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HomeMy WebLinkAboutWI0600199_DEEMED FILES_20180420D~ tNJDGOOfC/9 North Carolina Department of Environmental Quality-Division of Water Resources INJECTION EVENT RECORD (IER) Permit Number __ WI0600199 _____ _ 1. Permit Information S&ME.Inc. Permittee TF-10806 Bestwav Amoco Facility Name l 00 and 104 North Blvd . Clinton . NC, Sam pson County Facility Address (include County) 2. Injection Contractor Information S&ME Inc. Injection Contractor / Company Name Street Address 3201 S prin a. Forest Rd Ralei gh, City L910_) 977-7614 NC State Area code -Phone number 3. Well Information 27616 Zip Code RECEIVEDINCOl;W£tW APR 2 n'20f8 . Water Quality Number of wells used for injectio~eg•o ,, Operations Sectlo Well IDs_MW-8 and MW-13 _____ _ Were any new wells installed during this injection event? D Yes XO No If yes, please provide the following information: Number of Monitoring Wells _____ _ Number oflnjection Wells ______ _ Type of Well Installed (Check applicable type): D Bored D Drilled D Direct-Push D Hand-Augured D Other (specify) __ _ Please include a copy of the GW-1 form for each well installed. Were any wells abandoned during this injection event? 0 Yes X □ No If yes, please provide the following information: Number of Monitoring Wells _____ _ Number oflnjection Wells ______ _ Please include a copy of the GW-30 for each well abandoned. 4. Injectant Information O-SOX: Calcium Peroxide, Calcium H vdroxide Injectant(s) Type (can use separate additional sheets if necessary: Solid Concentration 10-40 m g/L at in iection po int If the injectant is diluted please indicate the source dilution fluid. No ---------- Total Volume Injected (gal) 6 socks (2" x 3') Volume Injected per well (ga1)_3 socks at MW-8 3 socks at MW-13 5. Injection History Injection date(s)_ 4-3-2018 Injection number (e.g. 3 ofS)_l _____ _ Is this the last injection at this site? (unknown) 0 Yes O No I DO HEREBY CERTIFY THAT ALL THE INFORMATION ON THIS FORM IS CORRECT TO THE BEST OF MY KNOWLEDGE AND THAT THE INJECTION WAS PERFORMED WITHIN THE STANDARDSJ.,AID OUT IN THE PERMIT. ~ ~~,ti) <-17-2018 SI GNATURE OFirnCTION CONTRACTOR DATE Jamie T Honeycutt fS&ME Inc. -Agent for NCDEO Print Name of Person Perfonning the Injection Submit the original of this form to the Division of Water Resources within 30 days of injection. Attn: UIC Program, 1636 Mail Service Center, Raleigh, NC 27699-1636, Phone No. 919-807-6464 Fonn UIC-IER Rev. 3-1-2016 Permit Number Program Category Deemed Ground Water Permit Type Wl0600199 Injection Deemed In-situ Groundwater Remediation Well Primary Reviewer shristi.shrestha Coastal SWRule Permitted Flow Facility Facility Name Bestway Amoco TF-10806 Location Address 100 North Blvd Clinton Owner Owner Name NC 28328 Ncdeq Dwm Us! Section-Federal & Stsate Lead Program Dates/Events Orig Issue 4/9/2018 App Received 4/9/2018 Regulated Activities Groundwater remediation Outfall Waterbody Name Draft Initiated Scheduled Issuance Public Notice Central Files: APS SWP 4/17/2018 Permit Tracking Slip Status Active Version 1.00 Project Type New Project Permit Classification Individual Permit Contact Affiliation Hassan Osman 1637 Mail Service Ctr Raleigh NC 27699 Major/Minor Minor Facility Contact Affiliation Owner Type Government -State Owner Affiliation Mark Petennann 1646 Mail Service Ctr Raleigh Region Fayetteville County Sampson NC Issue 4/9/2018 Effective 4/9/2018 27699164 Expiration Requested /Received Events Streamlndex Number Current Class Subbasin North Carolina Department of Environmental Quality -Division of Water Resources NOTIFICATION OF INTENT (NOi) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are "permitted by rule" and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C .0200. This form shall be submitted at least 2 'WEEKS prior to iniection. AQUIFER TEST WELLS O SA NCAC 02C .0220 l These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION U SA NCAC 02c .0225) or TRACER WELLS (ISA NCAC 02c .0229}: 1) Passive Injection Systems -In-well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be submitted for replacement of each sock used in ORC systems). 2) Small-Scale Injection Operations -Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or g~oundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding i0,000 square feet. 3) Pilot Tests -Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells are located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells -Used to inject ambient air to enhance in-situ treatment of soil or groundwater. Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete. DATE: ~4/~3 ___ ~ 20_18_ PERMIT NO. VV 20 G O O I 'f 9 (to be filled in by DWR) A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (MW-8) B. (1) (2) (3) (4) (5) (6) --~Air Injection Well ...................................... Complete sections B through F, K, N --~Aquifer Test Well ....................................... Complete sections B through F, K, N X __ Passive Injection System ............................... Complete sections B through F, H-N ___ Small-Scale Injection Operation ...................... Complete sections B through N --~Pilot Test.. ............................................... Complete sections B through \J/NCOEQ/UVY' ___ Tracer Injection Well ................................... Complete sections B throu N PR -9 L01~ STATUS OF WELL OWNER: Choose an item. Vater Quality ,n :~ ·n,.,., C. WELL OWNER(S) -State name of Business/Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name: Hassan Osman, NCDEO, DWM, UST Section Mailing Address: 1646 Mail Service Center City: Raleigh State: NC Zip Code: 27699 County:~W~ak~e _____ _ Day Tele No.: 919-707-8167 Cell No.: _________ _ EMAIL Address: hassan.osman@ncdenr.gov Deemed Permitted GW Remediation NOi Rev. 8-28-2017 Fax No.: __________ _ Page I D. PROPERTY OWNER(S) (if different than well owner) Name and Title: ___ W~il=li=am~W~in=d=ers~----------------------- Company Name --~N~ot~A~pp..,_l=ic=a=bl=e _______________________ _ Mailing Address: __ ~5=13~0~R=o=s=e~bo=r=o=H=wy......,.___ ____________________ _ City: Clinton State: _NC_ Zip Code: 28328 County: Sampson Day Tele No.: ___________ _ CellNo.: __________ _ EMAIL Address: _____________ _ Fax No.: __________ _ E. PROJECT CONTACT (Typically Environmental Engineering Firm) Name and Title: Jamie T Honeycutt. Environmental Professional Company Name --~S~&=ME~~In~c~. ____________________ _ Mailing Address: ___ 3_2~0 _1 ~S .... onn_·~g~Fo~r_e_st_R_o_a_d _________________ _ City: Raleigh State: _NC_ Zip Code: ________ County: Wake Day Tele No.: 910-977-7614 Cell No.: 910-977-7614 EMAIL Address: __ _____.j=h=on=ec..;y~cu=tt=®"-"'=sm=em=· =c=.c=o=m~--Fax No.: __________ _ F. PHYSICAL LOCATION OF WELL SITE (1) Facility Name & Address: ---=-l-=-00=--N"-'-=orth=B=lv-=d __________________ _ City: --~C_lin_t~on ___ County~: ___ S~am~p_so_n _____ Zip Code: 2..8 ,2 2...8' (2) Geographic Coordinates: Latitude**: ___ 0 ____ "or 0 Longitude**: 0 __ "or 0 Reference Datum: ________ Accuracy: _______ _ Method of Collection: _________________ _ **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume: ______ square feet Land surface area ofinj. well network: square feet (S.10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: (must be:::_ 5% of plume for pilot test injections) H. INJECTION ZONE MAPS -Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and (2) Cross-section{s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. Deemed Permitted GW Remediation NOi Rev. 8-28-2017 Page2 I. DESCRIPTION OF PROPOSED INJECTION ACTMTIES -Provide a brief narrative regarding the purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration of injection over time. A release of gasoline from a former underground storage tank system located on up-gradient adjoining gasoline station property (TF 10806 Bestway Amoco) has impacted groundwater above the ISA NCAC 2L .0202 groundwater quality standards. Sixteen monitor wells have been installed on the TF 10806 Bestway Amoco site and surrounding properties. Monitor well {MW-8) is located on the subject site and contains the highest concentration of dissolved petroleum constituents. The use of O-SOX (Calcium peroxide or EHC-O chemical) using MW-8 is planned to enhance the degradation of petroleum contaminant levels in the groundwater. J. APPROVED INJECTANTS -Provide a MSDS for each injectant. Attach additional sheets if necessary. NOTE: Only injectants approved by the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at http://deq.nc.gov/about/divisions/water- resources/water-resources-errnits/wastewater-branch/ ound-water-rotection/ ound-water-roved-in· ectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919- 807-6496). Injectant: Calcium Peroxide in solid fonn, by sock of chemical in monitor well, for oxygen Volume ofinjectant: Varies, by diffusion. 1.75 lb EHC-0 or 0.2625 lb Oxygen per well Concentration at point of injection: ___ l_0_-4_0_m~g/L~-------------- Percent if in a mixture with other injectants: Calcium peroxide <75%. Calcium Hydroxide <25% K. WELL CONSTRUCTION DATA (1) Number of injection wells: __ O~ __ Proposed ___ l~ __ Existing (provide GW-ls) (2) For Proposed wells or Existing wells not having GW-1 s, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as-built): (a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery (b) Depth below land surface of casing, each grout type and depth, screen, and sand pack (c) Well contractor name and certification number Date Grout Screen (ft-Casing-Well Well Installed Type (ft-bis)-bis) Length Contractor Cert.# (ft-bis) MW-8 3/17/1993 Permanent Not 3.5-23.5 3.5 Not Provided Not Provided Provided L. SCHEDULES -Briefly describe the schedule for well construction and injection activities. Monitoring well MW-8 was installed in March 1993. Passive oxygen releasing O-SOXs will be placed into the existing well following receipt of the notification permit number from NCDEO. M. MONITORING PLAN -Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. Deemed Permitted OW Remediation NOi Rev. 8-28-2017 Page3 The injection of oxen is not expected to result in violations of the 21.. Standards. The monitor wdl will be 4ampled on a regular basis and additional O-SOXs installed as per NCDEQ . This ma, be followed by post- remediation sampling without oxygen infusion to check for rebound of contaminant levels N. SIGNATURE OF APPLICANT AND PROPERTY OWNER APPLICANT; "I herebycertify, under penalty oflaw, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, far submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the 114 MAC 0.2C 0200 Rules. " rt„ 2, it-r- Jamie T. Honeycutt t S&ME. Inc. Assent for NCDEO I 'Signature of A4plicant Print or Type Full Name and Title PROPERTY OWNER if the prgpcxt), is not owned by the permit applicant): "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection wells) conform to the Well Construction Standards f." '`Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. [.Signature of Property Owner (if different from applicant) Print or Type Full Name and Title `tin access agreement between the applicant and property owner may be submitted hi lieu of a signature on this form. Please send this NO1 electronically to Shristi.Shresthaa.ncdenr.gov AND one hard copy to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 807-6464 Deemed Permitted GIN Remediarion NOI Rev. 8.28-2017 Page 4 BP Station Petroleum MTs MW-7 (Missing) MW-3 (Missing) MW-4 (Missing) Former UST Area Former Pump Island Existing Pump Islands Former Pump Island Doni's Beauty Parlor REFERENCE: 2017 AERIAL PHOTOGRAPH AND 2017 PARCEL DATA OBTAINED FROM NC ONEMAP. MW-12 (Missing) Surface Water (5W-1) Surface Water ,SW-2j MW-ia (Missing) 0 120 240 GRAPHIC SCALE (IN FEET) L SCALE: FIGURE NO. SITE MAP 1 AS SHOWN DATE BESTWAY AMOCO TF-10806 HIGHWAY 421/NORTH BOULEVARD CLINTON, NORTH CAROLINA JAN. 2018 PROJECT NUMBER 4305-17-246 MW 39WEssrngj sw=x; ,Mw4 Iissinyj [onh MW1 MW-5 (1262S) 1.12o 67) • -- RW-1 NA) I MW-6 •"{126 631 ►t MIA,-10 (125 57} (175.40) 1124 48) MW-15 [122.46J LEGEND - MONITORING WELL LOCATION - RECOVERY WELL LOCATION (125.54) - MEASURED GROUNDWATER ELEVATION (OCTOBER 27, 2017) - GROUNDWATER CONTOUR - GROUNDWATER FLOW DIRECTION NA - NOT APPLICABLE REFERENCE: 2017 AERIAL PHOTOGRAPH AND 2017 PARCEL DATA OBTAINED FROM NC ONEMAP 0 120 240 GRAPHIC SCALE (IN FEET) GROUNDWATER CONTOUR MAP SCALE FIGURE NO. AS SHOWN DATE: BESTWAY AMOCO TF-10806 HIGFHWAY 421/NORTH BOULEVARD CLINTON, NORTH CAROLINA JAN. 2018 PROJECT NUMBER 4305-17-246 J Itereree EthiterceeA hepentreerrne McMy$ lert-0u[R ether e-Proployenrerc Tolone 12k76.TAL Ibero e L3STrormeltrylMmex Total xylem nrt#Ay1 AkeEeol erhMere ucAiAymruene Erylbeeiree hcrpropylbe rzire Methyl ten -butyl rue. NAIFRAalre nsmPFroer,rene Totem - MONITORING WELL LOCATION • RECOVERY WELL LOCATION • EXCEEDS THE 2L STANDARD .. - EXCEEDS BOTH THE 2L STANDARD AND SURFACE WATER STANDARD BY A FACTOR OF 181 - EXCEEDS THE APPLICABLE SURFACE WATER STANDARD BY A FACTOR OF 10 ug/L - MICROGRAMS PER LITER ND - NOT DETECTED SAMPLES COLLECTED OH OCTOBER 27, 2017 REFERENCE 2017 A(t1AL PRQTCGgAPH AND .^017 PARCEL DATA OBTAINED TRpu:K ON EWAP. q 129 GRAPHIC SCALE IN FEET) Jamie T Honeycutt From: Osman, Hassan <hassan.osman@ncdenr.gov> Sent Monday, March 12, 2018 9:29 AM To: Jamie T Honeycutt Subject: RE: [External] Agent Authorization for 0-SOX Installation Hi AII: I am the incident manager of Johnny Williams # 10938, and Bestway Amoco # 10806. I am giving S&ME (State Contractor) permission to act as an agent for NCDEQ. If you have any questions please contact me at (919) 707-8167. Thanks Hassan Osman Hydrogeologist IDWM, Underground Storage Tank Section Department of Environmental Quality (919) 707-8167 office hassan.ostnanCNnedenr.c ov 217 West Jones Street 1646 Mail Service Center Raleigh, NC 27699-1646 rph Via "Nat�ir�g Compares Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Jamie T Honeycutt (mailto:JHoneycutt@smeinc.comj Sent: Friday, March 09, 2018 3:24 PM To: Osman, Hassan <hassan,osman@ncdenr.gov> Subject: [External] Agent Authorization for O-SOX Installation Hassan, I'm working on the notification forms to install the 0-S0Xs in monitor wells at the TF 10938 Johnny Williams and TF 10806 Bestway Amoco site which have to be submitted to NCDEQ, DWR. In the past, DWR has requested that since S&ME is signing the form as an agent for NCDEQ, he needs an email from the NCDEQ Incident Manager giving S&ME permission to act as an agent for NCDEQ. You can respond to this email stating that you give S&ME permission to act as an agent for NCDEQ and I'il attach it to the Notification Form when I submit it. Thanks. 1 Please note that our logo hos changed. Click on our logo to learn more. Jamie T. Honeycutt Environmental Professional El I I S&ME 3201 Spring Forest Road Raleigh, NC 27616 map 0: 919.872.2660 M: 910.977.7614 jhoneycutt@smeinc.com www.smeinc.com LinkedlnlTwitterlFacebook This electronic message is subject to the terms of use set forth at www.smeinc.com/email. If you received this message in error please advise the sender by reply and delete this electronic message and any attachments. Please consider the environment before printing this email. 2 ADVENTUS P11761 7 Si* Sedirutyn.3ri[r GRuaitAv3rcv RN.]w d+arinri feChnnfrki" Safety Data MATERIAL. SAFETY DATA SHEET: O-SOXT" Page; l of ft 1. PRODUCT IDENTIFICATION: PRODUCT USE.: MANUFACTURER: Adventus Americas Inc. 2871 W. Forest Rd.. Suite 2 Freeport, IL. 61032 O-SOXTsi Soil and water treatment. EMERGENCY PHONE: Office Hours: After Hours: 815-95-3503 815-235-3506 TRANSPORTATION OF DANGEROUS GOOD CLASSIFICATION: Oxidi?ing Solid, n.o.s. (Calcium Peroxide), Class 5.1, PG II, UN1479 WHIMS CLASSIFICATION: Oxidizer 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients Calcium Peroxide Calcium Hydroxide 3. PHYSICAL. DATA Appearance, Physical state - Odor threshold Bulk Density Solubility in Water PH. Decomposition Temperature Chemical Turmula Cap, Ca(OH ) White & brown granule`; Solid None 500-650gfL Insoluble Hitt CHEMICAL EMERCFNCY Spill, Leek, ?ire Exposure of Accident Call 1 FOTRAC - 24-Hour Number: 1-800-53S-5053 Ottttiidt: of the United Status Call 4-Hour Numbrr: 001-3.iL.3 3500 CAS No. Percentage 1305-79-g 45%-70% i30.40ut 3-04-20 - -11 _. _-- Self -accelerating decomposition with oxygen release starting from 275 degrees Celsius 4. HAZARDS IDENTIFICATION Emergency overview Oxidizing agent. contact with other material may cause fire. Under fire conditions this material may decompose and release oxygen that intensifies fire. This product also contains crystalline silica. Long tern exposure to hazardous levels of silica dusts can cause lung disease (silicosis). The World Health Organization had indicated that there is limited evidence that crystalline silica is carcinogenic to humans. but the NTP and OSHA have not classified this ingredient as carcinogenic. Potential Health Effects: • General Irritating to mucous membrane and eyes. (ADVENTUS Aar Arrow+ Stni, tircrkurwaror Remediati ,i T.chnoikves Safety Data MATERIAL. SAFETY DATA SHEET: O-SOXTM Page: 2 of 6 • 1 nho lotion Irritating to respiratory tract. Long term inhalation of elevated levels may cause lung disease (silicosis). • Eye contact May cause irritation to the eyes; Risks of serious or permanent eye lesions. • Skin contact - May cause skin irritation. • Ingestion Irritation of the mouth and throat with nausea and vomiting. 5. FIRST AID MEASURES • Inhalation Remove affected person to Fresh air. Seek medical attention if effects persist_ • Eye contact Flush eyes with running water for at least 15 minutes with eyelids held open. Seek specialist advice. • Skin contact Wash affected skin with soap and mild detergent and large amounts of water. • Ingestion if the person is conscious and not convulsing. give 2-4 cupful:: of water to dilute the chemical and seek medical attention immediately. Do not induce vomiting. 6. FIRE FIGHTING MEASURE Hash Point • Not applicable Flammability • Not applicable Ignition Temperature • Not applicable Danger of Explosion • Non -explosive Extinguishing Media • Water Fire Hazards • Oxidizer. Storage vessels involved in a fire may vent gas or rupture due to internal pressure. Damp material may decompose exothermically and ignite combustibles. Oxygen release due to exothermic decomposition may support combustion. May ignite other combustible materials. Avoid contact with incompatible materials such as heavy metals, reducing agents. acids. bases, 1 ADVENTUS Po3vc i Surf, `v(1lrutdrlf, frxl S.,rWNkMmter Re wdintinr, raclxmkrea+ Safety Data MATERIAL SAFETY DATA SHEET: O SQXTM Page: 3 of ft combustible t wood, papers, cloths etc.) Thermal decomposition releases oxygen and heat. Pressure hursfs may occur due to gas evolution. Pressurization if confined when heated or decomposing, Containers may burst violently. Fire Fighting Measures • Evacuate all non-esrential personnel • Wear protective clothing and self-contained breathing apparatus. • Remain upwind of fire to avoid hazardous vapors and decomposition products. • Use water spray to cool Fire- exposed containers. 7. ACCIDENTAI. RELEASE MEASURES Spill Clean-up Procedure • Oxidizer. Eliminate all sources of Ignition. Evacuate unprotected personnel from equipment recnntmendatinns Found in Section 9. Never exceed any occupational exposure limit. • Shovel or sweep material into plastic bags or vented containers for disposal. Do not return spilled or contaminated material to inventory. Avoid making dust. • Flash remaining area with water to remove trace residue and dispose of properly. erly. Avoid direct discharge to sewers and surface waters. Notify authorities if entry occur.. • Do nol touch iir walk through spilled material. Keep away from ccmtbustiblcs (wood, paper. oiIN. etc,). Do not return product to container because of risk of contamination. K. HANDL1NC Arm STORAGE murage • Oxidizer, Store in a cool, well -ventilated area away from all source of it iiitinn and out of direct sunlight. Store in a dry location away from heat. • Keep away From incompatible materials. Keep containers tightly dosed. Do not store in unlabeled or rnislabeled containers. • Protect from moisture. Do not store near combustible materials. Keep containers well sealed. Ensure pressure relief and adequate ventilation. • Store separately from organics and reducing materials. Avoid contamination that may lead to decumposil ion. Handling • Avoid contact with eyes. skin. and clothing. Use with adequate ventilation. • Do not swallow. Avoid breathing vapors, mists, or dust. Do not cat. drink, or smoke in work area. • Prevent contact with combustible or organic materials. • Label containers and keep them tightly closed when not in use. • Wash thoroughly after handling. 9. EXPOSURE CONTROLS/PERSONAL PROTECTION ADVENTUS floven Sur! tic_Uimenr. and [;rwrrnvatet Rerr ahatioitt::,cf1rttFi' its Safety .µData MATERIAL SAFETY DATA SHEET: 0-SOXII1 Page: 4 of ti Engineering Controls • General room ventilation is required. Local exhaust ventilation, process enclosures or other engineers controls may be needed to maintain airborne levels below recommended exposure limits. Avoid creating dust or mist. Maintain adequate ventilation. Do not use in closed or confined space3i. Keep levels below exposure limits. To determine exposure limits. monitoring should he performed regularly, Respiratory Protection • For many condition. no respiratory protection may be needed; however. in dusty or unknown atmospheres or when exposures exceed limit values, wear a NIOSH iippii k.ed respirator. EyelFace Protection • Wear chemical safety goggles- and a full face shield while handling this product. Skin Protection • Prevent contact with this product. Wear gloves and protective clothing depending on condition of use. Protective gloves: Chemical -resistant (Recommended materials: PVC. neoprene or rubber) Other Protective Equipment • Eye-watih station • Safety shower • Impervious clothing • Rubber boots General Hygiene Considerations • Wa_tih with soap and water before meal times and at the end of each work shift. Good manufacturing practices require gross amounts of any chemical removed from skin as soon as practical. especially before eating or smoking, IU. STABILITY AND REACTIVITY Stability • Stable under normal conditions Condition to Avoid • Water • Acids • Bases • Salts of heavy metals • Reducing agents • Organic materials • Flammable tiubstances Hazardous Decomposition Products • Oxygen which supports combustion 11. TOXICOLOGICAL INFORMATION le) Provwi tire. Spain it. ark, 6rUuortwater Remettlatinu kchnorive..S ADVENTUS Safety Data MATERIAL SAI.t.i Y DATA SHEET: O.SOXTM Pages 5 of 6 • LD50 Oral: Min,2O00 mglkg. rat • LD50 Dermal: Min, 2000nigikg, rat • LD50 inhaI ii nn: Min. 4580 mg/kg, rat 12. ECOLOGICAL INFORMATION EcotoxiroI ngi ra I Information • Hazards for the environmenl is limited due to the product properticti or no hioaccumulation, weak solubility and precipitation in aquatic environment, Chemical Fate Wort -tuition • As indicated by chemical properties oxygen is released into the envirnnntenI 13. DISPOSAL CONSIDERATIONS Waste Treatment • Dispose of in an approved waste facility operated by an authorized coatroom in compliance 1ith local regulations, Package Treatment • The empty and clean containers are to be recycled or disposed of in conformity with local regulations. 14. TRANSPORT INFORMATION • Proper Shipping Name: EHC-O • Huard Class: 5.1 • Labels: 5.I (Oxidizer) • Packing Group: II 15. REGULATORY INFORMATION • SARA Section Yes • SARA (313) Chemicals No • EPA TSCA Inventory Appears • Canadian WHMIS Classification _C, D2B • Canadian DSL Appears • EtNECS Inventory Appears 16. PREPARATION INFORMATION Prepared }3y: Kerry Bolanos-Show Adventus Remediation Technologies 1345 rewster Drive MissisNauga, Ontario L4W 2A5 Date Prep./Rev: Print Date: Phone: Fax 113107 t13107 905-273-5374 905-2734367