HomeMy WebLinkAboutWI0300136_Regional Office Historical File Pre 2018AQUIFER PROTECTION SECTION
APPLICATION REVIEW REQUEST FORM
Date: June 30, 2009
To: ❑ Landon Davidson, ARO-APS
❑ Art Barnhardt, FRO-APS
[Andrew Pitner, MRO-APS
❑ Jay Zimmerman, RRO-APS
From: Thomas Slusser , Groundwater Protection Unit
Telephone: (919) 715-6164 /cS�
E Mail: thomas.slusser@ncdenr.gov
A. Permit Number: WI0300136
B. Owner: SUNOCO
El David May, WaRO-APS
❑ Charlie Stehman, WiRO-APS
❑ Sherri Knight, WSRO-APS
Fax: (919) 71
FECEEIWIE
CDENRiV1R0
N.
DWQ -A • uifer Protection
C. Facility/Operation: FORMER COUNTRY CUPBOARD
❑ Proposed E-Existing 'Facility ❑ Operation"`
D. Application:
1. Permit Type: ❑ Animal ❑ Surface Irrigation ❑ Reuse ❑ H-R Infiltration
❑ Recycle ❑ I/E Lagoon ❑ GW Remediation (ND)
- (5I) in -situ groundwater remediation
For Residuals: ❑ Land App. ❑ D&M ❑ Surface Disposal
❑ 503 ❑ 503 Exempt ❑ Animal
2. Project Type: New ❑ Major Mod. ❑ Minor Mod. ❑ Renewal El Renewal w/ Mod.
E. Comments/Other Information: ❑ I would like to accompany you orl a site visit.
Attached, you will find all information submitted in support of the above -referenced application for your
review, comment, and/or action. Within 30 calendar days, please take the following actions:
[Return a Completed Form APSSRR.
❑ Attach Well Construction Data Sheet.
El Attach Attachment B for Certification by the LAPCU.
El Issue an Attachment B Certification from the RO*.
* Remember that you will be responsible for coordinating site visits, reviews, as well as additional
information requests with other RO-APS representatives in order to prepare a complete Attachment B for
certification. Refer to the RPP SOP for additional detail.
When you receive this request form, please write your name and dates in the spaces below, make a copy
of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person
listed above.
RO-APS Reviewer: Date:
FORM: APSARR 02/06 Page 1 of 1
Beverly Eaves Perdue
Governor
TA-
MCDE
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Coleen H. Sullins
Director
June 26, 2009
Devon Watts
Sunoco, Inc
203 South Falkenburg Road
Tampa, FL 33619
Subject: Acknowledgement of Application No. WI0300136
Former Country Cupboard Sunoco Inc
Injection In situ Groundwater Remediation Well (5I)
Rowan
Dear Devon:
Dee Freeman
Secretary
rocuivE
I JUL -1 2009
NC ❑ENR MRO
DWQ - As uifer Protection
The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit application and
supporting materials on June 26, 2009. This application package has been assigned the number listed above and will be reviewed by
Thomas Slusser.
The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the
maximum efficiency in processing permit applications, the Division requests your assistance in providing a timely and complete
response to any additional information requests.
Please be aware that the Division's Regional Office, copied below, must provide recommendations prior to final action by the
Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete
application.
If you have any questions, please contact Thomas Slusser at 919-715-6164, or via e-mail at thomas.slusser@ncdenr.gov. If the
reviewer is unavailable, you may leave a message, and they will respond promptly. Also note that the Division has reorganized. To
review our new organizational chart, go to http://h2o.enr.state.nc.us/documents/dwq orgchart.pdf.
PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS PROJECT.
Sincerely,
for Debra J. Watts
Supervisor
cc:
rcluirfe Protection S
Scott Dunsmuir (EnviroTracLtd 375 Winkler Drive, Ste E, Alpharetta, GA 30004)
Permit Application File W10300136
AQUIFER PROTECTION SECTION
1636 Mail Service Center, Raleigh, North Carolina 27699-1636
Location: 2728 Capital Boulevard, Raleigh, North Carolina 27604
Phone: 919-733-3221 \ FAX 1: 919-715-0588; FAX 2: 919-715-60481 Customer_Service: 1-877-623-6748
Internet: www.ncwateraualitv.orq
An Equal Opportunity \ Affirmative Action Employer
Tone ,
orthCarol..i Nna
Naturally
State of North Carolina
Department of Environment and Natural Resources
Division of Water Quality
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FO&JN
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer In, jection ^ binJ
♦
• Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject t
• Submit TWO copies of the completed application and all attachments to the address on the Last page of thi
• Any changes made to this form will result in the application package being returned.
Application Number (to be completed by DWQ): eZ 3c20 3-4
I. GENERAL INFORMATION:
1. Applicant's Name (generally the responsible party): Sunoco Inc
2. Signing Official's Name: Devon Watts
3. Mailing address of applicant: 203 South Falkenburg Road
Title: Environmental Specialist
City: Tampa
Telephone number: (813) 654-7789
State: FL Zip: 33619
Fax number: (813) 657-7608
4. Property Owner's Name (if different from Applicant): S Cashion LLC
5. Property Owner's mailing address:
322 E Fisher St
City: Salisbury
State: NC Zip: 28144
6. Name and address of contact person who can answer questions about the proposed injection project:
Name: Scott Dunsmuir
Company: EnviroTrac Ltd
Address: 375 Winkler Drive; Suite E
Title: Operations Manager
City: Alpharetta
Telephone number: (770) 777-1711
Email Address: scottd@envirotrac.com
II. PERMIT INFORMATION:
State: GA Zip: 30004
Fax number: (770) 777-1766
1. Project is: ❑x New ❑ Modification of existing permit ❑ Renewal of existing permit without modification
❑ Renewal of existing permit with modification
2. If this application is being submitted for renewal or modification to an existing permit, provide:
existing permit number and the issuance date
For renewal without modifications, fill out sections I & II only, sign the certification on the last page of this
form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner).
For all renewals, you must submit a status report including monitoring results of all injection activities to
date.
Revised 8/07 UIC-5I/5T RECEIVED I DENR I DWQ
Aquifer Protection Section
JUN 2 4 2009
Page 1 of 7
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
III. INCIDENT & FACILITY DATA
A. FACILITY INFORMATION
1. Facility name: Former Country Cupboard Sunoco Inc
2. Complete physical address of the facility:
2010 Statesville Blvd
City: Salisbury
County: Rowan
State: NC Zip: 28144
B. INCIDENT DESCRIPTION
1. Describe the source of the contamination:
The apparent source of contamination at the site was identified as a combination of a leak from a gasoline UST
that occurred in October 1986 and an aboveground spill of approximately 146 gallons of unleaded gasoline that
occurred during refilling operations in June 1997.
2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g.,
gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc):
Gasoline.
3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)?
❑X Yes If yes, list maximum measured separate phase thickness 2.24 . feet
❑ No If no, list maximum concentration of total VOCs observed at site: ppb
4. Agency managing the contamination incident:
i UST Section ❑ Superfund Section (including REC Program and DSCA sites)
❑ DWQ Aquifer Protection Section ❑ Solid Waste Section
❑ Hazardous Waste Section ❑ Other:
5. Incident managers name Dan Graham and phone number (704) 663-1699
6. Incident number or other site number assigned by the agency managing the contamination incident:
NCDENR Groundwater Incident #3519
C. PERMITS
List all permits or construction approvals that have been issued for the facility or incident, including those not
directly related to the proposed injection operation:
1. Hazardous Waste Management program permits under RCRA:
2. DWQ Non -Discharge or NPDES permits:
3. County or DEH subsurface wastewater disposal permits:
4. Other environmental permits required by state or federal law:
Revised 8/07 UIC-5I/5T Page 2 of 7
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
IV. INJECTION DATA
A. INJECTION FLUID DATA
1. List all proposed injectants.
NOTE: Any substance to be injected as a tracer or to promote in situ remediation must be reviewed by the
Occupational and Environmental Epidemiology Section (OEES) of the Division of Public Health, Department of
Health and Human Services. Review the list of approved injectantsT or contact the UIC Program to determine if
the injectants you are proposing have been reviewed by OEES.
Injectant: Regenox
Concentration at point of injection: Five Percent
Injectant:
Concentration at point of injection:
Injectant:
Concentration at point of injection:
Injectant:
Concentration at point of injection:
Injectant:
Concentration at point of injection:
2. Source of fluids used to dilute or chase the injectants listed above:
❑ None
❑x Municipal water supply
❑ Groundwater from private well or any well within 'A mile of injection site
❑ Air
❑ Other:
3. If any well within'/4 mile of injection site, a private well, or surface water is to be used as the fluid source, supply
the following information:
a. Location/ID number of source:
b. Depth of source:
c. Formation:
d. Rock/Sediment type:
e. In Attachment C, provide a current, complete chemical analysis of the water from the source well, including
analyses for all contaminants suspected or historically recognized in soil or groundwater on the site.
NOTE: If contaminated groundwater is to be used as the dilution or chase fluid, this is not the proper permit
application form. You must apply for a closed -loop groundwater remediation permit using application form
GWRS.
Revised 8/07 UIC-51/5T Page 3 of 7
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
B. PROPOSED OPERATING PARAMETERS
1. Duration of Injection:
Maximum number of separate injection events: Three
Expected duration of each injection event: Eight Hours
Expected duration between events (if more than one event): 30 days
2. Injection rate per well: One gallons per minute (gpm)
3. Total Injection volume: 200 gallons per day (gpd); 200
4. 'Injection pressure: Less than 20 pounds/square inch (psi)
5. Temperature at point of injection: 72 °F
6. Briefly describe how the above parameters will be measured and controlled:
Volume and flow will be measured using an in -line flow meter/totalizer. Pressure will be monitored with a
pressure gauge mounted on the injection manifold. Flow and pressure will be controlled via a gate valve
downstream from the pump, which can restrict the flow, and thereby lower the pressure.
7. Estimated hydraulic capacity of the well: Three gpm
gallons per event (if separate events)
C. INJECTION WELL CONSTRUCTION DATA
1. Injection will be via:
N Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of
your knowledge.
❑ Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as
proposed construction specifications.
2. Well Drilling Contractor's Name: Bore and Core
NC Well Contractor Certification number: 763
3. Date to be constructed: October 1989 Number of borings: Four
Approximate depth of each boring (feet): 35
4. Screened interval/Injection interval of injection wells:.
Depth: 7 to 35 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth).
5. Well casing (N/A if injection is through direct push rods):
Type: ❑x PVC ❑ Stainless steel ❑ Other:
Casing depth: to ft.
6. Grout (N/A if injection is through direct push rods):
Type: N Cement ❑ Bentonite ❑ Other:
Grout depth: 1 to 4 ft.
Revised 8/07 UIC-5I/5T Page 4 of 7
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
V. ATTACHMENTS
Provide the following items as attachments with the given headings:
A. SITE HISTORY
Provide a brief description of the site history including:
(1) site usage historically and present,
(2) origin of the contamination,
(3) previous remedial action(s).
NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the
public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under his or her
direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work which shall have been
prepared or approved by a licensed geologist or a subordinate under his or her direction be signed and sealed by him or
her.
B. HYDROGEOLOGIC DESCRIPTION
Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the
known or projected depth of contamination. The hydrogeologic description shall include:
(1) the regional geologic setting;
(2) significant changes in lithology;
(3) the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a
description of the test(s) used to determine these parameters; and
(4) the depth to the mean seasonal high water table.
C. INJECTION FLUID COMPOSITION
Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety
Data Sheet (MSDS) for each injectant. If a private well or a well within 'A mile of the injection site is used as the source
well, include chemical analysis of source fluid here.
D. INJECTION RATIONALE
Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including:
(1) goals of the injection project;
(2) a description of the reactions between the injectants and the contaminants present including specific breakdown
products or intermediate compounds that may be formed by the injection; and
(3) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change
(biological, chemical or physical) in the subsurface.
E. INJECTION PROCEDURE AND EQUIPMENT
Provide a detailed description of all planned_ activities related to the proposed injection including but not limited to:
(1) construction plans and materials;
(2) operation procedures;
(3) a detailed diagram of the surface and subsurface portions of the system; and
(4) a planned injection schedule.
F. MONITORING PLAN
Provide a plan for monitoring the results of the injection, including:
(1) a list of existing and proposed monitoring wells to be used;
(2) a list of monitoring parameters and analytical methods to be used; and
(3) a schedule for sampling to monitor the proposed injection.
NOTE: The selected monitoring wells must be located so as to detect any movement of injection fluids, process by-
products, or formation fluids outside the injection area or zone. The monitoring parameters should include the target
contaminants as well as secondary or intermediate contaminants which may result from the injection and other
parameters which may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved oxygen, and
Revised 8/07 UIC-5I/5T Page 5 of 7
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated
reactions and rate of transport of the injectants and contaminants.
G. WELL DATA
Provide a tabulation of data on all existing or abandoned wells within 1/4 mile of the injection well(s) which penetrate the
proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells.
Such data shall include a description of each well's use (water supply, monitoring, etc), total depth, screened or open
borehole depth interval, and well construction or abandonment record, if available.
H. MAPS
Attach the following scaled, site -specific maps:
(1) Area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and
showing the location of the proposed injection site.
(2) Site map including:
a. all property boundaries;
b. all buildings within the property boundary;
c. existing and proposed injection wells or well field(s)
d. any existing sources of potential or known groundwater contamination, including waste storage,
treatment or disposal systems within '/ mile of the injection well or well system;
e. all surface water bodies within'/4 mile of the injection well or well system; and
f. all existing or abandoned wells within 1/4 mile of the injection well(s) which penetrate the proposed
injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection
wells.
(3) Potentiometric surface map(s) including:
a. direction of groundwater movement
b. existing and proposed monitoring wells
c. existing and proposed injection wells
(4) Contaminant plume map(s) including:
a. the horizontal extent of the contaminant plume, including isoconcentration lines
b. existing and proposed monitoring wells
c. existing and proposed injection wells
(5) Cross-section(s) to the known or projected depth of contamination, including:
a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines
b. major changes in lithology
Revised 8/07
UIC-51/5T Page 6 of 7
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells - In Situ Groundwater Remediation / Type ST Wells - Tracer Injection
VI. CERTIFICATION
l)euoe Lak
1, (printed name of signing official) , hereby certify under penalty of law that
I have personally examined and am familiar with the information submitted in this document and all attachments
thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information,
I believe that the information is true, accurate and complete. I am aware that there are significant penalties,
including the possibility of fines and imprisonment, for submitting false information. I agree to construct,
operate; maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in
accordance with the approved specifications and conditions of the Permit.
Signature:
vd-h
Title: Environmental Specialist, Southeast
Date: (9- tc?-09
If authorized agent is acting on behalf of the applicant, supply a letter signed by the applicant authorizing the
above agent.
VIl. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant)
("Owner" means any person who holds the fee or other property rights in the well being constructed. A well is
real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of
contrary agreement in writing.)
.00t4l10) L�l Sarcira L. shi n
I, (printed dune of property owner) , as owner of the property on which the
injection well(s) are to be constructed and operated, hereby consent to allow the applicant to construct each
injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure
that the injection well(s) conform to the Well Construction Standards (Title 15A NCAC 2C .0200)
Signature: 0.41dt-/L-OLAAJ-0---
Title: 0\11Y....bd-
Date: 61 /5/aoc,9
Submit TWO copies of the completed application package, including all attachments, to:
UIC Program
Aquifer Protection Section
North Carolina DENR-DWQ
1636 Mail Service Center
Raleigh, NC 27699-1636
Telephone (919) 733-3221
Revised 8/07 UIC-5I/ST
ECEllY
JUL 1 2009
NC DENR MRO
DWQ - A. uifer Protection
RECEIVED / DENR / DWQ
Aquifer Protection Section
JUN 2 4 2009
Page 7 of 7
SIM 3VIIV
A. SITE HISTORY
Site Usage Historically and Present: The Country Cupboard Sunoco is a retail gasoline
and convenience store located at the intersection of Jake Alexander Boulevard (Highway
601) and Statesville Boulevard (Highway 70) in Salisbury, North Carolina. The site is
triangular in shape and approximately one-half acre in size. The 2,000 square foot
convenience store occupies the western half of the property. The site has been occupied
by a retail gasoline station for at least 47 years. The site is currently operating as a
British Petroleum (BP) retail petroleum and convenience store.
Origin of the Contamination: The apparent source of groundwater contamination at the
site was identified as a combination of a leak from a gasoline UST that occurred in
October 1986 and an aboveground spill of approximately 146 gallons of unleaded
gasoline that occurred during refilling activities in June 1987.
Previous Remedial Action(s): IT Corporation submitted a Corrective Action Plan (CAP)
in August 1993. The CAP proposed the use of soil vapor extraction (SVE) to remediate
the hydrocarbon compounds at the subject site. Following approval of the CAP, the SVE
system was activated in April 1994. A CAP Addendum, submitted in October 1996,
proposed the use of air sparging technology to address dissolved -phase petroleum
hydrocarbons in groundwater. Following approval of the CAP Addendum, the air sparge
system was activated on June 11, 1997. The AS/VE system is located at the rear of the
convenience store building. The system consists of an air sparge compressor that injects
compressed air beneath the zone of groundwater contamination through 10 air sparge
wells (SP-1, SP-2, SP-3, SP-4, SP-5, SP-6, SP-7, SP-8, SP-9, and SP-10). The system
also includes a vacuum extraction blower for recovering petroleum hydrocarbon vapors
through nine vapor extraction wells (VP-1, VP-2, VP-3, VP-4, VP-4, VP-5, MW-1, MW-
4, MW-7, and RW-1). The extracted vapors are discharged to the atmosphere.
Through the end of August 2002, the AS/VE system was managed and operated by
Groundwater & Environmental Services (GES). ATC acquired the AS/VE system in
September 2002. In October 2002, ATC personnel visited the site and noted that the
system was not operating. ATC personnel were able to troubleshoot and restart the SVE
blower; however, the air sparge unit required more extensive repair work. After
replacing several parts and hiring a vendor to perform additional maintenance, ATC
personnel restarted the air sparge unit in February 2003.
The AS/VE system has been shut down since June 2007 while remedial alternatives are
being reviewed.
B. HYDROGEOLOGIC DESCRIPTION
Regional Geologic Setting: The Salisbury area is underlain by Paleozoic rocks of the
Carolina Slate Belt, which consist of granite, granodiorite, quartz monzonite, and a
mixture of granite and diorite. These rocks are generally fine to medium -grained and are
easily weathered producing a sandy, clayey saprolite. The saprolite may range in
thickness from a few feet to 50 feet.
Significant changes in lithology: None observed.
Hydraulic Conductivity, Transmissivity, and specific yield of the aquifer to be used for
injection, including a description of the test used to determine these parameters: A rising
head bail test was performed on well MW-3 in lieu of a groundwater pumping test to
assess aquifer characteristics of the saprolite. The bail test was performed on well MW-3
by quickly bailing water from the well until the well was nearly dry. Bailing was stopped
and rising water levels measured with an electric water level probe until the water level in
the well had recovered to near static conditions. A log drawdown versus time recovery
plot of water level data was prepared and evaluated using the Hvorslev method.
The hydraulic conductivity (K) of the saprolite in the vicinity of well MW-3 determined
from the bail test is approximately 1.34 gpd/ft3. This value is within the range for silt,
sandy silts, and clayey silts, and clayey sands presented in the literature. Assuming a
minimum saturated thickness (b) of the saprolite to be 50 feet, then by the relationship T
= Kb, the minimum aquifer transmissivity (T) is approximately 67 gpolft.
Depth to the Mean Seasonal High Water Table: Water levels have been measured at the
site for several years, and it is apparent that he mean water level is approximately 32 feet
below land surface.
C. INJECTION FLUID COMPOSITION
See attached RegenoxTM Brochure. MSDS Sheets for RegenoxTM Part A and
Regenox Part B are also attached.
D. INJECTION RATIONALE
Based on review of historical groundwater analytical data and current site conditions, it
appears that dissolved -phase constituents of concern are isolated to four monitoring well
locations (MW-3, MW-5, MW-6, and VMW-7). Remediation of these areas via active
mechanical remediation may not reduce the current concentrations to the groundwater
governing standards applicable to this site (NCDENR Groundwater Quality 2L Standards)
in an acceptable timeframe. As such, an advanced chemical oxidation technology is
proposed to more rapidly and effectively destroy the targeted groundwater constituents. The
chemical -oxidizing agent (RegenoxTM, which is on the NCDENR approved -chemical list)
will be introduced to the subsurface as a slurry solution via direct -injection (geoprobe grout
pump) using the above -referenced monitoring wells as injection points. Once introduced to
the subsurface, efficient oxidation reactions will occur as a result of three mechanisms
including surface mediated oxidation, direct oxidation, and free radical oxidation.
RegenoxTM, which produces minimal heat, will continue to affect the oxidation process for
up to 30 days on a single injection.
TM
ge
CHEMICAL OXIDATION REDEFINED...
RegenOx- is an advanced in situ chemical oxidation technology* designed to treat organic
contaminants including high concentration source areas in the saturated and vadose zones
PRODUCT FEATURES:
• Rapid and sustained oxidation of target compounds
Easily applied with readily available equipment •
Destroys a broad range of contaminants
.'10 More efficient than other solid oxidants
=u 3 Enhances subsequent bioremediation
ttA'i Avoids detrimental impacts to groundwater aquifers
RegenOx product application
HOW IT WORKS:
RegenOx maximizes in situ performance using a solid alkaline oxidant that employs a sodium percarbonate complex with
a multi -part catalytic formula. The product is delivered as two parts that are combined and injected into the subsurface using
common drilling or direct -push equipment. Once in the subsurface, the combined product produces an effective oxidation
reaction comparable to that of Fenton's Reagent without a violent exothermic reaction. RegenOx safely, effectively and rapidly
destroys a wide range of contaminants in both soil and groundwater (Table 1).
ACHIEVES RAPID OXIDATION VIA A NUMBER OF MECHANISMS
RegenOx directly oxidizes contaminants while its unique catalytic complex generates a suite of highly charged, oxidative free
radicals that are responsible for the rapid destruction of contaminants. The mechanisms by which RegenOx operates are:
=s Surface- Mediated Oxidation: (see Figure 1 and description below)
+ Direct Oxidation: C,CI, + 2 Na,CO, • 3 H2O, + 2 H2O -4--► 2CO2 + 4 NaCI + 4 H2O + 2 H2CO3
Free Radical Oxidation:
— Perhydroxyl Radical (H02')
— Hydroxyl Radical (OH-)
— Superoxide Radical (0,•)
Figure 1. Surface -Mediated Oxidation is
responsible for the majority of RegenOx
contaminant destruction. This process takes
place in two stages. First, the RegenOx activator
complex coats the subsurface. Second, the
oxidizer complex and contaminant react with
the activator complex surface destroying the
contaminant.
* Patent applied for
Figure 1. RegenOx'" Surface -Mediated Oxidation
Contaminants
breakdown
CO2 and H=O
Activator Complex
(Surface),
Contarn"inant
TM
From Mass Reduction to Bioremediation:
RegenOx'" is an effective and rapid contaminant mass reduction technology. A single injection will remove significant amounts
of target contaminants from the subsurface. Strategies employing multiple Regenox injections coupled with follow-on accelerated
bioremediation can be used to treat highly contaminated sites to regulatory closure. In fact, RegenOx was designed specifically to
allow for a seamless transition to low-cost accelerated bioremediation using any of Regenesis controlled release compounds.
Significant Longevity:
RegenOx has been shown to destroy contaminants for periods of up to one month.
Product Application Made Safe and Easy:
RegenOx produces minimal heat and as with all oxidants proper health and safety procedures must be followed. The necessary
safety guidance accompanies all shipments of RegenOx and additional resources are available on request. Through the use of
readily available, highly mobile, direct -push equipment and an array of pumps, RegenOx has been designed to be as easy to
install as other Regenesis products like ORO' and HRC®.
Effective on a Wide Range of Contaminants:
RegenOx has been rigorously tested in both the laboratory and the field on petroleum hydrocarbons (aliphatics and aromatics),
gasoline oxygenates (e.g., MTBE and TAME), polyaromatic hydrocarbons (e.g., naphthalene and phenanthrene) and chlorinated
hydrocarbons (e.g., PCE, TCE, TCA).
Oxidant Effectiveness vs. Contaminant Type:
Activated
Persulfate Persulfate Ozone
Fenton's
Contaminant RegenOx" Reagent Permanganate
Petroleum Hydrocarbons
A
A
B
B
B
A
Benzene
A
A
D
B
B
A
MTBE
A
B
B
C
B
B
Phenols
A
A
B
C
B
A
Chlorinated Ethenes
(PCE, TCE, DCE, VC)
A
-A
A
B
A
A
Chlorinated Ethanes
(TCA, DCA)
A
B
C
D
C
B
Polycyclic Aromatic
Hydrocarbons (PAHs)
A
A
B
B
A
A
Polychlorinated
Biphenyls (PCBs)
B
C
D
D
D
B
Explosives (RDX, HMX)
A
A
A
A
A
A
Based on laboratory kinetic data, thermodynamic calculations, and literature reports.
Oxidant Effectiveness Key:
A = Short half life, low free energy (most energetically favored), most complete
B = Intermediate half life, low free energy, intermediate degree of completion
C = Intermediate half life, intermediate free energy, low degree of completion
D = Long half life, high free energy (least favored), very low degree of completion
REGENESES
Advanced Technologies for Groundwater Resources
1011 Calle Sombra !San Clemente r California 92673-6244
Tel: 949/366-8000 ! Fax: 949:366-8090 ! www.regenesis.com
Regen OX — Part A (Oxidizer Complex)
Material Safety Data Sheet (MSDS)
Last Revised: October 1, 2007
Section 1 — Supplier Information and Material Identification
Supplier:
REGENESIS
1011 Calle Sombra
San Clemente, CA 92673
Telephone: 949.366.8000
Fax: 949.366.8090
E-mail: infocregenesis.com
Chemical Description:
Chemical Family:
Trade Name:
Product Use:
A mixture of sodium percarbonate [2Na2CO3.3H202],
sodium carbonate [Na2CO3], sodium silicate and silica gel.
Inorganic Chemicals
Regen Ox — Part A (Oxidizer Complex)
Used to remediate contaminated soil and groundwater
(environmental applications)
Section 2 — Chemical Information/Other Designations
CAS No.
15630-89-4
5968-11-6
7699-11-6
63231-67-4
Chemical
Sodium Percarbonate
Sodium Carbonate Monohydrate
Silicic Acid
Silica Gel
Percentage
60 -100 %
10-30%
<1%
< 1 %
Section 3 — Physical Data
Form:
Color:
Odor:
Melting Point:
Boiling Point:
Powder
White
Odorless
NA
NA
RegenOx — Part A
Section 3 — Physical Data (cont)
Flammability/Flash Point:
Vapor Pressure:
Bulk Density:
Solubility:
Viscosity:
pH (3% solution):
Decomposition
Temperature:
NA
NA
0.9 — 1.2 g/cm3
Min 14.5g/100g water @ 20 °C
NA
10.5
Self -accelerating decomposition with oxygen release starts
at 50 °C.
Section 4 — Reactivity Data
Stability:
Conditions to
Avoid/Incompatibility:
Hazardous Decomposition
Products:
Stable under normal conditions
Acids, bases, salts of heavy metals, reducing agents, and
flammable substances
Oxygen. Contamination with many substances will cause
decomposition. The rate of decomposition increases with
increasing temperature and may be very vigorous with
rapid generation of oxygen and steam.
Section 5 — Regulations
TSCA Inventory Listed: Yes
CERCLA Hazardous Substance (40 CFR Part 302)
Listed Substance:
Unlisted Substance:
No
Yes
SARA, Title III, Sections 313 (40 CFR Part 372) — Toxic Chemical Release Reporting:
Community Right -To -Know
Extremely Hazardous No
Substance:
WHMIS Classification:
Canadian Domestic
Substance List:
C, D2B
Appears
J:\Operations\MSDS\Regenox Page 2
RegenOx — Part A
Section 6 — Protective Measures, Storage and Handling
Technical Protective Measures
Storage:
Handling:
Oxidizer. Store in a cool, well ventilated area away from
all sources of ignition and out of the direct sunlight. Store
in a dry location away from heat and in temperatures less
than 40 °C.
Keep away from incompatible materials and keep lids
tightly closed. Do not store in improperly labeled
containers.
Protect from moisture. Do not store near combustible
materials. Keep containers well sealed.
Store separately from reducing materials. Avoid
contamination which may lead to decomposition.
Avoid contact with eyes, skin and clothing. Use with
adequate ventilation.
Do not swallow. Avoid breathing vapors, mists or dust.
Do not eat, drink or smoke in the work area.
Label containers and keep them tightly closed when not in
use.
Wash hands thoroughly after handling.
Personal Protective Equipment (PPE)
Engineering Controls:
Respiratory Protection:
Hand Protection:
General room ventilation is required if used indoors. Local
exhaust ventilation, process enclosures or other
engineering controls may be needed to maintain airborne
levels below recommended exposure limits. Avoid
creating dust or mists. Maintain adequate ventilation at all
times. Do not use in confined areas. Keep levels below
recommended exposure limits. To determine actual
exposure limits, monitoring should be performed on a
routine basis.
For many conditions, no respiratory protection is
necessary; however, in dusty or unknown conditions or
when exposures exceed limit values a NIOSH approved
respirator should be used.
Wear chemical resistant gloves (neoprene, rubber, or
PVC).
J:\Operations\MSDS\Regenox Page 3
RegenOx — Part A
Section 6 — Protective Measures, Storage and Handling (cont)
Eye Protection:
Skin Protection:
Other:
Protection Against Fire &
Explosion:
Wear chemical safety goggles. A full face shield may be
worn in lieu of safety goggles.
Try to avoid skin contact with this product. Chemical
resistant gloves (neoprene, PVC or rubber) and protective
clothing should be worn during use.
Eye wash station.
Product is non -explosive. In case of fire, evacuate all non-
essential personnel, wear protective clothing and a self-
contained breathing apparatus, stay upwind of fire, and use
water to spray cool fire -exposed containers.
Section 7 — Hazards Identification
Potential Health Effects
Inhalation: Causes irritation to the respiratory tract. Symptoms may
include coughing, shortness of breath, and irritations to
mucous membranes, nose and throat.
Eye Contact: Causes irritation, redness and pain.
Skin Contact: Causes slight irritation.
Ingestion: May be harmful if swallowed (vomiting and diarrhea).
Section 8 — Measures in Case of Accidents and Fire
After Spillage/Leakage:
Extinguishing Media:
First Aid
Eye Contact:
Inhalation:
Ingestion:
Eliminate all ignition sources. Evacuate unprotected
personnel and never exceed any occupational exposure
limit. Shovel or sweep spilt material into plastic bags or
vented containers for disposal. Do not return spilled or
contaminated material to the inventory.
Water
Flush eyes with running water for at least 15 minutes with
eyelids held open. Seek a specialist.
Remove affected person to fresh air. Seek medical
attention if the effects persist.
If the individual is conscious and not convulsing, give two-
four cups of water to dilute the chemical and seek medical
attention immediately. Do Not induce vomiting.
J:\Operations\MSDS\Regenox Page 4
RegenOx — Part A
Section 8 — Measures in Case of Accidents and Fire (cont)
Skin Contact:
Wash affected areas with soap and a mild detergent and
large amounts of water.
Section 9 — Accidental Release Measures
Precautions:
Cleanup Methods:
Shovel or sweep spilt material into plastic bags orvented
containers for disposal. Do not return spilled or
contaminated material to the inventory.
Section 10 — Information on Toxicology
Toxicity Data
LD50 Oral (rat):
LD50 Dermal (rabbit):
LD50 Inhalation (rat):
2,400 mg/kg
Min 2,000 mg/kg
Min 4,580 mg/kg
Section 11— Information on Ecology
Ecology Data
Ecotoxicological
Information:
NA
Section 12 — Disposal Considerations
Waste Disposal Method
Waste Treatment:
Package (Pail) Treatment:
Dispose of in an approved waste facility operated by an
authorized contactor in compliance with local regulations.
The empty and clean containers are to be recycled or
disposed of in conformity with local regulations.
J:\Operations\MSDS\Regenox Page 5
RegenOx — Part A
Section 13 — Shipping/Transport Information
D.O.T. Shipping Name: Oxidizing Solid, N.O.S. [A mixture of sodium
percarbonate [2Na2CO3.3H202], sodium carbonate
[Na2CO3], sodium silicate and silica gel.] -
UN Number: 1479
Hazard Class: 5.1
Labels: 5.1 (Oxidizer)
Packaging Group: III
Section 14 — Other Information
HMIS° Rating Health — 1 (slight) Reactivity — 1 (slight)
Flammability — 0 (none) Lab PPE — goggles, gloves,
and lab coat
HMIS® is a registered trademark of the National Painting and Coating Association.
Section 15 — Further Information
The information contained in this document is the best available to the supplier at the
time of writing, but is provided without warranty of any kind. Some possible hazards
have been determined by analogy to similar classes of material. The items in this
document are subject to change and clarification as more information become
available. This document is intended only as a guide to the appropriate precautionary
handling of the material by a properly trained person. Individuals receiving this
information must exercise their independent judgment in determining its
appropriateness for a particular purpose.
J:\Operations\MSDS\Regenox Page 6
Regen OX — Part B (Activator Complex)
Material Safety Data Sheet (MSDS)
Last Revised: November 7, 2005
Section 1— Supplier Information and Material Identification
Supplier:
REGENESIS
1011 Calle Sombra
San Clemente, CA 92673
Telephone: 949.366.8000
Fax: 949.366.8090
E-mail: info@regenesis.com
Chemical Description:
Chemical Family:
Trade Name:
Product Use:
A mixture of sodium silicate solution, silica gel and
ferrous sulfate
Inorganic Chemicals
Regen Ox — Part B (Activator Complex)
Used for environmental remediation of contaminated
soils and groundwater
Section 2 — Chemical Information/Other Designations
CAS No.
1344-09-8
63231-67-4
7720-78-7
7732-18-5
Chemical
Silicic Acid, Sodium Salt, Sodium Silicate
Silica Gel
Ferrous Sulfate
Water
Section 3 — Physical Data
Form:
Color:
Odor:
Melting Point:
Boiling Point:
Flammability/Flash Point:
Vapor Pressure:
Liquid
Blue/Green
Odorless
NA
NA
NA
NA
RegenOx — Part B
Section 3 — Physical Data (cont)
Specific Gravity 1.39 g/cm3
Solubility: Miscible
Viscosity: NA
pH (3% solution): 11
Hazardous Decomposition Oxides of carbon and silicon may be formed when
Products: heated to decomposition.
Section 4 — Reactivity Data
Stability: Stable under normal conditions.
Conditions to Avoid: None.
Incompatibility: Avoid hydrogen fluoride, fluorine, oxygen difluoride,
chlorine trifluoride, strong acids, strong bases, oxidizers,
aluminum, fiberglass, copper, brass, zinc, and
galvanized containers.
Section 5 — Regulations
TSCA Inventory Listed: Yes
CERCLA Hazardous Substance (40 CFR Part 302)
Listed Substance: No
Unlisted Substance: Yes
SARA, Title III, Sections 302/303 (40 CFR Part 355) — Emergency Planning and
Notification
Extremely Hazardous No
Substance:
SARA, Title III, Sections 311/312 (40 CFR Part 370) — Hazardous Chemical
Reporting: Community Right -To -Know
Hazard Category: Acute
SARA, Title IH, Sections 313 (40 CFR Part 372) — Toxic Chemical Release
Reporting: Community Right -To -Know
Extremely Hazardous No
Substance:
Page 2
RegenOx — Part B
Section 6 — Protective Measures, Storage and Handling
Technical Protective Measures
Storage:
Keep in a tightly closed container (steel or plastic) and
store in a cool, well ventilated area away from all
incompatible materials (acids, reactive metals, and
ammonium salts). Store in a dry location away from
heat and in temperatures less than 24 ?C. Do not store in
aluminum, fiberglass, copper, brass, zinc or galvanized
containers.
Handling: Avoid contact with eyes, skin and clothing. Avoid
breathing spray mist. Use with adequate ventilation.
Do not use product if it is brownish -yellow in color.
Personal Protective Equipment (PPE)
Engineering Controls:
Respiratory Protection:
Hand Protection:
Eye Protection:
Skin Protection:
Other:
Protection Against Fire &
Explosion:
General room ventilation is required if used indoors.
Local exhaust ventilation, process enclosures or other
engineering controls may be needed to maintain airborne
levels below recommended exposure limits. Safety
shower and eyewash station should be within direct
access.
Use NIOSH-approved dust and mist respirator where
spray mist exists. Respirators should be used in
accordance with 29 CFR 1910.134.
Wear chemical resistant gloves.
Wear chemical safety goggles. A full face shield may
be worn in lieu of safety goggles.
Try to avoid skin contact with this product. Gloves and
protective clothing should be worn during use.
Product is non -explosive and non-combustible.
Page 3
RegenOx — Part B
Section 7 — Hazards Identification
Potential Health Effects
Inhalation:
Eye Contact:
Skin Contact:
Ingestion:
Causes irritation to the respiratory tract. Symptoms may
include coughing, shortness of breath, and irritations to
mucous membranes, nose and throat.
Causes irritation, redness and pain.
Causes irritation. Symptoms include redness, itching
and pain.
May cause irritation to mouth, esophagus, and stomach.
Section 8 — Measures in Case of Accidents and Fire
After Spillage/Leakage
(small):
After Spillage/Leakage
(large):
Extinguishing Media:
Further Information:
First Aid
Eye Contact:
Inhalation:
Ingestion:
Skin Contact:
Mop up and neutralize liquid, then discharge to sewer in
accordance with local, state and federal regulations.
Keep unnecessary personnel away; isolate hazard area
and do not allow entrance into the affected area. Do not
touch or walk through spilled material. Stop leak if
possible without risking injury. Prevent runoff from
entering into stone sewers and ditches that lead to
natural waterways. Isolate the material if at all possible.
Sand or earth may be used to contain the spill. If
containment is not possible, neutralize the contaminated
area and flush with large quantities of water.
Material is compatible with all extinguishing media.
Flush eyes with running water for at least 15 minutes
with eyelids held open. Seek a specialist.
Remove affected person to fresh air. Give artificial
respiration if individual is not breathing. If breathing is
difficult, give oxygen. Seek medical attention if the
effects persist.
If the individual is conscious and not convulsing, give
two-four cups of water to dilute the chemical and seek
medical attention immediately. DO NOT induce
vomiting.
Wash affected areas with soap and a mild detergent and
large amounts of water. Remove contaminated clothing
and shoes.
Page 4
RegenOx — Part B
Section 9 — Accidental Release Measures
Precautions:
PPE:
Environmental Hazards:
Cleanup Methods:
Wear chemical goggles, body -covering protective
clothing, chemical resistant gloves, and rubber boots
(see Section 6).
Sinks and mixes with water. High pH of this material
may be harmful to aquatic life. Only water will
evaporate from a spill of this material.
Pick-up and place in an appropriate container for
reclamation or disposal. US regulations (CERCLA)
require reporting spills and releases to soil, water and air
in excess of reportable quantities.
Section 10 — Information on Toxicology
Toxicity Data
Sodium Silicate:
When tested for primary eye irritation potential
according to OECD Guidelines, Section 405, a similar
sodium silicate solution produced corneal, iridal and
conjunctival irritation. Some eye irritation was still
present 14 days after treatment, although the average
primary irritation score has declined from 29.7 after 1
day to 4.0 after 14 days. When tested for primary skin
irritation potential, a similar sodium silicate solution
produced irritation with a primary irritation index of 3 to
abraded skin and 0 to intact skin. Human experience
confirms that irritation occurs when sodium silicates get
on clothes at the collar, cuffs, or other areas where
abrasion may exist.
The acute oral toxicity of this product has not been
tested.
Ferrous Sulfate: LD50 Oral (rat): 319 mg/kg not a suspected carcinogen.
Page 5
RegenOx — Part B
Section 11— Information on Ecology
Ecology Data
Ecotoxicological Based on 100% solid sodium silicate, a 96 hour median
Information: tolerance for fish of 2,320 mg/1; a 96 hour median
tolerance for water fleas of 247 mg/L; a 96 hour median
tolerance for snail eggs of 632 mg/L; and a 96 hour
median tolerance for Amphipoda of 160 mg/L.
Section 12 — Disposal Considerations
Waste Disposal Method
Waste Treatment:
Package (Pail) Treatment:
Neutralize and landfill solids in an approved waste
facility operated by an authorized contactor in
compliance with local regulations.
The empty and clean containers are to be recycled or
disposed of in conformity with local regulations.
Section 13 — Shipping/Transport Information
D.O.T. This product is not regulated as a hazardous material so
there are no restrictions.
Section 14 — Other Information
HMIS® Rating Health — 2 (moderate) Reactivity — 0 (none)
Flammability — 0 (none) Lab PPE — goggles,
Contact — 1 (slight) gloves, and lab coat
HMIS® is a registered trademark of the National Painting and Coating Association.
Section 15 — Further Information
The information contained in this document is the best available to the supplier at
the time of writing, but is provided without warranty of any kind. Some possible
hazards have been determined by analogy to similar classes of material. The items
in this document are subject to change and clarification as more information
become available. This document is intended only as a guide to the appropriate
precautionary handling of the material by a properly trained person. Individuals
receiving this information must exercise their independent judgment in determining
its appropriateness for a particular purpose.
Page 6
E. INJECTION PROCEDURE AND EQUIPMENT
Construction Plans and Materials: There will be no construction in order to complete the
proposed injections. All necessary equipment will be mobilized to the site, the injection
will take place, then all equipment will be removed from the site.
Operation Procedures: The proposed injection wells, MW-3, MW-5, MW-6, and VMW-
7, will be measured for Depth to Water, Temperature, pH, Oxidation -Reduction Potential
(ORP), Dissolved Oxygen (DO), Conductivity, and Alkalinity, then will be hooked up to
a pumping system that will be used to inject the Regenoxlm compound. See diagram
below:
ZEBRA
In Situ
Injection Setup
-od String Is advanced
by percussion
Infection Probe
Assembly
Injection Chemical
The pumping system will include a gate valve downstream from the pump for restricting
the flow, which will, in turn, allow the operator to control the pressure. There will be a
pressure gauge mounted on the injection manifold for monitoring pressure. The flow rate
and total flow volume will be measured with an in -line flowmeter, similar to the type
used for residential water supply lines.
Water quality parameters (pH, Temp, Conductivity, DO, ORP, and Alkalinity) will be
measured continuously throughout the injection, as well as at the conclusion of each
event.
Planned Injection Schedule: The first injection event will take place upon approval of
this permit application, and the second and third injection events will take place at 30 day
intervals afterward.
F. MONITORING PLAN
Monitoring of monitoring wells MW-3, MW-5, MW-6, and VMW-7 is proposed on a
quarterly basis to assess the effectiveness of the application of RegenoxTM. The first
quarterly post -injection monitoring event will be conducted approximately 30 days
subsequent to the date of injection. Data collected during the post -injection monitoring will
be summarized and presented in a quarterly groundwater monitoring letter report.
Groundwater samples will be analyzed by EPA Method 624 including B'1'P,X, MTBE,
DIPE, EDB, and Naphthalene. Additionally, pH, DO, temperature, ORP, and alkalinity
measurements will be collected from the above -referenced monitoring wells during
monitoring events subsequent to the injection.
G. WELL DATA
2010 Statesville Boulevard
Salisbury, North Carolina 28144
Sunoco Facility DUNS #0275-7383
NCDENR Groundwater Incident No. 3519
(3W >
�� ' ��
VA.a .. a�
To a1
De the
gfeeett1
.. Of e ) er+R.1,
Screened
Interxal
2feet
fi,,„, .� v
��v
�.�}C`dSl3tga r
Dia�ineter
pinches '
4 24,,q\
�n?
dip
.,<T ype
p #
p,,, 1,: i t 'T"
;Notes
y { # <
Ri ' .sy
MW-1
33.80
7-34
2
Type II
MW-2
35.75
7-36
2
Type II
MW-3
37.10
7-37
2
Type II
MW-4
34.65
7-35
2
Type II
MW-5
35.65
7-36
2
Type II
MW-6
33.80
3-34
2
Type II
MW-7
35.40
7-35
2
Type II
VMW-7
54.05
51-54
2
Type III
MW-8
33.65
22-34
2
Type II
*
MW-9
38.48
23-38
2
Type II
MW-10
33.40
23-33
2
Type II
VMW-11
80.00
75-80
2
Type III
MW-13
45.00
20-45
2
Type II
RW-12
40.00
10-40
6
Type II
Harris Well
25.58
15-26
2
Type II
Notes:
1. * Monitoring well MW-8 may have been destroyed by property construction.
Potable Wells:
Potable Well
Property Owner
Distance from
Site
(feet)
Hydraulic
Position
City Water
Connection
1920 Statesville
Blvd.
Anger Family Properties
170 Frances Street
Salisbury, NC 28147-
9009
276
Upgradient
No
1924 Statesville
Blvd.
Susan Barber
8965 Sherrils Ford Road
Salisbury, NC 28147
360
Upgradient
No
2021 Woodleaf Road
Dockins
224
Downgradient
Yes
2029 Woodleaf Road
Ann Miller Kieth
810 Duckview Court
Winston-Salem, NC
2740???
348
Downgradient
Yes
2034 Woodleaf Road
Harry L. Hipp, Jr.
360
Downgradient
No
2035 Woodleaf Road
Belle Realty Development
301 N. Main Street
P.O. Box 102
Salisbury, NC 28145
408
Downgradient
No
2036 Woodleaf Road
John H. Hipp
2036 Woodleaf Road
Salisbury, NC
432
Downgradient
No
2037 Woodleaf Road
Pinkston
480
Downgradient
No
2101 Woodleaf Road
Holly Leaf LLC
407 Riverbend Drive
Advance, NC 27006
600
Downgradient
No
2102 Woodleaf Road
Harry L. Hipp, Jr.
504
Downgradient
No
2104 Woodleaf Road
George L. Hipp
516
Downgradient
No
4b UNITED STATES
DEPARTMENT OF THE INTERIOR
c OEOLOOICAL SURVEY
ROWAN MILLS OUADRANOLE+i
mimrre SERIES (TOPOGRAPHIC) N.
i
%i
o,.,.M.,. O. s .,.,.
ROWAN MILLS, N. C.
FIGURE 1 Site Topographic Map
Sunoco
2010 Statesville Boulevard
Salisbury, North Carolina
Ewrc
Environmental Services
SOURCE: USGS Topographic Quadrangle for Rowan Mills, NC.
Scale 1:24,000
MW-9
6
STRIP
MALL
SEAFOOD
RESTAURANT
LEGEND:
CI CATCH BASIN
O UTILITY POLE
• MONITORING WELL (TYPE 1)
MONITORING WELL (TYPE 2)
O FORMER MONITORING WELL
® AIR SPARGE WELL
® SOIL VAPOR EXTRACTION WELL
ago _ inlet-Atm we S
HARRIS
WELL
GRASS
MW-8
(DESTROYED)
c!N
SP-9
c9
VP-3
OSP-10
KEROSENE
DISPENSER
STATESVILLE BOULEVARD
RESIDENTIAL
GRASS
MW-4
OSP-7
BMW 1
ar
ASPHALT
PARKING
(MOVIE THEATER) VACANT
MOVIE THEATER
MW-10
MW-13
SIGN GRASS
r® iac
375+ 057LT7fi�f63C*34
O 15 FT.
REVISION DATE
JUNE 22, 2009
SCALE:
1' - 15 FEET
REVISED BY: BS
FORMER COUNTRY CUPBOARD SUNOCO
2010 STATESVILLE BOULEVARD
SALISBURY, NORTH CAROLINA
SITE PLAN
FIGURE #
2
MW-9
Benzene ug/L
<0.9
Toluene ug/L
<0.8
Ethylbenzene ug/L
<0.8
Total Xylenes ug/L
<0.9
Total BTEX ug/L
ND
MTBE ug/L
<1
1,2—Dichloroethane ug/L
<1
EDE ug/L
<1
Tertachloroethene ug/L
<1
HARRIS WELL
Benzene ug/L
<0.9
Toluene ug/L
<0.8
Ethylbenzene ug/L
<0.8
Total Xylenes ug/L
<0.9
Total BTEX ug/L
ND
MTBE ug/L
<1
1,2—Dichloroethane
ug/L
- <1
EDB ug/L
<1
Tertachloroethene ug/L
<1
MW-11
Benzene ug/L
Toluene ug/L
Ethylbenzene ug/L
Total Xylenes ug/L
Total BTEX ug/L
MTBE ug/L
1,2—Dichloroethane ug/L
EDB ug/L
Tertachloroethene ug/L
LEGEND:
® MONITORING WELL LOCATION (TYPE 1)
$ MONITORING WELL LOCATION (TYPE 2)
SOIL VAPOR EXTRACTION WELL
O AIR SPARGE WELL
• POWER POLE
(lk
— — — OVERHEAD ELECTRICAL UNE
— — — UNDERGROUND ELECTRIC LINE
NATURAL GAS LINE
— — • — UNDERGROUND TELEPHONE LINE
STRIP
MALL
SEAFOOD
RESTAURANT
VMW-7
Benzene ug/L
1,600
Toluene ug/L
1,600
Ethylbenzene ug/L
740
Total Xylenes ug/L
4,300
Total BTEX ug/L
8,240
MTBE ug/L
<5
1,2—Dichloroethane
ug/L
<5
EDB ug/L
<5
Tertachloroethene ug/L
<5
HARRIS
ELL
MW-7
Benzene ug/L
<0.9
Toluene ug/L
<0.8
Ethylbenzene ug/L
<0.8
Total Xylenes ug/L
<0.9
Total BTEX ug/L
ND
MTBE ug/L
<1
1,2—Dichloroethane ug/L
<1
EDB ug/L
<1
Tertachloroethene ug/L
<1
PORKEYS
BBQ
STATESVI LLE BO U LEVAR D
MW-6
Benzene ug/L
5
Toluene ug/L
350
Ethylbenzene ug/L
470
Total Xylenes ug/L
2.800
Total ETD( ug/L
3,625
MTBE ug/L
91
1,2—Dichloroethane
ug/L
3
EDB ug/L
<1
Tertachloroethene ug/L
<1
MW-8
(DESTROYED)
0
ASPHALT
PARKING
(MOVIE THEATER)
MW-10
MW-5
Benzene ug/L
39
Toluene ug/L
1
Ethylbenzene ug/L
<0.8
Total Xylenes ug/L
<0.9
Total bIEX ug/L
40
MTBE ug/L
310
1,2—Dichloroethane
ug/L
24
EDB ug/L
<1
Tertachloroethene ug/L
<1
RESIDENTIAL
GRASS
VACANT
MOVIE THEATER
MW-10
Benzene ug/L
<0.9
Toluene ug/L
<0.8
Ethylbenzene ug/L
<0.8
Total Xylenes ug/L
<0.9
Total BTEX ug/L
ND
MTBE ug/L
<1
1,2—Dichloroethane ug/L
<1
EDB ug/L
<1
Tertachloroethene ug/L
<1
/
MW-4
Benzene ug/L
<0.9
Toluene ug/L
<0.8
Ethylbenzene ug/L
<0.8
Total Xylenes ug/L
<0.9
Total BTEX ug/L
ND
MTBE ug/L
<1
1,2—Dichloroethane ug/L
<1
EDB ug/L
<1
Tertachloroethene ug/L
<1
MW-2
Benzene ug/L
<0.9
Toluene ug/L
<0.8
Ethylbenzene ug/L .
<0.8
Total Xylenes ug/L
<0.9
Total BTEX ug/L
ND
MTBE ug/L
<1
1,2—Dichloroethane
ug/L
<1
EDB ug/L
<1
Tertachloroethene
GRASS
Dry — Not Sampled
MW-3
Benzene ug/L
590
Toluene ug/L
7,500
Ethylbenzene ug/L
1,700
Total Xylenes ug/L
11,000
Total BTEX ug/L
20,790
MTBE ug/L
360
1,2—Dichloroethane
ug/L
42
EDB ug/L
33
Tertachloroethene ug/L
<10
ug/L
<1
_
MW-13
Benzene ug/L
<0.9
Toluene ug/L
<0.8
Ethylbenzene ug/L
<0.8
Total Xylenes ug/L
<0.9
Total BTEX ug/L
ND
MTBE ug/L
<1
1,2—Dichloroethane ug/L
<1
EDB ug/L
<1
Tertachloroethene ug/L
110
Miro r c
MINE, SUM
SAERRVV7IC/E�S
375 WINKLER (770)777- 1711 AX: (770)m-117766�4
0 10 FT. 20
REVISION DATE
JANUARY 9, 2009
SCALE
1' = 20 FEET
REVISED BY: T8
FORMER COUNTRY CUPBOARD SUNOCO
2010 STATESViLLE BOULEVARD
SALISBURY, NORTH CAROLINA
CHEMICALS OF CONCERN, IN GROUNDWATER
FIGURE #
4
T MW-9
RESTAURANT
HARRIS
WELL
A
ASPHALT
r PARKING
VMW—
VM
MW-8
STORAGE
TANK ARREEAL1 /
M4 —7 /\ \
\ \
\ MN/ —4
\ T
MW-5
STATESVILLE
BLVD.
+RW-12
MW-6
MW-3
MW-1
ASPHALT
.1 PARKING
B'
MW-13
LEGEND
MONITORING WELL
o VERTICAL DEFINITION
MONITORING WELL
4- RECOVERY WELL
100
100
• MIN NMI
SCALE FEET
SOURCE: JAMES L. HAINES — 6/3/93 SURVEY
ODD
GROUNDWATER
TECHNOLOGY
1000 PERIMETER PARK DR
SUITE I
MORRISVILLE, NC 27560
(919) 467-2227
REV. NO.: ORA 8 �i6/93
ACAD FILE:
5398—SIT
LINES OF
GEOLOGIC CROSS -SECTIONS
A -A' & B-B'
CLIENT:
SUN COMPANY, INC.
PM:
LOCATION:
2001 WOODLEAF RD.
SALISBURY, NC
DESIGNED: DETAILED: PROJECT NO.:
TLW DKP 053245398
'PE/RC:
FIGURE:
4
r
(4°J) NOI1VA313
700 —
695 -
690
685
680
675 —
670 —
665 -
660
655 -
650 -
645 -
640
635 -
630 -
625
620 -
A
HARRIS WELL
(BDL)
GRAVEL (DGA)
CLAY
CLAYEY SILT
PSH PHASE —SEPARATED
HYDROCARBONS
LEGEND
l/
BDL
NS
VMW-11
(BDL)
SILTY SAND (FILL)
SILT
SAPROLITE
BELOW
DETECTION
NOT SAMPLED
LI M IT
MW-5
(NS)
MW-2
(1 8,540)
WELL CASING
WELL SCREEN
A'
MW-13
(BDL)
(18,540) TOTAL DISSOLVED BTEX
CONCENTRATION (ug/L)
BOL TOTAL DISSOLVED BTEX
ISOCONCENTRATION CONTOUR (ug/L)
.WATER —TABLE
ELEVATION (feet)
VERTICAL SCALE AS SHOWN
100
0
100
HORIZONTAL SCALE IN FEET
SOURCE: WELL LOG INFORMATION
LUC
❑ o
GROUNDWATER
TECHNOLOGY
100D PERIMER R PARK DR
SURE 1
N0RRISVLIE, NC 27560
(919) 467-2227
REV. NO.:
DRAB/ 1 11 3
GEOLOGIC CROSS-SECTION
A -A'
ACAD FILE: 5398-XAA
PI;
SUN COMPANY, INC.
LOCATION:
2001 WOODLEAF
SALISBURY, NC
DESIGNED: DETAILED: PROJECTDR. NO.:
FKP. 053245398
TLW
PE/RG:
FIGURE:
.5
({aal) N011VA313
7 00 -
695 -
690 -
685
680
675 -
670
665
660
655
650 -
645
640
635
630
625
620 —
GRAVEL
B
MWI
(BDL)
B'
MW-1O
,����/•,
s**,j
I
I
0ll (BDL)
D
L)
,I44.II��I1I 4�Ol4i$';�:`1�*:i110JII a�II♦:Oj4.1�lI„III11A
I.IIII�4,.r411./In111.4„II404•44/1.�4+4rszttettiggett-t,,,,effittitiflifietlifis
II.I�0s:.I1N�44,f44.I„III11,...IItstistittte,..11`�sIicesiII1.4.IO�1j11I1IIIIIIIIIIIIIIII�11IIIIIIII1II�rIII IIIIlIIIIIOYII�I,IOIIlOIII1/I1IIIIII$11I1IIII11�III1jI�Il11IIIII III1IIO1*111�I/1IIIIIIIIIII�•44$IlI 4/Ir�IIIIIIIII++I++4•4I*4;1$$er��IIIIII04IlIII1l IIIII14�1�I+IIIIr JI11•I14IIIIIIII1114$$#$�IIlIII+1I444IIII1.�1l�jOII5II1I1�IIII11IIIIittiftlit
�e1e11
CLAYEY SILT
PSH PETROLEUM PHASE
HYDROCARBONS
MW-7
(PSH) VMW-11
(BDL)
LEGEND
SILTY SAND (FILL)
BDL
SAPROLITE
BELOW
DETECTION
LIMIT
(BDL)
WELL CASING
WELL SCREEN
TOTAL DISSOLVED BTEX
CONCENTRATION (ug/L)
TOTAL DISSOLVED BTEX
ISOCONCENTRATION CONTOUR
_____ WATER —TABLE
ELEVATION (feet)
(ug/L)
VERTICAL SCALE AS SHOWN
100
0
100
HORIZONTAL SCALE IN FEET
SOURCE: WELL LOG INFORMATION
❑❑0
GROUNDWATER
TECHNO[AGY
000 PERMETER PARK DR
SUITE 1
YORRISVILLE. NC 27560
(919) 467-2227
REV. NO.:
DRA8N11/
ACAO FlIE` 5398-XBB
GEOLOGIC CROSS-SECTION
B-B'
CUENT:
SUN COMPANY, INC.
PM:
LOCATION:
DESIGNED:
TLW
2001 WOOOLEAF DR.
SALISBURY, NC
DETAILED; PROJECT
FKP 053245398NO.:
PE/RG:
FIGURE:
6
2101
\ 2037
\
2035
2029
s.
\� 2021
2104 -
/
\
2102
2036
2034
/`. p .Z WATER
�'" \\'t�O\/'� `- O TOWER 0 100 200
\ ��\0.
/ SCALE FEET
\%\ // m
�' \ �\ O� v / ROAD
2 BELLVUE SOURCE: WITHERS k RAVENEL ENVIRONMENTAL
/ ENGINEERING. INC. (12/22/92)
SITE
( TZT /' SUITE PERIMETER PARK DR.
I I to MORRISVILLE. NC 27560
FLUOR DANI[L GTI (919) 467-2227
\� I I 11920I
1000 PERIMETER PARK 0R.
1924 GT DESIGN SUITE I
I / SERVICES, INC., P.C. (D19) RRISY6Afi7- 2
7-2227 27560
9
•
•
REV NO • DRAWING DATE: ACAD FILE: 0245—ARE
9/13/96
PRIVATE WELL
INVENTORY MAP
JUNE 1996
LEGEND
PREVAILING GROUNDWATER
FLOW DIRECTION (JUNE 1996)
NOTE; THE BOLD NUMBERS SHOWN ON
THE PROPERTY PLOTS INDICATE
PROPERTIES WITH PRIVATE
POTABLE WATER WELLS. TABLE 3
PRESENTS THE NAMES AND
ADDRESSES OF THE TWELVE (12)
PROPERTY OWNERS LOCATED
WITHIN 1 500 FEET OF THE SITE.
CLIENT:
SUN COMPANY. INC.
LOCATION:
2010 STATESVILLE BLVD.
SALISBURY, NC
DESIGNED: DETAILED: PROJECT NO.:
WFB PJC 053240245
PM:
NEB
PE/RG:
TPR
FIGURE:
10