Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
NCG510532_Monitoring Report_20141222
NPDES DOCUMENT SCANNING; COVER SHEET NPDES Permit: NCG510532 140 West Franklin remediation Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Monitoring Report` ' Instream Assessment (67B) Environmental Assessment (EA) Permit History Document Date: December 22, 2014 This document is printed on reuse paper - %Wore any content on the reezerse side ARG Ammons Resource Group 2040 Peach Grove Lane Zebulon, NC 27597 919-369-5679 fredammons@att.net December 22, 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 RECEIVED JAN 0 6 2015 CENTRAL FILES DWR SECTION Subject: NOVEMBER 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the November 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill, North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Water samples were collected from outfall 001 on November 3, 2014 for the quarterly sampling event as required by the permit. Samples were sent to SGS Environmental Services, Inc. of Wilmington, North Carolina for analysis. Analytical results indicate that all compounds except lead were below the permitted daily maximum limits. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II, of Section D. (2.) of its NPDES Permit. The lead compound that is over the daily maximum limit is indicative of the carbon filter lifespan, and carbon changeout is scheduled to be completed by mid January 2015. A water sample will be collected and analyzed in January after the carbon is replaced to confirm the permit compounds to be below the permitted daily limits. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Resource Group red mmons ORC Enclosures: November 2014 DMR cc: Mr. Scott Milke, 140 West Franklin, LLC Mr. Ernest Odei-larbi, Chapel Hill EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MONTH November YEAR 2014 FACILITY NAME 140 WEST FRANKLIN CLASS NA COUNTY ORANGE CERTIFIED LABORATORY (1) SGS Environmental Services. Inc CERTIFICATION NO. 481 (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE I CERTIFICATION NO. 992126 PERSON(S) COLLECTING SAMPLES Fred Ammons ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE * CHECK BOX IF ORC HAS CHANGED 0 Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 (SIGNAT'�C1RE OFO OPERATOR N RESPONSIBLE CHARGE) BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS CCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. /2-27-1V DATE 0 DATE Operator Arrival Time 2400 Clods Operator Time On Site # c, ,�0 0 aco 0 50050 34030 34371 34010 81551 22417 34696 1 01051 I 00530 00400 32103 03604 00556 FLAW ;40 N sa w ETHYLBENZENE calM .a o TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) a 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EVFY I. INF ❑ DAILY RATE HRS HRS Y/B/N MGD UG/L UG/L UG/L UG/L UG/L UG/L UG/L mg(L UG/L UG/L 1 0.001103 2 0.001103 _ 3 1030 2 yes 0.001103 ND ND ND ND 0.66 ND 47.7 8 7.87 ND 4 4 0.001018 , 5 0.001018 6 0.001018 7 0.001018 8 0.001018 9 , 0.001018 10 0.001018 11 0.001018 12 0.001018 13 1100 2 yes 0.001018 14 0.000587 _ 15 0.000587 16 0.000587 17 0.000587 18 0.000587 19 0.000587 _ 20 0.000587 21 1300 2 yes 0.000587 22 0.000745 23 0.000745 24 0.000745 25 1000 2 yes 0.000745 26 0.000745 27 0.000745 28 0.000745 29 0.000745 30 0.000745 AVERAGE 0.000830 MAXIMUM MINIMUM Comp. (C) / Grab (G) G Daily Maximum 1.19 97 _ 11 670 19 12 25 30 6<pH<9 0.38 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NOT meet permit requirements Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. carbon filter changeout- to be completed by mid January 2015- sample collection and analytical to occur in January 2015 after carbon changeout to confirm daily permit limits "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Scott Milke, 140 West Franklin, LLC Permittee (Please print or type) 2-2'I-i`1 Si �l of Permittee*** Date (Res ired unless submitted electronically) 126 West Franklin Street, Chapel Hill NC 27516 (919) 868-1678 Permittee Address Phone Number e-mail address February 28, 2017 Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wqs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 Laboratory Report of Analysis To: Fred Ammons Ammons Resource Group 2040 Peach Grove Lane Zebulon, NC 27597 Report Number. 31401757 Client Project: 140 West Dear Fred Ammons, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Michael D. Page at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. Digitally signed by: Michael Page DN: CN = Michael Page C = US 0 = SGS North America OU = Environmental Services Date: 2014.11.19 10:13:40 -04'00' Michael D. Page Project Manager michael.page@sgs.com Date Print Date: 11 /19/20 t •, N.C. Certification # 481 This document is issued by the Company under its General Conditions of Service accessible at iiltp://www ses cobweb fTenns-and-Conditions htm. Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein. Any holder of this document is advised that information contained hereon reflects the Company's findings at the time of its intervention only and within the limits of Client's instructions, if any. The Company's sole responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their rights and obligations under the transaction documents. Any unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law. SGS Environmental Services 5500 Business Drive Wilmington, NC 28405 +1 910 350 1903 r +1 866 846 8290 www.egsmm Page 1 of 26 Member o1 the SGS Group (505 SA) Laboratory Qualifiers Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) J Estimated Concentration. E Amount detected is greater than the Upper Calibration Limit TIC Tentatively Identified Compound ND Not Detected P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the anatyst. A code definition is provided below: M1 Mis-identified peak M2 Software did not integrate peak M3 Incorrect baseline construction (i.e. not all of peak included; two peaks integrated as one) M4 Pattem integration required (i.e. DRO, GRO, PCB, Toxaphene and Technical Chlordane) M5 Other - Explained in case narrative Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Print Date 11/19/2014 N C. Certification # 481 Page 2 of 26 Client Sample ID Sample Summary Lab Sample ID Collected Received Matrix Outfall 31401757001 11/03/2014 10:00 11/05/2014 09:56 Water Print Date 1 1 / I9/2014 N C. Certification #481 Page 3 of 26 Case Narrative • Outfall SM4500H - The pH was analyzed outside of the method specified hold time. Print Date_ 1 ut9i2014 N.C. Certification # 481 Page 4 of 26 4, 1/4 Detectable Results Summary Client Sample ID: Outfall Lab Sample ID: 31401757001-G Parameter Result Units SM 4500-H+ B pH pH 7.87 S.U. pH at Temperature 7.8 C SW-846 6010C Lead 0.0477 mg/L SW-846 8260B tert-Butyl methyl ether (MTBE) 0.660 ug/L J Quality Control Samples Client Sample ID: MB for HBN 50726 [MXX/3716] Lab Sample ID: 151424 Parameter Result Units SW-846 6010C Lead 0.00862 mg/L J Print Date. 1 1119;2014 N.C. Certification 4 481 Page 5 of 26 e- Results of Outfall - - - - Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401757001-A Lab Project ID: 31401757 Results by SW-846 8260B Parameter 1,2-Dichloroethane Benzene Ethyl Benzene Naphthalene Toluene Xylene (total) tert-Butyl methyl ether (MTBE) Surrogates 1,2-Dichloroethane-d4 4-Bromofluorobenzene Toluene d8 Batch Information Result ND ND ND ND ND ND 0.660 104 96.0 100 VMS3406 Analytical Method:. SW-846 8260B Instrument: MSD9 Analyst: JHL Print Date: 11/19/2014 Collection Date: 11 /03/2014 10:00 Received Date: 11/05/2014 09:56 Matrix: Water Qual DL LOQ/CL Units DF U 0.119 1.00 ug/L 1 U 0.107 1.00 ug/L 1 U 0.105 1.00 ug/L 1 U 0.111 1.00 ug/L 1 U 0.101 1.00 ug/L 1 U 0.179 2.00 ug/L 1 J 0.145 1.00 ug/L 1 64.0-140 % 1 85.0-115 % 1 82.0-117 % 1 Prep Batch: VXX5300 Prep Method: SW-846 5030E Prep DatelTime: 11/07/2014 15:16 Prep Initial Wt.Nol.: 40 mL Prep Extract Vol: 40 mL Date Analyzed 11/5/2014 19:03 11/5/2014 19:03 11/5/2014 19:03 11/5/2014 19:03 11/5/2014 19:03 11/5/2014 19:03 11/5/2014 19:03 11/5/2014 19:03 11/5/2014 19:03 11/5/2014 19:03 N C. Certification # 481 Page 6 of 26 ,- Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401757001-D Lab Project ID: 31401757 Results by SW-846 6010C Parameter Lead Result 0.0477 Collection Date: 11/03/2014 10:00 Received Date: 11/05/2014 09:56 Matrix: Water Qual DL LOQ/CL Units DF Date Analyzed 0.00794 0.0100 mg/L 1 11/7/2014 16:19 Batch Information Analytical Batch: MIP2632 Prep Batch: MXX3716 Analytical Method SW-846 6010C Prep Method: SW-846 3010A Instrument: ICP1 Prep Date/Time: 11/07/2014 09:07 Analyst: PSW Prep Initial Wt.NoI.: 50 mL Prep Extract Vol: 50 mL Print Date: 11/19/2014 N C. Certification # 481 Page 7 of 26 Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401757001-F Lab Project ID: 31401757 \` Results by SM 2540-D Parameter Total Suspended Solids Batch Information nail:,cal Batch: N03456 Analytical Method, SM 2540-D Instrument: BAL10 Analyst: VML Result ND Qual DL 3.60 Collection Date: 11/03/2014 10:00 Received Date: 11/05/2014 09:56 Matrix: Water LOQ/CL Units DF 25.0 mg/L 1 Prep Batch: IN03456 Prep Method: SM 2540-D Prep Date/Time: 11/06/2014 08:23 Prep Initial Wt.Nol.: 1 mL Prep Extract Vol 1 mL Date Analyzed 11/6/2014 8:23 Print Date: 11/19/2014 N.C. Certification # 481 Page 8 of 26 r Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401757001-G Lab Project ID: 31401757 `Results by SM 4500-H+ B pH Parameter pH pH at Temperature Result Qual DL 7.87 0.0100 0.0100 S.U. 7.8 C Batch Information Analytical Batch: Batch: IN03457 Analytical Method: SM 4500-H+ B pH Instrument: PH1 Analyst: VML Collection Date: 11 /03/2014 10:00 Received Date: 11/05/2014 09:56 Matrix: Water LOQ/CL Units DF 1 1 Prep Batch: IN03457 Prep Method: SM 4500-H+ B pH Prep Date/Time: 11/06/2014 13:40 Prep Initial Wt.Nol.: 1 mL Prep Extract Vol: 1 mL Date Analyzed 11/6/2014 13:40 11/6/2014 13:40 Print Date: 11 /19/2014 N C. Certification # 481 Page 9 of 26 Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401757001-E Lab Project ID: 31401757 Collection Date: 11 /03/2014 10:00 Received Date: 11/05/2014 09:56 Matrix: Water Results by EPA 420.1 (SUB) Parameter Result gkai DL LOQ/CL Units DF Date Analyzed Phenol ND U 0.00400 mg/L 1 11/13/2014 0:00 Laboratory: Envirochem Analytical Date/Ti Ine: 11/13/2014 00:00 Print Date: 11/19/2014 Prep Method: Prep Date/Time N C Certification # 481 ♦ Page 10 of 26 Batch Summary Analytical Method: SW-846 8260E Prep Method: SW-846 5030B Prep Batch: VXX5300 Prep Date: 11/05/2014 10:17 Client Sample ID LCS for HBN 50681 [VXX/5300] LCSD for HBN 50681 [VXX/5300] MB for HBN 50681 [VXX/5300] Soil -Kurt Spill(150871MS) Soil -Kurt Spill(150871 MSD) Outfall Print Date 11/19/2014 Lab Sample ID Analysis Date 151118 11/05/2014 11:14 151119 11/05/2014 11:39 151120 11/05/2014 12:29 151477 11/05/2014 17:49 151478 11/05/2014 18:14 31401757001 11/05/2014 19:03 Analytical Batch Instrument Analyst VMS3406 MSD9 JHL VMS3406 MSD9 JHL VMS3406 MSD9 JHL VMS3406 MSD9 JHL VMS3406 MSD9 JHL VMS3406 MSD9 JHL N C. Certification # 481 Page 11 of 26 "—Method Blank Blank ID: MB for HBN 50681 [VXX/5300) Blank Lab ID: 151120 QC for Samples: 31401757001 Results by SW-846 8260B Parameter tert-Butyl methyl ether (MTBE) Benzene 1,2-Dichloroethane Toluene Ethyl Benzene Xylene (total) Naphthalene Surrogates 1,2-Dichloroethane-d4 Toluene d8 4-Bromofluorobenzene Result ND ND ND ND ND ND ND 104 101 98.0 Batch Information Analytical Batch. VMS3406 Analytical Method: SW-846 8260E Instrument: MSD9 Analyst: JHL DL 0.145 0.107 0.119 0.101 0.105 0.179 0.111 Matrix: Water LOQ/CL Units 1.00 ug/L 1.00 ug/L 1.00 ug/L 1.00 ug/L 1.00 ug/L 2.00 ug/L 1.00 ug/L 64.0-140 82.0-117 85.0-115 0/0 Prep Batch. VXX5300 Prep Method: SW-846 5030B Prep Date/Time: 11/5/2014 10:17:19AM Prep Initial Wt.Nol.: 40 mL Prep Extract Vol: 40 mL DF 1 1 1 1 1 1 1 1 1 1 Print Date 1 1/19/2014 N.C. Certification # 481 Page 12 of 26 Blank Spike Summary Blank Spike ID: LCS for HBN 50681 [VXX/5300] Blank Spike Lab ID: 151118 Date Analyzed: 11/05/2014 11:14 QC for Samples: 31401757001 Results by SW-846 8260E Parameter tert-Butyl methyl ether (MTBE) Benzene 1,2-Dichloroethane Toluene Ethyl Benzene Naphthalene Surrogates 1,2-Dichloroethane-d4 Toluene d8 4-Bromofluorobenzene Batch Information Spike Duplicate ID: LCSD for HBN 50681 [VXX/53001 Spike Duplicate Lab ID: 151119 Date Analyzed: 11/05/2014 11:39 Matrix: Water Blank Spike (ug/L) Spike Result Rec (%) Spike Duplicate (ug/L) Spike Resuit Rec (%) CL RPD (%) RPD CL 5.00 4.48 90 5.00 5.00 4.72 94 5.00 5.00 5.04 101 5.00 5.00 4.66 93 5.00 5.00 4.42 88 5.00 5.00 4.82 96 5.00 Analytical Batch: VMS3406 Analytical Method: SW-846 8260E Instrument: MSD9 Analyst: JHL 107 100 100 4.45 89 47.0-142 0.67 30.00 4.99 100 76.0-124 5.6 30.00 5.23 105 76.0-119 3.7 30.00 4.83 97 75.0-123 3.6 30.00 4.77 95 76.0-123 7.6 30.00 5.01 100 67.0-122 3.9 30.00 104 99 100 64.0-140 82.0-117 85.0-115 Prep Batch: VXX5300 Prep Method: SW-846 5030E Prep Date/Time: 11105f2014 10:17 Spike Init Wt.Nol.: 40 mL Extract Vol: 40 mL Dupe Init Wt.Nol.: 40 mL Extract Vol: 40 mL Print Dale 11/19,2014 N.C. Certification # 481 Page 13 of 26 Batch Summary Analytical Method: SW-846 6010C Client Sample ID MB for HBN 50726 [MXX/3716] LCS for HBN 50726 [MXX/3716] LCSD for HBN 50726 [MXX/3716] Dutfall Outfall(151131MS) Outfall(151131MSD) Outfall(151131DUP) Outfall(151131 DUP) Print Date 11119!2014 Prep Method: SW-846 3010A Prep Batch: MXX3716 Prep Date: 11/07/2014 09:07 Lab Sample ID Analysis Date 151424 11/07/2014 15:53 151425 11/07/2014 15:58 151426 11/07/2014 16:14 31401757001 11/07/2014 16:19 151428 11/07/2014 16:24 151429 11/07/2014 16:29 151427 11/07/2014 16:35 151427 11/07/2014 16:40 Analytical Batch Instrument Analyst MIP2632 MIP2632 MIP2632 MIP2632 MIP2632 MIP2632 MIP2632 MIP2632 ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW N C Certification # 481 Page 14 of 26 me'tnoa plant( Blank ID: MB for HBN 50726 [MXX/3716] Blank Lab ID: 151424 QC for Samples: 31401757001 `---- Results by SW-846 6010C Parameter Lead Result 0.00862 Batch Information Analytical Batch: MIP2632 Analytical Method: SW-846 6010C Instrument: ICP1 Analyst: PSW Qua! J Matrix: Water DL LOQ/CL Units 0.00794 0.0100 mg/L Prep Batch: MXX3716 Prep Method: SW-846 3010A Prep Date/Time: 11/7/2014 9:07:32AM Prep Initial Wt.Nol.: 50 mL Prep Extract Vol: 50 mL DF 1 Print Date: 11/19/2014 N.C. Certification # 481 Page 15 of 26 Blank Spike Summary Blank Spike ID: LCS for HBN 50726 [MXX/3716] Blank Spike Lab ID: 151425 Date Analyzed: 11/07/2014 15:58 QC for Samples: 31401757001 Results by SW-846 6010C Parameter Spike Lead 0.400 Batch Information Analytical Batch: MIP2632 Analytical Method: SW-846 6010C Instrument: ICP1 Analyst: PSW Spike Duplicate ID: LCSD for HBN 50726 [MXX/37161 Spike Duplicate Lab ID: 151426 Date Analyzed: 11/07/2014 16:14 Matrix: Water Blank Spike (mg/L) Spike Duplicate (mg/L) Result Rec % Spike Result Rec (%) CL RPD (%) RPD CL 0.378 94 0.400 0.370 93 80.0-120 2.1 20.00 Prep Batch: MXX3716 Prep Method: SW-846 3010A Prep Date/Time: 11/07/2014 09:07 Spike Init Wt.Nol.: 50 mL Extract Vol: 50 mL Dupe Init Wt.Nol.: 50 mL Extract Vol: 50 mL Pont Date 1 t i9r2fi14 N.C. Certification # 461 Page 16 of 26 e- Matrix Spike Summary Original Sample ID: 31401757001 (Outfall) MS Sample ID: 151428 MSD Sample ID: 151429 QC for Samples: 31401757001 Results by SW-846 6010C Analysis Date: 11/07/2014 16:19 Analysis Date: 11/07/2014 16:24 Analysis Date: 11/07/2014 16:29 Matrix: Water Matrix Spike (mg/L) Spike Duplicate (mg/L) Parameter Sample Spike Result Rec (%), Spike Result Rec (%) CL RPD (%) RPD CL Lead 0.0477 0.400 0.390 86 0.400 0.395 87 75.0-125 1.3 20.00 Batch Information Analytical Batch: M Analytical Method: Instrument: ICP1 Analyst: PSW IP2632 Prep Batch: MXX3716 SW-846 6010C Prep Method: SW-846 3010A Prep Date/Time: 11/07/2014 09:07 MS !nit Wt.Nol.: 50 mL Extract Vol.. 50 mL MSD 'nit Wt./Vol.: 50 mL Extract Vol.: 50 mL Print Date 11/19/2014 N.C. Certification # 481 Page 17 of 26 Duplicate Sample Summary — Original Sample ID: 31401757001-D Duplicate Sample ID: 151427 QC for Samples: 31401757001 Analysis Date: 11/07/2014 16:19 Analysis Date: 11/07/2014 16:35 Matrix: Water `Results by SW-846 6010C PARAMETER Original Original (mq/L) ual Duplicate (mq/L) gJal RPD (%) RPD CL Lead 0.0477 0.0412 15 20.00 Batch Information Analytical Batch: MIP2632 Analytical Method: SW-846 6010C Instrument: ICP1 Analyst: PSW Print Date Prep Batch: MXX3716 Prep Method: SW-846 3010A Prep Date/Time: 11/07/2014 09.07 N.C. Certification # 481 Page 18 of 26 Rafrh Smrmmary Analytical Method: SM 2540-D Client Sample ID MB for HBN 50686 [INO/3456] LCS for HBN 50686 [INO/3456] Outfall Outfall(151131 DUP) Prep Method: SM 2540-D Prep Batch: INO3456 Prep Date: 11/06/2014 08:23 Lab Sample ID Analysis Date 151148 11/06/2014 08:23 151149 11/06/2014 08:23 31401757001 11/06/2014 08:23 151150 11/06/2014 08:24 Analytical Batch Instrument Analyst IN03456 INO3456 INO3456 I NO3456 BAL10 VML BAL10 VML BAL10 VML BAL10 VML Print Date: 11/19/2014 N.C. Certification # 481 Page 19 of 26 - Method Blank Blank ID: MB for HBN 50686 [INO/34561 Blank Lab ID: 151148 QC for Samples: 31401757001 Matrix: Water �- Results by SM 2540-D Parameter Result ual DL LOQ/CL Units DF Total Suspended Solids ND 3.60 25.0 mg/L 1 Batch Information Analytical Batch: INO3456 Prep Batch: INO3456 Analytical Method: SM 2540-D Prep Method: SM 2540-D Instrument: BAL10 Prep Date/Time: 11/6/2014 8:23:57AM Analyst: VML Prep Initial Wt.Nol.: 1 mL Prep Extract Vol: 1 mL Print Date: 11/19/2014 N C. Certification # 481 Page 20 of 26 Blank Spike Summary Blank Spike ID: LCS for HBN 50686 [INO/3456] Blank Spike Lab ID: 151149 Date Analyzed: 11/06/2014 08:23 QC for Samples: 31401757001 Results by SM 2540-D Parameter Matrix: Water Total Suspended So lids Blank Spike (mg/L) Spike Result Rec (%) 500 472 94 CL 80.0-120 Batch Information Analytical Batch: IN03456 Analytical Method`. SM 2540-D Instrument: BAL10 Analyst: VML Print Date: 1 1. 1 °20 • Prep Batch: INO3456 Prep Method: SM 2540-D Prep Date/Time: 11/06/2014 08:23 Spike Init Wt.Nol.: 1 mL Extract Vol: 1 mL Dupe Init Wt.Nol.: Extract Vol: N C. Certification # 481 Page 21 of 26 f Duplicate Sample Summary Original Sample ID: 31401757001-F Duplicate Sample ID: 151150 QC for Samples: 31401757001 Results by SM 2540-D PARAMETER Total Suspended Solids Batch Information Analytical Batch: IN03456 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VML Print Date 11/19/2014 Analysis Date: 11/06/2014 08:23 Analysis Date: 11/06/2014 08:24 Matrix: Water Original (mg/L) ual Duplicate (mq/L) ual RPD (%) RPD CL ND ND 20.00 N C Certification # 481 Page 22 of 26 envirochem ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) 710 Bowsertown Road • Manteo, NC 27954 (252) 473-5702 NCDENR DWQ CEKIIFICATE #94. DLS CERTIFICATE #37729 SGS Environmental Services, Inc. 5500 Business Drive Wilmington NC 28405 Attention: Michael Page Date of Report: Nov 18, 2014 Customer PO #: Customer ID: 08100111 Report #: 201413742 Project ID: 31401757 Lab ID Sample ID: 14-33699 Site: 31401757001 Test Method Collect Date/Time 11/3/2014 10:00 AM Matrix Water Results Sampled by Client Date Analyzed Inorganic Phenols EPA 420.1 <0.004 mg/L 11/13/2014 Comment Reviewed by:IYINJLOLOi O 0I Report it~ 2014-13742 Page 23 of 26 Page 1of1 CHAIN OF CUSTODY I CONVENTIONAL & SHALE PROJECT INFO: (� n PROJECT: 21Lio1 (5 f P.O. #: `j QUOTE #: SITE REF: j TURN AROUND TIME: / 1 q f !C/ REPORT LEVEL: (seo reverse) ❑ Level I ❑ Level II 0 Level IV SPECIAL DELIVERABLES: ❑ EDD: ❑ State of Origin: Other: SEND DOCUMENTATION / RESULTS TO: COMPANY: 56,15 L 611 CONTACT: pjlichao.a. (PrT_ ADDRESS: PHONE: Ci(,o-3So— 190 EMAIL: pm ch „ Q INVOICE TO: (❑CHECK IF SAME) COMPANY: CONTACT; ADDRESS: PHONE: EMAIL: SPECIAL INSTRUCTIONS/COMMENTS: )61_ l37z PRESERVATIVE ANALYSIS & METHOD SAMPLE ID / DESCRIPTION ILI b1c25)31 DATE 14.3j111 TIME lu() QC MS MSD DUP TYPE (C, G) MATRIX L) CONT, CITY 1 Qto REMARKS 33� COLLECTED/RELINQUISHED BYO): RELINQUISHED BY (21: DATE: )J/ U iLj DATE: TIME: TIME: RE ED Y: Page 24 of 26 Page of SGS NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 910 350 1903 1910 794 1613 www.sgs.com Member of the SGS Grauo ISGS SA) w co N U1 SG$ CHAIN OF CUSTODY I CONVENTIONAL & SHALE PROJECT INFO: PROJECT: /'iQ (,d �'$1• P.O. #: QUOTE #: SITE REF: TURN AROUND TIME: Mk f REPORT LEVEL: (see reverse) 0 Level I 0 Level II 0 Level IV SPECIAL DELIVERABLES: ❑ State of Origin: ❑ EDD: ❑ Other. SAMPLE ID / DESCRIPTION 41)T SEND DOCUMENTATION / RESULTS TO: COMPANY: R. � /0L CONTACT: fQ„AwL ADDRESS: ZO � (i P&AC H atove C.A-N Ce, PHONE: Z J(,O i J %i/[, Z75 11 I — 30- 7°) INVOICE TO: ( WrCHECK IF SAME) EMAIL: COMPANY: CONTACT: ADDRESS: PHONE: EMAIL: DATE P4/0 TIME IOW ac MS MSO DL'P TYPE (C. 01 MATRIX thQ CONT. CITY 7 SPECIAL INSTRUCTIONS / COMMENTS: 31'40\159 PRESERVATIVE ANALYSIS & METHOD timigtzep, REMARKS B•G � 1` IAA Dos 1Pxu. A Vtg` N RELINQUISHED BY (1): RELINQUISHED BY (2): DATE: TIME: 10d?b TIME: RECEIVED BY: K. Rojo cote 3850 RECEIVED BY: TiME rr O•:. ;050.4 . ' 1NT P EN .'l *!?'' PE RECEIPT,` • o: Page of _L SOS NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 910 350 19031910 794 1613 www.sga.com Member of the SGS Group ISGS SA) Client: SGS North America Inc. Sample Receipt Checklist (SRC) CIZet/v err_ j1P7jt t Work Order No.: 3i -ion s 1. _Shipped Hand Delivered 2. .. COC Present on Receipt No COC Additional Transmittal Forms 3. Custody Tape on Container No Custody Tape 4. > Samples Intact Samples Broken / Leaking 5. )oChilled on Receipt Actual Temp.(s) in °C: Ambient on Receipt Walk-in on Ice; Coming down to temp. Temperature Blank Present 6. SO Sufficient Sample Submitted Insufficient Sample Submitted 7. Chlorine absent )oHNO3 < 2 HCL < 2 Additional Preservatives verified (see notes) 8. KReceived Within Holding Time Not Received Within Holding Time 9. CNo Discrepancies Noted Discrepancies Noted I NCDENR notified of Discrepancies* 10. 1iNo Headspace present in VOC vials Headspace present in VOC vials >6mm Comments: Notes: Thermometer DM 9.7 (-10J HZ�U�y cam. Inspected and Logged in by: ac—e.A. Date: 11/51/L j *NCDENR must be notified when collection, holding time or preservation requirements are not met. MI_11.9 Page 26 of 26 ARG 2040 Peach Grove Lane Zebulon. NC 27597 919-369-5679 fredammons@att. net November 12. 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 RECEIVED Nov 2 4 2014 CENTRAL FILES DWR SECTION Subject: OCTOBER 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the October 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill. North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as reauired by Part II, of Section D. (2.) of its NPDES Permit. Water samples will be collected and analyzed as required by the permit in November 2013. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Resource Group Fred A f'nrffons ORC Enclosures: October 2014 DMR cc: Mr. Scott Milke, 140 West Franklin, LLC Mr. Ernest Odei-Larbi, Chapel Hill FFLUENT i'DES PERMIT NO. NCG5I0532 DISCHARGE NO. 001 \ION FFI Off'"FOIRER l" AR _UI \(;ILITY NAME 140 WEST FRANKLIN LL,\SS NA COUNTY ORANGE ('ERTIFIED LABORATORY (1) SGS Environmental Services. Inc CERTIFICATION NO. -Mt list additional laboratories on the backside/page 2 of this tbrm ) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE I CERTIFICATION NO. 992126 'ERSON(S) COLLECTING SAMPLES ('IIIECK IlOX IF ORC HAS CHANCED Mail ORIGINAL and ONE COPY to: t rrN: CENTRAL FILES DIVISION OF WATER QUALITY i617 MAIL SERVICE CENTER R,ALEIGH. NC 27699-1617 Fred Ammons 0 ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE (SIGNATFIRE OP RATOR 1k ESPONS1BLE CHARGE) BY THIS SIGN TORE. 1 CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. DATE 0 - i� Operator Arrival Time 2400 aock Operator Thuc On Site ORC On Site? ** 50050 I 34030 34371 34010 1 81551 22417 1 346% 101051 I 00530 , 00400 32103 1 03604 1 00556 FLOW ETIIYLBENLENE TOLUENt TOTAL XYLENES METHYL TERT_BUTYL ETIIER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) ;. 1,2 DICHLOROETIIANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFF)6I 1 INF ❑ 1 �aG 0 V [IRS IIRS Y/B/N NIGH UG/L UG/L UG/L UG/L UG/L UG/L UG/L m /L UG/L UG/L I 0.001502 2 0.001502 3 0.001502 4 0.001502 5 0.001502 . 6 0.001502 7 1200 2 yes 0.001502 8 0.001408 9 0.001408 10 0.001408 11 0.001408 12 0.001408 13 0.001408 14 0.001408 15 0.001408 16 0.001408 17 1000 2 , yes 0.001408 18 0.001716 19 0.001716 4. 20 0.001716 21 1400 2 yes 0.001716 22 0.001283 23 0.001283 24 0.001283 25 0.001283 _ 26 0.001283 27 0.001283 28 1100 2 yes 0.001283 _ 29 0.001283 30 0.001283 31 0.001283 AVERAGE 0.001429 MAXIMUM _ NI INIMUM (bmp. (C') / Grab (G) G Daily Mazimum 1.19 97 _ 11 670 19 12 25 30 6<pH<9 0.38 300 monitor ()WO Form MR-1 (I 1/04) sciiity 1l atus: t f'Iea c cneck one ut the lntlowing) \ II monitoring data and sampling frequencies meet permit requirements inciudint %%eekly averages. if applicable! \II monitoring data and sampling frequencies do NOT meet permit requirements L 'omnliant Ntmcumpliant !'he permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentiaiiti threatens public, health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. •t certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision n accordance with a system designed to assure that qualified personnel properly gather and evaluate the information ,ubmitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information. the information submitted is. to the best of my knowledge and belief, true. accurate. and complete. I am aware that there are significant penalties for submitting false information. including the possibility of lines and imprisonment for knowing violations." Scott Milke. 140 West Franklin. LLC Permittee (Please print or type) Ir_t7-I`f Si etmittee*** Date (Rea � red unless submitted electronically) Permittee Address Phone Number 126 West Franklin Street. Chapel Hill NC 27516 (919) 868-1678 e-mail address Permit Expiration Date February 28.2017 Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. `* ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. * ** Signature of Pe ittee: If signed by other than the permittee, then the delegation of the signatory authority must be on lile with the state per I5A NCAC 2B .0506(b)(2)(D). Page 2 ARG Ammons Resource Group 2040 Peach Grove Lane Zebulon. NC 27597 919-369-5679 fredammons©att. net October 24. 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 RECEIVED OCT 31 2014 CENTRAL FILES OwR SECTION Subject: SEPTEMBER 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the September 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill. North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Water samples will be collected from outfall 001 during November 2014 for the quarterly sampling event as required by the permit. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II, of Section D. (2.) of its NPDES Permit. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Resource Group (Fred Ammons ORC Enclosures: September 2014 DMR cc: Mr. Scott Milke, 140 West Franklin, LLC Mr. Ernest Odei-Larbi, Chapel Hill 1. EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MONTH SEPT YEAR 2014 FACILITY NAME 140 WEST FRANKLIN CLASS NA COUNTY ORANGE CERTIFIED LABORATORY (1) SGS Environmental Services. Inc CERTIFICATION NO. 481 (list additional laboratories Qn the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE I CERTIFICATION NO. 992126 PERSON(S) COLLECTING SAMPLES Fred Ammons ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE * II CHECK BOX IF ORC HAS CHANGED Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 0 Ix (SIGNATU ' " Oh OPERATOR RESPONSIBLE CHARGE) BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. A,'• zV l7 DATE DATE Operator Arrival Time 2400 aock E rzR. a a �O O ORC On Site? ** 50050 134030 34371 34010 81551 22417 34696 01051 00530 00400 32103 03604 00556 FLOW w w z A° ETHYLBENZENE wa W C E■ TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) tn. 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFFAGI INF ❑ DAILY RATE HRS HRS Y/B/N MGD UG/L UG/L UG/L UG/L UG/L UG/L UG/L mg/L UG/L UG/L 1 0.002308 2 0.002308 . 3 0.002308 4 1600 2 yes 0.002308 5 0.001334 6 0.001334 7 0.001334 8 0.001334 9 0.001334 10 0.001334 11 0.001334 12 0.001334 13 0.001334 14 0.001334 15 1200 2 yes 0.001334 16 0.002015 17 0.002015 18 0.002015 19 0.002015 20 0.002015 21 0.002015 22 1200 2 yes 0.002015 23 0.001554 24 0.001554 25 0.001554 26 0.001554 27 0.001554 28 0.001554 29 0.001554 30 1300 2.00 yes 0.001554 AVERAGE 0.001681 MAXIMUM MINIMUM Comp. (C) I Grab (G) G Daily Maximum 1.19 97 11 670 19 12 25 30 _6<pH<9 0.38 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) :all monitorin<_ data and sampling frequencies do NOT meet permit requirements x Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "'certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.' Scott Milke. 140 West Franklin, LLC Permittee (Please print or type) %0- 27-/q Sienaermittee*** Date (Required unless submitted electronically) l26 West Franklin Street. Chapel Hill NC 27516 (919) 868-1678 February 28, 2017 Permittee Address Phone Number e-mail address Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES F PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wcis and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 ARG 2040 Peach Grove Lane Zebuton, NC 27597 919-369-5679 fredammons@att. net October 24.2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Subject SEPTEMBER 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Discharge Monitoring Report for the 140 West Franklin site on Attached is the September 2014 g 9 Franklin Street in Chapel Hill. North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Water samples will be collected from outfall 001 during November 2014 for the quarterly sampling event as required by the permit Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part I1, of Section D. (2.) of its NPDES Permit If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Resource Group • mans ORC Enclosures: September 2014 DMR cc: Mr. Scott Milke, 140 West Franklin, LLC Mr. Emest Odei-Larbi, Chapel Hill EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MONTH SEPT FACILITY NAME 140 WEST FRANKLIN CLASS NA COUNTY ORANGE CERTIFIED LABORATORY (1) SGS Environmental Services. Inc CERTIFICATION NO. 48 i (list additional laboratories on the backside/page 2 of this form OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE I CERTIFICATION NO. 992126 PERSON(S) COLLECTING SAMPLES Fred Ammons ORC PHONE (919)369-5679 --�� CHECK BOX IF ORC HAS CHANGED 7 NO FLOW / DISCHARGE FROM SITE * 4--I Mail ORIGINAL and ONE COPY to: ATFN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 SIGNATUR OF PERATO ' 1 RESPONSIBLE CHARGE) THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS CCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE YEAR 2014 /t-2$ lf� DATE 0 - 1a 1 : x .r a t y CI$ 0 o 0 L S o.y o - 50050 34030 34371 34010 81551 22417 34696 1 01051 1 00530 1 00400 32103 1 ossoas 1 00536 FLOW zZ DI z W w N m w UP Z pa ? cn W IA ..I x F a W a'I m Ey E• fg X FIX =" 2 NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) x.e I11,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE s EFFJ� ` RYF D - co 0 oa HRS HRS Y/BIN MGD UG/L UG/L UG/L UG/L UG/L UG/L ' UG/L mgJL UG/i' 1iwL 1 0.002308 , , 2 0.002308 _ 3 0.002308 4 1600 2 yes 0.002308 _ . 5 0.001334 _ , 6 0.001334 7 , 0.001334 , . 8 0.001334 _ 9 0.001334 . 10 0.001334 11 0.001334 _ 12 0.001334 , 13 0.001334 , 14 0.001334 , 15 1200 2 yes 0.001334 16 0.002015 _ 17 0.002015 - 18 0.002015 , 19 0.002015 20 ' 0.002015 - - 21 0.002015 . . 22 1200 2 yes _ 0.002015 _ 23 0.001554 24 _ 0.001554 25 0.001554 , 26 0.001554 , . 27 0.001554 28 0.001554 29 , 0.001554 , 30 1300 2.00 yes 0.001554 AVERAGE 0.001681 , MAXIMUM I MINIMUM 1 _ , - Comp. (C) / Crab (C) I G Dal Marimum 1.19 97 11 670 19 12 25 30 6<pH(9 038 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NOT meet permit requirements x Compliant Noncomoliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentials threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. 1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.' Scott Mllke. 140 West Franklin.. LLC Permittee (Please print or type) D - 27-/ 4 Signatuermittee*** Date (Required unless submitted electronically) 126 West Franklin Street. Chapel Hill NC 27516 (919) 868-1678 Permittee Address Phone Number e-mail address February 28, 2017 Permit Expiration Date ADDITIONAL CERTIFIED LABORATORIES Certified Laboratory (2) Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.statenc.us/wqs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result. there are no data to b entered for ail of the parameters on the DMR for the entire monitoring periiod. ORC On Site?: ORC must visit facility and document visitation of facility as required per 1SA NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(bx2)(D i. Page 2 ARG Ammons kesource Group 2040 Peach Grove Lane Zebulon. NC 27597 919-369-5679 fredammons@att.net September 28. 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh. North Carolina 27699-161- RECEIVED ilrj 0 1 2014 CENTRAL FILES (MR SECTION Subject: AUGUST 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the August 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill. North Carolina. This work was conducted under NPDES Permr No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Nater samples were collected from outfall 001 on August 29, 2014 for the quarterly sampling event as reauired by the permit. Samples were sent to SGS Environmental Services, Inc. of Wilmington. North Carolina for analysis. Analytical results indicate that compounds were below the permitted daily maximum limits. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II. of Section D. (2.) of its NPDES Permit. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerer Ammons Resoj.i ce Group Fred ORC mons Enclosures: August 2014 DMR cc: Mr. Scott Milke. 140 West Franklin, LLC Mr. Ernest Odei-Larbi. Town of Chapel Hill EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MONTH August YEAR 2014 FACILITY NAME 140 WEST FRANKLIN CERTIFIED LABORATORY (1) SGS Environmental Services. Inc CERTIFICATION NO. 481_ (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE I CERTIFICATION NO. 992126 PERSON(S) COLLECTING SAMPLES Fred Ammons ORC PHONE (919) 369-5679 C] NO FLOW / DISCHARGE FROM SITE CLASS NA COUNTY ORANGE CHECK BOX IF ORC HAS CHANGED Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH. NC 27699-1617 ISIGNZE 0' RAT R INRESPONSIBLE CHARGE) BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. 9-28-/Y DATE 0 DATE I Operator Arrival Time 2400 Clock ,1 o w gO O ORC On Site? ** 50050 34030 343711 34010 81551 22417 34696 01051 00530 1 00400 32103 03604 00556 FLOW BENZENE ETHYLBENZENE TOLUENg TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) o. 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFFIE] INF ❑I 2 O HRS HRS Y/B/N MGD UG/L UG/L UG/L UG/L UG/L UG/L UG/L mg/L UG/L UG/L 1 0.002217 2 0.002217 3 0.002217 4 0.002217 5 1400 2 yes 0.002217 6 0.000859 7 0.000859 8 0.000859 9 0.000859 10 0.000859 11, 715 2 yes 0.000859 12 0.003598 13 0.003598 14 0.003598 15 0.003598 16 0.003598 17 0.003598 , 18 2100 2 yes 0.003598 19 0.001991 20 0.001991 21 0.001991 22 ' 0.001991 23 0.001991 24 0.001991 25 1300 2 yes 0.001991 26 0.002038 27 0.002038 28 0.002038 29 1400 2 yes 0.002038 BQL BQL BQL BQL 0.53 BQL BQL BQL 7.93 BQL 6.00 NS 30 0.002038 31 0.002038 AVERAGE 0.002180 MAXIMUM l MINIMUM Comp. (C) / Grab (G) G Daily Maximum 1.19 97 11 670 19 12 25 30 6<pH<9 0.38 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NOT meet permit requirements Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentiate; threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the petmlttee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. -� certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.'" Scott Milke. 140 West Franklin, LLC Permittee (Please print or type) Si 9-30 -1 e r ** Date (R:.. ' r unless submitted electronically ) I26 West Franklin Street. Chapel Hill NC 27516 (919) 868-1678 Permittee Address Phone Number e-mail address February 28, 2017 Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 28 .0506(b)(2)(Dh. Page 2 Laboratory Report of Analysis To: Fred Ammons Ammons Resource Group 2040 Peach Grove Lane Zebulon. NC 27597 Report Number: 31401359 Client Project: 140 West Dear Fred Ammons. Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Melissa Lyles at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We Zook forward to working with you again on any additional analytical needs. Sincerely. SGS North America Inc. i Digitally signed by: Melissa Lyles Date: 2014.09.17 11:13:54 -04'00' Melissa Lyles Project Manager melissa.lyles@sgs.com Print Date: 09/17/2014 Terms and Condition_. Date All services are rendered in accordance with the applicable SGS General Conditions of Service accessibie via http:l/www.sgs.com/terms and conditions.htm W C. Certification 4 481 SGS Environmental Services 5500 Business Drive 1Mlmington. NC 28405 +1 910.350 1903 1 +1 886 840 8290 wwH.sgs.com Member of the SGS Group (SOS SA) Page 1 of 24 Laboratory Qualifiers Report Definitions DL Method. Instrument. or Estimated Detection Limit Der Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) J Estimated Concentration. E Amount detected is greater than the Upper Calibration Limit TIC Tentatively Identified Compound ND Not Detected P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak M2 Software did not integrate peak M3 Incorrect baseline construction (i.e. not all of peak included; two peaks integrated as one) M4 Pattern integration required (i.e. DRO, GRO, PCB, Toxaphene and Technical Chlordane) M5 Other - Explained in case narrative Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Print Date' 09/17i20' N C Certification # 481 Page 2 of 24 Samoie Summary Client Sample ID Lab Samole ID Collected Received Matrix Outfall 31401359001 08/29/2014 16:00 09/03/2014 10:42 Water Print Date 09/17/2014 N.C. Certification # 481 Pace 3 of 24 Case Narrative Because samples were received 7 days after collection, pH was analyzed outside method specified hold time. Print Date _;t,._61 N.C. Certification # 481 1 Paae 4 of 2 Detectable Results Summary Client Sample ID: Outfall Lab Sample ID: 31401359001-E Parameter Result Units EPA 420.1 (SUB) Phenol 0.006 mg/L SM 4500-H+ B pH pH 7.93 S.U. pH at Temperature 16.4 C SW-846 8260B tert-Butyl methyl ether (MTBE) 0.530 ug/L J Pnnt Date: 09/17/2014 N C Certification # 481 Page 5 of 24 r Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401359001-A Lab Project ID: 31401359 Results by SW-846 8260B Parameter 1.2-Dichloroethane Benzene Ethyl Benzene Naphthalene Toluene Xylene (total) tert-Butyl methyl ether (MTBE) Surrogates 1.2-Dichloroethane-d4 4-Bromofluorobenzene Toluene d8 Result ND ND ND ND ND ND 0.530 105 105 103 Batch Information Analytical Batch: VMS3347 Analytical Method: SW-846 82608 Instrument: MSD4 Analyst: JHL Print Date 09/17/2014 Qual Collection Date: 08/29/2014 16:00 Received Date: 09/03/2014 10:42 Matrix: Water DL LOQ/CL Units DF U 0.0880 1.00 ug/L 1 U 0.132 1.00 ua/L 1 U 0.0656 1.00 ug/L 1 U 0.112 1.00 ug/L 1 U 0.0660 1.00 ug/L 1 U 0.200 2.00 ug/L 1 J 0.0600 1.00 ug/L 1 64.0-140 % 1 85.0-115 % 1 82.0-117 % 1 Prep Batch. VXX5207 Prep Method: SW-846 5030B Prep Date/Time 09/04/2014 12:00 Prep Initial Wt.Nol.. 40 mL Prep Extract Vol: 40 mL Date Analyzed 09/4/2014 17:49 09/4/2014 17:49 09/4/2014 17:49 09/4/2014 17:49 09/4/2014 17:49 09/4/2014 17:49 09/4/2014 17:49 09/4/2014 17:49 09/4/2014 17:49 09/4/2014 17:49 N.C. Certification 4 481 Page 6 of 24 Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401359001-D Lab Project ID: 31401359 Results by SW-846 6010C Parameter Lead Result ND Batch Information Analytical Batch: MIP2522 Analytical Method: SW-846 6010C Instrument: ICP1 Analyst: PSW Print Date 09/17/2014 Qual DL U 0.00794 Collection Date: 08/29/2014 16:00 Received Date: 09/03/2014 10:42 Matrix: Water LOQ/CL Units DF 0.0100 ma/L 1 Prep Batch: MXX3566 Prep Method: SW-846 3010A Prep Date/Time: 09/04/2014 08:28 Prep Initial Wt.Nol.: 50 mL Prep Extract Vol: 50 mL Date Analyzed 09/4/2014 18:06 N,C Certification # 481 Paae 7 of 2-. Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401359001-F Lab Proiect ID: 31401359 Results by SM 2540-D Parameter Total Suspended Solids Batch Information A..nai,yticai Batch 1 Analytical Method: Instrument: BAL1i Analyst: VML Print Dale 09/17/2014 Result ND Qual DL 3.60 Collection Date: 08/29/2014 16:00 Received Date: 09/03/2014 10:42 Matrix: Water LOQ/CL Units DF 25.0 ma/L 1 Date Analyzed 09/3/2014 12:54 N03315 SM 2540-D Prep Batch: IN03315 Prep Method: SM 2540-0 Prep Date/Time: 09'03/2014 12:54 Prep Initial Wt.Nol.: 1 mL Prep Extract Vol: 1 mL N C. Certification # 481 Page 8 of 24 Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401359001-F Lab Project ID: 31401359 Collection Date: 08/29/2014 16:00 Received Date: 09/03/2014 10:42 Matrix: Water ''- Results by SM 4500-H+ B pH Parameter Result Qual DL LOQ/CL Units DF Date Analyzed DH 7.93 0.0100 0.0100 S.U. 1 09/9/2014 13:38 pH at Temperature 16.4 C 1 09/9/2014 13:38 Batch Information Analytical Batch: I0,103329 Analytical Method: SM 4500-H+ B pH Instrument_ PH1 Analyst VML Print Date 09/17/2014 Prep Batch: IN03329 Prep Method: SM 4500-H+ B pH Prep Date/Time: 09/09/2014 13:38 Prep Initial WI.Nol 1 mL Prep Extract Vol: 1 mL N C Certification # 481 Paw 9of24 Results of Outfall Client Sample ID: Outfall Client Project ID: 140 West Lab Sample ID: 31401359001-E Lab Project ID: 31401359 Collection Date: 08/29/2014 16:00 Received Date: 09/03/2014 10:42 Matrix: Water Results by EPA 420.1 (SUB) Parameter Result Qual DL LOQ/CL Units DF Phenol 0.006 mo/L 1 ;_a;;;r i:o: EC Analytical Date/Time 09/17/2014 10:51 Print Date: 09/17/2014 Prep Method Prep Date/Time Date Analyzed 09/17/2014 10:51 N.C. Certification # 481 Page 10 of 24 sGt Batch Summary Analytical Method: SW-846 8260E Prep Method: SW-846 5030E Prep Batch: VXX5207 Prep Date: 09/04/2014 09:58 Client Sample ID LCS for HBN 47294 [VXX/5207] LCSD for HBN 47294 [VXX/52071 MB for HBN 47294 [VXX/52071 Outfall 279508(144766MS) 279508(144766MSD) Print Date: 09/17/2014 Lab Sample ID Analysis Date 145184 09/04/2014 10:58 145185 09/04/2014 11:25 145186 09/04/2014 12:20 31401359001 09/04/2014 17:49 145207 09/04/2014 20:05 145208 09/04/2014 20:32 Analytical Batch Instrument Analyst VMS3347 MSD4 JHL VMS3347 MSD4 JHL VMS3347 MSD4 JHL VMS3347 MSD4 JHL VMS3347 MSD4 JHL VMS3347 MSD4 JHL N.C. Certification # 481 Paae 11 of 24 r Method Blank Blank ID: MB for HBN 47294 IVXX/52071 Blank Lab ID: 145186 QC for Samples: 31401359101 Results by SW-846 8260E Parameter tert-Butyl methyl ether (MTBE) Benzene 1.2-Dichloroethane Toluene Ethyl Benzene Xylene (total) Naphthalene Surrogates 1.2-Dichloroethane-d4 Toluene d8 4-Bromofluorobenzene Batch Information Result ND ND ND ND ND ND ND 106 103 103 Analytical Batch VMS;3:34i Analytical Method: SW-846 8260E Instrument: MSD4 Analyst: JHL Print Date: 09/17/201 Matrix: Water Qual DL LOQ/CL Units 0.0600 1.00 ualL 0.132 1.00 ug/L 0.0880 1.00 ug/L 0.0660 1.00 ug/L 0.0656 1.00 ua/L 0.200 2.00 ug/L 0.112 1.00 ug/L 64.0-140 82.0-117 85.0-115 Prep Batch VXX5207 Prep Method: SW-846 5030E Prep Date/Time. 9/4/2014 9:58:36AM Prep Initial Wt.Nol.: 40 mL Prep Extract Vol. 40 mL DF 1 1 1 1 1 1 1 1 1 1 N.C. Certification # 481 'aae 12 of 24 Blank Spike Summary Blank Soike ID: LCS for HBN 47294 NXX/5207] Blank Soike Lab ID: 145184 Date Analyzed: 09/04/2014 10:58 QC for Samples: 31401359001 Results by SW-846 8260B Parameter ♦ Spike Duplicate ID: LCSD for HBN 47294 (VXX/5207] Spike Duplicate Lab ID: 145185 Date Analyzed: 09/04/2014 11:25 Matrix: Water tert-Butyl methyl ether (MTBE) Benzene 1.2-Dichloroethane Toluene Ethyl Benzene Naphthalene Surrogates 1.2-Dichloroethane-d4 Toluene d8 4-Bromofluorobenzene Blank Spike (ug/L) Spike Duplicate (ug/L) ke Result Rec (%) coike Result Rec (%) CL RPD (%) RPD CL 5.00 5.29 106 5.00 5.03 101 47.0-142 5.0 30.00 5.00 5.00 100 5.00 4.85 97 76.0-124 3.0 30.00 5.00 5.29 106 5.00 5.08 102 76.0-119 4.1 30.00 5.00 4.99 100 5.00 4.81 96 75.0-123 3.7 30.00 5.00 4.53 91 5.00 4.25 85 76.0-123 6.4 30.00 5.00 4.54 91 5.00 4.21 84 67.0-122 7.5 30.00 104 106 64.0-140 103 103 82.0-117 102 103 85.0-115 Batch lnformatior Analytical Batch: IVMS3347 Analytical Method SW-846 8260E Instrument: MSD4 Analyst: JHL Print Date 09/17/2014 Prep Batch: VXX5207 Prep Method: SW-846 5030E Prep Date/Time: 09/04/2014 09:58 Spike Init Wt.Nol.: 40 mL Extract Vol: 40 mL Dupe Init Wt.Nol.: 40 mL Extract Vol: 40 mL N.0 Certification # 481 aae '13 of 24 Batch Summary Analytical Method: SW-846 6010C Client Sample ID MB for HBN 47287 [MXX/35661 LCS for HBN 47287 EMXX/3566) LCSD for HBN 47287 f MXX/3566] Outfall MB-F1 for HBN 47287 )MXX/3566) SW Inlet(145087MS) SW Inlet(145087MSD) SW Inlet (Dissol...(145092DUP) SW Inlet (Dissol...(145092DIJP) Print Date: 09/17/2014 Prep Method: SW-846 3010A Prep Batch: MXX3566 Prep Date: 09/04/2014 08:28 Lab Sample ID Analysis Date 145148 09/04/2014 16:52 145149 09/04/2014 16:57 145150 09/04/2014 17:03 31401359001 09/04/2014 18:06 145166 09/05/2014 11:07 145151 09/05/2014 11:28 145152 09/05/2014 11:32 145153 09/05/2014 11:41 145153 09/05/2014 12:10 Analytical Batch Instrument Analyst MIP2522 MIP2522 MIP2522 MIP2522 MIP2523 MIP2523 MIP2523 MIP2523 MIP2523 ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW N.C. Certification # 481 Pape 14 of 24 r Method Blank Blank ID: MB for HBN 47287 EMXX/35661 Blank Lab ID: 145148 QC for Samples: 31401359001 `Results by SW-846 6010C Parameter Result Lead ND Batch Information Analytical Batch: IMIP2522 Analytical Method: SW-846 6010C Instrument: ICP1 Analyst: PSW Print Date: 09/17/2014 Qual U Matrix: Water DL 0.00794 LOQ/CL Units 0.0100 ma/L Prep Batch: MXX3566 Prep Method: SW-846 3010A Prep Date/Time: 9/4/2014 8:28:54AM Prep Initial Wt.Nol.: 50 mL Prep Extract Vol: 50 mL DF 1 N.0 Certification # 481 :;=aae 15 of 24 Method Blank Blank ID: MB-F1 for HBN 47287 1MXX/35661 Blank Lab ID: 145166 QC for Samples: 31401359001 `Results by SW-846 6010C Parameter Lead Batch Information Result ND Analytical Batch: MIP2523 Analytical Method: SW-846 6010C Instrument: ICP1 Analyst: PSW Print Date 09/17/2014 Qual U Matrix: Water DL LOQ/CL Units 0.00794 0.0100 ma/L Prep Batch: MXX3566 Prep Method: SW-846 3010A Prep Date/Time: 9/4/2014 8:56:59AM Prep Initial Wt.Nol.: 50 mL Prep Extract Vol. 50 mL I DF 1 N C. Certification # 481 aqe 16 of 24 Blank Spike Summary Blank Spike ID: LCS for HBN 47287 [MXX/3566] Blank Spike Lab ID: 145149 Date Analyzed: 09/04/2014 16:57 QC for Samples: 11401359001 Results by SW-846 6010C Parameter Spike Blank Spike (mg/L) Spike Duplicate ID: LCSD for HBN 47287 [MXX/3566] Spike Duplicate Lab ID: 145150 Date Analyzed: 09/04/2014 17:03 Matrix: Water Spike Duplicate (mg/L) Result Rec (%) S ike Result Rec (%) CL RPD (%) RPD CL Lead 0.400 0.377 94 Batch Information Analytical Batch: MIP2522 Analytical Method, SW-846 6010C Instrument: ICP1 Analyst: PSW Print Date 09111;2014 0.400 0.373 93 80.0-120 1.1 20.00 Prep Batch: MXX3566 Prep Method: SW-846 3010A Prep Date/Time: 09/04/2014 08:28 Spike !nit Wt.Nol.: 50 mL Extract Vol: 50 mL Dupe !nit Wt.Nol. 50 mL Extract Vol. 50 mL N.0 Certification # 481 =aae 17 of 24 Batch Summary [AnalTcalMethod: SM 2540-D Prep Method: SM 2540-D Prep Batch: IN03315 Prep Date: 09/03/2014 12:54 Client Sample ID Lab Sample ID Analysis Date MB for HBN 47271 fINO/3315] LCS for HBN 47271 [INO/3315] Ht-H20 DG1 GDE 1...(145055DUP) Outfall Print Date: 09/17/2014 145079 09/03/2014 12:54 145080 09/03/2014 12:54 145081 09/03/2014 12:54 31401359001 09/03/2014 12:54 Analytical Batch Instrument Analyst IN03315 IN03315 IN03315 IN03315 BAL10 VML BAL10 VML BAL10 VML BAL10 VML N.C- Certification # 481 Paae 18 of 2= Method Blank Blank ID: MB for HBN 47271 IINO/33151 Blank Lab ID: 145079 QC for Samples: 31401359001 Results by SM 2540-D Parameter Total Suspended Solids Batch Information Resutt ND Qual Matrix: Water DL 3.60 LOQ/CL 25.0 Units ma/L DF 1 Analytical Batch: IN03315 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VML Print Date 09/17/2014 Prep Batch: INO3315 Prep Method: SM 2540-D Prep Date/Time: 9/3/2014 12:54:45PM Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 n1L N.0 Certification # 481 ?age 19 of 24 Blank Soike Summary Blank Soike ID: LCS for HBN 47271 FIN0/3315) Blank Spike Lab ID: 145080 Date Analyzed: 09/03/2014 12:54 QC for Samples: 31 401359001 Matrix: Water Results by SM 2540-0 Parameter Total Susoended Solids Batch Information Analytical Batch: IN03315 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VML Print Date 09r17/201a Blank Spike (mg/L) So:e Result Rec (% 500 456 91 CL 80.0-120 Prep Batch: IN03315 Prep Method: SM 2540-D Prep Date/Time: 09/03/2014 12:54 Spike Init Wt.Nol.: 1 mL Extract Vol: 1 mL Dupe Init Wt.Nol.. Extract Vol: N C Certification # 481 =aoe 20 of 24 Batch Summary Analytical Method: Client Sample ID SM 4500-H+ B pH Prep Method: SM 4500-H+ B pH Prep Batch: IN03329 Prep Date: 09/09/2014 13:38 Lab Sample ID Analysis Date Analytical Batch Instrument Analyst Outfall 31401359001 09/09/2014 13:38 IN03329 PH1 VML Print Date. 09/17/2014 N.C. Certification # 481 Pape 21 of 24 r- Batch Summary Analytical Method: Client Sample ID Outfall EPA 420.1 (SUB) Lab Sample ID Prep Method: Prep Batch: EC Prep Date: Analysis Date Analytical Batch Instrument Analyst 31401359001 09/17/2014 10:51 EC AGD N C Certification # 481 Page 22 of 24 CHAIN OF CUSTODY SOS ANALYTICAL PERSPECTIVES 5500 Business Drive Wilmington, NC 28405 +1910 3501903 WWWIS05ROM mom Aw &®ti s R Soo&CC, G�.OIJP SOS Reference II: l � �G- 3 �':'i 013J 1 PAGE �j, CONTACT; t; "tS� AN* Bpi s ?NaraHI/II Qi ) 3621 J��o7� • C rrna OF PROJECT: � C' d''(`� /—gel PWSID/WA9P: REPORTS TO: EMAIL: 0 W T A N EOAAB1� Da COMP Os Anna t\ , v 'v•4t4i/,YniiYt�y!;`'RElMARKS 4' , `qui ti1NVOICETO: . 1/(///// OUOTEII 0 Al 1 Ge' P.O. NUMBER 11 SAMPLE IDENTIFICATION DATE TIME MATRDI .:.:.._ ehir Gc.. Rom' f /(ACC the 'r 6 .--. •_-- A E •,CA .R tom' �' ,rv, . ��.'d� rA • , • /4444 CakillIA day 7 lte O \\ +�tis�i4KI..•• ..li , I . - , CO SHED BY: 11) DATE TIME 1 RECEIVED BY: Few ,."" REPORT LEVEL: REDUESTED TURNAROUND TIME' e_..• 00361Otani I Morel 11 0 Lewl Iv0 Rush: 4�teedard R'elint hal By: t2I Oats Ur* Received By: SPECIALOEUVERABLES; State of Origin; 0 Trust Fund 0 OoD 0 Epp; Other: Relinquished By: (3) Data Time Received By: 1 SPECIALINSTRUCUONS: B •:. • • 1 . .• , M, eCehiadY Y • '•..i>•,..,.; t,i,• il. ,.1 kl�t. :. i `�' ' � ". Date tat ,. �', ; � I� 1�'� If: , :.:I Time .4• ,. •l. ' . .. �-,.71 CoC $et3l: INTACT. i 8 OkEN • ENT � t �.� ••"ii•':;.1...LI :}'b CP SulnplaA�elAtT��nPCG •` h •' . 1 ♦, -' shi n Carrier;; , •� •,•,, ,• ppi' ,: ; : :t.,,} '' • ; h:.::. ; :t: •,: • supine Ticket No: , E , •; ::. •+ • �. �; Note:c: ' �•,,.;;',,. .,••;;,. E:.;. t'•; :� ., J r. ;••t, 11•• •� i i. • , ," i, ,.. ,� , + , 1 ,�.1, tii `,• ` r< •t..., -.... .•••,'•t . ..... .. '.::.,' -rat?.:.: , . � :1 •. .... . ♦ .. - ........ SGS•00055106VIZ1 ANALYTICAL PERSPECTIVES IS NOW PART OF SGS, THE WORLD'S LEADING INSPECTION. VERIFICATION.TESTING AND CERTIFICATION COMPANY Mts. R.tsintd by tab Y�llaw• iiataloadby t$..'t Page 23 of 24 SGS North America Inc. Sample Receipt Checklist (SRC) Client Ammons Resource Group Work Order No.: 31401359 1. X Shipped Notes: Hand Delivered 2. X' COC Present on Receipt No COC Additional Transmittal Forms 3. Custody Tape on Container X I No Custody Tape 4. X Samples Intact Samples Broken / Leaking 5. X Chilled on Receipt Actual Temp.(s) in °C: 5.0 Thermometer ID#: 98465 Ambient on Receipt Walk-in on Ice; Coming down to temp. Temperature Blank Present 6. X Sufficient Sample Submitted Insufficient Sample Submitted 7. Chlorine absent HNO3 < 2 HCL < 2 Additional Preservatives verified (see notes) 8. X Received Within Holding Time Not Received Within Holding Time 9. X No Discrepancies Noted _ Discrepancies Noted NCDENR notified of Discrepancies* 10. X No Headspace present in VOC vials Headspace present in VOC vials >6mm Comments: Inspected and Logged in by: Amalie Walker Date: 9/3/2014 *NCDENR must be notified when collection, holding time or preservation requirements are not met. MI_11.9 Page 24 of 24 EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MON JLY YEAR 2014 FACILITY NAME 140 WEST FRANKLIN CLASS NA 1NTY ORANGE CERTIFIED LABORATORY (1) SGS Environmental Services, Inc CERTIFICATION NO. 481 (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRAI _ CERTIFICATION NO. 992126 PERSON(S) COLLECTING SAMPLES Fred Ammons ORC E (919) 369-5679 CHECK BOX IF ORC HAS CHANGED 0 Mail ORIGINAL and ONE COPY to: MTN: CENTRAL FILETS DIVISION OF WATER Qt'Alin: 1617 MAIL. SERVICE CENTER RALEIGH. NC 27699-1617 LOW / DISCHARGE FROM SITE t x (SIGNAIfLRE OYUPEQATUR IN RESPONSI IARGE) B:' TIinS SIGNATURE, I CERTIFY TIiAT THIS RI S ACCURATE AND COMPLETE TO THE BEST OF )WLEDG . v Operator Time On Site : 2 a CvC c 50050 34030 1343711 34010 81551 22417 34696 01051 e LOw BENZENE 1 FUVLBENzENE L: '10'fAL XVLL\ES - ..v - . _ . r s� r _ .4. _ 7 .7.1. i^� . EFFN 31 INF❑ ;- < N = !IRS 11RS Y/B/N 3IGI) UG/I, UG/L UG/L UG1L UG/I. t G/L I'G/L 1 0.002423 2 0.002423 3 1400 2 y,.. 0.002423 4 0.002026 5 0.002026 6 0,01i2026 7 O.i;U202G RECEIVED 8 0.002026 9 1100 2 \ es 0.002026 2 9 10 0.002142 ,AUG 11 0.002142 cINTRAL. FILE 12 0.002142 D WQ/BOG 13 0.002142 14 1330 2 yes 0.002142 15 0.002150 16 0.002150 17 0.002150 18 0.002150 ED 19 0.002150 RECE1 6664 20 0.002150 9 21314 21 0.002150 AL 2 22 0.002150 I ES 13 0.002150 CENTRAL W003 (3 24 1400 2 yes 0.002150 25 0.002149 26 (1.002149 27 0.002149 28 0.0021.19 29 1400 2 yes 0.002149 30 0_0(12149 31 0.002149 AVERAGE (1.0(12151 MAXIMUM MINENitiiti Comp. (C) / Grab (G) Ci Daily Maximum i .19 97 11 676 19 17 25 g Zo /9 DATE 0 530 00400 32103 03604 00556 SOLIDS (I'SS) = i s ^v C N �v N TOTAL PHENOLS 011, AND CREASE 111. UG/L I'G/l 1 6<n1-1<9 0.38 300 monitor DWQ Forni MR-1 (1 U04) Facility Status: (Please check one of the folio ** All monitoring data and sampling frequencies meet pem (including weekly averages. if applicable All monitoring data and sampling frequencies do NOT meet The permittee shall report to the Director or the appropriate Regional Office any threatens public health or the environment. Any information shall be provided or permittee became aware of the circumstances. A written submission shall also hi permittee becomes aware of the circumstances. if the facility is noncompliant, please attach a list of corrective actions being improvements to be made as required by Part iI.E.6 of the NPDES permit. "I certify. under penalty of law. that this document and all attachments were prep in accordance tvith a system designed to assure that qualified personnel properly submitted. Based on my inquiry of the person or persons who managed the systet for gathering the information. the information submitted is. to the best of my kno' complete. I am aware that there are significant penalties for submitting false infc fines and imprisonment for knowing violations. - Scott Milke, 140 Permittee (Please Sig ta'turep Perin (RcgTii cd unless Permittee Address Phone Number 126 West Franklin Street, Chapel Hill NC 27516 (919) 868-1678 Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) e-mail ADDITIONAL CERTIFIED LABORATOI: PARAMETER CODES Certii Corti f Certii Certii Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 7 Water Protection Section's web site at h2o.enr.state.nc.ushvgs and linking to the t tJse only units of measurement designated in the reporting facility's NPDES pennit for repo * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result. entered for all of the parameters on the DMR for the entire monitoring period. ORC On Site?: ORC must visit facility and document visitation of facility as required ***Signature of Permittee: if signed by other than the permittee, then the delegation of th file with the state per 15A NCAC 2B .0506(b)(2)(D). i rements requirements X Compliant Noncompliant Zpliance that potentially thin 24 hours from the time the Jed within 5 days of the time the and a time -table for 'der my direction or supervision ind evaluate the information lose persons directly responsible and belief; true, accurate. and a, including the possibility of anklin. LLC or type) Date ed electronically) Permit Expiration Date February 28, 2017 No. No. No. No. 3 or by visiting the Surface 'formation pages. :a. e no data to he ,NCAC 8G .0204. ory authority must be on Page 2 ARG Ammons Resource Group 2040 Peach Grove Lane Zebulon, NC 27597 919-369-5679 fredammons@att.net July 13, 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 RECEIVED JUL 282014 CENTRAL FILES DWQ/BOG Subject: JUNE 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the June 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill, North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Water samples will be collected from outfall 001 during August 2014 for the quarterly sampling event as required by the permit. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II, of Section D. (2.) of its NPDES Permit. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Resource Group red Am ons ORC Enclosures: cc: June 2014 DMR Mr. Scott Milke, 140 West Franklin, LLC Mr. Ernest Odei-Larbi, Town of Chapel Hill EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MONTH June YEAR 2014 FACILITY NAME 140 WEST FRANKLIN CERTIFIED LABORATORY (1) SGS Environmental Services, Inc CERTIFICATION NO. 481 (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE I CERTIFICATION NO. 992126 PERSON(S) COLLECTING SAMPLES Fred Ammons ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE * NA COUNTY ORANGE CHECK BOX IF ORC HAS CHANGED Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 El CLASS (SIG .1A 'T . .9'' OR IN RESPONSIBLE CHARGE) BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. fi ./f1/ DATE DATE Operator Arrival Time 2400 aock Operator Time On Site ORC On Site? ** 50050 34030 134371 34010 81551 122417 34696 01051 00530 00400 32103 03604 00556 FLOW BENZENE ETHYLBENZENE TOLUENE TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) a 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFFX:il INF 0 DAILY RATE HRS HRS Y/B/N MGD UG/L UG/L UG/L UG/L UG/L UG/L UG/L mp,IL UG/L UG/L 1 0.005080 2 0.005080 3 0.005080 4 0.005080 5 0.005080 6 0.005080 7 1300 2 yes 0.005080 8 0.003180 9 0.003180 10 0.003180 11 1300 2 yes 0.003180 12 0.002943 13 0.002943 14 0.002943 15 0.002943 16 0.002943 17 0.002943 18 1300 2 yes 0.002943 19 0.002819 20 0.002/119 21 0.002819 22 0.002819 23 0.002819 24 0.002819 25 1300 2 yes 0.002819 26 0.002819 27 0.002819 28 0.002819 29 0.002819 , 30 0.002819 AVERAGE 0.003424 MAXIMUM MINIMUM Comp. (C) / Grab (G) G Daily Maximum 1.19 97 11 670 19 12 25 30 6<pH<9 0.38 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NOT meet permit requirements x Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Scott Milke, 140 West Franklin, LLC Permittee (Please print or type) Si of Permittee*** Date (Required unless submitted electronically) Permittee Address Phone Number 126 West Franklin Street, Chapel Hill NC 27516 (919) 868-1678 e-mail address Permit Expiration Date February 28, 2017 Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wqs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per I5A NCAC 2B .0506(b)(2)(D). Page 2 ARG Ammons Resource Group 2040 Peach Grove Lane Zebulon, NC 27597 919-369-5679 fredammons@att.net June 17, 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 RECEIVED JUL 022014 CENTRAL FILES DWQIBOG Subject: MAY 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the May 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill, North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Water samples were collected from outfall 001 on May 13, 2014 for the quarterly sampling event as required by the permit. Samples were sent to SGS Environmental Services, Inc. of Wilmington, North Carolina for analysis. Analytical results indicate that compounds were below the permitted daily maximum limits. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II, of Section D. (2.) of its NPDES Permit. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Reso rce Group Fred . ns ORC Enclosures: cc: May 2014 DMR Mr. Scott Milke, 140 West Franklin, LLC Mr. Ernest odei-Larbi, Chapel Hill NPDES PERMIT NO. NCG510532 EFFLUENT DISCHARGE NO. 001 MONTH MAY FACILITY NAME 140 WEST FRANKLIN CLASS NA COUNTY ORANGE YEAR 2014 CERTIFIED LABORATORY (1) SGS Environmental Services. Inc CERTIFICATION NO. 481 (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons PERSON(S) COLLECTING SAMPLES Fred Ammons CHECK BOX IF ORC HAS CHANGED CI Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 IxA (SIGNATURE 0 O RATOR IN RESPONSIBLE CHARGE) BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS CCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. GRADE I CERTIFICATION NO. 992126 ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE * DATE 0 Frl Q p Operator Arrival Time 2400 Clock Operator Time Oa Site « !. :: o 0 V a 0 50050 34030 34371 34010 81551 22417 34696 01051 00530 00400 32103 03604 00556 FLOW Z w Z wm ETHYLBENZENE TOLUEN16 TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) = c. 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFFX31 INF O, DAILY RATE -. HRS HRS Y/B/N MGD UG/L UG/L UG/L UG/L UG/L UG/L UG/L mg(L UG/L UG/L 1 0.003913 2 0.003913 3 0.003913 4 0.003913 5 0.003913 6 1200 2 yes 0.003913 7 0.003150 8 0.003150 9 0.003150 10 0.003150 11 0.0031150 12 0.003150 13 1200 2 yes 0.0031150 ND ND ND ND 0.28 ND ND ND 6.32 BQL 110 NS 14 0.005910 15 0.005910 16 0.005910 17 0.005910 18 0.005910 19 0.005910 20 1330 2 yes 0.005910 21 0.002688 22 0.002688 23 0.002688 24 0.002688 25 0.002688 26 0.002688 27 0.002688 28 0.002688 29 0.002688 30 730 2 yes 0.002688 - 31 0.002688 AVERAGE 0.003757 MAXIMUM MINIMUM Comp. (C) / Grab (G) G Daily Maximum 1.19 97 11 670 19 12 25 30 6<pH<9 0.38 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) AI I monitoring data and sampling frequencies do NOT meet permit requirements x Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part ILE.6 of the NPDES permit. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Scott Milke, 140 West Franklin, LLC Permittee (Please print or type) (0-18-1�i of Permittee*** Date fired unless submitted electronically) Permittee Address, Phone Number 126 West Franklin Street, Chapel Hill NC 27516 (919) 868-1678 Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) e-mail address ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Permit Expiration Date February 28, 2017 Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wgs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per I5A NCAC 8G .0204. ** * Signature of Permittee: If signed by other than the pennittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2XD). Page 2 Laboratory Report of Analysis To: Fred Ammons Ammons Resource Group 2040 Peach Grove Lane Zebulon, NC 27597 Report Number: 31400735 Client Project: 140 West Dear Fred Ammons, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Michael D. Page at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. Digitally signed by: Michael Page Date: 2014.05.22 11:07:08 -05'00' Michael D. Page Project Manager michael.page@sgs.com Date SGS Environn>ont:d Servicos 5500 Business Drive Wilmington. NC 28405 +1 910 350 1903 +1 866 846 8290 www.sgs.com Page 1 of 32 Member of the SGS Group (SGS SA) Laboratory Qualifiers 1 Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions * Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) J Estimated Concentration. E Amount detected is greater than the Upper Calibration Limit TIC Tentatively Identified Compound ND Not Detected P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak M2 Software did not integrate peak M3 Incorrect baseline construction (i.e. not all of peak included; two peaks integrated as one) M4 Pattem integration required (i.e. DRO, GRO, PCB, Toxaphene and Technical Chlordane) M5 Other- Explained in case narrative Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Page 2 of 32 Sample Summary Client Sample ID Lab Sample ID Collected Received Matrix Outfall 001 31400735001 05/13/2014 12:00 05/14/2014 09:40 Water Page 3 of 32 • Detectable Results Summary Client Sample ID: Outfall 001 Lab Sample ID: 31400735001-G Parameter Result Units EPA 420.4 (SUB) Phenol 0.11 mg/L SM 4500-H+ B pH pH 6.32 S.U. pH at Temperature 13.8 C SW-846 8260E tert-Butyl methyl ether (MTBE) 0.280 ug/L J Quality Control Samples Client Sample ID: MB for HEN 42519 [MXX/3365] Lab Sample ID: 136954 Parameter Result Units SW-846 6010C Lead 0.00806 mg/L J l Page 4 of 32 e-- Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400735001-D Lab Project ID: 31400735 Collection Date: 05/13/2014 12:00 Received Date: 05/14/2014 09:40 Matrix: Water ' Results by SW-846 8260B 1 Parameter Result Qual DL LOQ/CL Units DF Date Analyzed 1,2-Dichloroethane ND U 0.119 1.00 ug/L 1 05/15/2014 14:38 Benzene ND U 0.107 1.00 ug/L 1 05/15/2014 14:38 Ethyl Benzene ND U 0.105 1.00 ug/L 1 05/15/2014 14:38 Naphthalene ND U 0.111 1.00 ug/L 1 05/15/2014 14:38 Toluene ND U 0.101 1.00 ug/L 1 05/15/2014 14:38 Xylene (total) ND U 0.179 2.00 ug/L 1 05/15/2014 14:38 tert-Butyl methyl ether (MTBE) 0.280 J 0.145 1.00 ug/L 1 05/15/2014 14:38 Surrogates 1,2-Dichloroethane-d4 104 64.0-140 % 1 05/15/2014 14:38 4-Bromofluorobenzene 101 85.0-115 % 1 05/15/2014 14:38 Toluene d8 99.0 82.0-117 % 1 05/15/2014 14:38 Batch Information Page 5 of 32 - Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400735001-C Lab Project ID: 31400735 Results by SW-846 6010C Parameter Lead Batch Information Result ND Collection Date: 05/13/2014 12:00 Received Date: 05/14/2014 09:40 Matrix: Water l Qual DL LOQ/CL Units DF U 0.00794 0.0100 mg/L 1 Date Analyzed 05/19/2014 12:07 Page 6 of 32 r- Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400735001-A Lab Project ID: 31400735 Results by SM 2540-D Parameter Total Suspended Solids Batch Information Result ND Collection Date: 05/13/2014 12:00 Received Date: 05/14/2014 09:40 Matrix: Water Qual DL LOQ/CL Units DF 3.60 25.0 mg/L 1 Date Analyzed 05/14/2014 15:24 Page 7 of 32 Results of Outfall 001 - Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400735001-B Lab Project ID: 31400735 Collection Date: 05/13/2014 12:00 Received Date: 05/14/2014 09:40 Matrix: Water t- Results by SM 4500-H+ B pH Parameter Result Qual DL LOQ/CL Units DF Date Analyzed pH 6.32 0.0100 0.0100 S.U. 1 05/14/2014 12:05 pH at Temperature 13.8 C 1 05/14/2014 12:05 Batch Information Page 8 of 32 Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400735001-G Lab Project ID: 31400735 Collection Date: 05/13/2014 12:00 Received Date: 05/14/2014 09:40 Matrix: Water a-- Results by EPA 420.4 (SUB) Parameter Result Qual DL LOQ/CL Units DF Phenol 0.11 0.0100 mg/L 2 Laboratory: Pace }analytical Analytical DatefTir>te. 05/21/2014 21:27 Prep Methou Prep Date -`Tin,, ---- Date Analyzed 05/21/2014 21:27 Page 9 of 32 I ti PaceAnalytical www.pacelabs.com May 22, 2014 Mr. Michael Page SGS Environmental Services Inc 5500 Business Drive Wilmington, NC 28405 RE: Project: 31400735 Pace Project No.: 92201389 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Page: Enclosed are the analytical results for sample(s) received by the laboratory on May 14, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Jon D Bradley jon.bradley@pacelabs_com Project Manager Enclosures cc: Ms. Barbara Hager, SGS Environmental Services Inc. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 10 Page 10 of 32 -11aceAnalyticar wwwpacelabsc n CERTIFICATIONS Project: 31400735 Pace Project No.: 92201389 Pace Analytical Services, Inc. 9800 Kncey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification # 99030001 West Virginia Certification #: 356 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 10 Page 11 of 32 aceAnalytical wwwpaagabxoom SAMPLE SUMMARY Project: 31400735 Pace Project No.: 92201389 Pace Analytical Services, Inc. 9800 kiincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Matrix Date Collected Date Received 92201389001 31400735001 Water 05/13/14 12:00 05/14/14 10:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 10 Page 12 of 32 aceArralytical www.pacelaba com SAMPLE ANALYTE COUNT Project: 31400735 Pace Project No.: 92201389 Pace Analytical Services, Inc. 9800 Kncey Ave. Suite 100 Huntersvitle, NC 28078 (704)875-9092 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92201389001 31400735001 EPA 420.4 DMN 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 10 Page 13 of 32 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 31400735 Pace Project No.: 92201389 Pace Analytical Services, Inc. 9800 IGncey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 31400735001 Lab ID: 92201389001 Collected: 05/13/14 12:00 Received: 05/14/14 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 420.4 Phenolics, Total Phenol Date: 05/22/2014 10:36AM Analytical Method: EPA 420.4 0.11 mg/L 0.010 0.010 2 05/21/14 21:27 108-95-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 10 Page 14 of 32 'aceAnafytical www.pacelabscom QUALITY CONTROL DATA Project: 31400735 Pace Project No.: 92201389 Pace Analytical Services, Inc. 9800 IGncey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WETA/19064 Analysis Method: EPA 420.4 QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics Associated Lab Samples: 92201389001 METHOD BLANK: 1203658 Associated Lab Samples: 912201389001 1 Matrix: Water Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phenol mg/L ND 0.0050 05/21/14 20:41 LABORATORY CONTROL SAMPLE: 1203659 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Phenol mg/L .05 0.046 93 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1203660 1203661 MS MSD 92201191001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phenol mg/L 0.071 .05 .05 0.062 0.064 -17 -12 90-110 3 20 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1203662 1203663 MS MSD 92201046003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phenol Date: 05/22/2014 10:36 AM mg/L 0.045 .05 .05 0.061 0.060 33 31 90-110 1 20 M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 10 Page 15 of 32 aceAnalytical wre pacelab&earn QUALIFIERS Project: 31400735 Pace Project No.: 92201389 Pace Analytical Services, Inc. 9800 Krncey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at Or above adjusted reporting limit. J - Estimated concentra_tion above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted MethoJlDetection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clear! -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethytvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. Date: 05/22/2014 10:36 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 10 Page 16 of 32 aceAnalytical w ,w.pacelabsonm QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 31400735 Pace Project No.: 92201389 Pace Analytical Services, Inc. 9800 Kcncey Ave. Suite 100 HuntersvWe, NC 28078 (704)875-9092 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92201389001 31400735001 EPA 420.4 WETA119064 Date: 05/22/2014 10:36 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 10 Page 17 of 32 ,/ !2ceAnalytical Client Name: i Uocument Name: Sample Condition Upon Receipt (SCUR) Document Number: F-CHR-CS-003-rev.14 UUCUI I It I U r\cvicu_ ry. u . Page 1 of 2 Issuing Authority: Pace Huntersville Quality Office Courier: f Fed x ❑ UPS[] USPS[J Client❑, Commercial❑ Pace Other Custody Seal on Cooler/Box Present: (J yes 'V-' no`) Seals intact: ❑ yes U no ,. f Non ❑ Packing Material: ❑ Bubble Wrap Bubble Bags Thermometer Used: IR Gun T1102 140-) Type of Ice: Other Blue None o Correction T1301: No Correction Optional P.roj;pile.:Oete Prof: Name:' - Samples on ice, cooling process has begun .....-r ---------... ------ Corrected Cooler Temp.: C Biological Tissue is Frozen: Yes No N/A Comments: Date and Initials of person examining contents: al Sl /Stw Temp should be above freezing to 6°C Chain of Custody Present: Yes ❑No ID N/A 1. Chain of Custody Filled Out: �dYes ID No ❑N/A 2, Chain of Custody Relinquished: ®Yes ❑No DN/A 3. Sampler Name & Signature on COC: fYes ❑No ❑N/A 4. Samples Arrived within Hold Time: t�Yes ❑No ❑N/A 5. Short Hold Time Analysis (<72hr): ❑Yes lv1 o ❑N/A 6. Rush Turn Around Time Requested: DYes Ij1No ❑N/A 7. Sufficient Volume: des ❑No ❑N/A 8. Correct Containers Used: -Pace Containers Used: DYes t o DN/A Dves ,No ❑N/A 9. Containers Intact: des ❑No ❑N/A 10. Filtered volume received for Dissolved tests DYes ❑No {j!N/A 11 _ Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: des ID No ❑N/A 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, conform, TOC, O&G, W-DRO (water) Yes :No 1jYes ❑No DYes 4iNo ❑N/A ❑N/A 13. Samples checked for dechlorination: DYes ONo rA 14. Headspace in VOA Vials (>6mm): ❑Yes ❑No N/A 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): DYes DNo DYes ❑No N/A I4N/A 16. Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Date/Time: Field Data Required? Y / N SCURF Review: SRF Review: Date: 5 15 14- Date: -) 15 14-1 Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Place label here WOp:92201389 Page 18 of 32 Page 9 of 10 ZE Jo 6 L abed SGS CHAIN OF CUSTODY I CONVENTIONAL & SHALE PROJECT INFO: PROJECT. 3!i is t35.. P.O. #: QUOTE # SITE REF: / TURN. AROUND •TIME:,'7)-r L_. �CS�',I • REPORT LEVEL: (see reverse) ' Level I Level II Level IV SPECIAL DELIVERABLES: . State of Ong:r. EDD. Other: LAB ID SEND DOCUMENTATION / RESULTS TO: COMPANY:5' 5 CONTACT .1.- R'c[y tf• ADDRESS: )) PHONE: q(L :36 (i C EMAIL: i '1..-1 `.1 GZC' /-'i ` e:0,5" INVOICE TO: ( CHECK IF SAME) COMPANY CONTACT ADDRESS: PHONE: EMAIL: SPECIAL INSTRUCTIONS / COMMENTS: PRESERVATIV SAMPLE ID / DESCRIPTION DATE QC TIME MS MSD DUP TYPE (C, G) MATRIX CONT. QTY ANALYSIS & METHOD 5245 X • REMARKS COLLECTED/RELINQUISHED BY.{O): RELINQUISHED BY (2): DATE: • 57141(4- DATE: TIME: TIME: RECEIVED BY: (s '`XDIP ' srlsto RECEIVED BY RECEIVED BY LABORATORY: DATE TIME: COC SEAL: INTACT BROKEN ABSENT SAMPLE RECE(PTTEMP: "C CARRIER: TRACKING NOTES. Page of SOS NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington. NC 28,105 310 350 1903 1910 79.1 '613 www.sgs.com i- Batch Summary - -- Analytical Method: SW-846 8260E Client Sample ID LCS for HBN 42509 [VXX/5008] LCSD for HBN 42509 [VXX/5008] MB for HBN 42509 [VXX/5008] Outfall 001 8260 inffluent(136279MS) 8260 inffluent(136279MSD) Prep Method: SW-846 5030E Prep Batch: VXX5008 Prep Date: 05/16/2014 15:22 Lab Sample ID Analysis Date 136878 05/15/2014 11:40 136879 05/15/2014 12:06 136880 05/15/2014 12:56 31400735001 05/15/2014 14:38 137020 05/15/2014 18:09 137021 05/15/2014 18:34 Analytical Batch Instrument Analyst VMS3227 VMS3227 VMS3227 VMS3227 VMS3227 VMS3227 MSD9 JHL MSD9 JHL MSD9 JHL MSD9 JHL MSD9 JHL MSD9 JHL Page 20 of 32 r Method Blank Blank ID: MB for HBN 42509 [VXX/5008] Blank Lab ID: 136880 QC for Samples: 31400735001 Results by SW-846 8260E Matrix: Water Parameter Result Qual DL LOQ/CL Units DF tert-Butyl methyl ether (MTBE) ND U 0.145 1.00 ug/L 1 Benzene ND U 0.107 1.00 ug/L 1 1,2-Dichloroethane ND U 0.119 1.00 ug/L 1 Toluene ND U 0.101 1.00 ug/L 1 Ethyl Benzene ND U 0.105 1.00 ug/L 1 Xylene (total) ND U 0.179 2.00 ug/L 1 Naphthalene ND U 0.111 1.00 ug/L 1 Surrogates 1,2-Dichloroethane-d4 102 64.0-140 % 1 Toluene d8 98.0 82.0-117 % 1 4-Bromofluorobenzene 100 85.0-115 % 1 Batch Information Page 21 of 32 Blank Spike Summary Blank Spike ID: LCS for HBN 42509 [VXX/5008] Blank Spike Lab ID: 136878 Date Analyzed: 05/15/2014 11:40 QC for Samples: 31400735001 Results by SW-846 8260E Parameter tert-Butyl methyl ether (MTBE) Benzene 1,2-Dichloroethane Toluene Ethyl Benzene Naphthalene Surrogates 1,2-Dichloroethane-d4 Toluene d8 4-Bromofluorobenzene Batch Information Spike Duplicate ID: LCSD for HBN 42509 [VXX/5008] Spike Duplicate Lab ID: 136879 Date Analyzed: 05/15/2014 12:06 Matrix: Water Blank Spike (ug/L) Rec % 101 97 102 100 97 104 106 98 102 Spike Duplicate (ug/L) Rec 99 94 96 96 91 94 105 100 101 1 RPD (%) 2.0 3.3 5.9 3.9 5.5 9.7 Page 22 of 32 Batch Summary Analytical Method: SW-846 6010C Prep Method: SW-846 3010A Prep Batch: MXX3365 Prep Date: 05/15/2014 16:40 Client Sample ID MB for HBN 42519 [MXX/3365] LCS for HBN 42519 [MXX/3365] LCSD for HBN 42519 [MXX/3365] Outfall 001 Outfall 001(136784MS) Outfall 001(136784MSD) Outfall 02-CPC(136952DU P) Lab Sample ID Analysis Date 136954 05/19/2014 11:53 136955 05/19/2014 11:58 136956 05/19/2014 12:02 31400735001 05/19/2014 12:07 136957 05/19/2014 12:12 136958 05/19/2014 12:16 136959 05/19/2014 12:35 Analytical Batch Instrument Analyst MIP2395 MIP2395 MIP2395 MIP2395 MIP2395 MIP2395 MIP2395 ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW ICP1 PSW Page 23 of 32 ,= Method Blank ♦ Blank ID: MB for HBN 42519 [MXX/3365] Blank Lab ID: 136954 QC for Samples: 31400735001 Results by SW-846 6010C Parameter Lead Batch Information Matrix: Water Result Qua! DL LOQ/CL Units DF 0.00806 J 0.00794 0.0100 mg/L 1 Page 24 of 32 Blank Spike Summary Blank Spike ID: LCS for HBN 42519 [MXX/3365] Blank Spike Lab ID: 136955 Date Analyzed: 05/19/2014 11:58 QC for Samples: 31400735001 L Results by SW-846 6010C Parameter Blank Spike (mg/L) Rec Spike Duplicate ID: LCSD for HBN 42519 [MXX/3365] Spike Duplicate Lab ID: 136956 Date Analyzed: 05/19/2014 12:02 Matrix: Water Spike Duplicate (mg/L) Rec % RPD (%) Lead 92 87 6.1 Batch Information Page 25 of 32 Matrix Spike Summary Original Sample ID: 31400735001 (Outfall 001) MS Sample ID: 136957 MSD Sample ID: 136958 QC for Samples: 31400735001 Analysis Date: 05/19/2014 12:07 Analysis Date: 05/19/2014 12:12 Analysis Date: 05/19/2014 12:16 Matrix: Water \ - Results by SW-846 6010C — -- Matrix Spike (mg/L) Spike Duplicate (mg/L) Parameter Sample Rec % Rec (%) RPD (°/a) Lead ND 88 86 2.3 Batch Information Page 26 of 32 Batch Summary Analytical Method: SM 2540-D Client Sample ID MB for HBN 42494 [INO/3132] LCS for HBN 42494 [INO/3132] Outfall 001 Outfall 001(136784DUP) Prep Method: SM 2540-D Prep Batch: INO3132 Prep Date: 05/14/2014 15:24 Lab Sample ID Analysis Date 136830 05/14/2014 15:24 136831 05/14/2014 15:24 31400735001 05/14/2014 15:24 136832 05/14/2014 15:24 Analytical Batch Instrument Ana st INO3132 BAL10 VS INO3132 BAL10 VS INO3132 BAL10 VS INO3132 BAL10 VS N J Page 27 of 32 - Method Blank Blank ID: MB for HBN 42494 [INO/3132] Blank Lab ID: 136830 QC for Samples: 31400735001 Results by SM 2540-D Parameter Total Suspended Solids Batch Information Result ND Matrix: Water l Qual DL LOQ/CL Units DF 3.60 25.0 mg/L 1 Page 28 of 32 Blank Spike Summary Blank Spike ID: LCS for HBN 42494 [INO/3132] Blank Spike Lab ID: 136831 Date Analyzed: 05/14/2014 15:24 QC for Samples: 31400735001 Results by SM 2540-D Matrix: Water Blank Spike (mg/L) Parameter Rec Total Suspended Solids 81 Batch Information Page 29 of 32 e-- Duplicate Sample Summary Original Sample ID: 31400735001-A Duplicate Sample ID: 136832 QC for Samples: 31400735001 \-. Results by SM 2540-D PARAMETER Total Suspended Solids Batch Information Analysis Date: 05/14/2014 15:24 Analysis Date: 05/14/2014 15:24 Matrix: Water N Original (mq/L) Qual Duplicate (mq/L) gial RPD (%) RPD CL ND ND 20.00 Page 30 of 32 CHAIN OF CUSTODY ANALYTICAL PIERSPI GTevp SOS ANALYTICAL PERSPECTIVES 6500 Business Drive Wilmington. NC 28405 +1010 3501803 WWW.SO3.COM cum AV1tk©145 REsouReC GL.ovA SOS Referencell: • ::(4o � r PACE , CONTACTPiIDHE Na i -, Attkia0 s • 41q ) a6/�7f S C TYPE " OF PR PROJECT:ITE/PWSID/tNss/s , /'/o✓ REPORTS TO: EMAIII ____[... N I 5 cup au�+ uars/ Cb 'x t` 4.Dc ' • : % . ' ///// �� INVOICE Ilk WWIINOs Oro 1�I Lr P.O. NIMMOER i,�� � a i • lCralix,:liii .1!' :1 s SAMPLE IDENTUICKIION � DATE T1ME MATRIX � `• � � aka• Q tilf"�l�l.L. l �Z42.� � H 6 li ai ...y. C�'�j' �71 .y A. 4 gat :. '' . 'FAR ,{fz ;3.tt!i0i+i1l a' . ....mimisminioN •rtil V d1;:i:': ''' .4.:!..Pii;:r:;krtail: QViO , E aft PI COUE N ED BY: hl TIME RECEIVED SY: FPp 4g if 7 6$ SLs 377, REPORT LEVEL: . O Leve4 I 0 Level 11 0 Leval IV REQUESTED TURNAROUND 0 Rum r` _ • ,... . Reflngt iahad .12) ate The Reestved By: SPEDIALDREIVERABLES: Stec of wen. 0 Mist fund ' , ' O DoD O EDO. Other, Rel aqulsha0 By: CO Oats Time Reasived By: . SPECIAL INSTRUCTIONS: r • f' �iy.•t 1:•! /-, .`.' s , •{r' ••1 �� •-. �r I' 1 y. ,• .: ,� .1iY ti ii. .. tr!• .� .,'r� ` �►j • •a: ► I� ti' . • ..5..1. 1•+i. '.ry .rt •�/1 �' i i1 •�t 7 r r .' t;+ � �vr• N i. r 11J/�f� � y. �il�ris' i' 7 .4It;i.f. �' ��! r j�: ' 'J'��!L'• 11 i, /M� ^ �p� Codilial., NTACra B. V N: /tW7 ♦� i•: .� •1•.! r' �+1• ':1�ri•1'i«'1'.1�..Y. t.�r•tir''•�ir•� .'�� * •. ni - j (7'+ + r3�i }» Z'i..• 1 'I .. • .'1 :. �i. r .1 ,� � eii, n r. •: �• t;•• � 'f• ' rti ,....1, •�•►' - .•` ti�i • • ' �' f �- ' 'j'`•: ` �'. .ti •:'. a, i , �,+».�a,,. i.�r4 �y ' ar•�:! 1' t.61, 1� .4) ..,, �i' .f1y'• 'rl. CI' •. ii i. < •!• 1 l ••-�' �•� 1�i1ti �- .� �', i'. jpiv r� ti1 L{rj \ ►�..,••t•l i4 �• RMa) .'.ail ti i ,•, ' fill: '11 1 in. .,rr . .� i•I:lati; tallith: p+i. 4..1..Ai.i•I",.. ( r .A :i,• 1• nit 1 r +.�• t�l„ r• • ,i� ♦ i,�'•.t:' ..�. . . •i:..'Iwri#i.wrrb}i.i..i••:,�i:.,.:Z�t'r��rIM.K.L.Yr.a.•,t,',.1:..1' IS•x•• .�•. '4 .1: , � „ , , .,. .•I•,.., I .�..p� I:r• r , .r ..►.. «: !i��Et�p;iocetNaw� . .�h•IS.' ..�'�I.i N ANAIXIICAL PERSPECTIVES IS NOW PART OF SQS, THEWIORt.D'S LEADING INSPECTION, VFRIFICATION,TESTING AND CERTIFICATION COMPANY Ms • Rt1i11rd M lab Mato Rettbledbv mot Client: Ammons SGS North America Inc. Sample Receipt Checklist (SRC) Work Order No.: 1. X Shipped Hand Delivered 2. X COC Present on Receipt No COC Additional Transmittal Forms 3. 9ustody Tape on Container X No Custody Tape 4. X Samples Intact Samples Broken / Leaking Notes: 31400735 5. X Chilled on Receipt Actual Temp.(s) in °C: 5 Thermometer ID#: Login 1-D Ambient on Receipt Walk-in on Ice; Coming down to temp. Temperature Blank Present 6. X Sufficient Sample Submitted Insufficient Sample Submitted 7. Chlorine absent X HNO3 < 2 X HCL < 2 X Additional Preservatives verified (see notes) 8. X Received Within Holding Time Not Received Within Holding Time 9. X No Discrepancies Noted Discrepancies Noted NCDENR notified of Discrepancies* 10. X No Headspace present in VOC vials Headspace present in VOC vials >6mm Comments: H2SO4 Inspected and Logged in by: Russell Holz Date: Wed-5/14/14 00:00 *NCDENR must be notified when collection, holding time or preservation requirements are not met. MI_11.7 Page 32 of 32 ARG Ammons r-esource Group 2040 Peach Grove Lane ZebuIon, NC 27597 919-369-5679 fredammons@att.net May 8, 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 RECENED MA 2 2 2014 CENTRAL FILES DWQIBOG Subject: APRIL 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the April 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill, North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Water samples will be collected from outfall 001 during May 2014 for the quarterly sampling event as required by the permit. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II, of Section D. (2.) of its NPDES Permit. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely. Ammons Respurce Group Fred Amons ORC Enclosures: cc: April 2013 DMR Mr. Scott Milke, 140 West Franklin, LLC Mr. Ernest Odei-Larbi, Town of Chapel Hill EFFLUENT NPDES PERMIT NO. NCG510532 FACILITY NAME 140 WEST FRANKLIN CERTIFIED LABORATORY (1) SGS Environmental Services. Inc (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons PERSON(S) COLLECTING SAMPLES Fred Ammons CHECK BOX IF ORC HAS CHANGED ❑ DISCHARGE NO. 001 Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 MONTH APRIL YEAR 2014 CLASS NA COUNTY ORANGE CERTIFICATION NO. 481 GRADE I CERTIFICATION NO. 992126 ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE * (SI A 0 OPERATOR IN RESPONSIBLE CHARGE) Y THIS SIGNATURE, 1 CERTIFY THAT THIS REPORT IS CCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. 8 • /9 DATE DATE 1 Operator Arrival Time 2400 aock Operator Time On Site * l' 4-- 4) w c 0 v x 0 50050 134030 1 34371 34010 81551 1 22417 34696 01051 00530 00400 32103 03604 00556 FLOW BENZENE ETHYLBENZENE TOLUEN; TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) x a 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFFXi1 INF01 DAILY RATE HRS HRS Y/B/N MGD UG/L UG/L UG/L UG/L UG/L UG/L UG/L mg& UG/L UG/L 1 0.005813 2 0.005813 3 1100 2 yes 0.003492 4 0.003837 _ 5 0.003837 6 0.003837 7 0.003837 8 0.003837 9 0.003837 10 1100 2 yes 0.003837 11 0.003996 12 0.003996 13 0.003996 14 0.003996 15 0.003996 16 0.003996 17 0.003996 18 1100 2 yes 0.003996 19 0.004646 20 0.004646 21 0.004646 22 1100 2 yes 0.004646 23 0.004646 24 0.004646 25 0.004646 26 0.004646 27 0.004646 28 0.004646 29 0.004646 30 0.004646 AVERAGE 0.004323 MAXIMUM MINIMUM Comp. (C) / Grab (G) G Daily Maximum _ 1.19 97 11 670 19 _ 12 25 30 6<pH<9 0.38 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NOT meet permit requirements Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Scott Milke, 140 West Franklin, LLC Permittee (Please print or type) Si rmittee*** Date (Required unless submitted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date 126 West Franklin Street, Chapel Hill NC 27516 (919) 868-1678 February 28, 2017 Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wqs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 ARG 2040 Peach Grove Lane Zebulon, NC 27597 919-369-5679 fredammons@att. net April 19, 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Subject: MARCH 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: APR 302014 DWQg'���E OGS Attached is the March 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill, North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II, of Section D. (2.) of its NPDES Permit. Water samples will be collected and analyzed as required by the permit in the second quarter of 2014. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Resource Group Fldm ons ORC Enclosures: March 2014 DMR cc: Mr. Scott Milke, 140 West Franklin, LLC Mr. Mike Taylor, Chapel Hill EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MONTH March YEAR 2014 FACILITY NAME 140 WEST FRANKLIN CLASS NA COUNTY ORANGE CERTIFIED LABORATORY (1) SGS Environmental Services. Inc CERTIFICATION NO. 481 (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE I CERTIFICATION NO. 992126 PERSON(S) COLLECTING SAMPLES Fred Ammons CHECK BOX IF ORC HAS CHANGED 0 Mail ORIGINAL and ONE COPY to: AWN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE * (SIGNO ` 0 ERA i ' IN RESPONSIBLE CHARGE) BY THIS SIGNA I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. DATE Operator Arrival Time 2400 Clock Operator Time On Site ORC On Site? ** S0050 34030 34371 34010 1 81551 22417 34696 01051 00530 00400 32103 03604 00556 FLOW BENZENE ETHYLBENZENE TOLUENg TOTAL XYLENES METHYL TERT BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) a 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFFXII INF 0 j A HRS HRS Y/B/N MGD UG/L UG/L UG/L UG/L UG/L UG/L UG/L mg/L UG/L UG/L 1 0.003809 2 0.003809 3 0.003809 4 1000 2 yes 0.003809 5 0.003856 6 0.003856 7 0.003856 8 0.003856 9 0.003856 10 0.003856 11 1500 2 yes 0.003856 12 0.004618 13 0.004618 14 0.004618 15 0.004618 _ 16 0.004618 17 0.004618 18 0.004618 19 0.004618 20 0.004618 21 1000 2 yes 0.004618 22 0.004060 23 0.004060 24 0.004060 25 0.004060 26 0.004060 27 1530 2 yes 0.004060 28 0.004060 29 0.004060 30 0.004060 31 _ 0.004060 AVERAGE 0.004162 MAXIMUM MINIMUM Comp. (C) / Grab (G) G Daily Maximum 1.19 97 11 670 19 12 25 30 6<pH<9 0.38 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NO'l' meet permit requirements x Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part Il. E.6 of the NPDES permit. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Scott Milke, 140 West Franklin, LLC Permittee (Please print or type) 1/-23 -16( ure of Permittee*** Date (Required unless submitted electronically) Permittee Address Phone Number 126 West Franklin Street, Chapel Hill NC 27516 (919) 868-1678 e-mail address Permit Expiration Date February 28, 2017 ADDITIONAL CERTIFIED LABORATORIES Certified Laboratory (2) Environmental Testing Solutions, Inc Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES 37 Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wgs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 ARG Ammons Resource Grou0 2040 Peach Grove Lane Zebulon. NC 27597 919-369-5679 fredammons@att.net March 23, 201. To Whom It May Concern Central Files North Carolina Division of Water Quality_ 1617 Mail Service Center Raleigh. North Carolina 27699-1617 RECEIVED APR 01 2014 CENTRAL FILES DWQ/BOG Subject: FEBRUARY 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the February 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill. North Carolina. This work was conducted under NPDES Permii No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. !Hater samples were collected from outfall 001 on February 14, 2014 for the quarterly sampling event as required by the permit. Samples were sent to SGS Environmental Services, Inc. of Wilminaton, North Carolina for analysis. Analytical results indicate that compounds were below the permitted daily maximum limits. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part Il, of Section D. (2.) of its NPDES Permit. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerer Ammons Reso ce Group F ed mons ORC Enclosures: February 2014 DMR cc: Mr. Scott Milke. 140 West Franklin, LLC Mr. Mike Taylor, Chapel Hill EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MONTH February YEAR 2014 FACILITY NAME 140 WEST FRANKLIN CLASS NA COUNTY ORANGE CERTIFIED LABORATORY (1) SGS Environmental Services. Inc CERTIFICATION NO. 481 (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons PERSON(S) COLLECTING SAMPLES Fred Ammons CHECK BOX IF ORC HAS CHANGED ❑ Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 �, (SIG ATURE'OFfOPERATOR IN RESPONSIBLE CHARGE) BY THIS SIGNATURE. I CERTIFY THAT THIS REPORT IS CCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. GRADE I CERTIFICATION NO. 992126 ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE * I1 3 DATE 0 DATE G 11 Operator Time On Site w C a 0 50050 34030 343711 34010 81551 22417 1 34696 01051 00530 1 00400 32103 103604 was FLOW w w co ETHYLBENZENE TOLUENg TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) a 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFFia 1 >" kJ I"' co HRS_ }IRS Y/B/N MGD , UG/L UG/L UG/L UG/L UG/L UG/L UG/L asg/L UG/L UG/L 1 0.002372 , , 2 0.002372 3 0.002372 4 0.002372 5 600 2 yes 0.002372 6 0.002076 7 0.002076 8 0.002076 9 0.002076 10 0.002076 11 0.002076 12 0.002076 13 0.002076 14 1400 2 yes 0.002076 ND ND ND ND 0.25 ND 7.98E-06 7 6.5 ND ND NS 15 0.003651 _ 16 0.003651 17 0.003651 18 0.003651 19 1500 2 yes 0.003651 20 0.003249 _ 21 0.003249 22 0.003249 23 0.003249 24 1100 2 yes 0.0032'49 25 0.003249 26 0.003249 27 0.003249 28 0.003249 AVERAGE 0.002787 MAXIMUM • MINIMUM Comp. (C) / Grab (G) G 1 Daily Maximum 1.19 97 11 670 19 12 25 30 6<pH<9 0.38 300 monitor DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NO'l' meet permit requirements x Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentiak, threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. -t certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.' Scott Milke. 140 West Franklin. LLC Permittee (Please print or type) ature o P ittee*** Date unless submitted electronically) Peamittee Address Phone Number e-mail address Permit Expiration Date 126 West Franklin Street. Chapel Hill NC 27516 (919) 868-1678 February 28, 2017 Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wgs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result. there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the pemtittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 ANMM rncru Poresorcmor= Laboratory Report of Analysis To: Fred Ammons Ammons Resource Group 2040 Peach Grove Lane Zebulon, NC 27597 Report Number: 31400235 Client Project: 140 West Dear Fred Ammons, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of Tess than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Michael D. Page at (910) 350-1903. We will be happy to answer any questions or concems which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. G Digitally signed by: Michael Page Date: 2014.02.27 15:31:03-05'00' Michael D. Page Project Manager nnichael.page@sgs.com P inf Date: 02/27/2014 Date N C Certification # 481 ANALYTICAL PERSPECTIVES IS NOW PART OF SGS, THE WORLD'S LEADING INSPECTION, VERIFICATION, TESTING AND CERTIFICATION COMPANY. 5500 Business Or. US • 28405 Wilmington, NC t+1 9103501903 f +1 910 3501557 www.sgs cam Member of the SGS Group 1SGS SAI Page 1 of 25 Arl,l v�-c Laboratory Qualifiers Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) ✓ Recovery is below quality control limit. The data has been validated based on a favorable signal-to-noise and detection limit A Amount detected is less than the Lower Method Calibration Limit J Estimated Concentration. O The recovery of this analyte in the OPR is above the Method QC Limits and the reported concentration in the sample may be biased high E Amount detected is greater than the Upper Calibration Limit S The amount of analyte present has saturated the detector. This situation results in an underestimation of the affected analyte(s) Q Indicates the presence of a quantitative interference. This situation may result in an underestimation of the affected analyte(s) Indicates the presence of a qualitative interference that could cause a false positive or an overestimation of the affected analyte(s) DPE Indicates the presence of a peak in the polychlorinated diphenylether channel that could cause a false positive or an overestimation of the affected analyte(s) TIC Tentatively Identified Compound EMPC Estimated Maximum possible Concentration due to ion ratio failure ND Not Detected K Result is estimated due to ion ratio failure in High Resolution PCB Analysis P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Pri; It Date. 02f2 7 i'20 1 N C Certification # 481 5500 Business Dr. US•28405 Wilmington, NC t+19103501903 f.19t03501557 www.sgscom Page 2 of 25 Member of Me SGS Glow ISG S SAI Client Sample ID Outfall 001 A•1..1,-7,_ n,r ,1 V I . Sample Summary Lab Sample ID Collected Received Matrix 31400235001 02/14/2014 14:00 02/15/2014 11:30 Water Print Date 02/2712014 N.0 Certification # 481 SGC -'a:.j pt •;:m Per ipeo.YU$ 5500 Business Dr US - 28405 • Wilmington. NC t +1910 3501903 f +1910 3501557 www.sgs com Member of the SGS Orou, 1SGS SA) Page 3 of 25 API.\I Case Narrative Outfall 001 SM4500H-B - The pH was run outside of the method specified hold time. Print Date 02i27/2014 N.0 Certification # 481 5500 Business Dr US - 28405 Wilmington, NC t +1 910 3501903 f .1910 3501557 www.sgs corn Page 4 of 25 Member of the SIS Group ISG S SAI • Detectable Results Summary Client Sample ID: Outfall 001 Lab Sample ID: 31400235001-G SM 2540-D SM 4500-H+ B pH SW-846 6010C SW-846 8260B Print Date. 02/27/2014 Parameter Total Suspended Solids pH pH at Temperature Lead tert-Butyl methyl ether (MTBE) Result 7.00 6.5 17.1 0.00798 0.250 Units mg/L J S.U. C mg/L J uglL J N.C. Certification 4 481 5500Business Dr. US • 28405 • Wilmington, NC t +1 910 350 1903 1+19103501557 www.sgs.com Page 5 of 25 Member DI 1fie SI S Grnup ISGS SA) Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400235001-A Lab Project ID: 31400235 Results by SW-846 8260E Parameter 1,2-Dichloroethane Benzene Ethyl Benzene Naphthalene Toluene Xylene (total) tert-Butyl methyl ether (MTBE) Surrogates 1,2-Dichloroethane-d4 4-Bromofluorobenzene Toluene d8 Batch Information Result ND ND ND ND ND ND 0.250 103 101 98.0 Analytical Batch- VMS3151 Analytical Method: ISW-846 8260E Instrument: MSD4 Analyst: JHL Print Date 02/27/2014 Qual U U U U U U J DL 0.0880 0.132 0.0656 0.112 0.0660 0.200 0.0600 Collection Date: 02/14/2014 14:00 Received Date: 02/15/2014 11:30 Matrix: Water LOQ/CL 1.00 1.00 1.00 1.00 1.00 2.00 1.00 64.0-140 85.0-115 82.0-117 Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L OA OA OA DF 1 1 1 1 1 1 1 1 Prep Batch. VXX4918 Prep Method: SW-846 5030E Prep Date/Time• 02/26/2014 16:39 Prep Initial Wt.Nol.: 40 mL Prep Extract Vol: 40 mL Date Analyzed 02/25/2014 21:30 02/25/2014 21:30 02/25/2014 21:30 02/25/2014 21:30 02/25/2014 21:30 02/25/2014 21:30 02/25/2014 21:30 02/25/2014 21:30 02/25/2014 21:30 02/25/2014 21:30 N C Certification # 481 55CC Business Dr. U5 28405 • Wilmington. NC t r i 910 3501903 I.1910 3501557 wwwsgs com Page 6 of 25 IAembr• ul for SGS Gruup ISGS SAI Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400235001-D Lab Project ID: 31400235 Results by SW-846 6010C Parameter Lead Batch Information Result 0.00798 . nalytical Batch: MIP2310 Analytical Method: SW-846 6010C Instrument: ICP1 Analyst: PSW Print Date 02/27/2014 Qual DL J 0.00794 Collection Date: 02/14/2014 14:00 Received Date: 02/15/2014 11:30 Matrix: Water LOQ/CL Units DF 0.0100 mg/L 1 Prep Batch: MXX3238 Prep Method: SW-846 3010A Prep Date/Time: 02/21/2014 08:31 Prep Initial Wt.Nol.: 50 mL Prep Extract Vol: 50 mL Date Analyzed 02/25/2014 11:06 N.0 Certification # 481 5509 Business 0r. US • 28405 • Wilmington, NC t 910 3501903 1 el 910 3501557 www.sgs corn Page 7 of 25 Member ul the SGS Group ISGS SAI f Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400235001-G Lab Project ID: 31400235 Results by SM 2540-D Parameter Total Suspended Solids Batch Information Analytical Batch: I Analytical Method: 1 Instrument: BAL10 Analyst: PPH Print Date 02127/2014 102961 SM 2540-D Result 7.00 Qual J DL 2.50 Collection Date: 02/14/2014 14:00 Received Date: 02/15/2014 11:30 Matrix: Water LOQ/CL Units DF 25.0 mg/L 1 Prep Batch: IN02961 Prep Method: SM 2540-D Prep DatelTime: 02/19/2014 10:41 Prep Initial Wt.Nol.: 1 mL Prep Extract Vol: 1 mL Date Analyzed 02/19/2014 10:41 N C Certification # 481 55008usiness Or US • 28405 • Wilmington, NC t ♦1 910350 1903 f .19t0 3501557 www.sgs com i Page 8 of 25 Member of the SGS Gleuo ISG S SAI Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400235001-E Lab Project ID: 31400235 ' - Results by SM 4500-H+ B pH Parameter pH pH at Temperature Batch Information Result 6.5 17.1 Analytical Batch: IN02965 Analytical Method: SM 4500-H+ B pH Instrument: PH1 Analyst: PSW Print Date 02/27/2014 Collection Date: 02/14/2014 14:00 Received Date: 02/15/2014 11:30 Matrix: Water ual DL LOQ/CL Units 0.0100 0.0100 S.U. C DF 1 1 Prep Batch: IN02965 Prep Method: SM 4500-H+ B pH Prep Date/Time. 02/19/2014 16:30 Prep Initial Wt.Nol.: 1 mL Prep Extract Vol. 1 mL Date Analyzed 02/19/2014 16:30 02/19/2014 16:30 N.C. Certification # 481 5500 Business Di US • 28405 - Wilmington, NC t +1 910 3501903 (.1910 3501557 www.sgs coin Page 9 of 25 Mambr of the SOS Grow ISGS 54t A.l.tl ♦1.::n I Results of Outfall 001 Client Sample ID: Outfall 001 Client Project ID: 140 West Lab Sample ID: 31400235001-F Lab Project ID: 31400235 Collection Date: 02/14/2014 14:00 Received Date: 02/15/2014 11:30 Matrix: Water Results by EPA 420.1 (SUB) Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Phenol ND U 0.00400 mglL 1 02/20/2014 0:00 Laboratory: Envirohmental Chemists Analytical Date/Time: 02/20/2014 00:00 Prep Method: Prep Date/Time: Print Date. 02/27/2014 N.C. Certification # 481 I5500Business Or US•28405 Wilmington, NC t+19103501903 1+19103501557 www.sgscam Membv ofthrSGSGump ISGSSAI Page 10 of 25 SGSh AmmIrncia P R% C11W Batch Summary • Analytical Method: SW-846 8260E Client Sample ID LCS for HBN 40963 [' LCSD for HBN 40963 MB for HBN 40963 [V Outfall 001 Effluent PWC/TexFi(1 Cape Fear River U...( Print Date 02/27/2014 Prep Method: SW-846 5030B Prep Batch: VXX4918 Prep Date: 02/25/2014 16:22 Lab Sample ID Analysis Date Analytical Batch Instrument Analyst 00(/4918] 131118 02/25/2014 17:43 VMS3151 MSD4 JHL [VXX/4918] 131119 02/25/2014 18:09 VMS3151 MSD4 JHL KX/4918] 131107 02/25/2014 18:59 VMS3151 MSD4 JHL 31400235001 02/25/2014 21:30 VMS3151 MSD4 JHL 30564DUP) 131250 02/25/2014 23:10 VMS3151 MSD4 JHL 130563MS) 131249 02/25/2014 23:35 VMS3151 MSD4 JHL N C Certification # 481 5500 Business Dr. US • 28405 • Wilmington, NC t +1910 3501903 f ►1910 3501557 www.sgs corn Page 11 of 25 Member of the SGS Group ISGS SA Method Blank Blank ID: MB for HBN 40963 [VXX/4918] Blank Lab ID: 131107 QC for Samples: 31400235001 Results by SW-846 8260E Parameter tert-Butyl methyl ether (MTBE) Benzene 1,2-Dichloroethane Toluene Ethyl Benzene Xylene (total) Naphthalene Surrogates 1,2-Dichloroethane-d4 Toluene d8 4-Bromofluorobenzene Batch Information Result ND ND ND ND ND ND ND 105 100 100 Analytical L,;,cr VMS3151 Analytical Method: SW-846 8260B Instrument: MSD4 Analyst: JHL Print Date. 02/27/2014 3hS;•ca ,. Matrix: Water DL LOQ/CL Units 0.0600 1.00 ug/L 0.132 1.00 ug/L 0.0880 1.00 ug/L 0.0660 1.00 ug/L 0.0656 1.00 ug/L 0.200 2.00 ug/L 0.112 1.00 ug/L 64.0-140 82.0-117 85.0-115 Prep Batch: VXX4918 Prep Method: SW-846 5030B Prep Date/Time: 2/25/2014 12:08:37PM Prep Initial Wt.Nol.. 40 mL Prep Extract Vol: 40 mL DF 1 1 1 1 1 1 1 1 1 1 N C Certification # 481 5500 Business Or. US - 213405 . Wilmington, NC t +1 91035111903 1+19103501557 www.sgscom Page 12 of 25 PAembw of the SG S Gruua ISGSSA, AN, 'in:, u 1'I Blank Spike Summary Blank Spike ID: LCS for HBN 40963 [VXX/4918] Blank Spike Lab ID: 131118 Date Analyzed: 02/25/2014 17:43 QC for Samples: 31400235001 Results by SW-846 8260B Spike Duplicate ID: LCSD for HBN 40963 [VXX/4918] Spike Duplicate Lab ID: 131119 Date Analyzed: 02/25/2014 18:09 Matrix: Water Blank Spike (ug/L) Spike Duplicate (ug/L) Parameter S ike Result Rec (%) Spike Result Rec % CL RPD (%) RPD CL tert-Butyl methyl ether (MTBE) 5.00 5.57 111 5.00 5 26 105 47.0-142 5.7 30.00 Benzene 5.00 4.98 100 5.00 4.94 99 76.0-124 0.81 30.00 1,2-Dichloroethane 5.00 5.32 106 5.00 5.24 105 76.0-119 1.5 30.00 Toluene 5.00 5.12 102 5.00 5.07 101 75.0-123 0.98 30.00 Ethyl Benzene 5.00 4.54 91 5.00 4.62 92 76.0-123 1.7 30.00 Naphthalene 5.00 5.40 108 5.00 5.24 105 67.0-122 3.0 30.00 Surrogates 1,2-Dichloroethane-d4 106 105 64.0-140 Toluene d8 100 101 82.0-117 4-Bromofluorobenzene 101 102 85.0-115 Batch Information naiv,;cci c•aicil. VMS3151 Analytical Method: SW-846 8260E instrument: MSD4 Analyst: JHL Print Date 02,27;2014 Prep Batch VXX4918 Prep Method: SW-846 5030E Prep Date/Time: 02/25/2014 16:22 Spike Init Wt.Nol.: 40 mL Extract Vol: 40 mL Dupe Init Wt.Nol.: 40 mL Extract Vol: 40 mL N.C. Certification it 481 5500 Business or. US • 28405 Wilmington, NC t +1 910350 1903 1.•1910 3501557 www.sgs com Page 13 of 25 Member of me, SGS Glum ISUS SAI AN...I vr: nAI 1'f'�4 Batch Summary -1 Analytical Method: SW-846 6010C Prep Method: SW-846 3010A Prep Batch: MXX3238 Prep Date: 02/21/2014 08:31 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 40717 [MXX/3238] 130802 02/25/2014 10:27 MIP2310 ICP1 PSW LCS for HBN 40717 [MXX/3238] 130803 02/25/2014 10:33 MIP2310 ICP1 PSW LCSD for HBN 40717 [MXX/3238] 130804 02/25/2014 10:40 MIP2310 ICP1 PSW Effluent(130322MS) 130805 02/25/2014 10:53 MIP2310 ICP1 PSW Effluent(130322MSD) 130806 02/25/2014 11:00 MIP2310 ICP1 PSW Outfall 001 31400235001 02/25/2014 11:06 MIP2310 ICP1 PSW Outfall001(130424DUP) 130807 02/25/2014 11:13 MIP2310 ICP1 PSW Print Date 02/27/2014 N.0 Certification # 481 5500 Business 0r. US - 28405 • Wilmington. NC t +1 910 3501903 1 +1910 3501557 www.sgs corn Page 14 of 25 Member WO* SGSfirmaISGSSA) Method Blank Blank ID: MB for HBN 40717 [MXX/3238] Blank Lab ID: 130802 QC for Samples: 31400235001 Results by SW-846 6010C Parameter Lead Batch Information Result ND .Anaiy:icai Batch: MiP2310 Analytical Method: ISW-846 6010C Instrument: ICP1 Analyst: PSW Print Date: 02!27/20 14 Qual U DL 0.00794 Matrix: Water LOQ/CL Units 0.0100 mg/L Prep Batch: MXX3238 Prep Method: SW-846 3010A Prep Date/Time: 2/21/2014 8:31:26AM Prep Initial Wt./Vol.: 50 mL Prep Extract Vol. 50 rnL DF 1 N C Certification # 481 5500 Business Or. US•28405•Wilmington, NC t+19103501903 1+19103501557 www.sgs com Page 15 of 25 Limbo! of SGsciouoISGSSAI AN.\I ttl:.n1 1'r;Is;'vC.',vr 4 Blank Spike Summary Blank Spike ID: LCS for HBN 40717 [MXX/3238] Blank Spike Lab ID: 130803 Date Analyzed: 02/25/2014 10:33 QC for Samples: 31400235001 Results by SW-846 6010C Parameter Lead Batch Information Analytical Batch: MIP2310 Analytical Method SW-846 6010C Instrument: ICP1 Analyst: PSW Print Date: 02/27/2014 Spike Duplicate ID: LCSD for HBN 40717 [MXX/3238] Spike Duplicate Lab ID: 130804 Date Analyzed: 02/25/2014 10:40 Matrix: Water Blank Spike (mg/L) Spike Duplicate (mg/L) Rec % spike Result Rec % RPD (%) RPD CL 95 0.400 0.377 94 0.26 20.00 Prep Batch: MXX3238 Prep Method: SW-846 3010A Prep Date/Time: 02/21/2014 08:31 Spike Init Wt.NoI.: 50 mL Extract Vol: 50 mL Dupe Init Wt.Nol. 50 mL Extract Vol: 50 mL N C Certification # 481 5500 Business Dr US - 20405 • Wilmington, NC t rt 910350 1903 1+19103501557 wwwsgs corn Page 16 of 25 Member of the SGS Group ISG S SAI sG$ ANAUMWALIMONPECTNT. Duplicate Sample Summary Original Sample ID: 31400235001-D Duplicate Sample ID: 130807 QC for Samples: 31400235001 Results by SW-846 6010C Analysis Date: 02/25/2014 11:06 Analysis Date: 02/25/2014 11:13 Matrix: Water PARAMETER Original (mq/L) ual Duplicate (ma/L) gLiaj RPD (%1 RPD CL Lead 0.00798 J 0.0107 29* 20.00 Batch Information Analytical Batch: MI92310 Analytical Method: SW-846 6010C Instrument: ICP1 Analyst: PSW Prep Batch: MXX3238 Prep Method: SW-846 3010A Prep Date/Time: 02/21/2014 08:31 Print Date- 02/27/2014 N.C. Certification # 481 5500 Business Or. US • 29405 Wilmington, NC t +1910 3501903 I +1910 3501557 www.sgs com Membrr of Ihr SUS Chou; ISUSSAM Page 17 of 25 n,u„anCiA Potwaircenngs Batch Summary Analytical Method: SM 2540-D Client Sample ID MB for HBN 40660 [INO/2961] LCS for HBN 40660 [INO/2961] Outfall 001 Outfall 001(130424DUP) Print Date 02r27/2074 Prep Method: SM 2540-D Prep Batch: INO2961 Prep Date: 02/19/2014 10:41 Lab Sample ID Analysis Date 130666 02/19/2014 10:41 130667 02/19/2014 10:41 31400235001 02/19/2014 10:41 130668 02/19/2014 10:41 Analytical Batch Instrument Analyst INO2961 BAL10 PPH INO2961 BAL10 PPH IN02961 BAL10 PPH INO2961 BAL10 PPH N C. C ration # 481 5500 Business Dr. US 2B405 • Wilmington. NC t +1 9103501903 f+19103501557 www.sgs corn Page 18 of 25 Membe of the SGS Group ISGSSAI ,-- Method Blank Blank ID: MB for HBN 40660 [INO/2961] Blank Lab ID: 130666 QC for Samples: 31400235001 Results by SM 2540-D Parameter Total Suspended Solids Batch Information .".na vUc Gcilcn IO2961 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: PPH Print Date 022712014 Result ND Qua! U DL Matrix: Water LOQ/CL 2.50 25.0 Units mglL Prep Batch: IN02961 Prep Method: SM 2540-D Prep Date/Time: 2/19/2014 10:41:50AM Prep Initial Wt.Nol.: 1 mL Prep Extract Vol: 1 mL DF 1 N C. Certification # 48.1 5500 Business Dr. US - 28405 • Wilmington. NC t +1 910 3501903 IA 910 3501557 www.sgs corn Page 19 of 25 Member of Me SUS Group ISGS SA1 _SGS1 r- Blank Spike Summary Blank Spike ID: LCS for HBN 40660 [INO/2961] Blank Spike Lab ID: 130667 Date Analyzed: 02/19/2014 10:41 QC for Samples: 31400235001 • - Results by SM 2540-D Parameter Total Suspended Solids Batch Information Analytical Batch: IN02961 Analytical Method: SM 2540-D Instrument BAL10 Analyst: PPH Prim Date. 0212712014 Blank Spike (mg/L) Rep 81 Matrix: Water CL 80.0.120 Prep Batch: INO2961 Prep Method: SM 2540-D Prep DatefTime: 02/19/2014 10:41 Spike Init Wt.Nol.: 1 mL Extract Vol: 1 mL Dupe Init Wt.Nol.• Extract Vol N C Certification it 481 55C0 Business Dr. US - 28405 Wilmington. NC t.1 910350 1903 1.19103501557 www.sgs com Page 20 of 25 Membe+ of the SGS Group iSG S SA SGS_ Aruutncu PFRF�rcnvr-x Duplicate Sample Summary Original Sample ID: 31400235001-G Duplicate Sample ID: 130668 QC for Samples: 31400235001 �•- Results by SM 2540-D PARAMETER Total Suspended Solids Batch Information Analytical Batch: INO2961 Analytical Method: SM 2540-D Instrument: BAL10 Analyst. PPH Print Date 02.2 20t4 Analysis Date: 02/19/2014 10:41 Analysis Date: 02/19/2014 10:41 Matrix: Water Original (mg/L) ual Duplicate (mq/L) ual RPD (%) RPD CL 7.00 J 9.00 J 25* 20.00 N C Certification # 481 5500 Business Or US • 28405. Wilmington. NC t ft 910 3501903 10 910 3501557 www.sgs com Page 21 of 25 Member of thr SGS Croup ISGS SAI envirochem ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) 710 Bowsertown Road • Manteo, NC 27954 (252) 473-5702 NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 SGS Environmental Services, Inc. 5500 Business Drive Wilmington NC 28405 Attention: Michael Page Date of Report: Feb 27, 2014 Customer PO #: Report#: 2014-01819 Report to: Michael Page Project ID: 31400235 Lab ID 14-04452 Test Sample ID: 31400235001 Site: Method Collect DatelTime Matrix Sampled by 2/14/2014 2:00 PM Water Client Results Date Analyzed Inorganic Phenols EPA 420.1 <0.004 mg/L 02/20/2014 Comment Reviewed by: rLJI L, 4-- Report #:: 2014-01819 Page 22 of 25 Page 1 of 1 • SG$ CHAIN OF CUSTODY 1 CONVENTIONAL & SHALE PROJECT INFO: PROJECT: 31 Lf 00 2 3 PO. #: QUOTE #: SITE REF: TURN AROUND TIME: REPORT LEVEL: (see reverse) 0 Level 1 0 Level II 0 Level IV SPECIAL DELIVERABLES: 0 State of Origin: ❑ EDD: D Other. SEND DOCUMENTATION / RESULTS TO: COMPANY: 56 5 iJV l 1,1r1 f n 5 +0A CONTACT. MC ckCtel Pa P y ADDRESS: PHONE: e 10 3O 19 0 EMAIL: net scV1qeil, pQ9e C// 565, to WI INVOICE TO: (DCHECK IF SAME) COMPANY: CONTACT ADDRESS: PHONE: EMAIL: I Le o voi SPECIAL INSTRUCTIONS / COMMENTS: PRESERVATIVE ANALYSIS & METHOD ; i � • fti �'�qy ,;a� _� ' • AMPLE ID / DESCRIPTION DATE TIME QC TYPE CONT. MS MSD DUP (C, G) MATRIX QTY ,4-}i •-' Iiiir _ ; 1 µ 00 7 3 O Q! 3/isylo Ill.:UP tv 1 x • ,- • �� z [ • , • . A it. :qtrT COLLECTED/RELINQU1SHED BY (1): /.A _ / A ..raa. .. DATE: 2� ( TIME: . • • RECEIVED BY: i 4.1P -- R: I" • IJISHED BY (2): DATE: TIME: - C i ._., REMARKS N O M N 5, CA CO Page of S68 NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington. NC 28405 910 3501903 1910 7941613 www.sgs.com Momhor of tho cnc Rrrw in mng Cd1 CO CD (i1 SGSI ah CHAIN OF CUSTODY SOS ANALYTICAL PERSPECTIVES 5500 Business Drive Wilmington, NC 28405 +1910 3501903 WWW.SG$.COM CUEN1 /4 'IM4'. QES©vj2CF (A tl P ERR Reference l: 41ft f•mr)2-34 P PACE CONTACT: Fk ANIIIIMOYI1 PRONE HO:t ) I mum T arm °t° OF PROJEC : i `IO g11 i sin/ PWSID/WBS I:C 0 _i_____ REPORT8 TO: EMAU.- N ; N R\, ae calms GRAB li vi \ �� (- 0 ‘ \. e 40 ,,,, //// REMARKS WOE TO: nuaTE1 Q% IV L� P.O. NUMBER ;iiiin t; ......eg ., A • SAMPLE IDENTIFICATION OATS 1'iME MA?it1E . N s ear tc 09 l / * /la 7 6 r""�� Ole iltlfR e _ ilf,e2%,ith . N et 441‘ctitAtti giV:"Eilitil . 91;14 ii..W Jt l ram ,attJ ,mot tez . c . VAIN _ . !Vaili? f CO N0U18HED BY: (1) DA %G� y /TI,M�E1x ` ` 60 RECEIVEDj/1BY: 0( oils- 77 7 12,0 REPORT LEVEL: 0 Level 1 0 Level 1I O Level IV , REQUESTED TURNAROUND TIME: 0 RuA : Standard Relinquish By:121 Date Time Received By: SPECIAL DENVERABLES: State of Origin; 0 Trust Fund • O DoD O EDD: Other. Relinquished By: CB Date Time Received By: SPECIAL INSTRUCTIONS: • 'l b B'r"h-.• • . •r��A�^:.. .4r R%I��j{i-p b.•I�},.Kr"�. :4.kFi }r,� • •. '• '"L'`ar ', 7 . . ,i ' u+ ' nI..M1,i,Z .. TPA�:��: i .;��- �r ����: Jr � : ;/ •... INTAS�AOk✓Ni.'. �oL!^P 11 . �.�• i lt•'+eIY:C1`�k;1�/.1.-i ,h'•' _ �:• 1 • f� �• : � t.;1�:••"�r.py....)fii'; i!tF�•y .i.Cl,tiAfJi F��.q!1]�I "'��'!��i,r. ,ty�J� "• �.1}' .aidcetNat ,'.tr�• Not,#...1' '�rt..7•.' =f.:;d�....,P. ii.,.;' ... •• 'h.•: ♦'�� 1%' Klri•'� �_ r�aa.4r.ra'�'frt.o:;+i, ;:' • Ai.•�.'::'^F'�'•' Yg�.:r,1I Si1:�A•.s.S =.iw."..;M!3:...�•. , 0...-.• : .� r.�7, ' . .. .. {•i.r+wiyrM1.4M1?Zi.e.,..•.'-.w» �:t,• .....,w•.�.fTf., ANALYTICAL PERSPECTIVES IS NOW PART OF SGS, THE WORLD'S LEADING INSPECTION, VERIFICATION, TESTING AND CERTIFICATION COMPANY. Whita • Retetned by lab Yebw • Rstsined by Client Client: 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Comments: SGS North America Inc. Sample Receipt Checklist (SRC) Ammons Resource Group Work Order No.: 31400235 X Shipped Notes: Hand Delivered X COC Present on Receipt r)lo COC Additional Transmittal Forms _Custody Tape on Container X No Custody Tape X Samples Intact Samples Broken / Leaking X Chilled on Receipt Actual Temp.(s) in °C: 0 Thermometer ID#: Ambient on Receipt 1�Valk•in on Ice; Coming down to temp. Temperature Blank Present no X Sufficient Sample Submitted Insufficient Sample Submitted Chlorine absent X HNO3 < 2 X HCL<2 X Additional Preservatives verified (see notes) X Received Within Holding Time Not Received Within Holding Time X No Discrepancies Noted _Discrepancies Noted NCDENR notified of Discrepancies* X No Headspace present in VOC vials Headspace present in VOC vials >6mm H2SO4 Inspected and Logged in by: JTH Date: Mon-2/17/14 00:00 *NCDENR must be notified when collection, holding time or preservation requirements are not met. MI_11.7 Page 25 of 25 ARG .Ammons kesource Group 2040 Peach Grove Lane Zebulon, NC 27597 919-369-5679 fredammons@att.net February 11, 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Subject: JANUARY 2014 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the January 2014 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill, North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II, of Section D. (2.) of its NPDES Permit. Water samples will be collected and analyzed as required by the permit in February 2014. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Res9urce Group red riifnons ORC Enclosures: January 2014 DMR cc: Mr. Scott Milke, 140 West Franklin, LLC Mr. Mike Taylor, Chapel Hill REC R /E V FEB 272014 CEN ► r" ;L F1LEE DWQ/30G EFFLUENT NPDES PERMIT, NO. NCG510532 DISCHARGE NO. 001 MONTH January YEAR 2014 FACILITY NAME 140 WEST FRANKLIN CLASS NA COUNTY ORANGE CERTIFIED LABORATORY (1) SGS Environmental Services, Inc CERTIFICATION NO. 481 (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE 1 CERTIFICATION NO. 992126 PERSON(S) COLLECTING SAMPLES Fred Ammons ORC PHONE (919) 369-5679 CHECK BOX IF ORC HAS CHANGED ❑ NO FLOW / DISCHARGE FROM SITE * 0 Mail ORIGINAL and ONE COPY to: .A"ITN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 (SIARE ` BY THIS SIGN/(TURE, 1 CERTIFY THAT TIIIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. Pei'OR IN RESPONSIBLE CHARGE) //-rid DATE DATE Operator Arrival Time 2400 Clock Operator Time On Site ORC On Site? ** 50050 34030 34371 34010 81551 22417 34696 01051 00530 00400 32103 03604 00556 FLOW W N m W z N W C.:a .-. = TOLUENE TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) W z .7 = S 4 a 7. TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) _ 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFF)L51 INF D ..1 iW., ca IIRS !IRS Y/11/N MGD EGA, UG/L UG/L UG/L UG/L UG/L UG/L mg/L UG/L UG/L I 0.003031 2 1300 2 yes 0.003031 3 0.002461 4 0.002461 5 0.002461 6 0.002461 7 0.002461 8 0.002461 9 0.002461 10 1000 2 yes 0.002461 11 0.003513 12 0.003513 13 0.003513 14 0.003513 15 1130 2 yes 0.003513 16 0.003279 17 0.003279 18 0.003279 19 0.003279 20 0.003279 21 0.003279 22 1400 2 yes 0.003279 23 0.002361 24 0.002361 25 0.002361 26 0.002361 27 0.002361 28 0.002361 29 0.002361 30 0.002361 31 900 2 yes 0.002361 AVERAGE 0.002823 MAXIMUM MINIMUM Comp. (C) / Grab (G) G Daily Maximum 1.19 97 11 670 19 12 25 30 6<pH<9 0.38 300 monitor DWQ Form MR -I (I I/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NOT meet permit requirements x Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Scott Milke, 140 West Franklin, LLC Permittee (Please print or type) of ermittee*** Date quired unless submitted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date 126 West Franklin Street, Chapel Hill NC 27516 (919) 868-1678 February 28, 2017 ADDITIONAL CERTIFIED LABORATORIES Certified Laboratory (2) Environmental Testing Solutions, Inc Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES 37 Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wqs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 ARG Ammons Resource Group 2040 Peach Grove Lane Zebulon, NC 27597 919-369-5679 fredammons@att. net January13, 2014 To Whom It May Concern Central Files North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 JAN 2 8 2014 'vL"I`J i iiAL HiLE: DWQI30G Subject: DECEMBER 2013 DISCHARGE MONITORING REPORT 140 WEST FRANKLIN, LLC 140 WEST FRANKLIN STREET CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA NPDES PERMIT NO. NCG510532 Dear Sir/Madam: Attached is the December 2013 Discharge Monitoring Report for the 140 West Franklin site on Franklin Street in Chapel Hill, North Carolina. This work was conducted under NPDES Permit No. NCG510532. Discharge from site dewatering activities to outfall 001 began May 17, 2012. Flow rates were recorded and documented and were below the permitted daily maximum limits. This information is submitted as required by Part II, of Section D. (2.) of its NPDES Permit. Water samples will be collected and analyzed as required by the permit in the first quarter of 2014. If you have any questions or need additional information, please feel free to contact me at 919- 369-5679. Sincerely, Ammons Resource Group F ed mmons ORC Enclosures: December 2013 DMR cc: Mr. Scott Milke, 140 West Franklin, LLC Mr. Mike Taylor, Chapel Hill EFFLUENT NPDES PERMIT NO. NCG510532 DISCHARGE NO. 001 MONTH December FACILITY NAME 1.40 WEST FRANKLIN CERTIFIED LABORATORY (1) SGS Environmental Services, Inc CERTIFICATION NO. 481 (list additional laboratories on the backside/page 2 of this form) OPERATOR IN RESPONSIBLE CHARGE (ORC) Fred Ammons GRADE I CERTIFICATION NO. 992126 CLASS NA COUNTY ORANGE YEAR 2013 PERSON(S) COLLECTING SAMPLES Fred Ammons CHECK BOX IF ORC HAS CHANGED ❑ Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 ORC PHONE (919) 369-5679 NO FLOW / DISCHARGE FROM SITE * II F OPERATOR IN RESPONSIBLE CHARGE) BY THIS SIG ATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. (SI DATE 0 DATE Operator Arrival Time 2400 aock Operator Time On Site ORC On Site? ** 50050 34030 34371 34010 81551 22417 1 34696 01051 00530 00400 32103 03604 00556 FLOW BENZENE ETHYLBENZENE TOLUENE, TOTAL XYLENES METHYL TERT_BUTYL ETHER (MTBE) NAPHTHALENE TOTAL LEAD TOTAL SUSPENDED SOLIDS (TSS) a 1,2 DICHLOROETHANE (1,2 DCA) TOTAL PHENOLS OIL AND GREASE EFFa 1 INF 0 DAILY RATE IIRS HRS Y/B/N MGD UG/L UG/L UG/L UG/L UG/L UG/L UG/L mg/L UG/L UG/L 1 0.001186 2 0.001186 3 0.001186 4 0.001186 5 1930 2 yes 0.001186 6 0.001090 7 0.001090 8 0.001090 9 0.001090 10 0.001090 11 0.001090 12 0.001090 13 0.001090 14 0.001090 15 0.001090 16 1000 2 yes 0.001090 17 0.001249 18 0.001249 . 19 0.001249 20 0.001249 21 0.001249 22 1000 2 yes 0.001249 23 0.001815 24 0.001815 25 0.001815 26 0.001815 27 0.001815 28 1300 2 yes 0.001815 29 0.001815 30 0.001815 31 0.001815 AVERAGE 0.001347 MAXIMUM MINIMUM Comp. (C) / Grab (G) G Daily Maximum _ 1.19 97 11 670 19 12 25 30 6<pH<9_ 0.38 300 monitor_ DWQ Form MR-1 (1 1/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) All monitoring data and sampling frequencies do NOT meet permit requirements Compliant Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Scott Milke, 140 West Franklin, LLC Permittee (Please print or type) Sign lace*** Date (Required unless submitted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date 126 West Franklin Street, Chapel Hill NC 27516 (919) 868-1678 February 28, 2017 Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wqs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G _0204. *** Signature of Permittee: if signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2