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HomeMy WebLinkAboutWI0800489_DEEMED FILES_201712017)~ f/V 10 g O O lf-g 9 INJECTION EVENT RECORD North Carolina Department of Environment and Natural Resources -Division of Water Resources Permit Number WI0800489 1. Permit Information MCB Cam p Le jeune Permittee LCH 4015 Facility Name NC Rt. 24 and Butler Street Facility Address 2. Injection Contractor Information Consultech Environmental, LLC. Injection Contractor/ Company Name Street Address P.O. Box 5306 Ca ry NC City (919 ) 234-4238 State 27512 Zip Code R1Ec1.:1v1.:01N CDF.:Q1owR Area code -Phone number DEC O J 2017 3. Well Information 1y . Watero eg,on81 0 tJa/ity Peration Number of wells used for injection 3 s 8ection Well names UST4014-MW0I UST4015-MW0 I. UST4015- MW02 Were any new wells installed during this injection event? OYes 181 ·No If yes, please provide the following information: Number of Monitoring Wells _____ _ Number of Injection Wells ______ _ :;!J:pe of Well Installed (Check applicable type): LJ Bored □Drilled D Direct-Push D Hand-Augured Oother (specify) __ _ Please include a copy of the GW-1 form for each well installed. Were any wells abandoned during this injection event? DYes ~ No If yes, please provide the following information: Number of Monitoring Wells ______ _ Number oflnjection Wells _______ _ 4. lnjectant Information Ozone/Hydrogen Peroxide Injectant Type Concentration: 5% Ozone/11 % H vdro f!en Peroxide If the injectant is diluted please indicate the source dilution fluid. NA ------------ Total Volume Injected 5,040 L Ozone/I 10 gal H vdro e en Peroxide Volume Injected per well 1,680 L Ozone/37 gal H vdro e.en Peroxide 5. Injection History Injectiondate(s) 10/9/17to 10/14/17 Injection number ( e.g. 3 of 5) _1 ~of_l ___ _ Is this the last injection at this site? 181 Yes D No I DO HEREBY CERTIFY THAT ALL THE INFORMATION ON THIS FORM IS CORRECT TO THE BEST OF MY KNOWLEDGE AND THAT THE INJECTION WAS PERFORMED WITHIN THE ST AND ARDS LAID OUT IN THE PERMIT . SIGNAIORE OF INJECIION CONIRACIOR 11/28/17 DATE Submit the original of this form to the Division of Water Resources within 30 days of injection. Form UIC-IER Permit Number Program Category Deemed Ground Water Permit Type W10800489 Injection Deemed In-situ Groundwater Remediation Well Primary Reviewer shristi.shrestha Coastal SWRule Permitted Flow Facility Faclllty Name LCH-4015 Location Address NC Rt 24 And Butler St Incident #85352 Jacksonville NC Owner Owner Name Mcleast-McB Camp Lejeune Dates/Events Orig Issue 10/2/2017 App Received 9/26/2017 Regulated Activities Groundwater remediation Outfall Waterbody Name 28542 Draft Initiated Scheduled Issuance Public Notice Central Files: APS SWP 10/2/2017 Permit Tracking Slip Status Active Project Type New Project Version 1.00 Permit Classification Individual Permit Contact Affiliation Major/Minor Minor Faclllty Contact Affiliation Owner Type Government -Federal Owner Afflllation Jenni Reed 12 Post Ln Camp Lejeune Region Wilmington County Onslow NC Issue 10/2/2017 Effective 10/2/2017 28542 Expiration Requested /Received Events Streamlndex Number Current Class Subbasln Shrestha, Shristi R From: Sent: To: Cc: Subject: Shrestha, Shristi R Monday, October 02, 2017 2:13 PM 'Hunter CIV Bradley W' ~liebig@consultechenv.com'; Reed CIV Jenni P; Hall CTR Nicole L; Gregson, Jim; King, Morella s NOi WI0800489 LCH-4015 Thank you for submitting the Notice of Intent to Construct or Operate Injection Wells (NOi) for the above referenced site. Please remember to submit the following regarding this injection activity: 1) Well Construction Records (GW-1) and Abandonment Records (GW-30) when completed. Please provide copies of the GW-ls and GW-30s if not already submitted (originals go the address printed on the form). NOTE: Direct push or Geoprobe wells are considered wells and require construction ( GW-1) and abandonment forms ( GW- 30). If well construction/abandonment information is the same for the wells, only one form needs to be completed- just indicate total number of injection points in the Comments/Remarks section of form. These forms can be found on our website at http://deq.nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ ground-water- protection/ ground-water-reporting-forms 2) Injection Event Records (IER). All injections, including air and passive systems require an IER. The IER can be modified for air sparge wells (e.g., air flow 'continuous' for date or rate of injection, etc.). You can scan and send these forms directly to me at Shristi.shrestha@ncdenr.gov· or via regular mail to address below. When submitting the above forms, you will need to enter the nine-digit alpha-numeric number on the form (i.e., WIO:XXXXXX) that has been assigned to the injection activity at this site. This notification has been given the deemed permit number WI0800489. This number is also referenced in the subject line of this email. You may if you wish, scan and send back as attachments in reply to this email, as it will already have the assigned deemed permit number in the subject line. Shristi Shristi R. Shrestha Hydro geologist Water Quality Regional Operations Section Animal Feeding Operations & Groundwater Protection Branch North Carolina Department of Environmental Quality 919 807-6406 office shristi.shrestha@ncdenr.gov 512N. Salisbury Street 1636 Mail Service Center Raleigh, NC 27699 1636 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Hunter CIV Bradley W [mailto:bradley.w.hunter@usmc.mil] Sent: Monday, September 18, 2017 2:02 PM To: Shrestha, Shristi R <shristi.shrestha@ncdenr.gov> Cc: '.jliebig@consultechenv.com' <jliebig@consultechenv.com>; Reed CIV Jenni P <jenni.reed@usmc.mil>; Hall CTR Nicole L <nicole.hall.ctr@usmc.mil> Subject: USMC Camp Lejeune Notification of Intent to Operate an Injection Well Gottschalk Marina Site Shristi, I am forwarding the attached NOis for our petroleum remediation sites: Former Building 645 (NCDEQ Incident# 87556), Building 820 (NCDEQ Incident# 23135), and LCH-4015 (NCDEQ Incident# 85352). This is for pilot tests we would like to conduct at the sites using ozone/peroxide injections. In addition to this email, would you like hard copies of the site map and well construction records submitted? Please reply all in your response. Brad Hunter Environmental Engineer Environmental Management Division Marine Corps Base, Camp Lejeune Phone: 910-451-9610 Fax: 910-451-5997 e-mail: bradley.w.hunter@usmc.mil Privacy Act -1974 As amended applies, this E-Mail may contain information which must be protected IA W DoD 5400.1 lR, and is For Official Use Only (FOUO). This email and any files transmitted with it are intended solely for the use of the individual or agency to which they are addressed. If you have received this email in error, please notify me immediately. For Official Use Only -Privacy Sensitive: Any misuse or unauthorized disclosure may result in both civil and criminal penalties. Shrestha, Shristi R From: Sent: To: Subject: Attachments: Please find the attached NOL Shristi Shristi R. Shrestha Hydrogeologist Shrestha, Shristi R Monday, October 02, 2017 2:14 PM Gregson, Jim; King, Morella s NOi WI0800489 LCH-4015 LCH-4015 Site Notice of Intent to Construct or Operate Injection Wells.pdf Water Quality Regional Operations Section Animal Feeding Operations & Groundwater Protection Branch North Carolina Department of Environmental Quality 919 807-6406 office shristi.shrestha@ ncdenr.gov 512N. Salisbury Street 1636 Mail Service Center Raleigh, NC 27699 1636 Email correspondence to and from this addmss is subject to the North Carolina Public Records Law and may be disclosed to third p arties. North Carolina Department of Environmental Quality -Division of Water Resources NOTIFICATION OF INTENT (NOi) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are ''pennitted by rule" and do not require an individual pennit when constructed in accordance with the rules of ISA NCAC 02C .0200. This form shall be submitted at least 2 WEEKS prior to iniection. AQUIFER TEST WELLS (1 5A NCAC 02c .0220) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION (I SA NCAC 02c .0225 ) or TRACER WELLS (1 5A NCAC 02c .0229): 1) Passive In jection S ystems • In-well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods. 2) Small-Scale In jection O perations -Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests -Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells are located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air In jection Wells • Used to inject ambient air to enhance in-situ treatment of soil or groundwater. Print Clearly or Type Information. Illegible Sub ~@f~complete. vv 10800 4 ~9 DATE: Au gustl?,2017 PERMITNO. -SEP 26 201 ~obefilledinbyDWR) Water Qul:llity Regional A. WELL TYPE TO BE CONSTRUCTED OR OPERATED perations Section (1) (2) (3) (4) (5) (6) ___ .Air Injection Well ...................................... Complete sections B through F, K, N ___ .Aquifer Test Well ....................................... Complete sections B through F, K, N ___ Passive Injection System ............................... Complete sections B through F, H-N X Small-Scale Injection Operation ...................... Complete sections B through N ___ .Pilot Test ................................................. Complete sections B through N ___ Tracer Injection Well ................................... Complete sections B through N B. STATUS OF WELL OWNER: Federal Government C. WELL OWNER(S) -State name of Business/Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name(s): MCIEAST-MCB camp Le jeune . Attn: Jenni Reed. Environmental Management Division Mailing Address: 12 Post lane City: MCB Camp Le jeune State NC Zip Code: 28542 County: ONSLOW Day Tele No.: (910 ) 451-9017 Cell No.: _________ _ EMAIL Address: jenni.reed@usmc.mil Fax No.: ___________ _ Deemed Permitted GW Remediation NOi Rev. 3-1-2016 Page 1 D. PROPERTY OWNER(S) (if different than well owner) Name and Title: Same as Above Company Name Mailing Address: City; State: Zip Code: County: - Day Tele No.: Cell No.. EMAIL Address: Fax No.: E. PROJECT CONTACT (Typically Environmental Engineering Firm) Name and Title: Raj Shah, P.E. Company Name: Consultech Environmental . LLC Mailing Address: P.O. Box 5306 City: Care State: NC Zip Code:27512 County: Wake Day Tele No.: t919) 234-4238 Ext 101 Cell No.: 919-622-1155 EMAIL Address: rbshah@consultechenv_com Fax No.: 919-234-4239 F. PHYSICAL LOCATION OF WELL SITE (1) Facility Name & Address: LCH-4015. NC Rt. 24 and Batter Street INCIDENT #85352 City: MCB Camp Lejeune County: ONSLOW State: NC Zip Code: 28542 (2) Geographic Coordinates: Latitude**: N34° 43' 29.64" or Longitude**: W771 20' 19.68" or Reference Datum: Gooale Earth Accuracy: Method of Collection: Facility Site map *FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMr'1'1ED IN LIEU OF GEOGRAPHIC COORDINATES. 0 G. TREATMENT AREA Land surface area of contaminant plume: 74 8.000 Combined square feet Land surface area of inj. well network: 1000 square feet ( 10,000 ftF for small-scale injections) Percent of contaminant plume area to be treated: ` 5% (must be < 5% of plume for pilot test injections) H. INJECTION ZONE MAPS — Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface maps) indicating the rate and direction of groundwater movement, plus existing and proposed wells. Deemed Permitted GW Remediation NOI Rev. 3-1-2016 Page 2 I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES -Provide a brief narrative regarding the purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration of injection over time. Based on 2:roundwater monitorin2: events from 2015, the following constituents. Methylnaphthalene. Naphthalene, Benzene . C5-C18 Aliphatics and C9-C22 Aromatics exceed the site cleanup levels of the North Carolina Administrative Code 2L Surface Water Quality Standards. An ozone/peroxide sparn:in2: pilot test is proposed to determine if these contaminants can be effectively reduced at the site. For this pilot test. monitoring wells USTLCH4014-MW01, USTLCH4015-MW01 and USTLCH4015-MW02 will receive ozone and peroxide injections over a 24 hour period for 5 days. at 20 minute injection cycles per well. The injection wells will be monitored before system startup and immediately after the event for dissolved oxygen (DO), oxidation reduction potential (ORP), specific conductivity, pH. temperature and depth to 2roundwater measurements. The following monitoring wells will be monitored before, during and after to assess the effectiveness and possible limitations of the ozone/peroxide injection process. Those wells are USTLCH4015- MW11, USTLCH4015-MW20 and USTLCH4015-MW2. If after two days of ozone and peroxide injections , no influence is detected in the wells in the vicinity. then compressed air will be applied at a rate of 5-10 psi for a 40 minute cycle. post ozone/peroxide injection cycle to facilitate distribution of oxidant solution throuuhout the formation. The injection of pressurized air disperses the liquid oxidizer laterally. and to some extent , vertically. J. APPROVED INJECTANTS -Provide a MSDS for each injectant. Attach additional sheets if necessary. NOTE: Only injectants approved by the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at htt p://deg .nc.!l:ov/about/divisions/water- resources/water-resources-permits/wastewater-branch/!l:round-water-protection/!!round-water-a pproved-in jectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919-807-6496). Injectant: __ ___,H=.Ly=dr,,_.,0"""2=e=n'--"P'--'e=r=ox=i=d=e _______________________ _ Volume of injectant: 80-100 CC per hour Concentration at point of injection: 10% Percent if in a mixture with other injectants: Injectant: ___ O=z=on=e=------------------------------- Volume of injectant: to be determined Concentration at point of injection: ___ 5~%~o_@~~10~-~1=2~P~S~I~------------ Percent if in a mixture with other injectants: K. WELL CONSTRUCTION DATA (1) (2) Number of injection wells: -----~Proposed __ ~3~_~Existing (provide GW-ls) For Proposed wells or Existing wells not having GW-ls, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as-built): Deemed Permitted GW Remediation NOi Rev. 3-1-2016 Page3 (a) Well type as permanent, GeoprobefDPT, or subsurface distribution infiltration gallery (b) Depth below land surface of casing, each grout type and depth, screen, and sand pack (c) Weil contractor name and certification number L. SCHEDULES — Briefly describe the schedule for well construction and injection activities. Wells currently exist and no further construction action is needed. Within 2) weeks of the initial pilot test completion, parameters monitorinu primarily. DO and ORP in the injection and observation wells will be conducted. M. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in .« ui Fc h,t+ie7 (t ' I result from the injection activity. Within i4l weeks of the initial pilot test only the injection wells associated with the test will he sampled for MADEP VPH & EPII. 8260E and 8270D. An additional satnplim for the above mentioned parameters will be Performed on all site monitoring wells as part of the next annual eroundwater monitorine event to further track contaminate levels. N. SIGNATURE OF APPLICANT AND PROPERTY OWNER APPLICANT: "I hereby certify, under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenpces in accordance with th.e 1].•1 NC::1C 0 2C tltt'/ , Ruffs. " fao_v j„n, 4., 6--1414 tore of Applicant Print or Type Full Name and Tide PROPERTY OWNER (if the property is not owned by the permit applicant): "As owner of the property on which the injection well(s) are to be constructed and operated I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection welds) conform to the Well Construction Standards ([ _ t NCA C NC .WUOI. " "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. Signature* of Property Owner (if different From applicant) Print or Type Full Name and Title *An access agreement between the applicant and property owner may be submitted in lieu of a signature on this form. Submit the completed notification package to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 807-6464 Deemed Permitted GW Remediation NOI Rev. 3-1-2016 Page 4 FIGURES UNCLASSIFIED//FOR OFFICIAL L)SE ONLY SPEP 9.0 Cn.ze et2',&) oRa$��g� fit. �► Iza e1 r i ett ne ca U C nee:a oaMic 44 0 C. l 0�it,'} Y?c Ca Q o mac �° a o 9a o Ap d q[f. 4? 5� 0 tB C a 0 p °,hrr G4, ti �fe\� %; r,`r V 0 ab 04 en� pv Nt? O a a Building 0pb a LCH - 4015 80 tbo o, a ° a pQ b p � B� a q � C 4GC. 160a c a 0 o�cbo a 4- b 1,500 ft. Radius 2$ Darby 5; a a �8 %0 O �a �I C. oo a a �0 0 a Legend Woler Sum* Wei' 1 Athletic Fields as:. Cowls pPtoygrounds ©1.900.Fool Roue t-., }ylcidllon Aea ---- Suroce wale; 1 9rocrure/0ssmoY;hed Area ¢mood; 245 490 980 Feet RHEA CONSi1LTECii N FIGURE 1 LCH-4016 Vicinity Map MCB Camp Lejeune, NC Drawn HI w BG 713116 979 UNCLASSIFIED//FOR OFFICIAL USE ONLY AS Mt USTLCH4015-MW24 C'PG(�l� 54411403 1STLCH401SMWO? ,BS- BSI7 ILS-I6 USTLCH461 W 12 USTLC r15-1W1 USTL(_ :015MW13 1HJCH4015-M W 14 USTLCH4014-MWOI USTLC 4015MWO •DES 34 k6H4045 \ .4. 6t-3 1 .7 } ,C 7' 11STL ti'i21 C ;65�i6 ��,propone ~ I.CH4034 ` Gross= ASTs �15TLCH4015-MWDS -•65-75 LO+ CH4015-SB49 9 �s•s7 TLCH401- •r 50 "• • F• 95,24: /il- ��, 11STLCH4015-MW16 LCH 540422 , Bf,�15 F as- c 14: �I USTLCH4O15-MWO1 ${15TLCH 4015-M W is H4O15-MWO2 Zf 5-MW10 _ ., r !! °H�pl$ 4FLISTLCH4015-LAW26 ---- 11. UST LCH401SM W17R r _' `Former ASTs ,.q.` BS°5/ • p,5:^' BS�i 0.--U-M STLCH4015W25 CH10121 USTLCH4015-MW04 — FormerASTs'• USTCCH4015•MW 1$ USTL.CH4O15-MW 19 (MOP Former Fuel Lines & Dispenser Wood BS20 ICH1014. CHTO 1JSTLCH4015-MWCB USTLCH4015-MW23 ('SOC L TLCH401 -MW I70 Legend • Solf Boring Location • Deep Monitoring Well wile ISOC WA Approximate VMS Localb r [ ] Su/dings • Sndlow Monitoring Well --• SVE Wel Casing Sxisl1ng Feel Line 1= Roads and Cnveways • Ester marl late Monitoring Well ▪ Shatlaw Spurge Wet I-20 ft} - - Former Roe! thee 1-7 Parking Area Ai Enter mediate Monitoring Well With ISOC • intermediate Spore we51-44 fl] 5VE Well Screen • Deep Monitoring Wel — Blosporpe Line LJ Slreidure/DernoRshed Area �Cl- iO Hj\ LC4X]e ILCH1018\ L � Note: -4AW 17D converted from lnte-mediore Monitoring Wep ,o On Inlerrnediate Biosporge Wet x 40 ea Fee 7 t `LCH 1020%v z .1LCH1O22/ / LCIlI159 LC141102 j• >...a..a<.. _ 164% +4CH1024 •, i FIGURE 2 Site Map with EMnHnrins Well Locations LCH-4D1 MCB Camp Lejeune, NC ormer Fuel [roes;, II���•'�+ Dispenser hland + 65Tlclsmis.x�wp bsQt • ;hh0W15 Wl7R ^1��!SiLCN1015•M W 17O �SILCH40156W2e CH1100 LCH]1•FC eating Oi AST - Grn+euyaisty sad - - Silty Fine Sand SM V18 m• 4015-MWr 'LC .•IS-M -1 `"Gross 'T' Lot Silty Clay/Sandy Clay .l•9:n r'r•4nt A4v1 VM,S Unknown Geology Legend . Shdow Monitoring Well —]Groundwater Flow DIreoliar. - — Former Fuel Lines ---Shallow Wei Groundwater Como ur - ---Fadsli no Fuel Line r"9 L—iSIructure/Damollshed Area nA�klr gs Roads and Crlreways © Parking Area mrermadete Mnnitoring Weil Intermeciate Monitoring Wetl wish i50C ID Deep MOFJto1ing we!! S Deep Monitoring Well with .SCC i !Marina:kite Spurge well I-%Q flj Scale: FIGURE 3 Geologje Crews Section Map LCH-1015 MCB Camp Lejeu me, NC CONSGLT'ECH fY • 1 1 r LCHaD4 USTLCH4615-MW 16* 129.841 USTLCH4015- 12 127 7" USTL 4015-MW I 1 [27.09} US' CH4014-MW01. j27.43) USTLCH4015-MWDd ;29.33}7 LCH4034 ttCH4615-MW05 1311501 UST LCH4015-MW03 (29.63} IJSTLCH401S-MW09* 28.85) UST 1t4615-MW61 {30.02) u`ILCH4D14-Mw14 -1�7a7) USTLC• 15-AMW 15 LC �,8.75] Former Fuel Lines 3 Dispenser Wood 4015-M • :i? (29,59) .,._uSTLCH4015-MW 1 d t29.8Q1 I " USMCH40i5-MW17R r� 127.80} LCn•4015 !- MW24 LGN T r 5} rfahntnd ysleLn r ,'Former ASis tCH10124 rrler USTLCH46154}MW04 ;28.75} USTLCH4015-MWO8 t2galkdi Legend Shallow Monitoring Weal En Structure/t emolished Area -I. Groundwater Flow Direction — — • Forrner Fuer Lines I Buildings - Shallow Weil Groundwater Contour —••—• Existing Fuel Linc n Roods and Driveways {28.75} Groundwater Elevation in feet Pocking Area \ I.CH1010' LC lob Notes: -Hot all wei[s were wed for contouring purposes. 'LCH102V LCH lop/ 1.CH1I80.' • LCH1160▪ rr LCH1022 . :LCH1025') LCH117.8 FIGURE 38 Shallow Well Grau ndwate r Elevations (July WWI LCH-ii?l5 NCB Camp Lcj mine, \iC Legend • Intormedlale Monitoring Intermediate Monitoring — Former Fvei Efnes ^•�• Existing Fuel'Une ATM Well cD Slructerel0ernoLshed Areo Well with iSQC Buildings EmRoads and Driveways nParking Areo STLCH4015-MW22 [11. 2] Heating 011 AST LCH-014 t1STL '.4016-M • [11 43) �•+'Propane • ASTs sr Fuel Lines & t island •e \, f1 '115 4Q15-MW 170 N[1 /- USTLCH44:115-SAW23180C1H B„tlin [ y] • LC#1-4015 Treolmenl System 0\ Fcrneer AS[s LIMLCH4015-MW25 Intarmed late Spam e Well [-40 ftj —1► Groundwater Flow Direction — Groundwater Elevation Con -our (8.78) Groundwater Elena lion in feel USTLCH4015-M [8.781 [CH 101 Note: -Not all wells were used for contouring purposes. LCH100� �.ACH1022/ 1.LCH E C25 ` 4C H 1180.• t f LCH1100• LCH1178r LCH(7 LCH 1027 FIGURE 4B [ntetmediate Well Groundwater Elevations (July 2E15) LCHr1015 MCII Camp Lejeune, NC 99 117/2015 718l2015 C9•C1S Alt phollcr 5,630 uWWL 1.1/84 me. 700 NE C9- 22 Atom s 4,020 ug/L 1,640 a'L 200 NE USTL4015-MWO. 1/7/2016 7/612015 Naphthalene < 6 ug/L 16 ug/L 6 6,800 Naphthalene < 10 ug'L 7.8J ug/L. 6 6,000 C9.C727 Aromatics 41.1 uWL 290 ug/r. 200 NE ALMI usr Legend Shallow Monitor-klg Wel (? Shalaw1parge WA I-20 Hy Fitermedwle Spurge Wel I-40 H) - Blospor0e Lure LCH4034 1IJSTLCH4015-MW05 4015-MW 1 0 UST LC US1iC1-140I5-MWO I '51LC H 40 i 5-MW09 USTLCH4015EMW 12 Heating Oil S7 LCH40I4 es-26 CH4015-MW 14 4419-CH10 i 5-M W *-USLLCH'IO 5-MW 16 �•.' BS 21!,BS39 Former Fuel Liles• & BF184.3.0.* . T. 05-2pp erlshnd a r -, BS-I6 rr� e5-62• •• `,...„ \--.N./N.,U6LLCH4015MW17D Tregle, System-T.,. arricregNI f.-ICHa01 85.1i f/y 6;• I O •.6S%2ti USTLCH4015-MAW I7R 'Former ASH RIM& ASTS_ I USILCH4015-MWO4 • S1LCH4D15-MW06 SVE Well Sneer L_2, 51ructure/0ernoished Area - - - NCAC 2_ GWQS 3tceedance Piurt>m • SVE WeN Casing 77 Br,LdNys — Former Fuel Lines 0 Roads and 0+0'eways -- 6dsliig Fuel lice 77 Parking Area Benzene Naphthalene 1-Methylnaphfhatene 2-Metltylnaphtholerse Naphthalene CO-C18 Aliphatic' CH401` sW 15 1.9 ug/L 190 ug/L 130 ug/L 110 ngffL. 92 ugrL 1,700 eel, 778)2015 1.2 ngfL. 72 up% 140 ug/L 62 ug/L 69 ug/L 6 200 Lill ILR1 HS17$ 6,000 6000 :_LCH1102 •� YLCH1104 Lf�r NCAC 2L GLL 1/7/2016 7/8+1015 ;GWQS [v AI Benzene 8.5 ug'L. 9.4 ug1L 1 5,000 Nap Wise Tone 89 eel, 50 ugf1. 6 8,000 1.hiethylnaphthalene 6.1 eel, 9J ug(L, 1 1,000 Naphthalene 34 ugti, 40 uWL, 6 6,000 CS-C3 Aliphatic' 530 ugtL 950 up% 400 NE C9-C22 Aromatics 980 ug/L 930 ug/L 200 NE (LCH1010r, Notes: -NCAC 21 GWQS - North Corning Administrative Code 2L Groundwater Quality Standards -G C L - Gross Contamination Level -NS - No Standard -txceedonces of NCAC 21 GWQS are presented in yellow Pe. 0 PO n 013 LCH1024' FIGURE 6A 801E Shallow Groundwater Analytical Re RuAEU USEPA Method 6200 (602 List) LCH-W18 MCB ramp Lejeene, HC MonI a ATAAE 034 iCH4045 %! 's'&e-3a; LCH4034 LC 5•r,}w22 —c= M-7 r. e5-5 LCH4014 Beating OI AST • 85;3i0STLCH 15-MW 217 2a' ' Propane Grass ASis Lol •.66-23� • BS-26 fame, FuelLines & 2a' 10 3P dispenser Island ■ ' SS-181111& 17 BS-20 65.53 IISTLCH4015-MW 1713 • &S-16 �r • 9S-12 Aealmen�SYFlernBSA 1 • �B�II[9np�♦ (/ LCH-4015 • rA035 BS-10 .��v &A5/ Former AST& Forcer ASis -23 BS-2 BS- !G J5TLCH4015-MW25 ++.ar MTI! 1_CW101y r °LCH 1014/ • I -t TLCH10121 L._. ___J `LCHI010�. 1112I2015 7/812015 E7 ilia. lb sL�L ;LCH1100, 4VL MCAC 21 _ G1MOS Ng Ai (opfiy 20,030 LCH102O , LLCH1022] LCH1024'-: .1PArwa70'4PW26. 1/8/2015 1/812015 lointene 1.6 UWL 1.8 De, 5, I 0 ,LCH1007' Legend (.) Sr.t 0 w Sparge We[11-20 fl) — e:osporQe line LI� S1ruchse11]ernalished Area NC AC 2L GWQS Exceedence Fame 010 ms Inteedksre Spar0e Well 1-40 ft} --} SVE Wet 1 Screen I Bu'L7ings slis intermediate Monitoring Well ---• SVE Well Casing = Roods end Driveways 1SI tnteenedlote Monitoring WeI1 with 11OC — — fa/TOO! Fuel Lines Parking Area EX0ting Fuel Line Notes: -NCAC 2LGWCIk - North Carofha AdminBRattve Code 2L Groundwater Qualify S}QndXflds .GCL - Gross Con laminallon Level ids - Na Standard -6fceedances of NCAC 21 GWQS are presented i'1 ye1kW -MW 17❑ converted to an Inlermed W1e Biosporge WeL LCH 102: FIGURE 6B 2015 Intermediate Groundwater Analytical Resu[ts USEPA Method 8200 (002 List) LCH 1015 MC 8 Camp Le}nu net. NC TABLES ~ RH1i ENGINEER.~ & tQl<,<ilLTANTS, I>«. :ml ' ' . •·. lll;."!aI)i;o;J.m MW-1 shallow 32.52 MW-2 shallow 31.68 MW-3 shallow 34.70 MW-4 shallow 35.29 MW-5 shallow 32.25 MW-6 shallow 31.99 MW-7 shallow 32.38 MW-8 shallow 31.37 MW-9 shallow 30.91 MW-10 shallow 30.89 MW-11 shallow 31.76 MW-12 shallow 31.86 MW-13 deeo 32.35 MW-14 shallow 32.04 MW-15 shallow 31.89 MW-16 shallow 32.26 MW-17R shallow 32.78 MW-17D intermediate 33.01 MW-18 shallow 32.60 MW-19 deep 32.61 MW-20 deep 32.13 MW-21 intermediate 32.64 MW-22 intermediate 32.04 MW-23 intermediate 32.54 MW-24 shallow 31.23 MW-25 intermediate NA MW-26 intermediate 32.26 4014-shallow 32.40 MWOl .. ' ' . • 11llll'lill fill ~· l'Iil 'l".":1 14.87 4.9-14.9 4 12.23 2.3-12.3 4 15.31 2.1-12.1 4 15.39 1.9-11.9 4 11.05 1.7-11.7 4 12.12 2.5-12.5 2 12.10 2.5-12.5 2 12.47 2.5-12.5 2 12.12 2.5-12.5 2 12.03 2.5-12.5 2 12.00 2.5-12.5 2 11.75 2.5-12.5 2 47.62 45-50 2 11.88 2.5-12.5 2 11.90 2.5-12.5 2 11.64 2.5-12.5 2 15.75 5-15 2 30.20 25-30 2 12.03 2.5-12.5 2 51.00 45-50 2 47.90 45-50 2 30.20 26.5-31.5 2 31.95 27-32 2 32.05 27-32 2 14.40 4.4-14.4 2 26.75 25-30 2 30.00 25-30 2 13.00 3.0-13.0 2 TABLE 2 Groundwater Elevation Data Building LCH-4015 2015 Annual Monitoring Report Contract No. N40085-15-D-0303, CTO: 0004 MCB Camp Lejeune, North Carolina ~ • .. •~ l ■ III ,, ... • IM!' . ' " • [!r.[;ffi ~ mmm 1/6/2015 ND 4.15 0.00 1/6/2015 ND 1.25 0.00 1/6/2015 ND 3.97 0.00 1/6/2015 ND 4.12 0.00 1/6/2015 ND 1.14 0.00 116/2015 ND 2.74 0.00 116/2015 ND 1.77 0.00 116/2015 ND 0.50 0.00 116/2015 ND 0.00 0.00 116/2015 ND 0.40 0.00 116/2015 ND 2.97 0.00 116/2015 ND 3.08 0.00 116/2015 ND 22.74 0.00 1/6/2015 ND 3.45 0.00 116/2015 ND 2.69 0.00 1/6/2015 ND 0.40 0.00 1/6/2015 ND 4.49 0.00 1/6/2015 ND 5.03 0.00 1/6/2015 ND 1.31 0.00 1/6/2015 ND 23.45 0.00 1/6/2015 ND 21.91 0.00 116/2015 ND 23.20 0.00 1/6/2015 ND 0.60 0.00 1/6/2015 ND 2.64 0.00 1/6/2015 ND 0.50 0.00 1/6/2015 ND 22.54 0.00 1/6/2015 NA 23.03 NA 1/6/2015 ND 1.67 0.00 -. 11••1,;u -~ ro'-"':11 28.37 30.43 30.73 31.17 31.11 29.25 30.61 30.87 30.01 29.94 28.79 28.78 9.61 28.59 29.20 31.86 28.29 27.98 31.29 9.16 10.22 9.44 31.44 29.90 30.73 NA 9.23 30.73 ~ ~ ~ lr'II '.111'11 ,:. I 111·••11~:1,1 'f;l r::a , .••• ~ • ms mlil' UGm rr::rm rmr.m nrmm 7/8/2015 ND 2.50 0.00 30.02 7/8/2015 ND 1.31 0.00 30.37 7/8/2015 ND 5.07 0.00 29.63 7/8/2015 ND 6.54 0.00 28.75 7/8/2015 ND 1.75 0.00 30.50 7/8/2015 ND 2.66 0.00 29.33 7/8/2015 ND 2.79 0.00 29.59 7/8/2015 ND 2.89 0.00 28.48 7/8/2015 ND 2.06 0.00 28.85 7/8/2015 ND 1.05 0.00 29.84 7/8/2015 ND 4.67 0.00 27.09 7/8/2015 ND 4.14 0.00 27.72 7/8/2015 ND 20.47 0.00 11.88 7/8/2015 ND 4.27 0.00 27.77 7/8/2015 ND 3.14 0.00 28.75 7/8/2015 ND 2.46 0.00 29.80 7/8/2015 ND 4.98 0.00 27.80 7/8/2015 ND 20.91 0.00 12.10 7/8/2015 ND 2.18 0.00 30.42 7/8/2015 ND 21.06 0.00 11.55 7/8/2015 ND 20.18 0.00 11.95 7/8/2015 ND 21.21 0.00 11.43 7/8/2015 ND 20.12 0.00 11.92 7/8/2015 ND 10.05 0.00 22.49 7/8/2015 ND 1.18 0.00 30.05 7/8/2015 ND 20.82 0.00 NA 7/8/2015 ND 23.48 0.00 8.78 7/8/2015 ND 4.97 0.00 27.43 Note: TOC elevations, total depths, and screen intervals determined from Final Annual Monitoring Repart Building LCH-4015 prepared by Shaw Environmental, Inc. dated June 2009 and Final Remedial Action Optimization and Revised No free product was detected. 1 TOC: Top of well casing. 2 Groundwater elevations adjusted to account for the presence of free product when applicable (Specific Gravity = 0.8). ND: Not Detected. NA: Not Applicable, well abandoned, destroyed or not installed at the time of gauging. MSL: Mean sea level. I Page 1 of 1 ~ RH1i ENGINEER.~ & tQl<,<ilLTANTS, I>«. :ml ' ' . •·. lll;."!aI)i;o;J.m MW-1 shallow 32.52 MW-2 shallow 31.68 MW-3 shallow 34.70 MW-4 shallow 35.29 MW-5 shallow 32.25 MW-6 shallow 31.99 MW-7 shallow 32.38 MW-8 shallow 31.37 MW-9 shallow 30.91 MW-10 shallow 30.89 MW-11 shallow 31.76 MW-12 shallow 31.86 MW-13 deeo 32.35 MW-14 shallow 32.04 MW-15 shallow 31.89 MW-16 shallow 32.26 MW-17R shallow 32.78 MW-17D intermediate 33.01 MW-18 shallow 32.60 MW-19 deep 32.61 MW-20 deep 32.13 MW-21 intermediate 32.64 MW-22 intermediate 32.04 MW-23 intermediate 32.54 MW-24 shallow 31.23 MW-25 intermediate NA MW-26 intermediate 32.26 4014-shallow 32.40 MWOl .. ' ' . • 11llll'lill fill ~· l'Iil 'l".":1 14.87 4.9-14.9 4 12.23 2.3-12.3 4 15.31 2.1-12.1 4 15.39 1.9-11.9 4 11.05 1.7-11.7 4 12.12 2.5-12.5 2 12.10 2.5-12.5 2 12.47 2.5-12.5 2 12.12 2.5-12.5 2 12.03 2.5-12.5 2 12.00 2.5-12.5 2 11.75 2.5-12.5 2 47.62 45-50 2 11.88 2.5-12.5 2 11.90 2.5-12.5 2 11.64 2.5-12.5 2 15.75 5-15 2 30.20 25-30 2 12.03 2.5-12.5 2 51.00 45-50 2 47.90 45-50 2 30.20 26.5-31.5 2 31.95 27-32 2 32.05 27-32 2 14.40 4.4-14.4 2 26.75 25-30 2 30.00 25-30 2 13.00 3.0-13.0 2 TABLE 2 Groundwater Elevation Data Building LCH-4015 2015 Annual Monitoring Report Contract No. N40085-15-D-0303, CTO: 0004 MCB Camp Lejeune, North Carolina ~ • .. •~ l ■ III ,, ... • IM!' . ' " • [!r.[;ffi ~ mmm 1/6/2015 ND 4.15 0.00 1/6/2015 ND 1.25 0.00 1/6/2015 ND 3.97 0.00 1/6/2015 ND 4.12 0.00 1/6/2015 ND 1.14 0.00 116/2015 ND 2.74 0.00 116/2015 ND 1.77 0.00 116/2015 ND 0.50 0.00 116/2015 ND 0.00 0.00 116/2015 ND 0.40 0.00 116/2015 ND 2.97 0.00 116/2015 ND 3.08 0.00 116/2015 ND 22.74 0.00 1/6/2015 ND 3.45 0.00 116/2015 ND 2.69 0.00 1/6/2015 ND 0.40 0.00 1/6/2015 ND 4.49 0.00 1/6/2015 ND 5.03 0.00 1/6/2015 ND 1.31 0.00 1/6/2015 ND 23.45 0.00 1/6/2015 ND 21.91 0.00 116/2015 ND 23.20 0.00 1/6/2015 ND 0.60 0.00 1/6/2015 ND 2.64 0.00 1/6/2015 ND 0.50 0.00 1/6/2015 ND 22.54 0.00 1/6/2015 NA 23.03 NA 1/6/2015 ND 1.67 0.00 -. 11••1,;u -~ ro'-"':11 28.37 30.43 30.73 31.17 31.11 29.25 30.61 30.87 30.01 29.94 28.79 28.78 9.61 28.59 29.20 31.86 28.29 27.98 31.29 9.16 10.22 9.44 31.44 29.90 30.73 NA 9.23 30.73 ~ ~ ~ lr'II '.111'11 ,:. I 111·••11~:1,1 'f;l r::a , .••• ~ • ms mlil' UGm rr::rm rmr.m nrmm 7/8/2015 ND 2.50 0.00 30.02 7/8/2015 ND 1.31 0.00 30.37 7/8/2015 ND 5.07 0.00 29.63 7/8/2015 ND 6.54 0.00 28.75 7/8/2015 ND 1.75 0.00 30.50 7/8/2015 ND 2.66 0.00 29.33 7/8/2015 ND 2.79 0.00 29.59 7/8/2015 ND 2.89 0.00 28.48 7/8/2015 ND 2.06 0.00 28.85 7/8/2015 ND 1.05 0.00 29.84 7/8/2015 ND 4.67 0.00 27.09 7/8/2015 ND 4.14 0.00 27.72 7/8/2015 ND 20.47 0.00 11.88 7/8/2015 ND 4.27 0.00 27.77 7/8/2015 ND 3.14 0.00 28.75 7/8/2015 ND 2.46 0.00 29.80 7/8/2015 ND 4.98 0.00 27.80 7/8/2015 ND 20.91 0.00 12.10 7/8/2015 ND 2.18 0.00 30.42 7/8/2015 ND 21.06 0.00 11.55 7/8/2015 ND 20.18 0.00 11.95 7/8/2015 ND 21.21 0.00 11.43 7/8/2015 ND 20.12 0.00 11.92 7/8/2015 ND 10.05 0.00 22.49 7/8/2015 ND 1.18 0.00 30.05 7/8/2015 ND 20.82 0.00 NA 7/8/2015 ND 23.48 0.00 8.78 7/8/2015 ND 4.97 0.00 27.43 Note: TOC elevations, total depths, and screen intervals determined from Final Annual Monitoring Repart Building LCH-4015 prepared by Shaw Environmental, Inc. dated June 2009 and Final Remedial Action Optimization and Revised No free product was detected. 1 TOC: Top of well casing. 2 Groundwater elevations adjusted to account for the presence of free product when applicable (Specific Gravity = 0.8). ND: Not Detected. NA: Not Applicable, well abandoned, destroyed or not installed at the time of gauging. MSL: Mean sea level. I Page 1 of 1 Safety Data Sheets Ozone Solutions SAFETY DATA SHEET [formerly MSDS] Page 1 of 1 1. PRODUCT IDENTIFICATION Product Name: OZONE Common Names/Synonyms: Triatomic Oxygen, Trioxygen, Ozone Generator Mauufactm·er/Supplier Ozone Solutions, Inc, www.ozcncsulutions.com 451 Black Forest Rd. techf<l~ozonesolutions.com Hull, IA 51239 712-439-6880 Product Use: TI1is SOS is limited to ozone produced in gaseous form on site by an ozone generator, in varying concentrations, in either air or aqueous solution, for the purposes of odor abatement, oxidation of organic compounds, or antimicrobial intervention, in a variety of aoulications. 2. HAZARD IDENTIFICATION GHS Classifications: Phvsicol Health: Environmental: Oxidizing Gas Skin Irritation -Category 3 Acute Aquatic Eye Irritation -Category 2B Toxicity- Respiratory System Toxicity-Category 1 Category 1 (Sini!le & Reneated) NOTE: Severe respiratory toxicity will develop before skin or eye irritation go beyond listed categories. A11yo11e 111ifh c/,ro11lcp11/111011nry tJroblems esnecially asthma should avoid ex1,os11re to ozone. WHMIS Classifications (Workplace Hazardous Materials Information System, Canada): C, DIA, D2A, D2B, F Source: CCOHS CHEMINFO Record Number 774 3. Chemical name Common names Chemical Formula CAS Registry Number 4. Route of Entrv Skin Contact YES Skin Absorntion NO Eye Contact YES ln2estio11 NO Inhalation YES COMPOSITION Ozone Triatomic oxygen, trioxygen 01 10028-15-6 FIRST AID MEASURES Svmotoms First Aid Irritation Riusc with waler NA NA Irritation Rinse with water, remove contacts NA NA Headache, cough, Remove to fresh air, henvy chest, provide oxygen shortness ofbrcoth thera1w as needed For se1•ere cases tff lf.wm11to111s do11 't i111nro1°e, seek medical heln. 5. FIRE FIGHTING MEASURES Ozone itself is not flammable. As a strong oxidant it may accelerate, e\'en initiate, combustion, or cai1se explosions. Use whatever extin Ruishin g agents are indicated for the burning materials. 6. ACCIDENTAL RELEASE MEASURES Tum off the ozone generator, and ventilate the area. Evacuate until ozone levels subside to a snfe level (<0.1 ppm). 7 , HANDLING AND STORAGE Ozone must be contained within ozone-resistant tubing 11nd pipes from the e.enerntion noint to the application ooint. 8, EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA Pennissible Exoosure Limit: 8 hour TWA 0.1 mm1 ANSU ASTM: 8 hour TWA 0.1 1111111, STEL 0.3 ppm ACGIH: 8 hour TWA 0.1 11nm; STEL 0.3 nnm NIOSH: ELCV 0.1 ppm light; 0.08 ppm modeTAte; 0,05 p11m, heavy Light, moderate, heavy work TWA <= 2 hours: 0.:2 pp111 lnuncdiately Dangerous to Life or Health (IDLH) 5 ppm Respirotory Protection: Use foll face self-contained urcathing aoonratus for enterin11. areas witl1 a hi2h concentration of ozone. Em!in~eri1111 control: Use ozone destruct unit foroff 1mssinl! ofo:i:one. 9. PHYSICAL AND CHEMICAL PROPERTIES Ph}•sical state Gas DH Molecular 48 .0 Decomposition Weil!ht temoerature Appearance Clear at low Evaporation rate concentration, blue at hiaher concentration Odor Distinct pun11.ent odor Flash noint Odor 0.02 to 0.05 ppm; Auto-ignition threshold exposure desensitizes temoerature Melting ooint -193°C/-315°F Relative densi11• BoilinJ.l ooint -I 12°C/-169°F Partition coeflicient Vapor > I aim Flammability pressure Vaoor densitv 1.6 fair= I) Exolosivc limits Solubility in 570 mg/I, @20°C & Viscosity water 100% 01; 0.64 (iW°C 10. STABILITY AND REACTlVITY Ozone is highly unstable and highly reactive. Avoid contact with oxidizable substances. Ozone will readily react and spontaneously decompose under nonnal ambient temueratures . 11. TOXICOLOGICAL INFORMATION Likely routes of cxnosure: inhalation, eves, skin ex oosure . NA NA NA NA NA NA NA NA NA NA Effects of Acute Exposure: Discomfort, including headache, coughing, dry throat, shortness of breath, pulmonary edem1l; higher levels of exposure intensifr svmotoms. Possible irritation of skin and/or cres. Etlects of Chronic Exposure: Similar to acute exposure effects, with oossible develooment of chronic breathin11 disorders, includine asthma. LC!o : mice 12.6 nnm for 3 hours; hamsters 35.5 ,,nm for 3 hours Irritanc v of Ozone YES Sensitization lo Ozone NO Carci1102enicitv !NTP, IARC, OSHA) NO Reproductive Toxicity, Tcratogenicity, Not Proven Mulaacnicitv Toxicologically Synergistic Products Increased susceptibility to aller2ens, pathogens, irritants 12. ECOLOGICAL INFORMATION The immediate surrounding area may be adversely affected by an ozone release, particularly plant life. Discharge of ozone in water solution may be harmful to aquatic life. Due to natural decomposition, bionccumulation will not occur, and the area affected will be limited. 13. DISPOSAL CONSIDERATIONS Off-gassing ofozonc should be through an ozone destruct unit which breaks ozone down to ox1•2cn before release into the atmosohere. 14, TRANSPORT INFORMATION NOT APPLlCABLE, as ozone is unstable and either reacts or decomposes, and must be 2cnerated at the location and time of use. 15. REGULATORY INFORMATION SARA Title III Section 302 EHS TPO: 100 lbs. SARA Title III Section 304, EHS RQ: l 00 lbs. SARA Title ll1 Section 313: > I 0,000 lbs. uscd/,•ear. Source: EPA List of Lists 16. OTHER INFORMATlON Half-life ofozone in water at 20°C = 20 min; in dry still air at 2~°C = 25 hr; deerenses significantly with increase in humidity, presence of contaminants, air movement, and/or increase in temoerature. Preparer: Tim Mcconnel, Ozone Solutions Date of Preparation: 5/1/2012 Disclaimer: OzoM Solutious pro,ides this infom,ation in good faith but makts no ~laim a, to its compr~hen<iH ""S!I or accuracy. II is intcodetl solely ns n gUcidc for th~ ~3fe h,1ndling of II~ rroducl by prop~rly tmin,d p<.rso11ncl, •nd makes no representations l!f wnrranli~•. ~•pro• or implied, of the ~r~loanta~ilityor fitneu of1he product for 1111y purpose, alld Or.on~ Solution_s will not !kl roponsiblo lo, any &mag~• ..:suiting Ii-om the use of. or r~lian« 11po11. tiiis i11fonnatiQn . SAFETY DATA SHEET Hydrogen Peroxide (8 to 20%) MSDS Ref. No.: 7722-84-1-2 This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200 and Canada's Workplace Hazardous Materials Information System (WHMIS) requirements . 1. . PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Hydrogen Peroxide (8 to 20%) GENERAL USE: Standard 8% is formulated with an inorganic tin-based stabilizer for high stability and long term storage. Suitable for industrial bleaching, processing, pollution abatement and general oxidation reactions. Technical grade contains an organic based stabilizer. It is particularly useful in chemical synthesis where the presence of inorganic residues is objectionable. MANUFACTURER . E&C Chemicals, Inc. 211 Avenue C Carrollton, Georgia 30117 Tel: (770) 834-6207 Fax: (770) 834-6277 2. HAZARDS IDENTIFICATION EMERGENCY TELEPHONE NUMBERS For leak, fire, spill, or accident emergencies, call: {800) 424-9300 (CHEMTREC -U.S.A.) (613) 996-6666 (CANUTEC -Canada) EMERGENCY OVERVIEW: Clear, colorless, odorless liquid; Oxidizer. Contact with combustibles may cause fire. Decomposes yielding oxygen that supports combustion of organic matters and can cause overpressure if confined. Extremely irritating to eyes, nose, throat and lungs. POTENTIAL HEALTH EFFECTS: Extremely irritating to eyes, nose, throat and lungs. May cause skin irritation. 3. COMPOSITION/ INFORMATION ON INGREDIENTS Chemical Name CAS# W t.% EC No. EC Class Hydrogen Peroxide 7722-84-1 8-20 231-765-0 0, C, Xn; RS-R8-R35-R20/22 Water 7732-18-5 80-92 231-791-2 Not classified 4. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Flood with water. FIRE/ EXPLOSION HAZARDS: Product is non-combustible. On decomposition releases oxygen which may intensify fire. FIRE FIGHTING PROCEDURES: Any tank or container surrounded by fire should be flooded with water for cooling. Wear full protective clothing and self-contained breathing apparatus. FLAMMABLE LIMITS: Non-combustible SENSITIVITY TO IMPACT: No data available SENSITIVITY TO STATIC DISCHARGE: No data available Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06 /03 /2008 5. ACCIDENTAL RELEASE MEASURES RELEASE NOTES: Dilute with a large volume of water and hold in a pond or diked area until hydrogen peroxide decomposes. Dispose according to methods outlined for waste disposal. Combustible materials exposed to hydrogen peroxide should be immediately submerged in or rinsed with l~rge amounts of water to ensure that all hydrogen peroxide is removed. Residual hydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can concentrate) on organic materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result in a fire. 6. HANDLING AND STORAGE HANDLING: Wear chemical splash-type monogoggles and full-face shield, impervious clothing, such as rubber, PVC, etc ., and rubber or neoprene gloves and shoes . Avoid cotton, wool and leather. Avoid excessive heat and contamination . Contamination may cause decomposition and generation of oxygen gas which could result in high pressures and possible container rupture. Hydrogen peroxide should be stored only in vented containers and transferred only in a prescribed manner (see FMC Technical Bulletins). Never return unused hydrogen peroxide to original container, empty drums should be triple rinsed with water before discarding. Utensils used for handling hydrogen peroxide should only be made of glass, stainless steel, aluminum or plastic. STORAGE: Store drums in cool areas out of direct sunlight and away from combustibles. For bulk storage refer to FMC Technical Bulletins. COMMENTS: VENTILATION: Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into the work environment. 7. EXPOSURE CONTROLS/ PERSONAL PROTECTION EXPOSURE LIMITS Chemical Name !A CGIH OSHA Supplier Hydrogen Peroxide 1 ppm (TWA) 1 ppm (PEL) 1.4 mg/m3 (PEL) ENGINEERING CONTROLS: Ventilation should be provided to minimize the release of hydrogen peroxide vapors and mists into the work environment. Spills should be minimized or confined immediately to prevent release into the work area. Remove contaminated clothing immediately and wash before reuse. PERSONAL PROTECTIVE EQUIPMENT EVES AND FACE: Use chemical splash-type monogoggles and a full-face shield made of polycarbonate, acetate, polycarbonate/acetate, PETG or thermoplastic. RESPIRATORY: If concentrations in excess of 10 ppm are expected, use NIOSH/DHHS approved self-contained breathing apparatus (SCBA), or other approved atmospheric-supplied respirator (ASR) equipment (e.g., a full-face airline respirator (ALR)). DO NOT use any form of air-purifying respirator (APR) or filtering facepiece (AKA dust mask), especially those containing oxidizable sorbants such as activated carbon. PROTECTIVE CLOTHING: Rubber or neoprene footwear (avoid leather). Impervious clothing materials such as rubber, neoprene, nitrile or polyvinyl chloride (avoid cotton, wool and leather). Completely submerge hydrogen peroxide contaminated clothing or other materials in water prior to drying. Residual hydrogen peroxide, if allowed to dry on materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result in a fire. Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06 /03 /2 008 GLOVES: Liquid proof rubber or neoprene gloves. Thoroughly rinse the outside of gloves with water prior to removal. Inspect regularly for leaks . 8. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Odorless APPEARANCE: Clear, colorless liquid AUTOIGNITION TEMPERATURE: Non-combustible BOILING POINT:102°C {216°F) (8% and 10%) COEFFICIENT OF OIL/ WATER: Not available DENSITY/ WEIGHT PER VOLUME: Not available EVAPORATION RATE: > 1 (Butyl Acetate= 1) FLASH POINT: Non-combustible FREEZING POINT: -S°C (23°F) (8%); -6°C (21°F) (10%) ODOR THRESHOLD: Not available OXIDIZING PROPERTIES:Oxidizer PERCENT VOLATILE: 100 pH: 2.5 -3.5 5.0 -6.0 (1% solution) SOLUBILITY IN WATER: (in H20 % by wt) Above 1 SPECIFIC GRAVITY: (H20=1) 1.06 @ 20°C/4°C {8%); 1.03 @ 20°C/4°C (10%) VAPOR DENSITY: (Air= 1): Not available VAPOR PRESSURE: 31 mmHg@ 30°C (8%); 30 mmHg@ 30°C (10%) STABILITY AND REACTIVITY CONDITIONS TO AVOID:Excessive heat or contamination could cause product to become unstable. STABILITY: Stable (heat and contamination could cause decomposition) POLYMERIZATION: Will not occur INCOMPATIBLE MATERIALS: Reducing agents, wood, paper and other combustibles, iron and other heavy metals, copper alloys and caustic. HAZARDOUS DECOMPOSITION PRODUCTS: Oxygen which supports combustion. COMMENTS: Materials to Avoid : Dirt, organics, cyanides and combustibles such as wood, paper, oils, etc. 9. TOXICOLOGICAL INFORMATION EYE EFFECTS: 8% hydrogen peroxide: Extremely irritating (washed) (rabbit) 8% hydrogen peroxide: Moderately irritating (unwashed) (rabbit) 10% hydrogen peroxide: Extremely irritating (rabbit) SKIN EFFECTS: 10% hydrogen peroxide: Slightly irritating after 4 hr. exposure (rabbit) [FMC Study Number: 189-1078) DERMAL LDSO: 35% hydrogen peroxide:> 2,000 mg/kg (rabbit) [FMC Study Number: 183-746) ORAL LOSO: 10% hydrogen peroxide: > 5,000 mg/kg (rat) [FMC Study Number: 189-1077} INHALATION LCSO: 50% hydrogen peroxide: > 0.17 mg/I (rat) [FMC Study Number: 189-1080] TARGET ORGANS: Eyes, nose, throat and lungs ACUTE EFFECTS FROM OVEREXPOSURE : Extremely irritating to eyes, nose, throat and lungs. May cause skin irritation. CHRONIC EFFECTS FROM OVEREXPOSURE: The International Agency for Research on Cancer (IARC) has concluded that there is inadequate evidence for carcinogenicity of hydrogen peroxide in humans, but limited evidence in experimental animals (Group 3 -not classifiable as to its carcinogenicity to humans). The American Conference of Governmental Industrial Hygienists (ACGIH) has concluded that hydrogen peroxide is a 'Confirmed Animal Carcinogen with Unknown Relevance to Humans' (A3). 10. CARCINOGENICITY: Chemical Name IARC NTP OSHA Other Hydrogen Peroxide Not listed Not listed Not listed (ACGIH) Listed (A3, Animal Carcinogen) Hydrogen Peroxide (8 to 20%) (7722-84-1-2) 11. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: Channel catfish 96-hour LCSO = 37.4 mg/L Fathead minnow 96-hour LC50 = 16.4 mg/L Daphnia magna 24-hour EC50 = 7.7 mg/L Daphnia pulex 48-hour LC50 = 2.4 mg/L Freshwater snail 96-hour LC50 = 17.7 mg/L Date: 06/03/2008 For more information refer to ECETOC "Joint Assessment of Commodity Chemicals No. 22, Hydrogen Peroxide." ISSN-0773-6339, January 1993 12. CHEMICAL FATE INFORMATION: Hydrogen peroxide in the aquatic environment is subject to various reduction or oxidation processes and decomposes into water and oxygen. Hydrogen peroxide half-life in freshwater ranged from 8 hours to 20 days, in air from 10-20 hrs. and in soils from minutes to hours depending upon microbiological activity and metal contaminants. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: An acceptable method of disposal is to dilute with a large amount of water and allow the hydrogen peroxide to decompose followed by discharge into a suitable treatment system in accordance with all regulatory agencies. The appropriate regulatory agencies should be contacted prior to disposal. 14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) PROPER SHIPPING NAME: Hydrogen Peroxide, aqueous solutions with not less than 8%, but less than 20% hydrogen peroxide UN/NA NUMBER: UN 2984 PACKING GROUP: Ill LABEL(S): Oxidizer PLACARD(S): 5.1 (Oxidizer) ADDITIONAL INFORMATION: DOT Marking: Hydrogen Peroxide, aqueous solution with not less than 8%, but less than 20% Hydrogen Peroxide, UN 2984 Hazardous Substance/RQ: Not applicable 49 STCC Number: 4918689 DOT Spec: stainless steel/high purity aluminum cargo tanks and rail cars. UN Spec: HOPE drums. Contact FMC for specific details. INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) PROPER SHIPPING NAME: Hydrogen peroxide, aqueous solution with not less than 8%, but less than 20% peroxide. INTERNATIONAL CIVIL AVIATION ORGANIZATION {ICAO) / INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA) PROPER SHIPPING NAME: Hydrogen peroxide, aqueous solution with not less than 8%, but less than 20% peroxide(*). OTHER INFORMATION: (*) Air regulations permit shipment of Hydrogen Peroxide (8 -20%) in non-vented containers for Air Cargo Only aircraft, as well as for Passenger and Cargo aircraft. HOWEVER, all FMC Hydrogen Peroxide containers are vented and therefore, air shipments of FMC H202 is not permitted. IATA air regulations state that venting of packages containing oxidizing substances is not permitted for air transport. Protect from physical damage. Keep drums in upright position. Drums should not be stacked in transit. Do not store drum on wooden pallets. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE Ill (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A): Not listed SECTION 311 HAZARD CATEGORIES (40 CFR 370): Fire Hazard, Immediate (Acute) Health Hazard Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008 SECTION 312 THRESHOLD PLANNING QUANTITY {40 CFR 370): The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs; however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.: None, (cone. <52%) CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT) CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4): Unlisted (Hydrogen Peroxide 8-20%); RQ = 100 lbs.; lgnitability TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA INVENTORY STATUS (40 CFR 710): Listed RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261): Waste Number: D00l CANADA WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Hazard Classification/ Division: C D2B Ingredient Disclosure List: Domestic Substance List: INTERNATIONAL LISTINGS Hydrogen peroxide: China: Listed Japan {ENCS): (1)-419 Korea: KE-20204 Philippines (PICCS): Listed Listed All components listed HAZARD AND RISK PHRASE DESCRIPTIONS: EC Symbols: 0 (Oxidizer) C (Corrosive) EC Risk Phrases:RS (Heating may cause an explosion.) R8 (Contact with combustible material may cause fire) R35 (Causes severe burns.) R20/22 (Harmful by inhalation and if swallowed.) 16. OTHER INFORMATION HMIS Health Flammabilitv Phvsical Hazard 1 D 1 Personal Protection (PPE) H Xn (Harmful} Protection = H (Safety goggles, gloves, apron, the use of a supplied air or SCBA respirator is required in lieu of a vapor cartridge respirator) HMIS = Hazardous Materials Identification System Degree of Hazard Code: 4 = Severe 3 = Serious 2 = Moderate 1 = Slight O= Minimal NFPA Health Flammabilitv Reactivitv 5oecial 1 D 1 ox Hydrogen Peroxide (8 to 20%) (7722-84-1-2) SPECIAL= OX (Oxidizer) NFPA (National Fire Protection Association) Degree of Hazard Code: 4 = Extreme 3 = High 2 = Moderate 1 = Slight O = Insignificant Date : 06 /03 /2 008 Disclaimer: This information is provided in good faith, but makes no claim as to its comprehensiveness or accuracy. It is intended solely as a guide for the safe handling of the product by properly trained personnel, and makes no representations or warranties, express or implied, of the merchantability or fitness of the product for any purpose.