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HomeMy WebLinkAboutNC0020184_Permit Issuance_19970226NPDES DOCUHENT SCANNING COVER SHEET NC0020184 Gastonia — NPDES Permit: Long Creek WWTP Document Type: !Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Correspondence 201 Facilities Plan Instream Assessment (67B) Environmental Assessment (EA) Permit History Document Date: February 26, 1997 Thies document i s printed on reuse paper -ignore any content oa the reverse side State of Departm� Health ar Division o€ orth Carc.'ina nt of Environment, d Natural Resources Water Quaiity Janes B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Mr. Dona •City orG, Post Offic, Gastonia, Dear Mr. d E. Carmichael. P.E. stoma Box 1748 North Carolina 28053-1748 Carmichael: IE) NJ F February 26, 1997 Subject: NPDES Permits Issuance Permit No. NC0020192 Catawba Creek WWTP Permit No. NC0074268 Crowders WWTP Permit No. .NC0020I 84 Long Creek WWTP Gaston County In accordance with the discharge perinit applications received on March 11, 1996, the Division is forwarding herewith the subject NPDES permits�.These permits are issued pursuant to the requirements of North arolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U S. Environmental Protection Agency dated December 6, 1983. Thi letter responds to comments made in your December 19, 1996 letter. The format of this Ietter is similar to the December 19, 1996 letter so that Gastonia can easily reference their comments and questions. New Mo itorin• Rec uirements The of conce are condu Explanati Division requires monitoring for all parameters identified as pollutants of concern. A pollutant is a parameter that is Iikely to be present in a given discharge. Reasonable potential analyses ted for all pollutants of concern monitored to determine if these pollutants will be limited. ns for identification of new pollutants of concern are contained in the following paragraphs. Thr e industries discharge mercury to Catawba Creek WWTP. Review of Catawba Creek WWTP pretreatment data for the period 12/95-4/96 indicated one detection equal to 0.3 ug/1 (greater than the allowabl concentration of 0.013 ug/1) on 3/7/96. Catawba Creek WWTP is scheduled to be decommi sioned within a year. In addition, there is some uncertainty associated with mercury analyses. Therefor.. monitoring (no limit) for mercury will be required in the permit. Of mercury. indicated detection detection addition, limit) wi e facilities which discharge to Crowders Creek WWTP, none is expected to discharge However, review of Crowders Creek WWTP pretreatment data for the period 1/94-6/95 three detections: 0.25 ug/1 (4/29/94), 0.60 ug/1 (7/22/94), and 2.2 ug/11(8/26/94). All three were greater than the allowable concentration of 0.029 ug/1. Because there were three over the water quality standard, mercury will be limited in the proposed NPDES permit. In oluene was detected at a concentration above the water quality standard and monitoring (no be required in the final NPDES permit. An mony, beryllium, chloride, and chloroform monitoring is only required for the discharge to the South Fork Catawba River (Class WS-V stream). Long Creek is a Class C stream and thus, water quality standards for these parameters are not as stringent as in water supply classified waters. Results from an APAM, indicated that concentrations detected of these four parameters were greater than corresponding water quality standards. Thus, they were identified as pollutants of concern. However, they will not be limited because there was only one detection in the case of each parameter. P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-0719 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper Mr. Carmichael February 26, 1997 Page 2 The frequencies specified for the newly identified pollutants of concern are standard for toxicants +and other non -conventional parameters. These frequencies are based on Division policy and the facility's treatment class. The City may request a re-evaluation of these requirements after data from 12 sampling events are collected Stream Monitoring Requirements The Division concurs with Gastonia's request to eliminate instream monitoring of total nitrogen and total phosphorus from all three discharge permits. Catawba Creek WWTP is scheduled to be decommissioned within a year, so that the amount of data collected at this facility would be limited. At Long Creek WWTP, the Division does not want to discourage use of the automated stream monitoring system. However, as stated in the Catawba River Basinwide Water Quality Management Plan (July 1995), studies have documented eutrophic conditions in Lake Wylie and several of its major tributaries. The Division agrees with Gastonia that a special study (perhaps including a coordinated monitoring program) may be a better tool to evaluate nutrient problems in the Lake Wylie region. Metals and Cyanide Limitations The Division concurs with Gastonia that metals' concentrations appear to be generally decreasing since the onset of using clean sampling techniques. However, review of the effluent data from all three facilities indicate that there remain periodic instances of relatively higher concentrations. Thus, the Division anticipates receiving the results of the glean sampling techniques studies in March or April 1997, but cannot postpone issuance of the Gastonia permits until that date. Because review of the effluent data from al "three facilities indicate periodic instances of relatively higher concentrations, conducting reasonable potiitial analyses on data collected from November 1995 to the present would not necessarily benefit Gastonia. If, after at least one year of data are collected, some permit requirements are no longer representative of a facility's discharge, Gastonia may apply for permit modifications. Review of weekly average and daily maximum limit calculations indicated that some errors were made in the draft permits. In the Catawba Creek WWTP permit, the daily maximum limits for cadmium and lead should be 5.5 ugll and 37.4 ug/l, respectively. The Long Creek WWTP permit has a single effluent sheet for each of the three different discharge scenarios. There are no changes to the 8.0 MGD discharge to Long Creek. However, on the effluent sheet pertaining to the 8.0 MGD discharge to South Fork Catawba River, for cadmium, the weekly average should be 19.6 ug/1 and the daily maximum should be 49.0 ug/l. In addition, on the effluent sheet pertaining to the 16.0 MGD discharge to South Fork Catawba River, the weekly averages and daily maximums should be as designated in the following table: ParameterWeekly Average':(ugh) Daily Maximum (ug/1) . Cadmium 10.8 27.0 Cyanide • 27.0 118.7 Lead 134.9 182.3 DEPART Permit No. NC0020184 STATE OF NORTH CAROLINA ENT OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulation: promulgated and adopted by the forth Carolina Environmental Management Commission, . d the Federal Water Pollution Control Act, as amended, City gf.Gastonia is hereby auth • rized to discharge wastewater from a facility located at to receiving w in accordance II, III, and IV The permit sh This permit an Signed this da it Long Creek Wastewater Treatment Plant Old Spencer Mountain Road Gastonia Gaston County ters designated as Long Creek in the Catawba River Basin ith effluent limitations, monitoring requirements, and other conditions set forth in Parts I, ereof. 1 become effective April 1, 1997 the authorization to discharge shall expire at midnight on September 30, 2001 February 26, 1997 Original Signed By David A. Goodrich A. Preston Howard, Jr., P.E., Director Division of Water Quality By Authority of the Environmental Management Commission Mr. Carmichael February 26, 1997 Page 3 ,Loma Creek WWTP Total Nitroszen Limits The Division agrees that Fleischmann's Yeast appears to contribute a significant amount of nitrogen to the Long Creek WWTP. Unfortunately, conditions in the Lake Wylie region prevent the Division fromdmodifying the total nitrogen limits. As stated earlier in this letter, studies have documented nutrient problems in Lake Wylie and several of its major tributaries. Extensive water quality modeling conducted for this region demonstrated the need to implement a nutrient management strategy. The first strategy developed in 1992 was modified and made less stringent in 1995. The total nitrogen effluent limits in the Long Creek WWTP were modified from 4.0 mg/1 (summer) and 8.0 mg/1 (winter) in 1992 to 6.0 mg (summer) and no limit (winter) in 1995_ The Division believes the most recent limits are necessary to effectively manage nutrients in the Lake Wylie region. Crowders Creek WWTP Total Nitrogen and Total Phosphorous Limits The Division concurs with Gastonia's request to phase in nutrient limits at this WWTP. Please note that the Effluent Limitations and Monitoring Requirements page has been corrected to properly indicate that these limits are not effective until September 1, 2001. Catawba Creek WWTP - Decommissioning Flows (9.0, 6.0. and 3.0 MGD) The Division has modified the Catawba C{;eek WWTP NPDES permit to include effluent limitations and monitoring requirements (including toxicity test requirements) to correspond with anticipated flow decreases of 6.0 and 3.0 MGD associated with the decommissioning. The format is similar to that of the draft permit. Specifically, special conditions pages immediately follow the Effluent Limitations and Monitoring Requirements pages . In Part III, Section B. Pretreatment Program Requirements, Number 11. Public Notice of the NPDES permit, the requirement has been changed from two to four months. The four month time limit allows the Division to complete work and processing for one compliance period before beginning the next. A six month requirement would cause subsequent compliance periods to overlap. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings, Post Office Drawer 27447, Raleigh, North Carolina 27611-7447. Unless such demand is made, this decision shall be final and binding. Please take note that this permit is not transferable. Part II, E.4. addresses the requirements to be followed in case of change in ownership or control of this discharge. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, or any other Federal or Local governmental permit that may be required. If you have any questions concerning this permit, please contact Paul B. Clark at telephone number (919)733-5083, extension 580. Sincerely, Original Signed By David A. Goodrich A. Preston Howard, Jr., P.E. cc: Central Files Mooresville Regional Office, Water Quality Section Mr. Roosevelt Childress, EPA Permits and Engineering Unit Facility Assessment Unit Aquatic Survey and Toxicology Unit is hereby au horized to: 1. Continu lift stati polishin static ae expansi cyclone clarifier sludge Treatme permit), 2. Prior to location the Cata 3. After rel • Location_ Class W Permit No. NC0020184 SUPPLEMENT TO PERMIT COVER SHEET City of Gastonia tb operate an existing 8.0 MGD wastewater treatment facility consists of influent n, a mechanical bar screen and grit removal, primary clarifiers, trickling filters, ponds with floating aerators, dual chlorine contact chambers with dechlorination, a ator, sludge lagoons, and sludge, drying beds. Facilities under construction for n to 16.0 MGD wastewater treatment facility include mechanical bar screens, grit removal, anaerobic/anoxic/oxic basins, caustic and alum feed, secondary , tertiary filters, chlorine disinfection with dechlorination, static post aeration, and igesters. Wastewater treatment- facility is located at Long Creek Wastewater t Plant,.Old Spencer Mountain Road, Gastonia, Gaston County (See Part III of this nd elocution of discharge point, discharge wastewater from said treatment works at the pecified on the attached map into Long Creek which is classified Class C waters in ba River Basin. cation of discharge point, discharge wastewater from said treatment works at the specified on .the:attached:map into South. •Fork Catawba River which is classified -V waters in the Catawba River Basin. ROAD CLASSIFICATION PRIMARY HWY HARD SURFACE.— immazsmilm SECONDARY HWY HARD SURFACE••• • C=DSIM=i LIGHT -DUTY ROAD. HARD OR IMPROVED SURFACE... UN IMPROVED Existing Discharge Latitude 35°18'25" Proposed Discharg e Latitude 35°31'35" Point Longitude Point 81°08'04" Longitude 82°24'10" map # F14SW Sub -basin 030836 Stream Class C Discharge Class 01 Receiving Stream Long Crk/S. Fork Design 0 8.0 m(30 Permit expires 9/ 30/ 01 0 SCALE 1 :24 GOO 0 1 MILE 1•44.4.4*.;g.44:4 f:"6:4".';'444444:44:44:41 7000 FEET 1 KILOMETER CONTOUR INTERVAL 10 FEET City of Gastonia NC00020184 Gaston County Long Creek WWTP A.(2)EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS -PERMITTED DISCHARGE TO S. FORK CATAWBA• RIVER Permit No.•N00020184 During the period beginning after the relocation of the discharge to theSouth Fork Catawba River and lasting until expansion to 16.0 MGD, the Permittee i authorized to discharge from outfall(s) serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below: s Flow BOD, 5-day, 20°C2 (April 1 - October 31) BOD, 5-day, 20°C2 (November 1 - March 31) TSS2 NH3-N, (April 1 - October 31) NH3-N, (November 1 - March 31) Dissolved Oxygen3 Fecal Coliform (geometric mean) Temperature Total Residual Chlorine Conductivity 8.0 MGD 11.0 mg/I 22.0 mg/I 30.0 mg/I 4.0 mg/I 14.0 mg/I 200/100 ml 16.5 mg/I 33.0 mg/I 45.0 mg/I 400/100 mi Total Nitrogen (NO2+ NO3 + TKN) Total Phosphorus Chronic Toxicit Cadmium Mercury Antimony Beryllium Chloride Chloroform 4 ai:ly [aximu 28.0 ug/I 19.6 ug/I 0.12 ug/I ig/1 0.47 ug/I easure.ment Frequency Continuous Recording • Daily Daily Daily Daily Daily Daily Daily Daily Daily Daily Monthly Monthly -=_-� Quarterly Weekly Weekly Notes: 2/month 2/month 2/month 2/month Composite Composite Composite Composite Composite ample cafion?' I or E E,I E,I E,I E E Grab • Grab Grab Grab Grab Composite Composite Composite Composite Grab Composite Composite Composite Grab E,U,D E E,U,D E U,D E E E E' E E Sample locations: E - Effluent, 1 - Influent, U - Upstream at City of Gastonia Pump Station, D - Downstream at a) Spencer Mountain Dam pool at dam, b) NCSR 2003, and c) 1.5 miles below tailrace at powerlines. Instream monitoringshall be grab samples taken 3/wk (Jun -Sep) and 1/wk (Oct -May). These monitoring frequencies specified above for dissolved oxygen, temperature, conductivity, and pH are to be used only when experiencing operational problems with the YSI 6-series system. It is assume 2 that when the YSI system is operating properly, these four parameters will be monitored continuously. 3 The monthly average effluent BOD5 and Total Suspended Solids concentrations shall not exceed 15% of the respective influent value (85°/% removal). 4 The daily average dissolved oxygen effluent concentration shall not be less than 6.0 mg/I. Chronic Toxicity (Ceriodaphnia), P/F, no significant mortality at 10%; March, June, September, and December; See Supplement to Effluent Limitations and Monitoring Requirements Page - Special Conditions for flow of 8.0 MGD to South Fork Catawba River. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored daily at the effluent by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. A. (1) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - PERMITTED DISCHARGE TO LONG CREEK • Permit No.. NC0020184 During the period beginning on the effective date of the permit and lasting until relocation to the South Fork Catawba River, the Permittee is authorized to discharge from outfall(s) serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below: • Flow BOD, 5-day, 20°C2 (April 1 - October 31) BOD, 5-day, 20°C2 (November 1 - March 31) TSS2 NH3-N, (April 1 - October 31) -onth� u;e rag 8.0 MGD 11.0 mg/1 22.0 mg/I 30.0 mg/I 7..0 mg/1 NH3-N, (November 1 - March 31) 14.0 mg/I .Dissolved Oxygen3 Fecal Coliform (geometric mean) Temperature Total Residual Chlorine Conductivity 200/100 ml 16.5 mg/1 33.0 mg/1 45.0 mg/I 400/100 rill Measu'remeni Frequency Continuous . Daily Total Nitrogen (NO2+ NO3 + TKN) Total Phosphorus Chronic Toxicity 4 Cadmium Cyanide Lead Mercury Nickel Notes: 2 3 4 2.5 ug/I 6.2 ug/l 31.0 ug/I 0.015 ug/I 109 ug/I 6.Z,.Ug/I_ 27.3 ug/I 42.0 ug/1 0.060 ug/I 437 ug/I Daily Daily Daily Daily Daily Daily Daily Recor.ding Composite Composite Composite Composite Composite Daily Daily Weekly Weekly Quarterly Weekly Weekly Weekly Weekly Weekly Grab Grab Grab .Grab Grab I or E E, E,1 E,1 E E E,UzD E E,U,D Composite Composite Composite Composite Grab Composite Grab Composite E U,D E E Sample locations: E - Effluent, I - Influent, U - Upstream at NCSR 2264, D - Downstream at NCSR 2003. lnstream monitoring shall be grab samples taken 3/wk (Jun -Sep) and 1/wk (Oct -May). The monthly average effluent BOD5 and Total Suspended Solids concentrations shall not exceed 15% of the respective influent value (85% removal). The daily average dissolved oxygen effluent concentration shall not be less than 5.0 mg/I. Chronic Toxicity (Ceriodaphnia), P/F, 81 %; March, June, September, and December; See Supplement to Effluent Limitations and Monitoring Requirements Page - Special Conditions for flow of 8.0 MGD to Long Creek. The pH shall not be Tess than 6.0 standard units nor greater than 9.0 standard units and shall be monitored daily at the effluent by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. Permit No. NC 020184 A(4). CHRO SUPPLEMENT TO EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS SPECIAL CONDITIONS for Flow of 8.0 MGD to Long Creek IC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The effluent di charge shall at no time exhibit chronic toxicity using test procedures outlined in the "Norte Carolina Cell daphnia Chronic Effluent Bioassay Procedure," Revised November 1995, or subsequent versions. The effluent c ncentratl.on at which there may be no observable inhibition of reproduction or significant mortality is 81 % (defined as treatment two in the procedure document). The permit holder shall perform quarterly monitoring using this procedure to establish compliance with the permit condition. The tests will be performed dur ng the months of Mar., Jun., Sept., and Dec.. Effluent sampling for this testing shall be performed at th NPDES permitted final effluent discharge below all treatment processes. All toxicity tes ing_results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Fo m (MR-1) for the month in which it was performed, using the parameter code TGP3I3. Additionally, DWQ Form AT-1 (original) is to be $ent to the following address: ttention: Environmental Sciences Branch North Carolina Divison of Water Quality 4401 Reedy Creek Road Raleigh, North Carolina 27607 Test data shall b- complete and accurate and include all supporting chemical/physical measurements performed in association ith the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample ust be measured and reported if chlorine is employed for disinfection of the waste stream. • Should there be the'permittee w the facility nam "No Flow" in t Branch at the ad Should any sing begin immediat revert to quarter Should the per monitoring will requirement will Should any test Water Quality i include alternate NOTE: • Failur- organism surviv constitute an inv. of the month foll o discharge of flow from the facility during a month in which toxicity monitoring is required, 11 complete the information located at the top of the aquatic toxicity (AT) test form indicating -, permit number, pipe number, county, and the month/year of the report with the notation of e comment area of the form. The report shall be submitted to the Environmental Sciences ress cited above. e quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will ly until such time that a single test is passed. Upon passing, this monthly test requirement will y in the months specified above. ttee fail to monitor during a month in which toxicity monitoring is required, then monthly Begin immediately until such time that a single test is passed. Upon passing, this monthly test revert to quarterly in the months specified above. • ata from this monitoring requirement or tests performed by the North Carolina Division of dicate potential impacts to the receiving stream, this permit may be re -opened and modified to monitoring requirements or limits. to achieve test conditions as specified in the cited document, such as minimum control l, minimum control organism reproduction, and appropriate environmental controls, shall id test and will require immediate follow-up testing to be completed no later than the last day wing the month of the initial monitoring. • QCL PIP' Version 9/96 A.(3) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS -PERMITTED DISCHARGE TO S. FORK CATAWBA RIVER Permit ,No. •NC0020184 During the period beginning after the relocation of the discharge to the.South Fork Catawba River and the expansion to 16.0 MGD and lasting until expiration the Permittee is authorized to discharge from outfail(s) serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below: onthl' er.a• Flow 16.0 MGD BOD, 5-day, 20°C2 (April 1 - October 31) 5.0 mg/I BOD, 5-day, 20°C2 (November 1 - March 31) 10.0 mg/I TSS2 30.0 mg/I NH3-N, (April 1 - October 31) 2.0 mg/I NH3-N, (November 1 - March 31) 4.0 mg/I Dissolved Oxygen3 Fecal Coliform (geometric mean) 200/100 ml Temperature Total Residual Chlorine Conductivity Total Nitrogen (NO2+ NO3 + TKN) 6.0 mg/I 4 Total Phosphorus 1.0 mg/I Chronic Toxicity 5 Cadmium Cyanide Lead Mercury 6 Antimony Beryllium Chloride Chloroform Notes: 5 Chronic Toxicity (Ceriodaphnia), P/F, no significant mortality at 19%; March, June, September, and December; See Supplement to Effluent Limitations and Monitoring Requirements Page - Special Conditions for flow of 16.0 MGD to South Fork Catawba River. 6 The detection limit for mercury is 0.2 ug/I. If the measured levels of mercury are below the deection limit, then the measurement is considered to be zero for purposes of compliance evaluation and should be reproted on the DMR as < 0.2 ug/I. The pH shall not be Tess than 6.0 standard units nor greater than 9.0 standard units and shall be monitored daily at the effluent by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. eekly' Daily Measurement !:era`• e Maximum °Fre o uenc; 7.5 mg/I 15.0 mg/1 45.0 mg/i 400/100 ml 10.8 ug/I 27.0 ug/I 134.9 u•/I 28.0 ug/I 27.Mug/1 118.7 ug/I 182.3 ug/I Continuous . Daily Daily UIREMENtS Recording Composite Composite • Daily Composite Daily Composite Daily Composite Daily Grab Daily Grab Daily Grab Daily Grab Daily Grab Weekly Composite Weekly Composite �-= Quarterly Composite Weekly Composite Weekly Grab Weekly Weekly Composite ;ample., ocation1. I or E E,I E,I E, I E,U,D E E,U,D E U,D E Grab 2/month Composite 2/month Composite 2/month Composite 2/month Grab Sample locations: E - Effluent, I - Influent, U - Upstream at City offtastonia Pump Station, D - Downstream at a) Spencer Mountain Dam pool at dam, b) NCSR 2003, and c) 1.5 miles below tailrace at powerlines. Instream monitoring shall be grab samples taken 3/wk (Jun -Sep) and 1/wk (Oct -May). These monitoring frequencies specified above for dissolved oxygen, temperature, conductivity, and pH are to be used only when experiencing operational problems with the YSI 6-series system. It is assumed 2 that when the YSI system is operating properly, these four parameters will be monitored continuously. a The monthly average effluent BOD5 and Total Suspended Solids concentrations shall not exceed 15% of the respective influent value (85% removal). The daily average dissolved oxygen effluent concentration shall not be less than 6.0 mg/I. 4 TN limit applies only from April 1 through October 31. DEHNR/DWQ FACT SHEET FOR NPDES PERMIT DEVELOPMENT NPDES No. NC0020184 Applicant/Facility Name: Applic4nt Address: Facility Address: Permitted Flow Type of Waste: Facility/Permit Status: Facility Class: County{{ Regional Office: USGS :opo Quad: Stream Nharactclistics: Receiving Stream Stream lassification Subbasi Drainag Area (mi2): Summer 7Q10 (cfs) Winter Q10 (cfs): Averag Flow (cfs): IWC Lo gCrk @ 8.0 MGD(%): ``. IWC(Sib- rk @ 8.0 MGD(%): TVVSFk. \ 16.3 M ,D0:1:i: Wastelc d •.11 �. may^. , i.ii,.,..«v,.._,�.iilTl.u"\' City of Gastonia/Long Creek WWTP P.O. Box 1748, Gastonia, NC 28053-1748 Spencer Mountain Road, Gastonia 8.0/16.0 MGD Domesti c-40%/Indus-60% Existing/Renewal IV Gaston Mooresville G 14NW Long Creek/South Fork Catawba River C/WS-V 030836 6.4/558 109 11'/200 518/653 81 10 19 Monitoring and limits will remain the same for the majority of parameters in the permit. Oxygen consuming wastes have generally not been a problem. Lake Wylie continues to have proplems with nutrients and therefore the phased total nitrogen and total phosphorus limits will remain in the permit. Three reasonable potential analyses were conducted corresponding to the three different flow and discharge location scenarios. Conclusions from the three analyses follow: 1. 8.0 MGD - Long Creek: cadmium, cyanide, lead, mercury, and nickel will be limited. 2. 8.0 MGD - South Fork Catawba River: cadmium, cyanide, and mercury will be limited. 3. 16.0 MGD - S. Fork Catawba River: cadmium, cyanide, and mercury will be limited. Gastonia has concern with meeting metals limits on a consistent basis and they believe Long Creek WWTP would be less likely to violate metals limits if the NPDES permit had weekly averages as well as daily maximum values. Thus, the Division agreed to add weekly averages to the NPDES permit for limited parameters. Because hromium, copper, lead, nickel, silver, and zinc are required in the pretreatment Long Term Monitoring Plan (LTMP), monitoring for these parameters will not be required in the NPDES permit. Page 1 of 3 Long Creek WWTP has a Quarterly Chronic Pass/Fail Toxicity test with an 81% effluent concentration limit. They are under a SOC 8/21/95-11/30/97. The SOC requires them to conduct more extensive toxicity testing in at attempt to quantify the toxicity and identify possible sources of toxicity. Thus, more recently they have conducted toxicity tests using graduatO effluent concentrations (22,36,60,80,100). From January 1993 to the present, Long Creek WWTP failed all of their toxicity tests except 9/93 and 12/95. Gastonia submitted a Toxicity Reduction Evaluation (TRE) quarterly progress report (July 1996) aid Aquatic Toxicology (AT)'s concerns are summarized below. AT notes that the THE report does not document any actions undertaken to investigate/reduce and/or eliminate causative toxicants in Long Creek WWTP wastestream. AT inquired as to status of pilot Testing at Long Creek WWTP. AT emphasizes facility's ability to consistently meet its chro is permit limitation even though the facility is actively involved with expansion. Long C eek has undertaken several positive actions including: trunkline sampling, require ent for all SIUs to conduct chronic refractory screenings to meet pretreatment progr requirements, mail out of greater than 400 industrial waste surveys, in -plant "day - of -week toxicity monitoring, and treatability testing. AT further states that treatment technol gies at Catawba Facility may not necessarily be appropriate at Long Creek WWTP. See toxi ity report for actual toxicity results. Instream Monitoring Instream monitoring occurred at upstream station at NCSR 2264 and downstream station NCSR 2003. Instream data was examined from January 1994 through May 1996. The data sunmimaries below refer to monthly averages. - Dissolved oxygen dropped from the upstream to the downstream station as would be expected. However, the lowest DO value was only 7.0 mg/1 (8/95). - BOD values were generally higher downstream than upstream, but BOD monitoring may not be n cessary since DO is monitored instream. - The majority of pH values were in the vicinity of 7.0. A few extreme pH values in recent months 1.2 (3/96-downstream), 5.5 (1/96-downstream), and 2.1 (12/95-upstream) may be cause f concern and reason to continue to monitor pH instream. - Fecal c liform values ranged from 113/100 ml to 6929/100 ml (both measured at the downstre m station) and were lower down- than upstream more than half the time. - Conduc ivity values were higher downstream than upstream which is expected given the discharg of wastewater containing metals and ions into the receiving water. - The ma ority of the ammonia -nitrogen values were below 0.10 mg/1 upstream and concentrations ranged from below 0.10 mg/1 to 2.34 mg/1 (2/94) downstream. Instream data indicate the Long Creek WWTP is not having an adverse impact on the receiving water quality. Therefore, instream monitoring for BOD5 and fecal coliform will be elimin ted and instream monitoring for ammonia -nitrogen will be changed to total nitrogen t provide a greater amount of information on nutrients associated with nitrogen. The Division received Gastonia's instream monitoring modification request to use the YSI 6-series syxstem for continuous instream monitoring, move the upstream monitoring station location, ind delete fecal coliform instream monitoring on April 24, 1996. The Division concurs vvith Gastonia's proposed instream monitoring modification, but will continue to specify th original monitoring frequencies in the permit. Therefore, should the system experienc problems, it is expected that the monitoring frequencies specified in the permit would se a as a default. The Division also has no problem with relocating the upstream monitorin location and this new location will be specified in the proposed permit. Page 2 of 3 perms 1. Re locati `Proposed Schedule for Permit Issuance Draft Permit to Public Notice: 10/09/96 Permit Scheduled to Issue: 11/25/96 State Contact If you ave any questions on any of the above information or on the attached permit, please contact Paul Clark at (919) 733-5038 ext. 580. Copies of the following are attached to provide further information on development: sonable potential analyses for three different flow and discharge n scenarios. `. L` AI 3. Proposed Special Llllg pei ii11L ClliuCiiL SneeLS, and draft permit. Schedule Requirements and additional comments from Reviewers: Rec. Review:d Regional Permits mmended by: Date: by Supervisor: Date: & Engineering: Date: Page 3 of 3 N0002O184 Summary Augu t 15, 1996 Nove ber 15, 1996 (revised) City oGastonia/Long Creek wastewater treatment facility has applied for renewal of their discharge permit which allows the facility to discharge 8.0 and 16.0 MGD. This permit allows for the following discharge scenarios: 1. Disoharge 8.0 MGD into Long Creek 2. Discharge 8.0 MGD into South Fork Catawba River 3. Discharge 16.0 MGD into South Fork Catawba River Long 1 reek WWTP will relocate their discharge point from Long Creek to South Fork Cataw a River prior to expanding from 8.0 to 16.0 MGD because Long Creek would not be ab1: to assimilate a Long Creek WWTP discharge of 16.0 MGD. City o Gastonia has also applied for a permit modification. The modification would allow the use of automated sampling equipment at Long Creek WWTP to conduct instream monito ng and includes a relocation of the upstream monitoring location and elimination (or red ced) instream monitoring for fecal conform. Decom issioning Catawba WWTP and constructing a pump station so that Catawba WWT''s wastewater goes to Long Creek makes sense environmentally, but it would cost S9 mill on. City of Gastonia has already received at least S 15 million from the State Const ction Loans and Grants Section to help them fund some other wastewater treatment projects which may make obtaining future loans problematic. . Catawb Creek Decommissioning/Long Creek expansion proposed schedule follows: 9701: atawba Creek decommissioning plans and specifications submitted. 02. ' ong Creek expansion to 9.0 MCD complete I u : 1 elocation sewerline to be completed. 9707: ong Creek filters complete. 9712: ong Creek expansion to 16.0 MGD complete. 2001: pastonia will begin to examine Long Creek expansion from 16.0 to 24.0 MGD 2005: ong Creek expansion from 16.0 to 24.0 MGD becomes operational. Long C eek WWTP wastewater is currently treated through new portion of WWTP. Capacit of new portion of WWTP is 9.0 MGD. After older section of WWTP is renovat d an additional 7.0 MGD will be added resulting in a total of 16.0 MGD. Pease C nsultants prepared a report (5/31/96) on the decommissioning of Catawba Creek WWTP 'hich supported the decommissioning as cost-effective. Pease references the SVBK r port and mentions five main areas of cost savings. The statements provided in Pease re ort are summary statements and SVBK report should be examined for specifics. Informa ion compiled by the City of Gastonia in response to their lawsuit with the America Canoe Association (7/22/96) indicates that the City of Gastonia has obtained authoriz tion and funding to decommission the 40 year old Catawba Creek WWTP and construe a pump station and force main to divert the flow from the Catawba Creek WWTP to the ne er Long Creek WWTP. By decommissioning the Catawba Creek WWTP, the City is s pporting the State concept of regionalization of WWTPs and alleviating an eutrophi system. Catawba Creek WWTP receives wastewater from various industries that will be received at Long Cr ek WWTP (following the expansion). However, even with the increase in the type and umber of industries discharging to Long Creek, presently, the Long Creek NPDES ermit requires more extensive monitoring than the Catawba Creek WWTP permit. Page 1 of 8 N00020184 Summary August 15, 1996 November 15, 1996 (revised) City of Gastonia's Catawba Creek, Crowders Creek, and Long Creek WWTPs discharge into different arms of Lake Wylie and are all experiencing the following problems: • 1. Toxicity: the three facilities receive wastewater from several industries. 2. Nutrients: Point and nonpoint sources of pollution contribute nutrients to Lake Wylie. There are management strategies unique to Long, Catawba, and Crowders creeks that require point dischargers on these waters to abide by certain limits. The existing 8.0 MGD wastewater treatment facility consists of influent lift station, a mechanical bar screen and grit removal, primary clarifiers, trickling filters, polishing ponds with floating aerators, dual chlorine contact chambers with dechlorination, a static aerator, sludge lagoons, and sludge drying beds. Facilities under construction for expansion to 16.0 MGD wastewater treatment facility include mechanical bar screens, cyclone grit removal, anaerobic/anoxiJoxic basins, caustic and alum feed, secondary clarifiers, tertiary filters, chlorine disinfection with dechlorination, static post aeration, and sludge digesters. Industries (all SIUs) discharging to Long Creek WWTP include: 1. Armtex, Inc.: product - textile/domestic, rm: fiber reactive dyes, softners, wwc - BOD, TSS, NH3-N, COD, Cu, Zn, and Ni. 2. Danager Tool Group: product - metal finisher/domestic, rm: alloy steel ASTM, alkaline cleaners, plating chemicals, wwc - BOD, TSS NH3-N, COD, Cu, Zn, and Ni. 3. Fleishmann's Yeast: product - yeast/domestic, rm - molasses, starch, ammonia, phosphoric acid, growth additive (An, SO4. MgSO4), wwc - BOD, TSS NH3-N, COD,' Cu. Zn, and Ni. 4. Freightliner Corporation: product - metal finisher/domestic, rm - ??, wwc - BOD, TSS NH3-N, COD. Cu, Zn, and Ni. 5. Lida Stretch Fabrics: product - textile/domestic, rm - fiber reactive dyes, disperse dyes, wwc - BOD, TSS NH3-N, COD, Cu, Zn, and Ni. 6. Globe Manufacturing Company: product - OCPSF/Domestic, rm - polyester resin, ethvlenedianie, toluene, wwc - BOD, TSS NH3-N, COD, Cu, Zn, and Ni. 7. Ithaca Industries: product - textile/domestic, rm - dyes, caustic cotton, synthetic yarns, wwc - BOD, TSS NH3-N, COD, Cu, Zn, and Ni. 8. Stabilus: product - metal finisher/domestic, rm - steel rod & tube stock, painting materials, wwc - BOD, TSS NH3-N, COD, Cu, Zn, and Ni. 9. WIX: product - filter/domestic, rm - metal, paper, paint, plastisol, oil, silicone glue, and solvents, wwc - BOD, TSS NH3-N, COD, Cu, Zn, and Ni. 10. Weyerhaeuser Corporation: product - boxes/domestic, rm - corn starch, water, draft paper, flexographic ink, sodium hydroxide. wwc - BOD, TSS NH3-N, COD, Cu, Zn, and Ni. 11. Wales Fabrics: product - textile/domestic, rm - dyes, caustic, acid finishing chemicals, cottons, wwc - BOD, TSS NH3-N, COD, Cu, Zn, and Ni. SIU: Significant Industrial User To be classified as a SIU, an industry must meet one or more of the following conditions: 1) Flow to POTW > 25,000 GPD 2) Flow to POTW > 5% of POTW's Maximum Allowable Headworks Loading (MAHL) 3) Industry is a classified Categorical Industry (CI) 4) Other - an industry may not meet nos. 1-3 listed above, but if there is a concern that the industry may adversely impact the.POTW, it can be classified as a SIU and thus a pretreatment permit is required. Only the SIU dischargers have pretreatment permits. Page 2 of 8 114 NC0020184 Summary August 15, 1996 November 15, 1996 (revised) Compliance Summary Cornpli violatio nce data was evaluated for the period July 1994 through June 1996 and the s are compiled on the following table: Parameter Limit Result Date Cyanide 6.2 ug/1 10.3 ug/1 9605 BODS 11.0 mg/1 • 11.7 mg/1 9604 Mercury] 0.012 ug/1 1.0 ug/1 9604 Cyanide 6.2 ug/1 70.0 ug/1 9604 Cyanide 6.2 ug/1 34.0 ug/1 9603 Mercury -0.012 ug/1 0.4 ug/1 9603 Cyanide 6.2 ug/I 12.8 ug/1 9602 Cyanide 6.2 ug/l 40.2 ug/1 9601 Mercury 0.012 ug/1 1.0 ug/1 9601 . Cyanide 6.2 ug/1 12.1 ug/1 9512 Mercury 0.012 ug/1 0.20 ug/1 9512 Cyanide 6.2 ug/1 7.4 ug/I 9511 Mercury 0.012 ug/1 0.20 ug/1 9511 Cyanide 6.2 ug/1 15.0 ug/1 9509 Mercury 0.012 ug/1 0.20 ug/1 9509 Cyanide 6.2 ug/1 30.0 ug/1 . 9508 Cyanide 6.2 ug/1 17.0 ug/1 9507 Mercury I 0.012 ug/1 0.25 ug/1 9507 Cyanide 6.2 ug/1 12.0 ug/1 9506 Cyanide 6.2 ug/1 10.0 ug/1 9505 Cyanide 6.2 ug/1 9.0 ug/1 9504 Mercury 0.012 ug/1 0.20 ug/1 9504 Cyanide 6.2 ug/1. 18.0 ug/1 9503 Cadmium 2.5 ug/1 3.7 ug/1 9503 Cyanide 6.2 ug/I 10.0 ug/1 9503 Cadmium 2.5 ug/1 - 4.0 ug/1 9501 Cyanide 6.2 ug/1 14.0 ug/1 9501 Mercury 0.012 ug/1 0.48 ug/1 9501 Cadmium 2.5 ug/1 4.0 ug/1 9412 Cyanide 6.2 ug/I 14.0 ug/1 9412 Mercury 0.012 ug/1 0.40 ug/1 . 9412 Cadmium 2.5 ug/1 3.0 ug/1 9411 Cyanide 6.2 ug/1 13.0 ug/1 9411 Mercury 0.012 ug/1 1.68 ug/1 9411 Lead 31.0 ug/1 131.0 ug/1 9411 Fecal Coli orm violations were not recorded - method of determining violations unclear. Long Cree • WWTP has a Quarterly Chronic Pass/Fail Toxicity test with an 81% effluent concentrati n limit. They are under a SOC 8/21/95-11/30/97. The SOC requires them to conduct m re extensivetoxicitytesting in at attempt to quantify the toxicity and identify possible so rces of toxicity. Thus, more recently they have conducted toxicity tests using graduated ffluent concentrations (22,36,60,80,100). From January 1993 to the present, Long Cree WWTP failed all of their toxicity tests except 9/93 and 12/95. Page 3 of 8 NC0020184 Summary August 15, 1996 November 15, 1996 (revised) Gastonia submitted a Toxicity Reduction Evaluation (TRE) quarterly progress report (July 1996) and Aquatic Toxicology (AT)'s concerns are summarized below. AT notes that the TRE report does not document any actions undertaken to investigate/reduce and/or eliminate causative toxicants in Long Creek WWTP wastestream. AT inquired as to status of pilot testing at Long Creek WWTP. AT emphasizes facility's ability to consistently meet its chronic permit limitation even though the facility is actively involved with expansion. Long Creek has undertaken several positive actions including: trunkline sampling, requirement for all SIUs to conduct chronic refractory screenings to meet pretreatment program requirements, mail out of greater than 400 industrial waste surveys, in -plant "day - of -week toxicity monitoring, and treatability testing. AT further states that treatment technologies at Catawba Facility may not necessarily be appropriate at Long Creek WWTP. See toxicity report for actual toxicity results. WLA Summary Monitoring and limits will remain the same for the majority of parameters in the permit. Oxygen consuming wastes have generally not been a problem. Lake Wylie continues to have problems with nutrients and therefore the phased total nitrogen and total phosphorus limits will remain in the permit. Three reasonable potential analyses were conducted corresponding to the three different flow and discharge location scenarios. Conclusions from the three analyses follow: 1. 8.0 MGD - Long Creek: cadmium, cyanide, lead, mercury, and nickel will be limited. 2. 8.0 MGD - South Fork Catawba River: cadmium and mercury will be limited. 3. 16.0 MGD -.S. Fork Catawba River: cadmium. cyanide, lead, and mercury .will be ----- limited. Gastonia has concern with meeting metals limits on a consistent basis and they believe Long Creek WWTP would be less likely to violate metals limits if the NPDES permit had weekly averages as well as daily maximum values. Thus, the Division agreed to add weekly averages to the NPDES permit for limited parameters. As stated in the Instream Assessment SOP, under routine analyses, chemical specific effluent limits are calculated to protect to the chronic no -effect level for aquatic life instream under 7Q10 conditions. Since most criteria reflect between 4 and 7 consecutive day exposure period assumptions, a weekly average of daily monitoring basis should protect against chronic effects. However, as a result of a DEM cost/frequency of monitoring study conducted in the early 1980's, a procedure was established whereby once/week or 2/month sampling would be required dependent on facility classification. Thus, generally, chemical specific toxic limits shall be placed in NPDES permits as a maximum daily allowable concentration in light of this reduced monitoring frequency. Higher daily maximum concentrations may be allocated if a facility agrees to conduct daily monitoring (5/week). Gastonia's existing daily maximum limits will become weekly average limits since as stated above these existing limits already protect against chronic effects. A new daily maximum limit (to protect against acute effects) is equal to one-half of the toxicant's FAV value (or the CMC value) multiplied by dilution. Page 4 of 8 • NC00 0184 Summary August 15, 1996 November 15, 1996 (revised) Parameter 1/2 FAV Daily Max Wkly Avg Daily Max Wkly Avg Daily Max Wkly Avg Value Long Long SFC8, SFCB SFC16 SFC16 (ug/l) (ug/l) Lug/l) fug) fug) (ug/l) iug/li Cadmi m 5.0 (a) _ 6.2 2.5 49.0 19.6 27.0 ' 10.8 ' Cyanid ' 22 27.3 _ 6.2 215.4 49.0 118.7 27.0 Lead ' 33.8 42.0 31.0 330.9 244.8 182.3 -3.0 134.9 Merc 2.4 (b) 3.0 (c) 0.015 3.0 (c) 0.117 (c) ' 0.065 Nickel 789 _ 979.9 (d) 109.3 9593.5(d) 861.5 5286.7(d) 474.8 Note01 for daily maximum and weekly average value data and calculations, please refer to the yeas nable potential analyses worksheets. Note02 values in italics are not limited in permit. Long: ischarge 8.0 MGD into Long Creek SFC8: ischarge 8.0 MGD into South Fork Catawba River SFC16: Discharge 16.0 MGD into South Fork Catawba River (a) EP federal criteria = 1.79 ug/l, but 5.0 ug/l should be used per DWQ/Planning Branch investi lion. (b) Val e is for mercury (II). There is no CMC/FAV for methylmercury, for which data indicate higher toxicity than mercury (II). (c) Bec use a violation of the daily maximum for mercury would automatically cause a violatio of the weekly average, the daily maximum is calculated by multiplying the weekly average by five and subtracting the weekly average limit from this value. In the case of merc , (5*0.015) - 0.015 = 0.060 ug/1 - Daily maximum (Long Creek 8.0 MGD) (5*0.11 ?) - 0.117 = 0.468 - Daily maximum (S. Fork Catawba River 8.0 MGD) (5 0.06 ,) - 0.065 = 0.078 - Daily maximum (S. Fork Catawba River 16.0 MGD). (d) A vi lation of the daily maximum for nickel would almost always cause a violation of the wee , y average, thus, the daily maximum is calculated by multiplying the weekly average !• y five and subtracting the weekly average limit from this value. In the case of Nickel, 5*109.3) - 109.3 = 437.2 ug/1 - Daily maximum (Long Creek 8.0 MGD) (5*861. ) - 861.5 = 3446.0 ug/1 - Daily maximum (S. Fork Catawba River 8.0 MGD) (5*474. ;) - 474.8 = 1899.2 ug/1 - Daily maximum (S. Fork Catawba River 16.0 MGD). Cadmiu (8.0 and 16.0 MGD flows) and cyanide (16.0 MGD flow only) will have only daily m. imum limits (will not have weekly averages) for the discharges to South Fork Catawb • River because the proposed daily maximum limits would be lower than their weekly . verage. Monito g requirements (no limit) will vary depending upon thedischarge scenario. Long C ek: Because chromium, copper, silver, and zinc monitoring are required in the pretrea ' ,i ent Long Term Monitoring Plan (LTMP), monitoring for these three parameters will not se required in the NPDES permit. South F. rk Catawba 8 and 16MGD: Because chromium, copper, cyanide, lead, nickel, silver, and zinc monitoring are required in the pretreatment Long Term Monitoring Plan (LTMP), monitoring for these three parameters will not be required in the NPDES permit. South Fork Catawba 16 MGD: Lead monitoring will be required in NPDES permit. Page 5 of 8 NC0020184 Summary August 15, 1996 November 15, 1996 (revised) APAM data review is summarized below: Parameter 5/94 (ug/1) 4/95 (ug/1) 6/95 (ug/1) Antimony • .19 nd , <20 Arsenic - ' 2.5 nd <2 Beryllium <5 nd 161 _ Cadmium 10.5 nd <2 Chromium 24.0 nd 7.4 Copper 35.7 nd 25.1 Lead 49 nd 42 Nickel 62 nd 21 Selenium 155.9 nd <2 Silver 3.5 nd <3 Zinc 105.0 nd 136 Barium 34.3 nd <100 Chloride ' 284,900 304,900 nd Cyanide 13.0 9. nd Fluoride 1280 1200 nd Chloroform 20 11 nd _ Di-n-butyl phthalate <50 64 nd Hexndecanoic Acid nd 6 (estimate) nd Oleic Acid nd 120 (estimate) nd Octadecanoic Acid nd 23 (estimate) nd nd=no data Many of the pollutants detected in the APAM are already monitored (and some limited) in the NPDES permit and/or the pretreatment Long Term Monitoring Plan (LTMP). Other parameters detected in the APAM were examined on a case -by -case basis to determine if monitoring would be required in the NPDES permit. Monitoring for hexndecanoic, oleic, and octadecanoic acids will not be required because the concentrations are estimates. Monitoring for Di-n-butyl phthalate will not be required because this compound is.a suspected laboratory contaminant. Parameter Detected Conc (ug/l) WQ Standard (ug/1) Standard Type Antimony (ug/1) 19, <20 14/4300 W&OC/OC Arsenic (ug/l) 2.5 50 Aquatic Life Beryllium (ug/l) 8.8 0.117/0.0068 Human Health/WS Selenium (ug/l) _ 155.9 5 - Aquatic Life Barium (ug/1) 7.8 1000 Water Supply Chloride (mg/1) 285,385 230 AL/ 250 Aq. Life/WS Fluoride (mg/1) ' 1.28,1.2 1.8 Aq. Life Chloroform (ug/l) 20,11 5.7/470 W&OC/OC Page 6 of 8 NC0020184 Summary Augu t 15, 1996 Nove ber 15, 1996 (revised) Long Creek Discharge Monit ring will not be required for those compounds in the table above that have standards or fede al criteria that are human health based or are only applicable to water supply classifi d waters because Long Creek is a Class C stream. Therefore, monitoring will not be req ired for beryllium or barium. Antimony monitoring will not be required because the detecte concentrations are less than the applicable federal criterion (4300 ug/1 is applicable, 14 ug/1 is not). Arsenic monitoring will not required because the concentration detected is less th the water quality standard. Selenium monitoring will not be required because althou the concentration detected is greater than the water quality standard, selenium is monito ed in the LTMP. Chloride monitoring will not required because the concentrations detecte are only greater than a water supply standard and an action level. There is no water q ality standard for chloride applicable to just Class C waters. Water treatment facilitie add fluoride to the water. Fluoride concentrations in potable drinking water are probabl similar to the concentrations in the above table. Fluoride monitoring will not be requires . Chloroform monitoring will not be required because the detected concentrations are less than the applicable federal criterion (470 ug/1 is applicable, 5.7 ug/1 is not). South • rk Catawba River Dischar e South •rk River is a Class WS-V stream. Antimony, beryllium, chloride, and chloroform monito ng will be required because the concentrations detected are greater than the water quality tandards for these parameters. However, they will not be limited because there was only one detection in the case of each parameter. Arsenic monitoring will not required because the concentration detected is less than the water quality standard. Selenium monitoring will not be required because although the concentration detected is greater than the wat quality standard, selenium is monitored in the LTMP. Barium will not be - monitor d because the detection concentration is almost three orders of magnitude less than than the ater quality standard. Water treatment facilities add fluoride to the water. Fluoride concentrations in potable drinking water are probably similar to the concentrations in the a ove table. Fluoride monitoring will not be required. The pro osed Long Creek WWTP discharge location on South Fork Catawba River at the mouth o Long Creek is about 0.2 miles upstream of the Duke Power Spencer Mountain hydro p wer dam. The South Fork Catawba River is Class WS-V at this location. A level B analysis demonstrated that the proposed discharge point, although not ideal, is an acceptable location for the discharge of 16.0 MGD of treated wastewater. Alternative discharge points include remaining in Long Creek and moving South Fork below th Spencer Mountain Dam tailrace. Long Creek is already heavily used for the assimilat on of wastewater. If the proposed discharge was released to Long Creek the IWC would b 89%, whereas moving the discharge would result in a Long Creek IWC of 46%. Due to t pography and the 1.5 mile Duke Power hydro project, considerable effort would be requir d to pipe the effluent below the Spencer Mountain Dam tailrace. Therefore, the effort mi ht be better spend in advanced treatment. The BO 5, NH3-N, and DO limits in the proposed permit (for all three discharge scenarios were developed as a result of the level B analysis conducted during the previous permit repewal and will not change from the existing permit. The Division recommends Gastonia xamine the possibility of using a diffuser to ensure rapid mixing and dispersion of the eff uent across the South Fork Catawba River prior to Spencer Mountain Dam. Page 7 of 8 NC0020184 Summary V August 15, 1996 November 15, 1996 (revised) Instream Monitoring Instream monitoring occurred at upstream station at NCSR 2264 and downstream station NCSR 2003. Instream data was examined from January 1994 through May 1996. The data summaries below refer to monthly averages. - Dissolved oxygen dropped from the upstream to the downstream station as would be expected. However, the lowest DO value was only 7.0 mg/I (8/95). - BOD values were generally higher downstream than upstream, but BOD monitoring may not be necessary since DO is monitored instream. - The majority of pH values were in the vicinity of 7.0. A few extreme pH values in recent months 11.2 (3/96-downstream). 5.5 (1/96-downstream), and 2.1 (12/95-upstream) may be cause of concern and reason to continue to monitor pH instream. - Fecal coliform values ranged from 113/100 ml to 6929/100 ml (both measured at the downstream station) and were lower down- than upstream more than half the time. - Conductivity values were higher downstream than upstream which is expected given the discharge of wastewater containing metals and ions into the receiving water. - The majority of the ammonia -nitrogen values were below 0.10 mg/1 upstream and concentrations ranged from below 0.10 mg/1 to 2.34 mg/ (2/94) downstream. Instream data indicate the Long Creek WWTP is not having an adverse impact on the receivingwater quality. Therefore, instream monitoring for BOD5 and fecal coliform will be eliminated and instream monitoring for ammonia -nitrogen will be changed to total nitrogen to provide a greater amount of information on nutrients associated with nitrogen. The Division received Gastonia's instream monitoring modification request to use the YSI 6-series system for continuous instream monitoring, move the upstream monitoring station location, and delete fecal coliform instream monitoring on April 24, 1996. The Division concurs with Gastonia's proposed instream monitoring modification, but will continue to specify the original monitoring frequencies in the permit. Therefore, should the system experience problems, it is expected that the monitoring frequencies specified in the permit would serve as a default. The Division also has no problem with relocating the upstream monitoring location and this new location will be specified in the proposed permit. Finally, as is indicated in a previous paragraph, instream monitoring for fecal coliform will no longer be required. Page 8 of 8 SOC PRIORITY PROJECT: Yes No X If Yes, SOC No. EMC WQ 93-15 To: Permits and Engineering Unit Water Quality Section Attention: Jeanette Powell Date: April 25, 1996 NPDES STAFF REPORT AND RECOMMENDATION County: Gaston Permit No. NC0020184 PART I - GE ' RAL INFORMATION 1. Facility and Address: Long Creek WWTP City of Gastonia P.O. Box 1748 Gastonia, NC 28053 2. Date o ' Investigation: April 25, 1996 3. Report repared By: Todd St. John 4. Person • Contacted and Telephone Number: Mike O'Hara, ORC (704) 866-6991 5. Directi • ns to Site: From the intersection of Highway 279 and Old Spencer Mountain Road, travel east on Old Spencer Mountain Road approximately 1.4 miles. The treatment Plant is located at the end of this road. 6. Disch ge Point(s). List for all discharge points: Latitud : 3 5° 18' 25" Longitude: 81° 08' 04" Attach U.S.G.S. map extract and indicate treatment facility site and discharge point on map. U.S.G. . Quad No.: F14SW U.S.G.S. Name: Gastonia North,,NC 7. Site s and expansion are consistent with application? Yes X oIf No, explain: 8. Topog aphy (relationship to flood plain included): The site is moderately sloped and the influent area appears to be in the flood plain; however, large dykes have been constructed to protect znis area. 9. Location of nearest dwelling: None within 500 feet. 10. Receiving stream or affected surface waters: Long Creek a. Classification: C b. River Basin and Subbasin No.: 030836 c. Describe receiving stream features and n pertinent downstream Typical classcreek is C uses approximately 20 feet wide with y rocky bottom. downstream. PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. a. Volume of wastewater to be permitted: 8.0 MGD (Ultimate Design Capacity) b. What is the current permitted capacity of the wastewater treatment facility? 8.0 MGD c. Actual treatment capacity of the current facility (current design capacity)? 8.0 MGD d. Date(s) and construction activities allowed by previous Authorizations to Construct issued in the previous two years: An A to C was issued December 30, 1994, for an interim septage disposal system. The plant is currently being upgraded to 16.0 MGD. e. Please provide a description of existing or substantially constructed wastewater treatment facilities: The current facilities include an influent lift station, a mechanical bar screen and grit removal, primary_ clarifiers, trickling filters, polishing ponds with floating aerators, dual chlorine contact chambers with dechlorination, a static aerator, sludge lagoons, and sludge drying beds. f. Please provide a description of proposed wastewater treatment facilities: The facilities under construction include mechanical bar screens, cyclone grit removal, anaerobic/anoxic/oxic basins, caustic and alum feed, secondary clarifiers, tertiary filters, chlorine disinfection with dechlorination, static post aeration, and sludge digesters. Possible toxic impacts to surface waters: This facility serves various industries which could discharge toxic effluent. g. Page 2 h. Pretreatment Program (POTWs only): Yes in development: should be required: approved: X not needed: 2. Residualshandling and utilization/disposal scheme: a. If residuals are being land applied, please specify DEM permit no.: WQ0001793 R siduals Contractor: Amsco T lephone No.: (919) 766-0328 b. Residuals stabilization: PSRP: c. L d. 0 3. Treatmen Class IV. ndfill: N/A her disposal/utilization scheme (specify): N/A plant classification (attach completed rating sheet): Plant Classification will remain 4. SIC Code(s): 4952 Wastewater Code(s) of actual wastewater, not particular facilities, i.e., non -contact cooling water discharge from a metal plating company would be 14, not 56. Primary: 01 Secondary: Main Treatment Unit Code: 04503 PART III - OTHER PERTINENT INFORMATION 1. Is this f cility being constructed with Construction Grant Funds or are any public monies involved (municipals only)? Yes 2. Special onitoring or limitations (including toxicity) requests: None 3. Import t SOC, JOC or Compliance Schedule dates: (please indicate) Date Submiss on of Plans and Specifications 7/30/94 Begin C nstruction 4/30/95 Comple a Construction 9/30/97 Page 3 4. Alternative Analysis Evaluation: Has the facility evaluated all of the non -discharge options availa le. Please provide regional perspective for each option evaluated. Spray 'gation: N/A Connection to Regional Sewer System: N/A Subs Other- 5. Other PART IV-E ace: N/A )isposalOptions: N/A pecial Items: N/A TALUATION AND RECOMMENDATIONS The City of Gastonia has requested renewal of its NPDES permit for the Long Creek WWTP. This facility is currently under an SOC and has met all of the scheduled requirements to date. This facility appears to be well run and maintained; therefore, this Office recommends renewing the NPDES permit. Signature of Repo Water Qualit! 2 Date Preparer .' Regional Supervisor Page 4 DIVISION OF ENVIRONMENTAL MANAGEMENT August 11, 1994 MEMORANDUM TO: Rex Gleason FROM: Jacquelyn M. Nowell THRU: Don S Ruth Swanek 2C5 Carla Sanderson SUBJECT: Instream Assessments for the City of Gastonia Wastewater Treatment Plants Catawba Creek WWTP - NC0020192 - (SOC # 93-017) Long Creek WWTP - NC0020184 - (SOC # 93-015) Crowders Creek WWTP - NC0074268 - (SOC # 93-016) Gaston County Summary The Technical Support Branch has reviewed the request for instream assessments for the City of Gastonia's WWTPs . The City is requesting Special Orders of Consent (SOCs) for all facilities for whole effluent toxicity problems and noncompliance with limits for metals and other toxics. In addition, each facility is requesting an increase in wasteflow during the life of the SOC, however this flow will be 100% domestic and there will be no increase in allocated BOD. Based on this, the wasteflow at the Gastonia plants may be increased in the following amounts: SOC Flow (MGD) Catawba Creek WWTP 1.973 Long Creek WWTP 0.817 Crowders Creek WWTP 1.371 Existing design flows and instream waste concentrations of the three plants are as follows: pesign Qw IWC Catawba Creek WWTP 9 MGD 90% Long Creek WWTP 8 MGD 80.5% Crowders Creek WWTP 6 MGD 42% The Catawba Creek plant has consistently experienced toxicity problems since the implementation of toxicity testing, however the Long Creek and Crowders Creek plants have just recently started to have problems. Increased pollutants from industries tying on to the plants are evidently where the toxicity problems are originating but additional time is needed to correct the situation. MRO staff have indicated that the request for chronic toxicity monitoring - full range testing has already been reviewed and approved by the Environmental Sciences Branch, and Technical Support will concur with their recommendation. Memo to Rex Gleason page 2 Discussion G = has also requested monthly average limits for the metals instead of daily maximum limits that have been assigned in the NPDES permit The City has also requested SOC limits for several metals however the staff of the Mooresville Regional Office (MRO) does not think that SOC limits for all the requested metals are warranted. The MRO recommended daily maximum limits for the Gastonia WWTPs are as follows: Catawba Creek Cyanide 27 Nickel 205 Cadmium 12 Long Creek Crowders Creek 10 nr 210 nr 8 12 The Instream Assessment Unit has reviewed 1994 effluent data from all three facilities an has determined that the following metals limits could be recommended in the SOCs for th Gastonia facilities. The Division can offer Gastonia the option of limits permitted ' weekly averages and higher daily maximum limits. The daily maximum limit could be es blished to provide protection from acute toxic effects. Compliance with the weekly average limit is determined by the average of the daily samples for that week. For the purposes of this calculation, samples listed at less than analytical d tection will be assumed to be zero. The permittee may choose to collect 5 samples for the week and base the number of analyses run on the outcome of the first sample. If a first sample is in compliance with the weekly average limit, then no more analyses n be run for that week. However, if the first sample is above the weekly average, the more samples should be analyzed and the permittee must comply with both the weekly verage and daily maximum limits. If this option is implemented, the recommend metals limits for each of the plants would be as follows: Cyanide Nickel Cadmium Cyanide Nickel Cadmium Cadmium Weekly Avg. 5.5 µg/1(WQ) 97 µg/1 (WQ) 2.2 µg/1(WQ) Weekly Avg. 6.2 µg/1(WQ) 109 µg/1(WQ) 2.5 µg/1(WQ) Daily Maximum mil 388 µg/1 5.5 µg/1 Daily Maximum 25 µg/1 436 µg/1 6.2 µg/l Weekly Avg. Daily Maximum 4.8 µg/l (WQ) 12 µg/1 review of the effluent data for all the facilities and discussion with MRO staff, Assessment Unit recommends the following monitoring requirements for the Gastonia plants. The exceedance of allowable concentrations for parameters Memo to Rex Gleason page is not no that substan follows: y recommended, in those cases we suggest that effluent monitoring only for is placed in the SOC. Our recommendations for the Gastonia SOCs are as Long reek WW1? SOC requirement Cyanide monitor Nickel monitor Cadmium monitor SOC requirement Cyanide monitor Nickel monitor Cadmium monitor SOC requirement Cadmium monitor If there any questions concerning these recommendations, please contact me. cc: Kent iggins Dave Goodrich Cen ' : Files File DIVISION OF ENVIRONMENTAL MANAGEMENT June 2, 1994 Memorandum To: Ruth Swanek From: Prepared By: Subject: D. Rex Gleason Kim H. Colson '•,i City of Gastonia Long Creek WWTP SOC # 93-015 Gaston County, NC This Office request that the Instream Assessment Unit conduct an instream assessment for the subject facility's request for interim effluent limits for Nickel, Cyanide, Cadmium, Chromium, Lead, and Mercury (request enclosed). The facility has also requested that daily maximum limits for these parameters be changed to a monthly average. This Office does not recommend any interim limits for Chromium, Lead, or Mercury. Since the facility has not reported any violations for Chromium, and reported only 1 violation for Lead and 2 violations for Mercury in the past year, interim limitations do not appear to be needed. This Office would most likely recommend maximum interim limits for Nickel of 210 ug/1, Cyanide of 10 ug/1, and Cadmium of 8 ug/1 (all daily maximum). Please evaluate the facility's proposed interim limits and his Office's suggested interim limits with regard to potential instream affects. Also advise on other possible alternatives to monthly average limits, such as weekly average / daily maximum limits. If you have any questions concerning this matter, please advise. Attahment cc: Jeff Bouchelle, Facility Assessment Unit ZEQUEST FORM FOR INSTREAM ASSESSMENT FOR 67b SOC NAME OF FACILITY: Gastonia - Long Creek WWTP COUNTY: Gaston REGION: Mooresville DESIGN FLOW: 8.0 MGD RECEIVINe STREAM: Long Creek SUBBASIN: 030836 BACKGROU D DATA: A. Why is SOC needed? The facility can not comply with effluent limitations for Chr•nic Toxicity, Nickel, Cadmium, Cyanide. B. His uory of SOC requests: 1. Monthly average waste flow prior to any SOC: 5.2 MGD. Time period averaged: 4/93 through 3/94. 2. Previously approved SOC's: N/A 3. Flows lost from plant (facilities that have gone off line): None known within last year. 4. Current SOC Flow request: 0.817 MGD 5. Total plant flow post-SOC (sum of original flow and SOC flow minus losses): 6.0 MGD 6. Is this an accurate flow balance for plant? Yes. CURRENT SOC REQUEST: A. Req ulest is for domestic or industrial waste? If it is a co •ination, please specify percentages. Domestic. B. Wha type of industry? N/A C. The region proposes the following SOC limits: Chr•1ic Toxicity Monitor only - full range Nickel 210 ug/1 Cad ium 8 ug/1 Cyanide 10 ug/1 D. What is the basis for these limits? The limits were based on previous data taking into consideration that the facility sho ld be reducing peaks through continued pretreatment controls. • DEPARTMENT OF PUBLIC WORKS A D UTILITIES May 2, 994 Mr. Rex Gleason Regional NC Dept. Div. of 919 Nort Mooresvi Referenc 7 Subject: Dear Mr. WEPT. Of A1IRONiVMFNT, HF.ALTfh 1 1994 r.'rit!tt tit �� P. O. BOX 1748 G►''�S�� ii y,,�� � �. Gastonia, siTortli fQ mann Z8053-1748 N.C- �N�- oV . ill �Nh.jr�nsov` MAY 2 A994 *WailWitaittli 4% 1Iif of Gastonia Quality Wateffigiihr of EHNR nvironmental Management Main Street le, N.C. 28115 Long Creek Wastewater Treatment NPDES Permit No. NC0020184 Gaston County, N.C. Plant Application for a Special Order By Consent Gleason: On June 1, 1993 the City of Gastonia submitted an Application for a Specia Order By Consent (SOC) for the referenced wastewater treatmen plant. Reviewing the Application we have had several discussio s and meetings with your staff to discuss the details and sched le which are included in the Application. We do appreciate the efforts of you and your staff in preparing an SOC f r the Long Creek Wastewater Treatment Plant; however, during the recent months, we have performed additional testing of the Plants influent and effluent to determine the causes of our toxicity problems. Although the toxicity source has not yet been identifies, potential sources could include metals, surfactants, and speci lty organic chemicals. These toxicants can originate in a com ination of industrial, domestic and/or uncontrollable sources i the Long Creek basin. Based on an intensive study by us and ou consultants, Aware Environmental Inc. we have discov- ered that sixty percent of the City's waste stream - which causes the metal and toxicity violations at the Catawba Plant - are generated by uncontrollable sources; therefore, the City will not be able t correct the violations until improvements have been made at t e wastewater treatment plant. Since uncontrollable sources may be a significant factor at the Long Creep Plant, we request that interim limits for toxicity and metals require monitoring only until the facility is upgraded. Page 2 Mr. D. Rex Gleason, P.E. Applicatiion for a Special Order By Consent Long Cree Wastewater Treatment Plant As previously stated, we have undertaken additional testing at the wastewater treatment plant; and these tests will be continued until violations are corrected or the sources have been identi- fied. U fortunately, with limits on metals and toxicity, the more tes ing we undertake, the more the potential exists for additional violations. The goal for the City is the same as it is for D M, and that is to meet the conditions of the NPDES Permit as soon as possible in order to stay in compliance. If modified limits of "monitoring only" cannot be approved by. DEM, it 's recommended that the following modified limits be approved: 1. Toxicity - monitoring only 2. Metals: (a) Nickel - Monthly (b) Cyanide - Monthly (c) Cadmium - Monthly (d) Chromium - Monthly (e) Lead - Monthly (f) Mercury - Monthly Average Average Average Average Average Average of 142.0 ug/1 of 18.0 ug/1 of 8.4 ug/1 of 62.0 ug/1 of 31.0 ug/1 of .36 ug/1 Also, it s requested that paragraph seven (7) of the proposed Special O der By Consent be rewritten as follows: "Any violation of terms of this Special Order By Consent, includ- ing paragraphs 2(d), 2(e), and 2 (h) above and attachment A shall terminate paragraph five (5) of this Order and any authorized additionali waste not previously connected to the system shall not thereafte be connected until the violations of this Special Order By C nsent have been corrected or satisfied.". Your favor ble consideration of this request will be appreciated. Should you have any questions, please do not hesitate to call me. Sincerely, CITY OF GA-TONIA CCeAuaka Donald E. armichael, P.E. Director o Public Works/Utilities ATTACHMENTT (1) John huler Colem n Keeter Sam W lkins CC: Instream Assessment Request for Gastonia WWTPs - Crowders Creek WWTP- NC0074268 SOC No. 93-016 - Catawba Creek WWTP - NC0020192 SOC No. 93-017 - Long Creek WWTTP - NC0020184 SOC No. 93-015 The City of Gastonia is requesting SOCs for all their treatment plants for toxicity and metals. Telecon w/ Kim Colson All Gastonia plants are failing toxicity. Catawba creek started failing in the late 80's, starting passing and then started consistently failling again. Town submitted THE for Catawba Creek, and are in the process of finalizing TREs for Long Creek and Crowders Creek facilities. All the language for chronic monitoring and test ranges have been reviewed by Aquatic Toxicity. Gastonia wants monthly averages for all the metals. Gastonia knows that the problems are from pollutants coming into the plants from the industries that are tying on. Crowders plant can ease the problem through source reduction. Long Creek plant wants to wait until they expand and relocate to SF Catawba River to start working an toxicity problems. Catawba will be using lime precipitation and new industrial waste surveys and headworks analysis. The City requested SOC limits for several metals and MRO reviewed the requests and made recommendations of their own. The tables below show the limits requested from Gastonia and the MRO, plus data from January to April, 1994 for the treatment plants 1/2 FAV Values Cn Cr Ni Cd Pb Hg 22 984 789 5 33.8 2.4 Crowders Creek WWTP Existing Limits Town Requested MRO Recommended Max. value reported Max. value predicted # Obs. for analysis Below Detection Catawba Creek WWTP Existing Limits Town Requested MRO Recommended Max. value reported Max. value predicted # Obs. for analysis Below Detection Cn Cr Ni mon. 120 211 -data not included- 9 17 27 2 35 84 26 3 300 930 26 3 Cd Pb 4.8 60 12 16 104 42 478 25 26 7 10 Cn Cr Ni Cd Pb 5.5 55 97 2.2 28 12.4 55 212 5 28 27 - 205 12 - 72 25 230 17 113 410 57.5 552 42.5 520 21 21 21 21 21 9 4 - 3 5 Instream Assessment Request for Gastonia WWTPs page 2 Long Crtek WWTP Cn Exiting Limits 6.2 Town Requested 18 M1O Recommended 10 Max. value reported 4 0 M. . value predicted 2 3 2 # • bs. for analysis 15 Bel • w Detection 9 7/5/94 Talked w/ after talkin _ w/ Rex. 7/26/94 Kim Colso called with MRO recommendations: Catawba reek- can't meet the limits recommended by TSB Cr Ni Cd _pb Hg 62 109 2.5 31 0.02 62 142 8.4 31 0.36 210 8 - - 56 210 14 85 0.3 140 441 67 408 0.51 16 19 16 18 23 2 1 6 7 21 Colson and related recommendations for the SOCs. Said that he'd call back Weekly Avg. Cyanide 5.5 µg/1(WOJ Nickel 97 µg/1(WQ) Cadmium 2.2 p.g/1 (WOJ Daily Maximum 22 µel 388 µg/l 5.5 µg/1 MRO want to keep daily maximum values. Doesn't want the Town to spend all their efforts sampling effluent to try to meet weekly avg limit. Would rather have Gastonia sample inflient and collection systems to track down the source of the cyanide in the discharge. ased on recent samples, Kim doesn't think that Catawba Creek could meet the Cd limits r ommended by TSB. MRO recommends following Daily Max. limits for the Catawba P t: CN 27 µg/1 Ni 205 µg/1 Cd 12 µg/1 The SOC be effective through Dec. 1995. Gastonia has submitted ATC for addition of lime ci i ation at the Catawba plant that will precipitate out a lot of metals. The toxicity problems arprobablybeingcausd byconcentrations of Ni, Zn, Cu and Cd. �, , Dechlonnation has also been added that will help some with the toxicity problem, but chlorine is not the major source of the tox problem. Crowders be given for 12µg/1. Long Creel reek -MRO recommends that the daily max. limit of 12 ug/1 for Cadmium this facility. TSB had recommended Wk avg of 4.8 14/1 and Da. Max. limit of MRO recommends daily max. limits: Cn 10 µg/1 Cd 8 µg/1 Ni 210 nil Instream Assessment Request for Gastonia WWTPs page 3 Kim thou t that since MRO recommended da. max. values for some parameters like Ni were less TSB recommended limits, that it was okay. However, for Cd, the TSB recommen ed limits could not be met by the plants during the SOC and that some leeway needed to given. Told him that I would probably still include the wk avg./da. max. limits in the instream assessment letter but that our officewould probably go along with whatever recommendations the MRO wanted to give for the SOC limits. 7/28/94 After review of Carla's comments on the first draft of the instream assessment, I'm recommending effluent monitoring for the parameters where the MRO recommendation exceeds the allowable concentration. In the cases where the MRO recommendation is lower than e calculated daily maximum limit, we will concur with their lower limit for the SOC. . . , , . i il ix4s9 a trc-6. ip/.. zs-4 I a _____ i s-)(s. 77. zer , 1 ------7.- f ! _ 1 i i • C.a._ erivt6va :: /z, I, (.4‘ ! ! e / f.z. Y i. 7 2.2.44 2 37 S. I, .... 17, 2.- .......,:ii... iz.), /zit a C /2.4 -t- 3) () . 77. .- -... W. tzof /2. y -. Ce..4i(Li <Ca G 144 gla r ,, z C. e 7g, ,-) -= / 7. Cot 1. - i 2 / Z./ - ,I t 3 f, f On ;41•141 -4 _ iv .1/4,1-0- ---t- . .,--7 ,---r-- _ 1 _ . WHOLE EFFLUENT TOXICITY TESTING 0[SELF-MONITORING SUMMARY] Mon, Apr 18. 1994 MAY'J(M KIT. A1K; S}iP OCT NOV Urc PACII.ITY REQUIREMENT YEAR JAN FEB MAR APR- .•- - - - - - - 90 -- RANKL1N win, PERM CHR LIM: 1.6% 91 _- ... .-- - -� PASS •-- PASS NC00215.17I001 Bcgin:8/21/92 I:f riucncy: Q PIP A MAR JUN SF.P DEC NonComp:S{NG13? 91 - „- M PASS ... ... PASS PASS Region: ARO Suhbnafn: I:IN(YI 93 PASS ('ounty:MACUN {'F:1.65 Specia! 94 -•- - - - - 1J3 7Q10: 157 IWC(%):1.6 Order ••- FAIL - - FAIL Y 90 FAIL FAIL PASSFAIL PERM CHR LIM:90% PASS - - FAILIL- PASS I.1NCOO2BV 8/001 1(�:3/1/ l D , WWTP 91 PASS - - - PASS - - PASS -CC002BWAKE Bcgin:3/1/9'! Frequency: Q P/F A SEP DEC MAR JUN rlonComp:SINGLE 92 - - FAIL - •,- - PASS P :� R1 ton: RRO Subbasin: CPJ 07 93 - - PASSPASS County: WAKE , S- AIL pF:1.20 Special 94 I,p Nq � - r. 7Q10: 0.00 IWC(%):100.00 Order. - PASS - - - 90 -_ .� _, ... FAILFAIL,F GASTON CO SCHOOLS- E GASTON 11S PERM CIIR LIM:99% (GRAB) 91 •- -- »_ - PASS - FAIL Coun y: AST Degin:811191 Frequency: Q :PA:hi A MAR JUN SEP DEC NonComp: 92 - -., FAIL NR FAIL PASSPASS --- PASS County:GAST()N Region: MRO Suhhasin: CTD33 93 FAIL � LATE PASS FAIL NMI NAM Sptcint 94 - - FAIL 00 Order. 7Q10: 0.0 IWC(%): 100.0 90 GAS'l'ON CO. SC:11(X)LS PERM CI1R LIM:9996(GRAD) NC0041327/001 Begin:10/1/91 lhnrpteney: Q P/I: A FM MAY AUG NOV NonComp: 92 1 County:GASTON Region: MRU Subbasin: CTD37 92 Pig: 0.007 special SOC: 8/23/91.12!I/94 NO TOX REQ 94 w Ordeal- FAIL 3-bt's PASS(s) LATE PASS 7Q10:0.0 {WC(%):100.0 FAIL FAIL -•- FAIL- PASS(s) -•' •. 90 - FAIL(s) - - L(s) 3 b1'sFAIL(s) GAS'1' 020192 001 B gi CK. 93 C1' PERM CHR MARLIMJU90% 91 FAIL(s) bt.F - FAIL -•- PASS( P/F A J[JN STsP DEC �lonComp:S1NC,L8 FAIL,bt -- - 1NVALSD,PAS -- FAIL - FAIL Nounty:G ?J001 gen:4/l/93 .: MROn0Y Q , . 92 - FAIL FAIL -- - FAIL FAIL FAIL ' PP:9ty:GASTON RtfAiot�: MRS - i Subb> CI;137 . 93 FAIL(s) FAtL(s) FAIL Special 94 FAIL FAIL- - - - -- 7Q10: 1.50 ' IWC(%):90.29 90 ,,, ... - - - �, - -. GAS'I'ONIA•CIIUWDI'RS CREEK PERM CIIR LIM: 61% 91 ,,. - M ,_ ... FAIL FAIL(s) Ili FAIL(s) Frequency: Q P/P A MAR JUN SEP DEC NonComp: _, PASS ,,, FAIL. Nounty: AS-T Dcgin:3/9/89 Y: 92 - "' PAS FAtI. fAtl. PASS : Co:o.ts )A51'ON Rcpion: MRO Subbasin; C"I i137r' 0'1 FAIL(*) ('AIL(1) PASS .. �p,•..ta! 94 FAIL FAIL ... Ih�: 0.0 Order: - - PASS,PI - bl. FAIL 7Q10:6.0 IWC(%):60.78 ... bl --- - (PASS-- ... PASS(s) 90 - PASS ,o PI)S (s)PASS.PFAIL(s)FAIL GASI'020I 4/001 0c n:2/1/9P PERM CI1R MALIMJUNib 01 - - FAIL(s) - - FAIL -- MAR SEP DEC NonCon1Q11Pt[1U3FAIL PASS '-FAIL Nounty: 4rool DOgin:2/{rJ3 Frequency: Q 1'A• 92 .. ' ,,I --AIL . PASS ,- FAIL. :: :s f County:GA "�ON .J;gljicu}t MRU Subbasin: CTD3tj 93 FAIL(s) --. !iFA1L•.' FAIL • : .� Special 94 FAIL - FAIL PP: 0:8.3.0 „. '.. ... ... 7Q 10: IWC{96):80.0 Unreal -•- �' - •-- �' ... (ill I.IGI1'1'IN(i SYS'1'I:MS 1'1?RM CIIR I,IM:61%(GRAD) „, --- NC0077771/001 Begin:l l/II93 Frequency: Q PIP A MAR 111N SEP DEC NonCornp:S1NG1.1: 91 ,,, - N County:l1ENDERSON Region: ARO Subbasin: FRD02 92 - - --- Special 94 - - N - -- 7Q0.1 Order: - PASS - - P,P 7N 10: 0.3 1\VC(96):61.0 80 FAtUFAI PASS PASS PASS ... FAIL FAIL PASS PERM CIIR LIM:72% PASS - PASS - PASS - GENERAL 07/001I'R{C NonComp:91 FAILPASS PASS -PASS NC County: 7/001 Dcgin:5/I/89 Frequency: Q WI' A JAN APR JUL OCT 92 PASS - --- FAIL - PASS tz+tt itR Special sin: l;RDn� 93 PASS -" PASSPASS County:)IlsND1'sRSON � ' Pis:0.S0 Special 94 FASL FAIL 6.36 - r. 7Q10: 0.30 IWC(96):72.1 Order -_ -PASS - 90 - - - LATE PASS PASS w PERM CIIR LIM:4896 (GRAB) -PASS / - PASSP •.. PASS (il'NIi076Iil.IiCTRICPASS - PASS r. NC0076643/001 Begin: I/29/90 Fier{uency: Q P/F A nut MAY AUG NOV NonComp: 92 PASS - PASS PASS Region: MRO Subbasin: Cl'D35 93 - PASSPASS County:CATAWBA Sr l'F:0.094 Special 04 ... PASS 7C)I0:0.I6 1WC(9h):48 Order: Y 1',a• l'J'n) llata Avaflnble 0 :.•,a+a.vterla'v Whiles - ■Ir{nili,•nerl a•nuv.nry,ltaa.•r study + I NU: a R { y: Q' _ t [ tcsnu must occur - ly; WD- Only w en di' Non(1)- D = ontinu t m n itoring nmuireertxnl I d . l�tt:c srcncy Monitorin f ucnc (aatterly: M- Mondaly: BM- Dinaontlsly: SA- Suntiannually; A- Annually: OWD- Only when discluuging: D- Uiscontintrcd ntonitoting nxluircnxnt:lS• Conducting indcpcn cat PI(RM a 1'rnnit s*rercnacnt I.I1= AdmivinF %We 1.Ctlrf • Targcl i lli•cin a Icrrxt nu„3yer«uin d 7Q10 n Receiving zlrrnoe law flow criterion (cJr:) I,rir : quarterly chronic tratincrr+' ;� Is Acutely upon (�ilg single Chronic Moat 8 I'1' + Permitted rla,v •• • -.l •1 I\ • •• : Ista'0.; .ana woo,... concentration•.....vIt • c t e nt highest eo e niiun: nt - Pcrfamacel by 1)11M Au Tux Gouty. •Pad test r , • , , ., ,. • , •,,�.. , ..,,,,, , .n • ••,•• 41va,d ahruav t'V • Chronic valor: l - Mutuality of ■i:, el tart• a, ,i..•..1.• 1.•.....1. To ,•anrutertl: II • Active but not tlisclaarrint:: i.Marc data available for month in question SIG = ORC signature needed TOXICANT ANALYSIS Facility Name Gastonia -Long Creek NC0020184 NPDES # Ow (MGD) 8 7Q10s (cis) , 109 1WC (%) .________. �10.21 Rec'ving Stream S F Catawba River Stream Class C FINAL RESULTS Cadmium Max. Pred Cw 67.2 Allowable Cw 19.6 Nickel Max. Pred Cw 441 Allowable Cw 861.5 Cyanide Max. Pred Cw 232 Allowable Cw 49.0 Chromium Max. Pred Cw 140 Allowable Cw 489.5 Lead Max. Pred Cw 408 Allowable Cw 244.8 Mercury Max. Pred Cw 0.51 Allowable Cw 0.1 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 6/23/94 PAGE TOXICANT ANALYSIS Facility Name Gastonia -Long Creek NPDES # NC0020184 Qw (MGD) _ 8 7010s (cfs) 3 IWC (%) ,._.._________.._..___.._ �_. ._____0.52 Long Creek __..8 Stream Class C FINAL RESULTS Cadmium Max. Pred Cw 67.2 Allowable Cw 2.5 Nickel Max. Pred Cw 441 Allowable Cw 109.3 Cyanide Max. Pred Cw 232 Allowable Cw 6.2 Chromium Max. Pred Cw 140 Allowable Cw 62.1 Lead Max. Pred Cw 408 Allowable Cw 31.0 Mercury Max. Pred Cw 0.51 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 6/23/94 PAGE " Crc c /6- GJw% f e6c = o? 5 u L I` 64v vim= /Z s_ 5 = 7.5-kj/e 41./1,4X=(s /01) /6?=5-1Z5-/0? C. FA(/ G 7,R9 tgg 14,- 6.Z = 1/- 6.7- / 15-0 (ha- - - e (5.), 6 Z - Z- .2/8641/e P` //& _ J/ 75/E . _ ( ,?/) - 3 1 = / aq u /., 339u /✓ -- 044 74gMr07 74NA4Y5/ $ L cacilityName =try oiC3a�is oma7Long Creek WWT Parameter= Cadmium I Parameter= Cyanide NPDES # = NC0020184 Standard= 21110 ; Standard = 5 µ54/l Ow (MOD) = 8 7010s (cfs)= 3 n BDL=1/2DL Actual Data nd, <2 ..._ RESULTS ---4 n BDL=1/2DL Actual Data RESULTS /WC Mb= 80.52 9606 nd Std Dev. 3.861302264 9606 10.3 10.3 Std Dev. Mean 4.4291 8.491 9605 1 Mean 3.15862069 9605 10.3 10.3 FINAL RESULTS 9604 1 <2 C.V. 1.222464691 9604 21.3 21.3 C.V. 0.522 Cadmium 9603 1 <21 9603 14 14 Max. Pred Cw 36 9602 1 <2 _ _ <2 <2 9602 8.8 8.8 Allowable Cw' 2.5 9601 1 Mutt Factorr= 2.4 9601 15.3 15.3 MO Factor= 7.8 Cyanide 9512 1 Ma'. Value 15 µgf 9512 7.9 7.9 Max. Value 21.3;tig/l 166.1 nil µg/1 _ _ Max. Pred Cw 166.14 9511 1 <2 .2. Ma... Pred Cw 36 µg/1 9511 6.7 6.7 Max. Pred Cw Atlow3ble-CW 6.2 9510 i' Allowable C.w 2.55. pg/1 9510 2.5 <5 Allowable Cw 6.2 Chromium Max. Pred Cw Allowable Cw Copper Max. Pred Cw Allowable Cw Lead Max. Pred w Allowable Cw Mercury Max. Pred Cw Allowable Cw 9509 11 <21 L 9509 7.8 7.8 61.2` 9508 1 �_ <2, 9508 14 14 62.1 9507! 11 <21 <2! I 9507 8.8 8.8 9506 1. 9506 5.6 5.6 305.1 9505 1 2 <2 1 9505 5.5 5.5 8.7 1 9504 _ 2 9504 6.6 6.6 9503, 2.3' 2.3 1 -T 9503 7.6 7.6 `_L_ __- 9502 1 <2, 9502 5.5 5.5 119 9501 11 <2. 9501 6.5 6.5 31.0 94121- 2.5 2.5 9412 7.7 7.7 9411 2.4 2.4! 94111 6.4 6.4 --_ 1.248 9410' 2.1, 2.1 9410 2.5 <5 0.0 94091 7.8 7.8 9409 8.1 8.1 9408r 12, 12 9408 5 5 Nickel 9407, 15 151 9407 6 6 Max. Pred Cw: 183 9406F 5 5 9406 8 8 _ Allowable Cw. 109.3 9405 12 12 9405 14 14 Silver Max. Pred Cwi 9404 7 71 9404 12 12 9403 3 3 9403 2.5 <5 18.7 9402 3 3, 9402 2.5 <5 Allowable Cwl 0.1 9401! 0.5 <1 ' 9401 151 15 - Zinc 311 31 - 32 32 Max. Pred Cw! 597.6 33� 33 Allowable Cw; 62.1 34 i� 34 I 35, 35 pal 4,7f-4 - 4/1r.4e--YS,D L) 2 fiv609. - F ° (2- pon'-t(7 /E►� P/1-1t7 PAGE 1 A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Permit No. NC0049409 During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge from • outfall(s) serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below: Effluent Characteristics Discharge Limitations Monitoring Requirements Measurement Sample Sample Monthly Avg. Weekly Avg. Daily Max. Frequency Type Location 1 Flow Weekly Instantaneous E Total Suspended Solids 30.0 mg/1 45.0 mg/1 2/month Grab E Settleable Solids 0.1 mUl 0.2 m1/1 Weekly Grab E Turbidity 2 Weekly Grab U, D Iron Weekly Grab E Total Residual Chlorine Weekly Grab E Aluminum Weekly Grab E Footnotes: Sample locations: E - Effluent, I - Influent, U - Upstream at a location 100 feet from the discharge point, D - Downstream at a location 300 feet from the discharge point. 2 The discharge shall not cause the turbidity of the receiving water to exceed 10 NTU. If the turbidity exceeds these levels due to natural background conditions, the discharge level cannot cause any increase in the turbidity in the receiving water. All samples collected should be of a representative discharge. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored weekly at the effluent by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. LEXINGTON WINTP LEAD DATA (7/92 - 6/93) 'arameter= Chromium Parameter= Copper i':'"itParameter= Lead Standard = 50 µg/I Standard = 7 µg/I Standard = 25 µg/1 , __ n 9606 BDL=1/2DL 13.8 13.8 10 12 Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS ? r; <6 n BDL=1/2DL Actual Data RESULTS 13.8 Std Dev. 7.40917 96061 23' 23 Std DeV. 20.793 « .>, 9606 1 <2 Std Dev. 16.049 9605 13.8 10 12 Mean 182733 9605 9604 23 23 Mean 41.967 ' 9605 1 <2 Mean 15.863 9604 9603 9602 _ 9601 9512 C.V. 0.40546 ' ' 35 35 C.V. 0.4955 �'` c 9604 1 <2 C.V. 1.0117 9603 22 22 9603 1 <2 13.4 13.4 t"< 9602 15.5 15.5 9602 1 <2 11.3 11.3 Mutt Factor= 1.7 , 9601 34.5 34.5 Muft Factor= 2.7 9601 2.3 2.3 Mult Factor= 1.7 µg/I pg/ ./I 11.8 11.8 8.4 Max. Value 36 µg 1 . „`: 9512 30.5 30.5 Max. Value 113 µg/l 9512 5 <10 Max Valusa 70 9511 9510 8.4 Max. Pred Cw 61.2 KO ; •� 9511 28.5 28.5 Max. Pred Cw 305.1 µ. '• 9511 16.2 16.2 Max. Pred Cw 119 19.5 7.5 19.5 7.5 12.2 19.3 18.6 21.9 20.7 34 Allowable Cw 62.1 WI 9510 24 24 Allowable Cw 8.7 e yy'% 9510 5 <10 Allowable Cw 31.0 9509 9509 113 113 9509 8 8 9508 12.2 19.3 18.6 9508 28.5 '28.5 9508 14.2 14.2 9507 9507 30.5 30.5 9507 14 14 9506 9506 16.5 16.5 9506 12.8 12.8 9505 21.9 20.7 9505 42 42 $ a 9505 8.8 8.8 9504 9504 _ 41 41_, 9504 11.7 11.7 9503 34 -• 9503 _ _ 58.6 58.6, # 9503 8.1 8.1 9502 26.4 26.4 9502 25.7 25.7 mi 9502 9.8 9.8 9501 12.7 12.7 9501 27.5 27.5' 9501 11.4 11.4 9412 20.3 20.3 9412 41.5 41.5 : 9412 21.5 21.5 9411 22.9 22.9 ; 9411 52 52 ::: 9411 55.3 55.3 9410 24.3 24.3 9410 50.3 48.9 50.3 9410 17.6 17.6 9409 14.4 14.4 9409 48.9 9409 252 25.2 9408 19 19 9408 50 50 9408 40 40 9407 31 31 9407 74 74 9407 70 70 9406 14 14 `.4 9406 41 41 9406 22 22 9405 21 21 9405 47 47 9405 31 31 9404 36 36f: 9404 64 ~ 64 9404 19 19 9403 28 28 9403 73 73 9403 16 16 9402 18 18 9402 62 62' 9402 23 23 9401 12 12 9401 36 36 9401 3 3 31 31a u 31 32 32 32 33 33 33 34 34 " < 34 35 35 35 PAGE 1 SUPPLEMENT TO PERMIT COVER SHEET Chatham County Schools is hereby authorized to: Permit No. NC0039381 1. Continue to operate an existing 0.01 MGD wastewater treatment system consisting of a 2000 gallon grease trap, a 13500 gallon septic tank, a 4600 gallon dosing tank to be used as an equalization tank, a 6000 gallon equalization/pump tank, dual recirculating sand filters, a programmable controller system, and an ultraviolet disinfection system located at Chatham Central High School, on NC Highway 902, south of Bear Creek, Chatham County (See Part III of this permit), and 2. Discharge wastewater from said treatment works at the location specified on the attached map into an unnamed tributary to Bear Creek which is classified Class C waters in the Cape Fear River Basin. LEXINGTON WWTP LEAD DATA (7/92 - 6/93) Parameter = Nickel '-,`:Parameter= Silver Standard = 88 µg/i <>' u < Standard = 0.06 • n BDL=1/2DL Actual Data RESULTS i3 n BDL=1/2DL Actual Data RESULTS 9606 26 26 Std Dev. 24.594 ?'.< 9606 2 <4 Std Dev. 2.2547 9605 26 26 Mean 60.933 ':'' 9605 <4 Mean 9604 38 38 C.V. 0.4036 " > 9604 ® 4 ,.. ; 9603 30.8 30.8 # 9603 11 11 --- 9602 34.2 34.21 9602 2 <4 9601 72.5 72.5 Mult Factor = 1.51 ' ; '' 9601 2 <4 Mutt Factor = 1.7 9512 25.3 25.3 Max. -Value 122„!g/+ : ;�... 9519 <4 Mar Mar Value 1_1 9511 53.8 53.8 Max. Pred Cw 183 µg/i <:• < ;; 9511 2 <4 Max. Pred Cw 18.7 9510 56.3 56.3 Allowable Cw 109.3 µg/i `'"' 9510 2 <4 Allowable Cw 0.1 • 9509 48.8 48.8 9509 2 <4 9508 50.6 50.6 »>-`> 9508 2 <4 9508 62.3 62.3 "'>?'vF' 9507 2 <4 --� --� 9506 43 43 z 9506 2 <4 9505 72.5 72.5 > ' 9505 2 <4 --� 9504 36.7 36.7 y'"'F'` 9504 4 4 --� 9503 49.9 49.9 9503 2 <4 9502 40.6 40.6 `f> 9502 2 <4 9501 64 64 9501 2 <4 --� 9412 70.4 70.4 9412 2 <4 --� 9411 72 72 '' 9411 2 <4 9410 78.3 78.3 <'';v 9410 9.3 9.3 9409 55 55 9409 4.7 �_-� 9408 81 81 :�><>;; 9408 4 9407 122 122 9407 6 6 --� --� 9406 78 78 >`'' 9406 1.5 <3 9405 88 88 xi>< 9405 1.5 <3 9404 76 76 ` ' 9404 1.5 <3 9403 78 78 Y;r; 9403 1.5--� 4• 9402 83 83 9402 -_� 9401 115 115 ?sr:> 9401 1.5 <3 31 .„:.>':'>; 31---_� 32 ''' 32 ----� :...:.. 33 ---� 34 34 ---�� 35 Y.<>>: 35 PAGE 1 LEXINGTON WWTP LEAD DATA (7/92 - 6/93) parameter= Zinc Parameter= Mercury Standard = 50 µg/I "e. `<, Standard = 0.012 µg/I n BDL=1/2DL Actual Data RESULTS :.;:.. n BDL=1/2DL Actual Data RESULTS 9606 97.7 97.7 Std Dev. 40.227 9606 0.1 <0.2 Std Dev. 0.1062 9605 97.7 97.7 Mean 142.39 ,.,: 9605 0.1 <0.2 Mean 0.143 9604 126 126 C.V. 0.2825 9604 0.38 0.38 C.V. 0.7426 9603 76 76 ar`f 9603 0.1 <0.2 9602 121 121 9602 0.1 <0.2 9601 149 149 Mutt Factor= 2.4 ::: 9601 0.38 0.38 Mutt Factor= 2.4 9512 161.5 161.5 Max. Value 249 pgA 9512 0.1 <0.2 Max. Value 0.52 unA 9511 96.5 96.5 Max. Pred Cw 597.6 µg/I '`.4" i 9511 0.1 <0.2 Max. Pred Cw 1.248 µg/1 9510 132 132 Allowable Cw 62.1 g9A '` 9510 0.1 <0.2 Allowable Cw 0.0 µgll 9509 129 129 9509 0.1 <0.2 9508 118.5 118.5 9508 0.1 <0.2 9507 125 125 9507 0.1 <0.2 9506 67.6 67.6 9506 0.1 <0.2 9505 156.5 156.5 9505 0.1 <0.2 9504 137 137 9504 0.1 <0.2 9503 161.9 161.9 j' l!, 9503 0.1 <0.2 9502 115.8 115.8 3:5%a`i 9502 0.1 <0.2 9501 147.8 147.8 " 9501 028 0.28 9412 218.3 218.3 9412 0.23 0.23 9411 163.6 163.6 ': F l 9411 0.52 0.52 9410 141.3 141.3 ';: 9410 0.1 <0.2 9409 151 151 9409 0.1 <0.2 9408 115 115 9408 0.1 <0.2 9407 249 249 1.�><i 9407 0.1 <0.2 9406 207 207 _ ra: 9406 0.1 <0.2 9405 154 154 `: 9405 0.1 <0.2 9404 155 155 9404 0.1 <0.2 9403 207 207 0® 9403 0.1 <0.2 9402 140 140 = 9402 0.1 <0.2 9401 154 154 9401 0.1 <0.2 31 31 32 tz. 32 33 33 34 34 PAGE1 lebf/ 7o7acjd 4in+6:2, L j7/42 6/03) Facility Name G1tyof'Gastonia/Lon9CreekWWT Parameter = Cadmium NPDES#= NC0020184 Standard= Ow (MGD) = 7010s (cts)= IwCL)= 8 109 10.21 FINAL RESULTS Cadmium Max. Pred Cw -3 2 pg/I Parameter= 1 Standard = Cyanide 5 pg/1 n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS 9606 nd nd Std Dev. 3.861302264 9606 10.3 10.3 9605 9604 9603 9602 1 <2 1 1 1 Allowable Cw 9601 1 Cyanide Max. Pred Cw 14 9512 9511 1 1 Allowable Cw 9510' Chromium 9509 Max. Pred Cw 61.2 Allowable Cw 9508 489.5 9507 1 Copper Max. Pred Cw Allowable Cw Lead 305.1 68.5 9506 9505 9504 9503 9502 2 2.3 Max. Pred Cw Allowable Cw Mercury 119 244.8 9501 9412 9411 1 2.5 2.4 Mean <2 C.V. <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 2 2.3 <2 <2 2.5 2.4 Mult Factor= Max. Value Max. Pred Cw Allowable Cw 3.15862069 9605 1.222464691 9604 9603 9602 2.4 9601 15 pg/l 9512 36 pg/l 9511 19.6 pg/I 9510 9509 Std Dev. 4.429 10.3 10.3 21.3 21.3 14' 14 Mean C.V. 8.49 0.522 8.8 8.8 15.3 7.9 15.3 Mutt Factor 7.8 7.9 Max. Value 213 pg/I 6.7 6.7 Max. Prod Cw 166.1 2.5 7.8 9508 14 9507 8.8 9506 9505 9504 9503 9502 5.6 5.51 7.6 5.5 9501 9412 9411 6.5 7.7 6.4 Max. Pred Cw Allowable Cw 1.248 0.1 9410 9409 9408 2.1, 2.1 7.8 7.8 12 12 Nickel 9407 9410 9409 9408 2.5 8.1 5 15 15 9407 6 Max. Pred Cw 183 9406 5 5 9406 8 Allowable Cw Silver Max. Pred Cw 861.5 9405 9404 9403 9402 12 121 7 7' 3 3 3 3 Allowable Cw 6 9401 0.51 9405 9404 9403 9402 9401 14 12 2.5 2.5 15 <5 Allowable Cw 7.8 14 8.8 5.6 5.5 6.6 7.6 5.5 6.5 7.7 6.4 <5 8.1 5 6 8 14 12 <5 <5 15 31 31 Zinc Max. Pred Cw Allowable Cw 597.6 489.5 32 33 34 35 32 33 34 35 49.0 t p9� PAGE 1 LEXINGTON WWTP LEAD DATA (7/92 - 6/93) parameter= Chromium Parameter= Copper Parameter = Lead 16.049-- Standard = 50 µg/I Standard = 7 141 Standard = 25,11g/I n 9606 BDL=1/2DL Actual Data RESULTS ug/I -- Ng/1 t1g/1 • n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS 13.8 13.8 Std Dev. 7.40917 9606 23 23 Std Dev. 20.793 I 9606 1 <2 Std Dev. 9605 13.8 13.8 Mean 18.2733 9605 23 23 Mean 41.967 Seti 9605 1 <2 Mean 15.863' 1.0117 9604 10 ' 10 C.V. 0.40546 9604 35 35 C.V. 0.4955 9604 1 <2 C.V. 9603 12 12 9603 22 22 n, a ` 9603 1 <2 9602 13.4 13.4 9602 15.5 15.5 ?; 9602 1 <2 9601 11.3 11.3 Mutt Factor = 1.71 9601 9512 9511 9510 34.5 34.5 Mu/t Factor = 2.7 9601 2.3 2.3 Mulf Factor= 1.7 N 8, - 11. Max. Value- 36 30.6 30.5-Max-Value -1-1-3512 51 <10}Max Value 70 µglf _ 9512 9511 9510 _ 9509 9508 _ 9507 _ 9506 9505 8.4 8.4 Max. Pred Cw 61.2 28.5 28.5 Max. Pred Cw 305.1 ( 9511 16.2 16.2 Max. Pred Cw 119 µgll 19.5 19.5 Allowable Cw 489.5 24 24.Allowable Cw 68.5 µg/I 9510 5 <10 Allowable Cw 244.8 µO 7.5 7.5 9509 113 113 R 9509 8 8 12.2 12.2 9508 28.5 28.5 9508 14.2 14.2 19.3 19.3 9507 30.5 30.5 9 9507 14 14 18.6 18.6 9506 16.5 16.5.,§, 9506 12.8 12.8 21.9 21.9 t% 9505 42 42 9505 8.8 8.8 9504 20.7 20.7 9504 41 41 9504 11.7 11.7 9503 34 34 <. 9503 58.6 58.6 9503 _ 8.1 8.1 9502 26.4 26.4 #,;;� 9502 25.7 25.7 3x��; 9502 9.8 9.8 9501 12.7 12.7 20.3 20.3 9501 27.5 27.5 9501 11.4 11.4 9412 ;`ty� 9412 41.5 41.5 ;: r,>: 9412 '"r 21.5 21.5 9411 22.9 22.9 H ; � 9411 52 52 --: SSW 9411 55.3 55.3 9410 24.3 9409 14.4 9408 19 24.3 14.4 19 31 9410 50.3 50.3 .�. � ��5; 9410 17.6 17.6 9409 48.9 48.9 a : 9409 25.2 25.2 9408 50 50 9408 40 40 9407 31 9407 74 74 3 9407 70 22 70 22 9406 14 14 9406 41 41 9406 9405 21 21 9405 47 47 9405 31 31 9404 36 36 9404 64 64 9404 19 19 9403 28 28 9403 73 73 9403 16 16 9402 18 18 9402 62 62 9402 23 23 _ 9401 31 32 121 12 9401 36 36 9401 3 3 31 31 32 ?t 32 33 34 33 ,,r ; 33 34 z" 34 35 35 35 PAGE 1 LEXINGTON WW TP LEAD DATA (7/92 - 6/93) °ammeter= Nickel ;;,Parameter= Silver Standard = 88 µg/I _ ':':: Standard = 0.06 µg/1 n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS 9606 26 26 Std Dev. 24.594 9606 2 <4 Std Dev. 2.2547 9605 26 26 Mean 60.933 9605 2 <4 Mean 2.8833 9604 38 38 C.V. 0.4036 .:<' 9604 2 <4 C.V. 0.782 9603 30.8 30.8 9603 11 11 9602 342 34.2 : • 9602 2 <4 9601 72.5 72.5 Muf Factor= 1.5 z'.F 9601 2 <4 Mutt Factor= 1.7 9512 25.3 25.3 Max. Value 122 WI ^ 9512 2 <4 <41Max. Max. Value PWCw 11 18.7 Ng/1 µg/l µg/I -95-T1 b3:8 53.811/fax. Pred-Cw 1-83 µg71 f 951T 2 9510 56.3 56.3 Allowable Cw 861.5 µg/1 ; ,:? 9510 2 <4 Allowable Cw 1 0.6 _. 9509 48.8 48.8 9509 2 <4 9508 50.6 50.6 40 9508 2 <4 9508 62.3 62.3 9507 2 <4 9506 43 43 rry h:.. .9506 2 <4 9505 72.5 72.5 9505 2 <4 9504 36.7 36.7 ,, €' 9504 4 4 9503 49.9 49.9 9503 2 <4 9502 40.6 40.6 9501 64 64 . 9501 2 <4 9412 70.4 70.4 9412 2 <4 9411 72 72 .`. 9411 2 <4 9410 78.3 78.3 ' n; 9410 9.3 9.3 9409 55 55 0 9409 4.7 4.7' 9408 81 81 9408 4 4 9407 122 122 9407 6 6 9406 78 78 « 9406 1.5 <3 9405 88 88 y.;,, 9405 1.5 <3' 9404 76 76 9404 1.5 <3 9403 78 78 iZ 9403 1. 1.5 <3 9402 83 83 s 9402 4 4 9401 115 115 F' Y ; 9401 1.5 <3 31 s-' 31 32 32 33 33 34 34 35 35 PAGE 1 LEXINGTON WWTP LEAD DATA (7/92 - 6/93) Parameter= Zinc <.;fi> Parameter = Mercu Standard = 50 µg/l Standard = 0.012 n BDL=1/2DL Actual Data RESULTS < `> ` nl BDL=1/2DL Actual Data RESULTS 9606 97.7 97.7 Std Dev. 40.227 >, 9606 0.1 <0.2 Std Dev. 0.1062 9605 97.7 97.7 Mean 1 142.39 9605 0.1 <0.2 Mean 0.143 9604 126 126 C.V. 0.2825 >; 9604 0.38 0.38 C.V. 0.74261 9603 76 76 <;: �;:.. 9603 0.1 <0.2 9602 121 121 >`;:`:;>;3: 9602 0.1 <0.2 9601 149 149 Mult Factor = 2.4 9601 0.38 0.38 Mult Factor = 2.4 9512 161.5 161.5 Max. Value 249 µg/l <> 9512 0.1 <0.2 Max. Value 0.52 n 9511 96.5 96.5 Max. Pred Cw 597.6 489.51µg/I jig 1 . < < 9511 0.1 <0.2 Max. Pred Cw 9510 132 132 Allowable Cw 9510 0.1 <0.2 Allowable Cw 0.1 WM 9509 129 129 9509 0.1 <0.2 --� -. 9508 118.5 118.5 9508 0.1 <0.2 9507 125 125 9507 0.1 <0.2 9506 67.6 67.6 9506 0.1 <0.2 9505 156.5 156.5 9505 0.1 <0.2 9504 137 137 9504 0.1 <0.2 -� -� 9503 161.9 161.9 >>" 9503 0.1 <0.2--- <0.2 9502 115.8 115.8 "-.`«<' <'; 9502 0.1 9501 147.8 147.8 <> <»> 9501 0.28 0.28 9412 218.3 218.3 9412 0.23 0.23 --� --� M 9411 163.6 163.6 9411 0.52 0.52 9410 141.3 141.31 9410 0.1 <0.2 9409 151 151 <<: 9409 0.1 <0.2 9408 115 115 ' "'``' 9408 0.1 <0.2 <0.2 --� 9407 249 249 " "' 9407 0.1 9406 207 207 9406 0.1 <0.2 <0.2 --� -� -� 9405 154 154 9405 0.1 9404 155 155 "''` ' 9404 0.1 <0.2 -�-� 9403 207 207 9403 0.1 <0.2 9402 140 140 9402 0.1 <0.2 9401 154 154 9431 0.1 31 -<0.2 --- 32 32 ---� ---� 33 k>< 33 34 kS>5:: is 34 :Skis ---- 35 '>` "' 35 PAGE 1 GJL% / %xl cc._,. / i4 i Facility ., City of Gastoniai! .., ; .:r,k 1. NC0020184 _ Qw1iWGD)= 16 7'C rOs (cfs)= _.._.,. 109 IWC (%) = 18.54 -t 1__F_INAL RESULTS Cadmium Max. Pred Cw Allowable Cw Parameters Standard = L µy/I Parameter= Standard = Cyanide 5 N9/1 n BDL=1/2DL Actual Luna 9606 nd 9605 1, 9604 1 9603 1 1 1 1 36 10.8 9602 9601 Cyanide Max. Pred Cw Allowable Cw Chromium Max. Pred Cw Allowable Cw CoEeer Max. Pred Cw 9512 166_14 27.0 61.2 269.8 305.1 Allowable Cw 37.8 Lead 951-1.1 9510 9509, 9508' 9507 9506 9505 9504 9503 9502 1;- 1 <2 <2 <2 <2 <2 Mult Factor= <2 Max. Value <2 Max.-PredGror, ESULTS Dov. an <2 AllowableCw' <2 - -1 <2 Q4- 2 2 2.3, 2.3 1 <2 Max. Pred Cw Allowable Cw Mercury Max. Pred Cwl Allowable Cw Nickel Max. Pred Cw Allowable Cw 119 134.9 1.2481 0.11 183 474.8 Silver 9501 9412 9411 9410 9409 9408 9407 9406 9405 9404' 9403 Max_ Pred Cw Allowable Cw Zinc Max. Pred Cw Allowable Cw 18.7 0.3 597.6 269.8 9402 9401 31 32 33 34 35 1 <2'! 2.5 2.5 2.4_ 2.4 2.1 2.1 7.8 7.8 12 12 15 15 5 5 12 12 7 7 3 3. 3 0.5 <1 3.861302264 3.15862069 1.222464691 2.4 15 µg/l --38Tr9A 10.8 µg/l n 9606 9605 9604 9603 9602 9601 9512 9511 9510 9509 BDL=1/2DL Actual Data RESULTS 10.3 10.3 Std Dev. 10.3 10.3 Mean 21.3 21.3 14 8.8 15.3 14 8.8 15.3 C.V. Mult Factor = 4.429 8.49 0.522 7.8 7.9 7.9 Max. Value 21.3 b./ " .7IMax. Pred Cw' 166.1 2.5 7.8 <5 Allowable Cw 27.0 7.8 9508 14 14 9507 8.8 8.8 9506 9505 9504 9503 5.6 5.5 6.6 7.6 5.6 5.5 6.6 7.6 9502 5.5 5.5 9501 6.5 6.5 9412 7.7 7.7 9411 6.4 6.4 9410 2.5 <5 9409 8.1 8.1 9408 5 5 9407 6 6 9406 8 8 14 14 9404 12 12 9403 2.5 <5 9402 2.5 <5 9401 15 15 31 32 33 34 35 PAGE 1 Basins 030201-030206 Management Strategies Protecting Wetlands -Since small streams comprise the majority of stream length in watershed - headwater wetlands are responsible for intercepting 80 % of sediment.(Novitski 1978) - Acquiring land, requireing buffers for agric and forestry Management Strategies for Oxygen Consuming Wastes DO Mainstem Model - Dan R. from NC220 to NCVA state line NC Level B aplid to Dan R. mainstem, model does nto predict substandard DO conentrations at exisitng permitted loads, results houl be interpreted wi caution sinc empricial equaiton scontianed in level B proceure may no apply to Dan R. Instream DO collected form 1990 - 1994 does nto idnciate a need fr further modeling at this tim. However, DWQ will continu to cmoito instream DO conentration sand will analuyze the data for trends. Instream data willb e used to determine if field calibrated model is ncessary in future. Page 11 of 4 LEXINGTON WWTP LEAD DATA (7/92 - 6/93) 'arameter= Chromium >>'Parameter = Copper <:>`:Parameter= Lead 1 Standard = 50 µg/I <:`► "' Standard = 7 A "' `'' ` Standard = Y:>-;:>:: z 25, pg/I n$ BDL=1/2DL Actual Data1RESULTS n BDL=1/2DL Actual Data RESULTS <> >`:{? n BDL=1/2DL Actual Data RESULTS l 9606 13.8 13.8 Std Dev. 7.40917 9606 23 23 Std Dev. 20.793 >$ 9606 1 <2 Std Dev. 16.049 9605 13.8 13.8 Mean 18.2733 °y" ` 9605 23 23 Mean 41.967 < 'i 9605 1 <2 Mean 15.8631 1.0117 9604 10 10 C.V. 0.40546 s 9604 35 35 C.V. 0.4955(;<qA< 9604 1 <2 C.V. 9603 12 12 x:::: 9603 22 22 K 9603 1 <2 9602 13.4 13.4 • >.�:;?� 9602 15.5 15.5 €�;.>.:�}}/�::� 9602 1 <2 9601 11.3 11.3 Mult Factor = 1.7 ;<4>: 9601 34.5 34.5! Mult Factor = 2.7 5. 9601 2.3 2.3 Mult Factor = 1.7 9512 11.8 11.8 Max. Value 36 NA: x 9512 30.5 30.5 Max. Value 113 µg/I 9512 5 <10 Max. Value 70 µg/I 9511 8.4 8.4 Max. Pro Cw 61.2 µg/1 <` ``--9511 28.5 28.5 Max. Pred Cw 305.1 AO ;::;; •. 9511 16.2 16.2 Max. Pred Cw 119 µg/I µg/I 9510 19.5 19.5 Allowable Cw 269.8 µg/l < 9510 24 24, Allowable Cw 37.8 µg/l ,. } j 9510 5 <10 Allowable Cw 134.9 9509 7.5 7.5 ` 9509 113 113 j l ` 9509 8 8 9508 12.2 12.2 ' 9508 ;:�.<:;; 28.5 28.5}`'>'`< 9508 14.2 14.2 9507 19.3 19.3 «f 9507 30.5 30.51 9507 14 14 9506 18.6 18.6 ''' 9506 16.51 16.5E>'> 9506 12.8 12.8 9505 21.9 21.9 "<' < 9505 42 421 9505 8.8 8.8 9504 20.7 20.7 x'<>h' 9504 41 41: 9504 11.7 11.7 9503 34 34 <`'``'` 9503 58.6 58.6; ``j``'"'` 9503 8.1 8.1 9502 26.4 26.4 9502 25.7 25.7 ,: 9502 9.8 9.8 9501 12.7 12.7 '?'"`' 9501 27.5, 27.5 Y< <'< 9501 11.4 11.4 9412 20.3 20.3 </'>> 9412 41.5' 41.5 `:`^> 9412 21.5 21.5 9411' 22.9 22.9 '' 9411 52 521 '' 9411 55.3 55.3 9410 24.3 9410 50.3 50.3! <<:�:"< 9410 17.6 17.6 9409 14.4 14.4 9409 48.9 48.3 t�; `'"`` 9409 25.2 25.2 9408 19 19 9408 1-�� 50 50 > <" '.>' .�s..} 9408 40 40 94071 31 31 >.<xr 9407 74 741 ::,. f>.->:' 9407 70 70 9406 14 14 • `' 9406 41 41 "` ' 9406 22 22 9405 21 21 "`` 9405 <<>:;s:r; 47 471 ;<,.:;.;::.:., ' ' ': _3 9405 31 31 9404 36 36 '' 9404 h<;> 64 64; >•>a 9404 19 19 9403 28 28 '� 9403 73 73 to 9403 16 16 9402 18 18 ::vw �<.;„:y 9402 62 62 �''�" "' 9402 23 23 9401 12 12 :;: 9401 36 361 '' 9401 3 3 31 1>" 31 ''{`' 31 32 s> ::::>s: 32 5`''<::: 32 33 33 " 33 34 34 34 35 ¢ '> 35 35 PAGE 1 LEXINGTON WWTP LEAD DATA (7/92 - 6/93) p ammeter= Nickel 3>c„41Parameter = Silver Standard= 88µgA : Standard= 0.06j.tgA n BDL=1/2DL Actual Data RESULTS - n BDL=1/2DL Actual Data RESULTS 9606 26 26 Std Dev. 24.594- >)' 9606 2 <4 Std Day. 2.2547 9605 26 26 Mean 60.933 ' ` 9605 2 <4 Mean 2.8833 9604 38 38 30.8 34.2 72.5 C.V. 0.4036 ; 9604 2 11 2 2 2 - - 2 <4 C.V. 0.782 9603�30.8 34.2 i��+>ni 9603 11 9602 9602 <4 9601 72.5 Mult Factor= 1.5 9601 <4 Mutt Factor= 1.7 9512 25.3 25.3 53.8 Max. Value 122 µg/I .,::-. 9512 <4 Max. Value 11 µfill 95111 53.8 Max. Pred Cw 183 gA . °. 9511 <4 Max. Pred Cw 18.7 µgf 9510 -56.3 -56:3 AllowableOw 74.8 -- 9510 2 2 --<4Allowable-Ow 0.3 µgA- 9509 48.8 48.8 9509 <4 9508 50.6 50.6 9508, 2 <4 9508 62.3 62.3 q'r:' 9507 2 <4 9506 43 43 9506 2 <4 9505 _ 72.5 72.5 9505 2 <4 9504 36.7 36.7 9504 4 4 9503 _ 49.9 49.9 a 9503 2 <4 9502 40.6 40.6 9502 2 <4 9501 64 64 , 9501 2 <4 9412 70.4 70.4N 9412 2 <4 9411 72 72 ;,six<:;=: 9411 2 <4 9410 78.3 78.3 !.•`:i � 9410 9.3 9.3 9409 55 55 9409 4.7 4.7 9408 81 81 ''""` 9408 4 4 9407 122 122 "%'> 9407 6 6 9406 78 78 ' 9406 1.5 <3 9405 88 88 ,. 9405 1.5 <3 9404 76 76 9404 1.5 <3 9403 78 78 9403 1.5 <3 9402 83 83 o 9402 4 4 9401 115 115 9401 1.5 <3 31 Rt ;3s 31 32 32 33 33 34 £. $ 34 35 «........ 351 PAGE 1 All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGE6C. Additionally, DEM Form AT-2 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Water Quality 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should any test data from either these monitoring requirements or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. K. CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QUARTERLY) The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in: 1.) The North Carolina Ceriodaphnia chronic effluent bioassay procedure (North Carolina Chronic Bioassay Procedure - Revised *September 1989) or subsequent versions. The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is 72 % (defined as treatment two in the North Carolina procedure document). The permit holder shall perform quarterly, monitoring using this procedure to establish compliance with the permit condition. The first test will be performed after thirty days from the effective date of this permit during the months of January, April, July, and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DEM Form AT-1 (original) is to be sent to the following address: LEXINGTON WWTP LEAD DATA (7/92 - 6/93) Parameter= Zlnc ««q. Parameter= Mercury Standard= 50.29/I > " > : Standard= 0.012 µg/I n BDL=1/2DL Actual Data RESULTS > Y n BDL=1/2DL Actual Data RESULTS 9606 97.7 97.7 Std Dev. 40.227 `;<' 9606 0.1 <0.2 Std Dev. 0.1062 9605 97.7 97.7 Mean 142.39 ::;:;:: 9605 0.1 <0.2 Mean 0.143 9604 126 126 C.V. 0.2825 '''''`' 9604 0.38 0.38 C.V. 0.7426 9603 76 76 9603 0.1 <0.2 9602 121 121 9602 0.1 <02 9601 149 149 Mutt Factor= 2.4 9601 0.38 0.38 Mull Factor= 2.4 9512 161.5 161.5 Max. Value 249 µg/l > 9512 0.1 <0.2 Max. Value 0.5220. --9511 96.5 96.5 Max. Fred cw 597.6 µg/1>> >> 951T 0 T <0.2 Max. Pred Cw 1.248 µgll 9510 132 132 Allowable Cw 269.8 nil ;>; 9510 0.1 <0.2 Allowable Cw 0.1 µg/l 9509 129 129 9509 0.1 <0.2 9508 118.5 118.5 9508 0.1 <0.2 9507 125 125 ""` 9507 0.1 <0.2 9506 67.6 67.6 9506 0.1 <0.2 9505 156.5 156.5 % 9505 0.1 <0.2 9504 137 137 9504 0.1 <0.2 9503 161.9 161.9 9503 0.1 <0.2 9502 115.8 115.8 9502 0.1 <0.2 9501 147.8 147.8 Y^> 9501 0.28 0.28 9412 218.3 218.3 '< 9412 0.23 0.23 9411 163.6 163.6 9411 0.52 0.52 9410 141.3 141.3 f f: 9410 0.1 <0.2 9409 151 151 s,; »> : 9409 0.1 <0.2 9408 115 115 - ' 9408 0.1 <0.2 9407 249 249 '' `''` 9407 0.1 <0.2 9406 207 207 ``' " 9406 0.1 <0.2 9405 154 154 '`' 9405 0.1 <0.2 9404 155 155 »`: <'' 9404 0.1 <0.2 9403 207 207 `"'>`' ' 9403 0.1 <0.2 9402 140 140 '9402 0.1 <0.2 9401 154 154 9401 0.1 <0.2 31 31 32 32 33 `:::< 33 34 >{ 34 35 35 PAGE 1 NC0049409 Summary May 31, 1996 Town of Waynesville Water Treatment Plant (WTP) submitted an application for renewal of their NPDES permit on May 9,1996. No changes or modifications are proposed for the permit renewal. The WTP treatment system consists of a single settling basin located at the Waynesville Water Treatment Plant, 1530 Allen Creek Road, south of Waynesville, Haywood County. Drainage area and flow information specified below was taken from USGS station 0345750000 (Allen Creek at Hazelwood) which appeared to be in the vicinity of Town of Waynesville WTP. Drainage Area = 14.4 mi2, 7Q10S= 3.6 cfs, and 30Q2=9.9 cfs. The WTP had Total Suspended Solids and/or Settleable Solids violations every month (except 1/92) from 12/91-8/92 and a civil penalty was assessed for these violations in 10/92. DEM received payment for the civil penalty 7/93 and although there were still several violations during the later part of 1992 and early part of 1993, there have been fewer violations more recently. The last violation occurred in 1/94. A summary of Waynesville's violations (monthly averages) from 12/91 to the present follows: Date Parameter Total Suspend Solids (mg/1) Settleable Solids (ml/1) 9112 34.3 9202 3.4 9203 32.6 4.7 9204 34.5 1.6 9205 33.9 6.4 9206 41.0 8.7 9207 1.7 9208 44.7 12.7 9210 0.5 9211 1.2 9212 0.4 9301 0.45 9303 3.9 9304 3.0 9401 0.75 Values in bold were never assessed. Is there a need to sample for both Total Suspended Solids and Settleable ) Solids? This question will be raised with the regional office. Inspections conducted from 1992-95 indicated the facility was in compliance. A 168-hour Chronic Toxicity Test conducted 4/8/92 indicated that LC50=77% (half of the Ceriodaphnia were killed in a solution comprised of 77 percent wastewater from the WTP). It appears that there have not been any toxicity studies conducted since April 1992. The WTP discharges into Allen Creek (C-Trout) in the French Broad River Basin. Instream monitoring conducted by the WTP indicated turbidity levels not greater than 4.3 NTU at the upstream location and not greater than 3.8 NTU at the downstream location. The Waynesville WTP is located in the Pigeon River watershed. Much of the catchment is undeveloped land within the Great Smoky Mountains National Park, Pisgah National Forest and Pisgah Game Lands. The largest urban areas are Waynesville and Canton. Facility Name = City of Gastonia/Long Creek WWTP , Parameter = Cadmium NPDES # = NC0020184 I Standard = 2 pg/I Qw (MGD) = 8 Qw (cts) = 12.3776 it 7Q10s (cfs)= 3 n BDL=1/2DL Actual Data RESULTS IWC (%) = 80.52 960307 1 <2 Std Dev. 0.504429113 960314 1 <2 Mean 0.920412698 FINAL RESULTS CONVERSIC 960321 1 <2 C.V. 0.548046669 Cadmium 960328 1 <2 n=63 Max. Pred Cw 5.1 4.1 f 960403 1 <2 Allowable;Cw 2.5 2.0 960411 3 3 Mull Factor= 1.7 Chromium 960418 1 <2 Max. Value 3 NgA Max. Pred Cw 15.3 12.3 960425 1 <2 Max. Pred ON 5.1 pg/I Allowable Cw 62.1 50.0 960502 1 <2 Allowable Cw 2.5 pgA Copper I 960509 1 <2 Max. Pred bw 127.5 102.7 960516 1 <2 Allowable Cw 8.7 7.0 960522 1 <2 Lead 960523 1 <2 Max Pred Cw 19.4 15.6 960530 1 <2 Allowable Cw 31.0 25.0 960606 1 <2 Mercury I 960613 1 <2 Max Pred Cw 0.240 0.193 960620 1 <2 Allowable Cw 0.015 0.012 960627 1 <2 Nickel 960704 1 <2 Max. Pred Cw 117.0 94.2 960711 1 <2 Allowable Cw 109.3 88.0 960718 1 <2 Silver I I 960725 1 <2 Max. Pred Cw 54.000 43.465 960801 1 <2 Allowable Cw 0.075 0.060 960808 1 <2 Zinc I 960815 1 <2 � Max. Pred C1 659.2 530.6 960822 1 <2 Allowable Cw, 62.1 50.0 960829 1 <2 960905 1 <2 960912 1 <2 960919 1 <2 960928 1 <2 961003 1 <2 961010 1 <2 961017 1 <2 961024 1 <2 961031 1 <2 961107 3 3 961114 1 <2 961121 1 <2 961128 1 <2 961205 1 <2 961212 1 <2 961219 1 <2 961226 1 <2 970102 1 <2 970109 1 <2 970116 1 <2 970123 1 <2 970130 1 <2 970206 1 <2 970213 1 <2 970220 1 <2 970227 1 <2 1 0.076 0.076 2 0.089 0.089 3 0.104 0.104 4 0.073 0.073 5 0.075 0.075 6 0.304 0.304 7 0.09 0.09 8 0.063 0.063 9 0.074 0.074 10 0.038 0.038 Rc vAsGe ib7 4,7/4Z ,4 1/✓1 v�S).S 4n4U G . 74'/4- bA-7A us1416- 1 4-7 6 -7)Gastonia -Long Creek WWTP 8.OMGD to Long Creek (?o/''Lt9,e/6 Se,a/ 02/4- PAGE1 Gastonia -Long Creek WWTP 8.0MGD to Long Creek Parameter = Standard = Chromium 50 Ng/I n BDL=1/2DL Actual Data RESULTS 960307 7 Std Dev. 960314 6 Mean 960321 7 C.V. 960328 8 960403 4 960411 3 960418 3 960425 41 960502 960509 n=63 Mult Factor Max. Value Max. Pred G Allowable CN Parameter = Co.•er Standard = 1.997458471 3.16981132 0.63015059 n BDL=1/2DL Actual Data RESULTS 960307 19 23 Std Dev. 960314 nd nd Mean 960321 nd nd C.V. 960328 25 _ 18 n=63 1.7 960403 nd nd 960411 39 24 Mult Factor = 9POO 15.3 Ng/1 62.1 960418 nd 960425 31 960502 nd 2 12.727 32.724 0.3889 1.4 nd Max. Value 91.1 gg/I 11 Max. Pred Cw 127.54 gg/l nd Allowable Cw 8.7 pg/I 960509 25 10 960516 4 960522 960523 960530 960606 960613 960620 960627 960704 960516 nd nd 2 2 21 960522 26 9 21 2, 41 9' 1 960711 960718 960725 960801 960808 960815 960822 960829 960905 960912 960919 960926 961003 961010 961017 961024 961031 961107 2 5 1 2 6 3 2 3' 2 4' 1 2' 2 961114 i 1 961121 961126 961205 961212 9612191 970109 9701161 970123 970130, 970206 970213 970220 970227 54 55 56 57 58 59 60 61 62 63 3 7 2 3 2 2 960523 nd _ nd __ 960530 18 11 960606 nd nd 960613 44 14 960620 nd nd 960627 23 9 960704 nd nd 960711 29 21 960718 nd nd 960725 21 16 960801 nd nd 960808 32 16 960815 nd nd 960822 nd nd 960829 960905 960912 29 nd 41 960919 nd 23 nd 46 1 nd 960926 37 38 961003 nd nd 961010 41 26 961017 nd nd 961024 45 22 961031 nd nd 961107 37 25 961114 nd nd 961121 nd nd 961126 32 32 961205 nd nd 961212 26 26 961219 nd nd 961226 32 _ 32 970102 nd nd 970109 30 30 970116 nd nd 970123 nd nd 970130 28 28 970206 nd nd 970213 19 19 970220 nd _ nd 970227 nd nd 1 43.2 43.2 2 32.8 32.8 3 4 5 33 33 27.2 27.2 23.7 23.7 6 91.1 91.1 7 34 34 8 31.5 31.5 9 41.4 41.4 10 25.7 25.7 PAGE 1 PERMITS IN-HOUSE AS OF 6/30/96 (sorted by date received) Permit Facility County Reviewer Comments NC0030970 SPRING LAKE, TOWN-WWTP CUMBERLAND CLARK -- NC0003727-ARC-ADIAN FERTILIZER-- — -- NEW-HANOVER CLARK NC0059234 TAKEDA CHEMICAL PROD. USA,INC. NEW HANOVER CLARK NC0001406 SWIFT TEXTILES (ERWIN MILLS) HARNETT CLARK ..NG0379049-R H. JOHNSON-CONSTRUCTION CO. FORSYTH— CLARK NC0004961__DUKE_EOWER CO., RIVERBEND S.E.—_GASTON NC0065676-LELAND-IN�I��SR443-1 BRUNSWI CG N510337 BARTS SHELULITTLE HUFF OIL PERSON N60065185-AMOCO-PETROIE-UM-PAW CREEK --- MECKLENB CLARK NC0024937 CMUD-SUGAR CREEK WWTP MECKLENBURC NC0005169 FMC CORPORATION - LITHIUM DIV. GASTON NC0020184 GASTONIA, CITY -LONG CREEK WWTP GASTON NC0020192 GASTONIA,CITY/CATAWBA CRK WWTP I GASTON NC0074268 GASTONIA, CITY/CROWDERS CRKJ GASTON NC0004260 CR INDUSTRIES GASTON NCG510339 FOUR CORNERS FACIUTY)S%4LLN/Z-S d, ASH NC0079758 NATIONAL WELDERS SUPPLY CO.INC MECKLENBU LAR or AppRcd SRReq WLARe WLARa SRRcd ,FieL,u f� tYSft�11'� Notice Schlss BASIN Basin hold? 951109 951201 960102 960312 960201 . ••,. • 306T4 951206 9�207.- II4 95227 960102 EFFECTIVE 4/1/94 l (� 960131 EFFECTIVE 9/1/91 — f(EAR ,- - 960131- 960205 CffCCTIVEeM:01:94 96021Q 46n221 E CLARK PROCSS i GEAD �N (/ �• URC-CLARK ct (MINATED-OUTFAL-LS-0D2 AND-0— 03.715194 CLARK EFFECTIVE 11/1/91 CLARK EFFECTIVE 12.01.93 CLARK MODIFIED 6/2/95 CLARK 09 EFFECTIVE 4/1/93 CLARK EFFECTIVE 5/1/94 CLARK EFFECTIVE 06.01.95 CLARKL A/7W6- FOR lur° (Ak'w..)7)7►, 4L AA OkiRC CLARK EFFECTIVE 10/1/92 ' NC0083810=GASTON MERCHANTS OIL OMNI MART—GASTON CLARK /-A17W(, EFFECTIVE- 06.01:94- NC0083950 BELLSOUTH TELECOMMUNICATIONS GASTON CLARK --- EFFECTIVE 12.01.94 NCG510347 TRIANGLE TEXACO/REABEN OIL CO. HENDERSON CLARKw,t,T,ti6- r'04. 374FF rttPT NG0085758-5. CENTBA_-..! OIt GQ CROSSRBS-GRo STANLY CLAR _ NCG510350 WEST LEXINGTON SERVICE/SAVASUM DAVIDSON CLARK P+Z`-/ce5 NC0085782 CRESCENT MOTEL/R.K.&C.. INC. FRANKLIN CLARK NC0049409 WAYNESVILLE, TOWN OF - WTP HAYWOOD NC0085821 AMP, INC-CHURCH ROAD. GREENSBO GUILFORD NC0025321 WAYNESVILLE, TOWN OF - WWTP HAYWOOD NC0000400 K-T FELDSPAR CORPORATION MITCHELL NC0085855 T.H. TURNERANAKEFIELD SUPERETT WAKE CLARK CLARK F2' -' CLARK EFFECTIVE 5/1/94 CLARK 09 EFFECTIVE 8/1/93 CLARK NC0085871 ABB FLAKT, INCJFLAKT PRODUCTS FORSYTH CLARK CLARK EFFECTIVE 811/92 _57Ar'F 2EF'ole'T 59t4E I i 1411d. 1iJ 9g-G- 960102_ _ 960201 960102 960402 960222 960125 960228- 960321 960320 960220---- 06040 Q604 960223 960228 960325 ' -- - - 960304 960306 960311 960312 960311 960321 960311 960321 960311 960321 960325 960408 960327 960408 960328 960408 960401 960408 960401 960402 60409 960418 960501 960509 960509 960520 960528 960530 960610 960311 960312 960415 960429 960429 960429 960408 960507 960520 960509 960612 960706- 9g 960515 960629 30617 30613 -- - 30201 960508 960622 30 4 Q.6Q6Qg306i Z--= _ 960410 960525 30834.- 960422 960619 960803 30834 30836 30836 30837 30837 30837 30834 ---- 30838- 30836 CO L. 960523 96D1Y15 QR4179n 960607 960524 960610 960617 40305 40305 40306 Gastonia -Long Creek WWTP 8.0MGD to Long Creek Parameter= Lead 1 I Parameter= Mercury Standard = 25 pg/I Standard = 0.012 pg/1 d j n B L=1/2DL lActual Data RESULTS n BDL=1/2DL Actual Data RESULTS 960307 1, <2 Std Dev. 1.5441 970401 0.1 <0.2 Std Dev. ! 0.0458 960314 1 <2 Mean 1.7083 970410 0.1 <0.2 Mean 1 0.0641 960321 1 <2 C.V. 1 0.90391 970417 0.1 <0.2 C.V. 1 0.7156 960328 1 <2 n=63 970424 0.1 <0.2 n=23 I 960403 1 <2 970501 0.1 <0.2 960411 1 <2 Mutt Factor = 2 970508 0.1 <0.2 Mult Factor = 1 2.4 960418 1 <2 Max. Value 9.72 pg/l 970515 0.1 <0.2 Max. Value 1 0.1 pgfl 960425 1 <2 Max. Pred Cw 19.44Ig/1 970523 0.1 <0.2 Max. Pred Cwl 0.24 µgfl 960502 1 <2 Allowable Cw 31.0 pg/I 970529 0.1 <0.2 Allowable Cw 1 0.015 pg/1 960509 1, <2 970605 0.1 <0.2 960516 2.11 2.1 970612 0.1 <0.2 960522 1 <2 970619 0.1', <0.2 960523 1 <2 970626 0.1 <0.2 960530 1 <2 _ 1 0.007731 0.00773 960606 1 <2 2 0.006451 0.00645 960613 4' 4 3 0.00774 0.00774 960620, 2 2 ! 4 0.00686 0.00686 9606271 21 2 l 5 0.00643 0.00643 9607041 11 <2 6 0.1 0.1 960711' 1 <2 7 0.00743, 0.00743 960718 1 <2 8 0.007091 0.00709 960725 11 <2 9 0.0151 0.0151 960801 11 <2 10 0.0088 0.0088 960808 11 <2 1 960815 1, <2 1 960822 1 <2 960829� 1 <2 960905 1 <2 960912 2 21 960919 1 <2 960926 1 <2 961003 1 <2 1_ 961010 2 2' 961017 2 2 961024 1 <2 961031 1 <2 1 961107 1 <2 961114 3 3j 961121 4 4 961126 2 2j 1 961205 6 6' 961212 3 3 961219 5 5 961226 4 4 970102 1 <2 970109 1 <2 970116 11 <2 970123 1 <2 1 ! 970130 1 <2' 970206 1 <2 j 970213 1 <2 970220 4' 4 970227 4 4 1 2.165, 2.165 2 1.2 1.2 i 1 3 1.345 1.345 4 1.13 1.13 5, 1.23 1.23 61 9.72 9.72 7 1.06 1.06 8 0.54 0.54 1 9 0.647'1 0.647 101 0.487 0.487 PAGE 1 State of North Carolina Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director August 14, 1997 Colette B. Teachey, Executive Director Coastal Carolina Community College Foundation, Inc. 444 Western Blvd. Jacksonville, North Carolina 28546-6877 Subject: NPDES Permit Issuance Permit No. NC0071536 Windmill Restaurant Onslow County Dear Ms. Teachey: In accordance ith the application for a discharge permit received on February 4, 1997, the Division is forwarding herewi a subject NPDES permit. This permit is issued pursuant to the requirements of North Carolina General atute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental P tection Agency dated December 6, 1983. As sta d in the cover letter that accompanied the copy of the draft permit for this facility, curren , the facility is not perating. Before beginning operation, the facility must meet original specifications which would require some construction. An Authorization to Construct would have to be submitted before beginning the construction necessary for the facility to meet original specifications. The Division also recommends that the permittee continue to investigate alternatives to surface water discharge. A connection to the City of Jacksonville may be possible after annexation of an area near (but not including) the site. However, this annexation may still be several years in the future. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings, Post Office Drawer 27447, Raleigh, North Carolina 27611-7447. Unless such demand is made, this decision shall be final and binding. Please take note that this permit is not transferable. Part II, E.4. addresses the requirements to be followed in case of change in ownership or control of this discharge. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources or any other Federal or Local governmental permit that may be required. If you have any questions concerning this permit, please contact Paul B. Clark at telephone number (919)733-5083, extension 580. Sincerely, A. Preston Howard, Jr., P.E. cc: Central Files Raleigh Regional Office, Water Quality Section Mr. Roosevelt Childress, EPA Permits and Engineering Unit Facility Assessment Unit P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-0719 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper Gastonia -Long Creek WWTP 8.0MGD to Long Creek Parameter = Nickel Parameter Silver Standard = 1 88 Jg/l Standard = 0.06 pg/I n 960307 960314 960321 960328 IBDL=1/2DL Actual Data!RESULTS 70 70l Std Dev. 15.139 231 23 Mean 32.879'' 5 5 C.V. 0.4605 25 251 n=63 960403' 40 40 n BDL=1/2DL ;Actual Data RESULTS 960307 20! 20 Std Dev. 960314 nd' nd Mean 960321 ndi nd C.V. 960328 21 2 n=63 960403 nd nd 3.2889 1.9972 1.6468 960411 17 17 Mult Factor = J 1.5 960418 960425 960502 960509 960516 960522, 50 45 20 15 30 21 50 Max. Value 45 Max. Pred Cw 2 01 Allowable Cw 151 30 21 78 pg/I 117 pg/I 109.3 oil 960411 2 2 Mult Factor = 1 2.7 9604181 nd1 nd Max. Value 960425; 21 2 Max. Pred Cw 960502, nd nd Allowable Cw 960509' 2 ' 2 20 54 NO 0.1 pg/l 9605161 ndl nd 960522' 2 2 960523', 9605301 9606061 960613 20 20 50 50 9605231 960530 nd 2 nd, 2' 50 50r 37 37 960606 960613, nd nd 2 960620 960627 23' 23 45 4 5' 960704 960711 33 33 37 37' 960620. 9606271 9607041 960711 nd 2 nd 2' nd 21 nd 2, 960718 960725 5' 51 25 25 960718'1 960725 nd: 2' ndl 2 960801 30 30 960801, nd nd'1 960808 24 24' 960808' 2 2 960815 30 30 960815 ndl nd 960822 60 60 960822 nd, nd 960829 30 30 960829: 2 2' 960905 40 40' 960905 nd nd 960912 960919 26 26 30 30 960912! 2 2 960919, nd nd 960926 961003 961010 20 40 22 20 40 22 9609261 2 2 961003 nd nd 961010 2 2 961017i 20 20 961017' nd nd 961024i 30 30 96103170' 70 961107 7 8 78 961024, 961031 961107 2 2 1 nd, nd 2 2 961114 10' 10 961121I 20 20 96112 , 50 50 961114 961121, 961126 nd nd nd nd 2 2 961205i 96121 40 40' 40 40 961205' ndl nd 961212 2' 2 96121 96122 30 30 40 40 10 33 33 40 40 40 40 40 40 201 20 970102 10' 97010 97011 970123 97013C, 97020E 970213 970220 55 55 45 45 961219 nd 961226 2, nd 2 970102, nd' ndl, 970109; 2, 2' 9701161 nd 970123,11nd nd nd 970130 ' 2'I 2 9702061 nd nd 9702131 2 2 970220 nd nd 97022T 1 55 17.3 55 17.3 9702271 nd nd 11 0.128 0.128 2 25.5 25.5 2, 0.136 0.136 3 28.45 28.45, 23.6 23.6 3 0.104 0.104 5 19.3 19.3' 4' 51 61 7: 81 91 6 34.5 34.5 71 34.4 34.4 28.1 28.1 261 26 10. 30.2 30.2 0.1, 0.0756 0.608, 0.163' 0.104 0.255 10i 0.232 0.1 0.0756 0.608 0.163 0.104 0.255 0.232 PAGE 1 Gastonia -Long Creek VWVTP 8.0MGD to Long Creek parameter= Zinc I Standard = 50 gll n BDL=1/2DL Actual Data RESULTS 960307 20 20 Std Dev. 65.667 960314 nd' nd Mean 143.81 960321 nd nd C.V. 0.4566 960328 132 132 n=63 960403 nd nd 960411 150 150 Mult Factor = 1.6 960418 nd nd Max. Value 412 659.2 jig 1-19t1 960425 102 102 Max. Pred Cw 960502 nd nd Allowable Cw I 62.1 pg/I 960509 120 120 960516 ndl nd 960522� 100 100 960523 nd nd 960530 73 73 9606061 nd nd 960613 88 88 960620 nd nd 960627 101 101 960704 nd, nd 960711 120' 120 960718 nd nd 960725 106 106 9608011 nd nd f 960808 130 130 960815 nd nd 960822 nd nd 960829 116 116 960905 141 141 960912 160 1601 1 960919 nd nd 960926 nd nd 961003 nd nd 961010 140 140 961011 140, 140 961024 1691 169 961031 ndI nd 961107 130 130 961114 nd • nd 961121 nd nd 961126 197' 197 961205 ndl nd 961212 1301 130 961219 ndl nd 961226 4121 412 970102 ndl nd 970109 120 120 970116 nd; nd 970123 nd. nd 970130' 129 129 970206 nd nd 970213 nd nd 970220 nd nd 970227 169 169 1 158 158 2 137 137 3 126.5 126.5 4 1371 137 i 5 133; 133 61 285 285 7 141 141 8 171 171 9 256( 256 101 94' 941 PAGE 1 ROAD CLASSIFICATION PRIMARY HIGHWAY HARD SURFACE SECONDARY HIGHWAY HARD SURFACE LIGHT•DUTY ROAD, HARD OR IMPROVED SURFACE UNIMPROVED ROAD = Latitude 35°04'03" Longitude 83°13'31" Map # G6SW Sub -basin 040401 Stream Class B-Trout Discharge Class 1 Receiving Stream Little Tennessee River Design Q 0-50 MGM Permit expires 10/31/02 0 SCALE 1:24 000 0 1 MILE 7000 FEET 1 KILOMETER CONTOUR INTERVAL 40 FEET Town of Highlands NC0021407 Macon County Gastonia -Long Creek WWTP 8.0MGD to S Fork Catawba acitity Name = NPDES # = City of Gastonla/Lonq Creek WWTP NC0020184 Qw (MGD) = Qw (cfs) 7010s (cis)= IWC(%)= 8 12.3776 109 10.21 FINAL RESULTS CONRSIC Cadmium Max. Pred Cw Allowable Cw Chromium Max. Pred Cw Allowable Cw Copper Max. Pred Cw Allowable Cw Lead Max. Pred Cw Allowable Cw Mercury Max. Pred Cw Allowable Cw Nickel Max. Pred Cw Allowable Cw Silver 15.3 489.5 19.4 244.8 0.240 0.117 1.6 50.0 2.0 25.0 0.024 0.012 117.0 11.9 861.5 Max. Pred Cw Allowable Cw 54.000 0.587 Zinc Max. Pred Cw Allowable Cw 88.0 Parameter = Standard = Cadmium n 960307 960314 960321 960328 960403 960411 960418 960425 960502 960509 960516 960522 960523 960530 960606 960613 960620 960627 960704 960711 960718 960725 2 pg/l 8DL=1/2DL Actual Data RESULTS 1 3 1 1 1 1 1 1 1 <2 Std Dev. Parameter= Standard = n 0.504429113 960307 <2 Mean <2 C.V. <2 n=63 <2 3 Mult Factor = <2 Max. Value <2 Max. Pred Cw. <2 Allowable Cw <2 <2 <2 <2 <2 <2 0.920412698 0.548046669 1.7 960314 960321 960328 960403 960411 3 Ng/I 960418 5.1 pg/I 960425 19.6 pg/I 960502 960509 960516 <2 <2 <2 <2 1 <2 11 <2 1 <2 5.507 960801 0.060 960808 11 1i <2 <2 960815 659.2 67.2 960822 11 1F <2 <2 489.5 50.0 960829 11 <2 960905 1 <2 960912 1 <2 960919 1 <2 960926 1 <2 961003 1 <2 961010 1 <2 961017 1 <2 961024 1 <2 961031 1 <2 961107 3 3 961114 1 <2 961121 <2 961126 <2 961205 1 <2 961212 1 <2 961219 1 <2 961226 1 <2 970102 1 <2 970109 1 <2 970116 970123 1 <2 970130 1 <2 970206 1 <2 970213 1 <2 970220 1 <2 970227 i <2 960522 960523 960530 960606 960613 960620 960627 960704 960711 960718 960725 960801 960808 960815 960822 960829 960905 960912 960919 960926 961003 961010 961017 961024 961031 961107 961114 961121 961126 961205 961212 961219 961226 970102 970109 970116 970123 970130 970206 970213 970220 970227 PAGE1 Gastonia -Long Creek WWTP 16.0MGD to S Fork Catawba R cacllity Name = NPDES # = Qw (MGD) = Qw (cIs) = 7010s (cfs)= IWC (%) = City of Gastonia/Long Creek WWTP NC0020184 16 24.7552 109 18.54 Cadmium Max. Pred Cw Allowable Cw Chromium Max. Pred Cw Allowable Cw Copper Max. Pred Cw Allowable Cw Lead Max. Pred Cw Allowable Cw Mercury Max. Pred Cw Allowable Cw Nickel Max. Pred Cw FINAL RESULTS CONVERSIC 5.1 10.8 15.3 269.8 Allowable Cw Parameter = Standard = Cadmium 2 Ngn Parameter= Standard = n BDL=1/2DL Actual Data RESULTS n 960307 1 <2, Std Dev. 0.504429113 _ 960307 960314 11 <21Mean 0.920412698 960314 960321 1 <2 C.V. 0.548046669 960321 960328 1 <2 n=63 960328 0.9 960403 1 2.0 960411 3 960418 1 2.8 960425 1 50.0 960502 1 960509 1 <2 960403 3 Mull Factor =1 1ij 960411 <2 Max. Value 3 pg/I 960418 <2 Max. Pred Cw 5.1 pg/1 960425 <2 Allowable Cw 10.8 pg/I 960502 <2 960509 127.5 23.6 960516 1 <2 37.8 7.0 960522 1 <2 19.4 134.9 960523 1 <2 3.6 960530 1 <2 25.0 960606 1 <2 0.240 0.044 0.065 0.012 960613 1 <2 960620 1 <2 117.0 21.7 474.8 88.0 Silver Max. Pred Cw 54.000 9.994 960627 1 <2 960704 1 <2 960711 1 <2 960718 1 <2 960725 1 <2 960801 1 <2 Allowable Cw Zinc 0.324 0. 960808 1 <2 Max. Pred Cw 659.2 122.0 Allowable Cw 269.8 50.0 960815 1 <2 960822 1 <2 960829 1 <2 960905 1 <2 960912 1 <2 960919 11 <2 960926 11 <2 961003 1 <2 961010 1 <2 961017 11 <2 961024 1 <2 961031 1 <2 961107 3i 3 961114 1 <2 961121 1 <2 961126 11 <2 961205 1 <2 961212 1 <2 961219 1 <2 961226 1 <2 970102 1 <2 970109 1 <2 970116 1 <2 970123 1 <2 970130 1 <2 970206 1 <2 970213 1 <2 960516 960522 960523 960530 960606 960613 960620 960627 960704 960711 960718 960725 960801 960808 960815 960822 960829 960905 960912 960919 960926 961003 961010 961017 961024 961031 961107 961114 961121 961126 961205 961212 961219 961226 970102 970109 970116 970123 970130 970206 970213 970220 1 <2 970220 970227 1 <2 970227 PAGE1 Dfri Co>7 Crive Facility Name = City of Gastonia/Long Creek WWTP NPDES # = NC0020184 Qw (MGD) _ Ow (cis) _ 7Q10s (cfs)= /WC (%) = 8 12.3776 3 80.52 Cadmium Max. Pred Cw Allowable Cw Chromium Max. Pred Cw Allowable Cw Copper Max. Pred Cw Allowable Cw Lead Max. Pred Cw Allowable Cw Mercury Max. Pred Cw Allowable Cw Nickel Max. Pred Cw Allowable Cw. Silver Max. Pred Cw Allowable Cw Zinc Max. Pred Cw Allowable Cw FINAL RESULTS 4.2 2.5 15.3 62.1 58.5 8.7 10.8 31.0 0.120 0.015 124.8 109.3 52.000 41.855 0.075 0.060 659.2 62.1 • Parameter = Standard = CONVERSIC 3.4 2.0 - --- 960418 12.3 960425 50.0 960502 960509 47.1 960516 7.0 960522 960523 8.7 960530 25.0 960606 960613 0.097 960620 0.012' 960627 960704 100.5 , 960711 88.0 960718 960725 960801 960808 960815 530.6 960822 50.0 960829 960905 960912 960919 960926 961003 961010 961017 961024 961031 961107 961114 961121 961126 961205 961212 961219 961226, 970102 970109 970116, 970123 970130, 970206, 970213 970220 970227 Cadmium ma stoy 960307 960314 960321 960328 960403 960411 io9kong Creek WWTP 8.0MGD to Long Creek • BDL=1/2DL Actual Data RESULTS 1 <2 Std Dev. 0.384760495 1 <2 Mean 1.075471698 1 <2 C.V. 0.357759759 1 <2 n=53 1 <2 3 3 Mull Factor = 1: <2 Max. Value 3:pg/l 1 <2 Max. Pred Cw. 4.2.pg/I 1 <2 Allowable Cw 2.5 pg/I 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2. 1 <2. 1 <2 1 <2 1, <2. 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 3. 3 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2. 1 <2 1 <2 1 <2 1 <2 1 <2 . 1, <2 i <2 1 <2 1.4 Parameter = Standard = Chromium 50 pg/I n BDL=1/2DL Actual Data RESULTS 960307 7 Std Dev. 1.99745847 960314 960321 960328 960403 960411 960418 960425 960502 960509 960516 960522 960523 960530 960606 960613 960620 960627 960704 960711 960718 960725 960801 960808 960815 960822 960829 960905 960912 960919 960926 961003 961010 961017 961024 961031 961107 961114 961121 961126 961205 961212 961219 961226 970102 970109 970116 970123 970130 970206 970213, 970220 970227 Mean 3.16981132 C.V. 0.63015059 n=53 Mull Factor = :Max. Value 9 pg/I Max. Pred C‘ 15.3 pg/I Allowable CH 62.1 pg/I 4 3 4 1 6 7 6 2 3 21 2 1.7 PA E1 • c• 4.4 Self -Priming `Centrifugal Pumps Pump Performance HIGH HEAD 0 aik 20 40 10 60 100 120 ` ' 140 C.66AC1TY V.$. GALLONS PER MtNUTei 1a 100 HIGH HEAD i HP Cat. No. Dlecharoe Suellen lift Ir1 Feet Feet PSI Head 10' I 1 5' 1 20' I 25' GaIln'iE Per Minute DIIE 20 46.2 46. 43 41 38 35 30 69.3 35 29 25 21 40- -, z.4 50 115.5 19 15. 10 60 138.6 1-1/2 DHF 20 46.2 65 53 51 49 46 30 69.3 45 4 39 36. 32 40 92.4 50 115.5 31 27 22 18• 12 80 138.5 DHG 20 46.2 30 69.3 77 74 71 68 8; 40 92.4t 83 4M 60 44 56 ' 53 49 400• ; 35 $ 30' 50 115.5 27 601 139.61 f 20 13 2-1/2 DHHG 20 46.2 89 85 82 80 76 30. 69.3 75 72 68' 64 60 40 92.4 60 57 53 49 1 44 50 115.5 DHH DHJ 60 138.6 42 37 31 25 17 20 46.2 12! 30 89.3 irw I TM 40 92.4 ' 80 50 ' 115.5 51 20 48.2 • • 4S1 30 69.3 'CO 158. 40 _92.4 -„ 146 t 141 50 116.5 119 114 60 138.8 81 I 105 98 74 42 152 150 136 96 92 69 32 138 136 130 105 • 95 68 66 60 13 98 98 96 85 SS I 30 2 STA-RITE. Built On Commitment. Parameter = Copper Paramepr = ea - fJwTP 8iMGD to Long Parameter = Mercury Standard = 7 nil Standffla Creek Standard = 0.012 INA n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS 960307 19 23 Std Dev. 7.9554 960307 1 <2 Std Dev. 1.2245 970401 0.1 <0.2 Std Dev. 2E-09 960314 nd nd nd Mean 30.375 960314 1 <2 Mean 1.6623 0.7366� 970410 0.1 <0.2 Mean 0.1 960321 nd C.V. 0.2619 960321 1 <2 C.V. _ 970417 0.1 <0.2 C.V. 2E-08 960328 25 18 n=53 960328 1 <2 n=53 970424 0.1 <0.2 n=13 960403 nd nd 960403 1 <2 970501 0.1 <0.2 960411 39 24 Mult Factor = 1.3 960411 1 <2 Mutt Factor = 1.8 _ 970508 0.1 <0.2 Mult Factor = 1.2 --960418 nd nd Max Value- 45 pg/1 960418 1 <2 Max Value 6 p j 97051-5 0:1 <02-Max: Value 0.1 Ng/1 960425 31 11 Max. Pred Cw 58.5 pg/l 960425 1 <2 Max. Pred Cw 10.8 - Egli 970523 0.1 <0.2 Max. Pred Cw 0.12pg/i pg/i 960502 nd nd Allowable Cw 8.7 g /g_I 960502 1 1 <2 Allowable Cw 31.0 ' 970529 0.1 0.1 0.1 _ <0.2 <0.2 <0.2 Allowable Cw 0.015 960509 25 nd 10 960509 <2 _ _ 970605 960516 nd 960516 2.1 2.1 970612 960522 26 nd 9 960522 1 <2 970619 0.1 <0.2 960523 nd 960523 960530 1 <2 970626 0.1 <0.2 960530 18 11 1 <2 960606 nd 44 nd nd 960606 1 <2 960613 14 960613 4 _ 4 960620 nd 960620 2 2 960627 23 9 960627 2 2 960704 nd nd 960704 1j <2 960711 29 21 960711 1 <2 960718 nd nd 960718 1 <2 960725 21 16 960725 1 <2 960801 nd nd 960801 1 <2 960808 32 16 960808 1 <2 960815 nd nd 960815 1 <2� 960822 nd nd 960822 1 <2 960829_ 29 nd 41 23 960829 1 <2 960905~ nd� 960905 1 <2 _._ 960912 46 960912 2 1 2 960919 nd nd 960919 <2 960926 37 38 960926 1 <2 961003 nd nd 961003 1 961010 41 26 961010 2 2 961017 nd nd 961017 2 2 _ 961024 45 nd 22 961024 1 <2 961031 961107 nd 961031 1 <2 37 25 961107 1 <2 961114 nd nd 961114 3 3 961121 nd nd 961121 4 2 4 961126 32 32 961126 2 961205 nd nd 961205 61 6 961212 26 26 961212 3 3 - �- 961219 _ nd nd _ 961219 961226 5 4 5 961226 32 32 4 _ _.___----- ----- 970102 nd nd 970102 1 <2 -__.-. 970109 30 30 970109 1 <2 --- -- ---_ 970116 nd nd _ 970116 1 <2 970123 nd nd 970123 1 <2 970130 28 28 970130 1 <2 970206 nd nd 970206 1 <2 970213 19 19 970213 1 <2 _ 970220 nd nd 970220 4 4 IPAC 970227 ndi nd 970227 4 4 El FACTORS AFFEO'JNG WASTE LOAD ALLOCATIONS Over the past decade North Carolina has experienced rapid population growth and industrial development. With this growth has come more jobs and better housing opportunities. This prosperity has also brought an increasing demand on our State water's as locations for wastewater discharges. These waters are a resource with only limited capacity to accept wastewater. Additional discharges, in many cases, result in a requirement for upgraded treatment by the existing dischargers. This is an unfortunate side effect of our growth, but it is one that you must consider now, and throughout the life of your project. Beginning on page three of your NPDES permit are the effluent limitations that you are required to meet. These limitations were derived to protect the water quality in your receiving stream under existing conditions. The effluent limits contained in your permit are usually effective throughout the term of the permit. However, these limits can change during the term of the permit (usually five years) if: (1) a water quality concern is documented in the receiving stream or, (2) the federal guidelines change for facilities with limits based on effluent guidelines. Effluent limits in the permit are also subject to change at the time of reissuance of the NPDES permit. This change can result from several factors, for example: (1) more discharges in your immediate area, (2) an increase in total permitted flow to your stream, (3) a change in the condition of your stream, (4) an increase in our understanding of your receiving stream. If your limits do change, you will be responsible for taking the action necessary to upgrade your treatment facility to meet your new effluent limits. As the Division becomes aware of a change in the limitation of existing dischargers, we will provide you with as much notice as is possible so that you can begin making plans to meet those new limitations. parameter = Nickel Parameter_= Silver ° "Lcru%W. I IWTP 8 OMGD to Long Creek— Parameter = Zinc pg/l Standard = 88 Ng/i StandaV' Standard = 50 3.6742 n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS 960307 70 70'Std Dev. 16.095 960307 20 Std Dev. 960307 20 20 nd Std Dev. 67.253 960314 23 23 Mean 34.038 960314 nd nd Mean 2.75 960314 nd Mean 135.8 960321 5 5 C.V. 0.4728 960321 nd nd C.V. 1.3361 960321 nd nd C.V. 0.4952 960328 25 25 n=53 960328 2 2 n=53 960328 132 132 n=53 960403 40 40 960403 960411 nd nd 960403 nd 150 nd 150 960411 17 17 Mult Factor = 1.6 2 2 Mult Factor = 2.6 960411 Mult Factor = 1.6 960418 50 50.Max. Value Mpg 960418 nd nd Max. Value 20 pg/I-.--960418 pg/I nd nd Max. -Value— 4 412 pg/i pg/i pg/I J 960425 45 45 Max. Pred Cw 124.8 WI 960425 2 nd 2 Max. Pred Cw 52 960425 102 102 Max. Pred Cw 659.2 960502 2 0 2 0 Allowable Cw 109.3 Ng/i 960502 nd Allowable Cw 0.1 pg/i 960502 nd - nd Allowable Cw 62.1 960509 15 15 30 21 960509 960516 2 nd 2 960509 120 120 nd 100 nd 960516 3 0 nd 960516 nd 960522 21 960522 2 2 960522 100 960523 20 2 0 5 0 960523 nd nd 2 960523 nd 960530 5 0 960530 960606 2 960530 73 73 nd 960606 50 50 37 nd nd 960606 nd 960613 37 960613 2 2 960613 88 88 960620 23 2 3 960620 960627 nd nd 960620 nd nd 101 nd 960627 4 5 4 5 2 2 960627 101 960704 3 3 3 3 960704 nd nd 960704 nd 960711 3 7 37 960711 2 2 960711 120 120 960718 5 5 960718 nd nd 960718 nd nd 960725 2 5 2 5 960725 2 2 960725 106 106 960801 3 0 30 960801 nd nd 960801 nd nd 960808 24 2 4 960808 2 2 960808 130 130 960815 30 30 960815 nd nd 960815 nd nd nd 960822 6 0 60 960822 nd nd 960822 nd _ 960829 30 30 960829 960905r 2 nd 2 960829 116 116 960905 40 40 nd 960905_ 960912 141 160 141 160 960912 26 26 960912 960919 2 2 960919 30 30 nd nd 960919 nd nd nd 960926 20 20 40 960926 2 2 960926 nd 961003 40 961003 nd nd 961003 nd nd 140 961010 2 2 2 2 961010 961017 2 2 961010 140 961017 2 0 20 nd nd 961011 961024 140 169 nd 140 169 nd 130 961024 30 30 961024 2 2 961031 7 0 70 961031 nd nd 961031 961107 7 8 7 8 10 20 961107 961114 2 2 961107 130 961114 10 nd nd 961114 nd nd 961121 2 0 961121 961126 nd nd 961121 nd nd 961126 50 50- 2 2 961126 197 nd 197 nd 130 -1 961205 40 40 961205 961212 nd nd 961205 961212 40 40 2 2 961212 961219 1.30 nd 961219 30 30 40 961219 961226 nd nd nd _ 961226 40 2 2 961226 412 412 nd 970102 10 10 970102 970109 nd nd 970102 nd 970109 3 3 33 2 2 970109 120 120 970116 40 40 970116 nd nd 970116 970123 nd nd - rid 129 970123 40 40 - 970123 970130 nd nd nd 970130 40 40 2 2 970130 129 - 970206 20 20 5 5 970206 nd nd 970206 nd nd 970213 5 5 970213 2 2 970213 nd nd 970220 45 45 970220 nd nd 970220 nd nd 970227 5 5 5 5 970227 nd nd 970227 169 169 PAGE 1 ROAD CLASSIFICATION PRIMARY HWY HARD SURFACE•••• LIGHT -DUN ROAD, HARD OR IMPROVED SURFACE••• SECONDARY HWY HARDSURFACE•••• =MP UNIMPROVED ROAD ••• _ _ = 001-Latitude 35°31'34" Longitude 82°24'10" 002/3-Lat 35°31'25" Longitude 82°24'24" 004-Latitude 35°31'35" Longitude 82°24'10" Map # E9SW Sub -basin 040302 Stream Class C-Trout Discharge Class 14. 16. 56 Receiving Stream Cane Creek Design Q 0.0288MGp Permit expires 6/ 30/ 01 0 SCALE 1:24 000 0 1 MILE xzccxxozxsw�zaza.: 7000 FEET 0 1 KILOMETER WSW CONTOUR INTERVAL 40 FEET Communications Instruments NC00033227 Buncombe County WWTP cacility Name = NPDES # = Qw (MGD) = Qw (cfs) = 7010s (cfs)= IWC (%) = City of Gastonia/Long Creek WWTP NC0020184 8 12.3776 109 10.21 FINAL RESULTS Cadmium Max. Pred Cw Allowable Cw Chromium 4.2 19.6 Max. Pred Cw Allowable Cw Copper Max. Pred Cw Allowable Cw Lead Max. Pred Cw Allowable Cw, Mercury Max. Pred Cw Allowable Cw Nickel Max. Pred Cw Allowable Cw Silver Max. Pred Cw Allowable Cw Zinc Max. Pred Cw Allowable Cw 15.3 489.5 58.5 68.5 10.8 244.8 0.120 0.117 Parameter = Standard = CadGastunteg_R0g Creek WWfP8.0MGD to S Fork Catawba I n 960307 960314 CONVERSIC 960321 960328 0.4 960403 2.0 960411 1418 1.6 960425 50.0 960502 960509 6.0 960516 7.0 960522 960523 124.8 861.5 1.1 BDL=1/2DL Actual Data RESULTS 1 <2 Std Dev. <2 Mean <2 C.V. <2 n=53 <2 3 Mult Factor = <2 Max. -Value <2 Max. Pred Cw <2 Allowable Cw <2 <2 <2 1 1 1 1 3 1 1 1 1 1 1 <2 960530 1 _ <2 1 <2 1 <2 1 <2 25.0 960606 960613 0.0120/. 960620 0.0120 960627 1 <2 0.384760495 1.075471698 0.357759759 1.4 3 Ng/I 4.2 pg/I 19.6 pg/I 960704 1 <2 12.7 960711 1 88.0 960718 52.000 5.303 0.587 0.060 659.2 67.2 489.5 50.0 1 <2 <2 960725 1 960801' 1 <2 <2 960808 1 960815 1 <2 <2 960822 1 <2 960829 1 <2 960905 1 <2 960912 1 <2 960919 1 <2 960926 1 <2 961003 1 <2 961010 1 <2 961017 1 <2 961024 1 <2 961031 1 <2 961107 3 3 961114 1 <2 9611211 1 <2 961126 1 <2 961205 1 <2 961212 1 <2 961219 1 <2 961226 1 <2 970102 1 <2 970109 1 <2 9701161 1 <2 970123 - 1 <2 970130 1 <2 970206 1 <2 970213 1 <2 970220 1 <2 Parameter= Chromium Standard = 50 pg/l n BDL=1/2DL Actual Data RESULTS 960307` 7 960314 6 960321 7 960328 8 960403 4 960411 3 960418+ 3 960425 4 960502 1 960509 2 960516 4 960522 _ 2 960523 2 960530 2 960606 960613 960620 960627 960704 960711 960718 960725 960801 Std Dev. Mean C.V. n=53 1.99745847 3.16981132 0.63015059 Mult Factor = Max. Value Max. Pred C Allowable Cx 1.7 9 PO 15.3 pg/l 489.5 i g/I 960808 960815 960822 960829 960905 960912 960919 960926 961003 961010I 961017 961024. 961031 961107 961114`` 961121 961126 9612051 961212 961219 961226 970102 970109 970116 970123 970130 970206 970213 970220 2 5 1 2 6, 3 2 3 2 4 1 2 2 3 3 1 1 3 2 3 4 3' 4 1 2 6 7 6 2 3 2. 970227 1 <2 970227 PAGE 1 Parameter = Standard = Copper 7 n 960307 IJ 960314 960321 960328 960403 960411 960418 960425 960502 960509 BDL=1/2DL 19 nd nd 25 d nd Actual Data RESULTS 23 Std Dev. 7.9554 nd Mean 30.375 nd C.V. 0.2619 18 n=53 nd 24 Mult Factor = 1.3 nd Max. Value 45 31 11 Max. Pred Cw nd nd Allowable Cw 25 10 58.5 68.5 960516 nd nd 960522 26 9 960523 960530 960606 960613 960620 960627 960704 960711 960718 960725 960801 960808 960815 960822 960829 960905 960912 960919 960926 961003 nd - nd 18 11 nd nd 44 d 23 nd 29 nd 21 nd 32 nd nd 14 nd, 9' nd 21 nd 16 nd 16 nd nd 29 23 nd nd 41 46 nd nd 37 38 961010 nd nd 41 26 961017 961024 nd nd 961031 961107 961114 961121 961126 961205 961212 961219 961226 970102 970109 970116 970123 _970130 970206 970213 970220 970227 45 nd 37 nd nd 32 nd 26 nd 32 nd 30 nd nd 28 nd 19 nd nd 22 nd 25 nd nd 32 nd 26 nd 32 nd 30 nd nd 28 nd 19 nd nd N94 Parameter = Lead I E Sta98la -WHY C u ITP &0M3D to S Fortc tawba n BDL=1/2DL Actual Data 960307 1 960314 1 960321 1 960328 1 960403 1 960411 1 9604181 1 960425 960502 960509 960516 960522 960523 960530 960606 960613 960620 960627 960704 960711 960718 960725 960801 960808 960815 960822 960829 1 1 2.1 1 1. 1 1 4 2 2 1 1 1 1 960905 1 960912 2 960919 1 <2 960926 1 <2 961003 1 <2 961010 2 2 961017 2 2 961024 961031 961107 961114 961121 961126 961205 961212 961219 961226 970102 970109 970116 970123 970130 970206 970213 970220 970227 1 <2 1 <2 1 <2 3 3 4 4 2 2 6 6 3 5 4 1 1 1 1 1 1 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 2.1 <2 <2 RESULTS Std Dev. Mean C.V. n=53 1.2245 1.6623 0.7366 Mult Factor = .Max. Value 6 pg/1 Max. Pred Cw 10.8 pg/1 Allowable Cw 244.8 pg/l 4 2 2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 3 5 4 <2 <2 <2 <2 <2 <2 Parameter = Standard = Mercury 0.012 N9� n BDL=1/2DL Actual Data RESULTS_ 970401 0.1 <0.2 Std Dev. 2E-09 970410, 0.1 <0.2 Mean 0.1 970417 0.1 <0.2 C.V. 1 2E-08 970424 0.1 <0.2 n=13 970501 0.1 <0.2 970508 0.1 <0.2 Mutt Factor = 970515 970523 970529 970605 970612 970619 970626 0.1 - <0.2 Max. -Value- 4-_- 0.1 }WI 0.1 <0.2 Max. Pred Cw 0.12 pg/I 0.1 <0.2 Allowable Cw 0.117 Ng/1 0.1 <0.2 0.1 <0.2 0.1 <0.2 0.1 _<0.2 PAC El Parameter = Nickel Para eter = Silver to S Fork atawba R Parameter = Zinc _ Standard = 88 pg/l Sta Old -Lung Cre.I TP-8.0MGD i Standard = 50 pg/l RESULTS _ Actual Data 20 n 960307 BDL=1/2DL 20 nd nd 132 n BDL=1/2DL Actual Data n BDL=1/2DL Actual Data RESULTS 16.095 34.038 RESULTS Std Dev. 3.6742 960307 70 70 Std Dev. Mean 960307 960314 20 nd 20 Std Dev. 6.7.253 135.8 0.4952 960314 23 23 nd Mean 2.75 960314 nd nd 132 Mean C.V. n=53 960321 960328 960403 5 25 40 17 5 25 40 17 C.V. 0.4728 960321 nd nd C.V. 1.3361 960321 960328 n=53 Mull Factor = r 960328 960403 2 nd 2 2 nd 2 n=53 960403 nd nd Mull Factor = 960411 1.6 960411 Mull Factor = 2.6 960411 150 150 1.6 960418 50 50 Max.�/alue WW1 g/I • 60418 n d ndMax.-Value— —2 —0 pg/t 960418 nd� d Max. Value 412 pg/l 960425 1fJ O to O r 0. 0 O Is(h lA CrJ 1 h lA I IA O :r O I O O O (O O 0 0 N O. O i 0 GD O i 0 0 0 i 0 0 O O� M 1.4' N I r CO N Csl!LOlIUl M 1 N Nr I M!M 1N MIN M1CD M N M NV.IN Ni I� r NI O V',T'M ctIIri CI ' I 1 I I _ 4 5 Max. Pred Cw 124.8 pg/l 960425 2 2 Max. Pred Cw 52 pg/i 960425 102 102 Max. Pred Cw 659.2 pg/i 960502 2 0 Allowable Cw 861.5 pg/l _ 960502 _ nd _ _ nd Allowable Cw 0.6 pg/i 960502 nd nd Allowable Cw 489.5 pg/i 960509 15 960509 2 2 960509 120 120 960516 3 0 960516 nd nd 960516 nd nd 960522 21 960522 2 2 960522 100 100 960523 20 _ 960523 nd nd 960523 nd nd 960530 5 0 960530 2 2 960530 73 73 960606 5 0 960606 nd nd 960606 nd nd 960613 3 7 960613 - 2 2 960613 88 88 960620 2 3 960620 nd nd 960620 nd nd 960627 4 5 960627 2 2 960627 101 101 960704 3 3 960704 nd nd 960704 nd nd 960711 3 7 960711 2 2 960711 120 120 960718 5 960718 nd nd 960718 nd nd 960725 2 5 960725 2 2 960725 106 106 960801 3 0 960801 nd nd 960801 nd - nd 960808 2 4 960808 2 2 960808 130 130 960815 30 960815 nd nd 960815 nd nd 960822 6 0 960822 nd nd 960822 nd nd 960829 3 0 960829 2 2 960829 116 116 960905 40 960905 nd nd 960905 141 141 960912 26 960912 2 2 960912 160 160 960919 30 960919 nd nd 960919 nd nd 960926 20 960926 2 2 960926 nd nd 961003 4 0 961003 nd nd 961003 nd nd - 961010 2 2 961010 2 2 961010 140 140 961017 2 0 961017 nd nd 961011 140 140 _ 961024 3 0 961024 2 2 961024 169 1 961031 70 961031 nd nd 961031 nd nd 961107 78 961107 2 2 961107 130 130 961114 101 961114~ nd nd 961114 nd nd 961121 20 961121 nd nd 961121 nd nd• 961126 5 0 961126 2 2 961126 197 197 961205 40 961205 nd nd 961205 nd nd 961212 4 0 961212 2 2 961212 130 130 961219 30 961219 nd nd 961219 nd nd ' 961226 40 961226 2 2 961226 412 412 970102 10 970102 nd nd 970102 nd nd 970109 33 970109 21 2 970109 120 120 970116 40 40 970116 nd nd - _ 970116 nd nd 970123 40 40 970123 nd nd 970123 nd nd 970130 40 40 970130 2 2 970130 129 129 ' — 970206 20 20 970206 nd nd 970206 nd nd 970213 5 5 5 5 _ — 970213 2 2 _ 970213 nd nd 970220 45 4 5 970220 nd nd 970220 nd nd 970227 5 51 5 5 970227 nd nd 970227 169! 169 PAGE 1 acility Name = NPDES # = Qw (MGD) = Qw (cis) = 7010s (cfs)= !WC(%)= City of Gastonia/Long Creek 1NWTP Parameter= NC0020184 Standard = 16 24.7552 109 18.54 Cadmium GdbtUllld s .g➢SI Creek WW TP-16.0MGD to S-Fork -Catawba n BDL=1/2DL Actual Data RESULTS 960307 FINAL RESULTS Cadmium Max. Pred Cw Allowable Cw Chromium Max. Pred Cw Allowable Cw Copper Max. Pred Cw Allowable Cw Lead Max. Pred Cw Allowable Cw Mercury Max. Pred Cw Allowable Cwl Nickel Max. Pred Cw Allowable Cw 4.2 10.8 15.3 269.8 58.5 37.8 CONVERSIC 0.8 2.0 2.8 50.0 10.8 134.9 0.120 0.065 124.8 474.8 Silver Max. Pred Cw Allowable Cw Zinc Max. Pred Cw Allowable Cw 52.000 0.324 659.2 269.8 10.8 7.0 2.0 25.0 0.022 0.012. 23.1 88.0 960314 960321 960328 960403, 960411 960418 960425, 960502 960509 960516 960522 960523 960530 960606 960613 960620 960627 960704 960711 960718 960725 9.624 960801 0.060 122.0 50.0 960808 960815 960822 960829 960905 960912 960919 960926 961003 961010 961017 961024 961031 961107 961114 961121 961126 1 <2 Std Dev. 0.384760495 1 <2 Mean 1.075471698 1 <2 C.V. 0.357759759 1 <2 n=53 1 <2 3 3 Mutt Factor = 1.4 1 <2 Max. Value -3 119/l 1 <2 Max. Pred CW 4.2 pg/I 1 <2 Allowable Cw 10.8 pg/I 1 <2 _ 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 _ <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 1 <2 3 3 1 <2 1 <2 1 <2 961205 1 961212 961219 961226 970102 970109 970116 970123 1 1 970130 970206 <2 <2 <2 <2 <2 <2 <2 970213 970220 970227 <2 <2 <2 Parameter= Chromium Standard = 50 N�/1 n BDL=1/2DL Actual Data 960307L 7 960314 6 960321 7 960328 8 960403 960411 960418 960425 960502 960509 960516 960522 960523 960530 RESULTS Std Dev. 1.99745847 Mean 3.16981132 C.V. 0.63015059 n=53 4 3 4 4 Mu/t Factor = Max. Value Max. Pred C Allowable Cv, 1.7 9 pg/I 15.3 Ngll 269.8 pg/I 2 2 2 960606 2 960613 2 960620 4 960627 9 960704 1 960711, 960718 960725 960801 960808 960815 960822 960829 960905 960912 960919 4 960926 1 961003 961010 961017 961024 961031 961107 961114 961121 961126 961205 961212 961219 961226 970102 970109' 2 5 1 2 6 3' 2 3 2 3 1 1 4 3 4 1 970116 6 970123 7 970130 6 970206 2 970213 3 970220 2 970227 2 PAGE1 Parameter = Copper Pa meter = is - St �- Lead 'Luny C►eu � -16.0 � GD to S Fork atawba T R Parameter = Mercury Standard = 7 Ng/l 7.9554 30.375 0.2619 Standard = 0.012 Ng/l 2E-09 0.1 - Actual Data RESULTS J n 960307 RESULTS Std Dev. - BDL=1/2DL 0.1 0.1 BDL=1/2DL Actual Data 23 nd RESULTS Std Dev. Mean n BDL=1/2DL Actual Data 1.2245 1.6623 n 19 nd 960307 960314 1 1 <2 <2 <2 <2 970401 <0.2 <0.2 Std Dev. Mean 960314 Mean C.V. 970410 960321 nd nd C.V. 960321 1 0.7366 970417 970424 970501 0.1 <0.2 C.V. 2E-08 960328 25 nd 18 nd n=53 _ 960328 960403 960411 1 n=53 0.1 0.1 <0.2 n=13 960403 1 1 <2 <0.2 <0.2 960411 39 nd 24 Mult Factor = 1.3 <2 Mult Factor = 1.8 970508 0.1 Mult Factor = 1.2 960418 nd Max. Value 45 960418 1 <2.Max_Value . ii9a 97-0515 ax. Value 0.-1 pg/I 960425 31 11 Max. Pred Cw 58.5 pg/I 960425 1 <2 Max. Pred Cw - 10.8 pg/I 970523 0.1 <0.2 Max. Pred Cw 0.12 pg/I 960502 nd nd Allowable Cw 37.8 pg/I 960502 1 <2 Allowable Cw 134.9 pg/I 970529 0.1 <0.2 Allowable Cw 0.065 pg/I 960509 25 10 960509 1 <2 970605 0.1 <0.2 960516 nd nd 960516 i 2.1 2.1 970612 0.1 <0.2 960522 26 9 9605221 1 <2 970619 0.1 <0.2 960523 nd nd 960523 1 <2 970626 0.1 <0.2 1 960530 18 11 _ 960530 1 <2 - - 960606 nd nd 960606 1 <2 1 960613 44 14 960613 _ 4 4 960620 nd nd_ 960620 2 2 960627 23 9 960627 2 2 960704 nd nd 960704 1 <2 960711 29 21 960711 1 <2 - 960718 nd nd 960718 1 <2 960725 21 16 960725 1 <2 960801 nd nd 960801 1 <2 960808 32 16 960808 1 <2 1- 960815 nd _ nd 960815 960822 1 <2 _ 960822 nd nd 1 <2 960829 29 23 960829_ 1 <2 960905 nd nd - - - 960905 1 <2 960912 41 46 960912 2 2 960919 nd nd 960919 1 <2 960926 37 38 960926 1 <2 961003 nd nd 961003 1 <2 961010 41 26 961010 2 2 - 961017 NI nd 961017~ 2 2 - - 45 22 961024 1 961024 <2 961031 nd nd 961031 1 <2 961107 37 25 961107 1 <2 961114 nd nd 961114 3 3 961121 nd --- nd 961121 4 4 961126 32 32 961126 2 2 - - - - - 961205 nd nd 961205 6 6 961212 26 26 961212 3 3 961219 nd nd 961219 5 5 961226 32 32 961226 4 4 970102 nd nd 970102 1 <2 970109 30 30 970109 - 1 _ <2 - - - 970116 nd nd 970116 1 <2 970123 nd nd 970123 1 <2 970130 28 28 970130 1 <2 970206 nd nd 970206 1 <2 970213 19 19 970213 1 <2 970220 nd nd 970220 4 4 970227 nd nd 970227 4 4 PAC E1 Parameter: Nickel Para afar ir St liver 16.0h11GD to S Fork-&tawba I Parameter = Zinc _ n BDL=1/2DL 20 Actual DataFR-ESULTS n BDL=1/2DL Actual Data RESULTS Actual Data RESULTS n BDL=1/2DL 960307 70 70 Std Dev. 16.095 34.038 960307 20 Std Dev. 3.6742 960307 960314 20 nd 20 Std Dev. 67.253 960314 23 23 Mean 960314 nd nd Mean 2.75 1.3361 nd Mean 135.8 _ 960321 960328 5 5 C.V. 0.4728 960321 nd nd C.V. 960321 nd nd 132 C.V. 0.4952 25 25 n=53 960328 2 2 n=53 960328 132 nd _ n=53 960403 40 40 17 960403 nd nd 960403 nd 960411 960418 17 Muft Factor = 1.6 960411 2 2 Mult Factor = 2.6 960411 150 150 Muft Factor = 1.6 50 50 Max. V- I : : ! _960418 nd nd-Max-Value— 20 p pg/I pg/I 80418 nd nd Max. Value 412 pg/I pg/I pg/I ___ _ _ _ 960425 4 5 20 4 5 20 Max. Pred Cw Allowable Cw 124.8 pg/I 960425 2 2 Max. Pred Cw 52 960425 960502 102 nd 102 nd Max. Pred Cw Allowable Cw 659.2 960502 474.8 g/I 960502 nd nd Allowable Cw 0.3 269.8 960509 15 15 30 960509 2 2 - 960509 120 nd 120 nd 960516 30 960516 nd nd 960516 960522 21 20 21 960522 2 2 2 960522 100 nd 100 960523 20 960523 nd 960523 nd 960530 960606 960613 50 50 960530 2 nd 960530 73 73 50. 37 50 37 960606 960606,nd 960613 960620 960627 88 nd 101 nd 88 960613 2 2 960620 23 23 4 5 960620 nd nd nd 960627 4 5 960627 2 2 101 960704 33 33 37 960704 nd nd 2 960704 nd 120 nd 960711 960718 37 5 960711 2 960711 120 5 25_ 960718 nd nd 960718 960725 nd nd 960725 25 960725 2 2 nd 106 106 nd 960801 30 30 960801 nd 960801 nd 130 960808 2 4 2 4 960808 2 2 nd 960808 130 960815 960822 30 60 30 960815 nd 960815 nd nd 116 141 160 nd ndr 60 960822 nd nd 960822 960829 960905 960912 960919 nd 960829 30 30 960829 2 2 116 960905 960912 40 40 2 6 960905 960912 nd 2 nd 141 160 26 2 960919 30 30 960919 nd nd nd 960926 20 20 960926 2 2 nd 960926 nd nd nd 961003 40 40 961003 nd 961003 961010 961011 nd 140 961010 2 2 2 2 961010 2 nd 2 nd 140 140 169 961017 961024 20 30 70 20 961017 140 169 nd 30 961024 2 2 961024 961031 70 961031 961107 nd 2 nd nd 2 961031 nd 130 nd nd 197 961107 78 10 20 7 8 10 20 961107 130 961114 961114 nd 961114 nd 961121 961121 nd nd 961121 961126 nd 197 961126 961205 50 50 961126 2 2 40 40 301 40 961205 nd nd 961205 nd nd 130 nd 412 nd 961212 961219 40 961212 2 2 nd 2 nd 2 961212 961219 961226 970102 130 nd 412 30 961219 961226 970102 nd 2 nd 961226 970102 40 40 1 0 1 0 nd 970109 33 33 40 970109 2 970109 120 120 nd. nd 970116 40 970116 nd nd 970116 970123 nd nd 970123 970130 40 40 970123 nd nd 40 20 40 20 970130 2 2 970130 129 129 nd 970206 970206 nd nd 970206 nd 970213 55 55 970213 2 2 nd nd 970213 nd nd 970220 4 5 4 5 970220 nd ndl 970220 nd nd 169 970227 55 5 51 1 970227 i 970227 1691 PAGE 1 acility Name = City of Gastonla/CrowdersCreek WWTP Parameter= Cadmium ::?Parameter= Chromium NPDES # = NC0074268 Standard = 2 _ _ Standard = 50 pg/I Ow MGD = 6-- Ow (cis) = 9.2832 -- 7010s cis = 13.3C n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS �E� 960307 1 <2 Std Dev. 0.233295318 960307 7 Std Dev. 1.99745847 960314 1 <2 Mean 1.056603774 960314 6 Mean 3.16981132 WPM CONVERSIC 960321 1 <2 C.V. 0.220797354 960321 7 C.V. 0.63015059 Cadmium 960328 1 <2 n=53 960328 8 n=53 Max. Pred Cw 2.4 1.0 960403 1 <2 960403 4 Allowable Cw 4.9 2.0 960411 2 2 Mutt Factor = 1.2 960411 3 Mutt Factor 9 1.7 Chromium 960418 1 <2 Max. Value 2 i. 960418 3 Max. Value 9 pgil Ng+l Max. Pred Cw 15.3 6.3 960425 1 <2 Max. Pred C 2.4 „t 960425 4 Max. Pred C 15.3 Allowable Cw 121.5 50.0 960502 1 <2 Allowable Cw 4.9 .r 960502 1 Allowable Cv‘ 121.5 14 Coy=r 960509 1 <2 960509 2 Max. Pred Cw 73.6 30.3 960516 1 <2 -- 960516 4 AllowableCw 17.0 7.0 960522 1 <2 960522 2 Lead 960523 1 <2 -- 960523 2 Max Pred Cw 10.8 4.4 960530 1 <2 960530 2 Allowable Cw 60.8 25.0 960606 1 <2 960606 2 Mercur 960613 2 2 -- 960613 2 Max. Pred Cw 0.120 0.049 960620 1 <2 960620 4 Allowable Cw 0.029 0.012 960627 1 <2 960627 9 Nickel 960704 1 <2 960704 1 Max. Pred Cw 68.0 28.0 960711 1 <2 960711 1 AllowableCw 213.8 88.0 960718 1 <2 960718 2 Silver 960725 1 <2 960725 5 Max. Pred Cw 2.000 0.822 960801 1 <2 960801 1 Allowable Cw 0.146 0.060 960808 1 <2 960808 2 Zinc 960815 1 <2 960815 6 Max Pred Cw 143.0 58.8 960822 1 <2 960822 3 Allowable Cw 121.5 50.0 960829 1 <2 960829 2 960905 1 <2 960905 3 960912 1 <2 -- 960912 2 960919 1 <2 -- 960919 4 960926 1 <2 960926 1 961003 1 <2 961003 2 961010 1 <2 961010 2 961017 1 <2 961017 3 961024 1 <2 961024 3 961031 1 <2 961031 1 961107 2 2 -- 961107 1 961114 1 <2 961114 1 961121 1 <2 961121 3 961126 1 <2-_ <2 961126 2 961205 1 961205 3 961212 1 <2 961212 4 961219 1 <2 961219 3 961226 1 <2 -- 961226 4 970102 1 <2 970102 1 970109 1 <2 -- -- 970109 2 970116 1 <2 970116 6 970123 1 <2 -- 970123 7 970130 1 <2 -- 970130 6 970206 1 <2 -- 970206 2 970213 1 <2 -- 970213 3 970220 1 <2 970220 2 PAC 970227 1 <2 970227 2 _ o..v,it 66, � � �v77 - i9 2/ YSL 3 u v6- G .)/z.,t//I s CU cif. v --s'1'1112L /fL) 7c�t(�vl L2uc i9-7,11 a /tits4L7-&e4'f-7e- i x7i0v,ye7/101. Parameter = Copper Parameter= Lead ° wders CrkWWTP N Parameter = Mercury _ - Standard = 7 PO Standard = Gas - Standard = 0.012 pg/I n 960307 BDL=1/2DL 23 Actual Data 23 RESULTS 9.0769 n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS Std Dev. 960307 1 <2 Std Dev. 1.2245 1.6623 970401 0.1 <0.2 Std Dev. 2E-09 960314 nd nd Mean 18.708 960314 1 <2 Mean 970410 0.1 <0.2 Mean 0.1 960321 nd nd C.V. 0.4852 960321 1 <2 C.V. 0.7366 970417 0.1 _ _ <0.2 C.V. 2 E-08 960328 960403 18 nd 18 _ n=53 960328 1 <2 <2 n=53 1 970424 0.1 <0.2 n=13 nd 960403 - -- 1 1 970501 0.1 <0.2 960411 24 24 Mutt Factor = 1.6 960411 <2 Mutt Factor = 1.8 970508 0.1 <0.2 Mult Factor = 1.2 960418 nd nd Max. Value 46,01 73.6,L,g 960418 1 <2 Max Value 6-#911_ 970545 0.1 < . ax. Value- Max. Pred Cw _ 960425 960502 - _ 11 11 Max. Pred Cw - 960425 - 1 1 <2 Max. Pred Cw 10.8 _ pg/I 970523 0.1 -- <0.2 0.12 pg/I g -- nd nd Allowable Cw 17.0 pg/I 960502 <2 Allowable Cw 60.8 - pg/I 970529 0.1 <0.2 Allowable Cw 0.029 960509 10 10 960509 1 <2 970605 0.1 <0.2 960516 nd nd 960516 2.1 2.1 _ 970612 0.1 _ <0.2 960522 9 9 960522 1 <2 970619 0.1 0.1 <0.2 <0.2 960523 nd nd 11 960523 1 <2 _ 9.70626 960530 960606 11 960530 1 <2 - - nd nd 960606 1 <2 960613 14 nd 14 960613 4 4 - _ - 960815 nd nd 960815 1 <2 960822 960829 nd nd 960822 1 <2 - 23 23 nd 960829 _ 1 -_ <2 <2 960905 nd 960905 1 960912 46 nd 46 960912 2 2 <2 __-- -_---- �- - ---J- 960919 nd 960919 1 - - 960926 38 38 960926 1 <2 ___ 961003 961010 nd nd 961003 1 <2 26 26 961010 2 2 961017 nd nd 961017 2 1 1 2 ~ - 961024 961031 22 22 961024 <2 <2 nd nd 25 961031 961107 9611141- 25 961107 1 3 <2 nd nd~ 961114 _ 961121 nd nd 961121 4 4 1 1 961126 961205 16 nd 16 nd _-- 961126 2 6 2 6 961205 961212 961219 18 nd 18 961212 3 3 nd 961219 961226 --- 970102 9 9 961226 4 4 -- -- nd nd 970102 1 <2 - - - _- 970109 11 11 970109 1 <2 970116 nd nd - 970116 1 <2 f 970123 nd nd 970123 1 <2 970130 14 14 970130 1 <2 <2 970206 nd nd 970206 1 - 970213 19 19 970213 1 <2 1PAC 970220 nd nd 970220 4 4 970227 nd nd -~ 970227 4 4 El Parameter= Standard = Nickel 88 Parameter= Silver Standard =—6'ag44[0wders Crk WWTP n 960307 960314 960321 9603281 960403 960411 960418 960425 960502 960509 960516 960522 960523 960530 960606 960613 960620 960627 960704 960711 960718 960725 960801 960808 960815 960822 960829 960905 960912 960919 960926 961003 961010 961017 961024 961031 961107 961114 961121 BDL=1/2DL Actual Data 5 5 15 20 5 5 5 961126 961205 961212 961219 961226 970102 970109 970116 970123 970130' 970206 970213 970220 970227 25 10 5 30 5 5 40 10 5 28. 20 5 12 5 10 30 10 20 30 30 30 13 30 30 30 12 10 20 40 31 10' 20! 20 5 18 20 10 10 12 20 10 1 10 15 15 35 RESULTS Std Dev. 10.515 Mean 16.453 C.V. 0.6391 n=53 Mutt Factor = 1.7 Max. Value 40 Max. Pred Cw 68 N9/1 Sg/1 Allowable Cw 213.8 pg/I Parameter = Standard = n DDL=1/2DL Actual Data 960307 2 960314 nd 960321 nd 960328 2 960403 nd, 960411 2 960418 960425 2 960502 nd 960509 2, 960516 nd 960522 2 RESULTS Std Dev. 0 Mean 2 C.V. 0 n=53 Mult Factor = Max...Value 2 Max. Pred Cw 2 Allowable Cw 0.1 960523 nd Zinc 50 pg/I n BDL=1/2DL Actual Data 960307 55 _ 960314 nd 960321 nd 960328 61 960403 nd 960411 ' 52 Ng/l--960418 nd Ng/1 960425 33 pg/I 960502 nd 960509 61 960516, nd 960522 47 960523 nd 960530 2 960606 nd 960613 2 960620 nd 960627 2 RESULTS Std Dev. Mean C.V. n=53 Mull Factor = Max. Value Max. Pred Cw Allowable Cw 21.06 75.667 0.2783 1.3! 960530 960606, 960613 960620 960627 960704 nd 960704 960711 2 960711 960718 nd 960725 960801 960808 960815 2 nd 2 nd 960822 nd 960829 2 960905 nd 960912 2 960919 nd 960926 2 960718 960725 960801 960808 960815 960822 960829 960905 960912 960919 960926 961003 nd 961010 2 961003 961010 961017 nd 961017 961024 961031 961107 961114 961121 961126 961205 2 n 961024 961031 2 961107 nd nd 2 nd 961212 2 961219 nd 961226 2 970102 nd 970109 2 970116 nd 961114 39 nd 70 nd 94 nd 92 nd 96 nd 80 nd nd 110 I.1g/l 143 Vg/I 121.5 pg/I 85 nd 88 nd 66 nd 91 nd 79 nd 110 nd 961121 nd 961126 59 961205 nd 961212 100 961219 nd 970123 nd 970130 2 970206 nd 970213 2 970220 nd 970227 nd 961226 101 970102 nd 970109 - 80 970116 nd 970123 nd 970130! 61 9702061_ nd 970213' _ 96 970220 nd 970227 nd PAGE 1 PST Gastonia - Long Crk WWTP 8.0MGD to Long Creek Facility Name = City of Gastonia/Long Creek WWTP NPDES # = Qw (MGD)= Qw (cfs) 7010s (cis). /WC (%) = NC0020184 8 12.3776 3 80.52 Cadmium Max. Pred Cw Allowable Cw Nickel Max. Pred Cwt Allowable Cw Lead Max. Pred Cw Allowable Cw Mercury Max. Pred Cw' Allowable Cw Copper Max. Pred Cw Allowable Cw Silver _ Max. Pred Cw Allowable Cw Zinc Max. Pred Cw Allowable Cw FINAL RESULTS 1.2464 Parameter = Standard = CONVERSN BAT - RESLT£ 1.003 0.37 2.5 2.000 51.75 41.654 42.7 109.3 88.000 77.76 31.0 1.02 0.015 236.86 8.7 62.590 _ 13 25.000 Parameter= Standard = Cadmium 2 pg/I I n BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS 1 0.076 0.076 Std Dev. 0.0_7.4276062 1 17.3 17.3 Std Dev. 2 0.089 0.089 Mean _ _ 0.0986 2 25.5 25.5 Mean 3 0.104 0.104 C.V. ' 0.753306913 3 _ 28.45 28.45 C.V. 4 0.073 0.073 n=10 4' 23.6 23.6111=10 5 0 075 _-_ 0.075 5 --t9.3 19.3'- 6 0.304 0.304 Mutt Factor =) 4.1 'I 6 34.5 i 7 0.09 0.09 Max. Value 0.304 pg/I 7 _ 34.4' 0.063 0.063 Max. Pred Cy., 1.2464 pg/I 8' 28.1 0.074 0.074 Allowable Cw 2.5 pg/I 9 26 0.038 0.038 10 30.2 01E51L04/6-gBAT Parameter= Nickel - _ Standard = 88 Ng/I 0.821 0.131 0.012 190.651 155 7.000 2.4928 2.006 0.79 0.075 0.060 627 504.679 351 62.097 50.000 Parameter = Standard = Silver 0.06 p9" 5.69649259 26.735 0.21307247 34.5 Mull Factor 1.5j 34.4IIMax. Value 28.1 !MaxPred C1_ 26 Allowable CA 30.2 34.5 pg/I 51.75 pg/I 109.3 pg/I BDL=1/2DL Actual Data RESULTS n BDL=1/2DL Actual Data RESULTS 1 43.2 43.2 Std Dev. 19.54943591 1 0.128 0.128 Std Dev. 2 32.8 32.8 Mean 38.36 2 0.136 _ 0.136 Mean 3 33 33 C.V. 0.509630759 3 0.104 0.104 C.V. 4 27.2 27.2 n=10 j j 4 0.1 0.1 n=10 5 23.7 _ 23.7 _ 1.5 0.0756 0.0756 6 91.1 91.1 Mu __ lt Factor = { 2_61 6 0.608 0.608 Mult Factor 9r4.11 7 34 34 Max. Value 91.1 pg/I 7 0.163 0.163 Max. Value 0.608 pg/l_ 8 31.5, 31.5 Max. Pred Cw 236.86 ug/I S 0.104 0.104 Max. Pred C1 2.4928 pg/1_ 9 41.4 41.4 Allowable Cw 8.7 pg/I 9 0.255 _ 0.255 Allowable Col 0.1 pg/I 10 25.7 25.7 10 0.232 0.232 0.15782488 0.19056 0.82821619 Coe G? a cd (6)„ Cce PAGE 1 "BAT Gastonia - Long Crk WWTP 8.0MGD to Long Creek parameter= Standard = Lead Parameter= Mercury 25 pg/i Standard = 0.012 jg/I n n BDL=1/2DL BDL=1/2DL Actual Data RESULTS Actual Data RESULTS _ 0.029 1 2.165 2.165 Std Dev. Mean 2.772 1.9524 1 0.00773 0.00773 Std Dev. 2 1.2 1.2 2 0.00645 0.00645 Mean 0.0174 3 1.345 1.345 C.V. 1.4198 3 0.00774 0.00774 C.V. 1.6787 4 1.13 1.13 n=10 _ 4 0.00686 0.00686 n=53 5 1 23 1 23 r 3 --0.008431-0 00643 Mult Factor = 6 7 8 9 10 9.72 9.72 Mult Factor = 8 6 0.1 0.1 10.2 1.06 1.06 Max. Value 9.72 pg/I 7 0.00743 0.00743 Max. Value 0.1 pg/l g/l 0.54 0.54 Max. Pred Cw 77.76 pg/l 8 pg/I 9 10 0.00709 _ 0.00709 Max. Pred Cw 1.02 0.647 0.487 0.647 Allowable Cw 31.0 0.0151 0.0088 1 0.0151 Allowable Cw 0.01541g/1 0.487 0.0088 60.041 - - Parameter= Zinc -- - Standard = 50 pg/l Actual Data RESULTS n BDL=1/2DL 158 1 158 Std Dev. 2 3 137 137 Mean 163.85 - 126.5 126.5 C.V. n=10 0.3664 4 137 137 5 6 133 285 133 285 Mutt Factor = _ _ 7 8 141 141 Max. Value 285 ggll 171 171 Max. Pred Cw 627 9 _ 256 94 256 Allowable Cw 62.1 g/I 10 - 94 PAGE 1 Gastonia - Long Crk WWTP 8.0MGD to Long Creek Facility Name = City of Gastonia/Long Creek WWTP NPDES#= NC0020184 Qw (MOD) = 8 Qw (cfs) = 12.3776 7Q10s (cfs)= 3 1WC(%)= 80.52 FINAL RESULTS CONVERSN BAT Cadmium Max. Pred Cw RESLTE —1.2464 1:003 0.37 Allowable Cw 2.5 2.000 Nickel Max. Pred Cw 51.75 41.654 42.7 Allowable Cw 109.3 88.000 Lead Max. Pred Cw 77.76 62.590 13 Allowable Cw 31.0 25.000 Mercury Max. Pred Cw 0.02718 0.022 0.131 Allowable Cw 0.015 0.012 Copper Max. Pred Cw 236.86 190.651 155 Allowable Cw 8.7 7.000 Silver Max. Pred Cw 2.4928 2.006 0.79 Allowable Cw 0.075 0.060 Zinc Max Pred Cw 627 504.679 351 Allowable Cw 62.097 50.000 ,e(46oa. f ..� �� 0414/1��� PAGE 1 c-A'T Gastonia - Long Crk WWTP 8.0MGD to imor@reer' S Faciffry Name= City of Gastonia/Long Creek WWTP NPDES # = NC0020184 Qw (MGD) = 8 Ow (cfs) = 12.3776 7Q10s (cfs)= 109 IWC (%) = 10.21 FINAL RESULTS CONVERSN BAT Cadmium RESLT; PrAd [:w 1 2464 0.127-0:27 _Ma Allowable Cw 19.6 2.000 Nickel Max. Pred Cw 51.75 5.277 42.7 Allowable Cw 861.5 88.000 Lead Max. Pred Cw 77.76 7.930 13 Allowable Cw 244.8 25.000 0.131 155 Mercury -- 0.104 0.012 Max. Pred Cw 1.02 Allowable Cw 0.117. pper Max. Pred Cw 236.86 24.154 Allowable Cw 68.5 7.000 Silver Max. Pred Cw 2.4928 0.254 0.79 Allowable Cw 0.587 0.060 Zinc Max. Pred Cw 627 63.939 351 Allowable Cw 489.516 50.000 PAGE 1 Gastonia - Long Crk VVWTP,B.OMGD to Leorrereek---• S' Facility Name = City of Gastonia/Long Creek WWTP NPDES#= NC0020184 Qw (MGD) = 16 Ow (cfs) = 24.7552 7Q10s (cfs)= 109 IWC (%) = 18.54 BAT FINAL RESULTS CONVERSN Cadmium RESLTE 0.37 Max. Pred Ctv 1 24R4 0231 Allowable Cw 10.8 2.000 42.7 Nickel Max. Pred Cw 51.75 9.578 Allowable Cw 474.8 88.000 Lead 13 0.131 155 Max. Pred Cw 77.76 14.392 Allowable Cw 134.9 25.000 Mercury 0.189 Max. Pred Cw 1.02 Allowable Cw Copper Max. Pred Cw 0.065 0.012r 236.86 43.838 Allowable Cw 37.8 7.000 Silver Max. Pred Cw 2.4928 0.461 0.79 Allowable Cw 0.324 0.060 Zinc Max. Pred Cw 627 116.044 351 Allowable Cw 269.758 50.000 PAGE 1 �.Je i 't,Lk 1 0 -7n .a 6 t,Q,-fa C P A S E f,R,do��( bE «-1,1 1:5?,e- Architecture Engineering Planning Interiors ' ra7 October 3, 1996 c bite, J�-c� Mr. Paul Clark North Carolina Department of Environment, Health, and Natural Resources Division of Water Quality, NPDES Post Office Box 29535 Raleigh, North Carolina 27626-0535 Reference: Long Creek Wastewater Treatment Plant NPDES Permit No. NC0020184 Gaston County, North Carolina J.N. Pease Associates' Commission No. 96051-00 Subject: Automated Sampling and Analysis of the South Fork River Dear Mr. Clark: In accordance with our discussion, J.N. Pease Associates has been developing a design for the installation of the equipment necessary for the subject sampling. The following information is enclosed for your review: • A Map showing the Location of Sampling Sites • Photographs of Sites • Typical River Sonde (Probe) Installation Drawing • Literature on the Sampling Probes • Cross Section of Sampling Sites We have evaluated various methods for installing the probes in the river and have concluded that the best approach would be to install the probes in submerged pipe sleeves in a manner similar to the enclosed typical installation drawings. In previous discussions with Mr. Dave Goodrich concerning this project, he indicated that DEM would probably prefer that the sampling points be at mid- stream. We believe that sampling at mid -stream - a distance of 60 to 160 feet from the bank depending upon the site - is not achievable. The probes must be retrieved periodically for maintenance, calibration, and retrieval of stored data. The probe weighs approximately five pounds and would have to be inserted and retrieved using a cable and pulley system. J.N. Pease Associates 2925 East Independence Blvd. P.O. Box 18725 Charlotte, NC 28218 704 376-6423 Mr. Paul Clark Page 2 October 3,1996 In our opinion, approximately 25 feet would be the maximum distance from the bank that the probe could be inserted and retrieved with a reasonable amount of effort. Please advise if the DEM would allow the probes to be positioned in the river at a distance of approximately 25 feet from the bank. If you have any questions or need additional information, please call. A. Keith West, PE AKW/lh cc: Mr. Coleman Keeter Mr. Larry Cummings Mr. Thorne Martin Mr. John Shuler Mr. Don Garbrick eid4cad /02474Ja 4.01144,1a 444.11•41)-. 66i 0 1 4 I. ipt:Ao (7 Prmk, T'odu);, Pe_hc 492— ketk GO t 4 S Pa peovnt.)4 40-04.- 44444-e 642 Aca.4,-4-$- frnpfrIttA A,A.t. cj A 6AA_ moo 4) i - cm-/ac.— OlL0-40 e‘i 7,1-0 7°6' r c c a;'70,., Ind1;11 dac..J, o0.d 0 i rri S eta.)fY'v` effe ir on, 4,,,71-4 cm,€) keex4,3 -silt I t)-)of'fr, ./2, 1->v; /or at 044 ,t -c oia.d izuL . p-DA , %.4 �t' rx� +J /7-1a.3,ha�t A'S p2s _ �S" fort &k avoic0 poor-S 1-.-t--E 2 I srre z(-- ZIPf(-, ?WI/14aq lie- tb .6271'40 lel 11-c 40 6') h‘-e,. -6 Jo Mni VIIT.,C1/0114. 714alittIce ;/-rriitity6,/ 6(LA. a6i41/7."--q ttht TPT 4V1 ,Z) U4li79 7 4 7 -mic-7/7 (Aviv -5/A fr/ni 1( 4f1/xti • e [Lc/ 0)604 ratt Wry Gvid hirri‘t ((X ioro- ('t. rtioli . 7/ - ri1/99 7 /-iila / i .2 ..ice.-,;6„ --- 9 46,.• (new , 7 rf / 4,1—) „d.--c 3117 t/ril LAM ic-h' i ".(,-- - ...-- • , - 1 - ,-, . -..., (7 - 1:: ./Pit`/,.:-/ ( Ctn. --Air of- pv147 woycyr IFTI ti----ii? t-btic k ! ,,i'il (6. -.'fili---");..._,'?((e(1.i. 71.•:!''' 7/9(4).).\' ' i7fivalk Y tz.-friz 1,-- ;/-1::- cf . -:-----_,- 1 i 1 7 / ;4 L- Z• r( f°E62-- e'4,‘. 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Alems 3,g,nri4!40 C-14-5,-rn VIAT - Pe kvt_ wee.#171-- 74 rt krok 7 / 41-i'IN ft leir . toil -to riv6e bti...T.,e3:4:.- /44/ Tmi4.f- VA / Pi — - — -- - -- ---,.--- Wdedy t• ne5 gee . 1,2,.,7 h'n, ii • " /hi, aeiee75 't : - bn 0 'r / --- /iv / iCA 5;6 / .r. 514,6 ,-7A-4-- zt-Pfset Y ‘1 eci"-1,71' 47 ".-261:. TiC. 2 fr 6</retrum -1.-27/e•/;c1 ere' ha /le -/..C.:11•:74 4,..7,4 r7 frki-l'r ) A/4/7 tit 1 • lei / J.< (P2 • City of Gastonia NPDES Permit Compliance Meeting September 23, 1996 5-\ Meeting Objectives • Review compliance status • Discuss analysis of historical data • Review proposed study plan and obtain feedback Compliance Issues Catawba Creek WWTP » SOC expired May 31, 1996 Compliance achieved New SOC requested for de -commissioning Crowders Creek WWTP » SOC expires March 1, 1997 » Compliance achieved o Long Creek WWTP » SOC expires March 1, 1998kCY4 CSC v\cS---c.V • New SOC requested with Dec. 1, 1998 expiration Historical Data Review • Historical effluent metals data reviewed to determine if procedures implemented to date had reduced effluent metals concentrations • Reasonable potential to exceed (RPE) calculated for each plant (Catawba Creek, Crowders Creek, and Long Creek) for metals and cyanide • RPEs compared to NPDES permit limits to identify constituents of concern for each plant • Recommended further study for selected metals of concern and cyanide 4 140 Long Creek Wastewater Treatment Plant Effluent Lead Concentrations 120 - 100 • 80- 7 eU J 60 40 • • • • • • ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ • ♦ ♦ ♦ ♦ ♦ ♦ 20- * •• • • ♦ ♦ ♦ • ♦ ♦ ♦ ♦ NO ♦. • ♦ ♦ ♦ ♦♦ ♦ ♦♦ ♦. ♦♦ ♦♦ • ♦ ♦ ♦♦ N ♦ • 0 • • :4t ♦ ♦ • ! * ♦ 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 9496LGMT.XLS Pb 9/18/96 8/24/95 12/2/95 3/11/96 6/19/96 200 Long Creek Wastewater Treatment Plant Effluent Copper Concentrations 180 - 160 140 60 40 20 - • • • • • ♦ ♦ • • ♦ ♦♦• • . s • • • ♦ • • ♦ ♦ ♦♦♦ • • • • • Not included in statistical analysis ♦ ♦♦ • • • • • • • 0- i ♦ 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Cu 9/18/96 1.8 Long Creek Wastewater Treatment Plant Effluent Mercury Concentrations 1.6 - 1.4 1.2 - 0.6 - 0.4 - 0.2 - • ♦ • • ♦ • ••• •♦ ♦ .. * ♦ • NOWA* ♦ •• ♦ ♦ •O••••• •. ••••••S►••• **O••••• S••••••••• •••• ♦ ••••• ••• • 0- • • • • $ 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Hg 9/19/96 20 Long Creek Wastewater Treatment Plant Effluent Silver Concentrations 18- 16- 14- 0 • • • Not included in statistical analysis • • ♦ ♦♦ • ♦♦ • • ♦♦ • • • • • • N 4* N • • • ♦ ♦ N • • • N ♦ • • • ♦♦ w 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Ag 9/19/96 120 CROWDERS CREEK WWTP EFFLUENT COPPER CONCENTRATIONS 100 — 80 — • 60 — 0 U 40 -- • 20 — • • • • • ♦ • •• • ♦♦ • s • • •• • • • • • • • • • • • • • 01 01 01 01 0\ 01 01 01 01 Q1 N ` N N 0_0 01 O .-r CM Cnn .46 i 1 n .7 d' d' d d' .4- d' Ifl In Ir V1 Lfl in VI If) V) Ifl V) V'1 VN Vy i 1 in V1 10 1D 10 10 1D 10 10 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 0\ 01 01 01 01 01 01 0\ 0\ so O O = N (� M d' d' d V� 00 00 01 O 0 �--� _ _ t� N M d d in 10 10 r-[- 01 O O O_O 01 .O C I---. .-4 ( �1 .:-r M '' } 1N0 n n 0_0 C1 p .~- .--� ` .N� "" c� ~ c� m itrel 'mod i DATE 160 CROWDERS CREEK WWTP EFFLUENT LEAD CONCENTRATIONS • 140 — • 120 - 100 - • 80— 60 - 40 - • ♦ •• • • • ♦•♦ • • • ♦ ♦ • • 20--- ♦♦ • • ♦ ♦ ♦ ♦ •� N ♦• ♦•♦♦ • • ♦ • ♦♦ • NN♦♦ •♦• ♦♦ ♦♦ • • • • ♦ • ♦ ♦♦ 0--�►'•'P 1--1 --1 1♦ 1 F-+-1-1 i$ 1 F--I 1 1 i♦ 1 •1 4t 1 • ♦ I• 1 4t i• 1 • • 2 ♦♦ 01/4 M ril 01/4 1/40 dam' 01/4 01/4 00 V) ♦♦ 00 01/4 01/4 n 01/4 CO 0\ O 01 .-r 01 Csi VI sr) Sri in • d' V'1 00 DATE In 01/4 00 O1 O 0 - N N cr4 M N di' i 1 l- 000 O1 O — v in 1/40 1/40 No 1/40 �O 10 I- s 01 O O en en e4 1/40 CA in 30 CROWDERS CREEK WWTP EFFLUENT SILVER CONCENTRATIONS 25 — 20 — 10 — • 5• — * ♦♦♦♦♦ •♦ • ♦ ♦ ♦ ♦ N ♦ ♦ ♦ ♦ N 0 I♦ I 1 1 1 1 1 1 1 1 1 I -I I 1 Tr ,:r yr NI- et Tr ‘t ▪ d. v �t "zt Tr et d" ON ON ON ON CT ON ON OS as o, o\ C• , CA ON • a ▪ a �n �O �o C 00 ▪ co ▪ Ch O o 25 .� ~ a M M f I - in n .O N 0_0 Os - O O '--1 -� 12/3/94 4- • ♦♦ • ♦ ♦♦ ♦ ♦ ♦ N •♦ • •♦ • • ♦♦ • • 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 in it-) in in in in in in in in in tn in in to vO •O CR C\ O1 C, C\ ON C\ C\ C\ Ct C\ ON C\ CT ▪ C, ON Os ON C\ ON C1 C▪ ` C1 • Os 0▪ 000 00 O\ 0 0 • N • N en • Nr d • V1 �O �O n n ▪ CA 0 Ocn DATE 2 CROWDERS CREEK WWTP EFFLUENT MERCURY CONCENTRATIONS 1.8 — 1.6 — 1.4 — 1.2 — 0.8 — 0.6 — 0.4 — 0.2 — 0 • ♦ ♦ ♦ ♦ ♦ ♦♦ ♦ ♦ ♦ • v �t Nr Nr �r Tr yr �r tr �r v Nr ON o� o, O� o� O� O� O� cr a\ O� O� O� O� o� o� o� O\ r. v, oo co O O O .-. cv N M i o- a a r� �r O C- •-• O —_4 sch N 000 en DATE DATE CO ON N In ,43 0 0 vi in ill v') in v'i Vi vi 40 YC v:i iD \o NO NO O\ D\ ON ON Ot ON O\ ON ON ON ON O\ ON ON \ \ \ \ \ \ \ \ \ \ \ \ M �r v, O O •-+ 250 Figure 2 Catawba Creek - Data from November 1995 through April 1996 200 — O RPE - 99% Probability M RPE- 95% Probability ❑ SOC Limit ■ NPDES or Estimated Limit 50 — Cadmium Chromium Copper Cyanide Lead Mercury Nickel Silver Zinc 94-96CAT.XLS RPE Chart-6mo 250 200 -- 150 — 17.1 v 100 — 50 — Figure 4 Crowders Creek - Data from November 1995 through April 1996 Cadmium Chromium Copper Cyanide Lead Mercury Nickel Selenium Silver Z nc ❑ RPE - 99% Probability RPE- 95% Probability ❑ SOC Limit ■ NPDES or Estimated Limit CRMETALS.XLS RPE Chart-6mo 450 Figure 6 Long Creek - Data from November 1995 through April 1996 400 — 350 -- 300 — c 250 -- 0 co 00 200 — c 0 C) 150 -- 100 -- 50 -- 0 I rag' Cadmium Chromium Copper Cyanide Lead Mercury Nickel Silver Zinc D RPE - 99% Probability ®RPE- 95% Probability D SOC Limit ■ NPDES or Estimated Limit -Long Creek NPDES or Estimated Limit -South Fork 9496LGMT.XLS RPE Chart-6mo Metals Selected for Further Study Catawba Creek Crowders Creek Cadmium Copper -' Cyanide Lead Mercury Nickel Silver Zinc' Metal is borderline with Copper - Cyanide Lead Mercury SiIver- Zinc Long � Creek \)#r Cadmiumrt \\L! w'w Copper-7 C,\'' Cyanide Mercury Nickel Silver- Zino- 7 respect to requiring further study Action Plan o Identified constituents from each plant for further sampling and analysis (See study plan) o Consider modified structure for permit limitations (monthly average/daily maximum limits +�I • Request inclusion of quantitation levels (cyanide) (U�p, • Collect data to address bioavailability Objectives of Metals Study Plan • Determine if clean sampling techniques reduce reported effluent concentrations • Determine if clean laboratory analysis lowers reported effluent concentrations • Evaluate whether there is a statistical reasonable potential to exceed the permit limitations based on an applicable water quality standard Objectives of Cyanide Study Plan • Investigate the levels of cyanide which can be measured accurately and reproducibly • Evaluate potential matrix effects • Determine if cyanide is present in the influent and effluent at levels that have a reasonable potential to violate the water quality standard Metals Sampling Strategy • Sample at Long Creek and Crowders Creek only (due to planned shutdown of Catawba Creek) • Collect filtered and unfiltered samples • Collect 1 sample/week for 10 weeks • Collect grab samples using "clean" techniques • Collect field duplicate (true split) • Collect equipment and trip blank samples • Analyze matrix and blank spikes • Analyze standard reference materials samples to compare to blank spikes • Split samples between traditional lab and "clean" lab 9 Cyanide Sampling Strategy • Sample influent/effluent for Long and Crowders Creek WWTP and influent only for Catawba Creek • Conduct 10 week sampling (1/week) • Conduct the method of standard addition on influent (all plants) and effluent (Long and Crowders) samples (first sampling event only) to evaluate matrix effects • Pretreat samples for removal of sulfide, chlorine and aldehyde if necessary • Prepare blank and spiked effluent samples at 1X and 2X the permit limit for Crowders and Long Creek • Submit native (unspiked) and spiked samples to blind '° to lab analyst Figure 1 City of Gastonia Clean Metals and Cyanide Sampling Tentative Project Schedule ID Task Name Start September October November [ December January Febru 9/9 9/16 9/23 9/30 1 10/7 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 11/13 11/20 1/27 2/3 2/10 1 Meeting with NCDWQ 9/23/96 IIII- -- in- 111 2 Kickoff Clean Metal Sampling with Training by CH2M HILL 9/30/96 3 Clean Metal and Cyanide Sampling for Weeks 2-10 10/7/96 4 Potential Meeting with NCDWQ 11/11/96 5 Data Review and Analysis 1/6/97 6 Potential Meeting with NCDWQ 2/3/97 7 Implement Action Plan 2/10/97 Project: City of Gastonia Date: 9/18/96 Task Summary gr.IIIIIIMII.19P Rolled Up Progress Progress Rolled Up Task �. ., Milestone . Rolled Up Milestone O Page 1 TECHN ICAL MEMORANDUM cKMH111. Clean Metals Sampling Study Plan TO: COPIES: FROM: DATE: Larry Cummings/City of Gastonia Coleman Keeter/City of Gastonia Glenn Dukes/CH2M HILL Kristen Jenkins/CH2M HILL Bill Kreutzberger/CH2M HILL August 12,1996 Background As part of the clean sampling and analysis project, the City of Gastonia's metals and cyanide kustorical data were reviewed for all three wastewater treatment plants (Long Creek, C owders Creek, and Catawba Creek). Recommendations were made for further sampling which were presented in a Technical Memorandum dated July 19,1996. This memorandum presents the dean metals and cyanide sampling strategy and study plan. Objectives The obje fives of the clean metals sampling and analysis indude: • To determine if additional clean sampling techniques reduce reported effluent concentrations • To determine if use of clean laboratory lowers reported effluent concentrations • To evaluate whether there is a statistical reasonable potential to exceed the permit limit lions based on an applicable water quality standard The objec 'ves of cyanide sampling and analysis indude: • To ev luate whether sample results at, or near, the method reporting limit can be measured accurately and reproducibly • To investigate the levels of cyanide which can be measured accurately and reproducibly • To evaluate the effect of potential matrix interferences at the reporting limit on the final sampl result and, within this context, define the detection limits and reporting limits for th plant's influent and effluent • To de ermine if cyanide is present in the influent and effluent of the facilities at levels that have a reasonable potential to violate the water quality standard Samples ill be sent to two laboratories to fulfill the objectives of the study. The laboratori s should include a "dean" laboratory and the laboratory which normally performs analyses for the City of Gastonia. CLT/STDYPLAN 1 CLEAN METALS SAMPUNG STUDY PLAN Sampling Strategy Table 1 presents the proposed analyses to be performed at each plant. No clean sampling is recommended at Catawba Creek due to planned shutdown of the plant in the next 18 months. However, constituents which would have been monitored at the Catawba Creek facility should be monitored at the Long Creek facility because Catawba Creek facility flow will be directed to the Long Creek facility after shutdown of the plant. The City of Gastonia may want permit limits based on dissolved metal concentrations instead of total recoverable metals at some point in the future. Therefore, for each sample event, samples will be filtered in the field and submitted to the "clean" laboratory. The clean laboratory will store the samples until the total recoverable metal data has been analyze . At that time, target dissolved metal concentrations of interest can be analyzed. The hot ng time for all metals except mercury is 6 months. Mercury has a shorter holding time, bu there is no generally acceptable method for determining permit limits based on dissolved mercury concentrations. Approximately one sample per week should be collected at each plant for a duration of ten weeks. Tile samples should be grab samples collected using the "clean" procedures discussed below. Samples should be collected on weekdays as well as weekends to avoid any bias in the sampling. Samples should also be collected at different times of the day. For quali control, the following procedures should be followed: • One 'eld duplicate sample should be collected and analyzed for each sampling event. • Labo atory should perform duplicate analyses for each sample collected • Equipment blank samples should be collected to ensure that the tubing used is not adding contamination • Trip i?lanks should be prepared by the laboratories and analyzed during each event to ensure that activities at/around the sampling is not adding contamination • Stan lard reference materials (SRM) samples should be analyzed as part of QC 2 to 3 times during the study to compare to the blank spikes. Cyanide Blanks Blank samples will be prepared and submitted to each of the analytical laboratories. The blank samples will consist of ASTM Type II water that has been spiked. The standards used will be tr . ceable to NIST standards. The samples will be spiked at varying concentrations that brac et the lower end of sample concentrations (near the MDL and permit limit) and higher sa ple concentrations known to produce linear recoveries. Two concentrations (one near the ater quality based standard of 12 µg/1 for the Crowders Creek facility and the permit 1' i 't of 22 µg/L for the Long Creek facility (discharging to the South Fork) and one in a high=r concentration range) will be used for spiking at least 7 times. These results will provide e seven points required to statistically evaluate the results of the study. The purpose . f these samples is to evaluate whether the analytical laboratory is capable of precisely : d accurately measuring the concentration of an "ideal" sample at 1X and 2X the permit li 't. Tables 2 and 3 summarize sampling and analysis for cyanide at Crowders Creek an . Long Creek facilities, respectively. CLTJSTDYPLAN 2 CLEAN METALS SAMPLING STUDY PLAN Table 1 Sampling and Analysis Plan Constituent Plant Catawba Crowders Long Creek Cadmium NCS X ✓ Chromium NCS NCS NCS Copper NCS ✓ ✓ Cyanide NCS X ✓ Lead NCS X X Mercury NCS V V Nickel NCS NCS ✓ Selenium. NCS X NA Silver NCS ✓ ✓ Zinc NCS X ✓ ✓ - Clea X - Cle NCS - No NA - Constituent sampling required sampling at the City of Gastonia's discretion clean sampling required not monitored, therefore, clean sampling not applicable Spiked Samples Both "native" (unspiked) and spiked samples will be submitted to the laboratories. The standards used to prepare the spike samples will be traceable to NIST standards. The test will be fo used on evaluating whether the laboratory is capable of measuring the concentra ' ons of cyanide in an actual sample accurately and precisely. Two matrix spikes will be su mitted to each laboratory for both the influent and effluent each week for ten weeks. Sample Pretreatment Some ma ix interferences can be minimized or eliminated through sample pretreatment. Matrix int rferences can be a greater problem at, or near, the method reporting limit, and the effect f the matrix interference typically decreases with increasing cyanide concentra 'ons. Samples can be screened and if necessary, pretreated for sulfide, chlorine, and aldeh des. Instructions for pretreatment of samples is included in Attachment B. CLT/STDYPLAN 3 CLEAN METALS SAMPLING STUDY PLAN Sample ccuracy and Precision Because of the increased variablility of sample results at, or near, the method reporting limit, all the samples will be submitted to both laboratories in duplicate for the first 6 weeks. Sample results obtained during this period will be compared for precision within a specific laboratory as well as for comparability between the two laboratories. Method of Standard Addition For cyanide, during the first sampling event, samples should be analyzed using the method of standard addition to quantitate sample results and evaluate matrix effects at low sample concentrations. For Crowders Creek, the standard addition samples on the influent, effluent and blank should include (1) the native, (2) native + 10 µg/1, (3) native + 15 µg/1, (4) native +20 µg/1 (5) native + 30 µg/1, and (6) native + 50 µg/1. For Long Creek, the standard addition samples on the influent, effluent and blank should include (1) the native, (2) native + 20 µg/1. (3) native + 25 µg/1, (4) native + 30 µg/1, (5) native + 40 µg/1, and (6) native + 50 µg/1. Sample Collection Methods CH2M HILL's "clean" sampling procedure is presented as Attachment A. As noted in the procedure, the procedure may require modification based on conditions encountered in the field. The procedure requires two people for sampling - a "clean hands" person and a "dirty hands" p rson. For the first sampling event, CH2M HILL personnel will be present to train the samp ing personnel on using the dean sampling techniques. A field equipment checklist is also included in Attachment A. Laborat9ry Selection One set of samples (metals and cyanide) should be submitted to the laboratory which normally performs the analysis for the City of Gastonia. The duplicate set of samples should be submitted to Battelle or another clean laboratory for the metals analysis. A comparison laboratory should be selected for the duplicate cyanide analysis. Another laboratory should be selected for cyanide spike and blank sample preparation. CH2M HILL's Quality Analytical Laboratories have experience in both cyanide analysis and preparation of spike samples. Scheduli g and Coordination Sampling can begin at the City of Gastonia's convenience and is tentatively scheduled for early September. Figure 1 shows a tentative schedule for dean metals and cyanide sampling. CH2M HILL can coordinate with the contract laboratories to ensure that the required alyses are performed. CH2M HILL will help the City of Gastonia obtain the required e1d equipment prior to the first sampling event. CLT/STDYPLAN 4 Table 2 Cyanide Evaluation - City of Gastonia Crowders Creek WWTP Sampling and Analysis Plan Sampling Event# Influent Samples/Influent Matrix Spikes Effluent Samples/Effiuent Mat ix Spikes Blank Spikes Native +10 ug/L +15 ug/L +20 ug/L +30 ug/L +50 ug/L Native +10 ug/L +15 ug/L +20 ug/L +30 ug/L +50 ug/L Blank +10 ug/L +15 ug/L +20 ug/L +30 ug/L +50 ug/L -A/B-1 •A/B-2 -NB-3 -A/B-4 -NB-5 -A/B-6 -A/B-7 •NB-8 -A/B-9 -A/B-10 -A/B-11 -NB-12 -A/B-13 -A/B-14 -NB-15 -A/B-16 -A/B-17 -A/B-18 Week 1 Lab A Lab B Sampling Event l Result ID Influent Samples -NB-1 -A/B-2 Effluent Samples -A/B-3 -NB-4 Blank Spikes -A/B-5 -NB-6 Influent Matrix Spikes -NB-7 -A/B-8 Effluent Matrix Spikes -A/B-9 -A/B-10 Week 2 Spike 12 24 12 24 12 24 Lab A Lab B Week 3 Week 4 Spike 12 24 12 24 12 24 Lab A Lab B Spike 12 24 12 24 12 24 Lab A Lab B Week 5 Spike 12 24 12 24 12 24 Lab A Lab B Week 6 Week 7 Week 8 Week 9 Week 10 Spike 12 24 12 24 12 24 Lab A Lab B Spike Lab A Lab B Spike Lab A Lab B Spike Lab A Lab B Spike Lab A Lab B 12 Sample Codes: -A/B-1 & NB-2: Influent field duplicates for Laboratory A/B -NB-3 & NB-4: Effluent field duplicates for Laboratory NB -NB-5 & A/B-6: Blank spikes for Laboratory A/B -A/B-7 & A/B-8: Influent matrix spikes for Laboratory A/8 -A/B-9 & AB-10: Effluent matrix spikes for Laboratory NB -A/B-11 & A/8-12: Standard reference materials samples for Laboratory A/B 24 12 24 12 24 cnsum.XLS Crowders 8/12/96 Table 3 Cyanide Evaluation - City of Gastonia Long Creek WWTP Sampling and Analysis Plan Sampling Event# Influent Samples/Influent Matrix Spikes Effluent Samples/Effluent Matrix Spikes Blank Spikes Native +20 ug/L +25 ug/L +30 ug/L +40 ug/L +50 ug/L Native +20 ug/L +25 ug/L +30 ug/L +40 ug/L +50 ug/L Blank +20 ug/L +25 ug/L +30 ug/L +40 ug/L +50 ug/L -A/B-1 -A/B-2 -NB-3 -A/B-4 -NB-5 -NB-6 -A/B-7 -NB-8 -NB-9 -A/B-10 -NB-11 -A/B-12 -NB-13 -A/B-14 -A/B-15 -A/B-16 -A/8-17 -A/B-18 Week 1 Lab A Lab B Sampling Event # Result ID Influent Samples Effluent Samples Blank Spikes Influent Matrix Spikes Effluent Matrix Spikes -A/B-1 -NB-2 -NB-3 -NB-4 -NB-5 -NB-6 -A/B-7 -NB-8 -AIB-9 -NB-10 Week 2 Spike - - - - 20 40 20 40 20 40 Lab A ---------- Lab B _--------- Week 3 Spike - - - - 20 40 20 40 20 40 Lab A ---------- Lab B ---------- Week 4 Spike - - - - 20 40 20 40 20 40 Lab A ---------- Lab B -------_-- Week 5 Spike - 0 - - 20 40 20 40 20 40 Lab A ---------- Lab B _------_-- Week 6 Spike - - - - 20 40 20 40 20 40 Lab A ----_----- Lab B —_-------- Week 7 Spike - • - ,; 20 40 20 40 20 40 Lab A Lab B — r ------ Week 8 Spike - r —. Lab A Lab B Week 9 Spike - - LabA Lab B Week 10 Spike - - Lab A + - Lab B k ? —f r.. .-. _ `sfr r , r. Sample Codes: -A/B-1 & NB-2: Influent field duplicates for Laboratory NB -NB-3 & A/B-4: Effluent field duplicates for Laboratory A/B -A/B-5 & NB-6: Blank spikes for Laboratory A/B -A/B-7 & NB-8: Influent matrix spikes for Laboratory A/B -A/B-9 & NB-10: Efftuent matrix spikes for Laboratory NB -AB-11 & A/B-12: Standard reference materials samples for Laboratory NB cnsum.XLS Long 8/12/96 Figure 1 City of Gastonia Clean Metals and Cyanide Sampling Tentative Project Schedule ID Task Name September October November December January 8/26 9/2 9/9 9/16 9/23 9/30 10/7 0/1 0/2 0/2 11/4 1/1 1/1 1/2 12/2 12/9 2/1 2/2 2/3 1/6 1/13 1/20 1/27 2/3 1 Kickoff Clean Metal Sampling with Training by CH2M HILL 2 Clean Metal and Cyanide Sampling for Weeks 2-10 3 Data Review and Analysis 4 Regulatory Negotiation 5 Potential Meeting with NCDWQ 6 Potential Meeting with NCDWQ 7 Potential Meeting with NCDWQ 8 Action Plan Project: City of Gastonia Date: 8/12/96 Rolled Up Progress Task Summary Progress Up Task Milestone ♦ Rolled Rolled Up Milestone O Page 1 CLEAN METALS SAMPLING STUDY PLAN Attachment A Clean Sampling Procedure CLT/STDYPLAN "Clean" Sampling Procedures for Metals [from open channels or sewer manholes] (Developed by Elizabeth Krousel and Jerry Bills, CH2M HILL) Equipment/Workers Required 1. Masterflex "easy loading" peristaltic pump 2. 12 volt battery and connectors for peristaltic pump 3. Teflon tubing with neoprene tubing end (for insertion into pump) • • Previously cut to required length Prepared according to clean analytical procedures in laboratory • Stored in individual ziploc baggies [One for each sample location] 4. Teflon coated weight with clasps (for connection of weight to open end of tubing) 5. Tyvex coveralls including hood and booties • Stored in individual ziploc baggies [One for each field worker for each sample location] 6. H 'rnets [Ohe for each field worker for each sample location] ] 7. Du st/surgeons mask • Stored in individual ziploc baggies [One for each field worker for each sample location] 8. Sa • • II ple kits from Battelle Shipped from Battelle in ice chest(s) Including ziploc bag containing teflon sample containers and teflon ampules with certified metals -free double -distilled nitric acid. This ziploc bag is sealed within another ziploc bag containing non -talc (metals -free) gloves [One for each sample location] p:37205ek1t3me slclean.doc 1 9. Two field workers (one designated as the "clean hands" worker and the other designated as the "dirty hands" worker) 10. Additional field ice chest or box for storage of "clean" sampling gear (includes ziploc baggies containing tubing apparatus, tyvex coveralls, dust/surgeons mask, and h irnets) and sampling equipment (including ziploc baggies of tubing apparatus and t flon weights with clasps) 11. Additional ice chest with the required amount of ice for shipping of the samples directly to Battelle 12. Fgderal Express labels prepared for shipping the samples from the sample collection site or office to Battelle 13. G rbage bags and shipping tape 14. Waterproof field marker 15. Field notebook and graphite pencil 16. Field vehicle (preferably a van which has been vaccuumed and is free of dirty or maddy equipment, etc.) Miscellaneous Instructions 1. operations involving contact with the sample bottles, transfer of the sample, or any sample preparation are to be handled by the field worker designated as the "clean ha' ds" worker. 2. All operations involving preparation of the sample pump, batteries, opening of plastic containers must be performed by the individual assigned as the "dirty hands" workers. 3. Field workers should avoid contact with any metal -containing objects during the s ple collection period. In the case of unavoidable contact with metal- containing ob ects, the field workers must ensure that any objects which contact the collected sample - either directly or indirectly (including tubing, tyvex coveralls, outer portion of loves) - are not contaminated from exposure. For example, if one worker is re uired to remove a manhole cover or contact a metal grid to prepare for the sample co lection, the tyvex coveralls and appropriate gloves must be applied after this ac vity is conducted by the "dirty hands" worker. 2 4. Other contamination which may occur to the sample during sample collection such as from dusty winds, exhaust from nearby vehicles, and/or debris from disturbance of the sample collection location (such as removal of manhole cover) should be avoided. If possible, field workers should wait for the optimum time (low to zero winds, no nearby traffic, several minutes after the manhole lid is removed) before initiating the sample collection. If unavoidable during sample collection, the sample should be shielded from the source of contamination by the "clean hands" worker. Field Procedure 1. After arriving at the sample collection site and marking the required information in the field notebook (workers' names, date, time of arrival at sample location, etc.), both field workers must don "clean" sampling ensembles (includes tyvex coveralls, dust/surgeons mask, hairnet, and rubber gloves). Since both the dust/surgeons mask and tyvex coverall contain metal parts (face clasp and zipper), these components of the "clean" sampling gear must be put on prior to non -talc gloves. After both workers hre donned the ensembles, a new garbage bag or strip of plastic should be used to create a clean surface within the field van for the workers to use as a counter during field operations. 2. T 1 e "dirty hands" worker: i. ii. removes the ziploc bag containing sample kit from Battelle's ice chest, the ziploc bag containing the tubing apparatus, and the ziploc bag containing the teflon weight with clasps from the additional ice chest or box opens both the outer and inner ziploc baggies of the sample kit and the ziploc bag containing the tubing apparatus for the "clean hands" worker within a relatively wind- and dust -free environment (for example, the inside the back of the field van) transports the pump and battery to the sample collection location "clean hands" worker: removes the tubing apparatus from the ziploc bag and connects the weight with clasps to the teflon end of the tubing transports the tubing to the sample collection location, taking care to prevent any contamination to the tubing from wind and/or contact with surfaces lowers the teflon end of the tubing with weight to the sample collection location (approximately mid -depth and away from any metal -containing objects) 3 4. The "dirty hands" worker: ii inserts the neoprene end of the tubing apparatus into the peristaltic pump head ii. holds the teflon tubing which was lowered by the "clean hands" worker in the sample collection position (approximately mid -depth and away from any metal -containing objects) with one hand and holds the neoprene end of the tubing extending out of the pump head in the other hand (making sure that the end is directed away from the sample collection area to prevent contamination of the collected sample) turns the pump switch on to begin the 2-minute minimum purging of the sample tubing Note: During purging of the tubing and sample collection, the "dirty hands" worker must take care to maintain the location of the tubing end approximately mid -depth and away from any metal -containing objects and to prevent contact of the tubing apparatus (including both the teflon and neoprene portions) with any surfaces 5. The "clean hands" worker: i. returns to field van to retrieve sample container Note: The "clean hands" worker should not have to contact the outer portion of the ziploc bag since it was previously opened by the "dirty hands" worker after arriving at the sample site. ii. iii i v. 6. Th i. tranports closed sample container to sample collection location after the minimum of 2-minute purging of the tubing is completed, holds closed sample container within one inch of the tubing end before removing lid and begins collecting sample closes the sample container with lid once the sample container is full, Note: During sample collection, the "clean hands" worker must prevent contamination of the sample container lid transports the closed sample container back inside the field van "dirty hands" worker: raises the teflon tubing to empty the contents of the tubing and turns off the pump 4 ii. removes the neoprene end of the tubing from the pump head and rolls the length of the tubing for reinsertion into ziploc bag iii. transports rolled tubing, pump, and battery back to field van 7. The "clean hands" worker: ii. iv. v. vi secures the closed sample container (containing sample) on a level position with the field van and slighty loosens the lid of the sample container removes the teflon ampule containing preservative from the previously opened ziploc bag and removes the lid from the ampule quickly but carefully removes the previously loosened sample container lid with one hand, adds the preservative to the sample with the other hand, and then immediately re-covers the sample container tightly seals the sample container and then labels the sample container with the sample name, date and time of collection, and initials of field workers returns the sample container to its original ziploc bag, reseals it, and then places both the ziploc container with the sample and the empty teflon ampule inside the outer ziploc bag and reseals it stores the double bagged sample in the additional ice chest filled with ice 8. Both workers remove their "clean" sampling ensembles (gloves, tyvex, mask, and hairnet), dispose in a garbage bag, and seal prior to proceeding to the next sampling loation The abovprocedure (steps 1-8) is repeated for each of the sampling locations. After all samples are collected: her the "clean" or "dirty" hands worker: lines the inside of the ice chest sent by Battelle with a thick garbage bag places the double -bagged sample containers (also containing empty teflon ampules) with double -bagged ice or blue ice (to maintain a temperature of 4 degrees celcius) in the garbage bag lined ice chest, and tightly seals the garbage bag to prevent any leakage during shipping 5 prepares the ice chest for shipping to Battelle by sealing with strong package tape and affixing prepared Federal Express label and delivers to Federal Express location 6 � 1 Field Sampling Checklist Item Number Teflon tubing setups in baggies 1 Battelle 1 ottle kits with preservative 2 Battelle filter lter units 1 City of Gastonia standard laboratory bottle kits with preservative 2 Cyanide 'rampling bottle kit 2 Cyanide pretreatment kit 1 1 Geopump peristaltic pump 1 1 Battery and connections (if needed) 1 Teflon coated weight with clasps 1 Tyvex coveralls 2 Dust masks 2 Chest for storage of sampling gear 1 Plastic bottle rack apparatus 1 Federal Express Labels Several Chain of Custody Several Garbage bags, shipping tape, duct tape Several Waterproof field marker 1 Field notebook and graphite pencil 1 Safety glares, hard hat and hearing protection (if required) 1 CLT/STDYPLAN 7 CLEAN METALS SAMPUNG STUDY PLAN Attachment B Cyanide Pretreatment Procedure CLT/STDYPLAN Sampling Process Flowchart (Notes on the procedures followed will be recorded on the Field Sampling Record Form) (9/26/95) no Collect Field Screen # 1 for Sample (a) Residual Chlorine Pretreatment #1 ► Field Screen # 2 for Residual Sulfide 1 yes Pretreatment #2 no ► Field Screen # 3 for Aldehydes yes - Pretreatment #3 no Preserve Prepare for shipment Samples (b) to laboratory (a) For the Method of Standard Addition (MSA) sampling event (Week 1),12 L of influent and 12 L of effluent are required. For Weeks 1-6 (excluding the MSA sampling event), 8 L of influent and 8 L of effluent are required. For Week 7, 6 L of influent and 6 L of effluent are required. For Weeks 8-10, 2 L of influent and 2 L of effluent are required. (b) Samples will be preserved using 2 mL of sodium hydroxide(10 N) per liter of sample to raise the pH to 12 or 12.5. Field Screen # 1 for Residual Chlorine: 1) Use a disposable dropper to place a few drops of the sample on KI starch paper. 2) If the paper tums blue, chlorine is present and the sample must be pretreated with ascorbic acid (see pretreatment #1 below). Field Screen # 2 for Residual Sulfide: 1) Use a disposable dropper to place a few drops of the sample on lead acetate paper. 2) If the paper tums black, sulfide is present and the sample must be pretreated with powdered cadmium carbonate and filtered (see pretreatment #2 below). Field Screen # 3 for Aldehydes: 1) If the sample is alkaline, add 1 + 1 H2SO4 to the sample to adjust the pH to Tess than 8. 2) Place one drop of sample and one drop of distilled water (for a blank) on a white spot plate. 3) Add one drop of MBTH and one drop of FeCI3 oxidizing solution to each spot. 4) Note the color change on each spot. The blank should remain yellow. 5) If the sample spot tums from a faint green -yellow to a deeper green or blue-green to blue, aldehyde is present and the sample must be pretreated with ethylenediamine solution. (see pretreatment #3 below). Pretreatment # 1 for Residual Chlorine: 1) Add ascorbic acid to the sample until no further color change is noted on KI starch paper. 2) Add an additional 0.6 gram of ascorbic acid for each liter of sample. Pretreatment # 2 for Residual Sulfide: 1) Add powdered activated carbon to the sample until not further color change is noted on lead acetate paper and no additional cadmium sulfide precipitates. 2) Filter the sample through a clean, dry filter paper into a clean dry beaker and use the filtrate for the sample analysis. Note: Approximately 25 mL of additional sample should be treated to provide adequate volume after the filtration process. Pretreatment # 3 for Aldehydes: 1) Add 2 mL of 3.5% ethylenediamine solution per 100 mL of sample. p:1117456.ek\planlfleldp.xls TECHNICAL MEMORANDUM ai MHI LL Clean) Metals Sampling Historical Data Review PREPARED FO PREPARED BY COPIES: DATE: Larry Cummings/City of Gastonia Kristen Jenkins/CH2M HILL Bill Kreutzberger/CH2M HILL Coleman Keeter/City of Gastonia Glenn Dukes/CH2M HILL July 19,1996 (Revised) As part of the clean sampling and analysis project, the City of Gastonia's metals and cyanide d to were reviewed for all three wastewater treatment plants (Long Creek, Crowders Creek, and Catawba Creek). This memorandum summarizes the historical data review and presents recommendations for further action. Methodology For each of the metals and cyanide, effluent concentration plots presented in the project kickoff meting by the City of Gastonia generally showed a reduction for the period beginning 'n January 1994 through April 1996. The reduction was attributed to actions implemen ed to date by the City of Gastonia. Therefore, statistical parameters were determine and compared for two data sets: January 1994 through April 1996 (28 months) and the most recent 6 months (November 1995 through April 1996). The statistics included mean, stan and deviation, and coefficient of variation (standard deviation divided by the mean). The reason ble potential to exceed (RPE) concentration was calculated for each metal and cyanide according to the procedure presented in the EPA's Technical Support Document for Water Qua_ity-Based Toxics Control. The RPE according to this method is the maximum concentration in the data set multiplied by a factor. The multiplying factor is based on the coefficient of variation and the number of samples in the data set. The factors are for a 99 percent confidence level and either 95 or 99 percent probability. An RPE with 95 percent probability indicates that there is a five percent chance that the RPE will be exceeded. Similarly, a RPE with 99 percent probability indicates that there is a one percent chance the RPE will b exceeded. The RPE was compared to the NPDES permit limit, if applicable, or to an estim ted permit limit based on the water quality standard or action level for the particular eta) and the instream waste concentration (IWC). If the RPE for the 99 percent probability evel is less than the permit limit, then there is only a one percent chance that the permit limit will be exceeded. Discusson Tables 1 thr ugh 3 present summaries of the statistical analysis for each plant for each of the analysis periods. Figures 1 through 6 present RPEs and NPDES or estimated permit limits TM0709.Doc 1 CLEAN METALS SAMPLING DATA REVIEW for each metal for each plant. For some data sets, one high concentration value skewed the RPE. Therefore, if the data set included one outlying value, this value was omitted from the statistical analysis. The outlying value is noted on the appropriate figure in Attachment A. Compar son of Whole Data Set to Last Six Months For the C tawba Creek Plant, RPEs for all metals and cyanide were lower for the last six month period than for the entire data set indicating that actions to date have lowered effluent concentrations. For the Long Creek plant, RPEs for the six month period were lower than the vrhole data set for all constituents except cyanide. The mean cyanide concentration and the s andard deviation have increased slightly within the last six months for the Long Creek Plant which results in a higher RPE. For the Crowders Creek plant, RPEs for the six month period are lower than the whole data set for all constituents except for Mercury. In March anil April 1996, mercury concentrations were 2 and 1 µg/1, respectively, which resulted in higher mean, standard deviation, and RPE concentrations. Evaluati n of RPEs In general( actions implemented to date have lowered effluent metals concentrations, and the last si months of data are more representative of current effluent concentrations. Therefore the RPEs for the six month period will be compared to estimated or actual permit limits as presented in Figures 2, 4, and 6. For Catawba Creek, chromium is the only constituent with an RPE less than the NPDES permit limit at 99 percent probability. For Long Creek, again chromium is the only constituent with an RPE less than the estimated permit limit at 99 percent probability. The RPE at 99 ercent probability for cadmium is very close to the estimated limit for discharge to the Sou Fork. For Crowders Creek, RPEs with 99 percent probability are less than the permitted . 't for cadmium, chromium, and nickel. The RPE at 99 percent probability for selenium i very close to the estimated permit limit. In reviewing the NPDES permits, a possible error was noted for the Long Creek plant dischargin to the South Fork. The water quality standard for nickel is 88 µg/1. For discharge o Long Creek, the IWC is 80 percent resulting in a limit of 109 µg/1 which corresponds to the actual permit. For discharge to the South Fork, the IWC is 22 percent which sho nld correspond to a permit limit of 400 µg/1. However, the permit lists a limit of 112 µg/1 for nickel. This is most likely a typographical error since the limit for lead is 112 µg/1. If the actual permit limit for nickel is 400 µg/1, then the 99 percent probability RPE would be 1 ss than the permit limit. Recomriendations The 99 per limits. Ho permit lim additional The sampli will provid ent probability RPEs for several metals are less than actual or estimated permit ever, RPEs for the remaining metals and cyanide exceed estimated or actual Ls. Therefore, CH2M HILL recommends that the City of Gastonia conduct sampling and analysis. g should utilize as many clean sampling procedures as possible. CH2M HILL assistance with training and implementation of these additional procedures. TM0709.DOC 2 CLEAN METALS SAMPLING DATA REVIEW Approximately ten samples should be collected to provide a representative data set. Samples should be split between a "clean" lab (i.e. Battelle Northwest) and the lab(s) which normally performs the analysis for the City of Gastonia. All of the samples should be grab. If a composite sample is required for compliance, a grab sample should also be taken either at the be . *rig or end of the composite sampling. Additional analyses of cyanide should be condu ted including specific protocols to address interferences and matrix spiked samples to evaluate potential interferences. In summary, sampling and analysis should include the following: • 10 week duration (one sample per week from each plant) • Grab samples collected using clean protocols • Split ,grab samples between clean lab and normal lab • Contivation of composite sampling P p g The results from the two labs will be compared to determine if analysis by a clean lab improves Compliance with actual and estimated permit limits. Results prior to and after implementation of the additional clean metal sampling techniques will be compared to determine] if the additional procedures reduce effluent concentrations. Table 4 presents a proposed analysis plan. A checkmark indicates that data using the clean sampling rotocols and clean lab are needed to determine if an RPE less than the permit limit is a 'evable using these procedures. An "X" indicates that the current 95 percent probabili RPE is dose to the permit limit and additional sampling may be at the City of Gastonia' discretion. However, additional data would be beneficial to reinforce that compliance sampling should be reduced or eliminated for several constituents. For Long Creek, permit limits for discharge to the South Fork Catawba River were used for comparison to the RPE. No clean sampling is recommended at Catawba Creek due to planned shutdown of the plant. However, constituents which would have been monitored at Catawba Creek should be monitored at Long Creek because Catawba Creek flow will be sent to Long Creek after shutdown of the plant. CH2M L will prepare a sampling and analysis workplan if the City of Gastonia concurs with the p oposed analyses listed in Table 4. TM0709.DOC 3 tv,„ i? ,*-7/1 rP/otti) J Table 1 Catawba Creek (all values ug/l) Whole Data Set (January 1994 through April 1996) Average Standard Deviation Maximum RPE - 99% Probability RPE - 95% Probability SOC Limit NPDES Limit Cadmium 3 3 17 77 31 15 2.2 Chromium 12 8 42 110 59 55 Copper 11 7 33 76 46 7.8 (a) Cyanide 5 4 25 73 38 27 5.5 Lead 14 20 138 718 248 95 28 Mercury 0.2 0.1 1 2.1 1.0 0.013 (a' Nickel 49 45 262 838 393 230 97 Silver 2 1 9 21 13 0.067 (a) Zinc 168 83 427 854 555 56 ta) Six -Month Data Set (November 1995 through April 1996) Average Standard Deviation Maximum RPE - 99% Probability RPE - 95% Probability SOC Limit NPDES Limit Cadmium 0.6 0.4 2 5.2 2.8 15 2.2 Chromium 8.1 5.0 20 46 28 55 Copper 5.2 3.3 14 39 22 7.8 `a) Cyanide 3.1 1.9 7 17 10 27 5.5 Lead 2.6 3.3 10 45 18 95 28 Mercury 0.2 0.1 0.3 1.3 0.7 0.013 " Nickel 23.1 17.6 75 218 113 230 97 Silver 1.8 1.3 5 16 9 0.067 (a) Zinc 79.6 18.2 110 154 132 56 `") (a) Estimated permit limit = water qua ity standard * 100 / instream waste concentration (%) , pC‹. coiA6t(if 14p1 r(A.; 101- a (( 14,40 Flo/ ,a5P- 94-96CAT.XLS Table Table 2 Long Creek (all values ug/I) Whole Data Set (January 1994 through April 1996) Average Standard Deviation Maximum RPE 99% Probability RPE - 95 % Probability SOC Limit NPDES Limit -Long Creek NPDES Limit -South Fork Cadmium 3.5 5.4 32.2 167.44 57.96 20 2.5 9 tad Chromium 18.6 10.7 66 151.8 92.4 62 227 (a) Copper 44.1 21.4 121 242 157.3 8.75 (a) 32 (a) Cyanide 8.2 7.4 40.2 128.64 60.3 32 6.2 22 Lead 17.9 22.9 131 589.5 235.8 120 31 112 Mercury 0.2 0.2 1.68 7.56 3.024 0.02 0.05 (a) Nickel 62.8 35.9 210 483 294 250 109 112 Silver 2.8 2.2 13 37.7 19.5 0.075 (a) 0.27 (a) Zinc 152.6 57.2 329 592.2 394.8 62.5 (a) 227 (a) Six Months Data Set (11/1/95-4/30/96) Average Standard Deviation Maximum RPE 99% Probability RPE - 95 % Probability SOC Limit NPDES Limit Long Creek NPDES Limit - South Fork Cadmium 0.6 0.6 3.0 9.6 4.5 20 2.5 9 (a) Chromium 11.1 3.9 19 30 23 62 227 (a) Copper 27.7 10.7 39 78 55 8.75 {a} 32 (a) Cyanide ! 9.6 9.3 40 141 64 32 6.2 22 Lead 1 4.2 7.4 30 183 60 120 31 112 Mercury 0.2 0.2 1.0 4.2 1.7 0.02 0.05 (a) Nickel 1 35.6 24.0 90 234 126 250 109 112 Silver 1.6 0.9 3.0 8.4 4.8 0.075 (a) 0.27 (a) Zinc 121.7 45.7 203 406 284 62.5 tad 227 (a) (a) Estimated permit limit = water quality standard * 100 / instream waste concentration (%) 9496LGMT.XLS Table 7/9/96 Table 3 Crowders Creek (all values ug11) Whole Data Set (January 1994 through April 1996) Average Standard Deviation Maximum RPE - 99% Probability RPE - 95% Probability SOC Limit NPDES Limit Cadmium 4 4 22 92 37 17 5 Chromium 9 16 134 780 255 120 Copper 31 17 107 246 150 17 (a) Cyanide 4 3 25 73 38 12 (a) Lead 17 25 147 764 265 150 60 Mercury 0.2 0.4 2.0 12.2 4.0 0.029 (a) Nickel 32 28 160 512 240 211 Selenium 16 35 239 1625 478 12 (a) Silver 3 4 27 123 49 0.14 (a) Zinc 73 32 184 331 221 119 (a) Six Months Data Set (11/1/95-4/30/96) Average Standard Deviation Maximum RPE - 99% Probability RPE - 95% Probability SOC Limit NPDES Limit Cadmium 0.6 0.3 2.0 4.6 2.8 17 5 Chromium 3.8 2.6 10 26 14 120 Copper 16.2 5.8 25 52.5 35 17 (a) Cyanide 3.5 1.7 7.9 18.2 11.9 11.9 (a) Lead 3.6 5.7 20 110 38 150 60 Mercury 0.6 0.8 2.0 24.8 8.4 0.029 (a) Nickel 11.7 10.0 40 128 60 211 Selenium 4.6 1.3 8 12.8 9.6 11.9 (a) Silver 1.5 0.7 3 7.5 4.8 0.14 (a) Zinc 53 17 81 146 105 119 (a) (a) Estimated permit limit = water quality standard * 100 / instream waste concentration (%) CRMETALS.XLS Table 7/9/96 CLEAN METALS SAMPLING DATA REVIEW Table 4 Proposed Analysis Plan Metal Plant Catawba Crowders Long Creek Cadmium NCS X ✓ Chromium NCS NCS NCS Copper NCS V V Cyanide NCS X ✓ Lead NCS X X Mercury NCS ✓ V Nickel NCS NCS ✓ Selenium NCS X NA Silver NCS ✓ V Zinc NCS X ✓ ✓ - Clean X - Clea NCS - N NA - Co sampling required sampling at the City of Gastonia's discretion clean sampling required tituent not monitored, therefore, clean sampling not applicable TM0709.DOC 4 • 900 - Figure 1 Catawba Creek - Data from January 1994 through April 1996 800 — 700 — 600 — c 500 — 0 co L C.. 400 c U 300 — 200 — 100 — 0- EEEE EEEE EEEE I l Cadmium Chromium Copper Cyanide Lead Mercury Nickel Silver Zinc RPE - 99% Probability ® RPE- 95% Probability 0 SOC Limit ■ NPDES or Estimated Limit 94-96CAT.XLS RPE Chart-2yrs Figure 2 Catawba Creek - Data from November 1995 through April 1996 Cadmium Chromium Copper Cyanide 94-96CAT.XLS RPE Chart-6mo Lead Mercury Nickel Silver Zinc El RPE - 99% Probability ® RPE- 95% Probability ❑ SOC Limit • NPDES or Estimated Limit 500 - 0 To: 400 — 300 — 200 — Figure 3 Crowders Creek - Data from January 1994 through April 1996 Cadmium Chromium Copper Cyanide CRMETALS.XLS RPE Chart-2-yr Lead Mercury Nickel Selenium Silver Zinc D RPE - 99% Probability RPE- 95% Probability D SOC Limit ■ NPDES or Estimated Limit S 150 — c 0 al 48 c w o o 100 — Figure 4 Crowders Creek - Data from November 1995 through April 1996 Cadmium Chromium Copper Cyanide CRMETALS.XLS RPE Chart-6mo Lead Mercury Nickel Selenium Silver Z nc D RPE - 99% Probability ® RPE- 95% Probability ❑ SOC Limit ■ NPDES or Estimated Limit • 600 Figure 5 Long Creek - Data from January 1994 through May 1996 500 — 400 — c 0 J 300 — 200 — 100 0 Eiii Cadmium Chromium Copper Cyanide 9496LGMT.XLS RPE Chart- 2 yr HEE EEi EiE rm— Lead Mercury HEE NE EiE iiE Eii EEE Nickel Silver Zinc 0 RPE - 99% Probability RPE- 95% Probability 0 SOC Limit • NPDES or Estimated Limit -Long Creek NPDES or Estimated Limit -South Fork 450 Figure 6 Long Creek - Data from November 1995 through April 1996 400 — 350 — 300 c 250 0 e4 L ow 200 — c 0 0 150 -- 100 — 50 — 0- i Cadmium Chromium Copper Cyanide Lead 9496LGMT.XLS RPE Chart-6mo Mercury Nickel Silver Zinc 0 RPE - 99% Probability ▪ RPE- 95% Probability D SOC Limit ■ NPDES or Estimated Limit -Long Creek NPDES or Estimated Limit -South Fork i Attachment A Metals and Cyanide Trend Plots Cadmium (ug/l) 18 16- 14- 12- 10- 8 6 CATAWBA CREEK WWTP EFFLUENT CADMIUM CONCENTRATIONS • ♦♦ • • • Not included in statistical analysis • ♦ • 4 • • • ♦N • ♦ ♦ ♦ ♦ N ♦ ♦ ♦N N N••♦♦N ♦ ♦ ♦ ♦N ♦ ♦ ♦ 0 1 •* ,♦ • , ♦ ♦ 11/27/93 94-96CAT.XLS Cd7/10/96 • 3/7/94 6/15/94 9/23/94 1 /1 /95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 CATAWBA CREEK WWTP EFFLUENT CHROMIUM CONCENTRATIONS 4r 40 - 35 - 30 - 25 - E 2 20 - 0 15- 10- 5 0 11/27/93 • ♦♦ • • • • • • • • • • M♦ ♦♦ * M ♦♦ • • ♦♦ • • • ♦♦♦ • ♦ ♦ ♦ M • • • • • • ♦♦ • • • ♦ ♦ ♦ •. • • • • ♦40♦ ♦ • ♦ ♦M • • * M • ♦ 3/7/94 6/15/94 9/23/94 1/1/95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 94-96CAT.XLS Cr7/10/96 200 CATAWBA CREEK WWTP EFFLUENT COPPER CONCENTRATIONS 180 - 160 - 140 120 80 - 60 - 40 - 20 - 0 11/27/93 Not included in statistical analysis Not included in statistical analysis • • ♦♦ N♦ ♦ ♦:� ♦ ♦ ♦ ♦ ♦ •♦ •♦ ♦♦♦,►♦♦♦ M♦ ♦♦♦ ♦ ♦ ♦ ♦ ♦♦♦ ♦ ♦♦ ♦ ♦ • ♦♦♦ ♦♦ ♦ ♦♦ ♦♦♦ ♦ • 3/7/94 6/15/94 9/23/94 1/1/95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 94-96CAT.XLS Cu7/10/96 Cyanide (ugli) 80 CATAWBA CREEK WWTP EFFLUENT CYANIDE CONCENTRATIONS 70 - 60 - 50 - 40 - 30 - 20 - 10- 0 Not included in statistical analysis • • Not included in statistical analysis • ♦♦ • • ♦ • • ♦ ♦ • ♦ ♦ • ♦ • ♦ ♦♦ ♦ •♦♦ • ♦ $♦ M♦M♦ ♦M♦♦♦♦N N~ ♦♦NN ♦♦♦ ♦MN N♦ ♦ ♦~♦4•N♦~ M ♦♦ 9' • ♦ N yr♦~N♦ 40* N 4 11/27/93 3/7/94 6/15/94 9/23/94 1/1/95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 94-96CAT.XLS CN7/10/96 • 140 120 - 100 60 - 40 20 - CATAWBA CREEK WWTP EFFLUENT LEAD CONCENTRATIONS • ♦♦ • ♦ ♦♦ 400 ♦s Z 0 11/27/93 3/7/94 6/15/94 • • ♦ M • • • ♦♦ ♦♦ ♦ SO • • ♦ • •• ♦♦ M • • 40♦ ♦ • 0 M • ♦. • ♦. CAI►♦ •4 NM NO 4*4•0 ♦400 ♦ • ♦M AP 1• ♦ 4 • •, • • • , • defile ♦... , 9/23/94 1 /1 /95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 94-96CAT.XLS Pb7/10/96 Mercury (ug/l) 0.7 CATAWBA CREEK WWTP EFFLUENT MERCURY CONCENTRATIONS • 0.6 - 0.5 - 0.4 - 0.3 - 0.2 - 0.1 - 0, 11/27/93 • • • 3/7/94 6/15/94 9/23/94 1/1/95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 94-96CAT.XLS Hg7/10/96 t.; 0 150 - 0 z 300 CATAWBA CREEK WWTP EFFLUENT NICKEL CONCENTRATIONS 250 - 200 - 100 - 50 - 0 11/27/93 H • • • • ♦♦ M ♦♦ ♦ ♦♦ ♦ ♦ ♦4*•♦♦ • ♦♦ •• ♦ ♦ • • ♦♦ • • ♦ • ~ • ♦ ♦ ♦� •♦ • ♦ ♦i* ♦ ♦ ♦♦ ♦ • ♦♦ M ♦♦ • • N • ♦N• • • • • • • • ♦♦♦ ♦ ♦� ♦♦♦♦ • • • • • ♦♦ ♦ • M ♦ ♦ ♦ ~ • N ♦ • 3/7/94 6/15/94 9/23/94 1 /1 /95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 94-96CAT.XLS Ni7/10/96 • 90 CATAWBA CREEK WWTP EFFLUENT SILVER CONCENTRATIONS 80 - 70 - 60 - "a 50 - v "a' 40- 30 - 20 - 10- 0, 11/27/93 Not included in statistical analysis • ♦w 4,0.•♦♦♦�♦♦ ♦*♦• ♦♦� ♦♦♦♦ ♦♦♦♦ N ♦♦ ♦ ♦~ ♦• ♦♦♦♦♦�• ♦s • • ♦ • 3/7/94 6/15/94 9/23/94 1 /1 /95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 94-96CAT.XLS Ag7/10/96 450 CATAWBA CREEK WWTP EFFLUENT ZINC CONCENTRATIONS 400 - 350 300 t; 250 - • •• • • c_ ♦ ♦ N 200 - • 150 - 100 - 50 • • •♦ ♦ ♦M • •♦ 0- 11 /27/93 • N • • • ♦ ♦ ♦ ♦ • • • ♦♦ • ♦♦♦ •♦ • • • • • • ♦ ♦•♦ 3/7/94 6/15/94 9/23/94 1 /1 /95 4/11/95 7/20/95 10/28/95 2/5/96 5/15/96 8/23/96 94-96CAT.XLS Zn7/10/96 450 CROWDERS CREEK WWTP EFFLUENT CHROMIUM CONCENTRATIONS 0 400 — 350 — 300 — 250 — o% 200 — 150 — 100 — 50 — • • 0 i + i i i i i i i V v V v v v v v NN ` '0 '0 r- •� 00 00 ON 0m O O ...i � n co O\ Not included in statistical analysis • • 0\ • v 'Cr d' V' 01 NN-I c+1 N O I--- - (� • I l Y ON ON l it)V I Y 1 i I v 7 i! in VI _ _ I I I v! *! v! 1 �/ V � •V V V V M d' VI VD VD ON O 0 r-+ C d' v1 'O r. 00 O\ O DATE 50 CROWDERS CREEK WWTP EFFLUENT CADMIUM CONCENTRATIONS 45 -- 40 — 35 — 30 -- !25— 20 — 15 — 10 — 5 ON • • • Not included in statistical analysis • • ♦ ♦♦♦ •♦ ♦ ♦ _ ••• • M♦ • • • ♦ ♦ ♦• ♦ ♦ ♦ ♦ ♦ ♦ ♦• ♦ • N ON ON C7N ON ON cr‘ ON ON C:IN ON ON N_ N O O \ o\0 0\o Cs O O O t+ 1 M d' in v � 0\O C\ in • • ON ON ON C7N ON ON ON ON ON ON ON\ \ \ \ \ \ \ ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ vt in o0 0o G1 O O •� c� el M v d' in �D �D N l� ON CDO _ e M d to VD co O M 'Cr in DATE 25 CROWDERS CREEK WWTP EFFLUENT CYANIDE CONCENTRATIONS 20 - • 5- ♦♦ N ♦ ••• M► • •MM •• • ♦•• •• • • • • • • ♦ ♦ 0 1 •1 1 1 1 1 1 1 1 1 1 1 1 1 1 I d- Tt v Tr d• d- ck C\ 01 O` o\ C\ O\ 0\ C\ 01 C\ C\ C\ o\ ON o\ C\ C\ N N V'1 \D \O 00 00 O\ O O O 99.+ M ^_ .N�r ~ eq M V1 - Ls.-. -. O N (� M d tr \D N 00 ON •-r O 9 • 12/24/94 + • • • ♦ • • • 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Ui Vi V1 in V7 V) V1 vi V1 V1 in Vi V) 111 V1 N V-) \D \O \D \D \O \D \O C\ O\ O\ ON O, O\ O\ O\ O\ O\ O► O\ O\ ON O\ O\ O\ C\ Q1 O\ O\ O\ Q\ Q< 1,4 d' N 00 0`0 N N O` N c� = M \D \D N N C\ co O + t M d VI \D c� 00 C\ O il 11 h li f M Nt 1n DATE 300 CROWDERS CREEK WWTP EFFLUENT NICKEL CONCENTRATIONS Not included in statistical analysis 250 — 200 — • 150 - z 100 — 50 0 N • • ♦ ♦ • ♦ ♦♦♦ ♦ ♦ ♦• N • • • Not included in statistical analysis • • N ♦ ♦♦♦♦ ♦ • ♦ ♦ ♦ ♦~ ♦ •♦� • ♦ ♦ • ♦ • — ♦ ♦ • ♦�♦ • •♦ ♦ ---♦— - ♦ • N I I--1—~ I I f--F—_ I I I —I I I I ♦`. .♦ •♦ I I♦ I • • - 1♦—,,♦�� •� •• I I I d d' Tt d v v d d v v d •ct d' in vl vl Vl to vl Vi v-1 'r) In in in Il vl In vl ‘O ko NO NO NO NO NO O1 O\ O\ O\ O1 O\ O\ O\ CT O\ O\ O\ O\ ON O\ 01 O\ O\ O\ 01 O\ O\ O\ O\ 01 O\ O\ Oti O\ ON CT ON O\ O\ O\ O1 ON O\ O\ ON O\ ^• N �_ .O �O 00 00 ON O 0 O �--� N c� en -f d d N 00 22 N N O= c� c= VI 'et et VI NO 1 N O\ CIOO— C� M d' ,54 01 In 10 00 ON --� O .-+ NO t� 00 ON O �--� c� en d' �n DATE 250 CROWDERS CREEK WWTP EFFLUENT SELENIUM CONCENTRATIONS 200 — 150 — 100 — 50 — • M • • • • • • • • ♦ ♦♦ ♦ 1 • 0 ♦ ....1 1 �► I I I ♦1 N • ♦~~~ ♦•N�N• ,♦♦►♦ ♦ NO N .• Not included in statistical analysis ♦ ♦♦ ON ON ON M ON NO Cl") O. ON ON ON CA ON ON O 00 ON O O O ("1 CO Ch O ON ON V) ON Ch WI ON ON ON ON Oh ON O\ 01 ON 00 00 ON O O ---i (N N M ON dam' if) t` 000 DATE V) V1 VI NC NO NO NO NO ON ON ON ON CT ON ON O1 ON Orn V� N' O NO es t- esi M dam' i 30 CROWDERS CREEK WWTP EFFLUENT SILVER CONCENTRATIONS 25 -- 20 - v 15 -- az 10 - 5• - 0 0\ ♦ • • • • • M ♦♦♦♦♦ ♦ ♦ • ♦ ♦ ♦ ♦ ♦ N ♦ ♦ ♦ ♦ ♦ N ♦. ♦. ♦ ♦N ♦ ♦ ♦ ♦♦ • Nr mot' d d' 'Cr 'd' 't d' d' M" d' `Zr 'd' in to vi In '1 in in In Vi vn in N I1 Vi in in in '0 10 1O NO NO 1O 10 01 a, Q• 01 ON ON O► 01 01 a\ 01 ON CT 01 ON ON 01 01 01 01 Ot a\ 01 01 O` ON 01 01 01 ON ON O, 01 ON O1 ON ON CT ON 01 O1 N N V') NO NO t. 00 00 01 O O O .•.i N Ca 'Cr 00 00 O O v..4 N N M d d V) 10 NO t` s cn O O. .-, M t�en ` O N (� N _� -. -. N � 01 - '-' •.-� ~ M .--, cc1 cn 4 V7 \O N 00 O\ •-+ O ---- •--- ccI r-+ N M M. in so S 00 01 0 ---- •-• N ---- cc en et VI.--- ,--- .- 4 i--1 .--1 .--I DATE • 2 CROWDERS CREEK WWTP EFFLUENT MERCURY CONCENTRATIONS 1.8 - 1.6 - 1.4 - 1.2 - 0.8 - 0.6 - 0.4 - 0.2 - 0 • • ON ON 01 ON ON 01 O, ON ON 0\ ON 01 ON N N ' 0 is 00 00 ON O O O_ - M h - \ I- \ �O N 00 O\ ♦♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ O, O\ ON O, O, O\ O\ O\ ON O\ O, O, O\ _ M �t d' d' V'1 00 00 O\ O O O� O .--. ' a M d\' VI NO .-+ .-+ .--- DATE VI VI VI ON N - n ON 00 Cr)ON ON d d\' N ON • ON ON ON O, .- N N ON O \ a M M d\' 200 CROWDERS CREEK WWTP EFFLUENT ZINC CONCENTRATIONS 180 — 160 --- 140— ♦ s 120 a� 100 — • 80 —♦ ♦ • ♦ • ♦• ,► 60— • ♦ ♦♦• ♦♦ • • • • • 40 —• 20 — • • • • • • • • • • • • ♦♦ • • • • • • • • • ♦♦ • 0 I I I I I I I I I I I I I I I I I I I I I I i I I I I I I I I I I I I I I I I I it it it it it d' izt T ' it d itt it N v) In In to In v1 in in In in tn In v) \O \O O\ O\ O\ O\ ON O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O\ O1 O\ O\ O\ 0\ O\ O\ O\ O\ O\ O\ O\ O\ O\ N N N co c7, M N O .Nr N d N 00 OO Cr‘ O O �-+ (� N M d v) \p \p N N O\ O M I� O N l� O\ •may 1"''-� ~ Cr) N M �t in \p r- 00 O\ •� O 1--1 --� [� •-+ M d v) \p N 00 O\ O •--� •---11 DATE \o v\ ..r 120 CROWDERS CREEK WWTP EFFLUENT COPPER CONCENTRATIONS 100 — 80 — • 60 — o 40 — • 20 — . • • • • • •• • • ♦ ••. • ♦ . • •• • •• • • • • •• • • • • • • • • . • • • • • •• • • • 0 I I I I i I I I I I I I I I I I 1 I I I I I I I I I I I I I I I I I I I 1 1 1 1 Nt . VI %/I ul r 'n n in 'n In in 'n cn in in in in n 'o 'o \o O, CT ON ON ok ON ON o\ CA ON ON CT ON ON CA vh CA o\ O\ O\ O` ON CT o\ O, CT ON ON ON o, o\ CT o\ ON ON ON o, ON ON o, --� N �n vD \O o0 00 oo 0o ON O M in.o .p O O .-� en N M d to cNI ;D n oo ON r-+ O �--c� •-+ c� M er WI 10 I- oo ON O M -et DATE • ♦♦ 160 CROWDERS CREEK WWTP EFFLUENT LEAD CONCENTRATIONS 140 — • 120 — • 100 — • 80 - a a 60 — 40 — ♦ •• • • • ♦•♦ • • ♦ ♦ ♦ ♦ ♦ 20— ♦♦ ♦ N. ♦ • ♦ ♦ 0 - I• * 1 --;--1 • • - - • c, CT CT ON CT———-. ON ONONONONONCINONONONONONONO,ONONO,CI NONCAONONC7N� v 1 00a\ O O O -+ "el N M d' .1t dr vn o0 0o O O chi c� N M d d �n �O o I- oo •-• O �ON 0 DATE NO NO NO NO ON 0' ON ON ON O O M M VI. VI 35 30 25 20 U 15 10 Long Creek Wastewater Treatment Plant Effluent Cadmium Concentrations • • • • • • • • • ♦♦ • ♦♦• • ♦ ♦ ♦ ♦ ♦ ♦ ♦ • • • • ♦ N0 • «•♦ • • ♦ �♦ ♦ ♦ M.•M• ♦ •N •NAM •♦ M 0-$ 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Cd 7/10/96 70 Long Creek Wastewater Treatment Plant Effluent Chromium Concentrations 60 - 50 - 1 40- 0 30- U 20 - 10 • • •• • • • • • • • ♦♦ • • • • • • ♦ ♦ ♦ ♦ • ♦♦♦ ♦ • ♦ ♦♦ ♦ ♦ • ♦ • ♦♦ • s ♦♦ • 0- • M • • • • • ♦• • • • • • • • • • ♦ • • • • ♦ ♦ • ♦♦ • • ♦♦ • ♦ ♦ ♦ • • 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Cr 7/10/96 200 Long Creek Wastewater Treatment Plant Effluent Copper Concentrations 180 - 160 - 140 - 120 - • d 100 - o. • c.) 80 - ♦ ♦ ♦ ♦ • • 60 - ♦ ♦♦ •l, ♦ ♦♦• ♦ • • ♦♦• ♦ • ♦ •• ♦ ♦ 40- • • • • • 20 - • 0 - • ♦ •♦• • • • • Not included in statistical analysis • ♦ • • ♦ ♦♦ ♦ • ♦ • •N ♦ • • • • 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Cu 7/10/96 70 60 50 40 - 0 v co 0 30 - 20 - 10- 0- • • Civ• ' 1 Long Creek Wastewater Treatment Plant Effluent Cyanide Concentrations • • • • N♦ ♦ ♦ ♦ ♦• ♦ ♦♦ • ♦ • ♦ • • • • • • ♦♦ ♦ ♦ ♦ • •♦ ♦ • •-•. ♦- - • ♦ • • •• ♦ ♦NN*NO N • w ♦•N•NN ♦ ♦NON• N ♦♦♦M ♦ �► w • ♦ • ♦♦ ♦ •♦ • M • _ Not included in statistical analysis • • • 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 Page 9 140 Long Creek Wastewater Treatment Plant Effluent Lead Concentrations 120 - 100 80 co 'J 60 40 - • • • • • • • ♦ ♦ • ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ • ♦♦ • ♦ ♦ • 20- N ♦• ♦ • • • ♦ • • ♦ * N - -♦ - ♦ - ♦ ♦♦ • ♦•• M ♦• ♦♦ • NO • • • �♦ N • • 0 _ . 2 t4It• • • dk • • • , • • • 11•••• ••w ••••••► 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Pb 7/10/96 m 0.8 2 0.6 0.4 0.2 - 0- Long Creek Wastewater Treatment Plant Effluent Mercury Concentrations •• • • ♦ ♦• • • • ♦ N ♦A! N • • MOM ♦ M • • 41000000 • NM•SI►N• %OWNN♦ MNNM•• MN ♦ ♦~ M• • ♦• ♦ ilk 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Hg 7/10/96 • 250 Long Creek Wastewater Treatment Plant Effluent Nickel Concentrations 200 - 150 V Z 100 50 • ♦♦ • • Not included in statistical • analysis • ♦♦ % • • • • • ♦♦ • • • • • • • • • •• • ♦♦ •• ♦ • ♦ ♦ ♦ N • • • • • ♦ ♦� • • • • • ♦ • • • • • • ♦♦♦ N♦ • ♦♦ • ♦ ♦ • ♦ • M • • N♦ • • ♦ 0- • • ,♦ • 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Ni 7/10/96 Long Creek Wastewater Treatment Plant Effluent Silver Concentrations 20 - 18- 16- 14- 8 6 4 2 0 1 /1 /94 • • • • • ♦ ♦♦ • ♦♦ • • ♦♦• ♦• • • • ♦ ♦ N • • • N N • Not included in statistical analysis ♦r ♦ -M • • • • ♦♦ 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 8/24/95 12/2/95 3/11/96 6/19/96 9496LGMT.XLS Ag 7/10/96 350 Long Creek Wastewater Treatment Plant Effluent Zinc Concentrations 300 - 250 - • • • • • 200 - t c IV 150 100 - 50 • • • ♦r► ♦ • ♦ • ♦• • • • • • • • • • ♦♦ • ♦ • • • • • ♦♦ ♦ ♦ • • • • 0- , • 1 /1 /94 4/11/94 7/20/94 10/28/94 2/5/95 5/16/95 9496LGMT.XLS Zn 7/10/96 • • ♦♦ • • • • • • • • • • • • • 8/24/95 12/2/95 3/11/96 6/19/96 (11ttg of Gastonia P. O. BOX 1748 ki5ustartia, arts{ Qluraliva 28053-1748 DEPARTMENT OF PUBLIC WORKS AND UTILITIES June 7, 1996 Ms. Colleen Sullins DEM/WQ/P&E Supervisor of Permits and Engineering P.O. Box 29535 Raleigh, N.C. 27626-0535 Dear Ms. Sullins: Enclosed for your review is a summary of data for one of the issues which we will be discussing on Wednesday, June 12, at 8:30 a.m. via telephone conference. Sincerely, CITY OF GASTONIA u.. Co eman M. Keeter Superintendent of WWTD CHROMIUM Catawba Creek WWTP A Comparison of Effluent Metals Before and After the Lime Addition NICKEL COPPER ZINC 95 7.971 .06 1 1 LEAD 28 15 0.468 E 0.0 CADMIUM 27 2.052 L 0.3 CYANIDE ■ January - November 95 Average December, 95 - April, 96 Average ■ SOC COMPLIANCE LEVEL • NPDES COMPLIANCE LEVEL ZINC CATAWBA CREEK WWTP EFFLUENT METALS CHARACTERIZATION BY PERCENT BEFORE THE LIME FEED ADDITION CADMIUM 0% PERCENTAGES ARE OF 9.37478 LBS/DAY TOTAL EFFLUENT METALS COPPER, NICKEL, AND ZINC ARE CONSIDERED TO BE THE BIG THREE METALS OF CONCERN AND MAKE UP 92% OF THE TOTAL EFFLUENT METALS WITH A COMBINED AVERAGE OF 8.6248 LBS/DAY BEFORE THE LIME FEED ADDITION. CATAWBA CREEK WWTP EFFLUENT METALS CHARACTERIZATION BY PERCENT AFTER THE LIME FEED ADDITION PERCENTAGES ARE OF 0.46416 LBS/DAY TOTAL EFFLUENT METALS COPPER, NICKEL, AND ZINC ARE CONSIDERED TO BE THE BIG THREE METALS OF CONCERN AND MAKE UP 62% OF THE TOTAL EFFLUENT METALS WITH A COMBINED AVERAGE OF 0.288 LBS/DAY AFTER THE LIME FEED ADDITION. NICKEL 3% CADMIUM 3% CATAWBA CREEK WWTP A COMPARISON OF EFFLUENT POUNDS PER DAY BEFORE AND AFTER THE ADDITION OF THE LIME FEED PROCESS EFFLUENT CHROMIUM FINAL EFFLUENT AVERAGE OF 0.40688 LBS/DA\ DISCHARGED BEFORE THE ADDITION OF THE LIME FEED PROCESS BEFORE FINAL EFFLUE AVERAGE OF (1.1157OO6 LBS/DAY DISCHARGED AFTER THE ADDITION OF THE LIME FEED PROCESS 86 °''i RE DI f'T CIO F'FLU E C �a �►S/DAY 4>FTRR J IIIO4 P1Ell ] FEE PROCE�f SLIME FEED AFTER CATAWBA CREEK WWTP A COMPARISON OF EFFLUENT POUNDS PER DAY BEFORE AND AFTER THE ADDITION OF THE LIME FEED PROCESS EFFLUENT NICKEL FINAL EFFLUENT AVERAGE OF 1.90022 LBS/DAY DISCHARGED BEFORE THE ADDITION OF THE LIME FEED PROCESS BEFORE 93 E v t T H SLIME FEED AFTER VERA Il 139665 LBS SCHARGED AFT ADDITION OFTHIHI FEED Pfit� L E LUENT OF AY RTHE s,n IME CATAWBA CREEK WWTP A COMPARISON OF EFFLUENT POUNDS PER DAY BEFORE AND AFTER THE ADDITION OF THE LIME FEED PROCESS EFFLUENT COPPER 1 FINAL EFFLUENT AVERAGE OF 0.87669 LBS/DAY DISCHARGED BEFORE THE ADDITION OF THE LIME FEED PROCESS Y DI CTI E w'1 C OJ' AITERT FIHE1 'ROCESS BEFORE SLIME FEED AFTER FINAL EFFLUENT AVERAGE OF 0.013935 LBS/DAY DISCHARGED AFTER THE ADDITION OF THE LIME FEED PROCESS CATAWBA CREEK WWTP A COMPARISON OF EFFLUENT POUNDS PER DAY BEFORE AND AFTER THE ADDITION OF THE LIME FEED PROCESS EFFLUENT ZINC FINAL EFFLUENT AVERAGE OF 5.80382 LBS/DAY DISCHARGED BEFORE THE ADDITION OF THE LIME FEED PROCESS N BEFORE SLIME FEED AFTER 1 T FINAL EFFLUENT AVERAGE OF (1.25(1193 LBS/DAY DISCHARGED AFTER THE ADDITION OF THE LIME FEED PROCESS CATAWBA CREEK WWTP A COMPARISON OF EFFLUENT POUNDS PER DAY BEFORE AND AFTER THE ADDITION OF THE LIME FEED PROCESS EFFLUENT CADMIUM FINAL EFFLUENT AVERAGE OF 0.02147 LBS/DAY DISCHARGED BEFORE THE ADDITION OF THE LIME FEED PROCESS P F F r E L D Crl CA 711 'ICE D BEFORE SLIME FEED AFTER FINAL EFFLUENT AVERAGE OF 0.000443 LBS/DAY DISCHARGED AFTER THE ADDITION OF THE LIME FEED PROCESS CATAWBA CREEK WWTP A COMPARISON OF EFFLUENT POUNDS PER DAY BEFORE AND AFTER THE ADDITION OF THE LIME FEED PROCESS EFFLUENT LEAD FINAL EFFLUENT AVERAGE OF 0.36569 LBS/DAY DISCHARGED BEFORE THE ADDITION OF THE LIME FEED PROCESS BEFORE 9'9 Di • E: 41.1? v IU!s T LEA TER T Fi THE LI SLIME FEED AFTER FINAL EFFLUENT AVERAGE OF 0.00291.4 LBS/DAY DISCHARGED AFTER THE ADDITION OF THE LIME FEED PRO ESS CATAWBA CREEK WWTP A COMPARISON OF EFFLUENT POUNDS PER DAY BEFORE AND AFTER THE ADDITION OF THE LIME FEED PROCESS EFFLUENT CYANIDE FINAL EFFLUENT AVERAGE OF 0.09405 LBS/DA\' DISCHARGED BEFORE THE ADDITION OF THE LIME FEED PROCESS BEFORE L Y v D FINAL EFFLUENT AVERAGE OF 0.0180 LBS/DAY DISCHARGED AFTER THE ADDITION OF THE LIME FEED PROCESS CT I`ll! THE KE9 SLIME FEED AFTER