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WI0300290_DEEMED FILES_20150924
Permit Number WI0300290 Program Category Deemed Ground Water Permit Type Injection Deemed In-situ Groundwater Remediation Well Primary Reviewer ebonee .shire Coastal SWRule Permitted Flow Facility Facility Name Former Cemex Ready Mix Plant Location Address 4206 Unionville-Indian Trail Rd Lake Park Owner Owner Name Cemex Dates/Events NC Orig Issue 6/18/2015 App Received 6/16/2015 Regulated Activities Groundwater remediation Outfall Waterbody Name 28079 Draft Initiated Scheduled Issuance Public Notice Central Files: APS SWP 9/24/2015 Permit Tracking Slip Status Active Version 1.00 Project Type New Project Permit Classification Individual Permit Contact Affiliation Major/Minor Minor Facility Contact Affiliation Owner Type Non-Government Owner Affiliation Denise Corrales 3820 Northdale Blvd Tampa Region Mooresville County Union FL Issue 6/18/2015 Effective 6/18/2015 33624 Expiration Requested /Received Events Streamlndex Number Current Class Subbasin Permit Number WI0300290 Program Category Deemed Ground Water Permit Type Injection Deemed In-situ Groundwater Remediation Well Primary Reviewer ebonee.shire Coastal SWRule Permitted Flow Facility Facility Name Former Cemex Ready Mix Plant Location Address 4206 Unionville-Indian Trail Rd Lake Park Owner Owner Name Cemex Dates/Events NC Orig Issue 6/18/2015 App Received 6/16/2015 Re gulated Activities Groundwater remediation Outfall Waterbody Name 28079 Draft Initiated Scheduled Issuance Public Notice Central Files : APS SWP 8/13/2015 Permit Tracking Slip Status Active Version 1.00 Project Type New Project Permit Classification Individual Permit Contact Affiliation Major/Minor Minor Facility Contact Affiliation Owner Type Non-Government Owner Affiliation Denise Corrales 3820 Northdale Blvd Tampa Region Mooresville County Union FL Issue 6/18/2015 Effective 6/18/2015 33624 Expiration Requested /Received Events Streamlndex Number Current Class Subbasin w�a3�J3°ro EE Environmental Services June 2, 2015 Mr. Mike Rogers Division of Water Resources 1611 Mail Service Center Raleigh, North Carolina 27699-1611 Reference: Notification of intent to Construct or Operate Injection Wells Former Cemex Ready Mix Plant 4206 Unionville -Indian Trail Road Indian Trail, North Carolina NCDENR IHSB Site #NONCD0002395 Dear Mr. Rogers: EnviroTrac is pleased to submit the enclosed Notification of Intent to Install or Construct injection Wells. The purpose of this corrective action is to target the localized area of elevated trichloroethylene concentrations in monitoring well MW-4D at the site. Installing a passive hydrogen injection device in the well would increase the degradation rate of chlorinated hydrocarbons but still allow the well to be used as a monitoring point. Should you have any questions regarding this notification or require additional information, please contact the undersigned. Very truly yours, ENVIROTRAC LTD. Craig D. Neil, P.G. Senior Project Manager Attachments: Notification of Intent to Install or Construct injection Wells Cc: Ms. Denise Corrales, Cemex 11330 Vaen.•slcrry Drive, 1fimtt:rsrilic, NC'28078I Oflicc: (7041 897-0707 I tux: (704i 897•0.186 minv,cnvimmtrac,GOln NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES NOTIFICATION OF INTENT TO CONSTRUCT OR OPERATE INJECTION WELLS The following are "permitted by rule" and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C .0200. This form shall be submitted at least 2 weeks prior to iniection. AQUIFER TEST WELLS USA NCAC 02c .0220} These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION USA NCAC 02C .0225) or TRACER WELLS OSA NCAC 02C .0229): 1) Passive Injection Systems -In-well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods. 2) Small-Scale Injection Operations -Injection wells located within a land surface area not to exceed l0,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests -Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells are located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells -Used to inject ambient air to enhance in-situ treatment of soil or groundwater. Print Clearly or Type Information. lllegible Submittals Will Be Returned As Incomplete. DATE: -"'Jun=ec..:2,..._ __ _,, 2015 PERMIT NO. ________ (to be filled in by DWR) A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) (2) (3) (4) (5) (6) ___ .Air Injection Well ...........................•.......... Complete sections B-F, K, N ____ Aquifer Test Well ....................................... Complete sections B-F, K, N _X~_Passive Injection System ............................... Complete sections 8-F, H-N ___ Small-Scale Injection Operation ...................... Complete sections B-N ___ Pilot Test ................................................. Complete sections B-N ___ Tracer Injection Well ................................... Complete sections B-N B. STATUS OF WELL OWNER: Choose an item. C. WELL OWNER-State name of entity and name of person delegated authority to sign on behalf of the business or agency: Name: ----=C=em=ex=-...,M=s·c..::D=e=n=is=e'--'C""o::.:.rra=le:e,Se-____________________ _ Mailing Address: 3820 Northdale Blvd .. Suite 100B __________________ _ City: Tampa State: FL Zip Code:._..:a3=-36=2::..a4'--___ County: Hillsborough Day Tele No.: (813) 269-1035 EMAIL Address: denise.corralesr@,ce=m=e=x=.c=om==----- UIC//n Situ Remed. Notification (Revised 3/2/2015} Cell No.: _________ _ Fax No.: __ _,_{8=1=3_,_) 2=6~9~-l=-==0=3.:::...0 __ _ Pagel D. PROPERTY OWNER (if different than well owner) Name: ---------------------------------- Mailing Address · _______________________________ _ City: ____________ State: _ZipCode: _______ County . _____ _ Day Tele No.: ___________ _ Cell No.: _________ _ EMAIL Address: ____________ _ Fax No .. __________ _ E. PROJECT CONT ACT -Person who can answer technical questions about the proposed injection project. Name: Craig Neil. EnvfroTrac Ltd. Mailing Address : 11330 Vani;torv Drive City: Huntersville State: NC Zip Code:_=2~80~7~8 ____ County: Mecklenburg Day Tele No.: (704) 897-0707 Cell No.: <336) 407-45 85 EMAlL Address : craign@envirotrac.com Fax No.: __________ _ F. PHYSICAL LOCATION OF WELL SITE (1) (2) Physical Address: ___ 4=2=06'-=--'U=n=io=n"'"vt""'l=le~-=ln=d=ian~T=ra=il~R=o=ad~CF~i.,.gur=e~l'""') __________ _ _________________ Cou nty :-"U..,,n=io=n.,_ _____ _ City: Indian Trail State: NC Zip Code: --=2=80"-'7""'9 _____ _ Geographic Coordinates: Latitude**: ___ 0 __ , __ "orlL_0 • 075091 Longitude**: D __ " or :fill_ 0 . __ 6=3=----4=5=0_,,4 __ _ Reference Datum: ________ Accuracy: _______ _ Method of Collection: http://itouchmap.com/latlong.htm I **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPl-IlC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume : ______ .square feet Land surface area ofinj. well network: square feet~ 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: (must be .:S 5% of plume for pilot test injections) H. INJECTION ZONE MAPS -Attach the following to the notification . (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wel1s, and existing and proposed injection wells; and Figure 2 shows the site layout and existing monitoring well locations. Figure 3 shows the horizontal extent of impacted groundwater. The passive hydrogen injection system is proposed to be installed into MW-4D. VICI In Situ Remed. Notification (Revised 3/2/201 S) Page2 (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Figure 4 shows the location of the cross section A -A', Figure 5 shows the cross section with projected vertical extent of impacted groundwater that exceed the NCCS 21, Standard. Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. Figure 6 is the potentiometric surface map showing the rate and direction of groundwater movement based on data collected during the February 2015 sampling event. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES — Provide a brief narrative regarding the purpose, scope, and goals of the proposed injection activity. This should include the rate, votunte, and duration of injection over time. The injection activities are intended to improve trichloroetlnn lone CfCE f concentrations. Results of the February 2015 samplings event suiyest TCE immacted groundwater is limited and only M W -4 D exhibits TCE and daughter products at concentrations that exceed the groundwater remediation goals. Monitorinj_well MW-4D will have a_passive hydrogen deliver3 system installed inside the monitoring well. This system will allow hY droeen to be iniccted into the_t;roundwatcr affecting a localized area. The performance of this system will be monitored quarterly. - - J. INJECTANTS - Provide a MSDS and the following for each injectant. Attach additional sheets if necessary NOTE: Approved injectants (tracers and remediation additives) can be found online at hits.Ilvorial,ncdenr.oryfweblwglapslgwpro. .411 other substances must be reviewed by the Division of Public Health, Department of Nealrh and .Human Services. Contact the UIC Program for more info (919-807-6496). Injectant: _ Hydrogen - MSDS attached Volume of injectant; continuous release of hydrogen Ras at one cubic foot per day Concentration at point of injection: MW-4D will range from 2.4 to 2.5 PP (based on I to 19 feet of subrnerycncei, The In drosen concentrations are estimated base.d un a saturated h. cfrotten cnntcnl of 1.6 ppm per atmosphere. Percent if in a mixture with other injectants NA Injectant: Volume of injectant: Concentration at point of injection: __ Percent if in a mixture with other ixtjectants: - Injectant: _ Volume of injectant Concentration at point of injection: Percent if in a mixture with other injectants UIC/In Situ Reined. Notification (Revised 3/2/2015) Page 3 K. WELL CONSTRUCTION DATA (1) Number of injection wells: Proposed. __ ---= ___ Existing (2) Provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following: (a) well type as permanent, direct-push, or subsurface distribution system (infiltration gallery) (b) depth below land surface of grout, screen, and casing intervals (c) well contractor name and certification number A passive hydrogen injection system diagram with well construction details for MW-4D is attached. The well contractor name and certification number are unknown. L. SCHEDULES -Briefly describe the schedule for well construction and iajection activities. Envirotrac will travel to the si te and insta ll the de li ven s, stem u, , in rece ip t o f the permit. The h, d rogen will be iniectcd ctimin uouslv and the content of the h , drm;.en c , linders and lidJ parameters will be mon itored monthlv. M. MONITORING PLAN -Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subcharter 02L result from the injection activity. Groundwater samples will be collected from M W-4D quarterh. The performance of the passive h~ dr l!en deliverv svstem will be evaluated followine three months of operation. N. SIGNATURE OF APPLICANT AND PROPERTY OWNER APPLICANT: "I hereby certify, under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the i,iformation is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false i,iformation. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and ~ re.late·d. appurrrnces in acco:dance ~ith the 15A . ·c IC f 2C 0200 Rules. "A } · ~ ~ ~I\,~ L.ot'r<X-le' • ig n t~ or Applicant J:. . Print or Type Full Name \) \ e..e.c::fo( L.,f\Vi rbf\~,--A--L PROPERTY OWNER (if the property is not owned by the permit applicant): "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (I 5A NCAC 02C .0200)." UIC/Jn Situ Remed. Notification (Revised 3/2/2015) Page4 "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. Signature* of Property Owner (If different from applicant) Print or Type Full Name • An access agreement between the applicant and property owner may be submitted in lieu of a signature on this form. Submit the completed notification package to: UIC//n Situ Remed. Notification (Revised 3/2/2015) DWR -UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 807-6464 Pages !cnviro ra EnvirOnlnsnlll SeivIcex PASSIVE HYDROGEN INJECTION SYSTEM DIAGRAM PROJECT Farmer Cernex Ready Mix Plant- Indian Trail PROJECT NUMBER 11.990021.00 WELL NUMBER MW-4D ELEVATION OF TOP OF WELL CASING 643.17 feet MSL HYDROGEN INSTALLED ON June 2015 - Proposed STEEL WELL VAULT L A 18.13' 18.13' 23.13' DEPTH TO WATER FROM TOP OF WELL CASING 6.52 feet WATER LEVEL ELEVATION 836.85 feet MSL WATER LEVEL MEASURE[] ON 02/1212015 NOTE: DRAWING NOT TO SCALE GROUNDING ROD ,v SUPPLY LINE SUPPORT CABLE TOP OF FILTER PACK' TOP OF SCREEN -- HYDROGEN DIFFUSER BOTTOM OF WELL 23 REGULATOR/ PRESSURE GAUGE HYDROGEN CYLINDER tivromper- — TILT w ;tr:Mnr v AVF Sl ni .I I r..RFrIUSRIIRn NC 1 PW 335 7638025 I FAX: 336.7618034 f www.enviretrac.cam FIGURES :49 PM BY: annamane bIauser PLOTTED: S11/2015 a w a EN• VIR❑TARAC-I1330 0 tic .'f'��J At- v dp % S e CM • 104. Ltocag ChP 0 -320.vi SS y SS 9r` 3E Lake Park R r.� t t,RE�Ci� r f 1 Hpra w y t N. r 19 cz,INDIAN x °cL �TRAIL I ' IIN!(}NVALE ;WAINTf1t RP W ex te kr 49 `y} .i��- LDS SE e A ;r ▪ \ n oivVCnEril CSR g4 rs \ rS. , O , +US oft qd SOURCE: USGS Topographic map Matthews Quadrangle. STpt fi8kek'tOe �Q 4-Po ; 1,tL� ALP g°A i4. Lv w L ti� f,„5V56�� ti O % On t rC -en -ram R 0 sr OR HAVES sa� ti 2000 4000 SCALE: 1" 2000' SCALE IN FEET EFa Environmental Services PROJECT NO. 1193X21DC DRAWN BY: AB CHECKED BY: CDN DATE: 212712015 REVISED: SITE LOCATION MAP FARMER READY MIX PLANT UNIONVILLE-INDIAN TRAIL ROAD INDIAN TRAIL, NORTH CAROLUNA FIGURE 1 VANSTtRY DRIVE l HLINTERSVILLE, NC PHi 704,897.0707 FAX 704,997.0486 www,envtratrac.carl 0 37.5 75 !inw!!= 1 inch 1= 75 tt. �v ro ra Environmental Soo/leer Environmental Soo/leer usnvuf'Tansxn7 IWw1 115V 112,!10117n UROLSO.. 9rR7 XL i70a1I974767 5tNVIRCITRAC — 11330 VANSTORY DRIVE! IiJNTERSVLLE, NC I PHI 704.897,0707 I FAX' 704.897,0486 1 www.e'nv1rotrac.coi LEGEND �Approximate Groundwater trlonFtorknq 1%11 Location ti1 FIGURE 2 SITE AMP FORMER READY MIX Pied' UNIONYIF.L.f-TRAJL ROAU INDIAN TRAIL, NORTI CAAOIJNA 1 rpwawmMe CMS mew an pa 1 k PIPACrso i xraraoo 0 32.5 75 1 inoh - 75 it. Ulla Y/}dsW OMR NIMrt[%WOlft4 1W FIIFt/MILPOO a7-07O707 LECEND ' APPRO/WATE ORr7W.P.)WATEii hiYYl-s HCNITOR[Nc WELL LOCAPON OPARARDMAitR L. C-IOCE - as-1.2-Of LORTIFTHQiE '10E - TR ICHLOROET*tE.NE VC .. VINYL DeLORZE MWX IR. GRII N07SS Ali CONCENTHAT1ONS IN MICROGRAMS PER UTER. ONLY CONCENIRAIHNS WESTER THAR 2L STANDARDS SHOWN. FIGURE 3 GROUNDWATER EXCEEDANCE MAP FORMER READY MIX P APIT UNIDIMLLE-FRAIL ROAD INOLANTRAI; NGR7itCAROUNA MVACARD fit CYN swc MLNOW01 noun Nat 11 mom as E VXR©TRAC - 11330 VANSTORY DRIVE! HUNTERSVILL£, NC I PHI 704.897.0707 I FAX+ 704897.0486 i www.envirotraccon �viro ra Err 1r onmintal Services APPROXIMATE GROUNDWATER MW-B UONITOISNO WALL LOCATION APPROXIMATE ABANDONED usi-2 MONITORING WELL LOCATION FJGUR£4 CROSS SECTION LOCATION MAP FORMER READY MIX PLANT UNIONVILLE TRAIL ROAD INDIAN TRAIL, NORTH CAROLINA MTh orOwRws DUNN Ft: A M Arncldi en COM VALE AV119aWN P4011011.7.3 11012.1d NVIRDTRAC - 11330 VANSTOIRY DRIVE) HUNTERSVILLE, NC I PH, 704.897.0707 I FAXI 704.897.0486 I www.envIrotraccaM FTWalENT51. Q.AY MIROCK FRAcketro90 a -AY V1tH MAIM ID A 1 1L 1 l � � 1 N. MW-4D 0 - ............... ............. - • .. MW-4D C-DCE 453 TCE=116 VC= 4.2 70 --- BE ROCK TA-33A QN ,Arn4 COCLIRRANOM OP UTRIl9VES HORIZONTAL SCALE 1 *./ ..... A' VERTICAL SCALE EXAGGERATED BY 3. NOTES: RASED ON EA ENGINEERING, SCIENCE, AND TECHNOLOGY, INC. PROTECT NO. 12415.01, FIGURE 9, DATED 5/1993. ALL CONCENTRATIONS SHOWN IN MICROGRAMS PER LITER. ONLY CONCENTRATIONS GREATER THAN 2L 5T AN DA ROS SHOWN, LEGEND MW-40 uw-2 C-DCE TCE VC CaDIKAVATER ELEVATION DATA ER4M 23 MARCN 1993 90 GROUNDWATER ELEVATION DATA FROM FEB 2C15 yr 80 -- 70 60 APPROXIMATE GROUNDWATER MONITORING WELL .00ATI ON AP PROXIMATE ABANDONED MONITORING WELL tOCATICMI APPROX MATE EXTENT OF GROUNDWATER EMEEDANCES (N1 STORK} AP PROXIMATE EXTENT OF GRO UNXIrrATER EXCEEDAItCES(CURRENT) ▪ CI5-1,2-DICHLOROETHER/ TRILHLCROETHENE ▪ WNYLCHLORIDi nviroirac Environmental Services 1I 1110 YAMS TOEn anNl nvmASYu> e,HOA Mwwu In !KA- 1R%1397.6I07 FIGURE S CROSSSECflON Arl' FORMER MAW P PLANT URIONVf4E-TRAIL ROAD INDIAN TRAIL Hawn CAROUNA wo[:7ipNm MUNN it SEA NEW W Or wn icAt4: ASlJgWN PtaJECt MMO: S1ry077i 'F_NVIRC]TRAC - 11330 VANSTORY DRIVE,) HUNTER5VILLE, NC ! PHI 704.897,0707 1 TAX+ 704.897.0486 I wwYw.ennlrotrac,con 75 a 37.5 73 nvirai.rra E'rw1rwriitfnUal S.NIC 61 ,...,.VAIMORroRwt I inch — 76 ft. *gamma. worm painu. LEGEND µ�APPRPXO,ATE GROUNDWATER 8 UDNITnRiNG WELL LOCATION APPROXIMATE GROW1DWATER (640.30 ELEVATEON CONTOURS (ft) GROUNDWATER CONTOUR LINE GROUNDWATER FLOW DIRECTION RGURE 6 GROUNDWATER POTENTIOMETRICSURFACE MAP Mani !;A FORMER READY MIX PLANT UNIDNVILIE-TRAIL ROAD INMAN TRAIL NORTH CAROLINA ■PPFIoW ae: PROW NO: auarxoo ENVI OTARAC - 11330 VANSTORY DRIVE) HUNTERSVILLE, NC 1 PHI 704.697.0707 I FAX' 704.897.0486 I w►rw,envIrotrac,con HYDROGEN MSDS SAFFTV DATA SHEET Hydrogen Airgas LSection 1. Identification GH$ product identifier Chemical name Other means of Identification Product use Synonym SOS # Suppliers details Emergency telephone number (with hours of operation) Hydrogen hydrogen Dihydrogen; o-Hydrogen; p-Hydrogen; Molecular hydrogen; H2; UN 1049 Synthetic/Analytical chemistry. Dihydrogen; o-Hydrogen; p-Hydrogen; Molecular hydrogen; H2; UN 1049 001026 Airgas USA, LLC and its affiliates 259 North Radnor -Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 Lsection 2. Hazards identification OS HAIHCS status Classification of the substance or mixture [3HS label elements Hazard pictograms Signal word Hazard statements Precautianary atement- General Prevention Response Storage Disposal ate of issue/Date of revision This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). FLAMMABLE GASES - Category 1 GASES UNDER PRESSURE - Compressed gas I `I Danger • Extremely flammable gas. Contains gas under pressure; may explode if heated Burns with invisible flame. May displace oxygen and cause rapid suffocation, Read and follow ail Safety Data Sheets (SDS'S) before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Approach suspected leak area with caution_ Never Put cylinders into unventilated areas of passenger vehicles, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use and store only outdoors or in a well ventilated place. Leaking gas fire: Do not extinguish, unless leak can be stopped safety. Eliminate all ignition sources if safe to do so. Protect from sunlight Protect from sunlight when ambient temperature exceeds 52T/125°F. Store in a well -ventilated place Not applicable. 1O/I5P2014. Dale of previous issue : 10/2J21014. Version :0.02 1/12 } rewfw nd by rl bs ------------------------------Hydrogen Section 2. Hazards identification Hazards not otherwise classified : In addition to any other important health or physical hazards, this product may displace oxygen and cause rapid suffocation. Section 3. Composition/information on ingredients Substance/mixture Chemical name Other means of Identification CAS number/other Identifiers CAS number Product code Ingredient name hydrogen Substance hydrogen Dihydrogen; a-Hydrogen; p-Hydrogen; Molecular hydrogen; H2; UN 1049 1333-74-0 001026 % 100 CAS number 1333--74-0 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure llmlts, if available, are listed in Section 8. [ Section 4. First aid measures Description of necessary flrst aid measures Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 1 O minutes. Get medical attention tf irritation occurs. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact Ingestion Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. As this product is a gas, refer to the inhalation section. Most important symptoms/affects, acute and delayed Potential acute health effects Eye contact Inhalation Skin contact Frostbite Ingestion Contact with rapidly expanding gas may cause bums or frostbite . No known significant effects or critical hazards. Contact with rapidly expanding gas may cause bums or frostbite Try to warm up the frozen tissues and seek medical attention. As this product is a gas, refer to the inhalation section. over-exposure signs/symptoms Eye contact No specific data. Inhalation Skin contact No specific data. No specific data. Date of Issue/Date of revision : 10/15/2014. Date of previous Issue 10/2/2014. Version :0.02 Powered by IHS 2112 Hydrogen Section 4. First aid measures ingestion No specific data. Indication of immediate medical attention and ste#aJ tie Invent needed. if nece %.1Si Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. Protection of first -alders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire -fighting measures F.tgulshing media Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Special protective actions for fire-fighters Special protective equipment for fire-fighter=:. Use an extinguishing agent suitable for the surrounding fire. None known. Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. - No specific data. Promptly isolate the scene by removing a]! persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire -exposed containers cool. If involved in fire, shut off flow immediately if it can be done without risk. !f this is impossible, withdraw from area and allow fire to burn. Fight fire from protected location or maximum possible distance. Eliminate all ignition sources if safe to do so_ Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode_ [Section 6. Accidenta _ I release measures Personal Precautions projective For non -emergency personnel For emergency responders Environmental precautions Mtternent.nsl.gmel.9.e_e__efeetilt Accidental releases pose a serious fire or explosion hazard. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, snicking or flames in hazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non - emergency personnel . Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and clashing uQ Date of Issue/0 of revisian - 10/152014. Date of previous issue 1012n014 Version . 0.02 3/12 :wmr t!Po IH5 Hydrogen Section 6. Accidental release measures Small spill Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Large spill Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. I Section 7. Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Eliminate all ignition sources. Keep container tightly closed and sealed until ready for use. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). !Section 8. Exposure controls/personal protection control parameters Occuoational exoosure limits Ingredient name hydrogen Appropriate engineering controls Envlronmental exposure controls lndjyjduaf protection measures Date of issue/Data of revision Exposure limits Oxygen Depletion [Asphyxiant] Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. : 10/15/2014. Date of previous issue : 10/2/2014. VetS/on :0.02 Powered by IHS 4112 Hydrogen Section 8. Exposure controls/personal protection Hygiene measures Eye/face protection Skin protection Hand protection Body protection Other skin protection Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. [ Section 9. Physical and chemical properties Appearance Physical state Color Molecular weight Molecular fonnula Bolllng/condensation point Melting/freezing point Critical temperature Odor Odor threshold pH Flash point Bumingtime Burning rate Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Date of Issue/Date of revision Gas Colorless. 2.02 g/mole H2 -2s3•c (-423.4°F} -259.15°C (-434.S"F) -240.15°C (-400.3°F} Odorless. Not available. Not available. Not available. Not applicable. Not applicable. Not available. Extremely flammable in the presence of the following materials or conditions: oxidizing materials. Lower: 4% Upper: 76% : 10/15/2014 Date of previous issue : 10/2/2014 VetSion :0.02 5112 Powered by IHS Hydrogen Section 9. Physical and chemical properties Vapor pressure Vapor density Specific Volume (ft 3/lb) Gas Density (lblft 3) Relattve density Solubility Solubility In water Not available. 0.07 (Air= 1) 191.9386 0.00521 Not applicable. Not available. Not available. Liquid Density@BP: 4.43 lb/fl:3 (70.96 kg/m3) Partition coefficient: n-Not available. octanol/water Auto-Ignition temperature 500 to 571 °c (932 to 1059.8°F) Decomposition temperature Not available. SADT Not available. Viscosity Not applicable. jsection 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid lncompatibiUty with various substances No specific test data related to reactivity available for this product or its ingredients. The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Extremely reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. jsection 11. Toxicological information Informat ion on tox icological effects Acute toxk;Hy Not available. lrdtat;on/Cormsfoo Not available. Sensitization Not available. Mutagenfclty Not available. earc1nogan1ctty Date of fsaue/Dste of revision 10/15/2014. Date of previous Issue : 10/2/'2014. Version : 0 02 Powered by IHS 6112 Hydrogen Section 11. Toxicological information Not available. Btproductlya toxicltY Not available. Iaratoqeolcity Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely Not available. routes of exposure Potential acute b11ltb effects Eye contact Contact with rapidly expanding gas may cause bums or frostbite. Inhalation No known significant effects or critical hazards. Skin contact Contact with rapidly expanding gas may cause bums or frostbite. Ingestion As this product is a gas, refer to the inhalation section. symptoms refated to the physjca1, chemical and tox;cotogicat characterjstjcs Eye contact No specific data. Inhalation Skin contact Ingestion No specific data. No specific data. No specific data. Delayed and immediate effects and also chronic effects from short and tong term exposure Short tenn exposure Potential immediate effects Potential delayed effects Long tenn exposure Potential immediate affects Potential delayed effects Not available. Not available. Not available. Not available. potential chronic health effects Not available. General Carcinogenicity Mutagenlclty Teratogenlclty Developmental effects Fertility effects No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Date of lnuelDate of revision : 10/15/2014. Date of previous Issue : 10/2/2014. Version :0.02 Powered by IHS 7112 Section 11. Toxicological information N jcai measures of toxlcitx Acute toxicity estiipatel Not available. Section 12. Ecological information Toxicity Not available. Evals,tenckandslegradability Not available. Blceccumuiative potentia[ Not available. Mobility In soil Salliwater partition coefficient (Koc) Not available. Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at ail times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non -recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Empty Airgas-owned pressure vessels should be returned to Airgas_ Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. r -- LSection 14. Transport information DOT TOG Mexico UN number UN1049 UN proper shipping name Transport hazard class(es) Packing group Environment HYDROGEN, COMPRESSED 2,1 UN1049 IMDG IATA HYDROGEN, COMPRESSED 2.1 No. UN1049 HYDROGEN COMPRESSED No UN1049 UN1049 HYDROGEN, COMPRESSED 2.1 HYDROGEN, COMPRESSED No. 2.1 A No. Gate of issue/Dee of reriswn : 16W5 14. Date of previous issue-10Y21014. Version :0.02 P1f2 Pau/bred by !HS Hydrogen Section 14. Transport information Addition al l.lmflml IIUIO&lilt ~~.J.!.mJ!.i'.rut --easaene1t 1nd ~mg Yes . Llmlt!HI g111oltw lmll! &llimflQuantlty Information 0.125 Hmltation : 0 Forbidden eackaglng Instruction Cargo Alr:mft Qnb! Passenger aircraft EBAelDIIU Quantityllmltatlon: 150 Quantity limitation : 3000 kg Forbidden. filHDIIII: ~DJllUII Cargo aircraft 3b1Plodex Quantity limitation : 150 Forbidden kg eaa•an111E ~IDJIIJII BSllsl ac BIii fndax Forbidden "Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the product" Special precautions for user Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport In bulk according Not available to Annex II of MARPOL 73f18 and the IBC Code !Section 15. Regulatory information U.S. Federal regulations TSCA 8(a) CDR Exempt/Partial exemption: This material is listed or exempted . United States inventory (TSCA 8b): This material is listed or exempted. Clean Air Act (CAA} 112 regulated flammable substances: hydrogen Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 3021304 Not listed Not listed Not listed Not listed Not listed Composition/fntormatjon on ingredients No products were found. SARA304RQ SARA 311/312 Classification Not applicable. Fire hazard Sudden release of pressure Comoosmon/jnformation on ingredients Date of luue/Date of r&vl$/on · 10/15/2014. Dateofp,evlous/Ssue 10/2/2014. Version : 0 02 Powered by IHS 9112 HYdragen Section 15. Regulatory information Name hydrogen Stale remotions Massachusetts New York New Jersey Pennsylvania Canada Inventory International regulations International lists Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule !I Chemicals Chemical Weapons Convention List Schedule III Chemicals WHMIS (Canada} 1 DO Fire hazard Yes. Sudden release of pressure Yes. Reactive Na. Immediate (acute) health hazard Delayed (chronic) health hazard No. No. This material is listed. : This material is not listed. This material is listed. This material is listed. This material is listed or exempted. Australia inventory (AICS): This material is listed or exempted. China inventory (IECSC): This material is listed or exempted. Japan Inventory: Not determined. Korea inventory: This material is listed or exempted. Malaysia Inventory (EHS Register): This material is listed or exempted. New Zealand Inventory of Chemicals (NZloC): This material is listed or exempted. Philippines inventory (PICCS): This material is listed or exempted. Taiwan inventory (CSNN): Not determined. Not listed : Not listed • Not listed Class A: Compressed gas. Class B-1: Flammable gas. CEPA Toxic substances: This material is not listed, Canadian ARET: This material is not listed. Canadian NPRI: This material is not listed. Alberta Designated Substances: This material is not listed. Ontario Designated Substances: This material is not listed Quebec Designated Substances: This materiel is not listed. Section 16. Other information Canada Label requirements : Hazardous Material Information ,Health Flammability Physical hazards Class A: Compressed gas. Class B-1: Flammable gas. System tU,S.A.I Q 4 Date of katt 1lDai8 of revision : 1a►'1512014. Date of previous issue i402i2014. Version :0.02 1042 Powered by IiiS HYdrogon Section 16. Other information Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SO5s under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. fictional Fire Protection Assoriiation (U.S.A.1 Flammability Health 0 InstabllltylReactivity Special Reprinted with permission from NFPA 704-2001, identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. wry Date of printing Date of IssuelDate of revision Date of previous Issue Version Key to abbreviations 10/15/2014 10/15/2014. : 10/2I2014. : 0.02 ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73178 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978, ("Marpol" = marine pollution) UN = United NationsACGIH — American Conference of Governmental Industrial Hygienists AIHA — American Industrial Hygiene Association CAS — Chemical Abstract Services CEPA — Canadian Environmental Protection Act CERCLA — Comprehensive Environmental Response, Compensation, and Liability Act (EPA) CFR — United States Code of Federal Regulations CPR — Controlled Products Regulations DSL — Domestic Substances List GWP — Global Warming Potential IARC — International Agency for Research on Cancer ICAO — International Civil Aviation Organisation Inh— Inhalation LC — Lethal concentration LD — Lethal dosage NDSL Non -Domestic Substances List NIOSH — National Institute for Occupational Safety and Health DM M issuettes or ►evisfon fa'15/2014. Dare of prsvrous issue 1Or 14. 0 02 11fl2 1::ion 16. Other information References TOG -Canadian Transportation of Dangerous Goods Act and Regulations TL V -Threshold Limit Value TSCA -Toxic Substances Control Act WEEL -Workplace Environmental Exposure Level WHMIS -Canadian Workplace Hazardous Material Information System Not available. Indicates Information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of Its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the Information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of Issue/Date of revision : 10/15/2014. Date of previous issue : 10/2/2014. Version :0.02 12/12 Powered by IHS PASSIVE HYDROGEN INJECTION SYSTEM DIAGRAM tJ ID 1 Thank you for submitting the Notice of Intent to Construct or Operate Injection Wells (N01) at the Former Cemex Ready Plant. This facility is located at 4206 Unionville -Indian Trail Road Indian Trail, NC 28079. We received your complete NOI on June 18, 2015. Please remember to submit the following regarding this injection activity: 1) Well Construction Records (GW-1) and Abandonment Records (GW-30) when completed. Please provide copies of the GW-ls and GW-30s if not already submitted (originals go the address printed on the form). NOTE: Direct push or Geoprobe wells are considered wells and require construction (GW-1) and abandonment forms (GW-30). If well construction/abandonment information is the same for the wells, only one form needs to be completed- just indicate total number of injection points in the CommentsjRernarks section of form. These forms can be found on our website at httn l/Lsnrtal,rirdenr orpJweb/wq/anslhwprojreporting-forme. 2) Injection Event Records (IER). All injections, including air and passive systems require an fER. The [ER can be modified for air sparge wells (e.g., air flow `continuous' for date or rate of injection, etc.). You can scan and send these forms directly to meat -i rr:hael,r0gersgi@ncde-,r send by fax to my attention at 919-807-6406, or via regular mail to address bellow- When submitting the above forms, you will need to enter the nine -digit alpha -numeric number on the form (i.e., WIOXXXXXX) that has been assigned to the injection activity at this site. This notification has been given the deemed permit number WI0300290. This number is also referenced in the subject line of this email. You may if you wish, scan and send back as attachments in reply to this email, as it wilt already have the assigned deemed permit number in the subject line. Thank you for your cooperation. Michael Rogers, P.G. (NC & FL) Hydrogeologist NCDENR - DWR Water Quality Regional Operations Section 1636 Mail Service Center Raleigh, NC 27699 Direct No. 919-807-6406 Shire, Ebonee From: Sent: To: Cc: Subject: Attachments: Follow Up Flag: Flag Status: Shire, Ebonee Thursday, June 18, 2015 12:16 PM 'craig@envirotrac.com' Parker, Michael; Pitner, Andrew; 'denise.corrales@cemex.com' Thank you for submitting the Notice of Intent to Construct or Operate Injection Wells Thank you for submitting the Notice of Intent to Construct or Operate Injection Wells.pdf Follow up Completed 1 EF Environmental Services June 2, 2015 Mr. Mike Rogers Division of Water Resources 1611 Mail Service Center Raleigh, North Carolina 27699-1611 0, I06 ' Neer 4uetlty Reenel rypecat1on Reference: Notification of Intent to Construct or Operate Injection Wells Former Cemex Ready Mix Plant 4206 Unionville -Indian Trail Road Indian Trail, North Carolina NCDENR IHSB Site #NONCD0002395 Dear Mr, Rogers: EnviroTrac is pleased to submit the enclosed Notification of Intent to Install or Construct Injection Wells, The purpose of this corrective action is to target the localized area of elevated trichloroethylene concentrations in monitoring well MW-40 at the site Installing a passive hydrogen injection device in the well would increase the degradation rate of chlorinated hydrocarbons but still allow the well to be used as a monitoring point. Should you have any questions regarding this notification or require additional information, please contact the undersigned_ Very truly yours, ENVIROTRAC LTD. CraigDK-4 . Neil, P.G. Senior Project Manager craion@envirotrac.com Attachments: Notification of Intent to Install or Construct Injection Wells Cc: Ms. Denise Corrales, Cemex €1330 Vanstory Drive, Fruntersville, NC 28078I Office: (704) 897-0707 I Fax: (704) 897-0486 www.envirotrac.com t NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES NOTIFICATION OF INTENT TO CONSTRUCT OR OPERATE INJECTION WELLS The following are "permitted by rule" and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C .0200. This form shall be submitted at least 2 weeks prior to iniection. AQUIFER TEST WELLS (I SA NCAC 02C .0220) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION <l SA NCAC 02C .0225) or TRACER WELLS (f SA NCAC 02C .0229): 1) Passive In jection S ystems -In-well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods. 2) Small-Scale Injection O perations -Injection wells located within a land surface area not to exceed l0,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests -Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells are located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air In jection Wells -Used to inject ambient air to enhance in-situ treatment of soil or groundwater, Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete. DATE: _Jun_e_2 __ ~• 2015 PERMIT NO. \\)\(>2,()0'2,.G\() (t-0 be filled in by DWR) A. WELL TYPE TO BE CONSTRUCTED OR OPERA TED (1) (2) (3) (4) (5) (6) ___ Air Injection Well .................................... ,.Complete sections B-F, K, N ___ Aquifer Test Well.. ..................................... Complete sections B-F, K, N ~X __ Passive fujection System ...................... u•••,; .. Complete sections B-F, H-N ___ Small-Scale Injection Operation ........... ,,.., ....... Complete sections B-N ____ Pilot Test ..............................•.•.. ; ........ ,, ... Complete sections B-N ___ Tracer Injection Well .................................. _ •. Complete sections B-N B. ST A TUS OF WELL OWNER: Choose an item. C. WE LL OWNER -State name of entity and name of person delegated authority to sign on behalf of the business or agency: Name: ______ C~e=m __ e=x-=M=s~. =D~e=m""·s ... e_C..,o ... rra ...... le ... s _______________________ _ Mailing Address: 3820 Northdale Blvd. Suite 100B City: Tampa State: FL Zip Code:_3=3~6=24~ ___ County: Hillsborough Day Tele No.: (813 )269.,1035 EMAIL Address: deni~..r.r.ales@cemex.co=m~---- UIC//n Situ Remed. Notification (Revised 3/2/2015) Cell No.: ----------"""--- Fax No.: --~<8~1~31~2 ..... 6 ..... 9-~l-"-03"-'0'---- Page I D. PROPERTY OWNER (if different than well owner) Name: ----------------------------------- Mailing Address:-------------------------------- City:-· ____________ State: _ZipCode: _________ County: _____ _ Day Tele No.: _____________ .....,..., Cell No.: __________ _ EMAIL Address:--'-----------------Fax No.: __________ _ E. PROJECT CONT ACT -Person who can answer technical questions about the proposed injection project. Name: Crai e Neil. EmriroTrac Ltd. Mailing Address: ----=-1=13=3,_,0,_V"""-.=an=st=o:cory..s..=D=r_,,_iv'--"e'--____________________ _ City: Huntersville State: NC Zip Code: __ 2_80_7_8 ____ County: Mecklenburg Day Tele No.: (704) 897-0707 Cell No.: __ __.{=33=6=)=40=7,_-4=5=t=S __ _ EMAIL Addresst __ -=c=ra=i""gn""@=e::.:nv""'ir,:..o:::..:tr::..:a=-=cc:..:.c::..::oc.::.:mc:..._ __ _ Fax No.: ----------- F. PHYSICAL LOCATION OF WELL SITE (l) Physical Address: ___ 4~2~0~6~U~m=·o~n_vi=ll=e-~I=n~di~a=n ~T~ra=i ...... l ~R ...... ci~ad~(F~i ... gur~e_l-) __________ _ _______________________ County:.,...U.,..D....,io .... n ...... • ______ ___ City: Indian Trai.l State: NC Zip Code: --=2=-80"""'7-"-9 _____ _ (2) Geographic Coordinates: Latitude**: --- 0 --__ " or =35"--_0 -~0~7~5~0~9 ...... 1 __ _ Longitude**: ______ 0 __ ,, or ~0 634504 Reference Datum: ........ _______ Accuracy: _______ _ Method of Collection: http :/ /itouchmap.com/latlong.htm l -- ** FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant p lume: ______ square feet Land surface area of inj. well network; square feet~ 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: (must be ,5 5% ofph.11ne for pilot test injections) H. INJECTION ZONE MAPS -Attach the following to the notification. (I) Contaminant plume map(s) with isoconcehtration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and Figure 2 shows the site layout and existing monitoring well locations. Figure 3 shows the horizontal extent of impacted groundwater. The passive hydrogen injection system is proposed to be installed into MW-4D. UICI In Situ Remed. Notification (Revised 3/2/2015) Page2 (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. Figure 4 shows the location of the cross section A-A'. Figure 5 shows the cross section with projected vertical extent of impacted groundwater that exceed the NCGS 2L Standard. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. Figure 6 is the potentiometric surface map showing the rate and direction of groundwater move!)lent based on data collected during the February 2015 sampl!ng ~vent. I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES -Provide a brief narrative regarding the purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration of injection over time. The in iec tio n activities arc intended to irn.prove trichloroeth ylene (TCE) concentrations. Results of the Feb ruary 201,5 sam plin g eventSm.!ge st TCE im pacted groundwat\ir is. limi ted and 011I MW-4D e,chibits TCE and d aughter products,auioncen.trationsthat exceed the groundwater reme diati on goal s, Monttor ing well MW-40wiU have a passive h dro 1Hin deliverv svstem installed inside the monitorin g well. This systernwill allow h ydrogen to be. in jected ihto the g_rourtdwater affectin g a lotalized area. The p~rforrnanc~ of this svstcrn will be monitored uarterl . J. INJECT ANTS-Provide a MSDS and the following for each injectant. Attach additional sheets ifnecessacy. NOTE: Approved injectants (tracers and remediation additives) can be found online at http://portal.ncdenr.orglweblwqlapslgwpro, All other substances must be reviewed by the Division of Public Health, Department of Health and Human Services. Contact the U/C Program for more info (919-807-6496). Injectant: --~H~y-dr=o-g=e=n~-~M,e=-S=D~S~a=tta~ch~e~d~------------------- Volume ofinjectant: continuous release of hydrogen gas at one cubic foot per day Concentration at point of injection: MW-4D will range from 2.4 to 2.5 ppm (based on 16 to 19 feet of submergence). The hydr.qgen concentrations .are. estimated based on a saturated hydrogen contt!11t of 1.6 ppm per atmos phere. Percent if in a mixture with other injectants: __ ._.N .... A_.. •----------------- Injectant: ______________________________ _ Volumeofinjectant: ____________________________ _ Concentration at point of injection: ---------------------------- Percent if in a mixture with other injectants: --------------------~ Injectant: --------------------------------- Volume of injectant ____________________________ _ Concentration at point of injection: _______________________ _ Percent if in a mixture with other injectants: ____________________ _ UICI In Situ Remed. Notification (Revised 3/2/2015) Page3 K. WELL CONSTRUCTION DATA (1) Number of injection wells: -----'Proposed'--------=1 __ • _Existing (2) Provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following: (a) well type as permanent, direct-push, or subsurface distribution system (infiltration gallery) (b) depth below land surface of grout, screen, and casing intervals (c) well contractor name and cer:tification number A passive hydrogen injection system diagram with well construction details for MW-4D is attached. The well contractor name and certification number are unknown. L. SCHEDULES -Briefly d(;!scribe the schedule for well construction and injection activities. Enviro.trac wIHtravel to the site and install the delivery system upon recei pt of the permit · The .h dro gen will b e iniecfed con tinuousl y and th content of th hvdrogcn cvl inde and tie.Id parnnieter will ht, monitored. monthl. M. MONITORING PLAN -Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified inSubehaptg02L result from the injection activity. Groundwater samples wHI b -collected from MW~4D quarterl y. · The perfonnance of the passive hydrogen deliverv S)'5 ten, will be evaluated following three months of operation. N. SIGNATURE OF APPLICANT AND PROPERTY OWNER APPLICANT: "l hereby certify, under penalty of law, that lam familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, l believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. l agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and ({\ r. elate_dupptttf1c,rlce!i in acco0dance with the lSA N.(' tc 2l' 200 Rules."(\ . · 'iQ. J(\ -~""'-x....D. -<:.A-/ l\1!;1·e. LDY'rcr..le ~lgna7ttcorApplicant · . \)~ff t-tcJ{ Gr\Vi fbf\"t ~-%t,°"A _;f._, Print or Type Full Name PROPERTY OWNER (if the pro pertv is not owned by the permit a pp licant): "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each i~jection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (J 5A NCAC 02C .0200). " UIC/Jn Situ Remed. Notification (Revised 3/2/2015) Page4 "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. Signature* of Property Owner (if different from applicant) · Print or Type Full Name * An access agreement between the app/icam and property owner may be submitted in lieu of a signature on this form. Submit the completed notification package to: UICI In Situ Remed. Notification (Revised 3/2/2015) DWR -UIC Program 1636 Mail Service. Center Raleigh, NC 27699-1636 Telephone: (919) 807-6464 Page 5 FIGURES 6/1/2015 1:49 PM BY: annarnarie blause lndisnTrails_-figures 1 dwg 4'a CIR 44 1 oit ss1 fir N. \DLIN i w TRAIL lake Park fM oormL prowl' mt. Ro yy ti stturrue e goo' gfr SOURCE: IJSGS Topographic map Matthews Quadrangle. tirivirTo lira Environmental Services T PROJECT NO. 11AAL1�21Ad DRAWN BY: AS CHECKED BY: CON DATE: 2/27/2015 REVISED: IGO Red I tj R OGY rig eel 0 etcfr 2000 57 osib HAD • 4000 SCALE: I" = 2000' SCALE IN FEET SITE LOCATION MAP FORMER READY MIX PLANT UNIONVILLE-INDIAN TRAIL ROAD INDIAN TRAIL, NORTH CAROLINA FIGURE 1 ENVIRRTARAC-11330 VANSTORY DRIVE I HUNTERSVILLE, NC I PI-11 704.897,0707 I FAX! 704.897.0486 I www.envIrotrac.corl �rniro ra Environmental 9arvlwc Environmental Services 1133D VAMSORAV DRAR 1 inch = 75 f t. "" `C ' ORI t"" ,r " NV1ROTRAC - 11330 VANSTORY DRIVE.! HUNTERSVILLE, NC ! PH' 704.897.0707 I FAX! 704,897.0486 I www.envlrairar.ron M�Approximate Groundwater Monitoring 8 l Location DAME: O2 2 ' aws CRAYON MI As FIGURE 2 SITE MAP FORMER READY MIX PLANT UNIONVILLE-TRAIL ROAD INDIAN TRAIL, NORTH CAROLINA APPROVED IV: CDM win 1.. 7. imago- ow: U99:021 0 UW-9 • '1 • 0,4 • Approxim- a▪ te Loeatlon of the Sump 1 inch = 75 ft. r 'A Vr--• ,1 • 4 T.i :141k. It ,r a i �nviro ra Environmental Environm.ntal Services SUM W latYOWE NIINTSASSALLE, NGPM PAOUNA PNOMC: 1PWI 191'OIO7 :ENVIREJTRAC - 11330 VANSTURY DRIVE.' HUNTERSVILLE, NC I PHI 704.897,0707 I FAX' 704,897.0486 1 www.envIrotrac,com LEGEND APPROXIMATE GROUNDWATER MONITORING ,AEU. LCCATIGN r'� AFYRU7CMA+`� EAuETr r C� C-DCE r CIS-1,2•-01CI'ILORGETHE]IE TCE . TRiGillOROEETH w VC r VIM CHLORIDE NOTES ALL CONCENTRATIONS IN MICROGRAMS PER LITER. ONLY CONCENTRATIONS GREATER THAN SL STANDARDS SHOWN. Glatt o atILI 11i WAWA Dr OSA FIGURE 3 GROUNDWATER EXCEEDANCE MAP FORMER READY MIX PLANT UNIONVILLE-TRAIL ROAD INOIANTRAIL, NORTH CAROLINA AMwavrD srf CON SCALE A Q WWM recast MRlieg:M LO c 0 37.5 75 1 inch = 75 ft. viro ra Emrironmantal SafylC6i 11110WIKSODE EWA HIRCIERWIL LE, NORM OLROLNA PHEW: DIM u 7a707 t GELD MW-8 MW-2 APPROXIMATE GROUNDWATER MONITORING WELL LOCATION APPROXIMATE ARANb0NED MONITORING WELL LOCATION ..-- CROSS SECTION LOCATION FIGURE4 CROSS SECTION LOCATION MAP FORMER HEADY MIX PLANT UNION VILLE-TRAIL ROAD I NOIAN TRAIL, N ORTN CAROUNA DAM: s/m/lms (PAWNO'l: 61OH APPROVED Er: CAE SCAM 1,6511.7NN PROPERN0; 11.94001LG0 . NVIRDTRAC - 11330 VANSTORY DRIVE,' HUNTERSVILLE, NC I PHI 704,897,0707 I FAX; 704,897,0486 I www,envIro±rac,Com a M W-4D C-D w 453 f TCE =116 0 VC=4.2 100 OWN:W ER CvA1N DATA TOM Zi IIIARCH 1993 — 90 GROUNDWATER ELEVATION DATA FROM FEB 2015 MOMENTS CLAY A GRAVEL -ROCK 11 SMYT YOH ROCK> CLA� 90 {MW--21 I.taw 1 s g 1 4, 0 6 t Mw-4D 6 p III�F - lii iTCLAY WITH '1 1 \ : 1 '' '( ROCK FRA rNTT NAM arroirtm &� \ . r! '............... .... • '.-. 100 -- sN \ I ir / PWR 70-- 8EL WCOC ', :TAB-MARCO< Arm LIP HIRLI51VES HORIZONTAL SCALE 0 15 1 VERTICAL SCALE EXAGGERATED BY 3. NOTES: BASED ON EA ENGINEERING, SCIENCE, AND TECHNOLOGY, MC. PROJECT NO.,1241S.01. FIGURE9, DATED5/1993. AU. CONCENTRATIONS SHOWN IN MICROGRAMS PER LITER. ONLY CONCENTRATIONS GREATER THAN IL STANDARDS SHOWN. LEGEND MW-40 C-DLE TCE VL 80 70 130 APPROXIMATE GROUNDWATER MONITORING WELL LOCATION APPROXIMATE APANIDONED MONfr0RING WELL LOCAT]ON APPROXMATE EXTENT OF GROUNDWATER EXCEEo NCES(HISTORICy APPROXIMATE EXTENT Of GROUNDWATER EXCEEOANCES(CURRENT] = CIS-!, 2•DI CH LOROELHENE TRICHIOROETHENE = VINYL CHLORIDE I1 r p%%WartMY! ..ARIAP IC Nano COMM rnaN[: Frw)I107{1Z, FIGURE 5 CROSS SECTION A -AI FORMER READY NO% PLANT UNIOiVI LLE-TRAIL ROAD IND+AN TRAIL, NO5114CARO INA CATT1 0002,02015 ORASVrir•rr•14 APPAOPLO ma scxc: ►s EPnrwr mac op: union in L 4&NVIR[]TRAC - 11330 VANSTURY DRIVE,I HUNTERSVILI.E. NC I PH. 704.897.0707 I FAX+ 704.897,04136 wW*.e nvlrokra r.con 75 ■t• Approximate't Location of __ 1 the Sump 57,$ 75 viro ra Environmental Services 11330 VANSEORE MIME 1 inch = 75 it IfinfWOKE EEPPPALLE.COMM l a97-007 ENV1REITARAE — 11330 VANSTIJRY DRIVE,I HUNTERSVILLE, NCI PHI 704,897.0707 I FA* 704.897.0486 I www.erkvIrotracron LEGEND 0 APPRPXO,ATE GROUNDWATER M>M-8 AION€TARING WELL LOCATION APPROXIMATE GROUNDWATER (64030) ELEVATION CONTOURS (ft) GROUNDWATER CONTOUR LINE GROUNDWATER FLOW DIRECTION FIGURE 6 GROUNDWATER POTENT{OMETIi1C SURFACE MAP FORMER READY MIX PLANT UN ION VI LIE -TRAIL ROAD !WAN TRA14 NORTH CAROUNA DATE WED112015 DIRR1Nk RE: M APPROVED BY: C9x SEAIL 1•,75• PREVECT1101 1i 99007E00 HYDROGEN MSDS SAFETY DATA SHEET Airgas Hydrogen 1Se ction 1. identification GHS product identifier Chemical name Other means of identification Product use Synonym SOS # Supplier's details Emergency telephone number (with hours of operation) : Hydrogen : hydrogen Dihydrogen; a -Hydrogen; p-Hydrogen Molecular hydrogen; H2; UN 1049 : Synthetic/Analytical chemistry. : Dihydrogen; a -Hydrogen; p-Hydrogen; Molecular hydrogen; H2; UN 1049 : 001026 Airgas USA, LLC and its affiliates 259 North Radnor -Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 Section 2. Hazards identification OSHAIHCS status Classification of the substance or mixture GHQ label elements Hazard pictograms Signal word Hazard statements Precautionary statements General Prevention Response Storage Disposal : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). : FLAMMABLE GASES - Category 1 GASES UNDER PRESSURE - Compressed gas : Danger Extremely flammable gas. Contains gas under pressure; may explode if heated Burns with invisible flame. May displace oxygen and cause rapid suffocation. Read and follow all Safety Data Sheets (SDS'S) before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Approach suspected leak area with caution. : Never Put cylinders into unventilated areas of passenger vehicles. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use and store only outdoors or in a well ventilated place. Leaking gas fire; Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. Protect from sunlight. Protect from sunlight when ambient temperature exceeds 52'C/125°F. Store in a well -ventilated place. : Not applicable. Dale of issue/Date of revision : 10/15/2014. Date of previous issue : 1Oi2_2014, Version :0.02 1112 Powered by iHS Hydrogen Section 2. Hazards identification Hazards not otherwise classified : In addition to any other important health or physical hazards, this product may displace oxygen and cause rapid suffocation . Section 3. Composition/information on ingredients Substance/mixture Chemical name Other means of identification CAS number/other Identifiers <;AS number Product code Ingredient name hydrogen Substance hydrogen Dihydrogen; o-Hydrogen; p-Hydrogen; Molecular hydrogen; H2; UN 1049 1333-74-0 001026 % 100 CAS number 1333-74-0 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. I Section 4. First aid measures PmriPtkul of neces,wy tirst 1id me,sun:s Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the pers,on providing, aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in Fecovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact Ingestion Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. As this product is a gas, refer to the inhalation section. Most important &Ytnptomsteffects, acute and· delayed Pote nt ial acute healt h effec ts Eye contact Inhalation Skin contact Frostbite Ingestion Contact with rapidly expanding gas may cause burns or frostbite, No known significant effects or critical hazards. Contact with rapidly expanding gas may cause burns or frostbite, Try to warm up the frozen tissues and seek medical attention. As this product is a gas, refer to the inhalation section. Over-exposure signs/symptoms Eye contact No specific data. Inhalation Skin contact No specific data. No specific data. Date of issue/Date of revision : 10/1512014. Date of previous issue ; 1012/2014. Version : 0.02 Powered by IHS 2112 1-" Section 4. First aid measures Ingestion · ;. No specific data. Indication. of immediate roedtcat attention and special treatment otided, ff necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments Protection of first-aiders No specific treatment. · No action shall be taken involving any personal risk or without suitable training . It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fightipg measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing . media Specific hazards arising from the chemical Hazardous thermal decomposition products Special protective actions for fire-fighters Use an extinguishing agent suitable for the surrounding fire. : None known. Conta ins gas under pressure. Extremely flammable gas. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. • No specific data. : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk . Use water spray to keep fire-exposed containers -cool. If involved in fire, shut off flow immediately if it can be done without risk . If this is impossible, withdraw from area ~nd allow fire to burn. Fight fire from protected location or maximum possible distance. Eliminate all ignition sources if safe to do so. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. I Section 6. Accidental release measures persona• prjcauti2ni. protect.Ive eguip,nem anci emergeruw proeedvres For non-emergency Accidental releases pose a serious fire or explosion hazard. No action shall be taken personnel involving any personal risk or without suitable training. Evacuate surrounding areas. K_eep unnecessaiy and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area . Avoid breathing gas. Provide adequate ventilation . Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). MdJorui iJOd roaleriats for @otalnment and clHoing YR Date of issue/Date of revision : 10/15/2014. Date of previous issue : 10/'l/2014. Version : 0.02 3112 Powered by IHS Hydrogen Section 6. Accidental release measures Small spill Large spill Immediately contact emergency personnel. tools and explosion -proof equipment, : Immediately contact emergency personnel. tools and explosion -proof equipment. Note: information and Section 13 for waste dispos Stop leak If without risk. Use spark -proof Stop leak if without risk. Lise spark -proof see Section 1 for emergency contact al. Section 7. Handling and storage Preeeautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion -proof electrical (ventilating, lighting and material handling) equipment. Use only non -sparking tools. Empty containers retain product residue and can be hazardous. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store away from direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials (see Section 10). Eliminate ail ignition sources. Keep container tightly closed and sealed until ready for use. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Section 8. Exposure controls/personal protection Control parameters OccupatioLnal exposure limits ingredient name 'Exposure limits hydrogen Oxygen Depletion [Asphyxiant) Appropriate engineering : Use only with adequate ventilation. Use process enclosures, Iocal exhaust ventilation or controls other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion -proof ventilation equipment. Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protect►en measures Dale of issue/Date of revision 10/15+2014. Date of previous issue : 1012/2014. Version :0.02 4112 Powered by f - S Hydrogen Section 8. Exposure controls/personal protection Hygiene measures Eye/face protection Skin protection Hand protection Body protection Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing . Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, m ists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. • Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical .products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the g loves are still retaining their protective properties. It should be noted that the time to breakthrough for ariy glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For ttie greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Other skin protection Appropriate footwear and any add itional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. I Section 9. Physical and chemical properties Appe:arance Physical state Color Molecular weight Molecular formula Borling/condensation point Melting/freezing point Critical temperature Odor Odor threshold pH Flash point Burning time Burning rate Evaporation rate Flammablllty (solid, gas) Lower and upper explosive (flammable) limits Date of issue/Date of revision ,. Gas .. Colorless. 2.02 g/mole : H2 .. -253°C (-423.4°F) . -259.15°C (-434.5°F} .. -240.15°C (-400.3°F) Odorless. Not available. Not available. Not available. Not applicable. Not applicable. Not available. Extremely flammable in the presence of the following materials or conditions: oxidizing materials. • Lower: 4% Upper: 76% : 10/15/2014. Date of previous issue : 1012/2014 . Version : 0.02 5112 Powered by IHS Hydrogen Section 9. Physical and chemical properties Vapor pressure Vapor density Specific Volume (ft 3/lb) Gas Density (lb/ft 3) Relative density Solubility Solubility In water Partition coefficient: n- octanol/water Not available. 0.07 (Air= 1) : 191.9386 0.00521 Not applicable. Not available. Not available. Not available. Liquid Density@BP: 4 .43 lb/ft3 (70.96 kg/m3) Auto-ignition temperature 500 to 571°C (932 to 1059.8°F) Decomposition temperature Not available. SADT Not available. Viscosity Not applicable. [section 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatibility with various substances No specific test data related to reactivity available for this product or its ingredients, The product is stable .· Under normal conditions of storage and use, hazardous reactions will not occu r:: : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose· containers to heat or sources of ignition. Extremely reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Hazardous polymerization : Under normal conditions ofstorage and use, hazardous polymerization will not occur. !sectio-n-11. Toxicological information Information 20 toxicologic al effecbl Acute toxicity Not available. lrritation/Corrosjon Not available. Sensitization Not available. Mutagentcitv Not available. carcinogenicity Date of issue/Date of revision : 10/1512.014. Date of previous issue : 101'212014. Version : 0,02 Powered by IHS 6/12 Hydrogen Section 11. Toxicological information Not available. Reproductive toxicity Not available. Ieratogenicity Not available. Specific target oman toxicity tsiqgle expmu:tl Not available. Specific targ,rt organ toxicity (re_peated exposure) Not available. Aspiration hazard Not available. Information on the likely routes of exposure Potential acute health effects Eye contact Inhalation Skin contact Ingestion : Not available,. Contact with rapidly expanding gas may cause burns or frostbite. No known significant effects or critical hazards. Contact with rapidly expanding gas may cause burns or frostbite ; As this product is a gas, refer to the inhalation section. $Ymptoms related to the physical, ehernig;l and toxicological characteristics Eye contact No specific data. Inhalation Skin contact Ingestion No specific data. No specifiG data. .No specific data. peflYed and immedl,lte effects and also chronic effects from short and tonq term exposure Short term exposure Potential Immediate effects Potential delayed effects Long term exposure Potential immediate effects Potential delayed effects Potential chronic health effects Not available. General Carcinogenicity Mutagenlclty Teratogenlcity Developmental effects Fertility effects Not available. Not available. Not available. Not available. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Date of issue/Date of revision : 10/15/2014. Date of previous issue ; 10/2/2014. Version : 0. 02 Powered by IHS 7112 Hydrogen Section 11. Toxicological information Numerical measures of toxicity Acute toxicity est;mates Not available. !Section 12. Ecological information Toxicity Not available. Persi$nceanddeg,:adabifity . Not available. Bioaccumulatjye potential Not available. Mobility in soil Soil/water partition coefficient (Koc) Not available. Other adverse effects : No known significant effects or critical hazards. I Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste·should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorties with jurisdiction. Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. I section 14. Tra-nsp·ort information DOT TOG Mexico IMDG IATA UN number UN1049 UN1049 UN1049 UN1049 UN1049 UN proper HYDROGEN . HYDROGEN, HYDROGEN HYDROGEN, HYDROGEN, shipping name COMPRESSED COMPRESSED COMPRESSED COMPRESSED COMPRESSED Transport 2.1 2.1 2.1 2.1 2.1 hazard class(es) ♦ ♦ ♦ ♦ ♦ Packing group ·-.-.-··-- Environment No. No . No. No. No. I Date of issue/Date of revision :101151'2014. Date of previous issue : 1012/2014. Version :0.02 8/12 1 Powered by IHS ---·---Hydrogen Section 14. Transport information Additionel !.lmttld au1atib: ila:llsm!m Llmll lml . . P1i1&1!Hli[ IDd !a!llg !.1mllld Qianlft¥ Ir.ult& Yes. A!w:lflQuanlity Information Q.1 ~· .......... limitation: o Forbidden eai;lsiglog IDBD.ICtis:tD ~egg Alcctd Qalir: Passenger aircraft ERAPlndax Quantity limitation: 150 Quantity limitation: 3000 kg Forbidden . e11111oggc CiWJIDSI Cargo aircraft Ship lode.x Quantity limitation : 150 .Forbidden kg enlillSIIC~IEDdllU Bgad SJ[ Biil lodu Forbidden "Refer to CFR 49 (or aothorlty having jurisdiction) to determine the information required for shipment of the product." Special precautions for user Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according Not available. to Annex II of MARPOL 73n8 and the IBC Code !Section 15. Regulatory information U.S. Federal regulations TSCA 8(a) CDR Exempt/Partial exemption: This material is listed or exempted. United States inventory (TSCA Sb): This material is listed or exempted. Clean Air Act (CAA) 112 regulated flammable substances: hydrogen Clean Air Act Section 1_12 (b} Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 : Not listed Not listed Not listed Not listed Not listed ~903itiQnlinform,tt® Qn _ 1,ig,:.edi~nw No products were found . SARA304RQ SARA 311/312 Not applicable. Classification Fire hazard Sudden release of pressure Composit;onlintormatiQn 20 ingredients Date of issue/Date of revision : 10/15/2014. Date of previous issue : 10/2/2014. Version : 0.02 Powered by IHS 9112 'Hydrogen Section 15. Regulatory information Name hydrogen State regulations Massachusetts New York New Jersey Pennsylvania Canada Inventory lntematjonal regulations International lists % Fire hazard 100 Yes . This material is listed. : This material is not listed. :. This material is listed. This material is listed. Sudden release of pressure Yes. This material is listed or exempted. Reactive lmmec:llate (acute) health hazard No. No. Australia inventory (AICS): This material is listed or exempted. China inventory (IECSC): This material is listed or exempted. Japan inventory: Not determined. Korea inventory: This material is listed or exempted. Delayed (chronic) health hazard No. Malaysia Inventory (EHS Register): This material is listed or exempted. New Zealand Inventory of Chemicals (NZloC): This material is listed or exempted. Philippines inventory (PICCS): This material is listed or exempted. Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule Ill Chemicals Canada WHMIS (Canada) Taiwan inventory (CSNN): Not determined. !-: Not listed Not listed : Not listed Class A: Compressed gas. Class B-1: Flammable gas. CEPA Toxic substances: This material is not listed. Canadian ARET: This material is not listed. Canadian NPRI: This material is not listed. Alberta Designated Substances: This material is not listed. Ontario Designated Substances: This material is not listed, Quebec Designated Substances: This material is not listed. I Section 16. Other information Canada Label requirements : Class A: Compressed gas . Class B-1: Flammable gas. Hazardous Material mtormati<>nSystem (U.S.A.) . ., 0 ealt Flammability ehys,cal hazarcis Date of Issue/Date of revision 4 3 : 10/1512014. Date of previous issue : 10/2/2014. Version :0.02 Powered by IHS 10/12 Hydrogen Section 16. Other information Caution; HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Prote tion Association fl1,S.A.1 Flammability Health 0\> Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 01997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 02001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 Systems to classify chemicals does so at their own risk. History Date of printing : 10/15/2014. Date of issue/Date of : 10/15/2014. revision Date of previous issue : 10/2/2014, Version 0.02 Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = lnternationarAir Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanollwater partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United NationsACGIH -American Conference of Governmental Industrial Hygienists AIHA--American Industrial Hygiene Association CAS - Chemical Abstract Services CEPA - Canadian Environmental Protection Act CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act (EPA) CFR - United States Cade of Federal Regulations CPR - Controlled Products Regulations DSL - Domestic Substances List GWP - Global Warming Potential IARC - international Agency for Research on Cancer ICAO - International Civil Aviation Organisation Inh - Inhalation LC - Lethal concentration LD - Lethal dosage NDSL - Non -Domestic Substances List N1OSH - National Institute for Occupational Safety and Health Date of issue/Date of revision : 1011512014. Date of previous issue - f 2/20/4. Version :0.02 11/12 Powered by IHS ,----•-___ ...._;. ______ -'-______ -"--___________________________ --... Hydrogen Section 16. Other information TOG -Canadian Transportation of Dangerous Goods Act and Regulations TLV -Threshold Limit Value TSCA -Toxic Substances Control Act WEEL -Workplace Environmental Exposure Level WHMIS -Canadian Workplace Hazardous Material Information System References Not available. · Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. , Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue/Date of revision : 10/1512014. Date of previous issue : 101212014. Version : 0.02 12112 Powered by IHS PASSIVE HYDROGEN INJECTION SYSTEM DIAGRAM 0 Cemex tndian Ira >445�E:t �viro ra Environmental Services Environmental Services PASSIVE HYDROGEN INJECTION SYSTEM DIAGRAM PROJECT Former Comex Ready Mix Plant - Indian Trail DEPTH TO WATER FROM PROJECT NUMBER 11.090021.00 TOP OF WELL CASING 6.52 feet WELL NUMBER MW-4D WATER LEVEL ELEVATION 636.65 feet MSL ELEVATION OF TOP OF WELL CASING 643.17 feet MSL WATER LEVEL MEASURED ON 02112f2015 HYDROGEN INSTALLED ON June 2015 - Proposed NOTE: DRAWING NOT TO SCALE GROUNDING STEEL WELL ROD VAULT 18.13' 18 13' 23.13' { 1 SUPPLY LINE SUPPORT CABLE TOP OF FILTER PACK TOP OF SCREEN HYDROGEN DIFFUSER BOTTOM OF WELL REGULATOR] PRESSURE GAUGE HYDROGEN CYLINDER ENVIROTRAC — 7343 W. FRIENDLY AVE., SUITE J I GREENSBORO. NC 1 PH: 336.763.6025 I FAX: 336.763.6034 I www.envirptrac.com