Loading...
HomeMy WebLinkAboutWI0300136_Regional Office Historical File Pre 2018AQUIFER PROTECTION SECTION APPLICATION REVIEW REQUEST FORM Date: June 30, 2009 To: ❑ Landon Davidson, ARO-APS ❑ Art Barnhardt, FRO-APS [Andrew Pitner, MRO-APS ❑ Jay Zimmerman, RRO-APS From: Thomas Slusser , Groundwater Protection Unit Telephone: (919) 715-6164 /cS� E Mail: thomas.slusser@ncdenr.gov A. Permit Number: WI0300136 B. Owner: SUNOCO El David May, WaRO-APS ❑ Charlie Stehman, WiRO-APS ❑ Sherri Knight, WSRO-APS Fax: (919) 71 FECEEIWIE CDENRiV1R0 N. DWQ -A • uifer Protection C. Facility/Operation: FORMER COUNTRY CUPBOARD ❑ Proposed E-Existing 'Facility ❑ Operation"` D. Application: 1. Permit Type: ❑ Animal ❑ Surface Irrigation ❑ Reuse ❑ H-R Infiltration ❑ Recycle ❑ I/E Lagoon ❑ GW Remediation (ND) - (5I) in -situ groundwater remediation For Residuals: ❑ Land App. ❑ D&M ❑ Surface Disposal ❑ 503 ❑ 503 Exempt ❑ Animal 2. Project Type: New ❑ Major Mod. ❑ Minor Mod. ❑ Renewal El Renewal w/ Mod. E. Comments/Other Information: ❑ I would like to accompany you orl a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 30 calendar days, please take the following actions: [Return a Completed Form APSSRR. ❑ Attach Well Construction Data Sheet. El Attach Attachment B for Certification by the LAPCU. El Issue an Attachment B Certification from the RO*. * Remember that you will be responsible for coordinating site visits, reviews, as well as additional information requests with other RO-APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. When you receive this request form, please write your name and dates in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Reviewer: Date: FORM: APSARR 02/06 Page 1 of 1 Beverly Eaves Perdue Governor TA- MCDE North Carolina Department of Environment and Natural Resources Division of Water Quality Coleen H. Sullins Director June 26, 2009 Devon Watts Sunoco, Inc 203 South Falkenburg Road Tampa, FL 33619 Subject: Acknowledgement of Application No. WI0300136 Former Country Cupboard Sunoco Inc Injection In situ Groundwater Remediation Well (5I) Rowan Dear Devon: Dee Freeman Secretary rocuivE I JUL -1 2009 NC ❑ENR MRO DWQ - As uifer Protection The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit application and supporting materials on June 26, 2009. This application package has been assigned the number listed above and will be reviewed by Thomas Slusser. The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the maximum efficiency in processing permit applications, the Division requests your assistance in providing a timely and complete response to any additional information requests. Please be aware that the Division's Regional Office, copied below, must provide recommendations prior to final action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete application. If you have any questions, please contact Thomas Slusser at 919-715-6164, or via e-mail at thomas.slusser@ncdenr.gov. If the reviewer is unavailable, you may leave a message, and they will respond promptly. Also note that the Division has reorganized. To review our new organizational chart, go to http://h2o.enr.state.nc.us/documents/dwq orgchart.pdf. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS PROJECT. Sincerely, for Debra J. Watts Supervisor cc: rcluirfe Protection S Scott Dunsmuir (EnviroTracLtd 375 Winkler Drive, Ste E, Alpharetta, GA 30004) Permit Application File W10300136 AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard, Raleigh, North Carolina 27604 Phone: 919-733-3221 \ FAX 1: 919-715-0588; FAX 2: 919-715-60481 Customer_Service: 1-877-623-6748 Internet: www.ncwateraualitv.orq An Equal Opportunity \ Affirmative Action Employer Tone , orthCarol..i Nna Naturally State of North Carolina Department of Environment and Natural Resources Division of Water Quality APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FO&JN Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer In, jection ^ binJ ♦ • Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject t • Submit TWO copies of the completed application and all attachments to the address on the Last page of thi • Any changes made to this form will result in the application package being returned. Application Number (to be completed by DWQ): eZ 3c20 3-4 I. GENERAL INFORMATION: 1. Applicant's Name (generally the responsible party): Sunoco Inc 2. Signing Official's Name: Devon Watts 3. Mailing address of applicant: 203 South Falkenburg Road Title: Environmental Specialist City: Tampa Telephone number: (813) 654-7789 State: FL Zip: 33619 Fax number: (813) 657-7608 4. Property Owner's Name (if different from Applicant): S Cashion LLC 5. Property Owner's mailing address: 322 E Fisher St City: Salisbury State: NC Zip: 28144 6. Name and address of contact person who can answer questions about the proposed injection project: Name: Scott Dunsmuir Company: EnviroTrac Ltd Address: 375 Winkler Drive; Suite E Title: Operations Manager City: Alpharetta Telephone number: (770) 777-1711 Email Address: scottd@envirotrac.com II. PERMIT INFORMATION: State: GA Zip: 30004 Fax number: (770) 777-1766 1. Project is: ❑x New ❑ Modification of existing permit ❑ Renewal of existing permit without modification ❑ Renewal of existing permit with modification 2. If this application is being submitted for renewal or modification to an existing permit, provide: existing permit number and the issuance date For renewal without modifications, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner). For all renewals, you must submit a status report including monitoring results of all injection activities to date. Revised 8/07 UIC-5I/5T RECEIVED I DENR I DWQ Aquifer Protection Section JUN 2 4 2009 Page 1 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection III. INCIDENT & FACILITY DATA A. FACILITY INFORMATION 1. Facility name: Former Country Cupboard Sunoco Inc 2. Complete physical address of the facility: 2010 Statesville Blvd City: Salisbury County: Rowan State: NC Zip: 28144 B. INCIDENT DESCRIPTION 1. Describe the source of the contamination: The apparent source of contamination at the site was identified as a combination of a leak from a gasoline UST that occurred in October 1986 and an aboveground spill of approximately 146 gallons of unleaded gasoline that occurred during refilling operations in June 1997. 2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): Gasoline. 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? ❑X Yes If yes, list maximum measured separate phase thickness 2.24 . feet ❑ No If no, list maximum concentration of total VOCs observed at site: ppb 4. Agency managing the contamination incident: i UST Section ❑ Superfund Section (including REC Program and DSCA sites) ❑ DWQ Aquifer Protection Section ❑ Solid Waste Section ❑ Hazardous Waste Section ❑ Other: 5. Incident managers name Dan Graham and phone number (704) 663-1699 6. Incident number or other site number assigned by the agency managing the contamination incident: NCDENR Groundwater Incident #3519 C. PERMITS List all permits or construction approvals that have been issued for the facility or incident, including those not directly related to the proposed injection operation: 1. Hazardous Waste Management program permits under RCRA: 2. DWQ Non -Discharge or NPDES permits: 3. County or DEH subsurface wastewater disposal permits: 4. Other environmental permits required by state or federal law: Revised 8/07 UIC-5I/5T Page 2 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection IV. INJECTION DATA A. INJECTION FLUID DATA 1. List all proposed injectants. NOTE: Any substance to be injected as a tracer or to promote in situ remediation must be reviewed by the Occupational and Environmental Epidemiology Section (OEES) of the Division of Public Health, Department of Health and Human Services. Review the list of approved injectantsT or contact the UIC Program to determine if the injectants you are proposing have been reviewed by OEES. Injectant: Regenox Concentration at point of injection: Five Percent Injectant: Concentration at point of injection: Injectant: Concentration at point of injection: Injectant: Concentration at point of injection: Injectant: Concentration at point of injection: 2. Source of fluids used to dilute or chase the injectants listed above: ❑ None ❑x Municipal water supply ❑ Groundwater from private well or any well within 'A mile of injection site ❑ Air ❑ Other: 3. If any well within'/4 mile of injection site, a private well, or surface water is to be used as the fluid source, supply the following information: a. Location/ID number of source: b. Depth of source: c. Formation: d. Rock/Sediment type: e. In Attachment C, provide a current, complete chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site. NOTE: If contaminated groundwater is to be used as the dilution or chase fluid, this is not the proper permit application form. You must apply for a closed -loop groundwater remediation permit using application form GWRS. Revised 8/07 UIC-51/5T Page 3 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection B. PROPOSED OPERATING PARAMETERS 1. Duration of Injection: Maximum number of separate injection events: Three Expected duration of each injection event: Eight Hours Expected duration between events (if more than one event): 30 days 2. Injection rate per well: One gallons per minute (gpm) 3. Total Injection volume: 200 gallons per day (gpd); 200 4. 'Injection pressure: Less than 20 pounds/square inch (psi) 5. Temperature at point of injection: 72 °F 6. Briefly describe how the above parameters will be measured and controlled: Volume and flow will be measured using an in -line flow meter/totalizer. Pressure will be monitored with a pressure gauge mounted on the injection manifold. Flow and pressure will be controlled via a gate valve downstream from the pump, which can restrict the flow, and thereby lower the pressure. 7. Estimated hydraulic capacity of the well: Three gpm gallons per event (if separate events) C. INJECTION WELL CONSTRUCTION DATA 1. Injection will be via: N Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of your knowledge. ❑ Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as proposed construction specifications. 2. Well Drilling Contractor's Name: Bore and Core NC Well Contractor Certification number: 763 3. Date to be constructed: October 1989 Number of borings: Four Approximate depth of each boring (feet): 35 4. Screened interval/Injection interval of injection wells:. Depth: 7 to 35 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth). 5. Well casing (N/A if injection is through direct push rods): Type: ❑x PVC ❑ Stainless steel ❑ Other: Casing depth: to ft. 6. Grout (N/A if injection is through direct push rods): Type: N Cement ❑ Bentonite ❑ Other: Grout depth: 1 to 4 ft. Revised 8/07 UIC-5I/5T Page 4 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection V. ATTACHMENTS Provide the following items as attachments with the given headings: A. SITE HISTORY Provide a brief description of the site history including: (1) site usage historically and present, (2) origin of the contamination, (3) previous remedial action(s). NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under his or her direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work which shall have been prepared or approved by a licensed geologist or a subordinate under his or her direction be signed and sealed by him or her. B. HYDROGEOLOGIC DESCRIPTION Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The hydrogeologic description shall include: (1) the regional geologic setting; (2) significant changes in lithology; (3) the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters; and (4) the depth to the mean seasonal high water table. C. INJECTION FLUID COMPOSITION Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety Data Sheet (MSDS) for each injectant. If a private well or a well within 'A mile of the injection site is used as the source well, include chemical analysis of source fluid here. D. INJECTION RATIONALE Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including: (1) goals of the injection project; (2) a description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; and (3) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. E. INJECTION PROCEDURE AND EQUIPMENT Provide a detailed description of all planned_ activities related to the proposed injection including but not limited to: (1) construction plans and materials; (2) operation procedures; (3) a detailed diagram of the surface and subsurface portions of the system; and (4) a planned injection schedule. F. MONITORING PLAN Provide a plan for monitoring the results of the injection, including: (1) a list of existing and proposed monitoring wells to be used; (2) a list of monitoring parameters and analytical methods to be used; and (3) a schedule for sampling to monitor the proposed injection. NOTE: The selected monitoring wells must be located so as to detect any movement of injection fluids, process by- products, or formation fluids outside the injection area or zone. The monitoring parameters should include the target contaminants as well as secondary or intermediate contaminants which may result from the injection and other parameters which may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved oxygen, and Revised 8/07 UIC-5I/5T Page 5 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated reactions and rate of transport of the injectants and contaminants. G. WELL DATA Provide a tabulation of data on all existing or abandoned wells within 1/4 mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's use (water supply, monitoring, etc), total depth, screened or open borehole depth interval, and well construction or abandonment record, if available. H. MAPS Attach the following scaled, site -specific maps: (1) Area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site. (2) Site map including: a. all property boundaries; b. all buildings within the property boundary; c. existing and proposed injection wells or well field(s) d. any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within '/ mile of the injection well or well system; e. all surface water bodies within'/4 mile of the injection well or well system; and f. all existing or abandoned wells within 1/4 mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. (3) Potentiometric surface map(s) including: a. direction of groundwater movement b. existing and proposed monitoring wells c. existing and proposed injection wells (4) Contaminant plume map(s) including: a. the horizontal extent of the contaminant plume, including isoconcentration lines b. existing and proposed monitoring wells c. existing and proposed injection wells (5) Cross-section(s) to the known or projected depth of contamination, including: a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines b. major changes in lithology Revised 8/07 UIC-51/5T Page 6 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells - In Situ Groundwater Remediation / Type ST Wells - Tracer Injection VI. CERTIFICATION l)euoe Lak 1, (printed name of signing official) , hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate; maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit. Signature: vd-h Title: Environmental Specialist, Southeast Date: (9- tc?-09 If authorized agent is acting on behalf of the applicant, supply a letter signed by the applicant authorizing the above agent. VIl. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant) ("Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing.) .00t4l10) L�l Sarcira L. shi n I, (printed dune of property owner) , as owner of the property on which the injection well(s) are to be constructed and operated, hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title 15A NCAC 2C .0200) Signature: 0.41dt-/L-OLAAJ-0--- Title: 0\11Y....bd- Date: 61 /5/aoc,9 Submit TWO copies of the completed application package, including all attachments, to: UIC Program Aquifer Protection Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 733-3221 Revised 8/07 UIC-5I/ST ECEllY JUL 1 2009 NC DENR MRO DWQ - A. uifer Protection RECEIVED / DENR / DWQ Aquifer Protection Section JUN 2 4 2009 Page 7 of 7 SIM 3VIIV A. SITE HISTORY Site Usage Historically and Present: The Country Cupboard Sunoco is a retail gasoline and convenience store located at the intersection of Jake Alexander Boulevard (Highway 601) and Statesville Boulevard (Highway 70) in Salisbury, North Carolina. The site is triangular in shape and approximately one-half acre in size. The 2,000 square foot convenience store occupies the western half of the property. The site has been occupied by a retail gasoline station for at least 47 years. The site is currently operating as a British Petroleum (BP) retail petroleum and convenience store. Origin of the Contamination: The apparent source of groundwater contamination at the site was identified as a combination of a leak from a gasoline UST that occurred in October 1986 and an aboveground spill of approximately 146 gallons of unleaded gasoline that occurred during refilling activities in June 1987. Previous Remedial Action(s): IT Corporation submitted a Corrective Action Plan (CAP) in August 1993. The CAP proposed the use of soil vapor extraction (SVE) to remediate the hydrocarbon compounds at the subject site. Following approval of the CAP, the SVE system was activated in April 1994. A CAP Addendum, submitted in October 1996, proposed the use of air sparging technology to address dissolved -phase petroleum hydrocarbons in groundwater. Following approval of the CAP Addendum, the air sparge system was activated on June 11, 1997. The AS/VE system is located at the rear of the convenience store building. The system consists of an air sparge compressor that injects compressed air beneath the zone of groundwater contamination through 10 air sparge wells (SP-1, SP-2, SP-3, SP-4, SP-5, SP-6, SP-7, SP-8, SP-9, and SP-10). The system also includes a vacuum extraction blower for recovering petroleum hydrocarbon vapors through nine vapor extraction wells (VP-1, VP-2, VP-3, VP-4, VP-4, VP-5, MW-1, MW- 4, MW-7, and RW-1). The extracted vapors are discharged to the atmosphere. Through the end of August 2002, the AS/VE system was managed and operated by Groundwater & Environmental Services (GES). ATC acquired the AS/VE system in September 2002. In October 2002, ATC personnel visited the site and noted that the system was not operating. ATC personnel were able to troubleshoot and restart the SVE blower; however, the air sparge unit required more extensive repair work. After replacing several parts and hiring a vendor to perform additional maintenance, ATC personnel restarted the air sparge unit in February 2003. The AS/VE system has been shut down since June 2007 while remedial alternatives are being reviewed. B. HYDROGEOLOGIC DESCRIPTION Regional Geologic Setting: The Salisbury area is underlain by Paleozoic rocks of the Carolina Slate Belt, which consist of granite, granodiorite, quartz monzonite, and a mixture of granite and diorite. These rocks are generally fine to medium -grained and are easily weathered producing a sandy, clayey saprolite. The saprolite may range in thickness from a few feet to 50 feet. Significant changes in lithology: None observed. Hydraulic Conductivity, Transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test used to determine these parameters: A rising head bail test was performed on well MW-3 in lieu of a groundwater pumping test to assess aquifer characteristics of the saprolite. The bail test was performed on well MW-3 by quickly bailing water from the well until the well was nearly dry. Bailing was stopped and rising water levels measured with an electric water level probe until the water level in the well had recovered to near static conditions. A log drawdown versus time recovery plot of water level data was prepared and evaluated using the Hvorslev method. The hydraulic conductivity (K) of the saprolite in the vicinity of well MW-3 determined from the bail test is approximately 1.34 gpd/ft3. This value is within the range for silt, sandy silts, and clayey silts, and clayey sands presented in the literature. Assuming a minimum saturated thickness (b) of the saprolite to be 50 feet, then by the relationship T = Kb, the minimum aquifer transmissivity (T) is approximately 67 gpolft. Depth to the Mean Seasonal High Water Table: Water levels have been measured at the site for several years, and it is apparent that he mean water level is approximately 32 feet below land surface. C. INJECTION FLUID COMPOSITION See attached RegenoxTM Brochure. MSDS Sheets for RegenoxTM Part A and Regenox Part B are also attached. D. INJECTION RATIONALE Based on review of historical groundwater analytical data and current site conditions, it appears that dissolved -phase constituents of concern are isolated to four monitoring well locations (MW-3, MW-5, MW-6, and VMW-7). Remediation of these areas via active mechanical remediation may not reduce the current concentrations to the groundwater governing standards applicable to this site (NCDENR Groundwater Quality 2L Standards) in an acceptable timeframe. As such, an advanced chemical oxidation technology is proposed to more rapidly and effectively destroy the targeted groundwater constituents. The chemical -oxidizing agent (RegenoxTM, which is on the NCDENR approved -chemical list) will be introduced to the subsurface as a slurry solution via direct -injection (geoprobe grout pump) using the above -referenced monitoring wells as injection points. Once introduced to the subsurface, efficient oxidation reactions will occur as a result of three mechanisms including surface mediated oxidation, direct oxidation, and free radical oxidation. RegenoxTM, which produces minimal heat, will continue to affect the oxidation process for up to 30 days on a single injection. TM ge CHEMICAL OXIDATION REDEFINED... RegenOx- is an advanced in situ chemical oxidation technology* designed to treat organic contaminants including high concentration source areas in the saturated and vadose zones PRODUCT FEATURES: • Rapid and sustained oxidation of target compounds Easily applied with readily available equipment • Destroys a broad range of contaminants .'10 More efficient than other solid oxidants =u 3 Enhances subsequent bioremediation ttA'i Avoids detrimental impacts to groundwater aquifers RegenOx product application HOW IT WORKS: RegenOx maximizes in situ performance using a solid alkaline oxidant that employs a sodium percarbonate complex with a multi -part catalytic formula. The product is delivered as two parts that are combined and injected into the subsurface using common drilling or direct -push equipment. Once in the subsurface, the combined product produces an effective oxidation reaction comparable to that of Fenton's Reagent without a violent exothermic reaction. RegenOx safely, effectively and rapidly destroys a wide range of contaminants in both soil and groundwater (Table 1). ACHIEVES RAPID OXIDATION VIA A NUMBER OF MECHANISMS RegenOx directly oxidizes contaminants while its unique catalytic complex generates a suite of highly charged, oxidative free radicals that are responsible for the rapid destruction of contaminants. The mechanisms by which RegenOx operates are: =s Surface- Mediated Oxidation: (see Figure 1 and description below) + Direct Oxidation: C,CI, + 2 Na,CO, • 3 H2O, + 2 H2O -4--► 2CO2 + 4 NaCI + 4 H2O + 2 H2CO3 Free Radical Oxidation: — Perhydroxyl Radical (H02') — Hydroxyl Radical (OH-) — Superoxide Radical (0,•) Figure 1. Surface -Mediated Oxidation is responsible for the majority of RegenOx contaminant destruction. This process takes place in two stages. First, the RegenOx activator complex coats the subsurface. Second, the oxidizer complex and contaminant react with the activator complex surface destroying the contaminant. * Patent applied for Figure 1. RegenOx'" Surface -Mediated Oxidation Contaminants breakdown CO2 and H=O Activator Complex (Surface), Contarn"inant TM From Mass Reduction to Bioremediation: RegenOx'" is an effective and rapid contaminant mass reduction technology. A single injection will remove significant amounts of target contaminants from the subsurface. Strategies employing multiple Regenox injections coupled with follow-on accelerated bioremediation can be used to treat highly contaminated sites to regulatory closure. In fact, RegenOx was designed specifically to allow for a seamless transition to low-cost accelerated bioremediation using any of Regenesis controlled release compounds. Significant Longevity: RegenOx has been shown to destroy contaminants for periods of up to one month. Product Application Made Safe and Easy: RegenOx produces minimal heat and as with all oxidants proper health and safety procedures must be followed. The necessary safety guidance accompanies all shipments of RegenOx and additional resources are available on request. Through the use of readily available, highly mobile, direct -push equipment and an array of pumps, RegenOx has been designed to be as easy to install as other Regenesis products like ORO' and HRC®. Effective on a Wide Range of Contaminants: RegenOx has been rigorously tested in both the laboratory and the field on petroleum hydrocarbons (aliphatics and aromatics), gasoline oxygenates (e.g., MTBE and TAME), polyaromatic hydrocarbons (e.g., naphthalene and phenanthrene) and chlorinated hydrocarbons (e.g., PCE, TCE, TCA). Oxidant Effectiveness vs. Contaminant Type: Activated Persulfate Persulfate Ozone Fenton's Contaminant RegenOx" Reagent Permanganate Petroleum Hydrocarbons A A B B B A Benzene A A D B B A MTBE A B B C B B Phenols A A B C B A Chlorinated Ethenes (PCE, TCE, DCE, VC) A -A A B A A Chlorinated Ethanes (TCA, DCA) A B C D C B Polycyclic Aromatic Hydrocarbons (PAHs) A A B B A A Polychlorinated Biphenyls (PCBs) B C D D D B Explosives (RDX, HMX) A A A A A A Based on laboratory kinetic data, thermodynamic calculations, and literature reports. Oxidant Effectiveness Key: A = Short half life, low free energy (most energetically favored), most complete B = Intermediate half life, low free energy, intermediate degree of completion C = Intermediate half life, intermediate free energy, low degree of completion D = Long half life, high free energy (least favored), very low degree of completion REGENESES Advanced Technologies for Groundwater Resources 1011 Calle Sombra !San Clemente r California 92673-6244 Tel: 949/366-8000 ! Fax: 949:366-8090 ! www.regenesis.com Regen OX — Part A (Oxidizer Complex) Material Safety Data Sheet (MSDS) Last Revised: October 1, 2007 Section 1 — Supplier Information and Material Identification Supplier: REGENESIS 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8000 Fax: 949.366.8090 E-mail: infocregenesis.com Chemical Description: Chemical Family: Trade Name: Product Use: A mixture of sodium percarbonate [2Na2CO3.3H202], sodium carbonate [Na2CO3], sodium silicate and silica gel. Inorganic Chemicals Regen Ox — Part A (Oxidizer Complex) Used to remediate contaminated soil and groundwater (environmental applications) Section 2 — Chemical Information/Other Designations CAS No. 15630-89-4 5968-11-6 7699-11-6 63231-67-4 Chemical Sodium Percarbonate Sodium Carbonate Monohydrate Silicic Acid Silica Gel Percentage 60 -100 % 10-30% <1% < 1 % Section 3 — Physical Data Form: Color: Odor: Melting Point: Boiling Point: Powder White Odorless NA NA RegenOx — Part A Section 3 — Physical Data (cont) Flammability/Flash Point: Vapor Pressure: Bulk Density: Solubility: Viscosity: pH (3% solution): Decomposition Temperature: NA NA 0.9 — 1.2 g/cm3 Min 14.5g/100g water @ 20 °C NA 10.5 Self -accelerating decomposition with oxygen release starts at 50 °C. Section 4 — Reactivity Data Stability: Conditions to Avoid/Incompatibility: Hazardous Decomposition Products: Stable under normal conditions Acids, bases, salts of heavy metals, reducing agents, and flammable substances Oxygen. Contamination with many substances will cause decomposition. The rate of decomposition increases with increasing temperature and may be very vigorous with rapid generation of oxygen and steam. Section 5 — Regulations TSCA Inventory Listed: Yes CERCLA Hazardous Substance (40 CFR Part 302) Listed Substance: Unlisted Substance: No Yes SARA, Title III, Sections 313 (40 CFR Part 372) — Toxic Chemical Release Reporting: Community Right -To -Know Extremely Hazardous No Substance: WHMIS Classification: Canadian Domestic Substance List: C, D2B Appears J:\Operations\MSDS\Regenox Page 2 RegenOx — Part A Section 6 — Protective Measures, Storage and Handling Technical Protective Measures Storage: Handling: Oxidizer. Store in a cool, well ventilated area away from all sources of ignition and out of the direct sunlight. Store in a dry location away from heat and in temperatures less than 40 °C. Keep away from incompatible materials and keep lids tightly closed. Do not store in improperly labeled containers. Protect from moisture. Do not store near combustible materials. Keep containers well sealed. Store separately from reducing materials. Avoid contamination which may lead to decomposition. Avoid contact with eyes, skin and clothing. Use with adequate ventilation. Do not swallow. Avoid breathing vapors, mists or dust. Do not eat, drink or smoke in the work area. Label containers and keep them tightly closed when not in use. Wash hands thoroughly after handling. Personal Protective Equipment (PPE) Engineering Controls: Respiratory Protection: Hand Protection: General room ventilation is required if used indoors. Local exhaust ventilation, process enclosures or other engineering controls may be needed to maintain airborne levels below recommended exposure limits. Avoid creating dust or mists. Maintain adequate ventilation at all times. Do not use in confined areas. Keep levels below recommended exposure limits. To determine actual exposure limits, monitoring should be performed on a routine basis. For many conditions, no respiratory protection is necessary; however, in dusty or unknown conditions or when exposures exceed limit values a NIOSH approved respirator should be used. Wear chemical resistant gloves (neoprene, rubber, or PVC). J:\Operations\MSDS\Regenox Page 3 RegenOx — Part A Section 6 — Protective Measures, Storage and Handling (cont) Eye Protection: Skin Protection: Other: Protection Against Fire & Explosion: Wear chemical safety goggles. A full face shield may be worn in lieu of safety goggles. Try to avoid skin contact with this product. Chemical resistant gloves (neoprene, PVC or rubber) and protective clothing should be worn during use. Eye wash station. Product is non -explosive. In case of fire, evacuate all non- essential personnel, wear protective clothing and a self- contained breathing apparatus, stay upwind of fire, and use water to spray cool fire -exposed containers. Section 7 — Hazards Identification Potential Health Effects Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, and irritations to mucous membranes, nose and throat. Eye Contact: Causes irritation, redness and pain. Skin Contact: Causes slight irritation. Ingestion: May be harmful if swallowed (vomiting and diarrhea). Section 8 — Measures in Case of Accidents and Fire After Spillage/Leakage: Extinguishing Media: First Aid Eye Contact: Inhalation: Ingestion: Eliminate all ignition sources. Evacuate unprotected personnel and never exceed any occupational exposure limit. Shovel or sweep spilt material into plastic bags or vented containers for disposal. Do not return spilled or contaminated material to the inventory. Water Flush eyes with running water for at least 15 minutes with eyelids held open. Seek a specialist. Remove affected person to fresh air. Seek medical attention if the effects persist. If the individual is conscious and not convulsing, give two- four cups of water to dilute the chemical and seek medical attention immediately. Do Not induce vomiting. J:\Operations\MSDS\Regenox Page 4 RegenOx — Part A Section 8 — Measures in Case of Accidents and Fire (cont) Skin Contact: Wash affected areas with soap and a mild detergent and large amounts of water. Section 9 — Accidental Release Measures Precautions: Cleanup Methods: Shovel or sweep spilt material into plastic bags orvented containers for disposal. Do not return spilled or contaminated material to the inventory. Section 10 — Information on Toxicology Toxicity Data LD50 Oral (rat): LD50 Dermal (rabbit): LD50 Inhalation (rat): 2,400 mg/kg Min 2,000 mg/kg Min 4,580 mg/kg Section 11— Information on Ecology Ecology Data Ecotoxicological Information: NA Section 12 — Disposal Considerations Waste Disposal Method Waste Treatment: Package (Pail) Treatment: Dispose of in an approved waste facility operated by an authorized contactor in compliance with local regulations. The empty and clean containers are to be recycled or disposed of in conformity with local regulations. J:\Operations\MSDS\Regenox Page 5 RegenOx — Part A Section 13 — Shipping/Transport Information D.O.T. Shipping Name: Oxidizing Solid, N.O.S. [A mixture of sodium percarbonate [2Na2CO3.3H202], sodium carbonate [Na2CO3], sodium silicate and silica gel.] - UN Number: 1479 Hazard Class: 5.1 Labels: 5.1 (Oxidizer) Packaging Group: III Section 14 — Other Information HMIS° Rating Health — 1 (slight) Reactivity — 1 (slight) Flammability — 0 (none) Lab PPE — goggles, gloves, and lab coat HMIS® is a registered trademark of the National Painting and Coating Association. Section 15 — Further Information The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. J:\Operations\MSDS\Regenox Page 6 Regen OX — Part B (Activator Complex) Material Safety Data Sheet (MSDS) Last Revised: November 7, 2005 Section 1— Supplier Information and Material Identification Supplier: REGENESIS 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8000 Fax: 949.366.8090 E-mail: info@regenesis.com Chemical Description: Chemical Family: Trade Name: Product Use: A mixture of sodium silicate solution, silica gel and ferrous sulfate Inorganic Chemicals Regen Ox — Part B (Activator Complex) Used for environmental remediation of contaminated soils and groundwater Section 2 — Chemical Information/Other Designations CAS No. 1344-09-8 63231-67-4 7720-78-7 7732-18-5 Chemical Silicic Acid, Sodium Salt, Sodium Silicate Silica Gel Ferrous Sulfate Water Section 3 — Physical Data Form: Color: Odor: Melting Point: Boiling Point: Flammability/Flash Point: Vapor Pressure: Liquid Blue/Green Odorless NA NA NA NA RegenOx — Part B Section 3 — Physical Data (cont) Specific Gravity 1.39 g/cm3 Solubility: Miscible Viscosity: NA pH (3% solution): 11 Hazardous Decomposition Oxides of carbon and silicon may be formed when Products: heated to decomposition. Section 4 — Reactivity Data Stability: Stable under normal conditions. Conditions to Avoid: None. Incompatibility: Avoid hydrogen fluoride, fluorine, oxygen difluoride, chlorine trifluoride, strong acids, strong bases, oxidizers, aluminum, fiberglass, copper, brass, zinc, and galvanized containers. Section 5 — Regulations TSCA Inventory Listed: Yes CERCLA Hazardous Substance (40 CFR Part 302) Listed Substance: No Unlisted Substance: Yes SARA, Title III, Sections 302/303 (40 CFR Part 355) — Emergency Planning and Notification Extremely Hazardous No Substance: SARA, Title III, Sections 311/312 (40 CFR Part 370) — Hazardous Chemical Reporting: Community Right -To -Know Hazard Category: Acute SARA, Title IH, Sections 313 (40 CFR Part 372) — Toxic Chemical Release Reporting: Community Right -To -Know Extremely Hazardous No Substance: Page 2 RegenOx — Part B Section 6 — Protective Measures, Storage and Handling Technical Protective Measures Storage: Keep in a tightly closed container (steel or plastic) and store in a cool, well ventilated area away from all incompatible materials (acids, reactive metals, and ammonium salts). Store in a dry location away from heat and in temperatures less than 24 ?C. Do not store in aluminum, fiberglass, copper, brass, zinc or galvanized containers. Handling: Avoid contact with eyes, skin and clothing. Avoid breathing spray mist. Use with adequate ventilation. Do not use product if it is brownish -yellow in color. Personal Protective Equipment (PPE) Engineering Controls: Respiratory Protection: Hand Protection: Eye Protection: Skin Protection: Other: Protection Against Fire & Explosion: General room ventilation is required if used indoors. Local exhaust ventilation, process enclosures or other engineering controls may be needed to maintain airborne levels below recommended exposure limits. Safety shower and eyewash station should be within direct access. Use NIOSH-approved dust and mist respirator where spray mist exists. Respirators should be used in accordance with 29 CFR 1910.134. Wear chemical resistant gloves. Wear chemical safety goggles. A full face shield may be worn in lieu of safety goggles. Try to avoid skin contact with this product. Gloves and protective clothing should be worn during use. Product is non -explosive and non-combustible. Page 3 RegenOx — Part B Section 7 — Hazards Identification Potential Health Effects Inhalation: Eye Contact: Skin Contact: Ingestion: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, and irritations to mucous membranes, nose and throat. Causes irritation, redness and pain. Causes irritation. Symptoms include redness, itching and pain. May cause irritation to mouth, esophagus, and stomach. Section 8 — Measures in Case of Accidents and Fire After Spillage/Leakage (small): After Spillage/Leakage (large): Extinguishing Media: Further Information: First Aid Eye Contact: Inhalation: Ingestion: Skin Contact: Mop up and neutralize liquid, then discharge to sewer in accordance with local, state and federal regulations. Keep unnecessary personnel away; isolate hazard area and do not allow entrance into the affected area. Do not touch or walk through spilled material. Stop leak if possible without risking injury. Prevent runoff from entering into stone sewers and ditches that lead to natural waterways. Isolate the material if at all possible. Sand or earth may be used to contain the spill. If containment is not possible, neutralize the contaminated area and flush with large quantities of water. Material is compatible with all extinguishing media. Flush eyes with running water for at least 15 minutes with eyelids held open. Seek a specialist. Remove affected person to fresh air. Give artificial respiration if individual is not breathing. If breathing is difficult, give oxygen. Seek medical attention if the effects persist. If the individual is conscious and not convulsing, give two-four cups of water to dilute the chemical and seek medical attention immediately. DO NOT induce vomiting. Wash affected areas with soap and a mild detergent and large amounts of water. Remove contaminated clothing and shoes. Page 4 RegenOx — Part B Section 9 — Accidental Release Measures Precautions: PPE: Environmental Hazards: Cleanup Methods: Wear chemical goggles, body -covering protective clothing, chemical resistant gloves, and rubber boots (see Section 6). Sinks and mixes with water. High pH of this material may be harmful to aquatic life. Only water will evaporate from a spill of this material. Pick-up and place in an appropriate container for reclamation or disposal. US regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. Section 10 — Information on Toxicology Toxicity Data Sodium Silicate: When tested for primary eye irritation potential according to OECD Guidelines, Section 405, a similar sodium silicate solution produced corneal, iridal and conjunctival irritation. Some eye irritation was still present 14 days after treatment, although the average primary irritation score has declined from 29.7 after 1 day to 4.0 after 14 days. When tested for primary skin irritation potential, a similar sodium silicate solution produced irritation with a primary irritation index of 3 to abraded skin and 0 to intact skin. Human experience confirms that irritation occurs when sodium silicates get on clothes at the collar, cuffs, or other areas where abrasion may exist. The acute oral toxicity of this product has not been tested. Ferrous Sulfate: LD50 Oral (rat): 319 mg/kg not a suspected carcinogen. Page 5 RegenOx — Part B Section 11— Information on Ecology Ecology Data Ecotoxicological Based on 100% solid sodium silicate, a 96 hour median Information: tolerance for fish of 2,320 mg/1; a 96 hour median tolerance for water fleas of 247 mg/L; a 96 hour median tolerance for snail eggs of 632 mg/L; and a 96 hour median tolerance for Amphipoda of 160 mg/L. Section 12 — Disposal Considerations Waste Disposal Method Waste Treatment: Package (Pail) Treatment: Neutralize and landfill solids in an approved waste facility operated by an authorized contactor in compliance with local regulations. The empty and clean containers are to be recycled or disposed of in conformity with local regulations. Section 13 — Shipping/Transport Information D.O.T. This product is not regulated as a hazardous material so there are no restrictions. Section 14 — Other Information HMIS® Rating Health — 2 (moderate) Reactivity — 0 (none) Flammability — 0 (none) Lab PPE — goggles, Contact — 1 (slight) gloves, and lab coat HMIS® is a registered trademark of the National Painting and Coating Association. Section 15 — Further Information The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Page 6 E. INJECTION PROCEDURE AND EQUIPMENT Construction Plans and Materials: There will be no construction in order to complete the proposed injections. All necessary equipment will be mobilized to the site, the injection will take place, then all equipment will be removed from the site. Operation Procedures: The proposed injection wells, MW-3, MW-5, MW-6, and VMW- 7, will be measured for Depth to Water, Temperature, pH, Oxidation -Reduction Potential (ORP), Dissolved Oxygen (DO), Conductivity, and Alkalinity, then will be hooked up to a pumping system that will be used to inject the Regenoxlm compound. See diagram below: ZEBRA In Situ Injection Setup -od String Is advanced by percussion Infection Probe Assembly Injection Chemical The pumping system will include a gate valve downstream from the pump for restricting the flow, which will, in turn, allow the operator to control the pressure. There will be a pressure gauge mounted on the injection manifold for monitoring pressure. The flow rate and total flow volume will be measured with an in -line flowmeter, similar to the type used for residential water supply lines. Water quality parameters (pH, Temp, Conductivity, DO, ORP, and Alkalinity) will be measured continuously throughout the injection, as well as at the conclusion of each event. Planned Injection Schedule: The first injection event will take place upon approval of this permit application, and the second and third injection events will take place at 30 day intervals afterward. F. MONITORING PLAN Monitoring of monitoring wells MW-3, MW-5, MW-6, and VMW-7 is proposed on a quarterly basis to assess the effectiveness of the application of RegenoxTM. The first quarterly post -injection monitoring event will be conducted approximately 30 days subsequent to the date of injection. Data collected during the post -injection monitoring will be summarized and presented in a quarterly groundwater monitoring letter report. Groundwater samples will be analyzed by EPA Method 624 including B'1'P,X, MTBE, DIPE, EDB, and Naphthalene. Additionally, pH, DO, temperature, ORP, and alkalinity measurements will be collected from the above -referenced monitoring wells during monitoring events subsequent to the injection. G. WELL DATA 2010 Statesville Boulevard Salisbury, North Carolina 28144 Sunoco Facility DUNS #0275-7383 NCDENR Groundwater Incident No. 3519 (3W > �� ' �� VA.a .. a� To a1 De the gfeeett1 .. Of e ) er+R.1, Screened Interxal 2feet fi,,„, .� v ��v �.�}C`dSl3tga r Dia�ineter pinches ' 4 24,,q\ �n? dip .,<T ype p # p,,, 1,: i t 'T" ;Notes y { # < Ri ' .sy MW-1 33.80 7-34 2 Type II MW-2 35.75 7-36 2 Type II MW-3 37.10 7-37 2 Type II MW-4 34.65 7-35 2 Type II MW-5 35.65 7-36 2 Type II MW-6 33.80 3-34 2 Type II MW-7 35.40 7-35 2 Type II VMW-7 54.05 51-54 2 Type III MW-8 33.65 22-34 2 Type II * MW-9 38.48 23-38 2 Type II MW-10 33.40 23-33 2 Type II VMW-11 80.00 75-80 2 Type III MW-13 45.00 20-45 2 Type II RW-12 40.00 10-40 6 Type II Harris Well 25.58 15-26 2 Type II Notes: 1. * Monitoring well MW-8 may have been destroyed by property construction. Potable Wells: Potable Well Property Owner Distance from Site (feet) Hydraulic Position City Water Connection 1920 Statesville Blvd. Anger Family Properties 170 Frances Street Salisbury, NC 28147- 9009 276 Upgradient No 1924 Statesville Blvd. Susan Barber 8965 Sherrils Ford Road Salisbury, NC 28147 360 Upgradient No 2021 Woodleaf Road Dockins 224 Downgradient Yes 2029 Woodleaf Road Ann Miller Kieth 810 Duckview Court Winston-Salem, NC 2740??? 348 Downgradient Yes 2034 Woodleaf Road Harry L. Hipp, Jr. 360 Downgradient No 2035 Woodleaf Road Belle Realty Development 301 N. Main Street P.O. Box 102 Salisbury, NC 28145 408 Downgradient No 2036 Woodleaf Road John H. Hipp 2036 Woodleaf Road Salisbury, NC 432 Downgradient No 2037 Woodleaf Road Pinkston 480 Downgradient No 2101 Woodleaf Road Holly Leaf LLC 407 Riverbend Drive Advance, NC 27006 600 Downgradient No 2102 Woodleaf Road Harry L. Hipp, Jr. 504 Downgradient No 2104 Woodleaf Road George L. Hipp 516 Downgradient No 4b UNITED STATES DEPARTMENT OF THE INTERIOR c OEOLOOICAL SURVEY ROWAN MILLS OUADRANOLE+i mimrre SERIES (TOPOGRAPHIC) N. i %i o,.,.M.,. O. s .,.,. ROWAN MILLS, N. C. FIGURE 1 Site Topographic Map Sunoco 2010 Statesville Boulevard Salisbury, North Carolina Ewrc Environmental Services SOURCE: USGS Topographic Quadrangle for Rowan Mills, NC. Scale 1:24,000 MW-9 6 STRIP MALL SEAFOOD RESTAURANT LEGEND: CI CATCH BASIN O UTILITY POLE • MONITORING WELL (TYPE 1) MONITORING WELL (TYPE 2) O FORMER MONITORING WELL ® AIR SPARGE WELL ® SOIL VAPOR EXTRACTION WELL ago _ inlet-Atm we S HARRIS WELL GRASS MW-8 (DESTROYED) c!N SP-9 c9 VP-3 OSP-10 KEROSENE DISPENSER STATESVILLE BOULEVARD RESIDENTIAL GRASS MW-4 OSP-7 BMW 1 ar ASPHALT PARKING (MOVIE THEATER) VACANT MOVIE THEATER MW-10 MW-13 SIGN GRASS r® iac 375+ 057LT7fi�f63C*34 O 15 FT. REVISION DATE JUNE 22, 2009 SCALE: 1' - 15 FEET REVISED BY: BS FORMER COUNTRY CUPBOARD SUNOCO 2010 STATESVILLE BOULEVARD SALISBURY, NORTH CAROLINA SITE PLAN FIGURE # 2 MW-9 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDE ug/L <1 Tertachloroethene ug/L <1 HARRIS WELL Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L - <1 EDB ug/L <1 Tertachloroethene ug/L <1 MW-11 Benzene ug/L Toluene ug/L Ethylbenzene ug/L Total Xylenes ug/L Total BTEX ug/L MTBE ug/L 1,2—Dichloroethane ug/L EDB ug/L Tertachloroethene ug/L LEGEND: ® MONITORING WELL LOCATION (TYPE 1) $ MONITORING WELL LOCATION (TYPE 2) SOIL VAPOR EXTRACTION WELL O AIR SPARGE WELL • POWER POLE (lk — — — OVERHEAD ELECTRICAL UNE — — — UNDERGROUND ELECTRIC LINE NATURAL GAS LINE — — • — UNDERGROUND TELEPHONE LINE STRIP MALL SEAFOOD RESTAURANT VMW-7 Benzene ug/L 1,600 Toluene ug/L 1,600 Ethylbenzene ug/L 740 Total Xylenes ug/L 4,300 Total BTEX ug/L 8,240 MTBE ug/L <5 1,2—Dichloroethane ug/L <5 EDB ug/L <5 Tertachloroethene ug/L <5 HARRIS ELL MW-7 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDB ug/L <1 Tertachloroethene ug/L <1 PORKEYS BBQ STATESVI LLE BO U LEVAR D MW-6 Benzene ug/L 5 Toluene ug/L 350 Ethylbenzene ug/L 470 Total Xylenes ug/L 2.800 Total ETD( ug/L 3,625 MTBE ug/L 91 1,2—Dichloroethane ug/L 3 EDB ug/L <1 Tertachloroethene ug/L <1 MW-8 (DESTROYED) 0 ASPHALT PARKING (MOVIE THEATER) MW-10 MW-5 Benzene ug/L 39 Toluene ug/L 1 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total bIEX ug/L 40 MTBE ug/L 310 1,2—Dichloroethane ug/L 24 EDB ug/L <1 Tertachloroethene ug/L <1 RESIDENTIAL GRASS VACANT MOVIE THEATER MW-10 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDB ug/L <1 Tertachloroethene ug/L <1 / MW-4 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDB ug/L <1 Tertachloroethene ug/L <1 MW-2 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L . <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDB ug/L <1 Tertachloroethene GRASS Dry — Not Sampled MW-3 Benzene ug/L 590 Toluene ug/L 7,500 Ethylbenzene ug/L 1,700 Total Xylenes ug/L 11,000 Total BTEX ug/L 20,790 MTBE ug/L 360 1,2—Dichloroethane ug/L 42 EDB ug/L 33 Tertachloroethene ug/L <10 ug/L <1 _ MW-13 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDB ug/L <1 Tertachloroethene ug/L 110 Miro r c MINE, SUM SAERRVV7IC/E�S 375 WINKLER (770)777- 1711 AX: (770)m-117766�4 0 10 FT. 20 REVISION DATE JANUARY 9, 2009 SCALE 1' = 20 FEET REVISED BY: T8 FORMER COUNTRY CUPBOARD SUNOCO 2010 STATESViLLE BOULEVARD SALISBURY, NORTH CAROLINA CHEMICALS OF CONCERN, IN GROUNDWATER FIGURE # 4 T MW-9 RESTAURANT HARRIS WELL A ASPHALT r PARKING VMW— VM MW-8 STORAGE TANK ARREEAL1 / M4 —7 /\ \ \ \ \ MN/ —4 \ T MW-5 STATESVILLE BLVD. +RW-12 MW-6 MW-3 MW-1 ASPHALT .1 PARKING B' MW-13 LEGEND MONITORING WELL o VERTICAL DEFINITION MONITORING WELL 4- RECOVERY WELL 100 100 • MIN NMI SCALE FEET SOURCE: JAMES L. HAINES — 6/3/93 SURVEY ODD GROUNDWATER TECHNOLOGY 1000 PERIMETER PARK DR SUITE I MORRISVILLE, NC 27560 (919) 467-2227 REV. NO.: ORA 8 �i6/93 ACAD FILE: 5398—SIT LINES OF GEOLOGIC CROSS -SECTIONS A -A' & B-B' CLIENT: SUN COMPANY, INC. PM: LOCATION: 2001 WOODLEAF RD. SALISBURY, NC DESIGNED: DETAILED: PROJECT NO.: TLW DKP 053245398 'PE/RC: FIGURE: 4 r (4°J) NOI1VA313 700 — 695 - 690 685 680 675 — 670 — 665 - 660 655 - 650 - 645 - 640 635 - 630 - 625 620 - A HARRIS WELL (BDL) GRAVEL (DGA) CLAY CLAYEY SILT PSH PHASE —SEPARATED HYDROCARBONS LEGEND l/ BDL NS VMW-11 (BDL) SILTY SAND (FILL) SILT SAPROLITE BELOW DETECTION NOT SAMPLED LI M IT MW-5 (NS) MW-2 (1 8,540) WELL CASING WELL SCREEN A' MW-13 (BDL) (18,540) TOTAL DISSOLVED BTEX CONCENTRATION (ug/L) BOL TOTAL DISSOLVED BTEX ISOCONCENTRATION CONTOUR (ug/L) .WATER —TABLE ELEVATION (feet) VERTICAL SCALE AS SHOWN 100 0 100 HORIZONTAL SCALE IN FEET SOURCE: WELL LOG INFORMATION LUC ❑ o GROUNDWATER TECHNOLOGY 100D PERIMER R PARK DR SURE 1 N0RRISVLIE, NC 27560 (919) 467-2227 REV. NO.: DRAB/ 1 11 3 GEOLOGIC CROSS-SECTION A -A' ACAD FILE: 5398-XAA PI; SUN COMPANY, INC. LOCATION: 2001 WOODLEAF SALISBURY, NC DESIGNED: DETAILED: PROJECTDR. NO.: FKP. 053245398 TLW PE/RG: FIGURE: .5 ({aal) N011VA313 7 00 - 695 - 690 - 685 680 675 - 670 665 660 655 650 - 645 640 635 630 625 620 — GRAVEL B MWI (BDL) B' MW-1O ,����/•, s**,j I I 0ll (BDL) D L) ,I44.II��I1I 4�Ol4i$';�:`1�*:i110JII a�II♦:Oj4.1�lI„III11A I.IIII�4,.r411./In111.4„II404•44/1.�4+4rszttettiggett-t,,,,effittitiflifietlifis II.I�0s:.I1N�44,f44.I„III11,...IItstistittte,..11`�sIicesiII1.4.IO�1j11I1IIIIIIIIIIIIIIII�11IIIIIIII1II�rIII IIIIlIIIIIOYII�I,IOIIlOIII1/I1IIIIII$11I1IIII11�III1jI�Il11IIIII III1IIO1*111�I/1IIIIIIIIIII�•44$IlI 4/Ir�IIIIIIIII++I++4•4I*4;1$$er��IIIIII04IlIII1l IIIII14�1�I+IIIIr JI11•I14IIIIIIII1114$$#$�IIlIII+1I444IIII1.�1l�jOII5II1I1�IIII11IIIIittiftlit �e1e11 CLAYEY SILT PSH PETROLEUM PHASE HYDROCARBONS MW-7 (PSH) VMW-11 (BDL) LEGEND SILTY SAND (FILL) BDL SAPROLITE BELOW DETECTION LIMIT (BDL) WELL CASING WELL SCREEN TOTAL DISSOLVED BTEX CONCENTRATION (ug/L) TOTAL DISSOLVED BTEX ISOCONCENTRATION CONTOUR _____ WATER —TABLE ELEVATION (feet) (ug/L) VERTICAL SCALE AS SHOWN 100 0 100 HORIZONTAL SCALE IN FEET SOURCE: WELL LOG INFORMATION ❑❑0 GROUNDWATER TECHNO[AGY 000 PERMETER PARK DR SUITE 1 YORRISVILLE. NC 27560 (919) 467-2227 REV. NO.: DRA8N11/ ACAO FlIE` 5398-XBB GEOLOGIC CROSS-SECTION B-B' CUENT: SUN COMPANY, INC. PM: LOCATION: DESIGNED: TLW 2001 WOOOLEAF DR. SALISBURY, NC DETAILED; PROJECT FKP 053245398NO.: PE/RG: FIGURE: 6 2101 \ 2037 \ 2035 2029 s. \� 2021 2104 - / \ 2102 2036 2034 /`. p .Z WATER �'" \\'t�O\/'� `- O TOWER 0 100 200 \ ��\0. / SCALE FEET \%\ // m �' \ �\ O� v / ROAD 2 BELLVUE SOURCE: WITHERS k RAVENEL ENVIRONMENTAL / ENGINEERING. INC. (12/22/92) SITE ( TZT /' SUITE PERIMETER PARK DR. I I to MORRISVILLE. NC 27560 FLUOR DANI[L GTI (919) 467-2227 \� I I 11920I 1000 PERIMETER PARK 0R. 1924 GT DESIGN SUITE I I / SERVICES, INC., P.C. (D19) RRISY6Afi7- 2 7-2227 27560 9 • • REV NO • DRAWING DATE: ACAD FILE: 0245—ARE 9/13/96 PRIVATE WELL INVENTORY MAP JUNE 1996 LEGEND PREVAILING GROUNDWATER FLOW DIRECTION (JUNE 1996) NOTE; THE BOLD NUMBERS SHOWN ON THE PROPERTY PLOTS INDICATE PROPERTIES WITH PRIVATE POTABLE WATER WELLS. TABLE 3 PRESENTS THE NAMES AND ADDRESSES OF THE TWELVE (12) PROPERTY OWNERS LOCATED WITHIN 1 500 FEET OF THE SITE. CLIENT: SUN COMPANY. INC. LOCATION: 2010 STATESVILLE BLVD. SALISBURY, NC DESIGNED: DETAILED: PROJECT NO.: WFB PJC 053240245 PM: NEB PE/RG: TPR FIGURE: 10