronic (HH) 354.1 Max MDL = 10 Acute: 365.82 Chronic: 42.84 Max MDL = 1 Acute: 23.640 Chronic: 4.821 Max MDL = 1 Acute: NO WQS Chronic: 12.9 Max MDL = 0.1 Acute: 6,499.2 Chronic: 979.6 Acute: 90.0 Chronic: 72.5 knowable Cw Max reported value = 2.5 Max MDL = 5 Acute: 78.00 Chronic: 66 24 No value > Allowable Cw Acute:—_—_—_123.8 a) E. U 2 1.16 C.V. (default) NO DETECTS 1.160 C.V. (default) NO DETECTS 0.1 C.V. (default) NO DETECTS a u h Al L r 5 0 Note: n < 9 Limited data set 5 0 Note: n < 9 Limited data set 5 0 Note: n < 9 Limited data set 5 0 Note: n < 9 Limited data set O 0 O 0 Tot Cr value 5 0 Note: n < 9 Limited data set 7 N, O v sewn t,, t. t. t. t. t. t. t. t. t. 7bd o NC STANDARDS OR EPA CRITERIA Chronic Applied Acute Standard 150 FW(7Q10s) 340 10 HH/WS(Qavg) v, o a w 0.7315 FW(7Q10s) 4.2005 1 A(30Q2) 148.6191 FW(7Q10s) 1154.8102 11 FW(7Q10s) 16 10.0491 FW(7Q10s) 13.8602 N N o_ a w v, 111 U U Z Z Z Z Z Z Z z PARAMETER Arsenic Arsenic E 0 m Cadmium Chlorinated Phenolic Compounds Chromium III Chromium VI Chromium, Total Copper a 72 Outfall 001 I I CY L O 4- C E4 L r 4- C0 C y 0 0 C 0 as U 0) O L a 0) a cc L 0 4- as N L u_ Limited taN daset. o P R, Prd Maxedicte< 5-0% of Allowable Cw - No Monitoring required, other than pollutant scan (PS) Li- mited dataset. No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required, other than pollutant scan (PS) No - RP. All values reported non -detect < 5 ug/L Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS No RP. Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS Predicted Max > Allowable Cw. Limited dataset. No detects. Method with the lowest PQL must be used Predicted Max > 50% of Allowable Cw. No value > Allowable Cw. Continue Quarterly Monitoring - ---------------------------- Predicted Max > 50% of Allowable Cw. Limited dataset. No value > Allowable concentration. Pr- edicted Max > 50% of Allowable Cw. No value > Allowable concentration. Continue Quarterly Monitoring R- P exists. Predicted Max > Allowable Cw , 5 value(s) > Allowable Cw. Monitor monthly and add permit limit Acute: NO WQS 0.55 WS(Qavg) µg/L 5 3 41.29600 _____ _______________________ Note: n <9 C.V. (default) Chronic: 19.47473 RP exists. Predicted Max > Allowable Cw, no value > Limited data set No value> Allowable Cw Allowable Cw, limited data set. Apply Quarterly Monitoring Chronic: 33.0 Max MDL = 10 Acute: 593.364 Chronic: 26.688 No value > Allowable Cw Acute (FW): 2,426.5 Chronic (FW): 312.2 Max MDL =5 Chronic (WS): 164.8 Max MDL = 5 Acute: 315.2 Chronic: 33.0 Max MDL = 10 Acute: 2.783 Chronic: 0.395 Max MDL = 5 Acute: 910.3 Chronic: 1,063.0 No value > Allowable Cw Acute: NO WQS Chronic: 395 484 No value > Allowable Cw Acute: NO WQS Chronic: 11.33075 No value > Allowable Cw Acute: NO WQS Chronic: 0.26366 5 value(s)> Allowable Cw C.V. (default) NO DETECTS 5.800 C.V. (default) U 0.`+. w N 'O Q v O 11.6 C.V. (default) NO DETECTS 5.800 C.V. (default) NO DETECTS 7 O , 182.12000 C.V. (default) 12.97200 27.14400 C.V. (default) Note: n < 9 Limited data set 5 1 Note: n < 9 Limited data set t T cl VI'a C 1y V z I- 5 0 Note: n < 9 Limited data set 5 0 Note: n < 9 Limited data set M M 5 4 Note: n < 9 Limited data set - 5 2 Note: n < 9 Limited data set 4.0489 FW(7Q10s) 105.4315 47.3612 FW(7Q10s) 431.1483 25.0000 WS(7Q10s) 0 a w 0.06 FW(7Q10s) 0.4944 161.2745 FW(7Q10s) 161.7457 0 a o 0.32 HH(Qavg) 0.04 FW(7Q10s) Z Z Z Z Z Z Z C.)Z C.) ' 'p W J W W Y Y U U Selenium W jq U C N Chloroform Bis(2--ethylhexyl) phthalate Methyl Bromide Dichlorobromomethane co O a Metal Translator /95% Confidence Usi 95% Probabili Q a Freshwate MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 2. Parameters of Concern 0 cts E 0 cts c) w .O a a) O L U ❑ CHECK IF HQW OR ORW WQS J O) 7 J O) 7 J O) 7 J O) 7 -I 0) E J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J O) 7 J O) 7 J O) 7 J O) 7 J_ 0) C J O) 7 J O) 1 J O) 1 J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J_ O) 1 0 N- LO 0 p V CO N/A Ln 4.4269 M O0 (M N CO Q Z 14.6681 N N 112.7685 453.6479 Q Z CO in 0.5483 0) 0) O u_2 i 2 LL LL > Q Q LL LL LL LL LL LL LL LL > L�L > LLI)�L L�L L�L 5j 1 1 L_ O O (6 0.7625 O 300 155.4680 z 10.5327 U) 1,800 4.3060 (N 8 49.6174 25.0000 1C) 00 0 168.9694 co o 0.04 0 0 0 Z 0 Z 0 Z 0 Z 0 Z 0 Z 0 Z 0 Z 0 Z 0 Z 0 Z O Z 0 Z 0 Z 0 Z O Z 0 Z 0 Z 0 Z O Z 0 O Z Aquactic Life Human Health Water Supply Aquatic Life Aquatic Life Water Supply Water Supply Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Water Supply Aquatic Life Water Supply Aquatic Life Aquatic Life Aquatic Life Water Supply Human Health Aquatic Life Arsenic Arsenic Beryllium Cadmium Chlorides Chlorinated Phenolic Compounds Total Phenolic Compounds Chromium III Chromium VI Chromium, Total Copper Cyanide Fluoride Lead Mercury Molybdenum Nickel Nickel E 3 .c T.) 0) N, > U c Chloroform Bis(2--ethylhexyl) phthalate Methyl Bromide T N M W O N- CO M 0 N M V W O N OO 07 O • N M O O O 0 0 0 0 0 NNNNN a • a • a • a • a • a • a • a • a a a a a a a • a • a • a • a • a • a • a • a • a WWI Hickory -Catawba VWVTP > NC0025542 0 O 0 O 4) 2 0 J O O co O 0 ch Facility Name WWTPIWTP Class NPDES Permit 0 Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ❑✓ Apply WS Hardness WQC O 0 0 CO N 0 0 co 0 V) w N (.) u w (i u w O • O N V� O 55005 47.49 mg/L (Avg) 30.68 mg/L (Avg) J 0) E 1 () J 0) E L() co Effluent Hardness Upstream Hardness Combined Hardness Chronic Combined Hardness Acute w 0 0 a 0 0 w 0 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 COMBINED HARDNESS WWTP/WTP Class: IV 30.1762109 z W U K (0 1- a o. w a60 zw 0 vj 0 vj W Q a4 = W 7 d' 0 N 14.40966842 Effluent Hard: 0 value > 100 mg/L Effluent Hard Avg = 47.49 mg/L O O (O O CO O 0 2 N O O co O O N O 0 O 1- O O co O U1 cri M N ▪ co J E w w W W W y 0 0 N Q� bA 0 0 o a a adCY 3 '5' N o w � a . RECOMMENDED ACTION Limited dataset. No RP, Predicted Max < 50 % of Allowable Cw - No Monitoring required, other than pollutant scan (PS) A- ll values in limited dataset reported non -detect < 1 ug/L - No Monitoring required, other than PS. No - RP, Predicted Max < 50 % of Allowable Cw - No Monitoring required, other than PS. N- o RP, Predicted Max < 50 % of Allowable Cw - No Monitoring required, other than PS. See Chromium, Total See Chromium, Total a: No monitoring required other than PS if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. Pr- edicted Max > 50% Allowable Cw. No value > Allowable Cw. Apply Quarterly Monitoring REASONABLE POTENTIAL RESULTS ri # Det. Max Pred Cw Allowable Cw Acute (FW): 1,126.8 Chronic (FW) 569.4 Max MDL = 10 _ _ Chronic (HH) 182.0 Max MDL = 10 Acute: 215.41 Chronic: 24.67 Max MDL = 1 Acute: 14.670 Chronic: 2.894 Max MDL = 1 Acute: NO WQS Chronic: 6 9 Max MDL = 0.1 Acute: 4,020.2 Chronic: 590.1 Acute: 53.0 Chronic: 41.8 knowable Cw Max reported value = 2.5 Max MDL = 5 Acute: 48.61 Chronic: 39 98 No value > Allowable Cw Acute: 72.9 --_ 0 h U 2 1.16 C.V. (default) NO DETECTS 1.160 C.V. (default) NO DETECTS 0.1 C.V. (default) NO DETECTS < a < u h Al L r 5 0 Note: n < 9 Limited data set 5 0 Note: n < 9 Limited data set 5 0 Note: n < 9 Limited data set 5 0 Note: n < 9 Limited data set O 0 O 0 Tot Cr value 5 0 Note: n < 9 Limited data set 7 N O sewn t,, t. t. t. t. t. t. t. t. t. lbd o NC STANDARDS OR EPA CRITERIA Chronic Applied Acute Standard 150 FW(7Q10s) 340 10 HH/WS(Qavg) v, o a w 0.7625 FW(7Q10s) 4.4269 1 A(30Q2) 155.4680 FW(7Q10s) 1213.1031 11 FW(7Q10s) 16 10.5327 FW(7Q10s) 14.6681 N N o_ a w v, 111 U U Z Z Z Z Z Z Z z PARAMETER Arsenic Arsenic E 0 m Cadmium Chlorinated Phenolic Compounds Chromium III Chromium VI Chromium, Total Copper a 72 L 0 4- C r 4- C0 C y 0 0 C 0 U 0) O L a 0) a L 0 4- N L u_ mited dataset. Predicted Max < 50% of Allowable Cw. No Monitoring required, other than pollutant scan S) Li- mited dataset. No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required, other than pollutant scan (PS) No - RP. All values reported non -detect < 5 ug/L Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS Predicted Max > 50% of Allowable Cw. Limited dataset. No detects. Method with the lowest PQL must be used R- P exists. Predicted Max > Allowable Cw. Limited dataset. Apply Quarterly Monitoring. Method with the lowest PQL must be used Predicted Max > 50% of Allowable Cw. No value > Allowable Cw. Continue Quarterly Monitoring - ---------------------------- Predicted Max > 50% of Allowable Cw. Limited dataset. No value > Allowable concentration. R- P exists. Predicted Max > Allowable Cw. 1 value > Allowable concentration. Continue Quarterly Monitoring and update MA limit to 5.8 ug/I R- P exists. Predicted Max > Allowable Cw , 5 value(s) > Allowable Cw. Monitor monthly and add permit limit Acute: NO WQS 0.95 WS(Qavg) µg/L 5 3 41.29600 _____ _______________________ Note: n <9 C.V. (default) Chronic: 17.29409 RP exists. Predicted Max > Allowable Cw, 1 value > Allowable Cw, limited data set. Apply Quarterly Limited data set 1 value(s)> Allowable Cw Monitoring and add permit limit Chronic: 19.0 Max MDL = 10 Acute: 373.712 Chronic: 16.344 No value > Allowable Cw Acute (FW): 1,503.4 Chronic (FW): 188.3 Max MDL =5 Chronic (WS): 94.9 Max MDL = 5 Acute: 185.6 Chronic: 19.0 Max MDL = 10 Acute: 1.817 Chronic: 0.228 Max MDL = 5 Acute: 564.0 Chronic: 641.4 No value > Allowable Cw Acute: NO WQS Chronic: 227 742 No value > Allowable Cw Acute: NO WQS Chronic: 5.82538 1 value(s)> Allowable Cw Acute: NO WQS Chronic: 0.15183 5 value(s)> Allowable Cw C.V. (default) NO DETECTS 5.800 C.V. (default) U `+N . w 0.'O Q v 11.6 C.V. (default) NO DETECTS 5.800 C.V. (default) NO DETECTS 7 O 182.12000 C.V. (default) 12.97200 27.14400 C.V. (default) Note: n < 9 Limited data set 5 1 Note: n < 9 Limited data set t T cl VI'a C v V z I- 5 0 Note: n < 9 Limited data set 5 0 Note: n < 9 Limited data set M M 5 4 Note: n < 9 Limited data set - 5 2 Note: n < 9 Limited data set 4.3060 FW(7Q10s) 112.7685 49.6174 FW(7Q10s) 453.6479 25.0000 WS(7Q10s) 0 a w 0.06 FW(7Q10s) 0.5483 168.9694 FW(7Q10s) 170.1997 0 a o 0.32 HH(Qavg) 0.04 FW(7Q10s) Z Z Z Z Z Z Z U Z U ' 'p W J W W Y Y U U Selenium W jq U C N Chloroform Bis(2--ethylhexyl) phthalate Methyl Bromide Dichlorobromomethane co O a REASONABLE POTENTIAL ANALYSIS H1 Effluent Hardness Date Data BDL=1/2DL Results 1 10/5/2016 47.5 47.5 Std Dev. 2 11/1/2016 66.3 66.3 Mean 3 2/7/2017 56.6 56.6 C.V. 4 3/21/2017 51.5 51.5 n 5 4/11/2017 47.3 47.3 10th Per value 6 5/2/2017 46.4 46.4 Average Value 7 8/8/2017 51.6 51.6 Max. Value 8 11/6/2017 51.2 51.2 9 2/6/2018 49 49 10 5/8/2018 46.1 46.1 11 8/7/2018 45.5 45.5 12 11/6/2018 42.9 42.9 13 2/5/2019 46 46 14 5/7/2019 41 41 15 8/6/2019 52.7 52.7 16 11/5/2019 45.2 45.2 17 2/4/2020 37.8 37.8 18 5/5/2020 37.2 37.2 19 8/4/2020 45.6 45.6 20 11/10/2020 42.4 42.4 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 H2 Upstream Hardness 6.5695 47.4900 0.1383 20 40.68 mg/L 47.49 mg/L 66.30 mg/L Date Data BDL=1/2DL Results 1 10/5/2016 34.7 34.7 Std Dev. 2 11/1/2016 35.8 35.8 Mean 3 2/7/2017 33.9 33.9 C.V. 4 3/21/2017 33 33 n 5 4/11/2017 35.4 35.4 10th Per value 6 5/2/2017 29.3 29.3 Average Value 7 8/2/2017 21.5 21.5 Max. Value 8 11/6/2017 31.3 31.3 9 2/6/2018 27.3 27.3 10 5/8/2018 25.7 25.7 11 8/15/2018 33 33 12 11/6/2018 33.7 33.7 13 2/5/2019 30.4 30.4 14 5/7/2019 25.6 25.6 15 8/6/2019 30.2 30.2 16 11/5/2019 32.1 32.1 17 2/4/2020 30.2 30.2 18 5/5/2020 29.7 29.7 19 8/4/2020 27.8 27.8 20 11/10/2020 32.9 32.9 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 3.7009 30.6750 0.1206 20 25.69 mg/L 30.68 mg/L 35.80 mg/L 25542 RPA 3.0.xlsm, data - 1 3/10/2021 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Arsenic Date Data BDL=1/2DL Results 1 2/2/2016 < 10 5 Std Dev. 2 8/8/2017 < 10 5 Mean 3 11/6/2018 < 10 5 C.V. (default) 4 5/9/2019 < 10 5 n 5 2/4/2020 < 10 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 0.0000 5.0000 0.6000 5 2.32 5.0 ug/L 11.6 ug/L 25542 RPA 3.0.xlsm, data - 2 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS Par03 Beryllium Date Data BDL=1/2DL Results 1 2/2/2016 < 1 0.5 Std Dev. 2 8/8/2017 < 1 0.5 Mean 3 11/6/2018 < 1 0.5 C.V. (default) 4 5/9/2019 < 1 0.5 n 5 2/4/2020 < 1 0.5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par04 Cadmium 0.0000 0.5000 0.6000 5 2.32 0.50 ug/L 1.16 ug/L Date Data BDL=1/2DL Results 1 2/2/2016 < 1.0 0.5 Std Dev. 2 8/8/2017 < 1.0 0.5 Mean 3 11/6/2018 < 1.0 0.5 C.V. (default) 4 5/9/2019 < 1.0 0.5 n 5 2/4/2020 < 1.0 0.5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 0.0000 0.5000 0.6000 5 2.32 0.500 ug/L 1.160 ug/L 25542 RPA 3.0.xlsm, data - 3 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS Par05 Chlorides Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values.' then "COPY" . Maximum data points = 58 Par06 Chlorinated Phenolic Compounds NO DATA 1 NO DATA 2 NO DATA 3 0 4 5 N/A 6 N/A mg/L 7 N/A mg/L 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Date Data 2/2/2016 < 8/8/2017 < 11/6/2018 < 5/9/2019 < 2/4/2020 < BDL=1/2DL Results 0.1 0.05 Std Dev. 0.1 0.05 Mean 0.1 0.05 C.V. (default) 0.1 0.05 n 0.1 0.05 Mult Factor = Max. Value Max. Pred Cw Use "PASTE SF Values" then "I . Maximum c points = 5 0.0000 0.0500 0.6000 5 2.32 0.1 0.1 25542 RPA 3.0.xlsm, data - 4 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iota i8 Par07 Total Phenolic Compounds ug/L ug/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 Mult Factor = N/A Max. Value N/A ug/L Max. Pred Cw N/A ug/L Par08 Use "PASTE SF Values" then "I . Maximum c points = 5 Date Data BDL=1/2DL Results 1 Std Dev. NO DATA 2 Mean NO DATA 3 C.V. NO DATA 4 n 0 5 6 Mult Factor = N/A 7 Max. Value N/A 8 Max. Pred Cw N/A 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Chromium III 25542 RPA 3.0.xlsm, data - 5 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iota i8 Par09 Chromium VI pg/L pg/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par10 Chromium, Total NO DATA NO DATA NO DATA 0 N/A N/A pg/L N/A pg/L Date Data BDL=1/2DL Results 1 2/2/2016 < 5.0 2.5 Std Dev. 2 8/8/2017 < 5.0 2.5 Mean 3 11/6/2018 < 5.0 2.5 C.V. (default) 4 5/9/2019 < 5.0 2.5 n 5 2/4/2020 < 5.0 2.5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SF Values" then "I . Maximum c points = 5 0.0000 2.5000 0.6000 5 2.32 2.5 5.8 25542 RPA 3.0.xlsm, data - 6 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iota i8 Pall Copper pg/L pg/L Date Data BDL=1/2DL Results 1 2/2/2016 5.2 5.2 Std Dev. 2 5/4/2016 < 38 19 Mean 3 5/18/2016 < 38 19 C.V. 4 6/1/2016 < 38 19 n 5 6/15/2016 < 38 19 6 7/6/2016 < 38 19 Mult Factor = 7 7/20/2016 < 38 19 Max. Value 8 8/3/2016 < 38 19 Max. Pred Cw 9 8/17/2016 < 38 19 10 9/8/2016 < 38 19 11 9/23/2016 < 38 19 12 10/5/2016 < 50 25 13 10/19/2016 < 50 25 14 8/8/2017 < 5 2.5 15 11/6/2018 3.9 3.9 16 5/9/2019 1.2 1.2 17 2/4/2020 4.8 4.8 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par12 Cyanide 8.0218 15.1529 0.5294 17 1.39 25.00 ug/L 34.75 ug/L Date Data BDL=1/2DL Results 1 2/2/2016 < 0.1 5 Std Dev. 2 8/8/2017 < 0.1 5 Mean 3 11/6/2018 < 0.1 5 C.V. (default) 4 5/9/2019 < 0.1 5 n 5 2/4/2020 < 0.1 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SF Values" then "I . Maximum c points = 5 0.0000 5.00 0.6000 5 2.32 5.0 11.6 25542 RPA 3.0.xlsm, data - 7 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iota i8 Par14 Lead ug/L ug/L Date BDL=1/2DL Results 1 2/2/2016 < 0.10 0.05 Std Dev. 2 8/8/2017 0.15 0.15 Mean 3 11/6/2018 < 5.00 2.5 C.V. (default) 4 5/9/2019 < 5.00 2.5 n 5 2/4/2020 < 5.00 2.5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par15 Mercury 1.3150 1.5400 0.6000 5 2.32 2.500 ug/L 5.800 ug/L Date Data BDL=1/2DL Results 1 2/2/2016 2.29 2.29 Std Dev. 2 8/8/2017 3.37 3.37 Mean 3 10/22/2018 < 5.54 3.18 C.V. (default) 4 11/6/2018 3.18 0.883 n 5 1/9/2019 < 3.39 1.695 6 5/9/2019 0.883 2.77 Mult Factor = 7 2/4/2020 1.77 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SF Values" then "I . Maximum c points = 5 0.9475 2.3647 0.6000 6 2.01 3.4 6.8 25542 RPA 3.0.xlsm, data - 8 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iota i8 Par16 Molybdenum ng/L ng/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par17 & Par18 Nickel NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L Date Data BDL=1/2DL Results 1 2/2/2016 < 5.00 2.5 Std Dev. 2 8/8/2017 < 5.00 2.5 Mean 3 11/6/2018 < 5.00 2.5 C.V. (default) 4 5/9/2019 < 5.00 2.5 n 5 2/4/2020 < 5.00 2.5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PAS SPECIAL-Va then "COP Maximum points = 0.0000 2.5000 0.6000 5 2.32 2.5 5.8 25542 RPA 3.0.xlsm, data - 9 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS TE dues data 58 pg/L pg/L Par19 Selenium Date Data BDL=1/2DL Results 1 2/2/2016 < 10.00 5 Std Dev. 2 8/8/2017 < 10.00 5 Mean 3 11/6/2018 < 0.50 0.25 C.V. (default) 4 5/9/2019 < 0.50 0.25 n 5 2/4/2020 < 0.50 0.25 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use"PASTE SPECIAL -Values then "COPY" . Maximum data points = 58 Par20 Silver 2.6017 2.1500 0.6000 5 2.32 5.0 ug/L 11.6 ug/L Date Data BDL=1/2DL Results 1 2/2/2016 < 5.00 2.5 Std Dev. 2 8/8/2017 < 5.00 2.5 Mean 3 11/6/2018 < 0.50 0.25 C.V. (default) 4 5/9/2019 < 0.50 0.25 n 5 2/4/2020 < 0.50 0.25 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use"PASTE f. Values" then Maxim um dat: 58 1.2324 1.1500 0.6000 5 2.32 2.500 5.800 25542 RPA 3.0.xlsm, data - 10 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS SPECIAL - "COPY". points = Par21 Zinc ug/L ug/L Date Data BDL=1/2DL Results 1 2/2/2016 55.8 55.8 Std Dev. 2 5/4/2016 38 38 Mean 3 5/18/2016 64 64 C.V. 4 6/1/2016 65 65 n 5 6/15/2016 61 61 6 7/6/2016 73 73 Mult Factor = 7 7/20/2016 147 147 Max. Value 8 8/3/2016 52 52 Max. Pred Cw 9 8/17/2016 62 62 10 9/8/2016 38 38 11 9/23/2016 42 42 12 10/5/2016 < 50 25 13 10/19/2016 < 50 25 14 11 /1 /2016 138 138 15 2/7/2017 94.7 94.7 16 3/21/2017 83.8 83.8 17 4/11/2017 65.9 65.9 18 5/2/2017 39.8 39.8 19 8/8/2017 33.5 33.5 20 11/6/2017 49.1 49.1 21 2/6/2018 121 121 22 5/8/2018 39.9 39.9 23 8/7/2018 39.9 39.9 24 11/6/2018 49.1 49.1 25 2/5/2019 43.2 43.2 26 5/7/2019 35.2 35.2 27 5/9/2019 37.4 37.4 28 8/6/2019 44.6 44.6 29 11/5/2019 27.8 27.8 30 2/4/2020 430 430 31 5/5/2020 57.9 57.9 32 8/4/2020 36 36 33 11/10/2020 51.7 51.7 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par22 Chloroform 71.3971 68.6758 1.0396 33 1.28 430.0 ug/L 550.4 ug/L Date Data BDL=1/2DL Results 1 2/2/2016 28.6 28.6 Std Dev. 2 8/8/2017 78.5 78.5 Mean 3 11/6/2018 < 2 1 C.V. (default) 4 5/9/2019 73 73 n 5 2/4/2020 7.70 7.7 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 25542 RPA 3.0.xlsm, data - 11 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL - Values" then "COPY" . Maxim um data points - 58 Par23 Bis(2--ethylhexyl) phthalate 36.1953 37.7600 0.6000 5 2.32 78.500000 pg/L 182.120000 pg/L Date Data BDL=1/2DL Results 1 11/1/2016 < 5 2.5 Std Dev. 2 1/3/2017 < 5 2.5 Mean 3 4/5/2017 < 5 2.5 C.V. 4 7/5/2017 < 5 2.5 n 5 10/2/2017 9.2 9.2 6 1/2/2018 < 5 2.5 Mult Factor = 7 4/2/2018 < 5.1 2.55 Max. Value 8 7/18/2018 < 4.9 2.45 Max. Pred Cw 9 10/2/2018 < 5 2.5 10 1/9/2019 < 5 2.5 11 4/1/2019 < 5 2.5 12 7/9/2019 < 5 2.5 13 10/1/2019 < 5 2.5 14 1/6/2020 < 5 2.5 15 4/6/2020 < 5 2.5 16 7/6/2020 < 5 2.5 17 10/5/2020 < 5 2.5 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL -Values" then "COPY" . Maxim um data points = 58 Par24 Methyl Bromi 1.6251 2.8941 0.5615 17 1.41 9.200000 pg/L 12.972000 pg/L Date Data BDL=1/2DL 1 2/2/2016 4.4 4.4 2 8/8/2017 < 2 1 3 11/6/2018 11.7 11.7 4 5/9/2019 < 2 1 5 2/4/2020 < 2 1 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 25542 RPA 3.0.xlsm, data - 12 - 3/10/2021 REASONABLE POTENTIAL ANALYSIS ide Results Std Dev. Mean C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maxim um data points - 58 Par25 Dichlorobromomethane 4.6446 3.8200 0.6000 5 2.32 11.700000 pg/L 27.144000 pg/L Date Data BDL=1/2DL Results 1 2/2/2016 4.1 4.1 Std Dev. 2 8/8/2017 11.7 11.7 Mean 3 11/6/2018 < 2 1 C.V. (default) 4 5/9/2019 17.8 17.8 n 5 2/4/2020 < 2 1 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 7.4005 7.1200 0.6000 5 2.32 17.800000 pg/L 41.296000 pg/L 25542 RPA 3.0.xlsm, data - 13 - 3/10/2021 -1 CV 0 CV 00 m Hickory - Catawba WWTP NCOO25542 @ 2 £ To § > 2 0 @ s 4-, c_ 0 � v 1- k k m e o m»» e#_#»#»# e m t m e t e t m e#_ m o 0 o e o m e t o= o m o e m m e== o# o o e e « 4 a a a a a a a a CO a a a a& a a a a a CO a a« e e e e e e e e e e e e e e e e e e e e e e e e e e November-18 December-18 61 I . % % % % a a G 2 y •'_ / § E � / 2 ® / m October-19 November-19 December-19 January-20 February-20 0 0 0 0 0 \ 0 / / § m E / ®2 -, \ k e m October-20 November-20 December-20 January-21 February-21 CO e e e m m# t» o=» e e o o e# e m e t m »oee # o# m o t e#» e t 0 e t t e m# e e t m e# t m m e CC) e=_ a a a a a a a a a a a a a a« a a a a a a& 3 a a a a 3« e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e October-16 November-16 December-16 January-17 February-17 N \ \ \ f / • / § k / ® 2 < k e m October-17 November-17 December-17 January-18 February-18 00 % _ _ _ _ 00 % e e e % / » - § m E / / < > 2 Q \ o ® e \ m Overall TSS removal rate CC CC k k oee =» e e e m m e e e t e o= e= e m t# 0 0 0 m w f 0 g g w w g g w m m@ w e m@ e g g f@ » = e » _ = e = _ » » _ _ _ _ » » _ _ _ _ _ = e = » e e e e e e e e e e e e e e e e e e e e e e e e e November-18 December-18 % % C % ,_ \ 2 / / § \ E § ƒ / > Q 2 \ 3 October-19 November-19 December-19 January-20 February-20 0r \ \\\ N// \ E § / ®2 -, k e m October-20 November-20 December-20 January-21 February-21 / \ > q 0_ » 0 0# e t t e m# e t m» 0# e e e m e e e m e# e# e e@@@@ w w 0 g g w@ 0 e 0 g g 0 w m w m@ 0 w w f D f __» e e e e e= e e= e e e e e e e=_»»= e=»___ e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e \ / \ October-16 November-16 December-16 January-17 February-17 \ N N f qj a a S• E / § \ E / ® 2 < IDA k e m October-17 November-17 December-17 January-18 February-18 % _ _ _ _ % 00 2 / ® � % y '_ / § \ E a / ® � < m cc e / m Overall CBOD removal rate Reduction in Frequency Evaluation Hickory - Catawba WWTP Class III /1.5 MGD NC0025542 12/29/2017 - 12/29/2020 T u ra Facility Class/Flow: Permit No. Review period (use 3 yrs) LL Z >- Approval Criteria: z z z z I1. Currently under Special Orders by Consent (SOC) (3) 2. On EPA Quarterly noncompliance report 3. Facility or employees convicted of CWA violations within the last five years (2) 4. More than one civil penalty assessment for permit limit violations for each target parameter during previous three years (1) } } Z } M1• r-I A asessment M1• N A Z Z r Z 0 0 0 M1• N V 0 a M1• LA V Z Z >- Z 0 0 > N o .0 N O O cm -I ** w4 A 0 o O M1• o LA V C C w4 w4 Gl W E E w M LL O w 0 LD } } } 0 0 00 } 2.091666667 2.845824411 0.528381295 0.753938088 2 Ul 0 0 0 m 0 0 rV tJ, LO 0 0 J J J 0 \ \ \ 0 E E E Data Review 0 0 00 rn H ra c O E E Fecal Coliform z J z \ E k / 0 > 0 \ \ / / z ) OD \ { u rij CD_ b3 OD J % y E \\ f cc «cam ui cE -> / \ / / 0 ± § \ ii \ C \ \ / 2 a \ \ % \ \ k / a / a /{/ R k E c / 2 . . t \ \ cc ƒ G y \ / § I - / k & x ( / \ \ ƒ \ \ / . / ` ) 0 % % e - / / \ 0 > > ` / ® _ 0 . 0 « { . C a \ k \ o a 2 o R\ Rƒ E E u -/.ƒE / 5 F ® u u\\ 1- cc cc u - / % ® y \ > y /E °\1_ j E § k auk / / \> CI) u =I± ± « t § a / 0 , E> c c% u E } 2 3 / / R > 0- \`§ $ % / c\// %> o z z ) ) ®_ cc C c m \ g > % % @ @ 3 = Tea 3 c% E E_= e } ) / ® e ® ® § u §«' m a S 78 / { ƒ ƒ } ` k z \ 0 \ \ / k > / 7 > . . >— >- c \ \ o2ƒ.§§\ t [ / } \ / / . \ < _ m « z c » CO CO u u id=90fd d082-6172-42c0-b4ee-cf39 b8502019 & document li Conclusion: The facility meets the approval criteria for monitoring reduction for BOD, TSS, and Fecal Coliform NH3/TRC WLA Calculations Facility: City of Hickory/ Hickory - Catawba Wastewater Treatment Plant (WWTP) PermitNo. NC0025542 Prepared By: Diana Yitbarek Enter Design Flow (MGD): Enter s7Q10 (cfs): Enter w7Q10 (cfs): 1.5 13 19 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/I) IWC (%) Allowable Conc. (ug/I) Maintain limit at 28 ug/I Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) Maintain 200/100 ml MA limit Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) 13 s7Q10 (CFS) 1.5 DESIGN FLOW (MGD) 2.325 DESIGN FLOW (CFS) 17.0 STREAM STD (MG/L) 0 Upstream Bkgd (mg/I) 15.17 IWC (%) 112 Allowable Conc. (mg/I) Current MA limit: 2.0 mg/I There were no MA ammonia exceedances in summer Daily Max (summer): 5.8 mg/I Maintain limit Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100mI DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 6.59 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Current MA limit: 2.0 mg/I Maximum MA ammonia (winter): 5.2 mg/I Daily Max (winter): 10.3 mg/I Maintain limit Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed 13 1.5 2.325 1.0 0.22 15.17 5.4 19 1.5 2.325 1.8 0.22 10.90 14.7 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Summer: April 1 - Oct 30 Winter: Nov. 1 - March 31 NH3/TRC WLA Calculations Facility: City of Hickory/ Hickory - Catawba Wastewater Treatment Plant (WWTP) PermitNo. NC0025542 Prepared By: Diana Yitbarek Enter Design Flow (MGD): Enter s7Q10 (cfs): Enter w7Q10 (cfs): 3 13 19 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/I) IWC (%) Allowable Conc. (ug/I) Maintain limit at 28 ug/I Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) Maintain 200/100 ml MA limit Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) 13 s7Q10 (CFS) 3 DESIGN FLOW (MGD) 4.65 DESIGN FLOW (CFS) 17.0 STREAM STD (MG/L) 0 Upstream Bkgd (mg/I) 26.35 IWC (%) 65 Allowable Conc. (mg/I) Current MA limit: 1.0 mg/I There were no MA ammonia exceedances in summer Daily Max (summer): 5.8 mg/I Maintain limit Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100m1 DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 3.80 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Current MA limit: 3.0 mg/I Maximum MA ammonia (winter): 5.2 mg/I Daily Max (winter): 10.3 mg/I Maintain limit Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed 13 3 4.65 1.0 0.22 26.35 3.2 19 3 4.65 1.8 0.22 19.66 8.3 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Summer: April 1 - Oct 30 Winter: Nov. 1 - March 31 Hickory -Catawba WWTP /NC0025542 O • U • ct Acji ct ct V--I U N o N N O c-I c-I N Ol N c-I W -1 0 N N O m 00 -1 m N m m lO 0 N -1 m N T -1 Ol N # of Samples J OA J W CO J 00 J W CO Hickory -Catawba WWTP /NC0025542 O • U • ct Acji ct ct V--I U N o N N O c-I c-I N Ol N c-I W 0 N N O m 00 m N N O N N m m lO 0 N ir # of Samples J OA J W CO J 00 J W CO Whole Effluent Toxicity Testing and Self Monitoring Summary V O VI 0 Jan Apr Jul Oct New Hanover a E 0 V 0 Z LL o_ o_ o_ n CO m o 0 0 0 0 V O VI 0 N Feb May Aug Nov rn rsi LL V t0 on 00 O 00 O1 [C New Hanover N O Nn chr lim: 4.6% z; 7-1 C O, m m 6 m o_ ai ai n CO m o 0 0 0 0 V 0 0, Feb May Aug Nov on V f0 m County: Catawba NC0025542/001 Catawba WWTP NonComp: Single chr lim: 1.5 MGD @ 1 za n n CO m o 0 0 0 0 0 V O VI 0 N Mar Jun Sep Dec NC0038822/001 Central Care WWTP 0' o- v 0 O1 E L V O 0 N 0 00 O1 m d D D D C C O, n CO m o 0 0 0 0 0 U 0 0, Mar Jun Sep Dec W c G f0 m 0 cc O 00 O1 OC E O V T 0 O V NC0021865/001 Chadbourn WWTP 7Q10: 0.15 cu CO V7 a E O V 0 Z chr lim: 90% d d d C a a a 6o LL n CO m o 0 0 0 0 0 Page 16 of 122 Legend: P= Fathead minnow (Pimphales promelas), H=No Flow (facility is active), s = Split test between Certified Labs Parameter Data Location 00010 - Temperature, Water Deg. Centigre Average of Value Max of Value Min of Value Upstream Effluent Downstream 00300 - Oxygen, Dissolved (DO) Upstream Effluent Downstream 17.9 18.5 19.6 7.4 8.0 6.8 00900 - Hardness, Total (as CaCO3) Upstream Effluent 30675.0 47490.0 27.0 29.0 28.0 15.4 15.1 15.9 35800.0 66300.0 0.0 3.7 2.8 1.4 5.1 1.4 21500.0 37200.0 31616 - Coliform, Fecal MF, MFC Broth, 42 32230 - Chlorophyll A Upstream Effluent Downstream 1757.7 29.8 1456.4 6000.0 88.0 3600.0 1.0 6000.0 11.0 Upstream Downstream 8.5 14.4 2.0 9.3 14.9 2.0 C0600 - Nitrogen, Total - Concentration Upstream Effluent Downstream C0665 - Phosphorus, Total (as P) - Conce 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 ■ Upstream Upstream Effluent Downstrea m 1.3 7.3 1.0 4.6 30.0 7.3 0.3 0.9 0.2 Total Phosphorus, mg/I Effluent 0.3 2.8 0.3 0.7 6.4 1.4 0.3 0.3 0.3 Downstream C0665 - Phosphgirkef80 (aIiatoffliation Parameter Location Average C0665 - Phosphorus, Total (as P) - Concent Upstream Effluent Downstream Max Min 0.3 2.8 0.3 0.7 6.4 1.4 0.3 0.3 0.3 35.0 30.0 25.0 20.0 15.0 10.0 5.0 0.0 -. - Upstream Total Nitrogen, mg/I Effluent Downstream C0600-Nib 8talP8Werlirni3n Parameter Location Average Max Min C0600 - Nitrogen, Total - Concentration Upstream 1.3 4.6 0.3 Effluent 7.3 30.0 0.9 Downstream 1.0 7.3 0.2 35.0 30.0 25.0 20.0 15.0 10.0 5.0 0.0 Upstream Temperature, C Effluent Downstream 00010 - TempIAMFOFWaterNoft. Ce 8-ade Parameter Location Average Max Min 00010 - Temperature, Water Deg. Centigrad( Upstream 17.9 27.0 0.0 Effluent 18.5 29.0 3.7 Downstream 19.6 28.0 2.8 18.0 16.0 14.0 12.0 10.0 8.0 6.0 4.0 2.0 0.0 Upstream Parameter 00300 - Oxygen, Dissolved (DO) 16.0 14.0 12.0 10.0 8.0 6.0 4.0 2.0 0.0 DO, mg/I 1 Effluent Downstream 00300 I00300 PaVWDislicA4M (DdYlin 1 Location (Average Max Min Upstream 7.4 15.4 1.4 Effluent 8.0 15.1 5.1 Downstream 6.8 15.9 1.4 Chlorophyll A, µg/I ■ ■ Upstream ■ Average ■ MaxD i4l feam Location 'Average Max Min Upstream Downstrea m 8.5 14.4 2.0 9.3 14.9 2.0 Data Parameter Location Average of Value Max of Value Min of Value 31616 - Coliform, Fecal MF, MFC Broth, 42 Upstream Effluent Downstream 1757.7 29.8 1456.4 6000.0 3600.0 6000.0 88.0 1.0 11.0 31616 - Coliform, Fecal MF, MFC Broth, 44.5 C Total 234.1888268 6000 1 Parameter 7000.0 6000.0 5000.0 4000.0 3000.0 2000.0 1000.0 0.0 Upstream Location Average Max Min Upstream 1757.7 6000.0 88.0 Effluent 29.8 3600.0 1.0 Downstream 1456.4 6000.0 11.0 Fecal Coliform, #/100 ml ■ Averemeril Max ■ Min Downstream 1 2 Average of Value Parame Location 00010 - Temperature, Water [ F-Test Two -Sample for Variances Years Date Day Downst Upstream Diff 2016 Jun 1 22 21 1 2 23 23 0 6 22 23 -1 7 22 21 1 8 23 20 3 13 24 22 2 14 24 23 1 15 25 23 2 20 22 24 -2 21 22 22 0 22 24 25 -1 27 25 24 1 28 23 23 0 291 22 22 0 Jul Aug Sep 51 23 21 2 6 26 24 2 7 25 24 1 11 25 25 0 12 23 23 0 13 25 25 0 18 25 24 1 19 23 23 0 20 25 24 1 25 25 25 0 26 24 25 -1 27 27 26 1 1 24 23 1 2 25 25 0 3 23 24 -1 8 22 22 0 9 23 22 1 10 25 25 0 15 24 26 -2 16 26 25 1 17 26 25 1 22 24 23 1 23 23 23 0 24 25 25 0 29 24 23 1 30 24 24 0 31 24 23 1 6� 22 21 1 7 23 21 2 8 23 22 1 12 23 22 1 13 22 22 0 14 22 22 0 19 23 23 0 20 23 22 1 Variable 1 Variable 2 Mean Variance Observations df F P(F<=f) one -tail F Critical one-tE 19.58430913 44.57127904 427 426 1.201883182 0.029028083 1.173000352 17.91662763 37.08453508 427 426 Comment: The variance of Variable 1 is higher than the The variances of the two sets are unequal. t-Test: Two -Sample Assuming Unequal Variances Variable 1 Variable 2 Mean Variance Observations Hypothesized N df t Stat P(T<=t) one -tail t Critical one-tai P(T<=t) two -tail t Critical two-tai 19.58430913 44.57127904 427 0 845 3.813585535 7.34637E-05 1.646658895 0.000146927 1.962775363 17.91662763 37.08453508 427 We look at the p-value, two tail. Since we set alpha valL There is a statistically significant difference between thl 2016 2017 Sep 21 26 27 28 Oct 5 12 19 26 31 Nov Dec 1 7 14 22 28 5 12 19 27 Jan 3 10 17 23 30 Feb 6 13 20 27 Mar 1 6 13 22 27 Apr 3 10 17 24 May 1 8 15 22 30 Jun 5 6 7 12 13 14 19 20 21 26 27 28 Jul 22 21 22 22 21 21 21 21 16 16 20 18 15 16 8.3 8.1 15 15 17 16 9.3 8.5 10 9.8 4.9 4.4 13 14 6.4 8.3 8.7 9.1 7.4 7.3 9.6 10 9 9.2 5.7 6 7.3 7 10 10 7.1 7.3 5.5 6 5.8 6.3 5.2 6.1 7.8 8.2 6.1 7 11 13 8 8.3 8.2 9.3 8 8.3 11 11 16 16 13 14 17 18 14 14 15 16 14 14 16 18 10 10 12 10 15 13 19 19 20 18 22 22 20 22 22 22 23 23 24 23 24 23 24 21 24 21 24 19 25 23 1 0 0 0 0 2 - 1 0.2 0 1 0.8 0.2 0.5 - 1 - 2 - 0 0.1 - 0 - 0 - 0 0.3 0 - 0 - 1 - 1 - 1 - 0 - 1 - 2 - 0 - 1 - 0 0 0 - 1 - 1 0 - 1 0 - 2 0 2 2 0 2 0 - 2 0 0 1 1 3 3 5 2 2017 2018 Jul 5 6 10 11 12 17 18 19 24 25 26 31 Aug 1 2 7 8 9 14 15 16 21 22 23 28 29 30 Sep Oct 5 6 7 11 12 13 18 19 20 25 26 27 2 9 16 23 30 Nov 6 15 21 29 Dec 4 13 19 28 Jan 26 23 25 22 26 22 27 23 26 24 26 23 26 21 27 23 27 23 27 23 27 24 26 21 27 22 26 21 24 23 26 22 26 21 27 23 27 23 26 23 27 25 28 25 27 25 26 21 25 20 25 20 24 19 24 20 23 16 22 16 21 16 21 18 23 22 23 20 23 20 22 19 26 25 24 22 15 21 23 22 21 19 20 17 17 11 17 16 13 9 12 6.4 10 5.3 11 8.3 7.2 2.8 8 6.4 5.9 2.5 2 3.7 0 8 3.9 10 1.4 19 2.8 3.6 3 3 4 4 2 3 5 4 4 4 3 5 5 5 1 4 5 4 4 3 2 3 2 5 5 5 5 4 7 6 5 3 1 3 3 3 1 2 -6 1 2 3 6 1 4 5.6 4.7 2.7 4.4 1.6 3.4 3.7 3.9 -1 -1 2018 Jan 22 30 Feb 6 12 20 27 6 13 20 27 Mar Apr 2 10 17 24 May 1 8 15 23 30 Jun 4 5 6 11 12 13 18 19 20 25 26 27 Jul 2 3 5 9 10 11 16 18 19 23 24 25 30 31 Aug 4.3 4.7 6.5 7.1 5.1 4.7 8.7 14 9.6 11 11 10 10 9 7.9 5.7 12 13 10 10 13 14 13 12 11 10 16 15 12 15 17 17 19 20 21 21 20 20 22 22 21 19 21 19 23 23 22 20 22 20 24 25 24 25 23 22 25 24 23 22 22 22 24 24 24 24 25 24 20 20 26 26 24 24 25 24 25 24 27 25 22 22 25 24 26 25 24 23 27 27 1 26 24 6 26 24 7 25 23 8 25 24 13 25 22 14 25 23 151 24 23 20 25 23 21 25 24 22 22 25 -0 -1 0.4 -5 -1 1 1 2.2 -1 0 -1 1 1 1 -3 0 -1 0 0 0 2 2 0 2 2 -1 -1 1 1 1 0 0 0 1 0 0 0 1 1 2 0 1 1 1 0 2 2 2 1 3 2 1 2 1 -3 2018 2019 Aug 27 28 30 Sep 4 5 6 10 11 12 17 18 19 24 25 26 Oct 2 3 8 9 10 15 16 17 22 23 24 29 30 31 Nov 6 12 19 26 Dec 4 13 17 28 31 Jan 9 14 22 28 Feb 5 11 18 25 Mar 4 11 18 25 Apr 25 22 25 23 25 241 26 24 26 24 26 24 25 22 26 22 25 23 23 22 23 22 23 24 24 21 23 20 23 21 23 21 23 20 23 20 24 21 24 21 23 21 21 16 21 18 21 19 18 12 17 11 17 11 15 12 15 11 15 11 16 15 8.4 13 11 6.9 10 10 9.6 8.9 4.7 4.9 7.8 8 7.5 7.3 11 11 9.2 9.5 6.7 6.5 3 3.1 6.3 6.1 7.6 8.9 7.4 7.5 8 6.9 8.3 8.4 9 9.5 9.3 11 9.9 8 11 11 1 12 10 8 15 16 15 15 16 22 15 13 3 2 1 2 2 2 3 4 2 1 1 - 1 3 3 2 2 3 3 3 3 2 5 3 2 6 6 6 3 4 4 1 - 5 4.1 0 0.7 - 0 - 0 0.2 0 - 0 0.2 - 0 0.2 - 1 - 0 1.1 - 0 - 1 - 2 1.9 0 2 - 1 - 1 2 2019 Apr 29 17 17 May 7 13 20 28 Jun 3 4 5 10 11 12 17 18 19 24 25 26 Jul 1 2 3 8 9 10 15 16 17 22 23 24 29 30 31 Aug 5 6 7 12 13 14 19 20 21 26 27 28 Sep 3 4 5 9 10 11 16 17 18 23 24 19 18 19 19 20 20 23 21 23 20 23 19 24 20 22 20 22 19 18 18 21 21 22 21 21 21 23 21 22 21 23 21 23 23 23 23 23 22 26 23 27 23 23 23 22 22 25 23 25 24 27 24 26 23 25 20 26 22 26 21 26 22 26 21 25 22 22 22 26 22 27 23 26 23 27 23 27 23 27 23 25 20 25 20 24 20 25 21 25 22 25 22 25 21 26 22 26 22 26 21 26 21 22 22 22 19 24 20 2019 2020 Sep 25 30 Oct 1 7 14 21 28 Nov 5 11 18 25 Dec 2 10 16 23 30 Jan 6 17 21 28 Feb 4 10 18 24 Mar 2 9 16 24 30 Apr I 6 13 22 27 May 5 11 18 26 Jun 1 2 3 8 9 10 15 16 17 22 23 24 29 30 Jul 6 7 8 23 19 25 22 25 22 24 18 21 17 18 14 19 15 16 10 15 9.4 12 8.9 10 7.5 10 9.6 9.7 10 8.5 8.5 8.3 8 11 14 6.9 5.8 9.4 8.8 6.2 4.9 L 7 7.8 10 11 8.4 7.6 8.8 9 8.2 8.9 7.9 7.2 7.8 7 12 11 13 13 14 16 15 14 17 17 17 14 16 14 18 17 16 13 19 18 18 18 19 17 19 17 21 19 22 22 23 22 23 22 21 19 19 16 19 16 22 20 22 20 22 20 24 21 24 22 25 21 25 22 26 22 25 22 4 3 3 6 4 4 4 6 5.6 3.1 2.5 0.4 -0 0 0.3 -3 1.1 0.6 1.3 -1 -1 0.8 -0 -1 0.7 0.8 1 0 -2 1 0 3 2 1 3 1 0 2 2 2 0 1 1 2 3 3 2 2 2 3 2 4 3 4 3 2020 Jul 13 27 23 14 27 22 15 27 23 20 27 24 21 26 23 22 26 22 27 27 23 28 26 23 291 26 23 Aug 3 4 5 10 11 12 17 18 19 24 25 26 31 Sep 2 8 9 10 14 15 16 21 22 23 28 29 30 Oct 5 12 19 26 Nov 2 9 16 23 Dec 1 7 15 21 29 26 23 26 22 25 21 26 22 25 22 26 22 24 21 24 21 25 21 24 21 24 25 25 21 26 22 25 22 23 23 20 19 25 20 25 21 24 21 24 20 23 19 21 14 20 14 20 13 21 19 22 20 20 17 18 14 20 18 17 12 18 15 15 11 16 14 15 13 13 12 11 8.6 8.7 8.4 5.1 9.3 8.8 7.9 9.1 5.6 4 5 4 3 3 4 4 3 3 3 4 4 4 3 4 3 3 4 3 -1 4 4 3 0 1 5 4 3 4 4 7 6 7 2 2 3 4 2 5 3 4 2 2 1 1.7 -0 0.8 -1 -1 Average of Value Years Date 2016 2017 2018 2019 Jun Jul Aug Sep Oct Nov Dec Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2020 Jan Feb Mar Apr 1 2 Parame Location 00010 - Temperature, Water Deg. Centigrade Downst Upstream 23.07 24.67 24.13 22.25 14.86 10.84 8.025 22.57 24.08 23.87 21.67 14.62 10.54 8.675 7.82 7.9 6.08 6.72 9.24 9.98 15 15.5 13.4 13.6 21.75 20.5 26.23 22.69 26.21 22.43 23 19.42 19.2 18 13 9.175 8.025 5 4.24 3.36 8.6 9.925 9.975 9.425 13.25 12.75 17.8 18.6 22.67 21.92 24.57 24 24.85 23.38 24.42 22.42 20 16.33 11.35 11.23 8.12 8.02 6.3 6.3 7.825 7.925 9.8 9.875 14.8 14.4 20.25 19.5 22 20.17 24.87 22.53 25.58 21.83 24.62 21.08 21.4 17.2 13.25 8.95 9.5 10.02 7.375 6.825 8.85 9.125 10.94 10.84 16.25 14.75 2020 May 17.75 16.5 Jun 21.43 19.5 Jul 26.15 22.54 Aug 25.08 21.85 Sep 22.36 18.71 Oct 18.25 14.75 Nov 14.75 12.5 Dec 8.36 8.14 Sum of Value Jun Jul e upstream and downstream T Sep 1 2 6 7 8 13 14 15 20 21 22 27 28 29 5 6 7 11 12 13 18 19 20 25 26 27 1 2 3 8 9 10 15 16 17 22 23 24 29 30 31 6 7 8 12 13 14 19 20 2 Parameter Location 00300 - Oxygen, Dissolved (DO) Downstream Upstream 6.3 7.3 6.5 6.2 8.4 6 6.6 8 6 6.9 7.6 8 6.2 6.1 5.7 6 7 5.9 6.3 6.4 6.3 6.5 6.1 5.9 6.2 6 6.4 6.2 6.4 6.3 6.2 6.3 6.3 6.2 6.2 5.3 5.1 6.4 6.4 5.6 6.2 6.2 6.2 6.3 6.4 6.3 6.2 9.2 6.8 6.2 6.4 5.8 6.5 6.8 6.3 6.2 6.2 6.4 6.8 9 6.6 6.5 6.2 6.3 4.7 4.9 4.7 5 4.5 5.4 4.6 5.9 3.9 5.7 4.5 4.5 4.4 5.2 4.8 4.5 4.9 5.8 4.7 5.8 4.8 5.6 5.1 5.2 4.3 5I 1.4 6 5.6 7.4 5.5 2.4 2.9 5 Diff -1 0.3 2.4 -1.4 -0.9 -0.4 0.1 -0.3 1.1 -0.1 -0.2 0.2 0.2 0.2 0.2 0.1 0 0 -0.1 -0.1 0 -3.9 -1.7 0.2 0 -0.2 -0.3 0.1 -0.2 -2.2 0.1 -0.1 -0.2 -0.3 -0.9 -1.3 -1.8 0 -0.8 0.3 -0.9 -1.1 -0.8 -0.1 -0.7 -4.6 -1.8 3.1 -2.1 2016 Sep 2017 Oct Nov Dec Jan Feb Mar Apr May Jun 21 26 27 28 5 12 19 26 31 1 7 14 22 28 5 12 19 27 3 10 17 23 30 1 6 13 20 27 1 6 13 22 27 3 10 17 24 1 8 15 22 30 5 6 7 12 13 14 19 20 21 26 27 28 Jul 3 4.2 4.91 5.9 6.3 7 7.4 4.9 6 6.2 7.2 6.3 6.3 6.2 6.3 7 6.9 8.1 8.8 7.2 8.8 5.9 6 6.2 6.2 8.9 10.3 6.4 6.3 6.4 6.4 6.3 6.2 6.2 6.3 6.2 6.2 6.4 6.3 6.2 6.3 6.2 6.4 6.3 6.2 6.3 6.3 6.2 5.9 5.2 5.1 6.1 6.2 5.9 5.1 5.1 6.1 6.2 6.2 5.4 5.4 6.1 6.2 5.7 6 5.6 5.8 5.1 5.2 5.8 5.9 5.2 5.2 5.9 6 5.2 5.2 5.2 5.9 5.8 5.21 5.3 5.2 5.9 5.9 5.6 5.5 5.2 5.3 5.3 5.3 7.4 7 5.1 5.2 6.2 6.8 5.2 5.4 4.6 5.3 5.5 6 6 4.9 4.5 5.6 5.5 6.6 6.2 6 - 0.7 - 0.4 - 0.4 - 1.1 -1 0 - 0.1 0.1 - 0.7 - 1.6 - 0.1 0 - 1.4 0.1 0 0.1 - 0.1 0 0 0 0 0 - 0.1 0 0 0.1 0 0 0 0 - 0.1 - 0.3 - 0.2 - 0.1 - 0.1 0 - 0.1 0 - 0.1 0 0 - 0.1 0.1 - 0.1 0 0.4 - 0.1 - 0.6 - 0.2 - 0.7 - 0.5 1.1 - 1.1 - 1.1 0.2 2017 Jul Aug Sep Oct Nov Dec 2018 Jan 5 6 10 11 12 17 18 19 24 25 26 31 1 2 7 8 9 14 15 16 21 22 23 28 29 30 5 6 7 11 12 13 18 19 20 25 26 27 2 9 16 23 30 6 15 21 29 4 13 19 28 7.1 5.8 5.2 5.8 7.8 4.7 5.1 5.3 3.9 4.7 4.6 5.1 6.2 5.1 7 6.1 6.7 6.6 7.5 7.1 6.4 6.7 6.4 6.8 5.1 6.5 6.1 6.9 6.9 7.4 6 7.7 6.1 8 5.8 7.2 6.3 7.9 6 9.7 4.8 5.9 5 5.8 5.1 6.7 4.9 6.9 5.9 7.5 5.5 6.8 6.3 7.9 5.4 6.8 5.7 8.2 6.7 8.3 7.4 8.1 6.8 7.4 6.2 6.4 5.3 6.9 6.3 7.3 6.4 6.9 5.9 6.3 5.3 7 7.8 5.6 6 5.8 6.1 5.8 5.7 5.2 6.9 7.9 7.6 8.3 8.3 8.7 7.8 8.1 9.2 11.1 8 11 9.7 11.4 11.2 11.2 10 13.3 10.5 151 8 10.7 10 15.4 19 12.5 13.9 0.9 0.7 - 1.8 - 0.3 1.1 - 1.9 - 2.4 - 1.8 - 2.5 - 2 - 1.8 - 1.7 - 1.4 - 0.8 - 0.5 - 1.7 - 1.9 - 1.4 - 1.6 - 3.7 - 1.1 - 0.8 - 1.6 - 2 - 1.6 - 1.3 - 1.6 - 1.4 - 2.5 - 1.6 - 0.7 - 0.6 - 0.2 - 1.6 - 1 - 0.5 - 0.4 - 1.7 2.2 0.2 0.3 0.5 - 1 - 0.2 0.2 - 0.9 - 2.4 - 3 - 1.7 0 - 3.3 - 4.5 10.7 -15.4 - 1.4 2018 Jan Feb Mar Apr May Jun Jul 22 12 9.1 30 11.7 10.6 6 12 20 27 6 13 20 27 2 10 17 24 1 8 15 23 30 4 5 6 11 12 13 18 19 20 25 26 27 2 3 5 9 10 11 16 18 19 23 24 25 30 31 Aug 1 6 7 8 13 14 15 20 21 22 15.9 12.4 10.7 10 9.4 9.6 9.4 11 15.1 10.4 10.8 9.9 12.4 10.3 8.6 10 10.6 9.2 11.2 10.6 9.8 10.8 8.4 9.1 9.1 8.5 7 9.1 9.3 9.4 7.5 7.6 6.8 7 7.4 7.1 7.1 7.3 8.8 6.2 6.4 6.5 8.1 6.3 6.4 6.5 7.6 7.7 7.6 7.8 6.3 6.5 6.8 6.7 7.5 6.6 6.6 6.3 6.4 6.3 6.5 6.3 6.1 6.5 6.4 6.3 8.4 6.5 6.5 6.5 6.4 6.1 6.3 6.4 6.2 6.7 6.2 6.6 6.3 6.2 8.2 6.4 6.4 6.4 6.2 6.3 6.8 6.1 6.7 6.8 4 6 5.5 5.5 4.9 5.7 6.2 6.5 6.51 6.4 5.3 4.5I 4.3 1.4 4.9 4.9 2.9 1.1 0.8 2 - 0.1 0.1 - 3 - 0.7 0.8 1 1.4 0.6 - 1 - 0.7 0.6 - 2.1 - 0.1 - 0.1 - 0.2 - 0.2 - 0.6 - 0.5 - 0.5 2.5 - 0.3 - 0.4 - 0.2 0.6 - 0.3 - 0.2 0.2 0.1 - 0.1 0.3 - 0.4 - 0.1 - 0.1 0.1 0.1 0.2 0.1 0.1 0.1 0.2 - 0.2 0.6 - 0.4 0.2 0.4 - 1.3 1.5 1.2 4.1 0 0.8 2018 2019 Aug Sep Oct Nov Dec Jan Feb Mar Apr 27 5 4.6 28 5.8 5.6 30 5.6 2.3 4 5 6 10 11 12 17 18 19 24 25 26 1 2 3 8 9 10 15 16 17 22 23 24 29 30 31 6 12 19 26 4 13 17 28 31 9 14 22 28 5 11 18 25 4 11 18 25 3.5 4.8 4.2 4.9 4.3 4.9 4.3 4.8 4.8 5.4 4.8 5.4 5.2 7 4 6.6 4.1 6.1 5.2 7.1 4.9 6.4 4.4 5.9 4.8 5.7 5 5.4 5 5.1 4.6 5.3 4.3 6.4 5.5 6.3 5.7 6.3 5.9 7 5.7 7.1 7.3 8.6 6 8.6 6 8.5 6.3 8.3 6.4 8.8 7.2 9.7 6.5 9.8 9.9 10 7.1 7.3 10.7 9.8 9 9.6 11.1 11.6 9.8 10.6 11 12.2 10.6 10.8 8.7 9.2 11.7 12 10.7 10.9 10.9 10.9 11.2 10.2 10.5 10.7 11.9 10.6 11.6 10.9 8.4 10.7 9.8 10.8 10.1 9.8 8.7 10.5 1 8.6 8.2 8 9.9 10.4 15 8.4 7.9 22 7.6 9.2 0.4 0.2 3.3 - 1.3 - 0.7 - 0.6 - 0.5 - 0.6 - 0.6 - 1.8 - 2.6 - 2 - 1.9 - 1.5 - 1.5 - 0.9 - 0.4 - 0.1 - 0.7 - 2.1 - 0.8 - 0.6 - 1.1 - 1.4 - 1.3 - 2.6 - 2.5 - 2 - 2.4 - 2.5 - 0.6 2.5 - 0.8 0.2 - 0.6 - 0.5 - 0.8 - 1.2 - 0.2 - 0.5 - 0.3 - 0.2 0 - 0.7 - 0.4 - 1.1 - 0.2 - 1.7 0.9 1.1 0.3 0.4 - 0.5 0.5 - 1.6 2019 May Jun Jul Aug 7 13 20 28 3 4 5 10 11 12 17 18 19 24 25 26 1 2 3 8 9 10 15 16 17 22 23 24 29 30 31 5 6 7 12 13 14 19 20 21 26 27 28 3 4 5 9 10 11 16 17 18 23 24 8 8.1 7.6 6.4 6.3 6.2 8.1 7.1 7.3 7.1 5.3 6.2 6.1 6.7 6.1 6.4 6.9 6.7 6.6 5.6 5.1 4.8 6.2 6.5 6.2 6.7 6.8 6.8 7.1 6.9 6.5 5.9 5.6 5.6 5 5.4 6.1 6.3 6 5.7 6.2 6.4 5.7 6 6.2 6.4 6.3 6.1 5.9 6.2 5.1 5.2 5.3 6 5.1 5.8 6.1 6.2 4.9 5.6 5.5 5.1 4.6 5.1 4.6 5.4 4.7 6.2 4.1 5.4 4.2 5 4.4 5 3.7 5.4 3.9 5 3.9 5.6 3.6 4 6.3 7.1 5.3 6.5 5.1 6.4 5.6 6.6 5.4 6.4 5 6.2 4.2 6.1 3.7 5.3 4 5.2 4.8 4.7 4.4 4.9 5.5 5.7 5 5.8 5.1 6.1 - 0.1 - 0.5 - 0.7 - 1 - 0.9 - 0.9 - 0.3 - 0.1 0 - 0.7 - 0.4 - 0.2 - 0.2 0.1 - 0.3 - 0.5 - 0.8 - 0.4 - 0.2 0.3 - 0.2 - 0.3 - 0.2 0.2 - 0.3 - 0.1 - 0.7 - 0.7 - 0.1 - 0.7 0.4 - 0.5 - 0.8 - 1.5 - 1.3 - 0.8 - 0.6 - 1.7 - 1.1 - 1.7 - 0.4 - 0.8 - 1.2 - 1.3 - 1 - 1 - 1.2 - 1.9 - 1.6 - 1.2 0.1 - 0.5 - 0.2 - 0.8 - 1 2019 2020 Sep Oct Nov Dec Jan Feb Mar Apr May Jun Jul 25 4.9 5.8 30 5.7 6 1 7 14 21 28 5 11 18 25 2 10 16 23 30 6 17 21 28 4 10 18 24 2 9 16 24 30 6 13 22 27 5 11 18 26 1 2 3 8 9 10 15 16 17 22 23 24 29 30 1 6 7 8 5 6.4 5.3 6.1 5.8 6.7 6.3 7.1 6.4 7.7 6 7.7 7.7 10.3 8 9.3 8.7 10.7 9.6 9.6 9.9 10.6 11.3 11.7 10.4 11.6 11.3 9.7 10 9.8 9.4 10.4 12.2 9.8 12.2 11.7 11.4 11.2 10.4 10.2 10.7 10.9 11.8 12 10.5 10.8 9.7 10.2 7.8 11.4 11.2 10.3 11.4 7.3 9.3 10 7.6 8.1 8.4 11.3 7 9.2 8.1 8.2 8.7 8.3 8.4 9.7 8.2 7.8 7.4 8.21 8.3 8.7 7.7 8 7.3 7.5 7.2 7.8 7.4 7.7 7.3 7.8 8 8.7 7.8 8.9 7.7 8.4 7.2 8.4 7.6 8.6 8.2 8.7 7.1 7.7 7.2 7.6 8.4 8 7.5 7.9 7.7 7.6 - 0.9 - 0.3 - 1.4 - 0.8 - 0.9 - 0.8 - 1.3 - 1.7 - 2.6 - 1.3 - 2 - 2.1 - 0.8 - 1.7 - 0.7 1.6 - 2.2 0 - 2.8 - 1.3 0.2 0.2 - 0.2 - 0.2 - 0.9 - 0.4 - 0.6 - 1.2 0.5 - 0.7 - 0.5 - 2.9 - 2.2 - 0.3 - 1.5 0.5 0.5 - 0.8 - 0.4 - 0.3 - 0.2 - 0.6 - 0.3 - 0.5 - 0.7 - 1.1 - 0.7 - 1.2 - 1 - 0.5 - 0.6 - 0.4 0.4 - 0.4 0.1 2020 Jul Aug Sep Oct Nov Dec 13 14 15 20 21 22 27 28 29 3 4 5 10 11 12 17 18 19 24 25 26 31 1 2 8 9 10 14 15 16 21 22 23 28 29 30 5 12 19 26 2 9 16 23 1 7 15 21 29 8 7.1 7.5 7.9 7.1 7.3 7.1 6.8 7.2 7.7 7.2 7.5 5.8 7.5 6 7.2 6.2 7.2 5.5 6.3 5.9 8 5.4 7.9 6.5 6.3 6.4 6 6.4 6.7 6.9 7.5 7 7.5 8.5 9.5 6.5 7.2 6.6 6.5 6.4 7 5.9 5.8 6.2 7.8 7.2 7.3 6 5.9 6.2 6.6 6.5 7.6 5.3 7.4 6.1 7.6 6.3 7.8 6.7 9 6.8 9.3 6.9 9 7.4 8.2 7.5 8.6 7.8 8.5 8.2 7.5 7.7 6.9 10.1 8.7 10.3 8.7 6.5 7.5 6.9 7.9 8.7 8.4 8.3 10.6 8.6 10.1 9.4 10.9 11.4 10.4 10.3 10.1 10.7 11.8 0.9 - 0.4 - 0.2 0.3 - 0.5 - 0.3 - 1.7 - 1.2 - 1 - 0.8 - 2.1 - 2.5 0.2 0.4 - 0.3 - 0.6 - 0.5 - 1 - 0.7 0.1 - 0.6 0.1 - 1.6 - 0.1 0.1 - 0.4 - 1.1 - 2.1 - 1.5 - 1.5 - 2.3 - 2.5 - 2.1 - 0.8 - 1.1 - 0.7 - 1.9 - 1.2 - 2.6 - 1.8 - 2.2 - 0.9 - 1.4 - 2.7 - 1.8 - 0.2 - 0.7 0.2 - 0.4 F-Test Two -Sample for Variances Variable 1 Variable 2 Mean 7.364637002 6.768384075 Variance 4.162244175 3.752448791 Observation: 427 427 df 426 426 F 1.109207455 P(F<=f) one- 0.142592142 F Critical onE 1.173000352 Comment: We accept the null hypothesis. The variances of the two sets are equal. t-Test: Two -Sample Assuming Equal Variances Variable 1 Variable 2 Mean 6.768384075 7.364637002 Variance 3.752448791 4.162244175 Observation: 427 427 Pooled Varia 3.957346483 Hypothesize( 0 df 852 t Stat -4.379529195 P(T<=t) one- 6.68678E-06 t Critical one 1.646644046 P(T<=t) two- 1.33736E-05 t Critical two- 1.962752233 We look at the p-value, two tail. Since we set alpha value at 0.05, if the p-value is less than 0.05, we can There is statistically significant difference between the upstream and downstream DO Sum of Value Year 2016 See James' nutrient study 1 2 Nick - Have you had a permit th Parameter Location TNxTMFx8.34, Ib/mo CO600 - Nitrogen, Total - Concentration Date Day Downstream Upstream Jun Jul Aug 1 6 15 22 29 6 13 20 27 3 10 17 24 31 Sep Oct 7 14 21 28 Nov 1 Dec 5 2017 Jan 3 Feb 1 Mar 1 Apr 3 Ma Jun 5 19 Jul 5 19 Aug 2 16 Sep say that there is a statisti Oct 2018 Nov Dec Jan Feb Mar Apr Ma 5 19 Jun 2 6 4 2 6 6 2 5 19 Jul 10 24 Aug 7 21 Sep 0.84 1.7 0.67 0.27 0.29 1.1 0.91 1.2 1.1 0.89 7.3 1.2 1.8 1.7 0.71 0.65 0.81 0.79 0.94 1.1 1 1 2.6 1.2 0.82 1.1 1.1 0.81 0.76 1 1.1 0.99 1.4 0.87 0.57 0.54 0.62 0.61 1.4 0.62 0.75 0.72 1 1.2 1.2 1.3 0.97 0.91 3.9 4 1.2 1.2 0.42 1.4 0.73 0.37 1.5 1.3 0.78 0.19 1 1.7 0.37 0.29 1.1 0.91 0.79 0.52 0.52 0.52 1.2 0.52 0.52 0.52 0.42 0.77 0.58 1.2 1.8 0.72 0.65 1.4 0.54 0.52 1 1.1 0.52 0.53 0.83 1.1 1.1 0.52 0.52 0.66 0.52 0.97 2018 Sep 18 0.52 1.3 Oct 2 0.52 0.75 Nov 6 0.52 0.89 Dec 4 0.83 1 2019 Jan 9 0.81 1.3 Feb 5 0.92 1.2 Mar 5 1.2 1.4 Apr 1 0.96 1.3 May 7 1.3 1.9 Jun 4 0.65 1.4 18 0.85 1.7 Jul 9 0.78 1.5 23 1.3 1.8 Aug 6 1 2.3 20 0.94 4.1 Sep 3 0.66 1.3 17 1 1.5 Oct 1 0.64 1.7 Nov 5 0.81 1.1 Dec 2 0.78 1.7 2020 Jan 6 1 1.6 Feb 4 0.91 2.9 Mar 9 1.2 1.8 Apr 6 0.56 0.91 May 5 1.1 3.4 Jun 1 1 1.2 16 0.89 0.69 Jul 6 1 2 21 1.3 2.4 Aug 4 0.93 4.6 17 1.5 1.6 Sep 1 1.2 1.2 14 1.1 1.7 Oct 19 0.58 1.1 Nov 10 0.77 2.3 Dec 7 1.1 1.3 https://pubs.usgs.gov/wri/wri034191/pdf/newrir03-4191.pdf at collects upstream and downstream TN and TP, if yes, can you please share the permit number? I would like tc Diff F-Test Two -Sample for Variances - 0.86 0.4 Variable 1 Variable 2 - 0.81 Mean 0.969411765 1.344 - 0.29 Variance 0.720891317 0.586429048 0.21 Observations 85 85 6.1 df 84 84 0.1 F 1.229289919 0.06 P(F<=f) one -tail 0.173002223 0.02 F Critical one -tail 1.43472934 - 0.16 0 1.4 - 0.28 0.29 Comment: The variance of Variable 1 is higher than the variance of Variable 2. As a re: - 0.24 We accept the null hypothesis. The variances of the two sets are equal. 0.11 0.53 0.03 t-Test: Two -Sample Assuming Equal Variances 0.01 0.78 Variable 1 Variable 2 0.03 Mean 0.969411765 1.344 - 0.2 Variance 0.720891317 0.586429048 - 0.1 Observations 85 85 0.06 Pooled Variance 0.653660182 - 0.1 Hypothesized Mean D 0 - 0.1 df 168 0 t Stat -3.020456483 - 0.98 P(T<=t) one -tail 0.001459214 - 0.77 t Critical one -tail 1.653974208 - 0.93 P(T<=t) two -tail 0.002918429 - 0.22 t Critical two -tail 1.974185191 - 1.51 - 0.73 - 0.62 We look at the p-value, two tail. Since we set alpha value at 0.05, if the p-value is less 0.37 - 0.25 - 0.06 There is statistically significant difference between the upstream and downstream TN - 0.68 - 0.6 - 0.2 - 0.13 - 0.88 - 0.46 - 0.58 - 0.31 - 0.57 0.58 - 0.14 - 0.45 see what analysis pw perform on this data (before handling the package to MT.)(ie., does it make sense to ca Sum of Value Year 2016 Date Jun Jul Aug cult, Excel calculates the correct F Sep Oct Nov Dec 2017 Jan Feb Mar Apr than 0.05, we can sa 2018 Jun Jul Aug Sep that there Oct Nov Dec Jan Feb Mar Apr Jun Jul Aug Sep Parameter Location CO665 - Phosphorus, Total (as P) - Concentration Day Downstream Upstream 6 15 22 29 6 13 20 27 3 10 17 24 31 0.3 0.3 0.3 0.3 0.3 1.4 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 7 14 21 28 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 5 0.3 0.3 1 0.31 0.3 5 0.3 0.3 3 0.3 0.3 1 0.3 0.3 1 0.3 0.3 3 0.7 0.68 0.3 0.3 5 19 0.34 0.3 0.32 0.3 5 19 0.3 0.3 0.3 0.3 2 16 0.3 0.3 0.3 0.3 5 19 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 5 19 0.3 0.3 0.3 0.3 10 24 0.3 0.3 0.3 0.3 7 22 0.3 0.3 0.3 0.3 0.3 0.3 Diff 0 0 0 0 0 1.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0.01 0 0 0 0 0.02 0 0.02 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2018 Sep 18 0.3 0.3 Oct 2 0.3 0.3 Nov 6 0.3 0.3 Dec 4 0.3 0.3 2019 Jan 9 0.3 0.3 Feb 5 0.3 0.3 Mar 4 0.3 0.3 Apr 1 0.3 0.3 May 7 0.3 0.3 Jun 4 18 0.3 0.3 0.3 0.3 Jul 9 23 0.3 0.3 0.3 0.3 Aug 6 20 0.3 0.3 0.3 0.3 Sep 3 17 0.3 0.3 0.3 0.3 Oct 1 0.3 0.3 Nov 5 0.3 0.3 Dec 2 0.3 0.3 2020 Jan 6 0.3 0.3 Feb 4 0.3 0.3 Mar 9 0.3 0.3 Apr 6 0.3 0.3 May 5 0.3 0.3 Jun 1 15 0.3 0.3 0.3 0.3 Jul 6 21 0.3 0.3 0.3 0.3 Aug 4 17 0.3 0.3 0.3 0.3 Sep 1 14 0.3 0.3 0.3 0.3 Oct 5 0.3 0.3 Nov 10 0.3 0.3 Dec 7 0.3 0.3 ilculate lb/month lb/year?) F-Test Two -Sample for Variances Variable 1 Variable 2 Mean 0.318235294 0.304705882 Variance 0.015993277 0.001701401 Observation: 85 85 df 84 84 F 9.400065854 P(F<=f) one- 2.84817E-21 F Critical onE 1.43472934 Comment: The variance of Variable 1 is higher than the variance of Variable 2. As a result, Ex We accept the null hypothesis. The variances of the two sets are unequal. t-Test: Two -Sample Assuming Unequal Variances Variable 1 Variable 2 Mean 0.318235294 0.304705882 Variance 0.015993277 0.001701401 Observation: 85 85 Hypothesize) 0 df 102 t Stat 0.93770676 P(T<=t) one- 0.175305094 t Critical one 1.659929976 P(T<=t) two- 0.350610188 t Critical two- 1.983495259 We look at the p-value, two tail. Since we set alpha value at 0.05, if the p-value is less than 0.1 There is not statistically significant difference between the upstream and downstream TP Sum of Value Year 2016 Jun Jul Aug cel calculates the correct Sep Oct Parameter Location 32230 - Chlorophyll A Day Downstream Upstream 1 8 15 22 29 6 13 20 27 3 10 17 24 31 7 14 21 28 Nov Dec 1 5 2017 Jan Feb Mar Apr Ma 3 1 1 3 Jun 5 19 Jul 10 24 Aug 2 16 Sep 05, we can say that there 2018 Oct Nov Dec Jan Feb Mar Apr May 5 19 Jun 2 6 4 4 6 6 2 8 5 19 Jul 10 24 Aug 7 21 Sep 6.57 11.7 3.55 12.3 14.9 10.4 11.6 11.4 7.43 10.9 14.2 12.5 8.41 8.77 14.4 10.2 4.77 11.9 6.52 9.05 10.9 9.83 10.6 12.7 10.1 6.92 9.05 4.84 11.5 6.98 6.03 8.9 10.9 7.51 9.94 9.1 7.54 6.98 6.56 7.89 8.91 10.2 11 9.29 5.83 9.16 6.5 6.86 7.69 8.61 9.94 8.34 12.2 9.25 12.2 9.41 10.8 9.64 11.7 9.5 12.6 9.15 11.6 12.8 11.8 8.97 9.78 9.32 8.38 8.08 9.65 9.31 7.18 7.47 10.9 8.58 9.54 10.6 8.34 8.78 6.89 6.65 10.7 9.2 10.1 9.01 9.48 9.67 12.8 11.4 12.4 8.99 11.7 11.2 8.28 7.83 8.97 8.7 Diff - 7.83 1.5 - 1.22 0.4 8.38 1.35 0.7 1.57 - 3.17 - 1.8 4.1 5.58 - 0.64 3.93 0.6 - 0.53 - 3.91 - 0.2 1.71 - 2.18 0.06 1.03 1.22 1.59 1.06 0.95 2.95 2.79 1.16 2.2 3.45 - 1.2 2.83 0.46 - 1.16 - 2.52 1.31 0.53 0.29 0.82 0.2 - 0.62 1.09 - 0.19 1.4 3.41 0.5 0.45 0.27 2018 Sep 18 9.12 7.57 Oct 2 10.6 10.9 Nov 6 10 8.81 Dec 4 7.53 9.48 2019 Jan 9 8.3 5.35 Feb 5 6.32 5.24 Mar 4 6.63 6.62 Apr 1 9.07 7.7 May 7 6 4.5 Jun 4 7.84 10.6 18 11.5 8.64 Jul 9 11.8 8.3 23 11.8 6.58 Aug 6 8.75 7.14 20 13.1 6.91 Sep 3 6.01 6.48 17 6.86 12 Oct 1 10 6.27 Nov 5 7.65 5.18 Dec 2 5.88 6.41 2020 Jan 6 4.7 3.56 Feb 18 7.16 5.21 Mar 9 8.07 9.02 Apr 6 11.8 10.5 May 5 11.1 12.2 Jun 2 12 5.15 16 12 10.7 Jul 6 8 13.1 21 8.33 5.34 Aug 4 11.7 9.49 17 9.31 8.34 Sep 1 11.6 12.8 14 8.84 8.66 Oct 5 8.57 6.64 Nov 10 2 2 Dec 7 2 2 1.55 -0.3 1.19 -1.95 2.95 1.08 0.01 1.37 1.5 -2.76 2.86 3.5 5.22 1.61 6.19 -0.47 -5.14 3.73 2.47 -0.53 1.14 1.95 -0.95 1.3 -1.1 6.85 1.3 -5.1 2.99 2.21 0.97 -1.2 0.18 1.93 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 F-Test Two -Sample for Variances Variable 1 Variable 2 Mean 9.344823529 8.506941176 Variance 6.470180028 6.022916723 Observation: 85 85 df 84 84 F 1.074260251 P(F<=f) one- 0.371739399 F Critical onE 1.43472934 Comment: The variance of Variable 1 is higher than the variance of Variable 2. As a result, Excel calc We accept the null hypothesis. The variances of the two sets are equal. t-Test: Two -Sample Assuming Equal Variances Variable 1 Variable 2 Mean 9.344823529 8.506941176 Variance 6.470180028 6.022916723 Observation: 85 85 Pooled Varia 6.246548375 Hypothesize( 0 df 168 t Stat 2.185533435 P(T<=t) one- 0.015116895 t Critical one 1.653974208 P(T<=t) two- 0.03023379 t Critical two- 1.974185191 We look at the p-value, two tail. Since we set alpha value at 0.05, if the p-value is less than 0.05, we There is statistically significant difference between the upstream and downstream Chlorophyll A Sum of Value Year 2016 Date Jun ulates the correct F value, 2 Parameter Location 31616 - Coliform, Fecal MF, MFC Broth, 44.5 C Day Downstream Upstream 1 2 6 7 8 13 14 15 20 21 22 27 28 29 Jul 5 6 7 11 12 13 18 19 20 25 26 27 Aug ;an say that there is a stat Sep 1 2 3 8 9 10 15 16 17 22 23 24 29 30 31 127 6000 1600 1000 580 88 38 547 40 500 23 180 26 225 26 223 11 177 100 155 220 183 120 203 6000 6000 2200 2600 1400 3100 5700 5300 800 600 310 300 6000 6000 6000 6000 1800 1000 500 570 380 6000 390 280 460 580 300 540 6000 6000 3300 3900 6000 6000 6000 6000 6000 6000 1900 1388 338 540 373 430 270 360 3200 4000 593 620 313 407 200 420 213 220 100 187 6 283 300 7 195 213 8 87 390 12 150 135 13 175 1000 14 240 150 19 140 110 20 200 185 Diff -5873 600 492 -509 -460 -157 -199 -197 -166 -55 37 -83 0 -400 -1700 400 200 10 0 0 800 -70 -5620 110 -120 -240 0 -600 0 0 0 512 -202 -57 -90 -800 -27 -94 -220 -7 -87 -17 -18 -303 15 -825 90 30 15 2016 Sep 21 1100 520 26 3600 6000 27 6000 6000 28 1500 1300 Oct 5 12 19 26 31 220 190 220 280 125 115 84 125 200 110 580 -2400 0 200 30 -60 10 -41 90 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 F-Test Two -Sample for Variances Variable 1 Variable 2 Mean 1757.689655 1456.37931 Variance 5326569.481 4466157.257 Observation: 58 58 df 57 57 F 1.192651574 P(F<=f) one- 0.254073626 F Critical onE 1.55175754 860412.2 Comment: The variance of Variable 1 is higher than the variance of Variable 2. As a result, Excel calculates the co We accept the null hypothesis. The variances of the two sets are equal. t-Test: Two -Sample Assuming Equal Variances Variable 1 Variable 2 Mean 1757.689655 1456.37931 Variance 5326569.481 4466157.257 Observation: 58 58 Pooled Varia 4896363.369 Hypothesize( 0 df 114 t Stat 0.733290775 P(T<=t) one- 0.232443182 t Critical one 1.658329969 P(T<=t) two- 0.464886363 t Critical two- 1.980992298 We look at the p-value, two tail. Since we set alpha value at 0.05, if the p-value is less than 0.05, we can say that t There is not statistically significant difference between the upstream and downstream DO N (B 0 0 N MONITORING REPORT(MR) VIOLATIONS for: Violation Action: % Subbasin: % Param Nam( % Major Minor: REGION: Mooresville COUNTY: Catawba FACILITY: City of Hickory - Catawba WWTP NC0025542 F 5 w a Limit Violation VIOLATION ACTION VIOLATION TYPE PARAMETER LOCATION N > > > (/) 0 > N N N N as as O D U U O as m W z O U O U O U O U -O c O O O _ -O c -O C -O c N N c 0 "' a) N a) a) N N a) a) U E -O -O -O O '- -O N E N E N E N E O o w aoi aoi %) aoi o 2 0 2 2 0 d i U U < 0 i a i a i a i o O O O o m O o 0 0 0 c d a d z U d c c c c w w w w w Proceed to Enforcement Case a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) ii a) ii a) ii a) ii a) ii a) ii a) ii a) ii a`) a) a`) a) a`) a) a`) a) a`) a) a`) a) a`W a) a`W a) a`) a) a) a) a`) a) > 'O > 'O > 'O > 'O > 'O > 'O > 'O > 'O > 'O > 'O > 'O < a) < a) < a) < a) < a) < a) < a) < a) < a) < a) < a) >, a) >, a) _T a) >, a) >, a) >, a) _T _T a) a) _T a) a) U U U U U U U U U U U -c X -c X Y X -c X -c X -c X Y X Y X -c X Y X -c X c w c w N w c w c w c w N w N w c w N w c w o o Proceed to NOD Proceed to NOD Proceed to NOV O O O Z Z Z ED ED E -O 0 7 0 7 0 E € E € E s c m c m c m VIOLATION ACTION VIOLATION TYPE O O O) l() O O O N Co. 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Q o Downstream Downstream Downstream Downstream E a) a) 0 0 Downstream Downstream E a) 0 0 Downstream O - O - O - O - O - O - O - O - O - O - O - O - O - O - O - O O O O O O O O O O O O O O O O O CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO O O - O - O - O - O - O - O - O - O - O - O - O - O - O - O N N N N N N N N N N N N N N N N MONITORING REPORT(MR) VIOLATIONS for: Violation Action: % Subbasin: % Param Nam( % Major Minor: REGION: Mooresville COUNTY: Catawba FACILITY: City of Hickory - Catawba WWTP NC0025542 F 5 W a VIOLATION ACTION VIOLATION TYPE H 2 J FREQUENCY PARAMETER LOCATION as > > > > > > > > > > > > > > > > C c C C c c c C c C c C C c c c_ cE cE cE cE c€ cE c€ cE cE cE cE c€ cE cE cE cE o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) a d t d t d t d t d t d t d t d t d t d t d t d t d t d t d t d 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 z z z z z z z z z z z z z z z z c c c c c c c c c c c c c c c c 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 as as as as as as as as as as as as as as as as O O O O O O O O O O O O O O O 0 > > > > > > > > > > > > > > > > 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 c c c c c c c c c c c c c c c c a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CT a a a a a a a a a a a a a a a E E E E E E E E E E E E E E E E O O O O O O O O O O O O O O O O o o O O O O O O O O O O O O O O Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y aa)) a) a) a) a) a) aa)) aa)) a) a) a) a) a) a) aa)) aa)) > > > > > > > > > > > > > > > > v v ao ao v v 7 7 ao ao u) u) O O N N N N O O 7 7 N N N N N N N N N N 0 0 0 0 0 0 0 o O O O O O O O O U U 0 0 0 0 0 0 0 0 0 0 0 0 0 0 u_ LL LL LL LL LL LL LL LL LL LL LL LL LL LL LL LL U LL U LL U LL U LL U LL U LL C.)LL C.)LL C.)LL C.)LL C.)LL U LL U LL U LL U LL U m m 4 s m 4 s To 4 s m 4 s m m 4 s m 4 s To 4 s 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a) a) - a) a) - a) a) - a) a) - a) a) a) - a) a) - a) a) - a) i s i s i s i s i s i s i s i s i s i s i s i s i s i s i s i s o o o o o o o o o o o o o o o o o - o - o - o - o - o - o - o - o - o - o - o - o - o - o - o g m E m E m E m E m E m E m E m E m E m E m E m E m E m E m EL 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o O O O O O O O O O O O O O 0 U U 0 0 0 0 0 0 0 0 0 0 0 0 0 0 E m E m E m E m m E E m E m m E as as as as as as as as N 112 N N N N N N 0_ 3 O_ 3 0_ 3 0_ 3 3 0_ O_ 3 O_ 3 3 O_ D 0 D 0 D 0 D O 0 D D 0 D O 0 D D D D D D D D D O O O O O O O O O O O O O O O O o o O O O O O O O O O O O O O O O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N N N N N N N N N N N N N N N N N N N N N N N N O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 MONITORING REPORT(MR) VIOLATIONS for: Violation Action: % Subbasin: % Param Nam( % Major Minor: REGION: Mooresville COUNTY: Catawba FACILITY: City of Hickory - Catawba WWTP NC0025542 F 5 W a VIOLATION ACTION VIOLATION TYPE H 2 J FREQUENCY PARAMETER LOCATION J J Q LL C F O D T6 0 o_ O zF E 00 o I- a 0 0 CC D • D D 0 • 0 • 0 0 > > > > > > > > > > > > > > > as cE cE cE cE c€ cE c€ cE cE cE cE c€ cE cE cE cE o a) o a) o a`) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) o a) a d t d t d t d t d t d t d t d t d t d t d t d t d t d t d t d O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 z z z z z z z z z z z z z z z z O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 (o (o (o (o (o (o (o (o (o (o (o (o (o (o (o (o o o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 > > > > > > > > > > > > > > > > O ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 ▪ 0 c c c c c c c c c c c c c c c c a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) CT a a a a a a a a a a a a a a a E E - 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o - o - o - o - o - o - o - o - o - o - o - o - o - o - o g m E m E m E m E m E m E m E m E m E m E m E m E m E m E m EL 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 U U 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Downstream Downstream Downstream E a) w 0_ Downstream Downstream Downstream Downstream Downstream O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N N N N N N N N N CO CO CO CO CO CO 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Page 24 o1 27 0 0 0 Q N MONITORING REPORT(MR) VIOLATIONS for: Violation Action: % Subbasin: % Param Nam( % Major Minor: REGION: Mooresville COUNTY: Catawba FACILITY: City of Hickory - Catawba WWTP NC0025542 F 5 W a VIOLATION ACTION VIOLATION TYPE H 2 J FREQUENCY PARAMETER LOCATION J J Q LL c F O D T6 0 o_ O zF E O O o I- a OOCC D -es -es D D > > > > > > > > > > > > > > > as c c c c c c c c c c c c c c c c_ cE cE cE cE c€ cE c€ cE cE cE cE c€ cE cE cE cE o w o w o w o w o w 0 W 0 W 0 W 0 W 0 W 0 W 0 W 0 W 0 W 0 W 0 W d t d t d t d t d t d t d t d t d t d t d t d t d t d t d t d 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 z z z z z z z z z z z z z z z z c c c c c c c c c c c c c c c c 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 > > > > > > > > > > > > > > > > 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 c c c c c c c c c c c c c c c c a) a) a) as as as a) as as as as as as as as a) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CT a a a a a a a a a a a a a a a E E E E E E E E E E E E E E E E O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) > > > > > > > > > > > > > > > > 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N N N N N N N N N N N N N N N N W W V V Co- Co- In In N N O) O) CO CO N N O O 7 7 N N O O O O M M V V V V V V V V N N N N N N O O O O O O O O O O O O O O O O U U U U U U U U U U U U U U U U u_ LL LL LL LL LL LL LL LL LL LL LL LL LL LL LL LL U LL U LL U LL U LL U LL U LL U LL U LL U LL U LL U LL U LL U LL U LL U LL U m m 4 s m 4 s To 4 s m 4 s m m 4 s m 4 s To 4 s 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 i s i s i s i s i s i s i s i s i s i s i s i s i s i s i s i s o o o o o o o o o o o o o o o o o - o - o - o - o - o - o - o - o - o - o - o - o - o - o - o g m E m E m E m E m E m E m E m E m E m E m E m E m E m E m E m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 U U 0 0 0 0 0 0 0 0 0 0 0 0 0 0 E a) o_ Downstream Downstream E a) fn o_ Downstream Downstream E a) 0) o_ Downstream Downstream Downstream Downstream E a) a) 0) o_ O O O O O O O O O O O O O O O O o o O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N CO CO V V V V V V V V In In In In In In 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Page 25 o1 27 N 0 0 N MONITORING REPORT(MR) VIOLATIONS for: O U 0 ( 0 Permit: NC0025542 MRs Betweei 1 - 2016 and Violation Action: % Subbasin: % Param NamE % Facility Name: % Major Minor: REGION: Mooresville COUNTY: Catawba FACILITY: City of Hickory - Catawba WWTP NC0025542 F 5 W a VIOLATION ACTION VIOLATION TYPE FREQUENCY PARAMETER LOCATION J J Q LL C F O D 0 o_ O zI- C Ecc 00 o 1-0_ E 0 D D D D D D 0 -0 0 -0 0 -0 -0 0 0 0 as > > > > > > > > > > > > > > > > C c C C c c c C c C c C C c c c_ cE cE cE cE c€ cE c€ cE cE cE cE c€ cE cE cE cE o a`) o a`) o a`) o a`) o a) o a`) o a) o a`) o a`) o a`) o a`) 0 a) 0 a`) 0 a`) 0 a`) 0 W ▪ d t d tip- tip- t d t d tip- t d t d t d t d tip- tip- t d t d t d O 0 0 0 0 0 0 0 0 0 0 O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 z z z z z z z z z z z z z z z z C c c c c c c c c c c c c c c c O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N N N N N N N N N N N N N N N N o o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 > > > > > > > > > > > > > > > > o o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 c c c c c c c c c c c c c c c c a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) a) O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CT a a a a a a a a a a a a a a a E E - 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Catawba WWTP NC0025542 F 5 W a VIOLATION ACTION VIOLATION TYPE FREQUENCY PARAMETER LOCATION Frequency Violation 1- 0) N O ROY COOPER Governor MICHAEL S. REGAN Secretary S. DANIEL SMITH NORTH CAROLINA Director Environmental Quality January 19, 2021 Shawn Pennell, Public Utilities Director City of Hickory Post Office Box 398 Hickory, North Carolina 28603-0398 Subject: Compliance Evaluation Inspection Hickory -Catawba WWTP NPDES Permit No. NC0025542 Catawba County Dear Mr. Pennell: Enclosed is a copy of the Compliance Evaluation Inspection Report for the inspection conducted at the subject facility on January 14, 2021, by Mr. Wes Bell of this Office. Please inform the facility's Operator -in -Responsible Charge (ORC) of our findings by forwarding a copy of the enclosed report. Should you have any questions concerning this letter, please do not hesitate to contact Mr. Bell at (704) 235- 2192, or via email at wes.bell@ncdenr.gov. Enclosure: Inspection Report QE NORTH CAROLINA Department ,t En*o.,rapbl Qualllp Sincerely, T—DocuSigned by: —A14CC681AF27425... W. Corey Basinger, Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NCDEQ North Carolina Department of Environmental Quality I Division of Water Resources Mooresville Regional Office 1610 East Center Avenue, Suite 301 I Mooresville, North Carolina 28115 704.663.1699 United States Environmental Protection Agency EPA Washington, D.C. 20460 Water Compliance Inspection Report Form Approved. OMB No. 2040-0057 Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code 1 IN I 2[ I 211I1111 111111111 NPDES yr/mo/day Inspection 3 I NC0025542 111 121 21/01/14 117 Type 181 I II 111111111 Inspector Fac Type 191 s I 2011 II 1111111 I I II I 66 11 1 Inspection Work Days 67I2.0 Facility Self -Monitoring Evaluation Rating B1 QA Reserved I 7° I4 I 71 IN I 72 I N I 73I I 174 I 751 11 1 I I I I I I 180 l Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include POTW name and NPDES Dermit Number) Catawba WWTP End Of Sixth Ave Nw Catawba NC 28609 Entry Time/Date 09:25AM 21/01/14 Permit Effective Date 16/11/01 Exit Time/Date 12:05PM 21/01/14 Permit Expiration Date 20/04/30 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) /// David Archambault/ORC/828-234-7419/ Todd Atwell Bumgarner//828-322-5075 / Other Facility Data Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Warren Wood,PO Box 398 Hickory NC 286010398/City Manager/828-323-7412/ No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit Flow Measurement Operations & Maintenar Records/Reports Self -Monitoring Progran Sludge Handling Dispo: Facility Site Review Effluent/Receiving Wate Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) Wes Bell of Inspector(s) Agency/Office/Phone and Fax Numbers Date ,-DocuSigned by: DWR/MRO WQ/704-663-1699 Ext.2192/ ?4l, B 1/19/2021 '-A61696D90CC3437... Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date W. Corey Basinger DWR/Division of Water Quality/704-235-2194/ EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. 1- DocuSigned by: 1/19/2021 �A14CC681AF27425... Page# 1 NPDES yr/mo/day 31 NC0025542 111 121 21/01/14 I17 Inspection Type 18 [j 1 Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Page# 2 Permit: NC0025542 Inspection Date: 01/14/2021 Owner - Facility: Catawba WWTP Inspection Type: Compliance Evaluation Permit (If the present permit expires in 6 months or less). Has the permittee submitted a new application? Is the facility as described in the permit? # Are there any special conditions for the permit? Is access to the plant site restricted to the general public? Is the inspector granted access to all areas for inspection? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ • ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Comment: The Division received the facility's permit renewal application on 1/16/2020. The City implements a Division -approved Industrial Pretreatment Program. The last compliance evaluation inspection at this facility was performed by DWR staff on 12/12/2018. Record Keeping Are records kept and maintained as required by the permit? Is all required information readily available, complete and current? Are all records maintained for 3 years (lab. reg. required 5 years)? Are analytical results consistent with data reported on DMRs? Is the chain -of -custody complete? Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? Has the facility submitted its annual compliance report to users and DWQ? (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operatc on each shift? Is the ORC visitation log available and current? Is the ORC certified at grade equal to or higher than the facility classification? Is the backup operator certified at one grade less or greater than the facility classification' Is a copy of the current NPDES permit available on site? Facility has copy of previous year's Annual Report on file for review? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • • • • • • • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ • ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ ❑ • Page# 3 Permit: NC0025542 Inspection Date: 01/14/2021 Owner - Facility: Catawba WWTP Inspection Type: Compliance Evaluation Record Keeping Yes No NA NE Comment: The records reviewed during the inspection were organized and well maintained. Discharge Monitoring Reports (eDMRs) were reviewed for the period December 2019 through November 2020. All monitoring frequencies were correct. Weekly average effluent ammonia violations were reported in March and April 2020. Monthly average effluent ammonia violations were reported in January, March and April 2000. These violations have been previously addressed by the Division through the issuances of Notice of Violations (NOVs) and/or civil penalty assessments. Laboratory Are field parameters performed by certified personnel or laboratory? Are all other parameters(excluding field parameters) performed by a certified lab? # Is the facility using a contract lab? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? Incubator (BOD) set to 20.0 degrees Celsius +/- 1.0 degrees? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ • ❑ ❑ ❑ • ❑ Comment: Influent and effluent analyses are performed under the City of Hickory's municipal laboratory certification #203. Pace Analytical Services, Blue Ridge Labs and ETT Environmental have also been contracted to provide analytical support. Influent Sampling # Is composite sampling flow proportional? Is sample collected above side streams? Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is sampling performed according to the permit? Yes No NA NE • ❑ ❑ ❑ ❑ • ❑ ❑ • ❑ ❑ ❑ ▪ ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Comment: The subject permit requires influent BOD and TSS composite samples. Sampler aliquot checks are performed (and documented) multiple times per month. Filter backwash, plant drainage system and decant (sludge holding tanks) all discharge upstream of the influent sampling location; however, the ORC and staff do not decant during influent sampling events. The City is currently investigating a new influent sampling location above all side streams. Effluent Sampling Is composite sampling flow proportional? Is sample collected below all treatment units? Is proper volume collected? Yes No NA NE ▪ ❑ ❑ ❑ ▪ ❑ ❑ ❑ • ❑ ❑ ❑ Page# 4 Permit: NC0025542 Inspection Date: 01/14/2021 Owner - Facility: Catawba WWTP Inspection Type: Compliance Evaluation Effluent Sampling Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type representative)? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Comment: The subject permit requires composite and grab effluent samples. Sampler aliquot checks are performed (and documented) multiple times per month. Upstream / Downstream Sampling Yes No NA NE Is the facility sampling performed as required by the permit (frequency, sampling type, an( • ❑ ❑ ❑ sampling location)? Comment: Operations & Maintenance Is the plant generally clean with acceptable housekeeping? Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable Solids, pH, DO, Sludge Judge, and other that are applicable? Yes No NA NE ▪ ❑ ❑ ❑ ▪ ❑ ❑ ❑ Comment: The wastewater treatment facility appeared to be properly operated and well maintained. The facility staff incorporate a comprehensive process control program with all measurements being properly documented and maintained on -site. In-depth operation and maintenance records were also being maintained on -site. The facility is also equipped with a SCADA System. Although not required, the facility is visited by certified operators seven days per week. Bar Screens Type of bar screen a.Manual b.Mechanical Are the bars adequately screening debris? Is the screen free of excessive debris? Is disposal of screening in compliance? Is the unit in good condition? Comment: Grit Removal Type of grit removal a.Manual Yes No NA NE • • ❑ ❑ ❑ ▪ ❑ ❑ ❑ ▪ ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE Page# 5 Permit: NC0025542 Inspection Date: 01/14/2021 Owner - Facility: Catawba WWTP Inspection Type: Compliance Evaluation Grit Removal b.Mechanical Is the grit free of excessive organic matter? Is the grit free of excessive odor? # Is disposal of grit in compliance? Comment: Screenings and grit are disposed at the County Landfill. Oxidation Ditches Are the aerators operational? Are the aerators free of excessive solids build up? # Is the foam the proper color for the treatment process? Does the foam cover less than 25% of the basin's surface? Is the DO level acceptable? Are settleometer results acceptable (> 30 minutes)? Is the DO level acceptable?(1.0 to 3.0 mg/I) Are settelometer results acceptable?(400 to 800 ml/I in 30 minutes) Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Comment: One of two oxidation ditch trains was in service due to low influent flows. Each oxidation ditch train is equipped with an anaerobic and anoxic basin. Soda ash is added to maintain alkalinity/pH levels and a microbial supplement is added to provide an additional carbon source. Secondary Clarifier Yes No NA NE Is the clarifier free of black and odorous wastewater? Is the site free of excessive buildup of solids in center well of circular clarifier? Are weirs level? Is the site free of weir blockage? Is the site free of evidence of short-circuiting? Is scum removal adequate? Is the site free of excessive floating sludge? Is the drive unit operational? Is the return rate acceptable (low turbulence)? Is the overflow clear of excessive solids/pin floc? Is the sludge blanket level acceptable? (Approximately'/ of the sidewall depth) • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Comment: Both secondary clarifiers were operational; however, only one clarifier was in service. Page# 6 Permit: NC0025542 Inspection Date: 01/14/2021 Owner - Facility: Catawba WWTP Inspection Type: Compliance Evaluation Pumps-RAS-WAS Are pumps in place? Are pumps operational? Are there adequate spare parts and supplies on site? Comment: Filtration (High Rate Tertiary) Type of operation: Is the filter media present? Is the filter surface free of clogging? Is the filter free of growth? Is the air scour operational? Is the scouring acceptable? Is the clear well free of excessive solids and filter media? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE Down flow • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ • ❑ Comment: All four tertiary filters were operational; however, only one filter was in service. Disinfection -Liquid Is there adequate reserve supply of disinfectant? (Sodium Hypochlorite) Is pump feed system operational? Is bulk storage tank containment area adequate? (free of leaks/open drains) Is the level of chlorine residual acceptable? Is the contact chamber free of growth, or sludge buildup? Is there chlorine residual prior to de -chlorination? Comment: Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ De -chlorination Yes No NA NE Type of system ? Liquid Is the feed ratio proportional to chlorine amount (1 to 1)? ❑ ❑ ❑ Is storage appropriate for cylinders? ❑ ❑ • ❑ # Is de -chlorination substance stored away from chlorine containers? ❑ ❑ ❑ Comment: Are the tablets the proper size and type? ❑ ❑ • ❑ Are tablet de -chlorinators operational? ❑ ❑ • ❑ Number of tubes in use? Page# 7 Permit: NC0025542 Inspection Date: 01/14/2021 Owner - Facility: Catawba WWTP Inspection Type: Compliance Evaluation De -chlorination Yes No NA NE Comment: Flow Measurement - Effluent # Is flow meter used for reporting? Is flow meter calibrated annually? Is the flow meter operational? (If units are separated) Does the chart recorder match the flow meter? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ • ❑ Comment: The flow meter is calibrated twice per year and was last calibrated on 1/16/2020 by Diversified Integration, Inc. Effluent Pipe Is right of way to the outfall properly maintained? Are the receiving water free of foam other than trace amounts and other debris? If effluent (diffuser pipes are required) are they operating properly? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ • ❑ Comment: The effluent appeared clear with no floatable solids or foam. The receiving stream did not appear to be negatively impacted. Aerobic Digester Is the capacity adequate? Is the mixing adequate? Is the site free of excessive foaming in the tank? # Is the odor acceptable? # Is tankage available for properly waste sludge? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Comment: The facility is equipped with two aerated sludge holding tanks. Sludge is transported by City personnel to the Regional Compost Facility for continued processing/treatment. Standby Power Is automatically activated standby power available? Is the generator tested by interrupting primary power source? Is the generator tested under load? Was generator tested & operational during the inspection? Do the generator(s) have adequate capacity to operate the entire wastewater site? Is there an emergency agreement with a fuel vendor for extended run on back-up power? Is the generator fuel level monitored? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ ▪ ❑ ❑ ❑ ▪ ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Page# 8 Permit: NC0025542 Inspection Date: 01/14/2021 Owner - Facility: Catawba WWTP Inspection Type: Compliance Evaluation Standby Power Yes No NA NE Comment: The backup generator is tested twice per month with one of these tests being under a load. The generator is serviced by City personnel and Cummings has also been contracted to perform repairs, etc. Page# 9 Attachment A —Request for Missing Information Table 2. EPA Application Form 2A Missing Information 40 CFR 122.21(j)(1) 1.1 > Email address of facility contact Keith Rhyne, krhyne@hickorync.gov 1,2 Applicant email address Shawn Pennell, spennelf@hickorync.gov 1 3 :` Email address of the organization transporting the discharge for treatment prior to discharge City of Hickory, Keith Rhyne, krhyne@hickorync.gov 14 ': Email address of the organization receiving the discharge for treatment prior to discharge City of Hickory Regional Compost Facility, Paul Spencer, paul.spencer@veolia.com 1 5 ; Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(n)? (Check all that apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and when.) Discharges into marine waters (CWA Section Water quality related effluent limitation (CWA 301(h)) Section 302(b)(2)) El Not applicable 1.6 40 CFR Email address of contractor responsible for operational or maintenance Andrew Foy, afoy , hicko nc.gov 122.216)(6) aspects of the treatment works 1 7 Indicate the number of SIUs and NSCIUs that discharge to the POTW. Number of SIUs Number of ClUs 0 0 40 CFR 1,8 ': 122.22(a) and (d) were prepared under my direction or supervision in properly gather and evaluate the information submitted. system, or those persons directly responsible for gathering the and belief, true, accurate, and complete. I am aware that the possibility of fine and imprisonment for knowing Certification Statement 1 certify under penalty of law that this document and all attachments accordance with a system designed to assure that qualified personnel Based on my inquiry of the person or persons who manage the information, the information submitted is, to the best of my knowledge there are significant penalties for submitting false information, including violations. Name (print or type first and last name) Warren Wood Official title City Manager — City of Hickory Signat re Date signed 2/24/2021 Mail - Yitbarek, Diana - Outlook [External] RE: NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO Caleb Bynum <cbynum@hickorync.gov> Mon 2/22/2021 12:58 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> 2 attachments (407 KB) Catawba WWTP - Request for Missing Information.pdf; Catawba EPF Justification and Analyses.pdf; CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Good afternoon, Diana. I have been able to gather the information that you requested to help complete the Catawba WWTP permit renewal. I will address each of your requests using the numbering you established below. 1. See attached. 2. Outfall Coordinates: 35.715580 N, 81.073474 W Upstream (Lyle Creek @NC 10) : 35.715112 N, 81.077798 W Downstream (@ Marina off Canvasback Ln) : 35.710036 N, 81.060843 W 3. None 4. The City of Hickory would like to request reduced monitoring for BOD, TSS, NH3/N, and Fecal Coliform. I have attached the EPF Justification and Analysis document that was included with the permit renewal for reference. 5. The City of Hickory does not conduct an IWS for the Catawba WWTF as there are no industries in the service area. However, as a continuous IWS effort, the City would be notified if any new industry moved into the Catawba WWTF service area. At that point a completed short -form would be required from the user along with any other documentation deemed necessary. Let me know if you have any questions. Thanks, Caleb Bynum, El Utilities Engineer City of Hickory Public Utilities cbynum@hickorync.gov (828)323-7473 HICKORY 42 Middle Life. Well C t&d From: Yitbarek, Diana [mailto:diana.yitbarek@ncdenr.gov] Sent: Friday, February 12, 2021 4:17 PM To: Caleb Bynum <cbynum@hickorync.gov> Subject: NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO CAUTION: This email originated from outside of the organization https://outlook.office365.com/mail/inbox/id/AAQkADNmOTIxZjdhLTEyMWYtNDEzMS1 iOGNiLTkxNmZhYWJmZThIMAAQACfx0M44QwdNoMmNE%2... 1/2 2/24/2021 Mail - Yitbarek, Diana - Outlook Good afternoon, Caleb I recently started reviewing the October 30, 2019, NPDES permit application for renewal for the Catawba WWTP. Please provide additional or revised information to address the following comments: 1. Please complete this short form to meet the new application requirements for the updated application form 2A. 2. Please revise the outfall coordinate location (32°42155"N 81°04'25" W) and provide coordinates for the upstream and downstream location points (approximate coordinates from google maps would suffice). 3. If there are additional pollutants with certified methods to be reported, please submit this Chemical Addendum. If applicable, list the selected certified analytical method used. 4. I noted the cover letter included a request for this plant to be designated as an exceptionally performing facility and requested reduced monitoring. Please specify the parameters for which the City would like to request frequency monitoring reduction. 5. Please submit the last industrial waste survey (IWS) performed for the Catawba WWTP service area We'll appreciate it if you provide this information within the next three weeks; if you need more time, please let me know. Thanks for your continued cooperation with the NPDES program and your work protecting public health and the environment. Please let me know if you have any questions. Best, -Diana Diana Yitbarek Engineer T: +1-919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street, Rm. 925T, Raleigh, NC 27604-1170 E ..•,.,:•• OnpvinwM aI fm+r r•Irr nial 0ciai��r *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. https://outlook.office365.com/mail/inbox/id/AAQkADNmOTIxZjdhLTEyMWYtNDEzMS1 iOGNiLTkxNmZhYWJmZThIMAAQACfx0M44QwdNoMmNE%2... 2/2 Re: [External] RE: (methyl bromide) NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO Yitbarek, Diana <diana.yitbarek@ncdenr.gov> 3/29/202 To: Bynum, Caleb M <cbynum@hickorync.gov> Bcc: Montebello, Michael J <Michael.Montebello@ncdenr.gov> Good afternoon, Caleb - Thanks for your message. Analytical methods shall be in accordance with 40 CFR Part 136. If no approved methods can achieve results below the PQL/below the permit discharge requirement, the method with the lowest detection level must be used. According to the NC DEQ Methods and PQL list (revised on 1/22/2021), the current method for Methyl Bromide/Bromomethane with the lowest detection level is EPA 624/SW-846 8260 B (PQL 2 ug/I). I can't specify the method in the permit, but I will add the above language to the fact sheet. I will move forward with the compliance schedule. The draft permit will be public noticed on 4/6/2021. Please let me know if you have any questions. -Diana Diana Yitbarek Engineer T: +1-919-707-9130 dianayitbarekE ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing. 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street, Rm. 925T, Raleigh, NC 27604-1170 Qs,) 7�t ,rrn o.�naune�� aumiir *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Caleb Bynum <cbynum@hickorync.gov> Sent: Monday, March 29, 2021 08:37 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Subject: [External] RE: (methyl bromide) NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Good morning, Diana. I appreciate you taking the time to walk us through that RPA process. Is there language in the permit that makes it clear what test result will be considered in compliance? I believe you said that a result of below the PQL will be considered in compliance, but I just want to make sure that its clear in the permit. I just wanted to make sure there was no other method of writing in an end to the compliance schedule in the permit. We would like to move forward with the compliance schedule that you laid out in your first email. Thanks, Caleb Bynum, El Utilities Engineer City of Hickory Public Utilities cbynum@hickorync.gov (828)323-7473 HICKORY U£$. Welt CraF[d From: Yitbarek, Diana [mailto:diana.yitbarek@ncdenr.gov] Sent: Friday, March 26, 2021 3:52 PM To: Caleb Bynum <cbynum@hickorync.gov> Subject: (methyl bromide) NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO CAUTION: This email originated from outside of the organization Good afternoon, Caleb Thanks for your message. 1. I confirm that the proposed Methyl Bromide limit is 0.26 pg/I for the 1.5 MGD flow tier based on the reasonable potential analysis (RPA). In some cases, the RPA calculates the limit below the PQL. For this RPA, we used the methyl bromide data provided in the last effluent pollutant scans and the water quality standard for aquatic life, 0.04 ug/L. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of 1/2 detection limit for "less than" values; and 4) stream flows used for dilution consideration based on 15A NCAC 26.0206. I am attaching the RPA output table. 2. The City could "cancel" the compliance schedule by submitting a major permit modification. Further information on permit modification processes is here. a. You are correct. Methyl Bromide will be required as a grab sample. Please let me know if you have any questions. Have a good weekend! -Diana Diana Yitbarek Engineer T: +1-919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street, Rm. 925T, Raleigh, NC 27604-1170 *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Caleb Bynum <cbynum@hickorync.gov> Sent: Wednesday, March 24, 2021 16:17 To: Yitbarek, Diana <diana.yitbarekjncdenr.gov> Subject: [External] RE: (methyl bromide) NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO rCAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Diana, We have been discussing this one around the office pretty extensively, and we have a few questions. 1. Will you confirm that the proposed Methyl Bromide limit is 0.26 pg/I as provided below? What is the reason for having a limit that far below the PQL for the contaminant? 2. Is there a means for us to "cancel" the compliance schedule if after a year of testing we determine that we do not have a problem with Methyl Bromide? With it being a grab sample, it is more subject to contamination from surrounding elements than a composite sample. We feel that the elevated samples could have been a result of contamination rather than from an influent source. However, without more information it is hard to know. We do not want to decline the compliance schedule and then have a problem meeting the limit, but we also don't want to go through the additional effort for three years if we don't actually have a problem. I appreciate your help on this. Thanks, Caleb Bynum, El Utilities Engineer City of Hickory Public Utilities cbynin@hickorync.gov (828)323-7473 cid:image002.jpg@010E6B31.81355A50 From: Yitbarek, Diana[mailto:diana.yitbarek@ncdenr.gov] Sent: Monday, March 22, 2021 12:40 PM To: Caleb Bynum <cbynum@hickorync.gov> Subject: (methyl bromide) NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO CAUTION: This email originated from outside of the organization Good afternoon, Caleb Thanks for the information provided. We are close to completing the draft permit and need your input on the following: Background Information: Based on the reasonable potential analysis (RPA), we plan on including a Monthly Average limit for methyl bromide (0.26 pg/I). Here is the methyl bromide data provided in the last effluent pollutant scans: Date Data 2/2/2016 4.4 8/8/2017 < 2 11 /6/2018 11.7 5/9/2019 < 2 2/4/2020 < 2 To provide an opportunity for the City to develop a plan to assess sources of methyl bromide in order to come in compliance with the limits, we could add to the permit a 3-year schedule of compliance to the permit, as follows: 1. One year after the effective date, the Permittee shall submit to the Division of Water Resources a Corrective Action Plan summarizing the actions or strategy to be taken to achieve compliance with the methyl bromide limits at outfall 001. Specific dates for completion or implementation of each action shall be included. 2. Two years after the effective date, the Permittee shall identify sources of the pollutant and evaluate source reduction alternatives. The Permittee shall submit a report to the Division summarizing actions taken in accordance with the Corrective Action Plan. 3. Three years after the effective date, the Permittee shall achieve compliance with methyl bromide limits specified in Section A.(1). Upon approval of the Corrective Action Plan by the Division, the report and actions become an enforceable part of this permit. Any modifications to the schedule shall be requested to the Division at least ninety (90) days before the deadline. Modifications to the schedule in excess of four months will be subject to public notice. Here is where I need your input: Please let us know whether the City needs us to include the compliance schedule. Thanks, -Diana Diana Yitbarek Engineer T: +1-919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street, Rm. 925T, Raleigh, NC 27604-1170 i d: i mage001.j pg@01 D72006. F3 D624B0 *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Caleb Bynum <cbynum@hickorync.gov> Sent: Thursday, March 4, 2021 14:03 To: Yitbarek, Diana <diana.yitbarekjncdenr.gov> Subject: [External] FW: NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Good afternoon, Diana. Please see below for the response from our pretreatment coordinator concerning the required 2nd species test results, and the corrected numbers for the eDMR entries. Let me know if you need any more information from us. Thanks, Caleb Bynum, El Utilities Engineer City of Hickory Public Utilities cbynum@hickorync.gov (828)323-7473 cid:image002.jpg@010E6B31.81355A50 From: David Cox Sent: Thursday, March 4, 2021 7:57 AM To: Caleb Bynum <cbynum hickorync.gov> Subject: RE: NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO Good morning Caleb, 1. The 2nd species toxicity results were attached to the renewal and are on page 30. All required Fathead Minnow sampling was conducted and I have attached the spreadsheet with the monitoring results for your reference. 2. Hardness — 5/8/18 — 46,100 ug/I Zn — 10/5/16 — <50 ug/I Zn — 10/19/16 — <50 ug/I Zn — 5/8/18 — 39.9 ug/I Zn — 11/5/19 — 27.8 ug/I These were all unit errors. The eDMR system doesn't automatically input Hardness and Zn into the template, so we have to manually add those parameters (along with units and sample type) each month. Let me know if you need anything else. Thanks, David R. Cox Pretreatment Coordinator dcox©hickorync.gov City of Hickory (828) 322-4821 www.hickorync.gov ,,city logo (email) From: Caleb Bynum Sent: Wednesday, March 3, 2021 4:08 PM To: David Cox <dcox@hickorync.gov> Subject: FW: NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO David, Would you mind looking at the email below from Diana, and get the information together that she is asking for? I can send you a copy of what I sent with the renewal if you need it for reference. Thanks, Caleb Bynum, El Utilities Engineer City of Hickory Public Utilities cbynum@hickorync.gov (828)323-7473 cid:image002.jpg@010E6B31.81355A50 From: Yitbarek, Diana [mailto:diana.yitbarek@ncdenr.gov] Sent: Wednesday, March 3, 2021 3:55 PM To: Caleb Bynum <cbynumPhickorync.gov> Subject: NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO CAUTION: This email originated from outside of the organization Good afternoon, Caleb - Thank you for the information provided. I will appreciate your support with the following: 1. The permit for this facility requires four toxicity tests for a test organism other than Ceriodaphnia. Our database shows records for three 2nd species tests (11/2018, 2/2019, and 8/2019). Please double-check your records and submit the 2nd species test lab results. 2. Please clarify/correct the eDMR entries for the following values: hardness on 5/18/2018 (46100 mg/I.); zinc on 10/5/16 and 10/19/16 (<50 mg/I); zinc on 5/8/18 (39.9 mg/I) and 11/5/19 (27.8 mg/I). Thanks! -Diana Diana Yitbarek Engineer T: +1-919-707-9130 M: +1-415-735-5582 diana yitbarekAncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing. 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street Rm. 925T Raleigh NC 27604-1170 id: image004.png401D720C6.F3D624B0 *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Caleb Bynum <cbynum@hickorync.gov> Sent: Monday, February 22, 2021 12:58 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Subject: [External] RE: NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO rCAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Good afternoon, Diana. I have been able to gather the information that you requested to help complete the Catawba WWTP permit renewal. I will address each of your requests using the numbering you established below. 1. See attached. 2. Outfall Coordinates: 35.715580 N, 81.073474 W Upstream (Lyle Creek @NC 10) : 35.715112 N, 81.077798 W Downstream (@ Marina off Canvasback Ln) : 35.710036 N, 81.060843 W 3. None 4. The City of Hickory would like to request reduced monitoring for BOD, TSS, NH3/N, and Fecal Coliform. I have attached the EPF Justification and Analysis document that was included with the permit renewal for reference. 5. The City of Hickory does not conduct an IWS for the Catawba WWTF as there are no industries in the service area. However, as a continuous IWS effort, the City would be notified if any new industry moved into the Catawba WWTF service area. At that point a completed short -form would be required from the user along with any other documentation deemed necessary. Let me know if you have any questions. Thanks, Caleb Bynum, El Utilities Engineer City of Hickory Public Utilities cbynt.n@hickorync.gov (828)323-7473 cid:image002.jpg@010E6B31.81355A50 From: Yitbarek, Diana [mailto:diana.yitbarek@ncdenr.gov] Sent: Friday, February 12, 2021 4:17 PM To: Caleb Bynum <cbynum@hickorync.gov> Subject: NC0025542, Catawba WWTP, City of Hickory, Catawba County, MRO CAUTION: This email originated from outside of the organization Good afternoon, Caleb I recently started reviewing the October 30, 2019, NPDES permit application for renewal for the Catawba WWTP. Please provide additional or revised information to address the following comments: 1. Please complete this short form to meet the new application requirements for the updated application form 2A. 2. Please revise the outfall coordinate location (32°42155"N 81°04'25" W) and provide coordinates for the upstream and downstream location points (approximate coordinates from google maps would suffice). 3. If there are additional pollutants with certified methods to be reported, please submit this Chemical Addendum. If applicable, list the selected certified analytical method used. 4. I noted the cover letter included a request for this plant to be designated as an exceptionally performing facility and requested reduced monitoring. Please specify the parameters for which the City would like to request frequency monitoring reduction. 5. Please submit the last industrial waste survey (IWS) performed for the Catawba WWTP service area We'll appreciate it if you provide this information within the next three weeks; if you need more time, please let me know. Thanks for your continued cooperation with the NPDES program and your work protecting public health and the environment. Please let me know if you have any questions. Best, -Diana Diana Yitbarek Engineer T: +1-919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street, Rm. 925T, Raleigh, NC 27604-1170 cid:image004.png@O1D720C6.F3D624B0 *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Permit No. NC0025542 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.1366724ln hardness](0.041838)} - e^{0.9151 [ln hardness]-3.1485} Cadmium, Acute Trout waters WER*{1.1366724ln hardness](0.041838)} - e^{0.9151[ln hardness]-3.6236} Cadmium, Chronic WER*{1.1016724ln hardness](0.041838)} - e^{0.7998[ln hardness]-4.4451} Chromium III, Acute WER*0.316 - e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 • e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 • e^{0.9422[ln hardness]-1.700} Copper, Chronic WER*0.960 • e^{0.8545[ln hardness]-1.702} Lead, Acute WER*{1.462034ln hardness](0.145712)} • e^{1.273[ln hardness]-1.460} Lead, Chronic WER*{1.462034ln hardness](0.145712)} • e^{1.273[ln hardness]-4.705} Nickel, Acute WER*0.998 • e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 • e^{0.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NC0025542 Silver, Acute WER*0.85 • e^{1.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 • e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 • e^{0.8473[ln hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WQBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1Q10 using the formula 1Q10 = 0.843 (s7Q10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2of4 Permit No. NC0025542 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { [KPoI �SS(1+a)l r 1 0-6l } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Qw) (Cwqs) — (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) s7Q10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: 1Q10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0025542 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 47.49 Data provided in DMRs Average Upstream Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 30.68 Data provided in DMRs 7Q10 summer (cfs) 13 NPDESFiles 1Q10 (cfs) 10.76 Calculated in RPA Permitted Flow (MGD) 1.5 NPDES permit application Date: 3/10/2021 Permit Writer: Diana Yitbarek Page 4 of 4 BICKPY North Carolina Life. Well Crafted. Public Utilities February 16, 2016 NCDENR Division of Water Quality Water Quality Section Attn: NPDES unit 1617 Mail Service Center Raleigh, NC 27699-1617 City of Hickory Hickory Regional Laboratory 310 Cloninger Mill Rd. Hickory, NC 28601 Phone: (828) 322-4821 Fax: (828) 322-4961 Email: pprestwood@hickorync.gov RECEIVED/NCDEQ DWR FEB . 9 2016 Water Quality Section Dear Sir/Madam, Attached is a copy of the City of Hickory's Catawba POTW (NC0025542) PPA analyses. If additional information is needed, please advise. Sincerely, Paula Prestwood Senior Lab Technician City of Hickory Annual Monitoring and Pollutant Scan Facility Name City of Hickory - Catawba POTW Date of sampling 2/2/2016 Analytical Laboratory Pace Analytical Services, Inc. NPDES # ORC Phone Month Year February 2016 NC0025542 Watkins Bradberry (828) 228-3021 , Y,,:'-' :,,,. , •-•,;,11,, -.,,,,;. , ,, ' ,'.--7: „. --,i; Paraineiii,-- c ,,, -- _ - ;,,,:-*A.-,,i1-::;7•,'--:-,,;• -..-,: ,,zssanipie.-':• '-'_;7.i';PW:i.:V:' '- •-'•L-4,•::;'?'--Y-.'" • • Analytical :'';':-.Metiiiiif-::= r'' ', '''''''''''[ i;,:4,"`J':*; . iiiiiiii40611,: ':':' Le41';:;::2:: !;;;- N.,-'.,,; ,:-,.•2 ',•.-: -,-'' kS,g114P-' f: ;,_; ReSii1i:7,:' ;y Att.,_,:4::::, ;,•:: .4,i,: ':,., •'''Yni',9fre-;4' :,:ligaiiiienient si,:,::,-, Number of !-;-1,: iiiniPleS-- Ammonia (as N) Composite 350.1 0.10 ND mg/L 1 Dissolved oxygen Grab Nitrate/Nitrite Composite 353.2 0.20 15.1 mg/L 1 Total Kjeldahl nitrogen Composite 351.2 0.50 ND mg/L 1 Total Phosphorus Composite 365.1 0.050 1.6 mg/L 1 Total dissolved solids Composite 2540C 25.0 310 mg/L 1 Hardness Composite 2340B 662 43400 ug/L 1 Chlorine (total residual, TRC) Grab Oil and grease Grab 1664B 5.0 ND mg/L 1 ii*iilir(irei;_iiirii''4iiiii0$1:6), ICiiiiicfe',''iiii,`" iiitlii4eiiiiii:;;',,W,:,:.:2::„ ;:2',3,rt ::..:',.,:51:; ii':•.'-:,;:i'6,':'k:::: -;''''',•%i:::-.e.:-.-f.-InfiZ.Y.:-:i.A:' :..'.:-.:' -=':,:::. . :;:::" Antimony Composite 200.7 5.0 ND ug/L 1 Arsenic Composite 200.7 10.0 ND ug/L 1 Beryllium Composite 200.7 1.0 ND ug/L 1 Cadmium Composite 200.7 1.0 ND ug/L 1 Chromium Composite 200.7 5.0 ND ug/L 1 Copper Composite 200.7 5.0 5.2 ug/L 1 Lead Composite 200.8 0.10 ND ug/L 1 Mercury Composite 1631E 0.50 2.29 ng/L 1 Nickel Composite 200.7 5.0 ND ug/L 1 Selenium Composite 200.7 10.0 ND ug/L 1 Silver Composite 200.7 5.0 ND ug/L 1 Thallium Composite 200.7 10.0 ND ug/L 1 Zinc - Composite 200.7 10.0 55.8 ug/L 1 Cyanide Grab 4500CNE 0.0080 ND mg/L 1 Total phenolic compounds Grab 420.4 0.010 0.011 mg/L 1 V4iaOle-,i)igliiiiOinii;iiliiiiit;',;,SI'',1:16:4-c!,:F," ''',";V:',1:',V';'','-\i:VA::•:. ll',',:-..1':.-;':-=:;_7::',.i:E!;:::1:1 j,' ' - -4:-.e;t.,4., ' ''.',A-tifi')7,.'"2 '',i:t•'''-,‘" Acrolein Grab 624 5.0 ND ug/L 1 Acrylonitrile Grab 624 50.0 ND ug/L 1 Benzene Grab 624 2.0 ND ug/L 1 Bromoform Grab 624 2.0 ND ug/L 1 Carbon tetrachloride Grab 624 2.0 ND ug/L 1 Chlorobenzene Grab 624 2.0 ND ug/L 1 Chlorodibromomethane Grab 624 2.0 ND ug/L 1 Chloroethane Grab 624 2.0 ND ug/L 1 2-chloroethylvinylether Grab 624 5.0 ND ug/L 1 Chloroform Grab 624 2.0 28.6 ug/L 1 Dichlorobromomethane Grab 624 2.0 4.1 ug/L 1 1,1-dichloroethane Grab 624 2.0 ND ug/L 1 1,2-dichloroethane Grab 624 2.0 ND ug/L 1 Trans-1,2-dichloroethylene Grab 624 2.0 ND ug/L 1 Page 1 Annual Monitoring and Pollutant Scan Facility Name: City of Hickory - Catawba POTW NPDES #: NC0025542 Si-ra'Oietet, ' , ' j' : ,-- Ii:'11‘::9:',E': ,SAffif,i1--, ;1-iiiii)eZ' :Analytical.,: f_. lifilidi 4:21iii4ititi4priii-, ,I;T,,,,-;-:,,E1,:ii-,1: Sample--',:'f 4 iC..:Il'e'iii f'-' Units of , Miii4iieiiiiiitt: i:. Phip'!n! of.: :: .:,- samples - , • : 74,I-Y;;;;6'44 .4;',:-', .=.: ....:`,i;'; r :1- ''' ', ' ,-_,\IV::;1:'::.. ,,' ,,,,,,,; :A"? 's `•___ 1 >1-dichloroethylene Grab 624 2.0 ND ug/L 1 1,2-dichloropropane Grab 624 2.0 ND ug/L 1 1,3-dichloropropylene Grab 624 2.0 ND ug/L 1 Ethylbenzene Grab 624 2.0 ND ug/L 1 Methyl bromide Grab 624 2.0 4.4 ug/L 1 Methyl chloride Grab 624 2.0 ND ug/L 1 Methylene chloride Grab 624 2.0 ND ug/L 1 1,1,2,2-tetrachloroethane Grab 624 2.0 ND ug/L 1 Tetrachloroethylene Grab 624 2.0 ND ug/L 1 Toluene Grab 624 2.0 ND ug/L 1 1,1,1-trichloroethane Grab 624 2.0 ND ug/L 1 1,1,2-trichloroethane Grab 624 2.0 ND ug/L 1 Trichloroethylene Grab 624 2.0 ND ug/L 1 Vinyl chloride Grab 624 2.0 ND ug/L 1 Aiialiitieiiii;i::(3iig*ii *-' ,,,,:,;:'',,.,4:--_-,',:',141,:TA ,--::•il- :,' ,A- -.'-':F.;5, P-chloro-m-creso Grab 625 10.0 ND ug/L 1 2-chlorophenol Grab 625 5.0 ND ug/L 1 2,4-dichlorophenol Grab 625 5.0 ND ug/L 1 2,4-dimethylphenol Grab 625 10.0 ND ug/L 1 4,6-dinitro-o-cresol Grab 625 20.0 ND ug/L 1 2,4-dinitrophenol Grab 625 50.0 ND ug/L 1 2-nitrophenol Grab 625 5.0 ND ug/L 1 4-nitrophenol Grab 625 50.0 ND ug/L 1 Pentachlorophenol Grab 625 10.0 ND ug/L 1 Phenol Grab 625 5.0 ND ug/L 1 2,4,6-trichlorophenol Grab 625 10.0 ND ug/L 1 ii-i--i,,,eiiiiii,!--•-'inciia.:Nt;:'i,:;; (q,',z',.-,i4, -.i:'-<-'-;"';';;;k‘-:';111':=1;`•-'!0-.1-!::-.:‘,i-:.•:!q2';,--,;,<,=4.,':'•-4.:=*'''jYK'-'.,;_:4'l's':':'‘,',','::.-4••-•27:',:i:'E rK"-,`' '' Acenaphthene Grab 625 5.0 ND ug/L 1 Acenaphthylene Grab 625 5.0 ND ug/L 1 Anthracene Grab 625 5.0 ND ug/L 1 Benzidine Grab 625 50.0 ND ug/L 1 Benzo(a)anthracene Grab 625 5.0 ND ug/L 1 Benzo(a)pyrene Grab 625 5.0 ND ug/L 1 3,4 benzofluoranthene Grab 625 5.0 ND ug/L 1 Benzo(ghi)perylene Grab 625 5.0 ND ug/L 1 Benzo(k)fluoranthene Grab 625 5.0 ND ug/L 1 Bis (2-chloroethoxy)methane Grab 625 10.0 ND ug/L 1 Bis (2-chloroethyl)ether Grab 625 5.0 ND ug/L 1 Bis (2-chloroisopropyl)ether Grab 625 5.0 ND ug/L 1 Bis (2-ethylhexyl)phthalate Grab 625 5.0 ND ug/L 1 4-bromophenylphenylether Grab 625 5.0 ND ug/L 1 Butylbenzylphthalate Grab 625 5.0 ND ug/L 1 2-chloronaphthalene Grab 625 5.0 ND ug/L 1 4-chlorophenylphenylether Grab 625 5.0 ND ug/L 1 Page 2 Annual Monitoring and Pollutant Scan Facility Name: City of Hickory - Catawba POTW - NPDES #: NC0025542 - _ 1. •'S Pr yl., - t a ain ei� et Ii m� l'` a e�. r., S '+r �o e.F: ":JIB �i` nY�l�'h A a t cal'> Me�h'� �iaifitatioii� ?LeveL,.;•<�.' �Saiii"� le..'=, Result�a.'=� .i ``-Ua is of a . �Measuremeat�` Number�o f. `s am 11es;: s ase=iieiiti0:: com0iinds`1(4 ii - - Chrysene Grab 625 5.0 ND ug/L 1 Di-n-butyl phthalate Grab 625 5.0 ND ug/L 1 Di-n-octyl phthalate Grab 625 5.0 ND ug/L 1 Dibenzo(a,h)anthracene Grab 625 5.0 ND ug/L 1 1,2-dichlorobenzene Grab 625 5.0 ND ug/L 1 1,3-dichlorobenzene Grab 625 5.0 ND ug/L 1 1,4-dichlorobenzene Grab 625 5.0 ND ug/L 1 3,3-dichlorobenzidine Grab 625 25.0 ND ug/L 1 Diethyl phthalate Grab 625 5.0 ND ug/L 1 Dimethyl phthalate Grab 625 5.0 ND ug/L 1 2,4-dinitrotoluene Grab 625 5.0 ND ug/L 1 2,6-dinitrotoluene Grab 625 5.0 ND ug/L 1 1,2-diphenylhydrazine Grab 625 5.0 ND ug/L 1 Fluoranthene Grab 625 5.0 ND ug/L 1 Fluorene Grab 625 5.0 ND ug/L 1 Hexachlorobenzene Grab 625 5.0 ND ug/L 1 Hexachlorobutadiene Grab 625 5.0 ND ug/L 1 Hexachlorocyclo-pentadiene Grab 625 10.0 ND ug/L 1 Hexachloroethane Grab 625 5.0 ND ug/L 1 Indeno(1,2,3-cd)pyrene Grab 625 5.0 ND ug/L 1 Isophorone Grab 625 10.0 ND ug/L 1 Naphthalene Grab 625 5.0 ND ug/L 1 Nitrobenzene Grab 625 5.0 ND ug/L 1 N-nitrosodi-n-propylamine Grab 625 5.0 ND ug/L 1 N-nitrosodimethylamine Grab 625 5.0 ND ug/L 1 N-nitrosodiphenylamine Grab 625 10.0 ND ug/L 1 Phenanthrene Grab 625 5.0 ND ug/L 1 Pyrene Grab 625 5.0 ND ug/L 1 1,2,4,-trichlorobenzene Grab 625 5.0 ND ug/L 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsible for gathering the information, the information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. l.174 l7s/,`i? 5 arfrciberry Authorized Representative name rcf Signature Date " � — 6/6- Page 3 HICKQRY North Carolina Life Well Crafted Public Utilities August 28, 2017 NCDEQ Division of Water Resources Water Quality Section Attn: NPDES unit 1617 Mail Service Center Raleigh, NC 27699-1617 City of Hickory Hickory Regional Laboratory 310 Cloninger Mill Rd Hickory, NC 28601 Phone (828) 322-4821 Fax (828) 322-4961 Email pprestwood@hickorync gov RECEIVED/NCDEQ/DWR SEP 01 2017 Water Quality Permitting Section Dear Sir/Madam, Attached is a copy of the City of Hickory's Catawba POTW (NC0025542) PPA analyses. If additional information is needed, please advise. Sincerely, Paula Prestwood Senior Lab Technician City of Hickory Annual Monitoring and Pollutant Scan Facility Name Date of sampling Analytical Laboratory City of Hickory - Catawba POTW 8/8/2017 Pace Analytical Services, LLC NPDES # ORC Phone Month Year August 2017 NC0025542 Watkins Bradberry (828) 323-7500 Parameter Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Number of samples Ammonia (as N) Composite 350 1 0 10 ND mg/L 1 Dissolved oxygen Grab 1 Nitrate/Nitrite Composite 353 2 0 020 1 9 mg/L 1 Total Kjeldahl nitrogen Composite 351 2 0 50 0 64 mg/L 1 Total Phosphorus Composite 365 1 0 25 5 2 mg/L 1 Total dissolved sohds Composite 2540C 25 0 318 mg/L 1 Hardness Composite 2340B 662 52700 ug/L 1 Chlorine (total residual, TRC) Grab 1 Oil and grease Grab 1664B 5 0 ND mg/L 1 Metals (total recoverable), cyanide and total phenols Antimony Composite 200 7 5 0 ND ug/L 1 Arsenic Composite 200 7 10 0 ND ug/L 1 Beryllium Composite 200 7 1 0 ND ug/L 1 Cadmium Composite 200 7 1 0 ND ug/L 1 Chromium Composite 200 7 5 0 ND ug/L 1 Copper Composite 200 7 5 0 ND ug/L 1 Lead Composite 200 8 0 10 0 15 ug/L 1 Mercury Grab 1631E 0 50 3 37 ng/L 1 Nickel Composite 200 7 5 0 ND ug/L 1 Selenium Composite 200 7 10 0 ND ug/L 1 Silver Composite 200 7 5 0 ND ug/L 1 Thalhum Composite 200 7 10.0 ND ug/L 1 Zinc Composite 200 7 10 0 34 1 ug/L 1 Cyanide Grab 4500CNE 0 0080 ND mg/L 1 Total phenolic compounds Grab 420 4 0 010 ND mg/L 1 Volatile organic compounds Acrolem Grab 624 5 0 ND ug/L 1 Acrylonitrile Grab 624 50 0 ND ug/L 1 Benzene Grab 624 2 0 ND ug/L 1 Bromoform Grab 624 2 0 ND ug/L 1 Carbon tetrachloride Grab 624 2.0 ND ug/L 1 Chlorobenzene Grab 624 2 0 ND ug/L 1 Chlorodibromomethane Grab 624 2 0 ND ug/L 1 Chloroethane Grab 624 2 0 ND ug/L 1 2-chloroethylvinylether Grab 624 5 0 ND ug/L 1 Chloroform Grab 624 2 0 78 5 ug/L 1 Dichlorobromomethane Grab 624 2 0 11 7 ug/L 1 1,1-dichloroethane Grab 624 2 0 ND ug/L 1 1,2-dichloroethane Grab 624 2 0 ND ug/L 1 Trans-1,2-dichloroethylene Grab 624 2 0 ND ug/L 1 Page 1 Annual Monitoring and Pollutant Scan Facility Name: City of Hickory - Catawba POTW NPDES #: NC0025542 Parameter Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Number of samples Volatile organic compounds (Cont.) 1,1-dichloroethylene Grab 624 2 0 ND ug/L 1 1,2-dichloropropane Grab 624 2 0 ND ug/L 1 1,3-dichloropropylene Grab 624 2 0 ND ug/L 1 Ethylbenzene Grab 624 2 0 ND ug/L 1 Methyl bromide Grab 624 2.0 ND ug/L 1 Methyl chloride Grab 624 2 0 ND ug/L 1 Methylene chloride Grab 624 2 0 ND ug/L 1 1,1,2,2-tetrachloroethane Grab 624 2.0 ND ug/L 1 Tetrachloroethylene Grab 624 2 0 ND ug/L 1 Toluene Grab 624 2 0 ND ug/L 1 1,1,1-trichloroethane Grab 624 2 0 ND ug/L 1 1,1,2-trichloroethane Grab 624 2 0 ND ug/L 1 Trichloroethylene Grab 624 2 0 ND ug/L 1 Vinyl chlonde Grab 624 2 0 ND ug/L 1 Acid -extractable compounds P-chloro-m-creso Grab 625 10 0 ND ug/L 1 2-chlorophenol Grab 625 5 0 ND ug/L 1 2,4-dichlorophenol Grab 625 5 0 ND ug/L 1 2,4-dirnethylphenol Grab 625 10 0 ND ug/L 1 4,6-dmitro-o-cresol Grab 625 20.0 ND ug/L 1 2,4-dinitrophenol Grab 625 50 0 ND ug/L 1 2-nitrophenol Grab 625 5 0 ND ug/L 1 4-rutrophenol Grab 625 50 0 ND ug/L 1 Pentachlorophenol Grab 625 10 0 ND ug/L 1 Phenol Grab 625 5 0 ND ug/L 1 2,4,6-trichlorophenol Grab 625 10 0 ND ug/L 1 Base -neutral compounds Acenaphthene Grab 625 5.0 ND ug/L 1 Acenaphthylene Grab 625 5 0 ND ug/L 1 Anthracene Grab 625 5 0 ND ug/L 1 Benzidme Grab 625 50 0 ND ug/L 1 Benzo(a)anthracene Grab 625 5 0 ND ug/L 1 Benzo(a)pyrene Grab 625 5.0 ND ug/L 1 3,4 benzofluoranthene Grab 625 5 0 ND ug/L 1 Benzo(ghi)perylene Grab 625 5.0 ND ug/L 1 Benzo(k)fluoranthene Grab 625 5 0 ND ug/L 1 Bis (2-chloroethoxy)methane Grab 625 10.0 ND ug/L 1 Bis (2-chloroethyl)ether Grab 625 5 0 ND ug/L 1 Bis (2-chloroisopropyl)ether Grab 625 5 0 ND ug/L 1 Bis (2-ethylhexyl)phthalate Grab 625 5 0 ND ug/L 1 4-bromophenylphenylether Grab 625 5 0 ND ug/L 1 Butylbenzylphthalate Grab 625 5 0 ND ug/L 1 2-chloronaphthalene Grab 625 5 0 ND ug/L 1 4-chlorophenylphenylether Grab 625 5 0 ND ug/L 1 Page 2 Annual Monitoring and Pollutant Scan Facility Name: City of Hickory - Catawba POTW NPDES #: NC0025542 Parameter Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Number of samples Base -neutral compounds (cont.) Chrysene Grab 625 5 ND ug/L 1 Di-n-butyl phthalate Grab 625 5 ND ug/L 1 Di-n-octyl phthalate Grab 625 5 ND ug/L 1 Dibenzo(a,h)anthracene Grab 625 5 ND ug/L 1 1,2-dichlorobenzene Grab 625 5 ND ug/L 1 1,3-dichlorobenzene Grab 625 5 ND ug/L 1 1,4-dichlorobenzene Grab 625 5 ND ug/L 1 3,3-dichlorobenzidine Grab 625 25 ND ug/L 1 Diethyl phthalate Grab 625 5 ND ug/L 1 Dimethyl phthalate Grab 625 5 ND ug/L 1 2,4-dinitrotoluene Grab 625 5 ND ug/L 1 2,6-dinitrotoluene Grab 625 5 ND ug/L 1 1,2-diphenylhydrazine Grab 625 5 ND ug/L 1 Fluoranthene Grab 625 5 ND ug/L 1 Fluorene Grab 625 5 ND ug/L 1 Hexachlorobenzene Grab 625 5 ND ug/L 1 Hexachlorobutadiene Grab 625 5 ND ug/L 1 Hexachlorocyclo-pentadiene Grab 625 10 ND ug/L 1 Hexachloroethane Grab 625 5 ND ug/L 1 Indeno(1,2,3-cd)pyrene Grab 625 5 ND ug/L 1 Isophorone Grab 625 10 ND ug/L 1 Naphthalene Grab 625 5 ND ug/L 1 Nitrobenzene Grab 625 5 ND ug/L 1 N-nitrosodi-n-propylamme Grab 625 5 ND ug/L 1 N-nitrosodimethylamine Grab 625 5 ND ug/L 1 N-mtrosodiphenylamme Grab 625 10 ND ug/L 1 Phenanthrene Grab 625 5 ND ug/L 1 Pyrene Grab 625 5 ND ug/L 1 1,2,4,-trichlorobenzene Grab 625 5 ND ug/L 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsible for gathering the information, the information submitted is , to the best of my knowledge and belief, true, accurate and complete I am aware that there are significant penalties for submitting false information, including the possibility of fines and impnsonment for knowing violations. W6C oA5 @cibCt7Cr Authorized Representative n p e Signature Date ,S'- 2 ? " 1-7 Page 3 faesNsoiNcol✓ngovm. QILL 1 2 aS WGRO 10KNLOFFVG ooRLsV11.1- �1-0 Facility Name Date of sampling Analytical Laboratory City of Hickory - Catawba POTW 11/6/2018 Pace Analytical Annual Monitoring and Pollutant Scan NPDES # ORC Phone Month Year November 2018 NC0025542 Josh Archambault (828)323-7500 Parameter Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Number of samples Ammonia (as N) Composite 350.1 0.10 1,0 mg/L 1 Dissolved oxygen Grab 45000G 0.10 8.1 mg/L 1 Nitrate/Nitrite Composite 353.2 0.020 3.0 mg/L 1 Total Kjeldahl nitrogen Composite 351.2 0.50 1.7 mg/L 1 Total Phosphorus Composite 365.1 0.050 1.2 mg/L 1 Total dissolved solids Composite 2540C 25.0 219 mg/L 1 Hardness Composite 2340E 662.0 40700 ug/L 1 Chlorine (total residual, TRC) Grab 4500CLG 20.0 ND ug/L 1 Oil and grease Grab 1664E 5.0 ND mg/L 1 Metals (total recoverable), cyanide and total phenols Antimony Composite 200.7 5.0 ND ug/L 1 Arsenic Composite 200.7 10.0 ND ug/L 1 Beryllium Composite 200.7 1.0 ND ug/L 1 Cadmium Composite 200.8 0.080 ND ug/L 1 Chromium Composite 200.7 5.0 ND ug/L 1 Copper Composite 200.8 1,0 3.9 ug/L 1 Lead Composite 200.7 5.0 ND ug/L 1 Mercury Grab 1631E 0.50 3.18 ng/L 1 Nickel Composite 200.7 5.0 ND ug/L 1 Selenium Composite 200.8 0.50 ND ug/L 1 Silver Composite 200.8 0.50 ND ug/L 1 Thallium Composite 200.7 5.0 ND ug/L 1 Zinc Composite 200.7 10.0 49.1 ug/L 1 Cyanide Grab 4500CNE 0.0080 ND mg/L 1 Total phenolic compounds Grab 420.4 0.010 ND mg/L 1 Volatile organic compounds Acrolein Grab 624 5.0 ND ug/L 1 Acrylonitrile Grab 624 50.0 ND ug/L 1 Benzene Grab 624 2.0 ND ug/L 1 Bromoform Grab 624 2.0 ND ug/L 1 Carbon tetrachloride Grab 624 2.0 ND ug/L 1 Chlorobenzene Grab 624 2.0 ND ug/L 1 Chlorodibromomethane Grab 624 2.0 ND ug/L 1 Chloroethane Grab 624 2.0 ND ug/L 1 2-chloroethylvinylether Grab 624 5.0 ND ug/L 1 Chloroform Grab 624 2.0 ND ug/L 1 Dichlorobromomethane Grab 624 2.0 ND ug/L 1 1,1-dichloroethane Grab 624 2.0 ND ug/L 1 1,2-dichloroethane Grab 624 2.0 ND ug/L 1 Trans-1,2-dichloroethylene Grab 624 2.0 ND ug/L 1 Page 1 Annual Monitoring and Pollutant Scan Facility Name: City of Hickory - Catawba POTW NPDES #: NC0025542 Parameter Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Number of samples Volatile organic compounds (Cont.) 1,1-dichloroethylene Grab 624 2.0 ND ug/L 1 1,2-dichloropropane Grab 624 2.0 ND ug/L 1 1,3-dichloropropylene Grab 624 2.0 ND ug/L 1 Ethylbenzene Grab 624 2.0 ND ug/L 1 Methyl bromide Grab 624 2.0 11.7 ug/L 1 Methyl chloride Grab 624 2.0 ND ug/L 1 Methylene chloride Grab 624 2.0 ND ug/L 1 1,1,2,2-tetrachloroethane Grab 624 2.0 ND ug/L 1 Tetrachloroethylene Grab 624 2.0 ND ug/L 1 Toluene Grab 624 2.0 ND ug/L 1 1,1,1-trichloroethane Grab 624 2.0 ND ug/L 1 1,1,2-trichloroethane Grab 624 2.0 ND ug/L 1 Trichloroethylene Grab 624 2.0 ND ug/L 1 Vinyl chloride Grab 624 2.0 ND ug/L 1 Acid -extractable compounds P-chloro-m-creso Grab 625 9.4 ND ug/L 1 2-chlorophenol Grab 625 4.7 ND ug/L 1 2,4-dichlorophenol Grab 625 4.7 ND ug/L 1 2,4-dimethylphenol Grab 625 9.4 ND ug/L 1 4,6-dinitro-o-cresol Grab 625 18.9 ND ug/L 1 2,4-dinitrophenol Grab 625 47.2 ND ug/L 1 2-nitrophenol Grab 625 4.7 ND ug/L 1 4-nitrophenol Grab 625 47.2 ND ug/L 1 Pentachlorophenol Grab 625 9.4 ND ug/L 1 Phenol Grab 625 4.7 ND ug/L 1 2,4,6-trichlorophenol Grab 625 9.4 ND ug/L 1 Ease -neutral compounds Acenaphthene Grab 625 4.7 ND ug/L 1 Acenaphthylene Grab 625 4.7 ND ug/L 1 Anthracene Grab 625 4.7 ND ug/L 1 Benzidine Grab 625 47.2 ND ug/L 1 Benzo(a)anthracene Grab 625 4.7 ND ug/L 1 Benzo(a)pyrene Grab 625 4.7 ND ug/L 1 3,4 benzofluoranthene Grab 625 4.7 ND ug/L 1 Benzo(ghi)perylene Grab 625 4.7 ND ug/L 1 Benzo(k)fluoranthene Grab 625 4.7 ND ug/L 1 Bis (2-chloroethoxy)methane Grab 625 9.4 ND ug/L 1 Bis (2-chloroethyl)ether Grab 625 4.7 ND ug/L 1 Bis (2-chloroisopropyl)ether Grab 625 4.7 ND ug/L 1 Bis (2-ethylhexyl)phthalate Grab 625 4.7 ND ug/L 1 4-bromophenylphenylether Grab 625 4.7 ND ug/L 1 Butylbenzylphthalate Grab 625 4.7 ND ug/L 1 2-chloronaphthalene Grab 625 4.7 ND ug/L 1 4-chlorophenylphenylether Grab 625 4.7 ND ug/L 1 Page 2 Annual Monitoring and Pollutant Scan Facility Name: City of Hickory - Catawba POTW NPDES #: NC0025542 Parameter Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Number of samples Base -neutral compounds (cont.) Chrysene Grab 625 4.7 ND ug/L 1 Di-n-butyl phthalate Grab 625 4.7 ND ug/L 1 Di-n-octyl phthalate Grab 625 4.7 ND ug/L 1 Dibenzo(a,h)anthracene Grab 625 4.7 ND ug/L 1 1,2-dichlorobenzene Grab 625 4.7 ND ug/L 1 1,3-dichlorobenzene Grab 625 4.7 ND ug/L 1 1,4-dichlorobenzene Grab 625 4.7 ND ug/L 1 3,3-dichlorobenzidine Grab 625 23.6 ND ug/L 1 Diethyl phthalate Grab 625 4.7 ND ug/L 1 Dimethyl phthalate Grab 625 4.7 ND ug/L 1 2,4-dinitrotoluene Grab 625 4.7 ND ug/L 1 2,6-dinitrotoluene Grab 625 4.7 7.3 ug/L 1 1,2-diphenylhydrazine Grab 625 4.7 ND ug/L 1 Fluoranthene Grab 625 4.7 ND ug/L 1 Fluorene Grab 625 4.7 ND ug/L 1 Hexachlorobenzene Grab 625 4.7 ND ug/L 1 Hexachlorobutadiene Grab 625 4.7 ND ug/L 1 Hexachlorocyclo-pentadiene Grab 625 9.4 ND ug/L 1 Hexachloroethane Grab 625 4.7 ND ug/L 1 Indeno(1,2,3-cd}pyrene Grab 625 4.7 ND ug/L 1 Isophorone Grab 625 9.4 ND ug/L 1 Naphthalene Grab 625 4.7 ND ug/L 1 Nitrobenzene Grab 625 4.7 ND ug/L 1 N-nitrosodi-n-propylamine Grab 625 4.7 ND ug/L 1 N-nitrosodimethylamine Grab 625 4.7 ND ug/L 1 N-nitrosodiphenylamine Grab 625 9.4 ND ug/L 1 Phenanthrene Grab 625 4.7 ND ug/L 1 Pyrene Grab 625 4.7 ND ug/L 1 1,2,4,-trichlorobenzene Grab 625 4.7 ND ug/L 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsible for gathering the information, the information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. s. 0 /rc1,c, - h 14 Authorized Representative name ignature Date ia - 6 - Page 3 ED(NCO NRIDW51 JUN I 0 ?ON Annual Monitoring and Pollutant Scan WOROS MOORESVILLE REGIONAL OFFICE Facility Name Date of sampling Analytical Laboratory City of Hickory - Catawba POTW 5/9/2019 Pace Analytical Services, LLC NPDES # ORC Phone Month Year May 2019 NC0025542 Josh Archambault (828) 323-7500 Parameter Parameter Code Sample ' Type Analytical Method Quantitation Level Sample Result Units of Measurement Ammonia (as N) C0610 Composite 350.1 0.10 ND mg/L Dissolved oxygen 00300 Grab 45000G 0.10 7.76 mg/L Nitrate/Nitrite 00630 Composite 353.2 0.040 0.64 mg/L Total Kjeldahl nitrogen 00625 Composite 351.2 0.50 0.75 mg/L Total Phosphorus C0665 Composite 365.1 0.050 1.8 mg/L Total dissolved solids 70295 Composite 2540C 25.0 308 mg/L Hardness 00900 Composite 2340B 662 44800 ug/L Chlorine (total residual, TRC) 50060 Grab 4500CLG 20.0 ND ug/L Oil and grease 00556 Grab 1664B 5.0 ND mg/L Metals (total recoverable), cyanide and total phenols Antimony 01097 Composite 200.7 5.0 ND ug/L Arsenic 01002 Composite 200.7 10.0 ND ug/L Beryllium 01012 Composite 200.7 1.0 ND ug/L Cadmium 01027 Composite 200.8 0.080 ND ug/L Chromium 01034 Composite 200.7 5.0 ND ug/L Copper 01042 Composite 200.8 1.0 1.2 ug/L Lead 01051 Composite 200.7 5.0 ND ug/L Mercury COMER Grab 1631E 0.50 0.883 ng/L Nickel 01067 Composite 200.7 5.0 ND ug/L Selenium 01147 Composite 200.8 0.50 ND ug/L Silver 01077 Composite 200.8 0.50 ND ug/L Thallium 01059 Composite 200.7 10.0 ND ug/L Zinc 01092 Composite 200.7 10.0 37.4 ug/L Cyanide 00720 Grab 4500CNE 0.0080 ND mg/L Total phenolic compounds 32730 Grab 420.4 0.020 0.022 mg/L Volatile organic compounds Acrolein 34210 Grab 624 5.0 ND ug/L Acrylonitrile 34215 Grab 624 50.0 ND ug/L Benzene 34030 Grab 624 1.0 ND ug/L Bromoform 32104 Grab 624 2.0 ND ug/L Carbon tetrachloride 32102 Grab 624 2.0 ND ug/L Chlorobenzene 34301 Grab 624 2.0 ND ug/L Chlorodibromomethane 34306 Grab 624 2.0 2.2 ug/L Chloroethane 85811 Grab 624 2.0 ND ug/L 2-chloroethylvinylether 34576 Grab 624 10.0 ND ug/L Chloroform 32106 Grab 624 5.0 73.0 ug/L Dichlorobromomethane 32101 Grab 624 2.0 17.8 ug/L 1,1-dichloroethane 34496 Grab 624 2.0 ND ug/L 1,2-dichloroethane 32103 Grab 624 2.0 ND ug/L Trans-1,2-dichloroethylene 34546 Grab 624 2.0 ND ug/L Page 1 Annual Monitoring and Pollutant Scan Facility Name: City of hickory - Catawba POTW NPDES #: NC0025542 Parameter Parameter Code Sample .` Type Analytical Method Quantitation Level Sample Result Units of Measurement Volatile organic compounds (Cont.) 1,1-dichloroethylene 34501 Grab 624 2.0 ND ug/L 1,2-dichloropropane C0541 Grab 624 2.0 ND ug/L 1,3-dichloropropylene 51044 Grab 624 2.0 ND ug/L Ethylbenzene 37371 Grab 624 1.0 ND ug/L Methyl bromide 34413 Grab 624 2.0 ND ug/L Methyl chloride 34418 Grab 624 2.0 ND ug/L Methylene chloride 34423 Grab 624 5.0 ND ug/L 1,1,2,2-tetrachloroethane 34516 Grab 624 2.0 ND ug/L Tetrachloroethylene 34475 Grab 624 2.0 ND ug/L Toluene 34010 Grab 624 1.0 ND ug/L 1,1,1-trichloroethane 34506 Grab 624 2.0 ND ug/L 1,1,2-trichloroethane 34511 Grab 624 2.0 ND ug/L Trichloroethylene 39180 Grab 624 2.0 ND ug/L Vinyl chloride 39175 Grab 624 2.0 ND ug/L Acid -extractable compounds P-chloro-m-creso 34452 Grab 625 10.0 ND ug/L 2-chlorophenol 34586 Grab 625 5.0 ND ug/L 2,4-dichlorophenol 34601 Grab 625 5.0 ND ug/L 2,4-dimethylphenol 34606 Grab 625 10.0 ND ug/L 4,6-dinitro-o-cresol 34657 Grab 625 20.0 ND ug/L 2,4-dinitrophenol 34616 Grab 625 50.0 ND ug/L 2-nitrophenol 34591 Grab 625 5.0 ND ug/L 4-nitrophenol 34646 Grab 625 50.0 ND ug/L Pentachlorophenol 39032 Grab 625 10.0 ND ug/L Phenol 34694 Grab 625 5.0 ND ug/L 2,4,6-trichlorophenol 34621 Grab 625 10.0 ND ug/L _ Base -neutral compounds Acenaphthene 34205 Grab 625 5.0 ND ug/L Acenaphthylene 34200 Grab 625 5.0 ND ug/L Anthracene CO220 Grab 625 5.0 ND ug/L Benzidine 39120 Grab 625 50.0 ND ug/L Benzo(a)anthracene C0526 Grab 625 5.0 ND ug/L Benzo(a)pyrene 34247 Grab 625 5.0 ND ug/L 3,4 benzofluoranthene C0531 Grab 625 5.0 ND ug/L Benzo(ghi)perylene 34521 Grab 625 5.0 ND ug/L Benzo(k)fluoranthene 34242 Grab 625 5.0 ND ug/L Bis (2-chloroethoxy)methane 34278 Grab 625 10.0 ND ug/L Bis (2-chloroethyl)ether 34273 Grab 625 5.0 ND ug/L Bis (2-chloroisopropyl)ether 34283 Grab 625 5.0 ND ug/L Bis (2-ethylhexyl)phthalate CO100 Grab 625 5.0 ND ug/L 4-bromophenylphenylether 34636 Grab 625 5.0 ND ug/L Butylbenzylphthalate CO292 Grab 625 5.0 ND ug/L 2-chloronaphthalene 34581 Grab 625 5.0 ND ug/L 4-chlorophenylphenylether 34641 Grab 625 5.0 ND ug/L Page 2 Annual Monitoring and Pollutant Scan Facility Name: City of hickory - Catawba POTW NPDES #: NC0025542 Parameter Parameter Code Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Base -neutral compounds (cont.) Chrysene 34320 Grab 625 5.0 ND ug/L Di-n-butyl phthalate 39110 Grab 625 5.0 ND ug/L Di-n-octyl phthalate 34596 Grab 625 5.0 ND ug/L Dibenzo(a,h)anthracene 34556 Grab 625 5.0 ND ug/L 1,2-dichlorobenzene 34536 Grab 625 5.0 ND ug/L 1,3-dichlorobenzene 34566 Grab 625 5.0 ND ug/L 1,4-dichlorobenzene 34571 Grab 625 5.0 ND ug/L 3,3-dichlorobenzidine 34631 Grab 625 25.0 ND ug/L Diethyl phthalate 34336 Grab 625 5.0 ND ug/L Dimethyl phthalate 34341 Grab 625 5.0 ND ug/L 2,4-dinitrotoluene 34611 Grab 625 5.0 ND ug/L 2,6-dinitrotoluene CO626 Grab 625 5.0 ND ug/L 1,2-diphenylhydrazine 34346 Grab 625 5.0 ND ug/L Fluoranthene CO376 Grab 625 5.0 ND ug/L Fluorene 34381 Grab 625 5.0 ND ug/L Hexachlorobenzene CO700 Grab 625 5.0 ND ug/L Hexachlorobutadiene CO702 Grab 625 5.0 ND ug/L Hexachlorocyclo-pentadiene 34386 Grab 625 10.0 ND ug/L Hexachloroethane CO396 Grab 625 5.0 ND ug/L Indeno(1,2,3-cd)pyrene 34403 Grab 625 5.0 ND ug/L Isophorone 34408 Grab 625 10.0 ND ug/L Naphthalene 34696 Grab 625 5.0 ND ug/L Nitrobenzene 34447 Grab 625 5.0 ND ug/L N-nitrosodi-n-propylamine 34428 Grab 625 5.0 ND ug/L N-nitrosodimethylamine 34438 Grab 625 5.0 ND ug/L N-nitrosodiphenylamine 34433 Grab 625 10.0 ND ug/L Phenanthrene 34461 Grab 625 5.0 ND ug/L Pyrene 34469 Grab 625 5.0 ND ug/L 1,2,4,-trichlorobenzene CO551 Grab 625 5.0 ND ug/L "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate and complete. I am aware that thereare significant penalties for submitting false information, including the posibility of fines and imprisonment for knowing violations." Josh,, b,• c( flr c f b Ck i 4- Authorized Representative name Date t--5- -i Page 3 North Carolina Life. - Veil „rafted. Public Utilities February 27, 2020 Division of Water Resources 610 E. Center Ave. Suite 301 Mooresville, NC 28115 City of Hickory Hickory Regional Laboratory 310 Cloninger Mill Rd. Hickory, NC 28601 Phone: (828) 322-4821 Fax: (828) 322-4961 Email: pprestwood@hickorync.gov RECEIVEDINCDENR/DWR MAR - WOROS MOORIERAIILLE REGIONAL OFFION Dear Sir/Madam, Attached is a copy of the City of Hickory's Catawba POTW (NC0025542) PPA analyses. If additional information is needed, please advise. Sincerely, Paula Prestwood Senior Lab Technician City of Hickory Annual Monitoring and Pollutant Scan Facility Name Date of sampling Analytical Laboratory City of Hickory - Catawba POTW 2/4/2020 Pace Analytical NPDES # ORC Phone Month February ear NC0025542 Josh Archambault (828) 323-7500 Parameter Parameter Code Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Ammonia (as N) CO610 Composite 350.1 0.10 5.1 mg/L Dissolved oxygen 00300 Grab 4500OG 0.10 10.0 mg/L Nitrate/Nitrite 00630 Composite 353.2 0.040 2.6 mg/L Total Kjeldahl nitrogen 00625 Composite 351.2 0.50 6.1 mg/L Total Phosphorus CO665 Composite 365.1 0.050 0.21 mg/L Total dissolved solids 70295 Composite 2540C 25.0 327 mg/L Hardness 00900 Composite 2340B 662 39400 ug/L Chlorine (total residual, TRC) 50060 Grab 4500CLG 20.0 ND ug/L Oil and grease 00556 Grab 1664B 5.0 ND mg/L Metals (total recoverable), cyanide and total phenols Antimony 01097 Composite 200.7 5.0 ND ug/L Arsenic 01002 Composite 200.7 10.0 ND ug/L Beryllium 01012 Composite 200.7 1.0 ND ug/L Cadmium 01027 Composite 200.8 0.080 ND ug/L Chromium 01034 Composite 200.7 5.0 ND ug/L Copper 01042 Composite 200.8 1.0 4.8 ug/L Lead 01051 Composite 200.7 5.0 ND ug/L Mercury COMER Grab 1631E 0.50 1.77 ng/L Nickel 01067 Composite 200.7 5.0 ND ug/L Selenium 01147 Composite 200.8 0.50 ND ug/L Silver 01077 Composite 200.8 0.50 ND ug/L Thallium 01059 Composite 200.7 10.0 ND ug/L Zinc 01092 Composite 200.7 10.0 430 ug/L Cyanide 00720 Grab 4500CNE 0.0080 ND mg/L Total phenolic compounds 32730 Grab 420.4 0.020 ND mg/L Volatile organic compounds Acrolein 34210 Grab 624 5.0 ND ug/L Acrylonitrile 34215 Grab 624 5.0 ND ug/L Benzene 34030 Grab 624 1.0 ND ug/L Bromoform 32104 Grab 624 2.0 ND ug/L Carbon tetrachloride 32102 Grab 624 2.0 ND ug/L Chlorobenzene 34301 Grab 624 2.0 ND ug/L Chlorodibromomethane 34306 Grab 624 2.0 ND ug/L Chloroethane 85811 Grab 624 2.0 ND ug/L 2-chloroethylvinylether 34576 Grab 624 5.0 ND ug/L Chloroform 32106 Grab 624 2.0 7.7 ug/L Dichlorobromomethane 32101 Grab 624 2.0 ND ug/L 1,1-dichloroethane 34496 Grab 624 2.0 ND ug/L 1,2-dichloroethane 32103 Grab 624 2.0 ND ug/L Trans-1,2-dichloroethylene 34546 Grab 624 2.0 ND ug/L Page 1 Annual Monitoring and Pollutant Scan Facility Name: City of Hickory - Catawba POTW NPDES #: NC0025542 Parameter Parameter Code Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Volatile organic compounds (Cont.) 1,1-dichloroethylene 34501 Grab 624 2.0 ND ug/L 1,2-dichloropropane CO541 Grab 624 2.0 ND ug/L 1,3-dichloropropylene 51044 Grab 624 2.0 ND ug/L Ethylbenzene 37371 Grab 624 1.0 ND ug/L Methyl bromide 34413 Grab 624 2.0 ND ug/L Methyl chloride 34418 Grab 624 2.0 ND ug/L Methylene chloride 34423 Grab 624 2.0 ND ug/L 1,1,2,2-tetrachloroethane 34516 Grab 624 2.0 ND ug/L Tetrachloroethylene 34475 Grab 624 2.0 ND ug/L Toluene 34010 Grab 624 1.0 ND ug/L 1,1,1-trichloroethane 34506 Grab 624 2.0 ND ug/L 1,1,2-trichloroethane 34511 Grab 624 2.0 ND ug/L Trichloroethylene 39180 Grab 624 2.0 ND ug/L Vinyl chloride 39175 Grab 624 2.0 ND ug/L Acid -extractable compounds P-chloro-m-creso 34452 Grab 625 10.0 ND ug/L 2-chlorophenol 34586 Grab 625 5.0 ND ug/L 2,4-dichlorophenol 34601 Grab 625 5.0 ND ug/L 2,4-dimethylphenol 34606 Grab 625 10.0 ND ug/L 4,6-dinitro-o-cresol 34657 Grab 625 10.0 ND ug/L 2,4-dinitrophenol 34616 Grab 625 50.0 ND ug/L 2-nitrophenol 34591 Grab 625 5.0 ND ug/L 4-nitrophenol 34646 Grab 625 50.0 ND ug/L Pentachlorophenol 39032 Grab 625 10.0 ND ug/L Phenol 34694 Grab 625 5.0 ND ug/L 2,4,6-trichlorophenol 34621 Grab 625 10.0 ND ug/L Base -neutral compounds Acenaphthene 34205 Grab 625 5.0 ND ug/L Acenaphthylene 34200 Grab 625 5.0 ND ug/L Anthracene CO220 Grab 625 5.0 ND ug/L Benzidine 39120 Grab 625 50.0 ND ug/L Benzo(a)anthracene CO526 Grab 625 5.0 ND ug/L Benzo(a)pyrene 34247 Grab 625 5.0 ND ug/L 3,4 benzofluoranthene CO531 Grab 625 5.0 ND ug/L Benzo(ghi)perylene 34521 Grab 625 5.0 ND ug/L Benzo(k)fluoranthene 34242 Grab 625 5.0 ND ug/L Bis (2-chloroethoxy)methane 34278 Grab 625 10.0 ND ug/L Bis (2-chloroethyl)ether 34273 Grab 625 5.0 ND ug/L Bis (2-chloroisopropyl)ether 34283 Grab 625 5.0 ND ug/L Bis (2-ethylhexyl)phthalate CO100 Grab 625 5.0 ND ug/L 4-bromophenylphenylether 34636 Grab 625 5.0 ND ug/L Butylbenzylphthalate CO292 Grab 625 5.0 ND ug/L 2-chloronaphthalene 34581 Grab 625 5.0 ND ug/L 4-chlorophenylphenylether 34641 Grab 625 5.0 ND ug/L Page 2 Annual Monitoring and Pollutant Scan Facility Name: City of Hickory - Catawba POTW NPDES #: NC0025542 Parameter Parameter Code Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Base -neutral compounds (cont.) Chrysene 34320 Grab 625 5.0 ND ug/L Di-n-butyl phthalate 39110 Grab 625 5.0 ND ug/L Di-n-octyl phthalate 34596 Grab 625 5.0 ND ug/L Dibenzo(a,h)anthracene 34556 Grab 625 5.0 ND ug/L 1,2-dichlorobenzene 34536 Grab 625 5.0 ND ug/L 1,3-dichlorobenzene 34566 Grab 625 5.0 ND ug/L 1,4-dichlorobenzene 34571 Grab 625 5.0 ND ug/L 3,3-dichlorobenzidine 34631 Grab 625 25.0 ND ug/L Diethyl phthalate 34336 Grab 625 5.0 ND ug/L Dimethyl phthalate 34341 Grab 625 5.0 ND ug/L 2,4-dinitrotoluene 34611 Grab 625 5.0 ND ug/L 2,6-dinitrotoluene C0626 Grab 625 5.0 ND ug/L 1,2-diphenylhydrazine 34346 Grab 625 5.0 ND ug/L Fluoranthene C0376 Grab 625 5.0 ND ug/L Fluorene 34381 Grab 625 5.0 ND ug/L Hexachlorobenzene CO700 Grab 625 5.0 ND ug/L Hexachlorobutadiene CO702 Grab 625 5.0 ND ug/L Hexachlorocyclo-pentadiene 34386 Grab 625 10.0 ND ug/L Hexachloroethane CO396 Grab 625 5.0 ND ug/L Indeno(1,2,3-cd)pyrene 34403 Grab 625 5.0 ND ug/L Isophorone 34408 Grab 625 10.0 ND ug/L Naphthalene 34696 Grab 625 5.0 ND ug/L Nitrobenzene 34447 Grab 625 5.0 ND ug/L N-nitrosodi-n-propylamine 34428 Grab 625 5.0 ND ug/L N-nitrosodimethylamine 34438 Grab 625 5.0 ND ug/L N-nitrosodiphenylamine 34433 Grab 625 10.0 ND ug/L Phenanthrene 34461 Grab 625 5.0 ND ug/L Pyrene 34469 Grab 625 5.0 ND ug/L 1,2,4,-trichlorobenzene C0551 Grab 625 5.0 ND ug/L "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate and complete. I am aware that thereare significant penalties for submitting false information, including the posibility of fines and imprisonment for knowing violations." jk ircl�oMDacA(� Authoriped Rep ese ative hne gnature Date -090 //gik-e- Page 3 ROY COOPER Governor DIONNE DELLI-GATTI Secretary 5, DANIEL SMITH NORTH CANA. D rector Environmental Qrtalit MEMORANDUM To: April 6, 2021 Clinton Cook NC DEQ / DWR / Public Water Supply Mooresville Regional Office From: Diana Yitbarek NC DEQ / DWR / Municipal Permitting Unit Subject: Review of Draft NPDES Permit NC0025542 Hickory -Catawba WWTP Catawba County Please indicate below your agency's position or viewpoint on the draft permit and return this form by May 6, 2021. If you have any questions on the draft permit, please contact me at 919-707-9130 or via e-mail [diana.yitbarek(a7ncdenr.gov]. RESPONSE: (Check one) §§§§§§§§§§§§§§§§§§§§§§§§§§§§§§§§ Concur with the issuance of this permit provided the facility is operated and maintained properly, the stated effluent limits are met prior to discharge, and the discharge does not contravene the designated water quality standards. Concurs with issuance of the above permit, : ,- T. liA,V6 No APft.: Ikeel.F,° ExreK-7156 IN r`(ei, (`(Et lrAr'Iot•C U ' Tie cLeAt..1 b ATC-te, ACT"''Et ,uirea-lF:s,fAN!? (AVC t lI JlrtAL U JP TAN I & Z2 - 4E It•-iFe) iArk nj ZPiP 702 , S , z uz.. r �'. i -Aif & No 13/K G f j2 ¶P©51 J& TU-{ I✓ f ir-t cr. Opposes the issuance of the above permit, based on reasons stated below, or attached: Signature: Date: 4,7z7I ZP:2_' NoCareslinir0epartment of Environmental i t+alit}' 1 Division of Water Resources S1Z7vort15Salisbury Street 1 1617 Mall Service 919.707.9000 North Carolina 27699-1617 Hickory Daily Record Advertising Affidavit PO Box 968 Hickory, NC 28603 NCDEQ/DWR ATTN: WREN THEDFORD 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 Account Number 3611028 Date April 07, 2021 Date Category Description Ad Number Ad Size 04/07/2021 Legal Notices Public Notice North Carolina Environmental Management Comi 0000711963 2x29L Publisher of Hickory Daily Record Catawba County Before the undersigned, a Notary Public duly commissioned, qualified, and authorized by law to administer oaths, personally appeared the Publisher's Representative who by being duly sworn deposes and says: that he/she is authorized to make this affidavit and sworn statement; that the notice or other legal advertisement, a copy of which is attached hereto, was published in the Daily Record on the following dates: 04/07/2021 and that the said newspaper in which such notice, paper document, or legal advertisement was published, was at the time of each and every such publication, a newspaper meeting all the requirements and qualifications of Section 1-597 of the General Statutes of North CaroYtna. Billing Representative Newspaper reference: 0000711963 Sworn to and subscribed before me, this 7th day of April, 2021. wary Public State of Virginia County of Hanover My commission expires: Richard A. Hundley Notary Public Commonwealth of Virginia Notary Hegistratidn No. 7904041 Commission Exp. Jan 31, 2024 THIS IS NOT A BILL. PLEASE PAY FROM INVOICE. THANK YOU North na Environmental Mara emer't Commissio PDES Unit 1617 Mail Service Center Ralet h NC Z7699-1617 Notice of Intent to Issue a NPDES Wastewater Permit NC0025542 Caa- ermm to person(S) propoWWTP The North Carolina Environmental ses to issue a NPDES wastewater dischargep permit the ion listed below. Written comments regarding the proposed permit will be hoid . puDi hearing ac- cepted until 30 days alter the publish date of this notice. The Director o significant degree of public interest. Please mail com- ments NC Division of Water Resources (DWR)may ments there a DWR at the above address. Interest- ed persons sod/omayvinformation requests to Street, Raleigh, NC ed persons visit the DWR at 512 N. Salisbury wm information nc DESate 27604 to this lmay on on ourtwebs to h atrod .nc. per- mits and this notice may w t r_ e r s- rm its w st w to - divis on t r res urc 1. The City of Hickory (P.O. Box 398, Hickory, N.C. 8603) has requested re- newal Catawba Wastewater located in Catawba County. This permitted facility of NPDES Permit NC0025542 for its Hickory Treatment Plant, en, total intreated rent domestic mical oxygenodemand, dissolved Catawba bn River Basin. Currently, pH, ammonia, total residual chlorine, andsusmethyl solids, fecal water qualityer limited arameters in the permit. and misch ge may affecttfutureallocations pin this segment of Lyle This discharge Creek. Publish: April 7, 2021.