Loading...
HomeMy WebLinkAboutNC0020338_Wasteload Allocation_19940103NPDES DOCUHENT SCANNING COVER SHEET NC0020338 Yadkinville WWTP NPDES Permit: Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Speculative Limits Correspondence Instream Assessment (67B) Environmental Assessment (EA) Permit History Document Date: January 3, 1994 This document is printed on reuse paper - ignore any content cm the reverse side NPDES WASTE LOAD ALLOCATION PERMIT NO.: NC0020338 PERMITTEE NAME: Town of Yadkinville FACILITY NAME: Yadkinville WWTP Facility Status: Existing Permit Status: Renewal Major Pipe No.: 001 Minor Design Capacity: 1.0 MGD Domestic (% of Flow): 66 % Industrial (% of Flow): 34 % Comments: Completion of Std. Form A requested receipt . re9ves4e,/ ^e.(eca.x w - '1-11e€k 4�." .,e . —)4) - SIU info to be provided upon /92o err S'- -e de,.-.-e Y cif i s Ueite3-Le e'�/f` j RECEIVING STREAM: North Deep Creek J Class: Cm ') c/ as GU5-11/ /0/9s— /1Ml Sub -Basin: 03-07-02 Reference USGS Quad: C16NW County: Yadkin Regional Office: Winston-Salem Regional Office (please attach) Previous Exp. Date: 5/31/94 Treatment Plant Class: Classification changes within three miles: none Requested by: Gre Nizich�5� i Prepared by: Reviewed by: 1ft C. ou 'Bot / 3 CS) / Cop) 04CL -IA-- Date: Class II 10/13/93 Date: / 6c�% Date: /•(3D/S'3 3! 19 Modeler Date Rec. # C iS tO1 t3l k13 linZ3 Drainage Area (mil ) Avg. Streamflow (cfs): 39.0 7Q10 (cfs) 3, 9 Winter 7Q10 (cfs) 16.6 30Q2 (cfs) /4. 6 Toxicity Limits: IWC fib % Acute hronic /F / , c_er oda-Pt-^��- Parameters .60 %2YYt.p,` PCCJ �p(44vfl4, 0)14d°4;0 Instream Monitoring: Upstream V/ Downstream y Location ( de » vv y (J5 yQ r Location A.loa ve Comeau 0.1 fkoJEr a� 1 ShAe <1 uk1 ►'* Corn Wasteflow (MGD): BODS (mg/1): NH3N (mg/1): DO (mg/1): TSS (mg/1): Fecal Col. (/100 ml): pH (SU): Residual Chlorine (14/1): Oil & Grease (mg/1): TP (mg/1): TN (mg/1): Selenium (ug/1): Cadmium (ug/1): Chromium (ug/1): Copper (ug/1): Nickel (ug/1): Lead (ug/1): Zinc (ug/1): Cyanide (ug/1): Fluoride (mg/1): Mercury (ugfl): Silver (ug/1): Arsenic (ug/l): Aluminum (ug/1): Monthly Average Summer Winter 1.0 30 16 5 30 200 6-9 monitor 30 monitor monitor 1.0 30 monitor 5 30 200 6-9 monitor 30 monitor monitor Daily Max. 18 7.0 175 monitor 309 88 monitor 18 6.3 0.042 monitor monitor monitor ter Facility Name: NPDES No.: Type of Waste: Facility Status: Permit Status: Receiving Stream: Stream Classification: Subbasin: County: Regional Office: Requestor: Date of Request: Topo Quad: RECEIVED N.C. Dept. of EHNI DEC 20 1993 FACT SHEET FOR WASTELOAD ALLOCATION Winston-Salem Request # 7623 Rey ion; l Off ice Town of Yadkinville NC0020338 66% Domestic / 34% Industrial Existing Renewal North Deep Creek C 030702 Yadkin WSRO Greg Nizich 10/13/93 C 16NW Stream Characteristic: USGS # Date: Drainage Area (mi2): Summer 7Q10 (cfs): Winter 7Q10 (cfs): Average Flow (cfs): 30Q2 (cfs): IWC (%): 2.1156.1001 1990 35.9 3.9 10 39 14 28 Wasteload Allocation Summary (approach taken, correspondence with region, EPA, etc.) Facility will receive existing limits for relocation. New limits will be given for some metals Relocation was completed in July, 1992. Special Schedule Requirements and additional comments from Reviewers: Recommended by: Oa& atfide,v2e_o_ Reviewed by / f Instream Assessment: Date: kD //,-3/6-1k=s' Regional Supervisor: , Date: Permits & Engineering: ( �/ , Date: RETURN TO TECHNICAL SERVICES BY: tg94 Date: //i3/53 2 CONVENTIONAL PARAMETERS Existin Limits: (at relocation to North a Deep Creek) Monthly Average Summer Winter Wastefll w (MGD): 1.0 1.0 BOD5 (g/1): 30 30 NH3N mg/1): 16 monitor DO (mg/1): 5 5 TSS (mg/1): 30 30 Fecal Col. (/100 ml): 200 200 pH (SU): 6-9 6-9 Residual Chlorine (µg/1): monitor monitor Oil & Gease (mg/1): 30 30 TP (mg/»: monitor monitor TN (mg/1): monitor monitor m n� Li Monthly Average Summer Winter WQ or EL Wasteflow (MGD): 1.0 1.0 BOD5 (Mg/1): 30 30 NH3N (tng/1): 16 monitor DO (mg/1): 5 5 TSS (mg/1): 30 30 Fecal Cdl. (/100 ml): 200 200 pH (SO: 6-9 6-9 Residual Chlorine (14/1): monitor monitor Oil & G4ease (mg/1): 30 30 TP (mg/1): monitor monitor TN (mg/1): monitor monitor Limits changes Due To; parameter(s) Affected Change 7Q10 data Change in stream classification Relocation of discharge Change in wasteflow Other (onsite toxicity study, interaction, etc.) Instream data New reg ationslstandards/procedures New facility information (explana 'on of any modifications to past modeling analysis including new flows, rates, field data, interacting discharges) (See page 4 for miscellaneous and special conditions, if applicable) 3 Type of Toxicity Test: Existing Limit: Recommended Limit: Monitoring Schedule: TOXICS/METALS Chronic P/F 28% 28% Jan,Apr,Jul,Oct Existing Limits (at relocation Selenium (ug/1): Cadmium (ug/1): Chromium (ug/l): Copper (%g/1): Nickel (ug/1): Lead (ug/,1): Zinc (ug/1): Cyanide (ug/1): Fluoride (mg/1): Mercury (ug/1): Silver (ug/1): Arsenic (ug/1): Alumin u: Recommended Limits Selenium (ug/1): Cadmi (ug/1): Chromiu (ug/1): Copper (Iiig/1): Nickel (ugfl): Lead (ug/1): Zinc (ug//): Cyanide (ug/1): Fluoride (mg/1): Mercury (ug/1): Silver (u ' ): Arsenic ( g/1): Alumin (ug/1): to Norths Deep Creek) Daily Max. monitor 7.0 175 monitor 309 88 monitor 18 1.8 monitor monitor monitor monitor Daily Max. 18 7.0 175 monitor 309 88 monitor 18 6.3 0.042 monitor monitor monitor WQ or EL WQ WQ WQ WQ WQ WQ WQ WQ Limits Ganges Due To., Parameter(s) Affected Change ui 7Q10 data Change stream classification Relocatio of discharge Change ' wasteflow New pre tment information Failing to 'city test Other (onsite toxicity study, interaction, etc.) X Se, Hg, Fl - DMR data Parmeter(s) are water quality limited. For some parameters, the available load capacity of the immediate receiving water will be consumed. This may affect future water quality based effluent limitations for additional dischargers within this portion of the watershed. 4- INSTREAM MONITORING REQUIREMENTS Ups - • u Location: AT old US HWY 421 Downs I am Location: 1) above confluence w/ Haw Br and 2) AT Shacktown Road Bridge Parameters: DO, Temp., Fecal Coliform, and Conductivity Special thstream monitoring locations or monitoring frequencies: MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS Adequacy of Existing Treatment Has the facility de onstrated the ability to meet the proposed new limits with existing treatment facilities? Yes No 1%il no, which parameters cannot be met? ould a "phasing in" of the new limits be appropriate? Yes No If yes, please provide a schedule (and basis for that schedule) with the regional office recommendations: If no, why not? Special Instructions or Conditions Wasteload sent to EPA? (Major) (Y or N) (If yes, then attach schematic, toxics spreadsheet, copy of model, or, if not modeled, then old assumptions that were made, and description of iqw it fits into basinwide plan) Addition Information attached? (Y ofr N)J If yes, explain with attachments. Facility Name )hciX 11 Viko Permit # , DY 11 Pipe # a4 CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in: 1.) The North Carolina Ceriodaphnia chronic effluent bioassay procedure (North Carolina Chronic Bioassay Procedure - Revi *September 1989) or subsequent versions. The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is c98 % (defined.a's treatment two in the North Carolina procedure document). The permit holder shall perform Quarterly monitoring using this procedure to establish compliance with the permit condition. The first test will be performed after thirty days from the effective date of this permit during the months of - a-r, � j u 1, () t - . Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be co plete and accurate and include all supporting chemical/physical measurements performed in association with the xicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be me ured and reported if chlorine is employed for disinfection of the waste stream. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediatelyuntil such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should anytest data m this monitoringrequirement or tests performed bythe North Carolina Division of Environmntal Mana ement indicate potential impacts to the receiving stream, , this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. 7Q10 �. Permitted Flow b 1WC a$ij cfs 0 MGD Basin & Sub -basin Receiving S e�lm County)/aLLKTh 3v7 O a opt* Deep C'r-et Recommended by: 24-Adaaif Date 1 aI,(31i3 QCL P/F Version 9/91 Pollutant 12/13/93 ver 3.1 1 Facility: NPDES Permit No.: Status (E, P, or M) : Permitted Flow: Actual Average Flow: Subbasin: Receiving Stream: Stream Classification: 7Q10: IWC: Stn'd / Bkg AL Conc. (ug/1) (ug/1) Cadmium Chromium Copper Nickel Lead Zinc Cyanide Mercury Silver Selenium Arsenic Phenols NH3-N 2.0 50.0 7.0 88.0 25.0 50.0 5.0 0.012 0.06 5.00 50.00 NA T.R.Chlor.AL 17.0 Pollutant Cadmium Chromium Copper Nickel Lead Zinc Cyanide Mercury Silver Selenium Arsenic Phenols NH3-N T.R.Chlor.AL Town of Yadkinville NC0020338 E 1.0 mgd 0.6 mgd '030702 North Deep Creek C 3.9 cfs 28.44 % Removal Domestic Allowable Load ( /d) 0.17 6.95 0. 4. 1. 66 65 74 4.71 0.40 0.00 0.00 0.13 1. 32 Eff. 69% 81% 72% 50% 62% 72% 67% 0% 0% 0% 0% 0% 0% 0% ALLOWABLE Effluent Conc. CHRONIC Criteria (ug/1) TOXICS REVIEW WWTP I ---------PRETREATMENT DATA I----EFLLUENT DATA---- 1 ACTUAL PERMITTED' I Ind. + Ind. + 1 FREQUENCY I Domestic PERMITTED Domestic 1 OBSERVED of Chronic Act.Ind. Total Industrial Total 1 Eflluent Criteria Load Load Load Load Load I Conc. Violations (#/d) (#/d) (#/d) (t/d) (#/d) 1 (ug/1) (#vio/#sam) 0.0 0.0 0.02 0.0 0.050 1 2.2 ' 0.0 0.1 0.08 0.8 0.774 1 12.4 0.0 0.5 0.54 1.1 1.100 1 38.0 0.0 0.0 0.07 0.3 0.287 1 46.0 0.0 0.1 0.05 0.6 0.555 I 7.6 0.2 0.9 1.10 2.1 2.333 I 281.0 0.0 0.0 0.02 0.3 0.279 1 5.1 0.2 1 0.3 7.8 I 5.0 I 4.0 () PRDCT'D PRDCT'D PRDCT'D MONITOR/LIMIT I--ADTN'L Effluent Effluent Instream using using Conc. Based on Based on Based on ACTUAL PERMIT using ACTUAL PERMITTED OBSERVED Influent Influent OBSERVED Influent Influent Effluent (ug/1) (ug/1) (ug/1) Loading Loading Data 7.032 175.806 24.613 309.419 87.903 175.806 17.581 0.042 0.211 17.581 175.806 0.000 0.000 59.774 I N P U T S E C T I 0 N RECMMDTN'S-- Recomm'd FREQUENCY INSTREAM Eff. Mon. Monitor. based on Recomm'd ? OBSERVED (YES/NO) 1.218 2.897 0.63 Limit Limit Limit 1 NCAC 2.841 27.363 3.53 Monitor Limit Monitopf NCAC 28.199 57.362 10.81 Monitor Monitor Monitor 1 Weekly 6.889 26.718 13.08 Monitor Monitor Limit 1 NCAC 3.877 39.253 2.17 Monitor Limit Monitor 1 NCAC 57.451 121.627 79.92 Monitor Monitor Monitor 1 Weekly 1.344 17.166 1.45 Monitor Limit Limit 1 NCAC 0.000 0.000 0.07 Limit 1 NCAC 0.000 0.000 2.20 Monitor 1 Weekly 0.000 0.000 1.42 Limit 1 NCAC 0.000 0.000 1.14 Monitor 1 NCAC NO 0.000 0.000 0.00 0.00 0.00 NO NO YES NO NO YES NO YES YES NO A N A L Y S I S R E S U L T S iity/ytqiume, Lkki,6cuot_t lit a71 Do+ C6rp inA5ty), .6% frt-042 (ct, mp-te 6'mt tott ,paza,(:4y or-ixi- ov, 000 pot � rz-�✓s� 12/13/93 ver 3.1 T OXICS REVIEW Pollutant Facility: NPDES Permit No.: Status (E, P, or M) : Permitted Flow: Actual Average Flow: Subbasin: Receiving Stream: Stream Classification: 7Q10: IWC: Stn'd / Bkg AL Conc. (ug/1) (ug/1) Cadmium S 2.0 Chromium S 50.0 Copper AL 7.0 Nickel S 88.0 Lead S 25.0 Zinc AL 50.0 Cyanide S 5.0 Mercury S 0.012 Silver AL 0.06 Selenium S 5.00 Arsenic 5 50.00 Phenols S NA NH3-N C T.R.Chlor.AL 17.0 Pollutant Cadmium Chromium Copper Nickel Lead Zinc Cyanide Mercury Silver Selenium Arsenic Phenols NH3-N C T.R.Chlor.AL S S AL S S AL 5 5 AL S S S Allowable Load (4/d) 0.17 6.95 0.66 4.65 1.74 4.71 0.40 0.00 0.00 0.13 1.32 Town of Yadkinville WWTP NC0O20338 E 1.0 mgd 0.6 mgd '030702 North Deep Creek C 3.9 cfs 28.44 % Removal Domestic Eff. Load 69% 81% 72% 50% 62% 72% 67% 0% 0% 0% 0% 0% 0% 0% PRETREATMENT DATA ACTUAL PERMITTEDI Ind. + Ind. + 1 Domestic PERMITTED Domestic 1 OBSERVED Act.Ind. Total Industrial Total 1 Eflluent Load Load Load Load 1 Conc. (#/d) (#/d) (#/d) (#/d) (#/d) 1 (ug/1) 0.0 0.0 0.02 0.0 0 050 0.0 0.1 0.08 0.8 0.774 0.0 0.5 0.54 1.1 1.100 0.0 0.0 0.07 0.3 0.287 0.0 0.1 0.05 0.6 0.555 0.2 0.9 1.10 2.1 2.333 0.0 0.0 0.02 0.3 0.279 0.000 ALLOWABLE PRDCT'D PRDCT'D PRDCT'D Effluent Effluent Effluent Instream Conc. using using Conc. CHRONIC ACTUAL PERMIT using Criteria Influent Influent OBSERVED MONITOR/LIMIT 11.0 34.0 50.0 100.0 19.0 890.0 18.0 0.5 3.0 5.7 5.0 Based on Based on Based on ACTUAL PERMITTED OBSERVED Influent Influent Effluent (ug/1) (ug/1) (ug/1) (ug/1) Loading Loading Data 7.032 175.806 24.613 309.419 87.903 175.806 17.581 0.042 0.211 17.581 175.806 0.000 0.000 59.774 1.218 2.841 28.199 6.889 3.877 57.451 1.344 0.000 0.000 0.000 0.000 0.000 2.897 27.363 57.362 26.718 39.253 121.627 17.166 0.000 0.000 0.000 0.000 0.000 3.13 9.67 14.22 28.44 5.40 253.12 5.12 0.14 0.85 1.62 1.42 0.00 0.00 0.00 Limit Monitor Monitor Monitor Monitor Monitor Monitor Limit Limit Monitor Monitor Limit Monitor Limit Limit Limit Monitor Limit Limit Monitor Limit Limit Monitor Limit Monitor I ---EFLLUENT DATA ---- FREQUENCY of Chronic Criteria U\ Violations 1 C� \r� � 1 (#vio/#sam)1 6 1 / '1 7 I I N 1U U I T 5 E C T I 0 N I--ADTN'L RECMMDTN'S-- I Recomm'd I FREQUENCY INSTREAM I Eff. Mon. Monitor. based on Recomm'd ? OBSERVED (YES/NO) NCAC YES NCAC NO Weekly YES NCAC NO NCAC NO Weekly YES NCAC YES NCAC YES Weekly YES NCAC NO NCAC NO A N A L Y S I S R E S U L T S Yadkinville WWTP NC0020338 1 mgd 03.90 7Q10 Parameter Arsenic Cadmium Chromium Copper Cyanide Lead Mercury Nickel Selenium Silver Zinc Benzene Toluene Ethylbenzene Fluoride Standard mon 50.0 2.0 50.0 7.0 5.0 25.0 0.012 88.0 5.0 0.1 50.0 71.4 11 325 1800 Allowable nfi 176.05 7.04 176.05 24.65 17.61 88.03 0.04 309.85 17.61 0.21 176.05 251.40 38.73 1144.33 6337.82 r`v)tlj) kituf 0-4141-b 131d .i pitt;,-I- L' 01/4€0 Yadkinville WWTP NC0020338 1 mgd Q 39.00 7 l Parameter Standard Allowable mil KO Arsenic 50.0 10.50 Cadmium 2.0 52.42 Chromium 50.0 1 Copper 7.0 1 Cyanide 5.0 13 . 5 Lead 25.0 65 .25 Mercury 0.012 0 1 Nickel 88.0 2 ' • . 9 Selenium 5.0 41.0 Silver 0.1 1.57 Zinc 50.0 310.50 Benzene 71.4 1871.p Toluene 11 2 .31 Ethylbenzene 325 1 28 fa /0-q3 1 n o-i )c!')( rwii 640 / inG--19 L%rth /) ep Creel( fr z5.°1 YID- 2 (A=,3•oc-cs riodbui= lock vsi\ 4,k btc.,,*; 1).Aids: 10044u) D 1, IF 00 470 3-6 tiH5 jIli � I ccL (c)a.3 -7 pb C9� u a� Y `� OK @,0.,_1) CN Cud <, Mi" 40 0) 9 .4nalin .3t: 1- 't tt u ric 0 m-rt 010 vs Ua 4c max- S # 7146 Q .0 % ' c<,l f t! IL v� eccdi ara q/L=1.6, yk.- /,"� (-, p thitM v ,Surnritvi ‘jt(-)ast'Vl 1 A ) 6/7cD 4665- (myyi) 3 b d Cyncv) d -6/6-koW ago doJ n0 -±1r.attG (0A4) ntIa,-(D CoZnitivat. (/) 7 p vti'unt. Luy71) 1 75 e ciu;t;LQ /cKp.SC Lr?u.cL ( ) gg Woo) v ( 4) 0.024-� ;lit) - Luis g n43 Z VIC, attrY1A-60 (VIrpp.oA rt e-ytiI Y ( j,,-wki-77-v-acAt Cit4014,(:6 m 1. 1� do !� L vt ylt�t. Otto ire--) -r: Jmrdtd- )614 -tax tico been 5t i c cd.46 1/YAIT / M; 7Y RUDYidi -)--?; /atoll -7- 1 kn.+ '+cliv /' ke G-3 loxics �un?m rny� /' i� ug-` ti94 c9,1 v9ri iomK3 F-1 er O'it Ph S. 01064- 1g 1.3 50 /J.0 .3q 50 )9 , 56 06 a—h�'yl1/4-0f Oz ia.(/ 1,6a 4/6 /7a0 5 ? , 9- *kid- rya 6 0025 o.5 n7 n.Qmilled 0.134- SO% mov& =J . DD(= ..1 n.oluAid 0. 00012 # 0. 0000 oIc1: - .e0000 °5.1 /o/en o.0o0109 #-o G i5E9A . .DOOCC) - DOtOttliwyl = .D0144 19e11. 6-61°-7* L /t inolla J. /61391/- ,orc9u 51 -c-f TywL 3f O ?LD 1 c go _ m� = ('- p00D531ip000act{ :,-s 06/ `%lam ' G► � 024-tri (LAI 4f-ct/27/-( pa/apa(A&' 2/ o-Ton') oda,- - h "ku. @ ru4-74- ciook-c) River Mill MHP / Uniprop (NEW FLOWS) ResiduaI Chlorine 7010 (CS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) UPS BACKGROUND LEVEL (UG/L) IWC (%) Allowable Concentration (ugA) Fecal !limit (based Qn 331 : 1) Ammonia as NH3 (summer) 3.9 7010 (CFS) 1 DESIGN FLOW (MGD) 1.55 DESIGN FLOW (CFS) 17.0 STREAM STD (MG/L) 0 UPS BACKGROUND LEVEL (MG/L) 28.44 IWC (%) 59.77 Allowable Concentration (mgA) 200 mg/I Ammonia as NH3 (winter) 7010 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) UPS BACKGROUND LEVEL (MG/L) IWC (%) Allowable Concentration (mg/i) 3.9 1 1.55 1.0 0.22 28.44 2.96 10 1 1.55 1.8 0.22 13.42 11.99 NC0056499 12/1 0/9 3 CARLA - CADN C� N [cc- r-c.r-cr--'rr-t--r74.r:..c.c.r,, C ( MEMO To: oJeler 6;;^eer yf refre &Me a cosI 1.14/1,7004JYoriiitA er �d�i7i�n� yAdk;nV,lle Td 5 45 i))ere C9A?,rci' Ale I1 3 DATE: SUBJECT 10eiljtitiry -ri ',3 hre else. 5A-; 1 :_,: PIT R (OF Ate) CY0,061 0� From: a�ment of Environment,cb o�h CarOab NDea�Resources ����°°° ealth, and �f q11- NPDES PRETREATMENT INFORMATION REQUEST FORM FACILITY NAME: 7/I b k 1 N v L-U WTP NPDES NO. NCOO 2. 0 3 3 5' REQUESTER: Gr IJt z c h DATE: 0 13 9-1 RDGION: W51Z PERMIT CONDITIONS COVERING PRETREATMENT This facility has no SIUs and should not have pretreatment language. This facility should and/or is developing a pretreatment program. lease include the following conditions: Program Development Phase I due / /_ Phase II due / / Additional Conditions (attached) This facility is currently implementing a pretreatment program. Please include the following conditions: Program Implementation Additional Conditions (attached) SIGNIFICANT INDUSTRIAL USERS' (SIUs) CONTRIBUTIONS SIU Flaw - TOTAL: - COMPOSITION: METAL FINISHING: 609 yap MGD MGD MGD MGD MGD HErniaORcs R E vw PARAI+EI'II2 Cd Cr Cu Ni Pb Zn CN Phenol Other iSQ Z&e CrA /page teai° PASS ;THROUGH t i ALIZATABLE .167 6..85 jt/D crfr'� d c DAILY LOAD IN LBS/DAY ACTUAL DOMESTIC INDUSTRIAL Z REMOVAL .0/02 0303 .00 8P�'cr%-q y 0tiJy Xy)e4e , 37 1 .51Vc o50 7z .60 2,I2_ 72_ 27 , q�f .190 I.3S .6 f7/ on o 1,$ 0 .00096 2 5 a450- RECEIVED: / / REVIEWED BY: fiver RETURNED:4iptitt- /j /2 /13 N oT fill carreir 4n'rs or Curre or /1t4/4 r . 0109 . 00,s ,00069 13 qs- (0.Y A,_ WHOLE EFFLUENT TOXICITY TESTING </SELF -MONITORING SUMMARY] Wed, Nov 17, 1993 FACR.ITY QI I r•F .- "..... . B MOM AM MAT JUN JUI, A11(i SEP WILSON 1'Idl'R0I,IiUM PERM CIIR LIM:99%(GRAB) e0 - - - - - - - - rz NC0076252/001 Begin: I/18/90 Fmqucncy: Q P/F A MAR JUN SEP DEC NonComp: 90 - - H - - PASS - - PFi - County: WILSON Region: RRO Subbasin: NEU07 91 PASS - PASS - - PASS - - LATE PASS PF:0.005 Special 92 - - PASS - - PASS - - FAIL PASS 7Q10: 0.00 IWC(%):100.0 Order 93 - - LATE/FAIL - FAIL PASS - - - PASS WILSON WWII' PERM CIIR LIM:94% 89 - - - PASS,bt " NC0023906/001 Begin:2/1/90 Frequency: Q P/F A FEB MAY AUG NOV NonComp: 90 - PASS - - PASS - - PASS - - PASS County:WILSON Region: RRO Subbasin: NEU07 91 - PASS - - PASS - - PASS - - PASS - PF:12.000 Special 92 - FAILSIG FAIL PASS .FAIL PASS - - FAIL PASS - PASS - 7Q10:0.500 IWC(%):97.37 Order. 93 - PASS - - NR/FAIL FAIL PASS PASS - WINI)St)R WWII' PERM CIIR I.IM:'K)% 69 - -- - - - - - - - - - - ---' NC0026751/001 Begin:8/I/93 Frequency: Q P/1' A JAN APR JUL OCT NonContp:SINGLE 90 - - - - - - FAIL FAIL FAIL FAIL FAIL FAIL County: BE RTIE Region: WARO Subbasin: ROAIO 91 FAIL PASS - NR - - FAIL PASS - PASS - - PF: 1.15 Special 92 PASS - - PASS - - PASS - - FAIL 1.11 PASS 7Q10:0.0 IWC(%):100.0 Order 93 PASS - - FAIL NR/PASS - FAIL FAIL PASS WINSTON-SALEM ARCFIIE I],l1EDGE WWTP P2 PERM CIIR LIM: ChV 76% 89 - - - - - - - - - - -- - NC0037834/001 Begin:1020/92 Frequency: Q JAN APR JUL OCT NonComp:Chr Avg 90 - - - - - ... -- - - - - - County:FORSYTH Region: WSRO Subbasin: YAD04 91 - - - - - - - - - - - - PF: 30 Special 92 - - - - - - - - - >96.0 - 7Q10: 15.000 IWC(%):75.6 Order. 03 >96.0 - -- 54.0 >96.0 01.0 27.0 54.0 17.0 WINSTON-SALEM LOWER MUDDY CRK PERM CIIR LIM:4.0% 89 - - - - - - - - - NI NR MI 141 NC0050342/001 Begin:9/1/89 Frequency: Q P/F A JAN APR JUL OCT NonComp: 00 NR NR - - - - - - - PASS - - County: FORSYTIl Region: WSRO Suhhasin: YADO4 91 PASS - - PASS - - PASS - - PASS - - IT: 15.0 Special 02 PASS -- - PASS - - >te -- -- >I8.0 - - 7Q10:554.0 IWC(%):4.02 (fir 93 >16.0 - - >16.0 - - >16.0 - - WORTFJ CIIEMICAL CORP. PERM CHR LIM:22%(GRAB) 89 - - - - - - ... - -- - - - NC0078000/001 Begin:4/2/90 Frequency: Q P/F A JAN APR JUL OCT NonComp: 90 - - - - - - MI NR NR NR WI NR County:GUILFORD Region: WSRO Subbasin: CPF02 91 NR - - NR - - H - -_ - - - PF:0.216 Special 92 _- - - - - - _ - - - - - 7Q10:1.2 IWC(%):21.8 Order 93 PASS - - PASS - - PASS - - PASS WRIGHT CHEMICAL CORP/002 PERM: CIIR LIM 26% UNTIL 12l31/94 89 - - - - ._ - - - - -- - NC0003395/002 Begin:3/1/93 Frequency: Q P/F A FEB MAY AUG NOV NonComp:SINGLE 90 - - -- - - - - - - -_ - - - County:COLUMBUS Region: WIRO Subbuin: CPF17 91 - - - - - - - - - - - - PF:0.135 Special 92 - - - - - - - - - - _ - 7Q10: 0.6 IWC(%):25.8 Order. 93 - - -- - PASS -- -• NR/PASS - W YSONG & MILKS C0/003 PERM CIIR LIM: 90% (GRAB) 69 - - - - - - - - - - - - NC0327553/003 Begin:12/4/92 Frequency: Q P/F A JAN APR JUL OCT NonComp:SINGLE 90 - - - - - - - - - - _ - County:GUILFORD Region: WSRO Subbasin: CPF02 91 - - - - - - - - - - _- t - PF:0.0504 Special 92 - - - - - - - - - - - 7Q10:0.0 IWC(%):100.0 Orden 93 I - - 1 - - I - - 1 - YADKINVII.LE WWII' PERM CIIR LIM:28% 89 NR FAIL FAIL NR FAIL FAIL FAIL FAIL FAIL bt FAIL FAIL NC0020338/001 Begin:2/1/91 Frequency: Q P/F A JAN APR JUL OCT NonComp: 90 FAIL FAIL FAIL FAIL FAIL FAIL PASS FAIL PASS PASS - - County:YADKIN Region: WSRO Subbasin: YAD02 91 PASS - FAIL PASS PASS PASS PASS PASS PASS PASS - - PI': 1.00 Special Olin ` / 92 PASS - - FAIL FAIL PASS PASS - -- PASS - -- 7Q10: 0.20 IWC(%):813.57 Order �( 93 PASS - -- PASS •- - PASS - YANCEYVILLEWWI P PERM CHIT LIM:24% 80 - ._ .- -- - - -_ -- __ -- - - - NC004001I/001 Begin:9/I/92 Frequency: Q 1'/1' A JAN APR JUL OCT NonComp:SINGIli 00 - - -.- - - ..- .-- _- ___ - -- - Caunly:CASWI:I.L Region: WSIO Subbasin: ROA04 9I --• -- - _. -- _- -- -- - - - - PE: 0.250 tiperinl 02 - -_ - - ... - --- - - PASS - -- 7r)10- I IWt'11•1 2.1.1 ""M'' WI fAll MI M1 PASS ... -.- I'AtiS -.. ... PASS 0 2 consecutive failures = significant noncompliance Y Pre 1989 Data Available LEGEND: PERM = Permit Requirement LET = Administrative Letter - Target Frequency = Monitoring fiequency: Q- Quarterly; M. Monthly; BM- Bimonthly; SA- Semiannually; A- Annually; OWD- Only when discharging; D- Discontinued monitoring requirement; IS- Conducting independent study Begin =First month required 7Q10 = Receiving stream low flow criterion (cfs) A = quarterly monitoring increases to monthly upon single failure Months that testing must occur - ex. JAN,APR,JUL,OCT NonComp =Current Compliance Requirement P1; = Permitted Bow (MOD) IWC% = Inxtlerlrll wactc conccntmlion PA' = PacdFnd chronic test AC = Aculc C11R = Chronic Data Notation: f - Fathead Minnow: • - Ceriodanhnia so.: ntv - Mvsid shrimn: ChV - Chronic value; I' - Mortality of stnted nercentaee nt hiehcst conccntrntion: at - Performed by DEM Au Tox Groun: M - Dad test Reporting Notation: -- = Data not required; NR - Not reported; ( ) - Beginning of Quarter Facility Activity Status: 1 - Inactive, N - Newly luucd(To construct); 11 - Active but not discharging; t-More data available for month in question SIG = ORC signature needed 57 • Q - • • Annual Pollutant Analysis Monitoring Requirement Reporting Form A (Revised June 1990) 1. Facility information: \ .. Page 1 of 8 NPDES Permit NIo: Nr' n ()a a 318 Discharge (Pipe) No: 0-n 1 Year: 1 ! 9 2 Facility Name: p‘D1 NvILLE WWII' • Class: - County: YADKIN Person(s) Collecting Samples:..,_PgRRY wim ams Status of facility wastewater treatment operation - on day of sampling: typical: _. L Yes No If no, explain briefly: Analytical Laboratory: oXFQED IIA ORATOR TFS , INC . II. Sampling: 24 hr composite r for main sample / grab sample for purgeable fraction • Date Sampled: (composite sample) Corresponding sample taken for toxicity testing: Sampling begun (date, time): 12 / 0 4 / 9 2 8k15 AM Yes Sampling finished (date, time): 12 /Q 4 / 9 2 8 ;15 AM _AZ -No Date and time sampled (grab sample): 12 / 0 4 / 9 2 9;15 AM The purpose of this d for the Annual Pollutan Instructions • cument and the accompanying memo is to standardize the sampling, analysis and reporting procedures to be used Analysis Monitoring (APAM) Requirement as described In the permit. Sampling 1 • Take a 24-hour composite sample from the final effluent during midweek (Wednesday through Friday). Collect a grab sample for the volatile organic fraction when c ltectlon of the 24-hour composite sample is completed. Follow any other sampling Instructions provided by the let; oratory performing the analyst . 2 - indicate in the space ce provided at the Sep of tht* page whether a correspgoding sample for toxicity testing was taken. 3 - Make note of any unusual wastewater treatment operating conditions occurring on the day of sampling in the space provided on the form. Analysis 4 - Analyze the affluent for pollutants listed on the APAM form, Including those to be Identified and approxllnately quantified under the 10 significant peaks rule. using appropriate EPA -approved methods for each of the analytic fractions. Other analytical methods can be subst uteri only with prior, written approval of the Director of the Division of Environmental Management (DEM). Read and distribute tothe labors .ory performing the analyst the accompanying memo (Tedder, October 1990) clarifying analytical requirements. S - Identify chemicals to be analyzed for according to the 10 significant peaks rule (as described in Item 2 of the Annual Pollutant Analysts Monitoring Requiremen In the permit) using a GC/MS library search. Tentative identification is all that is required; confirmation by standard injection is not necessary. Estimate the concentration of each based on an Internal standard having the closest retention time. Reporting . 8 - Ouantitation Limit Targets that should be met are listed on this Revised APAM Reporting Form A. Report the use of eny higher guantlta• tlon limit and an explanation as to why the listed quantltation limit target could not be met. Examples of acceptable reasons for not meeting a quantitatlon limit target could be high background concentrations In a sample, or the necessity for sample fraction dilution to bring a chemical to within a quantifiable concentration. List any quantitatton limit diffident (whether higher or tower) from the target in the column provided for this purpose. - 7 - if a chemical le found to be below the guantltatlon limit, report the concentration detected as less than (or'<') the quantitatton limit In the appropriate space. Provide a concentration estimate for chemicals detected in concentrations greater than the detection limit and less than the quantitatton limit. Enter the detection limit In parentheses beside the estimate. Chemicals detected in concentrations above the quan- titation limits must be q entitled. QuanUtatlon limit and detection limit am defined in the accompanying memo (Tedder. October 1990). Enter the total number of pe s detected in each analytic fraction to the appropriate space on this Revised APAM Form A. Report all concentrations In units of micrograms er liter (ugll) and metals as total recoverable metal.. If no peaks to be Identified under the 10 slgnIAcant peaks rule are observed, enter "no e" In the space provided for "other" compounds In each appropriate analytic fraction section. Provide the concentra- tion estimate and reten Ion time •for "unknowns" as well as for "significant peaks" for which a structural assignment can be made. 8 - If "significant pa " are found. provide probable molecular weight, library match probability, retention time. Identification basis. and MS scan number fore h. In addition. list Internal standards and their retention times. 9 - In the section labeled "Organic Analytical Information" (p. 9), include for each organic fraction the method, extraction technique, GC operating conditions, and surrogate recovery. Report the size of the OCiMS library being utilized in the appropriate space. 10 - Use copies of this Annual Pollutant Analysis Monitoring Revised Form A to report the results of the analysis. Both the analytical laboratory representative and the facility operator In responsible charge should elgn completed forms (last page). 11 - Mall two completed copies of the form (and the laboratory report, If submitted to the facility on a different form) to: ATTN: Central Files, Division of Environmental Management, NC DEHNR. P.O. Box 27887. Raleigh, NC 27811. Mall the APAM form separately from Discharge Monitoring Reports. • •k A. Purgaeable (volatile Organic) Traction, EPA Method 8260. Yuaber of cheaibala detected in fraction: 3 Traction STORETNikaber 84085. Page 2 of 9 STORET Compound sunhat Quant. Target Quant. Licit * Conc. Dept. GC/MS Confiraation /. Pollutants to be analyzed for: • (µg/ lj �µg/ 1) �µg/ 1) Yee l4o 34210 icrolien , 100 20 I, BDL / 34215 Acrylonitrile 100 20 BDL 1 • 34030 Benzene 6 SOL 1 32101 Bormodici}loromethane 6 24 1 32104 BroaoforI 6 BDL i 1 • 34413 Bromorethane 10 5 BDL ' 1 32102 Carbon Tetrachloride 6 BDL 1 34301 ,chlorobOzene 6 5 BIM 1 34311 Chloroet ane 10 5 BDL 1 r 34576 2-Chloro thyl vinyl ether 10 5 BDL 1 32106 Chlorofo 5 46 1 34418 Chloromethane 10 5 BDL 1 32105 'Dibroaochloroeethana 6 5• 1 34496 1,1-Dichloroethane 5 BDL 1 , 34531 1,2-Dichloroethane 5 BDL 34501 1,1-Dichloroethlylene • •- 5 - BDL 1 r 34546 trane-1,2-Dichloroethylene 5 BDL 1 34541 1,2-Dichl.oropropane 6 5 BDL / 34704 cis 1, 3- ichlorpropen, 6 ,• • BDL se ' 34699 'trans 1,-Dichlorpropene 6 .• • BDL 1 34371 ithylbeniene 8 5 BDL 1 34423 Methylene chloride 6 BDL / 34516 1,1,2,2-Tetrachloroethane 7 5 BDL 1 34475 Tetrachlgroethylene 5 BDL 1 34010 Toluene 6 5 BDL - 34506 1,1,1,-Trichloroethane • 6 BDL 1 34511 1 1 2 Trichloroethane 6 BDL / 39180 Trichloroethylene 5 BDL 1 34488 Trichlorofluoromethane 10 5 BDL 1 39175 vinyl chloride 10 5 BDL / * If 'different from quantitaion licit target. A-1. Other purg a able r (up to 10 highest peaks) . . • EPA Method B260. ' Compound P rob. Mol. Weight Est. Conc. t igll) ;ib. Mat Prob. (%) Rat. Time (Kin) Identification Basis Scan Number Lib. Match Manual I me rp. P2 _ 1 1 1 1 1 1 NO ADDITIONAL COMPOUNDS TO PEPOPM . 1 1 1 , 1 1 1 1 1 1 1 1 1 1 1 1 7 1 Complete only if non -targeted compounds are present: Internal Standard 's Ret. Time (Pan) 4 - Bromof luorobe nz a ne Toluene -dB • Dibromof luorom se thane B. Acid Extractable Traction, EPA Method 8270. Number of chemicals detected in fraction: 0 Traction STORET Number 45582. Page 4 of 9 SZT Number Compound Quant. Target Quant. Limit* Conc. Doot. GC/KS Confirmation 1. Pollutants to be analysed fors (Ng/l) (pg/l) (pg/1) Tes No 34452 4-Chloro-3-methylphenol 10 _ BDL / _ 34586 2-Chlorojhenol 10 BOL / 34601 2,4-Dichlorophenol 10 BDL ✓ _ 34606 2,4-Dimethylphenol 10 _ SOL ✓ .. 1 34616 2,4-Dinitrophenol 60 10 BDL ' r _ 34657 2-Methylt-4, 6-dinitrophenol 50 10 BDL ✓ 34591 -2-NitroPhenol 10 BOL ✓ 34646 4-Nitrop'henol 50 10 BOL / _ 39032 Pentachiorophenol 50 10 _ BDL ✓ 34694 Phenol 10 BDL / 34621 2, 4, 6-Trichlorophenol 10 BDL ✓ * If different from quantitaion limit target. B-1. Other acid extractable s (up to 10 highest pe aks) . • ' Compound P rob. Kol. Est. Conc. (;t9/l) :ib . Mat Prob. (0 Ret. Time Ellin) Ide nti fi cati on Basis scan Number Lib. Match Manual Interp. RI 1-Isocyanato-2-Methyl Benzene 54 94 21 le •1860 2,3-Dime thyl- 2-butanol 36 78 9.91 _ ✓ 1 529 Unknown, similar to 3-Chloro- 2-me tttyl-2-pe ntanol 35 75 7.97 ✓ ✓ 296 Unknown, similar to 4-Broao- 3 -Phenyl Sydnone 18 64 24.78 ✓ 1 2313 Unknown, similar to 2-Bromoe thenyl Benzene 14 61 23.2 5 ✓ 1 2129 2-Amino-Phenyl sulphone _ 8.1 90 28.45 ✓ 1 2754 ✓ V • ✓ 1 1 ✓ V 1 V 1 Complete only if non -targeted compounds are present: Internal Standard Ret. Time (Min) 1, 4-oichlorobenz ene-d4 12.76 Mapthaleoe-d8 16 keenaptheae-d10 20.62 Phenanthrene-d10 24.55 Chrysene-d12 31.96 Perylene-d12 39.34 • C. Base/Neutral 1'action, IPA M.thod 8270. Number of chemicals detected in fraction: 0 Fraction STORET' Number 45583. Page 6 of 9 - STCRET Humber Compound Quant. Target Quant. Limit* Conc. Deet. GC/148 Confirmation T . pollutants to be analysed fors (pg/1) (pg/1) (Ng/1) Yeo 3405 Acenapthene 10 BDL 34200 Acenaphthylene 10 BDL 1 34220 Anthracene 10 BDL 39120 Benzidine 50 10 BDL 1 34526 Benzo (a) anthracene 10 BDL d • 34247 Benzo (a) pyrene 10 BDL 34230 Benzo (b) fluoranthene 10 BDL / 34521 Benzo (g'i) perylene 10 BDL 1 34242 Benzo (k) fluoranthene 10 BDL 34278 Bie (2-chloroethozy) methane 10 BDL . 1 34273 Bis (2-ch oroethyl) ether 10 BDL 34283 Bis (2-ch).oroieopropyl) ether 10 BDL 39100 Bis (2-ethylhexyl) phthalate 10 BDL 34636 4-Broaophenyl phenyl ether 10 BDL 34292 Butyl be zyl phthalate 10 BDL Or 34581 - oia hthalene 2 Chlor p 10 BDL 34641 4-Chloro henyl phenyl •them 10 - BDL 34320 'Chryeene 10 BDL 34556 Dibenzo(a,h)anthracene 10 BDL T 34536 1,2-Dich orobenzene . 10 - _ BDL se 34556 1,3-Dich orobenzene 10 .• • BDL 34571 11,4-Dichlorobenzene 10 BDL / 34631 '3,3-Dichlorobenzidine 20 10 BDL 34336 Diethyl phthalate 10 BDL / 34341 Dimethyl'phthalate 10 BDL i1 y' 39110 'Di-n-butyl phthalate 10 BDL 1 34611 2,4-Dinitrotoluene 10 BDL 34626 2,6-Dinitrotoluene 10 BDL 34596 Di-n-oct ' 1 phthalate. 10 BDL / 34346 1,2-Diph nylhydrazine 10 BIM 34376 Fluorantlene 10 BDL 34381 rluorener 10 BDL . 39700 Hezachlorobenzene 10• BDL I _ 34391 Hexachlorobutadiene 10 BDL 1 34386 Hexachloocyclopentadiene 10 BDL 34396 Hexachlotoethane 10 BDL 34403 Ideno (1, ;, 3-cd) pyrene 10 BDL 34408 Ieophoro a 10 BDL / 34696 Naphthal ne 10 BDL 34447 Nitrobenzene 10 BDL 34438 1 11-nitroecfdimethylaaine 10 BDL 34428 ii-nitroao-di-n-propylaaine 10 BDL se 34433 N-nitroeodiphenylamine 10 BDL / _ 34461 phenanthrene 10 BDL se _ 34469 pyrene 10 BDL 1 •. BDL / 34551 I1,2,4-Trichlorobenzene 10 C-1. Other base/neutrals (up to 10 highest peaks) . • Compound Prob. Mol. Est. Conc. (Kg/1) *.ib . Mat Prob. (%) Ret. Time (Min) Identification Buis Scan Mumher Lib. Match Manual rnterp. EST Unknown, similar to Napthale ne Carbothi of c Acid 11 33 28.14 ✓ ✓ 271.6 6thanone 1-(4,5-Diethyl-2-Methyl-1-Cyclopenten-1-y1) 10 73 19.13 i/ 1 1635 1 1 ✓ ' ✓ ✓ ✓ ✓ ✓ I ✓ v ✓ - v 1 - ✓ ✓ ✓ ✓ Complete only if non -targeted compounds are present: i Internal Standard Ret. Time (Min) 1,4-Di chlorobeazene-d4 12.75 Napthalene-d8 16 Acenapthene-d10 20.62 P he nanthre ne -d10 24.55 Chryseae-d12 31.94 Perylene-d12 39.32, • • D. organochlorine%organophoaphoroun Pesticides and PCB'si. Number of chemicals detected in fraction: 0 Fraction STETNumber 00188. Page 8 of 9 STORET Number Compound Quant. Target Quant. Limit* Conc. Dect. Confirmation' Dual Col.. GC/MS 1. Pollutants to be analysed for: (µg/1) (µg/1? organochlorine Pe ticidee/PCB'a$ EPA Method 507 (µg/1) Yee No Yee No 39330 Aldrin 0.05 BDL 1 -✓ 39337 alpha -BBC 0.05 BDL 1 ✓ , 39338 Beta-BHC 0.05 BDL 1 - I 34259 Delta-BHC 0.1 1 BDL • ✓ ✓ 39340 Gamma-B (Lindane) _ 0.05 BDL ✓ 1 �. 39350 chlordanei 0.2 2 BDL 1 1 39310 4,4'-DDD 0.1 1 BDL 1 1 39320 4,4'-ODE 0.1 , 1 BDL / / 39300 4,4'-DDT 0.1 1 BOL 1 ✓ 39380 Dieldrin 0.02 1 BDL 1- 1 34361 Endoeulfan I (alpha) 0.1 1 BDL ✓ 1 34356 Endoeulf8n II (beta) 0.1 1 BDL ✓ ✓ 34351 Endosulfan sulfate 0.7 2 BDL 1 . ✓ 39390 Endrin ' 0.06 1 BDL _ 1 1 r 34366 Endrin aldehyde - 0.2 2 ' BDL ✓ V 39410 Heptachlor 0.05 BDL 1 ✓ _ 39420 Heptachlor epoxide 0.8 0.05 BDL ✓ V 39480 Methoxycl�lor - _ 0.5 5 BDL 1_ 1 39755 Mirex 0.2 2. . BDL 1 1 39400 Toxaphen 2.4 20 BDL se i 34671 PCB 1016 0.5 20 BDL ✓ 1 39488 PCB 1221 0.5 20 BDL 1 1 39492 PCB 1232 0.5 20 - BDL ' 1 1 39496 PCB 1242 0.5 20 BDL ✓, 'r 39500 PCB 1248 0.5 20 BDL ✓ ✓ 39504 PCB 1254 1.0 20 BDL 1 . 1 39508 PCB 1260 .1.0 20 BDL 1 1 organochlorine Pesticides/PCB'as EPA Method 508 39560 Deaeton ' 2.5 • BDL L ✓ 1_ 39540 'Parathion + (ethyl)BDL 0.6 _ 17. 1 E. Herbicides, EPI1i :[umber of chemicals Fraction STO ET Number Method 517. ' detected in fractions 00148. STOET Number Compound Quant. Target Quant. Limit* Conc. Dect. Confirmation? Dual Column 1. Pollutants to be analyzed fors (µ0/1) 0g/1) (µg/1) Yea No 39730 2,4-D 12 _ 10 BDL 39045 silvex 2 BDL 1 39740 2,4,5-T 2 BDL ✓ * If differentifrom quantitation limit. Organic Analytical Information: Page 9 of 9 Organic Fraction Method Extraction GC Operating Conditions Column Deaeriptioh Surrogates (spikes) Batch Cont. Length X ID, Film Thickness Col. Type, Car. Gas d Flaw Rate, Tesp. Prog. Compound ` Res (%) Purgeablea 8260 I • 75m X 0.63am; 3.0pa; DB-624 Be; 12 psi; 35'C(8Min)-2008C (Smin)-10'/ain 4-111B Tol-dO DBS'M . A01 / f )'•' Acid Extractables 8270 _--7 ' 3011 X 0.25ma; 0.25p : DB-SMS ' 8e; 18 psi; 40 •C (4min) -290'C ' (18min) -10'/min 2-FP phenol-d6 2, 4, 6-TBP 7s ,ID /!9 Base/Neutral Extractables ' 8270 / sane as for Acid Extractables 1IB-d5 2-FBP Mar.-dl4 ts% 4j /// r.C/MS Library size (number of Reference spectra) : 51,680 T. Metals and Other Fhemicals Number of Metals and other Chemicals (as listed belawr) detected it; sample: Traction STORET Number 78240. ST RET Compound Number Quantitation Limit Target Quantitation Limit * Concentration Detected 1. tsollutanta to be analyzed tor: (pg/1) (pg/1) (pg/ 1) 01104 Aluminum 50 __ • 10 ; . 2 7 0 01097 Antimony SO 5 5.n 01002 Arsenio 10 6 .3.0 • 01012 Berylium 25 1 1 . n 01021 Cadmium 2 . 3 :1-4 01034 chromium 5 26.0 • 01042 Copper • 2 3 17.0 01051 Lead 10 _ 3 2.0 71900 Mercury 0.2 - - 01067 Mickel ! i0 5 19,0 01147 Selenium 5 6.0 01071 Silver S 2 3.0 01092 Zinc 10 5 $1, R 2. Other inorganics: • 01007 Barium 500 10 21.0 00940 Chloride 1000 _ a,Q6 00 00720 - Cyanide 20 S 2_„ 5 00951 • Fluoride 100 1001.0 ' If different fiom quantitation limit forget. Analytical L • - ratory Repreentive: signed: Facility operator in Responsible Charge (CRC) : • f r ! g � j fLi (q4 ..is I certify that thia•report is accurate and complete to the best of ay knowledge. �1 signed: K.146 Date: a Bruce A. Babson 'Date: Z.7 -i'3 JAt' — 4-93 MON 1 0 : 56 MESCO — GARNER P . Bi 1 QPERAT 0N/C0N$TRUCfl0N MANAGERS Municipal Services P.O. So: 97. am*:tlonn Ca'o�ena 27S20 (918)7Y2.S202 Garner Office Fax It (919) 772-1176 Oates elAA 4ri To �u $64e 14bock• IJGD E 1-1 tv e/13 �, TECHNICAL SUPPORT BRANCH Re ��w�..1 ijvl/x# `" CIV1USAHITAAY ENGINEERS Engineering Cam any, P.A. .0. Box 340. @Conte N Gamma 26407 (7041262.1767 • CEWED Boone'Offic Fax II (704)265- JAN 0 5 1`- cOCcALft,v 1; e 8,L9,rJ "or- o©Z.d"$38 Remarks PIease r-evi 4 14:PD ANL. hA Akko uck-N.:43 — Tee I • P vtke, eix.l.Sti uyke. P A-v 4? en" F-1-1..4 p i ..15 From f�f Vvv� Garner! NC Offic t of Pages Transmitting (Including this Sheet) (If copy is illegible or imcomplete, please call immediately for retransmission.) 0 0 (93o7oz- dam. ANNUAL PERIOD TOWN OF YADKINVILLE, NC — WASTEWATER DISCHARGE HISTORY (All Values Reported as Monthly Averages) Effective Expiration Amual Flow 1Bod5 TSS NI113 DO Total Total Oil & Grease Cadium Lead Cluomium Cyanide Nickel Fluoride Copper Zinn Permit Date Signed Date Date Period (MGD) mg/1 me mg/1 mg/1 Nitro. Phoa. Fecal Col. mg/1 mgll ag/l u8/1 ug/1 ug/1 mg/1 ug/1 ug/1 Toxicity Mercury Si NPDES NC All 1000/100 0020338 10/25/85 11/1/85 10/31/90 Year 0.600 30 30 -0- 5 monitor monitor ml 15 -0- -0- -0- -0- -0- -0- -0- -0- N/A N/A NPDES S NC 1000/100 0020338 12/10/87 10/31/90 manner 0.600 30 30 16 5 monitor monitor ml 15 -0- -0- -0- -0- -0- -0- -0- -0- N/A N/A 1000/100 winter 0.600 30 30 -0- 5 monitor monitor ml 15 -0 -0- -0- -0- -0- -0- -0- -0- N/A N/A O sOC 0 WQ 200/100 O 90-58 5/22/91 2/28/91 6/1/92 ammner 1.00 30 30 16 5 monitor monitor ml 30 *15 88 175 18 309 -0- monitor monitor 040% NIA W 200/100 winter 1.00 30 30 -0- 5 monitor monitor nd 30 *15 88 175 18 309 -0- monitor monitor Q40% N/A N 0 SOC WQ 200/100 90-58Ad — received 1/27/92 — 10/1/92 summer 1.00 30 30 16 5 monitor monitor m1 30 *•15 88 175 18 309 1.8 monitor monitor 028% monitor 200/100 winter 1.00 30 30 -0- 5 monitor monitor ml 30 **LS 88 175 18 309 1.8 monitor monitor c-28% monitor 2 NPDES O INC 200/100 j E 0020338 6/29/90 B/1/90 5/31/94 surtnater 1.00 30 /30 16 5 mrimtor monitor ml 30 J V2.3 j48 1 17:6 99 N/A 'monitor `monitor/@89% N/A 200/100 wider 1.00 30 30 -0- 5 monitor monitor m1 30 2.3 28 56 5.6 99 N/A monitor monitor 089 % N/A 1I 'I h IL Effective Expiration Annual Flow hods TSS N11 DO Total Total Oil &Grease Cadium Lead Chromium Cyanide Nickel Fluoride Copper Zinc Permit Date Signed Dade Date Period (MGD) mg/1 mg/1 mg/1 Nitro. Phew. Fecal Col. mg/1 ug/l ugh1 ug/l ugn ug11 a08n ugll ug/l Toxicity Memory Si NPDES I' NC �01100 ✓ / .,�,-off, arz ✓ - f 0010338 1/2191 2/1/91 5/31/94 summer 1.00 30 t✓30 ✓ 16 ✓5 mooitor�monito nil 30 4.0 88 ✓175 ✓18 309 8 N/A N/A Q28% N/A 1 200/100 winter 100 30 30 -0- 5 monitor monitor nil 30 7.0 88 175 18 309 1.8 N/A N/A Q28% N/A 1 1 WT i ▪ "SOC item 3(d) indicates the following: l7 Permit Limits Modified limits (SOC) Parameters Unit Dai Max Daily Max Cadmium ug/1 2.3 15 O Lead ug/l 28 88 O Chromium ugn 56 175 0 Cyanide ug/I 5.6 18 Nicel ug/1 99 309 W c E toxicity O *Permit Limits - Chronic effluent bioassay • Effluent concentration of 85 % I} .. Modified Limits - Clunnic effluent bioassay • Effluent concentration of40% O **SOC item 3(d) indicates that permit would have slowed radium limit to be 7.0 ug/1; however, this was raised to 15 ug/l during SOC period. z a z r� In wK� SoC tou-rs 40 I5Te6 Fotz-- 1 ,1•)-tAr) 13rb vs) ik L Rot srP�N ' ©F l iaNCo�tP. tt tkkJo l4Ab lJ ,� MiGNI�r%� 4 MPtu+�G� ( ' wr Gd- f C , 0.m l soC- . Mir ��4 oir5 foR 1ueyr DF 56(_.+ i octoR1-1 kN(.L