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HomeMy WebLinkAboutWI0100576_DEEMED FILES_20200219Permit Number WI0100576 Program Category Deemed Ground Water Permit Type Injection Deemed Tracer Well Primary Reviewer shristi.shrestha Coastal SWRule Permitted Flow Facility Facility Name Asheville Steam Electric Plant Location Address 46 Duke Energy Ln Arden Owner Owner Name Duke Energy Progress LLC Dates/Events NC Orig Issue 2/19/2020 App Received 2/18/2020 Regulated Activities Groundwater remediation Outfall Waterbody Name 28704 I' Draft Initiated Scheduled Issuance Public Notice Central Files: APS SWP 2/19/2020 Permit Tracking Slip Status Active Version 1.00 Project Type New Project Permit Classification Individual Permit Contact Affiliation Major/Minor Minor Region Asheville County Buncombe Facility Contact Affiliation Owner Type Non-Government Owner Affiliation Bryson Allison 526 S Chruch St Charlotte Issue 2/19/2020 Effective 2/19/2020 NC 28202 Expiration Requested /Received Events Streamlndex Number Current Class Subbasin synTerra 148 River Street, Suite 220 Greenville, South Carolina 29601 TRANSMITTAL (864) 421-9999 FAX (864) 421-9909 TO: Shristi Shrestha Cc: NCDEQ DWR UIC Program 1636 Mail Service Center RaIei_gh, NC 27669 DATE: FROM: PROJECT NAME: PROJECT NUMBER: 02/17/2020 Todd Plating Asheville Tracer Study 1026.102.51 El ENCLOSED 0 UNDER SEPARATE COVER DELIVERY METHOD ❑ US MAIL ® OVERNIGHT ❑ COURIER ❑ OTHER(Via Email) ITEMS ❑ ORIGINAL ❑ VENDOR ® PRINTS 0 SAMPLES ❑ SPECIFICATIONS ® ELECTRONIC FILES ❑ OTHER Item No. 1 Copies 1 Description 1 — Hardcopy Notification of intent Asheville Steam Electric Plant Tracer Study 1- Flash Drive - Same as above Action* FYU FYU *ACTION SCHEDULE: NET NO EXCEPTIONS TAKEN MCN MAKE CORRECTIONS NOTED R REJECTED FYU FOR YOUR USE RR REVISE AND RESUBMIT IFA IFC IFR IFI IFP BY: ISSUED FOR APPROVAL ISSUED FOR CONSTRUCTION ISSUED FOR REVIEW ISSUED FOR INFORMATION ISSUED FOR PERMITTING NC Department of Environmental Quality — Division of Water Resources (DWR) NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are `permitted by rule" and do not require an individual permit when constructed in accordance with the rules of 15-1 NC4C 02C .O. OO (NOTE: This form must be received at least 14 DAYS prior to injection) AQUIFER TEST WELLS r 1 aA NCAC 02C .022U1 These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION s 15A NC:AC 021:.cl22st or TRACER WELLS s 15A NCAC (12C .02291: 1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods (Note: injection Event Records (IER) do not need to be submitted for replacement of each sock used in ORC systems). 2) Small -Scale Injection Operations — Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall he required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility ofa remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells is located within an area that does not exceed five percent of the land swtace above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater. Print Clearly or Type Information. Illegible Submittals Wilt Be Returned as Incomplete: DATE: Febnian 14.2020 PERMIT NO. T. '`} C- (to be filled in by DWR) NOTE- If this NOI is being submitted as notification of a modification of a previously issued NOI for this site (e.g., different injection wells, plume, additives, etc.) and still meets the deemed permitted by rule criteria, provide the previously assigned permit tracking number and any needed relevant information to assess and approve injection: Permit No. WI issued Date: A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) Air Injection Well Complete sections B through F, d, M (2) Aquifer Test Well .Complete sections B through F, .1, M (3) Passive Injection System Complete sections B through F, H-M (4) Small -Scale Injection Operation Complete sections B through M (5) Pilot Test Complete sections B through M (6) Tracer Injection Well Complete sections B through M B. STATUS OF WELL OWNER: l3usine3s/COrganization vs 1st Deemed PermittedGW Remediation NOI Rev, 10-14-2019 Page 1 C. WELL OWNER(S) -State name of Business/ Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name(s): --=D~U=K=E--=E=N=E=R=G~Y~P~R~O~G=R=E=S~S~. =LL=C~-~B~R=Y=S~O~N~A=L=L=l=SO=N~---=E=N"'""G='IN'=-=E=ER=--- Mailing Address: --~52=6~S~O~U~T=H~C~H=U=R~C=H~S~T=RE=E=T~------------- City: CHARLOTTE State: NC Zip Code: 28202 County: MECKLENBURG Day Tele No.: 980-373-6636 Cell No.: 706-910-9638 EMAIL Address: b rv son.allison t duke-energv .com Fax No.: Not A pplicable D. PROPERTY OWNER(S) (if different than well owner/applicant) Name and Title: ANTONIO D. PRICE. PE -ASHEVILLE PLANT GENERAL MANAGER Company Name DUKE ENERGY PROG~R=E=S~S ~L=L~C~--------------- Mailing Address: ___ 4_6~D~U_K_E_E_NE~R~G~Y_L_A_NE __________________ _ City: ARDEN State: NC Zip Code: Day Tele No.: 828 650-0620 EMAIL Address: Antonio.Price@ duke-energ \ .com 28704 County: BUNCOMBE Cell No.: 919 696-2637 Fax No.: --"""'N'"'"/"'"A-=------ E. PROJECT CONT ACT (Typically Environmental Consulting/Engineering Firm) Name and Title: --~T~O=D~D~P=LA~T=IN~G~-~P~R:=O=JE~C~T~MA~-N~A~G=E=R~------------- Company Name --~S"""'YN~T_E_RRA~~C~O~RP~O_RA_T_I~O_N _________________ _ Mailing Address: -------=-14_,_,8'-'RIV:.=..:--=E=R.a....:c:;._ST=.c..::Se...::U"""I=T=E--=2=2-=--0 ------------------ City: GREENVILLE State: SC Day Tele No.: 864-421-9999 EMAIL Address: tplating@synterracorp.com F. PHYSICAL LOCATION OF WELL SITE Zip Code: 29601 County: GREENVILLE Cell No.: 864-420-8656 Fax No.: 864-421-9909 (I) Facility Name & Address: ASHEVILLE STEAM ELECTRIC PLANT 46DUKEENERGYLANE City: __ ..a...A=RD=.cE=N'-'-________ County: BUNCOMBE Zip Code: _28~7~0_4 __ _ (2) Geographic Coordinates: Latitude**: 35° 28' l0.37"or ___ 0 , _______ _ Longitude**: 82° 32' 34.79" or ___ 0 , _______ _ Reference Datum: PRIME MERIDIAN Accuracy: 0.01 ARC SECONDS Method of Collection: GOOGLE EARTH PRO **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume: ______ .square feet NOT APPLICABLE -Tracer Study Land surface area of inj. well network: _______ square feet~ 10,000 ft:2 for small-scale injections) Percent of contaminant plume area to be treated:, ____ (must be_::: 5% of plume for pilot test injections) H. INJECTION ZONE MAPS -Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and Deemed Permitted GW Remediation NOi Rev . 10-14-2019 Page2 (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES AT THE SITE -Provide a brief narrative regarding the cause of the contamination, and purpose, scope, goals of the proposed injection activity : A dye trace studv is pro posed to identi f\ the source of low pH water that has be gun to discharge into a see p. within the U pper East Channel. see attached Fi g ure. The U pp er East Channel is a storm water conve vance swale . lined with aggreirnte. It was desi uned and installed durin g the excavation and closure of the former ash basin. The water from the see p has similar characteristics as groundwater from the area of the former coal pile. Sixteen ounces ofred fluorescent Rhodamine WT d, e (Kin e scote Chemicals Brie.ht Dves® FWT Red 50 Li q uid) is pro posed to be infiltrated into the bedrock aquifer flow zone through existing monitorin g well CPA-4BR. which is located in the vicini ty of the former coal pile. Water guali tv at the see p location will then be monitored at the see p for the app earance of the dve to confirm or rule out a h vdraulic connection between the two areas. The elevation of the see p is a pp roximatel y 10 feet lower in elevation than the screened interval of well CPA- 4BR. J. WELL CONSTRUCTION DATA (1) No. of injection wells: 0 Proposed __ --=----'Existing (provide NC Well Construction Record (GW-1) for each well)-Existing Well CPA-4BR (2) Appx. injection depths (BLS): 31 to 41 feet below land surface (3) For Proposed wells or Existing wells not having GW-ls, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as-built): (a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery (b) Depth below land surface of casing, each grout type and depth, screen, and sand pack (c) Well contractor name and certification number K. INJECTION SUMMARY NOTE: Only in jectants approved by the epidemiology section of the NC Division o f Public Health. Department o f Health and Human Services can be in jected A pproved in iectants can be found online at h up ://deq .nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/e round-water-approved-in jectants . All other substances must be reviewed b y the DHHS prior to use. Contact the UJC Program for more in fo i f vou wish to get a pproval fo r a di fferent additive. However. please note it m ay take 3 months or longer. Deemed Permitted GW Remediation NOi Rev. 10-14-2019 Page 3 lnjectant~ Rhodamine WT ( FWT Red 50 ) Total Amt. to be injected (gal)/event~: ------"l -=-6 --=o=z _,_(O=·=l =2=-5 -"'g=al=)/-=-ev..:....e=n=t - Injectant.:...: ___________ Total Amt. to be injected (gal)/event~: _________ _ Amt. Water to be injected (gal/event): 5 oallons Total Amt. to be injected (gal/event): 5. 125 !!allons No. ofseparate injection events.:...: ----'='l __ Est. Total Amt. to be injected (gal): ____ ----'5:;.:•c:1=2=-5 _.g""'al:::.lo:::.;n:.:.:s'-- Source of Water (if applicable): Steam Plant Potable Water Su pp lv L. MONITORING PLAN -Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. Water discharg in g from the see p into the U pper East Channel will be monitored for the presence ofFWT Red 50 d ve usin g a geochemical sonde and data lo gger (C yclo ps -7F l. The fluorometer performance has a minimum detection limit ofO.0 I parts per billion to Rhodamine d ye. The e.eochemical sonde will be pro gr ammed to take a measurement once each dav . In addition to monitoring the seep. four bedrock monitoring wells will be samnled on a weekly basis to evaluate other potential flow paths from the in jection well and to provide an indication of the uroundwater flow veloci ~: • Wells CPA-5BR and CPA-6BR will be monitored to determine if flow from the in jection well CPA- 4BR is moving, to the west/southwest. • Wells CPA-3BR and GW-lBR will be monitored to determine if flow from the in jection well is movin g eastward from the in jection well. Monitoring of these wells will be b \ collecting a gra b sam p le with a bailer and checking the water column for fluorescence usin g field screenin g procedures. D epths to water in the four monitorin !! wells and the in jection well will also be measured each time the wells are sampled. The tracer dve test is estimated to be conducted over a 3-month period . dependin,z on the results of the field screening . Additional time mav be allocated, if deemed necessao -to better evaluate groundwater flow and discharge to the U pper East Channel. Over time, the concentration of d ye in the bedrock flow zone will decrease due to dis persion . and dilution within the a uifer. M. SIGNATURE OF APPLICANT AND PROPERTY OWNER Well Owner/A pp licant: "/ hereby certify, under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the I 5A NCAC 02C 0200 Rules. " Digitally signed by L Bryson S. L. Bryson s. Allison Allison Date: 2020.02.14 14:23:40 -05'00' L. B ry son Sheetz Allison, EHS Engineer Signature of Applicant Print or Type Full Name and Title Deemed Permitted GW Remediation NOi Rev . 10-14-2019 Page4 Propert. Owner Iif the proper!_ is not owned br the Well Owner/Araplicant1 "As owner of the properly on which the injection well(s) are to be constructed and vper-wed, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall he the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (l54 NCI(' 02C .U2OWW. "Owner' means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. J Antonio D. Price. PE General Plant Mana1er Signature" afTremertyOwner (if different from applicant) Print ar Type Full Name and Title 'An access agreement beN'een the applicant and property owner may be submitted in lieu ofa signature an this form. Please send 1 (one) Bard color copy of this NOI along with a copy on an attached CD or Flash Drive at least two (2) weeks prior to injection to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 707-9000 Deemed Permitted(iW' Rentediation N101 Rev. i0.14-20 9 Page 5 Attachments Site Map with Seep and Monitoring Well Locations GW-1 Form for Well CPA-4BR Technical Data Bulletin -FWT Red 50 Dye Safety Data Sheet -FWT Red 50 Dye Cyclops 7 Technical Data Sheet Deemed Permitted GW Remediation NOI Rev. 10-14-2019 Page 6 I /<‘,.._ DYES Division of Kingscote Chemicals 0 WATER TRACING DYE FWT RED PRODUCTS TECHNICAL DATA BULLETIN Bright Dyes FWT Red liquid products are specially formulated versions of Rhodarnine WT dye for convenient use in water tracing and leak detection studies. This bright, fluorescent red dye is certified by NSF International to ANSI/NSF Standard 60 for use in drinking water. It may be detected visually, by ultraviolet light and by appropriate fluoretnetric equipment. Today it is most often used visually. Visually the dye appears bright pink to red, depending on its concentration and under ultraviolet light as bright orange. The dye is resistant to absorption on most suspended matter in fresh and salt water. However, compared to Bright Dyes FLT Yellow/Green products it is significantly more resistant to degradation by sunlight and when used in fluoremetry, stands out much more clearly against background fluorescence. As always the suitability of these products for any specific application should be evaluated by a qualified hydrologist or other industry professional. General Properties Tablets Liquids (50) Powders Detestability of active ingredient l Visual <100 ppb Visual <100 ppb Visual <100 ppb Maximum absorbance wavelength 2 550/588 nm 550/588 nm 550/588 nun Appearance Dark red convex Clear dark red 1.6cm diameter aqueous solution Dark red fine powder NSF (Max use level in potable water) 0.3 ppb 0.4 ppb 0.1 ppb Weisht 1.35 gms ± 0.05 Dissolution Time } 50% < 3 minutes 95% < 6 minutes 50% <3 minutes 95% < 6 minutes Specific Gravity 1.03 + 0.05 c i. 25° C Viscosity 4 1.3 cps pH 8.7+0.5:a•25°C Coverage of Products One Tablet One Pint Liquid One Pound Powder Licht Visual 604 gallons _ 62,500 gallons 600,000 gallons Strong Visual 60 gallons , 6,250 gallons 60,700 gallons Caution: These products may cause irritation and/or staining if allowed to come in contact wit the skin. The use of gloves and goggles is recommended when handling this product, as with any other dye or chemical. To our best knowledge the information and recommendations contained herein arc accurate and reliable. However, this information and our recommendations are furnished without warranty, representation, inducement, or license of any kind, including but not limited to the implied warranties and fitness for a particular use or purpose. Customers are encouraged to conduct their own tests and to read the material safety data sheet carefully before using In dcionizcd water in 100 ml flask Actual detestability and coverage in the held will vary with spccsf'0c water conditions. No significant change in fluorescence between 6 and 11 pH. 3 (One tablet, I gram of powder), in flowing deionized water in a l0 gallon tank. 4 Measured on a Brookfield viscometer, model LV, UL adapter, 60 rpm @ 25° C. Kingscote Chemicals, 3334 S. Tech Blvd., Miamisburg, Ohio 45342 Telephone: (937) 886-9100 Fax: (937) 886-9300 Web: www.brightdyes.com Kingscote Safety Data Sheet CHEMICALS Issue Date: 09-Jan-2014 Revision Date: 18-Jan-2019 Version Number: 2.2 1. Identification Product Identifiers Product Name: Bright Dyese FWT Red SO Liquid Product Number: 106053 Recommended Use & Restrictions on Use Water tracing & leak detection dye Manufacturer /Su pp lier Kingscote Chemicals, Inc. 3334 South Tech Blvd . Miamisburg, OH 45342 U.S .A. Emergency Tele p hone Number Company Telephone Number: Emergency Telephone (24 hr): Classification (937) 886-9100 INFOTRAC (800) 535-5053 (North America) +1-352-323-3500 (International) 2. Hazards Identification This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product. 3. Composition/Information on Ingredients This product is not hazardous according to OSHA 29 CFR 1910.1200. Components not listed are not hazardous or are below reportable limits. First-Aid Measures Eye Contact Skin Contact Inhalation 4. First-Aid Measures Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists: Get medical advice/attention. Wash thoroughly with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Remove to fresh air. If breathing is difficult, administer oxygen; seek medical attention immediately. Page 1 of 6 Bri ght Dyes 19 FWY Red 50 Liquid Revision Date: 18-Jan-2019 Ingestion Rinse mouth. DO NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person. Get medical attention if large quantities were ingested or if nausea occurs. Most Im portant Symptoms and Effects Symptoms Will cause staining of the skin on contact. May cause eye irritation. Inhalation of dust may cause respiratory irritation. Ingestion may cause urine to be a red color until the dye has been washed through the system . Indication of An y Immediate Medical Attention and Special Treatment Needed Notes to Physician Treat symptomatically. 5. Fire-Fighting Measures Suitable Extin guishin g Media Water spray (fog). Carbon dioxide (CO2). Dry chemical. Regular foam. Unsuitable Extin guishing Media Not determined Specific Hazards Arisin g from the Chemical Product is not flammable. Burning/combustion may produce oxides of carbon and nitrogen (NOx). Protective Equi pment and Precautions for Firefighters Wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. Accidental Release Measures Personal Precautions . Protective Equi pment and Emergency Procedures Personal Precautions Use personal protective equipment as recommended in Section 8. Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12 and Section 13. Methods and Material for Containment and Cleanin g Up Methods for Containment Methods for Cleaning Up Precautions for Safe Handlin g Advice on Safe Handling Prevent further leakage or spillage if safe to do so . Sweep up and collect into suitable containers for disposal. Flush area with water. 7. Handling and Storage Handle in accordance with good industrial hygiene and safety practices . Use personal protection recommended in Section 8 . Avoid contact with skin, eyes, or clothing. Avoid breathing dusts. Contaminated clothing should be thoroughly washed before reusing. Page 2 of 6 Bright Dyes<!> FWT Red SO Liquid Revision Date: 18-Jan-2019 Conditions for Safe Stora ge, Including Incom patibilities Storage Conditions Keep container tightly closed and store in a cool, dry, and well- ventilated area. Keep from freezing. Incompatible Materials No materials to be especially mentioned 8. Exposure Controls/ Personal Protection Ex posure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. En gineerin g Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual Protection Measures, Such as Personal Protective Equi pment: Eye/Face Protection Skin & Body Protection Goggles. Rubber gloves . Suitable protective clothing. Respiratory Protection Hygiene Measures No protection is ordinarily required under normal conditions of use. Handle in accordance with good industrial hygiene and safety practices. 9. Physical and Chemical Properties Information on Basic Ph ysical and Chemical Pro perties Physical State Liquid Appearance Dark red liquid Color Dark red Property pH Melting/Freezing Point Boiling Point/Range Flash Point Evaporation Rate Flammability (solid, gas) Upper Flammability Limits Lower Flammability Limits Vapor Pressure Vapor Density Relative Density Specific Gravity Solubility Partition Coefficient Auto-ignition Temperature Decomposition Temperature Viscosity Values Not determined Not determined Not determined Not applicable Not applicable Liquid -not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not determined Highly soluble in water Not determined Not determined Not determined Not determined Page 3 of 6 Odor Odor Threshold Mild Not determined Bright Dy es~ FWT Red 50 Liquid 10. Stability and Reactivity Reactivit y Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibilit y of Hazardous Reactions None under normal processing. Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children. Incom patible Materials No materials to be especially mentioned Hazardous Decom position Products Oxides of carbon and nitrogen (NOx). 11: Toxicological Information Information on Like Routes of Ex osure Inhalation Ingestion Skin Contact Eye Contact Avoid breathing vapors or mists. Do not ingest. May cause an allergic skin reaction. Avoid contact with eyes. Dela yed , Immediate, and Chronic Effects from Short-and Lon g-Term Exposure May cause an allergic skin reaction. Numerical Measures of Toxicity Not determined Symptoms Associated with Ex posure See Section 4 of this SDS for symptoms. Carcinogenicit y NTP IARC OSHA None None None Page4of6 Revision Date: 18-Jan-2019 Bright Dyes • FWT Red 50 Liquid Revision Date: 18-Jan-2019 12. Ecological Information Ecotoxicit y This product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Com ponent Information Not available Persistence /Degradabili ty Not determined Bioaccumulation Not determined Mobility Not determined Other Adverse Effects Not determined Waste Dis posal Methods 13. Disposal Considerations Dispose of in accordance with federal, state, and local regulations. Contaminated Packa gin g Do not re-use empty containers. Dispose of containers in accordance with federal, state, and local regulations. 14. Transport Information Note See current shipping paper for most up-to-date shipping information, including exemptions and special circumstances. DOT IATA OMDG International Inventories TSCA U.S. Federal Re gulations CERCLA Not regulated Not regulated Not regulated 15: Regulatory Information Listed This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). Page 5 of 6 Bri ght Dyes• FWT Red 50 Liquid Revision Date: 18-Jan-2019 SARA 313 Section 313 of Title 111 of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 . CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). U.S. State Re gulations California Proposition 65 This product does not contain any Proposition 65 chemicals . U.S. State Right-to-Know This product does not contain any substances regulated under applicable state right-to-know regulations. HMIS Health Hazards 1 NFPA Health Hazards 1 Issue Date Revision Date Revision Note Disclaimer 16: Other Information Flammability 0 Flammability 0 09-Jan-2014 18-Jan-2019 Biennial Review Instability 0 Physical Hazards 0 Special Hazards Not determined Personal Protection B The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 6 of 6 CYGLDPS- GUOMERSIBLE SENSORS Cyclops-7F Submersible Sensors Cyclops-7F Sensors are high performance, compact submersible sensors designed for integration into any platform that provides power and datalogging. Available with multiple optical configurations, Cyclops-7F Sensors have a universal IIO for connection to parent systems. Recently updated to have a faster settling time, Cyclops-7F is ready to make measurements 1 second after power up. eZD rip IA) 7F Configured with DataBank Handheld Datalogger for field sampling Easily integrates with Submersible Loggers for in situ sampling Cyclops Logger sold by PME Trlmeter sold by Eureka Water Probes Configured with Ayyeka Wavelet for remote monitoring Reliable Instruments for an Unreliable World Cyclops-7F Highlights • Small and available in multiple housing/connector configurations • Built-in light scatter rejection - Low power consumption • Easily integrates into any third -party platform • Interfaces with DataBank Handheld Datalogger • Submersible Loggers Available • Explorer enables various lab applications Available Sensors • Blue Green Algae - Phycoerythrin (marine) - Phycocyanin (freshwater) • CDOM/FDOM • Chlorophyll in vivo - Blue excitation - Red excitation (high CDOM) • Fluorescent Dye Tracing - Fluorescein - PTSA - Rhodamine • Hydrocarbons - Crude Oil - Refined Fuels • Turbidity • Wastewater Monitoring - Optical Brighteners - Tryptopha n Custom Optics Available : 260-900 nm SUBMERSIBLE SENSORS Linearity: 0.99R2 1 Length x Diameter: 5.7"x0.9"; 14.48x 2.23cm (55torTi) 5.7" x 1.25 , 14.48 x 3.18 cm (Delrin) Weight: 5.0 oz; 142 grams CDOM/FDOM 0.1 ppb* 0-1,500 pph" 240 0.5 ppb*" 0-3,000 ppb" Chlorophyll in vivo Temperature Range: Blue excitation 0.03 pg/L 0-500 +JgIL 240 Ambient: 0 to 50 deg C Red excitation 0.3 }ig/L 0-500 µg/L 240 Water Temp : -2 to 50 deg C Fluorescein Dye 0.01 ppb 0-500 ppb 145 Depth Range: 600 meters Oil - Crude 0.2 ppb'* 0-1,500 ppb" 250 Oil - Fine 0.4 ppm`" 0-20 ppm**" 530 Signal Output: 0 - 5 VDC Optical Brighteners 0.6 ppb" 0-2,500 ppb" 200 Phycocyanin 2 ppb 0-4,500 ppL1' 160 Supply Voltage Range: 3 - 15 VDC Phycoerythrin 0.1 ppbil 0-750 ppb 270 PTSA Dye 0.1 ppb'** 0-650 ppb" 320 Rhodamine Dye 0.01 ppb 0-1,000 ppb 175 Tryptophan 3 ppb 0-5,000 ppb 540 Turbidity 0.05 NTU 0-1,500 NTIJ 120 • Quinine Sulfate ..PTSA (1,3, 6, 8 - Pyrenetetiasulfonic Acid Tetraaodium Salt) •• BTEX (8enzene.Toluene, Ethylbenzene, Xylenes) PC Phycacyanin pigment from Proryme diluted in Deranized water PE Phycoerythrin pigment from Prozyme diluted in ❑eionized water Ordering Information Stainless Steel, Titanium and Plastic Housings available. Titanium and Plastic withstand corrosion better than stainless steel and are recommended far stationary deployments in highly corrosive environments. ACCESSORIES Solid Secondary Standards Flowthrough Cap Shade Cap (Recommended for most deployments} 0.6 Meter Pigtail Cable with Locking Sleeve 5 Meter Pigtail Cable with Locking Sleeve 10 Meter Pigtail Cable with Lacking Sleeve 25 Meter Pigtail Cable with Locking Sleeve Explorer Contact Us Toll -Free : 1,877,316.8049 Email : sales@turnerdesigns.com Address: Phone : 408.749.0994 Web : www.turnerdesigns.com 1995 N. 1st Street Fax : 408.749.0998 San Jose, CA 95112 Reliable Instruments for an Unreliable World 5-0209 Rev. F WELL CONSTRUCTION RECORD This form tell he iced For sirglc or midisple wills 1. Wen Contractor Information: NICHOLAS HAYES Weil Camrarter Name A - 4121 NC Waif Contractor Corti Station Number GEOLOGIC EXPLORATION, INC Company Name { Fos Ileum I Use ONLY L 14. WATER ZONES FROM TO DEtc:RIFfl0N rL rt. n. n, Is, OUT&R CASING • for mold-coard wellsr OR LINER Of an Scalds} FROM 0.0 r. TO 23.0 h. DIAMETER I Tutc.sTem ' MATERIEL 6.0 In. SCH 40 PVC 16. INNER CASING OR TUBING {xeofherm°I closed -loop FROM TO DIAMETER THICKNESS I MATERIAL 2, Well Construction Permit d: _ lr� rt• 1.r..I 011 cp pliruhl' i elt ilrrtsrrnerooir prrrirrir p c- t imun; Skate. Variance, Or.)s.f 3. Well Use (cheek well usey: Water Supply Well: °Agricultural °Geothermal (Heating/Cooling Supply) ° i ndoslriallConimercial ❑Ir!IL':1Ron Non -Witter Supply Wein QiMtmitltreng ❑ Municipal/Public o Residential Water Supply (single) °Residential Water Supply (share►►► °Recovery injection Welt: °Aquifer Recharge °Aquifer Storage and Recovery ❑Aquifer Test ❑Experimental Technology ❑Geothermal (Closed Loop) °Geothermal tHeatin iCuohnj Return o Groundwater Remcdiatiun °Satinily Barrier flStorrnwriter Drainage ❑Subsidence Control °Tracer } °other texiiIain under 02 E Remarks} 4. dose Wang) Completed: 12/20/18 Well KWCPA-4HR Su, Well Locution: ASHEVILLE STEAM STATION FacilityTOwner Name Facility IDi/ (ifapptimbic) 200 C P & L DRIVE ARDEN 28704 Physical Address City. and Lip BUNCOMBE Calmly nano Idei i1I Am Na. IPIN) ib. Latitude and Longitude in degrees/minutes/seconds ordeeiraal degrees: (if welt rain. one aslll°nt is soffit 'ern) 35" 28' 10.37" N 82° 32' 34.79" 6. is tare) the steins): 1 Permanent or °Temporary W 7, Is this a repair to an existing well: ❑Yes or RIND 1f this is a rty+urr, fill OW krrnlrir u'rll cnnrtrrrrllrnr ietfrrrm°tmu and rtpinkr rFe• rmtrrre ra !hr rviwir tnnkr c;1 milrur!° .rer64711 nr rota the hark °f bile frame. 8. N tuiber of wells constructed: 1 Par ausftlplr irlfl'rrktrr fir Ieliir-n'WCr.4'npplj' i e1Lr Trn1. r ))tide the X.MR1r reitls:faction, }tore ran .5rr%Irnit nfrc' firmer. 9. Total well depth below land surruce: 41'0 ;ft,) Far melt) plv n'rllF IL-i all depdir if'dif eroa (rsrerple- 31921X1'eaent IQf irr1 10. Static water level below lop of casing: 8.0 (IN If ti'oI rkir! rs.thole ewirrn roc 11, Borehole diameter: 6.0/10.0 6[1.1 12. Well construction method: AIR (i. e. Niger, rotary, cable, direct push. etc 1 FOR WATER SUPPLY WELLS ONLY: 13u. Yield (gpm) hletlsud of test: lib. Disinfection type: )Amount: ft. 31.0 n. rt. 2.0 in la. SCH 40 PVC 17. SCREEN FROM TO 31,0It 41.0 n. fL rt. [&, GRQUT FROM To DIAMETER 2.0 L! to SLOT SIZE 010 IICKNE9S 1 MATERIAL SCH 40 PVC - I MATERIAL F.MPLICEM ENT METHOD LAMo(JNr 0.0 R. 0.0 N. 21.0 rr. 23.0 rr. INIA11.440.1 rrnnrrE caendrmawr°wR[ SLURRY SLURRY D. rl. 19, SAND/GRAVEL PACE 1[rapi.licablel FROM TO MATERIAL 29.0 II. 41.0 n. 20-40 RaMPIACCMENT M1[Erl10D FINE SILICA SAND ft. R. 3Q, PRILLJNG LOG !°Har1r addirresial sneers r1 aw nL, 7I (RCH1 TO 0.0 n, 5.0 5.0 h. 1 T.0 It' HISf. RID ttutr +[vier. Lerrdeea milrrrrrli r. g.- gain sla., .ir., AIR KNIFE PWR 17.0 ft. 41.0 n. ROCK fr. R. fr. R. ft. rt. fi. D. 21. RERIARKS _-.8'ENTONITE SEAL FROM 21.0 TO 29,0 FEET re'U-PACK SCREEN"' 22. Certifirotton: S ignainre o f Cent i lied Well Contractor 01/09/19 Dam th'.siXRing ohs freer, 1 hereby rxn+i• Hrnr the u•all(af nw.s (nrrc) veat.vrut•rrtl :wen/awe with )3r1 MCA(' Olt- .iJlGfi err 15e1 NOW WI'.v2rin Well Curporecoem tirrordorlfr foal clue ei ropy uiUrlr record hat Mewl providedm if tne11 'ovate. 73. Site diagram or additional well details: You may use the bad: of this page to provide additional well site details or well construction details- You may also attach additional pages if necessary. SIJBM ITTAL I Nei UCT EONS 24a, Fur All W.1 : Submit this form within 30 days of completion ul' well construction to the following; Division of Water Quality, infornrutiun Processing Unit, 1617 Mail Service Center, Raleigh, NC I7699-1617 24b. Fur Infection Wefts: In addition to sending the form to the address in 2aa above, also submit a copy of this larM W111145 30 days of completion of well construction to the fallowing: Division of Water Quality, Underground Injection Control Program, 1636 Moil Service Center, Raleigh, NC 27699.1636 24c. E r ►V to Su pule .Ft Infection ►Vella: tit udtf Ilion to sending the Perm to the oddress(es) above, also submit one copy of this form within 30 days vl' completion or well construction to the county health department of the county Where constructed. Noah Carolina Depannieur or Environment and Natural Resources - Division of Water Quehry Revised.1wi. 2UT"+ PROJECT: Asheville Stearn Plant PROJECT NO: 1026.102 WELL 1 BORING NO: CPA-4BR STARTED: 11/27/18 COMPLETED: 12/20/18 NORTHING: FASTING- G.S. ELEV: ft MSL M.P. ELEV: ft MSL DEPTH TO WATER: 16.60 tl TOC TOTAL DEPTH: 41.0 ft BGS LOGGED BY: G. Barrier CHECKED BY: 7. Plating DRILLING COMPANY: Geologic Exploration DRILLING METHOD: HSA/Air Rotary BOREHOLE DIAMETER: 10 and 6 IN NOTES: LJ g 0 x ❑ , 0 DESCRIPTION SAMPLE O ^ U co Z Q U WELL ❑ E n CONSTRUCTION �J -Prakedive rli Ali mn inr :. SILT, sandy -fine to medium, tan, PWR `ti. 3 r 4 '.. .r • I. 1P , /\ . ` covering -Neat cement grout - 6" sch 40 PVC surface casing -2" sch 40 PVC riser i -Bentoniteseal - Fitter pack (#2 silica - 2" pre -packed well screen) .. SILT, sandy -fine to medium. tan/white/ tdack, foliation, PWR 15 • SILT, sandy -fine to medium, tan/white/ black, more defined foillation, PWR 20 25 30 40 4 L � dp f ■ ko Rom\ BEDROCK' fractures at 25', 31', 33'. 35', and 41' ^. �. 45 - 0 CLIENT: Duke Energy Progress, LLC. SynTerra PROJECT LOCATION: Arden, NC 148 River Street, Suite 220 synTe� Greenville, South Carolina 29601 Phone: 8fi4 42]-9099 PAGE 1 OF 1 CC R-1 OOBR 2152.29 N WY' :3- CCR-105BR 2061.89 Le, hicaz WATER BEARING FRACTURE STRIKE EAST AND WEST CF FRENCH BROAD RIVER (N430). 111 jet a Injectant Well CPA-04BR 2154.69 ti , CPA-05BR l C 2133-67 1 tryRPM, y CPA-03BR 2147.99 DUKE Nle' ENERGY synTerra Upper East Channel Seepage Monitoring Location CB-01 BR 2160.36 GRAPHIC S - 180 IIN FEET, DRAWN EY: B. YOUNG REVISED BY: J. LEE CHECKED ELT; G. SAARIER APPROVED at G. DANDIER PROJECT MANAGER: G. BARRIER DATE 05/18/2G19 DATE 0246/2020 647E 02/OB/202C DATE 02/06/2020 W W W.9 r nferra cor !.COIn LEGEND 2160.361 GROUNDWATER ELEVATION S MONITORING WELL IN BEDROCK -- WATER LEVEL IN BEDROCK ZONE (NAD83. FEET) GROUNDWATER FLOW DIRECTION DUKE ENERGY PROGRESS ASHEVILLE PLANT SITE BOUNDARY STREAM (TWT 2016) WETIAND [TWIT 2015) NOTES: 1. WATER LEVELS GAUGED DURING JANUARY 2026. 2. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PREFFERE I g 207'01 2 THE STREAMS AND WETLANDS JURISDICTIONAL DETERMINATION WAS PERFORMED BY TM' AND ASSEGNED USACE NSAW,2014-00189. THESE WETLANDS AND STREAMS WERE APPROVED BY THE US ARMY CORPS OF ENGINEERS (US ACE) ON MAY 16.2018.- 4. AERIAL PHOTOGRAPHY COURTESY OF NCONEMAP IMAGE SERVER, DATE OF PHOTOGRAPHY 111r2019 5 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLJNA STATE PLANE COORDINATE SYSTEM FPS 3200 (NAD83}. WATER LEVEL MAP BEDROCK FLOW ZONE ASHEVILLE STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC ARDEN, NORTH CAROLINA E S 0