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HomeMy WebLinkAboutWQ0035576_Application_20210521P4 Box 146 Ronda, NC 28670 336-777-6909 www.usbiosolids.com Wednesday, May 19, 2021 North Carolina Department of Environmental Quality Division of Water Resources Water Quality Permitting Section Non -Discharge Unit 512 N. Salisbury Street Raleigh, NC 27604 Reference: Broad River Water Authority Permit Renewal Package Distribution of Alum Residuals Permit No. WO0035576 US Biosolids, Inc. is assisting the Broad River Water Authority with the renewal of the Authority's distribution of alum residuals permit. These residuals are produced through the treatment of potable water and are stored in two residuals holding lagoons. included with this permit renewal package are all the required forms and testing showing compliance with the requirements of a class A residual. There have been no changes in the process or how the residuals are produced since the last issuance of permit WQ0035576. Your attention in the review of this permit renewal application package is greatly appreciated. Please contact me with any question or concerns at zachkey@usbiosolids.com or at 336-957-7871. Sincerely, Zach Key US Blosolids, Inc. State of North Carolina DW Department of Environmental Quality qwRDivision of Water Resources Division of Water Resources 15A NCAC 02T .1100 — DISTRIBUTION OF CLASS A RESIDUALS INSTRUCTIONS FOR FORM: DCAR 06-16 & SUPPORTING DOCUMENTATION Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting, documentation For more information, visit the Water Quality Permitting ,Section's Non -Discharge Permitting Unit website General --This application is for treatment, storage, transport, distribution, land application, and/or marketing of Class A (or Equivalent) residuals under 15A NCAC 02T . 1100. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. A. Distribution of Class A Residuals (FORM: DCAR 06-16): ❑ Submit the completed and appropriately executed Distribution of Class A Residuals (FORM: DCAR 06-16) form. Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. EJ The project name should be consistent on the plans, specifications, etc. The Applicant's Certification on Page 3 of this form shall be signed in accordance with 1 JA NCAC 02T .0106(b). An alternate person may be designated as the signing official if a delegation letter is provided from a person who meets the criteria in 15A NCAC 02T .0106(b . ❑ If this project is for a modification of an existing permit, submit one copy of the existing permit. ❑ Please submit this application form at least 180 days prior to the expiration date on the existing permit, or 40 days prior to operation of proposed faeility(ies) for application packages involving new or changes to treatment and storage units. B. Application Fee (New and Major Modification Application Packages) El Submit a check, money order or electronic funds transfer made payable to: North Carolina Department of Environmental Quality (NCDEQ). - A major modification shall be defined as any permit modification that: increases the generating facility's residuals dry tonnage; adds additional residuals sources; or includes the addition of new treatment or storage units/processes not previously permitted. There is no fee for minor permit modifications. C. Cover Letter (All Application Packages) El List all items included in the application package, as well as a brief description of the requested permitting action. INSTRUCTIONS FOR FORM: DCAR 06-16 Page I of 3 D. Program Information (All Application Packages) [] Provide a narrative explaining the following: ❑ How the materials will be handled and transported from where the residuals were produced to where it will be treated. ❑ How the residuals will be processed/treated (attach process flow diagram), [] How leachate collection will be handled. Where the residuals will be stored until processed. [] How the final product will be distributed (packaging, bulk, etc.) C] What nutrients or other constituents (i.e. nitrogen, phosphorous, aluminum, calcium, etc.) are used or recommended as the limiting parameter for determination of residuals loading rate to ensure that it does not overload the soil and cause contravention of surface water or groundwater standards, limit crop growth, or adversely impact soil quality. ❑ Attach a marketability statement detailing destinations and approximate amounts of the final product to be distributed. ❑ Provide either a label that shall be affixed to the bagged processed residual or an information sheet that shall be provided to the person who receives the processed residual. The label or information sheet shall contain, at a minimum, the following information: 0 Name and address of the person who prepared the residual that is sold or given away. ❑ A statement that application of the residuals to the land shall be in accordance with the instructions on the label or information sheet. A statement that the residuals shall not be applied to any site that is flooded, frozen or snow-covered. ❑ A statement that adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored residuals into any surface waters. rl Information on all applicable setbacks in accordance with 15A NCAC 02T .1108(b). ❑ A statement that the residuals shall be applied at agronomic or recommended rates for intended uses. E. Detailed Plans and Specifications (Application Involving New or Changes to Treatment or Storage Units) [� Submit detailed plans and specifications that have been signed, sealed, and dated by a NC Professional Engineer per 15A NCAC 02T .1104(a). Specifications for standard equipment may only be omitted for municipalities with approved standard specifications, but use of the standard specifications must be noted on each sheet of the plans. ❑ Plans must include the following minimum items: a general location map, a topographic map, plan and profile view of the residuals treatment and storage units as well as the proximity of the residuals treatment and storage units to other utilities and natural features within 500 feet of all treatment and storage facilities, and detail drawings of all items pertinent to the residuals treatment and storage units. Depict minimum separations required in 15A NCAC 02T. 1108(a) on the plans. ❑ Specifications must include, at a minimum, the following for all items pertinent to residuals treatment and storage units: description of materials to be used, methods of construction, quality of construction testing procedures to ensure the integrity of the final product in accordance with 15A NCAC 02T .1104(a)(2)(B), including leakage and pressure testing as appropriate. ❑ Plans and specifications must not be labeled with preliminary phrases (e.g., FOR REVIEW ONLY, NOT FOR CONSTRUCTION, etc.) that indicate that they are anything other than final plans and specifications. However, the plans and specifications may be labeled with the phrase: FINAL DESIGN — NOT RELEASED FOR CONSTRUCTION. F. Engineering Calculations (Application Involving New or Changes to Treatment or Storage Units) ❑ Submit all design calculations that have been signed, sealed, and dated by a NC Professional Engineer per 15A NCAC 02T .110 a. G. Environmental Assessments (Maybe Required —See 15A NCAC I C .0300) ❑ Submit a copy of the Findings of No Significant Impact (FONSI) or Environmental Impact Statement (EIS). Also, include information on any mitigating factor(s) from the Environmental Assessment (EA) that impact the construction of the residuals treatment and storage facilities. An EA may also be required for private systems if any public funds and/or lands are used for the construction of the subject facilities. INSTRUCTIONS FOR FORM: DCAR 06-16 Page 2 of 3 H. Operation and Maintenance Plan (New and Renewal Application Packages) ❑ For Modification Application, if there are any changes to the existing plan, submit an updated O&M plan. ❑ Submit the O&M Plan in accordance with 15A NCAC 02T .1110 and include at a minimum: ❑ Operational functions; describe the operation of the program to show what operations are necessary for the program to function and by whom the functions are to be conducted. ❑ Maintenance schedules; may include equipments calibration, maintenance of signs, etc. ❑ Safety measures; may include safety training program, manuals, signs, etc. ❑ Spill response plan; including control, containment, remediation, emergency contact information, eta. ❑ Inspection plan including the following information; [] Names and titles of personnel responsible for conducting the inspections. ❑ Frequency and location of inspections, including those to be conducted by the ORC, and procedures to assure that the selected location(s) and inspection frequency are representative of the residuals management program. ❑ Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the event that noncompliance is observed. Sampling and monitoring plan including the following information; ❑ Names and titles of personnel responsible for conducting the sampling and monitoring. Detailed description of monitoring procedures including parameters to be monitored. ❑ Sampling frequency and procedures to assure that representative samples are being collected. Fluctuation in temperature, flow, and other operating conditions can affect the quality of the residuals gathered during a particular sampling event. The sampling plan shall account for any foreseen fluctuations in residuals quality and indicate the most limiting times for residuals to meet pathogen and vector attraction reduction requirements (e.g. facilities that land apply multiple times per year but have an annual sampling frequency, may need to sample during winter months when pathogen reduction is most likely to be negatively affected by cold temperatures. ONE ORIGINAL AND TWO COPIES OF THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION AND MATERIALS, SHALL BE SENT TO THE FOLLOWING ADDRESS: NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES WATER QUALITY PERMITTING SECTION NON -DISCHARGE PERMITTING UNIT By U.S. Postal Service: 1617 MAIL SERVICE CENTER RALEIGH, NORTH CAROLINA 27699-1617 TELEPHONE NUMBER: (919) 807-6464 Courier/Special Delivery: 512 N. SALISBURY STREET RALEIGH, NORTH CAROLINA 27604 FAX NUMBER: (919) 807-6496 INSTRUCTIONS FOR FORM: DCAR 06-16 Page 3 of 1 14 State of North Carolina Department of Environmental Quality Division of Water Resources Division of Water Resources 15A NCAC 02T .1100 — DISTRIBUTION OF CLASS A RESIDUALS FORM: DCAR 06-16 I. APPLICANT INFORMATION: 1. Applicant's name: Broad'kLyerVat-drAnthorily Applicant type: Individual Q Corporation ❑ General Partnership ❑ Privately -Owned Public Utility ❑ Federal 0 State 0 Municipal ❑ County Signature authority's name per 15A NCAC 02T .0106: Maria Hunnicutt Title: Manaeer Applicant's mailing address: P.O. Box 1269 City: Rutherfordton State: NC Zip: 28139 Telephone number: (828) 286-0640 Email Address: mhunniguaticbrwa.com 2. Consultant's name: Zach Kev License Number (for P.E.): Affiliation: [] On Staff 21 Retained (Firm: US Biosolids, Inc.) Consultant's mailing address: 958 Hoots Road City: Roaring River State: NC / Zip: 28669 Telephone number: (336) 957-7871 Email Address: zachkey Qusbiosolids.com 3. Fee submitted: $0.00 (See Instruction B) 1I. PERMIT INFORMATION: 1. Application is for (check all that apply): Q new, [] modified, & renewed permit 2. If this application is being submitted to renew or modify an existing permit, provide the following: Permit number: WQ0035576 Date of most -recently issued permit: 07/18/2016 Date of most -recently certified Attachment A (if different than the permit): 07/ 18/2016 III. FACILITY INFORMATION: 1. Name of residuals processing facility: Broad River Water Authority City: Rutherfordton State: NC Zip: 28139 Coordinates: Latitude: 35' 18' 44.77" Longitude: 81" 59' 20.87" Datum: NAD 83 Level of accuracy: 0.01 Method of measurement: MAP County where facility is located: Rutherford 2. Facility contact (person familiar with residuals preparation): Name: Brad Joyner Title: WTP Superintendent Mailing address: P.O. Box 1269 ' City: Rutherfordton State: NC Telephone number; 828) 297-7776 Zip: 28139 E-mail address: bioynner&cbrwa.com FORM: DCAR 06-16 Page I of 3 3. Is the residual process facility also the generator? ® Yes; ❑ No If No, please specify delivery frequency and quantity of residual to be processed: 4. Length of residuals storage at facility: 365+days (Note: the Division requires minimum 30 days storage in units that are separate from treatment system, i.e. not in clarifiers, aeration basins, etc.) IV. RESIDUALS QUALITY INFORMATION: 1. Specify how these residuals will be distributed: ❑ sold or given away in bags or other containers; ❑ lawn (bulk); ❑ home garden (bulk); 0 other (explain); Given away through land application Note: Bulk residuals shall mean residuals that are transported and not sold or giving away in a bag or other receptacles with a load capacity of one metric ton or less. 2. Complete the following if residuals are to be mixed with other materials: Type of Materials Amounts to be added Der 1.0 dry ton of residuals (dry ton) 3. Approximate amounts of the residuals received and processed at the facility: 1649 dry tons per year. 4. Approximate amounts of the final product (processed residuals) to be distributed: 1649 dry tons per year. 5. Provide a description of the onsite storage management plan for the treated residuals (including estimated average and maximum storage times prior to distribution): Two (2) 300' X 150' lagoons 6. Does the facility have a stormwater management plan? ❑ Yes; ® No Explain whether the treatment and storage areas are under roof or how stormwater runoff will be handled: All runoff will remain in the lagoon V. RESIDUALS SOURCE INFORMATION: (Required for all new, renewed, or modified residuals source) Complete and submit the attached Residuals Source Certification and all associated documentation. RSC 06-16.doc FORM: DCAR 06-16 Page 2 of 3 Professional Engineer's Certification: (Application Involving New or Changes to Treatment or Storage Units) attest that this application for has been reviewed by me and is accurate and complete to the best of my knowledge. 1 further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. North Carolina Professional Engineer's Seal, Signature, and Date: Applicant's Certification: The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active compliance schedule, and do not have any overdue annual fees under Rule I SA NCAC 02T .0105. ED Yes 0 No, Explain; 1, Maria Hunnicutt General Manager (Signature Authority's Name — PLEASE PRINT) (Title) attest that this application for _ Broad River Water Authority (Facility Name) has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water Resources may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes unless specifically granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate enforcement action, which may include civil penalties, -injunctive relief, and/or criminal prosecution. I will make no claim against the Division of Water Resources should a condition of this permit be violated. 1 also understand that if all required parts of this application are not completed and that if all required supporting information and attachments are not included, this application package will be returned to me as incomplete. Note: In accordance with North Carolina General Statutes §143-215.6A and §143-215.6B, any person who knowingly makes any false statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which may include a fine not to exceed $10,000 as well as civil penalties up to $25,000 per violation. Signature: L Date: FORM: DCAR 06-16 Page 3 of 3 Program Information All of the residuals produced from the Broad River Water Authority's Water Treatment plant are stored in one of two 750,000 gallon sludge holding lagoons. The first location during the treatment that the residuals are produced is from the sedimentation basins, from where the residuals are allowed to settle out. The return water left in the sedimentation basin is pumped to the sludge holding lagoons. The second place in the treatment process that produced residuals are from the filters. The filters are backwashed and the residuals from the backwash process are sent to the sludge holding pond. Also residuals are sent to the lagoons when a filter is rewashed during plant start- up. Once the residuals reach the sludge holding lagoons, they are stored until a lagoon is full enough to need a distribution even. Once it is determined that a distribution event is needed, the residuals are allowed to dry till they can be removed using loaders and dump trucks. The residuals are given to local landowner's for use as a soil amendment. All of the residual are stored in the sludge holding pond along with any leachate or run off the may be present. All land owners that receive the residuals are given an information sheet that will explain all of the requirements and regulations for the material. This information sheet will also highlight any nutrients that will be the limiting parameter for determining the residuals loading rate. In most cases, the limiting parameter for determining the loading rate will be nitrogen.. Marketability Statement: The product will be given to local landowners who desire the material as a soil amendment. The amount of residuals to be land applied per year is approximately 900 dry tons. These residuals can be beneficial to soils and plants and the improved soil physical properties are the results of the addition of organic matter and plant nutrients. Destinations for these residuals are local landowners and farmers that have sufficient amount of land to handle a bulk distribution of the alum residuals; a field or combination of fields of around 100 acres are desired. Product Information: Residuals produced from: Broad River Water Authority Mailing Address: PO Box 37 Spindale, NC 28139 Facility Address: 1661 Baber Road. Rutherfordton, NC 28139 (828) 287-7776 This product contains plant nutrients such as nitrogen and aluminum and can be used as a soil amendment. This material has been processed in accordance with EPA guidelines. Chemical composition of this product is such that it does not exceed pollutant ceiling concentrations This material shall not be applied to any site that is: 0 frozen, snow-covered or flooded 0 100 feet of any public or private water supply source (including wells) 0 100 feet of surface waters (streams, rivers, wetlands) 0 25 feet of water diversions (ditches) o Within a 100 year flood plain unless incorporated within 24 hours o During a measurable precipitation event (0.01 inch per hour) or within 24 hours of a rainfall event of 0.5 inches o Slope greater than 10% o Has a vertical separation of the bedrock less than one foot o If vertical separation of seasonal water table is less than one foot o Than does not have an established vegetative cover unless incorporated if soil pH is less than 6.0, lime shall be added to maintain at least 6.0 unless an agronomist provides information indication otherwise Residual stockpile for more than 14 days shall be covered For current analysis and appropriate loading rates for farmland application, contact: U.S. Biosolids, Inc. PO Box 146 Ronda, NC 28670 Phone (336) 777-6909 zachkey@usbiosolids.com Application of this material to the land is prohibited except in the accordance with the instructions on this label. Use of this material should conform to the recommendations of the current analysis and loading rates. Operation and Maintenance Plan Broad River Water Authority In accordance with the requirements as issued by the North Carolina Department of Environmental Quality using NCGS 143-215.1 and 143-215.3(a) based on 15A NCAC 02T .110, the Broad River Water Authority and U.S Biosolids, Inc. are implementing this Operation and Maintenance Plan. The Class A distribution program from the Broad River Water Authority's Water Treatment Plant will be conducted from the Water Treatment facility, located at 1661 Barber Road Rutherfordton, NC. Residuals will be removed and given away to local farmers to be used as a soil amendment. The residuals will be removed on as needed bases as fluctuation in the output of the plant will vary with changing economic conditions. The day -today operation of the running of the Water Treatment will be conducted by the Broad River Water Authority. The operations of the distribution program will be conducted by U.S Biosolids, Inc. A label shall be provided to every recipient of the residual material, in addition to this label, the ORC will make sure every recipient is educated in the proper use of the residuals. Prior to distributing these residuals to local farmers, the following sampling conditions must be met (as is outlined in greater detail in the sampling plan attached to this Operation and Maintenance Plan). Toxicity Characteristics Leaching Procedure (TCLP) will be conducted once per Permit cycle. An analysis of the parameters will be conducted quarterly if a distribution event takes place. These samples will be collected by the ORC or his/her designee and transported to an approved lab the same day the samples are taken, as in accordance with 15A NCAC 02B .0505. The samples must be taken in a matter to ensure a representative sample of the residuals has been taken. An inspection will be conducted will be conducted daily while a distribution event is taking place. This inspection will confirm that all requirements of permit WQ0035576 are complying. The fields should be inspected daily for compliance with the conditions that is outline in then permit. The inspection should consist of (but not limited to): l . All required setbacks and buffers are complying. 2. All required record keeping of truck and fields sheets are maintained and properly filled out so accurate records of the volume and locate of residuals are keep. 3. All public access points are controlled (signs posted, gates closed) 4. Make sure all fields' records are turned over to the ORC and the Broad River Water Authority so records can be reviewed by NCDEQ and an annual report can be constructed. If any issues or violations are discovered, the ORC, Broad River Water Authority and the Asheville Regional Office should be contacted as soon as safely possible. This inspection will be conducted by the following personal: o On Site Project Manager, US Biosolids, Inc. 336-957-7878 o Brad Joyner, BRWA 828-287-7776 To prevent any spills and or safety issues from occurring the flowing will take place during a distribution event. In the unlikely event of a spill consult the spill control plan immediately. 1. Access to the facility will be controlled with a locked gate and signs to prevent any unauthorized, entry into the complex; this gate will be lock at the end of each day. 2. All pumps and hose will be checked at the start of each day for leaks or loose fittings. 3. All tanker valves are closed prior to loading and lids are closed prior to transport. 4. All dump trailers or dump trucks gates are tightly fastened and do not leak prior to transport. 5. All on road equipment is check as per DOT regulations for any safety or mechanical hazards or issues. 6. All equipment is secured at the end of each working day to prevent any tampering or unauthorized use. 7. Enough freeboard is maintained in the residual ponds so that heavy precipitation events does not cause a spill due to the ponds overflowing. This can be accomplished by maintaining the levels of residuals to an acceptable level. 8. If enough freeboard cannot be maintained, residuals may have to be pumped and transported to the Wastewater Treatment Plant so that the ponds do not overflow. SPILL CONTROL PLAN- US Biosolids Inc Permit WQ0035576 Broad River Water Authority Water Treatment Plant In the event of a spill, the following should be taken IMMEDITALY. 1. Make sure all personal and bystanders are safe- if not contact emergency services 2. Halt the source of the spill- overturned truck, leaking valve, ruptured tank. 3. Contain the spill. Use straw bales or earthen barrier to forma dike to contain the spill 4. Cleanup. Employ vacuum trucks, dump trucks, and loaders to remove as much of the spilled material as possible. Use straw to soak -up the remaining material. Dispose of the same in a landfill. 5. Flush the roadways with water if needed. If the spill occurred on a tillable area, till the some into the soil and spread lime if necessary. If a spill occurs on private property, final clean-up should be to the satisfaction of the owner. 6. Notification. (This should be done as soon as safely possible.) A. US Biosolids, Inc. Main Office (336)777-6909 B. Broad River Water Authority Brad Joyner (828)287-7776 Maria Hunnicutt (828) 286 0640 C. NCDEQ-Asheville Regional Office (828) 296-4500 D. County Emergency Services (Sheriff, Fire Dept.) 911 7. Reporting: The Permittee shall report by telephone to the Asheville Regional Office, telephone number (828) 296-4500, as soon as possible, but in no case more than 24 hours or on the next working day following the occurrence or first knowledge of the occurrence of any of the following: A. Surface disposal of residuals abnormal in quantity or characteristic. B. Any failure of the surface disposal program resulting in a release of material to surface waters. C. Any time self -monitoring indicates the facility has gone out of compliance with its permit limitations. D. Any process unit failure, due to known or unknown reasons, rendering the facility incapable of adequate residual treatment E. Any spill or discharge from a vehicle or piping system during residuals transportation. Any emergency requiring immediate reporting (e.g., discharges to surface waters, imminent failure of a storage structure, etc.) outside of normal business hours shall be reported to the Division's Emergency Response personnel at telephone number (800) 662-7956, (800) 858-0368, or (919) 733-3300. Persons reporting such occurrences by telephone shall also file a written report in letter form within five days following first knowledge of the occurrence. This report shall outline the actions taken or proposed to be taken to ensure that the problem does not recur. 8. Spill Prevention. The easiest way to clean a spill is to prevent one. A. Ensure loading personal watch the vehicle being loaded. B. Ensure all valves and lids are closed C. Inspect all seals and replace if necessary. Broad River Water Authority Permit WQ0035576 WTP SAMPLING PLAN Quarterly, if a distribution event occurs, grab samples are collected from the two sludge lagoons. Samples from the two sludge lagoons will be combined to form individual grab samples to be sent to a laboratory for analysis. These individual grab samples are collected and tested for fecal coliform analysis, nutrient analysis, and a TCLP test. These tests will be taken by Zach Key of U.S. Biosolids, Inc. All samples will be taken to a state approved laboratory. All samples taken will be taken in the same condition as the residuals are to be land applied. Fecal Coliform is gathered in seven (7) individual samples and tested to meet the requirements of [503.32(b)(2)]. This requirement is for the geometric mean fecal coliform density of the samples be less than one thousand (1,000) MPN per gram. These samples will be placed in 250ml containers and placed on ice, in a cooler for transport to the laboratory before 1600 hours (4pm) the same day the samples are obtained. Quarterly, if land application occurs, a/composite residual sample will be analyzed, prior to a land application event for: Cadmium, Copper, Lead, Mercury, Molybdenum, Nickel, Selenium, Zinc, Aluminum, Ammonia Nitrogen, Calcium, Nitrate Nitrogen, Magnesium, %total Solids, pH, Phosphorus, Potassium, TKN, Sodium From this information, the Plant Available -Nitrogen (PAN) and a Sodium Absorption Ratio (SAR) will be calculated. This sample will be collected in a non -breakable container, at least one quart in size. This sample will be taken from the digester. The toxicity characteristic leaching procedure (TCLP) shall be preformed once per permit cycle of permit WQ0035576. This sample will be taken in at least 2, one -gallon containers and sent to a state approved laboratory. State of North Carolina Department of Environmental Quality Division of Water Resources Division of Water Resources RESIDUALS SOURCE CERTIFICATION INSTRUCTIONS FOR FORM: RSC 06-16 Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted, the Applicant shall submit one original and two conies of the application and supporting documentation For more information, visit the Neater Quality Permitting Section's Non -Discharge Permitting Unit General — This certification provides detailed information of residuals source generating facility and its residuals quality for land application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 11-15). Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. A. Residuals Source Certification (FORM: RSC 11-15): ❑ Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 1 1-15) form. Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. ❑ For new or renewed permits, submit a separate ce5ification for each source facility. ❑ For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification. ❑ Complete the residuals source facility summary•page. List all new, renewed, or modified facilities. B. Residuals Source -Generating Facility Information: ❑ For each source facility, attach the following: ❑ Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "MpRGiq dance,for Residuals. Land Application Permits". ❑ Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals' are to be generated, treated, processed, and stored at the facility. ❑ Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item 1. 8. Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed, and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during processing. ❑ Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition, ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as they are to be land applied, distributed, and/or disposed. C. Residuals Quality Information: ❑ For each source facility, attach the following: ❑ Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification. ❑ Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector attraction reduction requirements. ❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please attach analytical results of residuals generated from a similar facility along with the description of similarities of the two facilities. INSTRUCTIONS FOR FORM: RSC 06-16 Page I of 1 RESIDUALS SOURCE FACILITY SUMMARY Applicant's name: Broad River Water Authority Status Code Facility Permit Holder Facility Name County Permit Number Maximum Dry Tons Per Year Current b Proposed R Broad River Water Authority Broad River Water Authority WTP Rutherfordton NCO181035 1649 1649 I Status Code for source facility are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ D (Deleted) b The amount of residuals currently permitted for distribution, land application, or disposal (i.e. not applicable to new facility). SUMMARY FOR FORM: RSC 06-16 Page 1 Division of Water Resources State of North Carolina Department of Environmental Quality Division of Water Resources RESIDUALS SOURCE CERTIFICATION FORM: RSC 06-16 1. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.): I . Facility Name: Broad River Water Authority 2. Facility permit holder is: ] Federal, [] State, 0 Local Government, or a Private. Facility permit issued by: Div. of Water Resources, Div. of Environmental Health, or Other {explain:: ). 3. Facility contact person and title: Maria Hunnicutt Complete mailing address: P.O. Box 1269 City: Rutherfordton State: NC Zip: 28139 Telephone number: ($28) 286-0640 E-mail address: mhunnicutt@ncbrwa.com 4. Facility physical address: 1661 Baber Rd City: Rutherfordton State: NC Zip: 28139 Coordinates: Latitude: 35' IS' 44.77" i Longitude: 81' 59' 20.87" Datum: NAD 83 Level of accuracy: 0.01 Method of measurement: MAP S. Purpose of the facility: treatment of municipal wastewater, [3 treatment of 100% domestic wastewater, treatment of potable water, Q treatment of 100% industrial wastewater, treatment of industrial wastewater mixed with domestic wastewater, (approximate percentages::; °:' > % industrial and % domestic) other (explain: 6. Does the facility have an approved pretreatment program: Q Yes No 7. Facility permitted/design flow: 12.0 MGD and facility average daily flow: 6_1 MGD 8. Average amount of residuals being generated at this facility 600 dry tons per year. 9. Specify the following regarding treatment and storage volumes available at the facility: Type and volume of residuals treatment: 2 sludge lagoons 750,000 gallons each Type and volume of residuals storage (i.e., outside of residuals treatment units): None 11. RESIDUALS QUALITY INFORMATION (See Instruction C.): 1. Specify if residuals are regulated under: 40 CFR Part 503 or 40 CFR Part 257. Nate: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40 CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257. 2. Specify if residuals are defined under 15A NCAC 02T.1102(6) as: Q Biological 9 Non -Biological Nate: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems). FORM: RSC 06-16 Page I of 5 3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat 100% non -municipal, domestic wastewater only) a. Are the residuals listed in 40 CFR §261.31-§261.33: Q yes 0 no. If yes, list the number(s)::_. b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21- 261.24: Q yes 0 no. Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as well as those for corrosivity, ignitability, and reactivity: Laboratory: Statesville Analytical and Date of analysis: 06/01/2020 Passed corrosivity test: a yes E3 no. pH: sm. (2 < pH < 12.5) Passed ignitabiliry test: 0 yes 0 no. Flashpoint: 200 °F (> 140" F) Passed reactivity test: 0 yes Eno. HCN: ND mg/kg (<250) & H?S: ND mg/kg (<500) TCLP Parameter Limit (mg/1) Result (mg/1) TCLP Parameter Limit (mg/t) Result (m9/1) Arsenic 5.0 ND Hexachlorobenzene 0.13 ND Barium 100.0 0.53 Hexachloro-1,3-Butadiene 0.5 ND Benzene 0.5 ND Hexachloroethane 3.0 ND Cadmium 1.0 N D Lead 5.0 0.031 Carbon Tetrachloride -0.5- ND Lindane 0.4 ND Chlordane 0.03 ND Mercury 0.2 ND Chlorobenzene 100.0 ND Methoxychlor 10.0 ND Chloroform 6.0 ND Methyl Ethyl Ketone 200.0 ND Chromium 5.0 ND Nitrobenzene 2.0 ND m-Cresol. 200.0 ND Pentachlorophenol 100.0 ND o-Cresol 200.0 ND Pyridine 5.0 ND p-Cresol 200.0 ND Selenium 1.0 ND Cresol 200.0 ND Silver 5.0 ND 2,4-D 10.0 ND Tetrachloroethylene 0.7 ND 1,4-Dichlorobenzene 7.5 ND Toxaphene 0.5 ND 1,2-Dichloroethane 0.5 ND Trichloroethylene 0.5 ND 1,1-Dichloroethylene 0.7 ND 2,4,5-Trichlorophenol 400.0 ND 2,4-Dinitrotoluene 0.13 ND 2,4,6-Trichlorophenol 2.0 ND Endrin 0.02 ND 2,4,5-TP (Silvex) 1.0 ND Heptachlor and its Hydroxide 0.008 ND Vinyl Chloride 0.2 ND FORM: RSC 06-16 Page 2 of 5 4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not violate the ceiling concentrations for metals regulated under 15A NCAC 02T . 1105. a. For DistrlbWon/Land Apnilcation: Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following metal parameters: Laboratory: Statesville Analytical and Date of analysis: 10/15/2019 Parameter Ceiling Concentration Limits (ClassA & ClassB) (mg/kg) Monthly Average Concentration Limits (Class A Only) (mg/kg) Result (mglkg) Arsenic 75 41 1.67 Cadmium 85 39 0.5 Copper 4,300 1,500 27.94 Lead 840 300 25.16 Mercury 57 17 2.062 Molybdenum 75 n/a 0.74 Nickel 420 420 10.38 Selenium 100 100 1.67 Zinc 7,500 2,800 71,625 b. For Surface Disposal Unit (landfllll: Fill in the following table with the results of the latest analyses (i.e., on a dry weight . basis) for the following metal parameters: Laboratory: �� and Date of analysis: LLLL Distance from Disposal Unit to Boundary to Closest Property Line (meters, check one) Arsenic (mg/kg) Chromium (mg/kg) Nickel (mg/kg) ]. > 0 but < 25 30 200 210 Q > 25 but < 50 34 240 >_ 50 but < 75 39 F260 270 0 > 75 but < 100 46 320 E] > 100 but < 125 53 360 390 >_ 125 62 450 420 Result (mg/kg) FORM: RSC 06-16 Page 3 of 5 5. Nutrient/Micronutrient Determination: Complete the following: a. Total solids: 32 %. b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and micronutrient parameters: Laboratory: Statesville Analytical and Date of analysis: 10/15/2019 Parameter Result (mglkg) Aluminum 180638 Ammonia -Nitrogen 122.5 Calcium 750 Magnesium 716 Nitrate -Nitrite Nitrogen 203.75 pH (Standard Unit) 6.45 Phosphorus 406.2 Potassium 2480 Sodium 443.75 Total Kjeldahl Nitrogen 3640 c. Using the results listed in Item I'll. 5b. above, calculate the sodium adsorption ration (SAR): 1.57 [Note: if residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall' address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity and conditions conducive to crop growth]. d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 40 %. This rate is a (check one): 0 default value, or El actually established. If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical justification as to why the selected default value is appropriate to be applied to these residuals: Default for Unstsbilized Residuals e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table: Application Method First (151) Year PAN Five -Year Maximum Adjusted PAN (►nglk8) (mg/kV Surface 1672 2327.54 Injection/Incorporation 1733.25 2368.39 6. Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide the results of the latest analyses: None FORM: RSC 06-16 Page 4 of 5 7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements: a. For Distribution/Land Analicadon of Class A or Equivalent: IM A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids, or BA salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids. AND one of the followings (except for non -biological residuals): Alternative 1 [15A NCAC 02T.I 106(bx3)(A)] - Time/Temperature Compliance. fl Alternative 2 [15A NCAC 02T.1 106(bx3)(B)] - Alkaline Treatment. E] Alternative 3 [15A NCAC 02T.I 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova. 0 Alternative 4 [15A NCAC 02T.I 106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova. EJ Alternative 5 [15A NCAC 02T. I l06(bx3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP). Specify one: composting, Q heat drying, Q heat treatment, thermophilic aerobic digestion, beta ray irradiation, gamma ray irradiation, or pasteurization. b. For Land Application of Class B: EJ Alternative 1 [15A NCAC 02T.1 106(cxl)] - Fecal Coliform Density Demonstration. Alternative 2 [15A NCAC 02T.I 106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP). Specify one: aerobic digestion, S air drying, E] anaerobic digestion, 8 composting, or E] lime stabilization. c. For Surface Disposal: 3 Select One of the Class A or Equivalent Pathogen. Reduction Alternatives in Item 11.7a. above. Q Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item 11. 7b. above. El Exempt.- If Daily Cover Alternative is chosen in Item 11.8. below [15A NCAC 02T.1106(a)(2)]. E] Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution. 8. Vector Attraction Reduction (VAR): Per I5A NCAC 02T.1107, specify how residuals will meet the VAR requirements: [! Alternative I [15A NCAC 02T.1107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion). Alternative 2 [15A NCAC 02T.1107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion). iii1 Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion). E3 Alternative 4 [15A NCAC 02T.1107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion). [Q Alternative 5 [15A NCAC 02T.1 107(a)(5)] - 14-Day Aerobic Processes. Alternative 6 [15A NCAC 02T.1107(ax6)] - Alkaline Stabilization. Alternative 7 [15A NCAC 02T.1107(a)(7)] - Drying of Stabilized Residuals. Alternative 8 (15A NCAC 02T.I 107(a)(8)] - Drying of Unstabilized Residuals. Q Alternative 9 [15A NCAC 02T.I 107(a)(9)] - Injection. Alternative 10 [15A NCAC 02T.i 107(a)(10)] - Incorporation. Alternative for Surface Disposal Units Only - Soil/Other Material Cover [ 15A NCAC 02T.I 107(b)(2)]. Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution. Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically occur when these residuals are applied and left on the land surface. FORM: RSC 06-16 Page 5 of 5 I E.9494P MUnnlw�l +�,wo � M/i'AOIA�pY O�� �1:f � t _ m a . . v3i NOUMMORWA Mill: - k mom 81 t/ mr w man a" -Mam 11�111 Quantitative Justification The Broad River Water Authority has distributed the following amounts in the last 5 years: Year Dry Tons 2016 0 2017 0 2018 652.21 2019 544 2020 0 This data shows a year average of 239.24 dry tons with a five-year maximum of 652.21 dry tons. The 1,649 Dry tons per year currently permitted will be sufficient to handle the number of residuals the Broad River Water Authority is producing at this time. Broad River Water Authority Permit WQ0035576 WTP SAMPLING PLAN Quarterly, if a distribution event occurs, grab samples are collected from the two sludge lagoons. Samples from the two sludge lagoons will be combined to form individual grab samples to be sent to a laboratory for analysis. These Individual grab samples are collected and tested for fecal coliform analysis, nutrient analysis, and a TCLP test. These tests will be taken by Zach Key of U.S. Biosolids, Inc. All samples will be taken to a state approved laboratory. All samples taken will be taken in the same condition as the residuals are to be land applied. Fecal Coliform is gathered in seven (7) individual samples and tested to meet the requirements of (503.32(b)(2)]. This requirement is for the geometric mean fecal coliform density of the samples be less than one thousand (1,000) MPN per gram. These samples will be placed in 250ml containers and placed on ice, in a cooler for transport to the laboratory before 1600 hours (4pm) the same day the samples are obtained. Quarterly, if land application occurs, 9 composite residual sample will be analyzed, prior to a land application event for: Cadmium, Copper, Lead, Mercury, Molybdenum, Nickel, Selenium, Zinc, Aluminum, Ammonia Nitrogen, Calcium, Nitrate Nitrogen, Magnesium, % total Solids, pH, Phosphorus, Potassium, TKN, Sodium From this information, the Plant Available Nitrogen (PAN) and a Sodium Absorption Ratio (SAR) will be calculated. This sample will be collected in a non -breakable container, at least one quart in size. This sample will be taken from the digester. The toxicity characteristic leaching procedure (TCLP) shall be preformed once per permit cycle of permit W00035576. This sample will be taken in at least 2, one -gallon containers and sent to a state approved laboratory. Laboratory Data Analytical Results ct TAT V's �4 r ALI'T C U.S. Biosolids Inc 958 Hoots Road Roaring River, NC 28669 Receive Date: 06/01/2020 Reported: 06/1712020 For: BRWA Comments: Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200601-15-01 Corrosivity BRWA See Attached Sw-8°6 06/03/2020 PACE 200601-15-01 Ignitability BRWA See Attached 10101d 06/03/2020 PACE 200601-15-M Reactivity BRWA See Attached SW-M6 06103/2020 PACE 200601-15-01 TCLP BRWA See Attached as Wed 06/0312020 PACE Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 * Statesville, NC 28687 - 704/872/4697 Page 1 of 40 Condition of Receipt Sample Number 200601-15-01 Temp on Arrival: 3.0 Parameter Schedule: Reactivity Received on Ice Parameter Schedule: Corrosivity Received on Ice Parameter Schedule: Igniitability Received on Ice Parameter Schedule: TCLP Received on Ice PO Box 228 • Statesville, NC 28687 9 704/872/4697 Page 2 of 40 W, 14.01 Relinquished by: Received by: Relinquished by: Received by: Lab -ID o Time begin_ am, pm Date Time end am, pm Date c4 $LC� Se!llFtli�- J Time begin..........__ am, prn Date...---.J..._1— Time end __. . am, pm Data _!--J VE" IZT,A,T F.'.''It t 1.1.IE ANAL. MAL 0. L 122 bun Sums • RO. Box 2?N 5urcsvitle, NC 2M7 Chain of (.'ustody Record Fwwnm" requested for W WYsis _ Time ?"i i am, Date __�! !� Sampled by: Time E •' ", am�pm�3ate _ .�. 1 Transported by: 2 Time am, prn Date ! / _.. Holding times met - am, r' Time m Date —A /_.J Compliance work: -�-`�-'--�- Non-compliance work: — T lab Comm•nte' 1 Samples Transported On kw hamhs: It 0 , a N 's h C, h a h .a m 00 N u z ai M G7 R • 00 N N X 0 m O a CEAIk?I�JCc�® arsrxaacalauew ANALYTICAL RESULTS Project: USSiosolids-ORwA Pace Project No.: 92479947 Pace Analytical Sarvkss„ LLC 0800 Kincey Ave. Suite100 HuiHerWife. NC 28078 (704W$-9092 Sample: 200601.16 Lab 10: 924YM7001 Collected: 06/01120 09:00 Received: 0610212014:05 Matrix: Solid Results reported on a 'dry weight- basis and are adjusted for percent moisture, sample size and any difudons. Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 81S1A Analytical Method: EPA 8161A Preparation Method: 8161A Leachate MethodVate: 1311; 061100) 20;15 Initial pH: 5.4; Final pH: 5.03 Pecs National - Mt. Jut'iet 2A,5.TP(SiKex) NO mg/L 0.00200 1 06/1212007.11 06i12i2016:24 93-72-1 2,4-D ND mg/L 0.00200 1 0612f2007:ll 06112/2016:24 94.75.7 Surrogates 2.4-DCAA (S) 52.2 % 14.0-158 1 06112120 07:11 06112120 16.24 19719.28-9 8081 TCLP Pesticides RVE Analytical Method: EPA 80818 Preparation Method: EPA 3510C Leachate Method(Date: EPA 1311; 06103/20 15:02 Initial pH:5.W: Final pH: 5 Pace Analytical Services - Charlotte gamma-SHC (Undane) NO ug/L 0.50 1 08MWO 10:08 06111/20 18:38 58.89-9 Chlordane (Technical) ND ug/L 3.0 1 06105MV 10:06 06/11/20 18:38 57.74-9 Endrin NO ug/L 0.50 1 06/0512010:06 06111/2018:38 72.20-8 Heptachtor ND ug1L 0.50 1 0610512010:06 0611112018:38 76-44.8 Heptachlor epoxide ND ug/L 0.50 1 06/0512010:06 06f11/20 18:38 1024-57-3 MelhoxycNor NO ug/L / 10DO 1 0WOSQ010:06 06fl 1120 18:38 72-43-5 Toxaphene ND ugfL 3.0 1 06105/2D 10:06 O6f11/20 18:38 8001-35-2 Surrogates Decachlorobiphenyl(S) 111 % 10A38 1 06105120 10:06 06/11/20 18:38 2051-24-3 Tetrachioro-m-xylene (S) 97 % 1D-110 1 0610512010:06 06f11/201838 877-OM 8082 GCS PCB Analytical Method: EPA 8082A Preparation Method: EPA 35M Pace Analytical Services Charlotte PCB-1016 (Arodor 1016) ND trg/kg 148 1 116103/2011:16 0B/04120 16:54 12674-11-2 PCB-1221 (Aroclor 1221) ND u9/kg 148 1 06/03QQ 11:16 OSKW2016:54 11104-28.2 PCB-1232 (Aroclor 1232) NO u9/k9 148 1 06103/20 11.16 0610412016.,54 11141-16.5 PCB•1242(Arodor 1242) NO ug/kg 148 1 06103M 11:16 06M4120 16:54 53469-21-9 PCB-1248 (Arodor 1248) NO ug/kg 148 1 0610312011:16 06IM20 16:54 12672-29-6 PM1264 (Aroalor 1264) NO u09 148 1 0610312011-16 011M4120 16:54 11097-69.1 PCB-1260 (Arockw 1260) ND . ug/kg 146 1 061D3/20 11:16 06/04/20 16:54 1109"2-5 Surrogates Decachiorobiphenyl(S) 57 - % 10-130 1 06/03/20 11:16 06f04120 16:54 2051-24-3 $082 TCLP PCBs RVE Analytical MedwO; EPA 8082A Preparation Method: EPA 3510C Leachate Method/Date: EPA 1311: 06103/2015:02 Initial pH: 5.68: Final pH: 5 Pace Analytical Services - Charlotte PCe-1016 (Arodor 1016) NO ugk 1000 1 OWM20 10:06 06/09120 23:15 12674.11-2 PCB-1221 (Arodor1221) ND uglL 1000 1 06IM2010:06 0610912023;15 11104.28.2 PCB-1232 (Arodor 1232) NO ug/L 1000 1 06/05/20 10:06 06/09/20 23:15 11141-16.5 PCB-1242 (Arodor 1242) NO ug/L 1000 1 WOW() 10:06 06IM023:15 63469-21-9 PCB-1248 (Arodor 1248) NO ug/L 1000 1 06106/20 10:06 08/09120 23:15 12672.29.6 PCB-1254 (Arodor 1254) ND ug/L 1000 1 06/05f2010:06 06/0912023:15 11097-69.1 PCB-1260 (Arodor 1260) NO ug/L low 1 06105f20 10:06 08/09f2023:15 11098.82-5 Surrogates Decachlorobiphanyl(S) 93 % 10.132 1 06105120 1 D;06 06/09/2023;15 2051-24-3 REPORT OF LABORATORY ANALYSIS This taped Shall not be rentoducee, except in full. Date: 05/1612020 04:48 PM wlmout the wrinsn consent of Pace AnahAcal Services, I.I.C. Page 5 of 37 PO Box 228 a Statesville, NC 28687.704/872/4697 Page 8 of 40 /.. �fi'dCEAna cal ! uafrpalW.an ANALYTICAL RESULTS Project; US Biosolids- BRWA Pace Project No.: 92479947 Pace Anatli goat Sewiaa, LLC 9800KIrrceyAve. Suite 100 HuntersvAe. NC 29078 (704)875-9092 Sample. 200WAS Lab 92479947001 Collected: 0610112009:00 Received: 06M2/2014:05 Matrix: Solid Results reported on I dry weight" basis and are adjusted for percent moisture, sample size and any dNut Ions. Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Lival 6010 MET ICP, TCLP Analytical Method: EPA6010D Preparation Method: EPA 3010A Leachate Method/Date: EPA 1311; 06M412016:18 Initial pH: 5.46; Final pH: 2 Pace Analytical Services - Asheville Arsenic NO M91L 0.050 1 06MW20 07:40 06/09/20 11:16 7440-38.2 Barium 0.53 mg1L 0.25 1 06106QO 07:40 06/09120 11:16 7440-39.3 Cadmium NO MOIL 0.0050 1 06/0WO 07:40 VoMI2011:16 7440-43.9 Chromium NO mglL 0.050 1 06JO6120 07:40 06MMO 11:16 7440-47.3 Lead 0.031 mg/L 0.025 1 06MWO 07:40 0610WM 11:16 7439.92-1 Selenium NO mglL 0.10 1 OWOB/20 07,40 06/09/20 11:16 7782-49.2 Silver NO mglL 0.026 1 06/06120 07:40 06109/2011:16 7440-22-4 7470 Mercury, TCLP Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Oate: EPA 1311; 06/0412016:19 Initial pH: 5.46; Final pH: 2 Pace Analytical Services -Asheville Mercury ND mg/L O.00020 1 O6/08/2010:36 06/08/2017A7 7439.07.6 8270E TCLP RVE Analytical Method: EPA 8270E Preparation Method: EPA 3510C Leachate Mettmd/Date: EPA 1311; 060312015:02 Initial pH: 5.68: Final pH: 5 Pace Analytical Services - Charlotte 1,4-Dichlorobenzene NO ug/L 50.0 1 06105/20 08:57 OSM6/20 16:41 106-46.7 2,4.Diniirotoluene NO ug/L 50.0 1 06M5/20 08:57 06/05/20 16:41 121-14-2 Hexachloro-0-Iwtadiene NO ug/L 50.0 1 06105/2008V 06105/2016:41 87.68.3 Hexachlorollenzene NO -911- 50.0 1 06MW20 08:57 06/05/2016:41 118-74-1 Hexachloroethane NO uw1 50.0 1 06=120 08.57 06MS/2016:41 67-72-1 2-Mathylphend(o-Cresol) NO u9/1- 50.0 1 06/05120 08:57 06105/2016.41 95.46.7 %4-Methylphenol(m&p Cresol) NO ugA- 50.0 1 069W20 08:57 06105/2016:41 15a31-10.4 f4itrobenzene NO ugh. 50.0 1 06AWO 08:57 06I05/2016:41 W95-3 Pentachlorophenol NO ug/L 100 1 06AW2008:57 OBIOS/20 16:41 $74865 Pyridine NO uglL 50.0 1 06105/20 08:57 06/0512016:41 110-86.1 2,4,5-TricNwophenol NO ug/L 50.0 1 06105/20 08:57 06(05/20 16:41 95-95-4 2.4,6-Trichlorophenol NO ug/L 60.0 1 06/05120 06:57 0610512016.41 88.06-2 Surrogates Nitroberhzen"5 (3) 65 % 12-102 1 IDOM 20 08 57 OM512016:41 4165.60-0 2-Ftuorobiphenyl IS) es % 13-107 1 06105/20 00:57 0610512016:41 321-60-8 Terphenyl-04 (S) 112 % 21-132 1 06AWO 08:57 06MSM 16.41 1716-61-0 Phenot-d(l IS) 45 % 10.110 1 06/05120 08:57 06/06/20 16:41 13127-88.3 2-Ruorophenol (S) 59 % 10.110 1 06/1)5120 08:57 06105/2016:41 367-12-4 2,4,6-TribromophenolIS) 83 % 27-108 1 06105/2008:67 06MWO16:41 118-79-6 829W MSV TCLP Analytical Method: EPA 828W Leachate Method/Date: EPA 1311; 06/14/20 12,32 Pace Analytical Services - Charlotte Benzene NO ug/L 100 20 06115M 15:50 71-43-2 2-Butenone (MEK) NO ug/L 200 20 06115/2015:50 78-93-3 Carbon tetrachloride NO ugll. 100 20 06116/2015:50 56-23.5 Chlorobenzene NO ug(L 100 20 06/1S/2O 151.50 108-90.7 Chtordonn NO ug/L 1DO 20 06115I2015:50 67.66-3 REPORT OF LABORATORY ANALYSIS This report Shall not be repraduced. except in full. Date: 05/16/2020 04:48 PM wW=t the wrxten consent of Pace Analytical Services. LLC. Page 6 of 37 PO Box 228 a Statesville, NC 28687 a 704/872/4697 Page 9 of 40 I , mAnalytrae ANALYTICAL RESULTS Project: USSiasolids-BRWA Pace Project No.: 92472947 Pan Analytical Services, LLC MW KinaPy Ave. Suite 100 Hwrter"Re. NC 28078 (704)(175.9092 Sample; 200601.15 Lab 10: 92479947001 Collected: 0610112D 09:00 Received: 0610212014:05 Matrix: Solid Results reported on a 'dry weight' basis and are equated for percent moisture, sample sire and any dilutions. Pars"ters Results Units Report Limit OF Prepared Analyzed CAS No. Qual $2600 MSV TCLP Analytical Method: EPA 8260D Leachate Mettrod/Date: EPA 1311: 06114120 12:32 Pace Analytical Services - Charlotte IA-Diehlorobenzen , ND ugll. 100 20 0611512015:50 106-46-7 1.2-DicNoroelhane ND ug1L 100 20 0611SW16:60 107-06-2 1,1-DicNoroethene ND ug1L 100 20 0611512015:50 75-354 Tetrachlomethene ND ug1L 100 20 0611SM 1510 127-18.4 Trichlaroethene ND uglt 100 20 06115M 15:50 79.01.6 Vinyl chloride ND ug1L 100 20 W15M 15:50 75-01-4 Surrogates 1,2-DirhloroelhanetW (S) 110 % 70-130 20 06M5/2015:50 17060.07.0 Toluene•d8 is) 104 % 67-135 20 06/1512015:50 2037-26.5 4-Bromofluoroberemene (S) 104 % 70-130 20 06/15M 15:50 460-00-4 Percent Moisture Analytical Method; ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture 79.0 % 0.10 1 06/02/20 17.40 1010 Flashp*IKCkmd Cup Analytical Method: EPA 1010A / Pace Analytical Services - Asheville Flashpoint >200 deg F 70.0 1 06/1512013:05 9045 PH Soit Analytical Method: EPA 9046D Pace Analytical Services - Asheville pH at 25 Degrees C 6A Sid. Units 0.10 1 06115/20 13:37 H3 SON Paint Filter Liquid Test Analytical Method: EPA 9095B Pace Analytical Services - Asheville Free Liquids Pass 1.0 1 M12120 18:10 733C S Reactive Cyanide Analytical Method. EPAS014 Preparation Method: SW-846 7.3.3.2 Pace Analytical Services - Greensburg Cyanide, Reactive ND "109 4.6 1 06/04120 16:00 06/05/20 13:24 7348 Reactive Suiede Analytical Method: SM 4500S2F-2011 Preparation Method: SW-846 7.3.4.2 Pace Analytical Services - Greensburg "cle, Reactive ND Mpg 46.3 1 06/04/20 1&00 06104120 18:35 REPORT OF LABORATORY ANALYSIS This repan Shale not be rewoducad. ex W in toil. Date: 06/1612020 04:48 PM without the written consent of Pace AnayU Services. LLC. Page 7 of 37 PO Box 228 a Statesville, NC 28687 a 704/872/4697 Page 10 of 40 Analytical Results '° Southern Soil Builders 3 t' 958 Hoots Road Roaring River, NC 28669 Receive Date: 10/15/2019 Reported: 10/31 /2019 For: BRWA Comments: Sample Number parameter Sample ID Result Unit Method Analyzed Analyst 191015-15-01 Aluminum BRWA 180638 mg/kg SM 3111 0.2011 10/26/2019 MD 191015-15-01 Ammonia Nitrogen BRWA 122.5 mg/kg SM4500NH3SE-1997 10/17/2019 WE 191015-1"1 Arsenic - Solid BRWA 0.67 mg/kg SM3113B-2004 10/28/2019 MT 191015-15-01 Cadmium - Solid BRWA 0.5 mg/kg SM3111B-1999 10/25/2019 MD 191015-15-01 Calcium BRWA 750 mg/kg sw"152011 10/23/2019 MD 191015-15-01 Copper - Solid BRWA 27.94 mg/kg SM31118.2011 10123/2019 MD 191015-15-01 Lead -Solid BRWA 25.16 mg/kg SM31130 10/21/2019 MD 191015-15-01 Magnesium BRWA" 716 mg/kg SM3111B 2011 10/23/2019 MD 191015-15-01 Mercury Solid BRWA 2.062 mg/kg SM31128.2011 10/24/2019 MD 191015-15-01 Molybdenum - Solid BRWA 0.74 mg/kg EPA200-1 10/25/2019 MD 191015-15-01 Nickel - Solid BRWA 10.38 mg/kg SM31138 10/23/2019 MD 191015-15-01 Nitrate/Nitrite - BRWA 203.75 mg/kg SM4500F/A 10/28/2019 CL Solids 191015.15-01 Percent Solids BRWA 32 % SM2WB.2011 10/16/2019 MD 191015-15-01 pH BRWA 6.45 Std. Units 5WWOHe-2011 10/15/2019 CL 191015-15-01 Potassium - Solid BRWA 2480 mg/kg EPA200.7 10/28/2019 MT 191015-15-01 SAR BRWA 1.57 % Calci1a1i0i 10/30/2019 CL 191015-15-01 Selenium Solid BRWA <1.67 mg/kg SM3113B 1012812019 MT 191015-15-01 Sodium - Solid BRWA 443.75 mg/kg sM 31118 10/17/2019 MD 191015-15 01 T. Phosphorus Solid BRWA 406.2 mg/kg SM450OPE-2011 10/21/2019 CL 191015-15-01 TKN BRWA 3640 mg/kg SM4500NW9 8.2011 10/22/2019 CL 191015-15-01 Zinc - Solid BRWA 71.625 mg/kg SM31118.2011 10/23/2019 MD Respectfully submitted, PO Box 228 • Statesville, NC 28697 • 704/872/4697 Page 1 of 9 SAR Sodium Absorption Ratio Na: Sodium (Mg/L) Equivalent weight: 23 Ca: Calcium (Mg/L) Equivalent weight: 20 Mg: Magnesium (Mg/L) Equivalent weight: 12 Milli Equivalent = Mg/L / Equivalent weight Na M /L Ca M /L Mg M /L 142 240 229.1 Na ME Ca (ME) M IN 9167 6.173913 12 SAR= Na Milli Equivaient/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power L SAR = 1.565 662 (From Mg/L entered above) SAR= 1.56�49121(From ME entered below) Na (ME) Ca {ME1 Ma {ME} 6.17 12 1 a.09 i The amour amount of i Permitting PAN Mineralization as decimal Total dry tons/year lAcres Applied on 74 Rate 0.4 TKN 3640 NH3 122.5 NO3 203.75 NO2 0 % Solids 0.32 544 PAN Surface 16721mglkg 3.344 lbs/dry ton 1819.136 lbs total PAN 24.58292 lbs PAN/acre PAN Injection 1733.25 m lk 3.4665 lbs/dry ton 1885.7761 lbs total PAN 20.48346lbs PAN/acre Dq Tons71000 gal. 1.3344 1st year PAN Surface lbs. 1819.136 1st year PAN Injected. lbs. 1885.776 ibs.locre Surface_ 24.58291892 lbsJacre Injected 25.48345946 MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg Mg/kg x .002 =1bs/dry ton MR(TKN-NH3) + l(NH3)+NO3+NO2 =mg/kg Mg/kg x .002 =1bs/dry ton 1000 X 8.34 X %solids X sp. gravity "=dry tons/1000gal." 2000