WI0400526_DEEMED FILES_20191105

~~.b. Cawinia~Department of Environmental Quality-Division of Water Resources
INJECTION EVENT RECORD (I ER)
NOV 05 2019 D~ Vll~t.eo o ~
Permit Number NCWC 4415-C
I . Permit Information
ERM
Permittee
Energizer Plant
Facility Name
419 Art Brvan Dr, Asheboro. NC (Randolph
County)
Facility Address (include County)
2. Injection Contractor Information
Zachary Poole I Redox Tech, LLC
Injection Contractor/ Company Name
Street Address ;:.2-"--00~O:..-=u=ad=e=-D=-r _____ _
NC 27513
City State Zip Code
( 919 ) 678-0140
Area code -Phone number
3. Well Information
Number of wells used for injection ____ 2'---
Well IDs SVE -07 & AS-09
Were any new wells installed during this injection
event?
D Yes ■ No
If yes, please provide the following information:
Number of Monitoring Wells _____ _
Number oflnjection Wells. _______ _
Type of Well Installed (Check applicable type):
D Bored D Drilled O Direct-Push
D Hand-Augured O Other (specify) __ _
Please include a copy of the GW-1 form for each
well installed.
Were any wells abandoned during this injection
event?
D Yes ■ No
If yes, please provide the following information:
Number of Monitoring Wells _____ _
Number of Injection Wells _______ _
Please include a copy of the GW-30/or each well
abandoned.
4. Injectaot Information
Sodium Permanganate
Injectant(s) Type (can use separate additional sheets
if necessary
Concentration 10% --~"-"---------
If the injectant is diluted please indicate the source
dilution fluid. 40% ------'--"-'--''--------
Total Volume Injected (gal) __ _,2=·=2~00=----
Volume Injected per well (gal) 735( gal) for SVE-07
& l.465(gal) for AS-09
5. Injection History
Injection date(s) ___________ _
Injection number (e.g. 3 of 5) ______ _
Is this the last injection at this site?
0 Yes D No
I DO HEREBY CERTIFY THAT ALL THE
INFORMATION ON THIS FORM IS CORRECT TO
THE BEST OF MY KNOWLEDGE AND THAT THE
INJECTION WAS PERFORMED WITHIN THE
STANDARDS LAID OUT IN THE PERMIT.
10/25/19
SIGNATURE OF INJECTION CONTRACTOR DATE
Submit the original of this form to the Division of Water Resources within 30 days of injection .
Attn: UIC Program, 1636 Mail Service Center, Raleigh, NC 27699-1636, Phone No . 919-807-6464
Form UIC-IER
Rev. 3-1-2016
Zach arv le
PRINT NAME OF PERSON PERFORMING THE INJECTION
Submit the original of this form to the Division of Water Resources within 30 days of injection.
Attn: UIC Program, 1636 Mail Service Center, Raleigh, NC 27699-1636, Phone No. 919-807-6464
Form UIC-IER
Rev. 3-1-2016
Permit Number Wl0400526
Program Category
Deemed Ground Water
Permit Type
Injection Deemed In-situ Groundwater Remediation Well
Primary Reviewer
shristi.shrestha
Coastal SWRule
Permitted Flow
Facility
Facility Name
Energizer Manufacturing Inc.
Location Address
419 Art Bryan Dr
Asheboro
Owner
Owner Name
Energizer Manufacturing Inc
Dates/Events
NC
Orig Issue
9/6/2019
App Received
8/26/2019
Regulated Activities
Groundwater remediation
Outfall
Waterbody Name
27203
Draft Initiated
Scheduled
Issuance Public Notice
Central Files: APS SWP
9/6/2019
Permit Tracking Slip
Status
Active
Version
1.00
Project Type
New Project
Permit Classification
Individual
Permit Contact Affiliation
Major/Minor
Minor
Region
Winston-Salem
Facility Contact Affiliation
Scott Boyle
419 Art Bryan Dr
Asheboro
Owner Type
Non-Government
Owner Affiliation
Steve Hall
419 Art Bryan Dr
Asheboro
County
Randolph
NC
NC
Issue
9/6/2019
Effective
9/6/2019
27203
27203308
Expiration
Requested /Received Events
Streamlndex Number Current Class Subbasin
ERM
August 20, 2019
Shristi Shrestha, Hydrogeologist
NCDEQ DWR — U!C Program
1636 Mail Service Center
Raleigh, NC 27699-1636
[phone]
Reference: 0498725
15720 Bnxham Hill Avenue
Suite 120
Charlotte, NC
28277
Telephone: [phone]
Fax: [phone]
www.em.com
RE.CEIVIDINCEE0,113WR
AUG 6 2 2019
W otsr Qua}ay
Regional Opoarions Seaton
Subject: Notice of Intent to Construct or Operate Injection Wells - ISCO Pilot Test
Energizer Battery Manufacturing Inc.
419 Art Bryan Drive — Plant 11
Asheboro, Randolph County, North Carolina
Site ID. NCD000822957
Dear Shristi:
On behalf of Energizer, ERM NC, Inc. (ERM) is submitting this Notice of Intent (NOI) to Operate
injection Wells for a pilot test injection operation for the purpose of groundwater remediation at the
referenced site. Site remediation activities are being conducted in accordance with a NCDEQ
approved workplan detailing the activities.
This NOI is to cover a pilot study injection program that is to be conducted in two phases beginning
in October 2019. In the first phase, a limited injection volume will be delivered to the pifot test area to
evaluate the ability of the aquifer to accept a liquid amendment and to determine if precipitants from
the oxidation reaction will adversely affect the permeability of saturated aquifer near the injection
area. Slug testing will be conducted before and after the preliminary limited injection and the slug
test results will be used to determine if an unacceptable change in permeability of the saturated
aquifer in the injection area has occurred. If the preliminary limited injection does not result in an
unacceptable change in permeability, a second injection event will be conducted which delivers the
volume and mass of oxidant required to treat the contaminant mass present in the design pilot test
treatment area. The pilot study will include 4 groundwater monitoring events of the treatment area
including a baseline, 1 month, 3 month, and 6 month event.
If you have any questions regarding this project please contact me at [phone].
Sincerefy,
112-k-L
Alan Martin, P.G.
Project Manager
Enclosures
cc: Scott Boyle. Energizer
Torn Wilson, ERM
ERM

ERM 15720 Brixham Hill Avenue
Suite 120
Charlotte, NC
28277
Telephone: [phone]
Fax: [phone]

www.erm.com

August 20, 2019
Shristi Shrestha, Hydrogeologist
NCDEQ DWR – UIC Program
1636 Mail Service Center
Raleigh, NC 27699-1636
[phone]

Reference: 0498725

Subject: Notice of Intent to Construct or Operate Injection Wells - ISCO Pilot Test
Energizer Battery Manufacturing Inc.
419 Art Bryan Drive – Plant II
Asheboro, Randolph County, North Carolina
Site ID: NCD000822957

Dear Shristi:
On behalf of Energizer, ERM NC, Inc. (ERM) is submitting this Notice of Intent (NOI) to Operate
Injection Wells for a pilot test injection operation for the purpose of groundwater remediation at the
referenced site. Site remediation activities are being conducted in accordance with a NCDEQ
approved workplan detailing the activities.
This NOI is to cover a pilot study injection program that is to be conducted in two phases beginning
in October 2019. In the first phase, a limited injection volume will be delivered to the pilot test area to
evaluate the ability of the aquifer to accept a liquid amendment and to determine if precipitants from
the oxidation reaction will adversely affect the permeability of saturated aquifer near the injection
area. Slug testing will be conducted before and after the preliminary limited injection and the slug
test results will be used to determine if an unacceptable change in permeability of the saturated
aquifer in the injection area has occurred. If the preliminary limited injection does not result in an
unacceptable change in permeability, a second injection event will be conducted which delivers the
volume and mass of oxidant required to treat the contaminant mass present in the design pilot test
treatment area. The pilot study will include 4 groundwater monitoring events of the treatment area
including a baseline, 1 month, 3 month, and 6 month event.
If you have any questions regarding this project please contact me at [phone].

Sincerely,

Alan Martin, P.G.
Project Manager

Enclosures

cc: Scott Boyle, Energizer
Tom Wilson, ERM
ERM
Deemed Permitted GW Remediation NOI Rev. 3-21-2018 Page 1
North Carolina Department of Environmental Quality – Division of Water Resources

Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete.
DATE: August 16 , 2019____ PERMIT NO. (to be filled in by DWR)
A. WELL TYPE TO BE CONSTRUCTED OR OPERATED
(1)Air Injection Well……………………………..…Complete sections B through F, K, N
(2)Aquifer Test Well……………………….………..Complete sections B through F, K, N
(3)Passive Injection System…………………..……..Complete sections B through F, H-N
(4)Small-Scale Injection Operation………………….Complete sections B through N
(5) X Pilot Test………………………………………….Complete sections B through N
(6)Tracer Injection Well………………………….….Complete sections B through N
B.STATUS OF WELL OWNER: Business/Organization
C.WELL OWNER(S) – State name of Business/Agency, and Name and Title of person delegated authority to
sign on behalf of the business or agency:
Name(s): Energizer Manufacturing, Inc. - Steve Hall, Plant Manager
Mailing Address: 419 Art Bryan Drive
City: Asheboro State: NC Zip Code: 27203-3089 County: United States
Day Tele No.: 336-672-4501 Cell No.:
EMAIL Address: [e-mail] Fax No.:
NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS
The following are “permitted by rule” and do not require an individual permit when constructed in accordance
with the rules of 15A NCAC 02C .0200 (NOTE: This form must be received at least 14 DAYS prior to injection)
AQUIFER TEST WELLS (15A NCAC 02C .0220)
These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics.
IN SITU REMEDIATION (15A NCAC 02C .0225) or TRACER WELLS (15A NCAC 02C .0229):
1) Passive Injection Systems - In-well delivery systems to diffuse injectants into the subsurface. Examples include
ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be
submitted for replacement of each sock used in ORC systems).
2) Small-Scale Injection Operations – Injection wells located within a land surface area not to exceed 10,000
square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required
for test or treatment areas exceeding 10,000 square feet.
3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a
remediation strategy in order to develop a full scale remediation plan for future implementation, and where the
surface area of the injection zone wells are located within an area that does not exceed five percent of the land
surface above the known extent of groundwater contamination. An individual permit shall be required to conduct
more than one pilot test on any separate groundwater contaminant plume.
4) Air Injection Wells - Used to inject ambient air to enhance in-situ treatment of soil or groundwater.
Deemed Permitted GW Remediation NOI Rev. 3-21-2018 Page 2
D. PROPERTY OWNER(S) (if different than well owner/applicant)
Name and Title: Same as well owner
Company Name
Mailing Address:
City: State: _______Zip Code: County:
Day Tele No.: Cell No.:
EMAIL Address: Fax No.:

E. PROJECT CONTACT (Typically Environmental Engineering Firm)

Name and Title: Chris Means (Associate Geologist)
Company Name ERM NC, Inc.
Mailing Address: 15720 Brixham Hill Avenue, Suite 120
City: Charlotte State: NC Zip Code: 28277 County: Mecklenburg
Day Tele No.: 704-541-8345 Cell No.: 336-406-7625
EMAIL Address: [e-mail] Fax No.:

F. PHYSICAL LOCATION OF WELL SITE

(1) Facility Name & Address: 419 Art Bryan Drive

City: Asheboro County: Randolph Zip Code: 27203
(2) Geographic Coordinates: Latitude**: o ′ _____″N or 35 o. 769492
Longitude**: o ′ _____″W or -79 o. 817961
Reference Datum: Accuracy:
Method of Collection: Google Earth Pro
**FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY
BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES.

G. TREATMENT AREA

Land surface area of contaminant plume: 3,659,040 square feet (84 acres)
Land surface area of inj. well network: 5,000 square feet (< 10,000 ft2 for small-scale injections)
Percent of contaminant plume area to be treated: 0.137% (must be < 5% of plume for pilot test injections)

H. INJECTION ZONE MAPS – Attach the following to the notification.

(1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the
contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and
proposed injection wells; and
(2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical
extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed
monitoring wells, and existing and proposed injection wells.
(3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing
and proposed wells.

Deemed Permitted GW Remediation NOI Rev. 3-21-2018 Page 3
I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES – Provide a brief narrative regarding the
purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration
of injection over time.
The preliminary scope of work for the pilot test injection includes the following:
 ERM, on behalf of Energizer, will conduct a source area injection of sodium permanganate for pilot test
treatment of a dissolved contaminant plume containing primarily PCE and TCE. Two injection events
will comprise the pilot test. The initial treatment event will involve injecting a sodium permanganate
solution (up to 10% wt/wt) into one existing air sparge well AS-09 to treat the source area of the
dissolved contaminant plume. During the initial injection event, the injection location will receive
approximately 1,100 gallons of the 10% solution. The targeted injection zone is between 31 and 36 feet
below ground surface (bgs). The initial injection is to be completed by the low pressure gravity feeding
method if possible. A diaphragm pump will be added to assist the injection process if necessary.
 The supplemental injection event will include injecting 1,100 gallons of 10% sodium permanganate into
existing air sparging well AS-10 and existing soil vapor extraction (SVE) well SVE-7. The targeted
injection zone for the supplemental injection event is between 28 and 33 feet bgs in AS-10 and between
7 and 22 feet bgs in SVE-7. A total of 3,300 gallons of sodium permanganate solution will be injected
into the formation. Injection pressures in the treatment zone are expected to be less than 40 psi, if
pumping into the formation is required. The anticipated injection rate is between 1 and 5 gallons per
minute, although field conditions may vary. The injection events are anticipated to be completed in 5
days total for both events.
Based on the results of the injection activities described above, up to two additional pilot test injections may be
conducted to further evaluate the efficacy of ISCO for treatment of 1,4-dixoane in the pilot test area.

J. APPROVED INJECTANTS – Provide a MSDS for each injectant (attach additional sheets if necessary).

NOTE: Only injectants approved by the NC Division of Public Health, Department of Health and Human
Services can be injected. Approved injectants can be found online at http://deq.nc.gov/about/divisions/water-
resources/water-resources-permits/wastewater-branch/ground-water-protection/ground-water-approved-injectants.
All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919-
807-6496).

Injectant: Sodium Permanganate - RemOx L Carus Corporation
Volume of injectant: Up to 10,000 gallons
Concentration at point of injection: up to 12% by weight (mixed with water)
Percent if in a mixture with other injectants: Not applicable

Injectant:
Volume of injectant:
Concentration at point of injection:
Percent if in a mixture with other injectants:

Deemed Permitted GW Remediation NOI Rev. 3-21-2018 Page 4
K. WELL CONSTRUCTION DATA

(1) Number of injection wells: Proposed 3 Existing (provide GW-1s)
(2) For Proposed wells or Existing wells not having GW-1s, provide well construction details for each
injection well in a diagram or table format. A single diagram or line in a table can be used for
multiple wells with the same construction details. Well construction details shall include the
following (indicate if construction is proposed or as-built):
(a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery
(b) Depth below land surface of casing, each grout type and depth, screen, and sand pack
(c) Well contractor name and certification number
L. SCHEDULES – Briefly describe the schedule for well construction and injection activities.

The initial injection is scheduled to occur starting in late September 2019. The work should take approximately
3 days to complete. The secondary injection schedule is based on the initial results of the first injection and
anticipated to occur in November 2019. Additional pilot test injection events would be conducted as needed
based on the data collected from the pilot test area within 6 months of injection activities.

M. MONITORING PLAN – Describe below or in separate attachment a monitoring plan to be used to determine
if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity.

Prior to and immediately following ISCO implementation, groundwater samples will be collected from nearby
existing monitoring and observation wells. Additional groundwater monitoring events will be conducted 1
month, 3 month, and 6 months following the injection. A summary of the scheduled performance monitoring
from the ISCO Pilot Workplan (ERM) submitted to NCDEQ in July 2019 and approved by NCDEQ in August
2019 is attached.

N. SIGNATURE OF APPLICANT AND PROPERTY OWNER
Well Owner/Applicant: "1 hereby certii5), under penalty of law, that 1 am familiar with the information
submitted in this document and all attachments thereto and that, based on my inquiry of those individuals
immediately responsible for obtaining said information, 1 believe that the information is true, accurate and
complete. 1 am aware that there are significant penalties, including the possibility of fines and imprisonment,
for submitting false information. 1 agree to construct, operate, maintain, repair; and if applicable, abandon the
injection well and all related appurtenances in accordance with the 15A NCAC 02C 0200 Rules."
.5' i + tiziA 'i, 1A'tr+-1„ ' LI\ sST y"' A R,
Signa it o Applicant Print or Type Full Name and Title
Property Owner (if the property is not owned by the Well Owner/Applicant):
"As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to
allow the applicant to construct each injection well as outlined in this application and agree that it shall be the
responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards
(15A NCAC 02C .0200)."
"Owner" means any person who holds the fee or other property rights in the well being constructed. A well
is real property and its construction on land shall be deemed to vest ownership in the land owner, in the
absence of contrary agreement in writing.
Signature* of Property Owner (if different from applicant) Print or Type Full Name and Title
*An access agreement between the applicant and property owner may be submitted in lieu of a signature on this form.
Please send 1 (one) hard color copy of his NOI along with a copy on an attached CD or Flash Drive at least
two (2) weeks prior to injection to:
DWR— UIC Program
1636 Mail Service Center
Raleigh, NC 27699-1636
Telephone: [phone]
Deemed Permitted GW Remediation NO1 Rev. 3-21-2018 Page 5

INJECTION POINT BORING LOGS
Concrete
Gravel
Reddish orange clayey SILT
Tan fine sandy clayey SILT
Brown Sandy SILT
(PWR Auger refusal at 36)
38
36
34
32
30
28
26
24
22
20
18
16
14
12
10
8
6
4
2
0
Flushmount Steel Vault
Portland/Bentonite Grout
8.25" Diameter Borehole
2" Stainless Steel Casing
Bentonite Seal
Well Sand Filter Pack #3
2" Stainless Steel 0.010" Slot
Screen
End Cap
-
--
ML
ML
MH
Drilling Method:
Drilling Contractor:
Responsible Professional:
Borehole Diameter:
Drilling Equipment:
Total Depth (ft):
Elevation (msl):
Screened Interval:
Outer Casing Depth:
Depth to Water (Final):
Hollow Stem Auger
Geoprobe 7822DT
Chris Lacko (NC Driller #3516)
8.25"
TBD
36
31' - 36'
NA
TBD
ARS Technologies
Client:
Project:Date Started:
Date Completed:
Boring ID:
Logged By:
Project Number:
Site Location:
Energizer Asheboro
Plant II
0314524
AS-9
Tom Naumann
10/6/15
10/8/15
DepthLithologic Description Well
Construction Well Construction Details
Energizer
Latitude:
Longitude:
TBD
TBD
Lithology
....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........ ....... ........
......... . ..... . . ...... .. . ..... . . ...... .. . ..... . . ...... .. . ..... . . ...... ..
--...... . . ...... .. . ..... . . ...... ..
--...... . . ...... .. . ..... . . ...... .. . ..... . . ...... .. . ..... . __ ....... .. . ..... . . ...... .. . ..... . ___ _. .... .. . ..... . . ...... .. . ..... .
--....... .. . ..... . . ...... .. . ..... . . ...... .. . ..... .
ERM
Concrete
Gravel
Reddish orange clayey SILT
Tan fine sandy clayey SILT
24
22
20
18
16
14
12
10
8
6
4
2
0 Flushmount Steel Vault
4" Stainless Steel Casing
Portland/Bentonite Grout
Bentonite Seal
10.25" Diameter Borehole
Well Sand Filter Pack #1
4" Stainless Steel 0.005" Slot
Screen
End Cap
-
--
ML
ML
Drilling Method:
Drilling Contractor:
Responsible Professional:
Borehole Diameter:
Drilling Equipment:
Total Depth (ft):
Elevation (msl):
Screened Interval:
Outer Casing Depth:
Depth to Water (Final):
Hollow Stem Auger
Geoprobe 7822DT
Chris Lacko (NC Driller #3516)
10.25"
TBD
22
7' - 22'
NA
TBD
ARS Technologies
Client:
Project:Date Started:
Date Completed:
Boring ID:
Logged By:
Project Number:
Site Location:
Energizer Asheboro
Plant II
0314524
SVE-7
Tom Naumann
10/7/15
10/9/15
DepthLithologic Description Well
Construction Well Construction Details
Energizer
Latitude:
Longitude:
TBD
TBD
Lithology
ERM
Concrete
Gravel
Reddish orange clayey SILT
Tan fine sandy clayey SILT
Brown Sandy SILT
(PWR Auger refusal at 33)
34
32
30
28
26
24
22
20
18
16
14
12
10
8
6
4
2
0
Flushmount Steel Vault
Portland/Bentonite Grout
8.25" Diameter Borehole
2" PVC Casing
2" Stainless Steel Casing
Bentonite Seal
Well Sand Filter Pack #3
2" Stainless Steel 0.010" Slot
Screen
End Cap
-
--
ML
ML
MH
Drilling Method:
Drilling Contractor:
Responsible Professional:
Borehole Diameter:
Drilling Equipment:
Total Depth (ft):
Elevation (msl):
Screened Interval:
Outer Casing Depth:
Depth to Water (Final):
Hollow Stem Auger
Geoprobe 7822DT
Chris Lacko (NC Driller #3516)
8.25"
TBD
33
28' - 33'
NA
TBD
ARS Technologies
Client:
Project:Date Started:
Date Completed:
Boring ID:
Logged By:
Project Number:
Site Location:
Energizer Asheboro
Plant II
0314524
AS-10
Tom Naumann
10/6/15
10/8/15
DepthLithologic Description Well
Construction Well Construction Details
Energizer
Latitude:
Longitude:
TBD
TBD
Lithology
ERM
Table 1Energizer Asheboro Facility ‐ Source Area ISCO Pilot Treatment TestAddress: 419 Art Bryan Drive, Asheboro, North CarolinaDescripionNo. of Injection Points ConstructionDepth of Grout, Screen, and CasingTotal Depth(ft bgs)Injection Zone(ft bgs)Diameter(inch)Injection MethodAir Sparge Well AS‐9(Initial Pilot Injection Event)1 Permanent WellGrout = 0.5‐27Bentonite = 27‐29Sand = 29‐36Casing ‐ 0‐31Screen = 31‐36 36 31‐362Gravity Feed/PressurizedSoil Vapor Extraction Well SVE‐7(Supplemental Pilot Injection Event)1 Permanent WellGrout = 0.5‐3Bentonite = 3‐5Sand = 5‐22Casing ‐ 0‐7Screen = 7‐22 22 7‐22 4Gravity Feed/PressurizedAir Sparge Well AS‐10(Supplemental Pilot Injection Event)1 Permanent WellGrout = 0.5‐24Bentonite = 24‐26Sand = 26‐33Casing ‐ 0‐28Screen = 28‐3333 28‐33 2Gravity Feed/PressurizedObservation Well MW‐23Observation OnlyExisting Permanent WellGrout = 0.5‐7Bentonite = 7‐10Sand = 10‐27Casing ‐ 0‐12Screen = 12‐27 23Observation Only 2Observation OnlyObservation Wells OB‐5 A/B and OB‐6 A/BObservation OnlyProposed Permanent WellsGrout = 0.5‐10 & 0.5‐30Bentonite = 10‐13 & 30‐33Sand = 13‐25 & 33‐40Casing ‐ 0‐15 & 0‐35Screen = 15‐25 & 35‐40A ‐ 25B ‐ 40Observation Only2Observation OnlyNotes:bgs = below ground surface
FIGURES
Copyright:© 2013 National Geographic Society, i-cubed
02,000
Feet
1:24,000
Legend
D:\00GIS\EnergizerGIS\MXD\201703_GWRpt\F1_SLM.mxd, REVISED: 01/03/2017, SCALE: 1:24,000 when printed at 8.5x11DRAWN BY: A Freeman02,000
Feet
¯
1 inch = 2,000 feet
Source: Esri - World Topoographic Map
ERM
Environmental Resources
Management
www.erm.com
Figure 1
Site Location Map
Energizer Battery - Plant II
419 Art Bryan Drive
Asheboro, Randolph County
North Carolina
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Battery
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Legend
Site Wells
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Basemap NCCGIA.
ERM NC, Inc.
3/28/2017A FreemanAS SHOWN DATE:DRAWN:SCALE:
Figure 2
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419 Art Bryan Drive
Asheboro, Randolph County
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F4_SapGWE.mxd
ERM NC, Inc.
5/8/2019A FreemanAS SHOWN DATE:DRAWN:SCALE:
Figure 3Groundwater Elevation Contours Saprolite Aquifer - March 2019
Energizer Battery - Plant II
419 Art Bryan Drive
Asheboro, Randolph County
North Carolina
(668.02) Groundwater Elevation Measurement
\\SDCLTDC01\Data\Charlotte\Projects\0498725 Energizer Battery Manufacturing, In ASSVE System O&M.AM\SVE System O&M.AM\GIS\MXD\201904GWRpt\
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F6_SapTCE.mxd
ERM NC, Inc.
4/15/2019A. SoplataAS SHOWN DATE:DRAWN:SCALE:
Figure 4TCE Isoconcentration Contours Saprolite Aquifer - March 2019
Energizer Battery - Plant II
419 Art Bryan Drive
Asheboro, Randolph County
North Carolina
TCE = Trichloroethene
Concentrations in micrograms per liter (ug/L)
(1.4) = TCE concentration collected in March 2019
NS = No sample collected on this date
"<" = Not detected at a concentration greater than
the laboratory method detection limit
\\sdcltdc01\data\Charlotte\Projects\0498725 Energizer Battery Manufacturing, In ASSVE System O&M.AM\SVE System O&M.AM\GIS\MXD\201904GWRpt\
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02/22/17 <0.50 02/24/17 <0.50 02/21/17 3,600
09/07/17 <0.50 09/07/17 <0.50 9/8/17 4,000
02/14/18 1.7 02/14/18 <0.50 02/14/18 6,300
10/02/18 12 10/02/18 <0.50 10/04/18 250
03/07/19 <0.50 03/06/19 <0.50 03/07/19 330
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09/07/17 12,000 09/05/17 <0.50 9/5/17 <0.50
02/14/18 11,000 02/14/18 <0.50 02/15/18 <0.50
10/02/18 11,000 10/04/18 <0.50 10/03/18 <0.50
03/05/19 8,000 03/06/19 <0.50 03/04/19 <0.50
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02/23/17 14.0 02/23/17 <0.50 02/21/17 16,000
09/07/17 6.5 09/07/17 NS 09/08/17 30,000
02/12/18 2.1 02/15/18 NS 02/14/18 88,000
10/01/18 <0.50 10/04/18 <0.50 10/01/18 17,000
03/07/19 <0.50 03/05/19 <0.50 03/07/19 4,200
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09/05/17 2.0 09/06/17 170 09/08/17 1,600
02/13/18 2.2 02/15/18 8,200 02/15/18 4,300
10/03/18 1.6 10/05/18 1,100 10/01/18 570
03/07/19 18.0 03/08/19 3,700 03/07/19 330
MW-6 12/17/15 NS MW-23 12/17/15 520,000 OB-3 12/17/15 NS
11/29/16 NS 11/29/16 NS 11/29/16 1,700
02/22/17 <0.50 02/24/17 NS 02/21/17 NS
09/05/17 <0.50 09/07/17 88,000 09/08/17 740
02/13/18 <0.50 02/15/18 100,000 02/14/18 960
10/02/18 <0.50 10/05/18 10,000 10/04/18 4,900
03/06/19 <0.50 03/08/19 6,700 03/07/19 1,500
MW-11 12/17/15 NS MW-24 12/16/15 5,400
11/29/16 NS 11/29/16 6,100
02/24/17 16.0 02/22/17 6,100
09/07/17 11.0 09/08/17 8,200
02/14/18 21.0 02/14/18 6,300
10/03/18 6.5 10/04/18 3,600
03/06/19 1.4 03/07/19 11,000
NC 2L Ground Water StandardNC 2L Ground Water Standard NC 2L Ground Water Standard
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:9X Private Supply Water Well (Inactive)
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ERM NC, Inc.
4/18/2019A. SoplataAS SHOWN DATE:DRAWN:SCALE:
Figure 51,4-D Isoconcentration Contours Saprolite Aquifer (March 2019)
Energizer Battery - Plant II
419 Art Bryan Drive
Asheboro, Randolph County
North Carolina
Basemap Aerial provided by NC One Map
System Start-up February 22, 2016
SVE only (no sparge) Feb 22-Mar 28, 2016
AS started March 29, 2016
1,4-D = 1,4-Dioxane
Concentrations in micrograms per liter (ug/L)
(15) = 1,4-D concentration collected in March 2019
NS = No sample collected on this date
"<" = Not detected at a concentration greater than
the laboratory method detection limit
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\\sdcltdc01\data\Charlotte\Projects\0498725 Energizer Battery Manufacturing, In ASSVE System O&M.AM\SVE System O&M.AM\GIS\MXD\201904GWRpt\
Monitor Well Identification Date
1,4 Dioxane (Selective Ion Method - 8260B)Monitor Well Identification Date
1,4 Dioxane (Selective Ion Method - 8260B)Monitor Well Identification Date
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3 3 3
MW-2 12/17/15 <3.0 MW-15 12/17/15 NS MW-25 12/16/15 2.3
11/29/16 <3.0 11/29/16 NS 11/29/16 1.2
02/22/17 <3.0 02/24/17 <3.0 02/21/17 3.2
09/07/17 1.3 09/07/17 <3.0 09/08/17 2.1
02/14/18 <3.0 02/14/18 <3.0 02/14/18 1.3
10/02/18 <3.0 10/02/18 <3.0 10/04/18 <3.0
03/07/19 <3.0 03/06/19 1.1 03/07/19 <3.0
MW-3 12/17/15 NS MW-19 12/17/15 NS MW-28 12/17/15 NS
11/29/16 NS 11/29/16 NS 11/29/16 NS
02/23/17 1,800 02/23/17 <3.0 02/20/17 NS
09/07/17 2,200 09/05/17 <3.0 09/05/17 <3.0
02/14/18 1,700 02/14/18 <3.0 02/15/18 2.6
10/02/18 1,400 10/04/18 <3.0 10/03/18 <3.0
03/05/19 1,100 03/06/19 <3.0 03/04/19 <3.0
MW-4 12/17/15 NS MW-20 12/17/15 NS OB-1 12/16/15 32
11/29/16 NS 11/29/16 NS 11/29/16 NS
02/23/17 3.5 02/23/17 <3.0 02/21/17 180
09/07/17 1 09/07/17 NS 09/08/17 65
02/12/18 <3.0 02/15/18 NS 02/14/18 160
10/01/18 <3.0 10/04/18 <3.0 10/01/18 170
03/07/19 <3.0 03/05/19 <3.0 03/07/19 120
MW-5 12/17/15 NS MW-22 12/17/15 540 OB-2 12/16/15 <3.0
11/29/16 NS 11/29/16 1,200 11/29/16 2.8
02/21/17 17 02/24/17 800 02/21/17 5.4
09/05/17 5.3 09/06/17 360 09/08/17 8
02/13/18 1.7 02/15/18 2,400 02/15/18 2.4
10/03/18 <3.0 10/05/18 1,400 10/01/18 2.5
03/07/19 <3.0 03/08/19 1,900 03/07/19 15
MW-6 12/17/15 NS MW-23 12/17/15 6,200 OB-3 12/17/15 NS
11/29/16 NS 11/29/16 NS 11/29/16 NS
02/22/17 <3.0 02/24/17 NS 02/21/17 NS
09/05/17 <3.0 09/07/17 10000 09/08/17 180
02/13/18 <3.0 02/15/18 11,000 02/14/18 79
10/02/18 <3.0 10/05/18 10,000 10/04/18 140
03/06/19 <3.0 03/08/19 13,000 03/07/19 140
MW-11 12/17/15 NS MW-24 12/16/15 530
11/29/16 NS 11/29/16 1,100
02/24/17 1.2 02/22/17 1,000
09/07/17 <3.0 09/08/17 1,300
02/14/18 1.3 02/14/18 1,000
10/03/18 <3.0 10/04/18 350
03/06/19 <3.0 03/07/19 1,400
NC 2L Ground Water Standard NC 2L Ground Water Standard NC 2L Ground Water Standard
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ERM NC, Inc.
6/28/2019A FreemanAS SHOWN DATE:DRAWN:SCALE:
Figure 6Proposed Injection Layout
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II
ERM
6506556606656706756806856906957000 5 10 15 20 25 30 35 40FIGURECROSS SECTION A-A’ENERGIZER BATTERY - PLANT II419 ART BRYAN DRIVEASHEBORO, NORTH CAROLINA7SVE-07AS-09MW-23AS-101,4-Dioxane 13,000 µg/L TCE: 6,700 µg/LPCE: NDNote: Water level from MW-23 in March 2019. Contaminant concentrations from March 2019. PWRLOADING DOCKTANK FARMPilot test design notes:•Injection program will include the followingwells:•AS‐09 ‐Initial•SVE‐07 & AS‐10 ‐Supplemental•MW‐23 – Observation, existing•OB‐5 A/B & OB‐6 A/B ‐Observation,proposed•Slug testing of above wells pre‐and post‐initialinjection to evaluate effects on permeability•Sampling before injection (baseline) and at 1month, 3, month, and 6 months post injection•Injection treatment area is 20 feet deep by 30feet wide by 20 feet long.  Assume replace 10%of the pore space with injectant, results in3,300 gallons of injectant required.•Injection concentration 10% wt/wtsodiumpermanganate, or less.•Initial injection into AS‐09 of 1,100 gallons•Evaluate permeability impacts beforesubsequent•Supplemental injection of 1,100 gallons intoSVE‐07 and AS‐10•Total injection volume of 3,300 gallonsAA’Initial Injection WellSupplemental Injection WellSupplemental Injection WellExisting Observation WellOB-5 A/BProposed Observation WellOB-6 A/BProposed Observation WellI_•·-••-••··•-•·•-•-I .·.·.·.·.·.·.·.·.·.·.·. ERM .·.·.·.·.·.·.·.·.·.·,·,· )] !l /J !J :_\_\_\:_::,: :,1,1 :::::::: !l /::/:::::: I] ii ::::::j ~ }] ii )j !l • ". •. • ~ I! /J il ·.·.·., il )j i! nu ii }) 11 i:JEJH/J.~: :7':i: .. :'"~:':,,,':;,.\:': .. \7:77:7"""'"77"77"""""''"""""'""""""""""'" ________ _J .·.·, 1·-·.·.·.·.·.·.·.·.·.·.·.· II 1::!:!:!I!:i:!iJ:i:!:/
INJECTION PERFORMANCE MONITORING SUMMARY
PILOT TEST MONITORING PLAN
The following table outlines the proposed monitoring plan for the duration of the pilot test.
Pilot Test Monitoring Plan
Baseline and performance groundwater monitoring samples will be collected using low-flow groundwater
sampling methods. ERM proposes to use Shealy Environmental Services, Inc. (Shealy) of West
Columbia, SC (NC DEQ No. 329) or other NCDEQ-certified laboratory for analytical testing of VOCs via
EPA Method 8260. Groundwater samples will also be analyzed for 1,4-dioxane via EPA Method 8260B
SIM and manganese via EPA Method 200.7. Shealy will provide ERM with laboratory-prepared
containers. Upon filling each container, they will be labeled with the site name, analyses requested,
sampler’s initials, date of collection, and time of collection. This information will be transferred to the
chain-of-custody to ensure proper tracking and analysis of the sample. Groundwater samples will be
placed on ice immediately after collection and maintained under proper chain of custody control
throughout the handling process. 
Event Wells Ana lysis
Baseline SVE-07 , AS-09, . v oes vi a EPA Method 8260 B
AS-10, SV E-14 , . 1,4-Dioxane via EPA Method 8260B S IM'
AS-0 4, MW -23, . Ma nganese via EPA Met hod 200.7
O B-4N B , O B-5A/8 . Field parame ters: O RP, pH, DO , electrical con d uctivity (EC )
and tempera ture
Performance Sam pling MW -23, OB -4A /B, . v oes via EPA Method 8260B*
-1 month post injection O B-5N B . 1,4-Dioxane via EPA Method 8260B S IM* . Ma nganese via EPA Met hod 200.7 . Field parame ters: O RP, pH, DO , EC and tem pe rature
Performance sampling MW -23, OB -4A /B, . v oes vi a EPA Method 8260B*
-3 months foll owing O B-5A/B . 1,4-Dioxane via EPA Method 8260B S IM*
injection . Ma nganese via EPA Met hod 200.7 . Field parame ters: O RP, pH, DO , EC and tem pe rature
Performance sampling MW -23, OB -4A /B, . v oes via EPA Method 8260B*
-6 months fo ll owing O B-5N B . 1,4-Dioxane via EPA Me thod 8260B SIM *
injection . Manganese via EPA Me thod 200.7 . Fie ld parameters: O RP , pH , DO , EC and temperature
*If pennanganate is visib ly present in the well, sam ples wi ll e it h er be fie ld quench ed to consu me t h e remain in g pennanganat e
prior to laborat ory subm itta l, or will not be sampl ed, d epend ing on t he concentrati on of pennangan at e present.

Sodium Permanganate SDS
1. Identification
Product identifier
Other means of identification
Recommended use
Recommended restrictions
SAFETY DATA SHEET
RemOx® L ISCO Reagent
Not available.
Liquid oxidant recommended for applications that require a concentrated permanganate solution.
Use in accordance with supplier's recommendations.
Manufacturer / Importer / Supplier / Distributor information
Manufacturer/Supplier
Address
Telephone
E-mail
Website
Contact person
Emergency Telephone
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Environmental hazards
CARUS CORPORATION
315 Fifth Street,
Peru, IL 61354, USA
815 223-1500 - All other non -emergency inquiries about the product should be
directed to the company
[e-mail]
www.caruscorporation.com
Dr. Chithambarathanu Pillai
For Hazardous Materials [or Dangerous Goods] Incidents ONLY
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTREC®, USA: 001 [phone]
CHEMTREC®, Mexico (Toll -Free - must be dialed from within country):
01-800-681-9531
CHEMTREC®, Other countries: 001 [phone]
Oxidizing liquids
Acute toxicity, oral
Skin corrosion/irritation
Serious eye damage/eye irritation
Specific target organ toxicity, single exposure
Not classified.
Category 2
Category 4
Category 1 B
Category 1
Category 3 respiratory tract irritation
Danger
May intensify fire; oxidizer. Harmful if swallowed. Causes severe skin burns and eye damage. May
cause respiratory irritation.
Keep away from heat. Take any precaution to avoid mixing with combustibles. Keep/Store away
from clothing//combustible materials. Use only outdoors or in a well -ventilated area. Do not
breathe mist or vapor. Wear protective gloves/protective clothing/eye protection/face protection.
Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
In case of fire: Use water for extinction. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If on skin (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing
before reuse. If swallowed: Rinse mouth. Do NOT induce vomiting. If inhaled: Remove person to
fresh air and keep comfortable for breathing.
Store locked up. Store in a well -ventilated place. Keep container tightly closed.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Not classified.
Hazardous to the aquatic environment, acute Category 1
hazard
Hazardous to the aquatic environment,
long-term hazard
Category 1

Supplemental information
Hazard symbol
Hazard statement
Precautionary statement
Prevention
Response
Very toxic to aquatic life with long lasting effects.
Avoid release to the environment.
Collect spillage.
3. Composition/information on ingredients
Mixtures
Chemical name
CAS number
Sodium permanganate
10101-50-5 36 - 40
Composition comments
4. First -aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire -fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Move to fresh
air. For breathing difficulties, oxygen may be necessary. Call a physician or poison control center
immediately. Get medical attention immediately. Call a physician if symptoms develop or persist.
Get medical attention if symptoms persist.
Take off immediately all contaminated clothing. (Caution: Solution may ignite certain textiles).
Immediately flush skin with plenty of water. Get medical attention immediately. Wash
contaminated clothing before reuse.
Contact with skin may leave a brown stain of insoluble manganese dioxide. This can be easily
removed by washing with a mixture of equal volume of household vinegar and 3% hydrogen
peroxide, followed by washing with soap and water.
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open
eyelids wide apart. Continue rinsing. Get medical attention immediately.
Immediately rinse mouth and drink plenty of water. Never give anything by mouth to a victim who is
unconscious or is having convulsions. Do not induce vomiting. If vomiting occurs, keep head low
so that stomach content doesn't get into the lungs. Get medical attention immediately.
Before using, read Material Safety Data Sheet (MSDS) for this product. Rinse container at least
three times to an absence of pink color before disposing.
Contact with this material will cause burns to the skin, eyes and mucous membranes. Corrosive
effects. Irritation of eyes and mucous membranes. Symptoms may include stinging, tearing,
redness, swelling, and blurred vision. May cause temporary blindness and severe eye damage.
Permanent eye damage including blindness could result. Show this safety data sheet to the doctor
in attendance.
Provide general supportive measures and treat symptomatically. In case of shortness of breath,
give oxygen. Decomposition products are alkaline. Brown stain is insoluble manganese dioxide.
In the case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible). If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. For personal protection, see Section 8 of the MSDS. Show this safety data sheet to
the doctor in attendance. Wash contaminated clothing before reuse.
Flood with water from a distance, water spray or fog.
The following extinguishing media are ineffective: Dry chemical. Foam. Carbon dioxide (CO2).
Halogenated materials.
May intensify fire; oxidizer. May ignite combustibles (wood, paper, oil, clothing, etc.). Contact with
incompatible materials or heat (135 °C / 275 °F) could result in violent exothermic chemical
reaction. Oxidizing agent, may cause spontaneous ignition of combustible materials. By heating
and fire, corrosive vapors/gases may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace.

Fire -fighting
equipment/instructions
Move container from fire area if it can be done without risk. Cool containers exposed to flames with
water until well after the fire is out. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Dike fire control water for later disposal. Water runoff
can cause environmental damage.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Keep unnecessary personnel away. Keep upwind. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Avoid inhalation of vapors and contact with
skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Local
authorities should be advised if significant spillages cannot be contained.
Keep combustibles (wood, paper, oil, etc.) away from spilled material. Should not be released into
the environment. This product is miscible in water.
Large Spills: Stop leak if possible without any risk. Dike the spilled material, where this is possible.
Proceed with either of the following two options depending upon the size of the spill and the
availability of the neutralizing agents:
Option # 1: Dilute to approximately 6% with water, and then reduce with sodium thiosulfate, a
bisulfite or ferrous salt solution. The bisulfite or ferrous salt may require some dilute sulfuric acid
(10% w/w) to promote reduction. Neutralize with sodium carbonate to neutral pH, if acid was used.
Decant or filter and deposit sludge in approved landfill. Where permitted, the sludge may be
drained into sewer with large quantities of water.
Option # 2: Absorb with inert media like diatomaceous earth or inert floor dry, collect into a drum
and dispose of properly. Do not use saw dust or other incompatible media. Disposal of all
materials shall be in full and strict compliance with all federal, state, and local regulations
pertaining to permanganates.
To clean contaminated floors, flush with abundant quantities of water into sewer, if permitted by
federal, state, and local regulations. If not, collect water and treat as described above. Cover with
reducing agent (e.g. sodium bisulphite/thiosulphate or a ferrous salt plus 2M H2SO4). Transfer to
container with water and neutralize with soda ash. Otherwise, absorb spill with vermiculite or other
inert material, then place in a container for chemical waste. Do not use sawdust or other
combustible material. Following product recovery, flush area with water. Prevent product from
entering drains.
Small Spills: Cover with reducing agent (e.g. sodium bisulphite/thiosulphate or a ferrous salt plus
2M H2SO4). Transfer to container with water and neutralize with soda ash. Clean surface
thoroughly to remove residual contamination.
Never return spills in original containers for re -use. Never return spills in original containers for
re -use.
Do not allow to enter drains, sewers or watercourses. Contact local authorities in case of spillage
to drain/aquatic environment.
Take any precaution to avoid mixing with combustibles. Keep away from clothing and other
combustible materials. Do not get this material in your eyes, on your skin, or on your clothing. Do
not breathe mist or vapor. If clothing becomes contaminated, remove and wash off immediately.
Spontaneous ignition may occur in contact with cloth or paper. When using, do not eat, drink or
smoke. Good personal hygiene is necessary. Wash hands and contaminated areas with water and
soap before leaving the work site. Avoid release to the environment.
Store locked up. Keep container tightly closed and in a well -ventilated place. Store in a cool, dry
place. Store away from incompatible materials (See Section 10). Follow applicable
local/national/international recommendations on storage of oxidizers. Store in accordance with
NFPA 430 requirements for Class II oxidizers.
8. Exposure controls/personal protection
Occupational exposure limits No exposure limits noted for ingredient(s).
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type Value
Sodium permanganate Ceiling 5 mg/m3
(CAS 10101-50-5)
US. ACGIH Threshold Limit Values
Components
Type Value
Form
Sodium permanganate
(CAS 10101-50-5)
TWA
0.1 mg/m3 lnhalable fraction.
0.02 mg/m3 Respirable fraction.

US NIOSH Pocket Guide to Chemical Hazards: Recommended exposure limit (REL)
Components
Type Value
Form
Sodium permanganate TWA
(CAS 10101-50-5)
US NIOSH Pocket Guide to Chemical Hazards: Short Term Exposure Limit (STEL)
Components
1 mg/m3
Type Value
Fume.
Form
Sodium permanganate
(CAS 10101-50-5)
Biological limit values
Exposure guidelines
Appropriate engineering
controls
STEL 3 mg/m3
Fume.
No biological exposure limits noted for the ingredient(s).
Follow standard monitoring procedures.
Provide adequate general and local exhaust ventilation. An eye wash and safety shower must be
available in the immediate work area.
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.
Wear chemical -resistant, impervious gloves. Use protective gloves made of: Rubber or plastic.
Suitable gloves can be recommended by the glove supplier.
Wear appropriate chemical resistant clothing. Rubber or plastic apron.
In case of inadequate ventilation or risk of inhalation of vapors, use suitable respiratory equipment.
In the United States of America, if respirators are used, a program should be instituted to assure
compliance with OSHA 29 CFR 1910.134.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Keep from contact with clothing and other combustible
materials. Remove and wash contaminated clothing promptly. Wash hands before breaks and
immediately after handling the product. Handle in accordance with good industrial hygiene and
safety practice.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Dark purple liquid.
Liquid.
Aqueous solution.
Dark purple.
Odorless.
Not available.
5-8
< 24.8 °F (< -4 °C)
> 213.8 °F (> 101 °C)
Does not flash.
As water.
Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Partition coefficient
(n-octanol/water)
Auto -ignition temperature
Decomposition temperature
Viscosity
Not applicable.
Not applicable.
760 mm Hg (105 °C)
Not available.
1.37 - 1.4 (20 °C) ( Water = 1)
Miscible with water.
Not available.
Not available.
Not available.
Not available.

Other information
Explosive properties Not explosive. Can explode in contact with sulfuric acid, peroxides and metal powders.
Oxidizing properties Strong oxidizing agent.
10. Stability and reactivity
Reactivity The product is non -reactive under normal conditions of use, storage and transport.
Chemical stability Stable at normal conditions.
Possibility of hazardous Contact with combustible material may cause fire. Can explode in contact with sulfuric acid,
reactions peroxides and metal powders.
Conditions to avoid Contact with incompatible materials or heat (135 °C / 275 °F) could result in violent exothermic
chemical reaction.
Incompatible materials Acids. Peroxides. Reducing agents. Combustible material. Metal powders.
Hazardous decomposition By heating and fire, corrosive vapors/gases may be formed. Contact with hydrochloric acid
products liberates chlorine gas.
11. Toxicological information
Information on likely routes of exposure
Ingestion Causes digestive tract burns. Harmful if swallowed. Ingestion causes burns of the upper digestive
and respiratory tracts.
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Symptoms related to the Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent
physical, chemical and eye damage including blindness could result.
toxicological characteristics
Information on toxicological effects
Acute toxicity
Components
Causes severe skin burns and eye damage. Causes burns. Harmful if swallowed. Health injuries
are not known or expected under normal use. Harmful if swallowed.
Species Test Results
Potassium permanganate (CAS 7722-64-7)
Acute
Dermal
LD50 Rat 2000 mg/kg
Oral
LD50 Rat 2000 mg/kg
Toxicity data are not available for sodium permanganate. Toxicity is expected to be similar to that of potassium permanganate.
Skin corrosion/irritation Causes severe skin burns.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory sensitization Not classified.
Skin sensitization Not classified.
Germ cell mutagenicity Not classified.
Carcinogenicity Not classified.
Reproductive toxicity Not classified.
Specific target organ toxicity - May cause irritation of respiratory tract.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not classified.
Further information
Chronic effects are not expected when this product is used as intended. Prolonged exposure,
usually over many years, to manganese oxide fume/dust can lead to chronic manganese
poisoning, chiefly affecting the central nervous system.
12. Ecological information
Ecotoxicity Very toxic to aquatic life with long lasting effects.

Components
Species
Test Results
Potassium permanganate (CAS 7722-64-7)
Aquatic
Fish LC50
Toxicity data are not available
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Mobility in general
Other adverse effects
Bluegill (Lepomis macrochirus)
Carp (Cyprinus carpio)
Goldfish (Carassius auratus)
Milkfish, salmon -herring (Chanos
chanos)
Rainbow trout (Oncorhynchus mykiss)
2.7 mg/I, 96 hours, static
2.3 mg/I, 96 hours, flow through
2.3 mg/I, 96 hours
1.8 - 5.6 mg/I
3.16 - 3.77 mg/I, 96 hours
2.97 - 3.11 mg/I, 96 hours
3.3 - 3.93 mg/I, 96 hours, static
> 1.4 mg/I, 96 hours
1.8 mg/I, 96 hours
1.08 - 1.38 mg/I, 96 hours
0.77 - 1.27 mg/I, 96 hours
Rainbow trout,donaldson trout 0.275 - 0.339 mg/I, 96 hours
(Oncorhynchus mykiss)
for sodium permanganate. Toxicity is expected to be similar to that of potassium permanganate.
Expected to be readily converted by oxidizable materials to insoluble manganese oxide.
Potential to bioaccumulate is low.
The product is miscible with water. May spread in water systems.
The product is miscible with water. May spread in water systems.
None known.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Subsidiary class(es)
Packing group
Environmental hazards
Marine pollutant
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Subsidiary class(es)
Packaging group
Environmental hazards
Labels required
ERG Code
Dispose of contents/container in accordance with local/regional/national/international regulations.
Rinse container at least three times to an absence of pink color before disposing.
D001: Ignitable waste
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Do not allow this material to drain into sewers/water supplies. Dispose of in accordance with local
regulations.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Rinse container at least three times to an absence of pink color before disposing. Empty
containers should be taken to an approved waste handling site for recycling or disposal.
UN3214
Permanganates, inorganic, aqueous solution, n.o.s. (Sodium permanganate)
5.1
I I
Yes
Read safety instructions, SDS and emergency procedures before handling.
26, 353, IB2, T4, TP1
152
202
242
UN3214
Permanganates, inorganic, aqueous solution, n.o.s. (Sodium permanganate)
5.1
I I
Yes
5.1
5L

Special precautions for user
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Subsidiary class(es)
Packaging group
Environmental hazards
Marine pollutant
Labels required
EmS
Special precautions for user
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations
Read safety instructions, SDS and emergency procedures before handling.
UN3214
PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. (Sodium permanganate)
5.1
I I
Yes
5.1
F-H, S-Q
Read safety instructions, SDS and emergency procedures before handling.
This substance/mixture is not intended to be transported in bulk.
This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
CERCLA/SARA Hazardous Substances - Not applicable.
Drug Enforcement Administration (DEA) (21 CFR 1310.02 (b) 8: List II chemical.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Sodium permanganate (CAS 10101-50-5) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely
hazardous substance
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Chemical name
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
No
Yes
CAS number % by wt.
Sodium permanganate 10101-50-5 36 - 40
Potassium permanganate 7722-64-7 2
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Sodium permanganate (CAS 10101-50-5)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Sodium permanganate (CAS 10101-50-5) 6588
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Sodium permanganate (CAS 10101-50-5) 15 % wt
DEA Exempt Chemical Mixtures Code Number
Sodium permanganate (CAS 10101-50-5) 6588
Food and Drug
Administration (FDA)
Not regulated.

US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right -to -Know Act
Sodium permanganate (CAS 10101-50-5) 500 Ibs
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
US. Rhode Island RTK
Sodium permanganate (CAS 10101-50-5)
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) No
Canada Non -Domestic Substances List (NDSL) Yes
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version # 01
NFPA Ratings
References
27-November-2013
HSDB® - Hazardous Substances Data Bank
Registry of Toxic Effects of Chemical Substances (RTECS)
EPA: AQUIRE database
NLM: Hazardous Substances Data Base
US. IARC Monographs on Occupational Exposures to Chemical Agents
IARC Monographs. Overall Evaluation of Carcinogenicity
National Toxicology Program (NTP) Report on Carcinogens
ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices