NC0000396_Field Blank Didn't Meet Quality Control Criteria_20200902

Action History (UTC-05:00) Eastern Time (US & Canada)
Submit
Submit
by Anonymous User 9/2/2020 12:25:02 PM (Supplemental Submittal)
by Bennett, Tilman B 5/16/2021 8:31:32 PM (Supplemental Info Submittal)
p Information Included Seems Excessive for Records
• Bennett, Tilman B assigned the task to Bennett, Tilman B 5/16/2021 8:30 PM
• The task was assigned to Thedford, Wren, Bennett, Bradley 9/2/2020 12:25 PM

NPDES Wastewater EDMR Supplemental Information Upload
NORTH CAROLINA
Ertrlranmrrttat Quea(ity
Initial Review Information
Updated ID#:*
IMFORTANfFEVIENERSHOULDVERIFY and revise here if necessary.
NC0000396
How should this project be handled?*
(' File r Discard
Information Submitted on 9/2/2020
Submitter Information
Name: Teresa Williams
VNio is submitting the information?
Email Address:*
[e-mail]
Submittal Information
The Division of Water Resources (DWR) is providing this site to allow for the upload of required supplemental
information associated with discharge monitoring reports (DMR). All DMR data is required to be submitted
electronically through the eDMR system and should not be submitted here. Division staff will review all
uploaded documents and will only maintain required information. Documents such as laboratory reports are not required
to be submitted and will not be maintained in the system.
Project Information:
Rease supply the pernit number for this project.
Existing ID#* FtxrritNull ter
NC0000396
Exarrples: NCxxxxxxx or NCGxxxxxx
Facility Name:*
Asheville Steam Electric Plant
County: Buncombe
Please upload all files that need to be
submited. *
Click the upload button or drag and drop files here to attach docurrent
08-27-20 12520B NC0000396 Asheville July DMR
3.7MB
Upload Cover Memo.pdf
Only pdf files are accepted.
Comments about the attachments:
Supplemental information regarding Hg field blank detection.
* 17 By checking the box and signing box below, I certify that:
— I L....... .. �...... +.. �.. ......� �...+.. .....J .........I..+.. �..F...w...+�.... .... +L. �.. f......

o Ilavc ylVCI I LI uC, al.l.ul dLC, aIlU l.ul1IF/ICLC IIIIUI IlldLlull ull LI IIJ IUI Ill,
o I agree that submission of this Supplemental Information form is a "transaction" subject to Chapter 66, Article 40 of the
NC General Statutes (the "Uniform Electronic Transactions Act")
o I agree to conduct this transaction by electronic means pursuant to Chapter 66, Article 40 of the NC General Statutes
(the "Uniform Electronic Transactions Act");
o I understand that an electronic signature has the same legal effect and can be enforced in the same way as a written
signature; AND
o I intend to electronically sign and submit the Supplemental Information form."
Full Name: Teresa Williams
Signature:
Nag, 1.01,0t4
Date Submitted: 09/02/2020

Antonio D. Price, PE
Plant General Manager
Asheville Combined Cycle Station

Duke Energy Progress
ASVL PLT | 46 Duke Energy Lane
Arden, NC 28704

o: 828-650-0620
f: 828-650-0701
[e-mail]

Submitted Electronically

File No.: 12520B

August 27, 2020

Memo

To: Central Files
NCDEQ, Division of Water Resources
1617 Mail Service Center
Raleigh, NC 27699-1617

From: Duke Energy Progress
Asheville Combined Cycle Station
46 Duke Energy Lane
Arden, NC 28704

RE: Asheville Steam Electric Generating Plant
Buncombe County
NPDES Number NC0000396
Discharge Monitoring Report (DMR)

In accordance with condition I.A. (18) 1., replaced by electronic signature and submission
guidelines, the July 2020 NPDES eDMR for Duke Energy Progress’s Asheville Steam Electric
Plant – NPDES Permit Number NC0000396 has been submitted.

The Outfall 001, and Outfall 001 Upstream low-level mercury field blank samples collected July
7, and 23, 2020 did not meet quality control criteria in accordance with EPA Method 1631E. Per
Division guidance ("NPDES Mercury Requirement- EPA Method 1631 Additional
Information"), the mercury field blank samples have been noted in the eDMR comments section,
and the associated analytical reports are attached to this memo and uploaded electronically to the
eDMR Supplement Data Upload server.

Please contact Ms. Teresa Williams at [phone] or Ms. Mariea Keezel at [phone]
with any questions concerning the data in this submittal.

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
Report Comments:
Qualifiers included for the following parameters:
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
Applied to: Outfall 001 Chloride and Bromide on 7/23/20;
R1 RPD value was outside of control limits.
Applied to: Outfall 001 Upstream Bromide on 7/7/20.
Hg Field blank detection greater than allowable.
Applied to: Outfall 001 on 7/7/20 and 7/23/20. Outfall 001 Upstream on 7/7/2020.
Confirmed cause as lab contamination and lab reports are uploaded to DEQ server.

SAMPLING LOCATION: DOWNSTREAM DISCHARGE NO.: 001

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateSample TimeNo Reporting Reason****2400 clock
1
2
3
4
5
6
7 1400
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
00010 01002 71870 01025 CO034 01040 00900 01049 COMER
Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly
Grab Grab Grab Grab Grab Grab Grab Grab Grab
TEMP-C As-TOTAL BROMIDE CD-DISSV TOT CR CONC CU-DISSV TOT HARD PB-DISSV MERCURY -
deg c ug/l mg/l ug/l ug/l ug/l mg/l ug/l ng/l
22.5 0.13 < 0.1 < 0.08 0.92 1.4 9.1 0.14 2.87
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
22.5 0.13 0 0 0.92 1.4 9.1 0.14 2.87
22.5 0.13 0 0 0.92 1.4 9.1 0.14 2.87
22.5 0.13 0 0 0.92 1.4 9.1 0.14 2.87

SAMPLING LOCATION: DOWNSTREAM DISCHARGE NO.: 001 (Continue)

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateSample TimeNo Reporting Reason****2400 clock
1
2
3
4
5
6
7 1400
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
01147 70295 00070 01090
Monthly Monthly Monthly Monthly
Grab Grab Grab Grab
Se-TOTAL RES/DISS TURBIDTY ZN-DISSV
ug/l mg/l ntu ug/l
< 0.5 26 7.5 < 5
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
0 26 7.5 0
0 26 7.5 0
0 26 7.5 0

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001 NO DISCHARGE*: NO

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
50050 00400 CO530 CO600 CO665 01002 01012 71870 01027
Weekly Weekly Weekly Monthly Monthly Weekly Weekly Weekly Weekly
Instantaneous Grab Grab Grab Grab Grab Grab Grab Grab
FLOW pH TSS - Conc TOTAL N -TOTAL P - Conc As-TOTAL BERYLIUM BROMIDE CADMIUM
mgd su mg/l mg/l mg/l ug/l ug/l mg/l ug/l
0.3 8.4 < 2.5 2.1 0.17 < 10 < 1 2.6 < 1
0.73 8.4 5.3 < 10 < 1 3.6 < 1
8.5
1.27 8.5 3.2 < 10 < 1 1.6 < 1
1.57 8.2 2.6 < 10 < 1 1.9 < 1
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
30
0.9675 2.775 2.1 0.17 0 0 2.425 0
1.57 8.5 5.3 2.1 0.17 0 0 3.6 0
0.3 8.2 0 2.1 0.17 0 0 1.6 0

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001 NO DISCHARGE*: NO (Continue)

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
00940 01034 01042 00951 00900 01051 COMER 01067 00556 TGP3B 01147
Weekly Weekly Weekly Weekly Weekly Weekly Weekly Weekly Weekly Monthly Weekly
Grab Grab Grab Grab Grab Grab Grab Grab Grab Grab Grab
CHLORIDE Cr-TOTAL COPPER F-TOTAL TOT HARD LEAD MERCURY -NICKEL OIL-GRSE CERI7DPF Se-TOTAL
mg/l ug/l ug/l mg/l mg/l ug/l ng/l ug/l mg/l pass/fail ug/l
101 < 5 8.3 0.36 162 < 5 2.28 < 5 7.3 < 10
116 < 5 7.4 0.41 172 < 5 2.26 < 5 < 5 1 < 10
119 < 5 8.5 0.48 145 < 5 11.5 < 5 < 5 < 10
138 < 5 5.8 0.41 223 < 5 4.34 < 5 < 5 < 10
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
15
118.5 0 7.5 0.415 175.5 0 5.095 0 1.825 1 0
138 0 8.5 0.48 223 0 11.5 0 7.3 1 0
101 0 5.8 0.36 145 0 2.26 0 0 1 0

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001 NO DISCHARGE*: NO (Continue)

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
01077 70295 00070 01092 THP3B
Weekly Weekly Weekly Weekly
Grab Grab Grab Grab Grab
SILVER RES/DISS TURBIDTY ZINC CER7DCHV
ug/l mg/l ntu ug/l percent
< 5 407 2 < 10
< 5 425 4.7 23.6
< 5 445 3.8 < 10
< 5 523 2.7 < 10
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
0 450 3.3 5.9
0 523 4.7 23.6
0 407 2 0

SAMPLING LOCATION: UPSTREAM DISCHARGE NO.: 001

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateSample TimeNo Reporting Reason****2400 clock
1
2
3
4
5
6
7 1300
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
00010 01002 71870 01025 CO034 01040 00900 01049 COMER
Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly
Grab Grab Grab Grab Grab Grab Grab Grab Grab
TEMP-C As-TOTAL BROMIDE CD-DISSV TOT CR CONC CU-DISSV TOT HARD PB-DISSV MERCURY -
deg c ug/l mg/l ug/l ug/l ug/l mg/l ug/l ng/l
21.8 0.14 < 0.1 < 0.08 < 0.5 1.4 9.28 0.16 3.98
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
21.8 0.14 0 0 0 1.4 9.28 0.16 3.98
21.8 0.14 0 0 0 1.4 9.28 0.16 3.98
21.8 0.14 0 0 0 1.4 9.28 0.16 3.98

SAMPLING LOCATION: UPSTREAM DISCHARGE NO.: 001 (Continue)

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateSample TimeNo Reporting Reason****2400 clock
1
2
3
4
5
6
7 1300
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
01147 70295 00070 01090
Monthly Monthly Monthly Monthly
Grab Grab Grab Grab
Se-TOTAL RES/DISS TURBIDTY ZN-DISSV
ug/l mg/l ntu ug/l
< 0.5 24.8 7.4 < 5
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
0 24.8 7.4 0
0 24.8 7.4 0
0 24.8 7.4 0

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001A NO DISCHARGE*: NO

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
50050 CO530 00556
Monthly Monthly Monthly
Estimate Grab Grab
FLOW TSS - Conc OIL-GRSE
mgd mg/l mg/l
0.35 < 2.5 < 5
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
30 15
0.35 0 0
0.35 0 0
0.35 0 0

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001B NO DISCHARGE*: YES

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
50050 CO530 00556
Monthly Monthly Monthly
Estimate Grab Grab
FLOW TSS - Conc OIL-GRSE
mgd mg/l mg/l
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
30 15

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001C NO DISCHARGE*: NO

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
50050 CO530 00556
Monthly Monthly Monthly
Estimate Grab Grab
FLOW TSS - Conc OIL-GRSE
mgd mg/l mg/l
0.17 < 2.5 6.6
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
30 15
0.17 0 6.6
0.17 0 6.6
0.17 0 6.6

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001D NO DISCHARGE*: YES

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
50050 CO530 00556
Monthly Monthly Monthly
Estimate Grab Grab
FLOW TSS - Conc OIL-GRSE
mgd mg/l mg/l
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
30 15

SAMPLING LOCATION: DOWNSTREAM DISCHARGE NO.: 001E

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateSample TimeNo Reporting Reason****2400 clock
1
2
3
4
5
6
7 920
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
00010
Monthly
Grab
TEMP-C
deg c
21.6
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
21.6
21.6
21.6

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 002 NO DISCHARGE*: NO

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
50050 00010 00400 CO034 01042
Monthly Monthly Weekly Monthly Monthly
Calculated Recorder Grab Grab Grab
FLOW TEMP-C pH TOT CR CONC COPPER
mgd deg c su ug/l ug/l
0.25 27.6 8.9 < 5 < 5
8.3
7.7
7.6
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
44.4
0.25 27.6 0 0
0.25 27.6 8.9 0 0
0.25 27.6 7.6 0 0

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 004 NO DISCHARGE*: YES

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
50050 01042 01045
Once per discharge Once per discharge Once per discharge
Instantaneous Instantaneous Grab
FLOW COPPER IRON
mgd mg/l mg/l
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
1 1

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 005 NO DISCHARGE*: YES

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
50050 CO530 01002 COMER 00630 01147
Monthly Monthly Quarterly Quarterly Quarterly Quarterly
Instantaneous Grab Grab Grab Grab Grab
FLOW TSS - Conc As-TOTAL MERCURY - Conc NO2&NO3 Se-TOTAL
mgd mg/l ug/l ng/l mg/l ug/l
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
30 8 356 4.4 12

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 101 NO DISCHARGE*: NO

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
50050 00010 00400 CO530 01002 01007 01022 71870 01027
Quarterly Quarterly Quarterly Quarterly Quarterly Quarterly Quarterly Quarterly Quarterly
Estimate Grab Grab Grab Grab Grab Grab Grab Grab
FLOW TEMP-C pH TSS - Conc As-TOTAL BARIUM BORON BROMIDE CADMIUM
mgd deg c su mg/l ug/l mg/l ug/l mg/l ug/l
0.03 16 6.4 < 2.5 < 10 0.0301 3550 1.1 < 1
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
30
0.03 16 0 0 0.0301 3550 1.1 0
0.03 16 6.4 0 0 0.0301 3550 1.1 0
0.03 16 6.4 0 0 0.0301 3550 1.1 0

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 101 NO DISCHARGE*: NO (Continue)

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
00940 01034 CO034 00094 01042 00951 00900 01051 COMER 01067 00630
Quarterly Quarterly Monthly Quarterly Quarterly Quarterly Quarterly Quarterly Quarterly Quarterly Quarterly
Grab Grab Grab Grab Grab Grab Grab Grab Grab Grab Grab
CHLORIDE Cr-TOTAL TOT CR CNDUCTVY COPPER F-TOTAL TOT HARD LEAD MERCURY -NICKEL NO2&NO3
mg/l ug/l ug/l umhos/cm ug/l mg/l mg/l ug/l ng/l ug/l mg/l
117 < 5 1160 < 5 0.12 557 < 5 1.51 12.2 0.52
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
230 25
117 0 1160 0 0.12 557 0 1.51 12.2 0.52
117 0 1160 0 0.12 557 0 1.51 12.2 0.52
117 0 1160 0 0.12 557 0 1.51 12.2 0.52

SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 101 NO DISCHARGE*: NO (Continue)

**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR = No Visitation – Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation – Holiday

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
DateComposite Sample TimeTotal Composite TimeOperator Arrival TimeOperator Time On SiteORC On Site?**No Reporting Reason****2400 clock Hrs 2400 clock Hrs Y/B/N
1 N
2 N
3 N
4 N
5 N
6 N
7 500 10 Y
8 N
9 N
10 N
11 N
12 N
13 N
14 500 10 Y
15 N
16 730 4.2 B
17 N
18 N
19 N
20 N
21 700 0.8 B
22 N
23 500 7 Y
24 N
25 N
26 N
27 N
28 530 12.2 Y
29 N
30 N
31 N
00556 01147 70295 00945 01059 01092
Quarterly Quarterly Quarterly Quarterly Quarterly Quarterly
Grab Grab Grab Grab Grab Grab
OIL-GRSE Se-TOTAL RES/DISS SULFATE THALLIUM ZINC
mg/l ug/l mg/l mg/l ug/l ug/l
< 5 1.3 802 315 < 10 < 10
Monthly Average Limit:
Monthly Average:
Daily Maximum:
Daily Minimum:
15 5 125700
0 1.3 802 315 0 0
0 1.3 802 315 0 0
0 1.3 802 315 0 0

Electronically Certified by Mariea Keezel on 2020-08-26 07:55:31.815
ORC/Certifier Signature:Mariea Keezel Phone #:[phone] Date

I certify that this report is accurate and complete to the best of my knowledge.

The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment.
Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be
provided within 5 days of the time the permittee becomes aware of the circumstances. The written submission shall be made as required by part II.E.6 of the
NPDES permit.

Electronically Signed by Antonio D Price on 2020-08-26 08:30:11.909
Permittee/Submitter Signature: ***Antonio D Price Phone #:[phone] Date
Permittee Address: 46 Duke Energy Ln Arden NC 28704 Permit Expiration Date: 11/30/2023
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the
system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations.

CERTIFIED LABORATORIES

PARAMETER CODES
Parameter Code assistance may be obtained by visiting https://deq.nc.gov/about/divisions/water-resources/edmr/user-documentation.

FOOTNOTES
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: YES indicates that No Flow/Discharge occurred and, as a result, no data is reported for any parameter on the DMR for the
entire monitoring period.
** ORC on Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: If signed by other than the permittee, then delegation of the signatory authority must be on file with the state per 15A NCAC 2B
.0506(b)(2)(D).

Discharge Monitoring Report - Copy Of Record (COR_NC0000396_Ver_1.0_7_2020.pdf)
NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.2 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Mariea H Keezel ORC CERT NUMBER: 985770
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 07-2020 (July 2020)VERSION: 1.0 STATUS: Submitted
COMPLIANCE STATUS: Compliant CONTACT PHONE #: [phone] SUBMISSION DATE: 08/26/2020
LAB NAME: Asheville Steam Electric Plant, Pace Analytical Services, Inc., Environmental Testing Solutions, Duke Energy Analytical Laboratory
CERTIFIED LAB #: 5055, 40, 12, 37, 248
PERSON(s) COLLECTING SAMPLES: Matthew Fields, R. Smith, K. Hussey
#=CL#
July 14, 2020
LIMS USE: FR - MARIEA KEEZEL
LIMS OBJECT ID: 92484908
92484908
Project:
Pace Project No.:
RE:
Ms. Mariea Keezel
Duke Energy
,
OUTFALL 001 070720
Dear Ms. Keezel:
Enclosed are the analytical results for sample(s) received by the laboratory on July 07, 2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
cc:Mr. Matthew Fields, Duke Energy Progress, Inc.
Program Manager, Duke Energy
Ms. Teresa Williams, Duke Energy Progress, Inc.
Mr. Robert Wylie, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 22
TLW
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 2 of 22
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92484908001 FIELD BLANK EPA 1631E 1 PASI-ANMP
92484908002 OUTFALL 001_2020/07/07_1105_N EPA 1664B 1 PASI-CWAM
EPA 200.7 Rev 4.4 1994 11 PASI-ADS
EPA 1631E 1 PASI-ANMP
SM 2540C-2011 1 PASI-ARED
SM 2540D-2011 1 PASI-ARED
TKN+NO3+NO2 Calculation 1 PASI-AEWS
EPA 300.0 Rev 2.1 1993 2 PASI-ACDC
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 1 PASI-AKDF1
EPA 365.1 Rev 2.0 1993 1 PASI-AMDW
SM 4500-Cl-E-2011 1 PASI-ACJL
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 3 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Sample:FIELD BLANK Lab ID:92484908001 Collected:07/07/20 11:05 Received:07/07/20 16:33 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 0.534 ng/L 07/13/20 14:49 7439-97-607/09/20 14:070.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/14/2020 10:59 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Sample:OUTFALL
001_2020/07/07_1105_N
Lab ID:92484908002 Collected:07/07/20 11:05 Received:07/07/20 16:33 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
HEM, Oil and Grease
Oil and Grease 7.3 mg/L 07/13/20 09:205.0 1
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 07/08/20 18:10 7440-38-207/08/20 01:4710.0 1
Beryllium ND ug/L 07/08/20 18:10 7440-41-707/08/20 01:471.0 1
Cadmium ND ug/L 07/08/20 18:10 7440-43-907/08/20 01:471.0 1
Chromium ND ug/L 07/08/20 18:10 7440-47-307/08/20 01:475.0 1
Copper 8.3 ug/L 07/08/20 18:10 7440-50-807/08/20 01:475.0 1
Lead ND ug/L 07/08/20 18:10 7439-92-107/08/20 01:475.0 1
Nickel ND ug/L 07/08/20 18:10 7440-02-007/08/20 01:475.0 1
Selenium ND ug/L 07/08/20 18:10 7782-49-207/08/20 01:4710.0 1
Silver ND ug/L 07/08/20 18:10 7440-22-407/08/20 01:475.0 1
Hardness, Total(SM 2340B)162000 ug/L 07/08/20 18:1007/08/20 01:476621
Zinc ND ug/L 07/08/20 18:10 7440-66-607/08/20 01:4710.0 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 2.28 ng/L 07/13/20 11:19 7439-97-607/09/20 14:070.50 1
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 407 mg/L 07/09/20 19:5625.0 1
Analytical Method: SM 2540D-2011
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids ND mg/L 07/09/20 20:462.5 1
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen Calculation
Total Nitrogen 2.1 mg/L 07/14/20 10:560.52 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 2.6 mg/L 07/08/20 16:16 24959-67-90.10 1
Fluoride 0.36 mg/L 07/08/20 16:16 16984-48-80.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 1.2 mg/L 07/10/20 04:40 7727-37-907/09/20 17:510.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3 0.83 mg/L 07/08/20 12:480.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/14/2020 10:59 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Sample:OUTFALL
001_2020/07/07_1105_N
Lab ID:92484908002 Collected:07/07/20 11:05 Received:07/07/20 16:33 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
365.1 Phosphorus, Total
Phosphorus 0.17 mg/L 07/09/20 19:44 7723-14-007/08/20 15:510.050 1
Analytical Method: SM 4500-Cl-E-2011
Pace Analytical Services - Asheville
4500 Chloride
Chloride 101 mg/L 07/08/20 00:45 16887-00-610.0 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/14/2020 10:59 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552780
EPA 1664B
EPA 1664B
1664 HEM, Oil and Grease
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2937466
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Oil and Grease mg/L ND 5.0 07/13/20 09:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2937467LABORATORY CONTROL SAMPLE:
LCSSpike
Oil and Grease mg/L 44.440 111 78-114
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2937468MATRIX SPIKE SAMPLE:
MSSpike
Result
92484488002
Oil and Grease mg/L 43.340 85 78-1149.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/14/2020 10:59 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552200
EPA 1631E
EPA 1631E
1631E Mercury,Low Level
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908001, 92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2934542
Associated Lab Samples:92484908001, 92484908002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 07/13/20 14:41
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2934543
Associated Lab Samples:92484908001, 92484908002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 07/13/20 14:56
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2934544
Associated Lab Samples:92484908001, 92484908002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 07/13/20 15:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2934545LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ng/L 4.925 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2934546MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484863001
2934547
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 84 71-125100 17250.00116
ug/L
22.2 26.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2934548MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484733003
2934549
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 84 71-12589 5250.334J 21.4 22.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/14/2020 10:59 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
551744
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2932423
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Arsenic ug/L ND 10.0 07/08/20 18:01
Beryllium ug/L ND 1.0 07/08/20 18:01
Cadmium ug/L ND 1.0 07/08/20 18:01
Chromium ug/L ND 5.0 07/08/20 18:01
Copper ug/L ND 5.0 07/08/20 18:01
Hardness, Total(SM 2340B)ug/L ND 662 07/08/20 18:01
Lead ug/L ND 5.0 07/08/20 18:01
Nickel ug/L ND 5.0 07/08/20 18:01
Selenium ug/L ND 10.0 07/08/20 18:01
Silver ug/L ND 5.0 07/08/20 18:01
Zinc ug/L ND 10.0 07/08/20 18:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2932424LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 491500 98 85-115
Beryllium ug/L 500500 100 85-115
Cadmium ug/L 494500 99 85-115
Chromium ug/L 490500 98 85-115
Copper ug/L 498500 100 85-115
Hardness, Total(SM 2340B)ug/L 3210033100 97 85-115
Lead ug/L 495500 99 85-115
Nickel ug/L 498500 100 85-115
Selenium ug/L 486500 97 85-115
Silver ug/L 238250 95 85-115
Zinc ug/L 477500 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932425MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484908002
2932426
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 113 70-130111 2500ND564554
Beryllium ug/L 500 109 70-130107 2500ND545533
Cadmium ug/L 500 110 70-130108 2500ND551540
Chromium ug/L 500 107 70-130105 3500ND538524
Copper ug/L 500 109 70-130108 05008.3 553 551
Hardness, Total(SM 2340B)ug/L 33100 93 70-13090 133100162000193000192000
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932425MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484908002
2932426
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Lead ug/L 500 104 70-130102 2500ND518508
Nickel ug/L 500 105 70-130104 2500ND529520
Selenium ug/L 500 112 70-130108 4500ND561542
Silver ug/L 250 104 70-130102 2250ND260255
Zinc ug/L 500 104 70-130102 2500ND524514
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932427MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484742008
2932428
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 109 70-130109 0500ND544544
Beryllium ug/L 500 105 70-130104 1500ND524522
Cadmium ug/L 500 108 70-130107 1500ND541534
Chromium ug/L 500 104 70-130104 050013.4 532 532
Copper ug/L 500 106 70-130107 0500ND534536
Hardness, Total(SM 2340B)ug/L 33100 97 70-13099 13310093500125000126000
Lead ug/L 500 104 70-130103 1500ND518513
Nickel ug/L 500 105 70-130104 1500ND527520
Selenium ug/L 500 111 70-130109 150014.8 568 562
Silver ug/L 250 102 70-130102 0250ND254254
Zinc ug/L 500 103 70-130102 1500ND518512
REPORT OF LABORATORY ANALYSIS
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Page 10 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552292
SM 2540C-2011
SM 2540C-2011
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2935351
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 07/09/20 19:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2935352LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 260250 104 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92484742017
2935353SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 79.0 1667.0
Parameter Units
Dup
Result QualifiersRPDResult
92484854002
2935354SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 740 2752
REPORT OF LABORATORY ANALYSIS
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Page 11 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552260
SM 2540D-2011
SM 2540D-2011
2540D Total Suspended Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2935144
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Total Suspended Solids mg/L ND 2.5 07/09/20 20:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2935145LABORATORY CONTROL SAMPLE:
LCSSpike
Total Suspended Solids mg/L 246250 98 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92485186001
2935625SAMPLE DUPLICATE:
Total Suspended Solids mg/L 261 8284
Parameter Units
Dup
Result QualifiersRPDResult
92484854001
2935626SAMPLE DUPLICATE:
Total Suspended Solids mg/L 206 D637142
REPORT OF LABORATORY ANALYSIS
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Page 12 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
551810
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2932595
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Bromide mg/L ND 0.10 07/08/20 13:21
Fluoride mg/L ND 0.10 07/08/20 13:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2932596LABORATORY CONTROL SAMPLE:
LCSSpike
Bromide mg/L 2.22.5 90 90-110
Fluoride mg/L 2.52.5 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932597MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484552010
2932598
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L 2.5 99 90-11097 22.50.21 2.7 2.6
Fluoride mg/L 2.5 97 90-11096 12.50.12 2.6 2.5
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932599MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484854001
2932600
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L 2.5 98 90-11095 32.50.17 2.6 2.5
Fluoride mg/L 2.5 99 90-11096 32.50.45 2.9 2.8
REPORT OF LABORATORY ANALYSIS
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Page 13 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552197
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2934519
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Nitrogen, Kjeldahl, Total mg/L ND 0.50 07/10/20 04:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2934520LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 9.810 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2934521MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92483970001
2934522
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L M1109390-11088 610ND9.8 9.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2934523MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92483970002
2934524
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 94 90-11098 410ND9.6 10.1
REPORT OF LABORATORY ANALYSIS
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Page 14 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
551779
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
353.2 Nitrate + Nitrite, preserved
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2932503
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Nitrogen, NO2 plus NO3 mg/L ND 0.040 07/08/20 12:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2932504LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, NO2 plus NO3 mg/L 2.52.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932505MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484430002
2932506
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, NO2 plus NO3 mg/L 2.5 101 90-11097 12.58.0 10.5 10.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932507MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484495001
2932508
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, NO2 plus NO3 mg/L M12.5 61 90-11065 12.516.1 17.6 17.7
REPORT OF LABORATORY ANALYSIS
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Page 15 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
551957
EPA 365.1 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
365.1 Phosphorus, Total
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2933482
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Phosphorus mg/L ND 0.050 07/09/20 19:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2933483LABORATORY CONTROL SAMPLE:
LCSSpike
Phosphorus mg/L 2.52.5 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2933484MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484689004
2933485
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Phosphorus mg/L 2.5 100 90-110100 02.50.047J 2.5 2.5
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2933486MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484689005
2933487
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Phosphorus mg/L 2.5 100 90-110101 12.50.053 2.6 2.6
REPORT OF LABORATORY ANALYSIS
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Page 16 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
551723
SM 4500-Cl-E-2011
SM 4500-Cl-E-2011
4500 Chloride
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92484908002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2932369
Associated Lab Samples:92484908002
Matrix:Water
Analyzed
Chloride mg/L ND 1.0 07/08/20 00:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2932370LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/L 20.520 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484727001
2932385
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L 10 92 90-11092 0100.68J 9.9 9.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2932386MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92484727002
2932387
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L 10 93 90-11094 1100.74J 10.0 10.1
REPORT OF LABORATORY ANALYSIS
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Page 17 of 22
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Page 18 of 22
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92484908
OUTFALL 001 070720
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92484908002 552780OUTFALL 001_2020/07/07_1105_N EPA 1664B
92484908002 551744 551760OUTFALL 001_2020/07/07_1105_N EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92484908001 552200 552730FIELD BLANK EPA 1631E EPA 1631E
92484908002 552200 552730OUTFALL 001_2020/07/07_1105_N EPA 1631E EPA 1631E
92484908002 552292OUTFALL 001_2020/07/07_1105_N SM 2540C-2011
92484908002 552260OUTFALL 001_2020/07/07_1105_N SM 2540D-2011
92484908002 553096OUTFALL 001_2020/07/07_1105_N TKN+NO3+NO2
Calculation
92484908002 551810OUTFALL 001_2020/07/07_1105_N EPA 300.0 Rev 2.1 1993
92484908002 552197 552374OUTFALL 001_2020/07/07_1105_N EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92484908002 551779OUTFALL 001_2020/07/07_1105_N EPA 353.2 Rev 2.0 1993
92484908002 551957 552298OUTFALL 001_2020/07/07_1105_N EPA 365.1 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993
92484908002 551723OUTFALL 001_2020/07/07_1105_N SM 4500-Cl-E-2011
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Page 19 of 22
Page 20 of 22
Page 21 of 22
Page 22 of 22
#=CL#
August 07, 2020
LIMS USE: FR - MARIEA KEEZEL
LIMS OBJECT ID: 92487550
92487550
Project:
Pace Project No.:
RE:
Ms. Mariea Keezel
Duke Energy
,
OUTFALL 001 072320
Dear Ms. Keezel:
Enclosed are the analytical results for sample(s) received by the laboratory on July 23, 2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
cc:Mr. Matthew Fields, Duke Energy Progress, Inc.
Program Manager, Duke Energy
Ms. Teresa Williams, Duke Energy Progress, Inc.
Mr. Robert Wylie, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
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Page 1 of 19
TLW
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 19
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92487550001 FIELD BLANK EPA 1631E 1 PASI-ANMP
92487550002 OUTFALL 001_2020/07/23_0835_N EPA 1664B 1 PASI-CJSG
EPA 200.7 Rev 4.4 1994 11 PASI-ADS
EPA 1631E 1 PASI-ANMP
SM 2540C-2011 1 PASI-ARED
SM 2540D-2011 1 PASI-AJNS
EPA 300.0 Rev 2.1 1993 2 PASI-ABRJ
SM 4500-Cl-E-2011 1 PASI-AMDW
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
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Page 3 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Sample:FIELD BLANK Lab ID:92487550001 Collected:07/23/20 08:35 Received:07/23/20 14:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 4.94 ng/L 08/04/20 06:14 7439-97-6 C007/30/20 15:050.50 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Sample:OUTFALL
001_2020/07/23_0835_N
Lab ID:92487550002 Collected:07/23/20 08:35 Received:07/23/20 14:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
HEM, Oil and Grease
Oil and Grease ND mg/L 07/26/20 17:195.0 1
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 07/29/20 18:59 7440-38-207/29/20 01:3110.0 1
Beryllium ND ug/L 07/29/20 18:59 7440-41-707/29/20 01:311.0 1
Cadmium ND ug/L 07/29/20 18:59 7440-43-907/29/20 01:311.0 1
Chromium ND ug/L 07/29/20 18:59 7440-47-307/29/20 01:315.0 1
Copper 8.5 ug/L 07/29/20 18:59 7440-50-807/29/20 01:315.0 1
Lead ND ug/L 07/29/20 18:59 7439-92-107/29/20 01:315.0 1
Nickel ND ug/L 07/29/20 18:59 7440-02-007/29/20 01:315.0 1
Selenium ND ug/L 07/29/20 18:59 7782-49-207/29/20 01:3110.0 1
Silver ND ug/L 07/29/20 18:59 7440-22-407/29/20 01:315.0 1
Hardness, Total(SM 2340B)145000 ug/L 07/29/20 18:5907/29/20 01:316621
Zinc ND ug/L 07/29/20 18:59 7440-66-607/29/20 01:3110.0 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 11.5 ng/L 08/04/20 05:29 7439-97-607/30/20 15:050.50 1
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 445 mg/L 07/28/20 17:0825.0 1
Analytical Method: SM 2540D-2011
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids 3.2 mg/L 07/28/20 13:482.5 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 1.6 mg/L 07/26/20 02:00 24959-67-9 M10.10 1
Fluoride 0.48 mg/L 07/26/20 02:00 16984-48-80.10 1
Analytical Method: SM 4500-Cl-E-2011
Pace Analytical Services - Asheville
4500 Chloride
Chloride 119 mg/L 07/27/20 20:27 16887-00-6 M15.0 5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 08/07/2020 04:42 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
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Page 5 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
555860
EPA 1664B
EPA 1664B
1664 HEM, Oil and Grease
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92487550002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2952043
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Oil and Grease mg/L ND 5.0 07/26/20 17:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2952044LABORATORY CONTROL SAMPLE:
LCSSpike
Oil and Grease mg/L 43.940 110 78-114
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2952045MATRIX SPIKE SAMPLE:
MSSpike
Result
35564752002
Oil and Grease mg/L 37.040 92 78-1141.3U
REPORT OF LABORATORY ANALYSIS
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Eden, NC 27288
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Page 6 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
556828
EPA 1631E
EPA 1631E
1631E Mercury,Low Level
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92487550001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2956162
Associated Lab Samples:92487550001
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 08/04/20 05:21
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2956163
Associated Lab Samples:92487550001
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 08/04/20 08:24
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2956164
Associated Lab Samples:92487550001
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 08/03/20 17:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2956165LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ng/L 4.695 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2956166MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92487420001
2956167
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 107 71-125106 1250.0106
ug/L
37.4 37.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2956168MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92487470010
2956169
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 99 71-12598 1254.53 29.4 29.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 08/07/2020 04:42 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
556829
EPA 1631E
EPA 1631E
1631E Mercury,Low Level
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92487550002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2956172
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 08/04/20 08:26
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2956173
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 08/04/20 05:52
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2956174
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 08/04/20 08:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2956175LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ng/L 5.515 110 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2956176MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
20163347002
2956177
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 105 71-125107 1257.25 33.4 33.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2956178MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92487563003
2956179
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 87 71-125103 12258.47 30.3 34.1
REPORT OF LABORATORY ANALYSIS
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Eden, NC 27288
[phone]
Page 8 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
556410
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92487550002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2954337
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Arsenic ug/L ND 10.0 07/29/20 18:53
Beryllium ug/L ND 1.0 07/29/20 18:53
Cadmium ug/L ND 1.0 07/29/20 18:53
Chromium ug/L ND 5.0 07/29/20 18:53
Copper ug/L ND 5.0 07/29/20 18:53
Hardness, Total(SM 2340B)ug/L ND 662 07/29/20 18:53
Lead ug/L ND 5.0 07/29/20 18:53
Nickel ug/L ND 5.0 07/29/20 18:53
Selenium ug/L ND 10.0 07/29/20 18:53
Silver ug/L ND 5.0 07/29/20 18:53
Zinc ug/L ND 10.0 07/29/20 18:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2954338LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 440500 88 85-115
Beryllium ug/L 444500 89 85-115
Cadmium ug/L 442500 88 85-115
Chromium ug/L 437500 87 85-115
Copper ug/L 453500 91 85-115
Hardness, Total(SM 2340B)ug/L 2880033100 87 85-115
Lead ug/L 444500 89 85-115
Nickel ug/L 446500 89 85-115
Selenium ug/L 446500 89 85-115
Silver ug/L 217250 87 85-115
Zinc ug/L 436500 87 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2954339MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92487550002
2954340
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 93 70-13094 1500ND468473
Beryllium ug/L 500 91 70-13092 2500ND454462
Cadmium ug/L 500 93 70-13095 1500ND466473
Chromium ug/L 500 89 70-13090 1500ND447452
Copper ug/L 500 94 70-13095 15008.5 477 484
Hardness, Total(SM 2340B)ug/L 33100 107 70-130120 233100145000180000184000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 08/07/2020 04:42 PM
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Eden, NC 27288
[phone]
Page 9 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2954339MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92487550002
2954340
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Lead ug/L 500 89 70-13090 1500ND445450
Nickel ug/L 500 90 70-13091 1500ND451457
Selenium ug/L 500 98 70-13099 1500ND491495
Silver ug/L 250 91 70-13092 2250ND226231
Zinc ug/L 500 89 70-13090 1500ND454458
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2954341MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92486412026
2954342
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 94 70-13086 8500ND469431
Beryllium ug/L 500 92 70-13085 7500ND460427
Cadmium ug/L 500 95 70-13088 8500ND473439
Chromium ug/L 500 91 70-13084 8500ND457422
Copper ug/L 500 95 70-13088 7500ND479445
Hardness, Total(SM 2340B)ug/L 33100 95 70-13077 833100444007570070000
Lead ug/L 500 92 70-13085 8500ND461425
Nickel ug/L 500 92 70-13086 7500ND465432
Selenium ug/L 500 102 70-13094 8500ND510471
Silver ug/L 250 93 70-13086 8250ND233216
Zinc ug/L 500 93 70-13086 8500ND468434
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 08/07/2020 04:42 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
556325
SM 2540C-2011
SM 2540C-2011
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92487550002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2954014
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 07/28/20 17:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2954015LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 258251 103 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92487550002
2954016SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 445 0445
Parameter Units
Dup
Result QualifiersRPDResult
92487613001
2954017SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 121 4116
REPORT OF LABORATORY ANALYSIS
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
556157
SM 2540D-2011
SM 2540D-2011
2540D Total Suspended Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92487550002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2953323
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Total Suspended Solids mg/L ND 2.5 07/28/20 13:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2953324LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2953541
Total Suspended Solids mg/L 254250 101 90-110100250 2 25
Parameter Units
Dup
Result QualifiersRPDResult
92487587001
2953542SAMPLE DUPLICATE:
Total Suspended Solids mg/L 1160 01150
REPORT OF LABORATORY ANALYSIS
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
555626
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92487550002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2950807
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Bromide mg/L ND 0.10 07/25/20 21:31
Fluoride mg/L ND 0.10 07/25/20 21:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2950808LABORATORY CONTROL SAMPLE:
LCSSpike
Bromide mg/L 2.62.5 103 90-110
Fluoride mg/L 2.72.5 108 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2950809MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92487589001
2950810
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L 2.5 106 90-110107 02.50.79 3.5 3.5
Fluoride mg/L 2.5 105 90-110106 02.51.2 3.8 3.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2950811MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92487550002
2950812
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L M12.5 115 90-110115 02.51.6 4.4 4.4
Fluoride mg/L 2.5 108 90-110107 12.50.48 3.2 3.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 08/07/2020 04:42 PM
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Eden, NC 27288
[phone]
Page 13 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
556027
SM 4500-Cl-E-2011
SM 4500-Cl-E-2011
4500 Chloride
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92487550002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2952895
Associated Lab Samples:92487550002
Matrix:Water
Analyzed
Chloride mg/L ND 1.0 07/27/20 19:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2952896LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/L 20.820 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2952897MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92487550002
2952898
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L M1105190-11043 110119124123
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2952899MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92486704001
2952900
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L M11011790-110140 210104000
ug/L
116 118
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 08/07/2020 04:42 PM
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Eden, NC 27288
[phone]
Page 14 of 19
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Result confirmed by second analysis.C0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Eden, NC 27288
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Page 15 of 19
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92487550
OUTFALL 001 072320
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92487550002 555860OUTFALL
001_2020/07/23_0835_N
EPA 1664B
92487550002 556410 556438OUTFALL
001_2020/07/23_0835_N
EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92487550001 556828 557474FIELD BLANK EPA 1631E EPA 1631E
92487550002 556829 557497OUTFALL
001_2020/07/23_0835_N
EPA 1631E EPA 1631E
92487550002 556325OUTFALL
001_2020/07/23_0835_N
SM 2540C-2011
92487550002 556157OUTFALL
001_2020/07/23_0835_N
SM 2540D-2011
92487550002 555626OUTFALL
001_2020/07/23_0835_N
EPA 300.0 Rev 2.1 1993
92487550002 556027OUTFALL
001_2020/07/23_0835_N
SM 4500-Cl-E-2011
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 08/07/2020 04:42 PM
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[phone]
Page 16 of 19
Page 17 of 19
Page 18 of 19
Page 19 of 19
#=CL#
July 17, 2020
LIMS USE: FR - RICK SMITH
LIMS OBJECT ID: 92485560
92485560
Project:
Pace Project No.:
RE:
Mr. Rick Smith
Duke Energy Progress, Inc.
P.O.Box 1511
PEB4
Raleigh, NC 276021511
ASV_INST
Dear Mr. Smith:
Enclosed are the analytical results for sample(s) received by the laboratory on July 10, 2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
cc:Mr. Jason Brown, Duke Energy
Mr. Justin Dycus, Duke Energy
Mr. Ryan Fawcett, Duke Energy
Mr. Jay Fluckiger, Duke Energy
Mr. Reid Garrett, Duke Energy Progress, Inc.
Mr. Jason Green, Duke Energy Progress, Inc.
Derek Henderson, Duke Energy
Mr. Kyle Hussey, Duke Energy
Program Manager, Duke Energy
Mr. Robert Nichols, Duke Energy
Mr. Matt Pulliam, Duke Energy
Mr. Jonathan Stamas, Duke Energy Progress, Inc.
Mr. Mike Swing, Duke Energy Progress, Inc.
Mr. Thomas Thompson, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 19
TLW
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92485560
ASV_INST
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 19
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92485560
ASV_INST
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92485560001 ASV_INST_DN_1_INST_2020_077 EPA 200.7 Rev 4.4 1994 1 PASI-ASH1
EPA 200.8 Rev 5.4 3 PASI-AJOR
EPA 200.8 Rev 5.4 4 PASI-AJOR
EPA 1631E 1 PASI-ANMP
SM 2540C-2011 1 PASI-AJNS
EPA 300.0 Rev 2.1 1993 1 PASI-ABRJ
92485560002 ASV_INST_DN_1_INST_2020_078 EPA 1631E 1 PASI-ANMP
92485560003 ASV_INST_UP_1_INST_2020_079 EPA 200.7 Rev 4.4 1994 1 PASI-ASH1
EPA 200.8 Rev 5.4 3 PASI-AJOR
EPA 200.8 Rev 5.4 4 PASI-AJOR
EPA 1631E 1 PASI-ANMP
SM 2540C-2011 1 PASI-AJNS
EPA 300.0 Rev 2.1 1993 1 PASI-ABRJ
92485560004 ASV_INST_UP_1_INST_2020_080 EPA 1631E 1 PASI-ANMP
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92485560
ASV_INST
Sample:ASV_INST_DN_1_INST_20
20_077
Lab ID:92485560001 Collected:07/07/20 14:00 Received:07/10/20 10:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Hardness, Total(SM 2340B)9100 ug/L 07/15/20 23:2407/11/20 01:346621
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic 0.13 ug/L 07/13/20 01:15 7440-38-207/11/20 01:340.10 1
Chromium 0.92 ug/L 07/13/20 01:15 7440-47-307/11/20 01:340.50 1
Selenium ND ug/L 07/13/20 01:15 7782-49-207/11/20 01:340.50 1
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4
Pace Analytical Services - Asheville
200.8 MET ICPMS, Dissolved
Cadmium, Dissolved ND ug/L 07/14/20 01:37 7440-43-907/13/20 11:100.080 1
Lead, Dissolved 0.14 ug/L 07/14/20 01:37 7439-92-107/13/20 11:100.10 1
Zinc, Dissolved ND ug/L 07/14/20 01:37 7440-66-607/13/20 11:105.0 1
Copper, Dissolved 1.4 ug/L 07/14/20 01:37 7440-50-807/13/20 11:100.50 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 2.87 ng/L 07/16/20 18:51 7439-97-607/16/20 14:220.50 1
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 26.0 mg/L 07/13/20 11:3910.0 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide ND mg/L 07/12/20 00:20 24959-67-90.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92485560
ASV_INST
Sample:ASV_INST_DN_1_INST_20
20_078
Lab ID:92485560002 Collected:07/07/20 14:00 Received:07/10/20 10:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury ND ng/L 07/16/20 16:58 7439-97-607/16/20 14:220.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92485560
ASV_INST
Sample:ASV_INST_UP_1_INST_20
20_079
Lab ID:92485560003 Collected:07/07/20 13:00 Received:07/10/20 10:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Hardness, Total(SM 2340B)9280 ug/L 07/15/20 23:2807/11/20 01:346621
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic 0.14 ug/L 07/13/20 01:22 7440-38-207/11/20 01:340.10 1
Chromium ND ug/L 07/13/20 01:22 7440-47-307/11/20 01:340.50 1
Selenium ND ug/L 07/13/20 01:22 7782-49-207/11/20 01:340.50 1
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4
Pace Analytical Services - Asheville
200.8 MET ICPMS, Dissolved
Cadmium, Dissolved ND ug/L 07/14/20 01:45 7440-43-907/13/20 11:100.080 1
Lead, Dissolved 0.16 ug/L 07/14/20 01:45 7439-92-107/13/20 11:100.10 1
Zinc, Dissolved ND ug/L 07/14/20 01:45 7440-66-607/13/20 11:105.0 1
Copper, Dissolved 1.4 ug/L 07/14/20 01:45 7440-50-807/13/20 11:100.50 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 3.98 ng/L 07/16/20 18:58 7439-97-607/16/20 14:220.50 1
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 24.8 mg/L 07/13/20 11:3910.0 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide ND mg/L 07/12/20 01:02 24959-67-9 R10.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92485560
ASV_INST
Sample:ASV_INST_UP_1_INST_20
20_080
Lab ID:92485560004 Collected:07/07/20 13:00 Received:07/10/20 10:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 2.98 ng/L 07/16/20 20:38 7439-97-607/16/20 14:220.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92485560
ASV_INST
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
553250
EPA 1631E
EPA 1631E
1631E Mercury,Low Level
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92485560001, 92485560002, 92485560003, 92485560004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2939729
Associated Lab Samples:92485560001, 92485560002, 92485560003, 92485560004
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 07/16/20 16:12
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2939730
Associated Lab Samples:92485560001, 92485560002, 92485560003, 92485560004
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 07/16/20 17:28
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2939731
Associated Lab Samples:92485560001, 92485560002, 92485560003, 92485560004
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 07/16/20 20:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2939732LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ng/L 4.655 93 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2939733MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485815002
2939734
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 80 71-12579 02567.9 88.0 87.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2939735MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485560003
2939736
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 103 71-125102 1253.98 29.7 29.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92485560
ASV_INST
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552659
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92485560001, 92485560003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2937123
Associated Lab Samples:92485560001, 92485560003
Matrix:Water
Analyzed
Hardness, Total(SM 2340B)ug/L ND 662 07/15/20 21:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2937124LABORATORY CONTROL SAMPLE:
LCSSpike
Hardness, Total(SM 2340B)ug/L 3390033100 102 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937125MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485666001
2937126
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Hardness, Total(SM 2340B)ug/L 33100 115 70-130106 433100470008490082000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937127MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485554001
2937128
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Hardness, Total(SM 2340B)ug/L 33100 102 70-130106 233100515008530086600
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92485560
ASV_INST
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552660
EPA 200.8 Rev 5.4
EPA 200.8 Rev 5.4
200.8 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92485560001, 92485560003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2937129
Associated Lab Samples:92485560001, 92485560003
Matrix:Water
Analyzed
Arsenic ug/L ND 0.10 07/12/20 22:02
Chromium ug/L ND 0.50 07/12/20 22:02
Selenium ug/L ND 0.50 07/12/20 22:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2937130LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 11.210 112 85-115
Chromium ug/L 56.150 112 85-115
Selenium ug/L 53.550 107 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937131MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485530001
2937132
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 10 109 70-130110 1100.94 11.9 12.0
Chromium ug/L 50 109 70-130110 150ND54.9 55.3
Selenium ug/L 50 105 70-130105 050ND52.5 52.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937133MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485554003
2937134
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 10 110 70-130113 2100.69 11.7 11.9
Chromium ug/L 50 110 70-130112 2500.64 55.8 56.8
Selenium ug/L 50 105 70-130106 050ND52.8 53.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92485560
ASV_INST
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552812
EPA 200.8 Rev 5.4
EPA 200.8 Rev 5.4
200.8 MET Dissolved
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92485560001, 92485560003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2937603
Associated Lab Samples:92485560001, 92485560003
Matrix:Water
Analyzed
Cadmium, Dissolved ug/L ND 0.080 07/13/20 22:43
Copper, Dissolved ug/L ND 0.50 07/13/20 22:43
Lead, Dissolved ug/L ND 0.10 07/13/20 22:43
Zinc, Dissolved ug/L ND 5.0 07/13/20 22:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2937604LABORATORY CONTROL SAMPLE:
LCSSpike
Cadmium, Dissolved ug/L 10.410 104 85-115
Copper, Dissolved ug/L 54.450 109 85-115
Lead, Dissolved ug/L 51.750 103 85-115
Zinc, Dissolved ug/L 50.950 102 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937605MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485530001
2937606
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Cadmium, Dissolved ug/L 10 102 70-130103 210ND10.2 10.4
Copper, Dissolved ug/L 50 107 70-130107 0506.0 59.7 59.5
Lead, Dissolved ug/L 50 104 70-130103 1501.1 53.1 52.6
Zinc, Dissolved ug/L 50 95 70-13097 1508.3 55.9 56.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937607MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485559001
2937608
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Cadmium, Dissolved ug/L 10 105 70-130103 210ND10.5 10.3
Copper, Dissolved ug/L 50 109 70-130106 2501.7 56.1 54.8
Lead, Dissolved ug/L 50 105 70-130103 250ND52.6 51.5
Zinc, Dissolved ug/L 50 91 70-13088 3507.7 53.1 51.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92485560
ASV_INST
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552809
SM 2540C-2011
SM 2540C-2011
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92485560001, 92485560003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2937590
Associated Lab Samples:92485560001, 92485560003
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 10.0 07/13/20 11:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2937591LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 244251 97 80-120
Parameter Units
Dup
Result QualifiersRPDResult
92485530001
2937592SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 75.2 571.6
Parameter Units
Dup
Result QualifiersRPDResult
92485563002
2937593SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 22.0 422.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92485560
ASV_INST
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552693
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92485560001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2937230
Associated Lab Samples:92485560001
Matrix:Water
Analyzed
Bromide mg/L ND 0.10 07/11/20 17:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2937231LABORATORY CONTROL SAMPLE:
LCSSpike
Bromide mg/L 2.32.5 93 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937232MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485295001
2937233
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L 2.5 103 90-110105 22.50.94 3.5 3.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937234MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485543001
2937235
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L M1,R12.5 96 90-110112 152.5ND 2.4 2.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92485560
ASV_INST
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
552694
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92485560003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2937236
Associated Lab Samples:92485560003
Matrix:Water
Analyzed
Bromide mg/L ND 0.10 07/12/20 00:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2937237LABORATORY CONTROL SAMPLE:
LCSSpike
Bromide mg/L 2.32.5 92 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937238MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485560003
2937239
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L R12.5 94 90-110106 122.5ND 2.3 2.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2937290MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92485583001
2937291
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L 2.5 106 90-110105 12.5<0.060 2.7 2.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
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Page 14 of 19
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92485560
ASV_INST
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 19
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92485560
ASV_INST
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92485560001 552659 552675ASV_INST_DN_1_INST_2020_077 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92485560003 552659 552675ASV_INST_UP_1_INST_2020_079 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92485560001 552660 552672ASV_INST_DN_1_INST_2020_077 EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4
92485560003 552660 552672ASV_INST_UP_1_INST_2020_079 EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4
92485560001 552812 552832ASV_INST_DN_1_INST_2020_077 EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4
92485560003 552812 552832ASV_INST_UP_1_INST_2020_079 EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4
92485560001 553250 553816ASV_INST_DN_1_INST_2020_077 EPA 1631E EPA 1631E
92485560002 553250 553816ASV_INST_DN_1_INST_2020_078 EPA 1631E EPA 1631E
92485560003 553250 553816ASV_INST_UP_1_INST_2020_079 EPA 1631E EPA 1631E
92485560004 553250 553816ASV_INST_UP_1_INST_2020_080 EPA 1631E EPA 1631E
92485560001 552809ASV_INST_DN_1_INST_2020_077 SM 2540C-2011
92485560003 552809ASV_INST_UP_1_INST_2020_079 SM 2540C-2011
92485560001 552693ASV_INST_DN_1_INST_2020_077 EPA 300.0 Rev 2.1 1993
92485560003 552694ASV_INST_UP_1_INST_2020_079 EPA 300.0 Rev 2.1 1993
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2020 03:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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