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HomeMy WebLinkAboutWI0300452_Permit (Issuance)_20210420DocuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 NC Department of Environmental Quality — Division of Water Resources (DWR) NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are "permitted by rule"and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C.0200 (NOTE: This form must be received at least 14 DAYS prior to injection) AQUIFER TEST WELLS (15A NCAC 02C .0220) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION (15A NCAC 02C .0225) or TRACER WELLS (15A NCAC 02C .0229): 1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be submitted for replacement of each sock used in ORC systems). 2) Small -Scale Injection Operations - Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells is located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater. 5) In -Situ Thermal Wells (IST) - Used to `heat' contaminated groundwater to enhance remediation. Print Clearly or Type Information. Illegible Submittals Will Be Returned as Incomplete. DATE: April 1. 2021 PERMIT NO. W 10300452 (to be filled in by DWR) NOTE- If this NOI is being submitted as notification of a modification of a previously issued NOI for this site (e.g., different injection wells, plume, additives, etc.) and still meets the deemed permitted by rule criteria, provide the previously assigned permit tracking number and any needed relevant information to assess and approve injection: Permit No. WI Issued Date: A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) Air Injection Well Complete sections B through F, J, M (2) Aquifer Test Well . Complete sections B through F, J, M (3) Passive Injection System Complete sections B through F, H-M (4) X Small -Scale Injection Operation Complete sections B through M (5) Pilot Test . Complete sections B through M (6) Tracer Injection Well Complete sections B through M (7) In -Situ Thermal (IST) Well Complete sections B through M B. STATUS OF WELL OWNER: State Government Deemed Permitted GW Remediation NO1 Rev. 2-17-2020 Page 1 DocuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 C. WELL OWNER(S) — State name of Business/Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name(s): NCDEO — State Lead Program Mailing Address: 1 646 Mail Service Center City: Raleigh State: NC Zip Code: 27699 County: Wake Day Tele No.: 919-707-8168 Cell No.: Not Available EMAIL Address: Scott.Ryals@ncdenr.gov Fax No.: Not Available D. PROPERTY OWNER(S) (if different than well owner/applicant) Name and Title: Primax Properties, LLC Company Name Primax Properties, LLC Mailing Address: 1100 E Morehead Street City: Charlotte State: NC Zip Code: 28204 County: Mecklenburg Day Tele No.: Cell No.: Not Available EMAIL Address: Fax No.: Not Available E. PROJECT CONTACT (Typically Environmental ConsultinglEngineering Firm) Name and Title: AI Quarles, Senior Project Manager Company Name ATC Group Services Mailing Address: 7606 Whitehall Executive Center Drive, Suite 800 City: Charlotte State: NC Zip Code: 28273 County: Mecklenburg Day Tele No.: 704-529-3200 Cell No.: 803-984-6764 EMAIL Address: al.quarles(aatcgs.com Fax No.: 704-529-3272 F. PHYSICAL LOCATION OF WELL SITE (1) Facility Name & Address: McKinney Chevrolet, Incident 15651 725 York Road City: Kings Mountain (2) Geographic Coordinates: Latitude**: Longitude**: County: Cleveland Zip Code: 28086 " or 35.227929°. " or-81.332886°. Reference Datum: Former UST Basin Accuracy: Method of Collection: Google Earth **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume: 2,000 square feet Land surface area of inj. well network: 530 square feet (< 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: (must be < 5% of plume for pilot test injections) Deemed Permitted GW Remediation NO1 Rev. 2-17-2020 Page 2 DocuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 H. INJECTION ZONE MAPS — Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES AT THE SITE — Provide a brief narrative regarding the cause of the contamination, and purpose, scope, goals of the proposed injection activity: Gasoline UST release, with light non -aqueous phase liquid (LNAPL). Purpose of the injection is to mobilize LNAPL for removal by total fluid extraction (Aggressive Fluid Vapor Recovery or AFVR). Injection of up to 500 gallons of surfactant mixture (4% Ivey -soles 103 and water) into each of three monitoring wells (MW-2, MW-4, and MW-5) under low pressure during an approximately 8 to 10 hour period, followed by an 8-hour AFVR event conducted 1 to 2 days after the injection. Two weeks following the AFVR event, check for LNAPL in the wells and collect groundwater samples for laboratory analysis if no LNAPL. J. WELL CONSTRUCTION DATA (1) No. of injection wells: Proposed 3 Existing (provide NC Well Construction Record (GW-1) for each well) (2) Appx. injection depths (BLS): 5-15 ft (MW-2), and 10-20 ft (MW-4 and MW-5) (3) For Proposed wells or Existing wells not having GW-ls, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as -built): (a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery (b) Depth below land surface of casing, each grout type and depth, screen, and sand pack (c) Well contractor name and certification number K. INJECTION SUMMARY NOTE: Only injectants approved by the epidemiology section of the NC Division ofPublic Health, Department of Health and Human Services can he infected. Approved injectants can be found online at http:lldeq.nc. govlaboutldi visionslwa ter -re sourc a slwater-resources-per mitslwastewater-b ranch/ground-water- protectionlground-water-approved-injectants. All other substances must he reviewed by the DHHS prior to use. Contact the UIC Program for more info if you wish to get approval for a different additive. However, please note it may take 3 months or longer. If no injectants are to be used use N/A. Injectant: 4% Ivey-sol® 103 / 96% Water Total Amt. to be injected (gal)/event: 60 Ivey-sol® 1031 1,440 water Injectant: Total Amt. to be injected (gal)Ievent: Total Amt. to be injected (gal/event): 60 Ivey-sol® 103 / 1,440 water No. of separate injection events:1 Total Amt. to be injected (gal): 60 Ivey-sol® 103 / 1,440 water Deemed Permitted GW Remediation NO1 Rev. 2-17-2020 Page 3 DoeuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 Source of Water (if applicable): Municipal water, Winston-Salem L. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. A gauging of the monitoring wells to be conducted two weeks after the injectionlAFVR event. M. SIGNATURE OF APPLICANT AND PROPERTY OWNER Well Owner/Applicant: "I hereby certify, under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, 1 believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all rel ed appurtenances in accordance with the 15A NCAC 02C 0200 Rules." On behalf of NCDEQ, DWM Al Quarles, Senior Project Manager Signet r of Applicant Print or Type Full Name and Title Property Owner (if the property is not owned by the Well Owner/Applicant): "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C .0200)." "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the abseri eg fEcrntrary agreement in writing. 1�1 a Ytt (1 Signatutel of ri-operty Owner (if different from applicant) Print or Type Full Name and Title *An access agreement between the applicant and properly owner may be submitted in lieu of a signature on this, form. Please send 1 (one) hard color copy of this NOI along with a copy on an attached CD or Flash Drive at least two (2) weeks prior to injection to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 707-9000 Deemed Permitted GW Rcmediation NO1 Rev. 2-17-2020 Page 4 DocuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 Progress ~ P.O. Box 5884 NC 27113-5884 TELEPHONE; (336) 722- ENVIRONMENTAL INC Project: 13ojangle's Restaurant Job No.: 1016140.001 T rtcation: Winston-Salem, NC Boring/WellID:WIhTSTON-SUM- �� T 1V1VY- Date: August 2012 - � Pmject Manager: J. Ballsicpe Start Date: 8/12/16 Hole Diameter: 6.25" Total Depth: 20' Complete Date: 8/12/16 Casing Diameter: 2.00 (1.D.) Remarks - Drilling Method: Grairobe w/SSA Depth (feet) S le ID 0 b L, ILI p^ a3 i- 0 ay Q Geologic Deseri ?t19ri Well Diagram Ground Surface - — Pavement/gravel (5.0) Schedule 40 PVC ` - - ± (2.0') Grout cttm - Sea[onite Reddish brown fine sandy clay (15.O']O.O1O Slotted PVC • — . — " — = . { 1�� LD — — — Dark brownish red fine fine sandy clay 10 Greenish grey fine toanedium sand Strong Petr ole,nn Odor Light brown silty fine to medium sand Boring Terminated [g.20 feet bis 30 — 40 — SD — 60 — 30 40 50 Geologist: Page 1 of 1 DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 WELL CONSTRUCTION RECORD (GW-1) 1. Well Contractor Information: 7;1461 So 141 a.ft-4 W'cli Contractor Name 3307 NC Well Contactor Certification Number nv;roy, Mental Dian, + Pfob,`ny Serif' l'CPS Company Name 2. Well Construejon Permit #: List all applicable well construction permits (i,e. UI(:. County, State. Variance. etc.•i 3. Well Use (check well use): Water Supply Well: Agricultural Geothermal (Heating/Cooling Supply) Industrial/Commercial Irription Nyb-Water Supply well: p Mtmicipal/Public QResidential Water Supply (single) DResidentia! Water Supply (shared) Monitoring QRecovery Injection Well: Aquifer Recharge Aquifer Storage and Recovery Aquifer Test Experimental Technology Geothermal (Closed Loop) Geothermal (Heating/Cooling Return) 4. Date Well(s) Completed: 5a. Well Location: olOAo1 I'2s Facility/Owner Name ❑Groundwater Remediation Salinity Barrier 0Stormwater Drainage ()Subsidence Control Tracer Other (explain under 421 Remarks) Z-1`i-I Well ID# -y Facility !Ds: (if applicable) 585 West Mor+htAIes1- 8►vd. tJtrs nn- 5a/eM) Ile Physical Address. City. and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (dwell field, one lationg is sul iicteat) N W 6. $(are) the well(s) Permanent or DTemporary 7. Is this a repair to an existing well: Yes or No If this is a repair. fill out known well construction information and explain the nature of the repair under s 21 remarks section or on the back of this form 8. For Geoprobe/DPT or Closed -Loop Geothermal Wells having the same construction, only 1 GW;J is needed. indicate TOTAL NUMBER of wells drilled: O N is 9. Total well depth below land surface: I ZO For multiple wells list all depths if different (example- 3 0200' and 2ra1J00') (ft.) 10. Static water level below top of casing: (ft.) If water level Is above casing, use "- 11. Borehole diameter: 12. Well construction method: 8 (in.) NS1) (le auger, rotary, cable, direct push, etc ) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 136. Disinfection type: Amount: Print Form For Internal Use Only: 14. WATER. ZONES FROM TO fL ft n. 1t DESCRIPTION IS. OUTER CASING (for multi -eased wells) OR LINER Of appueable) FROM TO DIAMETER THICKNESS I MATERIAL 1t. ft. in. 16. INNER CASING OR TUBING (geothermal dosed -Mop) FROM TO DIAMETER THICKNESS MATERIAL r0 ft O n' 2 ir4 Sell. -to yiAfe fL ft. is 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL 7o ft 10 n• 2 0.01 Sc fl. ab eve ft ft. in. 18. GROUT FROM 8 I' CD ft TO ft C ..fL MATERIAL Bee. grove EMPLACEMENT METHOD & AMOUNT {peva rotor ft ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD xo. ft 9 ft -r oleo pev2 ft fL 20. DRILLING LOG (attach additional sheets if necessary) FROM ft TO ft DESCRIPTION (tyke, hardtsen, awl rock type, rinse me, eta) rt ft fL ft. ft ft ft ft. ft fL ft. rl. 21. REMARKS 22. Certification: Signal o - rufied Well Contractor Date By signing this form, 1 hereby cernf% :belt the-we/la/ was (were) constntcted in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to Me well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if nececcary. SUBMITTAL INSTRUCTIONS 24a. For Alt Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. Fur Infection Wells: In addition to sending the form to the address in 24a above, also submit one copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground injection Control Program, 1636 Mali Service Center, Raleigh, NC 27699-1636 24c. For Water Surely & Infection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well construction to the county health department of the county where constructed. ►Z jrelte Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revved 2-22-2016 DoouSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 1 Print Form Well Contractor Narnr WELL CONSTRUCTION RECORD (GW-1) 1. Well C'oatractor information: ?O t tivkl an Li tea 330 7 NC' Well CnntractOr ! enifscattnn Nnmbei r.%J iC0mme-ni-0.1 Dr,1tiir a a-- Pitrbirt, Sere ices Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UiC. Count). Stare. Variance. etc-1 3. Well Use (cheek well use): Water Supply Well: ['Agricultural (Geothermal (Heatmg/Cooling Supply) IndustnaWCommercial 1lrrigation N Water Supply Well: Monitoring Injection Well: Aquifer Recharge °Aquifer Storage and Recovery °Aquifer Test °Experimental Technology ['Geothermal (Closed Loop) °Geothermal (Heating/Cooling Return) °Municipal/Public °Residential Water Supply (single) }Residential Water Supply (shared) °Recovery ❑Groundwater Remediation ElSalinity Barrier DStormwater Drainage ▪ Subsidence Control °Tracer o Other (explain under #21 Remarks) 4. Date Well(s) Completed: 1? - 1- - tS Well ID# 1r►'I W - S- 53. Well Location: gO)aNgleS Facility/Owner Nirne Facility 1120( (if applicable) 58 5 Lest AlorHtwtst 8)vd. t.jfiithi,-gait' , Nc Physical Address, City, and Zip County Parcel Identification No (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: i,rf well field, one lat/long Is sufficient) %V 6. Is(are) the wcll(stePermanent or Dl empnrarn 7. Is this a repair to an existing well: ON es or �Tio If this is a repair. fill out known well construction information and explain the native of the repair under =21 remarks section or on the back of this form. 8. For Geoprobe/DP[ or Closed -Loop Geothermal Wells having the same construction, only 1 OW-1 is needed. Indicate TOTAL NUMBER of wells drilled: O NE 9. Total well depth below land surface: 1 e ZO For multiple wells list tall depths if different (example- 3(0200' and 2'd;1ool (ft) 10. Static water level below top of casing: (ft) If water level is above casing, use "- " 11. Borehole diameter: 11 Well construction method: 8 (in.) H5W (re. auger, rotary. cable, claret push. etc FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: For Interval Use Only: 14. WATER ZONES FROM TO DESCRIPTION ft. fL fL 15. OUTER CASING (for multi -eased wells) O FROM It. TO IL DIAMETER in. R ICICNE(BaTATERLL MA) 77HCK1VESS 16. INNER CASING OR TUBING (geothermal dosed -loop) FROM TO DIAMETER THICKNESS MATERIAL ib ft. fit. 2 in. SC.H. Ho pvc . it. ft in. 17. SCREEN FROM TO DIAMETER SLOT S12E THICKNESS MATERIAL 2O 10 rt in. 0.0 1 9CH.qo pvt ft. ft. in. 18. GROUT FROM 8 ft. fit ft. fL O it ft. MATERIAL 19. SAND/GRAVEL PACK (if appliable) FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT pooR pov& EMPLACEMENT METHOD 0 rt 8 ft It z rneo pouR ft. rt. 20. DRILLING LOG (attach additional sheets if necessary) FROM ft. TO ft DF:SCRIP77ON (ceder, hardness, ■e12n,ek type, grata size, etc-) r1. ft. ft ft ft ft ft. fit D. fit 21. REMARKS ft 22. Certification: Signature o Certified Well Contractor 1z)18/18 Date By signing this form. 1 hereby cert fi that the- well(s) was (were) constructed in accordance with 15A NC,IC 02C .0100 or 1 SA NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resource,, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Iniection Wells: in addition to sending the form to the address in 24a above, also submit one copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground injection Control Program, 1636 Mail Service Center, Rakigh, NC 27699-1636 24c. For Water Supply & lniection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well construction to the county health department of the county where constructed. Form GW-t North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 DocuSign Envelope ID: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 4'1•1)-4 I verg In tern a banal Inc. • ard.. ` " Today's Environmental Solutions For A Better Tomorrow" ATC Associates of North Carolina, P.C. 7606 Whitehall Executive Center Drive Suite 800 Charlotte, NC 28273 ATTN: Al Quarles, P.G. - Senior Project Manager RE: February 19, 2021 Ivey -sot® Surfactant Enhanced Remediation (SER®) Proposal Bojangles #552 - 584 West North West Blvd. Winston-Salem, NC Site ATC Project # 5LP4499208 NCDEQ Incident # 44992 Task Authorization: TA-08 1.0 OVERVIEW Ivey International Inc. (IVEY) is pleased to provide ATC Associates of North Carolina, P.C. (ATC) with this proposal for an in -situ Ivey -sot® Surfactant Enhanced Remediation (SER®) application, to treat a Gasoline LNAPL plume, at the Bojangles #552 Restaurant site, located at 584 West North West Blvd. Winston-Salem, NC (Figure 1-1). IAO4RPRING WELL l OCATION GRALl1FAWAT ER EiEVA T#JN 34 PEET) PAY MEASLREa GR611NEWATER ELEATION COp1OGJR LNE GMQUNYWATER Flom O'RECTNDr. Figure 1-1: Proposed IW Locations in Red Proposed EW Locations in © Ivey International Inc. Tel: + 1 604 538 1158 I Fax: + 1 888 640 3522 www. i►reyinternationaicom IW' and EW's MW-2, 4, 5 Not using MW-6 or MW-7 Doousign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ivey International Inc. "Today's Environmental Solutions For A Better Tomorrow" Page 2 of 18 The subject site is presently occupied and operating as a Bojangles Restaurant. The site was the historical location of a commercial business with an underground storage tank (UST) that leaked (>25 years ago) gasoline petroleum hydrocarbons into the subsurface, resulting in impacts the local soil and groundwater regimes. These impacts were discovered in August 2016. AST has confirmed the presence of light non aqueous phase liquids (LNAPL), which are the primary focus of site remediation. None of the former UST system remains onsite, with its suspected location indicated on Figure 1-1. ATC has indicated that they would like to perform an in -situ Ivey -soli SERF application at three (3) injection wells (IW): MW-2, MW-4, and MW-5, comprised of 300 to 500 Gal. of diluted Ivey -sot° 103 at each IW. Then following a residence time of --24 to 48 hours, they would perform an AFVR event, at two (2) Extraction Wells (EW) MW-6 and MW-7, to remove liberated sorbed, globule, and LNAPL phase COC mass. The effectiveness of these applications will be limited to the hydraulic communication between the IW and EW locations, and contact that is achieved with the sorbed, globule, and LNAPL mass, within the smear -zone. IVEY understands all IW locations are screened across the anticipated COC smear -zone, and 6.25 inches in diameter. This proposal is based on site information provided by ATC to IVEY, via email communication on February 13, 2021. This was limited to the Groundwater Monitoring Report (April 13, 2020), three (3) bore hold (BH) logs (MW-1, MW-2, and MW-3), and the IVEY 1-page writable site evaluation. This information, collectively, provided a site description, spill history, hydrogeological data, site figures, well construction details, and soil and groundwater related data. IVEY will provide application illustrations and an animation link within this document to convey how in -situ lveysoI® `Push-PullT""' injection and extraction events are undertaken, and how the observed COC and LNAPL contaminant mass remediation can be achieved. Client testimonials, published case studies, and related technical information will be appended to this proposal, and/or provided under separate cover, to augment the information presented in the proposal. Three-dimensional animations of in -situ Ivey-sol® `Push -Pull' and `Sweep' applications are provided via an internet link in Section 3.1. 1.1 TERMS OF REFERENCE The background site information provided to IVEY by ATC include: • Land use of the site is understood to be Commercial; • COC impacts in gasoline range including: BTEX and LNAPL; • Soil and groundwater COC impacts have been confirmed on -site; ■ Source of COC and LNAPL was former gasoline UST spill (>25 years ago); © Ivey International Inc. Tel: + 1 604 538 1158 I Fax: + 1 888 640 3522 www. i►reyinternational.com DomSign Envelope ID: F605E1AD-6FB8-4EDO-AAD3-072D7E168711 Ivey International Inc. "Today's fnvrranmenlil SoWutrons For A 8ene► Tomorrow" Page 3 of 18 • Depth to groundwater table -8 to 11 ft. (+1-) below ground surface (bgs), with a smear -zone equal to groundwater elevation fluctuations on -site; • ATC will inject 300 to 500 Gal. of Ivey-soP 103 at IW locations: MW-2, MW-4, and MW-5, and extract at EW locations MW-6 and MW-7. IW's MW-2, 4, 5 • The MW locations are 6.25 inch in diameter (Based on BH logs provided); • Shallow geology described as fine sandy silt to fine sandy clay to 20 ft. bgs; • The soil porosity indicated as -35 to 45%; • The hydraulic conductivity (K) indicated as 1 x 10-4 to 1 x 10-5 cm/sec; • The hydraulic gradient was indicated as -0.025; • The groundwater flow direction is to the northwest; • Area of COC contamination was indicated as--3,500 ft.2 (>2B); • Maximum depth of COC contamination was not indicated -18 ft. (+1-) bgs; • Primary remediation goal is to eliminate LNAPL, and significant reduction in COC; • Although ATC will use MW-2, MW-4 and MW-5, as IW's, and MW-6 and MW-7 as EW's, for the Ivey-sol® Push -Pull' applications, other wells on -site could also be employed. 1.2 CHALLENGE & OPPORTUNITY Normally hydrophobic organic chemicals (HOC), including low (Le., BTEX, MTBE and Gasoline), medium (i.e., Diesel and PAH), and high (i.e., Motor Oil, Lubricants, Bunker- C) molecular weight petroleum hydrocarbon contaminants (C6 to C5o range) exhibit limited solubility in groundwater, this is also true of chlorinated solvents, and as a result, these contaminants tend to partition and sorb (i.e., absorb and/or adsorb) onto the soil or weather bedrock matrix surfaces, and at high concentrations, they may form a free floating sheen or droplets (LNAPL) residing in pore spaces. For the purpose of this proposal HOC will be interchangeable COC. COC sorption and/or the formation of LNAPL (free product) will limit the Availability' of HOC for in -situ remediation. Hence they are less Physically Available' for pump and treatment methods; less Biologically Available' for bioremediation, and less 'Chemically Available' for chemical REDOX type chemical treatment. Hence COC (i.e., sorbed, dissolved, and/or free phases) can persist in soils, sediments, and fractured bedrock and/or groundwater systems for extended periods of time. This explains why some remediation projects are slow, costly and/or fail to achieve site remediation objectives. A concern regarding contaminant sorption, and its reduced availability for remediation, has been well cited in literature as demonstrated by the following sample quotation: "During the past decade, much discussion has centered on the unavailability of absorbed compounds to soil microorganisms; it is generally now assumed that desorption and diffusion of bound contaminants to the aqueous phase is required for microbial degradation." (W.F. lnskeep, J.M. Wraith, C.G. Johnston, Hazardous Substance Research Center, 2005). © Ivey International Inc. Tel: + 1 604 538 1158 I Fax: + 1 888 640 3522 www. i►►eyinternational.com DomSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ivey International Inc. "Today's Envirwunenta! Soiotioss For A 8arte► Tomorrow" Page 4 of 18 Generally, if we can overcome COC contaminant sorption and/or LNAPL formation, we can improve all forms of physical, biological, and chemical - air (vaporNOC), soil, and groundwater COC (LNAPL) remediation. The application and use of Ivey-sol® surfactant products and processes provided a unique methodology to enhance COC remediation at many sites globally. This is evidenced by many conference paper and poster presentations, peer reviewed journal publications, published case studies, magazine articles, and client testimonials (See Appendix). 1.3 FIELD SCALE OBJECTIVE The main focus for the Iveysol® applications would be to demonstrate effective LNAPL remediation within the COC plume area on -site. This will involve the completion of one (1) significant `Push -Pull' application at three (3) IW's (i.e. MW-2, MW-4, and MW-5) with extraction at two (2) EW's (i.e., MW-6 and MW-7) as the scope of work. Although the spill volume and mass remain unknown, this approach should produce a favourable LNAPL mass reductions, toward the site remediation goal. The remediation of the ❑bserved LNAPL will require the application of Ivey-soI® 103 based ❑n the characterization of the historical spill, and vapor, soil and groundwater analysis. This recommendation is based on the Ivey -soli guidance Table 1-1. Table 1-1 Ivey-soI° Product Application Guidelines Contaminant of Concern (COC) Ivey -sole Formulation Required BTEX, MTBE, Gasoline, Jet Fuel Diesel (Light -Medium Heavy), PAH Chlorinated Solvents (DNAPL, API <10) Motor Oil, Lubricants, Bunker-C 103 106 106 (CI) 108 Note: For COC not listed above contact IVEY. 'X' indicates Ivey-sol® formulations needed for subject site. 2.0 IVEY-SOL® SURFACTANT TECHNOLOGY This section will describe the Ivey-sol® surfactant technology and will include a range of in -situ and ex -situ applications, advantages and disadvantages, and the science of how it works below the critical micelle concentration (CMC). © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DomSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ivey International Inc. "Today's Erwironme:11W SoWotrons For A 8erte► Tomorrow" Page 5 of 18 2.1 IVEY-SQL® TECHNOLOGY Ivey-sol® Surfactant Technology is comprised of several patented and/or proprietary non- ionic surfactant formulations (biodegradable) that have the unique ability to selectively desorb sorbed (Le., absorbed and/or adsorbed) COC, and make NAPL miscible in the aqueous phase. This includes the broad range of Light Non Aqueous Phase Liquids (LNAPL) like petroleum hydrocarbons (API >10), and the Dense Non Aqueous Phase Liquids (DNAPL) including chlorinated solvents (API <10). Ivey-sol® has also been used for the remediation of recalcitrant compounds within fine to coarse soil textures, marine sediments and fractured bedrock, and within the groundwater table and associated smear -zones and capillary zones, with favorable results. The three (3) main Ivey -soli' application processes that were developed over two (2) decades for enhancing in -situ and ex -situ remediation of: Vapors/VOC, Soil/Bedrock (sorbed), and Groundwater (Dissolved, LNAPL, and Smear -Zone) COC site remediation, are outlined as follows: • SER® Surfactant Enhanced Remediation In -situ and ex -situ application processes to liberate sorbed and/or LNAPL COC making them more miscible (soluble) and more `Physically Available' for mass removal via `Sweep' or `Pump & Treatment' type remediation methods. It is also very effective for ex - situ soil washing of COC for soil texture with >85-90°k coarse textures; • SEB® Surfactant Enhanced Bioremediation In -situ and ex -situ application processes to liberate contaminants making them more `Biologically Available' for microbial (bacteria) and associated enzymatic degradation. SEB® improves both in -situ and/or ex -situ bioremediation treatment methods including bio-stimulation, bio-augmentation and newer enhanced biological techniques for aerobic, anaerobic and facultative microorganisms. • SEC® Surfactant Enhanced Chemicalization In -situ and ex -situ application processes to liberate contaminants making them more `Chemically-Available'for chemical REDOX (i.e. Reduction or Oxidation or combined) by chemical agents. SEC® improves the availability of the contaminants to the chemical REDOX, facilitating improved contact and reaction kinetics, to enhance the associated in - situ and/or ex -situ chemical reagent degradation of target COC. 2.2 IVEY-SOL® WATER CLUSTER SIZE REDUCTION IveysoI® surfactants, when introduced into contaminated soil and groundwater regimes, can reduce the surface tension of water from 73 dynes to <30 dynes. This capacity improves the wetting ability (capacity), and movement, of the aqueous phase in the soil © Ivey International Inc. Tel: + 1 604 538 1158 I Fax: + 1 888 640 3522 www. i►►eyinternational.com DomSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ivey International Inc.. "Today's Ea iroomentai Solutions For A Bette► Tomorrow" Page 6 of 18 and groundwater (unsaturated and saturated) zones, and the relative `Hydraulic Conductivity' (K), while Ivey-sol® is present. Once Ivey-sol® applications are completed the original site conditions return to normal. The Ivey-sol®surfactants accomplished this by reducing the size and formation of large water -clusters to smaller water -clusters (See Figure 2-1 below). In doing so, the Ivey-sol® allows the water clusters to become smaller, and to penetrate into less permeable soils such as: clays, silty -clay, silty -sand, sands with silty and clay content to weathered and fractured bedrock, improving LNAPL and COC remediation. Very Little Aggregation to Larger Clusters Much Greater Aggregation to Larger Clusters Figure 2-1: Ivey-sol€' reducing water cluster size (Lower surface tension) Improved Injection -Transport Within In Fine Texture Geology 2.3 ADVANTAGES AND DISADVANTAGES As detailed in the above sections, Ivey-s❑r makes the desorbed contaminants more `Physically -Available' for extraction by in -situ `Sweep' or `Push-PuIITM', MPE, Pump and Treatment and ex -situ Soil Washing; more Biologically -Available' for Bioremediation (in - situ and/or ex -situ); and by increasing the dissolved aqueous -phase contaminant concentrations which improves their `Chemical Availability' for Reductive -Oxidative (REDOX) chemical treatment (in -situ & ex -situ). This is also true when combining multiple physical, biological or chemical applications, or when rolled out in a stepwise manner. To expand on the flexibility, at full-scale, ATC could commence a physical `Sweep' mass recovery approach, and if site conditions permitted, then flexibly modify the remediation strategy to include in -situ SEB® and/or in -situ ISCO and/or conclude site closure by conventional MNA (Monitored Natural Attenuation). The following table lists several advantages and disadvantages associated with the Ivey- sol® remediation. © Ivey International Inc. Tel: + 1 604 538 1158 I Fax: + 1 888 640 3522 www. iveyinternationaicom DocuSign Envelope ID: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 ;'A'; Ivey International Inc. .' 'Today r fewropfnenlaf Salulrans for A $Eller Tomorrow Page 7 of 18 ADVANTAGES DISADVANTAGES i) The Ivey -solo products are non -toxic and biodegradable, so they do not persist in the environment after application; ii) Improves contaminant mass recovery for in - situ P&T or Sweep' by >400% to >1000%, for NAPL (LNAPL and DNAPL) contamination; iii) Improves in -situ and ex -situ soil and water bioremediation by 40-60% or more; iv) Improves chemicalization (REDOX) so 25% to 75% less chemical reagents are required, saving time and treatment costs; v) Does not negatively affect water treatments stems (i.e., O/W Separators, GAC, Mycelex, Zeolite, Air Stripping, Membrane Separation, Bio-reactors, Organo-clay, etc.). vi) Not toxic to bacteria, so can aid and/or improve natural attenuation; vii) Works well with dual phase extraction (DPE), multi -phase extraction (MPE), vacuum extraction, and conventional P&T; viii) Works well in finer grain soil textures (i.e., silty sand, silt, silty clay, clay and fractured bedrock); ix) Does not generale any significant operation and maintenance (O&M) issues; x) Application for the full range of LNAPLs has been demonstrated to be very effective; xi) Application for a broad range of DNAPL contaminants has been demonstrated to be very effective; xii) Can be used to treat several heavy metals that are organometallic's (TEL, TBT, etc.); xiii) Can be applied to saturated and/or unsaturated zones (in -situ or ex -situ); xiv) It is pH neutral, non -caustic, and non- corrosive so does not require chemically resistant equipment for applications xv) Only Standard Person Protective Equipment (PPE) is required to use Ivey -solo); xvi) Free of unwanted by-products including: PFOA, PFAS, 1,4-Dioxane, etc.; and xvii) REACH Compliant i) Extraction and treatment equipment can be expensive when used with P&T; ii) If the mixture freezes (below 0 °C or 32 °F) during storage and/or handling, it's effectiveness may be reduced; iii) With improved contaminant liberation, the site may go through more GAC or Zeolite or treatment absorbent than planned; iv) Monitoring VOCs during remediation, Ivey -solo may suppress VOCs, making them less detectable by standard handheld vapor meters [lvey-sol can aid VOC reductions when in- door air quality is a remediation driver]; vi) When used for SEC®, the Ivey -soli' may consume some of the REDOX reagents being introduced [Although limited as application concentrations are generally below the CMC — Critical Micelle Concentration]; vii) During SER®, and effective improvement in mass recovery, bacterial pluming in the soil and groundwater regimes may be observed. Ivey -soli® is free of unwanted regulated impurities including: PFOA, PFAS, 1,4-Dioxane, Dioxins, Furans, PCB, and tested and free of US EPA regulated compounds. A claim no other remediation technology is making! © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www.iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 fte Ivey International Inr. d y a Today fevr+onmental $olutr os For A Better Tomorrow' Page 8 of 18 2.4 IVEY-SOL® MECHANISM The IveysoI® surfactants can selectively desorb and/or dissolve (i.e. make miscible) COC at the molecular level, as microscopic `surfactant -hydrocarbon -water' partial non - encapsulations, called partial micelles, well below the critical micelle concentration (CMC). This capacity is unique to Ivey-sol® and explains why lower Ivey-sol® application concentration show efficacy for COC mass removal. This is particularly effective on treating LNAPL and DNAPL contamination. Through selective desorption and dissolution, below the CMC, Ivey-sol® significantly increases the availability of the target COC for all forms of in -situ or ex -situ physical, biological, and/or chemical remediation. The IveysoI® mechanism on COC is illustrated in Figure 2-2 below for LNAPL, sorbed and dissolved phase COC. -- ABSORBER CONTAMINATION Figure 2-2: - 1ro °'- IVEY-SOT. ii‘C> rr••43 c,prip +'P lMlCARTIALlll.f Ivey-sol® desorbing contamination off the soil surfaces, or from NAPL (Le. LNAPL and/or DNAPL) layers making them more `Available' for in -situ or ex -situ remediation. 2.5 IVEY-SOL® APPLICATIONS This section provides a higher level indication of Ivey-sol® effectiveness for treating COC with contaminated soil, bedrock and saturated and groundwater regimes. Photograph 2-1 below shows contaminated soil from a petroleum refinery site that was treated using Ivey-sol® in an ex -situ soil washing remediation process. The baseline soil concentrations ranged from 30,000 ppm to 40,000 ppm while the post treated soils TPH (C6 to C50) concentration were consistently <500 ppm after five (5) to seven (7) minutes of treatment. Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 ; Ivey International Inr. -Today-5 Environmental Soli:bons For A Better Tomorrow' Page 9 of 18 Photograph 2-1: Pre -post Ivey-sol® Remediation of Refinery Soils Photograph 2-2 shows free phase LNAPL that was treated using Ivey-sol® in an in -situ sail washing `Sweep' remediation process. The baseline dissolved concentrations were increased by >1000% following the Ivey-sol® application. Photograph 2-2: Pre -post Ivey-sol® Free LNAPL Remediation Photograph 2-3 demonstrates Ivey-sol® increasing the miscibility of DNAPL contamination in groundwater resulting in a greater than 500% increase in DNAPL contaminant mass recovery being observed at the subject site. © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 gte Ivey International inc. d y a Today fevrronmental 5olutr os For A Better Tomorrow" Page 10 of 18 Photograph 2-3: Pre -post Ivey-soI DNAPL Remediation. Increasing the miscibility for enhanced DNAPL extraction. In brief, an in -situ Ivey-sol® SER® application can accomplish three (3) feats. First, it overcomes the `Limitation' challenges associated with NAPL dissolution, contaminant sorption and low COC solubility. Secondly it lowers the relative surface tension of water improving both its wetting and associated hydraulic conductivity (K) properties, while the IveysoI® is present, across a broad range of soil textures. Third, through its selective dissolving of contaminants (COC) below the CMC, whereby it broadens the range of contaminants that can be treated, and enhances in -situ and ex -situ physical, biological, and chemical remediation methodologies, including combinations thereof. 3.0 IVEY-SOL® APPLICATION (DETAILED) This section will detail the in -situ application methods for the Ivey-sol® surfactant remediation products, as they relate to the subject site. Specifically how they are employed for IW and EW `Push -Puff SER° strategies to aid elimination of observed COC, including: LNAPL, vapor intrusion, sorbed, and dissolved phases, within the smear zone associated with local groundwater elevation fluctuations at a typical site. 3.1 IVEY-SOL® `PUSH-PULL' APPLICATIONS Figure 3-1 illustrates the Ivey-sol® `Push-PullTMin-situ approach when using [Ws designed and installed to target the IveysoI® injections into the subsurface zone(s) of identified COC, including LNAPL, within the saturated and unsaturated smear -zone. IVEY assumes the well screen interval of these [Ws will cover the entire smear- zone, and applicable capillary zone. This approach would desorb and make the targeted COC and LNAPL more miscible in groundwater, whereby they would be more Available' for © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4EDO-AAD3-072D7E168711 Ivey International inc. "Today s frwronmeruaf So!lawns For A Better Tomorrow' Page 11 of 18 physical mass extraction at the same IW locations, or at nearby groundwater Recovery Wells (RW) locations (see Figure 3-1). Note: I VEY generally recommends, where existing well infrastructure is limited, installation of 4 inch (100 mm) diameter injection wells (I W), screened across the COC plume and groundwater table, to improve the Ivey-sol° `Push-PullrM' application injection diffusion radius (idr), resulting in improved COC plume contact and COC or LNAPL or DNAPL mass recovery. Further, these larger diameter IW's can serve as multi -purpose wells; used for the Ivey-soI injections, can be employed as extraction wells (RW), and later as post-remediation monitoring wells (MWs) to help facilitate regulatory site closure or closure by a risk assessment. This type of IW is referred to as a Triple -Use -Well by 1VEY and only cost 10% to 15% more to install than 2 inch (50 mm) wells. CROSS SECTION IVEY-SOL INJECTION DIFFUSION RADIUS Not To Scale krthal *Pi IC; IOON<f' Dented idr ►RtTrt tnjadim Daum Rata !mr e13-22 S•Ia Mlps.a=so-33/3-s. - s-z oeas-vm w-.sarrtsa a . rrezv Imavialtv- 'm. r..n t .S-w-atl wO.O Figure 3-1: Ivey-sor' Push-PurlrM' injections at IW locations for broad lateral and depth of application to enhanced localized COC remediation. © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DomSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 ate Ivey International Inc. 4-74 J " Today fnvrronmental5olutrorls For A Better Tomorrow" Page 12 of 18 The Ivey-sol® `Push-PullTM' process is generally easy to apply, and often a very effective method to remove COC sorbed phase, dissolved phase, and LNAPL (i.e. LNAPL and DNAPL) contaminant mass within in -situ environments. Figure 3-2 illustrates a typical field -scale Ivey-sol® `Push-Pu11TM' application with anticipated idr shown for the injected Ivey-sol® volume associated with each injection `Push' which after allowing a prescribed `Contact Time' is then extracted - `Pull'- from the IW and RW locations. The idr values shown in the legend are based on 100 mm (4 inch) diameter wells, so should be viewed as conservative, as several site specific variables (i.e. soil texture, soil compaction, groundwater elevation, K, contaminant type, porosity, etc.) would affect the actual idr realized for different site conditions. IVEY-SOL INJECTION DIFFUSION RADIUS / .• • , / 5 55 V f / 1 I ► ► [ 5 I . 1 r . { / / `4 -•r / r Ali- - 51 • r // C ,� • r r.)5} { • • / I / 1 I i 5 r / I el.I r / t r ► ► 0 \ I' 1 N. N Not To Scale • / Legend: Contaminant Setl 0nd Gmundw.L11 PIume Inj.C11p1. Well { A' iOOmn1 ni.nitl Iveyti I Injp ✓ . Dot NW, Ra,au.4W1 limb - 1 ■ ➢O.1 ■ 1.10./A1 - 10 171117 •!ml Mgr -q• 101111.0•1300l 0010 Ci.M . illll bn. C1 - • SIlly I.awl •S 40wrM•1•wiwn NM/IM.rwa _..-... same... M 00.0.00.0 — i..�.eMwIY�>•w�.... Ww o.. .« .e.,it e.g. ,. a.........,..... Figure 3-2: Ivey -soli 'Push -Pull"' injection event with idr at IW locations to achieve contact with the COC plume. © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ite Ivey International inc. d y a Today fevrronmental 5oMmos For A Better Tomorrow Page 13 of 18 3.3 IVEY-SOL® `PUSH-PULL' ANIMATION The Ivey -sole `Push-Pu117M' and Sweep' animations, depict typical in -situ application strategies, to desorb COC sorbed to soil and bedrock surfaces, dissolution of dissolved and free phase LNAPL contaminants into the groundwater for enhanced remediation. This occurs in the vicinity of IW locations, following a 'Push' injection, and after a brief contact time (hours to days). The liberated contaminants are then extracted at each IW, for the 'Pull'to recover the liberated contaminant (COC) mass at RW's. For most sites, only a limited number of `Push-Pul1TM' or `Sweep' events are required to achieve significant advancements toward site -specific remediation goals. These applications can be completed daily, weekly, or monthly depending on the project logistics and budget. The web based 3-dimensional IveysoI® animation link is available as follows: http://wvyw.iveyinternational.com/videopresentation 3.4 IVEY-SOL® FIELD APPLICATION AFVR For calculating the required Ivey-sol® 103 volume, and costing, IVEY will assume the field scale injections will be limited one (1) `Push -Pull' Ivey-sol® application event, involving 300 to 500 Gal. of 4% Ivey-sol® at each of three (3) IW locations (MW-2, MW-4, and MW- 5), in the vicinity of the for UST source area, that are given a —24 to 48 hour residence time (post injection), before undertaking an AFVR event at EW's (MW-6 IW's MW-2, 4, 5 To achieve a 4% Ivey -sole dosage in the proposed 300 to 500 Gal of clean water, for injection at the three (3) IW's, this would require 12 to 20 Gal. of Ivey-sol 103, diluted into 288 to 480 Gal. of clean water, respectively, to be injected at each IW location, as per ATC's requested application, followed by a residence time, prior to undertake an AFVR event at MW-6 and MW-7. 1,500 gal = 60 gal surfactant 1,440 gal water At the conclusion of the Ivey-sol® applications, ATC may perform an `Optional' clean - water flush at involved wells, to remove residual IveysoI® and/or liberate COC. Note: During the field applications, ATC could measure the groundwater elevations at nearby MW locations to evaluate the extent of groundwater table mounding and lateral dispersion of injected Ivey -sot, and modify the Ivey -so! volume injected to achieve increased pore volume contact within the COC and LNAPL plumes. Volume of Ivey -so' required for the subject site application, involving four (4) IW locations, at 4% in 300 to 500 Gal. per IW, would be as follows: Volume = 1 Event x 3 IW x (12 to 20 Gal Ivey-sol® 103 / 300 to 500 Gal. Injection/IW) = 36 to 60 Gal Ivey -sole 103 Per Event © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ivey International inc. d y a Today fevrronmental 5olutr os For A Better Tomorrow Page 14 of 18 3.5 IVEY-SOL SURFACTANT `REAL-TIME' FIELD TEST KITS IVEY has developed a real-time field surfactant test that is easy to use and that helps clients verify when and where the Ivey-sol®, and liberated COC, are relative to injection well (IW) and recovery well (RW) locations on a site. It can also indicate when they have extracted enough groundwater associated with each ivey-sol® `Push -Pull' injection event. For the subject site the `Pull' will be the AFVR. A copy of this field test method will be included in the Appendix of the proposal. It should be noted that IVEY has developed a new field test method (See Figure 3-3) that has been used globally with over 20,000 individual tests completed since 2016. Test results have shown a >96% correlation with laboratory tests. This new field test method (a.k.a. Field Surfactant Test Kit = 100 test/ kit) is now available for general use. Test kits can be sources from IVEY, or through local distributors. Figure 3-3: NRW Ivey-soi® Field Surfactant test. Illustrates 3 time -based Tests - baseline through increasing [Ivey -soli If ATC wants to have the analytical capacity to analyze for Ivey-sol® in groundwater samples, IVEY has established three (3) USEPA approved analysis methods. These analytical laboratory methods are detailed in a technical handout included in the Appendix of this proposal. © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ite Ivey International inc. d y a Today fevrronmental 5oM,wis For A Better Tomorrow' Page 15 of 18 Special `Optional' Offer If required IVEY can provide an on -site IveysoI® application specialist on -site at a rate of $1000.00 per day (not including Transportation, Meals, and Accommodations). IVEY would provide logistical support, on -site training relating to injection and extraction (lessons learned), and associated field surfactant testing kit, and on -going technical support as required. However, with COVID-19 we are providing remote support to >80% of site applications. 3.6 DETAILED IVEY-SOL® PUSH-PULL' WITH AFVR Based on ATC's requested `Push -Pull' pairing an Ivey-sol® injection with AFVR extraction event, the following steps would describe the general actions associated with the proposed in -situ Push -Pull' application: Baseline Monitoring - Field sampling and testing of groundwater quality, groundwater elevation survey, and gauging LNAPL thickness, to establish 'Baseline' conditions prior to the Ivey-sol® and AFVR 'Push-Pull'application. This will allow for post Ivey-sol® - AFVR application evaluation of efficacy. This should be completed at wells on -site. ATC would like to act according to the following `modified' application strategy: i. Perform baseline monitoring, and/or testing to extent required; ii. Add 300 to 500 Gal. of 4% Ivey-sol® 103 at each of the three (3) designated IW locations (i.e. MW-2, MW4, and MW-5) by gravity or low pressure injection; iii. Allow for residence time of —24 to 48 Hours (IVEY usually suggests Hours for LNAPL, but some clients experienced favorable results after several days); iv. Undertake groundwater LNAPL gauging at involved well locations; v. Perform AFVR at -E-Ws: MW-6--and M-W 7, to remove injected Ivey-sol and liberated COC and LNAPL mass; IW's MW-2, 4, 5 vi. Use Real Time Field Surfactant Test Kits to help optimize the Ivey-sof® application extraction process (Section 3.5) and to confirm `Push -Pull' completion, and to minimize groundwater extraction volume for on -site or off -site treatment; vii. Gauging of involved well locations for LNAPL thickness, and the collection of groundwater quality samples to evaluate 'Push -Pull' application performance; and viii. Repeat process [IVEY usually suggest a minimum of three (3) events]. 4.0 ESTIMATED COST The project cost to undertake the ATC scope of work, at the subject site is detailed below, based on injecting a 300 to 500 Gal. volume of 4% lvey-sol® 103 at MW-2, MW-4, and MW-5. If ATC wants to have an IVEY Surfactant Remediation Specialist on -site, that would be an extra cost, otherwise remote support will be available. © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ivey International Inc. 4:a tie "Today's fey:um/men al $oluirons For A Better Tomorrow Page 16 of 18 Estimated project cost, based on one (1) event as proposed scope of work is as follows: Ivey-sol® 103 Estimated Cost: KEY recarnrends corrpteting mirimin e t three (3) events when treating LMPL Notes: 5.0 TERMS AND CONDITIONS 5.1 INVOICES The above rates will be billed in accordance with the cost breakdown presented and approved with ATC. A purchase order is generally requested to proceed. Payment terms are 30 days, 5.2 AUTHORIZATION This proposal will be honored for a period of 30 days from the date of this quotation. Acceptance of this proposal can be accomplished by the return of your organization's signed Purchase Order for authorization to proceed. © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DomSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 Ite Ivey International inc. td y a Today fevrronmental 5o►utr os For A Better Tomorrow" Page 17 of 18 5.3 SOURCES OF IVEY-SOL® The Ivey-sol® products can be supplied from IVEY with a lead-time of approximately 4 to 7 business days, in most cases, for standard ground transport. 5.4 LICENCE USE OF PROPRIETARY TECHNOLOGY No license fees will apply to IVEY clients who purchase and apply our patented and/or proprietary Ivey -soli' surfactant products and processes. The application design shown in the proposal falls within the Intellectual Property (IP) of IVEY. 6.0 CLOSING This cost proposal was generated based on the site information provided by ATC to IVEY. Should additional information become available, and/or if the proposed application strategy should change, we are prepared to review and modify our understanding and associated project costs. To aid ATC's understanding of the effectiveness of the Ivey-sol® surfactant technology, several applied case studies, and client testimonials will be appended to this proposal. If you have any questions regarding the information presented herein, please do not hesitate to contact the undersigned. Best Regards, Ivey International Inc. George A. Ivey, B.Sc., CEC, CES, CESA, P.Chem, EP Senior Remediation Specialist REF: lvey-sor SERA Proposal - &MANGLES 552 Spill Site (ATC 210119.02) © Ivey International Inc. Tel: + 1 604 538 1168 I Fax: + 1 888 640 3622 www. iveyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4ED0-AAD3-072D7E168711 ,: J Ivey International Inr. 4:44 a "Today"s Environmental Solulrans For A Bette, Tomorrow' APPENDIX ATC Site Evaluation Form ATC Site Figure Client Testimonials IVEY-SOL® CASE STUDIES Field Surface Tension Agitation Test EPA Ivey-sol® Testing Methods Awards Sheet Page 18 of 18 © Ivey International Inc. Tel: + 1 604 538 1168 l Fax: + 1 888 640 3622 www. i►leyinternational.com DocuSign Envelope ID: F605E1AD-6FB8-4EDo-AAD3-072D7E168711 IVEY-SOL® (� • • sllifwtivw.i afl1l tiorr�� of gm General Site Information Form Ivey International Inc. Unit 7, 19122 27th Avenue Surrey, BC, Canada V3Z 5T1 Tel: 1-800-246-2744 Fax: 1-888-640-3622 Email:info@iveyinternational.com Client Information Date: 2/15/21 Company name: ATC Associates of NC, Email: al.quarles@atcgs.com Ivey Contact: Bud Ivey PC Contact Person/Title: President Phone: 604-538-1168 Fax: Cellular: 25D-203-0867 Street address: 7606 Whitehall Exec Ctr Dr, Ste 800, Charlotte, NC 28273 Shipping address: TBD, Advanced Env, Greensboro, NC? Project Information: Project Name: TF-44992, Bojangles #552 Project Location: 584 West Northwest Boulevard, Winston-Salem, NC 27105 Project Number: SLC4499201 Regulatory Agency: NCDEQ, DWM, UST Section Land Use and Zoning (Circle): °Parkland °Agricultural °Residential @Commercial °Industrial Site Information: Remediation Objectives: removal of LNAPL (gasoline) Contaminant(s) of concern (TPH, BTEX, TCE, PCB, etc.) Soil Impacted: Yes / No Groundwater Impacted: Yes / Nofres Vapor Impacts: Yes / No {No Is NAPL Present: Yes Time Since Release: >25 years Soil Type(s): clayey silt Soil Porosity:—35-45% Depth to Groundwater: —8-11 ft-bgs Hydraulic Conductivity (K): -•1 E-4 to 1 E-5 cm/sec Hydraulic Gradient:--0.025 Groundwater Flow Direction: NW Area of Contamination:3,500 SF >26 Maximum Depth of Contamination: —18 ft-bgs Current Remediation Activities: 8-hr total fluid removal events Yes Site Remediation Goals: removal of LNAPL (--1,000 SF, MW-2, 4, and 5) Monitoring Well Network Information: Number of Existing or Proposed Monitoring Wells: 7 Number of Proposed Injection Wells: 3 (MW-2, 4, 5) Number of Proposed Extraction Wells: 2 (MW-6, 7) Please Provide the Following: • Detailed Site Location Maps, Figures, and Isoconcentration Plume Contours (if available) • Laboratory Analysis Results for Vapor, Soil and Groundwater • Groundwater Elevation Gauging data, and NAPL Gauging data (if applicable) • Bore Hole Logs (3 min.) and/or Geological cross -sections (if available) • Monitoring Well, Injection Well, Bio-Sparging Well construction details • Site Photographs, Videos and/or Animations • Past Pilot -Test Results (if available) • Site Investigation Report and/or Remediation Reports Please complete this site information form and return to: infoCciveyinternational.com @Ivey International Inc. DocuSign Envelope ID: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 NOTES: 1. CONCENTRATIONS IN BOLD EXCEED NC 2L STANDARD. 2. CONCENTRATIONS IN ITALICS EXCEED NC 2B STANDARD. 3 GROUNDWATER SAMPLES COLLECTED 03102/2020. 0), MW-3 No Concentrations Exceed Regulatory 5tandards DW-1 Benzene MTBE Naphthalene MW-6 Benzene Naphthalene 18.2 414 15.3 67.0 36.3 MW-5 Benzene 2,240 Ethylbenzene 3,020 Isopropylbenzene 148 Naphthalene 1,380 n-Propylbenzene 394 Tolouene 14,900 1,2,4-Trimethylbenzene 3,400 Total Xylenes 15,500 IMAGE SOURCE: GOOGLE EARTH PRO 0 25 50 MW-2 Free Product - 0.03 Feet 100 APPROXIMATE SCALE IN FEET MW-7 Benzene 76.3 Ethylbenzene Isopropylbenzene Naphthalene n-Propylbenzene Toluene 1,120 71.6 559 209 621 1,2,4-Trimethylbenzene 1,3, 5-Tri methylbenzene Total Xylenes 1,880 405 4,220 MW-4 Benzene 254 p 1IRWAY E STOP #s Naphthalene 485 n-Propylbenzene Tolouene 1, 2, 4-Tri methylbenzene Total Xylenes L___1 EXPLANATION 73 336 812 1,850 MONITORING WELL LOCATION FAIRWAY ONE STOP #5 UST LOCATION TITLE F G U R E 4 GROUNDWATER QUALITY MAP BOJANGLES #552 - NCDEQ INCIDENT #44992 585 W. NORTHWEST BOULEVARD WINSTON-SALEM, FORSYTH COUNTY, NORTH CAROLINA ATC ATC GROUP SERVICES LLC Charlotte, North Corolla 23275 (704) 529-3200 FAX (704) 520-3272 AD FILE rYPE CODE PREP BY LB CB AS SHOWN D3/30/2020 SLP4499208 DocuSign Envelope ID: F6O5E1AD-6FB8-4EDO-AAD3-072D7E168711 r- �,J r- YFb2OTH ' id,,i4 tio 4ti, a. ‚Fihi a F- . ��\ W 14THSr i NO C---) w� rHsr — i aC w �zrH.„ IS Ta 0 500 1 000 2 000 REFERENCE: USGS 7.5-MINUTE MAP, WINSTON-SALEM WEST (SITE) & WINSTON-SALEM EAST (ADJACENT), NORTH APPROXIMATE SCALE IN FEET CAROLINA. DATED 2016. 1= FGURE1 SITE LOCATION MAPfitTc BOJANGLES #552 - NCDEQ INCIDENT #44992 585 W. NORTHWEST BOULEVARD WINSTON-SALEM, FORSYTH COUNTY, NORTH CAROLINA Chl t.. Ncrth Carolna ATC ORRUP SERVICES LLC 28273 (704) 529-3290 FAX (7aa" 529-3272 ..._.: I.: 4992_SM TYPE CODE LB PREP BY CB REV BY SCALE 1"-1,000' DATE 01/22/2020 PROJECT NO. SLP4499207 DocuSign Envelope ID: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 NOTE: 1. GROUNDWATER LEVELS MEASURED ON 03(O212O20. 2. DASHED LINES INDICATE AREAS OF LESS CERTAINTY. a IMAGE SOURCE: GOGGLE EARTH PRO BOJANGLES #552 ty 4010 MW-3 JX 84.3 7 ` I '"83`83 84.44 L. AT k JP 4, � J 85.77 / 4'� r,^., 8,J, +6 24 QA.:e % N., ns, 4:111 t • lI 1111 86 83 • J FW-2 FAIRWAY ONE STOP a6 0 25 50 100 APPROXIMATE SCALE IN FEET L'4.52 NM of EXPLANATION MONITORING WELL LOCATION GROUNDWATER ELEVATION (IN FEET) NOT MEASURED GROUNDWATER ELEVATION CONTOUR LINE GROUNDWATER FLOW DIRECTION TITLE FIGURE 3 GROUNDWATER CONTOUR MAP BOJANGLES #552 - NCDEQ INCIDENT #44992 585 W. NORTHWEST BOULEVARD WINSTON-SALEM, FORSYTH COUNTY, NORTH CAROLINA ATC ATC GROUP SERVICES LLC Clmrlctl., North Ceram 28273 (704) 529-3200 FAX (704) 520-3272 AD FILE TYPE CODE PREP BY LB REV BY CH AS SHOWN D3/30/2020 SLP4499208 DoouSign Envelope 1D: F605E1AD-6FB8-4EDO-AAD3-072D7E16871 NOTES: 1. CONCENTRATIONS IN BOLD EXCEED NC 2L STANDARD 2. CONCENTRATIONS IN ITALICS EXCEED NC 2R STANDARD. 3. GROUNDWATER SAMPLES COLLECTED 03/02)2020. Regulatory Standards ell iNUV-1` t - .. DW-1 Benzen MTB E Naphthalene MW-6 Benzene Naphthalene 18.2 414 15.3 MW-5 Benzene Ethylbenzene isopropylbenzene Naphthalene n-Propylbenzene Tolouene 1, 2,4-Tri methyl benzene Total Xylenes gri* 2,240 3,020 148 I,380 394 14,900 3,400 I5,500 IMAGE SOURCE: GOGGLE EARTH PRO MW-7 Benzene Ethylbenzene Isopropylbenzene Naphthalene n-Propylbenzene Toluene 1,2,4-Tri methyl benzene 1,3,5-Tri methyl benzene 76.3 1,120 71.6 559 209 621 1,880 405 Total Xylenes , 4,220 litIVIV../ 2 MW-2 Free Product - 0.03 Feet yrr MW-4 Benzene 254 Naphthalene 485 n-Propylbenzene 73 Tolouene 336 1,2,4-Trimethylbenzene 812 Total Xylenes 1,850 IRWAY E STOP as y*Ir kat • 4411.* 25 50 100 APPROXIMATE SCALE IN FEET EXPLANATION • MONITORING WELL LOCATION FAIRWAY ONE STOP #6 UST LOCATION TITLE FIGURE 4 GROUNDWATER QUALITY MAP BOJANGLES #552 - NCDEQ INCIDENT #44992 585 W. NORTHWEST BOULEVARD WINSTON-SALEM, FORSYTH COUNTY, NORTH CAROLINA PREP. BY REV. BY ATC ATC GROUP SERVICES LLC Charlett% Narth C.IrattM 2a273 f7'04) 529-32O0 FAX (704) 529-3272 SCALL AD FILE TYPE CODE I LB I CB I AS SHOWN P3/30/2020 I SLP4499208 DocuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 TABLE 1 MONITORING WELL CONSTRUCTION DATA Bojangles #552 585 West Northwest Blvd Winston-Salem, North Carolina 27105 NCDEQ Incident #44992 Well ID Date Installed Well Diameter (in) Depth of Well (ft-bgs) Well Screen Interval (ft-bgs) TOC Elevation (ft) MW-1 8/12/16 2 20.0 5.0-20.0 89.08 MW-2 8/12/16 2 20.0 5.0-20.0 95.66 MW-3 8/12/16 2 20.0 5.0-20.0 91.99 MW-4 12/17/18 2 20.0 5.0-20.0 94.88 MW-5 12/17/18 2 20.0 S.0-20.0 93.80 MW-6 12/17/18 2 15.0 5.0-15.0 90.82 MW-7 3/14/19 2 20.0 5.0-15.0 97.09 DW-1 11/07/19 2 50.0 45.0-50.0 91.56 Notes: in = Inch ft-bgs = Feet below ground surface ft = Feet TOC = Top of Casing TOC Elevations for MW-1 through MW-3 by others, MW-4 through MW-6 by ATC on December 18, 2018 TOC Elevations for MW-7 and DW-1 by ATC on March 29, 2019 and November 7, 2019, respectively DocuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-07207E168711 TABLE 2 GROUNDWATER ELEVATION DATA Bojangles #552 585 West Northwest Blvd Winston-Salem, North Carolina 27105 NCDEQ Incident ft14992 1�'ell ID Gauging Date LNAPL Recovery Depth to Groundwater (ft-toc) Depth To LNAPL (ft-toc) LNAPL Thickness (ft) TOG Elevation (ft) Groundwater Elevation (ft) MW-1 12/20/2017 9.75 -- --- 89.OS 79.33 12/20/2018 CNL CNL CNL CNL 03/02/2020 CNL CNL CNL CNL MW-2 12/20/2017 11.38 --- - 95 6O 84.28 09/25/2018 Pump out 13.03 10.78 2.25 84.56 12/20/2018 11.88 9.53 2.35 85.80 02/14/2019 AFVR 11.97 9.6I 2.36 85.72 02/15/2019 13.00 --- --- 82.66 03/04/2019 9.00 8.96 0.04 86.69 03/14/2019 9.57 9.54 0.03 86.12 03/29/2019 9.93 9.83 0.10 85.82 04/24/2019 10.23 10.00 0.23 85.63 07/25/2019 AFVR 10.94 10.32 0.62 85.25 07/26/2019 12.60 --- --- 83.06 08/08/2019 10.81 10.61 0.20 85.02 02/17/2020 Al- V It 9.28 9.06 0.22 86.57 02/18/2020 10.98 --- --- 84.68 03/02/2020 9.45 9.42 0.03 86.24 M 1k -3 08/12/2016 9.42 --- 91 .99 82.57 12/20/2018 7.83 84.16 02/14/2019 8.10 --- -- 83.89 02/15/2019 8.12 83.87 03/04/2019 7.18 84.81 03/29/2019 7.73 --- --- 84.26 11/07/2019 8.75 83.24 02/17/2020 7.32 --- --- 84.67 02/18/2020 7.35 --- --- 84.64 03/02/2020 7.62 --- --- 84.37 Page 1 of 3 DocuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-07207E168711 TABLE 2 GROUNDWATER ELEVATION DATA Bojangles #552 585 West Northwest Blvd Winston-Salem, North Carolina 27105 NCDEQ Incident ft14992 1N'ell ID Gauging Date LNAPL Recovery Depth to Groundwater (ft-toc) Depth To LNAPL (ft-toc) LNAPL Thickness (ft) TOG Elevation (ft) Groundwater Elevation (ft) MW-4 12/20/2018 9.33 - --- 94.88 85.55 02/14/2019 AFVR 9.80 9.2 0.53 85.53 02/15/2019 12.55 - --- 82.33 03/04/2019 8.64 86.24 03/14/2019 9.33 8.75 0.58 86.05 03/29/2019 9.85 8.90 0.95 85.85 04/24/2019 10.47 8.94 1.53 85.72 07/25/2019 AFVR 12.24 8.86 3.38 85.54 07/26/2019 12.46 --- --- 82.42 08/08/2019 9.93 9.89 0.04 84.98 02/17/2020 AFVR 9.06 8.62 0.44 86.20 02/18/2020 10.96 - - 83.92 03/02/2020 9.11 --- --- 85.77 MW-5 12/20/2018 8.76 --- --- 93. NO 85.04 02/14/2019 8.85 --- --- 84.95 02/15/2019 9.37 --- --- 84.43 03/04/2019 8.04 --- --- 85.76 03/29/2019 8.45 --- --- 85.35 07/25/2019 9.01 -- --- 84.79 11/07/2019 10.08 9.42 0.66 84.29 02/17/2020 AFVR 9.12 7.91 1.21 85.72 02/18/2020 10.89 --- --- 82.91 03/02/2020 8.33 85.47 12/20/2018 _ 6.62 --- -- 90.82 84.20 03/04/2019 6.17 84.65 03/14/2019 6.24 --- --- 84.58 03/29/2019 6.30 -- -- 84.52 11/07/2019 7.17 83.65 02/17/2020 6.60 --- --- 84.22 02/18/2020 6.76 84.06 03/02/2020 6.38 --- --- 84.44 MW-7 03/29/2019 10.59 --- 97.0.) 86.50 07/25/2019 11.24 --- --- 85.85 02/17/2020 9.99 --- 87.10 02/18/2020 10.32 -.. 86.77 03/02/2020 10.26 --- --- 86.83 Page 2of3 DocuSign Envelope 1D: F665E1AD-6FB8-4EDO-AAD3-072D7E168711 TABLE 2 GROUNDWATER ELEVATION DATA Bojangles #552 585 West Northwest Blvd Winston-Salem, North Carolina 27105 NCDEQ Incident ft14992 IN ell ID Gauging Date LNAPL Recovery Depth to Groundwater (ft-toc) Depth To LNAPL (ft-toc) LNAPL Thickness (ft) TOC Elevation (ft) Groundwater Elevation (ft) DW-1 12/18/2019 8.40 - --- 91.56 83.16 02/17/2020 7.47 --- --- 84.09 03/02/2020 7.73 -- --- 83.83 Notes: TOC/toc = Top of Casing ft=feet ft-toc = feet below top of casing LNAPL = Light Aqueous Phase Liquid (ND = Not Detected) NM = not measured CNL = Could Not Locate Groundwater Elevation = TOC - (Water Level Measurement + (LNAPL Thickness x 0.8581)) Page 3of3 DocuSign Envelope 1D: F605E1Ap 6FB8-4ED0 AAD3-072D7E168711 saaaE6x [qoy I ml 0 otri Not sampled:2.35 ft LNAPL a Q Z a d = tyd z .y• •R 0 ^` 0 0 v M M -' w auaxuagiAgi u m-s`£'E =' g 6. ry o V c • c V 6 V I R. ve, o V ;" ,r1 rr- N z auaroagi.fq pulpy -Veil c5.. en g g .0. ? o V o V 4I oo A ffi a r . 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